additives waxes · 2015-05-14 · maleic anhydride grafted pp wax maleic anhydride grafted pp wax...

AdditivesWaxes

Licowax ®, Ceridust ®, Licolub ®, Licomont ®, Licocene®

General leaflet – Waxes

Exactly your chemistry.

2

Introduction

Clariant supplies a wide range of waxes for many different industries and applications, to solve particular problems in many application sectors like plastics, coating, polish etc.

Clariant is a global player since more than eight decades in the production of waxes, offering a widely diversified portfolio of synthetic and semi synthetic waxes.

The waxes of Clariant(previously Hoechst) are widely used in a huge, diversified field of application: from Adhesives, Coatings & Inks over Emulsions, Plastics, polish and care or specialized Applications as Road construction, Wax sculptures and candles, Powder metallurgy, Cosmetics, Metal working, Stationary.

Our portfolio comprises Montan wax based products, polyolefin and polymeric based waxes, as well as amide waxes and their micronized grades. Our Ceridust® micronized waxes, for instance, are widely established on the market as top quality products ideal for use in printing inks, paints, and many other plastic and coating applications.

With our long established expertise and focus on research and development, we are in the position to develop innovative solutions, orientated towards the demands of the markets and requirements of customers.

CONTENTS

Introduction 2

Test methods 3

Montan waxes 4 –9

Polyolefin waxes 10–13

Modified polyolefin waxes 14–17

Micronized waxes 18–21

Amide waxes 22–23

Special products 24–25

Safety data 26

Transport and storage 27

General leaflet Licowax®, Ceridust®, Licolub®, Licomont®, Licocene®

3

Test methods

Melting point DSC°C

Drop point ISO 2176°C ASTM D 3954 Softening point ASTM D 3104°C Acid value ISO 2114mg KOH/g ASTM D 1386 Saponification value ISO 3681mg KOH/g ASTM D 1387 Density at 23 °C ISO 1183g/cm3

Viscosity mPa·s DIN 53019

DIN Deutsches Institut für Normung e. V., Berlin

ASTM American Society for Testing and Materials, Philadelphia

ISO International Organization for Standardization, Geneva, Switzerland


4

Montan waxes

Licowax S

Licowax LP

Licowax SW

Licowax E

Licowax KPS

Licowax KSL

Licowax KST

Licolub WE 4

Acid wax

Acid wax

Acid wax

Ester wax

Ester wax

Ester wax

Ester wax

Ester wax

Emulsions for polishes and technical applications, lubricant for plastics, color bases, polishing waxes, technical emulsions

Polish emulsions; color bases, polishing waxes, emulsions

Beauty cosmetics

Polish emulsions and pastes (solvent based), carbon paper, lubricant for plastics, dispersing agent for fillers and pigments in engineering resins, multi functional lubricant in PVC

Polishes, especially dry bright emulsions, anti-blocking agents for plastic dispersions, emulsions for citrus fruit coating

Polishes, especially dry bright emulsions, paper and film coating, emulsions for citrus fruit coating

Dry bright emulsionsSizing agent for textile industry, release agent

Lubricant for plasticsDispersing agent for engineering resins especially polyester, lubricant for calandered PVC film

Name Chemical Main applications characterization

5

~ 82

~ 86

~ 84

~ 81

~ 80

~ 82

~ 60

~ 80

~ 144

~ 122

~ 125

~ 18

~ 30

~ 31

~ 3

~ 26

~ 170

~ 155

~ 160

~ 150

~ 143

~ 151

~ 8

~ 155

~ 1.01

~ 1.01

~ 1.01

~ 1.02

~ 1.01

~ 1.01

~ 1.08

~ 1.01

~ 20

~ 20

~ 20

~ 30

–

~ 30

–

~ 60

Paleyellowish

Yellowish

Almost white to paleyellowish

Pale yellowish

Yellowish

Yellowish

Pale yellowish

Yellowish

Flakes

Flakes

Flakes

FlakesPowder

Flakes

Flakes

Fine grain

Powder

Physical and chemical properties

Drop point Acid value Saponification Density at Viscosity at Color Supply forms 1

[°C] [mg KOH/g] value [mg KOH/g] 23 °C [g/cm 3] 100 °C [mPa·s]


1 = Fine grain < 2,000 µm Powder < 500 µm Fine powder < 125 µm Micro powder < 50 µm (d90-value)

