allan joseph medwick, edddescribe the chemical similarities and differences between toothpaste and...

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Chemistry Merit Badge Online Workshop

Merit Badge Counselor Allan Joseph Medwick, EdD [email protected] 267-872-0336 Requirements

1. Do EACH of the following activities: a. Describe three examples of safety equipment used in a chemistry laboratory and

the reason each one is used. Will be discussed online.

b. Describe what a safety data sheet (SDS) is and tell why it is used.

Will be discussed online.

c. Obtain an SDS for both a paint and an insecticide. Compare and discuss the toxicity, disposal, and safe-handling sections for these two common household products.

Will be discussed online. Included in packet.

d. Discuss the safe storage of chemicals. How does the safe storage of chemicals apply to your home, your school, your community, and the environment?


2. Do EACH of the following activities: a. Predict what would happen if you placed an iron nail in a copper sulfate solution.

Then, put an iron nail in a copper sulfate solution. Describe your observations and make a conclusion based on your observations. Compare your prediction and original conclusion with what actually happened. Write the formula for the reaction that you described.


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b. Demonstrate how you would separate sand (or gravel) from water. Describe how you would separate table salt from water, oil from water, and gasoline from motor oil. Name the practical processes that require these kinds of separations and how the processes may differ.


c. Describe the difference between a chemical reaction and a physical change.


3. Construct a Cartesian diver. Make this at home with your parents. Here is a relatively simple example: https://www.youtube.com/watch?v=Ypp4A7q0NV4 Describe its function in terms of how gases in general behave under different pressures and different temperatures. Will be discussed online. Describe how the behavior of gases affects a backpacker at high altitudes and a scuba diver underwater. Will be discussed online.

4. Do EACH of the following activities: a. Cut a round onion into small chunks. Separate the onion chunks into three equal

portions. Leave the first portion raw. Cook the second portion of onion chunks until the pieces are translucent. Cook the third portion until the onions are caramelized, or brown in color. Taste each type of onion. Do this at home with your parents. Describe the taste of raw onion versus partially cooked onion versus caramelized onion. Explain what happens to molecules in the onion during the cooking process. Will be discussed online.

b. Describe the chemical similarities and differences between toothpaste and an

abrasive household cleanser. Explain how the end use or purpose of a product affects its chemical formulation.

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c. In a clear container, mix a half-cup of water with a tablespoon of oil. Explain why the oil and water do not mix. Find a substance that will help the two combine and add it to the mixture. Do this at home with your parents.

Describe what happened and explain how that substance worked to combine the oil and water. Will be discussed online.

5. List the five classical divisions of chemistry. Briefly describe each one and tell how it

applies to your everyday life.


6. Do EACH of the following activities: a. Name two government agencies that are responsible for tracking the use of

chemicals for commercial or industrial use. Pick one agency and briefly describe its responsibilities.

Will be discussed online. Be prepared to share your report with the group at the third meeting.

b. Define pollution. Explain the chemical impacts on the ozone layer and global climate change.


c. Using reasons from chemistry, describe the effect on the environment of ONE of the following:

1. The production of aluminum cans 2. Burning fossil fuels 3. Single-use items, such as water bottles, bags, straws, or paper


d. Briefly describe the purpose of phosphates in fertilizer and in laundry detergent. Explain how the use of phosphates in fertilizers affects the environment. Explain why phosphates have been removed from laundry detergents.

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7. Do ONE of the following activities: a. Visit a laboratory and talk to a chemist. Ask what that chemist does, and what

training and education are needed to work as a chemist.

b. Using resources found at the library and in periodicals, books, and the Internet (with your parent's permission), learn about two different kinds of work done by chemists, chemical engineers, chemical technicians, or industrial chemists. For each of the positions, find out the education and training requirements.


c. Visit an industrial plant that makes chemical products or uses chemical processes

and describe the processes used. What, if any, by-products are produced and how they are handled.

d. Visit a county farm agency or similar governmental agency and learn how chemistry is used to meet the needs of agriculture in your county.

