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Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Prepared for: Aurecon Australasia Pty Ltd and the Australian Government Department of Defence
15 June 2018
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Document History and Status
Report Reference AU/17/ALBR003 Revision C – Final Date 15 June 2018 Previous Revisions A – Draft (6 April 2018)
B – Revised Draft (4 May 2018)
Limitations
Environmental Risk Sciences Pty Ltd has prepared this report for the use of Aurecon Australasia Pty Ltd (Aurecon) and the Australian Government Department of Defence (Defence) in accordance with the usual care and thoroughness of the consulting profession. It is based on generally accepted practices and standards at the time it was prepared. No other warranty, expressed or implied, is made as to the professional advice included in this report.
It is prepared in accordance with the scope of work and for the purpose outlined in the Section 1 of this report.
The methodology adopted and sources of information used are outlined in this report. Environmental Risk Sciences Pty Ltd has made no independent verification of this information beyond the agreed scope of works and assumes no responsibility for any inaccuracies or omissions. No indications were found that information contained in the reports provided for use in this assessment was false.
This report was prepared in March-May 2018, and updated in June 2018, and is based on the information provided and reviewed at that time. Environmental Risk Sciences Pty Ltd disclaims responsibility for any changes that may have occurred after this time.
This report should be read in full. No responsibility is accepted for use of any part of this report in any other context or for any other purpose or by third parties. This report does not purport to give legal advice. Legal advice can only be given by qualified legal practitioners.
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Table of Contents Section 1. Background ............................................................................................................... 1
1.1 Introduction ......................................................................................................................... 1 1.2 Objectives ........................................................................................................................... 2 1.3 Methodology ....................................................................................................................... 2 1.4 Available Information .......................................................................................................... 4
Section 2. Site Description and CSM ......................................................................................... 5 2.1 General ............................................................................................................................... 5 2.2 Site Location ....................................................................................................................... 5 2.3 Surface Water ..................................................................................................................... 5
2.3.1 Shoalhaven River ........................................................................................................ 5 2.3.2 Currambene Creek ...................................................................................................... 5 2.3.3 Recreational Fishing Activities ..................................................................................... 6
2.4 Use of Groundwater and Surface Water, Off-Base ............................................................. 8 2.5 Lowland Rainforest Community .......................................................................................... 8 2.6 Available Data .................................................................................................................... 9
2.6.1 Shoalhaven River and Currambene Creek .................................................................. 9 2.6.2 Lowland Rainforest .................................................................................................... 11 2.6.3 Quality and Completeness of Available Data ............................................................. 11
2.7 Conceptual Site Model (CSM) .......................................................................................... 11 Section 3. Issue Identification – Human Health....................................................................... 13
3.1 General ............................................................................................................................. 13 3.2 Receptors and Exposure Pathways .................................................................................. 13 3.3 Review of Sediment Data ................................................................................................. 15 3.4 Review of Surface Water Data .......................................................................................... 16 3.5 Review of Biota Data from Aurecon (2018) ....................................................................... 18 3.6 Review of Biota Data from NSW DPI ................................................................................ 21 3.7 Comparative Review of Investigation Data for PFOS ........................................................ 23
Section 4. Assessment of Human Health Risks ...................................................................... 26 4.1 Approach to Quantifying Risks to Human Health .............................................................. 26 4.2 Consumption of Fish and Crustaceans ............................................................................. 28
4.2.1 General...................................................................................................................... 28 4.2.2 Shoalhaven River ...................................................................................................... 29 4.2.3 Currambene Creek .................................................................................................... 31
4.3 Consideration of Multiple Exposures ................................................................................. 34 4.4 Uncertainties..................................................................................................................... 37
4.4.1 Fishing Patterns ......................................................................................................... 37 4.4.2 Biota Sampling .......................................................................................................... 37 4.4.3 Presence of Other PFAS ........................................................................................... 38
Section 5. Screening Ecological Risk Assessment ................................................................ 41 5.1 General ............................................................................................................................. 41 5.2 Lowland Rainforest ........................................................................................................... 41 5.3 Aquatic Environments ....................................................................................................... 44
Section 6. Conclusions ............................................................................................................. 47 6.1 General ............................................................................................................................. 47 6.2 Summary of Findings ........................................................................................................ 47
Section 7. References ............................................................................................................... 49
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Figures: Figure 1 HHERA Addendum biota sampling locations Figure 2 HHERA Addendum lowland rainforest sampling locations Appendices: Appendix A Summary of Data from Aurecon (2018) Appendix B Aurecon Report: Human Health and Ecological Risk Assessment Addendum – Field
Investigation Appendix C NSW DPI Zoning Map for Currambene Creek Appendix D Risk Calculations: Consumption of Fish and Crustaceans Appendix E Shoalhaven River Biota Data from NSW DPI
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Glossary of Terms
Additive Effect An additive effect is where two or more substances act together to produce a total effect that is the same as the sum of the individual effects
Adverse Health Effect
A change in body function or cell structure that might lead to disease or health problems
AFFF Aqueous Film Forming Foams ANZECC Australia and New Zealand Environment and Conservation Council ASC NEPM National Environmental Protection Measure – Assessment of Site Contamination ASLP Australian Standard Leaching Procedure AT Averaging Time Background Level
An average or expected amount of a substance or material in a specific environment, or typical amounts of substances that occur naturally in an environment.
BW Body weight Dermal Contact Contact with (touching) the skin (see route of exposure). Detection Limit The lowest concentration of a chemical that can reliably be distinguished from a zero
concentration. Dose The amount of a substance to which a person is exposed over some time period. Dose
is a measurement of exposure. Dose is often expressed as milligram (amount) per kilogram (a measure of body weight) per day (a measure of time) when people eat or drink contaminated water, food, or soil. In general, the greater the dose, the greater the likelihood of an effect. An “exposure dose” is how much of a substance is encountered in the environment. An “absorbed dose” is the amount of a substance that actually got into the body through the eyes, skin, stomach, intestines, or lungs.
ED Exposure Duration EF Exposure Frequency EFSA European Food Safety Authority ET Exposure time Exposure Contact with a substance by swallowing, breathing, or touching the skin or eyes.
Exposure may be short-term (acute exposure), of intermediate duration, or long-term (chronic exposure).
Exposure Assessment
The process of finding out how people come into contact with a hazardous substance, how often and for how long they are in contact with the substance, and how much of the substance they are in contact with.
Exposure Pathway
The route a substance takes from its source (where it began) to its end point (where it ends), and how people can come into contact with (or get exposed to) it. An exposure pathway has five parts: a source of contamination (such as chemical leakage into the subsurface); an environmental media and transport mechanism (such as movement through groundwater); a point of exposure (such as a private well); a route of exposure (eating, drinking, breathing, or touching), and a receptor population (people potentially or actually exposed). When all five parts are present, the exposure pathway is termed a completed exposure pathway.
FSANZ Food Standards Australia New Zealand
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Guideline Value Guideline value is a concentration in soil, sediment, water, biota or air (established by relevant regulatory authorities such as the National Health and Medical Research Council (NHMRC), Australia and New Zealand Environment and Conservation Council (ANZECC) and World Health Organisation (WHO)), that is used to identify conditions below which no adverse effects, nuisance or indirect health effects are expected. The derivation of a guideline value utilises relevant studies on animals or humans and relevant factors to account for inter- and intra-species variations and uncertainty factors. Separate guidelines may be identified for protection of human health and the environment. Dependent on the source, guidelines will have different names, such as investigation level, trigger value, ambient guideline etc.
HHERA Human Health and Ecological Risk Assessment HI Hazard Index Ingestion The act of swallowing something through eating, drinking, or mouthing objects. A
hazardous substance can enter the body this way (see route of exposure). Inhalation The act of breathing. A hazardous substance can enter the body this way (see route of
exposure). LOR Limit of Reporting NEPC National Environment Protection Council NEPM National Environment Protection Measure NHMRC National Health and Medical Research Council NSW DPI New South Wales Department of Primary Industries NSW EPA New South Wales Environment Protection Authority PFAS Per- or Poly-fluoroalkyl Substances PFHxS Perfluorohexanesulfonic Acid PFHpS Perfluoroheptanesufonic Acid PFOA Perfluorooctanoic Acid PFOS Perfluorooctanesulfonic Acid PFNA Perfluorononanoic Acid FOSA Perfluorooctane sulfonamide N-MeFOSE N-methyl-perfluorooctane sulfonamidoethanol Population A group or number of people living within a specified area or sharing similar
characteristics (such as occupation or age). Receptor Population
People who could come into contact with hazardous substances (see exposure pathway).
QA/QC Quality Assurance/Quality Control Risk The probability that something will cause injury or harm. RME Reasonable maximum exposure: The RME represents exposure scenario based on a
set of exposure parameters that is representative of expected maximum exposure for that receptor and activity. The RME would not be expected to be exceeded except under highly specific and exceptional circumstances.
Route of Exposure
The way people come into contact with a hazardous substance. Three routes of exposure are breathing [inhalation], eating or drinking [ingestion], or contact with the skin (dermal contact)
Toxicity The degree of danger posed by a substance to human, animal or plant life. Toxicology The study of the harmful effects of substances on humans or animals. TRV Toxicity Reference Value, e.g. an RfD, ADI, TDI, or PTWI. A guideline toxicity value
that incorporates uncertainty or safety factors to identify a safe dose assuming daily lifetime exposure to a substance that is unlikely to cause harm in humans.
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Uncertainty Factor
Mathematical adjustments for reasons of safety when knowledge is incomplete. For example, factors used in the calculation of doses that are not harmful (adverse) to people. These factors are applied to the lowest-observed-adverse-effect-level (LOAEL) or the no-observed-adverse-effect-level (NOAEL) to derive a minimal risk level (MRL). Uncertainty factors are used to account for variations in people's sensitivity, for differences between animals and humans, and for differences between a LOAEL and a NOAEL. Scientists use uncertainty factors when they have some, but not all, the information from animal or human studies to decide whether an exposure will cause harm to people (also sometimes called a safety factor).
USEPA United States Environmental Protection Agency
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross ES-1 | P a g e Ref: AU/18/ALBR003-C
Executive Summary
Introduction Environmental Risk Sciences Pty Ltd (enRiskS) has been engaged by Aurecon Australasia Pty Ltd (Aurecon), on behalf of the Australian Government Department of Defence (Defence), to review available data and prepare a human health and ecological risk assessment (HHERA) Addendum in relation to the presence of per- and polyfluoroalkyl substances (PFAS) located at, and in the vicinity of, HMAS Albatross (0026), Nowra, NSW (the “base”; refer to Figure 1 for the HMAS Albatross site boundary).
Investigations conducted by Aurecon have detected concentrations of some PFAS compounds in the environment at, and downgradient of, the base. PFAS are a family of fluorine-containing compounds with unique properties to make materials stain- and stick-resistant. PFAS are often described as being “ubiquitous in the environment”. They have been widely used in man-made products such as paints, roof treatments, hardwood floor protectant, surface protection products (e.g. carpet and clothing treatments) and coatings for cardboard and packaging. Some PFAS are or were also historically used in fire-fighting foams (also called Aqueous Film Forming Foams or AFFF). PFAS are not found in the environment from natural sources, only from anthropogenic sources (ATSDR 2015).
In November 2017, enRiskS prepared a HHERA for the base and surrounding area which is outlined in the following report:
enRiskS (2017), DEHP-ID-183-D1 Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross, 10 November 2017.
The HHERA identified several areas where there was the potential for exposures to PFAS to be elevated and further assessment was required to better understand human health and ecological risks.
For the on-base area, this was limited to ecological receptors within the Lowland Rainforest, where the potential for bioaccumulative effects on the terrestrial environment could not be excluded. No direct toxicity effects to the terrestrial environment were identified in this area.
For the off-base area, the HHERA identified that risks associated with the consumption of fish caught from the Shoalhaven River were low and acceptable (based on the limited data collected). However, it was identified that there was the potential for elevated exposures from fish intakes from Currambene Creek. The collection of additional data was recommended to better inform the risk assessment. It was also identified that there was the potential for adverse effects to the environment of the Shoalhaven River and Currambene Creek following bioaccumulation and intakes by higher order consumers.
It is acknowledged that there are known to be other sources of PFAS to the environment downgradient of the base, especially to the Shoalhaven River. The known sources include sewage treatment plant outfalls, industrial activities and rural fire brigade sites.
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross ES-2 | P a g e Ref: AU/18/ALBR003-C
Additional data has now been collected by Aurecon (2018) and this HHERA Addendum provides a further evaluation of the specific human health and ecological risk issues outlined above.
This HHERA Addendum should be read in conjunction with enRiskS (2017); it is not written to be read as a standalone report.
Objectives The objectives of the assessment presented in this report are:
To undertake a further quantitative evaluation of the potential risks to human health following the consumption of fish and crustaceans (“biota”) from the Shoalhaven River or Currambene Creek;
To undertake a further qualitative evaluation of the potential bioaccumulation risks to terrestrial ecological receptors within Lowland Rainforest areas on base; and
To undertake a further qualitative evaluation of the potential risks to aquatic (freshwater and marine if applicable) ecological receptors within the Shoalhaven River and Currambene Creek.
This assessment has been undertaken to evaluate potential risks to human health and the environment based on the information available up to 23 March 2018 and as described in Section 1.4. The HHERA has addressed human health and environmental risk issues relevant to PFAS in the investigated environmental media (including food products), and as arising from the use and storage of AFFF at HMAS Albatross. The assessment has not addressed human health or environmental risk issues associated with other chemicals.
This report is an addendum to the HHERA (enRiskS 2017) and as such only addresses risk issues relevant to the additional data collected. Refer to the HHERA for assessment of other risk issues on- and off-base.
The HHERA Addendum has considered risks to recreational fishers following the consumption of biota from the Shoalhaven River and Currambene Creek. Risks to commercial fishers and the public following sale of biota into the market have not been considered further as the NSW Government has indicated that any biota with PFAS from the site will be diluted sufficiently in the market so as not to be of further concern.
enRiskS acknowledges the assistance of the Aurecon Ecology team in preparing the ERA components of this HHERA Addendum.
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Conclusions Table E1 provides an overview of the ways in which the assessed receptors (including members of the community and the terrestrial and aquatic environments) may be exposed to PFAS, derived from the HMAS Albatross Base and the conclusions relevant to these areas.
Table E1: Conclusions of HHERA Addendum
How the community may be exposed?
Potential risks to health or the environment
Area where potential risk issues identified
Human health – Off-base Recreational exposures, Shoalhaven River and Currambene Creek Direct contact with PFAS in sediments
Low and acceptable. NA
Recreational use of surface water Low and acceptable NA Consumption of fish caught from local waterways
The available data indicates the potential for elevated exposures from fish and crustacean intakes.
All areas, however the highest impacts are present at SR-B2 and CC-B2.
Residential exposures Use of surface water for stock watering and irrigation
Low and acceptable. Shoalhaven River* and Currambene Creek*
Environment – On-base Terrestrial Environment of the Lowland Rainforest Direct toxicity No risk issues identified NA Bioaccumulation and effects on higher order consumers
The available data indicates the potential for elevated exposures to any resident populations of small insectivorous mammals within two areas of the Lowland Rainforest.
Yerriyong Gully, Northern End (HA89 to HA91) and Currambene Creek (HA86 to HA88)
Environment – Off-base Aquatic Environment of the Shoalhaven River* and Currambene Creek* Direct toxicity The available data does not suggest
the potential for significant effects due to direct toxicity.
NA
Bioaccumulation and higher order consumers
The potential for adverse effects to the environment cannot be excluded.
All areas, however the highest impacts are present at SR-B2 and CC-B2.
* The Shoalhaven River and Currambene Creek areas referenced in this table is limited to the waterways where sampling was undertaken, and the extent of sampling within these waterways.
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Section 1. Background 1.1 Introduction Environmental Risk Sciences Pty Ltd (enRiskS) has been engaged by Aurecon Australasia Pty Ltd (Aurecon), on behalf of the Australian Government Department of Defence (Defence), to review available data and prepare a human health and ecological risk assessment (HHERA) Addendum in relation to the presence of per- and polyfluoroalkyl substances (PFAS) located at, and in the vicinity of, HMAS Albatross (0026), Nowra, NSW (the “base”; refer to Figure 1 for the HMAS Albatross site boundary).
Investigations conducted by Aurecon have detected concentrations of some PFAS compounds in the environment at, and downgradient of, the base. PFAS are a family of fluorine-containing compounds with unique properties to make materials stain- and stick-resistant. PFAS are often described as being “ubiquitous in the environment”. They have been widely used in man-made products such as paints, roof treatments, hardwood floor protectant, surface protection products (e.g. carpet and clothing treatments) and coatings for cardboard and packaging. Some PFAS are or were also historically used in fire-fighting foams (also called Aqueous Film Forming Foams or AFFF). PFAS are not found in the environment from natural sources, only from anthropogenic sources (ATSDR 2015).
In November 2017, enRiskS prepared a HHERA for the base and surrounding area which is outlined in the following report:
enRiskS (2017), DEHP-ID-183-D1 Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross, 10 November 2017.
The HHERA identified several areas where there was the potential for exposures to PFAS to be elevated and further assessment was required to better understand human health and ecological risks.
For the on-base area, this was limited to ecological receptors within the Lowland Rainforest, where the potential for bioaccumulative effects on the terrestrial environment could not be excluded. No direct toxicity effects to the terrestrial environment were identified in this area.
For the off-base area, the HHERA identified that risks associated with the consumption of fish caught from the Shoalhaven River were low and acceptable (based on the limited data collected). However, it was identified that there was the potential for elevated exposures from fish intakes from Currambene Creek. The collection of additional data was recommended to better inform the risk assessment. It was also identified that there was the potential for adverse effects to the environment of the Shoalhaven River and Currambene Creek following bioaccumulation and intakes by higher order consumers.
It is acknowledged that there are known to be other sources of PFAS to the environment downgradient of the base, especially to the Shoalhaven River. The known sources include sewage treatment plant outfalls, industrial activities and rural fire brigade sites.
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Additional data has now been collected by Aurecon (2018) and this HHERA Addendum provides a further evaluation of the specific human health and ecological risk issues outlined above.
This HHERA Addendum should be read in conjunction with enRiskS (2017); it is not written to be read as a standalone report.
1.2 Objectives The objectives of the assessment presented in this report are:
To undertake a further quantitative evaluation of the potential risks to human health following the consumption of fish and crustaceans (“biota”) from the Shoalhaven River or Currambene Creek;
To undertake a further qualitative evaluation of the potential bioaccumulation risks to terrestrial ecological receptors within Lowland Rainforest areas on base; and
To undertake a further qualitative evaluation of the potential risks to aquatic (freshwater and marine if applicable) ecological receptors within the Shoalhaven River and Currambene Creek.
This assessment has been undertaken to evaluate potential risks to human health and the environment based on the information available up to 23 March 2018 and as described in Section 1.4. The HHERA has addressed human health and environmental risk issues relevant to PFAS in the investigated environmental media (including food products), and as arising from the use and storage of AFFF at HMAS Albatross. The assessment has not addressed human health or environmental risk issues associated with other chemicals.
This report is an addendum to the HHERA (enRiskS 2017) and as such only addresses risk issues relevant to the additional data collected. Refer to the HHERA for assessment of other risk issues on- and off-base.
The HHERA Addendum has considered risks to recreational fishers following the consumption of biota from the Shoalhaven River and Currambene Creek. Risks to commercial fishers and the public following sale of biota into the market have not been considered further as the NSW Government has indicated that any biota with PFAS from the site will be diluted sufficiently in the market so as not to be of further concern.
enRiskS acknowledges the assistance of the Aurecon Ecology team in preparing the ERA components of this HHERA Addendum.
1.3 Methodology In general, the approach taken for the assessment of human health and environmental risks is in accordance with guidelines/protocols endorsed by Australian regulators, including:
National Environmental Protection Measure – Assessment of Site Contamination (ASC NEPM) including: Schedule B1 Investigation Levels for Soil and Groundwater (NEPC 1999 amended
2013a)
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Schedule B4 Guideline on Health Risk Assessment Methodology (NEPC 1999 amended 2013c)
Schedule B6 Guideline on Risk Based Assessment of Groundwater Contamination (NEPC 1999 amended 2013e)
Schedule B7 Guideline on Health-Based Investigation Levels (NEPC 1999 amended 2013d)
enHealth Environmental Health Risk Assessment, Guidelines for Assessing Human Health Risks from Environmental Hazards (enHealth 2012a);
enHealth Australian Exposure Factor Guide (enHealth 2012b); and Australian and New Zealand Guidelines for Fresh and Marine Water Quality
(ANZECC/ARMCANZ 2000).
Additional guidance has been sought from international sources, and referenced within this document where relevant, however international guidance has not been adopted where it is inconsistent with the Australian regulatory or policy setting. The overall approach for the HHERA is outlined in the following (modified from enHealth 2012):
Issue Identification• Review the available site information• Review information on the nature and extent of
contamination• Develop a preliminary Conceptual Site Model (CSM)• Identify the Contaminants of Potential Concern (CoPC)
that require detailed evaluation• Identify and discuss uncertainties with CSM
Exposure Assessment• Identify and evaluate exposure populations
(human health and ecological) and exposure pathways
• Characterise exposure using available site data and assumptions relevant to the CSM
• Identify and discuss uncertainties
Hazard/Toxicity Assessment• Review health effects and dose-response
characteristics associated with exposure to the CoPC
• Identify appropriate toxicity reference values (TRVs) and ecological guidelines to be used to quantify effects associated with exposure
• Identify and discuss uncertainties
Risk Characterisation• Combine the evaluation of exposure and hazard/toxicity to
characterise risks to human health and the environment• Evaluate uncertainties relevant to the assessment and if
these may change the outcome of the risk assessment• Present conclusions
Risk Management• Identify options for risk management.• Determine if options adequately protective of health and
the environment• Consider economic, social and political aspects• Make informed decisions• Take actions to implement decisions• Monitor and evaluate the effectiveness of the decisions
Review and reality check, refine CSM
Review and reality check, refine CSM
Risk communication
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More specifically, the following PFAS-specific guidance has been considered in the HHERA:
PFAS National Environmental Management Plan (the “PFAS NEMP”), January 2018 (HEPA 2018); and
Food Standards Australia New Zealand (FSANZ) guideline Perfluorinated Chemicals in food (FSANZ 2017a), and associated supporting documents: Supporting Document 1 Hazard assessment report – Perfluorooctane sulfonate
(PFOS), Perfluorooctanoic acid (PFOA), Perfluorohexane sulfonate (PFHxS) (FSANZ 2017b) Critical review of pharmacokinetic modelling of PFOS and PFOA to assist in
establishing HBGVs for these chemicals (FSANZ 2017c) Immunomodulation by PFASs: a brief literature review (ToxConsult 2017)
Supporting Document 2 Assessment of potential dietary exposure to PFOS, PFOA and PFHxS occurring in foods sampled from contaminated sites (FSANZ 2017d) Occurrence of and dietary exposure to PFOS, PFOA and PFHxS reported in
the literature (FSANZ 2017e) Occurrence of PFOS, PFOA and PFHxS in foods and water sampled from
contaminated sites (FSANZ 2017f) Supporting Document 3 Summary of other controls for perfluorinated chemicals
(FSANZ 2017g); and Supporting Document 4 Criteria for the establishment of maximum levels in food
(FSANZ 2017h).
The overall approach adopted in this assessment is as follows:
Review of the Conceptual Site Model (CSM) for PFAS in environmental media on- and off-base, as relevant to the additional assessment of health and ecological risks (Sections 2 and 3);
Quantification of likely exposures by human receptors to PFAS off-base and the characterisation of human health risks (Section 4);
Qualitative (screening) ecological risk evaluation for the on- and off-base area (Section 5); and
Conclusions (Section 6).
1.4 Available Information This assessment has been conducted based on information and data presented in the following report:
Aurecon (2018), Investigation of per- and poly-fluoroalkyl substances at HMAS Albatross, Human Health and Ecological Risk Assessment Addendum – Field Investigation, 22 March 2018.
The relevant data is provided in Appendix A. A copy of Aurecon (2018) is provided in Appendix B. This information has been relied on for assessing human health and environmental risk issues.
No additional groundwater data was collected by Aurecon (2018), hence this assessment does not consider groundwater.
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Section 2. Site Description and CSM 2.1 General A full description of the site and CSM is provided in enRiskS (2017). The relevant details are summarised below for context. Additional information is also available in relation to fishing activities within the Shoalhaven River and Currambene Creek and this information is summarised. All information has been sourced from Aurecon (2018) unless otherwise indicated.
2.2 Site Location HMAS Albatross (the “base”) is located approximately 170 km south of Sydney and approximately 6 km south-west of Nowra in New South Wales. Owned by the Commonwealth of Australia, the base is a significant establishment for operational, training, engineering, administrative and logistic support for naval air squadrons. The base is bounded by Albatross Road to the north and Braidwood Road to the north and west, with access from the north via Albatross or BTU Road. The southern part of the base can be accessed via an unsealed road off Braidwood or Parma Road. The Princess Highway, which connects Nowra to Sydney, is located to the east of the site.
Land surrounding the base is generally zoned as ‘Rural Landscape’ with the Albatross Aviation and Technology Park zoned as ‘Business Park’, and the surrounding roads and some vegetated areas to the west zoned as ‘Infrastructure’.
2.3 Surface Water Surface water runoff from the site is released into the Shoalhaven River or Currambene Creek. These river systems are described below.
2.3.1 Shoalhaven River
The Shoalhaven River i receives surface water runoff from the northern and western portions of the base via Calymea Creek, Cabbage Tree Creek or Flat Rock Creek. Surface water from the northwest portion of the base also discharges to an unnamed tributary of Calymea Creek, named Braidwood Road drain for the purposes of this investigation. Calymea Creek discharges into the Shoalhaven River at surface water sampling location W01/SR-B2 (refer to Figure 1).
2.3.2 Currambene Creek
Currambene Creek receives surface water run-off from the southern and eastern portions of the site. The majority of this surface water is directed in surface drainage lines to discharge into the base’s sewage treatment plant (STP). In addition, Currambene Creek and two other freshwater creeks (Yerriyong Gully and Parma Creek) traverse the southern and eastern portion of the site. Yerriyong Gully and Parma Creek flow along the southern boundary of the site and drain into Currambene Creek at the Princes Highway. Currambene Creek then flows into Jervis Bay at Huskisson, located over 14 km to the east and south of the site. Currambene Creek (and its two major tributaries - Yerriyong Gully and Parma Creek) has been identified to be a primary migration pathway for PFAS from the base.
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2.3.3 Recreational Fishing Activities
Shoalhaven River The Shoalhaven River supports a large population of commercial fishers that produce seafood for domestic and export markets. The main biota species targeted within the Shoalhaven River include:
Bream; Dusky flathead; Luderick; Sea mullet; Sand whiting; Silver biddy; Yellowfin bream; School prawn; and Mud crab.
As indicated in Section 1.2, this HHERA Addendum has not considered risks following commercial fishing. However, it is assumed that the biota species targeted by commercial fishers would also be targeted by recreational fishers. Other primary industries in the Shoalhaven River include oyster growing and vegetable farming. The river also supports a tourism industry with activities including recreational fishing, surfing and boating.
A report is available outlining the findings of a 12-month field survey undertaken to investigate recreational fishing activities in the Shoalhaven River (Miles 2011). The study was undertaken between June 2009 and May 2010, and the main findings relevant to the HHERA Addendum are as follows:
2,203 individual fishers were interviewed. Most of the interviews were conducted on the weekend;
A total of 3,056 fishers were recorded during effort counts. It is not known how many of these fishers were repeat fishers;
The total fishing effort was approximately 212,500 hours. This is around 70 hours per fisher assuming there are no repeat fishers: If it is assumed that someone goes fishing for around 4 to 5 hours each occasion,
this equates to approximately 15 fishing trips per year If it is assumed that someone goes fishing for around 2-3 hours, this equates to
approximately 30 fishing trips per year
For repeat fishers, the number of fishing trips per year is unknown.
Approximately half of the study participants were visitors from other regions (with 65% of these people visiting the region specifically to go fishing):
The total catch was in estimated to be 59,952 fish of which around 31% were Bream, 22% were Flathead and 17% were Luderick;
Only 11.7% of fishers were catch and release fishing; Around 85% of fishers were recorded to be fishing from boats with shore fishing comprising
most of the remainder; and
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Most fishers interviewed (33.7%) reported that they were not specifically targeting a particular species (i.e. they were targeting anything). When fishers indicated they were targeting a species, the most popular were Flathead (31.3%), Bream (23.6%) and Luderick (4.2%). The remaining fishers were targeting Jewfish (2.3%), Whiting (1.2%), Tailor (1.1%), Leatherjacket (0.9%) and Estuary Perch (0.5%). The main flathead species targeted was Dusky Flathead.
Currambene Creek Several areas of Currambene Creek are zoned for protection by NSW DPI. An extract of the relevant section of the Zoning Map is shown below. The full map is provided in Appendix C.
The majority of upper Currambene Creek east of Princes Highway is a Sanctuary Zone and fishing is prohibited (although recreational boating is allowed). Downstream of the Sanctuary Zone, Currambene Creek is classed as a Habitat Protection Zone and recreational fishing and boating is allowed. Recreational fishing in the Habitat Protection Zone is known to target Yellowfin Bream, Dusky Flathead, Luderick, crabs and Garfish.
Commercial fishing in Currambene Creek is minimal. Commercial fishing is prohibited in the Sanctuary Zone, and limited activities are allowed in the Habitat Protection Zone (e.g. garfishing, line fishing and hand gathering).
Currambene Creek flows into Jervis Bay at Huskisson, which is a Marine Park managed by the NSW DPI. The marine area at Huskisson is used for activities, including fishing, boating, scuba diving, snorkelling and some commercial fishing. In Jervis Bay, outside the Marine Park Sanctuary Zones, both commercial and recreational fishing occurs:
Recreational fishing in Jervis Bay is estimated to catch approximately 21 tonnes per year, targeting Blue and Slimy Mackerel (as bait fish and for human consumption), Dusky Flathead, Sand Whiting, Sand Flathead, Squid, Rock Lobster, Yellowfin Bream, Snapper, Yellowtail Kingfish and Eastern Australian Salmon; and
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Species targeted for commercial fishing in Jervis Bay include Sand Whiting, Yellowtail Scad, Striped Grunter, Yellowfin Bream, Common Silver Biddy, Tailor, Longfin Pike, Blue Mackerel, Southern Calamari, Gummy Shark, Snapper, Silver Trevally, Blue Weed-Whiting, Tarwhine, Sole, Australian Salmon, Australian Sardine, Onespot Puller, Mulloway, Sea Mullet, Luderick, Eastern Sea Garfish, Eastern School Whiting, Sweep and Sandy Sprat (Whitebait). Commercial catch from ocean hauling, including Jervis Bay, varies from several hundred to over 25,000 kg.
2.4 Use of Groundwater and Surface Water, Off-Base During the preparation of enRiskS (2017) it was identified that property types in the off-base area included private residence and agriculture. Some of these properties were identified to be using surface water (dam water) for agricultural purposes e.g. stock watering and irrigation. No properties were identified to be extracting and using river water.
The data used in this HHERA Addendum has been collected from further downstream of the investigation area assessed in enRiskS (2017) and there is no further information available in to confirm if water from the Shoalhaven River or Currambene Creek is extracted and used. For the purpose of this HHERA Addendum it has been assumed that river water may be extracted and used for stock watering or irrigation.
Further discussion is provided in Section 4.3.
2.5 Lowland Rainforest Community Four areas of Lowland Rainforest were identified in the south-eastern corner of the base in 2006 by SKM. The key characteristics of this ecological community include (Aurecon 2018):
Distribution within the South Eastern Queensland bioregions and the NSW North Coast and Sydney bioregions;
Soil derived from basalt or alluvium; Altitude of less than 300 m above sea level; Areas of high annual rainfall (>1,300 mm); More than 2 km inland from the coast; Structure of the ecological community is typically a tall (20 to 30 m) closed forest, often with
multiple canopy layers; and Patches of the ecological community typically have high species richness.
Aurecon (2018) also indicates that the Lowland Rainforest at the base has yet to be listed as an endangered ecological community. Regardless, further assessment of the Lowland Rainforest has been undertaken in this HHERA Addendum for completeness.
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2.6 Available Data
2.6.1 Shoalhaven River and Currambene Creek
Sampling for fish and crustaceans (referred to as “biota” in this assessment) was undertaken by Aurecon (2018) at a total of six locations – three on each of the Shoalhaven River and Currambene Creek. The locations were as follows (refer to Figure 1):
Shoalhaven River: Approximately 7 km upstream of Calymea Creek and Shoalhaven River confluence,
closer to Burrier, but still in the intertidal zone (location SR-B1). This location is considered a background location for the sediment and surface water sampling, but is not a background location for the biota sampling as some of the fish species identified (e.g. Bass and Mullet) will easily swim distances more than 7 km
Confluence of Calymea Creek and Shoalhaven River (location W01/SR-B2) Approximately 7 km downstream of confluence of Calymea Creek and Shoalhaven
River, closer to Watersleigh (location SR-B3) Currambene Creek:
Existing water/sediment location W04, which is just downstream of the Sanctuary Zone to the east of Princess Highway
Approximately 5.7 km from the mouth of Currambene Creek (location W06/CC-B2) Approximately 2.2 km from the mouth of Currambene Creek, at the oxbow
adjacent/south of Woollamia (sample CC-B3)
Historical surface water and sediment data is also available for location W05 which is located between W04 and W06 on Currambene Creek (enRiskS 2017). This is a total of 3 sampling locations on the Shoalhaven River and 4 sampling locations on Currambene Creek.
A number of biota species were targeted as identified based on advice provided by the NSW Department of Primary Industries (DPI) and NSW Environment Protection Authority (EPA). Samples were collected using mesh nets and baited traps. Twelve species were able to be caught from each of the Shoalhaven River and Currambene Creek, with some variability in species caught between creeks:
Bream, Eastern Sea Garfish, Estuary Perch, Luderick, Mud Crab and Sea Mullet were caught in both waterways;
Australian Bass, Dusky Flathead, Herring, Sand Mullet, Tiger Mullet and Tailor were only caught in the Shoalhaven River; and
Black Sole, Blue Swimmer Crab, Freshwater Prawn, Mulloway, Sand Whiting and Silver Trevally were only caught in Currambene Creek.
Scientific names for the biota species are provided in Aurecon (2018) (Appendix B).
Currambene Creek samples were collected on 30 January 2018 and 4 to 7 February 2018. Shoalhaven River samples were collected on 8 to 10 February 2018. A surface water and sediment sample were also collected from each biota sampling location. Collected biota samples were generally analysed as 2 to 5-part composites of fillets with the skin on (i.e. portions likely to be consumed by humans) unless caught species were too small to fillet or there was insufficient
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sample for compositing. All samples were analysed for an extended PFAS suite. One duplicate and one triplicate soil sample was analysed, and 2 triplicate biota samples were analysed. The primary laboratory was Eurofins and the secondary laboratory was the Australian Government National Measurement Institute (NMI).
A summary of species targeted and caught at each sample location is provided in Table 2.1. Sampling locations are shown on Figure 1.
Table 2.1: Summary of Biota Species Targeted and Caught by Aurecon
Species Shoalhaven River Currambene Creek (SR-B1, SR-B2 and SR-B3) Upper (W-04) Mid to Lower
(CC-B2 and CC-B3) Targeted Caught1 Targeted Caught1 Targeted Caught1
Australian Bass (4) -- -- -- Black Sole -- -- -- -- -- (1)2 Blue Mackerel -- -- -- -- -- Blue Swimmer Crab -- -- -- -- -- (2)2 Bream (2)7 (1) -- (7)6 Common Yabby -- -- -- -- -- Dusky Flathead (1)3 -- -- -- Eastern Sea Garfish -- (1)2 (2) -- -- Eel -- -- -- -- -- Estuary Perch -- (3)4 -- -- -- (5) Freshwater Prawn -- -- -- -- -- (1)8 Herring -- (1)2 -- -- -- -- Luderick (1)3 -- -- (8) Mud Crab (2)2 -- -- (1)2 Mulloway -- -- -- -- (2) Rock Lobster -- -- -- -- -- Salmon -- -- -- -- -- Sand Flathead -- -- -- -- -- Sand Whiting -- -- -- (5) Sand Mullet -- (1)3 -- -- -- -- Sea Mullet (10) -- (2) (6) School Prawn -- -- -- -- -- Silver Biddy -- -- -- -- Silver Trevally -- -- -- -- -- (6)5 Snapper -- -- -- -- -- Squid -- -- -- -- -- Tailor -- (1)3 -- -- -- -- Tiger Mullet -- (5) -- -- -- -- Yellowtail Kingfish -- -- -- -- --
Notes: Refer to Appendix A and B for further details “” = Indicates biota targeted or caught. ‘--’ = Indicates biota not specifically targeted or no biota caught. Shading shows biota samples that were caught. 1 = Number of samples analysed indicated in parenthesis. Samples are composites of 2-5 fillets unless otherwise
indicated. 2 = Whole sample analysed. 3 = Individual fillet analysed. 4 = 1x1-part composite, 1x3-part composite and 1 individual fillet analysed. 5 = 3x5-part composite and 3 individual fillets analysed. 6 = 1x2-part composite, 2x3-part composite, 3x5-part composite and 1 individual fillet analysed. 7 = 1x2-part composite and 1 individual fillet analysed. 8 = 1 sample of 3 prawns.
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2.6.2 Lowland Rainforest
A total of 8 soil sampling locations were excavated within the 4 distinct areas of the Lowland Rainforest by Aurecon (2018) on 31 January 2018. The locations were as follows:
Southern end of the base: HA95 to HA97; Around Yerriyong Gully: HA92 to HA94 (Southern Area) and HA89 to HA91 (Northern Area);
and Around Currambene Creek: HA86 to HA88.
Soil samples were collected at 0.1 m and 0.5 m depth from each bore except for HA94 and HA95 where shallow bedrock was encountered at 0.2 m depth. Collected samples were analysed for an extended PFAS suite and for Australian Standard Leaching Procedure (ASLP) PFAS at neutral pH. ASLP is a leachate test that is relevant to understanding how PFAS in soil may leach under environmental condition e.g. following rainfall. The primary laboratory was Eurofins and the secondary laboratory was the NMI.
2.6.3 Quality and Completeness of Available Data
Aurecon (2018) provides a review of the Quality Assurance/Quality Control (QA/QC) produces adopted for the assessment and concluded that the quality of the analytical data is acceptable for interpretative use. A summary of the results for the primary and triplicate biota samples is provided in Table 2.2.
Table 2.2: Summary of Primary, Duplicate and Triplicate Sample Results
Sample ID PFOS in Biota (µg/kg ww) Primary Sample Triplicate Sample
SR-B1_MULLET1_180202 and QA101_180208 2.1 1.6 SR-B1_BASS1_180208 and QA102_180208 5.5 3.2
Notes: Refer to Appendix A and B for further details NA = Indicates not applicable ww = Indicates wet weight
Review of Table 2.2 indicates concentrations of PFOS were reported in the primary samples are 30 to 70% higher than those reported in the triplicate samples. The primary sample results have been adopted for this assessment.
2.7 Conceptual Site Model (CSM) The CSM presented in enRiskS (2017) (as compiled by Aurecon during the conduct of the Detailed Site Investigation) has been updated to reflect the risk issues being further evaluated in this HHERA Addendum and is presented in Table 2.3. The full CSM is provided in enRiskS (2017).
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Table 2.3: Updated PFAS CSM (Risk Issues Considered in this HHERA Addendum)
Source Pathway Receptor Primary Secondary Migration pathway Exposure route
On-
Site
Hangars, flight lines and associated activities
Former firefighting training areas
STP including irrigation area
PFAS impacted soils
--
Direct contact1 Terrestrial ecosystem of the Lowland Rainforest
Uptake of PFAS in soil by biota and subsequent consumption by higher order predators.
Bioaccumulation
Off-
Site
PFAS impacted surface water and sediment
Overland transport of particulate and dissolved PFAS
Direct contact1
Recreational users of the Shoalhaven River and Currambene Creek Aquatic ecosystem of the Shoalhaven River and Currambene Creek Uptake of PFAS in water and
sediment by biota Bioaccumulation and ingestion of biota
Notes: STP = Sewage Treatment Plant 1 = Unacceptable risks were not identified during enRiskS (2017) however this exposure pathway has been re-reviewed to ensure multiple exposure pathways are adequately
addressed.
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Section 3. Issue Identification – Human Health 3.1 General This purpose of this section of the HHERA Addendum is to review the available surface water, sediment and biota data to identify if the PFAS concentrations reported are sufficiently elevated to require a detailed assessment of risk. The assessment has also considered the existing information relating to the properties and likely fate and transport of PFAS in the environment.
PFAS are a family of man-made fluorine-containing chemicals that do not occur naturally in the environment. The have unique properties that make materials stain- and stick-resistant because the compounds repel oil, grease and water. However, these unique properties also make them persistent in the environment and highly mobile in soil and water.
There are many PFAS compounds however most reviews in the scientific literature, and by the Australian Government, have focused on PFOS, PFOA and PFHxS as these three PFAS are generally considered to be of most concern from an environmental health point of view. This is because of several factors including:
These PFAS are often identified in the highest concentrations in the environment; These PFAS are known to be bioaccumulative (with PFOS usually of most concern from a
bioaccumulation perspective); There is evidence of adverse health effects in experimental studies with animals; and These PFAS have been the focus of the most research historically (with most research
focusing on PFOS and PFOA).
The main exposure pathway for PFAS is the oral (ingestion) pathway (including the ingestion of biota) and this pathway normally drives the evaluation of risk issues. PFAS are not volatile at environmental pH, so the vapour inhalation/vapour intrusion pathway does not require assessment. Although the data is limited, there is also scientific evidence to suggest that the dermal absorption is negligible in comparison to the ingestion pathway.
The review presented here has considered data collected in the Shoalhaven River and Currambene Creek for characterising PFAS risk issues. Where historical data is available from the same sampling locations, the historical data has also been re-reviewed for completeness.
Figure 1 shows the locations of the sediment, surface water and biota data. Appendix A presents data relevant to PFAS reported in biota, surface water and sediment. Further information relating to the toxicity of PFAS is provided in Section 4 and enRiskS (2017).
3.2 Receptors and Exposure Pathways This HHERA Addendum has focused on potential risks to recreational users of the downstream waters of Shoalhaven River and Currambene Creek (at the locations sampled), from concentrations of PFAS in sediment, surface water and biota. In this context, users of the waterways may be exposed to PFAS impacted media during the following activities:
Direct contact with sediment (e.g. during wading in the shallows);
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Direct contact with surface water during swimming (called primary contact recreation) and incidental contact during boating and fishing activities (called secondary contact recreation); and
Home consumption of biota from the waterways.
Residents in properties adjacent to the waterways may also be exposed to PFAS impacted media during the following activities:
Use of surface water for irrigation or stock watering; and Home consumption of edible produce caught, grown or raised with PFAS impacted water.
There is no further information is available at this time in relation to the potential use of surface water from the downstream areas of the Shoalhaven River and Currambene Creek (as sampled by Aurecon 2018) for the above activities. Hence, further quantitative evaluation cannot be undertaken at this time. Further discussion is provided in Section 4.3.
Table 3.1 presents a more detailed overview of the exposure pathways relevant to the assessment of human exposures, as assessed in this HHERA Addendum. The table also outlines the data that is relevant to the assessment of these exposures and outcomes of the screening level assessment undertaken. Text shown in blue indicates that risks have been concluded to be acceptable while text shown in purple indicates that further assessment is required in the HHERA Addendum. Where data is available, this further assessment has been presented in the HHERA.
Table 3.1: Summary of Key Receptors and Exposure Pathways – HHERA Addendum
Exposure Pathway/Mechanism
Potentially Significant Pathway?
Comments Screening Assessment
Recreational Users of Surface Water Bodies Incidental ingestion of PFAS in sediment
Direct contact exposures (incidental ingestion and dermal contact) may occur during recreational use of surface water bodies.
The screening level assessment is presented in Section 3.3. No PFAS concentrations of concern identified in sediments.
Dermal contact with PFAS in sediment1
Incidental ingestion of PFAS in surface water
Direct contact exposures (incidental ingestion and dermal contact) may occur during recreational use of surface water bodies.
The screening level assessment is presented in Section 3.4. No PFAS concentrations of concern identified in surface water.
Dermal contact with PFAS in surface water1
Ingestion of biota Consumption of biota from local waterways may occur.
The screening level assessment is presented in Section 3.5. This assessment has identified the presence of elevated concentrations of PFAS (specifically PFOS) in edible biota in the Shoalhaven River and Currambene Creek. Further assessment of potential exposures is therefore required (refer to Section 4).
Notes for Table 3.1: “” = Exposure pathway is potentially complete 1 = Dermal uptake of PFAS in soil and water is understood to be limited in comparison to the incidental ingestion
pathways however further assessment has been provided in this HHERA Addendum for completeness. Refer to enRiskS (2017) for further information.
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3.3 Review of Sediment Data No PFAS concentrations of concern were identified in off-base sediments during the preparation of enRiskS (2017).
This section of the HHERA Addendum provides a review of the additional sediment data collected by Aurecon (2018). Table 3.2 presents a summary of the sediment concentrations reported in the Shoalhaven River and Currambene Creek (refer to Figure 1 for sample locations). The data has been presented for PFOS + PFHxS and PFOA, the key PFAS compounds where screening level guidelines are available. The screening level guidelines for soil for a public open space (recreational) setting have been adopted (HEPA 2018). Screening level guidelines for soil have been adopted as there are no screening level guidelines for PFAS in sediment. This is consistent with the approach adopted in enRiskS (2017). Exposures to soil and sediment in a recreational setting are expected to be similar hence the adoption of soil guidelines is appropriate.
In addition, the Total PFAS concentration has been reviewed. For the purpose of screening the total PFAS concentration has been compared against the screening level guideline for PFOS + PFHxS. This is conservative as there is some evidence that not all PFAS are as toxic as PFOS and PFOA, but appropriate for a screening level evaluation as if concentrations of Total PFAS are below the screening level guidelines for PFOS + PFHxS and PFOA then it can be concluded that no further evaluation of any detected PFAS is required.
For sediment, the only PFAS detected was PFOS, so the Total PFAS concentration is equal to the PFOS concentration (and the PFOS + PFHxS concentration).
Table 3.2: Summary and Review of PFAS Reported in Sediment: Human Health
Area Investigated Reported Concentration Range (mg/kg) PFOS + PFHxS PFOA Total PFAS
Shoalhaven River Background (SR-B1) ND ND ND Confluence of Calymea Creek and the Shoalhaven River (W012/SR-B2)
ND ND ND
Downstream (SR-B3) ND ND ND Currambene Creek (Locations from Upstream to Downstream) W042 0.011 ND 0.011 W052 ND ND ND CC-B2/W062 ND - 0.021 ND ND - 0.021 CC-B3 0.02 ND 0.02
Adopted screening guidelines1 Public Open Space 1 10 1
Notes: Shading indicates an exceedance of the adopted guideline value. 1 = Ref. HEPA (2018) guideline for public open space. Note that in the absence of guidelines for PFAS other than
PFOS+PFHxS and PFOA, total PFAS concentrations have been screened against the more conservative guidelines for PFOS+PFHxS.
2 = Includes data reported as part of enRiskS (2017). ND = Not detected at the laboratory limits of reporting: 0.005 to 0.0005 mg/kg.
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Review of Table 3.2 indicates the following:
PFAS has not been detected in sediment in the Shoalhaven River; PFOS has been detected in Currambene Creek however there are no concentrations of
PFOS (or any other PFAS) at any location sampled, that exceed the adopted screening guidelines (public open space). Hence there are no human health risk issues of concern for exposures to sediment in Currambene Creek;
Maximum concentrations of PFOS in sediment in Currambene Creek (0.021 mg/kg) are around 50 times below the adopted screening guideline (1 mg/kg). In addition, the adopted screening guideline assumes that 20% of the tolerable daily intake for PFOS comes from sediment (80% of exposure is assumed to come from other pathways). Hence, the adopted screening guideline is adequate to assess potential risks from multiple exposure pathways (if present); and
There is no clear pattern in relation to concentrations of PFOS in sediments in Currambene Creek, concentrations are similar at all locations.
The above assessment does not address potential exposures to PFAS following accumulation in biota, which may then be caught and consumed by users of the waterways. This exposure pathway has been assessed on the basis of the biota data collected, as presented in Section 3.5.
3.4 Review of Surface Water Data PFAS concentrations in excess of the recreational water guidelines were identified in surface water in off-base waterways during the preparation of enRiskS (2017). This included locations SW13-F and SW14-F in Currambene Creek (maximum PFOS + PFHxS concentration of 3.7 µg/L). Detailed calculations undertaken at that time, and presented in enRiskS (2017), indicated that risks associated with average or typical exposures that may occur for adults and children were low, and risks associated with upper estimate exposures by adults were also low. Risks associated with upper estimate exposures by young children were slightly elevated, however, the upper estimate of potential recreational exposures was considered to be overly conservative as the maximum surface water concentration was considered. In addition, young children were assumed to access and swim in the same locations 150 days per year, for 1.5 hours each time, for 5 years and access and use of surface waterways is not expected to occur at this level in these areas.
This section of the HHERA Addendum provides a review of the additional surface water data collected by Aurecon (2018). Data from previous surface water sampling locations that were not resampled by Aurecon (2018) have not been reassessed. This previous data is considered in enRiskS (2017).
Table 3.3 presents a summary of PFAS concentrations reported in surface water in the Shoalhaven River and Currambene Creek (refer to Figure 1 for locations).
The assessment of recreational exposures including swimming has been undertaken by comparing the concentrations reported in surface water against recreational water guidelines (Department of Health 2017). This is conservative as the Australian guidance for recreational water quality (NHMRC 2008) assumes that 0.2 L water is consumed every day during recreational activities. This is sufficient to cover exposures during swimming/wading as well as other incidental exposures.
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Table 3.3: Summary and Review of PFAS Reported in Surface Water: Human Health
Area Investigated Reported Concentration Range (µg/L) PFOS + PFHxS PFOA Total PFAS
Shoalhaven River Background (SR-B1) ND ND ND Confluence of Calymea Creek and the Shoalhaven River (W012/SR-B2)
0.0057 – 0.12 ND 0.0067 – 0.13
Downstream (SR-B3) 0.0057 ND 0.0067 Currambene Creek W042 0.051 - 0.27 ND 0.055 - 0.3 W052 0.23 ND 0.26 CC-B2/W062 ND - 0.032 ND ND - 0.038 CC-B3 0.016 ND 0.018
Adopted screening guidelines1 Recreational water use 0.7 5.6 0.7
Notes: Shading indicates an exceedance of the adopted guideline value. 1 = Ref. HEPA (2018). Note that in the absence of guidelines for PFAS other than PFOS+PFHxS and PFOA, total
PFAS concentrations have been screened against the more conservative guidelines for PFOS+PFHxS. 2 = Includes data reported as part of enRiskS (2017). ND = Not detected at the following laboratory limits of reporting: 0.001 to 0.005 µg/L.
Review of Table 3.3 indicates the following:
PFAS was not detected in surface water at the background location in the Shoalhaven River; PFOA was not detected in surface water. Hence there are no human health risk issues of
concern for exposures to PFOA in surface water and no further assessment of PFOA is required;
Concentrations of PFAS reported in surface water in the Shoalhaven River and Currambene Creek are below the recreational water use guidelines. Maximum concentrations of Total PFAS in surface water in the Shoalhaven River (0.013 µg/L) are around 5 times below the adopted screening guideline (0.7 µg/L). Maximum concentrations of Total PFAS in surface water in Currambene Creek (0.3 µg/L) are around 2 times below the adopted screening guideline. Hence there are no human health risk issues of concern for recreational exposures, including any multiple exposures, to PFAS in these surface water bodies and no further assessment is required; and
The available data suggests that PFAS concentrations in surface water decrease with distance downstream, however additional data would be required to confirm this pattern.
In relation to river flow rates and rainfall conditions at the time of the surface water sampling, previous data (from enRiskS 2017; at locations W01 and W04 to W06) was collected during baseflow conditions. Water sampling conducted by Aurecon (2018) in January/February 2018 was undertaken during low flow (dry) conditions. Baseflow and dry conditions are most representative of when people may swim in the waterbodies.
The above assessment does not address potential exposures to PFAS following accumulation in biota in the Shoalhaven River and Currambene Creek, which may then be caught and consumed by recreational fishers. This exposure pathway has been assessed based on the biota data collected, as presented in Section 3.5.
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3.5 Review of Biota Data from Aurecon (2018) The biota data reviewed as part of enRiskS (2017) indicated the potential for elevated exposures to recreational fishers from PFOS concentrations in fish and crustaceans, should fishing occur. However, it was noted that recreational fishing was more likely to occur further downstream of where the biota samples were collected, and there was no biota data available for the downstream locations. Given this, further sampling of edible biota at downstream locations, where recreational fishing is likely to occur, was recommended.
In this HHERA Addendum, the initial assessment of potential human health risks following the consumption of biota, has been undertaken by comparing the reported concentrations of PFOS + PFHxS in the biota collected by Aurecon (2018) to the FSANZ (FSANZ 2017a) trigger levels for PFOS + PFHxS in finfish and crustaceans. It is acknowledged that these trigger levels assume that all the tolerable daily intake is sourced from either fish or crustaceans. In addition, the trigger levels for crustaceans may not be protective of high consumers of some crustaceans (including prawns). However, the trigger levels are still considered suitable for use in the HHERA Addendum as concentrations of PFAS in sediment and surface water in the waterbodies are well below the relevant screening guidelines for recreational use (refer to Section 3.3 and 3.4).
Table 3.4 presents a summary of PFOS + PFHxS concentrations reported in biota caught from the estuarine reaches of the Shoalhaven River and Currambene Creek (refer to Figure 1 for locations). Samples of yabbie and Australian Bass previously collected from the freshwater areas of Currambene Creek (locations SW13-F and SW14-F), and reviewed as part of enRiskS (2017), have also been included. A review of the data for PFAS in biota shows that the main PFAS detected in fish was PFOS, with PFHxS also detected in 13 species (Yabbie, Mud Crab, Blue Swimmer Crab, Freshwater Prawn, Australian Bass, Silver Trevally, Black Sole, Estuary Perch and Mulloway). PFOA was detected in Yabbie from SW13-F (Currambene Creek upstream; maximum concentrations of 1.6 µg/kg ww well below the FSANZ trigger level of 520 µg/kg ww) but not detected in any other biota species/locations. Some other PFAS were also detected intermittently and are considered in Section 4.4.
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Table 3.4: Summary and Review of PFAS Reported in Biota: Human Health
Biota Species Reported PFOS + PFHxS Concentration (µg/kg wet weight) Shoalhaven River Currambene Creek
SR-B1 SR-B2 SR-B3 SW13-F/ SW14-F
W04 CC-B2 CC-B3
Fish – Data from Freshwater Locations (enRiskS 2017) Australian Bass -- -- -- 691 -- -- -- Fish – Data from Estuarine Locations (Appendix A & B) Australian Bass 5.5 - 9.4 5.3 6.7 -- -- -- -- Black Sole -- -- -- -- -- 367 -- Bream -- 1.3 1.2 -- 1.1 0.4 – 1 ND – 1.2 Dusky Flathead 4.3 -- -- -- -- -- -- Eastern Sea Garfish -- 2.0 -- -- 2.4 – 2.7 -- -- Estuary Perch 1.4 2.3 3.6 -- -- 15.5 – 18.5 11 Herring -- -- 8 -- -- -- -- Luderick -- 1.2 -- -- -- 4.9 – 6.6 1.6 – 2.5 Mulloway -- -- -- -- -- 11 – 15.5 -- Sand Mullet -- -- 10 -- -- -- -- Sand Whiting -- -- -- -- -- 12 ND – 1.6 Sea Mullet 1.5 – 3.4 8.5 – 22 5.3 – 5.4 -- 6.2 – 6.3 2.7 – 6.4 2.8 – 3.5 Silver Trevally -- -- -- -- -- 13 – 39.2 2.2 – 4.2 Tailor -- -- 0.9 -- -- -- -- Tiger Mullet 2.2 – 3.8 20 -- -- -- -- -- Crustaceans – Data from Freshwater Locations (enRiskS 2017) Yabbie -- -- -- 94 -- -- -- Crustaceans – Data from Estuarine Locations (Appendix A & B) Blue Swimmer Crab -- -- -- -- -- -- 5.9 Freshwater Prawn -- -- -- -- -- 45.3 -- Mud Crab -- -- 4.7 -- -- 4.6 --
Adopted screening guidelines (FSANZ)1 Finfish 5.2 Crustaceans 65
Notes: Shading indicates an exceedance of the adopted guideline value based on the maximum concentration. 1 = Ref. FSANZ (2017). “--” = Indicates no data available
Review of Table 3.4 indicates the following in relation to PFOS + PFHxS concentrations in biota:
Concentrations in all fish species sampled, except for Bream, Dusky Flathead, Eastern Sea Garfish and Tailor, exceed the trigger level for finfish;
The highest concentrations from the data collected by Aurecon (2018) were reported in Black Sole (367 µg/kg). This was based on one whole fish analysed. The next highest concentrations were reported in Silver Trevally (39.2 µg/kg) and then Tiger Mullet/Sea Mullet/Mulloway/Estuary Perch (all around 20 µg/kg);
Concentrations exceed the trigger levels for finfish in both the Shoalhaven River and Currambene Creek, and at all locations;
Four of the fish species (Australian Bass, Estuary Perch, Sea Mullet and Tiger Mullet) were caught from the Shoalhaven River upstream (SR-B1) and downstream of Calymea Creek (SR-B2). In relation to these fish: Concentrations in Australian Bass and Estuary Perch were similar
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Concentrations in Sea Mullet and Tiger Mullet were 5 to 10 times higher at the downstream location. On face value this seems to suggest that the base may be the source of the downstream concentrations, however Mullet will easily swim distances more than 7 km (i.e. between sample locations) so the data is not useful for determining the source of the impacts
Concentrations in Blue Swimmer Crabs and Mud Crabs were similar and below the trigger level for crustaceans; and
Concentrations in Freshwater Prawns are below the trigger level for crustaceans, based on one sample of 3 prawns. However, as noted above, the trigger levels for crustaceans may not be protected of prawns. Hence, further assessment of prawns has been undertaken in this HHRA.
In relation to the high concentrations of PFOS + PFHxS which were reported in the Black Sole, Aurecon have indicated that this fish is a carnivore that lies on the floor of the waterway, partially buried in the sand or mud with its eyes protruding. When prey (e.g. an invertebrate or small fish) comes near it, the Black Sole ambushes its prey and eats it. The Black Sole is known to bioaccumulate chemicals from the food it eats and would also typically digest more sediment than other fish species (e.g. the Flathead). A Black Sole will also consume more smaller fish than a Flathead, and its prey are also more likely to also be bottom dwellers. This, alongside the sample analysed (which was a whole fish), may explain why significantly elevated concentrations of PFOS were reported in the Black Sole, as compared to other fish/crustacean species. This is because other organs such as the liver have been analysed and higher concentrations of PFAS may be present in these organs.
A similar species to the Black Sole is the Lemon Tongued Sole, which may also occur in Currambene Creek1. As the behaviour of these fish are similar, Lemon Tongued Sole may also accumulate high levels of PFOS + PFHxS. However, neither species is commonly caught by recreational fishers.2,3
PFOS + PFHxS concentrations were reported below the FSANZ (2017) trigger levels in several species comprising Bream, Dusky Flathead, Eastern Sea Garfish, Tailor, Blue Swimmer Crab and Mud Crab. 7 composites (2 to 5-part) and 1 individual fillet of Bream were collected and analysed from Currambene Creek. This is adequate to conclude that no further assessment is require for Bream from Currambene Creek.
The available data for the remaining species is summarised in Table 3.5 (Shoalhaven River) and Table 3.6 (Currambene Creek). Limited samples were able to be collected for these biota species therefore a Margin of Safety (MOS) approach, which considers the ratio between the maximum reported concentration and the trigger level, has been used to check if further assessment is required. A MOS of 10 has been adopted as the threshold above which further assessment is required. A MOS of 10 allows for an order of magnitude change which is an industry rule of thumb
1 https://bie.ala.org.au/species/urn:lsid:biodiversity.org.au:afd.taxon:093d47c6-6358-462c-b44e-efb81c09b94f#overview 2 https://www.dpi.nsw.gov.au/__data/assets/pdf_file/0005/375944/Soles.pdf. 3 Aurecon Ecology team, pers. comm.
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and considered to be reasonable to account for any uncertainties in the investigation data. This is also in line with the range of concentrations reported in Table 3.4.
Table 3.5: Shoalhaven River: Dusky Flathead, Eastern Sea Garfish, Tailor, Bream and Mud Crab
Biota Species Shoalhaven River Margin of Safety (MOS) Comment Dusky Flathead 1 individual fillet 1.2 Species known to be targeted
by fishers Eastern Sea Garfish 1 whole fish of <10 cm 2.6 -- Tailor 1 individual fillet 6 -- Bream 1x2-part composite and 1
individual fillet 4 Species known to be targeted
by fishers Mud Crab 1x2 whole crabs 14 --
Notes: Shading indicates species where it is concluded that further assessment is required.
Review of Table 3.5 indicates that the highest MOS for the fish was reported for Tailor however only one fillet was analysed. On this basis, it is concluded that further, more detailed assessment of Tailor is required. Similarly, further, more detailed assessment is required for Dusky Flathead, Bream and Eastern Sea Garfish, as the MOS is only 1-4 times and limited samples have been able to be collected and analysed. The further, more detailed, assessment, is provided in Section 4.
Although only 2 Mud Crabs have been collected and analysed, the MOS is >10. This indicates there are unlikely to be significant health risk issues associated with the consumption of crab from the Shoalhaven River and no further assessment of Mud Crab is required.
Table 3.6: Currambene Creek: Eastern Sea Garfish, Crab, Mud Crab and Prawn
Biota Species Currambene Creek Margin of Safety (MOS) Comment Eastern Sea Garfish 8-part composite split into 2
samples 2 Species known to be targeted
by fishers Blue Swimmer Crab 1x2 whole crabs 11 Species known to be targeted
by fishers Mud Crab 1x1 whole crab 14 Species known to be targeted
by fishers Freshwater Prawn 1x3 prawns 1.4 --
Notes: Shading indicates species where it is concluded that further assessment is required.
Review of Table 3.6 indicates that a more detailed assessment is required for Eastern Sea Garfish and Freshwater Prawn, as the MOS is only 1-2 times and limited samples have been able to be collected and analysed. The further, more detailed, assessment is provided in Section 4.
Although only a few crabs have been collected and analysed, the MOS is >10. This indicates there are unlikely to be significant health risk issues associated with the consumption of crab from Currambene Creek and no further assessment of crab is required.
3.6 Review of Biota Data from NSW DPI In addition to the sampling conducted by Aurecon, the NSW Department of Primary Industries (DPI) has also assessed PFAS concentrations in edible fish species within the Shoalhaven River. The sampling was conducted over Summer and Autumn in 2015/16 under the NSW PFAS Expanded Sampling Program.
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Species targeted in the Shoalhaven River included Luderick, Sea Mullet, School Prawn, Sand Whiting, Yellowfin Bream, Mud Crab, Silver Biddy and Dusky Flathead. These species comprise 97% of the commercial catch (by biomass) in the Shoalhaven River. In addition, Blue Swimmer Crab and Eastern King Prawn were collected from the adjacent Lake Woolumboola, as they are not present in large numbers in the Shoalhaven River. The locations sampled are close to points of discharge from creeks evaluated in the Shoalhaven River, as well as further downstream. Appendix E presents the data provided for this assessment, including a figure showing the sample locations within the Shoalhaven River. Location 6 is near Aurecon location SR-B3, with locations 5 to 1 located progressively downstream.
Table 3.7 presents a summary of the PFAS concentrations reported in edible fish species with comparison against the FSANZ trigger levels.
Table 3.7: Summary and Review of PFAS Reported in Edible Fish Species in the Shoalhaven River, Data from NSW DPI
Biota Species Reported PFOS + PFHxS Concentration (µg/kg wet weight) SR-B3
(Aurecon 2018)
Location 6*
Location 5*
Location 4*
Location 3*
Location 2*
Location 1*
Fish Dusky Flathead 4.3
(SR-B1) -- -- 5.7 – 8.3 4.4 – 5.4 3.9 – 5.7 1.5 – 2.7
Luderick 1.2 (SR-B2)
-- -- 4.2 – 5.5 1.4 – 2.1 1.5 – 2.3 2.2 – 2.3
Sand Whiting -- -- -- 2.7 – 3.5 1.2 – 2.2 0.57 – 0.75 0.38 – 0.47 Sea Mullet 5.3 – 5.4 -- -- 5.1 - 6 1.7 – 4.7 1.5 – 1.9 -- Silver Biddy -- -- -- 10 - 12 4.1 2.7 – 4.8 1 – 3.3 Yellowfin Bream 1.2** -- -- 1.8 – 2.5 ** 0.81 – 1.4 0.38 – 0.52 ND** Crustaceans Mud Crab 4.7 -- -- -- -- 1.7 1.1 School Prawn -- 1.5 – 3.8 3.1 – 5.3 5.6 - 10 -- -- 1.4 – 2
Adopted screening guidelines (FSANZ)1 Finfish 5.2 Crustaceans 65
Notes: Shading indicates an exceedance of the adopted guideline value. “--” = Indicates no fish/crustacea caught. 1 = Ref. FSANZ (2017). * = Data for from NSW DPI for PFOS only, PFHxS not tested or reported on. ** = Identified as “Bream” on sampling documentation.
Review of Table 3.7 indicates the following:
Concentrations of PFAS reported in crustaceans in the Shoalhaven River area are below the trigger levels. This confirms that no further assessment of crustaceans (including crabs) in the Shoalhaven River is required;
PFOS concentrations reported in fish from sampling by NSW DPI at location 4 exceed the FSANZ trigger level. The maximum concentration of PFOS reported in fish in sampling locations 3 and 2 just exceeds the trigger level; and
PFOS concentrations reported in fish by Aurecon (2018) are similar to (and lower than) concentrations reported by NSW DPI.
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In relation to concentrations of PFOS in fish, not all sources of PFOS in the Shoalhaven River have been identified and hence source of the PFOS levels reported in fish in sampling locations 2 to 4 is not known. Any contribution from the base has not been not fully defined.
3.7 Comparative Review of Investigation Data for PFOS This section of the Addendum HHERA reviews the concentrations of PFOS reported in sediment, surface water and biota in the Shoalhaven River and Currambene Creek in January/February 2018 to see if any patterns are evident. Only three data points on one sampling occasions are available for all three media and any patterns that are identified from the review of the information should be considered in this context.
3.7.1 Shoalhaven River
Concentrations of PFOS in the Shoalhaven River are shown on Graph 1.
Graph 1. PFOS in sediment, surface water and biota in the Shoalhaven River, January/February 2018
PFOS was not detected in sediment in the Shoalhaven River so no conclusions can be drawn in relation to patterns between sediment and surface water/biota.
Concentrations of PFOS in surface water increase as you move downstream, after the entrance of Calymea Creek. Concentrations of PFOS in surface water appear to be linked to concentrations of PFOS in biota, with the maximum biota concentrations reported at SR-B2 and SR-B3 where surface water concentrations were highest. However, concentrations in biota were generally similar at all
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three sampling locations and this is apparent from a review of average concentrations. In addition, concentrations of PFOS in surface water were low in January/February 2018, which makes it difficult to draw any firm conclusions.
3.7.2 Currambene Creek
Concentrations of PFOS in Currambene Creek are shown on Graph 2.
Concentrations of PFOS in Black Sole (347 µg/kg) have not been presented on the graph. This fish species behaves differently to most of the other fish sampled as it buries in the mud rather than swimming in the water column. Hence, the data point is considered an outlier and has been excluded from the graph (but included in the discussion below).
Graph 2. PFOS in sediment, surface water and biota in Currambene Creek, January/February 2018
Graph 3 shows that PFOS concentrations in surface water decrease as you move downstream in Currambene Creek. Conversely, PFOS concentrations in biota (especially maximum concentrations) increase as you move downstream. PFOS was not detected in sediment at W04 but was detected at similar concentrations at CC-B2 and CC-B3. The Black Sole with the elevated PFOS concentrations was caught at location CC-B2 (no sediment dwelling fish were caught at CC-B3).
It is however noted that PFOS concentrations in surface water are within the same order or magnitude, so any patterns that appear to be present may be due to variability in the dataset
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caused by sampling and analysis protocols or other factors, rather than actual correlations between PFOS in the various media. Further, and like the data for the Shoalhaven River, average concentrations of PFOS in biota are similar across all sampling locations.
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Section 4. Assessment of Human Health Risks 4.1 Approach to Quantifying Risks to Human Health Based on the review of risk issues presented in Section 3, the consumption of some fish species and freshwater prawns containing PFAS requires a more detailed assessment of potential risks to human health.
The quantification of risks to human health has been undertaken in accordance with industry best practice and guidance (enHealth 2012a; NEPC 1999 amended 2013). This requires the following:
Quantification of exposure – this is how much PFAS can enter the body following the consumption of fish and crustaceans containing PFAS. The exposure assessment is undertaken to be representative of a particular population and does not calculate the exposure for a given individual. Populations are grouped to reflect common activities undertaken by that group (such as children) or by the location of the population in relation to the contaminant distribution. For this reason, it is important that the exposure assessment be undertaken in such a way that the most sensitive individuals within the potentially exposed population are adequately protected. The following steps have been followed to estimate the exposure or intake of PFAS:
Identification of exposure parameters for each of the identified exposure pathways and receptors. These are values that describe the physical and behavioural parameters relevant to the potentially exposed population and the pathway of exposure. Some examples include fish ingestion rate (e.g. amount of fish consumed each day), exposure frequency (i.e. days per year that fish from the Shoalhaven River or Currambene Creek is consumed), exposure duration (e.g. number of years that fish is consumed) and body weight. Where available, exposure parameters have been obtained from Australian sources (enHealth 2012b);
Estimation of the chemical concentration in fish and crustaceans. This is available from the sampling and analysis of biota samples from the Shoalhaven River and Currambene Creek; and
Calculation of the daily chemical intake or exposure concentration using the relevant exposure parameters and chemical concentration.
Exposures that may occur following the consumption of fish and crustaceans have been calculated for adults and young children, noting that children aged 2 to 3 years are considered to be the most sensitive receptors (NEPC 1999 amended 2013), young children have a lower body weight, so their intake per unit body weight is higher.
The assessment of risks is also limited to the waterways where sampling was undertaken, and the extent of sampling within these waterways.
Quantification of the hazard or toxicity of the PFAS compounds evaluated – this is where tolerable daily intake (TDI) values are identified for characterising the toxicity of the PFAS compounds evaluated in this assessment i.e. PFOS and PFHxS (PFOA was not detected in biota).
Consistent with reviews by other authorities (EFSA 2008; enHealth 2016; USEPA 2016a, 2016b), FSANZ has determined a TDI for PFOS on the basis of data derived from animal studies, that show exposure to these compounds can cause liver toxicity and tumours and reproductive and
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developmental effects. The available epidemiological studies have not provided sufficient evidence of a link between exposure to PFOS and PFHxS and any cancer type in human beings.
In relation to PFHxS, FSANZ determined there was insufficient information to establish a TDI for PFHxS. In the absence of a TDI, FSANZ agrees with enHealth (enHealth 2016) that using the TDI for PFOS is likely to be conservative and protective of public health. This means that PFHxS and PFOS should be summed for the purposes of exposure assessment and risk characterisation.
The TDIs adopted by FSANZ for the assessment PFOS + PFHxS are summarised in Table 4.1. This table also includes the background intakes, based on the reviews presented by ToxConsult (ToxConsult 2016a, 2016b) adopted for the characterisation of risk.
Table 4.1: Summary of toxicity reference values adopted for PFOS and PFHxS
PFAS Compound TDI Background intake Reference PFOS + PFHxS 0.02 µg/kg/day 0.0014 µg/kg/day (7% of the TDI) (FSANZ 2017b)
A detailed summary of the toxicity of PFOS + PFHxS is provided in enRiskS (2017).
Risk characterisation – this combines the exposure/intake and toxicity information to calculate a risk. For the assessment of PFAS, this has been undertaken on the basis of a threshold TDI.
The characterisation of risk has involved the calculation of a hazard quotient (HQ), which is the ratio of the estimated intake (or exposure concentration, as a daily average dose) to the TDI (expressed as an acceptable daily dose), with consideration for background intakes4. The HQs are then summed over all exposure pathways to calculate a Hazard Index (HI), which represents the potential risks associated with cumulative exposures from multiple pathways (where these are of potential significance). These calculations are as follows:
Hazard quotient (HQ)(e.g. ingestion or dermal) = Daily chemical intake(TRV-Background)
Where there is only one exposure pathway of relevant, the HQ is equal to the HI.
The interpretation of an acceptable HI needs to recognise an inherent degree of conservatism that is built into the establishment of appropriate TRVs adopted (using many uncertainty factors) and the exposure assessment. Hence, in reviewing and interpreting the calculated HI the following is noted:
4 Background intakes are intakes of a chemical that are derived from sources other than the contamination being assessed. This may include dietary intakes and intakes from drinking water or urban air. Refer to enRiskS (2017) for further discussion.
∑=PFASandpathwaysAll
HQHIHazard )(
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A HI less than or equal to a value of 1 (where the total intake or exposure is less than or equal to the TDI) represents no cause for concern as outlined in NEPM guidance (NEPC 1999 amended 2013); and
A HI greater than 1 requires further consideration within the context of the assessment undertaken. The calculation infers that there is the potential for the total intake of PFAS to be higher than the TDI. This does not necessarily mean that harm will occur as the intake parameters (e.g. amount of fish ingested) are conservative, and the TDI has inherent safety margins incorporated. The likelihood of harm occurring increases with the extent to which intakes exceed the TDI (i.e. with higher HIs).
