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An industrial example of oscillations in an exothermic reactor http://onlinelibrary.wiley.com/doi/10.1002/cjce.20444/abstract

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Page 1: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

An industrial example of oscillations in an exothermic reactor

http://onlinelibrary.wiley.com/doi/10.1002/cjce.20444/abstract

Page 2: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other
Page 3: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other
Page 4: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other
Page 5: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other
Page 6: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other
Page 7: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

Oscillations can also occur in isothermal reactors with complex reaction kinetics...

http://pubs.rsc.org/en/content/articlelanding/2013/lc/c2lc40649g

Page 8: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

See Supplementary Material, movie showing oscillations,see color changes at top of loop, flashing at bottom are peristaltic pumps http://www.rsc.org/suppdata/lc/c2/c2lc40649g/c2lc40649g.avi

Page 9: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

This is the reaction used in the micro reactor

Page 10: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other
Page 11: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

This reactor had a pulsing feed so the kinetic oscillations are superimposedover the feed pulsing and the limit cycle on right panel is complex

Page 12: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

Briggs-Rauscher https://www.youtube.com/watch?v=_gyzhvMLImg&nohtml5=False Start at 1:50 - sound OK

BZ https://www.youtube.com/watch?v=dMF4RjiITGM Start at 1:24 - music

Page 13: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other
Page 14: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

Oregonator model of BZ reaction

Page 15: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

We will discuss these approximations when we get to surface reactionkinetics over catalyst surfaces

Page 16: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other
Page 17: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

Results from my Matlab program, whichis listed at the endof the Grad CRE Noteson this subject

Page 18: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

Above are well-mixed reactors.

Now to thin layer of reactants approximating a 2D system

https://www.youtube.com/watch?v=3JAqrRnKFHo&nohtml5=False TURN OFF SOUND - MUSIC

Page 19: An industrial example of oscillations in an exothermic reactorreactorlab.net/resources-folder/ceng252/slides_07_April_2016.pdf · But, before you talk to a biologist, there are other

But, before you talk to a biologist, there are other factors involved...An introduction to cell differentiation. “Induction” similar to Turing's ideas.https://www.youtube.com/watch?v=9k4TFJe-ytk

http://rstb.royalsocietypublishing.org/content/royptb/237/641/37.full.pdf