[email protected]

Chemistry Merit Badge WorkshopCreated by: [email protected]

Time

4pm‎ - ‎5pm‎‎ (Eastern Time - New York)

Date

Wed Apr 8, 2020

Where

https://zoom.us/j/298055080

DescriptionAllan Medwick is inviting you to a scheduled Zoom meeting.Join Zoom Meetinghttps://zoom.us/j/298055080Meeting ID: 298 055 080One tap mobile+13126266799,,298055080# US (Chicago)+16465588656,,298055080# US (New York)Dial by your location+1 312 626 6799 US (Chicago)+1 646 558 8656 US (New York)+1 253 215 8782 US+1 301 715 8592 US+1 346 248 7799 US (Houston)+1 669 900 9128 US (San Jose)Meeting ID: 298 055 080

Cerilliant - SCM-039 Page 1 of 9

SAFETY DATA SHEET Version 5.8

Revision Date 03/15/2018 Print Date 10/06/2018

1. PRODUCT AND COMPANY IDENTIFICATION

1.1 Product identifiers Product name : Malathion

Product Number : SCM-039 Brand : Cerilliant Index-No. : 015-041-00-X CAS-No. : 121-75-5

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses : Laboratory chemicals, Synthesis of substances

1.3 Details of the supplier of the safety data sheet

Company : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA

Telephone : +1 800-325-5832 Fax : +1 800-325-5052

1.4 Emergency telephone number

Emergency Phone # : +1-703-527-3887 (CHEMTREC)

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Acute toxicity, Oral (Category 4), H302 Skin sensitisation (Category 1), H317 Carcinogenicity (Category 1B), H350 Acute aquatic toxicity (Category 1), H400 Chronic aquatic toxicity (Category 1), H410

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 GHS Label elements, including precautionary statements

Pictogram

Signal word Danger

Hazard statement(s)

H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H350 May cause cancer. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statement(s) P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and

understood. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.


P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face

protection. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.

Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances Molecular weight : 330.36 g/mol CAS-No. : 121-75-5 EC-No. : 204-497-7 Index-No. : 015-041-00-X

Hazardous components

Component Classification Concentration

Malathion

Acute Tox. 4; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1; H302, H317, H410

90 - 100 %

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

4.1 Description of first aid measures

General advice Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.

If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact Wash off with soap and plenty of water. Consult a physician.

In case of eye contact Flush eyes with water as a precaution.

If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed No data available


5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture No data available

5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary.

5.4 Further information No data available

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

6.4 Reference to other sections For disposal see section 13.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place.

Recommended storage temperature -20 °C Storage class (TRGS 510): 12: Non Combustible Liquids

7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components with workplace control parameters

Component CAS-No. Value Control parameters

Basis

Malathion 121-75-5 TWA 10 mg/m3 USA. NIOSH Recommended Exposure Limits

Remarks Potential for dermal absorption

TWA 15 mg/m3 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants

Skin designation


PEL 10 mg/m3 California permissible exposure limits for chemical contaminants (Title 8, Article 107)

Skin

TWA 1 mg/m3 USA. ACGIH Threshold Limit Values (TLV)

Cholinesterase inhibition Substances for which there is a Biological Exposure Index or Indices (see BEI® section), see BEI® for Acetylcholinesterase Inhibiting Pesticide Not classifiable as a human carcinogen Danger of cutaneous absorption

8.2 Exposure controls

Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment

Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

a) Appearance Form: liquid Colour: colourless

b) Odour No data available

c) Odour Threshold No data available

d) pH No data available

e) Melting point/freezing point

No data available

f) Initial boiling point and boiling range

156 - 157 °C (313 - 315 °F) at 1.00 hPa (0.75 mmHg)

g) Flash point No data available

h) Evaporation rate No data available

i) Flammability (solid, gas) No data available

j) Upper/lower flammability or explosive limits

No data available


k) Vapour pressure No data available

l) Vapour density No data available

m) Relative density 1.230 g/cm3

n) Water solubility slightly soluble

o) Partition coefficient: n-octanol/water

log Pow: 5.0

p) Auto-ignition temperature

No data available

q) Decomposition temperature

No data available

r) Viscosity No data available

s) Explosive properties No data available

t) Oxidizing properties No data available

9.2 Other safety information No data available

10. STABILITY AND REACTIVITY

10.1 Reactivity No data available

10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions No data available

10.4 Conditions to avoid No data available

10.5 Incompatible materials Strong oxidizing agents, Corrodes metal

10.6 Hazardous decomposition products Other decomposition products - No data available Hazardous decomposition products formed under fire conditions. - Carbon oxides, Sulphur oxides, Oxides of phosphorus In the event of fire: see section 5

