e-styrenics polystyrene gpps msds
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5/25/2018 E-Styrenics Polystyrene GPPS MSDS
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MSDSGeneralPurposePolystyrene
(GPPS) 10
MaterialSafetyDataSheet
GeneralPurposePolystyrene(GPPS)
Section1ChemicalProductandCompanyIdentification
TradeName E.Styrenics
Supplier EgyptianStyrene&PolystyreneProductionCo,Egypt
Manufacturer
Egypt,Alexandria,
El
Dekhela
Sea
Port
Telephone +2034460265
Fax +2034460269
HeadOfficeAddress Egypt,Cairo,6ElNabawyElMohandisSt.,HayElSefarat,NasrCity.
P.O.
Box
9550
Telephone +20226717198/+20226717199
Fax +20222739023
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MSDSGeneralPurposePolystyrene
(GPPS) 20
MSDSName Polystyrene
ThresholdExposureLimit(TLV) NotAvailable
ThisMSDScoversallprimegradesofGeneralPurposePolystyrene
Section2 Composition/InformationonIngredients
ChemicalName Polystyrene
ChemicalFamily Polymer
ChemicalFormula (C8H8)n
Synonym GeneralPurposePolystyrene,GPPS(Crystals)
CASRegistry
Number
9003
53
6
ThresholdExposureLimit(TLV) NotAvailable
Section3 HazardIdentification
PhysicalStateandAppearance Solid,TransparentPellets
EmergencyOverview
Irritating
vapors
to
respiratory
system
and
eyes
may
form
when
polymer
is
processedathightemperature.MoltenorHeatedmaterialinskincontactcan
causesevereburns.
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MSDSGeneralPurposePolystyrene
(GPPS) 30
RoutesofEntry ForHotMaterial:Skincontact,EyeContact,Inhalation
PotentialAcuteHealthEffects
Eye ThisProductisnotknowntocauseeyeirritation.However,aswithanychemical,
Some
sensitive
individual
may
experience
eye
irritation
upon
contact.
HeatedPolymer:EyeContactcancauseseriousthermalburns.
Vaporsformedwhenpolymerisheatedmaybeirritatingtotheeye
Skin NoKnowacuteeffectsofthisproductresultingfromskincontact.However,inlight
ofgoodindustrialhygienee,exposetoanychemicalshouldbekepttominimum.
Heated
Polymer:
Eye
contact
can
cause
serious
thermal
burns
Inhalation Negligiblehazardatroomtemperature.Nuisancedustscanbeirritationtothe
upperrespiratorytract.Irritationvaporsmayformwhenpolymerisprocessedat
hightemperature
Ingestion NoEffectsareexpectedforingestionofsmallamounts
PotentialChronic
Health
Effects
Carcinogenic
Effects:
Classified
NONE
by
NTP,
NONE
by
OSHA,
Not
Classified
for
humanbyIARC.
MutagenicEffects:NotAvailable
TERATOGENICEFFECTS:NotAvailable
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MSDSGeneralPurposePolystyrene
(GPPS) 40
MedicalConditionsAggravatedby
Overexposure
Thereisnoknowneffectfromchronicexposuretothisproduct.Repeatedor
prolongedexposureisnotknowntoaggravatedmedicalcondition.
Overexposure/Signs/Symptoms Noadversehealtheffectsanticipatedfromthesolidpellet.
RefertoToxicologicalinformation(Section11)
Section4 FirstAidMeasures
Inhalation Allowthevictimtorestinawellventilatedarea.
NoKnownEffectonskincontact,rinsewithwaterforafewminutes.
SkinContact HeatedPolymer:Forseriousburnsfromheatedpolymer,getmedicalattention.
EyeContact
Rinse
with
water
for
afew
minutes.
Seek
medical
attention
if
necessary.
Ingestion NoFirstaidproceduresareneeded.
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MSDSGeneralPurposePolystyrene
(GPPS) 50
Section5 FireandExplosiveData
NFPARating
FlammabilityoftheProduct Maybecombustibleathightemperature.
AutoIgnition
Temperature
440oC
(824
oF)
FlashPoint >200oC(>392
oF)
DecompositionTemperature >250oC(482
oF)
FlammableLimits NotAvailable
Products
of
Combustion
Carbon
Oxides
(CO,
CO2)
and
soot.
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MSDSGeneralPurposePolystyrene
(GPPS) 60
FireHazardsinPresenceofVarious
Substances
RisksofExplosionsoftheproductinpresenceofmechanicalimpact:NotExpected.
