ameren missouri labadie energy center - dnr · i ameren missouri labadie energy center groundwater...

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ENVIRONMENTAL ENGINEERING LAND - AIR – WATER

Project Engineering Team

Ameren Missouri Labadie Energy Center

Groundwater Monitoring Report 1st Background Sampling Event – April 16-17, 2013

Prepared for:

May 2013

Ameren Missouri Labadie Energy Center Groundwater Monitoring Report

1st Background Sampling Event – April 16-17, 2013

May 2013

Prepared By:

Reitz & Jens, Inc. 1055 Corporate Square Drive

St. Louis, Missouri 63132 (314) 993-4132

and

GREDELL Engineering Resources, Inc. 1505 East High Street

Jefferson City, Missouri 65101 (573) 659-9078

i

Ameren Missouri Labadie Energy Center Groundwater Monitoring Report

1st Background Sampling Event – April 16-17, 2013 Franklin County, Missouri

Table of Contents

1.0 INTRODUCTION.................................................................................................. 1

2.0 GROUNDWATER MONITORING SYSTEM ........................................................ 2 2.1 Monitoring Well Dedicated Tubing Installation ...........................................2

3.0 FIELD SAMPLING SUMMARY ........................................................................... 3 3.1 Field Quality Assurance/Quality Control .....................................................3 3.2 Water Table Surface ......................................................................................4

4.0 ANALYTICAL SUMMARY................................................................................... 5 4.1 Precision and Accuracy ................................................................................5 4.2 Representativeness.......................................................................................7 4.3 Comparability.................................................................................................7 4.4 Completeness ................................................................................................7

5.0 RESULTS SUMMARY......................................................................................... 8

ii

List of Tables

Table 1 – Groundwater Monitoring Network Summary

Table 2 – Groundwater Elevation Summary

Table 3 – Background Water Quality Summary

Table 4 – Constituents for Detection Monitoring

List of Figures

Figure 1 – Water Table Surface Contour Map

List of Appendices

Appendix 1 – Field Notes and Field Information Sheets

Appendix 2 – Laboratory Analytical Results

Appendix 3 – Laboratory Quality Assurance/Quality Control Data

and Chain-of-Custody

Background Groundwater Monitoring Report – 1st Event Ameren Missouri Labadie Energy Center

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1.0 INTRODUCTION The following discusses the methods used to sample and analyze groundwater samples from 29 monitoring wells surrounding Ameren Missouri’s proposed Utility Waste Landfill (UWL) at their Labadie Energy Center in Franklin County Missouri. The results of the sample analysis are also provided. The 29 monitoring wells sampled were installed mid-March through mid-April 2013. A groundwater monitoring well installation report has been prepared under separate cover This groundwater monitoring report represents the first round of background sampling and analytical data collection required prior to operation of the proposed UWL. An additional seven rounds of background sampling is planned prior to evaluating the groundwater quality data and recommending an appropriate statistical analysis plan. Subsequent rounds of sampling are currently scheduled at approximate 90 day intervals. Therefore, background sampling and reporting is projected to continue through early 2015. All field sampling activities, sample transport, laboratory analytical testing, and reporting are to be consistent with the accepted Groundwater Sampling and Analysis Plan found in Appendix Q of the CPA currently under review by MDNR-SWMP.


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2.0 GROUNDWATER MONITORING SYSTEM

The accepted groundwater monitoring system consists of 28 permanent wells and one temporary well. Each well was designed and installed to monitor uppermost groundwater within the alluvial aquifer underlying the UWL to an approximate maximum depth of 25 feet. A summary of monitoring well information is presented in Table 1. Additional information can be found in the groundwater monitoring well installation report.

An initial round of water level measurements from the 29 wells were collected within a six-hour period on April 15, 2013. A second round of water level measurements were collected during the groundwater sampling activities on April 16 and 17, 2013, which occurred over a 32-hour period. Groundwater levels recorded during the second round of water level measurements are summarized in Table 2. A groundwater contour map based on the second round of water level measurements is included in Figure 1.

A summary of the monitoring well analytical data results are presented in Table 3.

Table 4 lists the required constituents for detection monitoring, as shown in 10 CSR 80-11.010 - Appendix I, including Molybdenum which was added per MDNR-SWMP request on March 7, 2013. Table 4 also specifies the analytical method used during laboratory analysis for each constituent, units of measurement, and Practical Quantitation Limits. Generally, analytical methods are defined by the U.S. Environmental Protection Agency (EPA) in their Test Methods for Evaluating Solid Wastes and are presented in EPA Publication SW-846 available on-line at http://www.epa.gov.

2.1 Monitoring Well Dedicated Tubing Installation Dedicated tubing used for low-flow purging and sampling activities was installed to each monitoring well prior to sampling. The intake of the dedicated polyethelene tubing (semi-rigid 1/4" ID x 3/8" OD) intersects each monitoring well screened interval approximately two feet above the bottom of the well. Additionally, dedicated silicone tubing (flexible 0.170" ID x 3/8" OD) is slip-connected to the semi-rigid tubing at the top of each well casing. The flexible tubing is then connected to a non-dedicated peristaltic pump during the low-flow purging and sampling activities. It is approximately 30-inches in length to prevent contact with the ground when removed from within the interior of the monitoring well riser. The open end of the flexible tubing represents the point of sample collection. A clean, braided nylon string secures the semi-rigid tubing just below the connection with the flexible tubing, and is further secured with a plastic zip tie around the slip-connection. The nylon string is connected to the well cap to maintain the intake elevation of the semi-rigid tubing within the lower part of the well screen. Once purging and sampling activities are completed, the silicone tubing is returned to the interior of each monitoring well’s PVC riser.


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3.0 FIELD SAMPLING SUMMARY

The first background groundwater sampling event was performed by qualified Gredell Engineering field personnel on April 16 and 17, 2013. Groundwater samples were collected from all 29 monitoring wells using low-flow sampling techniques and dedicated sampling equipment per the accepted Groundwater Sampling and Analysis Plan. Field tests for indicator parameters, as specified under 10 CSR 80-11.010(11)(C) 4.B, were performed and each sample was analyzed for the suite of chemical constituents listed on Table 4.

All sample bottles were prepared (i.e., pre-labeled and appropriate preservatives added) prior to shipment by the analytical contractor Teklab, Inc. (Teklab) of Collinsville, Illinois and delivered to the offices of Gredell Engineering in Jefferson City, Missouri.

Field environmental staff inspected the condition of each monitoring well prior to sampling and completed a checklist during that inspection using the forms provided in the accepted Groundwater Sampling and Analysis Plan. Copies of field notes and the completed Monitoring Well Field Inspection forms are included in Appendix 1. Water levels in each monitoring well were initially determined using a Geotech ET electronic water level meter graduated in 0.01 foot increments. A non-dedicated Geotech Geopump Series II peristaltic pump was then connected to the dedicated tubing in each well and then purged at a rate no greater than 400 milliliters per minute (mL/min). During purging, a YSI 556MPS multi-function meter fitted with a flow-through cell was used to measure field pH, specific conductance, temperature, oxidation reduction potential and dissolved oxygen. Turbidity was determined at periodic intervals using a MicroTPI HF Scientific Turbidimeter. When field indicator parameters stabilized, samples were collected at the specified purge rate. Collected samples were stored in coolers on wet ice until delivered to Teklab using standard chain-of-custody procedures. Stabilization information for each sample was recorded on a Field Sampling Log and copies of each log are included in Appendix 1.

Subsequent to the sampling event, a list of required field parameters (i.e., groundwater elevation, specific conductivity and pH) was compiled and transmitted to Teklab to be added to the laboratory analytical report as field determined values.

3.1 Field Quality Assurance/Quality Control

Field Quality Assurance/Quality Control performed during the sampling event included the collection of two field replicate samples (presented to the laboratory as unspecified duplicate samples), a field blank, and a trip blank. Duplicate 1 is a replicate of MW-27 and was collected immediately after the initial sample. Duplicate 2 is a replicate of MW-10 and was collected immediately after the initial sample. Additionally, one field blank sample was collected following the completion of sampling of MW-21. Field staff prepared the trip blank with deionized water (provided by Teklab) prior to the beginning of sampling activities. Rinsate (equipment) blanks were not collected due to the use of dedicated sampling equipment. Samples were preserved


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in the manner required for the parameter being analyzed, placed in a cooler containing water-ice, and picked up by a Teklab courier and transported to the laboratory facility for analysis. Standard chain-of-custody procedures were followed and copies of the completed chain-of-custody records received from Teklab are included in Appendix 3. The completed chain-of-custody records indicate that, upon receipt by the laboratory, additional nitric acid was needed in the containers for the TMW-01 metals and Duplicate 2 metals samples. Field staff had previously noted minor amounts of suspected nitric acid leakage (i.e., label discoloration) on these sample containers when originally received from Teklab.

3.2 Water Table Surface The water level measurements taken April 16-17, 2013 are summarized in Table 2. The measurements show minor fluctuations relative to one another (+/- 2-3 ft) except for MW-18 (Table 2). This well had a water level several feet higher in elevation than the other wells. This is reflected on the water table surface map included as Figure 1. Otherwise, the movement of groundwater is generally from west-to-east across the site. Apparent hydraulic gradients as determined by the groundwater mapping software Surfer� Version 10.7.972 range from a minimum of 9.65 x 10-6 ft/ft to a maximum of 7.56 x 10-3 ft/ft in the vicinity of MW-18.


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4.0 ANALYTICAL SUMMARY

Analytical data provided by Teklab for each well sampled during the background sampling event is provided in Appendix 2. These data are summarized on Table 3. Appendix 2 also contains the analytical data for the sample duplicates, field blank, and trip blank. Laboratory quality assurance/quality control documentation, including data for inorganic parameters, metals, and organic (TOX) parameters are provided in Appendix 3.

The analytical data sheets note that Beryllium, Nickel, and Total Organic Halogens (Halides) (TOX) were reported in micrograms per liter (µg/L). These units were converted to milligrams per liter (mg/L) on the data summary presented on Table 3 to maintain consistency with the reporting requirements of 10 CSR 80-11.010 - Appendix I.

4.1 Precision and Accuracy

Precision is a measure of the reproducibility of analytical results, generally expressed as a Relative Percent Difference. Laboratory quality control procedures to measure precision consist of laboratory control sample (LCS) analysis and analysis of matrix spike/matrix spike duplicates (MS/MSD). These analyses are used to define analytical variability. Accuracy is defined as the degree of agreement between the measured amount of a species and the amount actually known to be present, expressed as a percentage. It is generally determined by calculating the percent recoveries for analyses of surrogate compounds, laboratory control samples, continuing calibration check standards and matrix spike samples. Acceptable percent recoveries are established for SW-846 and EPA methods. Field and laboratory blank analyses are also used to address measurement bias.

The Analytical Report received from Teklab states that “All quality control criteria applicable to the test methods employed for this project have been satisfactorily met and in accordance with NELAP except where noted” (Appendix 3). Quality control comments noted within the analytical report are described below:

• The matrix spike (MS) QC limits for Calcium and Magnesium in MW-2, MW-17 and TMW-1 are not applicable due to the high sample/spike ratio. These results are shown with an “S” flag.

• The MS QC limit for Iron in MW-2 and TMW-1 is not applicable due to the high sample/spike ratio. These results are shown with an “S” flag.

• Matrix interference for Antimony was present in the sample for MW-3 and was confirmed by bench spike. This result is shown with an “S” flag.

• MS and/or matrix spike duplicate (MSD) for Sulfate in MW-5, MW-6, MW-11 and MW-13 did not recover within control limits due to matrix interference. These results are shown with an “S” flag.


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• Results of MS and/or MSD for Sulfate in MW-12 have less certainty because value(s) exceed upper quantitation limits. A flagged value is not associated with this comment.

• In addition, a significant number of data results are shown with a “J” flag (Table 3). According to the laboratory, a “J” flag denotes an analyte was detected below quantitation limits (PQL). Review of these results confirms that reported values all fall below applicable PQL’s. It was also noted that “J” flags are used to report some parameters, but not others and no one parameter is consistently reported using “J” flag values.

• In some instances, dilution factors (DF) were required during analysis, specifically for Sulfate and Arsenic. A DF of two was used to obtain the analytical result for Sulfate in MW-10, whereas a DF of five was required for the analysis of Sulfate in MW-11, MW-13, MW-17, MW-19, MW-22, and TMW-1. Similarly, a DF of two was used to obtain the analytical result for Arsenic in MW-9, whereas a DF of five was required for the analysis of Arsenic in MW-7 and TMW-1. The analytical report defines DF as, “The dilution performed during analysis only and does not take into account any dilutions made during sample preparation. The reported result is final and includes all dilution factors.”

Additional Quality Assurance and Quality Control comments include the following:

• Field Replicates: Analyses of replicate samples are used to define the total variability of the sampling/analytical system as a whole. Two field replicates, Duplicate 1 and Duplicate 2, were collected during this sampling event (Duplicate 1 was a replicate sample of MW-27 and Duplicate 2 was a replicate sample of MW-10). The Relative Percent Difference (RPD) was calculated for detected chemical parameters, which consisted of Chloride, Fluoride, Hardness, Sulfate, TDS, TOC, Arsenic, Boron, Barium, Calcium, Iron, Magnesium, Manganese, and Nickel. Using a tolerance level of +/-20 percent, calculated RPDs were within acceptable ranges except for Fluoride (35%) and Sulfate (25%) in MW-27/Duplicate 1. The MW-10/Duplicate 2 sample comparisons were within acceptable ranges for each detected parameter.

• Field and Trip Blanks: One field blank and one trip blank were incorporated into the data set for this sampling event. The field blank contained reportable concentrations of Boron (36.7 µg/L), Calcium (0.091 µg/L), Copper (30.4 µg/L), Magnesium (0.012 µg/L), Sodium (0.464 µg/L) and Zinc (24.7 µg/L). The trip blank did not contain a reportable concentration of Total Organic Halogens (TOX), which is the only required test parameter for this sample.

• Laboratory Blanks: Method blanks, artificial, and matrix-less samples are analyzed to monitor the laboratory system for interferences and contamination from glassware,


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reagents, etc. Method blanks are taken throughout the entire sample preparation process. They are included with each batch of extractions or digestions prepared, or with each 20 samples, whichever was more frequent. Reference to Appendix 3 should be made for additional information related to these and other laboratory control samples.

4.2 Representativeness

Representativeness expresses the degree to which sample data accurately and precisely reflect site conditions. Representativeness of the data is determined by comparing actual sampling procedures to those delineated in the field sampling and analysis plan, comparing results from field replicate samples and reviewing the results of field blanks.

4.3 Comparability

Comparability expresses the confidence with which one data set can be compared to another data set measuring the same property. Comparability is ensured by using established and approved sample collection techniques and analytical methods, consistent basis of analysis, consistent reporting units, and analyzing standard reference materials.

4.4 Completeness

Completeness is a measure of the amount of valid data obtained from a measurement system compared to the amount expected under controlled laboratory conditions. Completeness is defined as the valid data percentage of the total tests requested. Valid data are defined as those where the sample arrived at the laboratory intact, properly preserved, in sufficient quantity to perform the requested analyses, and accompanied by a completed chain-of-custody form. Furthermore, the sample must have been analyzed within the specified holding time and in such a manner that analytical QC acceptance criteria are met.


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5.0 RESULTS SUMMARY As shown on Table 3, fourteen of the required analytical parameters were not detected in any of the 29 monitoring wells above established PQL concentrations. These “non-detect” parameters include Antimony, Beryllium, Cadmium, Chromium, Cobalt, Copper, Lead, Mercury, Molybdenum, Silver, Thallium, Zinc, Chemical Oxygen Demand (COD) and Total Organic Halogens (TOX). In some instances, “J” flag values, which imply a concentration below PQL but above Method Detection Limits (MDL), are used for reporting purposes for these fourteen parameters. This includes Cobalt (eight samples), Copper (two samples), Lead (eleven samples), Zinc (23 samples), COD (two samples), and TOX (five samples). Seven of the required analytical parameters were detected above established PQL concentrations in all 29 monitoring wells (Hardness concentrations are also reported for all wells, but it is not associated with an established PQL). These “detected” parameters include Boron, Barium, Calcium, Magnesium, Sodium, Total Dissolved Solids (TDS), and Total Organic Carbon (TOC) (Table 3). In some instances, “S” flag qualifiers were used to denote that the reported result is associated with a matrix spike (MS) outside of QC limits. An “S” flag was used for three of the results for Calcium, Magnesium, and Sulfate. It was also used to denote two of the results for Iron and one of the results for Antimony. The nine remaining required analytical parameters (Aluminum, Arsenic, Iron, Manganese, Nickel, Selenium, Chloride, Fluoride, and Sulfate) were reported as “detectable” in some wells and “non-detect” in other wells (Table 3). Iron, Manganese, Fluoride, and Sulfate were detected above the established PQL in 28 of the 29 wells. Arsenic was detected in 14 wells and Chloride was detected in 12 wells. Fewer wells contained detectable concentrations of Aluminum (five samples), Nickel (2 samples), and Selenium (2 samples). The usage of “J” flag qualifiers are also found in the results for Aluminum (nine samples), Arsenic (five samples), Nickel (18 samples), Chloride (17 samples), and Sulfate, Iron and Manganese (one sample each).

