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Process Safety Management of Highly Hazardous Chemicals

29 CFR 1910.119 (PSM)

Disasters That Led to Process Safety Management

Bhopal, India (1984)–2,000 deaths Isocyanate release

Pasadena, TX (1989)–23 deaths, 132 injuries Petroleum explosion

Cincinnati, OH (1990)–2 deaths Explosion

Sterlington, LA (1991) –8 deaths, 128 injuries Chemical release

Clean Air Act Amendments—1990

Requires Secretary of Labor along with EPA to promulgate a PSM standard

PSM standard must include a list of highly hazardous chemicals

Highly hazardous chemicals list must include: toxics, flammables, highly reactive and explosive materials

Minimum Program Requirements

Written safety information Workplace hazard assessment Consult with employees Establish a system to respond to findings Periodic review of assessments and response Written operating procedures Safety training and operating information

Minimum Program Requirements (cont.)

Appropriate information and training for contractors

Train and educate employees in emergency response

Establish a quality assurance program Establish maintenance systems Pre-start-up safety reviews Management of change Incident investigation

Application of PSM

Companies that process highly hazardous materials

Flammable liquids and gases in quantities in excess of 10,000 pounds

Initial Process Hazard Analysis Deadlines

25% complete by May 26, 1994 50% complete by May 26, 1995 75% complete by May 26, 1996 100% complete by May 26, 1997

Process Safety Information

Toxicity Permissible

Exposure Limits Physical Data Reactivity Data Corrosivity Data Thermal and Chemical

Stability Data

Process Technology

Block flow diagram or process flow diagram Process chemistry Maximum intended inventory Upper and lower limits Consequences of deviations

Information on Process Equipment

Materials of construction Piping and instrument diagrams (PIDs) Electrical classification Relief system design Ventilation system design Design codes Material and energy balances Safety systems

Items the PHA Must Address

Hazards of the process Identification of previous incidents Engineering and administrative controls Consequences of failure Facility siting Human factors Qualitative evaluation of S and H effects

Operating Phases

Initial start-up Normal operations Temporary operations Emergency shutdown Emergency operations Normal shutdown Start-up following turnaround

Operating Limits

Consequences of deviation Steps required to correct or avoid deviation

Safety and Health Considerations

Properties and hazards of the chemicals Precautions to prevent exposures Control measures to be taken Quality control for raw materials/

control of inventory Special or unique hazards Safety systems and their functions

Management of Change

Technical basis for the proposed change Impact of the change on safety and health Modifications of the operating procedures

Necessary time period for the change Authorization requirements for the change

Training Requirements

Initial training–Prior to work assignment–Waved for those already in a process

Refresher training–Every three years

Training documentation

Contractor Requirements

PSM applies to contractors in or adjacent to a process performing

–Maintenance–Repair–Turnaround–Major renovation–Specialty work

Does not apply to incidental contractors–Food service–Laundry–Delivery, etc.

Incident Investigation Reports

Date of incident Date investigation began Description of the incident Factors contributing to the incident Recommendations resulting from

the investigation

Quiz

1. The Process Safety Management Standard was drafted as a requirement of the Clean Air Act. True or False

2. The PSM program must include a list of highly hazardous chemicals. True or False

3. The initial start-up of a process is not included as an operating phase under the PSM Standard. True or False

4. List three items that the process hazard analysis must address. ___________, __________ and __________.

5. PSM does not apply to contractors, regardless of the work they are doing. True or False

Quiz (cont.)

6. The PSM Standard applies to companies that either process highly _____________ materials or use _____________ liquids and gases in excess of 10,000 pounds.

7. Process safety information includes:______________, _____________ and _____________.

8. Fault tree analysis is one form of an approved method of performing a process hazard analysis. True or False

9. A technical basis is not required to change a process covered by the PSM Standard. True or False

10.Two types of training required by the PSM standard are ________________ and_________________.

Quiz Answers1. True. The Process Safety Management Standard was drafted as a

result of the Clean Air Act Amendments of 1990.

2. True.3. False. The initial start-up of a process is an operating

phase that must be included.4. The items that a process hazard analysis must address include

hazards of the process, identification of previous accidents, engineering. and administrative controls, consequences of failure, facility citing, human factors, and qualitative evaluation of S and H effects.

5. False. PSM does apply to contractors who work on or adjacent to a process.

Quiz Answers (cont.)

6. The PSM Standard applies to companies that either process highly hazardous materials or use flammable liquids and gases in excess of 10,000 pounds.

7. Process safety information includes toxicity, permissible exposure limits, physical data, reactivity data, corrosivity data, and thermal and chemical stability data.

8. True. Fault Tree Analysis is one form of an approved method of performing a process hazard analysis.

9. False. All change must have a technical basis in order to be authorized.

10. Two types of training required by the PSM standard are initial and refresher.

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