oxygen scavenger,ethylene and other scavengers
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05/03/2023
1
OXYGEN SCAVENGER,ETHYLENE AND OTHER SCAVENGERS
Prepared by:SWAPNIL PRASHANT GAUTAMM.TECH (FOOD) 2 YEAR
15/PFT/007
2WHAT IS SCAVENGER? A scavenger in chemistry is a chemical substance added to a mixture in
order to remove or inactivate impurities or unwanted reaction products.
What is oxygen scavenger? Oxygen scavengers are added to enclosed packaging to
help remove or decrease the level of oxygen in the package.
3WHY OXYGEN SCAVENGER
The residual oxygen in a food package is main cause for food deterioration.
Oxygen is the main cause for food deterioration due to oxygen of fats ,oils and growth of aerobic m.o
Oxygen is well known to accelerate processes leading to discolouration, change in texture,rancidity,off flavor,off odour.
Oxygen Scavengers
presence of oxygen in food packages
-accelerates the spoilage of many foods.-cause off-flavour development-colour change-nutrient loss-microbial attack
Mechanisms of action of Oxygen Scavengers
a.) Oxidation of iron and iron salts
oxidation of iron and ferrous salts (provided in the packet) that react with water provided by food to produce a reaction that moisturizes the iron metal in the product packaging and irreversibly converts it to a stable oxide.
The iron powder is contained within small oxygen permeable bags that prevent contact with food. 4Fe (OH)2 + O2 + 2H2O→4Fe(OH)3
TYPES OXYGEN SCAVENGERS materials incorporated into package structures that
chemically combine with, and thus effectively remove, oxygen from the inner package environment
eg:- ferrous compounds, catechol, ascorbic acid and its analogues, ligands, oxidative enzymes such as glucose oxidase, unsaturated hydrocarbons and polyamides
OXYGEN INTERCEPTORS
blocks the adverse effect of oxygen in the air on the food, before the oxygen can enter the food.
OXYGEN ABSORBERS absorbers remove oxygen by physically
trapping the oxygen and not through chemical reaction
ANTIOXIDANTS compounds that react with lipid or peroxide
radicals or, in light, with singlet oxygen, and that are themselves oxidized to generate what are generally innocuous nontoxic compounds
BHA—butylated hydroxyanisole BHT—butylated hydroxytoluene PG—propyl gallate
Selection of the oxygen scavenger, considerations :
The nature of the food, such as size, shape and weight
The moisture content and water activity
The initial (residual) oxygen content in the package head-space
The amount of oxygen dissolved in the product
The maximum allowable oxygen intake to end product shelf-life
The packaging material permeability to oxygen.
EVOH as an oxygen barrier layer for prolonging the shelf-life of foods
plastic packaging systems (containing ethylene-vinyl alcohol copolymer (EVOH)
ADVANTAGES prevent oxidation phenomena: rancidification
of fats and oils and consequent emergence of off-odours and off-flavours, loss or change of colours characteristic of food, loss of oxygen-sensitive nutrients
prevent the growth of aerobic microorganisms.
reduce or eliminate the need for preservatives and antioxidants
slow down metabolism of food.
Principles
Ethylene is a plant hormone that accelerates the respiration rate
and subsequent senescence of horticultural products such as fruit,
vegetables and flowers. Many of the effects of ethylene are
necessary.
Ethylene is a very reactive compound that can be altered in many
ways, such as chemical cleavage and modification, absorption,
adsorption, etc. This creates a diversity of opportunities for
commercial applications for the removal of ethylene.
Ethylene scavengers
Ethylene Blocking Technologies
1-Methylcyclopropene (1-MCP). 1-MCP is the most widely used
commercial volatile ethylene inhibitor, which blocks ethylene binding
sites.
Silver thiosulfate (STS). The use of this material is largely restricted to
cut flowers and it is sold commercially under the trade name Chrysal
AVB®.
Aminoethoxyvinylglycine (AVG). This material is sold commercially as
ReTain® and acts as a plant growth regulator by blocking the
production of ethylene in the plant tissue.
Examples
activated alumina, vermiculite, and silica gel that have been impregnated with potassium permanganate (KMnO4).
Activated charcoal alone or after impregnation with bromine.
bentonite, Kieselguhr, and crystalline aluminosilicates, e.g., zeolites, have been reported capable of adsorbing ethylene
Carbon dioxide generators and absorbers
PrinciplesCarbon dioxide generators --- packaging for fresh produce where an increased
concentration of CO2, combined with decreased O2 concentration, reduces the
respiration rate thus increasing the product shelf-life
-- Emitters is in the packaging of meat products where a high level of CO2 may
inhibit microbial growth.
--Commercial solutions commonly used are the incorporation of a one-way valve
and more recently, the inclusion of a CO2 absorbing sachet.
Carbon Dioxide Generating System
High level of CO2 (10-80%) inhibits surface microbial growth and extends shelf life
EXAMPLES1. ferrous carbonate 2. mixture of ascorbic acid and sodium
bicarbonate
Fresh meat, poultry, fish, cheeses and strawberries
Commercial examples
Examples of generators or emitters include: Ageless G, Toppan
C and Vitalon GMA, although most of the carbon- and earth-
activated based ethylene absorbers also claim carbon dioxide
absorption capacity.
Ageless G is a self-working type, based on ascorbic acid
oxidation mechanism, and absorbs oxygen and generates an equal
volume of CO2. Examples of absorbers include Ageless E,
which also functions as oxygen scavenger.It is based on
powdered iron and calcium hydroxide
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