Risksofexplosionoftheproductinpresenceofstaticdischarge:Possible
NoSpecificinformationisavailableregardingtheproduct'sriskofexplosionin
presenceof
various
materials.
FireFightingMediaand
Instructions
SmallFire:UseDryChemicals,CO2,WaterSpray,Halonorfoam.
LargeFire:UsewaterSpray,fororfoam.DONOTusewaterjet,
Mayreigniteitselfafterfireisextinguished.
ProtectiveClothing(Fire) WearMSHA/NIOSHapprovedSelfcontainedbreathingapparatusorequivalent
andfullprotectivegears.
SpecialRemarksonFireHazards Firemayproduceirritatinggasesanddensesmoke.
Flowingmaterialmayproducestaticdischarge,ignitiondustaccumulations.
SpecialRemarksonExplosion
hazards
Processingormaterialhandlingequipmentmaygeneratedustofsufficientlysmall
size,thatwhensuspendedinairmaybeexplosive.
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MSDSGeneralPurposePolystyrene
(GPPS) 70
Section6AccidentalReleaseMeasures
SmallSpillandLeak Pelletsonthefloorcouldpresentaseriousslippingproblem.GoodHousekeeping
mustbemaintainedatalltimestoavoidthehazards.Sweep.Shovelorvacuum
materialinto
clean
containers.
LargeSpillandLeak Useashoveltoputthematerialintoaconvenientwastedisposalcontainer.
Donotallowanypotentiallycontaminatedwaterwithpelletstoenterany
waterway.Sewerordrain.
Section7HandlingandStorage
READANDOBSERVEALLPRECAUTIONSONPRODUCTLABEL.REFERTOPRODUCTLABELORMANUFACTURERSTECHNICAL
BULLETINSFORTHEPROPERUSEANDHANDLINGOFTHISMATERIAL
Handling AvoidTemperaturesof600oF(316oC)orabove.
Handlingofplasticmayformnuisancedust.
Protectpersonnel.
Pneumatic
transport
of
material
may
produce
dust.
Use
Filters
inpneumatictransportlinestoreducedust.Ifdustingisaproblem,careshouldbe
takentodissipatepotentialstaticelectricitybuildingup.Normalprecautionsfor
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5/25/2018 E-Styrenics Polystyrene GPPS MSDS
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MSDSGeneralPurposePolystyrene
(GPPS) 80
finelydividedpowdersshouldbemade.
StaticHazard:Electrostaticchargemayaccumulateandcreateahazardous
conditionwhenhandlingthismaterial.Tominimizethishazard,bondingand
groundingmaybenecessarybutmaynot,bythemselves,besufficient.Reviewall
operations,
which
have
the
potential
of
generating
an
accumulation
of
electrostatic
chargeand/oraflammableatmosphere(includingtankandcontainerfilling,splash
filling,tankcleaning,sampling,gauging,switchloading,filtering,mixing,agitation,
andvacuumtruckoperations)anduseappropriatemitigatingprocedures.For
moreinformation,refertoOSHAStandard29CFR1910.106,'Flammableand
CombustibleLiquids,NationalFireProtectionAssociation(NFPA77),
RecommendedPractice
on
Static
Electricity'
(liquids,
powders
and
dusts),
and/or
theAmericanPetroleumInstitute(API)RecommendedPractice2003,'Protection
AgainstIgnitionsArisingOutofStatic,Lightning,andStrayCurrents'(liquids).
Storage Keepcontainerdry.KeepinCoolPlace.Groundallequipmentcontainingmaterial.
Keepcontainertightlyclosed.Keepinacool,wellventilatedplace.Combustible
materialsshouldbestoredawayfromheatandawayfromstrongoxidizingagents.
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MSDSGeneralPurposePolystyrene
(GPPS) 90
Section8 ExposureControls/PersonalProtection
EngineeringControls Useprocessenclosures,localexhaustventilation,orotherengineeringcontrolsto
keepairbornelevelsbelowrecommendedexposurelimits.Ifusersoperations
generatedust
fume
or
mist,
use
ventilation
to
keep
exposure
to
airborne
contaminantsbelowexposurelimit.
PersonalProtection
Eyes SafetyGlasses
Body Coveralls
Respiratory
Ventilationisnormallyrequiredwhen
handlingthisproductathigh
temperatures.Wearappropriate
respiratorwhenventilationis
inadequate.
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MSDSGeneralPurposePolystyrene
(GPPS) 100
HandsThermalinsulatedglovesrequired
whenhandlinghotmaterial.
