adsorption thermodynamics of isoliquiritin on multi-walled carbon nanotubes

1
Adsorption thermodynamics of isoliquiritin on multi-walled carbon nanotubes Bo Han a,b , Wen Chen b , Chun-xin Wang b , Le Li a , Huan Yan b , Wen-xin Li a a Laboratory of Nano-biology and Medicine, Shanghai Institute of Applied physics, Chinese Academy of Science, Shanghai 201800, China b Key Laboratory of Xinjiang Phytomedicine Resources of Ministry of Education, Shihezi 832002, China Multi-walled carbon nanotubes (MWCNTs) can selectively adsorb structurally-similar liquiritin and isoliquiritin, both of which are flavonoid compounds. The adsorption thermodynam- ics of isoliquiritin on MWCNTs was investigated. Results indicate that the quantity of isoliquiritin adsorbed increases with isoli- quiritin concentration and decreases with temperature. Adsorp- tion data can be well described by the Freundlich equation. The values of DH 0 and DG 0 indicate that the adsorption is a spontane- ous exothermic process. [New Carbon Materials 2010;25(1):74–8]. doi:10.1016/j.carbon.2010.01.048 Professor Fu He and his research activities Chun-xiang Lu National Engineering Laboratory for Carbon Fiber Technology, Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China Professor Fu He was born in Jiaocheng County, Shanxi Prov- ince, China. He has been working in the Institute of Coal Chemis- try, Chinese Academy of Sciences since graduation from Shanxi University in 1964. He had undertaken and completed many research projects as a principal or main investigator during R&D and industrialization studies in the field of carbon fibers for over forty years. He has authored four books, held twelve patents, and published 120 research papers. Two of his books, The prepa- ration, properties and applications of carbon fibersand Carbon fibers and the techniques for applicationhave been recognized as classic textbooks by many researchers in the field of carbon fibers in China. A total of fifteen scientific achievements have been developed by him, five of which have been applied in the industri- alization of carbon fibers. He received the State Council Special Allowance in 1992, and was awarded the National Young and Mid- dle-aged Experts with Outstanding Contribution Award in 1988, the Excellent Graduate Supervisor of Chinese Academy of Sci- ences in 1998, the Second-Class Merit by the Labor Emulation Committee of Shanxi Province in 1999, and the Distinguished Achievement Award on Carbon Materials in 2009. [New Carbon Materials 2010;25(1):79–80]. doi:10.1016/j.carbon.2010.01.049 2126 CARBON 48 (2010) 2123 2126

Upload: bo-han

Post on 26-Jun-2016

213 views

Category:

Documents


1 download

TRANSCRIPT

Adsorption thermodynamics of isoliquiritin on multi-walled

carbon nanotubes

Bo Hana,b, Wen Chenb, Chun-xin Wangb, Le Lia, Huan Yanb,

Wen-xin Lia

a Laboratory of Nano-biology and Medicine, Shanghai Institute of

Applied physics, Chinese Academy of Science, Shanghai 201800, Chinab Key Laboratory of Xinjiang Phytomedicine Resources of Ministry of

Education, Shihezi 832002, China

Multi-walled carbon nanotubes (MWCNTs) can selectively

adsorb structurally-similar liquiritin and isoliquiritin, both of

which are flavonoid compounds. The adsorption thermodynam-

ics of isoliquiritin on MWCNTs was investigated. Results indicate

that the quantity of isoliquiritin adsorbed increases with isoli-

quiritin concentration and decreases with temperature. Adsorp-

tion data can be well described by the Freundlich equation. The

values of DH0 and DG0 indicate that the adsorption is a spontane-

ous exothermic process.

[New Carbon Materials 2010;25(1):74–8].

doi:10.1016/j.carbon.2010.01.048

Professor Fu He and his research activities

Chun-xiang Lu

National Engineering Laboratory for Carbon Fiber Technology, Key

Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese

Academy of Sciences, Taiyuan 030001, China

Professor Fu He was born in Jiaocheng County, Shanxi Prov-

ince, China. He has been working in the Institute of Coal Chemis-

try, Chinese Academy of Sciences since graduation from Shanxi

University in 1964. He had undertaken and completed many

research projects as a principal or main investigator during R&D

and industrialization studies in the field of carbon fibers for over

forty years. He has authored four books, held twelve patents,

and published 120 research papers. Two of his books, “The prepa-

ration, properties and applications of carbon fibers” and “Carbon

fibers and the techniques for application” have been recognized

as classic textbooks by many researchers in the field of carbon

fibers in China. A total of fifteen scientific achievements have been

developed by him, five of which have been applied in the industri-

alization of carbon fibers. He received the State Council Special

Allowance in 1992, and was awarded the National Young and Mid-

dle-aged Experts with Outstanding Contribution Award in 1988,

the Excellent Graduate Supervisor of Chinese Academy of Sci-

ences in 1998, the Second-Class Merit by the Labor Emulation

Committee of Shanxi Province in 1999, and the Distinguished

Achievement Award on Carbon Materials in 2009.

[New Carbon Materials 2010;25(1):79–80].

doi:10.1016/j.carbon.2010.01.049

2126 C A R B O N 4 8 ( 2 0 1 0 ) 2 1 2 3 – 2 1 2 6