ヨウ素系重合開始剤 iodine-containing initiators for living radical ... · α-iodo esters...
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モノマー
Effective for BA ( Bu4NI at 110 oC )
(70 oC )
104 ka (M-1 s-1) = 2500 100 88 74 69 62 23 5 <1
Effective for MMA ( Bu3MePI at 70 oC )
( PhCN-I ) ( PhE-I ) ( EEMA-I ) ( CP-I ) ( CE-I ) ( PMMA-I ) ( EMA-I ) ( EA-I ) ( E-I )
iodineFunctional group
Telechelic polymer
Star polymer( EMA-III )
ABA triblock copolymer
( EMA-II ) ( PhE-II )
BCMH PAME MMMF PNMM PNMH IBME RAME AAME
BBDG BPDG
TBTP
Ph CHCN
IPh CH
CI
O EtO
C CC
I
O EtO
OOEt
CCN
I CHCN
I CH2 CC
I
OO
n
CC
I
O EtO
CHC
I
O EtO
CH2C
I
O EtO
CC
I
OHO
OO
O
IO
I OO
O
IO
I
O
O
IO
O
IOO
I
CHC
IO
OOH
非金属触媒非金属触媒非金属触媒非金属触媒
メタクリレート選択的 アクリレート選択的
【有機触媒を用いたリビングラジカル重合の休眠種開始剤の検討有機触媒を用いたリビングラジカル重合の休眠種開始剤の検討有機触媒を用いたリビングラジカル重合の休眠種開始剤の検討有機触媒を用いたリビングラジカル重合の休眠種開始剤の検討】
(京大化研) ○雷 琳・ 谷嶋 美保・ 後藤 淳 ・ 梶 弘典
(合同資源) 宮本 充彦
第63回高分子学会年次大会May 28th, 2014 1F13
ヨウ素系重合開始剤ヨウ素系重合開始剤ヨウ素系重合開始剤ヨウ素系重合開始剤
Iodine-Containing Initiators for Living Radical Polymerization
α-Iodo Esters
Ethyl 2-Iodopropanoate
[31253-08-4]
C5H9IO2 (228.03)
RAME GSS-0003
Ethyl 2-Iodoacetate
[623-48-3]
C4H7IO2 (214.00)
AAME GSS-0006
Ethyl 2-Iodoisobutyrate
[7425-55-0]
C6H11IO2 (242.05)
IBME GSS-0008
Methyl 2-Iodoacetate
[5199-50-8]
C3H5IO2 (199.98)
AAMM GSS-0015
Ethyl 2-Iodobutyrate
[7425-47-0]
C6H11IO2 (242.05)
BAME GSS-0019
Ethyl 2-Iodovalerate
[31253-09-5]
C7H13IO2 (256.08)
VAME GSS-0023
Benzyl 2-Iodoisobutyrate
[NA]
C11H13IO2 (304.12)
IBMB GSS-0030
Methyl 2-Iodoisobutyrate
[67194-53-0]
C5H9IO2 (228.03)
IBMM GSS-0046
Benzyl Iodides
Highly Activated Compounds
Functionalized Compounds
Multi-Iodinated Compounds
α-Iodo α-Iodo α-Iodo α-Iodo α-Iodo
Carboxylic Acid Lactones Amides Nitriles Ketones
Highly Activated Compounds Multi-Iodinated Compounds
Benzyl Iodide
[620-05-3]
C7H7I (218.03)
BNMH GSS-0017
(1-Iodoethyl)benzene
[10604-60-1]
C8H9I (232.06)
EBMH GSS-0005
4-Nitrobenzyl Iodide
[3145-86-6]
C7H6INO2 (263.03)
NTMH GSS-0045
α-Iodo-γ-butyrolactone
[31167-92-7]
C4H5IO2 (211.99)
BLMH GSS-0042
2-Iodoacetic Acid
[64-69-7]
C2H3IO2 (185.95)
AAMH GSS-0007
2-Iodoisobutyric Acid
[7425-20-9]
C4H7IO2 (214.00)
IBMH GSS-0014
2-Iodopropanoic Acid
[598-80-1]
C3H5IO2 (199.98)
RAMH GSS-0004
2-Iodopropionamide
[19221-80-8]
C3H6INO (198.99)
RAMA GSS-0021
2-Iodoacetonitrile
[624-75-9]
C2H2IN (166.95)
ANMH GSS-0013
2-Iodopropionitrile
[104024-32-0]
C3H4IN (180.98)
PNMH GSS-0022
2-Iodoisobutyronitrile
[19481-79-9]
C4H6NI (195.00)
PNMM GSS-0044
2-Iodoacetophenone
[4636-16-2]
C8H7IO (246.05)
APMH GSS-0031
α-Iodobenzyl Cyanide
[63450-93-1]
C8H6IN (243.04)
BCMH GSS-0018
Iododiphenylmethane
[29704-39-0]
C13H11I (294.13)
PMMH GSS-0011
9-Iodo-9H-fluorene
[64421-01-8]
C13H9I (292.12)
FLMH GSS-0012
Ethyl 2-Iodo-2-methylacetoacetate
[1005452-92-5]
C7H11IO3 (270.06)
MAME GSS-0032
Ethyl 2-Iodo-2-phenylacetate
[78489-65-3]
C10H11IO2 (290.10)
PAME GSS-0009
Ethyl 2-Iodo-2-(4'-methylphenyl)acetate
[NA]
C11H13IO2 (304.12)
TAME GSS-0034
Ethyl 2-Iodo-2-(4'-nitrophenyl)acetate
[NA]
C10H10INO4 (335.10)
NPME GSS-0026
2-Iodo-2-phenylacetic Acid
[615256-95-6]
C8H7IO2 (262.04)
PAMH GSS-0020
2-Hydroxyethyl 2-Iodoisobutyrate
[NA]
C6H11IO3 (258.05)
IBMO GSS-0036
2-Hydroxyethyl 2-Iodo-2-phenylacetate
[NA]
C10H11IO3 (306.10)
PAMO GSS-0039
Diethyl 2,5-Diiodoadipate
[165334-67-8]
C10H16I2O4 (454.04)
ADDF GSS-0016
Ethylen Glycole Bis(2-iodo-2-phenylacetate)
[NA]
C18H16I2O4 (550.13)
BPDG GSS-0037
p-Xylylene Diiodide
[30362-89-1]
C8H8I2 (357.96)
PXDH GSS-0001
1,4-Bis(1'-iodoethyl)benzene
[NA]
C10H12I2 (386.01)
PXDL GSS-0027
1,3,5-Tris(1'-iodoethyl)benzene
[NA]
C12H15I3 (539.96)
MSTK GSS-0028
Ethylene Glycol Bis(2-iodoisobutyrate)
[NA]
C10H16I2O4 (454.04)
BBDG GSS-0024
Diethyl 2-Iodo-2-methylmalonate
[119368-33-1]
C8H13IO4 (300.09)
MMMF GSS-0010
Glycerol Tris(2-iodoisobutyrate)
[NA]
C15H23I3O6 (680.05)
TBTP GSS-0025
ヨウ素系重合開始剤
Iodine-Containing Initiators for Living Radical Polymerization
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