6

Montan waxes

Licolub WM 31

Licolub WE 40

Licowax OP

Licowax O

Licowax KLE

Ester wax

Ester wax

Ester wax,partly saponified

Ester wax,partly saponified

Ester wax, containing emulsifier

Lubricant for plastics

Lubricant and dispersing agent for plastics, multi funtional lubricant in PVC

Lubricant and dispersing agent for plastics, solvent based polishes, especially in paste form, release agents, carbon paper, multi functional lubricant in PVC

Solvent based polishes, especially in paste form

Dry bright emulsions, release agents


7


75

~ 76

~ 99

~ 99

~ 83

~ 10

~ 20

~ 12

~ 13

~ 29

~ 165

~ 183

~ 112

~ 120

~ 114

~ 1.00

~ 1.02

~ 1.02

~ 1.02

~ 1.01

~ 26

~ 150

~ 300(120 °C)

~ 200(120 °C)

–

Yellowish

Yellowish

Yellowish

Yellowish

Yellowish

FlakesPowder

Powder

FlakesPowder

Flakes

Flakes


Drop point Acid value Saponification Density at Viscosity at Color Supply forms 1

[°C] [mg KOH/g] value [mg KOH/g] 23 °C [g/cm 3] 100 °C [mPa·s]


8

Montan waxes

Licomont NaV 101

Licomont CaV 102

Sodium salt of long chain linear carboxylic acids

Calcium salt of long chain linear carboxylic acids

Lubricant and nucleating agent for partly cristalline plastics (polyester, polyamides), improvement of meltflow and demolding behaviour

Lubricant and nucleating agent in polyamides, improvement of melt flow behaviour and demoldability


9


–

–

~ 3

~ 10

> 5

~ 4.0

< 1

< 2

Yellowish

Paleyellowish

Powder

PowderFine grain


Drop point Acid value Cation cont. Volatility at Color Supply forms 1

[°C] [mg KOH/g] [% w/w] 105 °C [% w/w]


10

Polyolefi n waxes

Licowax PE 520

Licowax PE 130

Licowax PE 190

Polyethylene wax,non-polar

Polyethylene wax, non-polar


Solvent based polishes, additive for hydrocarbon waxes, rub resistance in printing inks, matting agent for paints and coatings, modification of hotmelt adhesives and coatings, dispersing agent for pigment concentrates, lubricant for plastics, external lubricant for PVC

Rub resistance for printing inks, solvent based polishes, especially for pastes, anti-offset agent for electro photographic toners, modification of hotmelt adhesives and coatings

Melting point booster, anti-offset agent for electro photographic toners, modification of hotmelt adhesives and coatings, lubricant for plastics


11

~ 120**

~ 130**

~ 135*

~ 0.93

~ 0.97

~ 0.96

~ 650

~ 300

~ 25,000

White

White

White

Granules Fine grainPowder

Granules Powder

Powder



Drop point Density at Viscosity at Color Supply forms 1

[°C] 23 °C [g/cm 3] 140 °C [mPa·s]


* = Softening point

** = Drop point (ASTM D 3954)

12

Polyolefi n waxes

Licocene PE 4201

Licocene PP 1302

Licocene PP 1502

Licocene PP 1602

Licocene PP 2602

Licocene PP 6102

Licocene PP 6502 TP❖

Licocene PP 7502 TP❖

Unpolar Metallocene PE wax

Unpolar, amorphousMetallocene PP wax




Unpolar, crystalline Metallocene PP wax



Lubricant for plastics, expandable PS, hotmelt, toner, silicon coating

Dispersing agent, carrier for pigment and additives masterbatch, lubricant for plastics, hotmelt application




Lubricant for plastics, dispersing agent for masterbatch, external lubricant for PVC, hotmelt application




13


~ 128

~ 90

~ 86*

~ 88*

~ 99*

~ 145

~ 146*

~ 165*

~ 0.97

~ 0.87

~ 0.87

~ 0.87

~ 0.87

~ 0.90

~ 0.90

~ 0.90

~ 60 (140 °C)

~ 200

~ 1800

~ 6000

~ 6300

~ 60

~ 1500

~ 1800

White, brittle hard

White-transparent, soft tacky




White, brittle hard

White, brittle hard

White, brittle hard

GranulesPowder

GranulesFine grain

Granules

Granules

Granules

GranulesFine grain

GranulesFine grain

Granules Fine grain


Drop point Density at Viscosity at Color Supply forms 1

[°C] 23 °C [g/cm 3] 170 °C [mPa·s]


