an industrial example of oscillations in an exothermic...
TRANSCRIPT
An industrial example of oscillations in an exothermic reactor
http://onlinelibrary.wiley.com/doi/10.1002/cjce.20444/abstract
Oscillations can also occur in isothermal reactors with complex reaction kinetics...
http://pubs.rsc.org/en/content/articlelanding/2013/lc/c2lc40649g
See Supplementary Material, movie showing oscillations,see color changes at top of loop, flashing at bottom are peristaltic pumps http://www.rsc.org/suppdata/lc/c2/c2lc40649g/c2lc40649g.avi
This is the reaction used in the micro reactor
This reactor had a pulsing feed so the kinetic oscillations are superimposedover the feed pulsing and the limit cycle on right panel is complex
Briggs-Rauscher https://www.youtube.com/watch?v=_gyzhvMLImg&nohtml5=False Start at 1:50 - sound OK
BZ https://www.youtube.com/watch?v=dMF4RjiITGM Start at 1:24 - music
Oregonator model of BZ reaction
We will discuss these approximations when we get to surface reactionkinetics over catalyst surfaces
Results from my Matlab program, whichis listed at the endof the Grad CRE Noteson this subject
Above are well-mixed reactors.
Now to thin layer of reactants approximating a 2D system
https://www.youtube.com/watch?v=3JAqrRnKFHo&nohtml5=False TURN OFF SOUND - MUSIC
But, before you talk to a biologist, there are other factors involved...An introduction to cell differentiation. “Induction” similar to Turing's ideas.https://www.youtube.com/watch?v=9k4TFJe-ytk
http://rstb.royalsocietypublishing.org/content/royptb/237/641/37.full.pdf