afm systems 7 - unipr.it and modes.pdf · 2012. 2. 28. · 16 17 insight 3d afm production-based 3d...

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6 7 AFM Systems Innovation with Integrity AFM Probes

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  • 67

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  • 89

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  • 12

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  • 14

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  • 16

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  • 18

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  • 20

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    SP

    oM

    31

    Sca

    nn

    ing

    Tu

    nn

    elin

    g M

    icro

    sco

    py -

    ST

    M

    32

    Sca

    nn

    ing

    Ele

    ctro

    chem

    ical

    Po

    ten

    tial M

    icro

    sco

    py

    - SE

    CP

    M

    33

    Tors

    ion

    al R

    eso

    nan

    ce

    34

    PeakF

    orc

    e T

    UN

    A &

    Co

    nd

    uct

    ive A

    FM

    35

    Sca

    nn

    ing

    Sp

    read

    ing

    Resi

    stan

    ce M

    icro

    sco

    py -

    SS

    RM

    36

    Sca

    nn

    ing

    Cap

    aci

    tan

    ce M

    icro

    sco

    py -

    SC

    M

    37

    Sca

    nn

    ing

    Th

    erm

    al M

    icro

    sco

    pie

    s

    38

    Pie

    zore

    spo

    nse

    Mic

    rosc

    op

    y

    39

    Cri

    tica

    l Dim

    ensi

    on

    Ato

    mic

    Fo

    rce

    Mic

    rosc

    op

    y - C

    DA

    FM

    40

    Deep

    Tre

    nch

    Mo

    de

    41

    SP

    M O

    pera

    tio

    n Pro

    tein

    mo

    lecu

    les i

    n

    liq

    uid

    be

    fore

    an

    d a

    fte

    r fo

    rce

    pu

    llin

    g

    wit

    h A

    FM

    .

    Scannin

    g P

    robe M

    icro

    scopy (S

    PM

    ) is

    a t

    ech

    niq

    ue t

    o p

    rovid

    e s

    patially

    lo

    caliz

    ed t

    hre

    e-d

    imensio

    nal in

    form

    ation b

    y r

    aste

    r scannin

    g a

    sharp

    pro

    be

    and a

    surf

    ace in c

    lose p

    roxim

    ity r

    ela

    tive t

    o e

    ach

    oth

    er

    and m

    onitoring

    pro

    be-s

    am

    ple

    inte

    ractions. D

    ependin

    g o

    n t

    he inte

    raction, a v

    ariety

    of

    surf

    ace p

    ropert

    ies c

    an b

    e m

    easure

    d in a

    dditio

    n t

    o t

    opogra

    phic

    in

    form

    ation, such

    as e

    lectr

    ical, m

    agnetic, and n

    anom

    ech

    anic

    al data

    .

    The m

    ain

    SP

    M s

    can m

    odes a

    re c

    onta

    ct

    mode, T

    appin

    gM

    ode

    ™, and

    Peak F

    orc

    e T

    appin

    g® m

    ode, and t

    hese b

    uild

    the f

    oundation o

    f all

    advanced s

    cannin

    g t

    ech

    niq

    ues.

    Z X Y

    Fe

    ed

    ba

    ck

    Lo

    op

    Ou

    tpu

    t S

    ign

    al

    Ad

    jus

    ts Z

    Po

    sit

    ion

    Ra

    ste

    r S

    ca

    n

    Pro

    be

    Sa

    mp

    le

    Detec

    tor

    Signa

    l

    Pro

    bes:

    – T

    ES

    P p

    g 6

    4– M

    PP

    -11100-1

    0 (R

    TE

    SP

    )

    p

    g 6

    8

    – E

    SP

    pg

    52

    – S

    NL-1

    0 p

    g 1

    08

    – D

    NP

    -10 p

    g 8

    4– M

    LC

    T p

    g 8

    0– M

    SN

    L-1

    0 p

    g 1

    06

  • 22

    23

    Co

    nta

    ct

    Mo

    de

    AFM

    Conta

    ct

    mode is a

    prim

    ary

    AFM

    mode. T

    he p

    robe is a

    mic

    rofa

    bricate

    d

    cantile

    ver

    with a

    sharp

    tip

    . Tip

    and s

    am

    ple

    are

    in p

    erp

    etu

    al conta

    ct

    during

    the r

    aste

    r-scan. D

    ete

    cto

    r sig

    nal is

    a m

    easure

    of

    cantile

    ver

    deflection in

    Z. In

    feedback

    mode, outp

    ut

    sig

    nal usually

    adju

    sts

    the Z

    positio

    n o

    f th

    e

    scanner

    to m

    ain

    tain

    a d

    eflection s

    etp

    oin

    t. T

    his

    mode e

    nable

    s n

    um

    ero

    us

    secondary

    modes, in

    clu

    din

    g L

    FM

    , Forc

    e M

    odula

    tion, S

    CM

    , S

    SR

    M,

    TU

    NA

    , and C

    AFM

    .

    Nati

    ve C

    ollag

    en

    fib

    rils

    exh

    ibit

    ing

    th

    ety

    pic

    al 67n

    mb

    an

    din

    g p

    att

    ern

    .

    Raste

    r S

    can

    Z X Y

    Feed

    back L

    oo

    p M

    ain

    tain

    s C

    on

    sta

    nt

    Can

    tile

    ver

    Defl

    ecti

    on

    Feed

    back

    Lo

    op

    Ou

    tpu

    tS

    ign

    al

    Ad

    justs

    Z P

    osit

    ion

    Pro

    bes:

    – E

    SP

    pg

    52

    – M

    PP

    -31100-1

    0 p

    g 5

    6

    – S

    NL-1

    0 p

    g 1

    08

    – D

    NP

    -10 p

    g 8

    4

    – M

    LC

    T p

    g 8

    0

    – M

    SN

    L-1

    0 p

    g 1

    06

    Tap

    pin

    gM

    od

    e

    AFM

    To

    po

    gra

    ph

    y o

    f a

    nti

    mo

    ny

    d

    en

    dri

    tes o

    n g

    rap

    hit

    e.