* = Softening point

TP ❖ = Test product

14

Polar Polyolefi n waxes

Licolub H 12

Licowax PED 521

Licowax PED 522

Licowax PED 121

Licowax PED 153

Licowax PED 191

Licowax PED 192

Licowax 371 FP

Polyethylene wax,polar




Polyethylene wax, polar




Lubricant for plastics, lubricant for wood plastic composites

Dispersions for textiles, leather, paper and polishes, improving the rheological properties in paints and coatings, modifier for hotmelts, release agent for various applications, lubricant for plastics and wood plastic composites

Dispersions for textiles, leather, paper and polishes, improving the rheological properties in paints and coatings, modifier for hotmelts, release agent for various applications

Emulsion for citrus fruit coating

Polish dispersion, dispersions for textiles, leather and paper, modification of hotmelts, release agent for various applications

Polish dispersion, dispersions for textiles, modification of hotmelts, lubricant for plastics especially PVC, release agent

Dispersion for textiles, paper and polishes, modification of hotmelts, release agent for various applications

Polishes, dry bright emulsion, metallic paints, paper coating, and adhesives


15


~ 104

~ 104

~ 101

~ 116

~ 120

~ 123

~ 123

~ 102

~ 17

~ 17

~ 25

~ 18

~ 25

~ 17

~ 22

~ 21

~ 0.95

~ 0.95

~ 0.96

~ 0.98

~ 0.98

~ 0.98

~ 0.98

~ 0.96

~ 350

~ 350

~ 250

~ 150 (140 °C)

~ 1,500(140 °C)

~ 1,800 (140 °C)

~ 1,500 (140 °C)

~ 3,000

Almost white

Almost white

Almost white

Almost white

Almost white

Almostwhite

Almostwhite

Almostwhite

Fine grain

Granules

Granules

Flakes

Flakes

FlakesPowder

Flakes

Flakes


Drop point Acid value Density at Viscosity at Color Supply forms 1

[°C] [mg KOH/g] 23 °C [g/cm 3] 120 °C [mPa·s]


16

Modifi ed Polyolefi n Waxes

Licocene PE MA 4221

Licocene PE MA 4351

Licocene PP MA 6252

Licocene PP MA 6452 TP❖

Licocene PP MA 7452 TP❖

Licocene PE SI 3361 TP❖

Maleic anhydride grafted PE wax

Maleic anhydride grafted PE wax

Maleic anhydride grafted PP wax



Polyethylene wax, modified with silane

Colorless lubricant for engineering / compounds, dispersing agent for masterbatch

Compatibilizer for wood-, glass- and natural fibre reinforced PE Compounds

Compounds, emulsions, hotmelt

Compatibilizer for wood-, glass-, and natural fibre reinforced PP Compounds, hotmelt, emulsion

Compatibilizer for wood-, glass-, and natural fibre reinforced PP Compounds, hotmelt, emulsion

Hotmelt adhesives, particularly in reactive systems It crosslinks in the presence of water


17



* = Softening point


~ 123

~ 123

~ 140

~ 140*

~ 161*

~ 119

~ 18

~ 45

~ 42

~ 41

~ 41

–

~ 0.98

~ 0.99

~ 0.93

~ 0.91

~ 0.93

0.97

~ 140 (140°C)

~ 350 (140°C)

~ 100

~ 1100

~ 1100

~ 150

White, brittle hard

Yellowish, brittle hard

Yellowish, brittle hard

Yellowish, hard

Yellowish, hard

White

Fine grain

GranulesFine grain

Granules

Granules Fine grain

Granules

Drums




18

Ceridust 3620

Ceridust 3610

Ceridust 3715

Ceridust 2051

Ceridust 3251

Ceridust 9615 A

Ceridust 8020 TP❖

Ceridust 3910

Ceridust 7820 TP❖


Polyethylene wax


Synthetic wax

Modifiedpolyethylene wax

Modifiedpolyethylene wax

Highly modifiedcopolymer wax

Amide wax

Modified amide wax

Rub resistance additive for printing inks, modifying surface properties for paints and coatings, matting agent, dispersing agent for pigment masterbatches

Rub resistance additive for printing inks, modifying surface properties for paints and coatings, matting agent

Rub resistance additive for printing inks, modifying surface properties for paints and coatings, also for water based system

