innova've)packaging)solu'ons)) for)bioeconomy)sector”) · „biotechnological...

"Innova've)packaging)solu'ons))

for)bioeconomy)sector”)

Workshop(on(Realizing(the(Bioeconomy((in(the(Bal6c(Sea(Region(–(Warsaw(4;5.03.2015!

Artur!Bartkowiak!West!Pomeranian!University!of!Technology!

!in!Szczecin!

CBIMO)structure)and)interna'onal)collabora'on)

Regional specializations

bioeconomy)

mari'me)&)logis'cs)

metal?machine)industry)

services)of)the)future)

tourism)&)health)

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Investors’)Assistance)Center)

www.iac.wzp.pl

Smart)specialisa'ons)in)West)Pomeranian)region)

Bioeconomy wood?furniture)sector,)fish)processing,)agri?food)sector,)

renewable)energy,)green)chemistry,)materials)science,)

packaging)

13)000)SMEs)

90)000)employed)

25)billion)PLN)revenue)

9)billion)PLN)export)

52%)of)export)

CLUSTERS:)Wood)&)Furniture)in)Koszalin,)Green)Chemistry,))

Construc'on)Cluster,)Green)Locomo've,)sEaNERGIA)

•)

•)

•)

•)

•)

•)

•)

Investors’)Assistance)Center)

www.iac.wzp.pl

“Smart”)specialisa'ons)in)West)Pomeranian)region)

Energy!

!!Raw!material!!!!!!!!!!!!!!Product!

Environment)

Human!

The)main)idea)of)West)Pomeranian)Centre)of)Bioeconomy))

OUR)MOTTO:)Sustainable!development!of!the!region!based!on!natural!resources!

Key)partners:)

!C!4)public)univeri'es)from!the!region!!(3!from!Szczecin!and!one!from!Koszalin);!

!C!Marshal)Office)of!West!Pomeranian!Region!

C  !other!public!organizaIons!(clusters!ect.)!C  !industrial!partners!

PUBLIC!UNIVERSITIES:!1. !West!Pomeranian!University!of!Technology,!Szczecin!(ZUT)!!!2. !Koszalin!University!of!Technology!(PK)!!!!

3. !Poznań!University!of!Technology!(PP)!!!!4. !Pomeranian!Medical!University!in!Szczecin!(PUM)!!!!5. !Poznań!University!of!Life!Sciences!(UP)!!!6. !University!of!Szczecin!(US)!!!!7. !University!of!Zielona!Góra!(UZ)!!!!

RESEARCH!INSTITUTES:!1. !InsItute!of!LogisIcs!and!Warehousing!(ILiM)!!!!2.  InsItute!of!NonCferrous!Metals!!

!Central!Laboratory!of!Ba]eries!and!Cells!(IMNCCLAiO)!!!

3. !Metal!Forming!InsItute!(INOP)!!!4. !InsItute!of!Plant!ProtecIon!–!NaIonal!Research!InsItute!(IORCPIB)!!!5. !Wood!Technology!InsItute!(ITD)!!!!6. !InsItute!of!Natural!Fibres!and!Medicinal!Plants!(IWNiRZ)!!!7. !Industrial!InsItute!of!Agricultural!Engineering!(PIMR!

North West Bioeconomy Centre BioAgroTech - BIOAT

North)West)Bioeconomy)Centre)BioAgroTech)

Sustainable(economic(development(based(on(natural(resources(

Under!the!umbrella!of!Marshal’s!offices!

4!

7!1!

h]p://pzcb.nauka.szczecin.pl!

Sector)of)Blue))

Bioeconomy))

Sector)of)Material)

and)Energy))

Bioeconomy)

Sector))

of)Wholesome))

and)Organic)Food)

Sector)of)Life)

Sciences)and)

Bioservices)

Sectors)of)Bioeconomy)in)the)WPV)&)planned)Intersectoral)Units)

Sector)of)Material)and)Energy)Bioeconomy)

! !C!biorefinery!of!biomass!including!agriculture,!wood!and!food!byCproducts!!

! !C!microC!and!nanomaterials!for!various!applicaIons!

! !C!conversion!of!natural!substances!to!valuable!chemicals!

! !C!polymer!technologies!(including!biopolymers),!composites!and!adhesives.!

! !C!composite!materials!based!on!natural!fibres!!!

! !C!innovaIve!materials!for!packaging!

! !C!plasma!technologies!as!powerful!tool!of!surface!modificaIon!

! !C!renewable!sources!of!energy!(from!biomass,!via!solar!to!wind!energy)!

! !C!energy!efficiency!of!the!producIon!and!use!of!biomass!

! !C!sustainable!refrigeraIon!and!air!condiIoning!Sector)of)Blue))

Bioeconomy))

Sector)of)Material)

and)Energy))

Bioeconomy)

Sector))

of)Wholesome))

and)Organic)Food)

Sector)of)Life)

Sciences)and)

Bioservices)

INNOVATIVE)packaging…..???)