    Tappin

    gM

    ode

    ™ is a

    prim

    ary

    AFM

    mode. T

    he p

    robe is a

    mic

    rofa

    bricate

    d

    cantile

    ver

    with a

    sharp

    tip

    . A

    drive s

    ignal, a

    pplie

    d t

    o t

    he “

    tappin

    g p

    iezo

    ,”

    mech

    anic

    ally

    oscill

    ate

    s t

    he p

    robe a

    t or

    near

    its r

    esonance f

    requency

    (usually

    the f

    undam

    enta

    l re

    sonance). D

    ete

    cto

    r sig

    nal is

    cantile

    ver

    oscill

    ation

    am

    plit

    ude, or

    phase (re

    lative t

    o d

    rive s

    ignal). In

    feedback

    mode, outp

    ut

    sig

    nal

    usually

    adju

    sts

    the Z

    positio

    n o

    f th

    e s

    canner

    to m

    ain

    tain

    an (rm

    s) am

    plit

    ude

    setp

    oin

    t. T

    appin

    gM

    ode e

    nable

    s n

    um

    ero

    us s

    econdary

    modes, in

    clu

    din

    g

    PhaseIm

    agin

    g™

    , E

    FM

    , M

    FM

    , and S

    urf

    ace P

    ote

    ntial im

    agin

    g.

    Z X Y

    Detec

    tor

    Signa

    l

    Drive

    Signal

    Feed

    back L

    oo

    pO

    utp

    ut

    Sig

    nal

    Ad

    justs

    Z P

    osit

    ion

    Feed

    back L

    oo

    p M

    ain

    tain

    sC

    on

    sta

    nt

    Can

    tile

    ver

    Am

    plitu

    de

    Raste

    r S

    can

    Pro

    bes F

    LU

    ID:

    – S

    NL-1

    0 p

    g 1

    08

    – D

    NP

    -10 p

    g 8

    4

    – M

    LC

    T p

    g 8

    0

    – M

    SN

    L-1

    0 p

    g 1

    06

    Pro

    bes A

    IR:

    – M

    PP

    -11100-1

    0 (

    RT

    ES

    P)

    pg

    68

    – T

    ES

    P p

    g 6

    4

    – O

    TE

    SP

    A p

    g 7

    0

    – F

    ES

    P p

    g 5

    8

  • 24

    25

    Pe

    ak F

    orc

    e T

    ap

    pin

    g

    Peak F

    orc

    e T

    appin

    g® is

    Bru

    ker’s e

    xclu

    siv

    e c

    ore

    tech

    nolo

    gy that enable

    s

    many o

    f our m

    ost re

    cent A

    FM

    innova

    tions, in

    clu

    din

    g S

    canA

    sys

    t®,

    PeakForc

    e Q

    NM

    ®, PeakForc

    e T

    UN

    A™ a

    nd S

    canA

    sys

    t-H

    R. Lik

    e

    Tappin

    gM

    ode

    ™, Peak F

    orc

    e T

    appin

    g is

    an A

    C im

    agin

    g tech

    niq

    ue, i.e

    ., the

    cantile

    ver is

    oscill

    ate

    d, and there

    fore

    very

    gentle o

    n e

    ven d

    elic

    ate

    sam

    ple

    s.

    What m

    ake

    s P

    eak F

    orc

    e T

    appin

    g tech

    nolo

    gy u

    niq

    ue is

    that th

    e p

    robe is

    oscill

    ate

    d w

    ell

    belo

    w it

    s resonance fre

    quency.

    By d

    oin

    g s

    o, eve

    ry in

    tera

    ction

    betw

    een the tip

    and s

    am

    ple

    can b

    e m

    easure

    d, genera

    ting a

    continuous

    series o

    f fo

    rce-d

    ista

    nce c

    urv

    es. R

    ath

    er th

    an the feedback

    loop c

    ontr

    olli

    ng

    the c

    antile

    ver am

    plit

    ude (i.e

    ., li

    ke T

    appin

    gM

    ode), it

    is the p

    eak forc

    e o

    f each

    tip

    -sam

    ple

    inte

    raction that is

    held

    consta

    nt. T

    his

    allo

    ws P

    eak F

    orc

    e

    Tappin

    g to o

    pera

    te a

    t m

    uch

    low

    er fo

    rces a

    nd m

    ake

    s it

    s o

    pera

    tion in

    here

    ntly

    more

    sta

    ble

    in b

    oth

    air a

    nd li

    quid

    . It a

    lso m

    ake

    s it

    possib

    le to m

    easure

    nanom

    ech

    anic

    al a

    nd n

    anoele

    ctr

    ical p

    ropert

    ies d

    uring e

    ach

    inte

    raction.

    A

    Time

    E

    B

    C

    Dapproach

    withdraw

    AB

    CE

    D

    Pro

    bes:

    – S

    can

    Asyst-

    Air

    pg

    88

    – S

    can

    Asyst-

    Flu

    id p

    g 8

    8

    – S

    can

    Asyst-

    Flu

    id+

    pg

    88

    Scan

    Asyst

    Po

    lym

    er

    bru

    sh

    sa

    mp

    le

    ima

    ge

    d o

    n a

    Mu

    ltiM

    od

    e® 8

    u

    sin

    g S

    ca

    nA

    sy

    st.

    S

    am

    ple

    co

    urt

    esy

    o

    f S

    . S

    he

    iko

    ,

    Un

    ive

    rsit

    y o

    f

    No

    rth

    Ca

    roli

    na

    ,

    Ch

    ap

    el

    Hil

    l.

