utilization of waste plastics coated aggregate for

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UTILIZATION OF WASTE PLASTICS COATED AGGREGATEFOR FLEXIBLE PAVEMENT AND

EASY DISPOSAL OF WASTE PLASTICSDr.R. Vasudevan

PLASTIC SCENARIO

Road side Plastics Waste

Low density polyethylene(LDPE): bags, sacks, bin lining, andsqueezable detergent bottles etc

High density polyethylene(HDPE): bottles of pharmaceuticals, disinfectants,milk, fruit juices, bottle caps etc

Polypropylene (PP): bottle cap and closures, film wrapping forbiscuits, microwave trays for ready-mademeals etc.

Polystyrene(PS): yoghurt pots, clear egg packs, bottle caps, lids

Foamed Polystyrene: food trays, egg boxes, disposable cups,protective packaging etc

Polyvinyl Chloride(PVC): mineral water bottles, credit cards, toys, pipesand gutters; electrical fittings, furniture, binders,folders and pens; medical disposables; etc

PLASTICS – A GOOD FRIEND

50%52%52%% of plastics in packaging

40372272976Plastics in packaging

805443741889Total

1415647203Others

28914034Polyethylene terephthalate -Bottles

1287867489Polyvinyl chloride(PVC) – Tubes

1790885340Polypropylene(PP) – Bags

32671835823Polyethylene (PE) – Carry bags

2006-072001-021995Polymer

(Thousand tones)(Thousand tones)

CPCB report: 4000 t/a (1990) to 40 lac.t/a (2001).

80000 tons/D waste(2006)

World Rank (INDIA) - III ( 4.0 kg :20 kg)Tamil Nadu - 2.4 lac. Tons IN 2003. 4.5 IN 2006

( 7000 industries with 7 lac. workers )

Major plastics in use – Polyethylene(Cups,bottle,bags. Etc) - Polypropylene 80%

- Polystyrene

Tubes - Poly vinyl chloride - 10%PET - 8 % Recycling - 55%

Problems – non- biodegradableaccumulation of waste with MSWdisposal technique andpeople garbage culture

Plastics areindispensable

PRESENT SCENARIO

BAN

PVC – Pipes

Others

PET – Bottle

PE, PP & PS - films

Bio-based Polymers

TOXICITY

INCREASE

Flex Board: PVC

CO,CO2>700CH4, C2H6270-350No gas110-140

PEPPPS

Products

reported

Ignitiontemp.

range inDeg. C

Productsreported

Decom.temp.range

in Deg.C

Productsreported

Soften.point

Type ofPolymer

THERMAL BEHAVIOUR

PVCPVC –– not considerednot considered

Chemical reactionChemical reaction (700 deg)(700 deg)

PE, PP, PSPE, PP, PS C, CO, COC, CO, CO22 but nobut no ClCl22

Use of PE, PP and PS can not liberate dioxin even onUse of PE, PP and PS can not liberate dioxin even onburningburning ..

PVCPVC C, CO, COC, CO, CO22 and Cland Cl22 andand HClHCl

C + OC + O22 + Cl2 Cu II Catalyst+ Cl2 Cu II Catalyst DioxinDioxin300300 ––350350 deg.Cdeg.C

PVC alone on heating may result in dioxin formationPVC alone on heating may result in dioxin formation(300(300--350 deg. C)350 deg. C) (reverse cooling(reverse cooling))

PE - (-CH2- CH2-)n PP - (-CH2- CH(CH3)-)n

PS - (-CH2- CH(C6H5)-)n PVC - (-CH2- CH(Cl)-)n

DIOXIN

l Source- Chlorine related pesticides– Chlorinated solvents– Bleaching– Chlorination of water– Leaded petrol– PVC

• Better Road

• Use of Waste Plastics

• Saving of Bitumen

• Cost Less

• Solid Waste into Manure

• Job for Self Help Group

Specialties

Plastic Tar Road -A New Path way

A small step towards…

AGGREGATES HOT AGGREGATES

POLYMER COATEDAGGREGATE BITUMEN MIXTURE ROAD LAYING (120°.C)

170 °C

HOTBITUMEN160 °C

POLY.COATEDAGGREGATES

Wasteplastics

WASTE PLASTICS COATED AGGREGATE- BITUMEN MIXProcess Outline

Plastics wastePlastics waste –– Cleaning processCleaning process

ShreddingShredding

Required sizeRequired sizewastewaste

Mini Hot Mix Plant

Aggregate heated To 170°c

Aggregate Transferred topuddling chamber

Waste Plastics mixed With the hotaggregate

Coated Aggregate Plain Aggregate

Bitumen added

Aggregate-plastics-bitumen mix

Polymer-Tar Road

SAVE

BITUMEN ENVIRONMENT

COST

CENTRAL MIXINGPLANT

PLASTICS – TAR ROAD

1. Better binding property2. Higher Softening point; withstands high temp.3. Lower penetration value; withstands higher load4. No stripping – Resists the permeation of water5. Higher Marshal Stability–increased strength of road6. Operation temperature range: 160-170 deg.C7. Cost less compared to CRMB.