There are many possibilities…

Digital!printed!cups!

InnovaIve!materials:!

•  New!construcIon,!shape!and!design!

•  Security!features!

•  AcIve!and!funcIonal!packaging!

•  Barrier!properIes!

•  Smart!packaging!

•  New!business!models!!

•  New!systems!of!transport&logisIcs!

Biodegradable)polymers)–!advantages!vs.!shortcomings!

Shortcomings)=)challenges:!

C!!high!cost!

C  !low!temperature!of!flow!and!high!glass!transiIon!

C  !high!durability!and!low!elongaIon!index!

C  !poor!gas!barrier!properIes!

C  !other!technological!problems!during!converIng!

C  some!“+values…”!

Advantages:!!

C!maintain!the!environmental!CO2!constant!

C!biodegradability!

C  !possible!formaIon!of!films!and!rigid!containers!

C  good!printability!!!

C  high!gloss!and!add!estheIc!values!

C  !possible!formaIon!of!mulIlayer!films!

LDPE!

Ecoflex!

PLA!

PHA!

PA6!

amylose/gluten/glycerol!

amylose/glycerol!(10/4)!

whey!protein/glycerol!

amylopecIn/glycerol!(10/4)!

PVDC!

chitosan!plast.!

EVOH!

Innova'on)–)biodegradable)films)with)high)O2)barrier)

Oxygen!barrier!

NEW!biopolymer!0,2μm!

chitosan!plast!2μm.!

PLA!!20μm.!

PLA!!20μm.!600![cm3/m2!24h]!

7![cm3/m2!24h]!3![cm3/m2!24h]!

PLA/PHA!!biopolymer!!PLA/PHA!

!!

"  development!of!packaging!material!of!selecIve!permeability!of!O2!/!CO2!for!packaging!fresh!products!such!as!fruit)and)vegetable)blends)and)cheeses;)

" materials)derived)from)biomass,))

"  coated)paper)with!polymeric!coaIngs,!polymer!foil!and!packaging!obtained!by!the!thermoforming.)

Consump'on))

O2))Produc'on)

)CO2)

Food(packaging(

Permselec'vity)

S)=)CO2TR)/O2TR=)2?4)

O2TR) CO2TR)

Food)packaging)materials)with)O2/CO2)permselec'vity.)

Isolation and screening of microorganisms

Optimization of culture medium and fermentation

conditions

Fermentation process

Separation and purification of particular metabolites

Valorization of purified metabolites for chemical products

Immobilization of microorganisms

Research partners: Potential industrail recipients:

http://www.zielonachemia.org.pl

„Biotechnological conversion of glycerol to polyols and dicarboxylic acids” PO IG 01.01.02-00-074/09 (2010-2014)

Production of novel bioplastics – polyesters, additives etc.

0,0 2,0 4,0 6,0 8,0

10,0 12,0 14,0 16,0 18,0 20,0

0 4 24 48 0 4 24 2 8 24 2 8 24 2 8 0 0 4 10

1,3-

Pro

pano

diol

[g/d

m3 ]

Time [h]

Kontrola Kapsuły (30min) Kapsuły (45min)

Pasaż I (72h) II (24h) III (24h) IV (24h) V-VI (10h)

Batch!bioconversion!of!glycerol!to!1,3C!propanodiolu!(1,3CPD)!!via!immobilised!C.#freundii#

NEW!patent!applicaIons:!M.!Soból,!A.!Bartkowiak,!A!process!for!preparing!microcapsules!–!PL!P.405101!i!EP13461563!(2013).!!

Control!–!alginate!caps.!

New!system!30!min!react.!

New!system!45!min!react.!

ConInious!bioconversion!of!glycerol!to!1,3C!propanodiolu!(1,3CPD)!!via!immobilised!C.#freundii!

10cm3/h 20cm3/h

Flow!through!the!column!

NEW!patent!applicaIons:!M.!Soból,!A.!Bartkowiak,!A!process!for!preparing!microcapsules!–!PL!P.405101!i!EP13461563!(2013).!!

West!Pomeranian!Uniwersity!of!Technology,!!Szczecin!

WP1.)Selec'on))

of)by?products))

WP2.)Processing/)

)purifica'on))

WP3/5.)Funct.)Coa'ngs)

WP4.)Compression)

moulding)

WP6.)Prototype))

WP6.)Injec'on)moulding))

PLA)+…)

„ERA?NET)MNT)„Development)and)processing)of)agricultural)by?products))

to)mul'material)microfibrous)composite)packaging)materials”)

Various)WPC)products)

Polish!C!German!research!project!in!the!field!of!sustainability!created!in!West!Pomerania!and!Brandenburg!

„Manufacturing)of)Micro?Fibres)from)Grain)By?products)for)the)

Reinforcement)of)Thermoplas'c)and)Thermosemng)Composites”)

511C06C010C4461/11!Agro4Comp!(2013C2015)!