TABLES

Ameren Missouri Labadie Energy CenterProposed Utility Waste Landfill

Franklin County, Missouri

Groundwater Monitoring Well Network SummaryTable 1

Monitoring Well ID1

Northing Location2

Easting Location2

Ground Surface Elevation2

(feet)

Top of Riser Elevation2

(feet)

Well Depth3

(feet, btor4)

Base of Well Elevation3

(feet, btor4)

Screen Length3,5

(feet)

Top of Screen Elevation3

(feet)

MW-1 995572 727213 469.45 472.05 27.76 444.29 9.7 454.49MW-2 995657 727664 469.30 471.86 26.35 445.51 9.7 455.71MW-3 995740 728101 468.49 471.01 25.15 445.86 9.7 456.06MW-4 995818 728546 468.34 470.96 25.54 445.42 9.7 456.62MW-5 995546 728819 467.42 470.06 24.68 445.38 9.7 455.58MW-6 995177 729227 467.09 469.68 23.10 446.58 9.7 456.78MW-7 994621 729411 466.65 469.15 21.94 447.21 9.7 457.41MW-8 994383 729643 465.57 468.25 21.82 446.43 9.7 456.63MW-9 994168 729893 465.14 467.81 20.18 447.63 9.7 457.83

MW-10 993950 730149 465.84 468.56 21.45 447.11 9.7 457.31MW-11 993725 730398 466.11 468.55 20.95 447.60 9.7 457.80MW-12 993470 730662 465.74 468.11 20.48 447.63 9.7 457.83MW-13 993256 730913 465.61 468.10 20.40 447.70 9.7 457.90MW-14 993052 731166 464.15 466.83 19.79 447.04 9.7 457.24MW-15 992807 731406 465.03 467.30 17.91 449.39 9.7 459.59MW-16 992618 731651 463.97 466.57 18.50 448.07 9.7 458.27MW-17 992302 731675 465.29 467.89 19.72 448.17 9.7 458.37MW-18 991678 730928 462.76 465.27 18.24 447.03 9.7 457.23MW-19 992089 730178 463.51 466.16 18.19 447.97 9.7 458.17MW-20 991669 729952 463.61 465.97 17.62 448.35 9.7 458.55MW-21 991334 729950 463.40 465.90 17.71 448.19 9.7 458.39MW-22 990929 729355 464.20 466.80 17.92 448.88 9.7 459.08MW-23 991099 728511 464.90 467.54 19.65 447.89 9.7 458.09MW-24 991819 727992 464.59 467.10 19.99 447.11 9.7 457.31MW-25 992707 727529 465.95 468.61 20.84 447.77 9.7 457.97MW-26 993976 726911 466.66 469.20 23.00 446.20 9.7 456.40MW-27 994664 726608 467.41 470.05 25.91 444.14 9.7 454.34MW-28 995276 726640 468.60 471.18 27.06 444.12 9.7 454.32TMW-1* 993783 728657 466.91 469.34 21.58 447.76 9.7 457.96

NOTES:

1. Refer to Figure 1 for monitoring well locations. 2. Monitoring well survey data provided by KdG, Inc. Ground Elevation at Monitoring Well is a Cut + on the Concrete Pad

Horizontal Datum: Missouri State Plane Coordinates - NAD 83 (Feet), Vertical Datum: NAVD 88 (Feet)

3. Numerical values were obtained from the Ameren Missouri Labadie Energy Center Utility Waste Landfill, Solid Waste Disposal Area, Franklin County, Missouri,

Groundwater Detection Monitoring Wells Installation Report prepared by Reitz & Jens, Inc., May 2013.

4. btor = below top of riser.

5. Actual screen length (9.7 feet) is the machine-slotted section of the 10-foot length of Schedule 40 PVC pipe.

* - TMW-1 is a temporary ("sentry") well located immediately east of initial cell construction area (Cell 1).

Prepared by: GREDELL Engineering Resources, Inc. May 2013



Groundwater Elevation SummaryTable 2

Monitoring Top ofWell RiserID Elev. (ft) Depth2 (ft) Elev. (ft)

MW-1 472.05 18.44 453.61MW-2 471.86 18.40 453.46MW-3 471.01 17.92 453.09MW-4 470.96 18.15 452.81MW-5 470.06 17.43 452.63MW-6 469.68 17.21 452.47MW-7 469.15 16.70 452.45MW-8 468.25 15.83 452.42MW-9 467.81 15.49 452.32MW-10 468.56 16.13 452.43MW-11 468.55 16.17 452.38MW-12 468.11 15.82 452.29MW-13 468.10 15.85 452.25MW-14 466.83 14.62 452.21MW-15 467.30 15.11 452.19MW-16 466.57 14.37 452.20MW-17 467.89 15.71 452.18MW-18 465.27 7.23 458.04MW-19 466.16 13.53 452.63MW-20 465.97 13.40 452.57MW-21 465.90 13.26 452.64MW-22 466.80 13.76 453.04MW-23 467.54 12.93 454.61MW-24 467.10 13.65 453.45MW-25 468.61 15.01 453.60MW-26 469.20 15.50 453.70MW-27 470.05 16.17 453.88MW-28 471.18 18.57 452.61TMW-1 469.34 16.21 453.13

5.86458.04452.18

NOTES:1 - Groundwater level measurements collected on April 16-17, 2013.2 - Depth measured from top of riser.

April 20131

Maximum Water Elevation (ft)Minimum Water Elevation (ft)

Monthly Variability (ft)

Groundwater

Prepared by: GREDELL Engineering Resources, Inc. May 2013



Background Water Quality SummaryTable 3

Constituent1 Spec.Cond. pH Chloride COD Fluoride Hardness SO4 TDS TOC TOX Ag Al As B Ba Be Ca Cd Co Cr Cu Fe Mg Mn Mo Na Ni Pb Sb Se Zn Hg Tl

Well Units2 µmhos/cm S.U. mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L mg/L µg/L µg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L

ID Date

MW-1 4/16/2013 991 6.83 10 <10 0.11 512 26 536 2.2 <0.02 <10.0 <50.0 22.1 79.4 402 <0.001 158 <2.0 3.3 "J" <10.0 <10.0 17000 28.7 1470 <10.0 5.05 0.0058 "J" <2.0 <5.0 <30.0 <10.0 <0.20 <2.0MW-2 4/16/2013 1305 6.85 17 <10 0.21 673 31 696 3.0 <0.02 <10.0 <50.0 29.5 121 416 <0.001 185 "S" <2.0 2.9 "J" <10.0 <10.0 28400 "S" 51.2 "S" 2960 <10.0 8.98 <0.0100 <2.0 <5.0 <30.0 2.5 "J" <0.20 <2.0MW-3 4/16/2013 987 6.99 9 <10 0.12 501 54 516 2.4 <0.02 <10.0 <50.0 1.2 "J" 63.6 415 <0.001 141 <2.0 <10.0 <10.0 3.3 "J" 16200 36.1 2760 <10.0 8.58 <0.0100 <2.0 <5.0 "S" <30.0 2.2 "J" <0.20 <2.0MW-4 4/16/2013 973 6.94 6 <10 0.18 527 25 532 1.5 <0.02 <10.0 <50.0 <3.0 72.8 274 <0.001 162 <2.0 <10.0 <10.0 <10.0 115 29.4 1240 <10.0 6.02 0.0091 "J" <2.0 <5.0 <30.0 <10.0 <0.20 <2.0MW-5 4/16/2013 899 6.86 2 "J" <10 0.16 486 16 "S" 482 1.4 <0.02 <10.0 <50.0 <3.0 52.9 293 <0.001 157 <2.0 <10.0 <10.0 <10.0 210 22.8 458 <10.0 5.33 0.0116 <2.0 <5.0 <30.0 2.1 "J" <0.20 <2.0MW-6 4/16/2013 992 6.82 3 "J" <10 0.14 539 19 "S" 566 1.8 <0.02 <10.0 37 "J" <3.0 62.2 227 <0.001 163 <2.0 <10.0 <10.0 <10.0 53.0 32.2 106 <10.0 6.78 0.0101 <2.0 <5.0 <30.0 4.3 "J" <0.20 <2.0MW-7 4/16/2013 1087 7.07 15 9 "J" 0.20 536 26 568 3.4 <0.02 <10.0 246 66.6 72.6 480 <0.001 150 <2.0 <10.0 <10.0 <10.0 30300 39.6 1670 <10.0 9.99 <0.0100 <2.0 <5.0 <30.0 2.9 "J" <0.20 <2.0MW-8 4/16/2013 856 6.83 8 7 "J" 0.16 431 10 "J" 460 2.6 <0.02 <10.0 <50.0 13.6 45.3 285 <0.001 136 <2.0 <10.0 <10.0 <10.0 23600 22.0 896 <10.0 4.95 <0.0100 <2.0 <5.0 <30.0 2.7 "J" <0.20 <2.0MW-9 4/16/2013 811 7.16 5 "J" <10 0.18 415 20 414 1.7 <0.02 <10.0 <50.0 26.4 53.6 265 <0.001 121 <2.0 <10.0 <10.0 <10.0 16700 27.5 1450 <10.0 5.44 <0.0100 <2.0 <5.0 <30.0 <10.0 <0.20 <2.0

MW-103 4/16/2013 947 6.99 6 <10 0.17 502 54 430 1.9 <0.02 <10.0 27 "J" 8.8 56.7 462 <0.001 144 <2.0 <10.0 <10.0 <10.0 16900 34.6 1350 <10.0 7.79 <0.0100 0.4 "J" <5.0 <30.0 <10.0 <0.20 <2.0MW-11 4/16/2013 887 6.89 2 "J" <10 0.12 493 64 "S" 460 1.8 <0.02 <10.0 <50.0 0.8 "J" 54.8 301 <0.001 145 <2.0 3.1 "J" <10.0 <10.0 436 32.0 523 <10.0 8.32 0.0068 "J" 0.5 "J" <5.0 <30.0 <10.0 <0.20 <2.0MW-12 4/16/2013 829 6.93 2 "J" <10 0.10 "J" 445 42 448 1.6 0.0151 "J" <10.0 18 "J" 1.4 "J" 52.9 253 <0.001 128 <2.0 3.0 "J" <10.0 <10.0 419 30.6 483 <10.0 6.96 0.0052 "J" <2.0 <5.0 <30.0 4.0 "J" <0.20 <2.0MW-13 4/16/2013 901 6.87 2 "J" <10 0.12 488 64 "S" 498 2.5 <0.02 <10.0 33 "J" <3.0 53.5 295 <0.001 143 <2.0 <10.0 <10.0 <10.0 59.2 32.0 117 <10.0 6.42 <0.0100 <2.0 <5.0 <30.0 5.1 "J" <0.20 <2.0MW-14 4/16/2013 843 6.95 3 "J" <10 0.14 465 42 490 1.8 <0.02 <10.0 30 "J" 7.1 48.2 268 <0.001 140 <2.0 3.3 "J" <10.0 <10.0 3590 27.8 979 <10.0 5.82 0.0039 "J" <2.0 <5.0 <30.0 5.5 "J" <0.20 <2.0MW-15 4/16/2013 791 6.84 2 "J" <10 0.16 436 27 404 1.7 <0.02 <10.0 <50.0 <3.0 58.1 206 <0.001 136 <2.0 <10.0 <10.0 <10.0 16 "J" 23.5 18.1 <10.0 5.64 0.0058 "J" <2.0 <5.0 <30.0 4.1 "J" <0.20 <2.0MW-16 4/16/2013 1038 6.85 6 <10 0.22 559 30 554 2.7 <0.02 <10.0 31 "J" 12.5 102 102 <0.001 157 <2.0 4.4 "J" <10.0 <10.0 8580 40.4 3740 <10.0 9.50 0.0041 "J" <2.0 <5.0 <30.0 5.0 "J" <0.20 <2.0MW-17 4/16/2013 1035 6.79 2 "J" <10 0.13 564 59 580 4.2 <0.02 <10.0 119 5.3 64.9 275 <0.001 165 "S" <2.0 3.4 "J" <10.0 <10.0 1620 36.7 "S" 1270 <10.0 8.58 0.0037 "J" 0.7 "J" <5.0 <30.0 3.5 "J" <0.20 <2.0MW-18 4/16/2013 861 7.00 1 "J" <10 0.18 450 34 476 1.7 0.0132 "J" <10.0 <50.0 <3.0 45.8 147 <0.001 135 <2.0 <10.0 <10.0 <10.0 22.3 27.3 89.5 <10.0 6.93 <0.0100 0.4 "J" <5.0 38.5 4.0 "J" <0.20 <2.0MW-19 4/16/2013 891 6.83 2 "J" <10 0.15 478 72 500 2.0 <0.02 <10.0 <50.0 <3.0 72.1 228 <0.001 143 <2.0 <10.0 <10.0 <10.0 136 29.4 98.9 <10.0 9.86 0.0057 "J" <2.0 <5.0 <30.0 4.2 "J" <0.20 <2.0MW-20 4/16/2013 663 6.99 2 "J" <10 0.19 355 21 356 2.3 <0.02 <10.0 <50.0 <3.0 48.7 182 <0.001 106 <2.0 <10.0 <10.0 <10.0 30.9 21.7 154 <10.0 5.21 0.0074 "J" 0.5 "J" <5.0 <30.0 4.0 "J" <0.20 <2.0MW-21 4/16/2013 675 6.92 3 "J" <10 0.16 350 30 262 1.6 0.0158 "J" <10.0 <50.0 1.0 "J" 57.7 237 <0.001 107 <2.0 <10.0 <10.0 <10.0 1080 19.9 412 <10.0 9.05 0.0036 "J" <2.0 <5.0 <30.0 3.8 "J" <0.20 <2.0MW-22 4/16/2013 1034 6.88 6 <10 0.25 537 30 560 2.8 <0.02 <10.0 <50.0 45.7 156 238 <0.001 145 <2.0 <10.0 <10.0 <10.0 19900 42.6 1900 <10.0 14.1 <0.0100 0.5 "J" <5.0 <30.0 4.1 "J" <0.20 <2.0MW-23 4/16/2013 1010 6.84 4 "J" <10 0.18 543 21 508 2.2 <0.02 <10.0 153 3.4 94.0 210 <0.001 144 <2.0 <10.0 <10.0 <10.0 3600 44.6 180 <10.0 17.0 0.0039 "J" <2.0 <5.0 <30.0 3.5 "J" <0.20 <2.0MW-24 4/16/2013 792 6.94 3 "J" <10 0.18 427 36 426 1.3 <0.02 <10.0 154 <3.0 47.1 190 <0.001 128 <2.0 <10.0 <10.0 3.0 "J" 277 25.9 4.1 "J" <10.0 7.71 0.0048 "J" 0.6 "J" <5.0 45.5 4.1 "J" <0.20 <2.0MW-25 4/16/2013 834 7.18 4 "J" <10 0.14 443 17 406 1.6 <0.02 <10.0 38 "J" 6.5 124 511 <0.001 132 <2.0 <10.0 <10.0 <10.0 4850 27.4 2730 <10.0 7.04 0.0036 "J" 0.7 "J" <5.0 <30.0 3.8 "J" <0.20 <2.0MW-26 4/16/2013 899 7.02 4 "J" <10 0.16 487 45 504 1.6 0.0175 "J" <10.0 55.5 <3.0 82.7 286 <0.001 146 <2.0 <10.0 <10.0 <10.0 630 29.9 3000 <10.0 7.84 0.0043 "J" 0.7 "J" <5.0 <30.0 <10.0 <0.20 <2.0MW-273 4/16/2013 1004 6.83 11 <10 0.18 549 29 576 1.8 0.0154 "J" <10.0 31 "J" 3.3 98.6 268 <0.001 169 <2.0 4.1 "J" <10.0 <10.0 3220 30.8 1280 <10.0 6.74 0.0058 "J" 0.5 "J" <5.0 <30.0 5.2 "J" <0.20 <2.0MW-28 4/16/2013 960 6.78 6 <10 0.16 530 31 556 1.7 <0.02 <10.0 16 "J" 1.5 "J" 86.7 269 <0.001 162 <2.0 <10.0 <10.0 <10.0 2020 30.2 402 <10.0 5.84 0.0082 "J" 1.0 "J" <5.0 <30.0 4.5 "J" <0.20 <2.0TMW-1 4/16/2013 1139 7.01 6 <10 0.26 593 128 674 2.6 <0.02 <10.0 <50.0 29.5 100 355 <0.001 163 "S" <2.0 <10.0 <10.0 <10.0 12100 "S" 45.4 "S" 4690 <10.0 11.0 0.0036 "J" <2.0 <5.0 <30.0 5.5 "J" <0.20 <2.0

NOTES:

1. Abbreviated chemical constituent names are defined in Table 4.

2. Abbreviated units for chemical constituents are defined in Table 4.

3. Duplicate 1 is a duplicate sample of MW-27. Duplicate 2 is a duplicate sample of MW-10. Analytical results for the duplicate samples are provided in Appendix 2.

"J" Flag - Analyte detected below quantitation limits

"S" Flag - Spike Recovery outside recovery limits

Sequence of sample collection for April 16 and 17, 2013 event is MW-22 through MW-28, MW-1 through MW-15, MW-21, MW-20, MW-19, MW-18, MW-17, MW-16 and TMW-1.