Waste Plastics ( MSW, road side etc.)8. Better disposal of waste plastics9. No toxic gas evaluation - No to Dioxin10. Waste plastics Disposal - No longer a problem

PATH WAYBLOCKS

SPEED BREAKERNeeds 20 blocks

PLASTIC TARROAD

Road Area: Bitumen- 100kg, Plastics – 10kg

Block: Plastic-88kg

Speed Breaker: Plastics- 6.25kg

10m

1m

3.75m

1 LAKH CARRY BAGS DISSAPPEARS IN 10M2 AREA

Toevaluated

100%250gmsNIL1m X 1mRoofingSheets

20%NIL40 tonsNIL1kmX 3.75Block

Road

Products

Rs,15,0001 tonnes1 tonnes9 tonnes1kmX 3.75m

Costreduced

Bitumensaved

Plasticsneeded

Bitumenneeded

Area

Plastic Tar Road Cheap and Good

Laid – March 2005

NOVEMBER 2006March 2006

Velacherry Main Road at Madurai

Date: 18-02-2007

Trisool Road

Laid at April 2004

Photo Date Jan2007

Kovilpatti Lenin Street

Laid at 4th october 2002

Photo date Jan 2007

Jambulingam Street Roadat Chennai

Laid Date:22-11-2002

Photo date : Jan 2007

SCIENTIFIC IMPORTANCE OFPLASTIC TAR ROAD

AggregateAggregate Waste plastics

140140°°CC

BlockBlockC.SC.S –– 300tons300tons

F.SF.S –– 2000 kg cm2000 kg cm..

(moment)(moment)

Waste Plastics – a Binder

PORTABLE SpeedBreaker Model

Binding Property

39032030

35029025

33527020

32525010

BendingStrength (Kg)

Compression Strength( Tonnes)

Percentage ofplastics coatingover aggregate

Coating Over Stone Improves QualityVoid Characteristics

NilNiltraces3%

1%Nil1.1%2%

2.2%Nil2%1%Withplasticcoating

4%~54%0Withoutplasticcoating

VoidsSoundnessMoistureAbsorption

Percentageof PlasticStone

Aggregate

•• Aggregate Coated with plain BitumenAggregate Coated with plain BitumenShows 5% stripping after 24 hoursShows 5% stripping after 24 hours

Bitumen Coating over PCABitumen Coating over PCARESISTANCE TO STRIPPINGRESISTANCE TO STRIPPING

• Aggregates coated with Plastics Wastefollowed by bitumen Shows Nil Strippingeven after 72 hours

No Pot Hole FormationNo Pot Hole Formation

83.676.761.339.72.551.0149.82

90.786.763.231.42.60.8050.33

92.388.763.52.422.50.6150.13

99.098.096.0-2.5-50.01

BitumenRemove

d(%)

BitumenRemove

d(%)

BitumenRemove

d(%)

15Minutes

10Minutes

5Minutes% of

Plasticsadded(gm)

Bitumen(gm)

Plastics

PE(gm)

Aggregate(gm)

Removal of Bitumen Difficult

Improved binding

Extraction of Bitumen from bitumen/PCA

4.525005.4

3.725205.0

2.725404.6

2.525204.5

2.219604.2

Flow value(mm)(2-4)

MarshallValue Kg

% of Bitumen(10% WP

Modified mix Properties

Standard Marshall Value = 1100kg

Plastic Roads – Increase Strength

% of Bitumen % of PolymerWith respect to bitumen

Marshall Value Kg

4.6 0 1150

4.6 5 2010

4.6 10 2540

4.6 15 2440

4.6 20 2300

5.0 15 2670

5.0 20 2040

5.5 20 1830

MIX MODIFIER

3044.10125050.10

5154.75245050.50

4064.70191050.25

M/Q(kg/mm)

Flow value(mm)

MarshallStability

Value(Kg)