FeetSafetyslipproofshoesinareaswhere
spillsorleakscanoccur.
PersonalProtection
in
Case
of
Large
Spill
Safety
glasses.
Gloves.
Coveralls
Section8 PhysicalandChemical
PhysicalStateandAppearance Solid.TransparentPellets.
MolecularWeight NotAvailable
MolecularFormula (CH(C5H5)CH2)X
pH(1%
Soln/Water)
Not
Applicable
Boiling/CondensationPoint NotApplicable
Melting/FreezingPoint >132.22oC(270
oF)
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MSDSGeneralPurposePolystyrene
(GPPS) 110
CriticalTemperature NotAvailable
SpecificGravity 1.04(Water=1)
VaporPressure NotAvailable
VaporDensity NotAvailable
Volatility Negligible
OdorThreshold NotAvailable
EvaporationRate NotAvailable
VOC 0%
Viscosity NotAvailable
LogKow NotAvailable
Lonicity(InWater) NotAvailable
DispersionProperties NotAvailable
SolubilityinWater InsolubleinWater
PhysicalChemicalComments NoAdditionalRemark
ExclusivityLimit NotAvailable
Odor Odorless
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MSDSGeneralPurposePolystyrene
(GPPS) 120
Taste NotAvailable
Color Polystyreneisacolorless,transparent,glassysolidorasoftcolorlessform
Section10 StabilityandReactivity
StabilityandReactivity Theproductisstable.Avoidtemperatureof600degF(316oC)orabove
Conditionsof
instability
No
additional
remark
IncompatibilitywithVarious
Substances
Reactivewithstrongoxidizingagents
HazardousDecompositionProducts Hazardousdecompositionproductsarecarbonmonoxide,carbondioxide,dense
smokeandhydrocarbons.Exposureofpolystyrenetoextremelyhightemperature
(600degForHigher)maycausepartialdecomposition.
Chemicalsthatmayreleaseincludestyrenemonomer,benzeneandother
hydrocarbons.
HazardousPolymerization No
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MSDSGeneralPurposePolystyrene
(GPPS) 130
Section11 ToxicologicalInformation
ToxicityAnimals LD50:NotAvailable
LC50:NotAvailable
ChronicEffects
on
Humans
Carcinogenic
Effects:
Classified
none
by
NTP,
none
by
OSHA,
(Not
Classified
for
Human)byIARC.
OtherToxicEffectsonHumans NotConsideredtobedangerousforhumansaccordingtoourdatabase
SpecialRemarksonToxicityto
Animals
NoAdditionalRemark
Special
Remarks
on
Chronic
Effects
onHumans No
Additional
Remark
SpecialRemarksonotherToxic
EffectsonHumans
NoAdditionalRemark
Section12 EcologicalInformation
Ecotoxicity NotAvailable
BOD5andCOD NotAvailable
Biodegradable/OECD NotAvailable
Mobility NotAvailable
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MSDSGeneralPurposePolystyrene
(GPPS) 140
ToxicityoftheProductsof
Biodegradable
NotAvailable
SpecialRemarksontheProductsof
Biodegradation
NotAvailable
Section
13
Considerations
of
Disposal
and
Treatment
WasteInformation Transfertoanapproveddisposalareainaccordancewithfederal,stateandlocal
regulations
WasteStream NotAvailable
Consultyourlocalorregionalauthorities
Section14 TransportInformation
DOTClassificationorBulkshipments
(NonBulkShipmentmaydiffer)
NotaDOTcontrolledmaterial
DOTProperShippingName NotApplicable
UNNumber NotEstablished
PackagingGroup NotAvailable
USCGProperShippingName NotAvailable
MarinePollutant NotListedinAppendixBto49CFR172.101
HazardousSubstancesReportable NotListedinAppendixAto49CFR172.101
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MSDSGeneralPurposePolystyrene
(GPPS) 150
Quantity
SpecialProvisionsforTransport NoAdditionalRemark
TDGClassification NotControlledunderTDG(Canada)
ADR/RIDClassification NotControlledunderADR(EUROPE)
IMO/IMDGClassification
Not
Controlled
under
IMDG
ICAO/IATAClassification NotControlledunderIATA
Section15 RegulatoryInformation
HCSClassification ThisProductisnota"HazardousChemical"asdefinedbytheOSHAHazard
Communicationstandard,29CFR1910.1200.
TSCA(Toxic
Substance
Control
Act):
This
product
is
listed
on
the
TSCA
Inventory.