Prepared by: GREDELL Engineering Resources, Inc. 1 May 2013

Ameren Missouri Labadie Energy Center Proposed Utility Waste Landfill


Constituents for Detection Monitoring (10 CSR 80-11.010 – Appendix I)

Table 4

Prepared by: GREDELL May 2013 Engineering Resources, Inc.

NOTES: 1. µg/L = micrograms per liter mg/L = milligrams per liter S.U. = Standard Unit µmhos/cm = micromhos per centimeter 2. Suggested Methods refer to analytical procedure numbers used in EPA Report SW-846 "Test Methods for

Evaluating Solid Waste", third edition, November 1986, as revised, December 1987, or applicable updates. 3. Practical Quantitation Limits as established by the contract laboratory. 4. Molybdenum added per the request of the MDNR-SWMP in correspondence dated March 7, 2013.

Chemical Constituent Units1 Method2 PQL3

Aluminum (Al) µg/L 6010B 50 Antimony (Sb) µg/L 7041 5 Arsenic (As) µg/L 7060A 3 Barium (Ba) µg/L 6010B 5 Beryllium (Be) mg/L 6010B 0.001 Boron (B) µg/L 6010B 20 Cadmium (Cd) µg/L 6010B 2 Calcium (Ca) mg/L 6010B 0.05 Chemical Oxygen Demand (COD) mg/L 410.4 10 Chloride mg/L 9251 5 Chromium (Cr) µg/L 6010B 10 Cobalt (Co) µg/L 6010B 10 Copper (Cu) µg/L 6010B 10 Fluoride mg/L 9214 0.10 Hardness mg/L 2340B NA Iron (Fe) µg/L 6010B 20 Lead (Pb) µg/L 7421 2 Magnesium (Mg) mg/L 6010B 0.010 Manganese (Mn) µg/L 6010B 5 Mercury (Hg) µg/L 7470A 0.2 Molybdenum (Mo)4 µg/L 6010B 10 Nickel (Ni) mg/L 6010B 0.01 pH (Field) S.U. 9040B NA Selenium (Se) µg/L 6010B 50 Silver (Ag) µg/L 6010B 10 Sodium (Na) mg/L 6010B 0.05 Specific Conductance (Field) µmhos/cm 9050A NA Sulfate (SO4) mg/L 9036 10 Thallium (Tl) µg/L 7841 2 Total Dissolved Solids (TDS) mg/L 2540C 20 Total Organic Carbon (TOC) mg/L 9060 1 Total Organic Halogens (TOX) mg/L 9020B 20 Zinc (Zn) µg/L 6010B 10 Ground Water Elevation feet NA NA

FIGURES

APPENDICES

Appendix 1

Field Notes and Field Information Sheets

Appendix 2

Laboratory Analytical Results

TeklabHdrP

Laboratory Results

Client Project: Ameren Labadie UWL

Client: Gredell Engineering Resources, Inc.

Report Date: 08-May-13

Work Order: 13040937

http://www.teklabinc.com/

Analyses Result Units Date AnalyzedRL DFCertification Qual

Collection Date: 04/16/2013 13:38

Lab ID: 13040937-001 Client Sample ID: MW-01

Matrix: GROUNDWATER

Batch

FIELD ELEVATION MEASUREMENTSElevation of groundwater surface 04/16/2013 13:380 ft 1453.61 R176371

SW-846 9040BpH, Field 04/16/2013 13:381.00 16.83 R176371

SW-846 9050ASpec. Conductance, Field 04/16/2013 13:381 µmhos/cm 1991 R176371

EPA 600 410.4Chemical Oxygen Demand 04/19/2013 14:2010 mg/L 1< 10NELAP R176172

STANDARD METHODS 2540 C (TOTAL)Total Dissolved Solids 04/19/2013 19:0020 mg/L 1536NELAP R176235

SW-846 9036 (TOTAL)Sulfate 04/19/2013 0:1610 mg/L 126NELAP R176145

SW-846 9060Total Organic Carbon (TOC) 04/18/2013 15:001.0 mg/L 12.2NELAP R176138

SW-846 9214 (TOTAL)Fluoride 04/23/2013 11:260.10 mg/L 10.11NELAP R176302

SW-846 9251 (TOTAL)Chloride 04/19/2013 0:165 mg/L 110NELAP R176155

STANDARD METHODS 2340 B, HARDNESS (TOTAL)Hardness, as ( CaCO3 ) 04/19/2013 0:001.00 mg/L 1512NELAP R176148

SW-846 3005A, 6010B, METALS BY ICP (TOTAL)Aluminum 04/19/2013 13:5050.0 µg/L 1< 50.0NELAP 87609

Barium 04/19/2013 13:505.0 µg/L 1402NELAP 87609

Beryllium 04/19/2013 13:501.0 µg/L 1< 1.0NELAP 87609

Boron 04/19/2013 13:5020.0 µg/L 179.4NELAP 87609

Cadmium 04/19/2013 13:502.0 µg/L 1< 2.0NELAP 87609

Calcium 04/19/2013 13:500.050 mg/L 1158NELAP 87609

Chromium 04/19/2013 13:5010.0 µg/L 1< 10.0NELAP 87609

Cobalt J 04/19/2013 13:5010.0 µg/L 13.3NELAP 87609

Copper 04/19/2013 13:5010.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 13:5020.0 µg/L 117000NELAP 87609

Magnesium 04/19/2013 13:500.010 mg/L 128.7NELAP 87609

Manganese 04/19/2013 13:505.0 µg/L 11470NELAP 87609

Molybdenum 04/19/2013 13:5010.0 µg/L 1< 10.0NELAP 87609

Nickel J 04/19/2013 13:5010.0 µg/L 15.8NELAP 87609

Selenium 04/19/2013 13:5030.0 µg/L 1< 30.0NELAP 87609

Silver 04/19/2013 13:5010.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 13:500.050 mg/L 15.05NELAP 87609

Zinc 04/19/2013 13:5010.0 µg/L 1< 10.0NELAP 87609

SW-846 3005A, 7010 METALS BY GFAA (TOTAL)Antimony 05/02/2013 21:195.0 µg/L 1< 5.0NELAP 87612

Arsenic 05/01/2013 19:456.0 µg/L 222.1NELAP 87612

Lead 05/01/2013 11:052.0 µg/L 1< 2.0NELAP 87612

Thallium 05/03/2013 17:372.0 µg/L 1< 2.0NELAP 87612

SW-846 7470A (TOTAL)Mercury 04/19/2013 11:460.20 µg/L 1< 0.20NELAP 87601

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Matrix: GROUNDWATER

Batch

SW-846 9020BTotal Organic Halides (TOX) 04/19/2013 9:1320.0 µg/L 1< 20.0NELAP R176204

Page 6 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 14:111.00 16.85 R176371










Barium 04/19/2013 13:545.0 µg/L 1416NELAP 87609


Boron 04/19/2013 13:5420.0 µg/L 1121NELAP 87609


Calcium S 04/19/2013 13:540.050 mg/L 1185NELAP 87609



Copper 04/19/2013 13:5410.0 µg/L 1< 10.0NELAP 87609

Iron S 04/19/2013 13:5420.0 µg/L 128400NELAP 87609

Magnesium S 04/19/2013 13:540.010 mg/L 151.2NELAP 87609



Nickel 04/19/2013 13:5410.0 µg/L 1< 10.0NELAP 87609


Silver 04/19/2013 13:5410.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 13:540.050 mg/L 18.98NELAP 87609

Zinc J 04/19/2013 13:5410.0 µg/L 12.5NELAP 87609

MS QC limits for Ca and Mg are not applicable due to high sample/spike ratio.MS QC limit for Fe are not applicable due to high sample/spike ratio.



Lead 05/01/2013 11:082.0 µg/L 1< 2.0NELAP 87612


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Matrix: GROUNDWATER

Batch



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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 14:391.00 16.99 R176371










Barium 04/19/2013 14:055.0 µg/L 1415NELAP 87609


Boron 04/19/2013 14:0520.0 µg/L 163.6NELAP 87609




Cobalt 04/19/2013 14:0510.0 µg/L 1< 10.0NELAP 87609

Copper J 04/19/2013 14:0510.0 µg/L 13.3NELAP 87609

Iron 04/19/2013 14:0520.0 µg/L 116200NELAP 87609




Nickel 04/19/2013 14:0510.0 µg/L 1< 10.0NELAP 87609


Silver 04/19/2013 14:0510.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 14:050.050 mg/L 18.58NELAP 87609

Zinc J 04/19/2013 14:0510.0 µg/L 12.2NELAP 87609

SW-846 3005A, 7010 METALS BY GFAA (TOTAL)Antimony S 05/03/2013 14:025.0 µg/L 1< 5.0NELAP 87612

Arsenic J 05/03/2013 11:493.0 µg/L 11.2NELAP 87612

Lead 05/01/2013 11:122.0 µg/L 1< 2.0NELAP 87612


Sb - Matrix interference present in sample. Confirmed by bench spike.


Page 9 of 112

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Matrix: GROUNDWATER

Batch


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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 15:221.00 16.94 R176371










Barium 04/19/2013 14:085.0 µg/L 1274NELAP 87609


Boron 04/19/2013 14:0820.0 µg/L 172.8NELAP 87609




Cobalt 04/19/2013 14:0810.0 µg/L 1< 10.0NELAP 87609

Copper 04/19/2013 14:0810.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 14:0820.0 µg/L 1115NELAP 87609






Silver 04/19/2013 14:0810.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 14:080.050 mg/L 16.02NELAP 87609

Zinc 04/19/2013 14:0810.0 µg/L 1< 10.0NELAP 87609


Arsenic 05/03/2013 11:593.0 µg/L 1< 3.0NELAP 87612

Lead 05/01/2013 11:222.0 µg/L 1< 2.0NELAP 87612



Page 11 of 112

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Matrix: GROUNDWATER

Batch


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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 15:581.00 16.86 R176371




SW-846 9036 (TOTAL)Sulfate S 04/19/2013 1:3510 mg/L 116NELAP R176145

MS and/or MSD did not recover within control limits due to matrix interference.



SW-846 9251 (TOTAL)Chloride J 04/19/2013 1:355 mg/L 12NELAP R176155



Barium 04/19/2013 14:125.0 µg/L 1293NELAP 87609


Boron 04/19/2013 14:1220.0 µg/L 152.9NELAP 87609




Cobalt 04/19/2013 14:1210.0 µg/L 1< 10.0NELAP 87609

Copper 04/19/2013 14:1210.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 14:1220.0 µg/L 1210NELAP 87609




Nickel 04/19/2013 14:1210.0 µg/L 111.6NELAP 87609


Silver 04/19/2013 14:1210.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 14:120.050 mg/L 15.33NELAP 87609

Zinc J 04/19/2013 14:1210.0 µg/L 12.1NELAP 87609



Lead 05/02/2013 15:352.0 µg/L 1< 2.0NELAP 87612



Page 13 of 112

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Matrix: GROUNDWATER

Batch


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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 16:271.00 16.82 R176371










SW-846 3005A, 6010B, METALS BY ICP (TOTAL)Aluminum J 04/19/2013 14:1650.0 µg/L 137NELAP 87609

Barium 04/19/2013 14:165.0 µg/L 1227NELAP 87609


Boron 04/19/2013 14:1620.0 µg/L 162.2NELAP 87609




Cobalt 04/19/2013 14:1610.0 µg/L 1< 10.0NELAP 87609

Copper 04/19/2013 14:1610.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 14:1620.0 µg/L 153.0NELAP 87609




Nickel 04/19/2013 14:1610.0 µg/L 110.1NELAP 87609


Silver 04/19/2013 14:1610.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 14:160.050 mg/L 16.78NELAP 87609

Zinc J 04/19/2013 14:1610.0 µg/L 14.3NELAP 87609



Lead 05/02/2013 15:452.0 µg/L 1< 2.0NELAP 87612



Page 15 of 112

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Matrix: GROUNDWATER

Batch


Page 16 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 17:061.00 17.07 R176371


EPA 600 410.4Chemical Oxygen Demand J 04/19/2013 14:2310 mg/L 19NELAP R176172







SW-846 3005A, 6010B, METALS BY ICP (TOTAL)Aluminum 04/19/2013 14:4050.0 µg/L 1246NELAP 87609

Barium 04/19/2013 14:405.0 µg/L 1480NELAP 87609


Boron 04/19/2013 14:4020.0 µg/L 172.6NELAP 87609




Cobalt 04/19/2013 14:4010.0 µg/L 1< 10.0NELAP 87609

Copper 04/19/2013 14:4010.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 14:4020.0 µg/L 130300NELAP 87609




Nickel 04/19/2013 14:4010.0 µg/L 1< 10.0NELAP 87609


Silver 04/19/2013 14:4010.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 14:400.050 mg/L 19.99NELAP 87609

Zinc J 04/19/2013 14:4010.0 µg/L 12.9NELAP 87609



Lead 05/02/2013 15:482.0 µg/L 1< 2.0NELAP 87612



Page 17 of 112

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Matrix: GROUNDWATER

Batch


Page 18 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 7:461.00 16.83 R176371


EPA 600 410.4Chemical Oxygen Demand J 04/19/2013 14:2310 mg/L 17NELAP R176172


SW-846 9036 (TOTAL)Sulfate J 04/19/2013 1:4510 mg/L 110NELAP R176145






Barium 04/19/2013 14:435.0 µg/L 1285NELAP 87609


Boron 04/19/2013 14:4320.0 µg/L 145.3NELAP 87609




Cobalt 04/19/2013 14:4310.0 µg/L 1< 10.0NELAP 87609

Copper 04/19/2013 14:4310.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 14:4320.0 µg/L 123600NELAP 87609




Nickel 04/19/2013 14:4310.0 µg/L 1< 10.0NELAP 87609


Silver 04/19/2013 14:4310.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 14:430.050 mg/L 14.95NELAP 87609

Zinc J 04/19/2013 14:4310.0 µg/L 12.7NELAP 87609



Lead 05/02/2013 15:522.0 µg/L 1< 2.0NELAP 87612



Page 19 of 112

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Matrix: GROUNDWATER

Batch


Page 20 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 8:151.00 17.16 R176371










Barium 04/19/2013 14:475.0 µg/L 1265NELAP 87609


Boron 04/19/2013 14:4720.0 µg/L 153.6NELAP 87609




Cobalt 04/19/2013 14:4710.0 µg/L 1< 10.0NELAP 87609

Copper 04/19/2013 14:4710.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 14:4720.0 µg/L 116700NELAP 87609




Nickel 04/19/2013 14:4710.0 µg/L 1< 10.0NELAP 87609


Silver 04/19/2013 14:4710.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 14:470.050 mg/L 15.44NELAP 87609

Zinc 04/19/2013 14:4710.0 µg/L 1< 10.0NELAP 87609



Lead 05/02/2013 15:552.0 µg/L 1< 2.0NELAP 87612



Page 21 of 112

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Matrix: GROUNDWATER

Batch


Page 22 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 8:471.00 16.99 R176371










Barium 04/19/2013 14:515.0 µg/L 1462NELAP 87609


Boron 04/19/2013 14:5120.0 µg/L 156.7NELAP 87609




Cobalt 04/19/2013 14:5110.0 µg/L 1< 10.0NELAP 87609

Copper 04/19/2013 14:5110.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 14:5120.0 µg/L 116900NELAP 87609




Nickel 04/19/2013 14:5110.0 µg/L 1< 10.0NELAP 87609


Silver 04/19/2013 14:5110.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 14:510.050 mg/L 17.79NELAP 87609

Zinc 04/19/2013 14:5110.0 µg/L 1< 10.0NELAP 87609



Lead J 05/02/2013 15:582.0 µg/L 10.4NELAP 87612



Page 23 of 112

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Matrix: GROUNDWATER

Batch


Page 24 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 9:281.00 16.89 R176371











Barium 04/19/2013 14:555.0 µg/L 1301NELAP 87609


Boron 04/19/2013 14:5520.0 µg/L 154.8NELAP 87609





Copper 04/19/2013 14:5510.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 14:5520.0 µg/L 1436NELAP 87609






Silver 04/19/2013 14:5510.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 14:550.050 mg/L 18.32NELAP 87609

Zinc 04/19/2013 14:5510.0 µg/L 1< 10.0NELAP 87609



Lead J 05/02/2013 16:022.0 µg/L 10.5NELAP 87612



Page 25 of 112

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Matrix: GROUNDWATER

Batch


Page 26 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 10:041.00 16.93 R176371





Results of MS and/or MSD have less certainty because value(s) exceed upper quantitation limits.