The calculation of a HI assumes that the toxicological effects of all the chemicals evaluated are additive. This means that the chemicals act in the same way in the body and affect the same target tissues. As this assessment has considered exposures to PFAS compounds, it is reasonable to assume that additive effects may occur.
4.2 Consumption of Fish and Crustaceans
4.2.1 General
Intakes of PFOS + PFHxS from the consumption of fish and crustaceans have been calculated based on the following equation:
Intakef=Cf x IRf x FI x Bo x EF x ED
BW x AT …Equation 4.1
Where
Intakef = Daily intake of PFOS + PFHxS from fish or crustaceans (µg/kg/day)
Cf = PFOS + PFHxS concentration in edible fish tissue (µg/kg)
IRm = Fish or crustacean ingestion rate (kg/day)
FI = Fraction ingested from contaminated source (unitless)
Bo = Oral bioavailability (unitless)
EF = Exposure frequency (days/year)
ED = Exposure duration (years)
AT = Averaging time (days)
BW = Body weight (kg)
Exposure parameters adopted for the assessment of intakes from fish and crustaceans are presented Table 4.2.
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Table 4.2: Exposure Parameters for Estimating Intakes from Fish and Crustaceans
Parameter Units Value Average Upper Estimate Basis/comment
Adult Child Adult Child
Cf µg/kg As measured in fish and crustaceans (refer to Section 3.5). Maximum concentrations have been adopted, with average concentrations also considered where data for more than 3 samples is available for a sampling location.
IR – fish kg/day 0.045 0.024 0.123 0.073 Mean and P90 values for consumers for Finfish (all)
IR –crustaceans kg/day 0.021 0.008 0.063 0.021 Mean and P90 values for consumers for
Crustaceans (all) FI unitless 1 Assumed to be 100%. BO unitless 1 Assumed to be 100%.
EF
days/year biota is caught and consumed
365 (maximum possible)
Assumes that a recreational fisher sources 100% of their diet of fish and crustaceans from the Shoalhaven River or Currambene Creek. Maximum possible exposure scenario and unlikely to be realistic of actual exposures.
200 (reasonable maximum exposure; RME)
Assumes that a recreational fisher sources 50% of their diet of fish and crustaceans from the Shoalhaven River or Currambene Creek. Potentially realistic of reasonable maximum exposures (RME) by local fishers.
104 (every weekend, likely exposure based on available information)
Assumes consumption occurs every weekend per year. This is equivalent to the assumption that a recreational fisher sources around 30% of their diet of fish and crustaceans from the Shoalhaven River or Currambene Creek.
28 (summer holidays, likely exposure based on information from NSW DPI)
Based on consumption everyday over a 4-week holiday period. This is equivalent to the assumption that a recreational fisher sources around 8% of their diet of fish and crustaceans from the Shoalhaven River or Currambene Creek.
ED years 35 5 35 5
95th percentile values for the duration at a residence in Australia (enHealth 2012b). The duration of exposure as a child relates to the time spent as a child aged 1-6 years.
AT days = ED x 365 Equal to exposure duration.
BW kg 78 15 78 15 Mean values for adults and children aged 2-3 years (enHealth 2012b)
4.2.2 Shoalhaven River
Table 4.3 presents a summary of the fish and crustaceans in the Shoalhaven River where exposures may be elevated if these species are regularly caught and consumed. The calculations presented have been based on the following upper estimate of the fish and crustacean consumption rates:
Fish: 123 g for adults and 73 g for children per day: and Crustaceans: 63 g for adults and 21 g for children per day.
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The assumed serving size of fish is roughly equivalent to the serving sizes assumed by NSW EPA (150 g for adults and 75 g for children).5 Exposures based on average consumption rates are around 3 to 4 times lower than those based on upper estimates. Exposures that are not elevated based on average consumption rates are indicated with a “*”.
Full calculations are presented in Appendix D.
Table 4.3: Summary of Species where Exposures May be Elevated - Shoalhaven River
Biota Species Shoalhaven River 100% of
fish/crustaceans from river
50% of fish/crustaceans
from river
Weekend consumption of fish/crustaceans
from river
Summer holiday consumption of fish/crustaceans
from river Adult Child Adult Child Adult Child Adult Child
Australian Bass < >* < >* < < < < Bream < < < < < < < < Dusky Flathead2 < >* < < < < < < Eastern Sea Garfish1 < < < < < < < < Estuary Perch < < < < < < < < Herring1 < >* < >* < < < < Luderick2 < < < < < < < < Sand Mullet2 < >* < >* < < < < Sea Mullet >* > < >* < >* < < Tailor2 < < < < < < < < Tiger Mullet >* > < >* < >* < <
Notes: Refer to Appendix D for further details. Not all species required further assessment hence some species are not presented in this table, refer to Section 3.5 for further information. Based on the maximum risk calculated across all sampling locations. Grey shading indicates HI >1. Blue shading indicates HI >2. Orange shading indicates HI > 5. Purple shading indicates HI > 10. “>” = Health risks are calculated to be above the acceptable HI = 1 based on upper estimate consumption rates. “<” = Health risks are calculated to be below the acceptable HI = 1 based on upper estimate consumption rates. “*” = Health risks are calculated to be below the acceptable HI = 1 based on average consumption rates. 1 = Based on the analysis of 1x whole fish <10 cm in size. 2 = Based on the analysis of a single fillet.
Review of Table 4.3 indicates the following:
Risks associated with upper estimate consumption rates by adults are low, with the HI less than 1 for all species except Sea Mullet (HI = 1.9) and Tiger Mullet (HI = 1.7). All calculated HI are <2 indicated that exposures are unlikely to be significantly elevated. Further, these HI assume that 100% of an adult’s diet of fish for the whole year comes from the Shoalhaven River, and an adult consumes 123 g/day fish every day. It is highly unlikely that this would occur in real life. HI based on more likely exposures, either average fish intakes or 50% of
5 https://www.epa.nsw.gov.au/news/media-releases/2017/epamedia17110617-dietary-advice-for-fish-from-the-shoalhaven-river
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dietary intakes from the Shoalhaven River, are below the acceptable level of 1. Exposures over the summer holidays are also acceptable;
Risks associated with upper estimate exposures by children, where 100% of the diet is sourced from the Shoalhaven River, are elevated for 6 fish species: Australian Bass Dusky Flathead Herring Sand Mullet Sea Mullet Tiger Mullet
This assumes that a child eats 73 g/day of fish and sources 100% of their diet of fish from the Shoalhaven River. It is highly unlikely that this would occur in real life. HI based on more likely exposures (i.e. 30% of fish diet from the Shoalhaven River) are elevated only for Sea Mullet and Tiger Mullet, and exposures are not elevated based on average intakes or intakes over the summer holidays.
If it is assumed a child eats 73 g/day fish and sources 50% of their diet from the Shoalhaven River, exposures are also slightly elevated (HI = 1.1 to 1.4) for Australian Bass, Herring and Sand Mullet. Exposures are not elevated based on average fish intakes, or for intakes over the summer holidays.
Overall, the calculations indicate that except for 2 species of Mullet, exposures by adults and children are unlikely to be elevated based on average fish consumption rates. Exposures by adults and children are also unlikely to be elevated based on upper bound fish consumption rates, unless over 50% of the diet of fish is sourced from the Shoalhaven River (in which case exposures by children may be elevated).
4.2.3 Currambene Creek
Table 4.4 presents a summary of the fish and crustaceans in Currambene Creek where exposures may be elevated if these species are regularly caught and consumed. The calculations based on the upper estimate of the fish and crustacean consumption rate have been presented. For adults this is 123 g/day of fish and 63 g/day of crustacea. For children, this is 73 g/day of fish and 21 g/day of crustacea. Exposures based on average consumption rates are around 3 to 4 times lower than those based on upper estimates. Exposures that are not elevated based on average consumption rates are indicated with a “*”.
Full calculations are presented in Appendix D.
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Table 4.4: Summary of Species where Exposures May be Elevated – Currambene Creek
Biota Species Currambene Creek 100% of
fish/crustaceans from creek
50% of fish/crustaceans
from creek
Weekends consumption of fish/crustaceans
from creek
Summer holiday consumption of fish/crustaceans
from creek Adult Child Adult Child Adult Child Adult Child
Fish – Upstream Data (enRiskS 2017) Australian Bass2,3 > > > > > > > > Crustaceans – Upstream Data (enRiskS 2017) Yabbie4 > > >* > >* >* < < Fish – Downstream Data (Appendix A & B) Black Sole1 > > > > > > >* > Eastern Sea Garfish < < < < < < < < Estuary Perch >* > < >* < >* < < Luderick < >* < < < < < < Mulloway >* > < >* < >* < < Sand Whiting < >* < >* < < < < Sea Mullet < >* < < < < < < Silver Trevally >* > >* > < >* < < Crustaceans – Downstream Data (Appendix A & B) Freshwater Prawn >* > >* >* < < < <
Notes: Refer to Appendix D for further details. Not all species required further assessment hence some species are not presented in this table, refer to Section 3.5 for further information. Based on the maximum risk calculated across all sampling locations. Grey shading indicates HI >1. Blue shading indicates HI >2. Orange shading indicates HI > 5. Purple shading indicates HI > 10. “>” = Health risks are calculated to be above the acceptable HI = 1 based on upper estimate consumption rates. “<” = Health risks are calculated to be below the acceptable HI = 1 based on upper estimate consumption rates. “*” = Health risks are calculated to be below the acceptable HI = 1 based on average consumption rates. 1 = Based on the analysis of 1x whole fish around 18cm in size. 2 = Based on the analysis of a single fillet 3 = Ref. enRiskS (2017), location SW14-F. 4 = Ref. enRiskS (2017), location SW13-F.
Review of Table 4.4 indicates the following in relation to risks associated with the consumption of fish and crustaceans from upstream (freshwater) locations SW13-F and SW14-F:
Risks associated with the consumption of Australian Bass are significantly elevated for both adults and children; and
Risks associated with the consumption of Yabbie are elevated for adults and children assuming 100%, 50% and 30% consumption rates, but are not elevated for occasional intakes such as intakes over the summer holidays.
Review of Table 4.4 indicates the following in relation to risks associated with the consumption of fish and crustaceans from downstream (estuarine) locations where recreational fishing is more likely to occur:
Risk associated with the consumption of Eastern Sea Garfish and Sand Mullet are below the acceptable level for both adults and children;
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Risks associated with the consumption of Black Sole are significantly elevated for both adults and children. Black Sole are rarely caught and consumed (and extremely unlikely to be consumed whole) and in relation to this the following is noted: An adult could consume 120 to 150 g/day of Black sole on 10 to 11 days/year before
the acceptable risk level of 1 was reached A child could consume 73 g/day of Black Sole on 3-4 days/year before the
acceptable risk level of 1 was reached Exposures are elevated based on average consumption rates
As part of the PFAS investigation for RAAF Base East Sale6, Carp were collected and PFOS + PFHxS concentrations were measured in both the fillets and remainder of the carcass. Concentrations in the fillets were in the range 18 to 72 µg/kg and concentrations in the remainder of the carcass were in the range 240 to 470 µg/kg. This confirms that concentrations of PFOS + PFHxS reported in the whole Black Sole in Currambene Creek are likely to overestimate concentrations reported in the edible portions. However, only 1 Black Sole has been caught and analysed whole, hence any variability in PFAS concentrations, and the actual PFOS concentration in the edible portions of the Black Sole, is not known. Overall, the interpretation of health risks based on a single data point is likely to be limited.
Risks associated with the consumption of Silver Trevally are also significantly elevated, especially for maximum possible or reasonable maximum exposures (i.e. 100% or 50% of a populations diet of fish comes from Currambene Creek). If it assumed that Silver Trevally is only caught and consumed over the Summer Holidays or Weekends (i.e. 8% to 30% of a population’s diet), risks to adults are below the acceptable level. Risks to children are 2 to 3 times the acceptable level based on the upper estimate consumption rate and below the acceptable level based on the average consumption rate;
Risks associated with the consumption of Estuary Perch, Sand Whiting, Mulloway and Freshwater Prawn are elevated based on maximum possible or reasonable maximum exposures. If it assumed that these species are only caught and consumed over the Summer Holidays or Weekends, risks for adults are below the acceptable level. Risks for children are at or below the acceptable level based on the upper estimate consumption rate and below the acceptable level based on the average consumption rate;
The majority of the elevated exposures relate to location CC-B2; No elevated exposures were identified for fish consumed from location W04 except for
slightly elevated risks to children (HI = 1.6) if 100% of the diet of fish for the year is Sea Mullet with the upper estimate consumption rate. Risks based on the average consumption rate are acceptable for 100% of the diet;
Similarly, risk calculated for downstream location CC-B3 were generally below the acceptable level except for: Consumption of Estuary Perch by children based on the upper estimate consumption
rate and 100% of the diet (HI = 2.9)
6 http://www.defence.gov.au/Environment/PFAS//docs/EastSale/Reports/RAAFEastSalePFASInvestigationInterimHumanHealthAndEcologicalRiskAssessmentFull.pdf
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Consumption of Estuary Perch by children based on the upper estimate consumption rate and 50% of the diet (HI = 1.6)
Consumption of Silver Trevally by children based on the upper estimate consumption rate and 100% of the diet)
Risks based on the average consumption rate are acceptable for both species.
4.3 Consideration of Multiple Exposures A discussed in Section 2.3, this HHERA Addendum has assumed that river water may be extracted and used for stock watering or irrigation at the surface water sampling locations investigated by Aurecon (2018). This is conservative but appropriate as there is no information on whether surface water is extracted and used.
The screening assessment for surface water data in Section 3.4 identified that there were no concentrations of PFOS + PFHxS above the recreational water use guidelines. Hence, there are no risk issues of concern associated with incidental contact exposures that may occur during the extraction and use of surface water (e.g. maintenance of pumping infrastructure, children playing in wading pools and sprinklers). However, where concentrations of PFAS are above the drinking water guidelines, the use of surface water for the irrigation of fruit and vegetables and crops or stock watering requires further evaluation.
Table 4.5 presents a summary of PFAS concentrations reported in surface water in the Shoalhaven River and Currambene Creek with the drinking water guidelines (refer to Figure 1 for locations).
Table 4.5: Summary and Review of PFAS Reported in Surface Water: Human Health
Area Investigated Reported Concentration Range (µg/L) PFOS + PFHxS PFOA Total PFAS
Shoalhaven River Background (SR-B1) ND ND ND Confluence of Calymea Creek and the Shoalhaven River (W012 / SR-B2)
0.0057 – 0.12 ND 0.0067 – 0.13
Downstream (SR-B3) 0.0057 ND 0.0067 Currambene Creek W042 0.051 - 0.27 ND 0.055 - 0.3 W052 0.23 ND 0.26 CC-B2 / W062 ND - 0.032 ND ND - 0.038 CC-B3 0.016 ND 0.018
Adopted screening guidelines1 Drinking water 0.07 0.56 0.07
Notes: Shading indicates an exceedance of the adopted guideline value. 1 = Ref. HEPA (2018). Note that in the absence of guidelines for PFAS other than PFOS+PFHxS and PFOA, total
PFAS concentrations have been screened against the more conservative guidelines for PFOS+PFHxS. 2 = Includes data reported as part of enRiskS (2017). ND = Not detected at the following laboratory limits of reporting: 0.001 to 0.005 µg/L.
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Review of Table 4.5 indicates the following in relation to PFAS in surface water:
Concentrations PFOA in surface water are below the drinking water guidelines. Hence there are no human health risk issues of concern for exposures to PFOA in surface water and no further assessment of PFOA is required;
Concentrations of PFAS reported in surface water at the confluence of Calymea Creek and the Shoalhaven River exceeded the drinking water guidelines when sampled in 2017 (refer to enRiskS 2017). When this location was re-sampled in 2018, reported concentrations were below the drinking water guidelines;
Concentrations of PFAS reported in surface water downstream in the Shoalhaven River are below the drinking water guidelines. However, based on the similarity of concentrations reported at this location and SR-B2, PFAS concentrations may exceed the drinking water guidelines seasonally;
Concentrations of PFAS reported in surface water in Currambene Creek exceed the drinking water guidelines at 2 of the 4 sampling locations; and
The data indicates there is some variability in PFAS concentrations which is consistent with what is known about the behaviour of PFAS in the environment (i.e. its highly leachable nature).
Whether surface water can be extracted and used will also depend on the saltiness of the water noting that both the Shoalhaven River and Currambene Creek are estuarine in their downstream reaches. The total dissolved solids (TDS) concentration in surface water at the Aurecon (2018) sampling locations is summarised in Table 4.6. The suitability of water for use for irrigation and stock water based on the TDS concentrations (ANZECC 1992; ANZECC/ARMCANZ 2000), a reported PFOS + PFHxS concentrations, have also been indicated.
Table 4.6: Summary of PFOS + PFHxS and TDS Concentrations in Surface Water
Sampling Location
TDS Concentration
(mg/L)1
Uses that Water is Suitable for Based on TDS Concentration
PFAS Concentration
Irrigation3 Stock Water4 PFOS + PFHxS (µg/L)2 SR-B1 300 (plants with medium
salt tolerance) (no adverse effects
expected) ND
SR-B2 6,400 × (salt tolerant crops or emergency use only)
(sheep should be able to adjust without loss in production or decline in
animal health)
0.0057 – 0.12
SR-B3 15,500 × (salt tolerant crops or emergency use only)
× (loss of production/decline in
animal health expected)
0.0057
W04 35,400 × (salt tolerant crops or emergency use only)
× (loss of production/decline in
animal health expected)
0.051 - 0.27
CC-B2 35,600 × (salt tolerant crops or emergency use only)
× (loss of production/decline in
animal health expected)
ND - 0.032
CC-B3 35,600 × (salt tolerant crops or emergency use only)
× (loss of production/decline in
animal health expected)
0.016
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Notes for Table 4.6: Shading indicates a potentially complete exposure pathway based on the salinity (TDS) of the water and the PFOS + PFHxS concentration. 1 = Total dissolved solids (TDS) concentration = electrical conductivity (EC) x 0.64, rounded to the nearest 100
mg/L. 2 = Refer to Table 4.5 and Appendix B. 3 = Ref. ANZECC (1992). 4 = Ref. ANZECC/ARMCANZ (2000). Review of Table 4.6 indicates the following:
The salinity of the water in the Shoalhaven River at location SR-B1 is such that the water quality is suitable for use as irrigation and stock water. This is independent of whether or not PFAS is present in the water;
The salinity of the water in the Shoalhaven River at location SR-B2 is such that the water quality is suitable for watering sheep, however is unsuitable for watering other stock or for irrigation; and
The salinity of the water in the Shoalhaven River location SR-B3 and Currambene Creek is such that the water quality is not suitable for irrigation or stock watering.
PFAS was not detected in surface water at location SR-B1 (Shoalhaven River). Hence, there are no health risk issues associated with the extraction of surface water containing PFAS from SR-B1, for use for irrigation or stock water.
In relation to location SR-B2 (Shoalhaven River), sheep can tolerate up to 10,000 mg/L TDS. Hence, it is possible that someone may want to use Shoalhaven River water for their sheep. Concentrations of PFOS + PFHxS in surface water at this location vary seasonally. Maximum PFOS + PFHxS concentrations (1.2 µg/L) are around 20 times the drinking water guidelines (0.07 µg/L) however minimum concentrations (0.0057 µg/L) are around 10 times below the guideline.
enRiskS (2017) included a detailed assessment (including calculations) of the potential risks to human health following the home consumption of sheep meat and offal raised on PFAS impacted water. Based on the calculations undertaken in enRiskS (2017), health risks were concluded to be acceptable for concentrations of PFOS + PFHxS in water up to 0.23 µg/L. The calculations were based on worst-case assumptions for the consumption of sheep offal by adults. At a PFOS + PFHxS water concentration of 0.23 µg/L:
Risks to children consuming sheep meat were 10 to 500 times below the acceptable level (Hazard Index = 0.002 to 0.1);
Risks to adults consuming sheep meat were 20 to >1,000 times below the acceptable level (Hazard Index = 0.0008 to 0.08); and
Risks to adults consuming sheep offal based on average and reasonable maximum exposure (RME) assumptions were 10 to 30 times below the acceptable level (HI = 0.03 to 0.1).
As the concentration of PFOS + PFHxS in water at SR-B2 is 2 times lower than that assumed in enRiskS (2017) (as outlined above), it can be inferred that risks following the home consumption of sheep meat and offal would also be acceptable and would be 2 times lower than that outlined above.
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On this basis, no unacceptable risks to human health are identified if surface water from SR-B2 is extracted and used for watering sheep.
Surface water from the Shoalhaven River and Currambene Creek would not be suitable for use for any other purposes (e.g. industrial use or aquaculture), without further assessment.
4.4 Uncertainties The main uncertainties identified during the conduct of this HHERA Addendum are discussed below. Overall, the available information is considered adequate for informing management actions for the protection of human health in the Shoalhaven River and Currambene Creek.
4.4.1 Fishing Patterns
The quantification of exposure has adopted several conservative assumptions regarding activities that the local community may undertake and how these activities may result in exposure to PFAS.
There is limited information in relation to how many times recreational fishers may catch fish from the Shoalhaven River and Currambene Creek (i.e. how much of their diet of fish may come from these waterways), and this assumption is an important input for the risk calculations.
In this assessment risk calculations have been based on a range of possible exposure scenarios, including a scenario where someone (adult or child) sources 100% of their diet of fish from the Shoalhaven River or Currambene Creek, down to a scenario where someone only consumes fish over the Summer Holidays (i.e. 8% of a populations diet; which may be representative of a tourist visiting the area). While the maximum exposure scenario is unlikely to be representative of actual exposures, it is possible that a fisher may consume fish from the waterways every day for the Summer Holidays or every weekend. Hence, the exposure assumptions adopted for the HHERA Addendum are considered reasonable for characterising likely exposures and informing the need for management.
A further fishing survey (of fishers) could be considered, however Aurecon have indicated that some fishers were unwilling to discuss their fishing activities when approached during the Aurecon (2018) data collection program. A further fishing survey may also not be able to rule out the possibility that a local fisher may catch and consume fish from the waterways every weekend, most weekends or while on holidays.
4.4.2 Biota Sampling
A limited number of samples of some species (e.g. Mud Crabs, Blue Swimmer Crabs, Freshwater Prawn, Sand Mullet and Tailor) have been able to be collected by Aurecon (2018). Some species (e.g. Herring, Black Sole, Eastern Sea Garfish) were also analysed as whole fish rather than fish fillets. The analysis of whole fish is expected to overestimate the concentrations of PFAS that may be present in the edible portions, as other organs such as the liver are analysed and higher concentrations of PFAS may be present in these organs. Some species such as Herring are also more likely to be used as bait rather than consumed by humans. Hence, the overall approach adopted for the HHERA Addendum is conservative.
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It is understood that Aurecon (2018) went to significant effort to target and obtain appropriate biota samples for the HHERA Addendum, and the samples obtained are likely to be representative of the availability of fish/crustaceans at the time of sampling. Hence, the available data is generally representative of the availability of species in the waterway at the time of sampling (and by inference the probability that the species may be caught by recreational fishers). For example, only 2 Blue Swimmer Crabs were above to be caught in Currambene Creek (no Blue Swimmer Crabs could be caught in the Shoalhaven River) which makes sense as these crabs are not known to be present in large numbers in these waterways. There is also adequate data for the assessment of 1 of the 3 main target fish species in the Shoalhaven River (Bream) and there is some data for the remaining 2 species (Luderick and Dusky Flathead) to confirm that the current NSW Government fishing advisories are appropriate.
Overall, the available information is considered adequate for informing management actions for the protection of human health in the Shoalhaven River and Currambene Creek.
4.4.3 Presence of Other PFAS
As discussed in Section 3.1, this HHERA Addendum has focused on health risks from PFOS and PFHxS as these PFAS are generally considered to be of most concern from an environmental health point of view, especially where edible products are concerned. No PFOA has been detected in environmental samples analysed by Aurecon (2018) so no further evaluation of PFOA is necessary.
For sediment and surface water data, the Total PFAS concentration has been screened against the guidelines for PFOS + PFHxS and no risk issues have been identified. This means that no further assessment of the other PFAS is required for sediment and surface water.
The main PFAS detected in biota samples collected by Aurecon (2018) was PFOS, the following other PFAS were detected:
PFHxS: 11 samples; PFNA: 1 sample; PFHpS: 2 samples; N-MeFOSE: 1 sample; and FOSA: 1 sample.
The available data is summarised in Table 4.7.
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Table 4.7: Summary of Concentrations of PFAS Other than PFOS in Biota
PFAS PFHxS PFHpS PFNA N-MeFOSE FOSA % PFOS + PFHxS
Black Sole 27 5.9 1.3 -- -- 98 Blue Swimmer Crab 1.4 -- -- -- -- 100 Estuary Perch (SR-B1 only)
-- -- -- 5.1 -- 22
Estuary Perch (Other Locations)
0.4 – 0.5 -- -- -- -- 100
Freshwater Prawn 9.3 0.9 -- -- -- 98 Mud Crab 0.7 – 1.8 -- -- -- -- 100 Mulloway 0.5 -- -- -- -- 100 Silver Trevally 1.1 – 2.2 -- -- -- -- 100 Sand Whiting -- -- -- -- 0.7 95
Notes: Refer to Appendix A and Appendix B for further details Concentrations of PFHxS have been considered in the risk calculations along with PFOS. Hence, no further evaluation of PFHxS is required.
PFHpS and PFNA were detected in Black Sole however exposures have been calculated to be potentially elevated for Black Sole based on PFOS and PFHxS concentrations. Hence, the detection of PFHpS and PFNA in Black Sole does not affect HHERA Addendum outcomes.
PFHpS has also been detected in low concentrations in Freshwater Prawn. However, concentrations of PFOS + PFHxS comprise 98% of the Total PFAS concentrations for the Freshwater Prawn sample. Hence, the detection of PFHpS in Freshwater Prawn does not affect HHERA Addendum outcomes. Similarly, FOSA concentrations in Sand Whiting make up only 5% of the Total PFAS concentration (with PFOS contributing the rest). Concentrations of Total PFAS in Sand Whiting are also above the FSANZ trigger level without consideration of FOSA. Hence, the detection of FOSA in Sand Whiting does not affect HHERA Addendum outcomes.
The detection of N-MeFOSE in Estuary Perch is interesting and unusual as N-MeFOSE was detected in the sample of Estuary Perch from SR-B1 but was not detected in samples from SR-B2 or SR-B3. Also, at SR-B1, concentrations of N-MeFOSE comprised 78% of the Total PFAS reported (concentration of 5.1 µg/kg; the remaining 22% of the Total PFAS concentration comprised PFOS at 1.4 µg/kg). Hence, health risks calculated based on PFOS may not be representative of health risks from Total PFAS. N-MeFOSE is a PFOS precursor which means it may degrade to PFOS in the environment.
If it is assumed the concentration of PFOS in Estuary Perch is 6.5 µg/kg ww, the revised risk estimates are obtained for the upper bound estimates:
Exposures 365 days/year: risks are acceptable for adults and 1-2 times the acceptable level for children (HI = 1.7);
Exposures 200 days/year: risks are acceptable for adults and at the acceptable level for children; and
Exposures over the weekend or Summer Holidays: risks are acceptable for adults and children.
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This is a similar level of health risk to that calculated for other fish species (Sea Mullet, Sand Mullet and Dusky Flathead) in the Shoalhaven River (refer to Table 4.3). Hence, no effect on HHERA Addendum outcomes is identified.
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Section 5. Screening Ecological Risk Assessment 5.1 General This section presents a screening level assessment of potential ecological risks relevant to the following on- and off-base environments:
Potential risks to terrestrial ecological receptors within Lowland Rainforest; and Potential risks to aquatic ecological receptors within the Shoalhaven River and Currambene
Creek.
The assessment is a screening level assessment, as it is largely based on the comparison of PFAS concentrations reported in various media with screening level guidelines, available and relevant to the protection of the terrestrial or aquatic ecosystems.
In relation to the assessment of potential ecological risk issues relevant to PFAS, it is important to note that PFAS are chemically and biologically stable in the environment, are mobile (in water and can easily leach from soil to water) and are persistent and bioaccumulative. Hence the assessment presented has considered issues relevant to the direct toxicity of PFAS, as well as the potential for bioaccumulation and secondary poisoning (i.e. where predators are harmed through the consumption of prey or food sources that contain PFAS).
5.2 Lowland Rainforest In relation to on-base terrestrial environments, PFAS in soil reported in the top 2 m (consistent with advice in the ASC NEPM) has been compared against screening criteria relevant to the protection of terrestrial environments (HEPA 2018). These guidelines relate to direct toxicity to flora and fauna species, as well as indirect pathways (e.g. consumption by higher level predators and off-site migration). The main PFAS detected in soil in the Lowland Rainforest Community was PFOS, with PFHxS also detected in 2 soil samples. Guidelines are only available for PFOS hence the focus of this review is PFOS.
Table 5.1 presents a summary of PFOS concentrations reported in soil in the top 2 m in the Lowland Rainforest Community. The table also presents a comparison against the adopted screening criteria.
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Table 5.1: Review of PFOS in Soil, Lowland Rainforest Community
Lowland Rainforest Community PFOS Concentration Range (average) (mg/kg) 0.1 m depth 0.5 m depth
Southern End (HA95 to HA97) ND ND Yerriyong Gully, Southern End (HA92 to HA94) ND ND Yerriyong Gully, Northern End (HA89 to HA91) ND – 0.047 (0.02) 0.032 – 0.13 (0.07) Currambene Creek (HA86 to HA88) ND – 0.032 (0.02) ND – 0.11 (0.07)
Adopted screening guidelines1 Direct toxicity 1 Indirect, bioaccumulation 0.01
Notes: Average concentration indicated in parenthesis. Average calculated on the basis of the value of the LOR where PFOS was not detected. Average only calculated when 3 sample results were available. “--” = No screening guideline adopted. 1 = Ref. HEPA (2018). ND = Not detected at the following laboratory limits of reporting: 0.005 mg/kg
Review of Table 5.1 indicates the following:
PFOS was not detected in soil in 2 of the 4 Lowland Rainforest areas – at the southern end of the base and at the southern end of Yerriyong Gully. Hence there are no environmental health risk issues of concern for exposures to soil in these 2 Lowland Rainforest areas; and
Maximum concentrations of PFOS reported in soil in the remaining 2 Lowland Rainforest area were below the screening level guideline for direct toxicity however exceeded the guideline for bioaccumulation and off-site transport. The affected communities are those adjacent to Currambene Creek and at the northern end of Yerriyong Gully. This confirms that there is the potential for PFAS exposures by higher order predators to be elevated in these two areas.
The screening guideline for bioaccumulation (0.01 mg/kg) was derived by Environment Canada (Environment Canada 2017). This guideline is the lowest value from a set of values derived for the protection of soil ingestion by primary, secondary and tertiary order consumers. The relevant guidelines are as follows:
Primary consumer – 2.2 mg/kg; Secondary consumer – 0.01 mg/kg; and Tertiary consumer – 0.6 mg/kg.
Concentrations of PFOS in soil in the Lowland Rainforest are below the guidelines for primary and tertiary consumers, however further review is required for secondary consumers.
The food chain used to derive the guideline for secondary consumers by Environment Canada was noted to be complex, involving up to 3 trophic levels. Guidelines were derived for an insectivorous mammal (Common Shrew; guideline of 0.012 mg/kg), omnivorous mammal (Deer Mouse; guideline of 0.17 mg/kg) and omnivorous bird (American Robin; guideline of 0.33 mg/kg). The low guideline for the Common Shrew was due to the low bodyweight, high food ingestion rate and high proportion of the diet (95%) that was insects/invertebrates, and which are known to accumulate PFOS to the greatest extent.
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Concentrations of PFOS in soil in the Lowland Rainforest are below the guideline for omnivorous birds and mammals but exceed the guideline for insectivorous mammals. The Common Shrew (the insectivorous mammal on which the Environment Canada guideline is based) is not found in Australia however a similar species might be the Antechinus which is also known as the Marsupial Mouse (marsupials are a sub-class of mammals). Two species of Antechinus – the Yellow-footed Antechinus (Antechinus flavipes) and the Brown Antechinus (Antechinus stuartii) may be present at the base. These Antechinus are around 35 to 56 g in weight for males and 20 to 34 g for females. They eat a variety of insects, spiders and centipedes, as well as some flowers, nectar, small birds, small reptiles/frogs and may also eat House Mice. Both species are short-lived (males typically 1 year, females up to 2-3 years).7
In relation to the significance of the potential risk issues for insectivorous marsupials such as the Antechinus, concentrations of PFOS in surface soil (0.1 m depth), which is the soil most likely to be accessed, are only 2-4 times the screening level guideline for bioaccumulation (average and maximum concentrations respectively). Concentrations in deeper soil (0.5 m depth) are less than 10 times the screening level guideline and are less likely to be accessed. This does not suggest the potential for significantly elevated exposures due to bioaccumulation, especially if the Antechinus population forages over an area larger than that impacted with PFOS. Further, the Antechinus species that may be present at the base are not listed on the Environment Protection and Biodiversity Conservation Act 1999 List of Threatened Fauna.8
It is however noted that there is limited information in general in relation to the specific dietary preferences of Australian marsupials and/or how they may be affected by PFOS concentrations in their diet. There is also limited information in relation to the small insectivorous mammal species that may be present in the Lowland Rainforest at the base.
In addition, and as noted in enRiskS (2017), the presence of PFAS in soil leachate in 2 areas of the Lowland Rainforest also remains an ongoing source of PFAS to the off-site environment.
7 Aurecon Ecology team, pers. comm.; referenced predominantly from Field Companion to the Mammals of Australia (Eds. Steve Van Dyck, Ian Gynther and Andrew Baker) (2011 edn)
8 http://www.environment.gov.au/cgi-bin/sprat/public/publicthreatenedlist.pl
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5.3 Aquatic Environments This section provides a review of concentrations of PFOS in surface water and biota in the Shoalhaven River and Currambene Creek with the relevant screening guidelines for the protection of aquatic environments. Consistent with enRiskS (2017), the following guidelines have been adopted:
The 95% species protection value for freshwater has been adopted for the assessment of effects due to direct toxicity. Comparison of PFOS concentrations in surface water against the 95% species protection level is presented in Table 5.2; and
The Environment Canada (2017) guidelines for birds and mammals consuming aquatic biota have been adopted for the assessment of effects due to bioaccumulation. Comparison of PFOS concentrations in biota against the Environment Canada guidelines is presented in Table 5.3. A further discussion of the relevance of these guidelines to the off-base area is provided in enRiskS (2017).
The 99% species protection value for freshwater has not been adopted for the assessment of effects due to bioaccumulation as aquatic biota sampling has been undertaken. HEPA (2018) lists this value as available for use however indicates that the guideline is “around the trace limit of reporting (LOR) currently offered by commercial laboratories. As such, interpreting and applying this screening value may present challenges in some contexts. The recommended approach is to sample and analyse aquatic biota to account for bioaccumulation and comparison with relevant criteria (see Environmental guidelines and criteria section).”
It is also noted that the majority of the biota data is for fish fillets and not whole fish, which may underestimate the concentrations of PFOS in the whole fish that may be consumed by higher order predators (due to the accumulation of PFOS in fish liver for example).
Table 5.2: Summary and Review of PFOS Reported in Surface Water Off-base: Ecological Effects
Area Investigated Reported PFOS Concentration Range (µg/L)
Shoalhaven River Background (SR-B1) ND Confluence of Calymea Creek and the Shoalhaven River (W012/SR-B2) 0.0027 – 0.08 Downstream (SR-B3) 0.0027 Currambene Creek W042 0.037 - 0.15 W052 0.13 CC-B2/W062 ND - 0.018 CC-B3 0.012
Adopted screening guidelines1 95% Species protection 0.13
Notes: Shading indicates an exceedance of the adopted guideline value. 1 = Ref. HEPA (2018). 2 = Includes data reported as part of enRiskS (2017). ND = Not detected at the following laboratory limits of reporting: 0.001 to 0.005 µg/L.
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Table 5.3: Summary and Review of PFAS Reported in Aquatic Biota
Biota Species Reported PFOS Concentration (µg/kg wet weight) Shoalhaven River Currambene Creek
SR-B1 SR-B2 SR-B3 W04 CC-B2 CC-B3 Fish Australian Bass 5.5 - 9.4 5.3 6.7 -- -- -- Black Sole -- -- -- -- 340 -- Bream -- 1.3 1.2 1.1 0.4 – 1 ND – 1.2 Dusky Flathead 4.3 -- -- -- -- -- Eastern Sea Garfish -- 2.0 -- 2.4 – 2.7 -- -- Estuary Perch 1.4 2.3 3.6 -- 15 – 18 11 Herring -- -- 8 -- -- -- Luderick -- 1.2 -- -- 4.9 – 6.6 1.6 – 2.5 Mulloway -- -- -- -- 11 – 15 -- Sand Mullet -- -- 10 -- -- -- Sand Whiting -- -- -- -- 12 ND – 1.6 Sea Mullet 1.5 – 3.4 8.5 – 22 5.3 – 5.4 6.2 – 6.3 2.7 – 6.4 2.8 – 3.5 Silver Trevally -- -- -- -- 13 – 37 2.2 – 4.2 Tailor -- -- 0.9 -- -- -- Tiger Mullet 2.2 – 3.8 20 -- -- -- -- Crustaceans Blue Swimmer Crab -- -- -- -- -- 4.5 Freshwater Prawn -- -- -- -- 36 -- Mud Crab -- -- 2.9 -- 3.9 --
Adopted screening guidelines1 Birds (consumption of aquatic biota)
8.2
Mammals (consumption of aquatic biota)
4.6
Notes: Shading indicates an exceedance of the adopted guideline value. 1 = Ref. Environment Canada (2017)/HEPA (2018). “--" = Indicates no data available
Review of Table 5.2 and Table 5.3 indicates the following:
Of the 6 surface water samples collected from Currambene Creek: Concentrations of PFOS at one location W04 were slightly above the adopted criteria
relevant to the protection of the aquatic environment (reported concentration of 0.15 µg/L compared to a guideline of 0.13 µg/L; as presented in Table 5.2)
Concentrations of PFOS at location W05 were at the guideline Concentrations of PFOS in the remaining 4 sample were below the guideline
This does not suggest the potential for significant effects due to direct toxicity.
Concentrations of PFOS reported in surface water at downstream locations in Currambene Creek, and at all locations in the Shoalhaven River, are below the adopted guideline relevant to the protection of the aquatic environment (as presented in Table 5.2). This confirms that there are unlikely to be adverse effects due to direct toxicity in these areas; and
Concentrations of PFOS reported in biota in Currambene Creek and the Shoalhaven River exceed the criteria relevant for assessing bioaccumulation, including effects on higher level consumers, birds and mammals. The relevant data is further summarised in Table 5.4.
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Table 5.4: Summary of Key Aquatic Biota Species, Guidelines for Birds and Mammals
Area and Species PFOS Concentrations > Guideline for
Birds1 Magnitude of the
Exceedance > Guideline for
Mammals2 Magnitude of the
Exceedance Shoalhaven River Australian Bass > 1.1 times > 2 times Herring < < > 1.7 times Sand Mullet > 1.2 times > 2.2 times Sea Mullet > 2.7 times > 4.8 times Tiger Mullet > 2.4 times > 4.3 times Currambene Creek Black Sole > 41 times > 74 times Estuary Perch > 2.2 times > 3.9 times Luderick < < > 1.4 times Mulloway > 1.8 times > 3.3 times Sand Whiting > 1.5 times > 2.5 times Sea Mullet < < > 1.4 times Silver Trevally > 4.5 times > 8 times Freshwater Prawn > 4.4 times > 7.8 times
Notes: Refer to Appendix A and Appendix B for further information. 1 = 8.2 µg/kg ww. Ref. Environment Canada (2017)/HEPA (2018). 2 = 4.6 µg/kg ww. Ref. Environment Canada (2017)/HEPA (2018)). “<” = Indicates concentration reported below the guideline. “>" = Indicates concentration exceed the guideline. Grey shading indicates PFOS concentration exceeds the guideline by up to 2 times. Blue shading indicates PFOS concentration exceeds the guideline by >2 times. Orange shading indicates PFOS concentration exceeds the guideline by >5 times. Purple shading indicates PFOS concentration exceeds the guideline by >10 times.
Review of Table 5.4 indicates the following key biota species in relation to potential risks to fish/crustacea eating birds and mammals (i.e. potential effects following bioaccumulation):
Birds and mammals in the Shoalhaven River: Sea Mullet and Tiger Mullet; and Birds and mammals in Currambene Creek: Black Sole, Silver Trevally and Freshwater
Prawn.
As noted above, Black Sole is a sediment dwelling predator and hence is less likely to be eaten by aquatic birds and mammals. However, the other fish/crustacea species may be caught and consumed.
In relation to concentrations of PFOS in fish, not all sources of PFOS in the Shoalhaven River have been identified and hence any contribution from the base has not been not fully defined.
In addition, the majority of the available data is for fish fillet and not whole fish which may underestimate PFOS concentrations in whole fish that may be consumed, and subsequently the assessment of ecological risks.
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross 47 | P a g e Ref: AU/18/ALBR003-C
Section 6. Conclusions 6.1 General On the basis of additional data collected to March 2018, enRiskS has undertaken a human health and ecological risk assessment (HHERA) Addendum in relation to the presence of per- and polyfluoroalkyl substances (PFAS) located at, and in the vicinity of, HMAS Albatross (0026), Nowra, NSW (the “base”).
In Investigations conducted by Aurecon have detected concentrations of some PFAS compounds in environmental at, and downgradient of, the base. In November 2017, enRiskS prepared a HHERA for the base and surrounding area which is outlined in the following report:
enRiskS (2017), DEHP-ID-183-D1 Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross, 10 November 2017.
The HHERA identified several areas where there was the potential for exposures to PFAS to be elevated and further assessment was required to better understand human health and ecological risks.
For the on-base area, this was limited to ecological receptors within the Lowland Rainforest, where the potential for bioaccumulative effects on the terrestrial environment could not be excluded. No direct toxicity effects to the terrestrial environment were identified in this area.
For the off-base area, the HHERA identified that risks associated with the consumption of fish caught from the Shoalhaven River were low and acceptable (based on the limited data collected within the geographic boundaries of the sampling). However, it was identified that there was the potential for elevated exposures from fish intakes from Currambene Creek. The collection of additional data was recommended to better inform the risk assessment. It was also identified that there was the potential for adverse effects to the environment of the Shoalhaven River and Currambene Creek following bioaccumulation and intakes by higher order consumers.
Additional data has now been collected by Aurecon (2018) and this HHERA Addendum provides a further evaluation of the specific human health and ecological risk issues outlined above. It is acknowledged that there are known to be other sources of PFAS to the environment downgradient of the base, especially in relation to the Shoalhaven River. The known sources include sewage treatment plant outfalls, industrial activities and rural fire brigade sites.
6.2 Summary of Findings Table 6.1 provides an overview of the ways in which the assessed receptors (including members of the community and the terrestrial and aquatic environments) may be exposed to PFAS, derived from the HMAS Albatross Base and the conclusions relevant to these areas.
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross 48 | P a g e Ref: AU/18/ALBR003-C
Table 6.1: Conclusions of HHERA Addendum
How the community may be exposed?
Potential risks to health or the environment
Area where potential risk issues identified
Human health – Off-base Recreational exposures, Shoalhaven River and Currambene Creek Direct contact with PFAS in sediments
Low and acceptable. NA
Recreational use of surface water Low and acceptable NA Consumption of fish caught from local waterways
The available data indicates the potential for elevated exposures from fish and crustacean intakes.
All areas, however the highest impacts are present at SR-B2 and CC-B2.
Residential exposures Use of surface water for stock watering and irrigation
Low and acceptable. Shoalhaven River* and Currambene Creek*
Environment – On-base Terrestrial Environment of the Lowland Rainforest Direct toxicity No risk issues identified NA Bioaccumulation and effects on higher order consumers
The available data indicates the potential for elevated exposures to any resident populations of small insectivorous mammals within two areas of the Lowland Rainforest.
Yerriyong Gully, Northern End (HA89 to HA91) and Currambene Creek (HA86 to HA88)
Environment – Off-base Aquatic Environment of the Shoalhaven River* and Currambene Creek* Direct toxicity The available data does not suggest
the potential for significant effects due to direct toxicity.
NA
Bioaccumulation and higher order consumers
The potential for adverse effects to the environment cannot be excluded.
All areas, however the highest impacts are present at SR-B2 and CC-B2.
* The Shoalhaven River and Currambene Creek areas referenced in this table is limited to the waterways where sampling was undertaken, and the extent of sampling within these waterways.
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross 49 | P a g e Ref: AU/18/ALBR003-C
Section 7. References ANZECC 1992, Australian and New Zealand Guidelines for Fresh and Marine Water Quality, Australian and New Zealand Environment and Conservation Council. ANZECC/ARMCANZ 2000, Australian and New Zealand Guidelines for Fresh and Marine Water Quality, Australian and New Zealand Environment and Conservation Council and Agriculture and Resource Management Council of Australia and New Zealand. Department of Health 2017, Health Based Guidance Values for PFAS for Use in Site Investigations in Australia, Australian Government. EFSA 2008, Perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA) and their salts, Scientific Opinion of the Panel on Contaminants in the Food chain, European Food Safety Authority. enHealth 2012a, Environmental Health Risk Assessment, Guidelines for assessing human health risks from environmental hazards, Commonwealth of Australia, Canberra. <http://www.health.gov.au/internet/main/publishing.nsf/content/804F8795BABFB1C7CA256F1900045479/$File/DoHA-EHRA-120910.pdf >. enHealth 2012b, Australian Exposure Factors Guide, Commonwealth of Australia, Canberra. <http://www.health.gov.au/internet/main/publishing.nsf/Content/health-pubhlth-publicat-environ.htm>. enHealth 2016, enHealth Statement: Interim national guidance on human health reference values for per- and poly-fluoroalkyl substances for use in site investigations in Australia, Environmental Health Standing Committee (enHealth) of the Australian Health Protection Principal Committee. <http://www.health.nsw.gov.au/environment/factsheets/Documents/pfas-interim-health-values-ahppc.pdf>. Environment Canada 2017, Canadian Environmental Protection Act, 1999, Federal Environmental Quality Guidelines, Perfluorooctane sulfonate (PFOS), Environment and Climate Change Canada. FSANZ 2017a, Perfluorinated chemicals in food, Food Standards Australia and New Zealand. <http://www.health.gov.au/internet/main/publishing.nsf/Content/ohp-pfas-hbgv.htm#final>. FSANZ 2017b, Hazard assessment report - Perfluorooctane sulfonate (PFOS), Perfluorooctanoic acid (PFOA), Perfluorohexane sulfonate (PFHxS), Food Standards Australia and New Zealand. FSANZ 2017c, A Critical Review of Pharmacokinetic Modelling of PFOS and PFOA to Assist in Establishing HGBVs for these Chemicals, Food Standards Australia and New Zealand, Commonwealth Department of Health. <http://www.health.gov.au/internet/main/publishing.nsf/Content/ohp-pfas-hbgv.htm>. FSANZ 2017d, Supporting Document 2 Assessment of potential dietary exposure to perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA) and perfluorohexane sulfonate (PFHxS) occurring in foods sampled from contaminated sites, Food Standards Australia and New Zealand, Commonwealth Department of Health. <http://www.health.gov.au/internet/main/publishing.nsf/Content/ohp-pfas-hbgv.htm>. FSANZ 2017e, Attachment 1 to Supporting Document 2 Occurrence of and dietary exposure to perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA) and perfluorohexane sulfonate (PFHxS) reported in the literature, Food Standards Australia and New Zealand, Commonwealth Department of Health. <http://www.health.gov.au/internet/main/publishing.nsf/Content/ohp-pfas-hbgv.htm>. FSANZ 2017f, Attachment 2 to Supporting Document 2 Occurrence of perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA) and perfluorohexane sulfonate (PFHxS) in foods and water sampled from contaminated sites, Food Standards Australia and New Zealand, Commonwealth Department of Health. <http://www.health.gov.au/internet/main/publishing.nsf/Content/ohp-pfas-hbgv.htm>. FSANZ 2017g, Supporting Document 3 Summary of other controls for perfluorinated chemicals, Food Standards Australia and New Zealand, Commonwealth Department of Health. <http://www.health.gov.au/internet/main/publishing.nsf/Content/ohp-pfas-hbgv.htm>. FSANZ 2017h, Supporting Document 4 Criteria for the establishment of maximum levels in food, Food Standards Australia and New Zealand, Commonwealth Department of Health. <http://www.health.gov.au/internet/main/publishing.nsf/Content/ohp-pfas-hbgv.htm>. HEPA 2018, PFAS National Environmental Management Plan, Heads of EPAs Australia and New Zealand, January 2018. Miles, NG, West, R.J., 2011, Recreational fishing in the Shoalhaven Region, NSW, Australia: optimising survey methods and assessing sustainability. , University of Wollongong, October 2011.
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross 50 | P a g e Ref: AU/18/ALBR003-C
NEPC 1999 amended 2013, Schedule B4, Guideline on Health Risk Assessment Methodology, National Environment Protection (Assessment of Site Contamination) Measure, National Environment Protection Council. <http://scew.gov.au/nepms/assessment-site-contamination>. NHMRC 2008, Guidelines for Managing Risks in Recreational Water, National Health and Medical Research Council, Canberra. ToxConsult 2016a, Toxicity profiles for the perfluorinated compounds, PFHxS and PFHxA. ToxConsult 2016b, Toxicity Profiles for the perfluorinated compounds, PFOS, PFOA, 6:2FTS and 8:2FTS. ToxConsult 2017, Immunomodulation by PFASs: A brief literature review, ToxConsult, Toxicology Consulting Australasia. <http://www.health.gov.au/internet/main/publishing.nsf/Content/ohp-pfas-hbgv.htm>. USEPA 2016a, Drinking Water Health Advisory for Perfluorooctanoic Acid (PFOA), United States Environmental Protection Agency, May 2016. USEPA 2016b, Drinking Water Health Advisory for Perfluorooctane Sulfonate (PFOS), United States Environmental Protection Agency, May 2016.
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Figures
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Figure 1: HHERA Addendum biota sampling locationsHMAS Albatross HHERA°
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Legend
A3 scale: 1:80,000 Job No: 251529-001-01
Date: 21/03/2018Aut
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Coordinate System: GDA 1994 MGA Zone 56
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Figure 2: HHERA Addendum lowland rainforest sampling locationsHMAS Albatross HHERA°
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Date: 1/03/2018Aut
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!A Hand auger sample locations
HMAS Albatross Site BoundaryCreeks
Endangered Ecological Communities (NSW)Lowland Rainforest
0 850425Metres
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Appendix A Summary of Data from Aurecon (2018)
Soil results HA86_0.1_180131 HA86_0.5_180131 HA87_0.1_180131 HA87_0.5_180131 HA88_0.1_180131 HA88_0.5_180131 HA89_0.1_180131 HA89_0.5_180131 HA90_0.1_180131 HA90_0.5_180131 HA91_0.1_180131
HMAS ALBATROSS (251529) Units S18‐Fe01813 S18‐Fe01814 S18‐Fe01815 S18‐Fe01816 S18‐Fe01817 S18‐Fe01818 S18‐Fe01819 S18‐Fe01820 S18‐Fe01821 S18‐Fe01822 S18‐Fe01823
% Moisture % 6 7.8 7.7 10 9.8 23 22 17 40 27 6.3
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <51H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <52‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5N‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5N‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kg <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10N‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5N‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kg <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10Perfluorooctane sulfonamide (FOSA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorodecanesulfonic acid (PFDS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluoroheptanesulfonic acid (PFHpS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorohexanesulfonic acid (PFHxS) µg/kg <5 <5 <5 27 <5 <5 <5 <5 <5 <5 <5Perfluorooctanesulfonic acid (PFOS) µg/kg <5 <5 32 88 14 110 <5 32 12 33 47Perfluoropentanesulfonic acid (PFPeS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorodecanoic acid (PFDA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorododecanoic acid (PFDoA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluoroheptanoic acid (PFHpA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorohexanoic acid (PFHxA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorononanoic acid (PFNA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorooctanoic acid (PFOA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluoropentanoic acid (PFPeA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorotetradecanoic acid (PFTeDA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorotridecanoic acid (PFTrDA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluoroundecanoic acid (PFUnA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
PFASs SummationsSum (PFHxS + PFOS)* µg/kg <5 <5 32 115 14 110 <5 32 12 33 47Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/kg <5 <5 32 115 14 110 <5 32 12 33 47Sum of PFASs (n=28)* µg/kg <50 <50 <50 115 <50 110 <50 <50 <50 <50 <50Sum of US EPA PFAS (PFOS + PFOA)* µg/kg <5 <5 32 88 14 110 <5 32 12 33 47Sum of WA DER PFAS (n=10)* µg/kg <10 <10 32 115 14 110 <10 32 12 33 47
1 of 2
Soil resultsHMAS ALBATROSS (251529) Units
% Moisture %
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
PFASs SummationsSum (PFHxS + PFOS)* µg/kgSum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/kgSum of PFASs (n=28)* µg/kgSum of US EPA PFAS (PFOS + PFOA)* µg/kgSum of WA DER PFAS (n=10)* µg/kg
HA91_0.5_180131 HA92_0.1_180131 HA92_0.5_180131 HA93_0.1_180131 HA93_0.5_180131 HA94_0.1_180131 HA95_0.1_180131 HA96_0.1_180131 HA96_0.4_180131 QA101_180131 HA97_0.1_180131 HA97_0.5_180131
S18‐Fe01824 S18‐Fe01825 S18‐Fe01826 S18‐Fe01827 S18‐Fe01828 S18‐Fe01829 S18‐Fe01830 S18‐Fe01831 S18‐Fe01832 S18‐Fe01833 S18‐Fe02002 S18‐Fe02003
15 4.8 31 30 29 15 27 17 21 50 55 42
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <512 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5130 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
142 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5142 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5142 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50130 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5142 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
2 of 2
Soil leachate results HA86_0.1_180131 HA86_0.5_180131 HA87_0.1_180131 HA87_0.5_180131 HA88_0.1_180131 HA88_0.5_180131 HA89_0.1_180131 HA89_0.5_180131 HA90_0.1_180131 HA90_0.5_180131HMAS ALBATROSS (251529) Units S18‐Fe06016 S18‐Fe06017 S18‐Fe06018 S18‐Fe06019 S18‐Fe06020 S18‐Fe06021 S18‐Fe06022 S18‐Fe06023 S18‐Fe06024 S18‐Fe06025
% Moisture %
AUS Leaching ProcedureLeachate Fluid 4 4 4 4 4 4 4 4 4 4pH (initial) 8.1 7.8 8.8 8.7 8.7 7.1 6.8 7.5 6.5 7.6pH (Leachate fluid) 7 7 7 7 7 7 7 7 7 7pH (off) 8 7.4 7.4 8.1 7.2 7.4 7.3 7 6.6 6.6
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.011H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.011H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.011H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.052‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05Perfluorooctane sulfonamide (FOSA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/L <0.01 <0.01 0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorodecanesulfonic acid (PFDS) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluoroheptanesulfonic acid (PFHpS) µg/L <0.01 <0.01 0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorohexanesulfonic acid (PFHxS) µg/L <0.01 0.01 0.16 0.13 0.1 0.05 <0.01 0.11 <0.01 0.02Perfluorooctanesulfonic acid (PFOS) µg/L 0.01 0.04 1.1 0.62 0.26 1.6 0.08 0.79 0.08 0.51Perfluoropentanesulfonic acid (PFPeS) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05Perfluorodecanoic acid (PFDA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorododecanoic acid (PFDoA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.02 <0.01 <0.01Perfluoroheptanoic acid (PFHpA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorohexanoic acid (PFHxA) µg/L <0.01 <0.01 0.05 0.02 0.02 0.09 <0.01 0.03 <0.01 <0.01Perfluorononanoic acid (PFNA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorooctanoic acid (PFOA) µg/L <0.01 <0.01 0.02 <0.01 <0.01 <0.01 <0.01 0.02 <0.01 <0.01Perfluoropentanoic acid (PFPeA) µg/L <0.01 <0.01 0.04 <0.01 <0.01 0.02 <0.01 0.02 <0.01 <0.01Perfluorotetradecanoic acid (PFTeDA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorotridecanoic acid (PFTrDA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.03 <0.01 <0.01Perfluoroundecanoic acid (PFUnA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
PFASs SummationsSum (PFHxS + PFOS)* µg/L 0.01 0.05 1.26 0.75 0.36 1.65 0.08 0.9 0.08 0.53Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/L 0.01 0.05 1.28 0.75 0.36 1.65 0.08 0.92 0.08 0.53Sum of PFASs (n=28)* µg/L <0.1 <0.1 1.4 0.77 0.38 1.76 <0.1 1.02 <0.1 0.53Sum of US EPA PFAS (PFOS + PFOA)* µg/L 0.01 0.04 1.12 0.62 0.26 1.6 0.08 0.81 0.08 0.51Sum of WA DER PFAS (n=10)* µg/L <0.05 0.05 1.39 0.77 0.38 1.76 0.08 0.97 0.08 0.53
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Soil leachate resultsHMAS ALBATROSS (251529) Units
% Moisture %
AUS Leaching ProcedureLeachate FluidpH (initial)pH (Leachate fluid)pH (off)
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/L1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/L1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/L1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/L
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/L2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/LN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/LN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/LN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/LN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/LPerfluorooctane sulfonamide (FOSA) µg/L
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/LPerfluorodecanesulfonic acid (PFDS) µg/LPerfluoroheptanesulfonic acid (PFHpS) µg/LPerfluorohexanesulfonic acid (PFHxS) µg/LPerfluorooctanesulfonic acid (PFOS) µg/LPerfluoropentanesulfonic acid (PFPeS) µg/L
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/LPerfluorodecanoic acid (PFDA) µg/LPerfluorododecanoic acid (PFDoA) µg/LPerfluoroheptanoic acid (PFHpA) µg/LPerfluorohexanoic acid (PFHxA) µg/LPerfluorononanoic acid (PFNA) µg/LPerfluorooctanoic acid (PFOA) µg/LPerfluoropentanoic acid (PFPeA) µg/LPerfluorotetradecanoic acid (PFTeDA) µg/LPerfluorotridecanoic acid (PFTrDA) µg/LPerfluoroundecanoic acid (PFUnA) µg/L
PFASs SummationsSum (PFHxS + PFOS)* µg/LSum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/LSum of PFASs (n=28)* µg/LSum of US EPA PFAS (PFOS + PFOA)* µg/LSum of WA DER PFAS (n=10)* µg/L
HA91_0.1_180131 HA91_0.5_180131 HA92_0.1_180131 HA92_0.5_180131 HA93_0.1_180131 HA93_0.5_180131 HA94_0.1_180131 HA95_0.1_180131 HA96_0.1_180131 HA96_0.4_180131 QA101_180131S18‐Fe06026 S18‐Fe06027 S18‐Fe06028 S18‐Fe06029 S18‐Fe06030 S18‐Fe06031 S18‐Fe06032 S18‐Fe06033 S18‐Fe06034 S18‐Fe06035 S18‐Fe06036
4 4 4 4 4 4 4 4 4 4 47.5 7 6.5 4.9 5.2 4.1 7.2 6.2 6.4 4.9 8.37 7 7 7 7 7 7 7 7 7 7
6.7 6.7 5.9 4.9 5.2 3.9 6 6.1 6.4 5.3 6.5
<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
<0.01 0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.010.06 0.59 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.011.4 4.7 0.02 <0.01 <0.01 <0.01 0.03 <0.01 <0.01 <0.01 <0.01
<0.01 0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 0.03 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.010.03 0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.010.02 0.03 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
1.46 5.29 0.02 <0.01 <0.01 <0.01 0.03 <0.01 <0.01 <0.01 <0.011.46 5.33 0.02 <0.01 <0.01 <0.01 0.03 <0.01 <0.01 <0.01 <0.011.51 5.62 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.11.4 4.74 0.02 <0.01 <0.01 <0.01 0.03 <0.01 <0.01 <0.01 <0.011.51 5.53 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
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Sediment results SED_W04_180130 SED_CC‐B3_180206 SED_CC‐B2_180206 SED‐SR‐B1‐180209 SED‐SR‐B2‐180209 SED‐SR‐B3‐180209
HMAS ALBATROSS (251529) Units S18‐Fe01835 S18‐Fe06719 S18‐Fe06721 B18‐Fe14883 B18‐Fe14884 B18‐Fe14885
% Moisture % 22 26 47 21 23 25
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg <5 <5 <5 <5 <5 <51H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg <5 <5 <5 <5 <5 <51H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg <5 <5 <5 <5 <5 <51H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg <10 <10 <10 <10 <10 <10
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg <5 <5 <5 <5 <5 <52‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kg <5 <5 <5 <5 <5 <5N‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kg <5 <5 <5 <5 <5 <5N‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kg <10 <10 <10 <10 <10 <10N‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kg <5 <5 <5 <5 <5 <5N‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kg <10 <10 <10 <10 <10 <10Perfluorooctane sulfonamide (FOSA) µg/kg <5 <5 <5 <5 <5 <5
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kg <5 <5 <5 <5 <5 <5Perfluorodecanesulfonic acid (PFDS) µg/kg <5 <5 <5 <5 <5 <5Perfluoroheptanesulfonic acid (PFHpS) µg/kg <5 <5 <5 <5 <5 <5Perfluorohexanesulfonic acid (PFHxS) µg/kg <5 <5 <5 <5 <5 <5Perfluorooctanesulfonic acid (PFOS) µg/kg <5 20 21 <5 <5 <5Perfluoropentanesulfonic acid (PFPeS) µg/kg <5 <5 <5 <5 <5 <5
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kg <5 <5 <5 <5 <5 <5Perfluorodecanoic acid (PFDA) µg/kg <5 <5 <5 <5 <5 <5Perfluorododecanoic acid (PFDoA) µg/kg <5 <5 <5 <5 <5 <5Perfluoroheptanoic acid (PFHpA) µg/kg <5 <5 <5 <5 <5 <5Perfluorohexanoic acid (PFHxA) µg/kg <5 <5 <5 <5 <5 <5Perfluorononanoic acid (PFNA) µg/kg <5 <5 <5 <5 <5 <5Perfluorooctanoic acid (PFOA) µg/kg <5 <5 <5 <5 <5 <5Perfluoropentanoic acid (PFPeA) µg/kg <5 <5 <5 <5 <5 <5Perfluorotetradecanoic acid (PFTeDA) µg/kg <5 <5 <5 <5 <5 <5Perfluorotridecanoic acid (PFTrDA) µg/kg <5 <5 <5 <5 <5 <5Perfluoroundecanoic acid (PFUnA) µg/kg <5 <5 <5 <5 <5 <5
PFASs SummationsSum (PFHxS + PFOS)* µg/kg <5 20 21 <5 <5 <5Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/kg <5 20 21 <5 <5 <5Sum of PFASs (n=28)* µg/kg <50 <50 <50 <50 <50 <50Sum of US EPA PFAS (PFOS + PFOA)* µg/kg <5 20 21 <5 <5 <5Sum of WA DER PFAS (n=10)* µg/kg <10 20 21 <10 <10 <10
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Surface water results SW_W04_180130 SW_CC‐B3_180206 SW_CC‐B2_180206 SW‐SR‐B1‐180209 SW‐SR‐B2‐180209 SW‐SR‐B3‐180209
HMAS ALBATROSS (251529) Units S18‐Fe01834 S18‐Fe06720 S18‐Fe06722 B18‐Fe14880 B18‐Fe14881 B18‐Fe14882
NutrientsAmmonia (as N) mg/L <0.01 <0.01 0.02 <0.01 <0.01 <0.01Conductivity (at 25°C) µS/cm 61000 52000 53000 520 9100 22000Nitrate & Nitrite (as N) mg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05Nitrate (as N) mg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02Nitrite (as N) mg/L <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Organic Nitrogen (as N) mg/L 1.9 0.34 0.3 0.33 0.28 0.36pH ‐ 7.9 8.1 7.8 7.8 7.7 7.8Phosphorus mg/L <5 0.05 <0.05 <0.05 <0.05 <0.05Suspended Solids mg/L 53 16 20 7.9 5.5 11Total Dissolved Solids mg/L 40000 34000 36000 200 3700 11000Total Kjeldahl Nitrogen (as N) mg/L 1.9 0.3 0.3 0.3 0.3 0.4Total Nitrogen (as N) mg/L 1.9 0.34 0.32 0.33 0.28 0.36Total Organic Carbon mg/L <5 <5 <5 <5 19 <5
Heavy MetalsArsenic mg/L 0.002 <0.01 <0.01 <0.005 <0.005 <0.005Cadmium mg/L <0.0002 <0.002 <0.002 <0.001 <0.001 <0.001Chromium mg/L <0.001 <0.01 <0.01 <0.005 <0.005 <0.005Copper mg/L <0.001 <0.01 <0.01 <0.005 <0.005 <0.005Lead mg/L 0.001 <0.01 <0.01 <0.005 <0.005 <0.005Mercury mg/L <0.0001 <0.001 <0.001 <0.0005 <0.0005 <0.0005Nickel mg/L <0.001 <0.01 <0.01 <0.005 <0.005 <0.005Zinc mg/L 0.005 <0.05 <0.05 <0.025 <0.025 <0.025
n:2 Fluorotelomer sulfonic acids ‐ Ultra Trace1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.0011H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.0011H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.0011H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/L <0.005 <0.005 <0.005 <0.005 <0.005 <0.005
Perfluoroalkane sulfonamides (PFASAs) ‐ Ultra Trace2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/L <0.005 <0.005 <0.005 <0.005 <0.005 <0.0052‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/L <0.005 <0.005 <0.005 <0.005 <0.005 <0.005N‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/L <0.005 <0.005 <0.005 <0.005 <0.005 <0.005N‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/L <0.005 <0.005 <0.005 <0.005 <0.005 <0.005N‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/L <0.005 <0.005 <0.005 <0.005 <0.005 <0.005N‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/L <0.005 <0.005 <0.005 <0.005 <0.005 <0.005Perfluorooctane sulfonamide (FOSA) <0.005 <0.005 <0.005 <0.005 <0.005 <0.005
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) ‐ Ultra TracePerfluorobutanesulfonic acid (PFBS) µg/L 0.001 <0.001 0.001 <0.001 <0.001 <0.001Perfluorodecanesulfonic acid (PFDS) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluoroheptanesulfonic acid (PFHpS) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluorohexanesulfonic acid (PFHxS) µg/L 0.014 0.004 0.014 <0.001 0.003 0.003Perfluorooctanesulfonic acid (PFOS) µg/L 0.037 0.012 0.018 <0.0001 0.0027 0.0027Perfluoropentanesulfonic acid (PFPeS) µg/L 0.001 <0.001 0.001 <0.001 <0.001 <0.001
Perfluoroalkyl carboxylic acids (PFCAs) ‐ Ultra TracePerfluorobutanoic acid (PFBA) µg/L <0.005 <0.005 <0.005 <0.005 <0.005 <0.005Perfluorodecanoic acid (PFDA) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluorododecanoic acid (PFDoA) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluoroheptanoic acid (PFHpA) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluorohexanoic acid (PFHxA) µg/L 0.002 0.001 0.003 <0.001 0.001 0.001Perfluorononanoic acid (PFNA) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluorooctanoic acid (PFOA) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluoropentanoic acid (PFPeA) µg/L <0.001 0.001 0.001 <0.001 <0.001 <0.001Perfluorotetradecanoic acid (PFTeDA) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluorotridecanoic acid (PFTrDA) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluoroundecanoic acid (PFUnA) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001
PFASs Summations µg/LSum (PFHxS + PFOS)* µg/L 0.051 0.016 0.032 <0.001 0.0057 0.0057Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/L 0.051 0.016 0.032 <0.001 0.0057 0.0057Sum of PFASs (n=28)* µg/L 0.055 0.018 0.038 <0.005 0.0067 0.0067Sum of US EPA PFAS (PFOS + PFOA)* µg/L 0.037 0.012 0.018 <0.001 0.0027 0.0027Sum of WA DER PFAS (n=10)* µg/L 0.054 0.018 0.037 <0.005 0.0067 0.0067
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Biota results BIO_W04_BRIM_180130 BIO_W04_GAR1_180130 BIO_W04_GAR2_180130 BIO_W04_MULLET1_180130 BIO_W04_MULLET2_180130 CC_B2_BREAM1_180206 CC_B2_BREAM2_180207 CC_B2_BREAM3_180207
Yellowfin/Black bream Eastern sea garfish Eastern sea garfish Sea mullet Sea mullet Yellowfin/Black bream Yellowfin/Black bream Yellowfin/Black breamFillets ‐ 5 Fillets ‐ 5 Fillets ‐ 3
HMAS ALBATROSS (251529) Units B18‐Fe01864 B18‐Fe01862 B18‐Fe18843 B18‐Fe01863 B18‐Fe18844 S18‐Fe09253 S18‐Fe10212 S18‐Fe10211
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.51H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.51H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.51H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.52‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5N‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5N‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5N‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5N‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorooctane sulfonamide (FOSA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorodecanesulfonic acid (PFDS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluoroheptanesulfonic acid (PFHpS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorohexanesulfonic acid (PFHxS) µg/kg <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3Perfluorooctanesulfonic acid (PFOS) µg/kg 1.1 2.7 2.4 6.3 6.2 1 0.9 0.4Perfluoropentanesulfonic acid (PFPeS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorodecanoic acid (PFDA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorododecanoic acid (PFDoA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluoroheptanoic acid (PFHpA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorohexanoic acid (PFHxA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorononanoic acid (PFNA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorooctanoic acid (PFOA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluoropentanoic acid (PFPeA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorotetradecanoic acid (PFTeDA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorotridecanoic acid (PFTrDA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluoroundecanoic acid (PFUnA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
SpeciesNumber in composite
1 of 11
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B2_EPRAWZ1_180206 CC_B2_LUDERICK1_180206 CC_B2_LUDERICK2_180206 CC_B2_LUDERICK3_180206 CC_B2_LUDERICK4_180206 CC_B2_MCRAB1_180206 CC_B2_MULLET1_180206 CC_B2_MULLET2_180206
Freshwater prawn Luderick Luderick Luderick Luderick Mud crab Sea mullet Sea mulletWhole ‐ 3 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Whole ‐ 1 Fillets ‐ 5 Fillets ‐ 5S18‐Fe09252 S18‐Fe09234 S18‐Fe09255 S18‐Fe09249 S18‐Fe09243 S18‐Fe09241 S18‐Fe09244 S18‐Fe09242
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.50.9 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.59.3 <0.3 <0.3 <0.3 <0.3 0.7 <0.3 <0.336 6.6 5.2 4.9 5.8 3.9 6.4 2.7
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
2 of 11
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B2_MULLOWAY1_180206 CC_B2_MULLOWAY2_180206 CC_B2_PERCH1_180206 CC_B2_PERCH2_180206 CC_B2_PERCH3_180206 CC_B2_PERCH4_180206 CC_B2_SOUL1_180206 CC_B2_STREVALLY1_180206
Mulloway Mulloway Estuary perch Estuary perch Estuary perch Estuary perch Black sole Silver trevallyFillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Whole ‐ 1 Fillets ‐ 5S18‐Fe09254 S18‐Fe09235 S18‐Fe09257 S18‐Fe09566 S18‐Fe09233 S18‐Fe09238 S18‐Fe09251 S18‐Fe09236
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 5.9 <0.50.5 <0.3 0.5 <0.3 0.5 0.4 27 1.115 11 15 17 18 18 340 23
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1.3 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
3 of 11
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B2_STREVALLY2_180206 CC_B2_STREVALLY3_180207 CC_B2_WHITING1_180206 CC_B3_BREAM1_180204 CC_B3_BREAM2_180204 CC_B3_BREAM3_180206 CC_B3_BREAM4_180207 CC_B3_LUDERICK1_180204
Silver trevally Silver trevally Sand whiting Yellowfin/Black bream Yellowfin/Black bream Yellowfin/Black bream Yellowfin/Black bream LuderickFillets ‐ 5 Fillet ‐ 1 Fillet ‐ 1 Fillets ‐ 5 Fillets ‐ 3 Fillets ‐ 2 Fillet ‐ 1 Fillets ‐ 5S18‐Fe09237 S18‐Fe10213 S18‐Fe09240 S18‐Fe06752 S18‐Fe06716 S18‐Fe09246 S18‐Fe10210 S18‐Fe06750
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 0.7 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.52.2 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.337 13 12 <0.3 <0.3 <0.3 1.2 1.6
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
4 of 11
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B3_LUDERICK2_180204 CC_B3_LUDERICK3_180204 CC_B3_LUDERICK4_180206 CC_B3_MULLET1_180204 CC_B3_MULLET2_180204 CC_B3_MULLET3_180204 CC_B3_MULLET4_180204 CC_B3_PERCH1_180204
Luderick Luderick Luderick Sea mullet Sea mullet Sea mullet Sea mullet Estuary perchFillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 3 Fillets ‐ 2S18‐Fe06751 S18‐Fe06714 S18‐Fe09245 S18‐Fe06747 S18‐Fe06748 S18‐Fe06749 S18‐Fe06718 S18‐Fe06713
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.32.5 1.6 1.6 3 3.5 3.3 2.8 11<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
5 of 11
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B3_SCRAB1_180206 CC_B3_STREVALLY1_180204 CC_B3_STREVALLY2_180206 CC_B3_STREVALLY3_180207 CC_B3_WHITING1_180204 CC_B3_WHITING2_180206 CC_B3_WHITING3_180206 CC_B3_WHITING4_180207
Blue swimmer crab Silver trevally Silver trevally Silver trevally Sand whiting Sand whiting Sand whiting Sand whitingWhole ‐ 2 Fillet ‐ 1 Fillets ‐ 5 Fillet ‐ 1 Fillets ‐ 3 Fillets ‐ 5 Fillets ‐ 3 Fillets ‐ 3S18‐Fe09247 S18‐Fe06715 S18‐Fe09250 S18‐Fe10209 S18‐Fe06717 S18‐Fe09248 S18‐Fe09256 S18‐Fe10208
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.51.4 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.34.5 2.5 4.2 2.2 <0.3 1.6 1.5 0.8<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
6 of 11
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
SR_B1_BASS1_180208 QA102_180208 SR_B1_BASS2_180208 SR_B1_DFLATHEAD1_180208 SR_B1_FMULLET1_180208 SR_B1_FMULLET2_180208 SR_B1_FMULLET3_180208 SR_B1_FMULLET4_180208
Australian bass SR_B1_BASS1_180208 Australian bass Dusky flathead Tiger mullet Tiger mullet Tiger mullet Tiger mulletFillets ‐ 5 Fillets ‐ 5 Fillet ‐ 1 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5S18‐Fe12616 N18/005396 S18‐Fe12618 S18‐Fe12612 S18‐Fe12617 S18‐Fe12611 S18‐Fe12615 S18‐Fe12614
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.5 <0.3 <0.3 <0.3 <0.3 <0.3 <0.35.5 3.2 9.4 4.3 2.2 2.3 3.8 2.8<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.3 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
7 of 11
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
SR_B1_MULLET1_180208 QA101_180208 SR_B1_MULLET2_180208 SR_B1_MULLET3_180208 SR_B1_MULLET4_180208 SR_B1_PERCH1_180208 SR_B2_BASS1_180209 SR_B2_BREAM1_180209
Sea mullet SR_B1_MULLET1_180208 Sea mullet Sea mullet Sea mullet Estuary perch Australian bass Yellowfin/Black breamFillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐3 Fillets ‐ 3 Fillets ‐ 5 Fillets ‐ 2S18‐Fe12619 N18/005395 S18‐Fe12613 S18‐Fe12609 S18‐Fe12608 S18‐Fe12610 S18‐Fe13497 S18‐Fe13494
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 5.1 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.5 <0.3 <0.3 <0.3 <0.3 <0.3 <0.32.1 1.6 3.4 1.5 1.6 1.4 5.3 1.3<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.3 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
8 of 11
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
SR_B2_FMULLET1_180209 SR_B2_GARFISH1_180209 SR_B2_LUDERICK1_180209 SR_B2_MULLET1_180209 SR_B2_MULLET2_180209 SR_B2_MULLET3_180209 SR_B2_MULLET4_180209 SR_B2_PERCH1_180209
Tiger mullet Eastern sea garfish Luderick Sea mullet Sea mullet Sea mullet Sea mullet Estuary perchFillet ‐ 1 Whole ‐ 1 Fillet ‐ 1 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillets ‐ 5 Fillet ‐ 1S18‐Fe13492 S18‐Fe13498 S18‐Fe13496 S18‐Fe13484 S18‐Fe13487 S18‐Fe13486 S18‐Fe13485 S18‐Fe13491
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.320 2 1.2 8.5 12 13 22 2.3
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
9 of 11
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
SR_B3_BASS1_180210 SR_B3_BREAM1_180210 SR_B3_HERRING1_180210 SR_B3_MACRAB1_180210 SR_B3_MULLET1_180209 SR_B3_MULLET2_180210 SR_B3_PERCH1_180210 SR_B3_SMULLET1_180210
Australian bass Yellowfin/Black bream Herring Mud crab Sea mullet Sea mullet Estuary perch Sand mulletFillet ‐ 1 Fillet ‐ 1 Whole ‐ 1 Whole ‐ 2 Fillets ‐ 5 Fillets ‐ 3 Fillets ‐ 2 Fillet ‐ 1S18‐Fe13501 S18‐Fe13488 S18‐Fe13490 S18‐Fe13499 S18‐Fe13483 S18‐Fe13489 S18‐Fe13495 S18‐Fe13500
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.3 <0.3 1.8 <0.3 <0.3 <0.3 <0.36.7 1.2 8 2.9 5.3 5.4 3.6 10<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
10 of 11
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H‐perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H‐perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H‐perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H‐perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2‐(N‐ethylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐EtFOSE) µg/kg2‐(N‐methylperfluoro‐1‐octane sulfonamido)‐ethanol (N‐MeFOSE) µg/kgN‐ethylperfluoro‐1‐octane sulfonamide (N‐EtFOSA) µg/kgN‐ethyl‐perfluorooctanesulfonamidoacetic acid (N‐EtFOSAA) µg/kgN‐methylperfluoro‐1‐octane sulfonamide (N‐MeFOSA) µg/kgN‐methyl‐perfluorooctanesulfonamidoacetic acid (N‐MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
SR_B3_TAILOR1_180210
TailorFillet ‐ 1S18‐Fe13493
<0.5<0.5<0.5<0.5
<0.5<0.5<0.5<0.5<0.5<0.5<0.5
<0.5<0.5<0.5<0.30.9<0.5
<0.5<0.5<0.5<0.5<0.5<0.5<0.5<0.5<0.5<0.5<0.5
11 of 11
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Appendix B Aurecon (2018) Report: Human Health and Ecological Risk Assessment Addendum – Field Investigation
Investigation of per- and poly-fluoroalkyl substances at HMAS Albatross Human Health and Ecological Risk Assessment Addendum – Field Investigation Department of Defence
Reference: 251529/DEHP-ID-183-D1
Revision: 1
21 June 2018
Project 251529/DEHP-ID-183-D1 File HMAS Albatross HHERA Addendum Field Investigation.docx 21 June 2018 Revision 1
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Report title Human Health and Ecological Risk Assessment Addendum – Field Investigation
Document ID Project number 251529/DEHP-ID-183-D1
File path http://cs.au.aurecongroup.com/cs/cs.exe/open/184039429
Client Department of Defence Client reference DEHP-ID-183-D1
Rev Date Revision details/status Author Reviewer Verifier (if required)
Approver
0 22 March 2018 Draft 0 Aurecon Aurecon Aurecon Aurecon
1 21 June 2018 Final Aurecon Aurecon Aurecon Aurecon
Current revision 1
Contents 1 Introduction .......................................................................................................................................... 1
1.1 Background .............................................................................................................................. 1 1.2 Objectives ................................................................................................................................. 1 1.3 Scope of works ......................................................................................................................... 1 1.4 Relevant legislation, standards and guidelines ........................................................................ 2 1.5 Data quality objectives and indicators ...................................................................................... 2 1.6 Statement of limitations ............................................................................................................ 5
2 Site identification and sampling locations ........................................................................................ 7 2.1 Site background ........................................................................................................................ 7 2.2 Sampling locations ................................................................................................................... 9
3 Fieldwork methodology .................................................................................................................... 11 3.1 Program .................................................................................................................................. 11 3.2 Field data collection and sampling ......................................................................................... 11 3.3 Permits to conduct works ....................................................................................................... 12 3.4 Laboratory analysis ................................................................................................................ 12 3.5 Compliance with the SAQP .................................................................................................... 12
4 Field results and observations ......................................................................................................... 13 4.1 Shoalhaven River sampling .................................................................................................... 13 4.2 Currambene Creek sampling ................................................................................................. 14 4.3 Lowland rainforest sampling ................................................................................................... 15
5 Laboratory results ............................................................................................................................. 16 5.1 General ................................................................................................................................... 16 5.2 Biota results ............................................................................................................................ 16 5.3 Surface water results .............................................................................................................. 18 5.4 Sediment results ..................................................................................................................... 18 5.5 Soil results .............................................................................................................................. 19
6 Quality assurance and quality control ............................................................................................ 20 6.1 Introduction ............................................................................................................................. 20 6.2 Data validation summary ........................................................................................................ 20
7 Conclusion ......................................................................................................................................... 21 8 References ......................................................................................................................................... 22
Appendices Appendix A
Summary laboratory results
Appendix B Laboratory certificates
Appendix C QA/QC results
Figures Figure 2.1 HHERA Addendum biota sampling locations Figure 2.2 HHERA Addendum lowland rainforest sampling locations Figure 4.1 Rainfall at Nowra, New South Wales (BoM 2018)
Tables Table 1.1 Scope of works Table 1.2 Data quality objectives Table 1.3 Data quality indicators Table 2.1 Sampling locations and species targeted Table 3.1 Program of works Table 3.2 Sampling methodology Table 4.1 Biota samples from Shoalhaven River Table 4.2 Surface water quality along Shoalhaven River Table 4.3 Biota samples from Currambene Creek Table 4.4 Surface water quality along Currambene Creek Table 4.5 General soil descriptions Table 5.1 Biota PFAS analytical results Table 5.2 Surface water PFAS analytical results Table 5.3 Sediment PFAS analytical results Table 5.4 Soil and soil leachate PFAS analytical results
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1 Introduction
1.1 Background A Detailed Site Investigation (DSI) and Human Health and Ecological Risk Assessment (HHERA) of per- and poly-fluoroalkyl substances (PFAS) at HMAS Albatross completed on behalf of the Department of Defence (Defence) in 2017. Based on the findings of the HHERA, additional biota sampling and risk assessment is required downstream on the Shoalhaven River and Currambene Creek. Additional soil sampling onsite, within the Lowland Rainforest areas, is also required.