% of Bitumenadded in the

mix

% of PlasticsWaste

added in themix

MSV for Polymer coated aggregate - bitumen mix

1. Aggregate

2. Plastics bonded with aggregate (polymer coating)

3. Bitumen–plastics blend (due to diffusion between molten plastics &hot bitumen)

4. Loosely bonded bitumen with dispersed plastics5. Plain bitumen

1 2 3 4 5

RECOGNITION

VisionBecome(path)Wayof Life

VisionAppreciation

Recent Successes

• 1000 km DRDA road laid by Tamil Nadu• Banners removed from Buses• Approval from CPCB• Plastics company Red to Green• The performance of the laid road• Public responses• Foreign Govt’s interact• Road at Mumbai• Interaction at Ranchi

Special Note: Roads are being laid using waste plastics throughout Tamilnaduunder the Scheme titled, ‘1000 km Plastic Tar Road’ as announced byHonourable Chief Minister of Tamil Nadu on 16th August 2003 at Namakkal, bythe Department of Rural Development Agency.

Block places Plastic – Tar Road Laid

Plastic materials ( PE, PP & PS ) usedPlastic materials ( PE, PP & PS ) usedNo LeachingStay on the RoadNo soil pollutionHeating to approx.160 deg.Less water diffusionRising temperature duringTraffic no effectNo dioxin formationBetter UV stabilization

No thermal decomposition

Acts as safe area for land filling.Acts as safe area for land filling.Avoids incineration.Avoids incineration.

Mumbai

How safe the road

Promotional efforts1000 kms of road – as ordered byHonourable Chief Minister of TamilNadu.Training programme for Engineers,Self Help Groups.

A Model Road at Pondicherry -Honourable Chief Minister ofPondicherry.

Chennai Corporation has laid 12 roads.

Model plastics tar roads at 20Majors Cities in TN.

Plastics – Tar Road at ThiagarajarCollege of Engineering,

CPCB Delhi has signed MoU withThiagarajar College of Engineering,Madurai on Plastics road.

policy note by TN Highways on layingPlastics – Tar Road.

Pamphlet released by TNGovt.

NEED OF THE HOUR

-- Awareness creation to SocietyAwareness creation to Society

-- Students involvementsStudents involvements

-- Mass media’s helpMass media’s help

-- Healthy Garbage cultureHealthy Garbage culture

-- Discipline in public houses.Discipline in public houses.

-- Government supportGovernment support

ØØ GrowthGrowth

ØØ EmploymentEmployment

ØØ SafeSafeØØ UtilityUtility

ØØ CheapCheap

ØØ Reuse of PolymersReuse of PolymersØØ ResearchResearchØØ solution of socialsolution of socialØØ problemproblem

GOVTGOVT INDUSTRYINDUSTRY

ØØ ‘‘Waste disposal’Waste disposal’

ØØ Solution for pollutionSolution for pollution

ØØ HygieneHygiene

PUBLICPUBLIC INSTITUTIONINSTITUTION

PlasticPlastic

The wonder materialsThe wonder materials

Land Filling

Postponement

Of Solution

• Water flow seepage affected• Land soil gets polluted• Solid waste --- Not disposed properly.• Non-availability of natural manure• Space not available

•Soil microbe activity reduced

• Water line clogging – CH4 evolution green house effect

IncinerationIncineration

• Burning or ˜\ 700-1100º C Toxic gases like• Incineration CO, CO2 & ash ( oxides)

• Air Pollution (dust, etc.,)• Loss of solid waste• Global warming• Monsoon failure• Cost is more• Improper technology• Dioxin ?

Brahma Siva

Vishnu

Protectionbetter road andpollutionprevention

Destruction ofPolymer Material

Creation of Blend

REUSE

Our Team

DR.R. VASUDEVANDR.R. VASUDEVANA.RAMALINGA CHANDRAA.RAMALINGA CHANDRASEKARSEKARB. SUNDARAKANNANB. SUNDARAKANNAN

Newer Products Using PlasticsNewer Products Using Plastics

1.1. Path way BlocksPath way Blocks** High compressive Strength (150 tons)High compressive Strength (150 tons)* High Flexural strength* High Flexural strength (250kg)(250kg)* High volume of Plastics utilization* High volume of Plastics utilization* Patent No:* Patent No: 0220/MAS/030220/MAS/03

2. Roofing Sheets2. Roofing Sheets** Better StrengthBetter Strength* Polymer Blend* Polymer Blend* Newer technologies for preparation* Newer technologies for preparation* Less moisture absorption* Less moisture absorption

3. Corrosion MS Rod3. Corrosion MS Rod

other productsother products –– Mastic flooring materialsMastic flooring materials

We WelcomeWe Welcome

Your interactionYour interaction

With us.With us.

TCE whereQuality and Ethics

Matter

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