SW-846 9214 (TOTAL)Fluoride J 04/23/2013 11:470.10 mg/L 10.10NELAP R176302




Barium 04/19/2013 14:585.0 µg/L 1253NELAP 87609


Boron 04/19/2013 14:5820.0 µg/L 152.9NELAP 87609





Copper 04/19/2013 14:5810.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 14:5820.0 µg/L 1419NELAP 87609






Silver 04/19/2013 14:5810.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 14:580.050 mg/L 16.96NELAP 87609

Zinc J 04/19/2013 14:5810.0 µg/L 14.0NELAP 87609



Lead 05/02/2013 16:052.0 µg/L 1< 2.0NELAP 87612



Page 27 of 112

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Matrix: GROUNDWATER

Batch

SW-846 9020BTotal Organic Halides (TOX) J 04/22/2013 11:2020.0 µg/L 115.1NELAP R176262

Page 28 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 10:451.00 16.87 R176371











Barium 04/19/2013 15:025.0 µg/L 1295NELAP 87609


Boron 04/19/2013 15:0220.0 µg/L 153.5NELAP 87609




Cobalt 04/19/2013 15:0210.0 µg/L 1< 10.0NELAP 87609

Copper 04/19/2013 15:0210.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 15:0220.0 µg/L 159.2NELAP 87609




Nickel 04/19/2013 15:0210.0 µg/L 112.3NELAP 87609


Silver 04/19/2013 15:0210.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 15:020.050 mg/L 16.42NELAP 87609

Zinc J 04/19/2013 15:0210.0 µg/L 15.1NELAP 87609



Lead 05/03/2013 9:582.0 µg/L 1< 2.0NELAP 87612



Page 29 of 112

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Matrix: GROUNDWATER

Batch


Page 30 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 11:151.00 16.95 R176371










Barium 04/19/2013 15:065.0 µg/L 1268NELAP 87609


Boron 04/19/2013 15:0620.0 µg/L 148.2NELAP 87609





Copper 04/19/2013 15:0610.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 15:0620.0 µg/L 13590NELAP 87609






Silver 04/19/2013 15:0610.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 15:060.050 mg/L 15.82NELAP 87609

Zinc J 04/19/2013 15:0610.0 µg/L 15.5NELAP 87609



Lead 05/02/2013 16:192.0 µg/L 1< 2.0NELAP 87612



Page 31 of 112

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Matrix: GROUNDWATER

Batch


Page 32 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 11:491.00 16.84 R176371










Barium 04/19/2013 15:095.0 µg/L 1206NELAP 87609


Boron 04/19/2013 15:0920.0 µg/L 158.1NELAP 87609




Cobalt 04/19/2013 15:0910.0 µg/L 1< 10.0NELAP 87609

Copper 04/19/2013 15:0910.0 µg/L 1< 10.0NELAP 87609

Iron J 04/19/2013 15:0920.0 µg/L 116NELAP 87609


Manganese 04/19/2013 15:095.0 µg/L 118.1NELAP 87609




Silver 04/19/2013 15:0910.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 15:090.050 mg/L 15.64NELAP 87609

Zinc J 04/19/2013 15:0910.0 µg/L 14.1NELAP 87609



Lead 05/02/2013 16:222.0 µg/L 1< 2.0NELAP 87612



Page 33 of 112

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Matrix: GROUNDWATER

Batch


Page 34 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 15:541.00 16.85 R176371










Barium 04/19/2013 15:135.0 µg/L 1377NELAP 87609


Boron 04/19/2013 15:1320.0 µg/L 1102NELAP 87609





Copper 04/19/2013 15:1310.0 µg/L 1< 10.0NELAP 87609

Iron 04/19/2013 15:1320.0 µg/L 18580NELAP 87609






Silver 04/19/2013 15:1310.0 µg/L 1< 10.0NELAP 87609

Sodium 04/19/2013 15:130.050 mg/L 19.50NELAP 87609

Zinc J 04/19/2013 15:1310.0 µg/L 15.0NELAP 87609



Lead 05/02/2013 16:252.0 µg/L 1< 2.0NELAP 87612



Page 35 of 112

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Matrix: GROUNDWATER

Batch


Page 36 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 15:211.00 16.79 R176371










Barium 04/19/2013 15:315.0 µg/L 1275NELAP 87610


Boron 04/19/2013 15:3120.0 µg/L 164.9NELAP 87610





Copper 04/19/2013 15:3110.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 15:3120.0 µg/L 11620NELAP 87610






Silver 04/19/2013 15:3110.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 15:310.050 mg/L 18.58NELAP 87610

Zinc J 04/19/2013 15:3110.0 µg/L 13.5NELAP 87610

MS QC limits for Ca and Mg are not applicable due to high sample/spike ratio.



Lead J 05/02/2013 16:292.0 µg/L 10.7NELAP 87612



Page 37 of 112

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Matrix: GROUNDWATER

Batch


Page 38 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 14:491.00 17.00 R176371










Barium 04/19/2013 15:425.0 µg/L 1147NELAP 87610


Boron 04/19/2013 15:4220.0 µg/L 145.8NELAP 87610




Cobalt 04/19/2013 15:4210.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 15:4210.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 15:4220.0 µg/L 122.3NELAP 87610




Nickel 04/19/2013 15:4210.0 µg/L 1< 10.0NELAP 87610

Selenium 04/19/2013 15:4230.0 µg/L 138.5NELAP 87610

Silver 04/19/2013 15:4210.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 15:420.050 mg/L 16.93NELAP 87610

Zinc J 04/19/2013 15:4210.0 µg/L 14.0NELAP 87610



Lead J 05/02/2013 16:322.0 µg/L 10.4NELAP 87612



Page 39 of 112

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Matrix: GROUNDWATER

Batch


Page 40 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 14:181.00 16.83 R176371










Barium 04/19/2013 15:465.0 µg/L 1228NELAP 87610


Boron 04/19/2013 15:4620.0 µg/L 172.1NELAP 87610




Cobalt 04/19/2013 15:4610.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 15:4610.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 15:4620.0 µg/L 1136NELAP 87610






Silver 04/19/2013 15:4610.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 15:460.050 mg/L 19.86NELAP 87610

Zinc J 04/19/2013 15:4610.0 µg/L 14.2NELAP 87610



Lead 05/02/2013 16:362.0 µg/L 1< 2.0NELAP 87612



Page 41 of 112

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Matrix: GROUNDWATER

Batch


Page 42 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 13:381.00 16.99 R176371










Barium 04/19/2013 15:505.0 µg/L 1182NELAP 87610


Boron 04/19/2013 15:5020.0 µg/L 148.7NELAP 87610




Cobalt 04/19/2013 15:5010.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 15:5010.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 15:5020.0 µg/L 130.9NELAP 87610






Silver 04/19/2013 15:5010.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 15:500.050 mg/L 15.21NELAP 87610

Zinc J 04/19/2013 15:5010.0 µg/L 14.0NELAP 87610



Lead J 05/02/2013 16:392.0 µg/L 10.5NELAP 87612



Page 43 of 112

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Matrix: GROUNDWATER

Batch


Page 44 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 12:571.00 16.92 R176371










Barium 04/19/2013 15:535.0 µg/L 1237NELAP 87610


Boron 04/19/2013 15:5320.0 µg/L 157.7NELAP 87610




Cobalt 04/19/2013 15:5310.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 15:5310.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 15:5320.0 µg/L 11080NELAP 87610






Silver 04/19/2013 15:5310.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 15:530.050 mg/L 19.05NELAP 87610

Zinc J 04/19/2013 15:5310.0 µg/L 13.8NELAP 87610



Lead 05/03/2013 10:042.0 µg/L 1< 2.0NELAP 87614



Page 45 of 112

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Matrix: GROUNDWATER

Batch


Page 46 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 8:241.00 16.88 R176371










Barium 04/19/2013 15:575.0 µg/L 1238NELAP 87610


Boron 04/19/2013 15:5720.0 µg/L 1156NELAP 87610




Cobalt 04/19/2013 15:5710.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 15:5710.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 15:5720.0 µg/L 119900NELAP 87610




Nickel 04/19/2013 15:5710.0 µg/L 1< 10.0NELAP 87610


Silver 04/19/2013 15:5710.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 15:570.050 mg/L 114.1NELAP 87610

Zinc J 04/19/2013 15:5710.0 µg/L 14.1NELAP 87610



Lead J 05/02/2013 17:062.0 µg/L 10.5NELAP 87614



Page 47 of 112

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Matrix: GROUNDWATER

Batch


Page 48 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 9:131.00 16.84 R176371










Barium 04/19/2013 16:085.0 µg/L 1210NELAP 87610


Boron 04/19/2013 16:0820.0 µg/L 194.0NELAP 87610




Cobalt 04/19/2013 16:0810.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 16:0810.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 16:0820.0 µg/L 13600NELAP 87610






Silver 04/19/2013 16:0810.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 16:080.050 mg/L 117.0NELAP 87610

Zinc J 04/19/2013 16:0810.0 µg/L 13.5NELAP 87610



Lead 05/02/2013 17:102.0 µg/L 1< 2.0NELAP 87614



Page 49 of 112

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Matrix: GROUNDWATER

Batch


Page 50 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 9:521.00 16.94 R176371










Barium 04/19/2013 16:125.0 µg/L 1190NELAP 87610


Boron 04/19/2013 16:1220.0 µg/L 147.1NELAP 87610




Cobalt 04/19/2013 16:1210.0 µg/L 1< 10.0NELAP 87610

Copper J 04/19/2013 16:1210.0 µg/L 13.0NELAP 87610

Iron 04/19/2013 16:1220.0 µg/L 1277NELAP 87610


Manganese J 04/19/2013 16:125.0 µg/L 14.1NELAP 87610



Selenium 04/19/2013 16:1230.0 µg/L 145.5NELAP 87610

Silver 04/19/2013 16:1210.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 16:120.050 mg/L 17.71NELAP 87610

Zinc J 04/19/2013 16:1210.0 µg/L 14.1NELAP 87610



Lead J 05/02/2013 17:132.0 µg/L 10.6NELAP 87614



Page 51 of 112

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Matrix: GROUNDWATER

Batch


Page 52 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 10:261.00 17.18 R176371










Barium 04/19/2013 16:155.0 µg/L 1511NELAP 87610


Boron 04/19/2013 16:1520.0 µg/L 1124NELAP 87610




Cobalt 04/19/2013 16:1510.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 16:1510.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 16:1520.0 µg/L 14850NELAP 87610






Silver 04/19/2013 16:1510.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 16:150.050 mg/L 17.04NELAP 87610

Zinc J 04/19/2013 16:1510.0 µg/L 13.8NELAP 87610



Lead J 05/02/2013 17:162.0 µg/L 10.7NELAP 87614



Page 53 of 112

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Matrix: GROUNDWATER

Batch


Page 54 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 11:001.00 17.02 R176371









SW-846 3005A, 6010B, METALS BY ICP (TOTAL)Aluminum 04/19/2013 16:1950.0 µg/L 155.5NELAP 87610

Barium 04/19/2013 16:195.0 µg/L 1286NELAP 87610


Boron 04/19/2013 16:1920.0 µg/L 182.7NELAP 87610




Cobalt 04/19/2013 16:1910.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 16:1910.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 16:1920.0 µg/L 1630NELAP 87610






Silver 04/19/2013 16:1910.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 16:190.050 mg/L 17.84NELAP 87610

Zinc 04/19/2013 16:1910.0 µg/L 1< 10.0NELAP 87610



Lead J 05/02/2013 17:202.0 µg/L 10.7NELAP 87614



Page 55 of 112

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Matrix: GROUNDWATER

Batch


Page 56 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 12:101.00 16.83 R176371










Barium 04/19/2013 16:235.0 µg/L 1268NELAP 87610


Boron 04/19/2013 16:2320.0 µg/L 198.6NELAP 87610





Copper 04/19/2013 16:2310.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 16:2320.0 µg/L 13220NELAP 87610






Silver 04/19/2013 16:2310.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 16:230.050 mg/L 16.74NELAP 87610

Zinc J 04/19/2013 16:2310.0 µg/L 15.2NELAP 87610



Lead J 05/03/2013 10:182.0 µg/L 10.5NELAP 87614



Page 57 of 112

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Matrix: GROUNDWATER

Batch


Page 58 of 112

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Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/16/2013 13:051.00 16.78 R176371










Barium 04/19/2013 16:265.0 µg/L 1269NELAP 87610


Boron 04/19/2013 16:2620.0 µg/L 186.7NELAP 87610




Cobalt 04/19/2013 16:2610.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 16:2610.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 16:2620.0 µg/L 12020NELAP 87610






Silver 04/19/2013 16:2610.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 16:260.050 mg/L 15.84NELAP 87610

Zinc J 04/19/2013 16:2610.0 µg/L 14.5NELAP 87610



Lead J 05/02/2013 17:402.0 µg/L 11.0NELAP 87614



Page 59 of 112

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Matrix: GROUNDWATER

Batch


Page 60 of 112

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Lab ID: 13040937-029 Client Sample ID: TMW-01

Matrix: GROUNDWATER

Batch


SW-846 9040BpH, Field 04/17/2013 16:271.00 17.01 R176371










Barium 04/19/2013 16:305.0 µg/L 1355NELAP 87610


Boron 04/19/2013 16:3020.0 µg/L 1100NELAP 87610




Cobalt 04/19/2013 16:3010.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 16:3010.0 µg/L 1< 10.0NELAP 87610

Iron S 04/19/2013 16:3020.0 µg/L 112100NELAP 87610






Silver 04/19/2013 16:3010.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 16:300.050 mg/L 111.0NELAP 87610

Zinc J 04/19/2013 16:3010.0 µg/L 15.5NELAP 87610

MS QC limits for Ca and Mg are not applicable due to high sample/spike ratio.MS QC limit for Fe are not applicable due to high sample/spike ratio.



Lead 05/02/2013 17:442.0 µg/L 1< 2.0NELAP 87614


Page 61 of 112

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Lab ID: 13040937-029 Client Sample ID: TMW-01

Matrix: GROUNDWATER

Batch



Page 62 of 112

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Lab ID: 13040937-030 Client Sample ID: Dup 1

Matrix: GROUNDWATER

Batch









Barium 04/19/2013 16:415.0 µg/L 1265NELAP 87610


Boron 04/19/2013 16:4120.0 µg/L 194.2NELAP 87610





Copper 04/19/2013 16:4110.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 16:4120.0 µg/L 12920NELAP 87610



Molybdenum J 04/19/2013 16:4110.0 µg/L 13.5NELAP 87610



Silver 04/19/2013 16:4110.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 16:410.050 mg/L 16.65NELAP 87610

Zinc J 04/19/2013 16:4110.0 µg/L 12.5NELAP 87610



Lead 05/02/2013 17:472.0 µg/L 1< 2.0NELAP 87614




Page 63 of 112

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Lab ID: 13040937-031 Client Sample ID: Dup 2

Matrix: GROUNDWATER

Batch









Barium 04/19/2013 16:525.0 µg/L 1439NELAP 87610


Boron 04/19/2013 16:5220.0 µg/L 155.9NELAP 87610




Cobalt 04/19/2013 16:5210.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 16:5210.0 µg/L 1< 10.0NELAP 87610

Iron 04/19/2013 16:5220.0 µg/L 116200NELAP 87610



Molybdenum J 04/19/2013 16:5210.0 µg/L 13.3NELAP 87610

Nickel 04/19/2013 16:5210.0 µg/L 1< 10.0NELAP 87610


Silver 04/19/2013 16:5210.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 16:520.050 mg/L 17.68NELAP 87610

Zinc J 04/19/2013 16:5210.0 µg/L 13.2NELAP 87610



Lead 05/02/2013 17:502.0 µg/L 1< 2.0NELAP 87614




Page 64 of 112

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Lab ID: 13040937-032 Client Sample ID: Field Blank

Matrix: GROUNDWATER

Batch


STANDARD METHODS 2540 C (TOTAL)Total Dissolved Solids 04/19/2013 19:1020 mg/L 1< 20NELAP R176235

SW-846 9036 (TOTAL)Sulfate J 04/19/2013 21:1010 mg/L 15NELAP R176207

SW-846 9060Total Organic Carbon (TOC) 04/18/2013 21:541.0 mg/L 1< 1.0NELAP R176138

SW-846 9214 (TOTAL)Fluoride 04/23/2013 16:200.10 mg/L 1< 0.10NELAP R176304


STANDARD METHODS 2340 B, HARDNESS (TOTAL)Hardness, as ( CaCO3 ) J 04/19/2013 0:001.00 mg/L 10.27NELAP R176148


Barium 04/19/2013 16:565.0 µg/L 1< 5.0NELAP 87610


Boron 04/19/2013 16:5620.0 µg/L 136.7NELAP 87610


Calcium 04/19/2013 16:560.050 mg/L 10.091NELAP 87610


Cobalt 04/19/2013 16:5610.0 µg/L 1< 10.0NELAP 87610

Copper 04/19/2013 16:5610.0 µg/L 130.4NELAP 87610

Iron J 04/19/2013 16:5620.0 µg/L 113NELAP 87610


Manganese 04/19/2013 16:565.0 µg/L 1< 5.0NELAP 87610


Nickel 04/19/2013 16:5610.0 µg/L 1< 10.0NELAP 87610


Silver 04/19/2013 16:5610.0 µg/L 1< 10.0NELAP 87610

Sodium 04/19/2013 16:560.050 mg/L 10.464NELAP 87610

Zinc 04/19/2013 16:5610.0 µg/L 124.7NELAP 87610



Lead 05/02/2013 17:542.0 µg/L 1< 2.0NELAP 87614




Page 65 of 112

TeklabHdrP

Laboratory Results








Lab ID: 13040937-033 Client Sample ID: Trip Blank

Matrix: TRIP BLANK

Batch


Page 66 of 112

Appendix 3

Laboratory Analytical Quality Assurance/Quality Control Data and Chain-of-Custody


May 08, 2013

WorkOrder: 13040937Ameren Labadie UWLRE:

Dear Travis Doll:

TEKLAB, INC received 33 samples on 4/18/2013 10:00:00 AM for the analysis presented in the following report.