This report presents the methodologies and findings of the HHERA Addendum field investigations. Through implementation of the Sampling and Analysis Quality Plan (SAQP), this investigation aims to provide a reliable data set to further assess potential risks to human health and ecological receptors on-base and off-base associated with PFAS which has originated from HMAS Albatross.
1.2 Objectives The objectives of the HHERA Addendum field investigation are to:
Undertake additional sampling and analysis to allow a quantitative evaluation of the potential risks to human health within the Shoalhaven River and Currambene Creek due to PFAS presence arising from the use and storage of AFFF at HMAS Albatross
Undertake additional sampling and analysis to allow a qualitative evaluation of the potential risks to terrestrial and aquatic (freshwater and marine if applicable) ecological receptors within Lowland Rainforest areas on base and within the Shoalhaven River and Currambene Creek due to PFAS presence arising from the use and storage of AFFF at HMAS Albatross.
1.3 Scope of works The field investigation was conducted to meet the requirements of the HHERA Addendum SAQP. The scope of works of the investigation subject to this report are summarised in Table 1.1.
Table 1.1 Scope of works
Key action Description
Field work Collection of field data and sampling from defined locations, as specified in the HHERA Addendum SAQP
The field investigation included: − Collection of waterway biota samples (fish and/or crustacea) within the Shoalhaven River
and Currambene Creek − Collection of water and sediment samples from each waterway biota sampling site − Collection of soil samples from the Lowland Rainforest situated on base
Groundwater sampling was not conducted as part of the HHERA Addendum as the objectives related to potential risks to human health and ecological receptors from Shoalhaven River and Currambene Creek as well as ecological receptors from the on base Lowland Rainforest.
Laboratory analysis
Analysis of waterway biota, surface water, sediment and soil samples (including intra- and inter-laboratory duplicates) for PFAS
Assessment of field investigation results
Field investigation results to be reviewed and assessed as part of the HHERA Addendum. Field investigation results are not analysed as part of this reporting scope
Reporting HHERA field investigation methodologies and results are summarised and presented in this report. Recommendations based on investigation findings are presented in the HHERA Addendum
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1.4 Relevant legislation, standards and guidelines Methods and standards set out in relevant guidance documents will be adopted for the investigation. The guidance documents are listed as follows:
Australian and New Zealand Environment Conservation Council (ANZECC) (2000), Australian and New Zealand Guidelines for Fresh and Marine Water Quality
NEPM (2013), National Environment Protection (Assessment of Site Contamination) Measure 1999 (Amendment 1, 2013)
enHealth (2012), Environmental Health Risk Assessment Guidelines for Assessing human health risk from environmental hazards. Produced by the Council of Australian Health Ministers
WA Department of Environment Regulation (2017), Interim Guideline on the Assessment and Management of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS)
HEPA (Heads of EPAs Australia and New Zealand) (2018), PFAS National Environmental Management Plan, January 2018 (noting that sampling was undertaken prior to the release of the NEMP on 16 February 2018)
NSW EPA, 2016, Designing Sampling Programs for Sites Potentially Contaminated by PFAS, Guidance Document
Department of Health 2017, Health Based Guidance Values for PFAS for Use in Site Investigations in Australia
1.5 Data quality objectives and indicators
1.5.1 Data quality objectives Data quality objectives (DQOs) are qualitative and quantitative statements derived from the outputs of the first six steps of the seven steps DQO process that:
Clarify the study objective Define the most appropriate type of data to collect Determine the most appropriate conditions from which to collect data Specify tolerable limits on decision errors which will be used as the basis for establishing the quantity and
quality of data needed to support the decision
This SAQP addresses the seventh step of the DQO process, which requires an SAQP to be developed to generate data to meet the DQOs.
The DQOs for this investigation have been prepared in line with the DQO process outlined in US Environmental Protection Agency (EPA) (2006), NEPM 2013 (Schedule B2) and the Guidelines for the NSW Site Auditor Scheme (DEC 2006), and are presented in the seven-step DQO approach presented in Table 1.2.
Table 1.2 Data quality objectives
Process Response
Step 1: State the Problem
Following completion of the HHERA, recommendations were made to undertake additional biota sampling to allow for further assess human health and ecological risk to be undertaken downstream of existing sampling locations, as well as soil sampling in the Lowland Rainforest areas on base to assess bioaccumulation risks. Biota sampling along the Shoalhaven River (upstream and downstream of Calymea Creek) and further downstream along Currambene Creek, as well as soil sampling in the Lowland Rainforest areas is required to assess human health and ecological risks.
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Process Response
Step 2: Identify the Decision
The principle objectives of the HHERA Addendum are to: Assess the nature and extent of PFAS in biota further downstream on the Shoalhaven
River and Currambene Creek in accordance with the relevant standards and guidelines (refer Section 1.4)
Assess the nature and extent of PFAS in soil in the Lowland Rainforest areas on base. Assess the adequacy and completeness of all information gathered Provide sufficient input to allow regulatory bodies to make informed decisions on
suitable management measures for the protection of human health and the environment, including: − Identification of suitability for consumption of biota in the surrounding area − Identification of the potential for bioaccumulation in the surrounding area
Step 3: Identify the Inputs to the Decision
Objectives and scope of works of this investigation Site history and previous investigations, including the DSI and HHERA CSM, including potential sources, pathways and receptors Potential contaminants of concern (PFAS) Field methods, such as sampling, sample storage and preservation, laboratory
methods, quality control (QC) and quality assurance (QA) Media to be sampled (biota including fish and crustacea, surface water, sediment and
soil samples) and location of samples Adopted assessment criteria for surface water and soil Where possible, biota samples will be collected at the change of tide, as a greater
number of biota are likely to be present during this time. To ensure consistency, surface water samples will also be collected during this period.
Field data (including water quality parameters and visual/olfactory observations) and laboratory analysis
Step 4: Define the Boundaries of the Study
The field investigation comprised sampling locations within HMAS Albatross and off site to provide additional information and allow assessment of the nature and extent of PFAS in biota in the surrounding waterways and in soil from the Lowland Rainforest areas on base, in accordance with the relevant standards and guidelines. Biota sampling will include fish/crustacea and water and sediment samples at locations described in Section 2.2. Soil sampling will also be undertaken from the four areas of Lowland Rainforest areas on the base. The sampling unit for soil and sediment will be an assessed, collected and logged soil sample in a HDPE jar. The sampling unit for surface water will be an assessed, collected and field screened water sample in a HDPE bottle. The sampling unit for biota will be an assessed, collected and identified sample collected from each sampling location and will comprise, where practicable, four composite samples each comprised of five individuals (or fillets depending on the fish size) from each species. Species targeted are provided in Section 2.2.1. All sampling containers/bags will be laboratory supplied.
Step 5: Develop a Decision Rule
The field investigation will be designed to collect data on PFAS concentrations in biota to assess the nature and extent of PFAS compounds in biota in the surrounding area, further downstream of previous sampling locations, as well as allowing the undertaking of further risk assessment based on the biota PFAS data. Assessment of PFAS presence and potential risks to human health and ecology receptors will be undertaken as per the Methodology for HHERA: HMAS Albatross (EnRiskS 2016) The HHERA Addendum will: Undertake a quantitative evaluation of the potential risks to human health associated
with potential direct contact exposures with PFAS from edible produce (including fish products) in the off base area, in the context of the existing land uses. This includes public users of off base waterways downstream of the base
To undertake a qualitative evaluation of the potential risks to terrestrial and aquatic (freshwater) ecological receptors in the on and off base areas
To undertake a qualitative evaluation of the potential risks to terrestrial, freshwater and (if applicable) marine ecological receptors in the off base area
The HHERA Addendum will be undertaken in general accordance with the relevant guidelines (refer Section 1.4).
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Process Response
Step 6: Specify Tolerable Limits on Decision Errors
Acceptance limits on field and laboratory data collected for this investigation will be in accordance with NEPM 2013 and the Western Australia Department of Environment Regulation 2017 Interim Guideline on the Assessment and Management of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS). The acceptable limits on decision errors to be applied in the investigation and the manner of addressing possible decision errors have been developed based on the data quality indicators (DQIs) of precision, accuracy, representativeness, comparability and completeness, and are presented in Section 1.5.2. The potential for significant decision errors will be minimised by completing a robust QA/QC program and by completing an investigation that has an appropriate sampling and analytical density for the purposes of the investigation. Completeness of data collected will be determined by a combination of factors, including: The target amount of four composite samples, consisting of five individuals for each
species to be caught (as per Section 2.2.1), as allowed by up to two weeks of fishing across the Shoalhaven River and Currambene Creek
Species likely to be caught (based on commercial fisher local knowledge and information provided by NSW Department of Primary Industries (DPI)), and those species able to be caught over the duration of the investigation. Species able to be caught over the duration of the investigation will be representative of those species likely to be caught by commercial and recreational fishers in the same period.
Step 7: Optimise the Design for Obtaining Data
The sampling strategy and SAQP have been developed in accordance with relevant guidelines specified in Section 1.4 through targeted sampling of potential source-pathway-receptors. Samples are to be analysed by a National Association of Testing Authorities (NATA) accredited laboratory within approved sample holding times. The recommended holding time for PFAS is 14 days.
1.5.2 Data quality indicators The DQIs for the assessment are presented in Table 1.3.
Table 1.3 Data quality indicators
DQI Field Laboratory Acceptability limits
Completeness Water identified to be potentially contain PFAS pose a potential risk to health, safety and the environment and may require management to remove the risk to human health and the environment. The area subsequently requires biota sampling and analysis
Surface water and sediment samples will be collected during waterway biota sampling
Biota samples will be collected at the turn of the tide where practicable
Soil samples will be collected in the Lowland Rainforest areas
Appropriate sampling procedures to be used (refer Section 1.4)
Suitably qualified field team to undertake investigation, led by suitably qualified person
Correct documentation to be completed (eg chain of custodies)
All required samples analysed in accordance with the SAQP, where practicable
Appropriate laboratory methods to be employed in accordance with US Department of Defence Quality Systems Manual (QSM) Version 5.1
Appropriate limits of reporting (LORs)
Sample documentation correct (eg chain of custodies, sample receipt notification etc)
Sample holding times in compliance (14 days for PFAS)
All required data must be obtained for critical samples to meet the objectives As per NEPM 2013
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DQI Field Laboratory Acceptability limits
Comparability Correct sample procedures used at each location
Experienced field team Same type (medium, volume
and sampling technique) of samples collected in accordance with laboratory requirements and Interim Guideline on the Assessment and Management of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) (Department of Environment Regulation 2017)
Same analytical methods used
Appropriate LORs Samples submitted to the
same NATA accredited laboratory
Analytical data is presented in the same unit
Results will be compared against previous investigation results
As per NEPM 2013 Department of Defence QSM 5.1 Western Australian Guidelines (Department of Environment Regulation 2017)
Representativeness Appropriate media sampled All media identified (ie fish,
crustacea, soil, water, sediment)
All required samples analysed
As per NEPM 2013 and Department of Defence QSM 5.1
Precision Correct sample procedures used at each location
Collection of appropriate QA/QC samples
Analysis of: Intra- and inter-laboratory
samples (1 per 10 samples collected, per sample type)
Laboratory duplicate samples
Relative percent deviation (RPD) of 30-50% RPDs may exceed this range where: Results are <10x
the LOR, or Results are <20x
the LOR and the RPD is <50%
Accuracy Sampling procedures appropriate and complied with
Collection of appropriate QA/QC samples
Analysis of: Method blanks Laboratory surrogate
spikes Laboratory control
samples Reference material Matrix spikes Matrix spike duplicates Surrogate spikes
Non-detect for PFAS
70-130%
1.6 Statement of limitations Aurecon performed the services in a manner consistent with the normal level of care and expertise exercised by members of the environmental profession. No warranties express or implied, are made. It should be noted that some information provided in this report is reliant on information provided by third parties such as Department of Defence and various State and Commonwealth government departments. Aurecon takes no responsibility for the quality/accuracy of information provided by third parties.
The outcome of this report is limited to information supplied for the activities associated with the scope of works only. It is intended that this assessment provides a description of the identified PFAS sources, pathways and receptors and recommendations on how to address and manage any issues at the location in question.
Soil and rock formations are often variable, resulting in heterogeneous distribution of PFAS across a site. PFAS concentrations may be estimated at chosen sample locations, however, conditions between sample sites can only be inferred on a basis of geological and hydrological conditions and the nature and the extent of the PFAS. Boundaries between zones of variable PFAS concentrations are often indistinct, and therefore interpretation is based on available information and the application of professional judgement. Aurecon uses best judgement acquired from working on similar sites and makes recommendations based solely on the results obtained.
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We note that this report has been prepared for the use of Defence only and is based on information provided by Defence. Aurecon takes no responsibility and disclaims all liability whatsoever for any loss or damage that Defence may suffer as a result of using or relying on any such information or recommendations contained in this report, except to the extent Aurecon expressly indicates in this report that it has verified the information to its satisfaction. This report does not provide a complete assessment of the environmental status of the site, and it is limited to the scope defined herein. Should further information become available regarding the conditions at the site, including previously unknown likely sources of PFAS, migration pathways or receptors, Aurecon reserves the right to review the report in the context of the additional information.
The findings, observations and conclusions expressed by Aurecon are not, and should not be considered as an opinion concerning the commercial feasibility of the property or asset. The report may contain various remarks about and observations on legal documents and arrangements such as contracts, supply arrangements, leases, licences, permits and authorities. A consulting scientist can make remarks and observations about the technical aspects and implications of those documents and general remarks and observations of a non-legal nature about the context of those documents. However, as consulting scientists, Aurecon is not qualified, cannot express and should not be taken as in any way expressing any opinion or conclusion about the legal status, validity, enforceability, effect, completeness or effectiveness of those arrangements or documents or whether what is provided for is effectively provided for. They are matters for legal advice.
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2 Site identification and sampling locations
2.1 Site background
2.1.1 Lowland Rainforest SKM (2006) identified areas of Lowland Rainforest, an endangered ecological community under the Threatened Species Conservation Act 1995 (NSW). The key characteristics of the ecological community include (DoEE 2018):
Distribution within the South Eastern Queensland bioregions and the NSW North Coast and Sydney bioregions
Soils derived from basalt or alluvium
Altitude of less than 300 m above sea level
Areas of high annual rainfall (>1,300 mm)
More than 2 km inland from the coast
Structure of the ecological community is typically a tall (20 to 30 m) closed forest, often with multiple canopy layers
Patches of the ecological community typically have high species richness
It should be noted that the Lowland Rainforest at HMAS Albatross has yet to be formally listed as an endangered ecological community.
2.1.2 Shoalhaven River
General Surface runoff from the northern and western portions of the site drain northwest to an unnamed tributary of Calymea Creek, named Braidwood Road drain for the purposes of this investigation. Calymea Creek also receives water from further south within Colymea State Conservation Area and Colymea State Forest. Cabbage Tree Creek and Flat Rock Creek flow from the north of the site through Triplarina Nature Reserve and Mundamia and West Nowra. Close to the site, these creeks are ephemeral in nature, however further from the site, the creeks become perennial, particularly as they join with other tributaries and are potentially recharged by the groundwater.
Shoalhaven River originates south of Braidwood and flows for 300 km in a north-easterly direction. The River flows through Nowra and receives water from base, through Calymea Creek, Cabbage Tree Creek and Flat Rock Creek. Primary industries in the Shoalhaven River include commercial fishing, oyster growing and vegetable farming. There is also a tourism industry with activities including recreational fishing, surfing and boating.
Fishing practices The Shoalhaven River supports a large population of commercial fishers that produce seafood for domestic and export markets (50/50 split). The main species targeted within the Shoalhaven River include (SOURCE):
School prawn
Luderick
Sea mullet
Silver biddy
Yellowfin bream
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Dusky flathead
Sand whiting
Mud crab
Blue swimmer crab
Approximately 100 to 200 tonnes of seafood are caught annually in the Shoalhaven River.
A survey of recreational fishing in Shoalhaven River was completed in 2011 and noted that there were very few fishers observed upstream of the Nowra Bridge, although noted that more fishers might be expected in the cooler months of the year, when bass and estuary perch are targeted in this region (Miles and West 2011). Dusky flathead, Yellowfin/Black bream and Luderick were caught and kept in the largest numbers (Miles and West 2011). It was estimated that recreational anglers spent approximately 212,500 hours fishing in the Shoalhaven River and was split evening between local and visiting fishers. During the surveyed year, between 52,000 and 68,000 fish were captured and kept and a further 195,000 to 240,000 fish were captured and released (Miles and West 2011).
2.1.3 Currambene Creek
General Currambene Creek is a primary migration pathway for PFAS from HMAS Albatross, including its two major tributaries, Yerriyong Gully and Parma Creek. The upper reaches of Currambene Creek (and Yerriyong Gully) are typically prone to high velocity flushes of water during rainfall events and low flows or limited connectivity throughout the remainder of the year (SKM 2009). As such, the upper reaches of both creeks provided minimal habitat for fish (SKM 2009). Further away from HMAS Albatross, Currambene Creek and Yerriyong Gully become perennial in nature as water from the wider catchment is captured and the creeks are potentially recharged by the groundwater.
The majority of upper Currambene Creek (east of Princes Highway) is a Sanctuary Zone with no fishing permitted. However, the lower reaches of Currambene Creek have the potential to be used for recreational boating, swimming and fishing.
Currambene Creek flows into Jervis Bay at Huskisson, which is a Marine Park managed by the NSW DPI. The marine area at Huskisson is used for activities, including fishing, boating, scuba diving, snorkelling and some commercial fishing (NSW Marine Parks Authority 2011).
Fishing practices Commercial fishing in Currambene Creek, a Habitat Protection Zone, is minimal to non-existent, although recreational fishing is known to occur in Currambene Creek. Recreational fishing in upper Currambene Creek, above the Sanctuary Zone, likely targets Australian Bass (largely catch and release) and is known for yabbying. Recreational fishing in lower Currambene Creek, in the Habitat Protection Zone, targets Yellowfin Bream, Dusky Flathead, Luderick, crabs and garfish.
In Jervis Bay, outside the Marine Park Sanctuary Zones, both commercial and recreational fishing occurs. Recreational fishing in Jervis Bay is estimated to catch approximately 21 tonnes per year, targeting Blue and Slimy Mackerel (as bait fish and for human consumption), Dusky Flathead, Sand Whiting, Sand Flathead, Squid, as well as rock lobster, Yellowfin Bream, Snapper, Yellowtail Kingfish and Eastern Australian Salmon.
Species targeted for commercial fishing in Jervis Bay include Sand Whiting, Yellowtail Scad, Striped Grunter, Yellowfin Bream, Common Silver biddy, Tailor, Longfin Pike, Blue Mackerel, Southern Calamari, Gummy Shark, Snapper, Silver Trevally, Blue Weed-Whiting, Tarwhine, Sole, Australian Salmon, Australian Sardine, Onespot Puller, Mulloway, Sea Mullet, Luderick, Eastern Sea Garfish, Eastern School Whiting, Sweep, Sandy Sprat (Whitebait). Commercial catch within the Jervis Bay estuary is estimated at 260 kg per year and the commercial catch from ocean hauling, including Jervis Bay, varies from several hundred to over 25,000 kg.
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2.2 Sampling locations
2.2.1 Shoalhaven River and Currambene Creek Six locations were selected as sampling locations (three on the Shoalhaven River and three on Currambene Creek), focusing on areas where the general public have access to Shoalhaven River and are likely to undertake recreational fishing, as well as providing a spread of sample locations to provide representative data along the waterways. Locations selected are presented in Figure 2.1 and include:
Shoalhaven River:
− Approximately 7 km upstream of Calymea Creek and Shoalhaven River confluence, closer to Burrier, but still in intertidal zone (SR-B1)
− Confluence of Calymea Creek and Shoalhaven River (SR-B2)
− Approximately 7 km downstream of confluence of Calymea Creek and Shoalhaven River, closer to Watersleigh (SR-B3)
Currambene Creek:
− Existing water/sediment location at WW04
− Approximately 5.7 km from the mouth of Currambene Creek (CC-B2)
− Approximately 2.2 km from the mouth of Currambene Creek, at the oxbow adjacent/south of Woollamia (CC-B3)
Species targeted in the Shoalhaven River and Currambene Creek are presented in Table 2.1.
Table 2.1 Sampling locations and species targeted
Sampling locations Species targeted
Shoalhaven River (SR-B1, SR-B2 and SR-B3)
Australian bass Mulloway School prawn Luderick Sea mullet Silver biddy Yellowfin/Black bream (including hybrids) Dusky flathead Sand whiting Mud crab Bream Others as caught and assessed during fishing activities Others as identified/highlighted by NSW DPI/EPA relevant to
commercial/recreational fishing
Currambene Creek Upper (CC-B1 and potentially CC-B1 alternate) Replaced by W04 due to sampling difficulties at CC-B1 and alternate (discussed in Section 3.5).
Australian bass Common yabby Eel Yellowfin/black bream (including hybrids) Dusky flathead Luderick Mud crabs Garfish Others as caught and assessed during fishing activities Others as identified/highlighted by NSW DPI/EPA relevant to
commercial/recreational fishing
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Sampling locations Species targeted
Currambene Creek Mid to Lower Reaches, closer to mouth of creek (CC-B2 and CC-B3)
Blue/Slimy mackerel Squid Sand flathead Sand whiting Rock lobster Snapper Yellowtail kingfish Sea mullet Silver biddy Salmon Others as caught and assessed during fishing activities Others as identified/highlighted by NSW DPI/EPA relevant to
commercial/recreational fishing
2.2.2 Lowland rainforest Soil sampling was undertaken in the four distinct areas of Lowland Rainforest situated at HMAS Albatross (refer Figure 2.2). Three soil sampling locations were targeted at each of these areas, with two soil samples taken per location.
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C ROOKHAVEN CRE EKSHOALHAVEN RIVERSHOALHAVEN RIVER
S HOAL
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SHOALHAVEN RIVER
CURRAMBENECREE K
SW13-F
SW14-F
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W05 W06W04
CC-B1(alternate)
CC-B1
Figure 2.1: HHERA Addendum biota sampling locationsHMAS Albatross HHERA°
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Source: Imagery - Department of Defence (2015).
Legend
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Coordinate System: GDA 1994 MGA Zone 56
!(Targeted Biota, sediment and surface watersample location but unable to be sampled
#*Biota, sediment and surface water samplelocation (this investigation)
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HMAS Albatross Site Boundary
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HA89
HA90HA91
HA92
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HA94
HA95
HA96HA97
PARMACREEK
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CUR RAMBENE CREEK
Figure 2.2: HHERA Addendum lowland rainforest sampling locationsHMAS Albatross HHERA°
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Source: Imagery - Department of Defence (2015).
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A3 scale: 1:20,000 Job No: 251529-001-01
Date: 1/03/2018Aut
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Coordinate System: GDA 1994 MGA Zone 56
!A Hand auger sample locations
HMAS Albatross Site BoundaryCreeks
Endangered Ecological Communities (NSW)Lowland Rainforest
0 850425Metres
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3 Fieldwork methodology
3.1 Program A summary of the program of works for the field investigation is provided in Table 3.1.
Table 3.1 Program of works
Activity Date Organisation
Lowland rainforest sampling 31 January 2018 Aurecon
Waterway sampling (Currambene Creek) 30 January 2018 4 to 7 February 2018
Aurecon
Waterway sampling (Shoalhaven River) 8 to 10 February 2018 Aurecon
3.2 Field data collection and sampling The sampling techniques implemented in accordance with the methodology in the Sampling and analysis quality plan (SAQP) for the Human Health and Ecological Risk Assessment (Aurecon 2017) and is summarised in Table 3.2.
Table 3.2 Sampling methodology
Activity Details
Safety Safe Work Method Statements (SWMS) and “Take 5” Risk Assessments were completed prior to commencement of site works.
Site inspection Proposed sample locations were inspected where accessible, and vetted for integrity to determine their suitability for sampling.
Waterway biota sampling (crustacea and fish)
Biota sampling included the collection of fish and crustacea at six locations. Samples were collected via the use of mesh nets and baited traps. Fish samples were gutted and filleted on site, with flesh samples sent to the laboratory to be analysed for PFAS compounds.
Surface water and sediment sampling
A surface water sample was taken from each of the waterway biota sampling locations and analysed for the full PFAS suite, in addition to heavy metals and general water quality parameters including nutrients, total organic carbon (TOC) pH, electrical conductivity (EC) and total suspended solids and total dissolved solids (TDS). Sediment samples were collected from accessible points as close to the proposed locations points as practicable. A fresh pair of disposable nitrile gloves were used for handling of each sample to minimise the opportunity for cross contamination. Samples were collected directly into laboratory supplied labelled sample bottles and stored in a chilled cooler prior to submission to the laboratory for testing under chain of custody documentation. The field parameter probes were decontaminated after each sample was collected.
Quality assurance and quality control
Work was conducted in accordance with industry-accepted standards and quality assured procedures. Quality control procedures are designed to increase sample data quality and help interpret discrepancies in results. Field quality control included rigorous sample collection, decontamination procedures (where appropriate), and sample documentation. As each sample was collected it was labelled with a unique sample identifier, the initials of the sampler, the date and the project number. Samples were placed immediately into cooler boxes for transport to the laboratory. Chain of Custody (COC) documentation was completed with data including sample identification, date sampled, matrix type, preservation method, analyses required and name of sampler. Quality control samples comprised of the collection of duplicate and triplicate samples. As per AS4482.1, duplicate (intra-laboratory duplicate) and triplicate (inter-laboratory duplicate) samples, equivalent to a minimum of 1:20 (5%) of the number of primary samples, and one per day of sampling, were collected and analysed for PFAS.
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3.3 Permits to conduct works The sampling of fish (including crustacea) during the field works was conducted under the provisions of Aurecon’s NSW DPI permits:
Scientific Collection Permit (P14/0025-1.5)
Marine Parks Permit (JBMP 18001/020219-1.0)
3.4 Laboratory analysis All biota, soil, water and sediment samples were analysed for the full PFAS analytical suite provided by the laboratories.
Primary biota samples were analysed by Eurofins laboratories, who are accredited by the National Association of Testing Authorities Australia (NATA) for the PFAS analytes. Secondary samples were analysed by the National Measurements Institute (NMI), who are also NATA accredited.
Samples were placed in laboratory supplied containers, which were completely filled with sample. Sample containers included the following:
PFAS analysis: Specialised bottles, jars and bags were used for storing samples, which are free from Teflon and other PFAS precursors. Glass jars were not used as there is evidence to suggest some PFAS can adsorb to glass surfaces
Analysis of PFAS in biota samples was conducted by high performance liquid chromatography/triple quadrupolemass spectrometry (HPLC/MS/MS). Analysis of PFAS in aqueous samples was by liquid chromatography tandem mass spectrometry (LC-MS/MS), in accordance with NATA.
3.5 Compliance with the SAQP Whilst every effort was made to implement the HHERA SAQP in its entirety, deviations from the SAQP were required. Such deviations included:
The sampling location in upper Currambene Creek (at Fall’s Creek) (CC-B1) was relatively dry during sampling with no surface water flow (refer Figure 4.1). Sampling effort was applied on 29 January, 1 February and 2 February 2018, although no biota was caught. In addition, no biota was observed at this sampling location. As such, it is unlikely that recreational fishers could catch biota from this location during this time.
Other upper Currambene Creek sampling locations (SW13 and SW14) were also very turbid during the time of sampling and assessed by Aurecon ecologists to be unsuitable for biota. Discussions with residents living along upper Currambene Creek suggested no fishing occurs as the creek is too shallow and intermittent.
The alternate location approximately 500 m downstream (CC-B1 alternate) was unable to be sampled, given it was situated within the Sanctuary Zone. As such, biota sampling was conducted at W04, just downstream of the Sanctuary Zone.
Despite sampling effort applied, not all targeted species could be caught in the quantity required in the SAQP. However, it is considered that a sufficient representation of species was caught to effectively conduct the risk assessment.
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4 Field results and observations
4.1 Shoalhaven River sampling
4.1.1 Biota samples The nature of the biota collected from sampling locations along the Shoalhaven River is detailed in Table 4.1.
Table 4.1 Biota samples from Shoalhaven River
Site Species
SR-B1 Sea mullet (Mugil cephalus) Tiger mullet (Liza argentea) Estuary perch (Macquaria colonorum) Dusky flathead (Platycephalus fuscus) Australian bass (Macquaria novemaculeata)
SR-B2 Sea mullet (Mugil cephalus) Estuary perch (Macquaria colonorum) Tiger mullet (Liza argentea) Yellowfin/Black bream (Acanthopagrus australis/Acanthopagrus butcheri) Luderick (Girella tricuspidata) Australian bass (Macquaria novemaculeata) Eastern sea garfish (Hyporhamphus australis)
SR-B3 Sea mullet (Mugil cephalus) Yellowfin/Black bream (Acanthopagrus australis/Acanthopagrus butcheri) Herring (Potamalosa richmondia) Tailor (Pomatomus saltatrix) Estuary perch (Macquaria colonorum) Mud crab (Scylla serrata) Sand mullet (Myxus elongatus) Australian bass (Macquaria novemaculeata)
4.1.2 Surface water sampling Surface water quality parameters were measured in order to characterise the physio-chemical properties of the potential PFAS migration pathways. Table 4.2 summarises the surface water quality parameters within the three sampling locations along Shoalhaven River.
Table 4.2 Surface water quality along Shoalhaven River
Sample ID pH Temperature (°C)
Electrical conductivity (μS/cm)
Dissolved oxygen (mg/L)
Redox (mV) Turbidity (NTU)
SR-B1 8.73 27.0 513 8.45 115 2.5
SR-B2 7.33 26.9 9,946 7.99 120 2.9
SR-B3 7.70 27.0 24,099 7.54 80 2.3
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4.2 Currambene Creek sampling
4.2.1 Biota sampling The nature of the biota collected from sampling locations along Currambene Creek is detailed in Table 4.3.
Table 4.3 Biota samples from Currambene Creek
Site Species
W04 Sea mullet (Mugil cephalus) Eastern sea garfish (Hyporhamphus australis) Yellowfin/Black bream (Acanthopagrus australis/Acanthopagrus butcheri)
CC-B2 Yellowfin/Black bream (Acanthopagrus australis/Acanthopagrus butcheri) Freshwater prawn (Paratya sp.) Luderick (Girella tricuspidata) Mud crab (Scylla serrata) Sea mullet (Mugil cephalus) Mulloway (Argyrosomus japonicus) Estuary perch (Macquaria colonorum) Black sole (Brachirus nigra) Silver trevally (Pseudocaranx georgianus) Sand whiting (Sillago ciliata)
CC-B3 Yellowfin/Black bream (Acanthopagrus australis/Acanthopagrus butcheri) Luderick (Girella tricuspidata) Sea mullet (Mugil cephalus) Estuary perch (Macquaria colonorum) Blue swimmer crab (Portunus armatus) Silver trevally (Pseudocaranx georgianus) Sand whiting (Sillago ciliata)
4.2.2 Surface water sampling Surface water quality parameters were measured in order to characterise the physio-chemical properties of the potential PFAS migration pathways. Table 4.2 summarises the surface water quality parameters within the three sampling locations along Currambene Creek.
Table 4.4 Surface water quality along Currambene Creek
Sample ID Date pH Temperature (°C)
Electrical conductivity (μS/cm)
Dissolved oxygen (mg/L)
Redox (mV)
Turbidity (NTU)
WW04 30/01/18 6.38 28.1 55,263 5.5 69.6 7.2
CC-B2 06/02/18 7.12 23.4 55,596 4.2 110 1.2
CC-B3 06/02/18 7.7 23.2 55,614 4.8 100 1.6
Figure 4.1 illustrates the rainfall at Nowra RAN Air Station AWS (#068072) and stream level at Currambene Creek (216004) during the sampling for the HHERA Addendum. It is noted that rainfall in the area occurred in early January, with the stream level of Currambene Creek rising to 0.19 m. However, very little rain occurred between 14 January and 20 February 2018, with the stream level of Currambene Creek steadily decreasing. Sampling for the HHERA Addendum occurred between 30 January and 10 February 2018.
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Figure 4.1 Rainfall at Nowra, New South Wales (BoM 2018)
4.3 Lowland rainforest sampling A summary description of soils encountered within the lowland rainforest is presented in Table 4.5.
It should be noted that sampling location HA96 was likely situated in a spring, given the saturated soil, although the spring was not flowing at the time of sampling.
Table 4.5 General soil descriptions
Location Depth (m bgl) Description Samples
HA86 0.0 – 0.5 Brown CLAY with medium plasticity and fine gravel and sand HA86_0.1_180131 HA86_0.5_180131
HA87 0.0 – 0.5 Brown CLAY with medium plasticity HA87_0.1_180131 HA87_0.5_180131
HA88 0.0 – 0.4 Brown fine to coarse rounded GRAVEL with some sand HA88_0.1_180131
0.4 – 0.5 Dark grey soft SILT with medium plasticity with some angular gravel inclusions
HA88_0.5_180131
HA89 0.0 – 0.5 Dark brown silty CLAY with gravel inclusions at the base of the creek
HA89_0.1_180131 HA89_0.5_180131
HA90 0.0 – 0.25 Brown TOPSOIL with medium to high plasticity and frequent rootlets and organic matter
HA90_0.1_180131
0.25 – 0.5 Dark grey CLAY with high plasticity. Very moist. HA90_0.5_180131
HA91 0.0 – 0.5 Brown TOPSOIL with medium plasticity HA91_0.1_180131 HA91_0.5_180131
HA92 0.0 – 0.25 Brown mottled orange/red CLAY with medium plasticity HA92_0.1_180131
0.25 – 0.5 Dark grey CLAY with medium to high plasticity HA92_0.5_180131
HA93 0.0 – 0.2 Brown sandy CLAY HA93_0.1_180131
0.2 – 0.5 Dark grey CLAY with high plasticity HA93_0.5_180131
HA94 0.0 – 0.2 Fine to coarse slightly clayey SAND over bedrock HA94_0.1_180131
HA95 - Creek bed sediment over bedrock – clayey SAND HA95_0.1_180131
HA96 0.0 – 0.2 Brown firm CLAY with medium to high plasticity HA96_0.1_180131 QA101_180131 QA201_180131
0.2 – 0.4 Dark grey stiff CLAY with high plasticity HA96_0.4_180131
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5 Laboratory results
5.1 General The laboratory analysis results for PFAS concentrations within samples collected during the field investigations are summarised in the sections below. A more detailed summary of laboratory results is provided in Appendix A, while the complete laboratory certificates are provided in Appendix B. The QA/QC results have been provided in Appendix C.
Comparison to relevant screening criteria will be undertaken in the HHERA Addendum.
5.2 Biota results Table 5.1 below is a summary of results from aquatic biota samples collected from Shoalhaven River and Currambene Creek.
Table 5.1 Biota PFAS analytical results
Analyte (µg/kg) PFOA PFHxS PFOS Sum of PFAS
Shoalhaven River – SR-B1
SR-B1_BASS1_180208 <0.5 <0.3 5.5 5.5
SR-B1_BASS2_180208 <0.5 <0.3 9.4 9.4
SR-B1_DFLATHEAD1_180208 <0.5 <0.3 4.3 4.3
SR-B1_FMULLET1_180208 <0.5 <0.3 2.2 2.2
SR-B1_FMULLET2_180208 <0.5 <0.3 2.3 2.3
SR-B1_FMULLET3_180208 <0.5 <0.3 3.8 3.8
SR-B1_FMULLET4_180208 <0.5 <0.3 2.8 2.8
SR-B1_MULLET1_180208 <0.5 <0.3 2.1 2.1
SR-B1_MULLET2_180208 <0.5 <0.3 3.4 3.4
SR-B1_MULLET3_180208 <0.5 <0.3 1.5 1.5
SR-B1_MULLET4_180208 <0.5 <0.3 1.6 1.6
SR-B1_PERCH1_180208 <0.5 <0.3 1.4 1.4
Shoalhaven River – SR-B2
SR_B2_BASS1_180209 <0.5 <0.3 5.3 5.3
SR_B2_BREAM1_180209 <0.5 <0.3 1.3 1.3
SR_B2_FMULLET1_180209 <0.5 <0.3 20 20
SR_B2_GARFISH1_180209 <0.5 <0.3 2 2
SR_B2_LUDERICK1_180209 <0.5 <0.3 1.2 1.2
SR_B2_MULLET1_180209 <0.5 <0.3 8.5 8.5
SR_B2_MULLET2_180209 <0.5 <0.3 12 12
SR_B2_MULLET3_180209 <0.5 <0.3 13 13
SR_B2_MULLET4_180209 <0.5 <0.3 22 22
SR_B2_PERCH1_180209 <0.5 <0.3 2.3 2.3
Shoalhaven River – SR-B3
SR_B3_BASS1_180210 <0.5 <0.3 6.7 6.7
SR_B3_BREAM1_180210 <0.5 <0.3 1.2 1.2
SR_B3_HERRING1_180210 <0.5 <0.3 8 8
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Analyte (µg/kg) PFOA PFHxS PFOS Sum of PFAS
SR_B3_MACRAB1_180210 <0.5 1.8 2.9 4.7
SR_B3_MULLET1_180209 <0.5 <0.3 5.3 5.3
SR_B3_MULLET2_180210 <0.5 <0.3 5.4 5.4
SR_B3_PERCH1_180210 <0.5 <0.3 3.6 3.6
SR_B3_SMULLET1_180210 <0.5 <0.3 10 10
SR_B3_TAILOR1_180210 <0.5 <0.3 0.9 0.9
Currambene Creek – W04
BIO_W04_BRIM_180130 <0.5 <0.3 1.1 1.1
BIO_W04_GAR1_180130 <0.5 <0.3 2.7 2.7
BIO_W04_GAR2_180130 <0.5 <0.3 2.4 2.4
BIO_W04_MULLET1_180130 <0.5 <0.3 6.3 6.3
BIO_W04_MULLET2_180130 <0.5 <0.3 6.2 6.2
Currambene Creek – CC-B2
CC-B2_BREAM1_180206 <0.5 <0.3 1 1
CC-B2_BREAM2_180207 < 0.5 < 0.3 0.9 0.9
CC-B2_BREAM3_180207 < 0.5 < 0.3 0.4 0.4
CC-B2_EPRAWZ1_180206 <0.5 9.3 36 46.2
CC-B2_LUDERICK1_180206 <0.5 <0.3 6.6 6.6
CC-B2_LUDERICK2_180206 <0.5 <0.3 5.2 5.2
CC-B2_LUDERICK3_180206 <0.5 <0.3 4.9 4.9
CC-B2_LUDERICK4_180206 <0.5 <0.3 5.8 5.8
CC-B2_MCRAB1_180206 <0.5 0.7 3.9 4.6
CC-B2_MULLET1_180206 <0.5 <0.3 6.4 6.4
CC-B2_MULLET2_180206 <0.5 <0.3 2.7 2.7
CC-B2_MULLOWAY1_180206 <0.5 0.5 15 15.5
CC-B2_MULLOWAY2_180206 <0.5 <0.3 11 11
CC-B2_PERCH1_180206 <0.5 0.5 15 15.5
CC-B2_PERCH2_180206 <0.5 <0.3 17 17
CC-B2_PERCH3_180206 <0.5 0.5 18 18.5
CC-B2_PERCH4_180206 <0.5 0.4 18 18.4
CC-B2_SOUL1_180206 <0.5 27 340 374.2
CC-B2_STREVALLY1_180206 <0.5 1.1 23 24.1
CC-B2_STREVALLY2_180206 <0.5 2.2 37 39.2
CC-B2_STREVALLY3_180207 < 0.5 < 0.3 13 13
CC-B2_WHITING1_180206 <0.5 <0.3 12 12.7
Currambene Creek – CC-B3
CC-B3_BREAM1_180204 <0.5 <0.3 <0.3 <0.5
CC-B3_BREAM2_180204 <0.5 <0.3 <0.3 <0.5
CC-B3_BREAM3_180206 <0.5 <0.3 <0.3 <0.5
CC-B3_BREAM4_180207 < 0.5 < 0.3 1.2 1.2
CC-B3_LUDERICK1_180204 <0.5 <0.3 1.6 1.6
CC-B3_LUDERICK2_180204 <0.5 <0.3 2.5 2.5
CC-B3_LUDERICK3_180204 <0.5 <0.3 1.6 1.6
Project number 251529/DEHP-ID-183-D1 File HMAS Albatross HHERA Addendum Field Investigation.docx, 21 June 2018 Revision 1 18
Analyte (µg/kg) PFOA PFHxS PFOS Sum of PFAS
CC-B3_LUDERICK4_180206 <0.5 <0.3 1.6 1.6
CC-B3_MULLET1_180204 <0.5 <0.3 3 3
CC-B3_MULLET2_180204 <0.5 <0.3 3.5 3.5
CC-B3_MULLET3_180204 <0.5 <0.3 3.3 3.3
CC-B3_MULLET4_180204 <0.5 <0.3 2.8 2.8
CC-B3_PERCH1_180204 <0.5 <0.3 11 11
CC-B3_SCRAB1_180206 <0.5 1.4 4.5 5.9
CC-B3_STREVALLY1_180204 <0.5 <0.3 2.5 2.5
CC-B3_STREVALLY2_180206 <0.5 <0.3 4.2 4.2
CC-B3_STREVALLY3_180207 < 0.5 < 0.3 2.2 2.2
CC-B3_WHITING1_180204 <0.5 <0.3 <0.3 <0.5
CC-B3_WHITING2_180206 <0.5 <0.3 1.6 1.6
CC-B3_WHITING3_180206 <0.5 <0.3 1.5 1.5
CC-B3_WHITING4_180207 < 0.5 < 0.3 0.8 0.8
5.3 Surface water results Table 5.2 below is a summary of results from surface water samples collected from Shoalhaven River and Currambene Creek.
Table 5.2 Surface water PFAS analytical results
Analyte (µg/L) PFOA PFHxS PFOS Sum of PFAS
Shoalhaven River
SW-SR-B1-180209 <0.001 <0.001 <0.0001 <0.005
SW-SR-B2-180209 <0.001 0.003 0.0027 0.0067
SW-SR-B3-180209 <0.001 0.003 0.0027 0.0067
Currambene Creek
SW_W04_180130 <0.001 0.014 0.037 0.055
SW_CC-B2_180206 <0.001 0.014 0.018 0.038
SW_CC-B3_180206 <0.001 0.004 0.012 0.018
5.4 Sediment results Table 5.3 below is a summary of results from sediment samples collected from Shoalhaven River and Currambene Creek.
Table 5.3 Sediment PFAS analytical results
Analyte (µg/kg) PFOA PFHxS PFOS Sum of PFAS
Shoalhaven River
SED-SR-B1-180209 <5 <5 <5 <5
SED-SR-B2-180209 <5 <5 <5 <5
SED-SR-B3-180209 <5 <5 <5 <5
Currambene Creek
SED_W04_180130 <5 <5 <5 <5
Project number 251529/DEHP-ID-183-D1 File HMAS Albatross HHERA Addendum Field Investigation.docx, 21 June 2018 Revision 1 19
Analyte (µg/kg) PFOA PFHxS PFOS Sum of PFAS
SED_CC-B2_180206 <5 <5 21 21
SED_CC-B3_180206 <5 <5 20 20
5.5 Soil results Table 5.4 below is a summary of results from soil and soil leachate samples collected from the Lowland Rainforest at HMAS Albatross.
Table 5.4 Soil and soil leachate PFAS analytical results
Analyte Soil concentrations (µg/kg) Soil leachate concentrations (µg/L)
PFOA PFHxS PFOS Sum of PFAS
PFOA PFHxS PFOS Sum of PFAS
HA86_0.1_180131 <5 <5 <5 <5 <0.01 <0.01 0.01 <0.1
HA86_0.5_180131 <5 <5 <5 <5 <0.01 0.01 0.04 <0.1
HA87_0.1_180131 <5 <5 32 32 0.02 0.16 1.1 1.4
HA87_0.5_180131 <5 27 88 115 <0.01 0.13 0.62 0.77
HA88_0.1_180131 <5 <5 14 14 <0.01 0.1 0.26 0.38
HA88_0.5_180131 <5 <5 110 110 <0.01 0.05 1.6 1.76
HA89_0.1_180131 <5 <5 <5 <5 <0.01 <0.01 0.08 <0.1
HA89_0.5_180131 <5 <5 32 32 0.02 0.11 0.79 1.02
HA90_0.1_180131 <5 <5 12 12 <0.01 <0.01 0.08 <0.1
HA90_0.5_180131 <5 <5 33 33 <0.01 0.02 0.51 0.53
HA91_0.1_180131 <5 <5 47 47 <0.01 0.06 1.4 1.51
HA91_0.5_180131 <5 12 130 142 0.04 0.59 4.7 5.62
HA92_0.1_180131 <5 <5 <5 <5 <0.01 <0.01 0.02 <0.1
HA92_0.5_180131 <5 <5 <5 <5 <0.01 <0.01 <0.01 <0.1
HA93_0.1_180131 <5 <5 <5 <5 <0.01 <0.01 <0.01 <0.1
HA93_0.5_180131 <5 <5 <5 <5 <0.01 <0.01 <0.01 <0.1
HA94_0.1_180131 <5 <5 <5 <5 <0.01 <0.01 0.03 <0.1
HA95_0.1_180131 <5 <5 <5 <5 <0.01 <0.01 <0.01 <0.1
HA96_0.1_180131 <5 <5 <5 <5 <0.01 <0.01 <0.01 <0.1
HA96_0.4_180131 <5 <5 <5 <5 <0.01 <0.01 <0.01 <0.1
HA97_0.1_180131 <5 <5 <5 <5 - - - -
HA97_0.5_180131 <5 <5 <5 <5 - - - -
Project number 251529/DEHP-ID-183-D1 File HMAS Albatross HHERA Addendum Field Investigation.docx, 21 June 2018 Revision 1 20
6 Quality assurance and quality control
6.1 Introduction Quality assurance and control (QA/QC) procedures relevant to the this investigation were carried out in general accordance with the relevant NEPM (2013) Schedule B(2) Guideline on Data Collection, Sample Design and Reporting – Section 4 and Schedule B(3) Guideline on Laboratory Analysis of Potentially Contaminated Sites.
Full details of the QA/QC methodology are included in Appendix C.
6.2 Data validation summary In summary, data assessment examined laboratory results, chain of custody documentation, and field QA/QCs. The following comments can be viewed as an overall summary of the quality of the analytical component for this project:
Sample integrity and container requirements were documented as acceptable for all samples
The method blanks were documented as below the LOR for all analytes indicating that contamination was not added during the laboratory analysis
Matrix spike duplicate recovery % R values indicated that sample accuracy acceptable for all samples
Laboratory surrogate recovery % R values and laboratory control spike recovery % R values were considered acceptable indicating that laboratory accuracy was acceptable for all samples
Laboratory duplicate RPD (% RPD) results indicated that sample precision was acceptable for the majority of analytes
All laboratory QA/QC method blanks were reported to have analytical concentrations below the laboratory detection limits and thus found to be acceptable
Based on the RPDs and the QA/QC report, the analytical results are considered representative of the concentration of the parameters within the sample media. It is therefore considered that the QA procedures implemented were acceptable in minimising cross contamination during sampling and transportation to the analytical laboratory.
The quality of the analytical component for this Project is considered acceptable.
Project number 251529/DEHP-ID-183-D1 File HMAS Albatross HHERA Addendum Field Investigation.docx, 21 June 2018 Revision 1 21
7 Conclusion The data collected during the HHERA Addendum field investigations is sufficient to allow a quantitative evaluation of the potential risks to be undertaken for human health and the environment within the Shoalhaven River, Currambene Creek and the on base areas of lowland rainforest, due to PFAS presence arising from the use and storage of AFFF at HMAS Albatross.
The HHERA field investigations provided for the collection of waterway biota surface water and sediment samples. The samples were subject to laboratory analysis for PFAS.
The laboratory analysis results for PFAS concentrations present in samples collected as part of the HHERA Addendum field investigations have been presented in this report. Biota containing elevated PFAS concentrations were detected from each sampling location on Shoalhaven River and Currambene Creek, with the highest concentration of PFAS recorded at site CC-B2 on Currambene Creek in the Black Sole (Brachirus nigra). Concentrations of PFAS were detected from each sampling location along Currambene Creek and the two sampling locations on the Shoalhaven River, downstream of the Calymea Creek confluence. In addition, PFAS was detected in two of the three sediment samples from Currambene Creek, although PFAS was not detected in sediment from Shoalhaven River.
The findings of the HHERA Addendum field investigations presented in this report and results of the laboratory analysis will be incorporated in the HHERA Addendum prepared by Environmental Risk Science Pty Ltd.
Project number 251529/DEHP-ID-183-D1 File HMAS Albatross HHERA Addendum Field Investigation.docx, 21 June 2018 Revision 1 22
8 References Australian and New Zealand Environment and Conservation Council and Agriculture and Resource Management Council of Australia and New Zealand 2000, Australian and New Zealand Guidelines for Fresh and Marine Water Quality, Volume 1: The Guidelines, National Water Quality Management Strategy, October 2000.
Department of Health 2017, Health Based Guidance Values for PFAS for Use in Site Investigations in Australia, Australian Government, April 2017.
Department of the Environment and Energy 2018, Species Profile and Threats Database – Lowland Rainforest of Subtropical Australia, viewed 26 February 2018, available at: http://www.environment.gov.au/cgi-bin/sprat/public/publicshowcommunity.pl?id=101.
Environmental Health Standing Committee (enHealth) 2012, Environmental Health Risk Assessment Guidelines for Assessing human health risk from environmental hazards, Commonwealth of Australia, Canberra.
Environmental Risk Sciences Pty Ltd (EnRiskS) 2016, DEHP-ID-183-DI Methodology for HHERA: HMAS Albatross, prepared for Aurecon Australasia Pty Ltd and the Department of Defence, December 2016.
Heads of EPAs Australia and New Zealand (HEPA) 2018, PFAS National Environmental Management Plan, January 2018
Miles, N.G. and West, R.J. 2011, Recreational fishing in the Shoalhaven Region, NSW, Australia: optimising survey methods and assessing sustainability, Australian National Centre for Ocean Resources and Security, University of Wollongong.
NEPM 2013, National Environment Protection (Assessment of Site Contamination) Measure 1999, (amendment 1, 2013), National Environment Protection Council, Canberra.
NSW Department of Environment and Conservation 2006, Guidelines for the NSW Site Auditor Scheme (2nd edition), State of NSW, Sydney.
NSW Environment Protection Authority 2016, Designing Sampling Programs for Sites Potentially Contaminated by PFAS, Guidance Document, State of New South Wales, Sydney.
NSW Marine Parks Authority 2011, Jervis Bay Marine Park Zoning Plan, viewed 7 July 2016, available at: http://www.mpa.nsw.gov.au/pdf/JBMP-User-Guide-August-2014.pdf.
Sinclair Knight Merz (SKM) 2006, Vegetation of HMAS Albatross, Prepared for the Department of Defence, June 2006.
Sinclair Knight Merz (SKM) 2009, HMAS Albatross Aquatic Ecology Study – Report on Baseline Conditions 2008-09, Prepared for Defence Maintenance Management, August 2009.
Western Australia Department of Environment Regulation (WA DER) 2017, Interim Guideline on the Assessment and Management of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS), Government of Western Australia, Perth.