    ScanA

    sys

    t® is

    an e

    xclu

    siv

    e im

    agin

    g m

    ode b

    ased o

    n P

    eak F

    orc

    e T

    appin

    tech

    nolo

    gy t

    hat

    auto

    matically

    optim

    izes im

    agin

    g p

    ara

    mete

    rs in

    clu

    din

    g

    setp

    oin

    t, feedback

    gain

    s, and s

    can r

    ate

    . This

    make

    s it

    faste

    r and e

    asie

    r to

    obta

    in c

    onsis

    tent

    hig

    h-q

    ualit

    y r

    esults. B

    ecause t

    he t

    ip-s

    am

    ple

    inte

    raction forc

    e

    is d

    irectly c

    ontr

    olle

    d, S

    canA

    sys

    t is

    very

    gentle o

    n s

    am

    ple

    s in

    both

    air a

    nd

    liquid

    . Faste

    r im

    agin

    g is

    now

    possib

    le u

    sin

    g S

    canA

    sys

    t w

    ith t

    he D

    imensio

    n

    FastS

    can

    ™ A

    FM

    or

    usin

    g S

    canA

    sys

    t-H

    R o

    n t

    he M

    ultiM

    ode

    ® 8

    AFM

    .

    A

    Tim

    e

    PeakF

    orc

    e T

    ap

    pin

    g

    Au

    toO

    pti

    miz

    ati

    on

    of:

    Set

    Po

    int

    Gain

    Scan

    Rate

    Z -

    Lim

    it

    E

    B+

    =

    C

    Dap

    pro

    ach

    wit

    hd

    raw

    Pro

    bes:

    – S

    can

    Asyst-

    Air

    pg

    88

    – S

    can

    Asyst-

    Flu

    id p

    g 8

    8

    – S

    can

    Asyst-

    Flu

    id+

    pg

    88

    – S

    can

    Asyst-

    Air

    -HR

    pg

    88

  • 26

    27

    Tap

    pin

    gM

    od

    e

    & P

    haseIm

    ag

    ing

    Tap

    pin

    gM

    od

    e p

    hase i

    mag

    e

    cle

    arl

    y s

    ho

    ws m

    icro

    ph

    ase

    sep

    ara

    tio

    n i

    n S

    BS

    tr

    i-b

    lock

    co

    po

    lym

    er.

    Tappin

    gM

    ode

    ™ A

    FM

    is a

    n A

    C t

    ech

    niq

    ue in w

    hic

    h t

    he c

    antile

    ver

    is

    opera

    ted a

    t or

    near

    its r

    esonance f

    requency.

    Forc

    es b

    etw

    een t

    ip a

    nd

    sam

    ple

    cause a

    change o

    f th

    e initia

    l re

    sonance b

    ehavio

    r. T

    ypic

    ally

    a

    reduction in t

    he f

    ree a

    ir a

    mplit

    ude is m

    ain

    tain

    ed t

    o t

    rack

    the s

    am

    ple

    to

    pogra

    phy.

    By s

    imultaneously

    monitoring t

    he p

    hase s

    hift

    betw

    een d

    rive

    sig

    nal to

    the c

    antile

    ver

    and its

    response, a s

    o-c

    alle

    d p

    hase im

    age c

    an b

    e

    genera

    ted t

    hat

    pro

    vid

    es v

    ery

    hig

    h s

    patial in

    form

    ation b

    ased o

    n v

    arious

    mate

    rial pro

    pert

    ies.

    2

    1

    Drive

    Signal

    Detector

    Signal

    Drive

    Signal

    Detector

    Signal

    PeakFo

    rce Q

    NM

    Mo

    du

    lus i

    ma

    ge

    of

    a m

    ult

    i-co

    mp

    on

    en

    t p

    oly

    me

    r b

    len

    d. T

    hre

    e

    co

    mp

    on

    en

    ts a

    re

    cle

    arl

    y i

    de

    nti

    fie

    d

    by

    th

    eir

    mo

    du

    lus.

    Tip

    -sa

    mp

    le S

    ep

    ara

    tio

    n

    DM

    T f

    it f

    or

    mo

    du

    lus

    De

    form

    ati

    on

    Dis

    sip

    ati

    on

    AdhesionPeak Force

    Att

    rac

    tiv

    eF

    orc

    es

    Pe

    ak

    Fo

    rce

    &D

    efo

    rma

    tio

    n

    Mo

    du

    lus

    Ad

    he

    sio

    nB

    as

    eli

    ne

    Ba

    se

    lin

    e

    Dis

    sip

    ati

    on

    Pro

    bes:

    – M

    PP

    -11120-1

    0 (

    RT

    ES

    PA

    ) p

    g 6

    8

    – M

    PP

    -12120-1

    0 p

    g 6

    8

    – M

    PP

    -13120-1

    0 p

    g 6

    8

    – P

    DN

    ISP

    -HS

    pg

    124

    – S

    can

    Asyst-

    Air

    pg

    88

    Pro

    bes:

    – M

    PP

    -11100-1

    0 (

    RT

    ES

    P)

    pg

    68

    – T

    ES

    P p

    g 6

    4

    – O

    TE

    SP

    A p

    g 7

    0

    – F

    ES

    P p

    g 5

    8

    PeakForc

    e Q

    NM

    ® is a

    noth

    er

    exclu

    siv

    e im

    agin

    g m

    ode b

    ased o

    n P

    eak F

    orc

    e

    Tappin

    g® t

    ech

    nolo

    gy.

    Here

    each

    tip

    -sam

    ple

    inte

    raction is a

    naly

    zed t

    o e

    xtr

    act

    quantita

    tive n

    anom

    ech

    anic

    al pro

    pert

    ies inclu

    din

    g e

    lastic m

    odulu

    s, adhesio

    n,

    defo

    rmation, and d

    issip

    ation. T

    his

    allo

    ws e

    ach

    of

    these p

    ropert

    ies t

    o b

    e

    mapped q

    uantita

    tively

    and a

    t hig

    h r

    esolu

    tion w

    hile

    still

    colle

    cting s

    tandard

    to

    pogra

    phy im

    ages a

    t norm

    al im

    agin

    g r

    ate

    s. U

    nlik

    e s

    om

    e c

    om

    peting

    tech

    nolo

    gie

    s b

    ased o

    n o

    ld c

    onta

    ct

    mode t

    ech

    nolo

    gy,

    PeakForc

    e Q

    NM

    work

    s

    well

    on a

    wid

    e r

    ange o

    f sam

    ple

    types f

    rom

    soft

    delic

    ate

    mate

    rials

    with

    modulu

    s <

    1M

    Pa a

    ll th

    e w

    ay u

    p t

    o m

    ate

    rials

    with m

    odulu

    s >

    50G

    Pa.