#  fibres!obtained!from!so!far!unexploited!grain!byCproducts!“husk!–!rue!and!wheat”!

#  reinforcement!in!thermoplasIc!and!thermoCsesng!polymers!as!subsItuIon!of!wood!products!+!???!(30C60%)!

!!!!classical!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!ideal!

CBIMO!new!concept!

water vapor heat

Backed)foams)based)on)mixture)of)agro?by?products)containing!proteins,!cellulose!and!starch!as!inner!layer!of!food!packages!

New!concept!of!backed!foams!based!on!mixture!of!pure!proteins,!cellulose!and!starch!+!other!substances!–!EPO,US!patent!applicaIon!(ZUT,!2009)!!

As!the!main!results!the!reduc'on)of)economical)losses)(that!someImes!are!even!to!30%))for!flowers!producers/growers/retailers! and!also! the!prolonga'on)of) the) shelf) life)and!maximal)protec'on)of)flowers!during!transport!and!storage!to!keep!the!quality!are!going!to!be!provided.!As!addiIonal!effect!the!reducIon!of!agroCwaste!will!be!reached.!!!

Bio?ac've)materials))?)an'microbial)surfaces)

An'microbial)packaging)surfaces)?)current!status:!C!coaIng!with!convenIonal!chemicals!of!antymi!acIon!C!about!50!used!

for!food!packaging!C!new!EU!regulaIon!regarding!reducIon! in!the!number!of!authorized!

anImicrobial!substances,!including!food!contact!(eg!use!of!Triclosan!LIMITATION)!

C!coaIng!with!nanoCsilver!parIcles!(very!negaIve!opinions!in!the!EU!–!need!further!longCterm!evaluaIon)!

Alterna've)use)of)an'microbials)of)natural)origin:)

C!organic!compounds!and!their!derivaIves!(salts,!organic!square)!C!biopolymers!(chitosan!C!in!2009!FDA!approve!in!USA)!C!bacteriocins!(eg.!nisin)!C!enzymes!(eg.!lysozyme)!C!plant!extracts!and!essenIal!oils!(eg.!rosemary!oil)!

24h! ! !!!!!!!!!!!!!! ! ! !!96h!

168h! ! !!!!!!!!!!!!!!! ! ! !312h!

!!!!0h!

Con'onious)produc'on)of)bacteriocine)solu'on)using)flow)bioreactor))

Monitoring)of)cont.)produc'on)of)nisin)

Fish)by?products)))))))))bioconversion))))))))))))))))))BACTERIOCINS)(nisin)!

)SHRIMP)shells)(CHITIN))))))))bioconversion))))))))CHITOSAN)

Test!„0”!!!!!!!!!!!!!!!!!!!!!!!!!!!!a.!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!b.!Fig. 1. Direct interactin of chitosan film on various microorganisms Staphylococcus aureus (TSB Agar + NaCl, after 24 hours.); b. Enterobacteriaceae (MacConkey Agar, after 24 hours.)

Chitosan!coaIng !!!b. !!!!!!!!!!!!!!!!!!!!!c.!!!!Fig.!2.!Chitosan!film!and!coated!paperboard!pouches!(a{er!two!weeks!!C!chitosan!coated!paperboard!pouches!vs.!PE!bag!)!

From)food)by?products)to)bioac've)substances)

New)green,)eco?friendly)processes)for)extrac'ng)value)added)products)from)lignocellulosic)

materials) for) food) industries,) cosme'cs) or) phytotherapy,) and) fibrous) residues) can) be)

valorised)in)a)process)such)as)papermaking)

Subcri'cal)water)extrac'on)

Extracts)(here)made)of)apple)

pomace))

Ac've)coa'ng)as)poten'al)

applica'on)

Fruit)pomace)(apple))

Oat)hulls)

Rapeseed)cakes)

Fibrous)residues)

(papermaking))

Cyclodextrin!inclusion!complex!

CoacervaIon!

Ionotropic!gelaIon!!

Emulsion/dispersion!

PLA!PHA!

Layer!

BioCacIve!substance!immobilized!

Methods)of)stabilisa'on)

Composite!

Formula'on)and)applica'on)of)temperature?stable)bio?based)an'microbial)agents)

The Association West Pomeranian Chemical Cluster "Green Chemistry” – 75 companies (4 platforms)

15!partners!6!companies!from!West!Pomeranian!Region!(Poland)!

h]p://chemia.rsi.org.pl/!

„Tailored?made”)solu'ons)

In!a!compeIIve!economy,!there!are!no!PROBLEMS?!!There!are!only!CHALLENGES!to!face!it!and!stand!together!

entrepreneurs!and!scienIfic!partners!........!!

„Triple)helix”)

Center of Bioimmobilisation and Innovative Packaging Materials CBIMO Faculty of Food Sciences and Fisheries

West Pomeranian University of Technology, Szczecin

ul. Klemensa Janickiego 35 71-270 Szczecin, Poland

ph. (48)91+4496592 ph/fax. (48)91+4496590

e-mail: cbimo@zut.edu.pl http://www.cbimo.zut.edu.pl