A
Summary laboratory
results
Soil results HA86_0.1_180131 HA86_0.5_180131 HA87_0.1_180131 HA87_0.5_180131 HA88_0.1_180131 HA88_0.5_180131 HA89_0.1_180131 HA89_0.5_180131 HA90_0.1_180131HMAS ALBATROSS (251529) Units S18-Fe01813 S18-Fe01814 S18-Fe01815 S18-Fe01816 S18-Fe01817 S18-Fe01818 S18-Fe01819 S18-Fe01820 S18-Fe01821
% Moisture % 6 7.8 7.7 10 9.8 23 22 17 40
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <51H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <51H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <51H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg <10 <10 <10 <10 <10 <10 <10 <10 <10
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <52-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kg <10 <10 <10 <10 <10 <10 <10 <10 <10N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kg <10 <10 <10 <10 <10 <10 <10 <10 <10Perfluorooctane sulfonamide (FOSA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorodecanesulfonic acid (PFDS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluoroheptanesulfonic acid (PFHpS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorohexanesulfonic acid (PFHxS) µg/kg <5 <5 <5 27 <5 <5 <5 <5 <5Perfluorooctanesulfonic acid (PFOS) µg/kg <5 <5 32 88 14 110 <5 32 12Perfluoropentanesulfonic acid (PFPeS) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorodecanoic acid (PFDA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorododecanoic acid (PFDoA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluoroheptanoic acid (PFHpA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorohexanoic acid (PFHxA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorononanoic acid (PFNA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorooctanoic acid (PFOA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluoropentanoic acid (PFPeA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorotetradecanoic acid (PFTeDA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluorotridecanoic acid (PFTrDA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5Perfluoroundecanoic acid (PFUnA) µg/kg <5 <5 <5 <5 <5 <5 <5 <5 <5
PFASs SummationsSum (PFHxS + PFOS)* µg/kg <5 <5 32 115 14 110 <5 32 12Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/kg <5 <5 32 115 14 110 <5 32 12Sum of PFASs (n=28)* µg/kg <50 <50 <50 115 <50 110 <50 <50 <50Sum of US EPA PFAS (PFOS + PFOA)* µg/kg <5 <5 32 88 14 110 <5 32 12Sum of WA DER PFAS (n=10)* µg/kg <10 <10 32 115 14 110 <10 32 12
Soil resultsHMAS ALBATROSS (251529) Units
% Moisture %
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
PFASs SummationsSum (PFHxS + PFOS)* µg/kgSum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/kgSum of PFASs (n=28)* µg/kgSum of US EPA PFAS (PFOS + PFOA)* µg/kgSum of WA DER PFAS (n=10)* µg/kg
HA90_0.5_180131 HA91_0.1_180131 HA91_0.5_180131 HA92_0.1_180131 HA92_0.5_180131 HA93_0.1_180131 HA93_0.5_180131 HA94_0.1_180131 HA95_0.1_180131S18-Fe01822 S18-Fe01823 S18-Fe01824 S18-Fe01825 S18-Fe01826 S18-Fe01827 S18-Fe01828 S18-Fe01829 S18-Fe01830
27 6.3 15 4.8 31 30 29 15 27
<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5
<10 <10 <10 <10 <10 <10 <10 <10 <10
<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5
<10 <10 <10 <10 <10 <10 <10 <10 <10<5 <5 <5 <5 <5 <5 <5 <5 <5
<10 <10 <10 <10 <10 <10 <10 <10 <10<5 <5 <5 <5 <5 <5 <5 <5 <5
<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 12 <5 <5 <5 <5 <5 <533 47 130 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5
<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5<5 <5 <5 <5 <5 <5 <5 <5 <5
33 47 142 <5 <5 <5 <5 <5 <533 47 142 <5 <5 <5 <5 <5 <5
<50 <50 142 <50 <50 <50 <50 <50 <5033 47 130 <5 <5 <5 <5 <5 <533 47 142 <10 <10 <10 <10 <10 <10
Soil resultsHMAS ALBATROSS (251529) Units
% Moisture %
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
PFASs SummationsSum (PFHxS + PFOS)* µg/kgSum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/kgSum of PFASs (n=28)* µg/kgSum of US EPA PFAS (PFOS + PFOA)* µg/kgSum of WA DER PFAS (n=10)* µg/kg
HA96_0.1_180131 HA96_0.4_180131 QA101_180131 HA97_0.1_180131 HA97_0.5_180131S18-Fe01831 S18-Fe01832 S18-Fe01833 S18-Fe02002 S18-Fe02003
17 21 50 55 42
<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5
<10 <10 <10 <10 <10
<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5
<10 <10 <10 <10 <10<5 <5 <5 <5 <5
<10 <10 <10 <10 <10<5 <5 <5 <5 <5
<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5
<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5<5 <5 <5 <5 <5
<5 <5 <5 <5 <5<5 <5 <5 <5 <5
<50 <50 <50 <50 <50<5 <5 <5 <5 <5
<10 <10 <10 <10 <10
Soil leachate results HA86_0.1_180131 HA86_0.5_180131 HA87_0.1_180131 HA87_0.5_180131 HA88_0.1_180131 HA88_0.5_180131 HA89_0.1_180131 HA89_0.5_180131 HA90_0.1_180131HMAS ALBATROSS (251529) Units S18-Fe06016 S18-Fe06017 S18-Fe06018 S18-Fe06019 S18-Fe06020 S18-Fe06021 S18-Fe06022 S18-Fe06023 S18-Fe06024
% Moisture %
AUS Leaching ProcedureLeachate Fluid 4 4 4 4 4 4 4 4 4pH (initial) 8.1 7.8 8.8 8.7 8.7 7.1 6.8 7.5 6.5pH (Leachate fluid) 7 7 7 7 7 7 7 7 7pH (off) 8 7.4 7.4 8.1 7.2 7.4 7.3 7 6.6
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.011H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.011H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.011H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.052-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05Perfluorooctane sulfonamide (FOSA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/L <0.01 <0.01 0.02 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorodecanesulfonic acid (PFDS) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluoroheptanesulfonic acid (PFHpS) µg/L <0.01 <0.01 0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorohexanesulfonic acid (PFHxS) µg/L <0.01 0.01 0.16 0.13 0.1 0.05 <0.01 0.11 <0.01Perfluorooctanesulfonic acid (PFOS) µg/L 0.01 0.04 1.1 0.62 0.26 1.6 0.08 0.79 0.08Perfluoropentanesulfonic acid (PFPeS) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05Perfluorodecanoic acid (PFDA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorododecanoic acid (PFDoA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.02 <0.01Perfluoroheptanoic acid (PFHpA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorohexanoic acid (PFHxA) µg/L <0.01 <0.01 0.05 0.02 0.02 0.09 <0.01 0.03 <0.01Perfluorononanoic acid (PFNA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorooctanoic acid (PFOA) µg/L <0.01 <0.01 0.02 <0.01 <0.01 <0.01 <0.01 0.02 <0.01Perfluoropentanoic acid (PFPeA) µg/L <0.01 <0.01 0.04 <0.01 <0.01 0.02 <0.01 0.02 <0.01Perfluorotetradecanoic acid (PFTeDA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01Perfluorotridecanoic acid (PFTrDA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 0.03 <0.01Perfluoroundecanoic acid (PFUnA) µg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
PFASs SummationsSum (PFHxS + PFOS)* µg/L 0.01 0.05 1.26 0.75 0.36 1.65 0.08 0.9 0.08Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/L 0.01 0.05 1.28 0.75 0.36 1.65 0.08 0.92 0.08Sum of PFASs (n=28)* µg/L <0.1 <0.1 1.4 0.77 0.38 1.76 <0.1 1.02 <0.1Sum of US EPA PFAS (PFOS + PFOA)* µg/L 0.01 0.04 1.12 0.62 0.26 1.6 0.08 0.81 0.08Sum of WA DER PFAS (n=10)* µg/L <0.05 0.05 1.39 0.77 0.38 1.76 0.08 0.97 0.08
Soil leachate resultsHMAS ALBATROSS (251529) Units
% Moisture %
AUS Leaching ProcedureLeachate FluidpH (initial)pH (Leachate fluid)pH (off)
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/L1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/L1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/L1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/L
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/L2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/LN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/LN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/LN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/LN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/LPerfluorooctane sulfonamide (FOSA) µg/L
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/LPerfluorodecanesulfonic acid (PFDS) µg/LPerfluoroheptanesulfonic acid (PFHpS) µg/LPerfluorohexanesulfonic acid (PFHxS) µg/LPerfluorooctanesulfonic acid (PFOS) µg/LPerfluoropentanesulfonic acid (PFPeS) µg/L
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/LPerfluorodecanoic acid (PFDA) µg/LPerfluorododecanoic acid (PFDoA) µg/LPerfluoroheptanoic acid (PFHpA) µg/LPerfluorohexanoic acid (PFHxA) µg/LPerfluorononanoic acid (PFNA) µg/LPerfluorooctanoic acid (PFOA) µg/LPerfluoropentanoic acid (PFPeA) µg/LPerfluorotetradecanoic acid (PFTeDA) µg/LPerfluorotridecanoic acid (PFTrDA) µg/LPerfluoroundecanoic acid (PFUnA) µg/L
PFASs SummationsSum (PFHxS + PFOS)* µg/LSum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/LSum of PFASs (n=28)* µg/LSum of US EPA PFAS (PFOS + PFOA)* µg/LSum of WA DER PFAS (n=10)* µg/L
HA90_0.5_180131 HA91_0.1_180131 HA91_0.5_180131 HA92_0.1_180131 HA92_0.5_180131 HA93_0.1_180131 HA93_0.5_180131 HA94_0.1_180131 HA95_0.1_180131S18-Fe06025 S18-Fe06026 S18-Fe06027 S18-Fe06028 S18-Fe06029 S18-Fe06030 S18-Fe06031 S18-Fe06032 S18-Fe06033
4 4 4 4 4 4 4 4 47.6 7.5 7 6.5 4.9 5.2 4.1 7.2 6.2
7 7 7 7 7 7 7 7 76.6 6.7 6.7 5.9 4.9 5.2 3.9 6 6.1
<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
<0.01 <0.01 0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
0.02 0.06 0.59 <0.01 <0.01 <0.01 <0.01 <0.01 <0.010.51 1.4 4.7 0.02 <0.01 <0.01 <0.01 0.03 <0.01
<0.01 <0.01 0.05 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
<0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 0.03 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 0.03 0.1 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 0.04 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 0.02 0.03 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01<0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
0.53 1.46 5.29 0.02 <0.01 <0.01 <0.01 0.03 <0.010.53 1.46 5.33 0.02 <0.01 <0.01 <0.01 0.03 <0.010.53 1.51 5.62 <0.1 <0.1 <0.1 <0.1 <0.1 <0.10.51 1.4 4.74 0.02 <0.01 <0.01 <0.01 0.03 <0.010.53 1.51 5.53 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Soil leachate resultsHMAS ALBATROSS (251529) Units
% Moisture %
AUS Leaching ProcedureLeachate FluidpH (initial)pH (Leachate fluid)pH (off)
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/L1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/L1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/L1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/L
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/L2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/LN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/LN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/LN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/LN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/LPerfluorooctane sulfonamide (FOSA) µg/L
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/LPerfluorodecanesulfonic acid (PFDS) µg/LPerfluoroheptanesulfonic acid (PFHpS) µg/LPerfluorohexanesulfonic acid (PFHxS) µg/LPerfluorooctanesulfonic acid (PFOS) µg/LPerfluoropentanesulfonic acid (PFPeS) µg/L
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/LPerfluorodecanoic acid (PFDA) µg/LPerfluorododecanoic acid (PFDoA) µg/LPerfluoroheptanoic acid (PFHpA) µg/LPerfluorohexanoic acid (PFHxA) µg/LPerfluorononanoic acid (PFNA) µg/LPerfluorooctanoic acid (PFOA) µg/LPerfluoropentanoic acid (PFPeA) µg/LPerfluorotetradecanoic acid (PFTeDA) µg/LPerfluorotridecanoic acid (PFTrDA) µg/LPerfluoroundecanoic acid (PFUnA) µg/L
PFASs SummationsSum (PFHxS + PFOS)* µg/LSum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/LSum of PFASs (n=28)* µg/LSum of US EPA PFAS (PFOS + PFOA)* µg/LSum of WA DER PFAS (n=10)* µg/L
HA96_0.1_180131 HA96_0.4_180131 QA101_180131S18-Fe06034 S18-Fe06035 S18-Fe06036
4 4 46.4 4.9 8.3
7 7 76.4 5.3 6.5
<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.05 <0.05 <0.05
<0.05 <0.05 <0.05<0.05 <0.05 <0.05<0.05 <0.05 <0.05<0.05 <0.05 <0.05<0.05 <0.05 <0.05<0.05 <0.05 <0.05<0.05 <0.05 <0.05
<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01
<0.05 <0.05 <0.05<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01<0.01 <0.01 <0.01
<0.01 <0.01 <0.01<0.01 <0.01 <0.01
<0.1 <0.1 <0.1<0.01 <0.01 <0.01<0.05 <0.05 <0.05
Surface water results SW_W04_180130 SW_CC-B3_180206 SW_CC-B2_180206 SW-SR-B1-180209 SW-SR-B2-180209 SW-SR-B3-180209HMAS ALBATROSS (251529) Units S18-Fe01834 S18-Fe06720 S18-Fe06722 B18-Fe14880 B18-Fe14881 B18-Fe14882
NutrientsAmmonia (as N) mg/L <0.01 <0.01 0.02 <0.01 <0.01 <0.01Conductivity (at 25°C) µS/cm 61000 52000 53000 520 9100 22000Nitrate & Nitrite (as N) mg/L <0.05 <0.05 <0.05 <0.05 <0.05 <0.05Nitrate (as N) mg/L 0.02 <0.02 <0.02 <0.02 <0.02 <0.02Nitrite (as N) mg/L <0.02 <0.02 <0.02 <0.02 <0.02 <0.02Organic Nitrogen (as N) mg/L 1.9 0.34 0.3 0.33 0.28 0.36pH - 7.9 8.1 7.8 7.8 7.7 7.8Phosphorus mg/L <5 0.05 <0.05 <0.05 <0.05 <0.05Suspended Solids mg/L 53 16 20 7.9 5.5 11Total Dissolved Solids mg/L 40000 34000 36000 200 3700 11000Total Kjeldahl Nitrogen (as N) mg/L 1.9 0.3 0.3 0.3 0.3 0.4Total Nitrogen (as N) mg/L 1.9 0.34 0.32 0.33 0.28 0.36Total Organic Carbon mg/L <5 <5 <5 <5 19 <5
Heavy MetalsArsenic 0.002 <0.01 <0.01 <0.005 <0.005 <0.005Cadmium <0.0002 <0.002 <0.002 <0.001 <0.001 <0.001Chromium <0.001 <0.01 <0.01 <0.005 <0.005 <0.005Copper <0.001 <0.01 <0.01 <0.005 <0.005 <0.005Lead 0.001 <0.01 <0.01 <0.005 <0.005 <0.005Mercury <0.0001 <0.001 <0.001 <0.0005 <0.0005 <0.0005Nickel <0.001 <0.01 <0.01 <0.005 <0.005 <0.005Zinc 0.005 <0.05 <0.05 <0.025 <0.025 <0.025
n:2 Fluorotelomer sulfonic acids - Ultra Trace1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.0011H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.0011H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.0011H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/L <0.005 <0.005 <0.005 <0.005 <0.005 <0.005
Perfluoroalkane sulfonamides (PFASAs) - Ultra Trace2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) <0.005 <0.005 <0.005 <0.005 <0.005 <0.0052-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) <0.005 <0.005 <0.005 <0.005 <0.005 <0.005N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) <0.005 <0.005 <0.005 <0.005 <0.005 <0.005N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) <0.005 <0.005 <0.005 <0.005 <0.005 <0.005N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) <0.005 <0.005 <0.005 <0.005 <0.005 <0.005N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) <0.005 <0.005 <0.005 <0.005 <0.005 <0.005Perfluorooctane sulfonamide (FOSA) <0.005 <0.005 <0.005 <0.005 <0.005 <0.005
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) - Ultra TracePerfluorobutanesulfonic acid (PFBS) 0.001 <0.001 0.001 <0.001 <0.001 <0.001Perfluorodecanesulfonic acid (PFDS) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluoroheptanesulfonic acid (PFHpS) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluorohexanesulfonic acid (PFHxS) 0.014 0.004 0.014 <0.001 0.003 0.003Perfluorooctanesulfonic acid (PFOS) 0.037 0.012 0.018 <0.0001 0.0027 0.0027Perfluoropentanesulfonic acid (PFPeS) 0.001 <0.001 0.001 <0.001 <0.001 <0.001
Perfluoroalkyl carboxylic acids (PFCAs) - Ultra TracePerfluorobutanoic acid (PFBA) <0.005 <0.005 <0.005 <0.005 <0.005 <0.005Perfluorodecanoic acid (PFDA) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001
Surface water results SW_W04_180130 SW_CC-B3_180206 SW_CC-B2_180206 SW-SR-B1-180209 SW-SR-B2-180209 SW-SR-B3-180209HMAS ALBATROSS (251529) Units S18-Fe01834 S18-Fe06720 S18-Fe06722 B18-Fe14880 B18-Fe14881 B18-Fe14882Perfluorododecanoic acid (PFDoA) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluoroheptanoic acid (PFHpA) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluorohexanoic acid (PFHxA) 0.002 0.001 0.003 <0.001 0.001 0.001Perfluorononanoic acid (PFNA) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluorooctanoic acid (PFOA) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluoropentanoic acid (PFPeA) <0.001 0.001 0.001 <0.001 <0.001 <0.001Perfluorotetradecanoic acid (PFTeDA) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluorotridecanoic acid (PFTrDA) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001Perfluoroundecanoic acid (PFUnA) <0.001 <0.001 <0.001 <0.001 <0.001 <0.001
PFASs SummationsSum (PFHxS + PFOS)* 0.051 0.016 0.032 <0.001 0.0057 0.0057Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.051 0.016 0.032 <0.001 0.0057 0.0057Sum of PFASs (n=28)* 0.055 0.018 0.038 <0.005 0.0067 0.0067Sum of US EPA PFAS (PFOS + PFOA)* 0.037 0.012 0.018 <0.001 0.0027 0.0027Sum of WA DER PFAS (n=10)* 0.054 0.018 0.037 <0.005 0.0067 0.0067
Sediment results SED_W04_180130 SED_CC-B3_180206 SED_CC-B2_180206 SED-SR-B1-180209 SED-SR-B2-180209 SED-SR-B3-180209HMAS ALBATROSS (251529) Units S18-Fe01835 S18-Fe06719 S18-Fe06721 B18-Fe14883 B18-Fe14884 B18-Fe14885
% Moisture % 22 26 47 21 23 25
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg <5 <5 <5 <5 <5 <51H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg <5 <5 <5 <5 <5 <51H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg <5 <5 <5 <5 <5 <51H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg <10 <10 <10 <10 <10 <10
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg <5 <5 <5 <5 <5 <52-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kg <5 <5 <5 <5 <5 <5N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kg <5 <5 <5 <5 <5 <5N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kg <10 <10 <10 <10 <10 <10N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kg <5 <5 <5 <5 <5 <5N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kg <10 <10 <10 <10 <10 <10Perfluorooctane sulfonamide (FOSA) µg/kg <5 <5 <5 <5 <5 <5
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kg <5 <5 <5 <5 <5 <5Perfluorodecanesulfonic acid (PFDS) µg/kg <5 <5 <5 <5 <5 <5Perfluoroheptanesulfonic acid (PFHpS) µg/kg <5 <5 <5 <5 <5 <5Perfluorohexanesulfonic acid (PFHxS) µg/kg <5 <5 <5 <5 <5 <5Perfluorooctanesulfonic acid (PFOS) µg/kg <5 20 21 <5 <5 <5Perfluoropentanesulfonic acid (PFPeS) µg/kg <5 <5 <5 <5 <5 <5
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kg <5 <5 <5 <5 <5 <5Perfluorodecanoic acid (PFDA) µg/kg <5 <5 <5 <5 <5 <5Perfluorododecanoic acid (PFDoA) µg/kg <5 <5 <5 <5 <5 <5Perfluoroheptanoic acid (PFHpA) µg/kg <5 <5 <5 <5 <5 <5Perfluorohexanoic acid (PFHxA) µg/kg <5 <5 <5 <5 <5 <5Perfluorononanoic acid (PFNA) µg/kg <5 <5 <5 <5 <5 <5Perfluorooctanoic acid (PFOA) µg/kg <5 <5 <5 <5 <5 <5Perfluoropentanoic acid (PFPeA) µg/kg <5 <5 <5 <5 <5 <5Perfluorotetradecanoic acid (PFTeDA) µg/kg <5 <5 <5 <5 <5 <5Perfluorotridecanoic acid (PFTrDA) µg/kg <5 <5 <5 <5 <5 <5Perfluoroundecanoic acid (PFUnA) µg/kg <5 <5 <5 <5 <5 <5
PFASs SummationsSum (PFHxS + PFOS)* µg/kg <5 20 21 <5 <5 <5Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* µg/kg <5 20 21 <5 <5 <5Sum of PFASs (n=28)* µg/kg <50 <50 <50 <50 <50 <50Sum of US EPA PFAS (PFOS + PFOA)* µg/kg <5 20 21 <5 <5 <5Sum of WA DER PFAS (n=10)* µg/kg <10 20 21 <10 <10 <10
Biota results BIO_W04_BRIM_180130 BIO_W04_GAR1_180130 BIO_W04_GAR2_180130 BIO_W04_MULLET1_180130 BIO_W04_MULLET2_180130 CC_B2_BREAM1_180206 CC_B2_BREAM2_180207Yellowfin/Black bream Eastern sea garfish Eastern sea garfish Sea mullet Sea mullet Yellowfin/Black bream Yellowfin/Black bream
Fillets - 5 Fillets - 5HMAS ALBATROSS (251529) Units B18-Fe01864 B18-Fe01862 B18-Fe18843 B18-Fe01863 B18-Fe18844 S18-Fe09253 S18-Fe10212
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.51H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.51H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.51H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.52-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorooctane sulfonamide (FOSA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorodecanesulfonic acid (PFDS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluoroheptanesulfonic acid (PFHpS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorohexanesulfonic acid (PFHxS) µg/kg <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3Perfluorooctanesulfonic acid (PFOS) µg/kg 1.1 2.7 2.4 6.3 6.2 1 0.9Perfluoropentanesulfonic acid (PFPeS) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorodecanoic acid (PFDA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorododecanoic acid (PFDoA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluoroheptanoic acid (PFHpA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorohexanoic acid (PFHxA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorononanoic acid (PFNA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorooctanoic acid (PFOA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluoropentanoic acid (PFPeA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorotetradecanoic acid (PFTeDA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluorotridecanoic acid (PFTrDA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5Perfluoroundecanoic acid (PFUnA) µg/kg <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
SpeciesNumber in composite
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B2_BREAM3_180207 CC_B2_EPRAWZ1_180206 CC_B2_LUDERICK1_180206 CC_B2_LUDERICK2_180206 CC_B2_LUDERICK3_180206 CC_B2_LUDERICK4_180206 CC_B2_MCRAB1_180206Yellowfin/Black bream Freshwater prawn Luderick Luderick Luderick Luderick Mud crabFillets - 3 Whole - 3 Fillets - 5 Fillets - 5 Fillets - 5 Fillets - 5 Whole - 1S18-Fe10211 S18-Fe09252 S18-Fe09234 S18-Fe09255 S18-Fe09249 S18-Fe09243 S18-Fe09241
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 0.9 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 9.3 <0.3 <0.3 <0.3 <0.3 0.7
0.4 36 6.6 5.2 4.9 5.8 3.9<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B2_MULLET1_180206 CC_B2_MULLET2_180206 CC_B2_MULLOWAY1_180206 CC_B2_MULLOWAY2_180206 CC_B2_PERCH1_180206 CC_B2_PERCH2_180206 CC_B2_PERCH3_180206Sea mullet Sea mullet Mulloway Mulloway Estuary perch Estuary perch Estuary perchFillets - 5 Fillets - 5 Fillets - 5 Fillets - 5 Fillets - 5 Fillets - 5 Fillets - 5S18-Fe09244 S18-Fe09242 S18-Fe09254 S18-Fe09235 S18-Fe09257 S18-Fe09566 S18-Fe09233
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.3 0.5 <0.3 0.5 <0.3 0.5
6.4 2.7 15 11 15 17 18<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B2_PERCH4_180206 CC_B2_SOUL1_180206 CC_B2_STREVALLY1_180206 CC_B2_STREVALLY2_180206 CC_B2_STREVALLY3_180207 CC_B2_WHITING1_180206 CC_B3_BREAM1_180204Estuary perch Black sole Silver trevally Silver trevally Silver trevally Sand whiting Yellowfin/Black breamFillets - 5 Whole - 1 Fillets - 5 Fillets - 5 Fillet - 1 Fillet - 1 Fillets - 5S18-Fe09238 S18-Fe09251 S18-Fe09236 S18-Fe09237 S18-Fe10213 S18-Fe09240 S18-Fe06752
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 0.7 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 5.9 <0.5 <0.5 <0.5 <0.5 <0.5
0.4 27 1.1 2.2 <0.3 <0.3 <0.318 340 23 37 13 12 <0.3
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 1.3 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B3_BREAM2_180204 CC_B3_BREAM3_180206 CC_B3_BREAM4_180207 CC_B3_LUDERICK1_180204 CC_B3_LUDERICK2_180204 CC_B3_LUDERICK3_180204 CC_B3_LUDERICK4_180206Yellowfin/Black bream Yellowfin/Black bream Yellowfin/Black bream Luderick Luderick Luderick LuderickFillets - 3 Fillets - 2 Fillet - 1 Fillets - 5 Fillets - 5 Fillets - 5 Fillets - 5S18-Fe06716 S18-Fe09246 S18-Fe10210 S18-Fe06750 S18-Fe06751 S18-Fe06714 S18-Fe09245
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3<0.3 <0.3 1.2 1.6 2.5 1.6 1.6<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B3_MULLET1_180204 CC_B3_MULLET2_180204 CC_B3_MULLET3_180204 CC_B3_MULLET4_180204 CC_B3_PERCH1_180204 CC_B3_SCRAB1_180206 CC_B3_STREVALLY1_180204Sea mullet Sea mullet Sea mullet Sea mullet Estuary perch Blue swimmer crab Silver trevallyFillets - 5 Fillets - 5 Fillets - 5 Fillets - 3 Fillets - 2 Whole - 2 Fillet - 1S18-Fe06747 S18-Fe06748 S18-Fe06749 S18-Fe06718 S18-Fe06713 S18-Fe09247 S18-Fe06715
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.3 <0.3 <0.3 <0.3 1.4 <0.3
3 3.5 3.3 2.8 11 4.5 2.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
CC_B3_STREVALLY2_180206 CC_B3_STREVALLY3_180207 CC_B3_WHITING1_180204 CC_B3_WHITING2_180206 CC_B3_WHITING3_180206 CC_B3_WHITING4_180207 SR_B1_BASS1_180208Silver trevally Silver trevally Sand whiting Sand whiting Sand whiting Sand whiting Australian bassFillets - 5 Fillet - 1 Fillets - 3 Fillets - 5 Fillets - 3 Fillets - 3 Fillets - 5S18-Fe09250 S18-Fe10209 S18-Fe06717 S18-Fe09248 S18-Fe09256 S18-Fe10208 S18-Fe12616
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3
4.2 2.2 <0.3 1.6 1.5 0.8 5.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
QA102_180208 SR_B1_BASS2_180208 SR_B1_DFLATHEAD1_180208 SR_B1_FMULLET1_180208 SR_B1_FMULLET2_180208 SR_B1_FMULLET3_180208 SR_B1_FMULLET4_180208SR_B1_BASS1_180208 Australian bass Dusky flathead Tiger mullet Tiger mullet Tiger mullet Tiger mullet
Fillets - 5 Fillet - 1 Fillets - 5 Fillets - 5 Fillets - 5 Fillets - 5N18/005396 S18-Fe12618 S18-Fe12612 S18-Fe12617 S18-Fe12611 S18-Fe12615 S18-Fe12614
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.3 <0.3 <0.3 <0.3 <0.3 <0.33.2 9.4 4.3 2.2 2.3 3.8 2.8
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
SR_B1_MULLET1_180208 QA101_180208 SR_B1_MULLET2_180208 SR_B1_MULLET3_180208 SR_B1_MULLET4_180208 SR_B1_PERCH1_180208 SR_B2_BASS1_180209Sea mullet SR_B1_MULLET1_180208 Sea mullet Sea mullet Sea mullet Estuary perch Australian bassFillets - 5 Fillets - 5 Fillets - 5 Fillets -3 Fillets - 3 Fillets - 5S18-Fe12619 N18/005395 S18-Fe12613 S18-Fe12609 S18-Fe12608 S18-Fe12610 S18-Fe13497
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 5.1 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.5 <0.3 <0.3 <0.3 <0.3 <0.3
2.1 1.6 3.4 1.5 1.6 1.4 5.3<0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.3 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
SR_B2_BREAM1_180209 SR_B2_FMULLET1_180209 SR_B2_GARFISH1_180209 SR_B2_LUDERICK1_180209 SR_B2_MULLET1_180209 SR_B2_MULLET2_180209 SR_B2_MULLET3_180209Yellowfin/Black bream Tiger mullet Eastern sea garfish Luderick Sea mullet Sea mullet Sea mulletFillets - 2 Fillet - 1 Whole - 1 Fillet - 1 Fillets - 5 Fillets - 5 Fillets - 5S18-Fe13494 S18-Fe13492 S18-Fe13498 S18-Fe13496 S18-Fe13484 S18-Fe13487 S18-Fe13486
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3
1.3 20 2 1.2 8.5 12 13<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
SR_B2_MULLET4_180209 SR_B2_PERCH1_180209 SR_B3_BASS1_180210 SR_B3_BREAM1_180210 SR_B3_HERRING1_180210 SR_B3_MACRAB1_180210 SR_B3_MULLET1_180209Sea mullet Estuary perch Australian bass Yellowfin/Black bream Herring Mud crab Sea mulletFillets - 5 Fillet - 1 Fillet - 1 Fillet - 1 Whole - 1 Whole - 2 Fillets - 5S18-Fe13485 S18-Fe13491 S18-Fe13501 S18-Fe13488 S18-Fe13490 S18-Fe13499 S18-Fe13483
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.3 <0.3 <0.3 <0.3 <0.3 1.8 <0.3
22 2.3 6.7 1.2 8 2.9 5.3<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Biota results
HMAS ALBATROSS (251529) Units
n:2 Fluorotelomer sulfonic acids1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) µg/kg1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) µg/kg1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) µg/kg1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) µg/kg
Perfluoroalkane sulfonamides (PFASAs)2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) µg/kg2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) µg/kgN-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) µg/kgN-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) µg/kgN-methylperfluoro-1-octane sulfonamide (N-MeFOSA) µg/kgN-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) µg/kgPerfluorooctane sulfonamide (FOSA) µg/kg
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)Perfluorobutanesulfonic acid (PFBS) µg/kgPerfluorodecanesulfonic acid (PFDS) µg/kgPerfluoroheptanesulfonic acid (PFHpS) µg/kgPerfluorohexanesulfonic acid (PFHxS) µg/kgPerfluorooctanesulfonic acid (PFOS) µg/kgPerfluoropentanesulfonic acid (PFPeS) µg/kg
Perfluoroalkyl carboxylic acids (PFCAs)Perfluorobutanoic acid (PFBA) µg/kgPerfluorodecanoic acid (PFDA) µg/kgPerfluorododecanoic acid (PFDoA) µg/kgPerfluoroheptanoic acid (PFHpA) µg/kgPerfluorohexanoic acid (PFHxA) µg/kgPerfluorononanoic acid (PFNA) µg/kgPerfluorooctanoic acid (PFOA) µg/kgPerfluoropentanoic acid (PFPeA) µg/kgPerfluorotetradecanoic acid (PFTeDA) µg/kgPerfluorotridecanoic acid (PFTrDA) µg/kgPerfluoroundecanoic acid (PFUnA) µg/kg
SpeciesNumber in composite
SR_B3_MULLET2_180210 SR_B3_PERCH1_180210 SR_B3_SMULLET1_180210 SR_B3_TAILOR1_180210Sea mullet Estuary perch Sand mullet TailorFillets - 3 Fillets - 2 Fillet - 1 Fillet - 1S18-Fe13489 S18-Fe13495 S18-Fe13500 S18-Fe13493
<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.3 <0.3 <0.3 <0.3
5.4 3.6 10 0.9<0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5<0.5 <0.5 <0.5 <0.5
B
Laboratory certificates
ABN – 50 005 085 521 e.mail : [email protected] web : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne3-5 Kingston Town CloseOakleigh Vic 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261 Site # 23736
Environmental LaboratoryAir AnalysisWater AnalysisSoil Contamination Analysis
NATA AccreditationStack Emission Sampling & AnalysisTrade Waste Sampling & AnalysisGroundwater Sampling & Analysis
38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience
Sample Receipt AdviceSample Receipt AdviceSample Receipt AdviceSample Receipt Advice
Company name: Aurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty Ltd
Contact name: Christine KennellyProject name: HMAS ALBATROSSProject ID: 251529COC number: Not providedTurn around time: 5 DayDate/Time received: Feb 2, 2018 9:47 AMEurofins | mgt reference: 582917582917582917582917
Sample informationSample informationSample informationSample information
☑ A detailed list of analytes logged into our LIMS, is included in the attached summary table.
☑ All samples have been received as described on the above COC.
☑ COC has been completed correctly.
☑ Attempt to chill was evident.
☑ Appropriately preserved sample containers have been used.
☑ All samples were received in good condition.
☑ Samples have been provided with adequate time to commence analysis in accordance with therelevant holding times.
☑ Appropriate sample containers have been used.
☑ Sample containers for volatile analysis received with zero headspace.
☒ Split sample sent to requested external lab.
☒ Some samples have been subcontracted.
N/A Custody Seals intact (if used).NotesNotesNotesNotes
Missing sample - analysis cancelled: HA88_0.5_180131| Extra samples received - placed on Hold:HA97_0.1_180131, HA97_0.5_180131| 2 PFAS jars received for HA87_0.5_180131
Contact notesContact notesContact notesContact notes
If you have any questions with respect to these samples please contact:
Ryan Gilbert on Phone : or by e.mail: [email protected]
Results will be delivered electronically via e.mail to Christine Kennelly - .
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Christine Kennelly
Report 582917-S-V3
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 02, 2018
Client Sample ID HA86_0.1_180131
HA86_0.5_180131
HA87_0.1_180131
HA87_0.5_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01813 S18-Fe01814 S18-Fe01815 S18-Fe01816
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 100 106 107 108
13C5-PFPeA (surr.) 1 % 73 99 94 97
13C5-PFHxA (surr.) 1 % 125 130 131 133
13C4-PFHpA (surr.) 1 % 125 131 129 130
13C8-PFOA (surr.) 1 % 122 125 123 123
13C5-PFNA (surr.) 1 % 118 125 118 123
13C6-PFDA (surr.) 1 % 116 134 131 136
13C2-PFUnDA (surr.) 1 % 76 124 119 128
13C2-PFDoDA (surr.) 1 % 103 138 138 139
13C2-PFTeDA (surr.) 1 % 133 148 139 140
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 110 126 133 127
D3-N-MeFOSA (surr.) 1 % 54 112 106 128
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 38
Report Number: 582917-S-V3
NATA AccreditedAccreditation Number 1261Site Number 18217
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID HA86_0.1_180131
HA86_0.5_180131
HA87_0.1_180131
HA87_0.5_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01813 S18-Fe01814 S18-Fe01815 S18-Fe01816
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamido substances
D5-N-EtFOSA (surr.) 1 % 78 108 120 108
D7-N-MeFOSE (surr.) 1 % INT INT 59 81
D9-N-EtFOSE (surr.) 1 % 54 109 107 117
D5-N-EtFOSAA (surr.) 1 % 109 133 132 143
D3-N-MeFOSAA (surr.) 1 % 74 122 121 148
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 N0927
Perfluoroheptanesulfonic acid (PFHpS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg < 5 < 5 N0932 N0988
Perfluorodecanesulfonic acid (PFDS)N15 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 108 116 115 115
18O2-PFHxS (surr.) 1 % 116 125 125 121
13C8-PFOS (surr.) 1 % 118 130 128 131
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTSA (surr.) 1 % 113 105 102 97
13C2-6:2 FTSA (surr.) 1 % 168 117 108 96
13C2-8:2 FTSA (surr.) 1 % 193 124 104 105
PFASs Summations
Sum (PFHxS + PFOS)* 5 ug/kg < 5 < 5 32 115
Sum of US EPA PFAS (PFOS + PFOA)* 5 ug/kg < 5 < 5 32 88
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 5 ug/kg < 5 < 5 32 115
Sum of WA DER PFAS (n=10)* 10 ug/kg < 10 < 10 32 115
Sum of PFASs (n=28)* 50 ug/kg < 50 < 50 < 50 115
% Moisture 1 % 6.0 7.8 7.7 10
Client Sample ID HA88_0.1_180131
HA88_0.5_180131
HA89_0.1_180131
HA89_0.5_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01817 S18-Fe01818 S18-Fe01819 S18-Fe01820
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 38
Report Number: 582917-S-V3
Client Sample ID HA88_0.1_180131
HA88_0.5_180131
HA89_0.1_180131
HA89_0.5_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01817 S18-Fe01818 S18-Fe01819 S18-Fe01820
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 105 104 102 103
13C5-PFPeA (surr.) 1 % 97 101 83 93
13C5-PFHxA (surr.) 1 % 129 130 125 127
13C4-PFHpA (surr.) 1 % 128 125 124 128
13C8-PFOA (surr.) 1 % 117 126 118 123
13C5-PFNA (surr.) 1 % 120 130 118 122
13C6-PFDA (surr.) 1 % 135 138 133 136
13C2-PFUnDA (surr.) 1 % 129 115 126 126
13C2-PFDoDA (surr.) 1 % 141 133 136 141
13C2-PFTeDA (surr.) 1 % 141 113 136 137
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 132 136 125 121
D3-N-MeFOSA (surr.) 1 % 128 90 109 116
D5-N-EtFOSA (surr.) 1 % 119 95 104 101
D7-N-MeFOSE (surr.) 1 % 120 83 45 95
D9-N-EtFOSE (surr.) 1 % 128 83 115 111
D5-N-EtFOSAA (surr.) 1 % 136 129 132 121
D3-N-MeFOSAA (surr.) 1 % 138 125 138 129
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg N0914 N09110 < 5 N0932
Perfluorodecanesulfonic acid (PFDS)N15 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 111 123 109 112
18O2-PFHxS (surr.) 1 % 124 129 120 121
13C8-PFOS (surr.) 1 % 130 114 129 129
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 38
Report Number: 582917-S-V3
Client Sample ID HA88_0.1_180131
HA88_0.5_180131
HA89_0.1_180131
HA89_0.5_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01817 S18-Fe01818 S18-Fe01819 S18-Fe01820
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTSA (surr.) 1 % 93 119 94 95
13C2-6:2 FTSA (surr.) 1 % 110 109 95 89
13C2-8:2 FTSA (surr.) 1 % 92 133 96 112
PFASs Summations
Sum (PFHxS + PFOS)* 5 ug/kg 14 110 < 5 32
Sum of US EPA PFAS (PFOS + PFOA)* 5 ug/kg 14 110 < 5 32
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 5 ug/kg 14 110 < 5 32
Sum of WA DER PFAS (n=10)* 10 ug/kg 14 110 < 10 32
Sum of PFASs (n=28)* 50 ug/kg < 50 110 < 50 < 50
% Moisture 1 % 9.8 23 22 17
Client Sample ID HA90_0.1_180131
HA90_0.5_180131
HA91_0.1_180131
HA91_0.5_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01821 S18-Fe01822 S18-Fe01823 S18-Fe01824
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 100 105 101 104
13C5-PFPeA (surr.) 1 % 85 95 90 89
13C5-PFHxA (surr.) 1 % 125 128 130 132
13C4-PFHpA (surr.) 1 % 125 127 127 129
13C8-PFOA (surr.) 1 % 116 120 115 122
13C5-PFNA (surr.) 1 % 112 118 120 123
13C6-PFDA (surr.) 1 % 115 130 129 134
13C2-PFUnDA (surr.) 1 % 100 114 114 115
13C2-PFDoDA (surr.) 1 % 68 119 119 130
13C2-PFTeDA (surr.) 1 % 54 109 116 123
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 38
Report Number: 582917-S-V3
Client Sample ID HA90_0.1_180131
HA90_0.5_180131
HA91_0.1_180131
HA91_0.5_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01821 S18-Fe01822 S18-Fe01823 S18-Fe01824
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 62 107 108 109
D3-N-MeFOSA (surr.) 1 % 78 99 107 107
D5-N-EtFOSA (surr.) 1 % 72 106 97 100
D7-N-MeFOSE (surr.) 1 % 63 190 82 83
D9-N-EtFOSE (surr.) 1 % 72 91 96 103
D5-N-EtFOSAA (surr.) 1 % 54 92 111 122
D3-N-MeFOSAA (surr.) 1 % 71 115 124 126
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 N0912
Perfluoroheptanesulfonic acid (PFHpS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg N0912 N0933 N0947 N09130
Perfluorodecanesulfonic acid (PFDS)N15 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 108 112 113 114
18O2-PFHxS (surr.) 1 % 113 119 120 118
13C8-PFOS (surr.) 1 % 118 126 120 117
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTSA (surr.) 1 % 92 94 94 94
13C2-6:2 FTSA (surr.) 1 % 103 103 92 112
13C2-8:2 FTSA (surr.) 1 % 88 92 103 99
PFASs Summations
Sum (PFHxS + PFOS)* 5 ug/kg 12 33 47 142
Sum of US EPA PFAS (PFOS + PFOA)* 5 ug/kg 12 33 47 130
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 5 ug/kg 12 33 47 142
Sum of WA DER PFAS (n=10)* 10 ug/kg 12 33 47 142
Sum of PFASs (n=28)* 50 ug/kg < 50 < 50 < 50 142
% Moisture 1 % 40 27 6.3 15
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 5 of 38
Report Number: 582917-S-V3
Client Sample ID HA92_0.1_180131
HA92_0.5_180131
HA93_0.1_180131
HA93_0.5_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01825 S18-Fe01826 S18-Fe01827 S18-Fe01828
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 100 98 97 85
13C5-PFPeA (surr.) 1 % 102 86 78 73
13C5-PFHxA (surr.) 1 % 131 126 125 111
13C4-PFHpA (surr.) 1 % 127 125 122 110
13C8-PFOA (surr.) 1 % 113 117 116 102
13C5-PFNA (surr.) 1 % 122 118 111 103
13C6-PFDA (surr.) 1 % 134 124 130 116
13C2-PFUnDA (surr.) 1 % 117 109 112 97
13C2-PFDoDA (surr.) 1 % 131 128 126 117
13C2-PFTeDA (surr.) 1 % 120 141 122 123
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 123 121 114 109
D3-N-MeFOSA (surr.) 1 % 109 112 109 99
D5-N-EtFOSA (surr.) 1 % 107 114 84 94
D7-N-MeFOSE (surr.) 1 % 69 83 150 INT
D9-N-EtFOSE (surr.) 1 % 108 113 110 105
D5-N-EtFOSAA (surr.) 1 % 108 120 105 111
D3-N-MeFOSAA (surr.) 1 % 119 116 122 116
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanesulfonic acid (PFDS)N15 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 112 110 109 96
18O2-PFHxS (surr.) 1 % 118 120 113 106
13C8-PFOS (surr.) 1 % 130 123 120 110
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 6 of 38
Report Number: 582917-S-V3
Client Sample ID HA92_0.1_180131
HA92_0.5_180131
HA93_0.1_180131
HA93_0.5_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01825 S18-Fe01826 S18-Fe01827 S18-Fe01828
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTSA (surr.) 1 % 98 86 89 78
13C2-6:2 FTSA (surr.) 1 % 111 106 109 100
13C2-8:2 FTSA (surr.) 1 % 99 108 80 87
PFASs Summations
Sum (PFHxS + PFOS)* 5 ug/kg < 5 < 5 < 5 < 5
Sum of US EPA PFAS (PFOS + PFOA)* 5 ug/kg < 5 < 5 < 5 < 5
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 5 ug/kg < 5 < 5 < 5 < 5
Sum of WA DER PFAS (n=10)* 10 ug/kg < 10 < 10 < 10 < 10
Sum of PFASs (n=28)* 50 ug/kg < 50 < 50 < 50 < 50
% Moisture 1 % 4.8 31 30 29
Client Sample ID HA94_0.1_180131
HA95_0.1_180131
HA96_0.1_180131
HA96_0.4_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01829 S18-Fe01830 S18-Fe01831 S18-Fe01832
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 99 94 86 87
13C5-PFPeA (surr.) 1 % 83 88 83 85
13C5-PFHxA (surr.) 1 % 127 125 128 134
13C4-PFHpA (surr.) 1 % 124 120 120 129
13C8-PFOA (surr.) 1 % 112 111 111 121
13C5-PFNA (surr.) 1 % 112 114 113 118
13C6-PFDA (surr.) 1 % 135 128 130 138
13C2-PFUnDA (surr.) 1 % 119 111 102 112
13C2-PFDoDA (surr.) 1 % 143 127 125 136
13C2-PFTeDA (surr.) 1 % 139 139 128 135
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 7 of 38
Report Number: 582917-S-V3
Client Sample ID HA94_0.1_180131
HA95_0.1_180131
HA96_0.1_180131
HA96_0.4_180131
Sample Matrix Sediment Sediment Sediment Sediment
Eurofins | mgt Sample No. S18-Fe01829 S18-Fe01830 S18-Fe01831 S18-Fe01832
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 135 128 122 136
D3-N-MeFOSA (surr.) 1 % 117 106 108 117
D5-N-EtFOSA (surr.) 1 % 106 101 92 90
D7-N-MeFOSE (surr.) 1 % 100 126 133 109
D9-N-EtFOSE (surr.) 1 % 126 117 113 110
D5-N-EtFOSAA (surr.) 1 % 132 133 120 127
D3-N-MeFOSAA (surr.) 1 % 133 128 123 131
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanesulfonic acid (PFDS)N15 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 113 107 109 115
18O2-PFHxS (surr.) 1 % 120 114 118 124
13C8-PFOS (surr.) 1 % 124 114 119 122
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTSA (surr.) 1 % 88 85 80 81
13C2-6:2 FTSA (surr.) 1 % 89 110 89 101
13C2-8:2 FTSA (surr.) 1 % 96 142 104 103
PFASs Summations
Sum (PFHxS + PFOS)* 5 ug/kg < 5 < 5 < 5 < 5
Sum of US EPA PFAS (PFOS + PFOA)* 5 ug/kg < 5 < 5 < 5 < 5
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 5 ug/kg < 5 < 5 < 5 < 5
Sum of WA DER PFAS (n=10)* 10 ug/kg < 10 < 10 < 10 < 10
Sum of PFASs (n=28)* 50 ug/kg < 50 < 50 < 50 < 50
% Moisture 1 % 15 27 17 21
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 8 of 38
Report Number: 582917-S-V3
Client Sample ID QA101_180131SED_W04_180130 QA101_180130
HA97_0.1_180131
Sample Matrix Sediment Sediment Soil Sediment
Eurofins | mgt Sample No. S18-Fe01833 S18-Fe01835 S18-Fe01845 S18-Fe02002
Date Sampled Jan 31, 2018 Jan 30, 2018 Jan 30, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 77 64 109 66
13C5-PFPeA (surr.) 1 % 83 84 110 90
13C5-PFHxA (surr.) 1 % 122 123 129 113
13C4-PFHpA (surr.) 1 % 117 115 121 116
13C8-PFOA (surr.) 1 % 113 110 127 121
13C5-PFNA (surr.) 1 % 110 102 131 117
13C6-PFDA (surr.) 1 % 127 129 146 120
13C2-PFUnDA (surr.) 1 % 95 107 117 101
13C2-PFDoDA (surr.) 1 % 119 130 135 111
13C2-PFTeDA (surr.) 1 % 123 141 130 104
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 113 142 139 106
D3-N-MeFOSA (surr.) 1 % 77 115 114 93
D5-N-EtFOSA (surr.) 1 % 82 95 87 90
D7-N-MeFOSE (surr.) 1 % 88 50 139 183
D9-N-EtFOSE (surr.) 1 % 86 134 101 72
D5-N-EtFOSAA (surr.) 1 % 121 126 172 101
D3-N-MeFOSAA (surr.) 1 % 123 123 160 109
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS)N15 5 ug/kg < 5 < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanesulfonic acid (PFDS)N15 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 107 106 121 115
18O2-PFHxS (surr.) 1 % 115 120 126 116
13C8-PFOS (surr.) 1 % 107 121 98 106
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 9 of 38
Report Number: 582917-S-V3
Client Sample ID QA101_180131SED_W04_180130 QA101_180130
HA97_0.1_180131
Sample Matrix Sediment Sediment Soil Sediment
Eurofins | mgt Sample No. S18-Fe01833 S18-Fe01835 S18-Fe01845 S18-Fe02002
Date Sampled Jan 31, 2018 Jan 30, 2018 Jan 30, 2018 Jan 31, 2018
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 10 ug/kg < 10 < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTSA (surr.) 1 % 70 58 125 84
13C2-6:2 FTSA (surr.) 1 % 96 83 109 88
13C2-8:2 FTSA (surr.) 1 % 89 81 170 132
PFASs Summations
Sum (PFHxS + PFOS)* 5 ug/kg < 5 < 5 < 5 < 5
Sum of US EPA PFAS (PFOS + PFOA)* 5 ug/kg < 5 < 5 < 5 < 5
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 5 ug/kg < 5 < 5 < 5 < 5
Sum of WA DER PFAS (n=10)* 10 ug/kg < 10 < 10 < 10 < 10
Sum of PFASs (n=28)* 50 ug/kg < 50 < 50 < 50 < 50
% Moisture 1 % 50 22 11 55
Client Sample ID HA97_0.5_180131
Sample Matrix Sediment
Eurofins | mgt Sample No. S18-Fe02003
Date Sampled Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5
Perfluoroundecanoic acid (PFUnDA)N11 5 ug/kg < 5
Perfluorododecanoic acid (PFDoDA)N11 5 ug/kg < 5
Perfluorotridecanoic acid (PFTrDA)N15 5 ug/kg < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5
13C4-PFBA (surr.) 1 % 84
13C5-PFPeA (surr.) 1 % 98
13C5-PFHxA (surr.) 1 % 118
13C4-PFHpA (surr.) 1 % 120
13C8-PFOA (surr.) 1 % 128
13C5-PFNA (surr.) 1 % 121
13C6-PFDA (surr.) 1 % 132
13C2-PFUnDA (surr.) 1 % 112
13C2-PFDoDA (surr.) 1 % 119
13C2-PFTeDA (surr.) 1 % 129
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 10 of 38
Report Number: 582917-S-V3
Client Sample ID HA97_0.5_180131
Sample Matrix Sediment
Eurofins | mgt Sample No. S18-Fe02003
Date Sampled Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10
13C8-FOSA (surr.) 1 % 114
D3-N-MeFOSA (surr.) 1 % 116
D5-N-EtFOSA (surr.) 1 % 98
D7-N-MeFOSE (surr.) 1 % 48
D9-N-EtFOSE (surr.) 1 % 92
D5-N-EtFOSAA (surr.) 1 % 110
D3-N-MeFOSAA (surr.) 1 % 114
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5
Perfluoropentanesulfonic acid (PFPeS)N15 5 ug/kg < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5
Perfluoroheptanesulfonic acid (PFHpS)N15 5 ug/kg < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg < 5
Perfluorodecanesulfonic acid (PFDS)N15 5 ug/kg < 5
13C3-PFBS (surr.) 1 % 118
18O2-PFHxS (surr.) 1 % 119
13C8-PFOS (surr.) 1 % 107
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 5 ug/kg < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 10 ug/kg < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 5 ug/kg < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 5 ug/kg < 5
13C2-4:2 FTSA (surr.) 1 % 96
13C2-6:2 FTSA (surr.) 1 % 120
13C2-8:2 FTSA (surr.) 1 % 126
PFASs Summations
Sum (PFHxS + PFOS)* 5 ug/kg < 5
Sum of US EPA PFAS (PFOS + PFOA)* 5 ug/kg < 5
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 5 ug/kg < 5
Sum of WA DER PFAS (n=10)* 10 ug/kg < 10
Sum of PFASs (n=28)* 50 ug/kg < 50
% Moisture 1 % 42
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 11 of 38
Report Number: 582917-S-V3
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 08, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
Perfluoroalkane sulfonamido substances Brisbane Feb 08, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
Perfluoroalkane sulfonic acids (PFSAs) Brisbane Feb 08, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Brisbane Feb 08, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
% Moisture Brisbane Feb 06, 2018 14 Day
- Method: LTM-GEN-7080 Moisture
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 12 of 38
Report Number: 582917-S-V3
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 HA86_0.1_180131
Jan 31, 2018 Sediment S18-Fe01813 X X
2 HA86_0.5_180131
Jan 31, 2018 Sediment S18-Fe01814 X X
3 HA87_0.1_180131
Jan 31, 2018 Sediment S18-Fe01815 X X
4 HA87_0.5_180131
Jan 31, 2018 Sediment S18-Fe01816 X X
5 HA88_0.1_180131
Jan 31, 2018 Sediment S18-Fe01817 X X
6 HA88_0.5_180 Jan 31, 2018 Sediment S18-Fe01818 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
First Reported:Feb 19, 2018
Date Reported:Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 13 of 38
Report Number: 582917-S-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
7 HA89_0.1_180131
Jan 31, 2018 Sediment S18-Fe01819 X X
8 HA89_0.5_180131
Jan 31, 2018 Sediment S18-Fe01820 X X
9 HA90_0.1_180131
Jan 31, 2018 Sediment S18-Fe01821 X X
10 HA90_0.5_180131
Jan 31, 2018 Sediment S18-Fe01822 X X
11 HA91_0.1_180131
Jan 31, 2018 Sediment S18-Fe01823 X X
12 HA91_0.5_180131
Jan 31, 2018 Sediment S18-Fe01824 X X
13 HA92_0.1_180 Jan 31, 2018 Sediment S18-Fe01825 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 14 of 38
Report Number: 582917-S-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
14 HA92_0.5_180131
Jan 31, 2018 Sediment S18-Fe01826 X X
15 HA93_0.1_180131
Jan 31, 2018 Sediment S18-Fe01827 X X
16 HA93_0.5_180131
Jan 31, 2018 Sediment S18-Fe01828 X X
17 HA94_0.1_180131
Jan 31, 2018 Sediment S18-Fe01829 X X
18 HA95_0.1_180131
Jan 31, 2018 Sediment S18-Fe01830 X X
19 HA96_0.1_180131
Jan 31, 2018 Sediment S18-Fe01831 X X
20 HA96_0.4_180 Jan 31, 2018 Sediment S18-Fe01832 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 15 of 38
Report Number: 582917-S-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
21 QA101_180131
Jan 31, 2018 Sediment S18-Fe01833 X X
22 SW_W04_180130
Jan 30, 2018 Water (Ultra-trace)
S18-Fe01834 X
23 SED_W04_180130
Jan 30, 2018 Sediment S18-Fe01835 X X
24 TP01_0.1_180130
Jan 30, 2018 Soil S18-Fe01837 X X
25 TP01_0.9_180130
Jan 30, 2018 Soil S18-Fe01838 X X
26 TP02_0.1_180130
Jan 30, 2018 Soil S18-Fe01839 X X
27 TP02_1.6_180 Jan 30, 2018 Soil S18-Fe01840 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 16 of 38
Report Number: 582917-S-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
130
28 TP03_0.1_180130
Jan 30, 2018 Soil S18-Fe01841 X X
29 TP03_1.0_180130
Jan 30, 2018 Soil S18-Fe01842 X X
30 TP04_0.1_180130
Jan 30, 2018 Soil S18-Fe01843 X X
31 TP04_1.0_180130
Jan 30, 2018 Soil S18-Fe01844 X X
32 QA101_180130
Jan 30, 2018 Soil S18-Fe01845 X X
33 TP05A_0.1_180130
Jan 30, 2018 Soil S18-Fe01847 X X
34 TP05B_0.1_18 Jan 30, 2018 Soil S18-Fe01848 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 17 of 38
Report Number: 582917-S-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
0130
35 TP06_0.1_180130
Jan 30, 2018 Soil S18-Fe01849 X X
36 TP06_1.0_180130
Jan 30, 2018 Soil S18-Fe01850 X X
37 TP07_0.1_180130
Jan 30, 2018 Soil S18-Fe01851 X X
38 TP07_1.0_180130
Jan 30, 2018 Soil S18-Fe01852 X X
39 TP08_0.1_180130
Jan 30, 2018 Soil S18-Fe01853 X X
40 TP08_0.9_180130
Jan 30, 2018 Soil S18-Fe01854 X X
41 TP09_0.1_180 Jan 30, 2018 Soil S18-Fe01855 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 18 of 38
Report Number: 582917-S-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
130
42 TP09_1.0_180130
Jan 30, 2018 Soil S18-Fe01856 X X
43 TP09_2.0_180130
Jan 30, 2018 Soil S18-Fe01857 X
44 SW_POU24_180130
Jan 30, 2018 Water (Ultra-trace)
S18-Fe01858 X
45 SED_POU24_180130
Jan 30, 2018 Sediment S18-Fe01859 X X
46 SED_POU25A_180130
Jan 30, 2018 Sediment S18-Fe01860 X X
47 SED_POU25B_180130
Jan 30, 2018 Sediment S18-Fe01861 X X
48 HA97_0.1_180 Jan 31, 2018 Sediment S18-Fe02002 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 19 of 38
Report Number: 582917-S-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
49 HA97_0.5_180131
Jan 31, 2018 Sediment S18-Fe02003 X X
50 HA86_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06016 X X
51 HA86_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06017 X X
52 HA87_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06018 X X
53 HA87_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06019 X X
54 HA88_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06020 X X
55 HA88_0.5_180 Jan 31, 2018 AUS Leachate S18-Fe06021 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 20 of 38
Report Number: 582917-S-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
56 HA89_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06022 X X
57 HA89_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06023 X X
58 HA90_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06024 X X
59 HA90_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06025 X X
60 HA91_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06026 X X
61 HA91_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06027 X X
62 HA92_0.1_180 Jan 31, 2018 AUS Leachate S18-Fe06028 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 21 of 38
Report Number: 582917-S-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
63 HA92_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06029 X X
64 HA93_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06030 X X
65 HA93_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06031 X X
66 HA94_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06032 X X
67 HA95_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06033 X X
68 HA96_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06034 X X
69 HA96_0.4_180 Jan 31, 2018 AUS Leachate S18-Fe06035 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 22 of 38
Report Number: 582917-S-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
70 QA101_180131
Jan 31, 2018 AUS Leachate S18-Fe06036 X X
71 SW_W04_180130
Jan 30, 2018 Water S18-Fe06037 X X X X X X X X
72 SED_W04_180130
Jan 30, 2018 AUS Leachate S18-Fe06038 X X
73 SED_POU24_180130
Jan 30, 2018 AUS Leachate S18-Fe06039 X X
74 SED_POU25A_180130
Jan 30, 2018 AUS Leachate S18-Fe06040 X X
75 SED_POU25B_180130
Jan 30, 2018 AUS Leachate S18-Fe06041 X X
Test Counts 1 1 1 1 1 1 1 25 1 1 46 71 2
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 23 of 38
Report Number: 582917-S-V3
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota/food results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the SRA.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
For VOCs containing vinyl chloride, styrene and 2-chloroethyl vinyl ether the holding time is 7 days however for all other VOCs such as BTEX or C6-10 TRH then the holding time is 14 days.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre ug/L: micrograms per litre
ppm: Parts per million ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 24 of 38
Report Number: 582917-S-V3
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 5 5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 5 5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 5 5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 5 5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 5 5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 5 5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 5 5 Pass
Perfluoroundecanoic acid (PFUnDA) ug/kg < 5 5 Pass
Perfluorododecanoic acid (PFDoDA) ug/kg < 5 5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 5 5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 5 5 Pass
Method Blank
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA) ug/kg < 5 5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 5 5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 5 5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 5 5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 5 5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 10 10 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 10 10 Pass
Method Blank
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 5 5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 5 5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 5 5 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 5 5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 5 5 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 5 5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTSA) ug/kg < 5 5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTSA) ug/kg < 10 10 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTSA) ug/kg < 5 5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTSA) ug/kg < 5 5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 91 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 100 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 87 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) % 92 50-150 Pass
Perfluorononanoic acid (PFNA) % 92 50-150 Pass
Perfluorodecanoic acid (PFDA) % 99 50-150 Pass
Perfluoroundecanoic acid (PFUnDA) % 70 50-150 Pass
Perfluorododecanoic acid (PFDoDA) % 105 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 81 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 87 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamido substances
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 25 of 38
Report Number: 582917-S-V3
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 89 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 95 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 94 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 73 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 105 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 101 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 82 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 91 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 87 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 97 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 102 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 76 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTSA) % 84 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTSA) % 87 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTSA) % 114 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTSA) % 125 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe01821 CP % 97 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01821 CP % 122 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01821 CP % 88 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01821 CP % 93 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe01821 CP % 98 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe01821 CP % 95 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe01821 CP % 112 50-150 Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01821 CP % 75 50-150 Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe01821 CP % 112 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01821 CP % 101 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01821 CP % 111 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamido substances Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe01821 CP % 93 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01821 CP % 84 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01821 CP % 84 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01821 CP % 80 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01821 CP % 100 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01821 CP % 93 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01821 CP % 91 50-150 Pass
Spike - % Recovery
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 26 of 38
Report Number: 582917-S-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonic acids (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S18-Fe01821 CP % 76 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01821 CP % 88 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01821 CP % 94 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01821 CP % 99 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01821 CP % 112 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01821 CP % 72 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01821 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01821 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01821 CP % 120 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01821 CP % 84 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe01831 CP % 98 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01831 CP % 120 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01831 CP % 85 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01831 CP % 94 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe01831 CP % 101 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe01831 CP % 98 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe01831 CP % 108 50-150 Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01831 CP % 73 50-150 Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe01831 CP % 111 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01831 CP % 108 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01831 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamido substances Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe01831 CP % 94 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01831 CP % 91 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01831 CP % 84 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01831 CP % 84 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01831 CP % 110 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01831 CP % 92 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01831 CP % 99 50-150 Pass
Spike - % Recovery
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 27 of 38
Report Number: 582917-S-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonic acids (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S18-Fe01831 CP % 78 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01831 CP % 89 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01831 CP % 93 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01831 CP % 110 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01831 CP % 97 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01831 CP % 73 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01831 CP % 87 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01831 CP % 99 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01831 CP % 130 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01831 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe01837 CP % 94 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01837 CP % 105 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01837 CP % 90 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01837 CP % 98 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe01837 CP % 101 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe01837 CP % 100 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe01837 CP % 104 50-150 Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01837 CP % 77 50-150 Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe01837 CP % 112 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01837 CP % 88 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01837 CP % 103 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamido substances Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe01837 CP % 93 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01837 CP % 104 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01837 CP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01837 CP % 104 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01837 CP % 128 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01837 CP % 86 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01837 CP % 94 50-150 Pass
Spike - % Recovery
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 28 of 38
Report Number: 582917-S-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonic acids (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S18-Fe01837 CP % 88 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01837 CP % 95 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01837 CP % 91 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01837 CP % 105 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01837 CP % 101 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01837 CP % 85 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01837 CP % 89 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01837 CP % 85 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01837 CP % 111 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01837 CP % 130 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe01848 CP % 92 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01848 CP % 99 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01848 CP % 86 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01848 CP % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe01848 CP % 91 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe01848 CP % 93 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe01848 CP % 98 50-150 Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01848 CP % 69 50-150 Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe01848 CP % 105 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01848 CP % 80 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01848 CP % 93 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamido substances Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe01848 CP % 85 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01848 CP % 90 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01848 CP % 88 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01848 CP % 83 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01848 CP % 111 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01848 CP % 96 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01848 CP % 109 50-150 Pass
Spike - % Recovery
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 29 of 38
Report Number: 582917-S-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonic acids (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S18-Fe01848 CP % 80 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01848 CP % 89 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01848 CP % 88 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01848 CP % 96 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01848 CP % 86 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01848 CP % 78 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01848 CP % 90 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01848 CP % 96 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01848 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01848 CP % 118 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe01861 CP % 95 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01861 CP % 98 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01861 CP % 91 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01861 CP % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe01861 CP % 96 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe01861 CP % 100 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe01861 CP % 104 50-150 Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01861 CP % 75 50-150 Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe01861 CP % 113 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01861 CP % 86 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01861 CP % 100 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamido substances Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe01861 CP % 94 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01861 CP % 88 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01861 CP % 89 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01861 CP % 82 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01861 CP % 105 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01861 CP % 102 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01861 CP % 106 50-150 Pass
Spike - % Recovery
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 30 of 38
Report Number: 582917-S-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonic acids (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S18-Fe01861 CP % 86 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01861 CP % 93 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01861 CP % 92 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01861 CP % 97 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01861 CP % 91 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01861 CP % 78 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01861 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01861 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01861 CP % 117 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01861 CP % 133 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Result 1 Result 2 RPD
% Moisture S18-Fe01813 CP % 6.0 7.3 19 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 31 of 38
Report Number: 582917-S-V3
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01818 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01818 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01818 CP ug/kg 110 110 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01818 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01818 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 32 of 38
Report Number: 582917-S-V3
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01820 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01820 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01820 CP ug/kg 32 33 1.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01820 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01820 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
% Moisture S18-Fe01824 CP % 15 14 2.0 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 33 of 38
Report Number: 582917-S-V3
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01830 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01830 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01830 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01830 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
% Moisture S18-Fe01835 CP % 22 23 6.0 30% Pass
Duplicate
Result 1 Result 2 RPD
% Moisture S18-Fe01844 CP % 11 11 1.0 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 34 of 38
Report Number: 582917-S-V3
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorododecanoic acid(PFDoDA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01847 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01847 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01847 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01847 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
% Moisture S18-Fe01855 CP % 8.6 7.6 12 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 35 of 38
Report Number: 582917-S-V3
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorodecanoic acid (PFDA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01859 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01859 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01859 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01859 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 36 of 38
Report Number: 582917-S-V3
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorodecanoic acid (PFDA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe01860 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe01860 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe01860 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe01860 CP ug/kg < 5 < 5 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 37 of 38
Report Number: 582917-S-V3
Comments
V3 - REMAINING SAMPLES
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Myles Clark Senior Analyst-Metal (QLD)
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 38 of 38
Report Number: 582917-S-V3
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Christine Kennelly
Report 582917-L-V3
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 02, 2018
Client Sample ID HA86_0.1_180131
HA86_0.5_180131
HA87_0.1_180131
HA87_0.5_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06016 S18-Fe06017 S18-Fe06018 S18-Fe06019
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 0.04 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 0.05 0.02
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 0.02 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 82 81 80 80
13C5-PFPeA (surr.) 1 % 89 81 90 91
13C5-PFHxA (surr.) 1 % 114 113 110 111
13C4-PFHpA (surr.) 1 % 115 118 118 118
13C8-PFOA (surr.) 1 % 123 132 134 135
13C5-PFNA (surr.) 1 % 110 119 125 130
13C6-PFDA (surr.) 1 % 118 130 136 136
13C2-PFUnDA (surr.) 1 % 92 90 105 99
13C2-PFDoDA (surr.) 1 % 98 86 102 108
13C2-PFTeDA (surr.) 1 % 72 54 80 79
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 92 87 108 95
D3-N-MeFOSA (surr.) 1 % 47 33 48 54
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 30
Report Number: 582917-L-V3
NATA AccreditedAccreditation Number 1261Site Number 18217
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID HA86_0.1_180131
HA86_0.5_180131
HA87_0.1_180131
HA87_0.5_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06016 S18-Fe06017 S18-Fe06018 S18-Fe06019
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamido substances
D5-N-EtFOSA (surr.) 1 % 59 35 58 65
D7-N-MeFOSE (surr.) 1 % 61 42 94 63
D9-N-EtFOSE (surr.) 1 % 43 31 43 46
D5-N-EtFOSAA (surr.) 1 % 69 72 74 70
D3-N-MeFOSAA (surr.) 1 % 68 71 75 74
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 0.02 < 0.01
Perfluoropentanesulfonic acid (PFPeS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 0.01 0.16 0.13
Perfluoroheptanesulfonic acid (PFHpS)N15 0.01 ug/L < 0.01 < 0.01 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L 0.01 0.04 1.1 0.62
Perfluorodecanesulfonic acid (PFDS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 105 106 104 103
18O2-PFHxS (surr.) 1 % 117 115 111 111
13C8-PFOS (surr.) 1 % 129 137 120 122
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTSA (surr.) 1 % 101 105 106 89
13C2-6:2 FTSA (surr.) 1 % 131 134 135 121
13C2-8:2 FTSA (surr.) 1 % 88 93 100 92
PFASs Summations
Sum (PFHxS + PFOS)* 0.01 ug/L 0.01 0.05 1.26 0.75
Sum of US EPA PFAS (PFOS + PFOA)* 0.01 ug/L 0.01 0.04 1.12 0.62
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.01 ug/L 0.01 0.05 1.28 0.75
Sum of WA DER PFAS (n=10)* 0.05 ug/L < 0.05 0.05 1.39 0.77
Sum of PFASs (n=28)* 0.1 ug/L < 0.1 < 0.1 1.4 0.77
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 8.1 7.8 8.8 8.7
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 8.0 7.4 7.4 8.1
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 30
Report Number: 582917-L-V3
Client Sample ID HA88_0.1_180131
HA88_0.5_180131
HA89_0.1_180131
HA89_0.5_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06020 S18-Fe06021 S18-Fe06022 S18-Fe06023
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 0.02 < 0.01 0.02
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L 0.02 0.09 < 0.01 0.03
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 0.02
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 0.02
Perfluorotridecanoic acid (PFTrDA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 0.03
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 81 80 79 197
13C5-PFPeA (surr.) 1 % 90 84 86 148
13C5-PFHxA (surr.) 1 % 111 109 111 150
13C4-PFHpA (surr.) 1 % 119 119 117 127
13C8-PFOA (surr.) 1 % 137 135 135 127
13C5-PFNA (surr.) 1 % 130 125 127 101
13C6-PFDA (surr.) 1 % 137 125 141 96
13C2-PFUnDA (surr.) 1 % 101 96 112 56
13C2-PFDoDA (surr.) 1 % 111 99 134 49
13C2-PFTeDA (surr.) 1 % 87 67 105 34
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 100 97 107 54
D3-N-MeFOSA (surr.) 1 % 56 47 62 13
D5-N-EtFOSA (surr.) 1 % 64 55 82 12
D7-N-MeFOSE (surr.) 1 % 50 53 47 INT
D9-N-EtFOSE (surr.) 1 % 48 41 55 11
D5-N-EtFOSAA (surr.) 1 % 68 70 81 140
D3-N-MeFOSAA (surr.) 1 % 70 70 79 155
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L 0.10 0.05 < 0.01 0.11
Perfluoroheptanesulfonic acid (PFHpS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L 0.26 1.6 0.08 0.79
Perfluorodecanesulfonic acid (PFDS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 106 106 107 17
18O2-PFHxS (surr.) 1 % 115 113 118 19
13C8-PFOS (surr.) 1 % 142 102 143 34
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 30
Report Number: 582917-L-V3
Client Sample ID HA88_0.1_180131
HA88_0.5_180131
HA89_0.1_180131
HA89_0.5_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06020 S18-Fe06021 S18-Fe06022 S18-Fe06023
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTSA (surr.) 1 % 99 109 98 199
13C2-6:2 FTSA (surr.) 1 % 134 137 139 149
13C2-8:2 FTSA (surr.) 1 % 103 93 105 80
PFASs Summations
Sum (PFHxS + PFOS)* 0.01 ug/L 0.36 1.65 0.08 0.9
Sum of US EPA PFAS (PFOS + PFOA)* 0.01 ug/L 0.26 1.6 0.08 0.81
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.01 ug/L 0.36 1.65 0.08 0.92
Sum of WA DER PFAS (n=10)* 0.05 ug/L 0.38 1.76 0.08 0.97
Sum of PFASs (n=28)* 0.1 ug/L 0.38 1.76 < 0.1 1.02
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 8.7 7.1 6.8 7.5
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 7.2 7.4 7.3 7.0
Client Sample ID HA90_0.1_180131
HA90_0.5_180131
HA91_0.1_180131
HA91_0.5_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06024 S18-Fe06025 S18-Fe06026 S18-Fe06027
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 0.02 0.03
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 0.03 0.10
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 0.03
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 0.04
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 81 82 81 82
13C5-PFPeA (surr.) 1 % 87 84 84 89
13C5-PFHxA (surr.) 1 % 112 109 109 109
13C4-PFHpA (surr.) 1 % 112 107 108 111
13C8-PFOA (surr.) 1 % 127 118 114 118
13C5-PFNA (surr.) 1 % 112 117 107 120
13C6-PFDA (surr.) 1 % 110 116 102 109
13C2-PFUnDA (surr.) 1 % 86 84 68 91
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 30
Report Number: 582917-L-V3
Client Sample ID HA90_0.1_180131
HA90_0.5_180131
HA91_0.1_180131
HA91_0.5_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06024 S18-Fe06025 S18-Fe06026 S18-Fe06027
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C2-PFDoDA (surr.) 1 % 94 96 61 97
13C2-PFTeDA (surr.) 1 % 51 65 34 53
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 93 102 56 91
D3-N-MeFOSA (surr.) 1 % 37 53 20 42
D5-N-EtFOSA (surr.) 1 % 46 75 27 50
D7-N-MeFOSE (surr.) 1 % 51 66 50 96
D9-N-EtFOSE (surr.) 1 % 35 47 19 35
D5-N-EtFOSAA (surr.) 1 % 63 69 91 120
D3-N-MeFOSAA (surr.) 1 % 67 66 65 74
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 0.04
Perfluoropentanesulfonic acid (PFPeS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 0.05
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 0.02 0.06 0.59
Perfluoroheptanesulfonic acid (PFHpS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 0.04
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L 0.08 0.51 1.4 4.7
Perfluorodecanesulfonic acid (PFDS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 105 103 105 104
18O2-PFHxS (surr.) 1 % 114 116 112 101
13C8-PFOS (surr.) 1 % 120 113 86 100
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTSA (surr.) 1 % 95 80 85 85
13C2-6:2 FTSA (surr.) 1 % 119 90 112 122
13C2-8:2 FTSA (surr.) 1 % 92 94 88 91
PFASs Summations
Sum (PFHxS + PFOS)* 0.01 ug/L 0.08 0.53 1.46 5.29
Sum of US EPA PFAS (PFOS + PFOA)* 0.01 ug/L 0.08 0.51 1.4 4.74
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.01 ug/L 0.08 0.53 1.46 5.33
Sum of WA DER PFAS (n=10)* 0.05 ug/L 0.08 0.53 1.51 5.53
Sum of PFASs (n=28)* 0.1 ug/L < 0.1 0.53 1.51 5.62
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 5 of 30
Report Number: 582917-L-V3
Client Sample ID HA90_0.1_180131
HA90_0.5_180131
HA91_0.1_180131
HA91_0.5_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06024 S18-Fe06025 S18-Fe06026 S18-Fe06027
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 6.5 7.6 7.5 7.0
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 6.6 6.6 6.7 6.7
Client Sample ID HA92_0.1_180131
HA92_0.5_180131
HA93_0.1_180131
HA93_0.5_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06028 S18-Fe06029 S18-Fe06030 S18-Fe06031
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 76 83 80 84
13C5-PFPeA (surr.) 1 % 82 85 87 85
13C5-PFHxA (surr.) 1 % 108 112 112 111
13C4-PFHpA (surr.) 1 % 104 110 107 104
13C8-PFOA (surr.) 1 % 107 118 103 102
13C5-PFNA (surr.) 1 % 88 116 79 86
13C6-PFDA (surr.) 1 % 83 125 78 79
13C2-PFUnDA (surr.) 1 % 54 95 55 55
13C2-PFDoDA (surr.) 1 % 56 110 61 57
13C2-PFTeDA (surr.) 1 % 28 74 41 39
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 46 105 42 48
D3-N-MeFOSA (surr.) 1 % 21 57 18 26
D5-N-EtFOSA (surr.) 1 % 21 64 19 30
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 6 of 30
Report Number: 582917-L-V3
Client Sample ID HA92_0.1_180131
HA92_0.5_180131
HA93_0.1_180131
HA93_0.5_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06028 S18-Fe06029 S18-Fe06030 S18-Fe06031
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamido substances
D7-N-MeFOSE (surr.) 1 % 15 62 15 73
D9-N-EtFOSE (surr.) 1 % 20 49 20 25
D5-N-EtFOSAA (surr.) 1 % 87 77 83 89
D3-N-MeFOSAA (surr.) 1 % 72 76 75 78
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L 0.02 < 0.01 < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 103 104 106 104
18O2-PFHxS (surr.) 1 % 88 114 85 84
13C8-PFOS (surr.) 1 % 55 131 59 50
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTSA (surr.) 1 % 89 88 100 89
13C2-6:2 FTSA (surr.) 1 % 125 108 103 97
13C2-8:2 FTSA (surr.) 1 % 103 106 100 116
PFASs Summations
Sum (PFHxS + PFOS)* 0.01 ug/L 0.02 < 0.01 < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA)* 0.01 ug/L 0.02 < 0.01 < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.01 ug/L 0.02 < 0.01 < 0.01 < 0.01
Sum of WA DER PFAS (n=10)* 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Sum of PFASs (n=28)* 0.1 ug/L < 0.1 < 0.1 < 0.1 < 0.1
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 6.5 4.9 5.2 4.1
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 5.9 4.9 5.2 3.9
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 7 of 30
Report Number: 582917-L-V3
Client Sample ID HA94_0.1_180131
HA95_0.1_180131
HA96_0.1_180131
HA96_0.4_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06032 S18-Fe06033 S18-Fe06034 S18-Fe06035
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 82 80 82 82
13C5-PFPeA (surr.) 1 % 85 84 83 86
13C5-PFHxA (surr.) 1 % 111 110 116 109
13C4-PFHpA (surr.) 1 % 109 106 118 106
13C8-PFOA (surr.) 1 % 121 119 134 117
13C5-PFNA (surr.) 1 % 117 114 123 121
13C6-PFDA (surr.) 1 % 122 119 149 116
13C2-PFUnDA (surr.) 1 % 88 83 98 84
13C2-PFDoDA (surr.) 1 % 102 99 107 104
13C2-PFTeDA (surr.) 1 % 84 66 65 67
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 101 98 106 108
D3-N-MeFOSA (surr.) 1 % 51 47 57 67
D5-N-EtFOSA (surr.) 1 % 48 47 49 65
D7-N-MeFOSE (surr.) 1 % 56 65 29 27
D9-N-EtFOSE (surr.) 1 % 50 43 42 51
D5-N-EtFOSAA (surr.) 1 % 74 67 114 69
D3-N-MeFOSAA (surr.) 1 % 75 70 79 71
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L 0.03 < 0.01 < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 106 105 110 103
18O2-PFHxS (surr.) 1 % 114 113 113 113
13C8-PFOS (surr.) 1 % 125 123 158 122
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 8 of 30
Report Number: 582917-L-V3
Client Sample ID HA94_0.1_180131
HA95_0.1_180131
HA96_0.1_180131
HA96_0.4_180131
Sample Matrix AUS Leachate AUS Leachate AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06032 S18-Fe06033 S18-Fe06034 S18-Fe06035
Date Sampled Jan 31, 2018 Jan 31, 2018 Jan 31, 2018 Jan 31, 2018
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTSA (surr.) 1 % 85 89 119 89
13C2-6:2 FTSA (surr.) 1 % 108 107 193 101
13C2-8:2 FTSA (surr.) 1 % 95 100 113 77
PFASs Summations
Sum (PFHxS + PFOS)* 0.01 ug/L 0.03 < 0.01 < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA)* 0.01 ug/L 0.03 < 0.01 < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.01 ug/L 0.03 < 0.01 < 0.01 < 0.01
Sum of WA DER PFAS (n=10)* 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Sum of PFASs (n=28)* 0.1 ug/L < 0.1 < 0.1 < 0.1 < 0.1
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0 4.0 4.0
pH (initial) 0.1 pH Units 7.2 6.2 6.4 4.9
pH (Leachate fluid) 0.1 pH Units 7.0 7.0 7.0 7.0
pH (off) 0.1 pH Units 6.0 6.1 6.4 5.3
Client Sample ID QA101_180131SED_W04_180130
Sample Matrix AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06036 S18-Fe06038
Date Sampled Jan 31, 2018 Jan 30, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnDA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorododecanoic acid (PFDoDA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA)N15 0.01 ug/L < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 83 86
13C5-PFPeA (surr.) 1 % 90 91
13C5-PFHxA (surr.) 1 % 114 113
13C4-PFHpA (surr.) 1 % 111 109
13C8-PFOA (surr.) 1 % 124 121
13C5-PFNA (surr.) 1 % 114 116
13C6-PFDA (surr.) 1 % 119 122
13C2-PFUnDA (surr.) 1 % 83 82
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 9 of 30
Report Number: 582917-L-V3
Client Sample ID QA101_180131SED_W04_180130
Sample Matrix AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06036 S18-Fe06038
Date Sampled Jan 31, 2018 Jan 30, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C2-PFDoDA (surr.) 1 % 99 102
13C2-PFTeDA (surr.) 1 % 63 86
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 109 102
D3-N-MeFOSA (surr.) 1 % 47 55
D5-N-EtFOSA (surr.) 1 % 37 50
D7-N-MeFOSE (surr.) 1 % 38 19
D9-N-EtFOSE (surr.) 1 % 44 51
D5-N-EtFOSAA (surr.) 1 % 66 69
D3-N-MeFOSAA (surr.) 1 % 68 66
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS)N15 0.01 ug/L < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS)N15 0.01 ug/L < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS)N15 0.01 ug/L < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 110 107
18O2-PFHxS (surr.) 1 % 116 115
13C8-PFOS (surr.) 1 % 134 125
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.05 ug/L < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.01 ug/L < 0.01 < 0.01
13C2-4:2 FTSA (surr.) 1 % 92 91
13C2-6:2 FTSA (surr.) 1 % 99 106
13C2-8:2 FTSA (surr.) 1 % 98 103
PFASs Summations
Sum (PFHxS + PFOS)* 0.01 ug/L < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA)* 0.01 ug/L < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.01 ug/L < 0.01 < 0.01
Sum of WA DER PFAS (n=10)* 0.05 ug/L < 0.05 < 0.05
Sum of PFASs (n=28)* 0.1 ug/L < 0.1 < 0.1
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 10 of 30
Report Number: 582917-L-V3
Client Sample ID QA101_180131SED_W04_180130
Sample Matrix AUS Leachate AUS Leachate
Eurofins | mgt Sample No. S18-Fe06036 S18-Fe06038
Date Sampled Jan 31, 2018 Jan 30, 2018
Test/Reference LOR Unit
AUS Leaching Procedure
Leachate FluidC01 comment 4.0 4.0
pH (initial) 0.1 pH Units 8.3 7.6
pH (Leachate fluid) 0.1 pH Units 7.0 7.0
pH (off) 0.1 pH Units 6.5 6.7
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 11 of 30
Report Number: 582917-L-V3
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 08, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
Perfluoroalkane sulfonamido substances Brisbane Feb 08, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
Perfluoroalkane sulfonic acids (PFSAs) Brisbane Feb 08, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Brisbane Feb 08, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
AUS Leaching Procedure Brisbane Feb 08, 2018 7 Days
- Method: LTM-GEN-7010 Leaching Procedure for Soils & Solid Wastes
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 12 of 30
Report Number: 582917-L-V3
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 HA86_0.1_180131
Jan 31, 2018 Sediment S18-Fe01813 X X
2 HA86_0.5_180131
Jan 31, 2018 Sediment S18-Fe01814 X X
3 HA87_0.1_180131
Jan 31, 2018 Sediment S18-Fe01815 X X
4 HA87_0.5_180131
Jan 31, 2018 Sediment S18-Fe01816 X X
5 HA88_0.1_180131
Jan 31, 2018 Sediment S18-Fe01817 X X
6 HA88_0.5_180 Jan 31, 2018 Sediment S18-Fe01818 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
First Reported:Feb 19, 2018
Date Reported:Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 13 of 30
Report Number: 582917-L-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
7 HA89_0.1_180131
Jan 31, 2018 Sediment S18-Fe01819 X X
8 HA89_0.5_180131
Jan 31, 2018 Sediment S18-Fe01820 X X
9 HA90_0.1_180131
Jan 31, 2018 Sediment S18-Fe01821 X X
10 HA90_0.5_180131
Jan 31, 2018 Sediment S18-Fe01822 X X
11 HA91_0.1_180131
Jan 31, 2018 Sediment S18-Fe01823 X X
12 HA91_0.5_180131
Jan 31, 2018 Sediment S18-Fe01824 X X
13 HA92_0.1_180 Jan 31, 2018 Sediment S18-Fe01825 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 14 of 30
Report Number: 582917-L-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
14 HA92_0.5_180131
Jan 31, 2018 Sediment S18-Fe01826 X X
15 HA93_0.1_180131
Jan 31, 2018 Sediment S18-Fe01827 X X
16 HA93_0.5_180131
Jan 31, 2018 Sediment S18-Fe01828 X X
17 HA94_0.1_180131
Jan 31, 2018 Sediment S18-Fe01829 X X
18 HA95_0.1_180131
Jan 31, 2018 Sediment S18-Fe01830 X X
19 HA96_0.1_180131
Jan 31, 2018 Sediment S18-Fe01831 X X
20 HA96_0.4_180 Jan 31, 2018 Sediment S18-Fe01832 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 15 of 30
Report Number: 582917-L-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
21 QA101_180131
Jan 31, 2018 Sediment S18-Fe01833 X X
22 SW_W04_180130
Jan 30, 2018 Water (Ultra-trace)
S18-Fe01834 X
23 SED_W04_180130
Jan 30, 2018 Sediment S18-Fe01835 X X
24 TP01_0.1_180130
Jan 30, 2018 Soil S18-Fe01837 X X
25 TP01_0.9_180130
Jan 30, 2018 Soil S18-Fe01838 X X
26 TP02_0.1_180130
Jan 30, 2018 Soil S18-Fe01839 X X
27 TP02_1.6_180 Jan 30, 2018 Soil S18-Fe01840 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 16 of 30
Report Number: 582917-L-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
130
28 TP03_0.1_180130
Jan 30, 2018 Soil S18-Fe01841 X X
29 TP03_1.0_180130
Jan 30, 2018 Soil S18-Fe01842 X X
30 TP04_0.1_180130
Jan 30, 2018 Soil S18-Fe01843 X X
31 TP04_1.0_180130
Jan 30, 2018 Soil S18-Fe01844 X X
32 QA101_180130
Jan 30, 2018 Soil S18-Fe01845 X X
33 TP05A_0.1_180130
Jan 30, 2018 Soil S18-Fe01847 X X
34 TP05B_0.1_18 Jan 30, 2018 Soil S18-Fe01848 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 17 of 30
Report Number: 582917-L-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
0130
35 TP06_0.1_180130
Jan 30, 2018 Soil S18-Fe01849 X X
36 TP06_1.0_180130
Jan 30, 2018 Soil S18-Fe01850 X X
37 TP07_0.1_180130
Jan 30, 2018 Soil S18-Fe01851 X X
38 TP07_1.0_180130
Jan 30, 2018 Soil S18-Fe01852 X X
39 TP08_0.1_180130
Jan 30, 2018 Soil S18-Fe01853 X X
40 TP08_0.9_180130
Jan 30, 2018 Soil S18-Fe01854 X X
41 TP09_0.1_180 Jan 30, 2018 Soil S18-Fe01855 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 18 of 30
Report Number: 582917-L-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
130
42 TP09_1.0_180130
Jan 30, 2018 Soil S18-Fe01856 X X
43 TP09_2.0_180130
Jan 30, 2018 Soil S18-Fe01857 X
44 SW_POU24_180130
Jan 30, 2018 Water (Ultra-trace)
S18-Fe01858 X
45 SED_POU24_180130
Jan 30, 2018 Sediment S18-Fe01859 X X
46 SED_POU25A_180130
Jan 30, 2018 Sediment S18-Fe01860 X X
47 SED_POU25B_180130
Jan 30, 2018 Sediment S18-Fe01861 X X
48 HA97_0.1_180 Jan 31, 2018 Sediment S18-Fe02002 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 19 of 30
Report Number: 582917-L-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
49 HA97_0.5_180131
Jan 31, 2018 Sediment S18-Fe02003 X X
50 HA86_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06016 X X
51 HA86_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06017 X X
52 HA87_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06018 X X
53 HA87_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06019 X X
54 HA88_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06020 X X
55 HA88_0.5_180 Jan 31, 2018 AUS Leachate S18-Fe06021 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 20 of 30
Report Number: 582917-L-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
56 HA89_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06022 X X
57 HA89_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06023 X X
58 HA90_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06024 X X
59 HA90_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06025 X X
60 HA91_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06026 X X
61 HA91_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06027 X X
62 HA92_0.1_180 Jan 31, 2018 AUS Leachate S18-Fe06028 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 21 of 30
Report Number: 582917-L-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
63 HA92_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06029 X X
64 HA93_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06030 X X
65 HA93_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06031 X X
66 HA94_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06032 X X
67 HA95_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06033 X X
68 HA96_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06034 X X
69 HA96_0.4_180 Jan 31, 2018 AUS Leachate S18-Fe06035 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 22 of 30
Report Number: 582917-L-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
70 QA101_180131
Jan 31, 2018 AUS Leachate S18-Fe06036 X X
71 SW_W04_180130
Jan 30, 2018 Water S18-Fe06037 X X X X X X X X
72 SED_W04_180130
Jan 30, 2018 AUS Leachate S18-Fe06038 X X
73 SED_POU24_180130
Jan 30, 2018 AUS Leachate S18-Fe06039 X X
74 SED_POU25A_180130
Jan 30, 2018 AUS Leachate S18-Fe06040 X X
75 SED_POU25B_180130
Jan 30, 2018 AUS Leachate S18-Fe06041 X X
Test Counts 1 1 1 1 1 1 1 25 1 1 46 71 2
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 23 of 30
Report Number: 582917-L-V3
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota/food results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the SRA.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
For VOCs containing vinyl chloride, styrene and 2-chloroethyl vinyl ether the holding time is 7 days however for all other VOCs such as BTEX or C6-10 TRH then the holding time is 14 days.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre ug/L: micrograms per litre
ppm: Parts per million ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 24 of 30
Report Number: 582917-L-V3
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnDA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoDA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamido substances