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity LD50 Oral - Rat - 644 mg/kg Remarks: (RTECS) Inhalation: No data available

LD50 Dermal - Rabbit - 8,790 mg/kg No data available

Skin corrosion/irritation No data available

Serious eye damage/eye irritation Eyes - Rabbit Result: No eye irritation Respiratory or skin sensitisation No data available


Germ cell mutagenicity Human leukocyte Cytogenetic analysis Human lymphocyte Cytogenetic analysis Human lymphocyte DNA inhibition Human fibroblast Other mutation test systems Human leukocyte Sister chromatid exchange Human fibroblast Sister chromatid exchange Hamster ovary Cytogenetic analysis Hamster Lungs Cytogenetic analysis Hamster Lungs Sister chromatid exchange Hamster ovary Sister chromatid exchange Human lymphocyte Unscheduled DNA synthesis Human lymphocyte Micronucleus test Mouse Cytogenetic analysis Mouse Cytogenetic analysis Mouse Cytogenetic analysis Hamster Cytogenetic analysis

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.


NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.

Reproductive toxicity No data available

Reproductive toxicity - Rat - Oral Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of implants).

Reproductive toxicity - Rat - Oral Effects on Newborn: Weaning or lactation index (e.g., # alive at weaning per # alive at day 4). Effects on Newborn: Growth statistics (e.g., reduced weight gain). Effects on Newborn: Other postnatal measures or effects.

Reproductive toxicity - Rat - Unreported Paternal Effects: Spermatogenesis (including genetic material, sperm morphology,motility, and count). Paternal Effects: Testes, epididymis, sperm duct.

No data available

Developmental Toxicity - Rat - Oral Specific Developmental Abnormalities: Urogenital system.

Developmental Toxicity - Rabbit - Oral Effects on Embryo or Fetus: Other effects to embryo.

Specific target organ toxicity - single exposure No data available

Specific target organ toxicity - repeated exposure No data available

Aspiration hazard No data available

Additional Information RTECS: Not available To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

12. ECOLOGICAL INFORMATION

12.1 Toxicity

Toxicity to fish LC50 - Fish - 0.252 mg/l - 96 h

Toxicity to daphnia and other aquatic invertebrates

EC50 - Daphnia magna (Water flea) - 0.002 mg/l - 48 h

Toxicity to algae EC50 - Pseudokirchneriella subcapitata (green algae) - 4.06 mg/l - 72 h

12.2 Persistence and degradability No data available

12.3 Bioaccumulative potential Bioaccumulation Oryzias latipes - 168 h

- 12.8 µg/l Bioconcentration factor (BCF): 12 Remarks: Can accumulate in aquatic organisms.

12.4 Mobility in soil No data available

12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted


12.6 Other adverse effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life with long lasting effects.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging Dispose of as unused product.

14. TRANSPORT INFORMATION

DOT (US) Not dangerous goods IMDG UN number: 3082 Class: 9 Packing group: III EMS-No: F-A, S-F Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Malathion) Marine pollutant:yes IATA UN number: 3082 Class: 9 Packing group: III Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Malathion)

Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

15. REGULATORY INFORMATION

SARA 302 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components The following components are subject to reporting levels established by SARA Title III, Section 313:

Malathion

CAS-No. 121-75-5

Revision Date 2007-07-01

SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard

Massachusetts Right To Know Components Malathion

CAS-No. 121-75-5


Pennsylvania Right To Know Components Malathion

CAS-No. 121-75-5


Malathion

CAS-No. 121-75-5


New Jersey Right To Know Components Malathion

CAS-No. 121-75-5


California Prop. 65 Components WARNING! This product contains a chemical known to the State of California to cause cancer. Malathion

CAS-No. 121-75-5



16. OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.

Acute Tox. Acute toxicity Aquatic Acute Acute aquatic toxicity Aquatic Chronic Chronic aquatic toxicity H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H350 May cause cancer. H400 Very toxic to aquatic life.