  • 28

    29

    Lif

    tMo

    de

    LiftM

    ode

    ™ is n

    ot

    an im

    agin

    g m

    ode, as it

    by its

    elf d

    oes n

    ot

    measure

    a

    new

    quantity

    to r

    eveal new

    info

    rmation, but

    rath

    er

    a t

    ech

    niq

    ue

    that

    enable

    s o

    ther

    modes s

    uch

    as M

    FM

    , E

    FM

    , and S

    CM

    . In

    LiftM

    ode

    the s

    am

    ple

    is s

    canned fi

    rst

    in a

    regula

    r to

    pogra

    phic

    mode:

    Conta

    ct,

    Tappin

    gM

    ode

    ™ o

    r Peak F

    orc

    e T

    appin

    g®. T

    he f

    ollo

    win

    g lin

    e,

    the “

    lift

    line,”

    tra

    ces t

    he p

    revio

    usly

    acquired t

    opogra

    phy b

    ack

    and a

    dds

    a Z

    -off

    set.

    As t

    he feedback

    laser

    is n

    ot

    necessarily

    needed d

    uring t

    he

    lift

    line, experim

    ents

    that

    would

    be influenced b

    y laser

    light

    can b

    e

    enable

    d (D

    ark

    Lift)

    .

    MFM

    an

    d E

    FM

    sam

    ple

    s.

    Lif

    t H

    eig

    ht

    Lif

    tMo

    de

    Sc

    an

    Ta

    pp

    ing

    Mo

    de

    He

    igh

    t D

    ata

    Pro

    bes:

    – M

    ES

    P p

    g 9

    8

    – S

    CM

    -PIT

    pg

    112

    – S

    CM

    -PIC

    pg

    112

    Mag

    neti

    c F

    orc

    e

    Mic

    rosco

    py -

    MFM

    Magnetic F

    orc

    e M

    icro

    scopy (M

    FM

    ) uses a

    com

    bin

    ation o

    f Ta

    ppin

    gM

    ode

    ™,

    LiftM

    ode

    ™ a

    nd a

    pro

    perly p

    repare

    d t

    ip t

    o g

    ath

    er

    info

    rmation a

    bout

    the m

    agnetic fi

    eld

    above a

    sam

    ple

    . E

    ach

    lin

    e o

    f th

    e s

    am

    ple

    is fi

    rst

    scanned in T

    appin

    gM

    ode o

    pera

    tion t

    o o

    bta

    in t

    he s

    am

    ple

    topogra

    phy.

    The t

    opogra

    phic

    info

    rmation is s

    tore

    d a

    nd r

    etr

    aced w

    ith a

    user-

    sele

    cta

    ble

    heig

    ht

    off

    set

    in L

    iftM

    ode, during w

    hic

    h t

    he m

    agnetic d

    ata

    are

    colle

    cte

    d. T

    ypic

    al lif

    t heig

    hts

    in M

    FM

    range f

    rom

    20-1

    00 n

    m.

    Ma

    gn

    eti

    c d

    om

    ain

    s

    in a

    ste

    el

    sa

    mp

    le.

    Lif

    tMo

    de

    Scan

    Heig

    ht

    Data

    = P

    hase S

    hif

    t

    Lif

    t H

    eig

    ht

    Mag

    neti

    c

    Pro

    be

    Mag

    neti

    c F

    orc

    es

    Cau

    se P

    hase S

    hif

    t

    over

    Dif

    fere

    nt

    Do

    main

    s d

    uri

    ng

    the L

    iftM

    od

    e S

    can

    Pro

    bes:

    – M

    ES

    P p

    g 9

    8

    – M

    ES

    P-H

    M p

    g 9

    8

    – M

    ES

    P-L

    M p

    g 9

    8

    – M

    ES

    P-R

    C p

    g 1

    00

  • 30

    31

    Ele

    ctr

    osta

    tic F

    orc

    e

    Mic

    rosco

    py -

    EFM

    Carb

    on

    bla

    ck a

    gg

    reg

    ate

    s

    in a

    ru

    bb

    er

    matr

    ix

    vis

    ualize

    d b

    y u

    tili

    zin

    g

    their

    ele

    ctr

    ic p

    rop

    ert

    ies.

    Ele

    ctr

    osta

    tic F

    orc

    e M

    icro

    scopy (E

    FM

    ) uses a

    com

    bin

    ation o

    f

    Tappin

    gM

    ode

    ™, LiftM

    ode

    ™ a

    nd a

    conductive t

    ip t

    o g

    ath

    er

    info

    rmation

    about

    the e

    lectr

    ic fi

    eld

    above a

    sam

    ple

    . E

    ach

    lin

    e o

    f th

    e s

    am

    ple

    is fi

    rst

    scanned in T

    appin

    gM

    ode o

    pera

    tion t

    o o

    bta

    in t

    he s

    am

    ple

    topogra

    phy.

    The t

    opogra

    phic

    info

    rmation is s

    tore

    d a

    nd r

    etr

    aced w

    ith a

    user-

    sele

    cta

    ble

    heig

    ht

    off

    set

    in L

    iftM

    ode, during w

    hic

    h t

    he e

    lectr

    ical data

    is

    colle

    cte

    d. T

    ypic

    al lif

    t heig

    hts

    in E

    FM

    range f

    rom

    20-8

    0 n

    m.