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTSA) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTSA) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTSA) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTSA) ug/L < 0.01 0.01 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06016 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 25 of 30
Report Number: 582917-L-V3
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06016 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06016 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06016 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06016 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06016 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06016 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06016 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06016 CP ug/L 0.01 0.01 5.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe06016 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe06016 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06024 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 26 of 30
Report Number: 582917-L-V3
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06024 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06024 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06024 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06024 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06024 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06024 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06024 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06024 CP ug/L 0.08 0.09 13 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe06024 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe06024 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06031 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 27 of 30
Report Number: 582917-L-V3
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06031 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06031 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06031 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06031 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06031 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06031 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06031 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe06031 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe06031 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06038 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid(PFDoDA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 28 of 30
Report Number: 582917-L-V3
Duplicate
Perfluoroalkane sulfonamido substances Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06038 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06038 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06038 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06038 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06038 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06038 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06038 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs) Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) S18-Fe06038 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) S18-Fe06038 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 29 of 30
Report Number: 582917-L-V3
Comments
V3 - REMAINING SAMPLES
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionC01 Leachate Fluid Key: 1 - pH 5.0; 2 - pH 2.9; 3 - pH 9.2; 4 - Reagent (DI) water; 5 - Client sample, 6 - other
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 30 of 30
Report Number: 582917-L-V3
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Christine Kennelly
Report 582917-W-V3
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 02, 2018
Client Sample ID SW_W04_180130
SW_W04_180130
Sample Matrix Water Water
Eurofins | mgt Sample No. S18-Fe01834 S18-Fe06037
Date Sampled Jan 30, 2018 Jan 30, 2018
Test/Reference LOR Unit
PFASs Summations
Sum (PFHxS + PFOS)* 0.001 ug/L 0.051 -
Sum of US EPA PFAS (PFOS + PFOA)* 0.001 ug/L 0.037 -
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.001 ug/L 0.051 -
Sum of WA DER PFAS (n=10)* 0.005 ug/L 0.054 -
Sum of PFASs (n=28)* 0.005 ug/L 0.055 -
Perfluoroalkyl carboxylic acids (PFCAs) - Ultra Trace
Perfluorobutanoic acid (PFBA)N11 0.005 ug/L < 0.005 -
Perfluoropentanoic acid (PFPeA)N11 0.001 ug/L < 0.001 -
Perfluorohexanoic acid (PFHxA)N11 0.001 ug/L N090.002 -
Perfluoroheptanoic acid (PFHpA)N11 0.001 ug/L < 0.001 -
Perfluorooctanoic acid (PFOA)N11 0.001 ug/L < 0.001 -
Perfluorononanoic acid (PFNA)N11 0.001 ug/L < 0.001 -
Perfluorodecanoic acid (PFDA)N11 0.001 ug/L < 0.001 -
Perfluoroundecanoic acid (PFUnDA)N11 0.001 ug/L < 0.001 -
Perfluorododecanoic acid (PFDoDA)N11 0.001 ug/L < 0.001 -
Perfluorotridecanoic acid (PFTrDA)N15 0.001 ug/L < 0.001 -
Perfluorotetradecanoic acid (PFTeDA)N11 0.001 ug/L < 0.001 -
13C4-PFBA (surr.) 1 % 23 -
13C5-PFPeA (surr.) 1 % 53 -
13C5-PFHxA (surr.) 1 % 61 -
13C4-PFHpA (surr.) 1 % 65 -
13C8-PFOA (surr.) 1 % 67 -
13C5-PFNA (surr.) 1 % 57 -
13C6-PFDA (surr.) 1 % 34 -
13C2-PFUnDA (surr.) 1 % 18 -
13C2-PFDoDA (surr.) 1 % 11 -
13C2-PFTeDA (surr.) 1 % INT -
Perfluoroalkane sulfonic acids (PFSAs)- Ultra Trace
Perfluorobutanesulfonic acid (PFBS)N11 0.001 ug/L 0.001 -
Perfluoropentanesulfonic acid (PFPeS)N15 0.001 ug/L N090.001 -
Perfluorohexanesulfonic acid (PFHxS)N11 0.001 ug/L N090.014 -
Perfluoroheptanesulfonic acid (PFHpS)N15 0.001 ug/L < 0.001 -
Perfluorooctanesulfonic acid (PFOS)N11 0.0001 ug/L N090.037 -
Perfluorodecanesulfonic acid (PFDS)N15 0.001 ug/L < 0.001 -
13C3-PFBS (surr.) 1 % 81 -
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 22
Report Number: 582917-W-V3
NATA AccreditedAccreditation Number 1261Site Number 18217
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID SW_W04_180130
SW_W04_180130
Sample Matrix Water Water
Eurofins | mgt Sample No. S18-Fe01834 S18-Fe06037
Date Sampled Jan 30, 2018 Jan 30, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonic acids (PFSAs)- Ultra Trace
18O2-PFHxS (surr.) 1 % 84 -
13C8-PFOS (surr.) 1 % 54 -
Perfluoroalkane sulfonamido substances- Ultra Trace
Perfluorooctane sulfonamide (FOSA)N11 0.005 ug/L < 0.005 -
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.005 ug/L < 0.005 -
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.005 ug/L < 0.005 -
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.005 ug/L < 0.005 -
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.005 ug/L < 0.005 -
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.005 ug/L < 0.005 -
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.005 ug/L < 0.005 -
13C8-FOSA (surr.) 1 % 38 -
D3-N-MeFOSA (surr.) 1 % INT -
D5-N-EtFOSA (surr.) 1 % INT -
D7-N-MeFOSE (surr.) 1 % INT -
D9-N-EtFOSE (surr.) 1 % INT -
D5-N-EtFOSAA (surr.) 1 % 30 -
D3-N-MeFOSAA (surr.) 1 % 35 -
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)- Ultra Trace
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA)N11 0.001 ug/L < 0.001 -
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA)N11 0.005 ug/L < 0.005 -
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA)N11 0.001 ug/L < 0.001 -
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTSA)N15 0.001 ug/L < 0.001 -
13C2-4:2 FTSA (surr.) 1 % 55 -
13C2-6:2 FTSA (surr.) 1 % 56 -
13C2-8:2 FTSA (surr.) 1 % 34 -
Ammonia (as N) 0.01 mg/L - < 0.01
Conductivity (at 25°C) 1 uS/cm - 61000
Nitrate & Nitrite (as N) 0.05 mg/L - < 0.05
Nitrate (as N) 0.02 mg/L - 0.02
Nitrite (as N) 0.02 mg/L - < 0.02
Organic Nitrogen (as N) 0.2 mg/L - 1.9
pH (at 25°C) 0.1 pH Units - 7.9
Suspended Solids 1 mg/L - 53
Total Dissolved Solids 10 mg/L - 40000
Total Kjeldahl Nitrogen (as N) 0.2 mg/L - 1.9
Total Nitrogen (as N) 0.2 mg/L - 1.9
Total Organic Carbon 5 mg/L - < 5
Phosphorus 0.5 mg/L - < 5
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 22
Report Number: 582917-W-V3
Client Sample ID SW_W04_180130
SW_W04_180130
Sample Matrix Water Water
Eurofins | mgt Sample No. S18-Fe01834 S18-Fe06037
Date Sampled Jan 30, 2018 Jan 30, 2018
Test/Reference LOR Unit
Heavy Metals
Arsenic 0.001 mg/L - 0.002
Cadmium 0.0002 mg/L - < 0.0002
Chromium 0.001 mg/L - < 0.001
Copper 0.001 mg/L - < 0.001
Lead 0.001 mg/L - 0.001
Mercury 0.0001 mg/L - < 0.0001
Nickel 0.001 mg/L - < 0.001
Zinc 0.005 mg/L - 0.005
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 22
Report Number: 582917-W-V3
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs) - Ultra Trace
Perfluoroalkyl carboxylic acids (PFCAs) - Ultra Trace Brisbane Feb 08, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
Perfluoroalkane sulfonic acids (PFSAs)- Ultra Trace Brisbane Feb 08, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
Perfluoroalkane sulfonamido substances- Ultra Trace Brisbane Feb 08, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)- Ultra Trace Brisbane Feb 08, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluoro Alkyl Substances (PFAS)
Nitrogens (speciated)
Ammonia (as N) Melbourne Feb 07, 2018 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Nitrate & Nitrite (as N) Melbourne Feb 07, 2018 28 Day
- Method: APHA 4500-NO3/NO2 Nitrate-Nitrite Nitrogen by FIA
Nitrate (as N) Melbourne Feb 07, 2018 28 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Nitrite (as N) Melbourne Feb 07, 2018 2 Day
- Method: APHA 4500-NO2 Nitrite Nitrogen by FIA
Organic Nitrogen (as N) Melbourne Feb 06, 2018 7 Day
- Method: APHA 4500 Organic Nitrogen (N)
Total Kjeldahl Nitrogen (as N) Melbourne Feb 07, 2018 7 Day
- Method: LTM-INO-4310 TKN in Waters & Soils by FIA
Conductivity (at 25°C) Melbourne Feb 07, 2018 28 Day
- Method: LTM-INO-4030 Conductivity
pH (at 25°C) Melbourne Feb 07, 2018 0 Hours
- Method: LTM-GEN-7090 pH in water by ISE
Suspended Solids Melbourne Feb 07, 2018 7 Days
- Method: LTM-INO-4070 Analysis of Suspended Solids in Water by Gravimetry
Total Dissolved Solids Melbourne Feb 07, 2018 7 Day
- Method: LTM-INO-4170 Total Dissolved Solids in Water
Total Organic Carbon Melbourne Feb 07, 2018 28 Day
- Method: APHA 5310B Total Organic Carbon
Phosphorus Melbourne Feb 07, 2018 180 Day
- Method: USEPA 6010
Metals M8 Melbourne Feb 07, 2018 28 Days
- Method: LTM-MET-3040 Metals in Waters, Soils & Sediments by ICP-MS
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 22
Report Number: 582917-W-V3
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 HA86_0.1_180131
Jan 31, 2018 Sediment S18-Fe01813 X X
2 HA86_0.5_180131
Jan 31, 2018 Sediment S18-Fe01814 X X
3 HA87_0.1_180131
Jan 31, 2018 Sediment S18-Fe01815 X X
4 HA87_0.5_180131
Jan 31, 2018 Sediment S18-Fe01816 X X
5 HA88_0.1_180131
Jan 31, 2018 Sediment S18-Fe01817 X X
6 HA88_0.5_180 Jan 31, 2018 Sediment S18-Fe01818 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
First Reported:Feb 19, 2018
Date Reported:Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 5 of 22
Report Number: 582917-W-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
7 HA89_0.1_180131
Jan 31, 2018 Sediment S18-Fe01819 X X
8 HA89_0.5_180131
Jan 31, 2018 Sediment S18-Fe01820 X X
9 HA90_0.1_180131
Jan 31, 2018 Sediment S18-Fe01821 X X
10 HA90_0.5_180131
Jan 31, 2018 Sediment S18-Fe01822 X X
11 HA91_0.1_180131
Jan 31, 2018 Sediment S18-Fe01823 X X
12 HA91_0.5_180131
Jan 31, 2018 Sediment S18-Fe01824 X X
13 HA92_0.1_180 Jan 31, 2018 Sediment S18-Fe01825 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 6 of 22
Report Number: 582917-W-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
14 HA92_0.5_180131
Jan 31, 2018 Sediment S18-Fe01826 X X
15 HA93_0.1_180131
Jan 31, 2018 Sediment S18-Fe01827 X X
16 HA93_0.5_180131
Jan 31, 2018 Sediment S18-Fe01828 X X
17 HA94_0.1_180131
Jan 31, 2018 Sediment S18-Fe01829 X X
18 HA95_0.1_180131
Jan 31, 2018 Sediment S18-Fe01830 X X
19 HA96_0.1_180131
Jan 31, 2018 Sediment S18-Fe01831 X X
20 HA96_0.4_180 Jan 31, 2018 Sediment S18-Fe01832 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 7 of 22
Report Number: 582917-W-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
21 QA101_180131
Jan 31, 2018 Sediment S18-Fe01833 X X
22 SW_W04_180130
Jan 30, 2018 Water (Ultra-trace)
S18-Fe01834 X
23 SED_W04_180130
Jan 30, 2018 Sediment S18-Fe01835 X X
24 TP01_0.1_180130
Jan 30, 2018 Soil S18-Fe01837 X X
25 TP01_0.9_180130
Jan 30, 2018 Soil S18-Fe01838 X X
26 TP02_0.1_180130
Jan 30, 2018 Soil S18-Fe01839 X X
27 TP02_1.6_180 Jan 30, 2018 Soil S18-Fe01840 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 8 of 22
Report Number: 582917-W-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
130
28 TP03_0.1_180130
Jan 30, 2018 Soil S18-Fe01841 X X
29 TP03_1.0_180130
Jan 30, 2018 Soil S18-Fe01842 X X
30 TP04_0.1_180130
Jan 30, 2018 Soil S18-Fe01843 X X
31 TP04_1.0_180130
Jan 30, 2018 Soil S18-Fe01844 X X
32 QA101_180130
Jan 30, 2018 Soil S18-Fe01845 X X
33 TP05A_0.1_180130
Jan 30, 2018 Soil S18-Fe01847 X X
34 TP05B_0.1_18 Jan 30, 2018 Soil S18-Fe01848 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 9 of 22
Report Number: 582917-W-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
0130
35 TP06_0.1_180130
Jan 30, 2018 Soil S18-Fe01849 X X
36 TP06_1.0_180130
Jan 30, 2018 Soil S18-Fe01850 X X
37 TP07_0.1_180130
Jan 30, 2018 Soil S18-Fe01851 X X
38 TP07_1.0_180130
Jan 30, 2018 Soil S18-Fe01852 X X
39 TP08_0.1_180130
Jan 30, 2018 Soil S18-Fe01853 X X
40 TP08_0.9_180130
Jan 30, 2018 Soil S18-Fe01854 X X
41 TP09_0.1_180 Jan 30, 2018 Soil S18-Fe01855 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 10 of 22
Report Number: 582917-W-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
130
42 TP09_1.0_180130
Jan 30, 2018 Soil S18-Fe01856 X X
43 TP09_2.0_180130
Jan 30, 2018 Soil S18-Fe01857 X
44 SW_POU24_180130
Jan 30, 2018 Water (Ultra-trace)
S18-Fe01858 X
45 SED_POU24_180130
Jan 30, 2018 Sediment S18-Fe01859 X X
46 SED_POU25A_180130
Jan 30, 2018 Sediment S18-Fe01860 X X
47 SED_POU25B_180130
Jan 30, 2018 Sediment S18-Fe01861 X X
48 HA97_0.1_180 Jan 31, 2018 Sediment S18-Fe02002 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 11 of 22
Report Number: 582917-W-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
49 HA97_0.5_180131
Jan 31, 2018 Sediment S18-Fe02003 X X
50 HA86_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06016 X X
51 HA86_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06017 X X
52 HA87_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06018 X X
53 HA87_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06019 X X
54 HA88_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06020 X X
55 HA88_0.5_180 Jan 31, 2018 AUS Leachate S18-Fe06021 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 12 of 22
Report Number: 582917-W-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
56 HA89_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06022 X X
57 HA89_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06023 X X
58 HA90_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06024 X X
59 HA90_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06025 X X
60 HA91_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06026 X X
61 HA91_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06027 X X
62 HA92_0.1_180 Jan 31, 2018 AUS Leachate S18-Fe06028 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 13 of 22
Report Number: 582917-W-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
63 HA92_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06029 X X
64 HA93_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06030 X X
65 HA93_0.5_180131
Jan 31, 2018 AUS Leachate S18-Fe06031 X X
66 HA94_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06032 X X
67 HA95_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06033 X X
68 HA96_0.1_180131
Jan 31, 2018 AUS Leachate S18-Fe06034 X X
69 HA96_0.4_180 Jan 31, 2018 AUS Leachate S18-Fe06035 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 14 of 22
Report Number: 582917-W-V3
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 2, 2018 9:47 AMAddress: Level 14, 32 Turbot St Report #: 582917 Due: Feb 9, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH Phosphorus
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
AU
S Leaching P
rocedure
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X X
Perth Laboratory - NATA Site # 23736
131
70 QA101_180131
Jan 31, 2018 AUS Leachate S18-Fe06036 X X
71 SW_W04_180130
Jan 30, 2018 Water S18-Fe06037 X X X X X X X X
72 SED_W04_180130
Jan 30, 2018 AUS Leachate S18-Fe06038 X X
73 SED_POU24_180130
Jan 30, 2018 AUS Leachate S18-Fe06039 X X
74 SED_POU25A_180130
Jan 30, 2018 AUS Leachate S18-Fe06040 X X
75 SED_POU25B_180130
Jan 30, 2018 AUS Leachate S18-Fe06041 X X
Test Counts 1 1 1 1 1 1 1 25 1 1 46 71 2
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 15 of 22
Report Number: 582917-W-V3
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota/food results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the SRA.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
For VOCs containing vinyl chloride, styrene and 2-chloroethyl vinyl ether the holding time is 7 days however for all other VOCs such as BTEX or C6-10 TRH then the holding time is 14 days.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre ug/L: micrograms per litre
ppm: Parts per million ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 16 of 22
Report Number: 582917-W-V3
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs) - Ultra Trace
Perfluorobutanoic acid (PFBA) ug/L < 0.005 0.005 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.001 0.001 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.001 0.001 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.001 0.001 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.001 0.001 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.001 0.001 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.001 0.001 Pass
Perfluoroundecanoic acid (PFUnDA) ug/L < 0.001 0.001 Pass
Perfluorododecanoic acid (PFDoDA) ug/L < 0.001 0.001 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.001 0.001 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.001 0.001 Pass
Method Blank
Perfluoroalkane sulfonic acids (PFSAs)- Ultra Trace
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.001 0.001 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.001 0.001 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.001 0.001 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.001 0.001 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.0001 0.0001 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.001 0.001 Pass
Method Blank
Perfluoroalkane sulfonamido substances- Ultra Trace
Perfluorooctane sulfonamide (FOSA) ug/L < 0.005 0.005 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.005 0.005 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.005 0.005 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.005 0.005 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.005 0.005 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.005 0.005 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.005 0.005 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)- Ultra Trace
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTSA) ug/L < 0.001 0.001 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTSA) ug/L < 0.005 0.005 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTSA) ug/L < 0.001 0.001 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTSA) ug/L < 0.001 0.001 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Nitrate & Nitrite (as N) mg/L < 0.05 0.05 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Nitrite (as N) mg/L < 0.02 0.02 Pass
Suspended Solids mg/L < 1 1 Pass
Total Dissolved Solids mg/L < 10 10 Pass
Total Kjeldahl Nitrogen (as N) mg/L < 0.2 0.2 Pass
Total Organic Carbon mg/L < 5 5 Pass
Phosphorus mg/L < 0.5 0.5 Pass
Method Blank
Heavy Metals
Arsenic mg/L < 0.001 0.001 Pass
Cadmium mg/L < 0.0002 0.0002 Pass
Chromium mg/L < 0.001 0.001 Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 17 of 22
Report Number: 582917-W-V3
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Copper mg/L < 0.001 0.001 Pass
Lead mg/L < 0.001 0.001 Pass
Mercury mg/L < 0.0001 0.0001 Pass
Nickel mg/L < 0.001 0.001 Pass
Zinc mg/L < 0.005 0.005 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) - Ultra Trace
Perfluorobutanoic acid (PFBA) % 82 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 72 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 82 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 79 50-150 Pass
Perfluorooctanoic acid (PFOA) % 80 50-150 Pass
Perfluorononanoic acid (PFNA) % 81 50-150 Pass
Perfluorodecanoic acid (PFDA) % 83 50-150 Pass
Perfluoroundecanoic acid (PFUnDA) % 77 50-150 Pass
Perfluorododecanoic acid (PFDoDA) % 75 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 110 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 66 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids (PFSAs)- Ultra Trace
Perfluorobutanesulfonic acid (PFBS) % 80 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 78 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 74 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 75 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 78 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 79 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamido substances- Ultra Trace
Perfluorooctane sulfonamide (FOSA) % 74 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 68 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 68 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 65 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 65 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 65 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 68 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)- Ultra Trace
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTSA) % 79 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTSA) % 79 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTSA) % 72 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTSA) % 71 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 100 70-130 Pass
Nitrate & Nitrite (as N) % 101 70-130 Pass
Nitrate (as N) % 100 70-130 Pass
Nitrite (as N) % 109 70-130 Pass
Suspended Solids % 100 70-130 Pass
Total Dissolved Solids % 100 70-130 Pass
Total Kjeldahl Nitrogen (as N) % 102 70-130 Pass
Total Organic Carbon % 100 70-130 Pass
Phosphorus % 99 70-130 Pass
LCS - % Recovery
Heavy Metals
Arsenic % 85 80-120 Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 18 of 22
Report Number: 582917-W-V3
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Cadmium % 82 80-120 Pass
Chromium % 90 80-120 Pass
Copper % 83 80-120 Pass
Lead % 86 80-120 Pass
Mercury % 81 75-125 Pass
Nickel % 83 80-120 Pass
Zinc % 86 80-120 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) - Ultra Trace Result 1
Perfluorobutanoic acid (PFBA) M18-Fe06677 NCP % 99 50-150 Pass
Perfluoropentanoic acid (PFPeA) M18-Fe06677 NCP % 92 50-150 Pass
Perfluorohexanoic acid (PFHxA) M18-Fe06677 NCP % 96 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe06677 NCP % 97 50-150 Pass
Perfluorooctanoic acid (PFOA) M18-Fe06677 NCP % 95 50-150 Pass
Perfluorononanoic acid (PFNA) M18-Fe06677 NCP % 97 50-150 Pass
Perfluorodecanoic acid (PFDA) M18-Fe06677 NCP % 99 50-150 Pass
Perfluoroundecanoic acid(PFUnDA) M18-Fe06677 NCP % 99 50-150 Pass
Perfluorododecanoic acid(PFDoDA) M18-Fe06677 NCP % 99 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe06677 NCP % 126 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe06677 NCP % 96 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids (PFSAs)- Ultra Trace Result 1
Perfluorobutanesulfonic acid(PFBS) M18-Fe06677 NCP % 99 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe06677 NCP % 98 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M18-Fe06677 NCP % 92 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe06677 NCP % 97 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M18-Fe06677 NCP % 94 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe06677 NCP % 83 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamido substances- Ultra Trace Result 1
Perfluorooctane sulfonamide(FOSA) M18-Fe06677 NCP % 97 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe06677 NCP % 99 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe06677 NCP % 97 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe06677 NCP % 100 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe06677 NCP % 85 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe06677 NCP % 94 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe06677 NCP % 94 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)- Ultra Trace Result 1
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 19 of 22
Report Number: 582917-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) M18-Fe06677 NCP % 97 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) M18-Fe06677 NCP % 99 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) M18-Fe06677 NCP % 99 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) M18-Fe06677 NCP % 116 50-150 Pass
Spike - % Recovery
Result 1
Ammonia (as N) M18-Fe06060 NCP % 98 70-130 Pass
Nitrate & Nitrite (as N) M18-Fe06060 NCP % 100 70-130 Pass
Nitrate (as N) M18-Fe06060 NCP % 99 70-130 Pass
Nitrite (as N) M18-Fe06060 NCP % 112 70-130 Pass
Total Organic Carbon M18-Fe05983 NCP % 82 70-130 Pass
Phosphorus S18-Fe06037 CP % 103 70-130 Pass
Spike - % Recovery
Heavy Metals Result 1
Arsenic M18-Fe06874 NCP % 84 75-125 Pass
Cadmium P18-Fe04578 NCP % 98 75-125 Pass
Chromium P18-Fe04578 NCP % 97 75-125 Pass
Copper M18-Fe06874 NCP % 80 75-125 Pass
Lead P18-Fe04578 NCP % 95 75-125 Pass
Mercury P18-Fe04578 NCP % 106 70-130 Pass
Nickel M18-Fe06874 NCP % 84 75-125 Pass
Zinc M18-Fe06874 NCP % 93 75-125 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) - Ultra Trace Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid(PFUnDA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid(PFDoDA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids (PFSAs)- Ultra Trace Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 20 of 22
Report Number: 582917-W-V3
Duplicate
Perfluoroalkane sulfonic acids (PFSAs)- Ultra Trace Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamido substances- Ultra Trace Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids (n:2 FTSAs)- Ultra Trace Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTSA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTSA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTSA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTSA) M18-Fe06678 NCP ug/L < 0.5 < 0.5 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M18-Fe05030 NCP mg/L 14 12 13 30% Pass
Conductivity (at 25°C) M18-Fe07349 NCP uS/cm 650 610 6.0 30% Pass
Nitrate & Nitrite (as N) M18-Fe05030 NCP mg/L < 2.5 < 2.5 <1 30% Pass
Nitrate (as N) M18-Fe05030 NCP mg/L < 1 < 1 <1 30% Pass
Nitrite (as N) M18-Fe05030 NCP mg/L < 1 < 1 <1 30% Pass
pH (at 25°C) M18-Fe07349 NCP pH Units 6.7 6.7 pass 30% Pass
Suspended Solids B18-Fe06316 NCP mg/L 31 37 19 30% Pass
Total Dissolved Solids M18-Fe06045 NCP mg/L 240 260 5.0 30% Pass
Total Kjeldahl Nitrogen (as N) M18-Fe05733 NCP mg/L 1.5 1.3 9.0 30% Pass
Total Organic Carbon S18-Fe05550 NCP mg/L < 5 < 5 <1 30% Pass
Phosphorus S18-Fe06037 CP mg/L < 5 < 5 <1 30% Pass
Duplicate
Heavy Metals Result 1 Result 2 RPD
Arsenic P18-Fe03004 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Cadmium P18-Fe03004 NCP mg/L < 0.0002 < 0.0002 <1 30% Pass
Chromium P18-Fe03004 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Copper P18-Fe03004 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Lead P18-Fe03004 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Mercury P18-Fe03004 NCP mg/L < 0.0001 < 0.0001 <1 30% Pass
Nickel P18-Fe03004 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Zinc P18-Fe03004 NCP mg/L < 0.005 < 0.005 <1 30% Pass
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 21 of 22
Report Number: 582917-W-V3
Comments
V3 - REMAINING SAMPLES
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionG01 The LORs have been raised due to matrix interference
N09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Ryan Gilbert Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Michael Brancati Senior Analyst-Inorganic (VIC)
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: Feb 19, 2018
Date Reported: Apr 06, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 22 of 22
Report Number: 582917-W-V3
ABN – 50 005 085 521 e.mail : [email protected] web : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne3-5 Kingston Town CloseOakleigh Vic 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261 Site # 23736
Environmental LaboratoryAir AnalysisWater AnalysisSoil Contamination Analysis
NATA AccreditationStack Emission Sampling & AnalysisTrade Waste Sampling & AnalysisGroundwater Sampling & Analysis
38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience
Sample Receipt AdviceSample Receipt AdviceSample Receipt AdviceSample Receipt Advice
Company name: Aurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty Ltd
Contact name: Christine KennellyProject name: HMAS ALBATROSSProject ID: 251529COC number: Not providedTurn around time: 10 DayDate/Time received: Feb 6, 2018 1:30 AMEurofins | mgt reference: 583541583541583541583541
Sample informationSample informationSample informationSample information
☑ A detailed list of analytes logged into our LIMS, is included in the attached summary table.
☒ All samples have been received as described on the above COC.
☒ COC has been completed correctly.
☒ Attempt to chill was evident.
☒ Appropriately preserved sample containers have been used.
☒ All samples were received in good condition.
☑ Samples have been provided with adequate time to commence analysis in accordance with therelevant holding times.
☒ Appropriate sample containers have been used.
☒ Split sample sent to requested external lab.
☒ Some samples have been subcontracted.
N/A Custody Seals intact (if used).
Contact notesContact notesContact notesContact notes
If you have any questions with respect to these samples please contact:
Ryan Gilbert on Phone : or by e.mail: [email protected]
Results will be delivered electronically via e.mail to Christine Kennelly - .
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Christine Kennelly
Report 583541-S
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 02, 2018
Client Sample ID BIO_W04_GAR1_180130
BIO_W04_MULLET1_180130
BIO_W04_BRIM_180130
BIO_W04_GAR2_180130
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. B18-Fe01862 B18-Fe01863 B18-Fe01864 B18-Fe18843
Date Sampled Jan 30, 2018 Jan 30, 2018 Jan 30, 2018 Jan 30, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 96 93 103 98
13C5-PFPeA (surr.) 1 % 88 82 86 89
13C5-PFHxA (surr.) 1 % 61 76 83 60
13C4-PFHpA (surr.) 1 % 86 62 90 88
13C8-PFOA (surr.) 1 % 74 80 124 80
13C5-PFNA (surr.) 1 % 115 86 126 123
13C6-PFDA (surr.) 1 % 135 118 127 136
13C2-PFUnDA (surr.) 1 % 138 114 133 124
13C2-PFDoDA (surr.) 1 % 137 118 123 124
13C2-PFTeDA (surr.) 1 % 130 117 95 150
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 115 69 95 122
D3-N-MeFOSA (surr.) 1 % 32 INT 27 34
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 13
Report Number: 583541-S
Client Sample ID BIO_W04_GAR1_180130
BIO_W04_MULLET1_180130
BIO_W04_BRIM_180130
BIO_W04_GAR2_180130
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. B18-Fe01862 B18-Fe01863 B18-Fe01864 B18-Fe18843
Date Sampled Jan 30, 2018 Jan 30, 2018 Jan 30, 2018 Jan 30, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 17 INT 19 20
D7-N-MeFOSE (surr.) 1 % 63 31 37 72
D9-N-EtFOSE (surr.) 1 % 41 15 29 52
D5-N-EtFOSAA (surr.) 1 % 186 135 145 156
D3-N-MeFOSAA (surr.) 1 % 174 121 134 143
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N092.7 N096.3 N091.1 N092.4
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 86 79 98 85
18O2-PFHxS (surr.) 1 % 112 118 137 118
13C8-PFOS (surr.) 1 % 131 123 129 135
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 81 99 66 83
13C2-6:2 FTS (surr.) 1 % INT INT INT INT
13C2-8:2 FTS (surr.) 1 % INT INT 179 INT
Client Sample ID BIO_W04_MULLET2_180130
Sample Matrix Fish
Eurofins | mgt Sample No. B18-Fe18844
Date Sampled Jan 30, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5
13C4-PFBA (surr.) 1 % 94
13C5-PFPeA (surr.) 1 % 88
13C5-PFHxA (surr.) 1 % 75
13C4-PFHpA (surr.) 1 % 63
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 13
Report Number: 583541-S
Client Sample ID BIO_W04_MULLET2_180130
Sample Matrix Fish
Eurofins | mgt Sample No. B18-Fe18844
Date Sampled Jan 30, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C8-PFOA (surr.) 1 % 79
13C5-PFNA (surr.) 1 % 87
13C6-PFDA (surr.) 1 % 117
13C2-PFUnDA (surr.) 1 % 108
13C2-PFDoDA (surr.) 1 % 103
13C2-PFTeDA (surr.) 1 % 119
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5
13C8-FOSA (surr.) 1 % 66
D3-N-MeFOSA (surr.) 1 % 10
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % 33
D9-N-EtFOSE (surr.) 1 % 16
D5-N-EtFOSAA (surr.) 1 % 138
D3-N-MeFOSAA (surr.) 1 % 101
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N096.2
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5
13C3-PFBS (surr.) 1 % 80
18O2-PFHxS (surr.) 1 % 114
13C8-PFOS (surr.) 1 % 121
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5
13C2-4:2 FTS (surr.) 1 % 99
13C2-6:2 FTS (surr.) 1 % INT
13C2-8:2 FTS (surr.) 1 % INT
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 13
Report Number: 583541-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 16, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 16, 2018 180 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 16, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 20, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 13
Report Number: 583541-S
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 6, 2018 1:30 AMAddress: Level 14, 32 Turbot St Report #: 583541 Due: Feb 20, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 BIO_W04_GAR1_180130
Jan 30, 2018 Fish B18-Fe01862 X
2 BIO_W04_MULLET1_180130
Jan 30, 2018 Fish B18-Fe01863X
3 BIO_W04_BRIM_180130
Jan 30, 2018 Fish B18-Fe01864 X
4 BIO_W04_GAR2_180130
Jan 30, 2018 Fish B18-Fe18843 X
5 BIO_W04_MULLET2_180130
Jan 30, 2018 Fish B18-Fe18844X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 13
Report Number: 583541-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 6, 2018 1:30 AMAddress: Level 14, 32 Turbot St Report #: 583541 Due: Feb 20, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
Test Counts 5
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 13
Report Number: 583541-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 13
Report Number: 583541-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 0.5 0.5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 0.5 0.5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 0.5 0.5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 0.5 0.5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 0.5 0.5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 0.5 0.5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 0.5 0.5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 0.5 0.5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 0.5 0.5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 0.5 0.5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 0.5 0.5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 0.5 0.5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 0.5 0.5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 0.5 0.5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 0.5 0.5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 0.5 0.5 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 0.5 0.5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 0.5 0.5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 0.3 0.3 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 0.5 0.5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 0.3 0.3 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 0.5 0.5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 93 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 98 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 89 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 98 50-150 Pass
Perfluorooctanoic acid (PFOA) % 101 50-150 Pass
Perfluorononanoic acid (PFNA) % 137 50-150 Pass
Perfluorodecanoic acid (PFDA) % 79 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 90 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 92 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 57 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 117 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 13
Report Number: 583541-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 91 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 87 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 81 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 114 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 94 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 91 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 102 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 85 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 103 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 94 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 90 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 101 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 52 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 98 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 96 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 91 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 75 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B18-Fe19347 NCP % 86 50-150 Pass
Perfluoropentanoic acid (PFPeA) B18-Fe19347 NCP % 127 50-150 Pass
Perfluorohexanoic acid (PFHxA) B18-Fe19347 NCP % 98 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B18-Fe19347 NCP % 110 50-150 Pass
Perfluorooctanoic acid (PFOA) B18-Fe19347 NCP % 110 50-150 Pass
Perfluorononanoic acid (PFNA) B18-Fe19347 NCP % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) B18-Fe19347 NCP % 93 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B18-Fe19347 NCP % 118 50-150 Pass
Perfluorododecanoic acid (PFDoA) B18-Fe19347 NCP % 99 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B18-Fe19347 NCP % 65 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B18-Fe19347 NCP % 123 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B18-Fe19347 NCP % 97 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B18-Fe19347 NCP % 85 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B18-Fe19347 NCP % 87 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B18-Fe19347 NCP % 102 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B18-Fe19347 NCP % 105 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B18-Fe19347 NCP % 101 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B18-Fe19347 NCP % 110 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 13
Report Number: 583541-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) B18-Fe19347 NCP % 81 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B18-Fe19347 NCP % 126 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B18-Fe19347 NCP % 87 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B18-Fe19347 NCP % 86 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B18-Fe19347 NCP % 86 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B18-Fe19347 NCP % 80 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B18-Fe19347 NCP % 88 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B18-Fe19347 NCP % 85 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B18-Fe19347 NCP % 90 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B18-Fe19347 NCP % 112 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06747 NCP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06747 NCP ug/kg < 10 < 10 <1 30% Pass
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 13
Report Number: 583541-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06747 NCP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06747 NCP ug/kg < 5 < 5 <1 30% Pass
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 13
Report Number: 583541-S
Quality Control Analyte Summary Compliance
The table below is the actual occurrence of QC performed on the batch of samples within this report and as defined below
Analysis SamplesAnalysed
LaboratoryDuplicatesReported
LaboratoryMatrix Spikes
Reported
Method BlanksReported
LaboratoryControl Samples
Reported
Perfluoroalkyl carboxylic acids (PFCAs) 5 1 1 1 1
Perfluoroalkane sulfonamides (PFASAs) 5 1 1 1 1
Perfluoroalkane sulfonic acids & Perfluoroalkane 5 1 1 1 1
n:2 Fluorotelomer sulfonic acids 5 1 1 1 1
Quality Control Parameter Frequency Compliance follows guidelines delineated in the National Environment Protection (Assessment of SiteContamination) Measure April 2011, Schedule B3, Guideline on Laboratory Analysis of Potentially Contaminated Soils and US EPA SW-846Chapter 1: 'Quality Control'.
It comprises the following when a laboratory process batch is deemed to consist of up to 20 samples that are similar in terms of matrix and testprocedure, and are processed as one unit for QC purposes. If more than 20 samples are being processed, they are considered as more than onebatch.
Method blank
One method blank per process batch.
Laboratory duplicate
There should be at least one duplicate per process batch, or two duplicates if the process batch exceeds 10 samples.
Laboratory control sample (LCS)
There should be at least one LCS per process batch.
Matrix spikes
There should be one matrix spike per matrix type per process batch.
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 12 of 13
Report Number: 583541-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident No
Sample correctly preserved No
Appropriate sample containers have been used No
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Feb 20, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 13 of 13
Report Number: 583541-S
ABN – 50 005 085 521 e.mail : [email protected] web : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne3-5 Kingston Town CloseOakleigh Vic 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261 Site # 23736
Environmental LaboratoryAir AnalysisWater AnalysisSoil Contamination Analysis
NATA AccreditationStack Emission Sampling & AnalysisTrade Waste Sampling & AnalysisGroundwater Sampling & Analysis
38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience
Sample Receipt AdviceSample Receipt AdviceSample Receipt AdviceSample Receipt Advice
Company name: Aurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty Ltd
Contact name: Georgina KerrProject name: HMAS ALBATROSSProject ID: 251529COC number: Not providedTurn around time: 5 DayDate/Time received: Feb 7, 2018 9:32 AMEurofins | mgt reference: 583547583547583547583547
Sample informationSample informationSample informationSample information
☑ A detailed list of analytes logged into our LIMS, is included in the attached summary table.
☑ All samples have been received as described on the above COC.
☑ COC has been completed correctly.
☑ Attempt to chill was evident.
☑ Appropriately preserved sample containers have been used.
☑ All samples were received in good condition.
☑ Samples have been provided with adequate time to commence analysis in accordance with therelevant holding times.
☑ Appropriate sample containers have been used.
☑ Sample containers for volatile analysis received with zero headspace.
☒ Split sample sent to requested external lab.
☒ Some samples have been subcontracted.
N/A Custody Seals intact (if used).
Contact notesContact notesContact notesContact notes
If you have any questions with respect to these samples please contact:
Ryan Gilbert on Phone : or by e.mail: [email protected]
Results will be delivered electronically via e.mail to Georgina Kerr - .
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Georgina Kerr
Report 583547-S
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 07, 2018
Client Sample ID SED_CC-B3_180206
SED_CC-B2_180206
Sample Matrix Sediment Sediment
Eurofins | mgt Sample No. S18-Fe06719 S18-Fe06721
Date Sampled Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5
Perfluorotridecanoic acid (PFTrDA)N15 5 ug/kg < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5
13C4-PFBA (surr.) 1 % 74 66
13C5-PFPeA (surr.) 1 % 83 77
13C5-PFHxA (surr.) 1 % 103 94
13C4-PFHpA (surr.) 1 % 95 90
13C8-PFOA (surr.) 1 % 104 92
13C5-PFNA (surr.) 1 % 98 87
13C6-PFDA (surr.) 1 % 144 131
13C2-PFUnDA (surr.) 1 % 172 157
13C2-PFDoDA (surr.) 1 % 171 137
13C2-PFTeDA (surr.) 1 % 138 118
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10
13C8-FOSA (surr.) 1 % 119 99
D3-N-MeFOSA (surr.) 1 % 105 95
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 15
Report Number: 583547-S
NATA AccreditedAccreditation Number 1261Site Number 18217
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID SED_CC-B3_180206
SED_CC-B2_180206
Sample Matrix Sediment Sediment
Eurofins | mgt Sample No. S18-Fe06719 S18-Fe06721
Date Sampled Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 84 77
D7-N-MeFOSE (surr.) 1 % 86 79
D9-N-EtFOSE (surr.) 1 % 110 103
D5-N-EtFOSAA (surr.) 1 % 178 138
D3-N-MeFOSAA (surr.) 1 % INT 179
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5
Perfluoropentanesulfonic acid (PFPeS)N15 5 ug/kg < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS)N15 5 ug/kg < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg N0920 N0921
Perfluorodecanesulfonic acid (PFDS)N15 5 ug/kg < 5 < 5
13C3-PFBS (surr.) 1 % 126 108
18O2-PFHxS (surr.) 1 % 118 108
13C8-PFOS (surr.) 1 % 117 117
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 5 ug/kg < 5 < 5
13C2-4:2 FTS (surr.) 1 % 51 47
13C2-6:2 FTS (surr.) 1 % 75 69
13C2-8:2 FTS (surr.) 1 % 92 99
PFASs Summations
Sum (PFHxS + PFOS)* 5 ug/kg 20 21
Sum of US EPA PFAS (PFOS + PFOA)* 5 ug/kg 20 21
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 5 ug/kg 20 21
Sum of WA DER PFAS (n=10)* 10 ug/kg 20 21
Sum of PFASs (n=28)* 50 ug/kg < 50 < 50
% Moisture 1 % 26 47
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 15
Report Number: 583547-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs) - Ultra Trace
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
% Moisture Brisbane Feb 07, 2018 14 Day
- Method: LTM-GEN-7080 Moisture
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 15
Report Number: 583547-S
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 7, 2018 9:32 AMAddress: Level 14, 32 Turbot St Report #: 583547 Due: Feb 21, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
pH Phosphate total (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 CC-B3_PERCH1_180204
Feb 04, 2018 Fish S18-Fe06713X
2 CC-B3_LUDERICK3_180204
Feb 04, 2018 Fish S18-Fe06714X
3 CC-B3_STREVALLY1_180204
Feb 04, 2018 Fish S18-Fe06715X
4 CC-B3_BREAM2_180204
Feb 04, 2018 Fish S18-Fe06716X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 15
Report Number: 583547-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 7, 2018 9:32 AMAddress: Level 14, 32 Turbot St Report #: 583547 Due: Feb 21, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
pH Phosphate total (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 23736
5 CC-B3_WHITING1_180204
Feb 04, 2018 Fish S18-Fe06717X
6 CC-B3_MULLET4_180204
Feb 04, 2018 Fish S18-Fe06718X
7 SED_CC-B3_180206
Feb 06, 2018 Sediment S18-Fe06719 X X
8 SW_CC-B3_180206
Feb 06, 2018 Water S18-Fe06720 X X X X X X X X X
9 SED_CC-B2_180206
Feb 06, 2018 Sediment S18-Fe06721 X X
10 SW_CC-B2_180206
Feb 06, 2018 Water S18-Fe06722 X X X X X X X X X
Test Counts 2 2 2 2 2 2 2 2 2 2 6 2
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 5 of 15
Report Number: 583547-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 6 of 15
Report Number: 583547-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 5 5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 5 5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 5 5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 5 5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 5 5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 5 5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 5 5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 5 5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 5 5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 5 5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 5 5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 5 5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 5 5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 5 5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 5 5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 5 5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 10 10 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 10 10 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 5 5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 5 5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 5 5 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 5 5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 5 5 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 5 5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 5 5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 10 10 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 5 5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 5 5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 93 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 84 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 93 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) % 91 50-150 Pass
Perfluorononanoic acid (PFNA) % 91 50-150 Pass
Perfluorodecanoic acid (PFDA) % 95 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 92 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 92 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 84 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 89 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 7 of 15
Report Number: 583547-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 91 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 89 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 95 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 95 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 88 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 91 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 94 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 88 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 92 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 86 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 93 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 58 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 96 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 102 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 62 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe06714 CP % 96 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06714 CP % 101 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06714 CP % 96 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06714 CP % 96 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe06714 CP % 93 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe06714 CP % 93 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe06714 CP % 95 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06714 CP % 94 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06714 CP % 95 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06714 CP % 84 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06714 CP % 92 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe06714 CP % 91 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06714 CP % 78 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06714 CP % 92 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06714 CP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06714 CP % 101 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06714 CP % 90 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06714 CP % 96 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 8 of 15
Report Number: 583547-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) S18-Fe06714 CP % 97 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06714 CP % 92 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06714 CP % 97 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06714 CP % 95 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06714 CP % 94 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06714 CP % 66 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06714 CP % 98 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06714 CP % 99 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06714 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06714 CP % 103 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe06716 CP % 95 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06716 CP % 102 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06716 CP % 96 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06716 CP % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe06716 CP % 93 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe06716 CP % 95 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe06716 CP % 93 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06716 CP % 93 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06716 CP % 92 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06716 CP % 87 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06716 CP % 91 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe06716 CP % 92 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06716 CP % 87 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06716 CP % 91 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06716 CP % 102 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06716 CP % 84 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06716 CP % 93 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06716 CP % 95 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S18-Fe06716 CP % 94 50-150 Pass
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 9 of 15
Report Number: 583547-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06716 CP % 89 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06716 CP % 93 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06716 CP % 87 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06716 CP % 95 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06716 CP % 62 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06716 CP % 96 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06716 CP % 99 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06716 CP % 90 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06716 CP % 95 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M18-Fe05896 NCP % 93 50-150 Pass
Perfluoropentanoic acid (PFPeA) M18-Fe05896 NCP % 100 50-150 Pass
Perfluorohexanoic acid (PFHxA) M18-Fe05896 NCP % 106 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe05896 NCP % 98 50-150 Pass
Perfluorooctanoic acid (PFOA) M18-Fe05896 NCP % 94 50-150 Pass
Perfluorononanoic acid (PFNA) M18-Fe05896 NCP % 102 50-150 Pass
Perfluorodecanoic acid (PFDA) M18-Fe05896 NCP % 120 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M18-Fe05896 NCP % 119 50-150 Pass
Perfluorododecanoic acid (PFDoA) M18-Fe05896 NCP % 107 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe05896 NCP % 121 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe05896 NCP % 90 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M18-Fe05896 NCP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe05896 NCP % 84 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe05896 NCP % 109 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe05896 NCP % 101 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe05896 NCP % 91 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe05896 NCP % 95 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe05896 NCP % 97 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M18-Fe05896 NCP % 85 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe05896 NCP % 115 50-150 Pass
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 10 of 15
Report Number: 583547-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorohexanesulfonic acid(PFHxS) M18-Fe05896 NCP % 88 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe05896 NCP % 98 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M18-Fe05896 NCP % 72 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe05896 NCP % 100 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M18-Fe05896 NCP % 87 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M18-Fe05896 NCP % 87 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M18-Fe05896 NCP % 111 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M18-Fe05896 NCP % 128 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 11 of 15
Report Number: 583547-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06713 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06713 CP ug/kg 11 11 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 12 of 15
Report Number: 583547-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06715 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06715 CP ug/kg 2.5 2.3 9.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe05895 NCP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe05895 NCP ug/kg < 10 < 10 <1 30% Pass
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 13 of 15
Report Number: 583547-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M18-Fe05895 NCP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
% Moisture S18-Ja03358 NCP % 6.0 5.5 9.0 30% Pass
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 14 of 15
Report Number: 583547-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Inorganic (QLD)
Jonathon Angell Senior Analyst-Organic (QLD)
Myles Clark Senior Analyst-Metal (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 15 of 15
Report Number: 583547-S
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Georgina Kerr
Report 583547-W
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 07, 2018
Client Sample ID SW_CC-B3_180206
SW_CC-B2_180206
Sample Matrix Water Water
Eurofins | mgt Sample No. S18-Fe06720 S18-Fe06722
Date Sampled Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.005 ug/L < 0.005 < 0.005
Perfluoropentanoic acid (PFPeA)N11 0.001 ug/L 0.001 0.001
Perfluorohexanoic acid (PFHxA)N11 0.001 ug/L 0.001 0.003
Perfluoroheptanoic acid (PFHpA)N11 0.001 ug/L < 0.001 < 0.001
Perfluorooctanoic acid (PFOA)N11 0.001 ug/L < 0.001 < 0.001
Perfluorononanoic acid (PFNA)N11 0.001 ug/L < 0.001 < 0.001
Perfluorodecanoic acid (PFDA)N11 0.001 ug/L < 0.001 < 0.001
Perfluoroundecanoic acid (PFUnA)N11 0.001 ug/L < 0.001 < 0.001
Perfluorododecanoic acid (PFDoA)N11 0.001 ug/L < 0.001 < 0.001
Perfluorotridecanoic acid (PFTrDA)N15 0.001 ug/L < 0.001 < 0.001
Perfluorotetradecanoic acid (PFTeDA)N11 0.001 ug/L < 0.001 < 0.001
13C4-PFBA (surr.) 1 % 96 98
13C5-PFPeA (surr.) 1 % 105 109
13C5-PFHxA (surr.) 1 % 71 79
13C4-PFHpA (surr.) 1 % 95 110
13C8-PFOA (surr.) 1 % 100 117
13C5-PFNA (surr.) 1 % 100 124
13C6-PFDA (surr.) 1 % 60 76
13C2-PFUnDA (surr.) 1 % 59 71
13C2-PFDoDA (surr.) 1 % 59 58
13C2-PFTeDA (surr.) 1 % 40 39
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.005 ug/L < 0.005 < 0.005
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.005 ug/L < 0.005 < 0.005
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.005 ug/L < 0.005 < 0.005
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.005 ug/L < 0.005 < 0.005
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.005 ug/L < 0.005 < 0.005
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.005 ug/L < 0.005 < 0.005
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.005 ug/L < 0.005 < 0.005
13C8-FOSA (surr.) 1 % 51 60
D3-N-MeFOSA (surr.) 1 % 46 44
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 13
Report Number: 583547-W
NATA AccreditedAccreditation Number 1261Site Number 18217
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID SW_CC-B3_180206
SW_CC-B2_180206
Sample Matrix Water Water
Eurofins | mgt Sample No. S18-Fe06720 S18-Fe06722
Date Sampled Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 25 25
D7-N-MeFOSE (surr.) 1 % 35 36
D9-N-EtFOSE (surr.) 1 % 34 32
D5-N-EtFOSAA (surr.) 1 % 53 52
D3-N-MeFOSAA (surr.) 1 % 54 61
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.001 ug/L < 0.001 0.001
Perfluoropentanesulfonic acid (PFPeS)N15 0.001 ug/L < 0.001 0.001
Perfluorohexanesulfonic acid (PFHxS)N11 0.001 ug/L 0.004 N090.014
Perfluoroheptanesulfonic acid (PFHpS)N15 0.001 ug/L < 0.001 < 0.001
Perfluorooctanesulfonic acid (PFOS)N11 0.0001 ug/L 0.012 N090.018
Perfluorodecanesulfonic acid (PFDS)N15 0.001 ug/L < 0.001 < 0.001
13C3-PFBS (surr.) 1 % 84 94
18O2-PFHxS (surr.) 1 % 124 138
13C8-PFOS (surr.) 1 % 71 94
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.001 ug/L < 0.001 < 0.001
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.005 ug/L < 0.005 < 0.005
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.001 ug/L < 0.001 < 0.001
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.001 ug/L < 0.001 < 0.001
13C2-4:2 FTS (surr.) 1 % 61 78
13C2-6:2 FTS (surr.) 1 % 82 116
13C2-8:2 FTS (surr.) 1 % 44 68
PFASs Summations
Sum (PFHxS + PFOS)* 0.001 ug/L 0.016 0.032
Sum of US EPA PFAS (PFOS + PFOA)* 0.001 ug/L 0.012 0.018
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.001 ug/L 0.016 0.032
Sum of WA DER PFAS (n=10)* 0.005 ug/L 0.018 0.037
Sum of PFASs (n=28)* 0.005 ug/L 0.018 0.038
Ammonia (as N) 0.01 mg/L < 0.01 0.02
Conductivity (at 25°C) 1 uS/cm 52000 53000
Nitrate & Nitrite (as N) 0.05 mg/L < 0.05 < 0.05
Nitrate (as N) 0.02 mg/L < 0.02 < 0.02
Nitrite (as N) 0.02 mg/L < 0.02 < 0.02
Organic Nitrogen (as N) 0.2 mg/L 0.34 0.30
pH 0.1 pH Units 8.1 7.8
Phosphate total (as P) 0.05 mg/L 0.05 < 0.05
Suspended Solids 1 mg/L 16 20
Total Dissolved Solids 10 mg/L 34000 36000
Total Kjeldahl Nitrogen (as N) 0.2 mg/L 0.3 0.3
Total Nitrogen (as N) 0.2 mg/L 0.34 0.32
Total Organic Carbon 5 mg/L < 5 < 5
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 13
Report Number: 583547-W
Client Sample ID SW_CC-B3_180206
SW_CC-B2_180206
Sample Matrix Water Water
Eurofins | mgt Sample No. S18-Fe06720 S18-Fe06722
Date Sampled Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Heavy Metals
Arsenic 0.001 mg/L < 0.01 < 0.01
Cadmium 0.0002 mg/L < 0.002 < 0.002
Chromium 0.001 mg/L < 0.01 < 0.01
Copper 0.001 mg/L < 0.01 < 0.01
Lead 0.001 mg/L < 0.01 < 0.01
Mercury 0.0001 mg/L < 0.001 < 0.001
Nickel 0.001 mg/L < 0.01 < 0.01
Zinc 0.005 mg/L < 0.05 < 0.05
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 13
Report Number: 583547-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs) - Ultra Trace
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 12, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 12, 2018 14 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 12, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 12, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Nitrogens (speciated)
Ammonia (as N) Melbourne Feb 08, 2018 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Nitrate & Nitrite (as N) Melbourne Feb 08, 2018 28 Day
- Method: APHA 4500-NO3/NO2 Nitrate-Nitrite Nitrogen by FIA
Nitrate (as N) Melbourne Feb 08, 2018 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Nitrite (as N) Melbourne Feb 08, 2018 2 Day
- Method: APHA 4500-NO2 Nitrite Nitrogen by FIA
Organic Nitrogen (as N) Melbourne Feb 07, 2018 7 Day
- Method: APHA 4500 Organic Nitrogen (N)
Total Kjeldahl Nitrogen (as N) Melbourne Feb 09, 2018 7 Day
- Method: APHA 4500 TKN
Conductivity (at 25°C) Melbourne Feb 08, 2018 28 Day
- Method: LTM-INO-4030
pH Melbourne Feb 08, 2018 0 Hours
- Method: LTM-GEN-7090 pH in water by ISE
Phosphate total (as P) Melbourne Feb 08, 2018 28 Day
- Method: APHA 4500-P E. Phosphorous
Suspended Solids Melbourne Feb 08, 2018 7 Days
- Method: LTM-INO-4070 Analysis of Suspended Solids in Water by Gravimetry
Total Dissolved Solids Melbourne Feb 08, 2018 7 Day
- Method: LTM-INO-4170 Total Dissolved Solids in Water
Total Organic Carbon Melbourne Feb 08, 2018 28 Day
- Method: APHA 5310B Total Organic Carbon
Metals M8 Melbourne Feb 08, 2018 28 Days
- Method: LTM-MET-3040 Metals in Waters, Soils & Sediments by ICP-MS
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 13
Report Number: 583547-W
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 7, 2018 9:32 AMAddress: Level 14, 32 Turbot St Report #: 583547 Due: Feb 21, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
pH Phosphate total (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 CC-B3_PERCH1_180204
Feb 04, 2018 Fish S18-Fe06713X
2 CC-B3_LUDERICK3_180204
Feb 04, 2018 Fish S18-Fe06714X
3 CC-B3_STREVALLY1_180204
Feb 04, 2018 Fish S18-Fe06715X
4 CC-B3_BREAM2_180204
Feb 04, 2018 Fish S18-Fe06716X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 5 of 13
Report Number: 583547-W
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 7, 2018 9:32 AMAddress: Level 14, 32 Turbot St Report #: 583547 Due: Feb 21, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
pH Phosphate total (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 23736
5 CC-B3_WHITING1_180204
Feb 04, 2018 Fish S18-Fe06717X
6 CC-B3_MULLET4_180204
Feb 04, 2018 Fish S18-Fe06718X
7 SED_CC-B3_180206
Feb 06, 2018 Sediment S18-Fe06719 X X
8 SW_CC-B3_180206
Feb 06, 2018 Water S18-Fe06720 X X X X X X X X X
9 SED_CC-B2_180206
Feb 06, 2018 Sediment S18-Fe06721 X X
10 SW_CC-B2_180206
Feb 06, 2018 Water S18-Fe06722 X X X X X X X X X
Test Counts 2 2 2 2 2 2 2 2 2 2 6 2
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 6 of 13
Report Number: 583547-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 7 of 13
Report Number: 583547-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.005 0.005 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.001 0.001 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.001 0.001 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.001 0.001 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.001 0.001 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.001 0.001 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.001 0.001 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.001 0.001 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.001 0.001 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.001 0.001 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.001 0.001 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.005 0.005 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.005 0.005 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.005 0.005 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.005 0.005 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.005 0.005 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.005 0.005 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.005 0.005 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.001 0.001 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.001 0.001 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.001 0.001 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.001 0.001 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.0001 0.0001 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.001 0.001 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.001 0.001 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.005 0.005 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.001 0.001 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.001 0.001 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Nitrate & Nitrite (as N) mg/L < 0.05 0.05 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Nitrite (as N) mg/L < 0.02 0.02 Pass
Phosphate total (as P) mg/L < 0.05 0.05 Pass
Suspended Solids mg/L < 1 1 Pass
Total Dissolved Solids mg/L < 10 10 Pass
Total Kjeldahl Nitrogen (as N) mg/L < 0.2 0.2 Pass
Total Organic Carbon mg/L < 5 5 Pass
Method Blank
Heavy Metals
Arsenic mg/L < 0.001 0.001 Pass
Cadmium mg/L < 0.0002 0.0002 Pass
Chromium mg/L < 0.001 0.001 Pass
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 8 of 13
Report Number: 583547-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Copper mg/L < 0.001 0.001 Pass
Lead mg/L < 0.001 0.001 Pass
Mercury mg/L < 0.0001 0.0001 Pass
Nickel mg/L < 0.001 0.001 Pass
Zinc mg/L < 0.005 0.005 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 90 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 87 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 107 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 90 50-150 Pass
Perfluorooctanoic acid (PFOA) % 101 50-150 Pass
Perfluorononanoic acid (PFNA) % 116 50-150 Pass
Perfluorodecanoic acid (PFDA) % 80 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 80 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 76 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 56 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 82 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 106 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 93 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 112 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 89 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 90 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 85 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 98 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 84 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 104 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 90 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 92 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 106 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 71 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 98 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 89 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 95 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 116 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 101 70-130 Pass
Nitrate & Nitrite (as N) % 102 70-130 Pass
Nitrate (as N) % 102 70-130 Pass
Nitrite (as N) % 114 70-130 Pass
Phosphate total (as P) % 104 70-130 Pass
Suspended Solids % 100 70-130 Pass
Total Dissolved Solids % 94 70-130 Pass
Total Kjeldahl Nitrogen (as N) % 84 70-130 Pass
Total Organic Carbon % 99 70-130 Pass
LCS - % Recovery
Heavy Metals
Arsenic % 95 80-120 Pass
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 9 of 13
Report Number: 583547-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Cadmium % 101 80-120 Pass
Chromium % 99 80-120 Pass
Copper % 97 80-120 Pass
Lead % 100 80-120 Pass
Mercury % 105 75-125 Pass
Nickel % 96 80-120 Pass
Zinc % 99 80-120 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M18-Fe05925 NCP % 96 50-150 Pass
Perfluoropentanoic acid (PFPeA) M18-Fe05925 NCP % 97 50-150 Pass
Perfluorohexanoic acid (PFHxA) M18-Fe05925 NCP % 118 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe05925 NCP % 101 50-150 Pass
Perfluorooctanoic acid (PFOA) M18-Fe05925 NCP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) M18-Fe05925 NCP % 136 50-150 Pass
Perfluorodecanoic acid (PFDA) M18-Fe05925 NCP % 86 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M18-Fe05925 NCP % 89 50-150 Pass
Perfluorododecanoic acid (PFDoA) M18-Fe05925 NCP % 84 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe05925 NCP % 54 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe05925 NCP % 93 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M18-Fe05925 NCP % 115 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe05925 NCP % 100 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe05925 NCP % 131 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe05925 NCP % 99 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe05925 NCP % 91 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe05925 NCP % 98 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe05925 NCP % 112 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M18-Fe05925 NCP % 92 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe05925 NCP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M18-Fe05925 NCP % 102 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe05925 NCP % 109 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M18-Fe05925 NCP % 94 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe05925 NCP % 63 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 10 of 13
Report Number: 583547-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M18-Fe05925 NCP % 108 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M18-Fe05925 NCP % 96 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M18-Fe05925 NCP % 100 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M18-Fe05925 NCP % 119 50-150 Pass
Spike - % Recovery
Result 1
Ammonia (as N) M18-Fe08161 NCP % 102 70-130 Pass
Nitrate & Nitrite (as N) M18-Fe08161 NCP % 107 70-130 Pass
Nitrate (as N) M18-Fe08161 NCP % 107 70-130 Pass
Nitrite (as N) B18-Fe06319 NCP % 113 70-130 Pass
Total Organic Carbon M18-Fe00595 NCP % 103 70-130 Pass
Spike - % Recovery
Heavy Metals Result 1
Arsenic M18-Fe06010 NCP % 89 75-125 Pass
Cadmium M18-Fe06010 NCP % 89 75-125 Pass
Chromium M18-Fe06010 NCP % 91 75-125 Pass
Copper M18-Fe06010 NCP % 87 75-125 Pass
Lead M18-Fe06010 NCP % 91 75-125 Pass
Mercury M18-Fe06010 NCP % 99 70-130 Pass
Nickel M18-Fe06010 NCP % 87 75-125 Pass
Zinc M18-Fe06010 NCP % 89 75-125 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M18-Fe05924 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M18-Fe05924 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe05924 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe05924 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe05924 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe05924 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 11 of 13
Report Number: 583547-W
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe05924 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe05924 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M18-Fe05924 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M18-Fe05924 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) B18-Fe06319 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Conductivity (at 25°C) B18-Fe06316 NCP uS/cm 290 300 1.0 30% Pass
Nitrate & Nitrite (as N) B18-Fe06319 NCP mg/L < 0.05 < 0.05 <1 30% Pass
Nitrate (as N) B18-Fe06319 NCP mg/L < 0.02 < 0.02 <1 30% Pass
Nitrite (as N) B18-Fe06319 NCP mg/L < 0.02 < 0.02 <1 30% Pass
pH B18-Fe06316 NCP pH Units 7.9 7.8 pass 30% Pass
Phosphate total (as P) B18-Fe06322 NCP mg/L < 0.05 < 0.05 <1 30% Pass
Suspended Solids M18-Fe08381 NCP mg/L 530 490 9.0 30% Pass
Total Dissolved Solids M18-Fe07795 NCP mg/L 2800 2900 4.0 30% Pass
Total Kjeldahl Nitrogen (as N) B18-Fe06322 NCP mg/L 0.3 0.3 16 30% Pass
Total Organic Carbon M18-Fe01334 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Heavy Metals Result 1 Result 2 RPD
Arsenic M18-Fe06010 NCP mg/L 0.003 0.004 22 30% Pass
Cadmium M18-Fe06010 NCP mg/L < 0.0002 < 0.0002 <1 30% Pass
Chromium M18-Fe06010 NCP mg/L 0.002 0.002 40 30% Fail Q15
Copper M18-Fe06010 NCP mg/L 0.003 0.003 14 30% Pass
Lead M18-Fe06010 NCP mg/L 0.001 0.001 7.0 30% Pass
Mercury M18-Fe06010 NCP mg/L < 0.0001 < 0.0001 <1 30% Pass
Nickel M18-Fe06010 NCP mg/L 0.004 0.005 16 30% Pass
Zinc M18-Fe06010 NCP mg/L 0.007 0.008 15 30% Pass
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 12 of 13
Report Number: 583547-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Q15 The RPD reported passes Eurofins | mgt's QC - Acceptance Criteria as defined in the Internal Quality Control Review and Glossary page of this report.
Authorised By
Ryan Gilbert Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Michael Brancati Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 13 of 13
Report Number: 583547-W
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Georgina Kerr
Report 583547-S-V2
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 07, 2018
Client Sample IDCC-B3_PERCH1_180204
CC-B3_LUDERICK3_180204
CC-B3_STREVALLY1_180204
CC-B3_BREAM2_180204
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe06713 S18-Fe06714 S18-Fe06715 S18-Fe06716
Date Sampled Feb 04, 2018 Feb 04, 2018 Feb 04, 2018 Feb 04, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 54 54 55 56
13C5-PFPeA (surr.) 1 % 68 64 66 64
13C5-PFHxA (surr.) 1 % 82 80 81 81
13C4-PFHpA (surr.) 1 % 83 83 79 78
13C8-PFOA (surr.) 1 % 92 87 84 83
13C5-PFNA (surr.) 1 % 88 88 86 83
13C6-PFDA (surr.) 1 % 97 95 94 89
13C2-PFUnDA (surr.) 1 % 68 44 53 53
13C2-PFDoDA (surr.) 1 % 40 80 66 70
13C2-PFTeDA (surr.) 1 % 81 78 66 53
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 52 64 66 62
D3-N-MeFOSA (surr.) 1 % 65 45 61 54
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 16
Report Number: 583547-S-V2
Client Sample IDCC-B3_PERCH1_180204
CC-B3_LUDERICK3_180204
CC-B3_STREVALLY1_180204
CC-B3_BREAM2_180204
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe06713 S18-Fe06714 S18-Fe06715 S18-Fe06716
Date Sampled Feb 04, 2018 Feb 04, 2018 Feb 04, 2018 Feb 04, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 67 66 69 57
D7-N-MeFOSE (surr.) 1 % 42 38 43 37
D9-N-EtFOSE (surr.) 1 % 48 34 48 41
D5-N-EtFOSAA (surr.) 1 % 161 149 146 133
D3-N-MeFOSAA (surr.) 1 % 130 133 127 118
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0911 N091.6 N092.5 < 0.3
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 92 90 92 92
18O2-PFHxS (surr.) 1 % 99 96 96 97
13C8-PFOS (surr.) 1 % 96 103 99 98
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 90 89 84 78
13C2-6:2 FTS (surr.) 1 % 103 115 97 91
13C2-8:2 FTS (surr.) 1 % 140 136 128 126
Client Sample IDCC-B3_WHITING1_180204
CC-B3_MULLET4_180204
Sample Matrix Fish Fish
Eurofins | mgt Sample No. S18-Fe06717 S18-Fe06718
Date Sampled Feb 04, 2018 Feb 04, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 57 54
13C5-PFPeA (surr.) 1 % 69 69
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 16
Report Number: 583547-S-V2
Client Sample IDCC-B3_WHITING1_180204
CC-B3_MULLET4_180204
Sample Matrix Fish Fish
Eurofins | mgt Sample No. S18-Fe06717 S18-Fe06718
Date Sampled Feb 04, 2018 Feb 04, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C5-PFHxA (surr.) 1 % 84 82
13C4-PFHpA (surr.) 1 % 81 82
13C8-PFOA (surr.) 1 % 88 88
13C5-PFNA (surr.) 1 % 86 91
13C6-PFDA (surr.) 1 % 90 99
13C2-PFUnDA (surr.) 1 % 75 51
13C2-PFDoDA (surr.) 1 % 78 82
13C2-PFTeDA (surr.) 1 % 76 106
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 64 65
D3-N-MeFOSA (surr.) 1 % 66 35
D5-N-EtFOSA (surr.) 1 % 70 61
D7-N-MeFOSE (surr.) 1 % 40 38
D9-N-EtFOSE (surr.) 1 % 49 26
D5-N-EtFOSAA (surr.) 1 % 121 149
D3-N-MeFOSAA (surr.) 1 % 109 128
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg < 0.3 N092.8
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 91 84
18O2-PFHxS (surr.) 1 % 97 91
13C8-PFOS (surr.) 1 % 96 81
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 82 106
13C2-6:2 FTS (surr.) 1 % 95 106
13C2-8:2 FTS (surr.) 1 % 119 159
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 16
Report Number: 583547-S-V2
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs) - Ultra Trace
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 07, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 07, 2018 180 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 07, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 15, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 16
Report Number: 583547-S-V2
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 7, 2018 9:32 AMAddress: Level 14, 32 Turbot St Report #: 583547 Due: Feb 21, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
pH Phosphate total (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 CC-B3_PERCH1_180204
Feb 04, 2018 Fish S18-Fe06713X
2 CC-B3_LUDERICK3_180204
Feb 04, 2018 Fish S18-Fe06714X
3 CC-B3_STREVALLY1_180204
Feb 04, 2018 Fish S18-Fe06715X
4 CC-B3_BREAM2_180204
Feb 04, 2018 Fish S18-Fe06716X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
First Reported:Feb 22, 2018
Date Reported:Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 5 of 16
Report Number: 583547-S-V2
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 7, 2018 9:32 AMAddress: Level 14, 32 Turbot St Report #: 583547 Due: Feb 21, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
pH Phosphate total (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 23736
5 CC-B3_WHITING1_180204
Feb 04, 2018 Fish S18-Fe06717X
6 CC-B3_MULLET4_180204
Feb 04, 2018 Fish S18-Fe06718X
7 SED_CC-B3_180206
Feb 06, 2018 Sediment S18-Fe06719 X X
8 SW_CC-B3_180206
Feb 06, 2018 Water S18-Fe06720 X X X X X X X X X
9 SED_CC-B2_180206
Feb 06, 2018 Sediment S18-Fe06721 X X
10 SW_CC-B2_180206
Feb 06, 2018 Water S18-Fe06722 X X X X X X X X X
Test Counts 2 2 2 2 2 2 2 2 2 2 6 2
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 6 of 16
Report Number: 583547-S-V2
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 7 of 16
Report Number: 583547-S-V2
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 0.5 0.5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 0.5 0.5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 0.5 0.5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 0.5 0.5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 0.5 0.5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 0.5 0.5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 0.5 0.5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 0.5 0.5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 0.5 0.5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 0.5 0.5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 0.5 0.5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 0.5 0.5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 0.5 0.5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 0.5 0.5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 0.5 0.5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 0.5 0.5 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 0.5 0.5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 0.5 0.5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 0.3 0.3 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 0.5 0.5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 0.3 0.3 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 0.5 0.5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 93 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 84 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 93 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) % 91 50-150 Pass
Perfluorononanoic acid (PFNA) % 91 50-150 Pass
Perfluorodecanoic acid (PFDA) % 95 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 92 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 92 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 84 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 89 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 8 of 16
Report Number: 583547-S-V2
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 91 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 89 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 95 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 95 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 88 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 91 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 94 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 88 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 92 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 86 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 93 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 58 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 96 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 102 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 62 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe06714 CP % 96 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06714 CP % 101 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06714 CP % 96 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06714 CP % 96 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe06714 CP % 93 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe06714 CP % 93 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe06714 CP % 95 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06714 CP % 94 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06714 CP % 95 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06714 CP % 84 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06714 CP % 92 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe06714 CP % 91 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06714 CP % 78 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06714 CP % 92 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06714 CP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06714 CP % 101 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06714 CP % 90 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06714 CP % 96 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 9 of 16
Report Number: 583547-S-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) S18-Fe06714 CP % 97 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06714 CP % 92 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06714 CP % 97 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06714 CP % 95 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06714 CP % 94 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06714 CP % 66 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06714 CP % 98 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06714 CP % 99 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06714 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06714 CP % 103 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe06716 CP % 95 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06716 CP % 102 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06716 CP % 96 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06716 CP % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe06716 CP % 93 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe06716 CP % 95 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe06716 CP % 93 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06716 CP % 93 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06716 CP % 92 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06716 CP % 87 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06716 CP % 91 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe06716 CP % 92 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06716 CP % 87 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06716 CP % 91 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06716 CP % 102 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06716 CP % 84 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06716 CP % 93 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06716 CP % 95 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S18-Fe06716 CP % 94 50-150 Pass
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 10 of 16
Report Number: 583547-S-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06716 CP % 89 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06716 CP % 93 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06716 CP % 87 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06716 CP % 95 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06716 CP % 62 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06716 CP % 96 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06716 CP % 99 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06716 CP % 90 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06716 CP % 95 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M18-Fe05896 NCP % 93 50-150 Pass
Perfluoropentanoic acid (PFPeA) M18-Fe05896 NCP % 100 50-150 Pass
Perfluorohexanoic acid (PFHxA) M18-Fe05896 NCP % 106 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe05896 NCP % 98 50-150 Pass
Perfluorooctanoic acid (PFOA) M18-Fe05896 NCP % 94 50-150 Pass
Perfluorononanoic acid (PFNA) M18-Fe05896 NCP % 102 50-150 Pass
Perfluorodecanoic acid (PFDA) M18-Fe05896 NCP % 120 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M18-Fe05896 NCP % 119 50-150 Pass
Perfluorododecanoic acid (PFDoA) M18-Fe05896 NCP % 107 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe05896 NCP % 121 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe05896 NCP % 90 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M18-Fe05896 NCP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe05896 NCP % 84 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe05896 NCP % 109 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe05896 NCP % 101 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe05896 NCP % 91 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe05896 NCP % 95 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe05896 NCP % 97 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M18-Fe05896 NCP % 85 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe05896 NCP % 115 50-150 Pass
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 11 of 16
Report Number: 583547-S-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorohexanesulfonic acid(PFHxS) M18-Fe05896 NCP % 88 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe05896 NCP % 98 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M18-Fe05896 NCP % 72 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe05896 NCP % 100 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M18-Fe05896 NCP % 87 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M18-Fe05896 NCP % 87 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M18-Fe05896 NCP % 111 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M18-Fe05896 NCP % 128 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 12 of 16
Report Number: 583547-S-V2
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06713 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06713 CP ug/kg 11 11 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06713 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 13 of 16
Report Number: 583547-S-V2
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06715 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06715 CP ug/kg 2.5 2.3 9.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06715 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe05895 NCP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe05895 NCP ug/kg < 10 < 10 <1 30% Pass
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 14 of 16
Report Number: 583547-S-V2
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M18-Fe05895 NCP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M18-Fe05895 NCP ug/kg < 5 < 5 <1 30% Pass
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 15 of 16
Report Number: 583547-S-V2
Comments
V2 - BIOTA REPORT
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Inorganic (QLD)
Jonathon Angell Senior Analyst-Organic (QLD)
Myles Clark Senior Analyst-Metal (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: Feb 22, 2018
Date Reported: Feb 22, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 16 of 16
Report Number: 583547-S-V2
ABN – 50 005 085 521 e.mail : [email protected] web : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne3-5 Kingston Town CloseOakleigh Vic 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261 Site # 23736
Environmental LaboratoryAir AnalysisWater AnalysisSoil Contamination Analysis
NATA AccreditationStack Emission Sampling & AnalysisTrade Waste Sampling & AnalysisGroundwater Sampling & Analysis
38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience
Sample Receipt AdviceSample Receipt AdviceSample Receipt AdviceSample Receipt Advice
Company name: Aurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty Ltd
Contact name: Christine KennellyProject name: HMAS ALBATROSSProject ID: 251529COC number: Not providedTurn around time: 5 DayDate/Time received: Feb 6, 2018 4:00 PMEurofins | mgt reference: 583551583551583551583551
Sample informationSample informationSample informationSample information
☑ A detailed list of analytes logged into our LIMS, is included in the attached summary table.