Gloss reduction additive for powder coatings

Rub resistance additive for printing inks, modifying surface properties for paints and coatings

Modifying surface properties for paints and coatings, mattingagent, sanding aid

Additive for soft touch matting and improved scratch resistance in water and solvent based coatings, lubricant for plastics

Modifying surface properties for paints and coatings, sanding aid,slip additive for printing inks, dispersing agent for pigment masterbatches of engineering resins

To maintain gloss in powder coating applications (almost no matting effect). Additionally, it displays very good degassing properties


Micronized waxes

19


~ 125

~ 128

~ 125

~ 112

~ 123

~ 140

~ 73

~ 142

~ 132

–

–

~ 4

–

–

~ 4

~ 84

~ 7

~ 9

~ 8.5

~ 5.0

~ 8.5

~ 6.5

~ 7.0

~ 6.5

~ 8.0

~ 6.5

~ 6

White

White

White

White

White

White

Yellowish

White

White

Micronized powder

Micronized powder

Micronized powder

Micronized powder

Micronized powder

Micronized powder

Micronized powder

Micronized powder

Micronized powder


Drop point Acid value Particle size Color Supply forms 1

[°C] [mg KOH/g] [d50 (µm)]



20

Ceridust 5551

Ceridust 9610 F

Ceridust 9630 F

Ceridust 6050 M

Ceridust 3920 F

Ceridust 3940 F

Ceridust 3941 F

Ceridust 9202 F

Ceridust 9205 F

Ceridust 8330 TP❖

Ester wax

PE/PTFE

PE/PTFE

PP wax

PE/PTFE

PE/PTFE

PE/PTFE

PTFE

PTFE

Micronized wax compound, based on renewable polymer wax

Modifying surface properties for paints and coatings, matting agent, also for water based system, dispersing agent for pigment masterbatches of engineering resins

Rub resistance additive for printing inks, modifying surface properties for paints and coatings, matting agent, slip additive

Rub resistance additive for printing inks, modifying surface properties for paints and coatings, matting agent, slip additive

Dispersing agent for pigment masterbatches, adhesion promoterand degassing agent for powder coatings

Additive to improve scratch resistance and slip in coatings

Additive to improve scratch resistance and slip, texturizing agentin powder coatings

Additive to improve scratch resistance and slip, texturizing agent in powder coatings

Improvement of the surface for printing inks, paints and coatings, lubricant

Improvement of the surface for printing inks, paints and coatings, lubricant

Rub resistance additive for printing inks. Modifying of surface properties, matting agent for paints and coatings. Powder coating


Micronized waxes

21


~ 96

~ 127**

~ 127**

~ 145

~ 127**

~ 127**

~ 127**

–

–

n / a

~ 16

–

~ 2

–

max. 1

max. 1

max. 1

–

–

n / a

~ 8.5

~ 8.5

~ 8.0

~ 9.5

~ 6

~ 14

~ 14

~ 4

~ 8

~ 5.5

Yellowish

White

White

White

White

White

White

Almostwhite

Almostwhite

White

Micronized powder

Micronized powder

Micronized powder

Micronizedpowder

Micronized powder

Micronizedpowder

Micronizedpowder

Micronizedpowder

Micronizedpowder

Micronizedpowder


Drop point Acid value Particle size Color Supply forms 1

[°C] [mg KOH/g] [d50 (µm)]


** = Melting point


22

Amide waxes

Licowax C

Licolub FA 1 powdervegetable based

Licowax CMicropowder PM

Amide wax

Amide wax

Amide wax

Slip agent for paints, plastics and coatings, lubricant for plastics, release agent, lubricant for wood plastic composites

Slip agent and lubricant for plastics

Lubricant for powder metallurgy, release agent


23


~ 142

~ 142

~ 142

~ 6

~ 6

~ 6

~ 1.00

~ 1.00

~ 1.00

Almostwhite

Almostwhite

White

Powder

Powder

Micro powder


Drop point Acid value Density at Color Supply forms 1

[°C] [mg KOH/g] 23 °C [g/cm 3]


24

Special products

Wax emulsifier 2106

Wax emulsifier 4106

Licowax R 21

Licolub H 4

Licomont BS 100

Licolub CE 2 TP❖

ContainsPhenolethoxylates

ContainsAlkylethoxylates

Branched alkane carboxylic acid/salt

Modifiedhydrocarbon wax

Mixture offatty acid derivatives

Highly polar modified copolymer wax

Non-ionogenic emulsifiers for waxes with acid numbers up to 40 mg KOH/g (e. g. Licowax KPS, Licowax KSL).