Samples are analyzed on an as received basis unless otherwise requested and documented. The sample results contained in this report relate only to the requested analytes of interest as directed on the chain of custody. NELAP accredited fields of testing are indicated by the letters NELAP under the Certification column. Unless otherwise documented within this report, Teklab Inc. analyzes samples utilizing the most current methods in compliance with 40CFR. All tests are performed in the Collinsville, IL laboratory unless otherwise noted in the Case Narrative.

All quality control criteria applicable to the test methods employed for this project have been satisfactorily met and are in accordance with NELAP except where noted. The following report shall not be reproduced, except in full, without the written approval of Teklab, Inc.

If you have any questions regarding these tests results, please feel free to call.

Sincerely,

1505 E. High StreetJefferson City, MO 65101

(573) 659-9078(314) 770-1142

TEL:FAX:

Travis DollGredell Engineering Resources, Inc.

Michael L. AustinProject Manager(618)344-1004 ex [email protected]

Page 1 of 112

This reporting package includes the following:

Report Contents






Cover Letter 1

Report Contents 2

Definitions 3

Case Narrative 4

Laboratory Results 5

Sample Summary 67

Dates Report 68

Quality Control Results 88

Receiving Check List 112

Chain of Custody Appended

Page 2 of 112

____TeklabHdrP

Definitions






Abbr DefinitionCCV Continuing calibration verification is a check of a standard to determine the state of calibration of an instrument between recalibration.

DF Dilution factor is the dilution performed during analysis only and does not take into account any dilutions made during sample preparation. The reported result is final and includes all dilutions factors.

DNI Did not ignite

DUP Laboratory duplicate is an aliquot of a sample taken from the same container under laboratory conditions for independent processing and analysis independently of the original aliquot.

ICV Initial calibration verification is a check of a standard to determine the state of calibration of an instrument before sample analysis is initiated.

IDPH IL Dept. of Public Health

LCS Laboratory control sample, spiked with verified known amounts of analytes, is analyzed exactly like a sample to establish intra-laboratory or analyst specific precision and bias or to assess the performance of all or a portion of the measurement system. The acceptable recovery range is in the QC Package (provided upon request).

LCSD Laboratory control sample duplicate is a replicate laboratory control sample that is prepared and analyzed in order to determine the precision of the approved test method. The acceptable recovery range is listed in the QC Package (provided upon request).

MB Method blank is a sample of a matrix similar to the batch of associated sample (when available) that is free from the analytes of interest and is processed simultaneously with and under the same conditions as samples through all steps of the analytical procedures, and in which no target analytes or interferences should present at concentrations that impact the analytical results for sample analyses.

MDL Method detection limit means the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero and is determined from analysis of a sample in a given matrix type containing the analyte.

MS Matrix spike is an aliquot of matrix fortified (spiked) with known quantities of specific analytes that is subjected to the entire analytical procedures in order to determine the effect of the matrix on an approved test method’s recovery system. The acceptable recovery range is listed in the QC Package (provided upon request).

MSD Matrix spike duplicate means a replicate matrix spike that is prepared and analyzed in order to determine the precision of the approved test method. The acceptable recovery range is listed in the QC Package (provided upon request).

MW Molecular weight

ND Not Detected at the Reporting Limit

NELAP NELAP Accredited

PQL Practical quantitation limit means the lowest level that can be reliably achieved within specified limits of precision and accuracy during routine laboratory operation conditions. The acceptable recovery range is listed in the QC Package (provided upon request).

RL The reporting limit the lowest level that the data is displayed in the final report. The reporting limit may vary according to customer request or sample dilution. The reporting limit may not be less than the MDL.

RPD Relative percent difference is a calculated difference between two recoveries (ie. MS/MSD). The acceptable recovery limit is listed in the QC Package (provided upon request).

SPK The spike is a known mass of target analyte added to a blank sample or sub-sample; used to determine recovery deficiency or for other quality control purposes.

Surr Surrogates are compounds which are similar to the analytes of interest in chemical composition and behavior in the analytical process, but which are not normally found in environmental samples.

TNTC Too numerous to count ( > 200 CFU )

Qualifiers# - Unknown hydrocarbon B - Analyte detected in associated Method Blank

E - Value above quantitation range H - Holding times exceeded

J - Analyte detected below quantitation limits M - Manual Integration used to determine area response

ND - Not Detected at the Reporting Limit R - RPD outside accepted recovery limits

S - Spike Recovery outside recovery limits X - Value exceeds Maximum Contaminant Level

Page 3 of 112

Case Narrative






Cooler Receipt Temp: 2.4 °C

This report was revised on 05/08/2013 per Travis Doll's request. The reason for the revision is to change the Groundwater Elevation, for sample MW-8, from 446.44 to 452.42. Please replace report dated 05/07/2013 with this report. MLA 04/08/2013

NELAPState Cert # Exp Date LabDept

Locations and Accreditations

___________________________________Collinsville

AddressAddressAddressAddress 5445 Horseshoe Lake Road

Collinsville, IL 62234-7425

PhonePhonePhonePhone (618) 344-1004

FaxFaxFaxFax (618) 344-1005

EmailEmailEmailEmail [email protected]

___________________________________Springfield

AddressAddressAddressAddress 3920 Pintail Dr

Springfield, IL 62711-9415




___________________________________Kansas City

AddressAddressAddressAddress 8421 Nieman Road

Lenexa, KS 66214




Illinois 100226 1/31/2014 CollinsvilleNELAPIEPA

Kansas E-10374 1/31/2014 CollinsvilleNELAPKDHE

Louisiana 166493 6/30/2013 CollinsvilleNELAPLDEQ

Louisiana 166578 6/30/2013 SpringfieldNELAPLDEQ

Texas T104704515-12-1 7/31/2013 CollinsvilleNELAPTCEQ

Arkansas 88-0966 3/14/2014 CollinsvilleADEQ

Illinois 17584 4/30/2013 CollinsvilleIDPH

Kentucky 0073 4/5/2014 CollinsvilleUST

Missouri 00930 4/13/2013 CollinsvilleMDNR

Oklahoma 9978 8/31/2013 CollinsvilleODEQ

Page 4 of 112

Lab Sample ID Client Sample ID Collection DateFractions

TeklabHdrP

Matrix

Sample Summary






13040937-001 MW-01 04/16/2013 13:385Groundwater

13040937-002 MW-02 04/16/2013 14:115Groundwater

13040937-003 MW-03 04/16/2013 14:395Groundwater

13040937-004 MW-04 04/16/2013 15:225Groundwater

13040937-005 MW-05 04/16/2013 15:585Groundwater

13040937-006 MW-06 04/16/2013 16:275Groundwater

13040937-007 MW-07 04/16/2013 17:065Groundwater

13040937-008 MW-08 04/17/2013 7:465Groundwater

13040937-009 MW-09 04/17/2013 8:155Groundwater

13040937-010 MW-10 04/17/2013 8:475Groundwater

13040937-011 MW-11 04/17/2013 9:285Groundwater

13040937-012 MW-12 04/17/2013 10:045Groundwater

13040937-013 MW-13 04/17/2013 10:455Groundwater

13040937-014 MW-14 04/17/2013 11:155Groundwater

13040937-015 MW-15 04/17/2013 11:495Groundwater

13040937-016 MW-16 04/17/2013 15:545Groundwater

13040937-017 MW-17 04/17/2013 15:215Groundwater

13040937-018 MW-18 04/17/2013 14:495Groundwater

13040937-019 MW-19 04/17/2013 14:185Groundwater

13040937-020 MW-20 04/17/2013 13:385Groundwater

13040937-021 MW-21 04/17/2013 12:575Groundwater

13040937-022 MW-22 04/16/2013 8:245Groundwater

13040937-023 MW-23 04/16/2013 9:135Groundwater

13040937-024 MW-24 04/16/2013 9:525Groundwater

13040937-025 MW-25 04/16/2013 10:265Groundwater

13040937-026 MW-26 04/16/2013 11:005Groundwater

13040937-027 MW-27 04/16/2013 12:105Groundwater

13040937-028 MW-28 04/16/2013 13:055Groundwater

13040937-029 TMW-01 04/17/2013 16:275Groundwater

13040937-030 Dup 1 04/16/2013 0:005Groundwater

13040937-031 Dup 2 04/17/2013 0:005Groundwater

13040937-032 Field Blank 04/17/2013 12:575Groundwater

13040937-033 Trip Blank 04/16/2013 9:001Trip Blank

Page 67 of 112

Analysis Date/TimeTest Name Prep Date/Time

____TeklabHdrP

Sample ID Client Sample ID Collection Date Received Date

Dates Report






13040937-001A MW-01 04/16/2013 13:38 04/18/2013 10:00

Field Elevation Measurements 04/16/2013 13:38

Standard Methods 2540 C (Total) 04/19/2013 19:00

SW-846 9036 (Total) 04/19/2013 0:16

SW-846 9040B 04/16/2013 13:38

SW-846 9050A 04/16/2013 13:38

SW-846 9214 (Total) 04/23/2013 11:26

SW-846 9251 (Total) 04/19/2013 0:16

13040937-001B MW-01 04/16/2013 13:38 04/18/2013 10:00

Standard Methods 2340 B, Hardness (Total) 04/19/2013 0:00

SW-846 3005A, 6010B, Metals by ICP (Total) 04/19/2013 13:5004/18/2013 13:53


SW-846 3005A, 7010 Metals by GFAA (Total) 05/01/2013 11:0504/18/2013 15:23




SW-846 7470A (Total) 04/19/2013 11:4604/18/2013 12:48

13040937-001C MW-01 04/16/2013 13:38 04/18/2013 10:00

SW-846 9020B 04/19/2013 9:13

13040937-001D MW-01 04/16/2013 13:38 04/18/2013 10:00

SW-846 9060 04/18/2013 15:00

13040937-001E MW-01 04/16/2013 13:38 04/18/2013 10:00

EPA 600 410.4 04/19/2013 14:20

13040937-002A MW-02 04/16/2013 14:11 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 0:27

SW-846 9040B 04/16/2013 14:11

SW-846 9050A 04/16/2013 14:11

SW-846 9214 (Total) 04/23/2013 11:29

SW-846 9251 (Total) 04/19/2013 0:27

13040937-002B MW-02 04/16/2013 14:11 04/18/2013 10:00






Page 68 of 112


____TeklabHdrP


Dates Report








SW-846 7470A (Total) 04/19/2013 11:5204/18/2013 12:48

13040937-002C MW-02 04/16/2013 14:11 04/18/2013 10:00

SW-846 9020B 04/19/2013 10:13

13040937-002D MW-02 04/16/2013 14:11 04/18/2013 10:00

SW-846 9060 04/18/2013 15:06

13040937-002E MW-02 04/16/2013 14:11 04/18/2013 10:00

EPA 600 410.4 04/19/2013 14:21

13040937-003A MW-03 04/16/2013 14:39 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 14:41

SW-846 9040B 04/16/2013 14:39

SW-846 9050A 04/16/2013 14:39

SW-846 9214 (Total) 04/23/2013 11:31

SW-846 9251 (Total) 04/19/2013 0:38

13040937-003B MW-03 04/16/2013 14:39 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 11:5504/18/2013 12:48

13040937-003C MW-03 04/16/2013 14:39 04/18/2013 10:00

SW-846 9020B 04/19/2013 11:14

13040937-003D MW-03 04/16/2013 14:39 04/18/2013 10:00

SW-846 9060 04/18/2013 15:13

13040937-003E MW-03 04/16/2013 14:39 04/18/2013 10:00

EPA 600 410.4 04/19/2013 14:21

13040937-004A MW-04 04/16/2013 15:22 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 1:13

Page 69 of 112


____TeklabHdrP


Dates Report






SW-846 9040B 04/16/2013 15:22

SW-846 9050A 04/16/2013 15:22

SW-846 9214 (Total) 04/23/2013 11:32

SW-846 9251 (Total) 04/19/2013 1:13

13040937-004B MW-04 04/16/2013 15:22 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 11:5704/18/2013 12:48

13040937-004C MW-04 04/16/2013 15:22 04/18/2013 10:00

SW-846 9020B 04/19/2013 12:16

13040937-004D MW-04 04/16/2013 15:22 04/18/2013 10:00

SW-846 9060 04/18/2013 15:18

13040937-004E MW-04 04/16/2013 15:22 04/18/2013 10:00

EPA 600 410.4 04/19/2013 14:22

13040937-005A MW-05 04/16/2013 15:58 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 1:35

SW-846 9040B 04/16/2013 15:58

SW-846 9050A 04/16/2013 15:58

SW-846 9214 (Total) 04/23/2013 11:37

SW-846 9251 (Total) 04/19/2013 1:35

13040937-005B MW-05 04/16/2013 15:58 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 11:5904/18/2013 12:48

13040937-005C MW-05 04/16/2013 15:58 04/18/2013 10:00

Page 70 of 112


____TeklabHdrP


Dates Report






SW-846 9020B 04/19/2013 13:18

13040937-005D MW-05 04/16/2013 15:58 04/18/2013 10:00

SW-846 9060 04/18/2013 17:01

13040937-005E MW-05 04/16/2013 15:58 04/18/2013 10:00

EPA 600 410.4 04/19/2013 14:22

13040937-006A MW-06 04/16/2013 16:27 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 2:15

SW-846 9040B 04/16/2013 16:27

SW-846 9050A 04/16/2013 16:27

SW-846 9214 (Total) 04/23/2013 11:38

SW-846 9251 (Total) 04/19/2013 2:15

13040937-006B MW-06 04/16/2013 16:27 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:0604/18/2013 12:48

13040937-006C MW-06 04/16/2013 16:27 04/18/2013 10:00

SW-846 9020B 04/19/2013 14:20

13040937-006D MW-06 04/16/2013 16:27 04/18/2013 10:00

SW-846 9060 04/18/2013 17:07

13040937-006E MW-06 04/16/2013 16:27 04/18/2013 10:00

EPA 600 410.4 04/19/2013 14:22

13040937-007A MW-07 04/16/2013 17:06 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 0:49

SW-846 9040B 04/16/2013 17:06

SW-846 9050A 04/16/2013 17:06

SW-846 9214 (Total) 04/23/2013 11:40

SW-846 9251 (Total) 04/19/2013 0:49

Page 71 of 112


____TeklabHdrP


Dates Report






13040937-007B MW-07 04/16/2013 17:06 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:0804/18/2013 12:48

13040937-007C MW-07 04/16/2013 17:06 04/18/2013 10:00

SW-846 9020B 04/19/2013 15:56

13040937-007D MW-07 04/16/2013 17:06 04/18/2013 10:00

SW-846 9060 04/18/2013 17:14

13040937-007E MW-07 04/16/2013 17:06 04/18/2013 10:00

EPA 600 410.4 04/19/2013 14:23

13040937-008A MW-08 04/17/2013 7:46 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 1:45

SW-846 9040B 04/17/2013 7:46

SW-846 9050A 04/17/2013 7:46

SW-846 9214 (Total) 04/24/2013 16:34

SW-846 9251 (Total) 04/19/2013 1:45

13040937-008B MW-08 04/17/2013 7:46 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:1004/18/2013 12:48

13040937-008C MW-08 04/17/2013 7:46 04/18/2013 10:00

SW-846 9020B 04/19/2013 16:24

13040937-008D MW-08 04/17/2013 7:46 04/18/2013 10:00

SW-846 9060 04/18/2013 17:20

Page 72 of 112


____TeklabHdrP


Dates Report






13040937-008E MW-08 04/17/2013 7:46 04/18/2013 10:00

EPA 600 410.4 04/19/2013 14:23

13040937-009A MW-09 04/17/2013 8:15 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 2:56

SW-846 9040B 04/17/2013 8:15

SW-846 9050A 04/17/2013 8:15

SW-846 9214 (Total) 04/23/2013 11:43

SW-846 9251 (Total) 04/19/2013 2:56

13040937-009B MW-09 04/17/2013 8:15 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:1204/18/2013 12:48

13040937-009C MW-09 04/17/2013 8:15 04/18/2013 10:00

SW-846 9020B 04/19/2013 17:23

13040937-009D MW-09 04/17/2013 8:15 04/18/2013 10:00

SW-846 9060 04/18/2013 17:26

13040937-009E MW-09 04/17/2013 8:15 04/18/2013 10:00

EPA 600 410.4 04/19/2013 14:26

13040937-010A MW-10 04/17/2013 8:47 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 14:57

SW-846 9040B 04/17/2013 8:47

SW-846 9050A 04/17/2013 8:47

SW-846 9214 (Total) 04/23/2013 11:44

SW-846 9251 (Total) 04/19/2013 3:06

13040937-010B MW-10 04/17/2013 8:47 04/18/2013 10:00




Page 73 of 112


____TeklabHdrP


Dates Report










SW-846 7470A (Total) 04/19/2013 12:1504/18/2013 12:48

13040937-010C MW-10 04/17/2013 8:47 04/18/2013 10:00

SW-846 9020B 04/19/2013 18:23

13040937-010D MW-10 04/17/2013 8:47 04/18/2013 10:00

SW-846 9060 04/18/2013 17:33

13040937-010E MW-10 04/17/2013 8:47 04/18/2013 10:00

EPA 600 410.4 04/19/2013 14:27

13040937-011A MW-11 04/17/2013 9:28 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 15:54