    Lif

    tMo

    de

    Sc

    an

    He

    igh

    t D

    ata

    =

    P

    ha

    se

    Sh

    ift

    Lif

    t H

    eig

    ht

    Co

    nd

    uc

    tiv

    e

    Pro

    be

    Ele

    ctr

    ic F

    orc

    es

    Ca

    us

    e P

    ha

    se

    Sh

    ift

    ov

    er

    Dif

    fere

    nt

    Do

    ma

    ins

    du

    rin

    g

    the

    Lif

    tMo

    de

    Sc

    an

    Sin

    gle

    Pa

    ss

    (D

    ua

    l F

    req

    ue

    nc

    y)

    is a

    lso

    av

    ail

    ab

    le

    Pro

    bes:

    – S

    CM

    -PIT

    pg

    112

    – M

    ES

    P p

    g 9

    8

    – M

    ES

    P-R

    C p

    g 1

    00

    – O

    SC

    M-P

    T p

    g 1

    12

    Su

    rface P

    ote

    nti

    al

    Mic

    rosco

    py -

    SP

    oM

    Surf

    ace P

    ote

    ntial M

    icro

    scopy (S

    PoM

    ) is

    based o

    n t

    he m

    acro

    scopic

    K

    elv

    in m

    eth

    od. S

    PoM

    is a

    ble

    to m

    easure

    surf

    ace t

    opogra

    phy a

    nd s

    urf

    ace

    pote

    ntial (V

    DC) in

    form

    ation s

    imultaneously

    . Topogra

    phy is a

    cquired u

    sin

    g

    Tappin

    gM

    ode

    ™ o

    pera

    tion b

    ut

    with a

    conductive t

    ip. T

    he e

    lectr

    ical in

    form

    ation

    is e

    xtr

    acte

    d b

    y a

    pply

    ing A

    C a

    nd D

    C v

    oltages t

    o t

    he t

    ip. T

    he t

    ota

    l voltage

    acting o

    n t

    he t

    ip is: V

    = V

    DC +

    VA

    C s

    in (

    t). A

    dedic

    ate

    d feedback

    loop

    adju

    sts

    the D

    C v

    oltage t

    o t

    he t

    ip t

    o z

    ero

    the c

    onta

    ct

    pote

    ntial diffe

    rence

    betw

    een t

    he t

    ip a

    nd s

    urf

    ace a

    t each

    pix

    el, m

    akin

    g D

    C a

    measure

    of

    the

    surf

    ace p

    ote

    ntial. S

    PoM

    can b

    e c

    arr

    ied o

    ut

    usin

    g L

    iftM

    ode

    ™ o

    r in

    a d

    ual-

    frequency o

    ne-p

    ass f

    ashio

    n.

    Co

    mp

    osit

    e i

    ma

    ge

    of

    He

    igh

    t a

    nd

    Su

    rfa

    ce

    po

    ten

    tia

    l

    of

    a l

    ase

    r d

    iod

    e

    (8 μ

    m s

    ca

    n).

    Lif

    tMo

    de

    Scan

    Heig

    ht

    Data

    Lif

    t H

    eig

    ht

    2V

    Po

    ten

    tial D

    ata

    0V

    -1V

    Co

    nd

    ucti

    ve

    Pro

    be

    Sin

    gle

    Pass (

    Du

    al F

    req

    uen

    cy)

    Cap

    acit

    y is a

    lso

    availab

    le

    Pro

    bes:

    – S

    CM

    -PIT

    pg

    112

    – M

    ES

    P p

    g 9

    8

    – M

    ES

    P-R

    C p

    g 1

    00

    – O

    SC

    M-P

    T p

    g 1

    12

  • 32

    33

    Scan

    nin

    g T

    un

    nelin

    g

    Mic

    rosco

    py -

    ST

    M

    STM

    is a

    prim

    ary

    AFM

    mode. T

    he p

    robe is a

    meta

    l needle

    . D

    ete

    cto

    r sig

    nal is

    the t

    unnelin

    g c

    urr

    ent

    betw

    een t

    he t

    ip a

    nd s

    am

    ple

    when a

    n

    ele

    ctr

    ical bia

    s, V

    , is

    applie

    d. In

    feedback

    mode, outp

    ut

    sig

    nal usually

    adju

    sts

    the Z

    positio

    n o

    f th

    e s

    canner

    to m

    ain

    tain

    a t

    unnelin

    g c

    urr

    ent

    setp

    oin

    t. S

    TM

    is t

    he h

    ighest

    resolu

    tion A

    FM

    mode.

    Z

    X Y

    DC Bias

    Tu

    nn

    elin

    gC

    urr

    en

    t A

    mp

    lifi

    er

    Feed

    back L

    oo

    p M

    ain

    tain

    sC

    on

    sta

    nt

    Tu

    nn

    elin

    g C

    urr

    en

    t

    Feed

    back L

    oo

    pO

    utp

    ut

    Sig

    nal

    Ad

    justs

    Z P

    osit

    ion

    XY

    Raste

    r S

    can

    Pro

    bes:

    – T

    T10 p

    g 1

    29

    – P

    T10 p

    g 1

    28

    – S

    TM

    pg

    129

    – C

    LS

    T-P

    TB

    O p

    g 1

    28

    – D

    PT

    10 p

    g 1

    28

    – D

    TT

    10 p

    g 1

    28

    – P

    T-E

    CM

    10 p

    g 1

    28

    – T

    T-E

    CM

    10 p

    g 1

    29

    Scan

    nin

    g E

    lectr

    och

    em

    ical

    Po

    ten

    tial

    Mic

    rosco

    py -

    SE

    CP

    M

    The p

    robe in S

    EC

    PM

    is a

    sharp

    meta

    l needle

    . D

    ete

    cto

    r sig

    nal is

    ele

    ctr

    ic p

    ote

    ntial diffe

    rence b

    etw

    een t

    ip a

    nd s

    am

    ple

    (or

    betw

    een t

    ip

    and a

    refe

    rence e

    lectr

    ode) in

    an ionic

    or

    pola

    r liq

    uid

    , w

    here

    an e

    lectr

    ic

    double

    -layer

    exis

    ts a

    t th

    e liq

    uid

    /sam

    ple

    inte

    rface. S

    EC

    PM

    maps

    the e

    lectr

    ic p

    ote

    ntial pro

    file

    acro

    ss t

    he d

    epth

    of

    the d

    ouble

    -layer

    (v

    ers

    us Z

    , th

    e t

    ip-s

    am

    ple

    dis

    tance) at

    tip X

    Y location. In

    feedback

    mode,

    the o

    utp

    ut

    sig

    nal usually

    adju

    sts

    the Z

    positio

    n o

    f th

    e s

    canner.