SARA302/304/311/312ExtremelyHazardousSubstances:Noproductswere
found.
U.SFederalRegulations SARA302/304EmergencyPlanningandnotification:NoProductswerefound.
SARA302/304/311/312HazardousChemicals:NoProductswerefound
SARA311/312MSDSdistribution Chemicalinventory hazardidentification:No
Productswere
found.
CleanWateract(CWA)307:Noproductswerefound
Cleanwateract(CWA)311:Noproductswerefound
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MSDSGeneralPurposePolystyrene
(GPPS) 160
Cleanairact(CAA)112Accidentalreleaseprevention:Noproductswerefound
Cleanairact(CAA)112regulatedflammablesubstances:NoProductswerefound
Cleanairact(CAA)112regulatedtoxicsubstances:Noproductswerefound
InternationalRegulations
WHMIS(Canada)
Not
Controlled
under
WHMIS
(Canada)
CEPAToxicSubstances:Thismaterialisnotlisted.
CanadianARET:Thismaterialisnotlisted.
AlbertaDesignedSubstances:Thismaterialisnotlisted
OntarioDesignatedSubstances:Thismaterialisnotlisted
QuebecDesignatedSubstances:Thismaterialisnotlisted
EINECS
Notavailable
DSCL(EEC) NotcontrolledunderDSCL(Europe)
InternationalLists AustraliaInventory(AICS):Thismaterialislistedorexempted
ChinaInventory(IECSC):Thismaterialislistedorexempted
JapanInventory(ENCS):Thismaterialislistedorexempted
JapanInventory
(ISHL):
This
material
is
listed
or
exempted
KoreaInventory(KECI):Thismaterialislistedorexempted
NewZealandInventoryofChemicals(NZIoC):Thismaterialislistedorexempted
PhilippinesInventory(PICCS):Thismaterialislistedorexempted
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MSDSGeneralPurposePolystyrene
(GPPS) 170
Section16 OtherInformation
LabelRequirements Irritatingvaporstorespiratorysystemandeyesmayformwhenpolymeris
processedathightemperature.
Moltenorheatedmaterialinskincontactcancausesevereburns
NFPA RATINGS
Health:1Flammability:1Reactivity:0Special:NA(0Least,1Slight,2Moderate,
3High,4Extreme,PPE:PersonalProtectionEquipmentIndexrecommendation,*
ChronicEffectIndicator).Thesevaluesareobtainedusingtheguidelinesor
publishedevaluationspreparedbytheNationalFireProtectionAssociation
(NFPA).
ABBREVIATIONS THAT MAY HAVE
BEEN USED IN THIS DOCUMENT
TLV ThresholdLimitValue
STEL
Short
term
Exposure
Limit
ACGIH AmericanConferenceofGovernmentIndustrialHygienists
NIOSH NationalInstituteforOccupationalSafety&Health
WHMIS WorkplaceHazardousMaterialsInformationSystem
EINECS EuropeanInventoryofexisting
TWA
Time
Weighted
Average
PEL PermissibleExposureLimit
OSHA OccupationalSafety&HealthAdministration
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MSDSGeneralPurposePolystyrene
(GPPS) 180
NFPANationalFireProtectionAgency
IARC Intl.AgencyforResearchonCancer
RCRA ResourceConservationRecoveryAct
CommercialChemicalSubstances
SARASuperfund
Amendments
and
Reauthorization
Act.
EC50 EffectiveConcentration
LD50 LethalDose
NDA NoDataAvailable
=Greater
Than
or
Equal
To
CNS CentralNervousSystem
TSCA ToxicSubstanceControlAct
LC50 LethalConcentration
CAS ChemicalAbstractService
NANot
Applicable
MAK GermanyMaximumConcentrationValues
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MSDSGeneralPurposePolystyrene
(GPPS) 190
References HSDB HazardousSubstancesDataBook
RTECS RegistryofToxicEffectsofChemicalsSubstances
Theaboveinformationisbasedonthedataofwhichweareawareandisbelievedtobecorrectasofthedatehereof.Since
thisinformation
may
be
applied
under
conditions
beyond
our
control
and
with
which
we
may
be
unfamiliar
and
since
data
madeavailablesubsequenttothedatehereofmaysuggestmodificationsoftheinformation,wedonotassumeany
responsibilityfortheresultsofitsuse.Thisinformationisfurnisheduponconditionthatthepersonreceivingitshallmakehis
owndeterminationofthesuitabilityofthematerialforhisparticularpurpose.
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