☑ All samples have been received as described on the above COC.
☑ COC has been completed correctly.
☑ Attempt to chill was evident.
☑ Appropriately preserved sample containers have been used.
☑ All samples were received in good condition.
☑ Samples have been provided with adequate time to commence analysis in accordance with therelevant holding times.
☑ Appropriate sample containers have been used.
☒ Split sample sent to requested external lab.
☒ Some samples have been subcontracted.
N/A Custody Seals intact (if used).
Contact notesContact notesContact notesContact notes
If you have any questions with respect to these samples please contact:
Ryan Gilbert on Phone : or by e.mail: [email protected]
Results will be delivered electronically via e.mail to Christine Kennelly - .
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Christine Kennelly
Report 583551-S
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 06, 2018
Client Sample IDCC-B3_MULLET1_180204
CC-B3_MULLET2_180204
CC-B3_MULLET3_180204
CC-B3_LUDERICK1_180204
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe06747 S18-Fe06748 S18-Fe06749 S18-Fe06750
Date Sampled Feb 04, 2018 Feb 04, 2018 Feb 04, 2018 Feb 04, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 93 103 113 107
13C5-PFPeA (surr.) 1 % 85 92 105 95
13C5-PFHxA (surr.) 1 % 72 77 89 86
13C4-PFHpA (surr.) 1 % 67 75 89 98
13C8-PFOA (surr.) 1 % 86 97 121 123
13C5-PFNA (surr.) 1 % 99 111 135 144
13C6-PFDA (surr.) 1 % 121 130 147 142
13C2-PFUnDA (surr.) 1 % 124 125 100 133
13C2-PFDoDA (surr.) 1 % 122 120 106 156
13C2-PFTeDA (surr.) 1 % 65 127 112 114
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 75 106 88 115
D3-N-MeFOSA (surr.) 1 % 17 43 45 41
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 15
Report Number: 583551-S
Client Sample IDCC-B3_MULLET1_180204
CC-B3_MULLET2_180204
CC-B3_MULLET3_180204
CC-B3_LUDERICK1_180204
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe06747 S18-Fe06748 S18-Fe06749 S18-Fe06750
Date Sampled Feb 04, 2018 Feb 04, 2018 Feb 04, 2018 Feb 04, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT 30 29 23
D7-N-MeFOSE (surr.) 1 % 23 58 60 87
D9-N-EtFOSE (surr.) 1 % INT 20 21 40
D5-N-EtFOSAA (surr.) 1 % 135 152 151 155
D3-N-MeFOSAA (surr.) 1 % 151 158 134 186
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N093.0 N093.5 N093.3 N091.6
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 80 81 94 95
18O2-PFHxS (surr.) 1 % 120 123 133 140
13C8-PFOS (surr.) 1 % 129 133 128 135
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 129 126 127 82
13C2-6:2 FTS (surr.) 1 % INT INT INT INT
13C2-8:2 FTS (surr.) 1 % INT INT INT INT
Client Sample IDCC-B3_LUDERICK2_180204
CC-B3_BREAM1_180204
Sample Matrix Fish Fish
Eurofins | mgt Sample No. S18-Fe06751 S18-Fe06752
Date Sampled Feb 04, 2018 Feb 04, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 105 108
13C5-PFPeA (surr.) 1 % 96 101
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 15
Report Number: 583551-S
Client Sample IDCC-B3_LUDERICK2_180204
CC-B3_BREAM1_180204
Sample Matrix Fish Fish
Eurofins | mgt Sample No. S18-Fe06751 S18-Fe06752
Date Sampled Feb 04, 2018 Feb 04, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C5-PFHxA (surr.) 1 % 82 95
13C4-PFHpA (surr.) 1 % 77 100
13C8-PFOA (surr.) 1 % 92 132
13C5-PFNA (surr.) 1 % 115 138
13C6-PFDA (surr.) 1 % 137 141
13C2-PFUnDA (surr.) 1 % 128 134
13C2-PFDoDA (surr.) 1 % 152 138
13C2-PFTeDA (surr.) 1 % 125 110
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 124 117
D3-N-MeFOSA (surr.) 1 % 42 16
D5-N-EtFOSA (surr.) 1 % 21 10
D7-N-MeFOSE (surr.) 1 % 79 59
D9-N-EtFOSE (surr.) 1 % 38 37
D5-N-EtFOSAA (surr.) 1 % 151 151
D3-N-MeFOSAA (surr.) 1 % 189 154
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N092.5 < 0.3
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 86 105
18O2-PFHxS (surr.) 1 % 129 139
13C8-PFOS (surr.) 1 % 133 142
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 125 80
13C2-6:2 FTS (surr.) 1 % INT INT
13C2-8:2 FTS (surr.) 1 % INT INT
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 15
Report Number: 583551-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 07, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 07, 2018 180 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 07, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 15
Report Number: 583551-S
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 6, 2018 4:00 PMAddress: Level 14, 32 Turbot St Report #: 583551 Due: Feb 20, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 CC-B3_MULLET1_180204
Feb 04, 2018 Fish S18-Fe06747X
2 CC-B3_MULLET2_180204
Feb 04, 2018 Fish S18-Fe06748X
3 CC-B3_MULLET3_180204
Feb 04, 2018 Fish S18-Fe06749X
4 CC-B3_LUDERICK1_180204
Feb 04, 2018 Fish S18-Fe06750X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 5 of 15
Report Number: 583551-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 6, 2018 4:00 PMAddress: Level 14, 32 Turbot St Report #: 583551 Due: Feb 20, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Christine Kennelly
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
5 CC-B3_LUDERICK2_180204
Feb 04, 2018 Fish S18-Fe06751X
6 CC-B3_BREAM1_180204
Feb 04, 2018 Fish S18-Fe06752X
Test Counts 6
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 6 of 15
Report Number: 583551-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 7 of 15
Report Number: 583551-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 0.5 0.5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 0.5 0.5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 0.5 0.5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 0.5 0.5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 0.5 0.5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 0.5 0.5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 0.5 0.5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 0.5 0.5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 0.5 0.5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 0.5 0.5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 0.5 0.5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 0.5 0.5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 0.5 0.5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 0.5 0.5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 0.5 0.5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 0.5 0.5 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 0.5 0.5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 0.5 0.5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 0.3 0.3 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 0.5 0.5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 0.3 0.3 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 0.5 0.5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 93 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 98 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 89 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 98 50-150 Pass
Perfluorooctanoic acid (PFOA) % 101 50-150 Pass
Perfluorononanoic acid (PFNA) % 137 50-150 Pass
Perfluorodecanoic acid (PFDA) % 79 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 90 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 92 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 57 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 117 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 8 of 15
Report Number: 583551-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 91 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 87 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 81 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 114 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 94 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 91 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 102 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 85 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 103 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 94 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 90 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 101 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 52 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 98 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 96 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 91 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 75 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe06748 CP % 91 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06748 CP % 89 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06748 CP % 83 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06748 CP % 107 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe06748 CP % 100 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe06748 CP % 112 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe06748 CP % 82 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06748 CP % 89 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06748 CP % 86 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06748 CP % 102 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06748 CP % 118 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe06748 CP % 92 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06748 CP % 71 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06748 CP % 87 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06748 CP % 138 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06748 CP % 117 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06748 CP % 96 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06748 CP % 99 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 9 of 15
Report Number: 583551-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) S18-Fe06748 CP % 85 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06748 CP % 117 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06748 CP % 80 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06748 CP % 75 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06748 CP % 88 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06748 CP % 71 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06748 CP % 96 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06748 CP % 85 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06748 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06748 CP % 128 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe06750 CP % 90 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06750 CP % 88 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06750 CP % 85 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06750 CP % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe06750 CP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe06750 CP % 106 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe06750 CP % 80 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06750 CP % 86 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06750 CP % 79 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06750 CP % 71 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06750 CP % 123 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe06750 CP % 94 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06750 CP % 91 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06750 CP % 68 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06750 CP % 117 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06750 CP % 117 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06750 CP % 93 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06750 CP % 96 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S18-Fe06750 CP % 85 50-150 Pass
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 10 of 15
Report Number: 583551-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06750 CP % 108 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06750 CP % 81 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06750 CP % 75 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06750 CP % 81 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06750 CP % 66 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06750 CP % 98 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06750 CP % 87 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06750 CP % 89 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06750 CP % 108 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 11 of 15
Report Number: 583551-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06747 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06747 CP ug/kg 3.0 3.1 4.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06747 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 12 of 15
Report Number: 583551-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe06749 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe06749 CP ug/kg 3.3 3.3 3.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe06749 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 13 of 15
Report Number: 583551-S
Quality Control Analyte Summary Compliance
The table below is the actual occurrence of QC performed on the batch of samples within this report and as defined below
Analysis SamplesAnalysed
LaboratoryDuplicatesReported
LaboratoryMatrix Spikes
Reported
Method BlanksReported
LaboratoryControl Samples
Reported
Perfluoroalkyl carboxylic acids (PFCAs) 6 2 2 1 1
Perfluoroalkane sulfonamides (PFASAs) 6 2 2 1 1
Perfluoroalkane sulfonic acids & Perfluoroalkane 6 2 2 1 1
n:2 Fluorotelomer sulfonic acids 6 2 2 1 1
Quality Control Parameter Frequency Compliance follows guidelines delineated in the National Environment Protection (Assessment of SiteContamination) Measure April 2011, Schedule B3, Guideline on Laboratory Analysis of Potentially Contaminated Soils and US EPA SW-846Chapter 1: 'Quality Control'.
It comprises the following when a laboratory process batch is deemed to consist of up to 20 samples that are similar in terms of matrix and testprocedure, and are processed as one unit for QC purposes. If more than 20 samples are being processed, they are considered as more than onebatch.
Method blank
One method blank per process batch.
Laboratory duplicate
There should be at least one duplicate per process batch, or two duplicates if the process batch exceeds 10 samples.
Laboratory control sample (LCS)
There should be at least one LCS per process batch.
Matrix spikes
There should be one matrix spike per matrix type per process batch.
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 14 of 15
Report Number: 583551-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Feb 20, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 15 of 15
Report Number: 583551-S
1
Enviro Sample NSW
From: Georgina Kerr
Sent: Friday, 9 February 2018 9:16 AM
To: Enviro Sample NSW
Cc: Christine Kennelly
Subject: RE: Eurofins | mgt Sample Receipt Advice - Report 583847 : Site HMAS ALBATROSS
(251529)
Follow Up Flag: Follow up
Flag Status: Flagged
Apologies, I forgot to add, that for CC-B2_MCRAB1_180206, please analyse the edible portions of the crab only (ie don’t analyse the shell). Thanks Georgina Georgina Kerr Senior Consultant, Environment and Planning, Aurecon T F
DISCLAIMER
From: Georgina Kerr
Sent: Friday, 9 February 2018 8:14 AM
To: '[email protected]' <[email protected]>
Cc: Christine Kennelly
Subject: RE: Eurofins | mgt Sample Receipt Advice - Report 583847 : Site HMAS ALBATROSS (251529)
Hi Ursula, Can you please schedule CC-B2_PERCH2_180206 for PFAS analysis? In addition, please re-label CC-B2_PERCHZ_180206 as CC-B2_PERCH3_180206. Let me know if there are any issues. Thanks, Georgina Georgina Kerr Senior Consultant, Environment and Planning, Aurecon T F
DISCLAIMER
From: [email protected] [mailto:[email protected]]
Sent: Thursday, 8 February 2018 5:51 PM
To: Georgina Kerr
Cc: Christine Kennelly
Subject: Eurofins | mgt Sample Receipt Advice - Report 583847 : Site HMAS ALBATROSS (251529)
2
Dear Valued Client, CC-B2_PERCH3_180206 sample not received, hence analysis cancelled. However, we have received CCB2_PERCH2_180206 which is placed on hold. Please find attached a Sample Receipt Advice (SRA), a Summary Sheet and a scanned copy of your Chain-of-Custody (COC). It is important that you check this documentation to ensure that the details are correct such as the Client Job Number, Turn Around Time, any comments in the Notes section and sample numbers as well as the requested analysis. If there are any irregularities then please contact your Eurofins | mgt Analytical Services Manager as soon as possible to make certain that they get changed.
Regards
Ursula Long
Sample Receipt
Eurofins | mgt
Unit F3, Parkview Building
16 Mars Road
LANE COVE WEST NSW 2066
AUSTRALIA
Phone: +61 299 008 400
Email: [email protected]
Website:environment.eurofins.com.au
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EnviroNote 1074 - Passive Samplers for VOCs in Air
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ABN – 50 005 085 521 e.mail : [email protected] web : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne3-5 Kingston Town CloseOakleigh Vic 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261 Site # 23736
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38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience
Sample Receipt AdviceSample Receipt AdviceSample Receipt AdviceSample Receipt Advice
Company name: Aurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty Ltd
Contact name: Georgina KerrProject name: HMAS ALBATROSSProject ID: 251529COC number: Not providedTurn around time: 5 DayDate/Time received: Feb 8, 2018 3:03 PMEurofins | mgt reference: 583847583847583847583847
Sample informationSample informationSample informationSample information
☑ A detailed list of analytes logged into our LIMS, is included in the attached summary table.
☑ All samples have been received as described on the above COC.
☑ COC has been completed correctly.
☑ Attempt to chill was evident.
☑ Appropriately preserved sample containers have been used.
☑ All samples were received in good condition.
☑ Samples have been provided with adequate time to commence analysis in accordance with therelevant holding times.
☑ Appropriate sample containers have been used.
☒ Split sample sent to requested external lab.
☒ Some samples have been subcontracted.
N/A Custody Seals intact (if used).
Contact notesContact notesContact notesContact notes
If you have any questions with respect to these samples please contact:
Ryan Gilbert on Phone : or by e.mail: [email protected]
Results will be delivered electronically via e.mail to Georgina Kerr - .
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Georgina Kerr
Report 583847-S
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 08, 2018
Client Sample IDCC-B2_PERCH3_180206
CC-B2_LUDERICK1_180206
CC-B2_MULLOWAY2_180206
CC-B2_STREVALLY1_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09233 S18-Fe09234 S18-Fe09235 S18-Fe09236
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 63 57 57 55
13C5-PFPeA (surr.) 1 % 71 69 68 65
13C5-PFHxA (surr.) 1 % 89 82 82 80
13C4-PFHpA (surr.) 1 % 91 83 82 78
13C8-PFOA (surr.) 1 % 93 85 86 80
13C5-PFNA (surr.) 1 % 91 88 87 83
13C6-PFDA (surr.) 1 % 97 101 98 86
13C2-PFUnDA (surr.) 1 % 97 94 94 61
13C2-PFDoDA (surr.) 1 % 102 103 100 67
13C2-PFTeDA (surr.) 1 % 80 93 71 55
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 78 77 66 59
D3-N-MeFOSA (surr.) 1 % 78 55 61 54
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 24
Report Number: 583847-S
Client Sample IDCC-B2_PERCH3_180206
CC-B2_LUDERICK1_180206
CC-B2_MULLOWAY2_180206
CC-B2_STREVALLY1_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09233 S18-Fe09234 S18-Fe09235 S18-Fe09236
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 76 67 69 56
D7-N-MeFOSE (surr.) 1 % 51 46 46 37
D9-N-EtFOSE (surr.) 1 % 58 36 52 42
D5-N-EtFOSAA (surr.) 1 % 144 156 148 108
D3-N-MeFOSAA (surr.) 1 % 127 135 125 101
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg 0.5 < 0.3 < 0.3 1.1
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0918 N096.6 N0911 N0923
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 98 94 91 91
18O2-PFHxS (surr.) 1 % 105 97 98 97
13C8-PFOS (surr.) 1 % 97 101 96 84
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 94 91 87 79
13C2-6:2 FTS (surr.) 1 % 92 102 93 78
13C2-8:2 FTS (surr.) 1 % 122 127 125 113
Client Sample IDCC-B2_STREVALLY2_180206
CC-B2_PERCH4_180206
CC-B2_WHITING1_180206
CC-B2_MCRAB1_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09237 S18-Fe09238 S18-Fe09240 S18-Fe09241
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 52 57 55 53
13C5-PFPeA (surr.) 1 % 60 65 62 56
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 24
Report Number: 583847-S
Client Sample IDCC-B2_STREVALLY2_180206
CC-B2_PERCH4_180206
CC-B2_WHITING1_180206
CC-B2_MCRAB1_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09237 S18-Fe09238 S18-Fe09240 S18-Fe09241
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C5-PFHxA (surr.) 1 % 75 79 79 25
13C4-PFHpA (surr.) 1 % 73 81 78 38
13C8-PFOA (surr.) 1 % 79 84 82 85
13C5-PFNA (surr.) 1 % 80 82 80 90
13C6-PFDA (surr.) 1 % 87 91 92 97
13C2-PFUnDA (surr.) 1 % 74 92 84 92
13C2-PFDoDA (surr.) 1 % 81 87 84 82
13C2-PFTeDA (surr.) 1 % 62 65 75 63
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 N090.7 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 64 71 70 65
D3-N-MeFOSA (surr.) 1 % 53 68 63 67
D5-N-EtFOSA (surr.) 1 % 62 71 67 69
D7-N-MeFOSE (surr.) 1 % 40 45 40 35
D9-N-EtFOSE (surr.) 1 % 41 51 47 33
D5-N-EtFOSAA (surr.) 1 % 131 124 128 140
D3-N-MeFOSAA (surr.) 1 % 113 112 115 132
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg N092.2 0.4 < 0.3 0.7
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0937 N0918 N0912 N093.9
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 84 90 90 39
18O2-PFHxS (surr.) 1 % 91 95 97 94
13C8-PFOS (surr.) 1 % 83 89 91 101
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 71 78 83 14
13C2-6:2 FTS (surr.) 1 % 77 92 88 66
13C2-8:2 FTS (surr.) 1 % 117 113 118 90
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 24
Report Number: 583847-S
Client Sample IDCC-B2_MULLET2_180206
CC-B2_LUDERICK4_180206
CC-B2_MULLET1_180206
CC-B3_LUDERICK4_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09242 S18-Fe09243 S18-Fe09244 S18-Fe09245
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 54 55 60 55
13C5-PFPeA (surr.) 1 % 62 64 66 61
13C5-PFHxA (surr.) 1 % 81 79 84 79
13C4-PFHpA (surr.) 1 % 81 79 82 80
13C8-PFOA (surr.) 1 % 87 80 91 81
13C5-PFNA (surr.) 1 % 91 86 100 83
13C6-PFDA (surr.) 1 % 105 98 107 97
13C2-PFUnDA (surr.) 1 % 92 95 91 91
13C2-PFDoDA (surr.) 1 % 101 103 101 91
13C2-PFTeDA (surr.) 1 % 98 92 107 83
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 70 76 69 72
D3-N-MeFOSA (surr.) 1 % 47 50 44 54
D5-N-EtFOSA (surr.) 1 % 54 67 50 66
D7-N-MeFOSE (surr.) 1 % 45 43 39 45
D9-N-EtFOSE (surr.) 1 % 23 27 18 40
D5-N-EtFOSAA (surr.) 1 % 156 151 147 150
D3-N-MeFOSAA (surr.) 1 % 127 136 124 132
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N092.7 N095.8 N096.4 N091.6
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 88 89 91 90
18O2-PFHxS (surr.) 1 % 97 95 88 95
13C8-PFOS (surr.) 1 % 100 98 95 102
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 24
Report Number: 583847-S
Client Sample IDCC-B2_MULLET2_180206
CC-B2_LUDERICK4_180206
CC-B2_MULLET1_180206
CC-B3_LUDERICK4_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09242 S18-Fe09243 S18-Fe09244 S18-Fe09245
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 97 87 78 86
13C2-6:2 FTS (surr.) 1 % 94 91 107 107
13C2-8:2 FTS (surr.) 1 % 154 125 168 123
Client Sample IDCC-B3_BREAM3_180206
CC-B3_SCRAB1_180206
CC-B3_WHITING2_180206
CC-B2_LUDERICK3_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09246 S18-Fe09247 S18-Fe09248 S18-Fe09249
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 56 46 58 54
13C5-PFPeA (surr.) 1 % 64 44 67 63
13C5-PFHxA (surr.) 1 % 77 29 80 80
13C4-PFHpA (surr.) 1 % 76 66 76 78
13C8-PFOA (surr.) 1 % 78 93 80 80
13C5-PFNA (surr.) 1 % 76 90 81 86
13C6-PFDA (surr.) 1 % 89 113 96 101
13C2-PFUnDA (surr.) 1 % 75 87 100 90
13C2-PFDoDA (surr.) 1 % 83 110 108 79
13C2-PFTeDA (surr.) 1 % 63 104 68 98
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 5 of 24
Report Number: 583847-S
Client Sample IDCC-B3_BREAM3_180206
CC-B3_SCRAB1_180206
CC-B3_WHITING2_180206
CC-B2_LUDERICK3_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09246 S18-Fe09247 S18-Fe09248 S18-Fe09249
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 68 40 75 68
D3-N-MeFOSA (surr.) 1 % 58 12 60 52
D5-N-EtFOSA (surr.) 1 % 58 16 63 65
D7-N-MeFOSE (surr.) 1 % 40 12 50 41
D9-N-EtFOSE (surr.) 1 % 44 INT 53 35
D5-N-EtFOSAA (surr.) 1 % 128 138 146 150
D3-N-MeFOSAA (surr.) 1 % 113 126 123 133
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 N091.4 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg < 0.3 N094.5 N091.6 N094.9
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 89 50 90 88
18O2-PFHxS (surr.) 1 % 95 83 96 94
13C8-PFOS (surr.) 1 % 102 89 103 98
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 76 31 84 95
13C2-6:2 FTS (surr.) 1 % 91 99 84 123
13C2-8:2 FTS (surr.) 1 % 111 147 118 141
Client Sample IDCC-B3_STREVALLY2_180206
CC-B2_SOUL1_180206
CC-B2_EPRAWZ1_180206
CC-B2_BREAM1_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09250 S18-Fe09251 S18-Fe09252 S18-Fe09253
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 1.3 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 6 of 24
Report Number: 583847-S
Client Sample IDCC-B3_STREVALLY2_180206
CC-B2_SOUL1_180206
CC-B2_EPRAWZ1_180206
CC-B2_BREAM1_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09250 S18-Fe09251 S18-Fe09252 S18-Fe09253
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 57 69 46 66
13C5-PFPeA (surr.) 1 % 63 74 64 75
13C5-PFHxA (surr.) 1 % 81 80 71 84
13C4-PFHpA (surr.) 1 % 79 77 43 81
13C8-PFOA (surr.) 1 % 85 81 47 87
13C5-PFNA (surr.) 1 % 86 80 87 86
13C6-PFDA (surr.) 1 % 99 59 91 93
13C2-PFUnDA (surr.) 1 % 73 70 82 95
13C2-PFDoDA (surr.) 1 % 78 63 97 106
13C2-PFTeDA (surr.) 1 % 68 49 57 106
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 64 65 24 76
D3-N-MeFOSA (surr.) 1 % 49 55 INT 67
D5-N-EtFOSA (surr.) 1 % 54 54 12 70
D7-N-MeFOSE (surr.) 1 % 40 32 INT 46
D9-N-EtFOSE (surr.) 1 % 41 34 INT 47
D5-N-EtFOSAA (surr.) 1 % 143 130 127 162
D3-N-MeFOSAA (surr.) 1 % 120 110 117 131
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 N0927 N099.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 N095.9 N090.9 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N094.2 N09340 N0936 N091.0
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 93 93 88 97
18O2-PFHxS (surr.) 1 % 101 71 65 93
13C8-PFOS (surr.) 1 % 100 80 80 99
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 7 of 24
Report Number: 583847-S
Client Sample IDCC-B3_STREVALLY2_180206
CC-B2_SOUL1_180206
CC-B2_EPRAWZ1_180206
CC-B2_BREAM1_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09250 S18-Fe09251 S18-Fe09252 S18-Fe09253
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
13C2-4:2 FTS (surr.) 1 % 93 43 54 61
13C2-6:2 FTS (surr.) 1 % 99 72 64 66
13C2-8:2 FTS (surr.) 1 % 136 80 132 84
Client Sample IDCC-B2_MULLOWAY1_180206
CC-B2_LUDERICK2_180206
CC-B3_WHITING3_180206
CC-B2_PERCH1_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09254 S18-Fe09255 S18-Fe09256 S18-Fe09257
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 62 64 71 63
13C5-PFPeA (surr.) 1 % 72 72 77 68
13C5-PFHxA (surr.) 1 % 79 85 84 73
13C4-PFHpA (surr.) 1 % 77 82 82 70
13C8-PFOA (surr.) 1 % 86 85 87 70
13C5-PFNA (surr.) 1 % 88 88 80 70
13C6-PFDA (surr.) 1 % 94 95 86 74
13C2-PFUnDA (surr.) 1 % 98 90 87 58
13C2-PFDoDA (surr.) 1 % 111 107 84 54
13C2-PFTeDA (surr.) 1 % 102 89 71 47
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 62 76 78 66
D3-N-MeFOSA (surr.) 1 % 61 44 57 57
D5-N-EtFOSA (surr.) 1 % 63 50 57 55
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 8 of 24
Report Number: 583847-S
Client Sample IDCC-B2_MULLOWAY1_180206
CC-B2_LUDERICK2_180206
CC-B3_WHITING3_180206
CC-B2_PERCH1_180206
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe09254 S18-Fe09255 S18-Fe09256 S18-Fe09257
Date Sampled Feb 06, 2018 Feb 06, 2018 Feb 06, 2018 Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D7-N-MeFOSE (surr.) 1 % 43 40 38 33
D9-N-EtFOSE (surr.) 1 % 45 27 43 32
D5-N-EtFOSAA (surr.) 1 % 155 154 137 86
D3-N-MeFOSAA (surr.) 1 % 125 135 120 85
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg 0.5 < 0.3 < 0.3 0.5
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0915 N095.2 N091.5 N0915
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 94 98 101 90
18O2-PFHxS (surr.) 1 % 93 91 92 80
13C8-PFOS (surr.) 1 % 92 98 98 76
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 52 53 55 38
13C2-6:2 FTS (surr.) 1 % 63 82 59 46
13C2-8:2 FTS (surr.) 1 % 101 91 88 66
Client Sample IDCC-B2_PERCH2_180206
Sample Matrix Fish
Eurofins | mgt Sample No. S18-Fe09566
Date Sampled Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5
13C4-PFBA (surr.) 1 % 60
13C5-PFPeA (surr.) 1 % 69
13C5-PFHxA (surr.) 1 % 73
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 9 of 24
Report Number: 583847-S
Client Sample IDCC-B2_PERCH2_180206
Sample Matrix Fish
Eurofins | mgt Sample No. S18-Fe09566
Date Sampled Feb 06, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C4-PFHpA (surr.) 1 % 73
13C8-PFOA (surr.) 1 % 76
13C5-PFNA (surr.) 1 % 78
13C6-PFDA (surr.) 1 % 79
13C2-PFUnDA (surr.) 1 % 71
13C2-PFDoDA (surr.) 1 % 70
13C2-PFTeDA (surr.) 1 % 51
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5
13C8-FOSA (surr.) 1 % 68
D3-N-MeFOSA (surr.) 1 % 65
D5-N-EtFOSA (surr.) 1 % 63
D7-N-MeFOSE (surr.) 1 % 37
D9-N-EtFOSE (surr.) 1 % 37
D5-N-EtFOSAA (surr.) 1 % 116
D3-N-MeFOSAA (surr.) 1 % 98
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0917
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5
13C3-PFBS (surr.) 1 % 91
18O2-PFHxS (surr.) 1 % 86
13C8-PFOS (surr.) 1 % 81
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5
13C2-4:2 FTS (surr.) 1 % 38
13C2-6:2 FTS (surr.) 1 % 48
13C2-8:2 FTS (surr.) 1 % 66
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 10 of 24
Report Number: 583847-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 15, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 11 of 24
Report Number: 583847-S
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 8, 2018 3:03 PMAddress: Level 14, 32 Turbot St Report #: 583847 Due: Feb 22, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 CC-B2_PERCH3_180206
Feb 06, 2018 Fish S18-Fe09233X
2 CC-B2_LUDERICK1_180206
Feb 06, 2018 Fish S18-Fe09234X
3 CC-B2_MULLOWAY2_180206
Feb 06, 2018 Fish S18-Fe09235X
4 CC-B2_STREVALLY1_180206
Feb 06, 2018 Fish S18-Fe09236X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 12 of 24
Report Number: 583847-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 8, 2018 3:03 PMAddress: Level 14, 32 Turbot St Report #: 583847 Due: Feb 22, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
5 CC-B2_STREVALLY2_180206
Feb 06, 2018 Fish S18-Fe09237X
6 CC-B2_PERCH4_180206
Feb 06, 2018 Fish S18-Fe09238X
7 CC-B2_WHITING1_180206
Feb 06, 2018 Fish S18-Fe09240X
8 CC-B2_MCRAB1_180206
Feb 06, 2018 Fish S18-Fe09241X
9 CC-B2_MULLET2_180206
Feb 06, 2018 Fish S18-Fe09242X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 13 of 24
Report Number: 583847-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 8, 2018 3:03 PMAddress: Level 14, 32 Turbot St Report #: 583847 Due: Feb 22, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
10 CC-B2_LUDERICK4_180206
Feb 06, 2018 Fish S18-Fe09243X
11 CC-B2_MULLET1_180206
Feb 06, 2018 Fish S18-Fe09244X
12 CC-B3_LUDERICK4_180206
Feb 06, 2018 Fish S18-Fe09245X
13 CC-B3_BREAM3_180206
Feb 06, 2018 Fish S18-Fe09246X
14 CC-B3_SCRAB1_180206
Feb 06, 2018 Fish S18-Fe09247X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 14 of 24
Report Number: 583847-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 8, 2018 3:03 PMAddress: Level 14, 32 Turbot St Report #: 583847 Due: Feb 22, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
15 CC-B3_WHITING2_180206
Feb 06, 2018 Fish S18-Fe09248X
16 CC-B2_LUDERICK3_180206
Feb 06, 2018 Fish S18-Fe09249X
17 CC-B3_STREVALLY2_180206
Feb 06, 2018 Fish S18-Fe09250X
18 CC-B2_SOUL1_180206
Feb 06, 2018 Fish S18-Fe09251X
19 CC-B2_EPRAWZ1_180206
Feb 06, 2018 Fish S18-Fe09252X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 15 of 24
Report Number: 583847-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 8, 2018 3:03 PMAddress: Level 14, 32 Turbot St Report #: 583847 Due: Feb 22, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
20 CC-B2_BREAM1_180206
Feb 06, 2018 Fish S18-Fe09253X
21 CC-B2_MULLOWAY1_180206
Feb 06, 2018 Fish S18-Fe09254X
22 CC-B2_LUDERICK2_180206
Feb 06, 2018 Fish S18-Fe09255X
23 CC-B3_WHITING3_180206
Feb 06, 2018 Fish S18-Fe09256X
24 CC-B2_PERCH1_180206
Feb 06, 2018 Fish S18-Fe09257X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 16 of 24
Report Number: 583847-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 8, 2018 3:03 PMAddress: Level 14, 32 Turbot St Report #: 583847 Due: Feb 22, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
25 CC-B2_PERCH2_180206
Feb 06, 2018 Fish S18-Fe09566X
Test Counts 25
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 17 of 24
Report Number: 583847-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 18 of 24
Report Number: 583847-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 0.5 0.5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 0.5 0.5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 0.5 0.5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 0.5 0.5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 0.5 0.5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 0.5 0.5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 0.5 0.5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 0.5 0.5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 0.5 0.5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 0.5 0.5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 0.5 0.5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 0.5 0.5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 0.5 0.5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 0.5 0.5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 0.5 0.5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 0.5 0.5 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 0.5 0.5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 0.5 0.5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 0.3 0.3 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 0.5 0.5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 0.3 0.3 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 0.5 0.5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 97 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 95 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 94 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 96 50-150 Pass
Perfluorooctanoic acid (PFOA) % 93 50-150 Pass
Perfluorononanoic acid (PFNA) % 93 50-150 Pass
Perfluorodecanoic acid (PFDA) % 91 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 96 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 96 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 74 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 93 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 19 of 24
Report Number: 583847-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 90 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 90 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 81 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 104 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 90 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 92 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 98 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 91 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 90 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 88 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 94 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 94 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 52 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 93 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 88 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 87 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 53 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe09255 CP % 95 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe09255 CP % 97 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe09255 CP % 103 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe09255 CP % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe09255 CP % 91 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe09255 CP % 92 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe09255 CP % 93 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe09255 CP % 95 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe09255 CP % 95 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe09255 CP % 96 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe09255 CP % 92 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe09255 CP % 91 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe09255 CP % 76 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe09255 CP % 80 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe09255 CP % 99 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe09255 CP % 124 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe09255 CP % 93 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe09255 CP % 93 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 20 of 24
Report Number: 583847-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) S18-Fe09255 CP % 91 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe09255 CP % 89 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe09255 CP % 88 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe09255 CP % 92 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe09255 CP % 103 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe09255 CP % 80 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe09255 CP % 99 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe09255 CP % 98 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe09255 CP % 95 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe09255 CP % 143 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 21 of 24
Report Number: 583847-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe09253 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe09253 CP ug/kg 1.0 0.8 12 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe09253 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 22 of 24
Report Number: 583847-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe09257 CP ug/kg 0.5 0.5 3.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe09257 CP ug/kg 15 15 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe09257 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 23 of 24
Report Number: 583847-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Feb 23, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 24 of 24
Report Number: 583847-S
ABN – 50 005 085 521 e.mail : [email protected] web : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne3-5 Kingston Town CloseOakleigh Vic 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261 Site # 23736
Environmental LaboratoryAir AnalysisWater AnalysisSoil Contamination Analysis
NATA AccreditationStack Emission Sampling & AnalysisTrade Waste Sampling & AnalysisGroundwater Sampling & Analysis
38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience
Sample Receipt AdviceSample Receipt AdviceSample Receipt AdviceSample Receipt Advice
Company name: Aurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty Ltd
Contact name: Georgina KerrProject name: HMAS ALBATROSSProject ID: 251529COC number: Not providedTurn around time: 5 DayDate/Time received: Feb 9, 2018 9:31 AMEurofins | mgt reference: 583978583978583978583978
Sample informationSample informationSample informationSample information
☑ A detailed list of analytes logged into our LIMS, is included in the attached summary table.
☑ All samples have been received as described on the above COC.
☑ COC has been completed correctly.
☑ Attempt to chill was evident.
☑ Appropriately preserved sample containers have been used.
☑ All samples were received in good condition.
☑ Samples have been provided with adequate time to commence analysis in accordance with therelevant holding times.
☑ Appropriate sample containers have been used.
☒ Split sample sent to requested external lab.
☒ Some samples have been subcontracted.
N/A Custody Seals intact (if used).
Contact notesContact notesContact notesContact notes
If you have any questions with respect to these samples please contact:
Ryan Gilbert on Phone : or by e.mail: [email protected]
Results will be delivered electronically via e.mail to Georgina Kerr - .
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Georgina Kerr
Report 583978-S
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 09, 2018
Client Sample IDCC-B3_WHITING4_180207
CC-B3_STREVALLY3_180207
CC-B3_BREAM4_180207
CC-B2_BREAM3_180207
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe10208 S18-Fe10209 S18-Fe10210 S18-Fe10211
Date Sampled Feb 07, 2018 Feb 07, 2018 Feb 07, 2018 Feb 07, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 74 61 63 71
13C5-PFPeA (surr.) 1 % 79 68 68 74
13C5-PFHxA (surr.) 1 % 95 77 76 92
13C4-PFHpA (surr.) 1 % 104 75 71 104
13C8-PFOA (surr.) 1 % 107 81 74 109
13C5-PFNA (surr.) 1 % 96 84 76 98
13C6-PFDA (surr.) 1 % 105 92 82 122
13C2-PFUnDA (surr.) 1 % 80 83 80 110
13C2-PFDoDA (surr.) 1 % 57 93 75 120
13C2-PFTeDA (surr.) 1 % 34 90 64 130
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 70 70 70 84
D3-N-MeFOSA (surr.) 1 % 46 53 59 68
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 12
Report Number: 583978-S
Client Sample IDCC-B3_WHITING4_180207
CC-B3_STREVALLY3_180207
CC-B3_BREAM4_180207
CC-B2_BREAM3_180207
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe10208 S18-Fe10209 S18-Fe10210 S18-Fe10211
Date Sampled Feb 07, 2018 Feb 07, 2018 Feb 07, 2018 Feb 07, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 59 55 55 58
D7-N-MeFOSE (surr.) 1 % 18 39 40 37
D9-N-EtFOSE (surr.) 1 % 52 41 39 58
D5-N-EtFOSAA (surr.) 1 % 98 142 127 153
D3-N-MeFOSAA (surr.) 1 % 103 120 102 155
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N090.8 N092.2 N091.2 0.4
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 94 92 90 93
18O2-PFHxS (surr.) 1 % 97 88 84 97
13C8-PFOS (surr.) 1 % 100 99 91 114
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 93 58 45 97
13C2-6:2 FTS (surr.) 1 % 119 70 48 141
13C2-8:2 FTS (surr.) 1 % 122 96 67 135
Client Sample IDCC-B2_BREAM2_180207
CC-B2_STREVALLY3_180207
Sample Matrix Fish Fish
Eurofins | mgt Sample No. S18-Fe10212 S18-Fe10213
Date Sampled Feb 07, 2018 Feb 07, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 63 59
13C5-PFPeA (surr.) 1 % 63 64
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 12
Report Number: 583978-S
Client Sample IDCC-B2_BREAM2_180207
CC-B2_STREVALLY3_180207
Sample Matrix Fish Fish
Eurofins | mgt Sample No. S18-Fe10212 S18-Fe10213
Date Sampled Feb 07, 2018 Feb 07, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C5-PFHxA (surr.) 1 % 72 73
13C4-PFHpA (surr.) 1 % 69 69
13C8-PFOA (surr.) 1 % 71 73
13C5-PFNA (surr.) 1 % 76 76
13C6-PFDA (surr.) 1 % 83 84
13C2-PFUnDA (surr.) 1 % 77 77
13C2-PFDoDA (surr.) 1 % 85 95
13C2-PFTeDA (surr.) 1 % 97 98
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 68 66
D3-N-MeFOSA (surr.) 1 % 71 47
D5-N-EtFOSA (surr.) 1 % 72 48
D7-N-MeFOSE (surr.) 1 % 49 34
D9-N-EtFOSE (surr.) 1 % 48 35
D5-N-EtFOSAA (surr.) 1 % 132 135
D3-N-MeFOSAA (surr.) 1 % 101 108
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N090.9 N0913
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 86 90
18O2-PFHxS (surr.) 1 % 81 83
13C8-PFOS (surr.) 1 % 87 86
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 43 49
13C2-6:2 FTS (surr.) 1 % 49 53
13C2-8:2 FTS (surr.) 1 % 77 80
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 12
Report Number: 583978-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 09, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 15, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 12
Report Number: 583978-S
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 9, 2018 9:31 AMAddress: Level 14, 32 Turbot St Report #: 583978 Due: Feb 23, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 CC-B3_WHITING4_180207
Feb 07, 2018 Fish S18-Fe10208X
2 CC-B3_STREVALLY3_180207
Feb 07, 2018 Fish S18-Fe10209X
3 CC-B3_BREAM4_180207
Feb 07, 2018 Fish S18-Fe10210X
4 CC-B2_BREAM3_180207
Feb 07, 2018 Fish S18-Fe10211X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 5 of 12
Report Number: 583978-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 9, 2018 9:31 AMAddress: Level 14, 32 Turbot St Report #: 583978 Due: Feb 23, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
5 CC-B2_BREAM2_180207
Feb 07, 2018 Fish S18-Fe10212X
6 CC-B2_STREVALLY3_180207
Feb 07, 2018 Fish S18-Fe10213X
Test Counts 6
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 6 of 12
Report Number: 583978-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 7 of 12
Report Number: 583978-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 0.5 0.5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 0.5 0.5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 0.5 0.5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 0.5 0.5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 0.5 0.5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 0.5 0.5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 0.5 0.5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 0.5 0.5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 0.5 0.5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 0.5 0.5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 0.5 0.5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 0.5 0.5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 0.5 0.5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 0.5 0.5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 0.5 0.5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 0.5 0.5 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 0.5 0.5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 0.5 0.5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 0.3 0.3 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 0.5 0.5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 0.3 0.3 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 0.5 0.5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 101 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 117 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 106 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 107 50-150 Pass
Perfluorooctanoic acid (PFOA) % 103 50-150 Pass
Perfluorononanoic acid (PFNA) % 107 50-150 Pass
Perfluorodecanoic acid (PFDA) % 94 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 109 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 90 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 103 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 8 of 12
Report Number: 583978-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 107 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 100 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 102 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 105 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 95 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 121 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 95 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 91 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 101 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 96 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 104 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 103 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 72 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 95 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 101 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 130 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 64 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe10211 CP % 101 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe10211 CP % 116 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe10211 CP % 104 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe10211 CP % 106 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe10211 CP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe10211 CP % 109 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe10211 CP % 101 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe10211 CP % 99 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe10211 CP % 109 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe10211 CP % 101 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe10211 CP % 111 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe10211 CP % 105 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe10211 CP % 90 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe10211 CP % 85 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe10211 CP % 136 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe10211 CP % 111 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe10211 CP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe10211 CP % 109 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 9 of 12
Report Number: 583978-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) S18-Fe10211 CP % 88 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe10211 CP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe10211 CP % 101 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe10211 CP % 101 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe10211 CP % 97 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe10211 CP % 67 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe10211 CP % 92 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe10211 CP % 97 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe10211 CP % 114 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe10211 CP % 127 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 10 of 12
Report Number: 583978-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe10208 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe10208 CP ug/kg 0.8 0.7 3.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe10208 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 11 of 12
Report Number: 583978-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace N/A
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 12 of 12
Report Number: 583978-S
ABN – 50 005 085 521 e.mail : [email protected] web : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne3-5 Kingston Town CloseOakleigh Vic 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261 Site # 23736
Environmental LaboratoryAir AnalysisWater AnalysisSoil Contamination Analysis
NATA AccreditationStack Emission Sampling & AnalysisTrade Waste Sampling & AnalysisGroundwater Sampling & Analysis
38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience
Sample Receipt AdviceSample Receipt AdviceSample Receipt AdviceSample Receipt Advice
Company name: Aurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty Ltd
Contact name: Georgina KerrProject name: HMAS ALBATROSSProject ID: 251529COC number: Not providedTurn around time: 5 DayDate/Time received: Feb 12, 2018 10:00 AMEurofins | mgt reference: 584352584352584352584352
Sample informationSample informationSample informationSample information
☑ A detailed list of analytes logged into our LIMS, is included in the attached summary table.
☑ All samples have been received as described on the above COC.
☑ COC has been completed correctly.
☑ Attempt to chill was evident.
☑ Appropriately preserved sample containers have been used.
☑ All samples were received in good condition.
☑ Samples have been provided with adequate time to commence analysis in accordance with therelevant holding times.
☑ Appropriate sample containers have been used.
☒ Split sample sent to requested external lab.
☒ Some samples have been subcontracted.
N/A Custody Seals intact (if used).
Contact notesContact notesContact notesContact notes
If you have any questions with respect to these samples please contact:
Ryan Gilbert on Phone : or by e.mail: [email protected]
Results will be delivered electronically via e.mail to Georgina Kerr - .
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Georgina Kerr
Report 584352-S
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 12, 2018
Client Sample IDSR-B1_MULLET4_180208
SR-B1_MULLET3_180208
SR-B1_PERCH1_180208
SR-B1_FMULLET2_180208
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe12608 S18-Fe12609 S18-Fe12610 S18-Fe12611
Date Sampled Feb 08, 2018 Feb 08, 2018 Feb 08, 2018 Feb 08, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 74 74 84 86
13C5-PFPeA (surr.) 1 % 91 83 91 97
13C5-PFHxA (surr.) 1 % 106 103 127 120
13C4-PFHpA (surr.) 1 % 115 114 139 132
13C8-PFOA (surr.) 1 % 116 110 139 131
13C5-PFNA (surr.) 1 % 103 99 120 115
13C6-PFDA (surr.) 1 % 134 123 148 146
13C2-PFUnDA (surr.) 1 % 125 117 133 147
13C2-PFDoDA (surr.) 1 % 148 138 161 153
13C2-PFTeDA (surr.) 1 % 142 121 147 159
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 5.1 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 53 71 68 71
D3-N-MeFOSA (surr.) 1 % 44 53 50 67
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 15
Report Number: 584352-S
Client Sample IDSR-B1_MULLET4_180208
SR-B1_MULLET3_180208
SR-B1_PERCH1_180208
SR-B1_FMULLET2_180208
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe12608 S18-Fe12609 S18-Fe12610 S18-Fe12611
Date Sampled Feb 08, 2018 Feb 08, 2018 Feb 08, 2018 Feb 08, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 18 24 41 42
D7-N-MeFOSE (surr.) 1 % 16 27 126 35
D9-N-EtFOSE (surr.) 1 % 22 31 25 41
D5-N-EtFOSAA (surr.) 1 % 169 170 INT 193
D3-N-MeFOSAA (surr.) 1 % 139 161 149 INT
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N091.6 N091.5 N091.4 N092.3
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 101 91 115 109
18O2-PFHxS (surr.) 1 % 100 90 114 107
13C8-PFOS (surr.) 1 % 121 114 134 135
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 163 139 171 160
13C2-6:2 FTS (surr.) 1 % INT INT INT INT
13C2-8:2 FTS (surr.) 1 % INT INT INT INT
Client Sample IDSR-B1_DFLATHEAD1_180208
SR-B1_MULLET2_180208
SR-B1_FMULLET4_180208
SR-B1_FMULLET3_180208
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe12612 S18-Fe12613 S18-Fe12614 S18-Fe12615
Date Sampled Feb 08, 2018 Feb 08, 2018 Feb 08, 2018 Feb 08, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 82 76 76 75
13C5-PFPeA (surr.) 1 % 88 80 83 75
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 15
Report Number: 584352-S
Client Sample IDSR-B1_DFLATHEAD1_180208
SR-B1_MULLET2_180208
SR-B1_FMULLET4_180208
SR-B1_FMULLET3_180208
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe12612 S18-Fe12613 S18-Fe12614 S18-Fe12615
Date Sampled Feb 08, 2018 Feb 08, 2018 Feb 08, 2018 Feb 08, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C5-PFHxA (surr.) 1 % 112 109 110 103
13C4-PFHpA (surr.) 1 % 126 121 125 121
13C8-PFOA (surr.) 1 % 121 120 126 117
13C5-PFNA (surr.) 1 % 107 108 111 108
13C6-PFDA (surr.) 1 % 112 140 129 126
13C2-PFUnDA (surr.) 1 % 77 126 124 115
13C2-PFDoDA (surr.) 1 % 63 151 133 115
13C2-PFTeDA (surr.) 1 % 51 121 114 90
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 73 70 70 75
D3-N-MeFOSA (surr.) 1 % 48 55 56 58
D5-N-EtFOSA (surr.) 1 % 61 21 41 32
D7-N-MeFOSE (surr.) 1 % 19 14 INT 25
D9-N-EtFOSE (surr.) 1 % 53 27 43 36
D5-N-EtFOSAA (surr.) 1 % 109 191 172 172
D3-N-MeFOSAA (surr.) 1 % 119 165 177 180
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N094.3 N093.4 N092.8 N093.8
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 105 103 103 98
18O2-PFHxS (surr.) 1 % 100 100 103 100
13C8-PFOS (surr.) 1 % 107 130 117 116
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 125 146 130 111
13C2-6:2 FTS (surr.) 1 % 161 INT 194 166
13C2-8:2 FTS (surr.) 1 % 134 INT 179 172
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 15
Report Number: 584352-S
Client Sample ID SR-B1-BASS1-180208
SR-B1_FMULLET1_180208
SR-B1_BASS2_180208
SR-B1_MULLET1_180208
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe12616 S18-Fe12617 S18-Fe12618 S18-Fe12619
Date Sampled Feb 08, 2018 Feb 08, 2018 Feb 08, 2018 Feb 08, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 80 76 78 76
13C5-PFPeA (surr.) 1 % 70 73 71 79
13C5-PFHxA (surr.) 1 % 108 102 100 108
13C4-PFHpA (surr.) 1 % 122 117 111 122
13C8-PFOA (surr.) 1 % 121 118 106 122
13C5-PFNA (surr.) 1 % 100 108 85 110
13C6-PFDA (surr.) 1 % 129 135 102 141
13C2-PFUnDA (surr.) 1 % 106 118 67 127
13C2-PFDoDA (surr.) 1 % 103 127 61 155
13C2-PFTeDA (surr.) 1 % 79 114 47 148
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 79 69 56 71
D3-N-MeFOSA (surr.) 1 % 67 48 45 65
D5-N-EtFOSA (surr.) 1 % 93 38 59 25
D7-N-MeFOSE (surr.) 1 % 23 15 15 17
D9-N-EtFOSE (surr.) 1 % 69 36 48 37
D5-N-EtFOSAA (surr.) 1 % 129 169 89 185
D3-N-MeFOSAA (surr.) 1 % 124 188 89 196
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N095.5 N092.2 N099.4 N092.1
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 101 98 93 102
18O2-PFHxS (surr.) 1 % 100 101 88 100
13C8-PFOS (surr.) 1 % 116 124 91 129
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 15
Report Number: 584352-S
Client Sample ID SR-B1-BASS1-180208
SR-B1_FMULLET1_180208
SR-B1_BASS2_180208
SR-B1_MULLET1_180208
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe12616 S18-Fe12617 S18-Fe12618 S18-Fe12619
Date Sampled Feb 08, 2018 Feb 08, 2018 Feb 08, 2018 Feb 08, 2018
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 116 110 107 137
13C2-6:2 FTS (surr.) 1 % 169 171 141 INT
13C2-8:2 FTS (surr.) 1 % 150 169 117 INT
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 5 of 15
Report Number: 584352-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 12, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 12, 2018 180 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 12, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 20, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 6 of 15
Report Number: 584352-S
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 12, 2018 10:00 AMAddress: Level 14, 32 Turbot St Report #: 584352 Due: Feb 26, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 SR-B1_MULLET4_180208
Feb 08, 2018 Fish S18-Fe12608X
2 SR-B1_MULLET3_180208
Feb 08, 2018 Fish S18-Fe12609X
3 SR-B1_PERCH1_180208
Feb 08, 2018 Fish S18-Fe12610X
4 SR-B1_FMULLET2_180208
Feb 08, 2018 Fish S18-Fe12611X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 7 of 15
Report Number: 584352-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 12, 2018 10:00 AMAddress: Level 14, 32 Turbot St Report #: 584352 Due: Feb 26, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
5 SR-B1_DFLATHEAD1_180208
Feb 08, 2018 Fish S18-Fe12612X
6 SR-B1_MULLET2_180208
Feb 08, 2018 Fish S18-Fe12613X
7 SR-B1_FMULLET4_180208
Feb 08, 2018 Fish S18-Fe12614X
8 SR-B1_FMULLET3_180208
Feb 08, 2018 Fish S18-Fe12615X
9 SR-B1-BASS1-180208
Feb 08, 2018 Fish S18-Fe12616X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 8 of 15
Report Number: 584352-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 12, 2018 10:00 AMAddress: Level 14, 32 Turbot St Report #: 584352 Due: Feb 26, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
10 SR-B1_FMULLET1_180208
Feb 08, 2018 Fish S18-Fe12617X
11 SR-B1_BASS2_180208
Feb 08, 2018 Fish S18-Fe12618X
12 SR-B1_MULLET1_180208
Feb 08, 2018 Fish S18-Fe12619X
Test Counts 12
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 9 of 15
Report Number: 584352-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 10 of 15
Report Number: 584352-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 0.5 0.5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 0.5 0.5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 0.5 0.5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 0.5 0.5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 0.5 0.5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 0.5 0.5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 0.5 0.5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 0.5 0.5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 0.5 0.5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 0.5 0.5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 0.5 0.5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 0.5 0.5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 0.5 0.5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 0.5 0.5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 0.5 0.5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 0.5 0.5 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 0.5 0.5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 0.5 0.5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 0.3 0.3 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 0.5 0.5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 0.3 0.3 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 0.5 0.5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 101 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 117 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 106 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 107 50-150 Pass
Perfluorooctanoic acid (PFOA) % 103 50-150 Pass
Perfluorononanoic acid (PFNA) % 107 50-150 Pass
Perfluorodecanoic acid (PFDA) % 94 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 109 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 90 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 103 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 11 of 15
Report Number: 584352-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 107 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 100 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 102 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 105 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 95 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 121 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 95 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 91 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 101 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 96 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 104 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 103 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 72 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 95 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 101 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 130 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 64 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe12609 CP % 103 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe12609 CP % 112 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe12609 CP % 98 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe12609 CP % 104 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe12609 CP % 99 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe12609 CP % 106 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe12609 CP % 105 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe12609 CP % 90 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe12609 CP % 116 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe12609 CP % 99 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe12609 CP % 120 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe12609 CP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe12609 CP % 133 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe12609 CP % 61 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe12609 CP % 133 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe12609 CP % 112 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe12609 CP % 118 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe12609 CP % 116 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 12 of 15
Report Number: 584352-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) S18-Fe12609 CP % 84 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe12609 CP % 89 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe12609 CP % 101 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe12609 CP % 96 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe12609 CP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe12609 CP % 58 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe12609 CP % 91 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe12609 CP % 81 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe12609 CP % 116 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe12609 CP % 126 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 13 of 15
Report Number: 584352-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe12608 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe12608 CP ug/kg 1.6 1.5 7.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe12608 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 14 of 15
Report Number: 584352-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 15 of 15
Report Number: 584352-S
ABN – 50 005 085 521 e.mail : [email protected] web : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne3-5 Kingston Town CloseOakleigh Vic 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261 Site # 23736
Environmental LaboratoryAir AnalysisWater AnalysisSoil Contamination Analysis
NATA AccreditationStack Emission Sampling & AnalysisTrade Waste Sampling & AnalysisGroundwater Sampling & Analysis
38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience
Sample Receipt AdviceSample Receipt AdviceSample Receipt AdviceSample Receipt Advice
Company name: Aurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty Ltd
Contact name: Georgina KerrProject name: HMAS ALBATROSSProject ID: 251529COC number: Not providedTurn around time: 5 DayDate/Time received: Feb 13, 2018 10:19 AMEurofins | mgt reference: 584460584460584460584460
Sample informationSample informationSample informationSample information
☑ A detailed list of analytes logged into our LIMS, is included in the attached summary table.
☑ All samples have been received as described on the above COC.
☑ COC has been completed correctly.
☑ Attempt to chill was evident.
☑ Appropriately preserved sample containers have been used.
☑ All samples were received in good condition.
☑ Samples have been provided with adequate time to commence analysis in accordance with therelevant holding times.
☑ Appropriate sample containers have been used.
☒ Split sample sent to requested external lab.
☒ Some samples have been subcontracted.
N/A Custody Seals intact (if used).
NotesNotesNotesNotes
SR-B3_TAILOR1_180210 on COC labelled as ..._180209 on sample bag. Please advise if sample names shouldbe updated.
Contact notesContact notesContact notesContact notes
If you have any questions with respect to these samples please contact:
Ryan Gilbert on Phone : or by e.mail: [email protected]
Results will be delivered electronically via e.mail to Georgina Kerr - .
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Georgina Kerr
Report 584460-S
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 13, 2018
Client Sample ID SR_B3_MULLET1_180209
SR_B2_MULLET1_180209
SR_B2_MULLET4_180209
SR_B2_MULLET3_180209
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13483 S18-Fe13484 S18-Fe13485 S18-Fe13486
Date Sampled Feb 09, 2018 Feb 09, 2018 Feb 09, 2018 Feb 09, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 39 71 68 76
13C5-PFPeA (surr.) 1 % 57 74 70 84
13C5-PFHxA (surr.) 1 % 65 76 76 87
13C4-PFHpA (surr.) 1 % 67 72 71 83
13C8-PFOA (surr.) 1 % 70 80 77 88
13C5-PFNA (surr.) 1 % 74 86 82 94
13C6-PFDA (surr.) 1 % 75 90 83 95
13C2-PFUnDA (surr.) 1 % 83 85 88 95
13C2-PFDoDA (surr.) 1 % 109 123 112 131
13C2-PFTeDA (surr.) 1 % 94 97 92 88
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 58 80 75 94
D3-N-MeFOSA (surr.) 1 % 29 39 45 49
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 1 of 21
Report Number: 584460-S
Client Sample ID SR_B3_MULLET1_180209
SR_B2_MULLET1_180209
SR_B2_MULLET4_180209
SR_B2_MULLET3_180209
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13483 S18-Fe13484 S18-Fe13485 S18-Fe13486
Date Sampled Feb 09, 2018 Feb 09, 2018 Feb 09, 2018 Feb 09, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 41 56 63 64
D7-N-MeFOSE (surr.) 1 % 21 35 39 48
D9-N-EtFOSE (surr.) 1 % INT 16 18 19
D5-N-EtFOSAA (surr.) 1 % 108 139 113 150
D3-N-MeFOSAA (surr.) 1 % 91 110 103 113
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N095.3 N098.5 N0922 N0913
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 75 79 77 87
18O2-PFHxS (surr.) 1 % 69 74 75 85
13C8-PFOS (surr.) 1 % 90 93 89 98
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 56 71 71 78
13C2-6:2 FTS (surr.) 1 % 88 85 89 91
13C2-8:2 FTS (surr.) 1 % 133 133 130 136
Client Sample ID SR_B2_MULLET2_180209
SR_B3_BREAM1_180210
SR_B3_MULLET2_180210
SR_B3_HERRING1_180210
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13487 S18-Fe13488 S18-Fe13489 S18-Fe13490
Date Sampled Feb 09, 2018 Feb 10, 2018 Feb 10, 2018 Feb 10, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 63 74 57 49
13C5-PFPeA (surr.) 1 % 72 77 67 56
13C5-PFHxA (surr.) 1 % 77 79 74 55
13C4-PFHpA (surr.) 1 % 70 75 68 47
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 2 of 21
Report Number: 584460-S
Client Sample ID SR_B2_MULLET2_180209
SR_B3_BREAM1_180210
SR_B3_MULLET2_180210
SR_B3_HERRING1_180210
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13487 S18-Fe13488 S18-Fe13489 S18-Fe13490
Date Sampled Feb 09, 2018 Feb 10, 2018 Feb 10, 2018 Feb 10, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C8-PFOA (surr.) 1 % 76 76 74 37
13C5-PFNA (surr.) 1 % 80 79 79 56
13C6-PFDA (surr.) 1 % 85 82 80 61
13C2-PFUnDA (surr.) 1 % 80 78 80 69
13C2-PFDoDA (surr.) 1 % 103 116 104 90
13C2-PFTeDA (surr.) 1 % 89 71 87 92
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 70 91 66 40
D3-N-MeFOSA (surr.) 1 % 38 53 35 24
D5-N-EtFOSA (surr.) 1 % 54 58 54 42
D7-N-MeFOSE (surr.) 1 % 33 40 32 18
D9-N-EtFOSE (surr.) 1 % 13 42 14 17
D5-N-EtFOSAA (surr.) 1 % 110 130 101 74
D3-N-MeFOSAA (surr.) 1 % 103 107 94 67
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N0912 N091.2 N095.4 N098.0
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 78 83 78 66
18O2-PFHxS (surr.) 1 % 73 82 73 57
13C8-PFOS (surr.) 1 % 84 113 99 55
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 74 59 65 69
13C2-6:2 FTS (surr.) 1 % 89 62 93 107
13C2-8:2 FTS (surr.) 1 % 130 89 128 144
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 3 of 21
Report Number: 584460-S
Client Sample ID SR_B2_PERCH1_180209
SR_B2_FMULLET1_180209
SR_B3_TAILOR1_180210
SR_B2_BREAM1_180209
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13491 S18-Fe13492 S18-Fe13493 S18-Fe13494
Date Sampled Feb 09, 2018 Feb 09, 2018 Feb 10, 2018 Feb 09, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 76 69 70 74
13C5-PFPeA (surr.) 1 % 80 71 73 70
13C5-PFHxA (surr.) 1 % 81 75 78 79
13C4-PFHpA (surr.) 1 % 75 73 75 76
13C8-PFOA (surr.) 1 % 76 74 77 77
13C5-PFNA (surr.) 1 % 74 73 77 77
13C6-PFDA (surr.) 1 % 69 75 78 79
13C2-PFUnDA (surr.) 1 % 57 73 79 80
13C2-PFDoDA (surr.) 1 % 48 96 101 109
13C2-PFTeDA (surr.) 1 % 35 68 60 71
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 82 82 88 84
D3-N-MeFOSA (surr.) 1 % 47 48 52 60
D5-N-EtFOSA (surr.) 1 % 46 57 61 65
D7-N-MeFOSE (surr.) 1 % 27 36 39 38
D9-N-EtFOSE (surr.) 1 % 26 31 42 42
D5-N-EtFOSAA (surr.) 1 % 83 111 120 121
D3-N-MeFOSAA (surr.) 1 % 86 98 100 91
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N092.3 N0920 N090.9 N091.3
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 84 82 83 83
18O2-PFHxS (surr.) 1 % 81 80 80 81
13C8-PFOS (surr.) 1 % 101 99 112 113
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 4 of 21
Report Number: 584460-S
Client Sample ID SR_B2_PERCH1_180209
SR_B2_FMULLET1_180209
SR_B3_TAILOR1_180210
SR_B2_BREAM1_180209
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13491 S18-Fe13492 S18-Fe13493 S18-Fe13494
Date Sampled Feb 09, 2018 Feb 09, 2018 Feb 10, 2018 Feb 09, 2018
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 56 54 55 56
13C2-6:2 FTS (surr.) 1 % 59 54 60 59
13C2-8:2 FTS (surr.) 1 % 78 82 89 89
Client Sample ID SR_B3_PERCH1_180210
SR_B2_LUDERICK1_180209
SR_B2_BASS1_180209
SR_B2_GARFISH1_180209
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13495 S18-Fe13496 S18-Fe13497 S18-Fe13498
Date Sampled Feb 10, 2018 Feb 09, 2018 Feb 09, 2018 Feb 09, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 68 73 73 59
13C5-PFPeA (surr.) 1 % 70 77 75 68
13C5-PFHxA (surr.) 1 % 71 76 77 74
13C4-PFHpA (surr.) 1 % 68 76 73 43
13C8-PFOA (surr.) 1 % 67 71 71 51
13C5-PFNA (surr.) 1 % 65 71 71 65
13C6-PFDA (surr.) 1 % 65 74 72 75
13C2-PFUnDA (surr.) 1 % 69 78 72 73
13C2-PFDoDA (surr.) 1 % 88 112 82 108
13C2-PFTeDA (surr.) 1 % 56 70 41 101
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 5 of 21
Report Number: 584460-S
Client Sample ID SR_B3_PERCH1_180210
SR_B2_LUDERICK1_180209
SR_B2_BASS1_180209
SR_B2_GARFISH1_180209
Sample Matrix Fish Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13495 S18-Fe13496 S18-Fe13497 S18-Fe13498
Date Sampled Feb 10, 2018 Feb 09, 2018 Feb 09, 2018 Feb 09, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 77 88 80 41
D3-N-MeFOSA (surr.) 1 % 53 50 57 36
D5-N-EtFOSA (surr.) 1 % 58 61 60 50
D7-N-MeFOSE (surr.) 1 % 36 40 32 14
D9-N-EtFOSE (surr.) 1 % 36 29 34 19
D5-N-EtFOSAA (surr.) 1 % 94 117 98 97
D3-N-MeFOSAA (surr.) 1 % 79 100 87 75
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg < 0.3 < 0.3 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N093.6 N091.2 N095.3 N092.0
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 76 82 78 74
18O2-PFHxS (surr.) 1 % 69 75 73 61
13C8-PFOS (surr.) 1 % 90 104 95 86
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 51 57 60 74
13C2-6:2 FTS (surr.) 1 % 50 68 62 82
13C2-8:2 FTS (surr.) 1 % 70 86 84 147
Client Sample ID SR_B3_MACRAB1_180210
SR_B3_SMULLET1_180210
SR_B3_BASS1_180210
Sample Matrix Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13499 S18-Fe13500 S18-Fe13501
Date Sampled Feb 10, 2018 Feb 10, 2018 Feb 10, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluoropentanoic acid (PFPeA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluorohexanoic acid (PFHxA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluoroheptanoic acid (PFHpA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluorooctanoic acid (PFOA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluorononanoic acid (PFNA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluorodecanoic acid (PFDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluoroundecanoic acid (PFUnA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluorododecanoic acid (PFDoA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 6 of 21
Report Number: 584460-S
Client Sample ID SR_B3_MACRAB1_180210
SR_B3_SMULLET1_180210
SR_B3_BASS1_180210
Sample Matrix Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13499 S18-Fe13500 S18-Fe13501
Date Sampled Feb 10, 2018 Feb 10, 2018 Feb 10, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorotridecanoic acid (PFTrDA)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluorotetradecanoic acid (PFTeDA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
13C4-PFBA (surr.) 1 % 49 66 76
13C5-PFPeA (surr.) 1 % 60 61 71
13C5-PFHxA (surr.) 1 % 24 67 81
13C4-PFHpA (surr.) 1 % 34 62 77
13C8-PFOA (surr.) 1 % 62 62 79
13C5-PFNA (surr.) 1 % 83 70 76
13C6-PFDA (surr.) 1 % 86 71 79
13C2-PFUnDA (surr.) 1 % 88 74 81
13C2-PFDoDA (surr.) 1 % 123 103 100
13C2-PFTeDA (surr.) 1 % 75 80 61
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
13C8-FOSA (surr.) 1 % 57 67 88
D3-N-MeFOSA (surr.) 1 % 26 44 61
D5-N-EtFOSA (surr.) 1 % 32 61 60
D7-N-MeFOSE (surr.) 1 % 13 40 36
D9-N-EtFOSE (surr.) 1 % 13 25 36
D5-N-EtFOSAA (surr.) 1 % 107 107 112
D3-N-MeFOSAA (surr.) 1 % 97 82 96
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluoropentanesulfonic acid (PFPeS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluorohexanesulfonic acid (PFHxS)N11 0.3 ug/kg 1.8 < 0.3 < 0.3
Perfluoroheptanesulfonic acid (PFHpS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5
Perfluorooctanesulfonic acid (PFOS)N11 0.3 ug/kg N092.9 N0910 N096.7
Perfluorodecanesulfonic acid (PFDS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5
13C3-PFBS (surr.) 1 % 32 70 86
18O2-PFHxS (surr.) 1 % 73 63 81
13C8-PFOS (surr.) 1 % 105 84 103
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.5 ug/kg < 0.5 < 0.5 < 0.5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.5 ug/kg < 0.5 < 0.5 < 0.5
13C2-4:2 FTS (surr.) 1 % 34 64 62
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 7 of 21
Report Number: 584460-S
Client Sample ID SR_B3_MACRAB1_180210
SR_B3_SMULLET1_180210
SR_B3_BASS1_180210
Sample Matrix Fish Fish Fish
Eurofins | mgt Sample No. S18-Fe13499 S18-Fe13500 S18-Fe13501
Date Sampled Feb 10, 2018 Feb 10, 2018 Feb 10, 2018
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
13C2-6:2 FTS (surr.) 1 % 69 86 66
13C2-8:2 FTS (surr.) 1 % 100 119 89
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 8 of 21
Report Number: 584460-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 13, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 13, 2018 180 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 13, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 20, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 9 of 21
Report Number: 584460-S
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 13, 2018 10:19 AMAddress: Level 14, 32 Turbot St Report #: 584460 Due: Feb 27, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 SR_B3_MULLET1_180209
Feb 09, 2018 Fish S18-Fe13483 X
2 SR_B2_MULLET1_180209
Feb 09, 2018 Fish S18-Fe13484 X
3 SR_B2_MULLET4_180209
Feb 09, 2018 Fish S18-Fe13485 X
4 SR_B2_MULLET3_180209
Feb 09, 2018 Fish S18-Fe13486 X
5 SR_B2_MULLET2_180209
Feb 09, 2018 Fish S18-Fe13487 X
6 SR_B3_BREA Feb 10, 2018 Fish S18-Fe13488 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 10 of 21
Report Number: 584460-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 13, 2018 10:19 AMAddress: Level 14, 32 Turbot St Report #: 584460 Due: Feb 27, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
M1_180210
7 SR_B3_MULLET2_180210
Feb 10, 2018 Fish S18-Fe13489 X
8 SR_B3_HERRING1_180210
Feb 10, 2018 Fish S18-Fe13490 X
9 SR_B2_PERCH1_180209
Feb 09, 2018 Fish S18-Fe13491 X
10 SR_B2_FMULLET1_180209
Feb 09, 2018 Fish S18-Fe13492 X
11 SR_B3_TAILOR1_180210
Feb 10, 2018 Fish S18-Fe13493 X
12 SR_B2_BREAM1_180209
Feb 09, 2018 Fish S18-Fe13494 X
13 SR_B3_PERC Feb 10, 2018 Fish S18-Fe13495 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 11 of 21
Report Number: 584460-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 13, 2018 10:19 AMAddress: Level 14, 32 Turbot St Report #: 584460 Due: Feb 27, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
H1_180210
14 SR_B2_LUDERICK1_180209
Feb 09, 2018 Fish S18-Fe13496X
15 SR_B2_BASS1_180209
Feb 09, 2018 Fish S18-Fe13497 X
16 SR_B2_GARFISH1_180209
Feb 09, 2018 Fish S18-Fe13498 X
17 SR_B3_MACRAB1_180210
Feb 10, 2018 Fish S18-Fe13499 X
18 SR_B3_SMULLET1_180210
Feb 10, 2018 Fish S18-Fe13500 X
19 SR_B3_BASS1_180210
Feb 10, 2018 Fish S18-Fe13501 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 12 of 21
Report Number: 584460-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 13, 2018 10:19 AMAddress: Level 14, 32 Turbot St Report #: 584460 Due: Feb 27, 2018
Brisbane Phone: 07 3173 8000 Priority: 10 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
Test Counts 19
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Page 13 of 21
Report Number: 584460-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 14 of 21
Report Number: 584460-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 0.5 0.5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 0.5 0.5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 0.5 0.5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 0.5 0.5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 0.5 0.5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 0.5 0.5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 0.5 0.5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 0.5 0.5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 0.5 0.5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 0.5 0.5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 0.5 0.5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 0.5 0.5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 0.5 0.5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 0.5 0.5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 0.5 0.5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 0.5 0.5 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 0.5 0.5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 0.5 0.5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 0.3 0.3 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 0.5 0.5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 0.3 0.3 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 0.5 0.5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 0.5 0.5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 87 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 101 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 106 50-150 Pass
Perfluorooctanoic acid (PFOA) % 105 50-150 Pass
Perfluorononanoic acid (PFNA) % 104 50-150 Pass
Perfluorodecanoic acid (PFDA) % 124 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 108 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 87 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 102 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 15 of 21
Report Number: 584460-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 100 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 99 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 100 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 108 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 97 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 103 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 102 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 97 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 101 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 107 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 62 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 109 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 111 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 63 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe13491 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe13491 CP % 94 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe13491 CP % 103 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe13491 CP % 104 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe13491 CP % 108 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe13491 CP % 106 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe13491 CP % 108 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe13491 CP % 104 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe13491 CP % 108 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe13491 CP % 96 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe13491 CP % 107 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe13491 CP % 101 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe13491 CP % 104 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe13491 CP % 101 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe13491 CP % 110 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe13491 CP % 99 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe13491 CP % 105 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe13491 CP % 102 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 16 of 21
Report Number: 584460-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) S18-Fe13491 CP % 105 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe13491 CP % 99 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe13491 CP % 102 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe13491 CP % 105 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe13491 CP % 100 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe13491 CP % 92 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe13491 CP % 115 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe13491 CP % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe13491 CP % 100 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe13491 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S18-Fe13496 CP % 102 50-150 Pass
Perfluoropentanoic acid (PFPeA) S18-Fe13496 CP % 94 50-150 Pass
Perfluorohexanoic acid (PFHxA) S18-Fe13496 CP % 102 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe13496 CP % 103 50-150 Pass
Perfluorooctanoic acid (PFOA) S18-Fe13496 CP % 105 50-150 Pass
Perfluorononanoic acid (PFNA) S18-Fe13496 CP % 107 50-150 Pass
Perfluorodecanoic acid (PFDA) S18-Fe13496 CP % 104 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe13496 CP % 104 50-150 Pass
Perfluorododecanoic acid (PFDoA) S18-Fe13496 CP % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe13496 CP % 93 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe13496 CP % 104 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S18-Fe13496 CP % 101 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe13496 CP % 93 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe13496 CP % 99 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe13496 CP % 113 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe13496 CP % 115 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe13496 CP % 103 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe13496 CP % 100 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S18-Fe13496 CP % 106 50-150 Pass
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 17 of 21
Report Number: 584460-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoropentanesulfonic acid(PFPeS) S18-Fe13496 CP % 101 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe13496 CP % 105 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe13496 CP % 102 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe13496 CP % 104 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe13496 CP % 91 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe13496 CP % 108 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe13496 CP % 108 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe13496 CP % 97 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe13496 CP % 117 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 18 of 21
Report Number: 584460-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe13488 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe13488 CP ug/kg 1.2 1.2 1.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe13488 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanoic acid (PFOA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorononanoic acid (PFNA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorodecanoic acid (PFDA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 19 of 21
Report Number: 584460-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S18-Fe13494 CP ug/kg < 0.3 < 0.3 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S18-Fe13494 CP ug/kg 1.3 1.4 9.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S18-Fe13494 CP ug/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 20 of 21
Report Number: 584460-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Feb 27, 2018
Eurofins | mgt Unit F3, Building F, 16 Mars Road, Lane Cove West, NSW, Australia, 2066
ABN : 50 005 085 521 Telephone: +61 2 9900 8400
Page 21 of 21
Report Number: 584460-S
ABN – 50 005 085 521 e.mail : [email protected] web : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne3-5 Kingston Town CloseOakleigh Vic 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261 Site # 23736
Environmental LaboratoryAir AnalysisWater AnalysisSoil Contamination Analysis
NATA AccreditationStack Emission Sampling & AnalysisTrade Waste Sampling & AnalysisGroundwater Sampling & Analysis
38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience38 Years of Environmental Analysis & Experience
Sample Receipt AdviceSample Receipt AdviceSample Receipt AdviceSample Receipt Advice
Company name: Aurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty LtdAurecon Australia (BRIS) Pty Ltd
Contact name: Georgina KerrProject name: HMAS ALBATROSSProject ID: 251529COC number: Not providedTurn around time: 5 DayDate/Time received: Feb 14, 2018 10:40 AMEurofins | mgt reference: 584697584697584697584697
Sample informationSample informationSample informationSample information
☑ A detailed list of analytes logged into our LIMS, is included in the attached summary table.