SW-846 9040B 04/17/2013 9:28

SW-846 9050A 04/17/2013 9:28

SW-846 9214 (Total) 04/23/2013 11:46

SW-846 9251 (Total) 04/19/2013 15:43

13040937-011B MW-11 04/17/2013 9:28 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:1704/18/2013 12:48

13040937-011C MW-11 04/17/2013 9:28 04/18/2013 10:00

SW-846 9020B 04/22/2013 10:13

13040937-011D MW-11 04/17/2013 9:28 04/18/2013 10:00

SW-846 9060 04/18/2013 17:39

13040937-011E MW-11 04/17/2013 9:28 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:21

13040937-012A MW-12 04/17/2013 10:04 04/18/2013 10:00


Page 74 of 112


____TeklabHdrP


Dates Report







SW-846 9036 (Total) 04/19/2013 16:29

SW-846 9040B 04/17/2013 10:04

SW-846 9050A 04/17/2013 10:04

SW-846 9214 (Total) 04/23/2013 11:47

SW-846 9251 (Total) 04/19/2013 16:29

13040937-012B MW-12 04/17/2013 10:04 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:1904/18/2013 12:48

13040937-012C MW-12 04/17/2013 10:04 04/18/2013 10:00

SW-846 9020B 04/22/2013 11:20

13040937-012D MW-12 04/17/2013 10:04 04/18/2013 10:00

SW-846 9060 04/18/2013 17:45

13040937-012E MW-12 04/17/2013 10:04 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:24

13040937-013A MW-13 04/17/2013 10:45 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 17:20

SW-846 9040B 04/17/2013 10:45

SW-846 9050A 04/17/2013 10:45

SW-846 9214 (Total) 04/23/2013 11:50

SW-846 9251 (Total) 04/19/2013 16:50

13040937-013B MW-13 04/17/2013 10:45 04/18/2013 10:00








Page 75 of 112


____TeklabHdrP


Dates Report






SW-846 7470A (Total) 04/19/2013 12:2104/18/2013 12:48

13040937-013C MW-13 04/17/2013 10:45 04/18/2013 10:00

SW-846 9020B 04/23/2013 15:17

13040937-013D MW-13 04/17/2013 10:45 04/18/2013 10:00

SW-846 9060 04/18/2013 18:36

13040937-013E MW-13 04/17/2013 10:45 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:24

13040937-014A MW-14 04/17/2013 11:15 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 16:04

SW-846 9040B 04/17/2013 11:15

SW-846 9050A 04/17/2013 11:15

SW-846 9214 (Total) 04/23/2013 11:55

SW-846 9251 (Total) 04/19/2013 16:04

13040937-014B MW-14 04/17/2013 11:15 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:2404/18/2013 12:48

13040937-014C MW-14 04/17/2013 11:15 04/18/2013 10:00

SW-846 9020B 04/22/2013 13:40

13040937-014D MW-14 04/17/2013 11:15 04/18/2013 10:00

SW-846 9060 04/18/2013 18:43

13040937-014E MW-14 04/17/2013 11:15 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:24

13040937-015A MW-15 04/17/2013 11:49 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 17:01

SW-846 9040B 04/17/2013 11:49

SW-846 9050A 04/17/2013 11:49

Page 76 of 112


____TeklabHdrP


Dates Report






SW-846 9214 (Total) 04/23/2013 11:56

SW-846 9251 (Total) 04/19/2013 17:01

13040937-015B MW-15 04/17/2013 11:49 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:2604/18/2013 12:48

13040937-015C MW-15 04/17/2013 11:49 04/18/2013 10:00

SW-846 9020B 04/23/2013 16:23

13040937-015D MW-15 04/17/2013 11:49 04/18/2013 10:00

SW-846 9060 04/18/2013 18:49

13040937-015E MW-15 04/17/2013 11:49 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:24

13040937-016A MW-16 04/17/2013 15:54 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 17:36

SW-846 9040B 04/17/2013 15:54

SW-846 9050A 04/17/2013 15:54

SW-846 9214 (Total) 04/23/2013 15:42

SW-846 9251 (Total) 04/19/2013 17:36

13040937-016B MW-16 04/17/2013 15:54 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:3304/18/2013 12:48

13040937-016C MW-16 04/17/2013 15:54 04/18/2013 10:00

SW-846 9020B 04/22/2013 19:24

13040937-016D MW-16 04/17/2013 15:54 04/18/2013 10:00

Page 77 of 112


____TeklabHdrP


Dates Report






SW-846 9060 04/18/2013 18:55

13040937-016E MW-16 04/17/2013 15:54 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:25

13040937-017A MW-17 04/17/2013 15:21 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 17:52

SW-846 9040B 04/17/2013 15:21

SW-846 9050A 04/17/2013 15:21

SW-846 9214 (Total) 04/23/2013 15:44

SW-846 9251 (Total) 04/19/2013 17:47

13040937-017B MW-17 04/17/2013 15:21 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:4204/18/2013 13:19

13040937-017C MW-17 04/17/2013 15:21 04/18/2013 10:00

SW-846 9020B 04/22/2013 20:27

13040937-017D MW-17 04/17/2013 15:21 04/18/2013 10:00

SW-846 9060 04/18/2013 19:02

13040937-017E MW-17 04/17/2013 15:21 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:25

13040937-018A MW-18 04/17/2013 14:49 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 17:58

SW-846 9040B 04/17/2013 14:49

SW-846 9050A 04/17/2013 14:49

SW-846 9214 (Total) 04/23/2013 15:46

SW-846 9251 (Total) 04/19/2013 17:58

13040937-018B MW-18 04/17/2013 14:49 04/18/2013 10:00



Page 78 of 112


____TeklabHdrP


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SW-846 7470A (Total) 04/19/2013 12:4804/18/2013 13:19

13040937-018C MW-18 04/17/2013 14:49 04/18/2013 10:00

SW-846 9020B 04/22/2013 21:29

13040937-018D MW-18 04/17/2013 14:49 04/18/2013 10:00

SW-846 9060 04/18/2013 19:08

13040937-018E MW-18 04/17/2013 14:49 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:25

13040937-019A MW-19 04/17/2013 14:18 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 18:27

SW-846 9040B 04/17/2013 14:18

SW-846 9050A 04/17/2013 14:18

SW-846 9214 (Total) 04/23/2013 15:47

SW-846 9251 (Total) 04/19/2013 18:22

13040937-019B MW-19 04/17/2013 14:18 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:5104/18/2013 13:19

13040937-019C MW-19 04/17/2013 14:18 04/18/2013 10:00

SW-846 9020B 04/22/2013 22:37

13040937-019D MW-19 04/17/2013 14:18 04/18/2013 10:00

SW-846 9060 04/18/2013 19:15

13040937-019E MW-19 04/17/2013 14:18 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:26

13040937-020A MW-20 04/17/2013 13:38 04/18/2013 10:00

Page 79 of 112


____TeklabHdrP


Dates Report








SW-846 9036 (Total) 04/19/2013 18:33

SW-846 9040B 04/17/2013 13:38

SW-846 9050A 04/17/2013 13:38

SW-846 9214 (Total) 04/23/2013 15:51

SW-846 9251 (Total) 04/19/2013 18:33

13040937-020B MW-20 04/17/2013 13:38 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 12:5304/18/2013 13:19

13040937-020C MW-20 04/17/2013 13:38 04/18/2013 10:00

SW-846 9020B 04/23/2013 17:28

13040937-020D MW-20 04/17/2013 13:38 04/18/2013 10:00

SW-846 9060 04/18/2013 19:21

13040937-020E MW-20 04/17/2013 13:38 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:26

13040937-021A MW-21 04/17/2013 12:57 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 18:44

SW-846 9040B 04/17/2013 12:57

SW-846 9050A 04/17/2013 12:57

SW-846 9214 (Total) 04/23/2013 15:54

SW-846 9251 (Total) 04/19/2013 18:44

13040937-021B MW-21 04/17/2013 12:57 04/18/2013 10:00







Page 80 of 112


____TeklabHdrP


Dates Report







SW-846 7470A (Total) 04/19/2013 12:5904/18/2013 13:19

13040937-021C MW-21 04/17/2013 12:57 04/18/2013 10:00

SW-846 9020B 04/23/2013 18:31

13040937-021D MW-21 04/17/2013 12:57 04/18/2013 10:00

SW-846 9060 04/18/2013 20:12

13040937-021E MW-21 04/17/2013 12:57 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:27

13040937-022A MW-22 04/16/2013 8:24 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 18:54

SW-846 9040B 04/16/2013 8:24

SW-846 9050A 04/16/2013 8:24

SW-846 9214 (Total) 04/23/2013 15:55

SW-846 9251 (Total) 04/19/2013 18:54

13040937-022B MW-22 04/16/2013 8:24 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 13:0204/18/2013 13:19

13040937-022C MW-22 04/16/2013 8:24 04/18/2013 10:00

SW-846 9020B 04/23/2013 19:33

13040937-022D MW-22 04/16/2013 8:24 04/18/2013 10:00

SW-846 9060 04/18/2013 20:18

13040937-022E MW-22 04/16/2013 8:24 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:27

13040937-023A MW-23 04/16/2013 9:13 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 19:05

SW-846 9040B 04/16/2013 9:13

Page 81 of 112


____TeklabHdrP


Dates Report






SW-846 9050A 04/16/2013 9:13

SW-846 9214 (Total) 04/23/2013 15:57

SW-846 9251 (Total) 04/19/2013 19:05

13040937-023B MW-23 04/16/2013 9:13 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 13:0404/18/2013 13:19

13040937-023C MW-23 04/16/2013 9:13 04/18/2013 10:00

SW-846 9020B 04/23/2013 20:41

13040937-023D MW-23 04/16/2013 9:13 04/18/2013 10:00

SW-846 9060 04/18/2013 20:25

13040937-023E MW-23 04/16/2013 9:13 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:27

13040937-024A MW-24 04/16/2013 9:52 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 19:30

SW-846 9040B 04/16/2013 9:52

SW-846 9050A 04/16/2013 9:52

SW-846 9214 (Total) 04/23/2013 15:59

SW-846 9251 (Total) 04/19/2013 19:30

13040937-024B MW-24 04/16/2013 9:52 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 13:0604/18/2013 13:19

13040937-024C MW-24 04/16/2013 9:52 04/18/2013 10:00

SW-846 9020B 04/24/2013 11:23

Page 82 of 112


____TeklabHdrP


Dates Report






13040937-024D MW-24 04/16/2013 9:52 04/18/2013 10:00

SW-846 9060 04/18/2013 20:31

13040937-024E MW-24 04/16/2013 9:52 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:27

13040937-025A MW-25 04/16/2013 10:26 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 19:40

SW-846 9040B 04/16/2013 10:26

SW-846 9050A 04/16/2013 10:26

SW-846 9214 (Total) 04/23/2013 16:00

SW-846 9251 (Total) 04/19/2013 19:40

13040937-025B MW-25 04/16/2013 10:26 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 13:0804/18/2013 13:19

13040937-025C MW-25 04/16/2013 10:26 04/18/2013 10:00

SW-846 9020B 04/24/2013 12:33

13040937-025D MW-25 04/16/2013 10:26 04/18/2013 10:00

SW-846 9060 04/18/2013 20:37

13040937-025E MW-25 04/16/2013 10:26 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:27

13040937-026A MW-26 04/16/2013 11:00 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 19:51

SW-846 9040B 04/16/2013 11:00

SW-846 9050A 04/16/2013 11:00

SW-846 9214 (Total) 04/23/2013 16:06

SW-846 9251 (Total) 04/19/2013 19:51

13040937-026B MW-26 04/16/2013 11:00 04/18/2013 10:00

Page 83 of 112


____TeklabHdrP


Dates Report













SW-846 7470A (Total) 04/19/2013 13:1104/18/2013 13:19

13040937-026C MW-26 04/16/2013 11:00 04/18/2013 10:00

SW-846 9020B 04/24/2013 13:43

13040937-026D MW-26 04/16/2013 11:00 04/18/2013 10:00

SW-846 9060 04/18/2013 20:43

13040937-026E MW-26 04/16/2013 11:00 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:28

13040937-027A MW-27 04/16/2013 12:10 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 20:02

SW-846 9040B 04/16/2013 12:10

SW-846 9050A 04/16/2013 12:10

SW-846 9214 (Total) 04/23/2013 16:07

SW-846 9251 (Total) 04/19/2013 20:02

13040937-027B MW-27 04/16/2013 12:10 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 13:1304/18/2013 13:19

13040937-027C MW-27 04/16/2013 12:10 04/18/2013 10:00

SW-846 9020B 04/24/2013 14:51

13040937-027D MW-27 04/16/2013 12:10 04/18/2013 10:00

SW-846 9060 04/18/2013 20:50

13040937-027E MW-27 04/16/2013 12:10 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:28

Page 84 of 112


____TeklabHdrP


Dates Report






13040937-028A MW-28 04/16/2013 13:05 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 20:13

SW-846 9040B 04/16/2013 13:05

SW-846 9050A 04/16/2013 13:05

SW-846 9214 (Total) 04/23/2013 16:13

SW-846 9251 (Total) 04/19/2013 20:13

13040937-028B MW-28 04/16/2013 13:05 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 13:1504/18/2013 13:19

13040937-028C MW-28 04/16/2013 13:05 04/18/2013 10:00

SW-846 9020B 04/24/2013 15:59

13040937-028D MW-28 04/16/2013 13:05 04/18/2013 10:00

SW-846 9060 04/18/2013 20:56

13040937-028E MW-28 04/16/2013 13:05 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:28

13040937-029A TMW-01 04/17/2013 16:27 04/18/2013 10:00



SW-846 9036 (Total) 04/19/2013 20:42

SW-846 9040B 04/17/2013 16:27

SW-846 9050A 04/17/2013 16:27

SW-846 9214 (Total) 04/23/2013 16:15

SW-846 9251 (Total) 04/19/2013 20:37

13040937-029B TMW-01 04/17/2013 16:27 04/18/2013 10:00






Page 85 of 112


____TeklabHdrP


Dates Report








SW-846 7470A (Total) 04/19/2013 13:1704/18/2013 13:19

13040937-029C TMW-01 04/17/2013 16:27 04/18/2013 10:00

SW-846 9020B 04/24/2013 17:06

13040937-029D TMW-01 04/17/2013 16:27 04/18/2013 10:00

SW-846 9060 04/18/2013 21:03

13040937-029E TMW-01 04/17/2013 16:27 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:29

13040937-030A Dup 1 04/16/2013 0:00 04/18/2013 10:00


SW-846 9036 (Total) 04/19/2013 20:48

SW-846 9214 (Total) 04/23/2013 16:16

SW-846 9251 (Total) 04/19/2013 20:48

13040937-030B Dup 1 04/16/2013 0:00 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 13:2004/18/2013 13:19

13040937-030C Dup 1 04/16/2013 0:00 04/18/2013 10:00

SW-846 9020B 04/24/2013 18:13

13040937-030D Dup 1 04/16/2013 0:00 04/18/2013 10:00

SW-846 9060 04/18/2013 21:09

13040937-030E Dup 1 04/16/2013 0:00 04/18/2013 10:00

EPA 600 410.4 04/23/2013 7:23

13040937-031A Dup 2 04/17/2013 0:00 04/18/2013 10:00


SW-846 9036 (Total) 04/19/2013 20:59

SW-846 9214 (Total) 04/23/2013 16:17

SW-846 9251 (Total) 04/19/2013 20:59

13040937-031B Dup 2 04/17/2013 0:00 04/18/2013 10:00


Page 86 of 112


____TeklabHdrP


Dates Report












SW-846 7470A (Total) 04/19/2013 13:3104/18/2013 13:19

13040937-031C Dup 2 04/17/2013 0:00 04/18/2013 10:00

SW-846 9020B 04/24/2013 19:21

13040937-031D Dup 2 04/17/2013 0:00 04/18/2013 10:00

SW-846 9060 04/18/2013 21:47

13040937-031E Dup 2 04/17/2013 0:00 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:31