HMIS Rating Health hazard: 2 Chronic Health Hazard: Flammability: 0 Physical Hazard 0

NFPA Rating Health hazard: 2 Fire Hazard: 0 Reactivity Hazard: 0

Further information Copyright 2016 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

Preparation Information Sigma-Aldrich Corporation Product Safety – Americas Region 1-800-521-8956 Version: 5.8 Revision Date: 03/15/2018 Print Date: 10/06/2018

Emerald® Interior Latex FlatExtra White

Not available.

Liquid.

US / Canada: (800) 424-9300Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year

SAFETY DATA SHEET

Product name

Other means of identificationProduct type

Emergency telephone number of the company

Section 1. Identification:

:

:

:

Manufacturer : THE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Paint or paint related material.

K35W351

K35W351Product code :

Product Information Telephone Number

: US / Canada: 1-800-474-3794Mexico: Not Available

Regulatory Information Telephone Number

: US / Canada: (216) 566-2902Mexico: Not Available

Transportation Emergency Telephone Number

: US / Canada: (800) 424-9300Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year

Section 2. Hazards identification

CARCINOGENICITY - Category 2Classification of the substance or mixture

:

Signal word : Warning

Hazard pictograms :

Precautionary statements

Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing.

Response : IF exposed or concerned: Get medical attention.

Storage : Store locked up.

GHS label elements

General : Read label before use. Keep out of reach of children. If medical advice is needed,have product container or label at hand.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Suspected of causing cancer.:Hazard statements

Date of issue/Date of revision : 1/15/2020 Date of previous issue : 11/27/2019 Version : 13.01 1/11

K35W351 Emerald® Interior Latex FlatExtra White

SHW-85-NA-GHS-US

Section 2. Hazards identificationDisposal Dispose of contents and container in accordance with all local, regional, national and

international regulations.

Hazards not otherwise classified

: None known.

Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.

Supplemental label elements

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

:

Section 3. Composition/information on ingredients

Titanium Dioxide ≥10 - ≤25 13463-67-7Amorphous Silica ≤5 7631-86-9Heavy Paraffinic Oil ≤1 64742-65-0

Ingredient name CAS number% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Other means of identification

: Not available.

Substance/mixture

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

No known significant effects or critical hazards.:Eye contact

Potential acute health effects



SHW-85-NA-GHS-US

Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

:

:

:

Eye contact : No specific data.

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:metal oxide/oxides

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

:

:

:

None known.

Suitable extinguishing media

:

Unsuitable extinguishing media

:

Special protective actions for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

:

: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".



SHW-85-NA-GHS-US

Section 6. Accidental release measures

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

:

:

Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.Avoid breathing vapor or mist. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

:

Precautions for safe handling

Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2019). TWA: 10 mg/m³ 8 hours.OSHA PEL (United States, 5/2018). TWA: 15 mg/m³ 8 hours. Form: Total dust

Amorphous Silica 7631-86-9 NIOSH REL (United States, 10/2016). TWA: 6 mg/m³ 10 hours.

Heavy Paraffinic Oil 64742-65-0 OSHA PEL (United States, 5/2018). TWA: 5 mg/m³ 8 hours.ACGIH TLV (United States, 3/2019). TWA: 5 mg/m³ 8 hours. Form: Inhalable fraction

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits (OSHA United States)

CAS #



SHW-85-NA-GHS-US

Section 8. Exposure controls/personal protectionNIOSH REL (United States, 10/2016). TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: Mist

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Eye/face protection

:

:

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,5/2019). TWA: 3 mg/m³ 8 hours. Form: Respirable dust TWA: 10 mg/m³ 8 hours. Form: Total dustCA Quebec Provincial (Canada, 1/2014). TWAEV: 10 mg/m³ 8 hours. Form: Total dust.CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m³ 8 hours.CA Ontario Provincial (Canada, 1/2018). TWA: 10 mg/m³ 8 hours.CA Saskatchewan Provincial (Canada,7/2013). STEL: 20 mg/m³ 15 minutes. TWA: 10 mg/m³ 8 hours.

Ingredient name Exposure limits

Occupational exposure limits (Canada)

Environmental exposure controls

:

None.