Non-ionogenic emulsifiers for waxes with acid numbers up to 40 mg KOH/g (e. g. Licowax KPS, Licowax KSL)

Corrosion protection, liquid wax

Lubricant for plastics

Bitumen modification for road construction

Lubricant for plastics emulsions, polish, toner, cosmetics


25


~ 57

~ 55

~ 107

~ 111

~ 142

~ 73

–

–

~ 5

–

~ 6

~ 84

~ 1.08

~ 1.06

~ 0.94

~ 0.92

~ 1.00

–

–

–

~ 10

~ 8

–

~ 350(100 °C)

White, wax like

White,wax like

White

White

Almostwhite

Paleyellowish

Blocks

Blocks

Flakes

Fine grain

PowderGranules

Fine grainGranules






26

A safety data sheet giving further details is avail able for each Clariant product introduced here.

The toxicological and ecological proper ties were tested on typical prod ucts in the range. The vast majority of products have very good toxicolo gical and ecotoxicological proper-ties. The most recent values are given in the safety data sheets.

TOXICOLOGICAL PROPERTIES

Acute oral toxicityThe acute oral toxicity (LD50) of most products is > 2,000 mg/kg (rat or mouse).

When handling Ceridust 9202 F, Ceridust 9205 F, Ceridust 9610 F, Ceridust 3920 F, Ceridust 3940 F, Ceridust 9630 F and Ceridust 3941 F, the usual pre cautions for products containing PTFE should be observed. It is essential to avoid contamination of clothes and tobacco. Dangerous decomposition products can be formed at tempera tures above 300 °C.

Status according to (CLP) EC 1272/2008The products mentioned here do usually not require a hazard warning label under the CLP regulations on dangerous substances (EC 1272/2008).

Wax emulsifier 2106 has to be labeled with N, R 50/53.Wax emulsifier 4106 has to be labeled with Xn, N, R 22, 38, 41, 50.

Notes on handling powdersWhen handling organic powders, VDI Directive 2263 “Prevention of dust fires and dust explosions” or the corresponding national regulations should be observed.

Status according to the European chemicals law (REACH)The products mentioned in this data sheet or its monomers are either preregistered, registered or as polymer exempt from registration (EC 1907/2006).

Status under food legislationA number of the products mentioned here are permitted to be used as indirect additives under the food legislation of the Federal Republic of Germany and other countries, or comply with the recommendations of government health departments. These products may thus be used for the manufacture of consumer commodities which come into contact with food. Detailed information is available upon request. Please contact our sales representatives or refer to our Product Data Sheets or Material Safety Data Sheets.

Safety data

27


Transport and storage

StorageThe products mentioned in this leaflet should be stor ed in a dry place at room temperature.

Dispatch, transportRID, GGVE, ADR, GGVS, ADNR, IMDG-Code, ICAO/IATA-DGR

The products mentioned in this leaflet are not classified as dangerous goods under these regulations.

This information corresponds to the present state of our knowledge and is intended as a general description of our products and their possible applications. Clariant makes no warranties, express or implied, as to the information’s accuracy, adequacy, suffi ciency or freedom from defect and assumes no liability in connection with any use of this information. Any user of this product is responsible for determining the suitability of Clariant’s products for its particular application. * Nothing included in this information waives any of Clariant’s General Terms and Conditions of Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due to possible changes in our products and applicable national and international regulations and laws, the status of our products could change. Material Safety Data Sheets providing safety precautions, that should be observed when handling or storing Clariant products, are available upon request and are provided in compliance with applicable law. You should obtain and review the applicable Material Safety Data Sheet information before handling any of these products. For additional information, please contact Clariant.

* For sales to customers located within the United States and Canada the following applies in addition: NO EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR SERVICE. DA

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www.additives.clariant.com

Clariant International LtdBusiness Unit AdditivesMarketing and Operations WaxesRothausstrasse 614132 MuttenzSwitzerlandPhone: +41-61-469-7912Fax: +41-61-469-7550

Exactly your chemistry.

® = Trademark of Clariant registered in many countries

© 2012 Clariant International Ltd

additives waxes · 2015-05-14 · maleic anhydride grafted pp wax maleic anhydride grafted pp wax...

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