amet tm how to manually assign ghs hazcom pictograms to a mixture

7/31/2019 Amet Tm How to Manually Assign Ghs Hazcom Pictograms to a Mixture

1/3

1

A METHOD FOR ASSIGNING GHS HAZARD COMMUNICATION PICTOGRAMS

TO A PREPARATION/MIXTURE WITHOUT AN AUTOMATED CLASSIFICATIONS SYSTEM

Theodore M. Amet

Regulatory Research Analyst

This is training material. Not for private, public or industrial use.

Table 1. Sao Boso PJI Mix

Ingredient/Component Name CAS # EC # % GHS Hazard PictogramsPentan-2-one 107-87-9 203-528-1 30 - 50 -

Ethanol 64-17-5 200-578-6 10 - 25 - -

Tributylmethylammonium chloride 56375-79-2 260-135-8 3 - 10 - -

1-methoxypropan-2-ol 107-98-2 203-539-1 3 - 8 -

Propyl acetate 109-60-4 203-686-1 1 - 3 -

Propan-2-ol 67-63-0 200-661-7 1 - 3 -

Butan-1-ol 71-36-3 200-751-6 1 - 3

GHS Label Elements

Pictogram

Signal word Danger

Table 2. Classificationaccording toGHS (Substance/Ingredient/Chemical in Table 1)

CAS # EC# Index No. UN # % Product name Classification

According to GHS107-87-9 203-528-1 - 1249 30 - 50 Pentan-2-one Flam. Liq. 2, H225

Acute Tox. 4* (oral), H302

Skin Irrit. 2, H315

Eye Irrit. 2, H319

STOT SE 3, H335

64-17-5 200-578-6 603-002-00-5 1170 10 - 25 Ethanol Flam. Liq. 2, H225

56375-79-2 260-135-8 - - 3 - 10 Tributylmethylammonium

chloride

Skin irrit. 2, H315

Eye irrit. 2, H319

STOT SE 3, H335

107-98-2 203-539-1 603-064-00-3 3092 3 - 8 1-methoxypropan-2-ol Flam. Liq. 3, H226

STOT SE 3, H336

109-60-4 203-686-1 607-042-00-6 1276 1 - 3 Propyl acetate Flam. Liq. 2, H225

Eye Irrit. 2, H319STOT SE 3, H336

EUH066

67-63-0 200-661-7 603-117-00-0 1219 1 - 3 Propan-2-ol Flam. Liq. 2, H225

Eye Irrit. 2, H319

STOT SE 3; H336

71-36-3 200-751-6 603-004-00-6 1120 1 - 3 Butan-1-ol Flam. Liq.3, H226

Acute Tox. 4* (oral), H302

Skin Irrit. 2, H315

STOT SE 3, H335

Eye Dam. 1, H318

STOT SE 3, H336


2/3

2

Table 3. GHS Hazard Classification (Product - Sao Boso PJI Mix)

GHS Classification Category Hazard Statement Code(s) Hazard Statement(s)

Flam. Liq. 2 H225 Highly flammable liquid and vapor.

Acute Tox. (oral) 4 H302 Harmful if swallowed.

Skin irritant 2 H315 Causes skin irritation.

Eye Irrit. 1 H318 Causes serious eye irritation.

STOT SE: RTI 3 H335 May cause respiratory irritation.

STOT SE: NE 3 H336 May cause drowsiness or dizziness.

Classification of the Preparation/Mixture (Table 3)

Flammable liquids, Category 2, H225

Acute toxicity (oral), Category 4, H302

Skin corrosion/irritation, Category 2, H315

Serious eye damage/Eye irritation, Category 1, H318

Specific Target Organ Toxicity - Single exposure: Respiratory tract irritation, Category 3, H335

Specific Target Organ Toxicity - Single exposure: Narcotic effects, Category 3, H336

Indications of Danger: Highly flammable liquid. Irritating to eyes, skin and respiratory system.

Harmful if swallowed. Inhalation may cause drowsiness or dizziness.

Repeated exposure may cause skin dryness or cracking.

GHS Label Elements

Hazard Pictograms (see Table 1)

Signal word: Danger

Hazard statement(s)H225: Highly flammable liquid and vapor.

H302: Harmful if swallowed.

H315: Causes skin irritation.

H318: Causes serious eye damage.H335: May cause respiratory irritation.

Precautionary statement(s)P101: If medical advice is needed, have product container or label at hand.

P102: Keep out of reach of children.

P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P233: Keep container tightly closed.

P240: Ground/bond container and receiving equipment.

P243: Take precautionary measures against static discharge.

P261: Avoid breathing dust/fume/gas/mist/vapors/spray.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,

if present and easy to do. Continue rinsing.P310: Immediately call a POISON CENTER or doctor/physician.

P403 + P233: Store in a well-ventilated place. Keep container tightly closed.

P501: Dispose of contents/container to be in accordance with local/regional/national regulations.

Other hazards which do not result in classification: Repeated exposure may cause skin dryness or cracking.

References:

Various Internet sources;

http://www.unece.org/fileadmin/DAM/trans/danger/publi/ghs/ghs_rev02/English/07e_annex3.pdf; and

http://chemsub.online.fr/


3/3

3

Pointer:

May retain corrosive hazard pictogram ( ) if mixture pH is highly acidic (pH 2.0) or highly basic/alkaline (pH 12.5).

amet tm how to manually assign ghs hazcom pictograms to a mixture

Documents