    Sn

    60

    Ph

    40

    all

    oy

    in

    gly

    ce

    rol.

    Refe

    ren

    ce E

    lectr

    od

    e

    Wo

    rkin

    g E

    lectr

    od

    e=

    Sam

    ple

    Co

    un

    ter

    Ele

    ctr

    od

    e

    Po

    ten

    tio

    sta

    t

    Po

    ten

    tio

    mete

    r

    Pro

    bes:

    – P

    T-E

    CM

    10 p

    g 1

    28

    In-s

    itu

    ato

    m r

    eso

    luti

    on

    ele

    ctr

    och

    em

    ical S

    TM

    im

    ag

    e o

    f C

    u

    un

    derp

    ote

    nti

    al

    dep

    osit

    ion

    on

    Au

    (111

    ).

  • 34

    35

    Tors

    ion

    al

    Re

    so

    nan

    ce

    During T

    ors

    ional R

    esonance m

    ode (TR

    -Mode

    ™), t

    he t

    ip is a

    ctu

    ate

    d p

    ara

    llel

    rath

    er

    then v

    ert

    ical w

    ith r

    espect

    to t

    he s

    urf

    ace. Forc

    es b

    etw

    een t

    ip a

    nd

    sam

    ple

    cause a

    change in r

    esonance b

    ehavio

    r th

    at

    can b

    e u

    sed t

    o t

    rack

    th

    e s

    urf

    ace a

    t a c

    onsta

    nt

    dis

    tance. T

    R-M

    ode h

    as t

    he a

    dvanta

    ge t

    hat

    the

    tip r

    em

    ain

    s a

    t a c

    onsta

    nt

    dis

    tance t

    o t

    he s

    urf

    ace a

    t all

    tim

    es. T

    his

    can b

    e

    advanta

    geous in m

    odes lik

    e T

    R-T

    UN

    A™

    or

    nearfi

    eld

    -optical experim

    ents

    .

    Ste

    ps o

    n H

    OP

    G

    as s

    een

    by t

    he t

    ip

    op

    era

    tin

    g i

    n

    TR

    -Mo

    de.

    Z X Y

    La

    tera

    l T

    ip D

    ith

    er

    Fe

    ed

    ba

    ck

    Lo

    op

    Ou

    tpu

    t S

    ign

    al

    Ad

    jus

    ts Z

    Po

    sit

    ion

    Fe

    ed

    ba

    ck

    Lo

    op

    Ma

    inta

    ins

    Co

    ns

    tan

    t L

    ate

    ral

    De

    fle

    cti

    on

    Dri

    ve S

    ign

    al

    Ra

    ste

    r S

    ca

    n

    Detec

    tor

    Signa

    l

    Pro

    bes:

    – M

    PP

    -21100-1

    0 p

    g 6

    2

    – F

    ES

    P p

    g 5

    8

    PeakFo

    rce T

    UN

    A &

    Co

    nd

    ucti

    ve A

    FM

    Co

    nd

    ucti

    ve

    AF

    M P

    rob

    e

    Co

    nta

    ct

    Mo

    de

    Si

    np

    VDC

    (Su

    b p

    A -

    100 µ

    A)

    TU

    NA

    Data

    Cu

    rren

    t A

    mp

    lifi

    er

    To

    po

    gra

    ph

    y

    Co

    nd

    ucti

    ve

    Po

    lym

    er

    (rig

    ht)

    , P

    oly

    -an

    ali

    ne

    on

    In

    diu

    m T

    in O

    xid

    e (

    left

    ).

    Pro

    bes:

    – S

    CM

    -PIC

    pg

    112

    – S

    CM

    -PIT

    pg

    112

    – D

    DE

    SP

    -FM

    pg

    110

    – P

    FT

    UN

    A p

    g 1

    12

    Tunnelin

    g A

    FM

    (TU

    NA

    ) and C

    onductive A

    FM

    tra

    ditio

    nally

    opera

    te in c

    onta

    ct

    mode u

    sin

    g a

    conductive p

    robe. T

    he im

    agin

    g s

    ignal is

    the e

    lectr

    ic c

    urr

    ent

    betw

    een t

    ip a

    nd s

    am

    ple

    for

    an a

    pplie

    d D

    C b

    ias. In

    the feedback

    mode, th

    e

    DC

    bia

    s is d

    ynam

    ically

    adju

    ste

    d t

    o m

    ain

    tain

    a c

    onsta

    nt

    tip-s

    am

    ple

    curr

    ent.

    The o

    pera

    tional curr

    ent

    ranges is f

    rom

    fA

    (TU

    NA

    ) to

    μA

    (C

    AFM

    ). M

    ore

    re

    cently,

    CA

    FM

    and T

    UN

    A h

    ave b

    een u

    tiliz

    ed w

    ith P

    eak F

    orc

    e T

    appin

    g® into

    a n

    ew

    mode, PeakForc

    e T

    UN

    A™

    , w

    hic

    h e

    nable

    s t

    hese m

    easure

    ments

    to

    be t

    aken m

    ore

    relia

    bly

    and o

    n a

    much

    wid

    er

    range o

    f sam

    ple

    s, as w

    ell

    as

    allo

    win

    g f

    or

    the d

    irect

    corr

    ela

    tion o

    f ele

    ctr

    ical data

    with n

    anom

    ech

    anic

    al

    info

    rmation f

    rom

    PeakForc

    e Q

    NM

    ® m

    easure

    ments

    .

