aecc/concawe 2016 gpf rde pn test programme: pn ... · pdf file© ricardo plc 2017 ......

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© Ricardo plc 2017 Jon Andersson 1 , Joachim Demuynck 2 , Heather Hamje 3 (1) Ricardo UK; (2) AECC; (3) Concawe AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and Below 23nm 21st ETH-Conference on Combustion Generated Nanoparticles June 19th - 22nd, 2017, ETH Zurich, Switzerland

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Page 1: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

© Ricardo plc 2017

Jon Andersson1, Joachim Demuynck2, Heather Hamje3

(1) Ricardo UK; (2) AECC; (3) Concawe

AECC/Concawe 2016 GPF RDE PN Test

Programme: PN Measurement Above and

Below 23nm

21st ETH-Conference on Combustion Generated Nanoparticles

June 19th - 22nd, 2017, ETH Zurich, Switzerland

Page 2: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

2June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Introduction

• Objectives

• Measurements

• Test Cycles

• Results

• Conclusions

Contents

Page 3: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

3June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• The introduction of Real Driving Emissions (RDE) and the inclusion of a Particle

Number (PN) limit for direct injection gasoline (GDI) vehicles has accelerated the

development of Gasoline Particle Filters (GPF)

– GPFs are expected to appear on mass-market production vehicles during 2017

• As part of a larger programme exploring exhaust emissions under RDE, a 1.4 litre Euro

6b stoichiometric lambda 1 GDI was tested in standard build, and when retrofitted with

a catalysed-GPF

• Particle number measurements were made of >23nm “PN↑23” and >7nm “PN ↑7” size

ranges to explore emissions levels and filtration impacts under a range of operating

conditions

Introduction

Page 4: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

4June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Introduction

• Objectives

• Measurements

• Test Cycles

• Results

• Conclusions

Contents

Page 5: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

5June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• To measure PN emissions from Real Driving Emissions (RDE) tests transposed to a

chassis dynamometer and evaluate impact of moving towards RDE boundary

conditions, including:

• Normal and reduced test temperatures: 23°C, 0°C, -7°C

• Dyno load changes: ~ road load, ~25% increase, ~50% increase

• To assess the impact of a specific GPF on PN emissions

– Including impact on PN ↑7 and PN↑23, if different

• Extras

– To compare magnitude of PN-PEMS and CVS-based PN emissions

– To assess any impact of a TWC on PN reduction

PN-related Objectives

Page 6: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

6June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Introduction

• Objectives

• Measurements

• Test Cycles

• Results

• Conclusions

Contents

Page 7: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

7June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

PN Systems’ Sampling Configurations

2 raw systems, 2 dilute systems, >7nm system, 3 x >23nm systems

Initial

dilution

Pre-

classifier

PND1

(diluter#1)

Volatile

Removal

PND2

(diluter#2)

PNC

(counter)

4: Raw

PN-PEMS(prototype)

[-]

3: Raw

SPCS

2: Dilute

Catalytic

Stripper

CVS (<30) [-] [-] [-]

1: Dilute

SPCS CVS (<30)

1µm dilution

10

dilution

10

DOC

350°C

d50

23nm

dilution

10

dilution

10

dilution

15

Evap tube

350°Cd50

23nm<10µm

≤350°C

<52°C

DOC

350°C

d50

7nm*

<52°C

dilution

10

Evap tube

350°C

~190°C

~190°C

dilution

15

d50

23nm<10µm

ambient ambient

< 35°C

< 35°C

*The emissions levels recorded with the 7nm d50 CPC were corrected for losses in the catalytic stripper

Page 8: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

8June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Introduction

• Objectives

• Measurements

• Test Cycles

• Results

• Conclusions

Contents

Page 9: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

9June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Regulatory Test Cycles at 23°C

conducted at dyno load consistent

with real road load

– NEDC

– WLTC

Test Cycles

• Real Driving Emissions (RDE)

performed on dyno with increased

acceleration rates

– Nominated as SRDE (Severitized

RDE)

– Minimal increase in dyno load

• SRDE_L at 23°C

• SRDE_L0 at 0°C

• SRDE_L-7 at -7°C

– ~25% increase of dyno load

• SRDE_M

– ~50% increase of dyno load

• SRDE_H [also 0°C & -7°C]

• SRDE variants tested with and

without GPF

• Real Driving Emissions (RDE)

– Based upon actual valid on-road

drive

– EMROAD processing of RDE

using WLTC cycle conducted

above

– On road cycle then transposed to

dyno, driven and reprocessed in

EMROAD

• CO2 levels from on-road and on-

dyno very close

Page 10: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

10June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• SRDE approach allows the valid

RDE “space” to be explored

within the controllable

environment of the test

laboratory

On-dyno RDE

EMROAD outputs for On-dyno RDE: SRDE_L, SRDE_M, SRDE_H

“mild” / “Low”

SRDE_L“moderate” / “Normal”

SRDE_M

“Ave

rag

e”

CO

2

“Ave

rag

e”

CO

2

“Average” Speed “Average” Speed

“severe” / “High”

SRDE_H

“Ave

rag

e”