Exposure limits

Occupational exposure limits (Mexico)

CAS #

CAS #



SHW-85-NA-GHS-US

Section 8. Exposure controls/personal protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Respiratory protection :

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

:

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point/freezing point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

Not available.

1.38

1 [Air = 1]

2.3 kPa (17.5 mm Hg) [at 20°C]

Not available.

Not available.Odor

pH

Not available.Color

Evaporation rate 0.09 (butyl acetate = 1)

Auto-ignition temperature

Flash point

Not available.

Closed cup: >94°C (>201.2°F)

Not available.

8.8

Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)

Not available.Odor threshold

Partition coefficient: n-octanol/water

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point/boiling range : 100°C (212°F)

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Heat of combustion : 0.77 kJ/g

Aerosol product

Molecular weight : Not applicable.

Section 10. Stability and reactivity

Conditions to avoid No specific data.

The product is stable.Chemical stability :

:

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.



SHW-85-NA-GHS-US

Section 10. Stability and reactivity

Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

No specific data.

:

Incompatible materials :

Section 11. Toxicological information

Acute toxicity

Heavy Paraffinic Oil LD50 Dermal Rabbit >5000 mg/kg -LD50 Oral Rat >5000 mg/kg -

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Irritation/Corrosion

Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 ug I

-

Amorphous Silica Eyes - Mild irritant Rabbit - 24 hours 25 mg

-

Product/ingredient name Result Score Exposure Observation

Sensitization

Not available.

Species

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Not available.

Not available.

Aspiration hazard

Name Result

Heavy Paraffinic Oil ASPIRATION HAZARD - Category 1

Information on toxicological effects

Classification

Titanium Dioxide - 2B -Amorphous Silica - 3 -

Product/ingredient name NTPIARCOSHA

Information on the likely routes of exposure

No known significant effects or critical hazards.:Eye contact

: Not available.

Potential acute health effects



SHW-85-NA-GHS-US

Section 11. Toxicological information

Not available.

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

No known significant effects or critical hazards.General :

Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

:

:

:

Eye contact : No specific data.

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Not available.

Acute toxicity estimates

Potential immediate effects

: Not available.

Short term exposure

Potential delayed effects : Not available.

Potential immediate effects

: Not available.

Long term exposure

Potential delayed effects : Not available.

Section 12. Ecological information

Bioaccumulative potential

Not available.

Toxicity

Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Not available.



SHW-85-NA-GHS-US

Section 12. Ecological information

Other adverse effects : No known significant effects or critical hazards.

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Section 14. Transport information

-

-

-

-

-

-

Not regulated. Not regulated.

- -

DOT Classification

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

Special precautions for user

Transport in bulk according to Annex II of MARPOL and the IBC Code

No. No.

Not available.

:

Proper shipping name :

Ship type : Not available.

Not available.

:

TDG Classification

Not regulated.

-

-

-

No.

-

Mexico Classification

Not regulated.

-

-

-

No.

-

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.

IATA

Not regulated.

-

-

-

No.

-



SHW-85-NA-GHS-US

Section 14. Transport informationPollution category : Not available.

Section 15. Regulatory information

SARA 313

TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone

SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

California Prop. 65

Australia inventory (AICS): Not determined.China inventory (IECSC): Not determined.Japan inventory (ENCS): Not determined.Japan inventory (ISHL): Not determined.Korea inventory (KECI): Not determined.New Zealand Inventory of Chemicals (NZIoC): Not determined.Philippines inventory (PICCS): Not determined.Taiwan Chemical Substances Inventory (TCSI): Not determined.Thailand inventory: Not determined.Turkey inventory: Not determined.Vietnam inventory: Not determined.

International regulations

International lists :

Section 16. Other information

1/15/2020

History

Date of printing

Date of issue/Date of revision

Version

Date of previous issue

:

:

:

:

1/15/2020

11/27/2019

13.01

Hazardous Material Information System (U.S.A.)

0

0

0

*Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

CARCINOGENICITY - Category 2 Calculation method

Procedure used to derive the classification

Classification Justification



SHW-85-NA-GHS-US

Section 16. Other information

It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.

Indicates information that has changed from previously issued version.

Key to abbreviations :

Notice to reader

ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)N/A = Not availableSGG = Segregation GroupUN = United Nations



SHW-85-NA-GHS-US

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