☑ All samples have been received as described on the above COC.
☑ COC has been completed correctly.
☑ Attempt to chill was evident.
☑ Appropriately preserved sample containers have been used.
☑ All samples were received in good condition.
☑ Samples have been provided with adequate time to commence analysis in accordance with therelevant holding times.
☑ Appropriate sample containers have been used.
☑ Sample containers for volatile analysis received with zero headspace.
☒ Split sample sent to requested external lab.
☒ Some samples have been subcontracted.
N/A Custody Seals intact (if used).
Contact notesContact notesContact notesContact notes
If you have any questions with respect to these samples please contact:
Ryan Gilbert on Phone : or by e.mail: [email protected]
Results will be delivered electronically via e.mail to Georgina Kerr - .
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Georgina Kerr
Report 584697-S
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 14, 2018
Client Sample ID SED-SR-B1-180209
SED-SR-B2-180209
SED-SR-B3-180209
Sample Matrix Soil Soil Soil
Eurofins | mgt Sample No. B18-Fe14883 B18-Fe14884 B18-Fe14885
Date Sampled Feb 09, 2018 Feb 09, 2018 Feb 09, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg < 5 < 5 < 5
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5
Perfluorooctanoic acid (PFOA)N11 5 ug/kg < 5 < 5 < 5
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA)N15 5 ug/kg < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 140 119 119
13C5-PFPeA (surr.) 1 % 106 96 99
13C5-PFHxA (surr.) 1 % 123 111 116
13C4-PFHpA (surr.) 1 % 130 119 127
13C8-PFOA (surr.) 1 % 108 101 105
13C5-PFNA (surr.) 1 % 94 87 98
13C6-PFDA (surr.) 1 % 121 111 116
13C2-PFUnDA (surr.) 1 % 149 136 139
13C2-PFDoDA (surr.) 1 % 129 116 128
13C2-PFTeDA (surr.) 1 % 121 109 125
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 127 109 125
D3-N-MeFOSA (surr.) 1 % 128 117 132
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 11
Report Number: 584697-S
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID SED-SR-B1-180209
SED-SR-B2-180209
SED-SR-B3-180209
Sample Matrix Soil Soil Soil
Eurofins | mgt Sample No. B18-Fe14883 B18-Fe14884 B18-Fe14885
Date Sampled Feb 09, 2018 Feb 09, 2018 Feb 09, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 104 97 107
D7-N-MeFOSE (surr.) 1 % 75 73 78
D9-N-EtFOSE (surr.) 1 % 100 91 99
D5-N-EtFOSAA (surr.) 1 % 82 73 84
D3-N-MeFOSAA (surr.) 1 % 156 137 148
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg < 5 < 5 < 5
Perfluoropentanesulfonic acid (PFPeS)N15 5 ug/kg < 5 < 5 < 5
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg < 5 < 5 < 5
Perfluoroheptanesulfonic acid (PFHpS)N15 5 ug/kg < 5 < 5 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg < 5 < 5 < 5
Perfluorodecanesulfonic acid (PFDS)N15 5 ug/kg < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 100 93 98
18O2-PFHxS (surr.) 1 % 115 109 116
13C8-PFOS (surr.) 1 % 123 112 129
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 5 ug/kg < 5 < 5 < 5
13C2-4:2 FTS (surr.) 1 % 99 80 74
13C2-6:2 FTS (surr.) 1 % 85 81 75
13C2-8:2 FTS (surr.) 1 % 92 83 90
PFASs Summations
Sum (PFHxS + PFOS)* 5 ug/kg < 5 < 5 < 5
Sum of US EPA PFAS (PFOS + PFOA)* 5 ug/kg < 5 < 5 < 5
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 5 ug/kg < 5 < 5 < 5
Sum of WA DER PFAS (n=10)* 10 ug/kg < 10 < 10 < 10
Sum of PFASs (n=28)* 50 ug/kg < 50 < 50 < 50
% Moisture 1 % 21 23 25
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 11
Report Number: 584697-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs) - Ultra Trace
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 15, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 15, 2018 180 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 15, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 15, 2018 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
% Moisture Brisbane Feb 14, 2018 14 Day
- Method: LTM-GEN-7080 Moisture
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 11
Report Number: 584697-S
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 14, 2018 10:40 AMAddress: Level 14, 32 Turbot St Report #: 584697 Due: Feb 21, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
pH Phosphate total (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 SW-SR-B1-180209
Feb 09, 2018 Water B18-Fe14880 X X X X X X X X X
2 SW-SR-B2-180209
Feb 09, 2018 Water B18-Fe14881 X X X X X X X X X
3 SW-SR-B3-180209
Feb 09, 2018 Water B18-Fe14882 X X X X X X X X X
4 SED-SR-B1-180209
Feb 09, 2018 Soil B18-Fe14883 X X
5 SED-SR-B2-180209
Feb 09, 2018 Soil B18-Fe14884 X X
6 SED-SR-B3- Feb 09, 2018 Soil B18-Fe14885 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 11
Report Number: 584697-S
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 14, 2018 10:40 AMAddress: Level 14, 32 Turbot St Report #: 584697 Due: Feb 21, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
pH Phosphate total (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
180209
Test Counts 3 3 3 3 3 3 3 3 3 3 3
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 11
Report Number: 584697-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 11
Report Number: 584697-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 5 5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 5 5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 5 5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 5 5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 5 5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 5 5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 5 5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 5 5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 5 5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 5 5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 5 5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 5 5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 5 5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 5 5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 5 5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 5 5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 10 10 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 10 10 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 5 5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 5 5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 5 5 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 5 5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 5 5 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 5 5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 5 5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 10 10 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 5 5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 5 5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 117 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 100 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 103 50-150 Pass
Perfluorooctanoic acid (PFOA) % 89 50-150 Pass
Perfluorononanoic acid (PFNA) % 99 50-150 Pass
Perfluorodecanoic acid (PFDA) % 83 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 93 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 129 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 118 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 11
Report Number: 584697-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 76 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 73 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 92 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 109 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 88 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 105 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 101 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 92 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 80 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 103 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 117 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 94 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 92 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 93 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 118 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 115 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M18-Fe17057 NCP % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) M18-Fe17057 NCP % 118 50-150 Pass
Perfluorohexanoic acid (PFHxA) M18-Fe17057 NCP % 98 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe17057 NCP % 107 50-150 Pass
Perfluorooctanoic acid (PFOA) M18-Fe17057 NCP % 92 50-150 Pass
Perfluorononanoic acid (PFNA) M18-Fe17057 NCP % 105 50-150 Pass
Perfluorodecanoic acid (PFDA) M18-Fe17057 NCP % 84 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M18-Fe17057 NCP % 92 50-150 Pass
Perfluorododecanoic acid (PFDoA) M18-Fe17057 NCP % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe17057 NCP % 131 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe17057 NCP % 119 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M18-Fe17057 NCP % 74 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe17057 NCP % 77 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe17057 NCP % 87 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe17057 NCP % 113 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe17057 NCP % 89 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe17057 NCP % 102 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe17057 NCP % 103 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 11
Report Number: 584697-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) M18-Fe17057 NCP % 92 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe17057 NCP % 87 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M18-Fe17057 NCP % 96 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe17057 NCP % 114 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M18-Fe17057 NCP % 93 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe17057 NCP % 94 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M18-Fe17057 NCP % 98 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M18-Fe17057 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M18-Fe17057 NCP % 110 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M18-Fe17057 NCP % 124 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe20421 NCP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe20421 NCP ug/kg < 10 < 10 <1 30% Pass
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 11
Report Number: 584697-S
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M18-Fe20421 NCP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M18-Fe20421 NCP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
% Moisture M17-De24313 NCP % 23 24 1.0 30% Pass
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 11
Report Number: 584697-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code Description
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Authorised By
Ryan Gilbert Analytical Services Manager
Jonathon Angell Senior Analyst-Inorganic (QLD)
Jonathon Angell Senior Analyst-Organic (QLD)
Myles Clark Senior Analyst-Metal (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 11
Report Number: 584697-S
Certificate of Analysis
Aurecon Australia (BRIS) Pty Ltd
Level 14, 32 Turbot St
Brisbane
QLD 4001
Attention: Georgina Kerr
Report 584697-W
Project name HMAS ALBATROSS
Project ID 251529
Received Date Feb 14, 2018
Client Sample ID SW-SR-B1-180209
SW-SR-B2-180209
SW-SR-B3-180209
Sample Matrix Water Water Water
Eurofins | mgt Sample No. B18-Fe14880 B18-Fe14881 B18-Fe14882
Date Sampled Feb 09, 2018 Feb 09, 2018 Feb 09, 2018
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.005 ug/L < 0.005 < 0.005 < 0.005
Perfluoropentanoic acid (PFPeA)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluorohexanoic acid (PFHxA)N11 0.001 ug/L < 0.001 N090.001 N090.001
Perfluoroheptanoic acid (PFHpA)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluorooctanoic acid (PFOA)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluorononanoic acid (PFNA)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluorodecanoic acid (PFDA)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluoroundecanoic acid (PFUnA)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluorododecanoic acid (PFDoA)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluorotridecanoic acid (PFTrDA)N15 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluorotetradecanoic acid (PFTeDA)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
13C4-PFBA (surr.) 1 % 41 36 34
13C5-PFPeA (surr.) 1 % 67 75 92
13C5-PFHxA (surr.) 1 % 79 83 85
13C4-PFHpA (surr.) 1 % 92 95 95
13C8-PFOA (surr.) 1 % 93 95 94
13C5-PFNA (surr.) 1 % 81 83 82
13C6-PFDA (surr.) 1 % 90 91 84
13C2-PFUnDA (surr.) 1 % 79 75 69
13C2-PFDoDA (surr.) 1 % 70 70 79
13C2-PFTeDA (surr.) 1 % 39 42 56
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.005 ug/L < 0.005 < 0.005 < 0.005
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.005 ug/L < 0.005 < 0.005 < 0.005
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.005 ug/L < 0.005 < 0.005 < 0.005
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.005 ug/L < 0.005 < 0.005 < 0.005
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.005 ug/L < 0.005 < 0.005 < 0.005
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.005 ug/L < 0.005 < 0.005 < 0.005
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.005 ug/L < 0.005 < 0.005 < 0.005
13C8-FOSA (surr.) 1 % 72 71 79
D3-N-MeFOSA (surr.) 1 % 54 52 77
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 13
Report Number: 584697-W
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID SW-SR-B1-180209
SW-SR-B2-180209
SW-SR-B3-180209
Sample Matrix Water Water Water
Eurofins | mgt Sample No. B18-Fe14880 B18-Fe14881 B18-Fe14882
Date Sampled Feb 09, 2018 Feb 09, 2018 Feb 09, 2018
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 46 51 73
D7-N-MeFOSE (surr.) 1 % 39 31 52
D9-N-EtFOSE (surr.) 1 % 46 44 60
D5-N-EtFOSAA (surr.) 1 % 85 90 76
D3-N-MeFOSAA (surr.) 1 % 83 86 77
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluoropentanesulfonic acid (PFPeS)N15 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluorohexanesulfonic acid (PFHxS)N11 0.001 ug/L < 0.001 N090.003 N090.003
Perfluoroheptanesulfonic acid (PFHpS)N15 0.001 ug/L < 0.001 < 0.001 < 0.001
Perfluorooctanesulfonic acid (PFOS)N11 0.0001 ug/L < 0.0001 N090.0027 N090.0027
Perfluorodecanesulfonic acid (PFDS)N15 0.001 ug/L < 0.001 < 0.001 < 0.001
13C3-PFBS (surr.) 1 % 92 94 93
18O2-PFHxS (surr.) 1 % 103 103 100
13C8-PFOS (surr.) 1 % 114 112 108
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.005 ug/L < 0.005 < 0.005 < 0.005
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.001 ug/L < 0.001 < 0.001 < 0.001
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS)N15 0.001 ug/L < 0.001 < 0.001 < 0.001
13C2-4:2 FTS (surr.) 1 % 111 114 114
13C2-6:2 FTS (surr.) 1 % 191 188 183
13C2-8:2 FTS (surr.) 1 % 164 155 141
PFASs Summations
Sum (PFHxS + PFOS)* 0.001 ug/L < 0.001 0.0057 0.0057
Sum of US EPA PFAS (PFOS + PFOA)* 0.001 ug/L < 0.001 0.0027 0.0027
Sum of enHealth PFAS (PFHxS + PFOS + PFOA)* 0.001 ug/L < 0.001 0.0057 0.0057
Sum of WA DER PFAS (n=10)* 0.005 ug/L < 0.005 0.0067 0.0067
Sum of PFASs (n=28)* 0.005 ug/L < 0.005 0.0067 0.0067
Ammonia (as N) 0.01 mg/L < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm 520 9100 22000
Nitrate & Nitrite (as N) 0.05 mg/L < 0.05 < 0.05 < 0.05
Nitrate (as N) 0.02 mg/L < 0.02 < 0.02 < 0.02
Nitrite (as N) 0.02 mg/L < 0.02 < 0.02 < 0.02
Organic Nitrogen (as N) 0.2 mg/L 0.33 0.28 0.36
pH 0.1 pH Units 7.8 7.7 7.8
Phosphate total (as P) 0.05 mg/L < 0.05 < 0.05 < 0.05
Suspended Solids 1 mg/L 7.9 5.5 11
Total Dissolved Solids 10 mg/L 200 3700 11000
Total Kjeldahl Nitrogen (as N) 0.2 mg/L 0.3 0.3 0.4
Total Nitrogen (as N) 0.2 mg/L 0.33 0.28 0.36
Total Organic Carbon 5 mg/L < 5 19 < 5
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 13
Report Number: 584697-W
Client Sample ID SW-SR-B1-180209
SW-SR-B2-180209
SW-SR-B3-180209
Sample Matrix Water Water Water
Eurofins | mgt Sample No. B18-Fe14880 B18-Fe14881 B18-Fe14882
Date Sampled Feb 09, 2018 Feb 09, 2018 Feb 09, 2018
Test/Reference LOR Unit
Heavy Metals
Arsenic 0.001 mg/L < 0.005 < 0.005 < 0.005
Cadmium 0.0002 mg/L < 0.001 < 0.001 < 0.001
Chromium 0.001 mg/L < 0.005 < 0.005 < 0.005
Copper 0.001 mg/L < 0.005 < 0.005 < 0.005
Lead 0.001 mg/L < 0.005 < 0.005 < 0.005
Mercury 0.0001 mg/L < 0.0005 < 0.0005 < 0.0005
Nickel 0.001 mg/L < 0.005 < 0.005 < 0.005
Zinc 0.005 mg/L < 0.025 < 0.025 < 0.025
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 13
Report Number: 584697-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs) - Ultra Trace
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Feb 14, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Feb 14, 2018 14 Day
- Method: LTM-ORG-2100 Determination of Per- and Polyfluoro Alkyl Substances (PFAS) in Aqueous and Soil Samples by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Feb 14, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Feb 14, 2018 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Nitrogens (speciated)
Ammonia (as N) Melbourne Feb 15, 2018 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Nitrate & Nitrite (as N) Melbourne Feb 15, 2018 28 Day
- Method: APHA 4500-NO3/NO2 Nitrate-Nitrite Nitrogen by FIA
Nitrate (as N) Melbourne Feb 15, 2018 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Nitrite (as N) Melbourne Feb 15, 2018 2 Day
- Method: APHA 4500-NO2 Nitrite Nitrogen by FIA
Organic Nitrogen (as N) Melbourne Feb 14, 2018 7 Day
- Method: APHA 4500 Organic Nitrogen (N)
Total Kjeldahl Nitrogen (as N) Melbourne Feb 15, 2018 7 Day
- Method: APHA 4500 TKN
Conductivity (at 25°C) Melbourne Feb 15, 2018 28 Day
- Method: LTM-INO-4030
pH Melbourne Feb 15, 2018 0 Hours
- Method: LTM-GEN-7090 pH in water by ISE
Phosphate total (as P) Melbourne Feb 15, 2018 28 Day
- Method: APHA 4500-P E. Phosphorous
Suspended Solids Melbourne Feb 15, 2018 7 Days
- Method: LTM-INO-4070 Analysis of Suspended Solids in Water by Gravimetry
Total Dissolved Solids Melbourne Feb 15, 2018 7 Day
- Method: LTM-INO-4170 Total Dissolved Solids in Water
Total Organic Carbon Melbourne Feb 16, 2018 28 Day
- Method: APHA 5310B Total Organic Carbon
Metals M8 Melbourne Feb 15, 2018 28 Days
- Method: LTM-MET-3040 Metals in Waters by ICP-MS
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 13
Report Number: 584697-W
.Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 14, 2018 10:40 AMAddress: Level 14, 32 Turbot St Report #: 584697 Due: Feb 21, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
pH Phosphate total (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 SW-SR-B1-180209
Feb 09, 2018 Water B18-Fe14880 X X X X X X X X X
2 SW-SR-B2-180209
Feb 09, 2018 Water B18-Fe14881 X X X X X X X X X
3 SW-SR-B3-180209
Feb 09, 2018 Water B18-Fe14882 X X X X X X X X X
4 SED-SR-B1-180209
Feb 09, 2018 Soil B18-Fe14883 X X
5 SED-SR-B2-180209
Feb 09, 2018 Soil B18-Fe14884 X X
6 SED-SR-B3- Feb 09, 2018 Soil B18-Fe14885 X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 13
Report Number: 584697-W
Company Name: Aurecon Australia (BRIS) Pty Ltd Order No.: 251529 Received: Feb 14, 2018 10:40 AMAddress: Level 14, 32 Turbot St Report #: 584697 Due: Feb 21, 2018
Brisbane Phone: 07 3173 8000 Priority: 5 DayQLD 4001 Fax: +61 7 3173 8001 Contact Name: Georgina Kerr
Project Name: HMAS ALBATROSSProject ID: 251529
Eurofins | mgt Analytical Services Manager : Ryan Gilbert
Sample Detail
Conductivity (at 25°C
)
pH Phosphate total (as P
)
Suspended S
olids
Total D
issolved Solids
Total O
rganic Carbon
Metals M
8
Nitrogens (speciated)
Moisture S
et
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss) - U
ltra Trace
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X
Perth Laboratory - NATA Site # 23736
180209
Test Counts 3 3 3 3 3 3 3 3 3 3 3
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 13
Report Number: 584697-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 13
Report Number: 584697-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.005 0.005 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.001 0.001 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.001 0.001 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.001 0.001 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.001 0.001 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.001 0.001 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.001 0.001 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.001 0.001 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.001 0.001 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.001 0.001 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.001 0.001 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.005 0.005 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.005 0.005 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.005 0.005 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.005 0.005 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.005 0.005 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.005 0.005 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.005 0.005 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.001 0.001 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.001 0.001 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.001 0.001 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.001 0.001 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.0001 0.0001 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.001 0.001 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.001 0.001 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.005 0.005 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.001 0.001 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.001 0.001 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Nitrate & Nitrite (as N) mg/L < 0.05 0.05 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Nitrite (as N) mg/L < 0.02 0.02 Pass
Phosphate total (as P) mg/L < 0.05 0.05 Pass
Suspended Solids mg/L < 1 1 Pass
Total Dissolved Solids mg/L < 10 10 Pass
Total Kjeldahl Nitrogen (as N) mg/L < 0.2 0.2 Pass
Total Organic Carbon mg/L < 5 5 Pass
Method Blank
Heavy Metals
Arsenic mg/L < 0.001 0.001 Pass
Cadmium mg/L < 0.0002 0.0002 Pass
Lead mg/L < 0.001 0.001 Pass
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 13
Report Number: 584697-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Mercury mg/L < 0.0001 0.0001 Pass
Nickel mg/L < 0.001 0.001 Pass
Zinc mg/L < 0.005 0.005 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 92 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 96 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 98 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 90 50-150 Pass
Perfluorooctanoic acid (PFOA) % 90 50-150 Pass
Perfluorononanoic acid (PFNA) % 88 50-150 Pass
Perfluorodecanoic acid (PFDA) % 82 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 88 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 94 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 106 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 76 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 80 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 88 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 78 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 78 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 76 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 82 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 80 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 82 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 106 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 86 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 100 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 86 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 80 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 88 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 92 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 102 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 102 70-130 Pass
Nitrate & Nitrite (as N) % 105 70-130 Pass
Nitrate (as N) % 104 70-130 Pass
Nitrite (as N) % 110 70-130 Pass
Phosphate total (as P) % 94 70-130 Pass
Suspended Solids % 93 70-130 Pass
Total Dissolved Solids % 85 70-130 Pass
Total Kjeldahl Nitrogen (as N) % 101 70-130 Pass
Total Organic Carbon % 98 70-130 Pass
LCS - % Recovery
Heavy Metals
Arsenic % 101 80-120 Pass
Cadmium % 96 80-120 Pass
Chromium % 97 80-120 Pass
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 13
Report Number: 584697-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Copper % 94 80-120 Pass
Lead % 97 80-120 Pass
Mercury % 86 75-125 Pass
Nickel % 96 80-120 Pass
Zinc % 99 80-120 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B18-Fe14895 NCP % 93 50-150 Pass
Perfluoropentanoic acid (PFPeA) B18-Fe14895 NCP % 100 50-150 Pass
Perfluorohexanoic acid (PFHxA) B18-Fe14895 NCP % 91 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B18-Fe14895 NCP % 94 50-150 Pass
Perfluorooctanoic acid (PFOA) B18-Fe14895 NCP % 93 50-150 Pass
Perfluorononanoic acid (PFNA) B18-Fe14895 NCP % 93 50-150 Pass
Perfluorodecanoic acid (PFDA) B18-Fe14895 NCP % 88 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B18-Fe14895 NCP % 96 50-150 Pass
Perfluorododecanoic acid (PFDoA) B18-Fe14895 NCP % 90 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B18-Fe14895 NCP % 111 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B18-Fe14895 NCP % 92 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B18-Fe14895 NCP % 89 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B18-Fe14895 NCP % 87 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B18-Fe14895 NCP % 84 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B18-Fe14895 NCP % 89 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B18-Fe14895 NCP % 94 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B18-Fe14895 NCP % 104 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B18-Fe14895 NCP % 96 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B18-Fe14895 NCP % 87 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B18-Fe14895 NCP % 98 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B18-Fe14895 NCP % 82 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B18-Fe14895 NCP % 100 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B18-Fe14895 NCP % 91 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B18-Fe14895 NCP % 80 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B18-Fe14895 NCP % 97 50-150 Pass
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 13
Report Number: 584697-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B18-Fe14895 NCP % 97 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B18-Fe14895 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B18-Fe14895 NCP % 113 50-150 Pass
Spike - % Recovery
Result 1
Ammonia (as N) P18-Fe15523 NCP % 106 70-130 Pass
Nitrate & Nitrite (as N) P18-Fe15523 NCP % 81 70-130 Pass
Nitrate (as N) P18-Fe15523 NCP % 80 70-130 Pass
Nitrite (as N) P18-Fe15523 NCP % 116 70-130 Pass
Phosphate total (as P) B18-Fe14880 CP % 98 70-130 Pass
Total Kjeldahl Nitrogen (as N) B18-Fe14880 CP % 70 70-130 Pass
Spike - % Recovery
Heavy Metals Result 1
Arsenic M18-Fe15574 NCP % 92 75-125 Pass
Cadmium M18-Fe15574 NCP % 90 75-125 Pass
Chromium M18-Fe15574 NCP % 88 75-125 Pass
Copper M18-Fe15574 NCP % 91 75-125 Pass
Lead M18-Fe15574 NCP % 100 75-125 Pass
Mercury M18-Fe15574 NCP % 100 70-130 Pass
Nickel M18-Fe15574 NCP % 89 75-125 Pass
Zinc M18-Fe15574 NCP % 102 75-125 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M18-Fe14447 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M18-Fe14447 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M18-Fe14447 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M18-Fe14447 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M18-Fe14447 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M18-Fe14447 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M18-Fe14447 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M18-Fe14447 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 13
Report Number: 584697-W
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M18-Fe14447 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M18-Fe14447 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) P18-Fe15523 NCP mg/L 0.05 0.05 3.0 30% Pass
Conductivity (at 25°C) A18-Fe14807 NCP uS/cm 1800 1800 2.0 30% Pass
Nitrate & Nitrite (as N) P18-Fe15523 NCP mg/L 2.4 2.2 6.0 30% Pass
Nitrate (as N) P18-Fe15523 NCP mg/L 2.4 2.2 6.0 30% Pass
Nitrite (as N) P18-Fe15523 NCP mg/L < 0.02 < 0.02 <1 30% Pass
pH A18-Fe14807 NCP pH Units 8.3 8.3 pass 30% Pass
Phosphate total (as P) P18-Fe15525 NCP mg/L 0.31 0.30 4.0 30% Pass
Suspended Solids M18-Fe13969 NCP mg/L 1.8 2.3 24 30% Pass
Total Kjeldahl Nitrogen (as N) P18-Fe15525 NCP mg/L 0.3 0.2 35 30% Fail Q15
Total Organic Carbon M18-Fe19373 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Heavy Metals Result 1 Result 2 RPD
Arsenic M18-Fe15574 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Cadmium M18-Fe15574 NCP mg/L < 0.0002 < 0.0002 <1 30% Pass
Chromium M18-Fe15574 NCP mg/L 0.005 0.006 23 30% Pass
Copper M18-Fe15574 NCP mg/L 0.12 0.13 5.0 30% Pass
Lead M18-Fe15574 NCP mg/L 0.002 0.002 17 30% Pass
Mercury M18-Fe15574 NCP mg/L < 0.0001 < 0.0001 <1 30% Pass
Nickel M18-Fe15574 NCP mg/L 0.004 0.005 14 30% Pass
Zinc M18-Fe15574 NCP mg/L 0.32 0.34 5.0 30% Pass
Duplicate
Result 1 Result 2 RPD
Total Dissolved Solids B18-Fe14881 CP mg/L 3700 4000 10 30% Pass
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 12 of 13
Report Number: 584697-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Comments
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds.
N15Where the native PFAS compound does not have labelled analogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention timeto the analyte and no recovery correction has been made (Internal Standard Quantitation).
Q15 The RPD reported passes Eurofins | mgt's QC - Acceptance Criteria as defined in the Internal Quality Control Review and Glossary page of this report.
Authorised By
Ryan Gilbert Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Michael Brancati Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Feb 21, 2018
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 13 of 13
Report Number: 584697-W
Environmental
SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : EB1803662
:: LaboratoryClient Environmental Division BrisbaneAURECON AUSTRALASIA PTY LTD
: :ContactContact MS GEORGINA KERR Customer Services EB
:: AddressAddress LOCKED BAG 331 32 TURBOT
STREET
BRISBANE QLD, AUSTRALIA 4001
2 Byth Street Stafford QLD Australia
4053
:: E-mailE-mail [email protected]
:: TelephoneTelephone +61-7-3243 7222
:: FacsimileFacsimile +61-7-3243 7218
::Project 251529 HMAS Albatross Page 1 of 3
:Order number 251529 :Quote number EM2017CONWAG0002 (EN/057/17)
:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard
Site : ----
Sampler :
DatesDate Samples Received : Issue Date : 07-Feb-201807-Feb-2018 12:00
Scheduled Reporting Date: 14-Feb-2018:Client Requested Due
Date
14-Feb-2018
Delivery DetailsMode of Delivery : :Carrier Intact.Security Seal
No. of coolers/boxes : :1 Temperature 17.0°C - Ice Bricks present
: : 2 / 2FOAM ESKYReceipt Detail No. of samples received / analysed
General Comments
This report contains the following information:l
- Sample Container(s)/Preservation Non-Compliances
- Summary of Sample(s) and Requested Analysis
- Proactive Holding Time Report
- Requested Deliverables
l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.
l Analysis will be conducted by ALS Environmental, Sydney, NATA accreditation no. 825, Site No.
10911 (Micro site no. 14913).l Please direct any turn around / technical queries to the laboratory contact designated above.
l Sample Disposal - Aqueous (3 weeks), Solid (2 months) from receipt of samples.
l Breaches in recommended extraction / analysis holding times (if any) are displayed overleaf in
the Proactive Holding Time Report table.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
0 0.00 True
Environmental
CERTIFICATE OF ANALYSISWork Order : Page : 1 of 7EB1803662
:: LaboratoryClient AURECON AUSTRALASIA PTY LTD Environmental Division Brisbane
: :ContactContact MS GEORGINA KERR Customer Services EB
:: AddressAddress LOCKED BAG 331 32 TURBOT STREET
BRISBANE QLD, AUSTRALIA 4001
2 Byth Street Stafford QLD Australia 4053
:Telephone :Telephone +61-7-3243 7222
:Project 251529 HMAS Albatross Date Samples Received : 07-Feb-2018 12:00
:Order number 251529 Date Analysis Commenced : 10-Feb-2018
:C-O-C number ---- Issue Date : 14-Feb-2018 13:39
Sampler : ----
Site : ----
Quote number : EN/057/17
2:No. of samples received
2:No. of samples analysed
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Certificate of Analysis contains the following information:
l General Comments
l Analytical Results
l Surrogate Control Limits
Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with
Quality Review and Sample Receipt Notification.
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Alex Rossi Organic Chemist Sydney Inorganics, Smithfield, NSW
Alex Rossi Organic Chemist Sydney Organics, Smithfield, NSW
Celine Conceicao Senior Spectroscopist Sydney Inorganics, Smithfield, NSW
Edwandy Fadjar Organic Coordinator Sydney Inorganics, Smithfield, NSW
R I G H T S O L U T I O N S | R I G H T P A R T N E R
2 of 7:Page
Work Order :
:Client
EB1803662
251529 HMAS Albatross:Project
AURECON AUSTRALASIA PTY LTD
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When sampling time information is not provided by the client, sampling dates are shown without a time component. In these instances, the time component has been assumed by the laboratory for processing
purposes.
Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
^ = This result is computed from individual analyte detections at or above the level of reporting
ø = ALS is not NATA accredited for these tests.
~ = Indicates an estimated value.
Key :
Analysis will be conducted by ALS Environmental, Sydney, NATA accreditation no. 825, Site No. 10911 (Micro site no. 14913).l
3 of 7:Page
Work Order :
:Client
EB1803662
251529 HMAS Albatross:Project
AURECON AUSTRALASIA PTY LTD
Analytical Results
----------------QA201_180130Client sample IDSub-Matrix: ASLP LEACHATE
(Matrix: WATER)
----------------30-Jan-2018 00:00Client sampling date / time
--------------------------------EB1803662-002UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EP231A: Perfluoroalkyl Sulfonic Acids
<0.02Perfluorobutane sulfonic acid
(PFBS)
---- ---- ---- ----µg/L0.02375-73-5
<0.02Perfluoropentane sulfonic acid
(PFPeS)
---- ---- ---- ----µg/L0.022706-91-4
0.02Perfluorohexane sulfonic acid
(PFHxS)
---- ---- ---- ----µg/L0.02355-46-4
<0.02Perfluoroheptane sulfonic acid
(PFHpS)
---- ---- ---- ----µg/L0.02375-92-8
0.01Perfluorooctane sulfonic acid
(PFOS)
---- ---- ---- ----µg/L0.011763-23-1
<0.02Perfluorodecane sulfonic acid
(PFDS)
---- ---- ---- ----µg/L0.02335-77-3
EP231B: Perfluoroalkyl Carboxylic Acids
<0.1Perfluorobutanoic acid (PFBA) ---- ---- ---- ----µg/L0.1375-22-4
<0.02Perfluoropentanoic acid (PFPeA) ---- ---- ---- ----µg/L0.022706-90-3
<0.02Perfluorohexanoic acid (PFHxA) ---- ---- ---- ----µg/L0.02307-24-4
<0.02Perfluoroheptanoic acid (PFHpA) ---- ---- ---- ----µg/L0.02375-85-9
<0.01Perfluorooctanoic acid (PFOA) ---- ---- ---- ----µg/L0.01335-67-1
<0.02Perfluorononanoic acid (PFNA) ---- ---- ---- ----µg/L0.02375-95-1
<0.02Perfluorodecanoic acid (PFDA) ---- ---- ---- ----µg/L0.02335-76-2
<0.02Perfluoroundecanoic acid
(PFUnDA)
---- ---- ---- ----µg/L0.022058-94-8
<0.02Perfluorododecanoic acid
(PFDoDA)
---- ---- ---- ----µg/L0.02307-55-1
<0.02Perfluorotridecanoic acid
(PFTrDA)
---- ---- ---- ----µg/L0.0272629-94-8
<0.05Perfluorotetradecanoic acid
(PFTeDA)
---- ---- ---- ----µg/L0.05376-06-7
EP231C: Perfluoroalkyl Sulfonamides
<0.02Perfluorooctane sulfonamide
(FOSA)
---- ---- ---- ----µg/L0.02754-91-6
<0.05N-Methyl perfluorooctane
sulfonamide (MeFOSA)
---- ---- ---- ----µg/L0.0531506-32-8
<0.05N-Ethyl perfluorooctane
sulfonamide (EtFOSA)
---- ---- ---- ----µg/L0.054151-50-2
4 of 7:Page
Work Order :
:Client
EB1803662
251529 HMAS Albatross:Project
AURECON AUSTRALASIA PTY LTD
Analytical Results
----------------QA201_180130Client sample IDSub-Matrix: ASLP LEACHATE
(Matrix: WATER)
----------------30-Jan-2018 00:00Client sampling date / time
--------------------------------EB1803662-002UnitLORCAS NumberCompound
Result ---- ---- ---- ----
EP231C: Perfluoroalkyl Sulfonamides - Continued
<0.05N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
---- ---- ---- ----µg/L0.0524448-09-7
<0.05N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
---- ---- ---- ----µg/L0.051691-99-2
<0.02N-Methyl perfluorooctane
sulfonamidoacetic acid
(MeFOSAA)
---- ---- ---- ----µg/L0.022355-31-9
<0.02N-Ethyl perfluorooctane
sulfonamidoacetic acid
(EtFOSAA)
---- ---- ---- ----µg/L0.022991-50-6
EP231D: (n:2) Fluorotelomer Sulfonic Acids
<0.054:2 Fluorotelomer sulfonic acid
(4:2 FTS)
---- ---- ---- ----µg/L0.05757124-72-4
<0.056:2 Fluorotelomer sulfonic acid
(6:2 FTS)
---- ---- ---- ----µg/L0.0527619-97-2
<0.058:2 Fluorotelomer sulfonic acid
(8:2 FTS)
---- ---- ---- ----µg/L0.0539108-34-4
<0.0510:2 Fluorotelomer sulfonic acid
(10:2 FTS)
---- ---- ---- ----µg/L0.05120226-60-0
EP231P: PFAS Sums
0.03 ---- ---- ---- ----µg/L0.01----Sum of PFAS
0.03Sum of PFHxS and PFOS ---- ---- ---- ----µg/L0.01355-46-4/1763-23-
1
0.03 ---- ---- ---- ----µg/L0.01----Sum of PFAS (WA DER List)
EP231S: PFAS Surrogate
110 ---- ---- ---- ----%0.02----13C4-PFOS
100 ---- ---- ---- ----%0.02----13C8-PFOA
5 of 7:Page
Work Order :
:Client
EB1803662
251529 HMAS Albatross:Project
AURECON AUSTRALASIA PTY LTD
Analytical Results
------------QA201_180130QA201_180131Client sample IDSub-Matrix: SOIL
(Matrix: SOIL)
------------30-Jan-2018 00:0031-Jan-2018 00:00Client sampling date / time
------------------------EB1803662-002EB1803662-001UnitLORCAS NumberCompound
Result Result ---- ---- ----
EA055: Moisture Content (Dried @ 105-110°C)
48.9 10.3 ---- ---- ----%1.0----Moisture Content
EN60: ASLP Leaching Procedure
---- 8.1 ---- ---- ----pH Unit0.1----Initial pH
---- 1.9 ---- ---- ----pH Unit0.1----After HCl pH
---- 4.9 ---- ---- ----pH Unit0.1----Extraction Fluid pH
---- 5.0 ---- ---- ----pH Unit0.1----Final pH
EP231A: Perfluoroalkyl Sulfonic Acids
<0.0002Perfluorobutane sulfonic acid
(PFBS)
<0.0002 ---- ---- ----mg/kg0.0002375-73-5
<0.0002Perfluoropentane sulfonic acid
(PFPeS)
<0.0002 ---- ---- ----mg/kg0.00022706-91-4
<0.0002Perfluorohexane sulfonic acid
(PFHxS)
0.0003 ---- ---- ----mg/kg0.0002355-46-4
<0.0002Perfluoroheptane sulfonic acid
(PFHpS)
<0.0002 ---- ---- ----mg/kg0.0002375-92-8
<0.0002Perfluorooctane sulfonic acid
(PFOS)
0.0003 ---- ---- ----mg/kg0.00021763-23-1
<0.0002Perfluorodecane sulfonic acid
(PFDS)
<0.0002 ---- ---- ----mg/kg0.0002335-77-3
EP231B: Perfluoroalkyl Carboxylic Acids
<0.001Perfluorobutanoic acid (PFBA) <0.001 ---- ---- ----mg/kg0.001375-22-4
<0.0002Perfluoropentanoic acid (PFPeA) <0.0002 ---- ---- ----mg/kg0.00022706-90-3
<0.0002Perfluorohexanoic acid (PFHxA) <0.0002 ---- ---- ----mg/kg0.0002307-24-4
<0.0002Perfluoroheptanoic acid (PFHpA) <0.0002 ---- ---- ----mg/kg0.0002375-85-9
<0.0002Perfluorooctanoic acid (PFOA) <0.0002 ---- ---- ----mg/kg0.0002335-67-1
<0.0002Perfluorononanoic acid (PFNA) <0.0002 ---- ---- ----mg/kg0.0002375-95-1
<0.0002Perfluorodecanoic acid (PFDA) <0.0002 ---- ---- ----mg/kg0.0002335-76-2
<0.0002Perfluoroundecanoic acid
(PFUnDA)
<0.0002 ---- ---- ----mg/kg0.00022058-94-8
<0.0002Perfluorododecanoic acid
(PFDoDA)
<0.0002 ---- ---- ----mg/kg0.0002307-55-1
<0.0002Perfluorotridecanoic acid
(PFTrDA)
<0.0002 ---- ---- ----mg/kg0.000272629-94-8
<0.0005Perfluorotetradecanoic acid
(PFTeDA)
<0.0005 ---- ---- ----mg/kg0.0005376-06-7
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Analytical Results
------------QA201_180130QA201_180131Client sample IDSub-Matrix: SOIL
(Matrix: SOIL)
------------30-Jan-2018 00:0031-Jan-2018 00:00Client sampling date / time
------------------------EB1803662-002EB1803662-001UnitLORCAS NumberCompound
Result Result ---- ---- ----
EP231C: Perfluoroalkyl Sulfonamides
<0.0002Perfluorooctane sulfonamide
(FOSA)
<0.0002 ---- ---- ----mg/kg0.0002754-91-6
<0.0005N-Methyl perfluorooctane
sulfonamide (MeFOSA)
<0.0005 ---- ---- ----mg/kg0.000531506-32-8
<0.0005N-Ethyl perfluorooctane
sulfonamide (EtFOSA)
<0.0005 ---- ---- ----mg/kg0.00054151-50-2
<0.0005N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
<0.0005 ---- ---- ----mg/kg0.000524448-09-7
<0.0005N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
<0.0005 ---- ---- ----mg/kg0.00051691-99-2
<0.0002N-Methyl perfluorooctane
sulfonamidoacetic acid
(MeFOSAA)
<0.0002 ---- ---- ----mg/kg0.00022355-31-9
<0.0002N-Ethyl perfluorooctane
sulfonamidoacetic acid
(EtFOSAA)
<0.0002 ---- ---- ----mg/kg0.00022991-50-6
EP231D: (n:2) Fluorotelomer Sulfonic Acids
<0.00054:2 Fluorotelomer sulfonic acid
(4:2 FTS)
<0.0005 ---- ---- ----mg/kg0.0005757124-72-4
<0.00056:2 Fluorotelomer sulfonic acid
(6:2 FTS)
<0.0005 ---- ---- ----mg/kg0.000527619-97-2
<0.00058:2 Fluorotelomer sulfonic acid
(8:2 FTS)
<0.0005 ---- ---- ----mg/kg0.000539108-34-4
<0.000510:2 Fluorotelomer sulfonic acid
(10:2 FTS)
<0.0005 ---- ---- ----mg/kg0.0005120226-60-0
EP231P: PFAS Sums
<0.0002 0.0006 ---- ---- ----mg/kg0.0002----Sum of PFAS
<0.0002Sum of PFHxS and PFOS 0.0006 ---- ---- ----mg/kg0.0002355-46-4/1763-23-
1
<0.0002 0.0006 ---- ---- ----mg/kg0.0002----Sum of PFAS (WA DER List)
EP231S: PFAS Surrogate
87.0 88.0 ---- ---- ----%0.0002----13C4-PFOS
86.0 94.0 ---- ---- ----%0.0002----13C8-PFOA
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Surrogate Control Limits
Recovery Limits (%)Sub-Matrix: ASLP LEACHATE
Compound CAS Number Low High
EP231S: PFAS Surrogate
13C4-PFOS ---- 60 130
13C8-PFOA ---- 60 130
Recovery Limits (%)Sub-Matrix: SOIL
Compound CAS Number Low High
EP231S: PFAS Surrogate
13C4-PFOS ---- 60 130
13C8-PFOA ---- 60 130
True
Environmental
QA/QC Compliance Assessment to assist with Quality ReviewWork Order : EB1803662 Page : 1 of 5
:: LaboratoryClient Environmental Division BrisbaneAURECON AUSTRALASIA PTY LTD
:Contact MS GEORGINA KERR Telephone : +61-7-3243 7222
:Project 251529 HMAS Albatross Date Samples Received : 07-Feb-2018
Site : ---- Issue Date : 14-Feb-2018
----:Sampler No. of samples received : 2
:Order number 251529 No. of samples analysed : 2
This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated
reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this
report contribute to the overall DQO assessment and reporting for guideline compliance.
Brief method summaries and references are also provided to assist in traceability.
Summary of Outliers
Outliers : Quality Control Samples
This report highlights outliers flagged in the Quality Control (QC) Report.
l NO Method Blank value outliers occur.
l NO Duplicate outliers occur.
l NO Laboratory Control outliers occur.
l NO Matrix Spike outliers occur.
l For all regular sample matrices, NO surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
l NO Analysis Holding Time Outliers exist.
Outliers : Frequency of Quality Control Samples
l Quality Control Sample Frequency Outliers exist - please see following pages for full details.
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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Outliers : Frequency of Quality Control Samples
Matrix: WATER
Quality Control SpecificationQuality Control Sample Type
Method ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type Count
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC StandardPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS 9.09 10.001 11
Analysis Holding Time Compliance
Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and
should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.
Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics
14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.
If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.
This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container
provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.
Matrix: SOIL Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EA055: Moisture Content (Dried @ 105-110°C)
HDPE Soil Jar (EA055)
QA201_180130 13-Feb-2018---- 12-Feb-2018----30-Jan-2018 ---- üHDPE Soil Jar (EA055)
QA201_180131 14-Feb-2018---- 12-Feb-2018----31-Jan-2018 ---- üEN60: ASLP Leaching Procedure
Non-Volatile Leach: 180 day HT (e.g. metals ex.Hg) (EN60a)
QA201_180130 ----29-Jul-2018 ----10-Feb-201830-Jan-2018 ü ----
EP231A: Perfluoroalkyl Sulfonic Acids
HDPE Soil Jar (EP231X)
QA201_180130 24-Mar-201829-Jul-2018 13-Feb-201812-Feb-201830-Jan-2018 ü üHDPE Soil Jar (EP231X)
QA201_180131 24-Mar-201830-Jul-2018 13-Feb-201812-Feb-201831-Jan-2018 ü üEP231B: Perfluoroalkyl Carboxylic Acids
HDPE Soil Jar (EP231X)
QA201_180130 24-Mar-201829-Jul-2018 13-Feb-201812-Feb-201830-Jan-2018 ü üHDPE Soil Jar (EP231X)
QA201_180131 24-Mar-201830-Jul-2018 13-Feb-201812-Feb-201831-Jan-2018 ü üEP231C: Perfluoroalkyl Sulfonamides
HDPE Soil Jar (EP231X)
QA201_180130 24-Mar-201829-Jul-2018 13-Feb-201812-Feb-201830-Jan-2018 ü üHDPE Soil Jar (EP231X)
QA201_180131 24-Mar-201830-Jul-2018 13-Feb-201812-Feb-201831-Jan-2018 ü ü
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Matrix: SOIL Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP231D: (n:2) Fluorotelomer Sulfonic Acids
HDPE Soil Jar (EP231X)
QA201_180130 24-Mar-201829-Jul-2018 13-Feb-201812-Feb-201830-Jan-2018 ü üHDPE Soil Jar (EP231X)
QA201_180131 24-Mar-201830-Jul-2018 13-Feb-201812-Feb-201831-Jan-2018 ü üEP231P: PFAS Sums
HDPE Soil Jar (EP231X)
QA201_180130 24-Mar-201829-Jul-2018 13-Feb-201812-Feb-201830-Jan-2018 ü üHDPE Soil Jar (EP231X)
QA201_180131 24-Mar-201830-Jul-2018 13-Feb-201812-Feb-201831-Jan-2018 ü üMatrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.
AnalysisExtraction / PreparationSample DateMethod
EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)
EP231A: Perfluoroalkyl Sulfonic Acids
HDPE (no PTFE) (EP231X)
QA201_180130 09-Aug-2018---- 12-Feb-2018----10-Feb-2018 ---- üEP231B: Perfluoroalkyl Carboxylic Acids
HDPE (no PTFE) (EP231X)
QA201_180130 09-Aug-2018---- 12-Feb-2018----10-Feb-2018 ---- üEP231C: Perfluoroalkyl Sulfonamides
HDPE (no PTFE) (EP231X)
QA201_180130 09-Aug-2018---- 12-Feb-2018----10-Feb-2018 ---- üEP231D: (n:2) Fluorotelomer Sulfonic Acids
HDPE (no PTFE) (EP231X)
QA201_180130 09-Aug-2018---- 12-Feb-2018----10-Feb-2018 ---- üEP231P: PFAS Sums
HDPE (no PTFE) (EP231X)
QA201_180130 09-Aug-2018---- 12-Feb-2018----10-Feb-2018 ---- ü
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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers.
Matrix: SOIL Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üMoisture Content EA055
NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 100.00 9.091 1 üASLP for Non & Semivolatile Analytes EN60a
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 8.33 5.001 12 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.
Quality Control SpecificationQuality Control Sample Type
ExpectedQC Regular Actual
Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method
Laboratory Duplicates (DUP)
NEPM 2013 B3 & ALS QC Standard 9.09 10.001 11 ûPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
Laboratory Control Samples (LCS)
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
Method Blanks (MB)
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
Matrix Spikes (MS)
NEPM 2013 B3 & ALS QC Standard 9.09 5.001 11 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X
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Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.
Analytical Methods Method DescriptionsMatrixMethod
In house: A gravimetric procedure based on weight loss over a 12 hour drying period at 105-110 degrees C.
This method is compliant with NEPM (2013) Schedule B(3) Section 7.1 and Table 1 (14 day holding time).
Moisture Content EA055 SOIL
In-House. A portion of soil is extracted with MTBE. The extract is taken to dryness, made up in mobile phase.
Analysis is by LC/MSMS, ESI Negative Mode using MRM. Where commercially available, isotopically labelled
analogues of the target analytes are used as internal standards for quantification. Where a labelled analogue is
not commercially available, the internal standard with similar chemistry and the closest retention time to the
target is used for quantification. PFOS is quantified using a certified, traceable standard consisting of linear and
branched PFOS isomers.
Per- and Polyfluoroalkyl Substances
(PFAS) by LCMSMS
EP231X SOIL
Preparation Methods Method DescriptionsMatrixMethod
In house QWI-EN/60 referenced to AS4439.3 Preparation of LeachatesASLP for Non & Semivolatile Analytes EN60a SOIL
In houseSample Extraction for PFAS EP231-PR SOIL
False
4 4.00True
Environmental
QUALITY CONTROL REPORTWork Order : EB1803662 Page : 1 of 10
:: LaboratoryClient Environmental Division BrisbaneAURECON AUSTRALASIA PTY LTD
:Contact MS GEORGINA KERR :Contact Customer Services EB
:Address LOCKED BAG 331 32 TURBOT STREET
BRISBANE QLD, AUSTRALIA 4001
Address : 2 Byth Street Stafford QLD Australia 4053
::Telephone +61-7-3243 7222:Telephone
:Project 251529 HMAS Albatross Date Samples Received : 07-Feb-2018
:Order number 251529 Date Analysis Commenced : 10-Feb-2018
:C-O-C number ---- Issue Date : 14-Feb-2018
Sampler : ----
Site : ----
Quote number : EN/057/17
No. of samples received 2:
No. of samples analysed 2:
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.
This Quality Control Report contains the following information:
l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits
l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits
l Matrix Spike (MS) Report; Recovery and Acceptance Limits
SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Accreditation CategoryPosition
Alex Rossi Organic Chemist Sydney Inorganics, Smithfield, NSW
Alex Rossi Organic Chemist Sydney Organics, Smithfield, NSW
Celine Conceicao Senior Spectroscopist Sydney Inorganics, Smithfield, NSW
Edwandy Fadjar Organic Coordinator Sydney Inorganics, Smithfield, NSW
R I G H T S O L U T I O N S | R I G H T P A R T N E R
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General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed QC
Key :
Laboratory Duplicate (DUP) Report
The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:
No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.
Sub-Matrix: SOIL Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EA055: Moisture Content (Dried @ 105-110°C) (QC Lot: 1427308)
EA055: Moisture Content ---- 1 % 10.3 10.2 0.00 0% - 50%QA201_180130 EB1803662-002
EA055: Moisture Content ---- 1 % 16.8 18.2 8.31 0% - 50%Anonymous ES1804123-015
EP231A: Perfluoroalkyl Sulfonic Acids (QC Lot: 1426338)
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.0002 mg/kg <0.0002 <0.0002 0.00 No LimitQA201_180131 EB1803662-001
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.0002 mg/kg <0.0002 <0.0002 0.00 No LimitAnonymous ES1804294-016
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231B: Perfluoroalkyl Carboxylic Acids (QC Lot: 1426338)
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0002 mg/kg <0.0002 <0.0002 0.00 No LimitQA201_180131 EB1803662-001
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
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Sub-Matrix: SOIL Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP231B: Perfluoroalkyl Carboxylic Acids (QC Lot: 1426338) - continued
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.0002 mg/kg <0.0002 <0.0002 0.00 No LimitQA201_180131 EB1803662-001
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.001 mg/kg <0.001 <0.001 0.00 No Limit
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0002 mg/kg <0.0002 <0.0002 0.00 No LimitAnonymous ES1804294-016
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.001 mg/kg <0.001 <0.001 0.00 No Limit
EP231C: Perfluoroalkyl Sulfonamides (QC Lot: 1426338)
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.0002 mg/kg <0.0002 <0.0002 0.00 No LimitQA201_180131 EB1803662-001
EP231X: N-Methyl perfluorooctane
sulfonamidoacetic acid (MeFOSAA)
2355-31-9 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoacetic acid (EtFOSAA)
2991-50-6 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
31506-32-8 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: N-Ethyl perfluorooctane sulfonamide
(EtFOSA)
4151-50-2 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
24448-09-7 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
1691-99-2 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.0002 mg/kg <0.0002 <0.0002 0.00 No LimitAnonymous ES1804294-016
EP231X: N-Methyl perfluorooctane
sulfonamidoacetic acid (MeFOSAA)
2355-31-9 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoacetic acid (EtFOSAA)
2991-50-6 0.0002 mg/kg <0.0002 <0.0002 0.00 No Limit
EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
31506-32-8 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: N-Ethyl perfluorooctane sulfonamide
(EtFOSA)
4151-50-2 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
24448-09-7 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
1691-99-2 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
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Sub-Matrix: SOIL Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 1426338)
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2
FTS)
757124-72-4 0.0005 mg/kg <0.0005 <0.0005 0.00 No LimitQA201_180131 EB1803662-001
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2
FTS)
27619-97-2 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2
FTS)
39108-34-4 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2
FTS)
120226-60-0 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2
FTS)
757124-72-4 0.0005 mg/kg <0.0005 <0.0005 0.00 No LimitAnonymous ES1804294-016
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2
FTS)
27619-97-2 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2
FTS)
39108-34-4 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2
FTS)
120226-60-0 0.0005 mg/kg <0.0005 <0.0005 0.00 No Limit
Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP231A: Perfluoroalkyl Sulfonic Acids (QC Lot: 1426317)
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.19 0.16 14.2 0% - 50%Anonymous EB1803622-003
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L 0.06 0.05 0.00 No Limit
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231B: Perfluoroalkyl Carboxylic Acids (QC Lot: 1426317)
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 0.02 0.01 0.00 No LimitAnonymous EB1803622-003
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L 0.03 0.03 0.00 No Limit
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L 0.03 0.03 0.00 No Limit
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 <0.1 0.00 No Limit
EP231C: Perfluoroalkyl Sulfonamides (QC Lot: 1426317)
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous EB1803622-003
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Sub-Matrix: WATER Laboratory Duplicate (DUP) Report
Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)
EP231C: Perfluoroalkyl Sulfonamides (QC Lot: 1426317) - continued
EP231X: N-Methyl perfluorooctane
sulfonamidoacetic acid (MeFOSAA)
2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous EB1803622-003
EP231X: N-Ethyl perfluorooctane
sulfonamidoacetic acid (EtFOSAA)
2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit
EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane sulfonamide
(EtFOSA)
4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Methyl perfluorooctane
sulfonamidoethanol (MeFOSE)
24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: N-Ethyl perfluorooctane
sulfonamidoethanol (EtFOSE)
1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 1426317)
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2
FTS)
757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No LimitAnonymous EB1803622-003
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2
FTS)
27619-97-2 0.05 µg/L 0.15 0.14 0.00 No Limit
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2
FTS)
39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2
FTS)
120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit
EP231P: PFAS Sums (QC Lot: 1426317)
EP231X: Sum of PFAS ---- 0.01 µg/L 0.48 0.42 13.3 0% - 20%Anonymous EB1803622-003
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Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC
parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: SOIL Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EN60: ASLP Leaching Procedure (QCLot: 1425381)
EN60a: Final pH ---- 0.1 pH Unit 1.0 -------- --------
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 1426338)
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.0002 mg/kg <0.0002 68.70.00125 mg/kg 12157
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.0002 mg/kg <0.0002 67.60.00125 mg/kg 12555
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.0002 mg/kg <0.0002 66.40.00125 mg/kg 12652
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.0002 mg/kg <0.0002 89.00.00125 mg/kg 12354
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.0002 mg/kg <0.0002 83.00.00125 mg/kg 12755
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.0002 mg/kg <0.0002 86.30.00125 mg/kg 12554
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 1426338)
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.001 mg/kg <0.001 57.70.00625 mg/kg 12852
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0002 mg/kg <0.0002 98.00.00125 mg/kg 12954
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.0002 mg/kg <0.0002 70.20.00125 mg/kg 12758
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.0002 mg/kg <0.0002 71.80.00125 mg/kg 12857
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.0002 mg/kg <0.0002 85.40.00125 mg/kg 13460
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.0002 mg/kg <0.0002 77.40.00125 mg/kg 13063
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.0002 mg/kg <0.0002 97.50.00125 mg/kg 13055
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.0002 mg/kg <0.0002 89.40.00125 mg/kg 13062
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.0002 mg/kg <0.0002 87.40.00125 mg/kg 13453
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.0002 mg/kg <0.0002 85.10.00125 mg/kg 12949
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.0005 mg/kg <0.0005 1070.00312 mg/kg 12959
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 1426338)
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.0002 mg/kg <0.0002 74.90.00125 mg/kg 13252
EP231X: N-Methyl perfluorooctane sulfonamide (MeFOSA) 31506-32-8 0.0005 mg/kg <0.0005 66.60.00312 mg/kg 12665
EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 4151-50-2 0.0005 mg/kg <0.0005 74.10.00312 mg/kg 12664
EP231X: N-Methyl perfluorooctane sulfonamidoethanol
(MeFOSE)
24448-09-7 0.0005 mg/kg <0.0005 65.50.00312 mg/kg 12463
EP231X: N-Ethyl perfluorooctane sulfonamidoethanol
(EtFOSE)
1691-99-2 0.0005 mg/kg <0.0005 76.20.00312 mg/kg 12558
EP231X: N-Methyl perfluorooctane sulfonamidoacetic acid
(MeFOSAA)
2355-31-9 0.0002 mg/kg <0.0002 90.20.00125 mg/kg 13061
EP231X: N-Ethyl perfluorooctane sulfonamidoacetic acid
(EtFOSAA)
2991-50-6 0.0002 mg/kg <0.0002 1180.00125 mg/kg 13055
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 1426338)
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 757124-72-4 0.0005 mg/kg <0.0005 1000.00125 mg/kg 13054
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Sub-Matrix: SOIL Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 1426338) - continued
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 27619-97-2 0.0005 mg/kg <0.0005 85.40.00125 mg/kg 13061
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 39108-34-4 0.0005 mg/kg <0.0005 64.60.00125 mg/kg 13062
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 120226-60-0 0.0005 mg/kg <0.0005 81.10.00125 mg/kg 13060
Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 1426317)
EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 79.00.5 µg/L 13070
EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 95.80.5 µg/L 13070
EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L <0.02 80.00.5 µg/L 13070
EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 90.60.5 µg/L 13070
EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 83.00.5 µg/L 13070
EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 85.40.5 µg/L 13070
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 1426317)
EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 87.62.5 µg/L 13070
EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 90.60.5 µg/L 13070
EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L <0.02 79.40.5 µg/L 13070
EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 95.20.5 µg/L 13070
EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 94.00.5 µg/L 13070
EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 91.00.5 µg/L 13070
EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 95.40.5 µg/L 13070
EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 98.40.5 µg/L 13070
EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 96.40.5 µg/L 13070
EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 1010.5 µg/L 13070
EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 91.91.25 µg/L 15070
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 1426317)
EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 79.40.5 µg/L 13070
EP231X: N-Methyl perfluorooctane sulfonamide (MeFOSA) 31506-32-8 0.05 µg/L <0.05 90.31.25 µg/L 15070
EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 4151-50-2 0.05 µg/L <0.05 1021.25 µg/L 15070
EP231X: N-Methyl perfluorooctane sulfonamidoethanol
(MeFOSE)
24448-09-7 0.05 µg/L <0.05 73.31.25 µg/L 15070
EP231X: N-Ethyl perfluorooctane sulfonamidoethanol
(EtFOSE)
1691-99-2 0.05 µg/L <0.05 79.91.25 µg/L 15070
EP231X: N-Methyl perfluorooctane sulfonamidoacetic acid
(MeFOSAA)
2355-31-9 0.02 µg/L <0.02 1050.5 µg/L 13070
EP231X: N-Ethyl perfluorooctane sulfonamidoacetic acid
(EtFOSAA)
2991-50-6 0.02 µg/L <0.02 72.60.5 µg/L 13070
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 1426317)
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Sub-Matrix: WATER Method Blank (MB)
Report
Laboratory Control Spike (LCS) Report
Spike Spike Recovery (%) Recovery Limits (%)
Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 1426317) - continued
EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 757124-72-4 0.05 µg/L <0.05 1140.5 µg/L 13070
EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 27619-97-2 0.05 µg/L <0.05 95.00.5 µg/L 13070
EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 39108-34-4 0.05 µg/L <0.05 1170.5 µg/L 13070
EP231X: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 120226-60-0 0.05 µg/L <0.05 77.20.5 µg/L 13070
Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on
analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.
Sub-Matrix: SOIL Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 1426338)
QA201_180130 EB1803662-002 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 90.00.00125 mg/kg 13050
2706-91-4EP231X: Perfluoropentane sulfonic acid (PFPeS) 76.80.00125 mg/kg 13050
355-46-4EP231X: Perfluorohexane sulfonic acid (PFHxS) 68.40.00125 mg/kg 13050
375-92-8EP231X: Perfluoroheptane sulfonic acid (PFHpS) 88.80.00125 mg/kg 13050
1763-23-1EP231X: Perfluorooctane sulfonic acid (PFOS) 82.80.00125 mg/kg 13050
335-77-3EP231X: Perfluorodecane sulfonic acid (PFDS) 73.60.00125 mg/kg 13050
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 1426338)
QA201_180130 EB1803662-002 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 59.40.00625 mg/kg 13030
2706-90-3EP231X: Perfluoropentanoic acid (PFPeA) 1170.00125 mg/kg 13050
307-24-4EP231X: Perfluorohexanoic acid (PFHxA) 75.60.00125 mg/kg 13050
375-85-9EP231X: Perfluoroheptanoic acid (PFHpA) 92.80.00125 mg/kg 13050
335-67-1EP231X: Perfluorooctanoic acid (PFOA) 1060.00125 mg/kg 13050
375-95-1EP231X: Perfluorononanoic acid (PFNA) 80.00.00125 mg/kg 13050
335-76-2EP231X: Perfluorodecanoic acid (PFDA) 98.00.00125 mg/kg 13050
2058-94-8EP231X: Perfluoroundecanoic acid (PFUnDA) 87.60.00125 mg/kg 13050
307-55-1EP231X: Perfluorododecanoic acid (PFDoDA) 95.20.00125 mg/kg 13050
72629-94-8EP231X: Perfluorotridecanoic acid (PFTrDA) 84.80.00125 mg/kg 13030
376-06-7EP231X: Perfluorotetradecanoic acid (PFTeDA) 86.40.00312 mg/kg 13030
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 1426338)
QA201_180130 EB1803662-002 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 75.60.00125 mg/kg 13050
31506-32-8EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
49.70.00312 mg/kg 13030
4151-50-2EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 56.90.00312 mg/kg 13030
24448-09-7EP231X: N-Methyl perfluorooctane sulfonamidoethanol
(MeFOSE)
59.80.00312 mg/kg 13030
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Sub-Matrix: SOIL Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 1426338) - continued
QA201_180130 EB1803662-002 1691-99-2EP231X: N-Ethyl perfluorooctane sulfonamidoethanol
(EtFOSE)
51.30.00312 mg/kg 13030
2355-31-9EP231X: N-Methyl perfluorooctane sulfonamidoacetic
acid (MeFOSAA)
87.20.00125 mg/kg 13030
2991-50-6EP231X: N-Ethyl perfluorooctane sulfonamidoacetic
acid (EtFOSAA)
1040.00125 mg/kg 13030
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 1426338)
QA201_180130 EB1803662-002 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1140.00125 mg/kg 13050
27619-97-2EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 65.60.00125 mg/kg 13050
39108-34-4EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 75.60.00125 mg/kg 13050
120226-60-0EP231X: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 80.80.00125 mg/kg 13050
Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 1426317)
Anonymous EB1803622-003 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 77.60.5 µg/L 13050
2706-91-4EP231X: Perfluoropentane sulfonic acid (PFPeS) 1050.5 µg/L 13050
355-46-4EP231X: Perfluorohexane sulfonic acid (PFHxS) 88.00.5 µg/L 13050
375-92-8EP231X: Perfluoroheptane sulfonic acid (PFHpS) 1080.5 µg/L 13050
1763-23-1EP231X: Perfluorooctane sulfonic acid (PFOS) 92.80.5 µg/L 13050
335-77-3EP231X: Perfluorodecane sulfonic acid (PFDS) 91.20.5 µg/L 13050
EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 1426317)
Anonymous EB1803622-003 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 1012.5 µg/L 13050
2706-90-3EP231X: Perfluoropentanoic acid (PFPeA) 1170.5 µg/L 13050
307-24-4EP231X: Perfluorohexanoic acid (PFHxA) 94.80.5 µg/L 13050
375-85-9EP231X: Perfluoroheptanoic acid (PFHpA) 1140.5 µg/L 13050
335-67-1EP231X: Perfluorooctanoic acid (PFOA) 99.20.5 µg/L 13050
375-95-1EP231X: Perfluorononanoic acid (PFNA) 1100.5 µg/L 13050
335-76-2EP231X: Perfluorodecanoic acid (PFDA) 1080.5 µg/L 13050
2058-94-8EP231X: Perfluoroundecanoic acid (PFUnDA) 1170.5 µg/L 13050
307-55-1EP231X: Perfluorododecanoic acid (PFDoDA) 87.60.5 µg/L 13050
72629-94-8EP231X: Perfluorotridecanoic acid (PFTrDA) 97.60.5 µg/L 13050
376-06-7EP231X: Perfluorotetradecanoic acid (PFTeDA) 1271.25 µg/L 15050
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 1426317)
Anonymous EB1803622-003 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 97.20.5 µg/L 13050
31506-32-8EP231X: N-Methyl perfluorooctane sulfonamide
(MeFOSA)
1081.25 µg/L 15050
4151-50-2EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 96.01.25 µg/L 15050
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Sub-Matrix: WATER Matrix Spike (MS) Report
SpikeRecovery(%) Recovery Limits (%)Spike
HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number
EP231C: Perfluoroalkyl Sulfonamides (QCLot: 1426317) - continued
Anonymous EB1803622-003 24448-09-7EP231X: N-Methyl perfluorooctane sulfonamidoethanol
(MeFOSE)
91.51.25 µg/L 15050
1691-99-2EP231X: N-Ethyl perfluorooctane sulfonamidoethanol
(EtFOSE)
1131.25 µg/L 15050
2355-31-9EP231X: N-Methyl perfluorooctane sulfonamidoacetic
acid (MeFOSAA)
96.60.5 µg/L 13050
2991-50-6EP231X: N-Ethyl perfluorooctane sulfonamidoacetic
acid (EtFOSAA)
85.00.5 µg/L 13050
EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 1426317)
Anonymous EB1803622-003 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1170.5 µg/L 13050
27619-97-2EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 1240.5 µg/L 13050
39108-34-4EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 1040.5 µg/L 13050
120226-60-0EP231X: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 83.60.5 µg/L 13050
C
QA/QC results
Project number 251529/DEHP-ID-183-D1 File HMAS Albatross HHERA Addendum Field Investigation.docx, 21 June 2018 Revision 1 28
Appendix C QA/QC results
Sampling and laboratory QA/QC QA/QC procedures relevant to the this investigation were carried out in general accordance with the relevant NEPM (2013) Schedule B(2) Guideline on Data Collection, Sample Design and Reporting – Section 4 and Schedule B(3) Guideline on Laboratory Analysis of Potentially Contaminated Sites.
Aurecon considers that adequate QA has been achieved by meeting the following DQOs:
Maintenance of sample integrity (sampling and analytical equipment decontamination, minimisation of cross contamination of samples, cross checking of sample identities, duplicate sampling and analytical data evaluation)
Method accuracy (field and laboratory procedures)
Data precision (laboratory instrumentation checks and record review, laboratory quality control analysis
To ensure that the results of the investigation were valid and defensible, work was carried out according to industry-accepted standards by experienced environmental scientists and in accordance with the requirements of NEPM 2013.
Field QC procedures for the investigation included:
Rigorous sample collection
Collection of intra-laboratory duplicate samples
− One soil sample
Collection of inter-laboratory duplicate samples
− Two biota samples
− One soil sample
Handling and transfer protocols
The laboratories selected for carrying out the laboratory analysis, Eurofins (primary and intra-laboratory duplicate sample analysis), NMI (biota inter-laboratory duplicate sample analysis) and ALS (soil inter-laboratory duplicate sample analysis) are accredited and certified by NATA to carry out each analysis. Internal laboratory QC procedures include duplicate sample analysis and an assessment of laboratory holding times.
Laboratory results of QA/QC testing show that the laboratory data is representative of conditions at sample locations, and therefore can be relied upon for the purpose of this investigation.
Laboratory QA/QC
Sample conditions The majority of samples were received by the laboratories in appropriate sample containers that were pre-treated and preserved.
Samples were stored in a chilled esky with ice bricks whilst in the field and were frozen upon receipt by the laboratory. All samples were delivered to the laboratories within the recommended holding times.
Project number 251529/DEHP-ID-183-D1 File HMAS Albatross HHERA Addendum Field Investigation.docx, 21 June 2018 Revision 1 29
Laboratory blanks The assessment of the laboratory blank samples by Eurofins and ALS reported concentrations of all parameters below the LOR, indicating that the samples were not contaminated during laboratory analysis.
Laboratory duplicates The assessment of laboratory duplicates were generally within the recommended RPD, although there were two instances where the duplicates had an RPD above 30%. This occurred in work order 583547 from chromium and in work order 584697 for total kjeldahl nitrogen. However, Eurofins noted that in both instances, the RPDs passed Eurofins internal criteria, given the low concentrations near and below detection.
As such, it is considered that the level of precision is acceptable.
Laboratory and matrix spikes The laboratory control spikes were within the recovery limits for all analytes. The matrix spikes reported by all laboratories were within the recommended recovery limits for all samples.
Field QA/QC
Sample collection The SAQP contained instructions for hand augering, sediment sampling, surface water monitoring and biota sampling, whilst ensuring cross-contamination is avoided.
Field equipment used during the investigated was free from material containing Teflon® (eg Teflon® tubing, containers, tape etc) as Teflon® is known to contain fluorinated compounds. Waterproof field books and clipboards were not used to avoid plastic coating and glue materials. Markers and Post-It Notes were also avoided.
Field clothing used during the investigation were made of synthetic and natural fibres were used and well laundered, avoiding fabric softener. Water resistant, waterproof or stain-treated clothing were avoided as was Tyvek® clothing.