CO

2

“Average” Speed

Valid range for

RDE data

Page 11: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

11June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Introduction

• Objectives

• Measurements

• Test Cycles

• Results

• Conclusions

Contents

Page 12: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

12June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Comparison of raw

and dilute SPCS

systems indicates <5%

difference

• CVS levels are slightly

higher

– May indicate CVS

background

contribution not

present in raw

sample

– Other differences

exist though

• Additional raw

diluter

• Different pre-

classifier

CVS (dilute) and Raw >23nm PN sampling appear sufficiently similar

to be considered equivalent

Non-GPF sampling

Non-GPF sampling

Page 13: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

13June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Draft RDE regulation

requires measured PEMS

emissions to be ±50% of

CVS levels

– Easily achieved

• Higher PEMS-PN levels

indicative of differences in:

– Methodology for

corrections of losses

– Absolute losses (raw v

dilute)

• Good linearity of relationship

allows ‘correction’ of PN-

PEMS data to simulate CVS

levels from raw exhaust

Prototype PN-PEMS system shows good correlation with CVS-based

PN↑23 system, but ~20% higher levels

post-GPF sampling

non-GPF sampling

post-GPF

sampling

non-GPF

sampling

Page 14: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

14June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Equating non-GPF

measurements from

the raw SPCS (pre-

TWC) with the

‘corrected’ tailpipe

PN-PEMS shows <5%

difference

• Losses / elimination of

particles in the TWC

are <10%

– With the difference

between raw and

dilute SPCS

factored-in

The Three-Way Catalyst (TWC) is not a major source of particle

removal or loss

non-GPF

sampling

non-GPF

sampling

Page 15: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

15June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• PN↑23 levels rise as cold-start

temperature reduces

– Larger rise 23°C to 0°C than

from 0°C to -7°C

• Post-GPF PN levels rise by ~80%

with each step from SRDE_L to

SRDE_M to SRDE_H

• Engine-out PN levels from all

conditions equal to, or in excess of

CF=1.5

• Post-GPF PN↑23 levels below CF=1

from all SRDE

0°C and -7°C SRDE PN↑23 data, based upon CVS measurements

using dilute SPCS Error bars = 1s of 3

repeats of SRDE_M

applied to other tests

as the same %

Euro 6c/d

Euro 6c/d

CF=1.5

Page 16: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

16June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• CVS-based measurements of

PN↑7 and PN↑23 show that all

post-GPF tests’ emissions

were below the Euro 6c limit

– NEDC, WLTC and

SRDE_L,M &H testing

• When a GPF is applied, the

differential between the

number of particles >7nm and

the number of particles >23nm

is minimised

• The GPF appears to

preferentially trap the smallest

particles

– Diffusion collection

mechanism dominates

Relationship between total PN↑7 and total PN↑23 changes when

specific GPF is applied

0.00E+00

2.00E+11

4.00E+11

6.00E+11

8.00E+11

1.00E+12

1.20E+12

1.40E+12

1.60E+12

0.00E+00 6.00E+11 1.20E+12 1.80E+12 2.40E+12 3.00E+12

PN

Em

issi

on

s >2

3n

m

PN Emissions >7nm

CF=1

CF=1

Post GPF

Post GPF:

PN↑7 = ~1.2 x PN↑23

NO GPF:

PN↑7 = >1.5 x PN↑23

Page 17: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

17June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

GPF efficiencies for >23nm particles range from ~60% to ~80%, but

are exceeded by >7nm efficiencies (70% to >90%)

>23nm

>7nm

SRDE_L SRDE_M SRDE_H SRDE_H0 SRDE_L-7 SRDE_H-7

• Observed increase in filtration efficiency between >7nm and >23nm ranges indicates

larger increase for 7nm to 23nm range in isolation (>95%)

Page 18: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

18June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Introduction

• Objectives

• Measurements

• Test Cycles

• Results

• Conclusions

Contents

Page 19: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

19June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• The addition of a GPF enabled the regulatory limit value for GDI vehicles (6x1011#/km)

to be achieved, for PN↑23, from standard chassis dyno cycles and very demanding RDE

conditions, including high load and low temperature tests

• Increases in engine-out PN of >50% were seen when extending the measurement

range from d50=23nm down to ~7nm, but with a GPF in place this differential dropped

to ~20%

– The GPF tested appears especially efficient for <23nm PM

• CVS (dilute) and Raw PN↑23 lab-based PN sampling (the latter currently being

considered as an option for certification testing) appear sufficiently similar to be

considered equivalent in the configurations used at Ricardo

• >23nm PN-PEMS particle number emissions proved to be ~20% higher than CVS-

based levels, due to lower sampling losses

– but agreement is well within the ±50% range permitted for regulatory correlation

Conclusions

Page 20: AECC/Concawe 2016 GPF RDE PN Test Programme: PN ... · PDF file© Ricardo plc 2017 ... AECC/Concawe 2016 GPF RDE PN Test Programme: PN Measurement Above and ... NO GPF: PN↑7 = >1.5

20June 201721st ETH-Conference© Ricardo plc 2017

21st ETH-Conference on Combustion Generated Nanoparticles

• Thanks to:

– AECC members

– Concawe members

– Staff at Ricardo

• Simon de Vries

• Carl Jemma

Acknowledgements

Any

questions?