  • 36

    37

    Scan

    nin

    g S

    pre

    ad

    ing

    Resis

    tan

    ce

    Mic

    rosco

    py -

    SS

    RM

    SS

    RM

    uses c

    onta

    ct

    mode A

    FM

    and a

    conductive p

    robe. S

    ensor

    Sig

    nal

    is t

    he e

    lectr

    ic c

    urr

    ent

    betw

    een t

    he t

    ip a

    nd s

    am

    ple

    for

    an a

    pplie

    d D

    C b

    ias,

    VD

    C. S

    SR

    M m

    easure

    s t

    he c

    urr

    ent

    by r

    efe

    rencin

    g it

    to a

    n inte

    rnal re

    sis

    tor,

    usin

    g a

    logarith

    mic

    am

    plifi

    er, t

    o y

    ield

    local re

    sis

    tance v

    alu

    e. S

    SR

    M m

    aps

    the v

    ariation in m

    ajo

    rity

    carr

    ier

    concentr

    ation in d

    oped s

    em

    iconducto

    rs.

    Tra

    nsis

    tor

    cro

    ss s

    ecti

    on

    .

    Co

    nd

    ucti

    ve

    AF

    M P

    rob

    e

    Co

    nta

    ct

    Mo

    de

    (SS

    RM

    Data

    )

    (10 p

    A -

    100 µ

    A)

    Lo

    gari

    thm

    ic A

    mp

    lifi

    er

    log

    (I)

    Si

    np

    Spre

    adin

    g R

    esis

    tance

    R =

    4 x

    rad

    ius

    VD

    C

    ρ

    Resis

    tan

    ce

    Pro

    bes:

    – D

    DE

    SP

    pg

    110

    Scan

    nin

    g C

    ap

    acit

    an

    ce

    Mic

    rosco

    py -

    SC

    M

    To

    po

    gra

    ph

    y (

    left

    ),

    SC

    M (

    rig

    ht)

    la

    se

    r

    dio

    de c

    ross s

    ecti

    on

    .

    SC

    M u

    ses c

    onta

    ct

    mode A

    FM

    and a

    conductive p

    robe a

    nd a

    pplie

    s t

    o

    sem

    iconducto

    r sam

    ple

    s w

    ith a

    n A

    C b

    ias (am

    plit

    ude D

    V, ~

    90 k

    Hz)

    with a

    DC

    off

    set.

    The c

    apacitance o

    f th

    e m

    eta

    l-oxid

    e-s

    em

    iconducto

    r (M

    OS

    ) capacitor

    at

    tip-s

    am

    ple

    conta

    ct

    is a

    function o

    f m

    ajo

    rity

    carr

    ier

    concentr

    ation in t

    he

    sam

    ple

    . S

    CM

    uses a

    n u

    ltra

    -hig

    h-f

    requency (1 G

    Hz)

    dete

    cto

    r to

    measure

    tip-s

    am

    ple

    capacitance v

    ariation, D

    C, at

    the b

    ias f

    requency.

    Sensor

    sig

    nal

    is D

    C/D

    V. In feedback

    mode, outp

    ut

    sig

    nal is

    DV,

    adju

    ste

    d t

    o m

    ain

    tain

    a

    DC

    /DV

    Setp

    oin

    t. S

    CM

    maps r

    ela

    tive c

    hanges o

    f m

    ajo

    rity

    carr

    ier

    concentr

    ation in s

    em

    iconducto

    rs.

    Co

    nd

    uc

    tiv

    eA

    FM

    Pro

    be

    Co

    nta

    ct

    Mo

    de

    Si

    np

    VAC

    SC

    M D

    ata

    Ca

    pa

    cit

    an

    ce

    Se

    ns

    or

    SC

    M S

    en

    so

    r

    To

    po

    gra

    ph

    y

    n

    n

    n

    p

    p

    Pro

    bes:

    – S

    CM

    -PIC

    pg

    112

    – S

    CM

    -PIT

    pg

    112

    – M

    ES

    P-R

    C p

    g 1

    00

    – O

    SC

    M-P

    T p

    g 1

    12

  • 38

    39

    Scan

    nin

    g T

    herm

    al

    Mic

    rosco

    pie

    s

    To

    po

    gra

    ph

    y a

    nd

    th

    erm

    al m

    ap

    of

    a

    data

    sto

    rag

    e

    sam

    ple

    .

    In S

    cannin

    g T

    herm

    al M

    icro

    scopy (S

    ThM

    ) a h

    eate

    d t

    ip is s

    canned a

    cro

    ss a

    sam

    ple

    . C

    hanges in t

    he t

    ip’s

    resis

    tivity r

    eveal either

    therm

    al conductivity

    or

    therm

    al gra

    die

    nts

    on t

    he s

    am

    ple

    .

    In N

    anoscale

    Therm

    al A

    naly

    sis

    (N

    anoTA

    ), a

    tip

    is h

    eate

    d in s

    uch

    a

    way t

    hat

    it induces a

    phase t

    ransitio

    n in t

    he s

    am

    ple

    . That

    transitio

    n is

    monitore

    d u

    sin

    g t

    he c

    antile

    ver

    deflection a

    nd is m

    ate

    rial specifi

    c.