Disposable nitrile gloves were worn at all times with a new pair of nitrile gloves worn before commencing the following activities at each new sampling location:
Decontamination of re-usable sampling equipment
Prior to contact with sample bottles or water containers
Handling of any QA/QC samples including field blanks and equipment blanks
After the handling of any non-dedicated sampling equipment, contact with non-decontaminated surfaces, or when judged necessary by field personnel
Soil, sediment and water samples were collected in polypropylene or HDPE bottles fitted with unlined polypropylene HDPE screw caps (not Teflon® lined). Glass containers were avoided due to potential loss of analyte through adsorption. Samples were stored in a chilled portable fridge prior to submission to the laboratory for testing under appropriate chain of custody documentation.
During decontamination, Decon 90® was not used as it is known to contain fluorinated compounds. Instead, a water only decontamination procedure was used for all sampling equipment, as recommended by the Western Australia (2017) Interim Guideline on the Assessment and Management of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS). The decontamination procedure implemented is as follows:
Scrub off excess dirt in first cleaning container
Rinse in tap water (three times)
Project number 251529/DEHP-ID-183-D1 File HMAS Albatross HHERA Addendum Field Investigation.docx, 21 June 2018 Revision 1 30
Rinse with deionised/distilled water (twice)
Intra- and inter-laboratory duplicates
General Data validation of duplicate samples was undertaken by calculation of the RPD from the mean. RPDs for the samples are calculated using the formula:
𝑅𝑅𝑅𝑅𝑅𝑅% =𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅 𝑛𝑛𝑛𝑛. 1 − 𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅 𝑛𝑛𝑛𝑛. 2
𝑚𝑚𝑅𝑅𝑚𝑚𝑛𝑛 𝑟𝑟𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅× 100
RPD data are used to determine the precision/reproducibility of results. The precision of laboratory analytical results is deemed to be suitable if RPD values fall within the recommended range of 30% RPD where one or both values were greater than 10 x LOR or 50% RPD where one or both values less than 10 x LOR.
Where both values fall below the LOR, the RPD is not calculated. However, if only one value is below the LOR, the LOR is used as that value in the above calculations.
Biota RPD analysis Table F.1 provides details of the two primary samples and the corresponding intra- and inter-laboratory duplicate biota samples collected during the investigation.
Table F.1 Field intra- and inter-laboratory duplicates
Primary sample Intra-laboratory duplicate Inter-laboratory duplicate
SR-B1_MULLET1_180208 - QA101_180208
SR-B1_BASS1_180208 - QA102_180208
RPDs were calculated and reported within criteria with the exception of the following presented in Table F.2.
Table F.2 Biota RPD exceedances
Analyte Laboratory results Intra- and inter- laboratory results
RPD (%)
SR-B1_MULLET1_180208
The RPDs did not exceed 30% for the selected analytes
SR-B1_BASS1_180206
PFOS 5.5 3.2 52.9
One RPD exceedance of the recommended target RPD percentage was identified, although it is noted that higher variations can also be expected for samples with low analyte concentrations. Based on this, Aurecon deems the exceedances in Table F.2 as acceptable.
Soil RPD analysis Table F.3 provides details of the one primary sample and the corresponding intra- and inter-laboratory duplicate soil samples collected during the investigation.
Table F.3 Field intra- and inter-laboratory duplicates
Primary sample Intra-laboratory duplicate Inter-laboratory duplicate
HA96_0.1_180131 QA101_180131 QA102_180131
RPDs were calculated and reported within criteria with the exception of the following presented in Table F.4.
Project number 251529/DEHP-ID-183-D1 File HMAS Albatross HHERA Addendum Field Investigation.docx, 21 June 2018 Revision 1 31
Table F.4 Soil RPD exceedances
Analyte Laboratory results Intra- and inter- laboratory results
RPD (%)
HA96_0.1_180131 (QA102_180131)
PFHxS <0.01 µg/L 0.02 µg/L 66.6
Only a single inter-laboratory duplicate result exceeded the recommended target RPD, with the sample a soil leachate result from HA96. The high RPD is indicative of the low values that are near or below detection, which can exaggerate the RPD.
Based on this, Aurecon deems the exceedances in Table F.4 as acceptable.
Aurecon offices are located in: Angola, Australia, Botswana, China, Ghana, Hong Kong, Indonesia, Kenya, Lesotho, Macau, Mozambique, Namibia, New Zealand, Nigeria, Philippines, Qatar, Singapore, South Africa, Swaziland, Tanzania, Thailand, Uganda, United Arab Emirates, Vietnam.
Document prepared by Aurecon Australasia Pty Ltd ABN 54 005 139 873 Level 14, 32 Turbot Street Brisbane QLD 4000 Locked Bag 331 Brisbane QLD 4001 Australia T F E W
+61 7 3173 8000 +61 7 3173 8001 [email protected] aurecongroup.com
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Appendix C NSW DPI Zoning Map for Currambene
Creek
CURRARONG
#*
#* #*
#*
KinghornPoint
CaramaCreek
BeecroftHead
500 metres
SnakeInlet
Gum GettersInlet
CrocodileHead
PointPerpendicular
#*
#*6A6B
TargetBeach
LongnosePoint
DartPoint
#*
#*7A
7B
GROPER COASTSANCTUARY ZONE
Honeymoon BayBindijine#*
Figtree Inlet
LongBeach
COMMONWEALTH WATERS OF BOODEREENATIONAL PARKRegulations Apply
HARE BAYSANCTUARY ZONE
#* #*
#*
#*
HareBay
Montagu Point
Cabbage Tree Point
Green Point
RedPoint
WOWLY GULLYSANCTUARY ZONE
WowlyGully
CALLALABAY
#*
CALLALABEACH Callala
Point
CallalaCreek
UPPER CURRAMBENE CREEKSANCTUARY ZONE
#*
8C
8B
8A 8D
HUSKISSONSANCTUARY
ZONE
See Inset C
MOONA MOONA CREEKSANCTUARY
ZONE
#*
#*
#*
#*#*
#*
#*
CURRAMBENE CREEK MUDFLATSSANCTUARY ZONE
#*
BowenIsland
See Inset B
HYAMS BEACHSANCTUARY ZONE
Nelson Beach
PlantationPoint
Blenheim Beach
Greenfields Beach
HYAMSBEACH
Sailors Beach
HMAS CRESWELLSPECIAL PURPOSE ZONE
p
p
p
p
p
p
CurrambeneCreek
Bherwerre Peninsula
MoesRock
CapeSt George
ST GEORGES HEAD-STEAMERS HEAD
SANCTUARY ZONE
SteamersBeach
SteamersHead
BrooksRock
St GeorgesHead
KittyPoint
CaveBeach
WreckBay
Bherwerre Beach
SUSSEXINLET
St GeorgesBasin
JervisBay
TheTubes
SANCTUARYPOINT
EROWALBAY
#*
150°
49.
250'
E
150°
37.
500'
E
150°
39.
933'
E
150°
41.
770'
E
150°
44.
300'
E
150°
38.
617'
E
150°
50.
811'
E
150°
45.
817'
E
150°
50.
567'
E
150°
47.
267'
E
150°
43.
733'
E
150°
42.
400'
E
150°
40.
867'
E
150°
44.
950'
E
150°
48.
050'
E
150°
47.
483'
E
35° 5.683' S
35° 5.175' S
35° 4.750' S
35° 5.567' S
35° 3.567' S
35° 4.583' S
35° 1.167' S
35° 1.700' S
35° 4.367' S
35° 3.567' S
34° 58.567' S
34° 59.983' S
35° 11.583' S
35° 12.280' S
35° 12.805' S
35° 11.388' S
34° 59.500' S
34° 57.800' S
34° 59.300' S
150°50'E
150°50'E
150°45'E
150°45'E
150°40'E
150°40'E
150°35'E
150°35'E
35°0
'S
35°0
'S
35°5
'S
35°5
'S
35°1
0'S
35°1
0'S
[
35° 1.767' S
35° 2.467' S
35° 2.733' S15
0° 4
0.86
7' S
150°
41.
533'
S
150°
40.
717'
S
HAMMERHEAD
SANCTUARYZONE
BLACKS CAVE CREEKSANCTUARY ZONE
DRUM & DRUMSTICKSSANCTUARY ZONE
See Inset A
POINTPERPENDICULAR-CROCODILE HEAD
SANCTUARYZONE
THE DOCKSSANCTUARY
ZONE
2A
2B2C
2D
HUSKISSON SANCTUARY ZONE
HUSKISSON WHARF
SPECIAL PURPOSE
ZONE
Inset C
0 250 500
metres
#* #*
#*
#*
#*
#*
#*
#*
#*
CURRAMBENECREEK
MUDFLATSSANCTUARY
ZONEExtends to meanhigh water mark
DRUM & DRUMSTICKSSANCTUARY ZONE
Sanctuary zone extends 50 metres from mean high water mark
Inset B
0 100 200
metres
BOWEN ISLANDSANCTUARY ZONE
BowenIsland
GovernorHead
COMMONWEALTH WATERSRegulations Apply
35° 7.167' S
100 metres
VINCENTIA
HUSKISSON
Collingwood Beach
OrionBeach
p
12A 12B
12C
12D
#*
0 250 500
metres
Jervis Bay Marine ParkZoning Map
Map Projection: Unprojected Geographic. Horizontal Datum: Geodetic Datum of Australia (GDA94) 1:75000 @ A2. Produced April, 2015.
THIS MAP IS NOT TO BE USED FOR NAVIGATION
Sanctuary Zone
Sanctuary Zone (Designated Anchoring Area)
Habitat Protection Zone
Habitat Protection Zone (No Spearf ishing)
Habitat Protection Zone (No Anchoring November to April)
General Use Zone
Special Purpose Zone
Public Mooring (Conditions apply)
Sanctuary Zone Marker
Boat Ramp
Activity Sanctuary Zone
HabitatProtection
Zone
GeneralUse
Zone
SpecialPurpose
Zone
✗ ✓ ✓ ✓
Trapping ✗ ✓ ✓ ✓
✗ ✓ (a) ✓ ✓
Netting ✗ ✓ (b) ✓ ✓ (b)Boating and Water CraftRecreational boating ✓ ✓ ✓ ✓
Personal water craft ✗ (c) ✓ ✓ ✓
Anchoring ✗ (d) ✓ ✓ ✓
Hovercraft P P P PScuba Diving and SnorkellingRecreational ✓ ✓ ✓ ✓
CollectingP P P P
Collecting for aquariums (private)* ✗ P P PCollecting for aquariums (commercial) ✗ ✗ ✗ ✗
Collecting (recreational: bait, ✗ ✓ (e) ✓ ✓ (e)
Competitions✗ P P PP P P P
Commercial Fishing*Trawling ✗ ✗ ✓ ✗
✗ ✓ (f ) ✓ ✗
Purse seine netting (non-saleable only) ✗ ✗ (f ) ✓ ✗
Setline/dropline ✗ ✗ ✓ ✗
Longlining (surface and demersal) ✗ ✗ ✗ ✗
Estuary mesh netting ✗ ✗ ✗ ✗
✗ ✓ ✓ ✓
Hand gathering (pipis and beach worms) ✗ ✓ ✓ ✓
Spanner crab netting ✗ ✓ ✓ ✓
Crab trapping ✗ ✓ ✓ ✓
Lobster trapping ✗ ✓ ✓ ✓
Fish and eel trapping (maximum of 10 traps) ✗ ✓ ✓ ✓
Lift netting for bait (non-saleable only) ✗ ✓ (f ) ✓ ✗
✓
✗
Activity allowedActivity prohibited
* Requires NSW Fishing licence or permit under the Fisheries Management ActP Permission required from the Marine Parks Authority NSW
(a)Protection Zone
(b) Recreational nets permitted for the taking of prawns and crabs in habitat protection zones and special purpose zones are the scoop, landing, scissor (push) or hoop (lift) nets.
(c) Personal watercraft are allowed to traverse sanctuary zones directly to and from the point of launching only, at a maximum speed of ten knots
(d) Anchoring is restricted to designated anchoring areas in some sanctuary zones, see map. Anchoring is allowed in any zone in an emergency where necessary to protect life or property
(e) Restrictions apply to the species that can be collected, see user guide (f)
Permits are non-transferable
##
0 1 2 3 4 5Kilometres
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Appendix D Risk Calculations – Consumption of Fish
and Crustaceans
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Exposure to Chemicals via Ingestion of Fish and Crustaceans - 100% of Diet
(µg/kg/day)
AdultsAverage Upper Estimate
Ingestion Rate of Fish (IRf, kg/day) 0.045 0.123Ingestion Rate of Crustaceans (IRf, kg/day) 0.021 0.063Fraction from site in diet (FI) 100% 100%Exposure Frequency (EF, days/year) 365 365Exposure Duration (ED, years) 35 35Body Weight (BW, kg) 78 78Bioaccessibility (B) 100% 100%Averaging Time - Threshold (Atn, days) 12775 12775
Daily Intake Calculated HQThreshold TDI Background
Intake (% TDI)TDI Allowable for Assessment (TDI-
Background)
Average Upper Estimate Average Upper Estimate Average Upper Estimate
(µg/kg/day) (µg/kg/day) (µg/kg) (µg/kg) (µg/kg/day) (µg/kg/day) (unitless) (unitless)Shoalhaven River SR-B1Australian Bass 2.0E-02 7% 1.9E-02 9.4 9.4 5.4E-03 1.5E-02 0.3 0.8Dusky Flathead 2.0E-02 7% 1.9E-02 4.3 4.3 2.5E-03 6.8E-03 0.1 0.4Estuary Perch 2.0E-02 7% 1.9E-02 1.4 1.4 8.1E-04 2.2E-03 0.04 0.1Sea Mullet 2.0E-02 7% 1.9E-02 2.2 3.4 1.2E-03 5.4E-03 0.1 0.3Tiger Mullet 2.0E-02 7% 1.9E-02 2.8 3.8 1.6E-03 6.0E-03 0.1 0.3Shoalhaven River SR-B2Australian Bass 2.0E-02 7% 1.9E-02 5.3 5.3 3.1E-03 8.4E-03 0.2 0.4Bream 2.0E-02 7% 1.9E-02 1.3 1.3 7.5E-04 2.1E-03 0.04 0.1Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2.0 2.0 1.2E-03 3.2E-03 0.1 0.2Estuary Perch 2.0E-02 7% 1.9E-02 2.3 2.3 1.3E-03 3.6E-03 0.1 0.2Luderick 2.0E-02 7% 1.9E-02 1.2 1.2 6.9E-04 1.9E-03 0.04 0.1Sea Mullet 2.0E-02 7% 1.9E-02 13.9 22 8.0E-03 3.5E-02 0.4 1.9Tiger Mullet 2.0E-02 7% 1.9E-02 20 20 1.2E-02 3.2E-02 0.6 1.7Shoalhaven River SR-B3Australian Bass 2.0E-02 7% 1.9E-02 6.7 6.7 3.9E-03 1.1E-02 0.2 0.6Bream 2.0E-02 7% 1.9E-02 1.2 1.2 6.9E-04 1.9E-03 0.04 0.1Estuary Perch 2.0E-02 7% 1.9E-02 3.6 3.6 2.1E-03 5.7E-03 0.1 0.3Herring 2.0E-02 7% 1.9E-02 8 8 4.6E-03 1.3E-02 0.2 0.7Sand Mullet 2.0E-02 7% 1.9E-02 10 10 5.8E-03 1.6E-02 0.3 0.8Sea Mullet 2.0E-02 7% 1.9E-02 5.4 5.4 3.1E-03 8.5E-03 0.2 0.5Tailor 2.0E-02 7% 1.9E-02 0.9 0.9 5.2E-04 1.4E-03 0.03 0.1Currambene Creek W04Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2.7 2.7 1.6E-03 4.3E-03 0.1 0.2Sea Mullet 2.0E-02 7% 1.9E-02 6.3 6.3 3.6E-03 9.9E-03 0.2 0.5Currambene Creek CC-B2Black Sole 2.0E-02 7% 1.9E-02 367 367 2.1E-01 5.8E-01 11.4 31.1Estuary Perch 2.0E-02 7% 1.9E-02 17.4 18.5 1.0E-02 2.9E-02 0.5 1.6Luderick 2.0E-02 7% 1.9E-02 5.6 6.6 3.2E-03 1.0E-02 0.2 0.6Mulloway 2.0E-02 7% 1.9E-02 15.5 15.5 8.9E-03 2.4E-02 0.5 1.3Sand Whiting 2.0E-02 7% 1.9E-02 12 12 6.9E-03 1.9E-02 0.4 1.0Sea Mullet 2.0E-02 7% 1.9E-02 6.4 6.4 3.7E-03 1.0E-02 0.2 0.5Silver Trevally 2.0E-02 7% 1.9E-02 25.4 39.2 1.5E-02 6.2E-02 0.8 3.3Freshwater Prawn 2.0E-02 7% 1.9E-02 45.3 45.3 1.2E-02 3.7E-02 0.7 2.0Currambene Creek CC-B3Estuary Perch 2.0E-02 7% 1.9E-02 11 11 6.3E-03 1.7E-02 0.3 0.9Luderick 2.0E-02 7% 1.9E-02 1.8 2.5 1.1E-03 3.9E-03 0.1 0.2Sand Whiting 2.0E-02 7% 1.9E-02 1.1 1.6 6.1E-04 2.5E-03 0.03 0.1Sea Mullet 2.0E-02 7% 1.9E-02 3.2 3.5 1.8E-03 5.5E-03 0.1 0.3Silver Trevally 2.0E-02 7% 1.9E-02 3 4.2 1.7E-03 6.6E-03 0.1 0.4Currambene Creek SW14-FAustralian Bass 2.0E-02 7% 1.9E-02 691.0 691.0 4.0E-01 1.1E+00 21.4 58.6Currambene Creek SW13-FYabbie 2.0E-02 7% 1.9E-02 94.0 94.0 2.5E-02 7.6E-02 1.4 4.1
PFAS in edible tissue
Exposure Parameters
PFOS + PFHxS Toxicity Data
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
ChildAverage Upper Estimate
Ingestion Rate of Fish (IRf, kg/day) 0.024 0.073Ingestion Rate of Crustaceans (IRf, kg/day) 0.008 0.021Fraction from site in diet (FI) 100% 100%Exposure Frequency (EF, days/year) 365 365Exposure Duration (ED, years) 5 5Body Weight (BW, kg) 15 15Bioaccessibility (B) 100% 100%Averaging Time - Threshold (Atn, days) 1825 1825
Daily Intake Calculated HQThreshold TDI Background
Intake (% TDI)TDI Allowable for Assessment (TDI-
Background)
Average Upper Estimate Average Upper Estimate Average Upper Estimate
(µg/kg/day) (µg/kg/day) (µg/kg) (µg/kg) (µg/kg/day) (µg/kg/day) (unitless) (unitless)Shoalhaven River SR-B1Australian Bass 2.0E-02 7% 1.9E-02 9.4 9.4 1.5E-02 4.6E-02 0.8 2.5Dusky Flathead 2.0E-02 7% 1.9E-02 4.3 4.3 6.9E-03 2.1E-02 0.4 1.1Estuary Perch 2.0E-02 7% 1.9E-02 1.4 1.4 2.2E-03 6.8E-03 0.1 0.4Sea Mullet 2.0E-02 7% 1.9E-02 2.2 3.4 3.4E-03 1.7E-02 0.2 0.9Tiger Mullet 2.0E-02 7% 1.9E-02 2.8 3.8 4.5E-03 1.8E-02 0.2 1.0Shoalhaven River SR-B2Australian Bass 2.0E-02 7% 1.9E-02 5.3 5.3 8.5E-03 2.6E-02 0.5 1.4Bream 2.0E-02 7% 1.9E-02 1.3 1.3 2.1E-03 6.3E-03 0.11 0.3Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2 2 3.2E-03 9.7E-03 0.2 0.5Estuary Perch 2.0E-02 7% 1.9E-02 2.3 2.3 3.7E-03 1.1E-02 0.2 0.6Luderick 2.0E-02 7% 1.9E-02 1.2 1.2 1.9E-03 5.8E-03 0.10 0.3Sea Mullet 2.0E-02 7% 1.9E-02 13.9 22 2.2E-02 1.1E-01 1.2 5.8Tiger Mullet 2.0E-02 7% 1.9E-02 20 20 3.2E-02 9.7E-02 1.7 5.2Shoalhaven River SR-B3Australian Bass 2.0E-02 7% 1.9E-02 6.7 6.7 1.1E-02 3.3E-02 0.6 1.8Bream 2.0E-02 7% 1.9E-02 1.2 1.2 1.9E-03 5.8E-03 0.10 0.3Estuary Perch 2.0E-02 7% 1.9E-02 3.6 3.6 5.8E-03 1.8E-02 0.3 0.9Herring 2.0E-02 7% 1.9E-02 8 8 1.3E-02 3.9E-02 0.7 2.1Sand Mullet 2.0E-02 7% 1.9E-02 10 10 1.6E-02 4.9E-02 0.9 2.6Sea Mullet 2.0E-02 7% 1.9E-02 5.4 5.4 8.6E-03 2.6E-02 0.5 1.4Tailor 2.0E-02 7% 1.9E-02 0.9 0.9 1.4E-03 4.4E-03 0.1 0.2Currambene Creek W04Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2.7 2.7 4.3E-03 1.3E-02 0.2 0.7Sea Mullet 2.0E-02 7% 1.9E-02 6.3 6.3 1.0E-02 3.1E-02 0.5 1.6Currambene Creek CC-B2Black Sole 2.0E-02 7% 1.9E-02 367 367 5.9E-01 1.8E+00 31.6 96.0Estuary Perch 2.0E-02 7% 1.9E-02 17.4 18.5 2.8E-02 9.0E-02 1.5 4.8Luderick 2.0E-02 7% 1.9E-02 5.6 6.6 9.0E-03 3.2E-02 0.5 1.7Mulloway 2.0E-02 7% 1.9E-02 15.5 15.5 2.5E-02 7.5E-02 1.3 4.1Sand Whiting 2.0E-02 7% 1.9E-02 12.0 12.0 1.9E-02 5.8E-02 1.0 3.1Sea Mullet 2.0E-02 7% 1.9E-02 6.4 6.4 1.0E-02 3.1E-02 0.6 1.7Silver Trevally 2.0E-02 7% 1.9E-02 25.4 39.2 4.1E-02 1.9E-01 2.2 10.3Freshwater Prawn 2.0E-02 7% 1.9E-02 45.3 45.3 2.4E-02 6.3E-02 1.3 3.4Currambene Creek CC-B3Estuary Perch 2.0E-02 7% 1.9E-02 11 11 1.8E-02 5.4E-02 0.9 2.9Luderick 2.0E-02 7% 1.9E-02 1.8 2.5 2.9E-03 1.2E-02 0.2 0.7Sand Whiting 2.0E-02 7% 1.9E-02 1.1 1.6 1.7E-03 7.8E-03 0.1 0.4Sea Mullet 2.0E-02 7% 1.9E-02 3.2 3.5 5.0E-03 1.7E-02 0.3 0.9Silver Trevally 2.0E-02 7% 1.9E-02 3.0 4.2 4.8E-03 2.0E-02 0.3 1.1Currambene Creek SW14-FAustralian Bass 2.0E-02 7% 1.9E-02 691 691 1.1E+00 3.4E+00 59.4 180.8Currambene Creek SW13-FYabbie 2.0E-02 7% 1.9E-02 94 94 5.0E-02 1.3E-01 2.7 7.1
Notes:The scenario evaluates potential health risks for a population that obtains 100% of the fish or prawns that they eat from the Shoalhaven River or Currambene CreekUpper estimate based on the maximum concentration reported at each sampling locationAverage estimate based on the average concentration reported at each sampling location. Average only calculated when 3 or more samples were analysed.Grey shading indicates HI >1.Blue shading indicates HI >2.Orange shading indicates HI > 5. Purple shading indicates HI > 10.
PFAS in edible tissue PFOS + PFHxS Toxicity Data
Exposure Parameters
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Exposure to Chemicals via Ingestion of Fish and Crustaceans - 50% of Diet
(µg/kg/day)
AdultsAverage Upper Estimate
Ingestion Rate of Fish (IRf, kg/day) 0.045 0.123Ingestion Rate of Crustaceans (IRf, kg/day) 0.021 0.063Fraction from site in diet (FI) 100% 100%Exposure Frequency (EF, days/year) 200 200Exposure Duration (ED, years) 35 35Body Weight (BW, kg) 78 78Bioaccessibility (B) 100% 100%Averaging Time - Threshold (Atn, days) 12775 12775
Daily Intake Calculated HQThreshold TDI Background
Intake (% TDI)TDI Allowable for Assessment (TDI-
Background)
Average Upper Estimate Average Upper Estimate Average Upper Estimate
(µg/kg/day) (µg/kg/day) (µg/kg) (µg/kg) (µg/kg/day) (µg/kg/day) (unitless) (unitless)Shoalhaven River SR-B1Australian Bass 2.0E-02 7% 1.9E-02 9.4 9.4 3.0E-03 8.1E-03 0.2 0.4Dusky Flathead 2.0E-02 7% 1.9E-02 4.3 4.3 1.4E-03 3.7E-03 0.1 0.2Estuary Perch 2.0E-02 7% 1.9E-02 1.4 1.4 4.4E-04 1.2E-03 0.02 0.1Sea Mullet 2.0E-02 7% 1.9E-02 2.2 3.4 6.8E-04 2.9E-03 0.04 0.2Tiger Mullet 2.0E-02 7% 1.9E-02 2.8 3.8 8.9E-04 3.3E-03 0.05 0.2Shoalhaven River SR-B2Australian Bass 2.0E-02 7% 1.9E-02 5.3 5.3 1.7E-03 4.6E-03 0.1 0.2Bream 2.0E-02 7% 1.9E-02 1.3 1.3 4.1E-04 1.1E-03 0.02 0.1Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2.0 2 6.3E-04 1.7E-03 0.03 0.1Estuary Perch 2.0E-02 7% 1.9E-02 2.3 2.3 7.3E-04 2.0E-03 0.04 0.1Luderick 2.0E-02 7% 1.9E-02 1.2 1.2 3.8E-04 1.0E-03 0.02 0.1Sea Mullet 2.0E-02 7% 1.9E-02 13.9 22 4.4E-03 1.9E-02 0.2 1.0Tiger Mullet 2.0E-02 7% 1.9E-02 20 20 6.3E-03 1.7E-02 0.3 0.9Shoalhaven River SR-B3Australian Bass 2.0E-02 7% 1.9E-02 6.7 6.7 2.1E-03 5.8E-03 0.1 0.3Bream 2.0E-02 7% 1.9E-02 1.2 1.2 3.8E-04 1.0E-03 0.02 0.1Estuary Perch 2.0E-02 7% 1.9E-02 3.6 3.6 1.1E-03 3.1E-03 0.1 0.2Herring 2.0E-02 7% 1.9E-02 8 8 2.5E-03 6.9E-03 0.1 0.4Sand Mullet 2.0E-02 7% 1.9E-02 10 10 3.2E-03 8.6E-03 0.2 0.5Sea Mullet 2.0E-02 7% 1.9E-02 5.4 5.4 1.7E-03 4.7E-03 0.1 0.3Tailor 2.0E-02 7% 1.9E-02 0.9 0.9 2.8E-04 7.8E-04 0.02 0.04Currambene Creek W04Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2.7 2.7 8.5E-04 2.3E-03 0.05 0.1Sea Mullet 2.0E-02 7% 1.9E-02 6.3 6.3 2.0E-03 5.4E-03 0.1 0.3Currambene Creek CC-B2Black Sole 2.0E-02 7% 1.9E-02 367 367 1.2E-01 3.2E-01 6.2 17.0Estuary Perch 2.0E-02 7% 1.9E-02 17.4 18.5 5.5E-03 1.6E-02 0.3 0.9Luderick 2.0E-02 7% 1.9E-02 5.6 6.6 1.8E-03 5.7E-03 0.1 0.3Mulloway 2.0E-02 7% 1.9E-02 15.5 15.5 4.9E-03 1.3E-02 0.3 0.7Sand Whiting 2.0E-02 7% 1.9E-02 12 12 3.8E-03 1.0E-02 0.2 0.6Sea Mullet 2.0E-02 7% 1.9E-02 6.4 6.4 2.0E-03 5.5E-03 0.1 0.3Silver Trevally 2.0E-02 7% 1.9E-02 25.4 39.2 8.0E-03 3.4E-02 0.4 1.8Freshwater Prawn 2.0E-02 7% 1.9E-02 45.3 45.3 6.7E-03 2.0E-02 0.4 1.1Currambene Creek CC-B3Estuary Perch 2.0E-02 7% 1.9E-02 11 11 3.5E-03 9.5E-03 0.2 0.5Luderick 2.0E-02 7% 1.9E-02 1.8 2.5 5.8E-04 2.2E-03 0.03 0.1Sand Whiting 2.0E-02 7% 1.9E-02 1.1 1.6 3.3E-04 1.4E-03 0.02 0.1Sea Mullet 2.0E-02 7% 1.9E-02 3.2 3.5 1.0E-03 3.0E-03 0.1 0.2Silver Trevally 2.0E-02 7% 1.9E-02 3 4.2 9.5E-04 3.6E-03 0.1 0.2Currambene Creek SW14-FAustralian Bass 2.0E-02 7% 1.9E-02 691 691 2.2E-01 6.0E-01 11.7 32.1Currambene Creek SW13-FYabbie 2.0E-02 7% 1.9E-02 94 94 1.4E-02 4.2E-02 0.7 2.2
Exposure Parameters
PFOS + PFHxS Toxicity Data PFAS in edible tissue
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
ChildAverage Upper Estimate
Ingestion Rate of Fish (IRf, kg/day) 0.024 0.073Ingestion Rate of Crustaceans (IRf, kg/day) 0.008 0.021Fraction from site in diet (FI) 100% 100%Exposure Frequency (EF, days/year) 200 200Exposure Duration (ED, years) 5 5Body Weight (BW, kg) 15 15Bioaccessibility (B) 100% 100%Averaging Time - Threshold (Atn, days) 1825 1825
Daily Intake Calculated HQThreshold TDI Background
Intake (% TDI)TDI Allowable for Assessment (TDI-
Background)
Average Upper Estimate Average Upper Estimate Average Upper Estimate
(µg/kg/day) (µg/kg/day) (µg/kg) (µg/kg) (µg/kg/day) (µg/kg/day) (unitless) (unitless)Shoalhaven River SR-B1Australian Bass 2.0E-02 7% 1.9E-02 9.4 9.4 8.2E-03 2.5E-02 0.4 1.3Dusky Flathead 2.0E-02 7% 1.9E-02 4.3 4.3 3.8E-03 1.1E-02 0.2 0.6Estuary Perch 2.0E-02 7% 1.9E-02 1.4 1.4 1.2E-03 3.7E-03 0.1 0.2Sea Mullet 2.0E-02 7% 1.9E-02 2.2 3.4 1.9E-03 9.1E-03 0.1 0.5Tiger Mullet 2.0E-02 7% 1.9E-02 2.8 3.8 2.5E-03 1.0E-02 0.1 0.5Shoalhaven River SR-B2Australian Bass 2.0E-02 7% 1.9E-02 5.3 5.3 4.6E-03 1.4E-02 0.2 0.8Bream 2.0E-02 7% 1.9E-02 1.3 1.3 1.1E-03 3.5E-03 0.06 0.2Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2 2 1.8E-03 5.3E-03 0.1 0.3Estuary Perch 2.0E-02 7% 1.9E-02 2.3 2.3 2.0E-03 6.1E-03 0.1 0.3Luderick 2.0E-02 7% 1.9E-02 1.2 1.2 1.1E-03 3.2E-03 0.1 0.2Sea Mullet 2.0E-02 7% 1.9E-02 13.9 22 1.2E-02 5.9E-02 0.7 3.2Tiger Mullet 2.0E-02 7% 1.9E-02 20 20 1.8E-02 5.3E-02 0.9 2.9Shoalhaven River SR-B3Australian Bass 2.0E-02 7% 1.9E-02 6.7 6.7 5.9E-03 1.8E-02 0.3 1.0Bream 2.0E-02 7% 1.9E-02 1.2 1.2 1.1E-03 3.2E-03 0.06 0.2Estuary Perch 2.0E-02 7% 1.9E-02 3.6 3.6 3.2E-03 9.6E-03 0.2 0.5Herring 2.0E-02 7% 1.9E-02 8 8 7.0E-03 2.1E-02 0.4 1.1Sand Mullet 2.0E-02 7% 1.9E-02 10 10 8.8E-03 2.7E-02 0.5 1.4Sea Mullet 2.0E-02 7% 1.9E-02 5.4 5.4 4.7E-03 1.4E-02 0.3 0.8Tailor 2.0E-02 7% 1.9E-02 0.9 0.9 7.9E-04 2.4E-03 0.0 0.1Currambene Creek W04Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2.7 2.7 2.4E-03 7.2E-03 0.1 0.4Sea Mullet 2.0E-02 7% 1.9E-02 6.3 6.3 5.5E-03 1.7E-02 0.3 0.9Currambene Creek CC-B2Black Sole 2.0E-02 7% 1.9E-02 367 367 3.2E-01 9.8E-01 17.3 52.6Estuary Perch 2.0E-02 7% 1.9E-02 17.4 18.5 1.5E-02 4.9E-02 0.8 2.7Luderick 2.0E-02 7% 1.9E-02 5.6 6.6 4.9E-03 1.8E-02 0.3 0.9Mulloway 2.0E-02 7% 1.9E-02 15.5 15.5 1.4E-02 4.1E-02 0.7 2.2Sand Whiting 2.0E-02 7% 1.9E-02 12 12 1.1E-02 3.2E-02 0.6 1.7Sea Mullet 2.0E-02 7% 1.9E-02 6.4 6.4 5.6E-03 1.7E-02 0.3 0.9Silver Trevally 2.0E-02 7% 1.9E-02 25.4 39.2 2.2E-02 1.0E-01 1.2 5.6Freshwater Prawn 2.0E-02 7% 1.9E-02 45.3 45.3 1.3E-02 3.5E-02 0.7 1.9Currambene Creek CC-B3Estuary Perch 2.0E-02 7% 1.9E-02 11 11 9.6E-03 2.9E-02 0.5 1.6Luderick 2.0E-02 7% 1.9E-02 1.8 2.5 1.6E-03 6.7E-03 0.1 0.4Sand Whiting 2.0E-02 7% 1.9E-02 1.1 1.6 9.2E-04 4.3E-03 0.05 0.2Sea Mullet 2.0E-02 7% 1.9E-02 3.2 3.5 2.8E-03 9.3E-03 0.1 0.5Silver Trevally 2.0E-02 7% 1.9E-02 3 4.2 2.6E-03 1.1E-02 0.1 0.6Currambene Creek SW14-FAustralian Bass 2.0E-02 7% 1.9E-02 691 691 6.1E-01 1.8E+00 32.6 99.1Currambene Creek SW13-FYabbie 2.0E-02 7% 1.9E-02 94 94 2.7E-02 7.2E-02 1.5 3.9
Notes:The scenario evaluates potential health risks for a population that obtains 50% of the fish or prawns that they eat from the Shoalhaven River or Currambene CreekUpper estimate based on the maximum concentration reported at each sampling locationAverage estimate based on the average concentration reported at each sampling location. Average only calculated when 3 or more samples were analysed.Grey shading indicates HI >1.Blue shading indicates HI >2.Orange shading indicates HI > 5. Purple shading indicates HI > 10.
PFOS + PFHxS Toxicity Data PFAS in edible tissue
Exposure Parameters
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Exposure to Chemicals via Ingestion of Fish and Crustaceans - Weekends
(µg/kg/day)
AdultAverage Upper Estimate
Ingestion Rate of Fish (IRf, kg/day) 0.045 0.123Ingestion Rate of Crustaceans (IRf, kg/day) 0.021 0.063Fraction from site in diet (FI) 100% 100%Exposure Frequency (EF, days/year) 104 104Exposure Duration (ED, years) 35 35Body Weight (BW, kg) 78 78Bioaccessibility (B) 100% 100%Averaging Time - Threshold (Atn, days) 12775 12775
Daily Intake Calculated HQThreshold TDI Background
Intake (% TDI)TDI Allowable for Assessment (TDI-
Background)
Average Upper Estimate Average Upper Estimate Average Upper Estimate
(µg/kg/day) (µg/kg/day) (µg/kg) (µg/kg) (µg/kg/day) (µg/kg/day) (unitless) (unitless)Shoalhaven River SR-B1Australian Bass 2.0E-02 7% 1.9E-02 9.4 9.4 1.5E-03 4.2E-03 0.1 0.2Dusky Flathead 2.0E-02 7% 1.9E-02 4.3 4.3 7.1E-04 1.9E-03 0.04 0.1Estuary Perch 2.0E-02 7% 1.9E-02 1.4 1.4 2.3E-04 6.3E-04 0.01 0.03Sea Mullet 2.0E-02 7% 1.9E-02 2.2 3.4 3.5E-04 1.5E-03 0.02 0.1Tiger Mullet 2.0E-02 7% 1.9E-02 2.8 3.8 4.6E-04 1.7E-03 0.02 0.1Shoalhaven River SR-B2Australian Bass 2.0E-02 7% 1.9E-02 5.3 5.3 8.7E-04 2.4E-03 0.05 0.1Bream 2.0E-02 7% 1.9E-02 1.3 1.3 2.1E-04 5.8E-04 0.01 0.03Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2 2 3.3E-04 9.0E-04 0.02 0.05Estuary Perch 2.0E-02 7% 1.9E-02 2.3 2.3 3.8E-04 1.0E-03 0.02 0.1Luderick 2.0E-02 7% 1.9E-02 1.2 1.2 2.0E-04 5.4E-04 0.01 0.03Sea Mullet 2.0E-02 7% 1.9E-02 13.9 22 2.3E-03 9.9E-03 0.1 0.5Tiger Mullet 2.0E-02 7% 1.9E-02 20 20 3.3E-03 9.0E-03 0.2 0.5Shoalhaven River SR-B3Australian Bass 2.0E-02 7% 1.9E-02 6.7 6.7 1.1E-03 3.0E-03 0.1 0.2Bream 2.0E-02 7% 1.9E-02 1.2 1.2 2.0E-04 5.4E-04 0.01 0.03Estuary Perch 2.0E-02 7% 1.9E-02 3.6 3.6 5.9E-04 1.6E-03 0.03 0.1Herring 2.0E-02 7% 1.9E-02 8.0 8.0 1.3E-03 3.6E-03 0.1 0.2Sand Mullet 2.0E-02 7% 1.9E-02 10 10 1.6E-03 4.5E-03 0.1 0.2Sea Mullet 2.0E-02 7% 1.9E-02 5.4 5.4 8.9E-04 2.4E-03 0.05 0.1Tailor 2.0E-02 7% 1.9E-02 0.9 0.9 1.5E-04 4.0E-04 0.01 0.02Currambene Creek W04Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2.7 2.7 4.4E-04 1.2E-03 0.02 0.1Sea Mullet 2.0E-02 7% 1.9E-02 6.3 6.3 1.0E-03 2.8E-03 0.1 0.2Currambene Creek CC-B2Black Sole 2.0E-02 7% 1.9E-02 367 367 6.0E-02 1.6E-01 3.2 8.9Estuary Perch 2.0E-02 7% 1.9E-02 17.4 18.5 2.9E-03 8.3E-03 0.2 0.4Luderick 2.0E-02 7% 1.9E-02 5.6 6.6 9.3E-04 3.0E-03 0.05 0.2Mulloway 2.0E-02 7% 1.9E-02 15.5 15.5 2.5E-03 7.0E-03 0.1 0.4Sand Whiting 2.0E-02 7% 1.9E-02 12 12 2.0E-03 5.4E-03 0.1 0.3Sea Mullet 2.0E-02 7% 1.9E-02 6.4 6.4 1.1E-03 2.9E-03 0.1 0.2Silver Trevally 2.0E-02 7% 1.9E-02 25.4 39.2 4.2E-03 1.8E-02 0.2 0.9Freshwater Prawn 2.0E-02 7% 1.9E-02 45.3 45.3 3.5E-03 1.0E-02 0.2 0.6Currambene Creek CC-B3Estuary Perch 2.0E-02 7% 1.9E-02 11 11 1.8E-03 4.9E-03 0.1 0.3Luderick 2.0E-02 7% 1.9E-02 1.8 2.5 3.0E-04 1.1E-03 0.02 0.06Sand Whiting 2.0E-02 7% 1.9E-02 1.1 1.6 1.7E-04 7.2E-04 0.01 0.04Sea Mullet 2.0E-02 7% 1.9E-02 3.2 3.5 5.2E-04 1.6E-03 0.03 0.1Silver Trevally 2.0E-02 7% 1.9E-02 3 4.2 4.9E-04 1.9E-03 0.03 0.1Currambene Creek SW14-FAustralian Bass 2.0E-02 7% 1.9E-02 691 691 1.1E-01 3.1E-01 6.1 16.7Currambene Creek SW13-FYabbie 2.0E-02 7% 1.9E-02 94 94 7.2E-03 2.2E-02 0.4 1.2
Exposure Parameters
PFOS + PFHxS Toxicity Data PFAS in edible tissue
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
ChildAverage Upper Estimate
Ingestion Rate of Fish (IRf, kg/day) 0.024 0.073Ingestion Rate of Crustaceans (IRf, kg/day) 0.008 0.021Fraction from site in diet (FI) 100% 100%Exposure Frequency (EF, days/year) 104 104Exposure Duration (ED, years) 5 5Body Weight (BW, kg) 15 15Bioaccessibility (B) 100% 100%Averaging Time - Threshold (Atn, days) 1825 1825
Daily Intake Calculated HQThreshold TDI Background
Intake (% TDI)TDI Allowable for Assessment (TDI-
Background)
Average Upper Estimate Average Upper Estimate Average Upper Estimate
(µg/kg/day) (µg/kg/day) (µg/kg) (µg/kg) (µg/kg/day) (µg/kg/day) (unitless) (unitless)Shoalhaven River SR-B1Australian Bass 2.0E-02 7% 1.9E-02 9.4 9.4 4.3E-03 1.3E-02 0.2 0.7Dusky Flathead 2.0E-02 7% 1.9E-02 4.3 4.3 2.0E-03 6.0E-03 0.1 0.3Estuary Perch 2.0E-02 7% 1.9E-02 1.4 1.4 6.4E-04 1.9E-03 0.03 0.1Sea Mullet 2.0E-02 7% 1.9E-02 2.2 3.4 9.8E-04 4.7E-03 0.1 0.3Tiger Mullet 2.0E-02 7% 1.9E-02 2.8 3.8 1.3E-03 5.3E-03 0.1 0.3Shoalhaven River SR-B2Australian Bass 2.0E-02 7% 1.9E-02 5.3 5.3 2.4E-03 7.3E-03 0.1 0.4Bream 2.0E-02 7% 1.9E-02 1.3 1.3 5.9E-04 1.8E-03 0.03 0.1Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2 2 9.1E-04 2.8E-03 0.05 0.1Estuary Perch 2.0E-02 7% 1.9E-02 2.3 2.3 1.0E-03 3.2E-03 0.1 0.2Luderick 2.0E-02 7% 1.9E-02 1.2 1.2 5.5E-04 1.7E-03 0.03 0.1Sea Mullet 2.0E-02 7% 1.9E-02 13.9 22 6.3E-03 3.1E-02 0.3 1.6Tiger Mullet 2.0E-02 7% 1.9E-02 20 20 9.1E-03 2.8E-02 0.5 1.5Shoalhaven River SR-B3Australian Bass 2.0E-02 7% 1.9E-02 6.7 6.7 3.1E-03 9.3E-03 0.2 0.5Bream 2.0E-02 7% 1.9E-02 1.2 1.2 5.5E-04 1.7E-03 0.03 0.1Estuary Perch 2.0E-02 7% 1.9E-02 3.6 3.6 1.6E-03 5.0E-03 0.1 0.3Herring 2.0E-02 7% 1.9E-02 8 8 3.6E-03 1.1E-02 0.2 0.6Sand Mullet 2.0E-02 7% 1.9E-02 10 10 4.6E-03 1.4E-02 0.2 0.7Sea Mullet 2.0E-02 7% 1.9E-02 5.4 5.4 2.5E-03 7.5E-03 0.1 0.4Tailor 2.0E-02 7% 1.9E-02 0.9 0.9 4.1E-04 1.2E-03 0.02 0.1Currambene Creek W04Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2.7 2.7 1.2E-03 3.7E-03 0.1 0.2Sea Mullet 2.0E-02 7% 1.9E-02 6.3 6.3 2.9E-03 8.7E-03 0.2 0.5Currambene Creek CC-B2Black Sole 2.0E-02 7% 1.9E-02 367 367 1.7E-01 5.1E-01 9.0 27.4Estuary Perch 2.0E-02 7% 1.9E-02 17.4 18.5 7.9E-03 2.6E-02 0.4 1.4Luderick 2.0E-02 7% 1.9E-02 5.6 6.6 2.6E-03 9.2E-03 0.1 0.5Mulloway 2.0E-02 7% 1.9E-02 15.5 15.5 7.1E-03 2.1E-02 0.4 1.2Sand Whiting 2.0E-02 7% 1.9E-02 12.0 12.0 5.5E-03 1.7E-02 0.3 0.9Sea Mullet 2.0E-02 7% 1.9E-02 6.4 6.4 2.9E-03 8.9E-03 0.2 0.5Silver Trevally 2.0E-02 7% 1.9E-02 25.4 39.2 1.2E-02 5.4E-02 0.6 2.9Freshwater Prawn 2.0E-02 7% 1.9E-02 45.3 45.3 6.9E-03 1.8E-02 0.4 1.0Currambene Creek CC-B3Estuary Perch 2.0E-02 7% 1.9E-02 11 11 5.0E-03 1.5E-02 0.3 0.8Luderick 2.0E-02 7% 1.9E-02 1.8 2.5 8.3E-04 3.5E-03 0.04 0.2Sand Whiting 2.0E-02 7% 1.9E-02 1.1 1.6 4.8E-04 2.2E-03 0.03 0.1Sea Mullet 2.0E-02 7% 1.9E-02 3.2 3.5 1.4E-03 4.9E-03 0.1 0.3Silver Trevally 2.0E-02 7% 1.9E-02 3.0 4.2 1.4E-03 5.8E-03 0.1 0.3Currambene Creek SW14-FAustralian Bass 2.0E-02 7% 1.9E-02 691 691 3.2E-01 9.6E-01 16.9 51.5Currambene Creek SW13-FYabbie 2.0E-02 7% 1.9E-02 94 94 1.4E-02 3.7E-02 0.8 2.0
Notes:Upper estimate based on the maximum concentration reported at each sampling locationAverage estimate based on the average concentration reported at each sampling location. Average only calculated when 3 or more samples were analysed.Grey shading indicates HI >1.Blue shading indicates HI >2.Orange shading indicates HI > 5. Purple shading indicates HI > 10.
PFOS + PFHxS Toxicity Data PFAS in edible tissue
Exposure Parameters
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Exposure to Chemicals via Ingestion of Fish and Crustaceans - Summer Holidays
(µg/kg/day)
AdultsAverage Upper Estimate
Ingestion Rate of Fish (IRf, kg/day) 0.045 0.123Ingestion Rate of Crustaceans (IRf, kg/day) 0.021 0.063Fraction from site in diet (FI) 100% 100%Exposure Frequency (EF, days/year) 28 28Exposure Duration (ED, years) 35 35Body Weight (BW, kg) 78 78Bioaccessibility (B) 100% 100%Averaging Time - Threshold (Atn, days) 12775 12775
Daily Intake Calculated HQThreshold TDI Background
Intake (% TDI)TDI Allowable for Assessment (TDI-
Background)
Average Upper Estimate Average Upper Estimate Average Upper Estimate
(µg/kg/day) (µg/kg/day) (µg/kg) (µg/kg) (µg/kg/day) (µg/kg/day) (unitless) (unitless)Shoalhaven River SR-B1Australian Bass 2.0E-02 7% 1.9E-02 9.4 9.4 4.2E-04 1.1E-03 0.02 0.1Dusky Flathead 2.0E-02 7% 1.9E-02 4.3 4.3 1.9E-04 5.2E-04 0.01 0.03Estuary Perch 2.0E-02 7% 1.9E-02 1.4 1.4 6.2E-05 1.7E-04 0.003 0.01Sea Mullet 2.0E-02 7% 1.9E-02 2.2 3.4 9.5E-05 4.1E-04 0.01 0.02Tiger Mullet 2.0E-02 7% 1.9E-02 2.8 3.8 1.2E-04 4.6E-04 0.01 0.02Shoalhaven River SR-B2Australian Bass 2.0E-02 7% 1.9E-02 5.3 5.3 2.3E-04 6.4E-04 0.01 0.03Bream 2.0E-02 7% 1.9E-02 1.3 1.3 5.8E-05 1.6E-04 0.003 0.01Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2 2 8.9E-05 2.4E-04 0.005 0.01Estuary Perch 2.0E-02 7% 1.9E-02 2.3 2.3 1.0E-04 2.8E-04 0.01 0.01Luderick 2.0E-02 7% 1.9E-02 1.2 1.2 5.3E-05 1.5E-04 0.003 0.01Sea Mullet 2.0E-02 7% 1.9E-02 13.9 22 6.2E-04 2.7E-03 0.03 0.1Tiger Mullet 2.0E-02 7% 1.9E-02 20 20 8.9E-04 2.4E-03 0.05 0.1Shoalhaven River SR-B3Australian Bass 2.0E-02 7% 1.9E-02 6.7 6.7 3.0E-04 8.1E-04 0.02 0.04Bream 2.0E-02 7% 1.9E-02 1.2 1.2 5.3E-05 1.5E-04 0.003 0.01Estuary Perch 2.0E-02 7% 1.9E-02 3.6 3.6 1.6E-04 4.4E-04 0.01 0.02Herring 2.0E-02 7% 1.9E-02 8 8 3.5E-04 9.7E-04 0.02 0.1Sand Mullet 2.0E-02 7% 1.9E-02 10 10 4.4E-04 1.2E-03 0.02 0.1Sea Mullet 2.0E-02 7% 1.9E-02 5.4 5.4 2.4E-04 6.5E-04 0.01 0.04Tailor 2.0E-02 7% 1.9E-02 0.9 0.9 4.0E-05 1.1E-04 0.002 0.01Currambene Creek W04Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2.7 2.7 1.2E-04 3.3E-04 0.01 0.02Sea Mullet 2.0E-02 7% 1.9E-02 6.3 6.3 2.8E-04 7.6E-04 0.01 0.04Currambene Creek CC-B2Black Sole 2.0E-02 7% 1.9E-02 367 367 1.6E-02 4.4E-02 0.9 2.4Estuary Perch 2.0E-02 7% 1.9E-02 17.4 18.5 7.7E-04 2.2E-03 0.04 0.1Luderick 2.0E-02 7% 1.9E-02 5.6 6.6 2.5E-04 8.0E-04 0.01 0.04Mulloway 2.0E-02 7% 1.9E-02 15.5 15.5 6.9E-04 1.9E-03 0.04 0.1Sand Whiting 2.0E-02 7% 1.9E-02 12 12 5.3E-04 1.5E-03 0.03 0.1Sea Mullet 2.0E-02 7% 1.9E-02 6.4 6.4 2.8E-04 7.7E-04 0.02 0.04Silver Trevally 2.0E-02 7% 1.9E-02 25.4 39.2 1.1E-03 4.7E-03 0.1 0.3Freshwater Prawn 2.0E-02 7% 1.9E-02 45.3 45.3 9.4E-04 2.8E-03 0.1 0.2Currambene Creek CC-B3Estuary Perch 2.0E-02 7% 1.9E-02 11 11 4.9E-04 1.3E-03 0.03 0.1Luderick 2.0E-02 7% 1.9E-02 1.8 2.5 8.1E-05 3.0E-04 0.004 0.02Sand Whiting 2.0E-02 7% 1.9E-02 1.1 1.6 4.6E-05 1.9E-04 0.002 0.01Sea Mullet 2.0E-02 7% 1.9E-02 3.2 3.5 1.4E-04 4.2E-04 0.01 0.02Silver Trevally 2.0E-02 7% 1.9E-02 3 4.2 1.3E-04 5.1E-04 0.01 0.03Currambene Creek SW14-FAustralian Bass 2.0E-02 7% 1.9E-02 691 691 3.1E-02 8.4E-02 1.6 4.5Currambene Creek SW13-FYabbie 2.0E-02 7% 1.9E-02 94 94 1.9E-03 5.8E-03 0.1 0.3
Exposure Parameters
PFOS + PFHxS Toxicity Data PFAS in edible tissue
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
ChildAverage Upper Estimate
Ingestion Rate of Fish (IRf, kg/day) 0.024 0.073Ingestion Rate of Crustaceans (IRf, kg/day) 0.008 0.021Fraction from site in diet (FI) 100% 100%Exposure Frequency (EF, days/year) 28 28Exposure Duration (ED, years) 5 5Body Weight (BW, kg) 15 15Bioaccessibility (B) 100% 100%Averaging Time - Threshold (Atn, days) 1825 1825
Daily Intake Calculated HQThreshold TDI Background
Intake (% TDI)TDI Allowable for Assessment (TDI-
Background)
Average Upper Estimate Average Upper Estimate Average Upper Estimate
(µg/kg/day) (µg/kg/day) (µg/kg) (µg/kg) (µg/kg/day) (µg/kg/day) (unitless) (unitless)Shoalhaven River SR-B1Australian Bass 2.0E-02 7% 1.9E-02 9.4 9.4 1.2E-03 3.5E-03 0.1 0.2Dusky Flathead 2.0E-02 7% 1.9E-02 4.3 4.3 5.3E-04 1.6E-03 0.03 0.1Estuary Perch 2.0E-02 7% 1.9E-02 1.4 1.4 1.7E-04 5.2E-04 0.01 0.03Sea Mullet 2.0E-02 7% 1.9E-02 2.2 3.4 2.6E-04 1.3E-03 0.01 0.1Tiger Mullet 2.0E-02 7% 1.9E-02 2.8 3.8 3.4E-04 1.4E-03 0.02 0.1Shoalhaven River SR-B2Australian Bass 2.0E-02 7% 1.9E-02 5.3 5.3 6.5E-04 2.0E-03 0.03 0.1Bream 2.0E-02 7% 1.9E-02 1.3 1.3 1.6E-04 4.9E-04 0.01 0.03Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2 2 2.5E-04 7.5E-04 0.01 0.04Estuary Perch 2.0E-02 7% 1.9E-02 2.3 2.3 2.8E-04 8.6E-04 0.02 0.05Luderick 2.0E-02 7% 1.9E-02 1.2 1.2 1.5E-04 4.5E-04 0.01 0.02Sea Mullet 2.0E-02 7% 1.9E-02 13.9 22 1.7E-03 8.2E-03 0.1 0.4Tiger Mullet 2.0E-02 7% 1.9E-02 20 20 2.5E-03 7.5E-03 0.1 0.4Shoalhaven River SR-B3Australian Bass 2.0E-02 7% 1.9E-02 6.7 6.7 8.2E-04 2.5E-03 0.04 0.1Bream 2.0E-02 7% 1.9E-02 1.2 1.2 1.5E-04 4.5E-04 0.01 0.02Estuary Perch 2.0E-02 7% 1.9E-02 3.6 3.6 4.4E-04 1.3E-03 0.02 0.1Herring 2.0E-02 7% 1.9E-02 8 8 9.8E-04 3.0E-03 0.1 0.2Sand Mullet 2.0E-02 7% 1.9E-02 10 10 1.2E-03 3.7E-03 0.1 0.2Sea Mullet 2.0E-02 7% 1.9E-02 5.4 5.4 6.6E-04 2.0E-03 0.04 0.1Tailor 2.0E-02 7% 1.9E-02 0.9 0.9 1.1E-04 3.4E-04 0.01 0.02Currambene Creek W04Eastern Sea Garfish 2.0E-02 7% 1.9E-02 2.7 2.7 3.3E-04 1.0E-03 0.02 0.1Sea Mullet 2.0E-02 7% 1.9E-02 6.3 6.3 7.7E-04 2.4E-03 0.04 0.1Currambene Creek CC-B2Black Sole 2.0E-02 7% 1.9E-02 367 367 4.5E-02 1.4E-01 2.4 7.4Estuary Perch 2.0E-02 7% 1.9E-02 17.4 18.5 2.1E-03 6.9E-03 0.1 0.4Luderick 2.0E-02 7% 1.9E-02 5.6 6.6 6.9E-04 2.5E-03 0.04 0.1Mulloway 2.0E-02 7% 1.9E-02 15.5 15.5 1.9E-03 5.8E-03 0.1 0.3Sand Whiting 2.0E-02 7% 1.9E-02 12.0 12.0 1.5E-03 4.5E-03 0.1 0.2Sea Mullet 2.0E-02 7% 1.9E-02 6.4 6.4 7.9E-04 2.4E-03 0.04 0.1Silver Trevally 2.0E-02 7% 1.9E-02 25.4 39.2 3.1E-03 1.5E-02 0.2 0.8Freshwater Prawn 2.0E-02 7% 1.9E-02 45.3 45.3 1.9E-03 4.9E-03 0.1 0.3Currambene Creek CC-B3Estuary Perch 2.0E-02 7% 1.9E-02 11 11 1.4E-03 4.1E-03 0.1 0.2Luderick 2.0E-02 7% 1.9E-02 1.8 2.5 2.2E-04 9.3E-04 0.01 0.1Sand Whiting 2.0E-02 7% 1.9E-02 1.1 1.6 1.3E-04 6.0E-04 0.01 0.03Sea Mullet 2.0E-02 7% 1.9E-02 3.2 3.5 3.9E-04 1.3E-03 0.02 0.1Silver Trevally 2.0E-02 7% 1.9E-02 3.0 4.2 3.7E-04 1.6E-03 0.02 0.1Currambene Creek SW14-FAustralian Bass 2.0E-02 7% 1.9E-02 691 691 8.5E-02 2.6E-01 4.6 13.9Currambene Creek SW13-FYabbie 2.0E-02 7% 1.9E-02 94 94 3.8E-03 1.0E-02 0.2 0.5
Notes:Upper estimate based on the maximum concentration reported at each sampling locationAverage estimate based on the average concentration reported at each sampling location. Average only calculated when 3 or more samples were analysed.Grey shading indicates HI >1.Blue shading indicates HI >2.Orange shading indicates HI > 5. Purple shading indicates HI > 10.
PFOS + PFHxS Toxicity Data PFAS in edible tissue
Exposure Parameters
Addendum Human Health and Ecological Risk Assessment for PFAS: HMAS Albatross Ref: AU/18/ALBR003-C
Appendix E Shoalhaven River Biota Data from NSW
DPI
Bridge (17 km upstream of ocean)
Proposed sampling region for PFOS Shoalhaven River reference sites
Lake Wollumboolafor king prawns and blue crabs
DRAFT
Location Site Common name Type Received Blended Sample
Weight /g
PFOA (Perfluor
o-n-octanoic
acid)
PFHxS (Perfluor
o-n-hexanesulfonate)
PFOS (Perfluoro-n-octanesulfo
nate)
(6:2FTS) C2H4-
perfluoro-octane
sulfonate
(8:2FTS) C2H4-
perfluoro-decane
sulfonate
Perfluorooctanoic
Acid (PFOA) (LOR)
Perfluorooctanesulphon
ate (LOR)
6:2 FTS (LOR)
8:2 FTS (LOR) Extracted LCMSMS
Analysis
1 Shoalhaven River
School Prawn Muscle/vein 5/02/2016 Y 1.01 g <0.0003 0.0014 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 5/02/2016 10/02/2016
1 Shoalhaven River
School Prawn Muscle/vein 5/02/2016 Y 1.09 g <0.0003 0.0017 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 5/02/2016 10/02/2016
1 Shoalhaven River
School Prawn Muscle/vein 5/02/2016 Y 1.02 g <0.0003 0.002 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 5/02/2016 10/02/2016
1 Shoalhaven River
School Prawn Muscle/vein 5/02/2016 Y 1.13 g <0.0003 0.0014 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 5/02/2016 10/02/2016
3 Shoalhaven River Luderick Muscle 5/02/2016 Y 1.10 g <0.0003 0.0014 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 5/02/2016 10/02/2016
3 Shoalhaven River Luderick Muscle 5/02/2016 Y 1.09 g <0.0003 0.0019 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 5/02/2016 10/02/2016
3 Shoalhaven River Luderick Muscle 5/02/2016 Y 1.08 g <0.0003 0.0021 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 5/02/2016 10/02/2016
3 Shoalhaven River Luderick Muscle 5/02/2016 Y 1.13 g <0.0003 0.0018 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 5/02/2016 10/02/2016
1 Shoalhaven River Silver Biddy Muscle 10/02/2016 Y 1.10 g <0.0003 0.0011 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
1 Shoalhaven River Silver Biddy Muscle 10/02/2016 Y 1.19 g <0.0003 0.0025 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
1 Shoalhaven River Silver Biddy Muscle 10/02/2016 Y 1.08 g <0.0003 0.0033 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
1 Shoalhaven River Silver Biddy Muscle 10/02/2016 Y 1.08 g <0.0003 0.001 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
2 Shoalhaven River Luderick Muscle 10/02/2016 Y 1.20 g <0.0003 0.0021 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
2 Shoalhaven River Luderick Muscle 10/02/2016 Y 1.13 g <0.0003 0.0015 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
2 Shoalhaven River Luderick Muscle 10/02/2016 Y 1.19 g <0.0003 0.0017 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
2 Shoalhaven River Luderick Muscle 10/02/2016 Y 1.00 g <0.0003 0.0023 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
2 Shoalhaven River Sea Mullet Muscle 10/02/2016 Y 1.06 g <0.0003 0.0015 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
2 Shoalhaven River Sea Mullet Muscle 10/02/2016 Y 1.13 g <0.0003 0.0015 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
2 Shoalhaven River Sea Mullet Muscle 10/02/2016 Y 1.15 g <0.0003 0.0019 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
2 Shoalhaven River Sea Mullet Muscle 10/02/2016 Y 1.18 g <0.0003 0.0017 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
3 Shoalhaven River Sea Mullet Muscle 10/02/2016 Y 1.19 g <0.0003 0.003 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
3 Shoalhaven River Sea Mullet Muscle 10/02/2016 Y 1.12 g <0.0003 0.0047 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
3 Shoalhaven River Sea Mullet Muscle 10/02/2016 Y 1.13 g <0.0003 0.0026 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
3 Shoalhaven River Sea Mullet Muscle 10/02/2016 Y 1.08 g <0.0003 0.0017 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
3 Shoalhaven River
Yellowfin Bream Muscle 10/02/2016 Y 1.06 g <0.0003 0.00081 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
3 Shoalhaven River
Yellowfin Bream Muscle 10/02/2016 Y 1.00 g <0.0003 0.0009 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
3 Shoalhaven River
Yellowfin Bream Muscle 10/02/2016 Y 1.20 g <0.0003 0.0011 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
3 Shoalhaven River
Yellowfin Bream Muscle 10/02/2016 Y 1.08 g <0.0003 0.0014 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
4 Shoalhaven River
School Prawn Muscle 10/02/2016 Y 1.05 g <0.0003 0.0071 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
4 Shoalhaven River
School Prawn Muscle 10/02/2016 Y 1.06 g <0.0003 0.0082 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
4 Shoalhaven River
School Prawn Muscle 10/02/2016 Y 1.18 g <0.0003 0.01 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
4 Shoalhaven River
School Prawn Muscle 10/02/2016 Y 1.17 g <0.0003 0.0056 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
4 Shoalhaven River Silver Biddy Muscle 10/02/2016 Y 1.09 g <0.0003 0.01 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
4 Shoalhaven River Silver Biddy Muscle 10/02/2016 Y 1.06 g <0.0003 0.012 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
4 Shoalhaven River Silver Biddy Muscle 10/02/2016 Y 1.16 g <0.0003 0.011 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
4 Shoalhaven River Silver Biddy Muscle 10/02/2016 Y 1.07 g <0.0003 0.01 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 10/02/2016 15/02/2016
1 Shoalhaven River
Dusky Flathead Muscle 1/03/2016 Y 1.07 g <0.0003 0.0015 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 4/03/2016 8/03/2016
1 Shoalhaven River
Dusky Flathead Muscle 1/03/2016 Y 1.17 g <0.0003 0.0023 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 4/03/2016 8/03/2016
1 Shoalhaven River
Dusky Flathead Muscle 1/03/2016 Y 1.05 g <0.0003 0.0027 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 4/03/2016 8/03/2016
1 Shoalhaven River
Dusky Flathead Muscle 1/03/2016 Y 1.21 g <0.0003 0.0019 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 4/03/2016 8/03/2016
4 Shoalhaven River Sea Mullet Muscle 1/03/2016 Y 1.10 g <0.0003 0.006 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 4/03/2016 8/03/2016
4 Shoalhaven River Sea Mullet Muscle 1/03/2016 Y 1.20 g <0.0003 0.006 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 4/03/2016 8/03/2016
4 Shoalhaven River Sea Mullet Muscle 1/03/2016 Y 1.01 g <0.0003 0.0058 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 4/03/2016 8/03/2016
4 Shoalhaven River Sea Mullet Muscle 1/03/2016 Y 1.13 g <0.0003 0.0051 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 4/03/2016 8/03/2016
5 Shoalhaven River
School Prawn Muscle/vein 16/03/2016 Y 1.12 g <0.0003 0.0053 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 30/03/2016 4/04/2016
5 Shoalhaven River
School Prawn Muscle/vein 16/03/2016 Y 1.10 g <0.0003 0.0031 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 30/03/2016 4/04/2016
5 Shoalhaven River
School Prawn Muscle/vein 16/03/2016 Y 1.15 g <0.0003 0.0044 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 30/03/2016 4/04/2016
5 Shoalhaven River
School Prawn Muscle/vein 16/03/2016 Y 1.14 g <0.0003 0.0037 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 30/03/2016 4/04/2016
6 Shoalhaven River
School Prawn Muscle/vein 16/03/2016 Y 1.07 g <0.0003 0.0018 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 30/03/2016 4/04/2016
6 Shoalhaven River
School Prawn Muscle/vein 16/03/2016 Y 1.15 g <0.0003 0.0016 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 30/03/2016 4/04/2016
6 Shoalhaven River
School Prawn Muscle/vein 16/03/2016 Y 1.15 g <0.0003 0.0038 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 30/03/2016 4/04/2016
6 Shoalhaven River
School Prawn Muscle/vein 16/03/2016 Y 1.16 g <0.0003 0.0015 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 30/03/2016 4/04/2016
1 Shoalhaven River
Sand Whiting Muscle 23/03/2016 Y 1.16 g <0.0003 0.00044 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 31/03/2016 7/04/2016
1 Shoalhaven River
Sand Whiting Muscle 23/03/2016 Y 1.15 g <0.0003 0.00047 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 31/03/2016 7/04/2016
1 Shoalhaven River
Sand Whiting Muscle 23/03/2016 Y 1.10 g <0.0003 0.00038 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 31/03/2016 7/04/2016
1 Shoalhaven River
Sand Whiting Muscle 23/03/2016 Y 1.18 g <0.0003 0.00039 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 31/03/2016 7/04/2016
1 Shoalhaven River
Luderick Muscle 7/04/2016 Y 1.13 g <0.0003 0.0022 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
1 Shoalhaven River
Luderick Muscle 7/04/2016 Y 1.16 g <0.0003 0.0023 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
1 Shoalhaven River
Luderick Muscle 7/04/2016 Y 1.11 g <0.0003 0.0023 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
1 Shoalhaven River
Luderick Muscle 7/04/2016 Y 1.03 g <0.0003 0.0023 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
4 Shoalhaven River
Sand Whiting
Muscle 13/04/2016 Y 1.04 g <0.0003 0.0035 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/08/2016
4 Shoalhaven River
Sand Whiting
Muscle 13/04/2016 Y 1.06 g <0.0003 0.0034 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/08/2016
4 Shoalhaven River
Sand Whiting
Muscle 13/04/2016 Y 1.08 g <0.0003 0.0027 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/08/2016
DRAFT
Location Site Common name Type Received Blended Sample
Weight /g
PFOA (Perfluor
o-n-octanoic
acid)
PFHxS (Perfluor
o-n-hexanesulfonate)
PFOS (Perfluoro-n-octanesulfo
nate)
(6:2FTS) C2H4-
perfluoro-octane
sulfonate
(8:2FTS) C2H4-
perfluoro-decane
sulfonate
Perfluorooctanoic
Acid (PFOA) (LOR)
Perfluorooctanesulphon
ate (LOR)
6:2 FTS (LOR)
8:2 FTS (LOR) Extracted LCMSMS
Analysis
4 Shoalhaven River
Sand Whiting
Muscle 13/04/2016 Y 1.15 g <0.0003 0.0028 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/08/2016
3 Shoalhaven River
Yellowfin Bream
Muscle 21/04/2016 Y 1.19 g <0.0003 0.001 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
3 Shoalhaven River
Yellowfin Bream
Muscle 21/04/2016 Y 1.17 g <0.0003 0.0013 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
3 Shoalhaven River
Yellowfin Bream
Muscle 21/04/2016 Y 1.18 g <0.0003 0.0014 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
4 Shoalhaven River
Dusky Flathead
Muscle 26/04/2016 Y 1.17 g <0.0003 0.0083 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
4 Shoalhaven River
Dusky Flathead
Muscle 26/04/2016 Y 1.04 g <0.0003 0.0067 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
4 Shoalhaven River
Dusky Flathead
Muscle 26/04/2016 Y 1.18 g <0.0003 0.0067 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
4 Shoalhaven River
Dusky Flathead
Muscle 26/04/2016 Y 1.08 g <0.0003 0.0057 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
3 Shoalhaven River
Sand Whiting
Muscle 21/04/2016 Y 1.01 g <0.0003 0.0012 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
3 Shoalhaven River
Sand Whiting
Muscle 21/04/2016 Y 1.07 g <0.0003 0.0013 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
3 Shoalhaven River
Sand Whiting
Muscle 21/04/2016 Y 1.16 g <0.0003 0.0016 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
3 Shoalhaven River
Sand Whiting
Muscle 21/04/2016 Y 0.11 g <0.0003 0.0022 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
3 Shoalhaven River
Dusky Flathead
Muscle 21/04/2016 Y 1.06 g <0.0003 0.0049 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
3 Shoalhaven River
Dusky Flathead
Muscle 21/04/2016 Y 1.02 g <0.0003 0.0054 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
3 Shoalhaven River
Dusky Flathead
Muscle 21/04/2016 Y 1.02 g <0.0003 0.005 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
3 Shoalhaven River
Dusky Flathead
Muscle 21/04/2016 Y 1.20 g <0.0003 0.0044 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Yellowfin Bream
Muscle 21/04/2016 Y 1.16 g <0.0003 0.00052 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Yellowfin Bream
Muscle 21/04/2016 Y 1.17 g <0.0003 0.00038 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Yellowfin Bream
Muscle 21/04/2016 Y 1.09 g <0.0003 0.00052 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Yellowfin Bream
Muscle 21/04/2016 Y 1.13 g <0.0003 0.00038 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Sand Whiting
Muscle 21/04/2016 Y 1.06 g <0.0003 0.00062 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Sand Whiting
Muscle 21/04/2016 Y 1.18 g <0.0003 0.00057 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Sand Whiting
Muscle 21/04/2016 Y 1.08 g <0.0003 0.00075 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Sand Whiting
Muscle 21/04/2016 Y 1.04 g <0.0003 0.00067 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Dusky Flathead
Muscle 21/04/2016 Y 1.08 g <0.0003 0.0045 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Dusky Flathead
Muscle 21/04/2016 Y 1.05 g <0.0003 0.0044 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Dusky Flathead
Muscle 21/04/2016 Y 1.06 g <0.0003 0.0039 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 11/05/2016
2 Shoalhaven River
Dusky Flathead
Muscle 26/04/2016 <0.0003 0.0057 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/08/2016
2 Shoalhaven River
Silver Biddy Muscle 21/04/2016 Y 1.06 g <0.0003 0.0027 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 16/05/2016
2 Shoalhaven River
Silver Biddy Muscle 21/04/2016 Y 1.20 g <0.0003 0.0044 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 16/05/2016
2 Shoalhaven River
Silver Biddy Muscle 21/04/2016 Y 1.12 g <0.0003 0.0028 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 16/05/2016
3 Shoalhaven River
Silver Biddy Muscle 21/04/2016 Y 1.11 g <0.0003 0.0041 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 16/05/2016
2 Shoalhaven River
Mud Crab Muscle 26/04/2016 Y 1.19 g <0.0003 0.0017 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 16/05/2016
1 Shoalhaven River
Mud Crab Muscle 26/04/2016 Y 1.09 g <0.0003 0.0011 <0.0005 <0.0005 <0.0003 <0.0003 <0.0005 <0.0005 6/05/2016 16/05/2016
4 Shoalhaven River
Bream Muscle 8/05/2016 <0.0003 0.0023 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/08/2016
4 Shoalhaven River
Bream Muscle 8/05/2016 <0.0003 0.0018 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/08/2016
4 Shoalhaven River
Bream Muscle 8/05/2016 <0.0003 0.0025 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/08/2016
4 Shoalhaven River
Bream Muscle 8/05/2016 <0.0003 0.0023 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/08/2016
4 Shoalhaven River
Luderick Muscle 8/05/2016 Y 1.17 g <0.0003 0.0055 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
4 Shoalhaven River
Luderick Muscle 8/05/2016 Y 1.09 g <0.0003 0.0042 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
4 Shoalhaven River
Luderick Muscle 8/05/2016 Y 1.06 g <0.0003 0.0046 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
4 Shoalhaven River
Luderick Muscle 8/05/2016 Y 1.06 g <0.0003 0.0049 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
1 Shoalhaven River
Bream Muscle 8/05/2016 Y 1.14 g <0.0003 <0.0003 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
1 Shoalhaven River
Bream Muscle 8/05/2016 Y 1.11 g <0.0003 <0.0003 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
1 Shoalhaven River
Bream Muscle 8/05/2016 Y 1.09 g <0.0003 <0.0003 <0.0005 <0.0005 0.0003 0.0003 0.0005 0.0005 31/05/2016 6/06/2016
DRAFT