analysis of remediation techniques for cadmium- contaminated soils at 62 street dump tampa, fl by:...
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Analysis of Remediation Techniques for Cadmium-
Contaminated Soils at 62 Street Dump
Tampa, FL
By: Rosemary Collins
Overview
Site Background InformationContaminant ReviewPast Remediation Techniques and Analysis
My Remediation Plan
62 Street Dump Started operations in
1960’s as borrow pit Became industrial
disposal site until 1976
Continued as unauthorized disposal site
EPA.gov, 2012
Site Contamination
•Added to NPL in 1983•48,000 cubic yards of waste •Contamination in debris, soil and groundwater•Arsenic, cadmium, chromium, copper, lead, nickel and PCBs
Cadmium
•Trace Metal, Cd(II) ion•No essential biological functions•Few toxicological properties•Water-soluble
http://meganandtehmeedah.blogspot.com/2013
Sources
•Natural: underlying bedrock, transported parent material, and atmospheric deposition•Anthropogenic: fertilizers, pesticides, refined petroleum products, batteries, biosolids and industrial wastes.
Background Concentrations
•Most often occurs in small quantities •Tampa, FL .008-.015ppm (Chen, 1999)
•Zinc Cores: 200-14,000 ppm (ICA)
•FDEP TCLs: •Residential: 82 ppm • Industrial: 1700 ppm
Negative Effects
•High toxicity at low exposures•Direct-contact risk • Eating and drinking contaminated
water•Breathing contaminated air•Negatively impact metabolic
processes/ kidney disfunction
Remediation
• Excavated and treated contaminated soil•Constructed a below-ground wall around
the site •Placed 4.5 acre vegetative cap over site
Started in 1993
http://www.ids-environment.com/environment/us/slurry_wall/192/products.html
Site Update
•Cleanup actions ended in 1995•Deleted from NPL in 1999•Site inspections and GW monitoring are continued annually •Site’s 3rd five year review completed in 2009
In Situ Remediation
•3 Main Strategies: •Removal: Soil Flushing• Isolation: Below-ground wall and Vegetative Cap •Stabilization: Phytoextraction/ Phytostablization
Removal: Soil Flushing
US EPA, A citizens guide to in situ soil flushing, 1996. http://infohouse.p2ric.org/ref/07/06188/
Soil Flushing•Use of Citrate Solution Reagent, 90%
removal (Wasay, McGill Univers., 2000)
•Reduce costs by recycling clean water back to environment•Most efficient at sites with soils
• Relatively homogeneous & permeable• Areas with high water table • Contaminant that is water-soluble
Negatives: Spreading to GW, estimating the completeness of removal
Isolation: Slurry Walls and Cap
•Soil, bentonite and water mixture•Low permeability and chemical resistance at a low cost•Conjunction with capping: 95% effectiveness (FRTR)
•Vegetative Cap
Stabilization: Phytoremediation
•Phytoextraction: remove contaminant from soil and accumulate in roots •Phytostabilization: decrease mobility and bioavailability by adsorbing to roots/rhizosphere
T. caerulescens/ Alpine Pennycress
•Study by Sneller et al. •Cadmium hyperaccumulator •High cadmium uptake and
uptake rate due to Cd-specific transport channels in root membrane •Final: Harvest plants and smelt•Relatively Cheap
Strategy Comparison
ExcavationPro: almost complete removalCon: expensive, dispersal during transport
In SituPro: inexpensive, on site, almost complete removal/isolationCon: long term, trouble determining completeness
Conclusion
•Small area, soil type and moderate level of cadmium contamination make 62 Street Dump perfect location for In Situ Remediation•Cost effective in removing cadmium from soil over time• Improve environment by bringing vegetation back to site
• Agency for Toxic Substances and Disease Registry, Cadmium, CAS number 7440-43-9, Atlanta, GA. http://www.epa.gov/osw/hazard/wastemin/minimize/factshts/cadmium.pdf
• • Chen, M., Ma, L., Harris, W., Hornesby, A., 1999, Background concentrations of trace metals in Florida surface soils: Taxonomic and geographic distribution
of total-total and total-recoverable concentrations of selected trace metals, Report #99-7, p.2-15 to 2-17, University of Florida, Gainesville, FL. • • EnviroTools, Soil, Sediment, Bed, Sludge: Steps to Cleanup, http://www.envirotools.msu.edu/remediation/remedisoilsed.shtml • • Florida Department of Environmental Protection, 2005, Soil Target Cleanup Levels, Table II, p.49• • Federal Remediation Technologies Roundtable. Remediation technology screening matrix and reference guide, version 4.0. Tech: Groundwater, Surface
Water, and Leachate. http://www.frtr.gov/ • • International Cadmium Association, www.cadmium.org , Great Falls, VA• • Lambert, M., Leven, B.A., Green, R.M., New methods for cleaning up heavy metal in soils and water, Environmental Science Technology Briefs for Citizens,
Hazardous Substance Research Centers, Manhattan, KS. • • Lone, M., He, Z., Stofella, P., Yang, X. 2008. Phytoremediation of heavy metal polluted soils and water: progresses and perspective. Journal of Zhejiang
University Science B. p.210-220.• • Martin, T., Ruby, M., 2004, Review of In Situ remediation technologies for lead, zinc, and cadmium in soil. Remediation. Vol 14, Issue 3, P.35-53• • McLean, J., Bledsoe, B., 1992, Behavior of metals in soils, Ground Water Issue, EPA Office of Research and Development, Washington, D.C. • • Mohrherr, C., Liebens, J., Rao, K., 2008, Environmental assessment of sediments and water in Bayou Grande, Pensacola, Fl., University of West Florida,
Pensacola, FL. • • Mulligan, C.N., Yong, R.N., Gibbs, B.F., 2001. Remediation technologies for metal-contaminated soils and groundwater: an evaluation. Engineering Geology.
Vol 60, Issues 1-4, p.193-207• • United States Environmental Protection Agency, Updated July 31, 2012, Sixty Second Street Dump, National Priorities List- Florida, Tampa, FL. • • United States Environmental Protection Agency, August 1997, Technology alternatives for the remediation of soils contaminated with As, Cd, Cr, Hg, and Pb,
Engineering Bulletin. • • Wasay, S.A., Barrington, S., Tokunaga, S. 2001. Organic acids for the in situ remediation of soils polluted by heavy metals: soil flushing in columns. McGill
University, Ste-Anne-de-Bellevue, Canada• • Wuana, R., Okieimen, F., 2011, Heavy metals in contaminated soils: A review of sources, chemistry, risks and best available strategy for remediation, ISRN
Ecology, Volume 2011.