13040937-032A Field Blank 04/17/2013 12:57 04/18/2013 10:00


SW-846 9036 (Total) 04/19/2013 21:10

SW-846 9214 (Total) 04/23/2013 16:20

SW-846 9251 (Total) 04/19/2013 21:10

13040937-032B Field Blank 04/17/2013 12:57 04/18/2013 10:00








SW-846 7470A (Total) 04/19/2013 13:3304/18/2013 13:19

13040937-032C Field Blank 04/17/2013 12:57 04/18/2013 10:00

SW-846 9020B 04/24/2013 20:23

13040937-032D Field Blank 04/17/2013 12:57 04/18/2013 10:00

SW-846 9060 04/18/2013 21:54

13040937-032E Field Blank 04/17/2013 12:57 04/18/2013 10:00

EPA 600 410.4 04/19/2013 23:32

13040937-033A Trip Blank 04/16/2013 9:00 04/18/2013 10:00

SW-846 9020B 04/24/2013 21:25

Page 87 of 112

Quality Control Results






EPA 600 410.4

SampID: MBLK

SampType: MBLK mg/LUnitsR176172Batch

Analyses ResultDate

AnalyzedRL SpikeQual SPK Ref Val %REC Low Limit High Limit

Chemical Oxygen Demand 04/19/201310 < 10

SampID: LCS

SampType: LCS mg/LUnitsR176172Batch

Analyses ResultDate


Chemical Oxygen Demand 04/19/201320 151151 100.30 90 110

SampID: 13040937-001E MS

SampType: MS mg/LUnitsR176172Batch

Analyses ResultDate



SampID: 13040937-001E MSD

SampType: MSD mg/LUnitsR176172Batch RPD Limit 10

Analyses ResultDate

AnalyzedRL SpikeQual SPK Ref Val %REC RPD Ref Val %RPD

Chemical Oxygen Demand 04/19/201320 100100 99.7 4.070 95.69

SampID: 13040937-011EMS


Analyses ResultDate



SampID: 13040937-011EMSD


Analyses ResultDate



SampID: 13040937-031EMS


Analyses ResultDate



SampID: 13040937-031EMSD


Analyses ResultDate



SampID: MBLK


Analyses ResultDate


Chemical Oxygen Demand 04/23/201310 < 10

Page 88 of 112







EPA 600 410.4

SampID: LCS


Analyses ResultDate



SampID: 13040937-030E MS


Analyses ResultDate



SampID: 13040937-030E MSD


Analyses ResultDate



STANDARD METHODS 2540 C (TOTAL)

SampID: MBLK


Analyses ResultDate


Total Dissolved Solids 04/19/201320 < 20Total Dissolved Solids 04/19/201320 < 20Total Dissolved Solids 04/19/201320 < 20Total Dissolved Solids 04/19/201320 < 20

SampID: LCS


Analyses ResultDate


Total Dissolved Solids 04/19/201320 1000928 92.80 90 110

SampID: LCSQC

SampType: LCSQC mg/LUnitsR176235Batch

Analyses ResultDate





SampID: 13040937-005AMS


Analyses ResultDate


Total Dissolved Solids 04/19/201320 5001020 108.0482.0 85 115

SampID: 13040937-005AMSD


Analyses ResultDate


Total Dissolved Solids 04/19/201320 5001020 108.0 0.00482.0 1022

Page 89 of 112







STANDARD METHODS 2540 C (TOTAL)

SampID: 13040937-020AMS


Analyses ResultDate


Total Dissolved Solids 04/19/201320 500872 103.2356.0 85 115



Analyses ResultDate


Total Dissolved Solids 04/19/201320 500862 101.2 1.15356.0 872.0

SampID: 13040937-011A-DUP

SampType: DUP mg/LUnitsR176235Batch RPD Limit 15

Analyses ResultDate


Total Dissolved Solids 04/19/201320 482 4.67460.0

SampID: 13040937-024A-DUP

SampType: DUP mg/LUnitsR176235Batch RPD Limit 15

Analyses ResultDate


Total Dissolved Solids 04/19/201320 426 0.00426.0

SW-846 9036 (TOTAL)

SampID: MBLK


Analyses ResultDate


Sulfate 04/18/201310 < 10

SampID: LCS


Analyses ResultDate


Sulfate 04/18/201310 2020 100.30 90 110

SampID: 13040937-004AMS


Analyses ResultDate


Sulfate 04/19/201310 1035 94.925.27 85 115



Analyses ResultDate


Sulfate 04/19/201310 1034 85.9 2.6225.27 34.76

Page 90 of 112







SW-846 9036 (TOTAL)

SampID: 13040937-005AMS


Analyses ResultDate


Sulfate S 04/19/201310 1024 80.616.25 85 115



Analyses ResultDate


Sulfate S 04/19/201310 1023 71.1 3.9916.25 24.31

SampID: 13040937-006AMS


Analyses ResultDate


Sulfate 04/19/201310 1027 86.318.66 85 115



Analyses ResultDate


Sulfate S 04/19/201310 1026 76.1 3.8118.66 27.29

SampID: MBLK


Analyses ResultDate


Sulfate J 04/19/201310 5

SampID: LCS


Analyses ResultDate


Sulfate 04/19/201310 2020 99.40 90 110

SampID: 13040937-011AMS


Analyses ResultDate


Sulfate S 04/19/201350 50106 84.463.70 85 115



Analyses ResultDate


Sulfate S 04/19/201350 50104 79.9 2.1563.70 105.9

SampID: 13040937-012AMS


Analyses ResultDate


Sulfate E 04/19/201310 1052 96.341.98 85 115

Page 91 of 112







SW-846 9036 (TOTAL)



Analyses ResultDate


Sulfate E 04/19/201310 1053 113.0 3.1841.98 51.61

SampID: 13040937-013AMS


Analyses ResultDate


Sulfate S 04/19/201350 5079 31.363.63 85 115



Analyses ResultDate


Sulfate S 04/19/201350 5082 36.0 2.9363.63 79.27

SampID: MBLK


Analyses ResultDate


Sulfate 04/22/201310 < 10

SampID: LCS


Analyses ResultDate


Sulfate 04/22/201310 2021 105.70 90 110

SW-846 9060

SampID: CCB/MBLK


Analyses ResultDate


Total Organic Carbon (TOC) 04/18/20131.0 < 1.0

SampID: CCV/LCS


Analyses ResultDate


Total Organic Carbon (TOC) 04/18/201310.0 59.762.2 104.30 90 110

SampID: 13040937-004DMS


Analyses ResultDate


Total Organic Carbon (TOC) 04/18/20131.0 5.05.8 85.61.520 85 115

Page 92 of 112







SW-846 9060

SampID: 13040937-004DMSD


Analyses ResultDate


Total Organic Carbon (TOC) 04/18/20131.0 5.05.9 86.8 1.031.520 5.800

SampID: 13040937-012DMS


Analyses ResultDate





Analyses ResultDate



SampID: 13040937-020DMS


Analyses ResultDate





Analyses ResultDate



SampID: 13040937-032DMS


Analyses ResultDate


Total Organic Carbon (TOC) 04/18/20131.0 5.04.8 96.40 85 115



Analyses ResultDate


Total Organic Carbon (TOC) 04/18/20131.0 5.04.8 95.8 0.620 4.820

SW-846 9214 (TOTAL)

SampID: MBLK


Analyses ResultDate


Fluoride 04/23/20130.10 < 0.10

Page 93 of 112







SW-846 9214 (TOTAL)

SampID: LCS


Analyses ResultDate


Fluoride 04/23/20130.10 1.001.05 105.00 90 110

SampID: 13040937-004A MS


Analyses ResultDate


Fluoride 04/23/20130.10 2.002.28 104.80.1840 85 115

SampID: 13040937-004A MSD


Analyses ResultDate


Fluoride 04/23/20130.10 2.002.30 105.8 0.870.1840 2.280

SampID: 13040937-013A MS


Analyses ResultDate


Fluoride 04/23/20130.10 2.002.37 112.60.1190 85 115



Analyses ResultDate


Fluoride 04/23/20130.10 2.002.37 112.6 0.000.1190 2.370

SampID: MBLK


Analyses ResultDate


Fluoride 04/23/20130.10 < 0.10

SampID: LCS


Analyses ResultDate


Fluoride 04/23/20130.10 1.000.99 99.20 90 110

SampID: 13040937-019A MS


Analyses ResultDate


Fluoride 04/23/20130.10 2.001.91 88.20.1450 85 115



Analyses ResultDate


Fluoride 04/23/20130.10 2.001.99 92.2 4.100.1450 1.910

Page 94 of 112







SW-846 9214 (TOTAL)

SampID: 13040937-025A MS


Analyses ResultDate


Fluoride 04/23/20130.10 2.002.44 114.80.1440 85 115



Analyses ResultDate


Fluoride 04/23/20130.10 2.002.41 113.3 1.240.1440 2.440

SampID: 13040937-031A MS


Analyses ResultDate


Fluoride 04/23/20130.10 2.002.34 111.00.1190 85 115



Analyses ResultDate


Fluoride 04/23/20130.10 2.002.39 113.6 2.110.1190 2.340

SampID: MBLK


Analyses ResultDate


Fluoride 04/24/20130.10 < 0.10

SampID: LCS


Analyses ResultDate


Fluoride 04/24/20130.10 1.001.00 100.00 90 110

SampID: LCS-R176357


Analyses ResultDate


Fluoride 04/24/20130.10 1.001.00 100.00 90 110

SampID: 13040937-008A MS


Analyses ResultDate


Fluoride 04/24/20130.10 2.002.12 97.80.1650 85 115



Analyses ResultDate


Fluoride 04/24/20130.10 2.002.15 99.2 1.410.1650 2.120

Page 95 of 112







SW-846 9251 (TOTAL)

SampID: MBLK


Analyses ResultDate


Chloride J 04/18/20135 2

SampID: LCS


Analyses ResultDate


Chloride 04/18/20135 2022 109.10 90 110

SampID: 13040937-004AMS


Analyses ResultDate


Chloride 04/19/20135 2027 105.06.020 85 115



Analyses ResultDate


Chloride 04/19/20135 2027 106.8 1.326.020 27.02

SampID: 13040937-005AMS


Analyses ResultDate


Chloride 04/19/20135 2022 99.41.670 85 115



Analyses ResultDate


Chloride 04/19/20135 2021 99.0 0.371.670 21.54

SampID: 13040937-006AMS


Analyses ResultDate


Chloride 04/19/20135 2022 98.82.530 85 115



Analyses ResultDate


Chloride 04/19/20135 2023 101.3 2.262.530 22.28

SampID: MBLK


Analyses ResultDate


Chloride J 04/19/20135 2

Page 96 of 112







SW-846 9251 (TOTAL)

SampID: LCS


Analyses ResultDate


Chloride 04/19/20135 2022 109.90 90 110

SampID: 13040937-011AMS


Analyses ResultDate


Chloride 04/19/20135 2020 92.61.790 85 115



Analyses ResultDate


Chloride 04/19/20135 2020 91.2 1.391.790 20.31

SampID: 13040937-012AMS


Analyses ResultDate


Chloride 04/19/20135 2021 93.81.870 85 115



Analyses ResultDate


Chloride 04/19/20135 2020 92.9 0.921.870 20.64

SampID: 13040937-013AMS


Analyses ResultDate


Chloride 04/19/20135 2020 94.41.600 85 115



Analyses ResultDate


Chloride 04/19/20135 2021 95.2 0.831.600 20.47

SampID: MBLK


Analyses ResultDate


Chloride J 04/22/20135 4

SampID: LCS


Analyses ResultDate


Chloride 04/22/20135 2021 105.20 90 110

Page 97 of 112







SW-846 3005A, 6010B, METALS BY ICP (TOTAL)