    Tem

    pera

    ture

    Measu

    rem

    en

    t

    Vert

    ical D

    efl

    ecti

    on

    Mo

    nit

    ore

    d a

    s T

    ip H

    eate

    d

    Heate

    rC

    on

    tro

    l

    T∆

    Th

    erm

    al

    Pro

    pert

    y M

    ap

    To

    po

    gra

    ph

    ical

    Map

    To

    po

    gra

    ph

    ical M

    easu

    rem

    en

    t

    Pro

    bes:

    – V

    ITA

    -Nan

    oT

    A P

    rob

    es p

    g 1

    31

    – V

    ITA

    -ST

    hM

    Pro

    bes p

    g 1

    30

    Pie

    zo

    resp

    on

    se

    Mic

    rosco

    py

    Pie

    zore

    sponse (P

    iezo

    forc

    e) M

    icro

    scopy (P

    FM

    ) is

    a t

    ech

    niq

    ue b

    ased o

    n

    conta

    ct

    mode t

    hat

    maps o

    ut

    the invers

    e p

    iezo

    ele

    ctr

    ic e

    ffect

    on a

    sam

    ple

    . The s

    am

    ple

    is e

    lectr

    ically

    stim

    ula

    ted a

    nd t

    he t

    opogra

    phic

    response o

    f th

    e s

    am

    ple

    is m

    onitore

    d u

    sin

    g lock

    -in t

    ech

    niq

    ues. A

    mplit

    ude a

    nd p

    hase

    info

    rmation r

    eveal in

    form

    ation a

    bout

    the s

    trength

    and d

    irection o

    f th

    e

    pola

    riza

    tion o

    n t

    he s

    am

    ple

    .

    Sm

    all

    de

    fect

    on

    th

    e

    po

    lin

    g b

    ou

    nd

    ary

    of

    a

    Lit

    hiu

    m n

    iob

    ate

    film

    v

    isib

    le i

    n t

    he

    am

    pli

    tud

    e

    sig

    na

    l o

    f a

    PF

    M

    ex

    pe

    rim

    en

    t.P

    rob

    es:

    – M

    ES

    P-R

    C p

    g 1

    00

    – S

    CM

    -PIT

    pg

    112

    – M

    ES

    P p

    g 9

    8

    – D

    DE

    SP

    -FM

    pg

    110

  • 40

    41

    Cri

    tical D

    imen

    sio

    n A

    tom

    ic F

    orc

    e

    Mic

    rosco

    py -

    CD

    AFM M

    ult

    iple

    sem

    ico

    nd

    ucto

    r tr

    en

    ches.

    Critical D

    imensio

    n A

    tom

    ic F

    orc

    e M

    icro

    scopy (C

    DA

    FM

    ) is

    a n

    on-

    destr

    uctive, hig

    h-r

    esolu

    tion t

    ech

    niq

    ue t

    hat

    enable

    s a

    ccura

    te

    measure

    ment

    of

    thre

    e-d

    imensio

    nal (3

    D) fe

    atu

    res. C

    D-A

    FM

    is a

    ccura

    te

    as it

    pro

    vid

    es h

    ighly

    lin

    ear

    measure

    ment

    over

    a r

    ange o

    f lin

    e-w

    idth

    s a

    nd

    is u

    naff

    ecte

    d b

    y featu

    re t

    ype, density o

    r m

    ate

    rial ty

    pe. A

    dditio

    nally

    , th

    e

    tech

    niq

    ue is a

    ble

    to m

    easure

    underc

    ut

    featu

    res a

    nd c

    an b

    e c

    alib

    rate

    d

    usin

    g N

    IST t

    raceable

    calib

    ration s

    tandard

    s t

    o e

    nsure

    accura

    cy o

    f m

    easure

    ments

    . C

    DA

    FM

    capabili

    ties h

    ave e

    nable

    d its

    use a

    s a

    refe

    rence

    metr

    olo

    gy t

    ool.

    Fla

    re o

    f T

    ip E

    na

    ble

    sM

    ea

    su

    rem

    en

    tso

    f U

    nd

    erc

    ut

    Fe

    atu

    res

    Bo

    tto

    m C

    D

    Sid

    ew

    all

    Pro

    file

    Sid

    ew

    all

    An

    gle

    s

    Mid

    dle

    CD

    To

    p C

    D

    De

    pth

    Lin

    e W

    idth

    Ro

    ug

    hn

    es

    sL

    WR

    & L

    ER

    Pro

    bes:

    – 3

    D M

    etr

    olo

    gy P

    rob

    es p

    g 1

    14

    Deep

    Tre

    nch

    Mo

    de

    Deep T

    rench

    (D

    T) M

    ode is a

    n A

    FM

    mode d

    evelo

    ped s

    pecifi

    cally

    for

    the

    repeata

    ble

    measure

    ment

    of

    deep s

    em

    iconducto

    r tr

    ench

    str

    uctu

    res f

    or

    90 n

    m a

    nd b

    elo

    w. It

    is a

    n a

    daptive s

    can m

    eth

    od in w

    hic

    h d

    ata

    is

    only

    colle

    cte

    d w

    hen u

    ser-

    specifi

    ed s

    yste

    m s

    tate

    conditio

    ns a

    re m

    et.

    This

    means t

    hat

    the t

    ip is “

    allo

    wed” t

    o m

    ove o

    nly

    in c

    ert

    ain

    serv

    o s

    tate

    s.

    DT M

    ode “

    ste

    ps” t

    he t

    ip a

    long t

    he s

    am

    ple

    surf

    ace c

    olle

    cting d

    ata

    poin

    ts

    only

    when “

    good” s

    can c

    rite

    ria a

    re m

    et.

    This

    perm

    its featu

    re-d

    ependent

    scan o

    ptim

    ization in w

    hic

    h t

    he c

    oncentr

    ation o

    f data

    poin

    ts is h

    ighest

    on t

    he featu

    res o

    f in

    tere

    st

    and low

    els

    ew

    here

    , re

    sultin

    g in im

    pro

    ved

    measure

    ment

    pre

    cis

    ion.

    Iso

    late

    d

    se

    mic

    on

    du

    cto

    r

    via

    .

    Hig

    h S

    ca

    nR

    ate

    Slo

    we

    r S

    ca

    n

    Hig

    he

    r R

    es

    olu

    tio

    no

    n H

    ori

    zo

    nta

    l S

    urf

    ac

    es

    Pro

    bes:

    – F

    IB P

    rob

    es p

    g 1

    20

    – D

    ep

    th M

    etr

    olo

    gy P

    rob

    es p

    g 1

    16

    – C

    NT

    Pro

    bes p

    g 1

    22

    – T

    ES

    P-H

    AR

    pg

    118