adsorption and desorption in ism

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    Gas-grain modeling for interstellarGas-grain modeling for interstellar

    chemistrychemistry

    Supervisors: MINISSALE M.

    P. THEULE

    Presented by:  AURI

    SHARMA

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    CONTENTS

    Introduction

    1)Interstellar medium2)Processes3)Experimental setup

    Simulation

    1)Gas-grain model

    ●Experiments

    1)ure H!O

    !)ure CO")ure CO!#)Mixture o$ H!O%CO!

    ●Conclusion

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    INTRO&UCTION

    &i$$use

    medium

    &ense

    medium Molecular cloudImage credit: Kohler M. et al. Edited ! "harma G.

    #redit: $ue%o M. et al.

    1'( cemical

    compounds

    O*ser+ed in

    molecular clouds,

    ISM

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    HOW do they form ????

      Image credit: KI&&-PK' and http:((sta.on.r(*l+m(astron2e(&,MEI& / edited ! "harma G.

    1- &UST

    http://staff.on.br/jlkm/astron2e/AT_MEDIAhttp://staff.on.br/jlkm/astron2e/AT_MEDIA

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    .ormation o$ molecules on &UST

    Ho/ do /e o*ser+e tem in 0as pase in spectroscop 22222

    COSMIC RA3S4

    Image credit: 0Khler M. et al. 45 &165)/ edited ! "harma G.

    5ic te psical penomenon occurs tere 22222

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    Adsorption

    rocesses and experimental setup

    Cosmic ras

    '7Photons

    Interstellar medium

    6a*orator

    "pecimen chamer"P8&!

    #redit:Philip 9o-mann

    #redit: $eu%o M et al.

    "ample 

    H

    7

    )

    m

    *

    M"

    ;a+eshoreinstrument

    Temperature

    ro0rammed

    &esorption

    8T&)

       <  e  e   d     a  c   +

      %  o   l   t  a  g  e

    esorption

    ● Adsorption

    ●&esorption 

    ● &i$$usion

    ,     e   l     e   s   c   o     p   

    e   

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     as%0rain modelin0

    Ho/ to e+aluate T& 22222

    Polan!i-=igner E>uation:

    8 ? esorption rate$ ? $o. o molecules per s>uare cm

    n? order o esorption@eta ? ramp rate

    E ? esorption energ!, ? esorption temperature

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    Experiments

    ●ure H!O

    ●ure CO

    ●ure CO!

    ●Mixture o$ H!O%CO!

    Atain,P

    #alculate energ!rom ,P

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    H!O

    Experiment

                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            M                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        o                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        l                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        e                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     c                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        u             

                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                               l                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        e                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                   s                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     c                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    m                                                                                                                                                                                                                                                                                                                                                                                                                                      -                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     2                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        K                                                                                                                                                                                                                                                                                                                                                                                                                                      -                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                       1

    &morphousphase o 92A

    ● E:des ;

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    CO

    Experiment

                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            M                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        o             

                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                               l                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        e                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     c                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        u             

                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                               l                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        e                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                   s                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     c                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    m                                                                                                                                                                                                                                                                                                                                                                                                                                      -                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     2                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        K                                                                                                                                                                                                                                                                                                                                                                                                                                      -                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                       1

    ● E:des ; 987.0±36.00 ● A ; 1(1!?1 sec%1● T:des B "< ● Residence time ;

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    CO!

    Experiment

                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            M                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        o                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        l                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        e                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     c                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        u             

                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                               l                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        e                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                   s                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     c                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    m                                                                                                                                                                                                                                                                                                                                                                                                                                      -                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     2                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        K                                                                                                                                                                                                                                                                                                                                                                                                                                      -                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                       1

    ● E:des ; !#(±50.00

    ● A ; 1(1!?1 sec%1● T:des B = ● Residence time ; #>@ x 1(1( ears

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    Mixture

    CO!%H!O

                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            M

                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            o                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        l                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        e                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     c                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                        u             

                                                                     