SampID: MBLK-87609

SampType: MBLK µg/LUnits87609Batch

Analyses ResultDate


Aluminum 04/19/201350.0 50.0< 50.0 00 -100 100

Barium 04/19/20135.0 5.0< 5.0 00 -100 100

Beryllium 04/19/20131.0 1.0< 1.0 00 -100 100

Boron 04/19/201320.0 20.0< 20.0 00 -100 100

Cadmium 04/19/20132.0 2.0< 2.0 00 -100 100

Calcium 04/19/20130.050 0.050< 0.050 00 -100 100

Calcium 04/19/20130.0500 0.0500< 0.0500 00 -100 100

Chromium 04/19/201310.0 10.0< 10.0 00 -100 100

Cobalt 04/19/201310.0 10.0< 10.0 00 -100 100

Copper 04/19/201310.0 10.0< 10.0 00 -100 100

Iron 04/19/201320.0 20.0< 20.0 00 -100 100

Magnesium 04/19/20130.010 0.010< 0.010 00 -100 100

Magnesium 04/19/20130.0100 0.0100< 0.0100 00 -100 100

Manganese 04/19/20135.0 5.0< 5.0 00 -100 100

Molybdenum 04/19/201310.0 10.0< 10.0 00 -100 100

Nickel 04/19/201310.0 10.0< 10.0 00 -100 100

Selenium 04/19/201350.0 50.0< 50.0 00 -100 100

Silver 04/19/201310.0 10.0< 10.0 00 -100 100

Sodium 04/19/20130.0500 0.0500< 0.0500 00 -100 100

Sodium 04/19/20130.050 0.050< 0.050 00 -100 100

Zinc 04/19/201310.0 10.0< 10.0 00 -100 100

SampID: LCS-87609

SampType: LCS µg/LUnits87609Batch

Analyses ResultDate


Aluminum 04/19/201350.0 20001940 96.80 85 115

Barium 04/19/20135.0 20001900 95.00 85 115

Beryllium 04/19/20131.0 50.048.3 96.60 85 115

Boron 04/19/201320.0 500479 95.70 85 115

Cadmium 04/19/20132.0 50.047.7 95.40 85 115

Calcium 04/19/20130.0500 1.201.25 104.20 85 115

Calcium 04/19/20130.050 1.201.27 105.90 85 115

Chromium 04/19/201310.0 200191 95.60 85 115

Cobalt 04/19/201310.0 500488 97.70 85 115

Copper 04/19/201310.0 250240 95.90 85 115

Iron 04/19/201320.0 1000949 94.90 85 115

Magnesium 04/19/20130.0100 0.7500.762 101.60 85 115

Magnesium 04/19/20130.010 0.7500.747 99.60 85 115

Manganese 04/19/20135.0 500468 93.50 85 115

Molybdenum 04/19/201310.0 500488 97.50 85 115

Nickel 04/19/201310.0 500480 96.10 85 115

Selenium 04/19/201350.0 20002000 100.20 85 115

Silver 04/19/201310.0 50.046.7 93.40 85 115

Sodium 04/19/20130.050 1.201.18 98.10 85 115

Sodium 04/19/20130.0500 1.201.13 94.20 85 115

Zinc 04/19/201310.0 500462 92.40 85 115

Page 98 of 112








SampID: 13040937-002BMS

SampType: MS µg/LUnits87609Batch

Analyses ResultDate


Aluminum 04/19/201350.0 20002020 100.80 75 125

Barium 04/19/20135.0 20002330 95.7415.6 75 125

Beryllium 04/19/20131.0 50.048.2 96.40 75 125

Boron 04/19/201320.0 500606 97.0120.9 75 125

Cadmium 04/19/20132.0 50.046.4 92.80 75 125

Calcium S 04/19/20130.050 1.20187 191.7185.1 75 125

Chromium 04/19/201310.0 200190 95.20 75 125

Cobalt 04/19/201310.0 500488 97.02.900 75 125

Copper 04/19/201310.0 250246 98.30 75 125

Iron 04/19/201320.0 100029300 94.028350 75 125

Magnesium 04/19/20130.010 0.75051.8 88.051.18 75 125

Manganese 04/19/20135.0 5003410 90.22959 75 125

Molybdenum 04/19/201310.0 500493 98.50 75 125

Nickel 04/19/201310.0 500478 95.60 75 125

Selenium 04/19/201350.0 20002040 101.80 75 125

Silver 04/19/201310.0 50.048.1 96.20 75 125

Sodium 04/19/20130.050 1.2010.1 94.78.984 75 125

Zinc 04/19/201310.0 500450 89.52.500 75 125

SampID: 13040937-002BMSD

SampType: MSD µg/LUnits87609Batch RPD Limit 20

Analyses ResultDate


Aluminum 04/19/201350.0 20002020 101.0 0.200 2016

Barium 04/19/20135.0 20002320 95.4 0.26415.6 2330

Beryllium 04/19/20131.0 50.048.3 96.6 0.210 48.20

Boron 04/19/201320.0 500608 97.3 0.23120.9 606.1

Cadmium 04/19/20132.0 50.046.3 92.6 0.220 46.40

Calcium S 04/19/20130.050 1.20185 -25.0 1.40185.1 187.4

Chromium 04/19/201310.0 200190 94.8 0.420 190.3

Cobalt 04/19/201310.0 500485 96.4 0.602.900 487.7

Copper 04/19/201310.0 250246 98.4 0.080 245.7

Iron S 04/19/201320.0 100028800 50.0 1.5128350 29290

Magnesium S 04/19/20130.010 0.75051.1 -12.0 1.4651.18 51.84

Manganese 04/19/20135.0 5003360 81.2 1.332959 3410

Molybdenum 04/19/201310.0 500495 99.0 0.490 492.7

Nickel 04/19/201310.0 500477 95.3 0.310 478.1

Selenium 04/19/201350.0 20002040 101.8 0.000 2036

Silver 04/19/201310.0 50.048.1 96.2 0.000 48.10

Sodium 04/19/20130.050 1.2010.2 98.8 0.498.984 10.12

Zinc 04/19/201310.0 500449 89.3 0.272.500 450.0

Page 99 of 112








SampID: MBLK-87610


Analyses ResultDate


Aluminum 04/19/201350.0 50.0< 50.0 00 -100 100

Barium 04/19/20135.0 5.0< 5.0 00 -100 100

Beryllium 04/19/20131.0 1.0< 1.0 00 -100 100

Boron 04/19/201320.0 20.0< 20.0 00 -100 100

Cadmium 04/19/20132.0 2.0< 2.0 00 -100 100

Calcium 04/19/20130.0500 0.0500< 0.0500 00 -100 100

Chromium 04/19/201310.0 10.0< 10.0 00 -100 100

Cobalt 04/19/201310.0 10.0< 10.0 00 -100 100

Copper 04/19/201310.0 10.0< 10.0 00 -100 100

Iron 04/19/201320.0 20.0< 20.0 00 -100 100

Magnesium 04/19/20130.0100 0.0100< 0.0100 00 -100 100

Manganese 04/19/20135.0 5.0< 5.0 00 -100 100

Molybdenum 04/19/201310.0 10.0< 10.0 00 -100 100

Nickel 04/19/201310.0 10.0< 10.0 00 -100 100

Selenium 04/19/201350.0 50.0< 50.0 00 -100 100

Silver 04/19/201310.0 10.0< 10.0 00 -100 100

Sodium 04/19/20130.0500 0.0500< 0.0500 00 -100 100

Zinc 04/19/201310.0 10.0< 10.0 00 -100 100

SampID: LCS-87610


Analyses ResultDate


Aluminum 04/19/201350.0 20002010 100.60 85 115

Barium 04/19/20135.0 20001980 99.20 85 115

Beryllium 04/19/20131.0 50.050.2 100.40 85 115

Boron 04/19/201320.0 500501 100.20 85 115

Cadmium 04/19/20132.0 50.049.4 98.80 85 115

Calcium 04/19/20130.0500 1.201.32 110.40 85 115

Chromium 04/19/201310.0 200197 98.60 85 115

Cobalt 04/19/201310.0 500509 101.70 85 115

Copper 04/19/201310.0 250252 100.70 85 115

Iron 04/19/201320.0 1000987 98.70 85 115

Magnesium 04/19/20130.0100 0.7500.777 103.60 85 115

Manganese 04/19/20135.0 500485 97.00 85 115

Molybdenum 04/19/201310.0 500510 101.90 85 115

Nickel 04/19/201310.0 500500 100.10 85 115

Selenium 04/19/201350.0 20002090 104.40 85 115

Silver 04/19/201310.0 50.048.5 97.00 85 115

Sodium 04/19/20130.0500 1.201.22 101.90 85 115

Zinc 04/19/201310.0 500478 95.60 85 115

Page 100 of 112








SampID: 13040937-017BMS


Analyses ResultDate


Aluminum 04/19/201350.0 20002130 100.6119.1 75 125

Barium 04/19/20135.0 20002270 99.6274.8 75 125

Beryllium 04/19/20131.0 50.050.2 100.40 75 125

Boron 04/19/201320.0 500577 102.464.90 75 125

Cadmium 04/19/20132.0 50.048.1 96.20 75 125

Calcium S 04/19/20130.050 1.20162 -283.3165.4 75 125

Chromium 04/19/201310.0 200197 98.60 75 125

Cobalt 04/19/201310.0 500506 100.53.400 75 125

Copper 04/19/201310.0 250259 103.50 75 125

Iron 04/19/201320.0 10002600 98.81615 75 125

Magnesium S 04/19/20130.010 0.75036.6 -10.736.70 75 125

Manganese 04/19/20135.0 5001750 94.81272 75 125

Molybdenum 04/19/201310.0 500512 102.30 75 125

Nickel 04/19/201310.0 500500 99.23.700 75 125

Selenium 04/19/201350.0 20002150 107.70 75 125

Silver 04/19/201310.0 50.050.0 100.00 75 125

Sodium 04/19/20130.050 1.209.66 90.38.577 75 125

Zinc 04/19/201310.0 500468 92.83.500 75 125



Analyses ResultDate


Aluminum 04/19/201350.0 20002100 99.0 1.47119.1 2131

Barium 04/19/20135.0 20002250 99.0 0.58274.8 2267

Beryllium 04/19/20131.0 50.050.0 100.0 0.400 50.20

Boron 04/19/201320.0 500567 100.4 1.6864.90 576.7

Cadmium 04/19/20132.0 50.047.9 95.8 0.420 48.10

Calcium S 04/19/20130.050 1.20165 -41.7 1.77165.4 162.0

Chromium 04/19/201310.0 200197 98.4 0.150 197.1

Cobalt 04/19/201310.0 500502 99.8 0.713.400 506.0

Copper 04/19/201310.0 250254 101.5 1.910 258.7

Iron 04/19/201320.0 10002600 98.5 0.121615 2603

Magnesium S 04/19/20130.010 0.75036.9 22.7 0.6836.70 36.62

Manganese 04/19/20135.0 5001750 95.2 0.111272 1746

Molybdenum 04/19/201310.0 500512 102.3 0.020 511.5

Nickel 04/19/201310.0 500492 97.8 1.413.700 499.5

Selenium 04/19/201350.0 20002100 104.8 2.780 2154

Silver 04/19/201310.0 50.049.1 98.2 1.820 50.00

Sodium 04/19/20130.050 1.209.78 99.8 1.178.577 9.661

Zinc 04/19/201310.0 500466 92.5 0.393.500 467.7

Page 101 of 112








SampID: 13040937-029BMS


Analyses ResultDate


Aluminum 04/19/201350.0 20001950 97.30 75 125

Barium 04/19/20135.0 20002320 98.2355.4 75 125

Beryllium 04/19/20131.0 50.049.2 98.40 75 125

Boron 04/19/201320.0 500599 99.6100.5 75 125

Cadmium 04/19/20132.0 50.046.6 93.20 75 125

Calcium S 04/19/20130.050 1.20163 41.7162.7 75 125

Chromium 04/19/201310.0 200194 96.80 75 125

Cobalt 04/19/201310.0 500494 98.70 75 125

Copper 04/19/201310.0 250253 101.30 75 125

Iron S 04/19/201320.0 100012800 66.012090 75 125

Magnesium S 04/19/20130.010 0.75045.0 -48.045.41 75 125

Manganese 04/19/20135.0 5005070 75.64694 75 125

Molybdenum 04/19/201310.0 500501 100.10 75 125

Nickel 04/19/201310.0 500486 96.63.600 75 125

Selenium 04/19/201350.0 20002070 103.60 75 125

Silver 04/19/201310.0 50.049.1 98.20 75 125

Sodium 04/19/20130.050 1.2012.1 92.511.02 75 125

Zinc 04/19/201310.0 500452 89.45.500 75 125



Analyses ResultDate


Aluminum 04/19/201350.0 20001960 97.8 0.560 1946

Barium 04/19/20135.0 20002330 98.9 0.60355.4 2319

Beryllium 04/19/20131.0 50.049.9 99.8 1.410 49.20

Boron 04/19/201320.0 500602 100.3 0.52100.5 598.7

Cadmium 04/19/20132.0 50.047.5 95.0 1.910 46.60

Calcium S 04/19/20130.050 1.20166 266.7 1.64162.7 163.2

Chromium 04/19/201310.0 200196 98.2 1.440 193.6

Cobalt 04/19/201310.0 500504 100.7 2.010 493.5

Copper 04/19/201310.0 250254 101.6 0.240 253.3

Iron 04/19/201320.0 100013100 97.0 2.4012090 12750

Magnesium S 04/19/20130.010 0.75045.9 60.0 1.7845.41 45.05

Manganese 04/19/20135.0 5005140 89.4 1.354694 5072

Molybdenum 04/19/201310.0 500513 102.6 2.470 500.7

Nickel 04/19/201310.0 500496 98.4 1.873.600 486.4

Selenium 04/19/201350.0 20002090 104.3 0.670 2072

Silver 04/19/201310.0 50.049.3 98.6 0.410 49.10

Sodium 04/19/20130.050 1.2012.2 102.5 0.9811.02 12.13

Zinc 04/19/201310.0 500462 91.3 2.065.500 452.5

Page 102 of 112







SW-846 3005A, 7010 METALS BY GFAA (TOTAL)

SampID: MBLK-87612


Analyses ResultDate


Antimony 05/02/20135.0 5.0< 5.0 00 -100 100

Arsenic 05/03/20133.0 3.0< 3.0 00 -100 100

Arsenic 05/01/20133.0 3.0< 3.0 00 -100 100

Lead 05/01/20132.0 2.0< 2.0 00 -100 100

Thallium 05/03/20132.0 2.0< 2.0 00 -100 100

SampID: LCS-87612


Analyses ResultDate


Antimony 05/03/201310.0 30.027.9 92.90 80 120

Arsenic 05/01/20133.0 15.014.2 94.70 80 120

Arsenic 05/03/20133.0 15.013.2 88.10 80 120

Lead 05/01/20132.0 15.013.8 92.20 80 120

Thallium 05/06/20132.0 15.015.0 100.00 80 120

SampID: 13040937-003BMS


Analyses ResultDate


Antimony S 05/03/20135.0 30.019.2 64.10 70 130

Arsenic 05/03/20133.0 15.013.4 81.51.213 70 130

Lead 05/01/20132.0 15.012.9 85.70 70 130

Thallium 05/03/20132.0 15.015.9 106.00 70 130



Analyses ResultDate


Antimony S 05/03/20135.0 30.019.6 65.4 1.970 19.23

Arsenic 05/03/20133.0 15.012.2 73.5 9.361.213 13.43

Lead 05/01/20132.0 15.012.5 83.6 2.470 12.85

Thallium 05/03/20132.0 15.015.8 105.0 0.950 15.90

SampID: 13040937-005BMS


Analyses ResultDate


Antimony 05/03/20135.0 30.030.3 100.90 70 130

Arsenic 05/03/20133.0 15.012.9 85.80 70 130

Lead 05/02/20132.0 15.013.9 92.70 70 130

Thallium 05/06/20132.0 15.019.1 127.40 70 130

Page 103 of 112










Analyses ResultDate


Antimony 05/03/20135.0 30.027.4 91.4 9.830 30.27

Arsenic 05/03/20133.0 15.013.1 87.3 1.690 12.88

Lead 05/02/20132.0 15.013.7 91.0 1.820 13.91

Thallium 05/06/20132.0 15.019.5 129.9 1.940 19.11

SampID: MBLK-87614


Analyses ResultDate


Antimony 05/03/20135.0 5.0< 5.0 00 -100 100

Arsenic 05/03/20133.0 3.0< 3.0 00 -100 100

Lead 05/02/20132.0 2.0< 2.0 00 -100 100

Thallium 05/06/20132.0 2.0< 2.0 00 -100 100

SampID: LCS-87614


Analyses ResultDate


Antimony 05/03/201310.0 30.025.7 85.70 80 120

Arsenic 05/03/20136.0 15.012.1 80.50 80 120

Lead 05/03/20132.0 15.015.1 100.90 80 120

Thallium 05/06/20132.0 15.014.0 93.50 80 120

SampID: 13040937-021BMS


Analyses ResultDate


Antimony 05/03/20135.0 30.031.5 105.00 70 130

Arsenic 05/03/20133.0 15.013.9 86.11.009 70 130

Lead 05/03/20132.0 15.014.3 95.30 70 130

Thallium 05/06/20132.0 15.017.9 119.00 70 130



Analyses ResultDate


Antimony 05/03/20135.0 30.032.0 106.5 1.420 31.51

Arsenic 05/03/20133.0 15.012.4 75.6 11.951.009 13.93

Lead 05/03/20132.0 15.014.3 95.2 0.170 14.30

Thallium 05/06/20132.0 15.017.9 119.3 0.190 17.86

Page 104 of 112








SampID: 13040937-027BMS


Analyses ResultDate


Antimony 05/03/20135.0 30.024.9 83.10 70 130

Arsenic 05/03/20133.0 15.015.6 81.43.345 70 130

Lead 05/03/20132.0 15.014.9 96.00.5016 70 130

Thallium 05/03/20132.0 15.017.5 116.80 70 130



Analyses ResultDate


Antimony 05/03/20135.0 30.024.2 80.7 2.990 24.94

Arsenic 05/03/20133.0 15.015.4 80.5 0.943.345 15.56

Lead 05/03/20132.0 15.014.5 93.4 2.660.5016 14.90

Thallium 05/03/20132.0 15.017.4 115.9 0.750 17.52

SW-846 7470A (TOTAL)

SampID: MBLK-87601


Analyses ResultDate


Mercury 04/19/20130.20 0.20< 0.20 00 -100 100

SampID: LCS-87601


Analyses ResultDate


Mercury 04/19/20130.20 5.005.10 102.00 85 115

SampID: 13040937-001BMS


Analyses ResultDate


Mercury 04/19/20130.20 5.005.20 104.00 75 125



Analyses ResultDate


Mercury 04/19/20130.20 5.005.22 104.4 0.360 5.200

SampID: MBLK-87606


Analyses ResultDate


Mercury 04/19/20130.20 0.20< 0.20 00 -100 100

Page 105 of 112







SW-846 7470A (TOTAL)

SampID: LCS-87606


Analyses ResultDate


Mercury 04/19/20130.20 5.005.04 100.80 85 115

SampID: 13040937-017BMS


Analyses ResultDate


Mercury 04/19/20130.20 5.005.12 102.40 75 125



Analyses ResultDate


Mercury 04/19/20130.20 5.004.95 99.0 3.420 5.121

SampID: 13040937-030BMS


Analyses ResultDate


Mercury 04/19/20130.20 5.005.00 100.00 75 125



Analyses ResultDate


Mercury 04/19/20130.20 5.005.03 100.6 0.560 5.000

SW-846 9020B

SampID: 130419MBLK

SampType: MBLK µg/LUnitsR176204Batch

Analyses ResultDate


Total Organic Halides (TOX) 04/19/201320.0 < 20.0

SampID: 1304192lcs

SampType: LCS µg/LUnitsR176204Batch

Analyses ResultDate


Total Organic Halides (TOX) 04/19/201320.0 50.039.7 79.40 58 148

SampID: 130419LCS


Analyses ResultDate



Page 106 of 112







SW-846 9020B

SampID: 13040937-007C MS

SampType: MS µg/LUnitsR176204Batch

Analyses ResultDate



SampID: 13040937-001C DUP

SampType: DUP µg/LUnitsR176204Batch RPD Limit 30

Analyses ResultDate


Total Organic Halides (TOX) 04/19/201320.0 < 20.0 0.000



Analyses ResultDate





Analyses ResultDate





Analyses ResultDate





Analyses ResultDate





Analyses ResultDate





Analyses ResultDate





Analyses ResultDate



Page 107 of 112







SW-846 9020B



Analyses ResultDate



SampID: 130422MBLK


Analyses ResultDate



SampID: 130422LCS


Analyses ResultDate



SampID: 304222 lcs


Analyses ResultDate



SampID: 13040937-018cMS


Analyses ResultDate


Total Organic Halides (TOX) 04/22/201320.0 50.074.9 123.213.24 58 148

SampID: 13040937-011cDUP


Analyses ResultDate





Analyses ResultDate


Total Organic Halides (TOX) J 04/22/201320.0 15.2 0.0015.08



Analyses ResultDate





Analyses ResultDate



Page 108 of 112







SW-846 9020B



Analyses ResultDate





Analyses ResultDate



SampID: 130423MBLK


Analyses ResultDate



SampID: 1304232LCS


Analyses ResultDate



SampID: 130423LCS


Analyses ResultDate



SampID: 13040937-022CMS


Analyses ResultDate



SampID: 13040937-013CDUP


Analyses ResultDate


Total Organic Halides (TOX) J 04/23/201320.0 16.3 0.000



Analyses ResultDate





Analyses ResultDate



Page 109 of 112







SW-846 9020B



Analyses ResultDate


Total Organic Halides (TOX) 04/23/201320.0 < 20.0 0.0015.78



Analyses ResultDate



SampID: 130424MBLK


Analyses ResultDate



SampID: 1304242LCS


Analyses ResultDate



SampID: 130424LCS


Analyses ResultDate



SampID: 13040937-030CMS


Analyses ResultDate





Analyses ResultDate





Analyses ResultDate





Analyses ResultDate



Page 110 of 112







SW-846 9020B



Analyses ResultDate





Analyses ResultDate





Analyses ResultDate





Analyses ResultDate





Analyses ResultDate



SampID: 13040937-033ADUP


Analyses ResultDate



Page 111 of 112

Receiving Check List






Received By: TWMCarrier: Ricky Schmidt

Completed by: Reviewed by:

On:

18-Apr-13

On:

18-Apr-13

Shipping container/cooler in good condition? Yes No Not Present

Chain of custody present? Yes No

Chain of custody signed when relinquished and received? Yes No

Chain of custody agrees with sample labels? Yes No

Samples in proper container/bottle? Yes No

Sample containers intact? Yes No

Sufficient sample volume for indicated test? Yes No

All samples received within holding time? Yes No

Container/Temp Blank temperature in compliance? Yes No

Temp °C 2.42.42.42.4

When thermal preservation is required, samples are compliant with a temperature between 0.1°C - 6.0°C, or when samples are received on ice the same day as collected.

Any No responses must be detailed below or on the COC.Any No responses must be detailed below or on the COC.Any No responses must be detailed below or on the COC.Any No responses must be detailed below or on the COC.

Additional nitric acid was needed upon arrival at the laboratory in metals container for TMW-01, Dup 2. TWM 4/17/13

Water – at least one vial per sample has zero headspace? Yes No No VOA vials

Water - pH acceptable upon receipt? Yes No NA

Type of thermal preservation? None Ice Blue Ice Dry Ice

Chain of custody 4 Extra pages included 0

Reported field parameters measured: Field Lab NA

Pages to follow:Pages to follow:Pages to follow:Pages to follow:

Water - TOX containers have zero headspace? No TOX containersYes No

NPDES/CWA TCN interferences checked/treated in the field? Yes No NA

Timothy W. Mathis Michael L. Austin

Page 112 of 112

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