Subject Index

A

Acetaldehyde degradationMCM-48 mesoporous materials, 185fMn doped TiO2-SiO2 aerogels, 219fsilica-supported silver halidephotocatalysts, 198f

Acetaldehyde photocatalysis, 210Advanced lubrication, 144additives, 140

Aerosol particle sizeand epithelial lining fluid, 226

Air filtrationacetaldehyde, 87, 91fASZM-TEDA carbon, 87, 91fbreakthrough apparatus, 84, 86f, 88fnanoActive ZnO sorbent, breakthroughcurves, 84, 88f

nanocrystalline sorbents, 81removal capacities, 86, 90f, 91f

Air purificationand TiO2-SiO2-Mn aerogel, 207

α-FeOOH nanorods, 26α-FeOOH nanorods and microrodscharacterization, 26oxalate-promoted dissolution, 26, 28f,30f

Aluminosilicate, 18fAuger analysis, 156f, 158f

B

Bacillus Anthracis, 7, 8fBacillus Subtillus, 7BAL. See Broncheoalvelolar lavage fluidBiocidal nanoscale materials, 6Block-on-ring tribological testing, 151ffriction and wear scar volume, 154, 155f

Boundary lubrication regime, 139Broncheoalvelolar lavage fluid, TiO2exposure, 27f

C

Catalysts, MgOsunflower oil, transesterification, 66, 67t

triglyceride and methanol,transesterification, 67t

Catalytic transition metal ions, destructiveadsorption, 7DMMP, 7, 9fVClx exchanges Cl-/O2-, 10f

CCl4 reduction, zero-valent metals, 165,168s, 169f, 170t, 173f, 174f

2-CEES. See 2-Chloroethylethyl sulfideCeO2 (111), 71, 73fChemical warfare agentsand candidate reactive sorbentsdeposition, 130treactivity ranking, 133tshortest sustained half-lives, 133t

CARC panel decontamination, 134tand nanosize metal oxides, 125

2-Chloroethylethyl sulfideapparent quantum yields, 180, 181fdestructive adsorption on AP-MgO, 5, 6f

Claisen-Schmidt condensation, 70fClean coal technologies, 89CO2 temperature programmed desorption,67, 69f

CO-Al-MCM-41 system, 182tCopper oxide sorbents, mercurybreakthrough plot, 93f, 94

CO2-TPD. See CO2 temperatureprogrammed desorption

CWA. See Chemical warfare agents

D

Destructive adsorbents, 2, 6Destructive adsorptionand catalytic transition metal ions, 7DMMP, 8, 9f

Digestive ripeningdefinition, 39ligands, 37, 40tmaterials, 37, 40tnanoparticle colloids, 39, 42fpolydisperse colloid transformation, 37,40f

Dimethylmethyl phosphate. See DMMPDMMP, 8, 9fDry milling process, 149

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E

Environmental applications,nano-catalysts, 7

Environmental processes, oxide-basednanomaterials, 15, 31

Environmental remediationsemiconductor photocatalysis, 110, 116silica-supported silver halidephotocatalysts, 194

sorbents, 2visible and UV light photocatalysts, 179

Environmental technology, merging areas,167f

Epithelial lining fluidaerosol particle size, 226, 229solubility and dissolution rate, 228

F

FAST-ACTchemical warfare agents, removal, 241,241f

developments, 235efficacy, 239, 240t, 243hazardous vapors, removal, 239, 239fmarketing and sales, 247and nanocrystalline MgO and TiO2, 237,237f

product manufacture, 243products, 236, 236fquality control, 243shelf life, 243and spill countermeasure technologies,245, 246t

and toxicity, 244t, 245utilization, 237f

FAST-ACT formulationparticle size distribution, 237, 238fSEM image, 237, 238fshelf-life, 243f

FeOOH nanorods, 26Four-ball test tribological testing, 151fcoefficient of friction, 153f, 154wear scar diameter, 153, 154

G

Gas-phase heterogeneous photocatalysisacetaldehyde degradation, 198freactor, 198f

silica-supported silver halidephotocatalysts, 199

H

Heterogeneous photocatalysisgas-phase, 199liquid-phase, 200

Human skin, nanoparticle penetration, 228Hybrid chemo-mechanical milling, 147ball mill SPEX8000D, 145f, 147MoS2, 146f, 147

Hybrid milled MoS2−ZDDP tribofilmAuger analysis, 158f, 159fTOF-SIMS analysis, 160, 160fXPS analysis, 158f, 159f

Hybrid milling process, 149f, 150f, 151Hydrocarbon processing, 11Hydrodynamic particle size, 227Hydrogen sulfide removal, 92t, 93

I

Inverse micelle methodamphiphilic molecule, 36, 38fas-prepared gold particles, 38f

L

Ligated nanoparticle, 39, 43fLiquid-phase heterogeneousphotocatalysis, 200

Lung epithelial cells, 229, 232

M

MCM-48 mesoporous materials, 185fMesoporous titanium dioxide, 97Metal oxide nanoparticlesand lung epithelial cells, 229, 232

(111) Metal oxides, 62MgO(100), 52, 54fcalcination temperatures, 67, 70tcatalysts, 66, 67f, 67t

MgO(110), 54fcalcination temperatures, 67, 70tcatalysts, 66, 67f, 67tcleavage energies, 56tCO2-TPD, 67, 69f

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MgO(111), 52, 54f, 62, 68calcination temperatures, 67, 70tcatalysts, 66, 67f, 67tCO2-TPD, 67, 69fH2 adsorption, 58, 60fenergy interaction, 59, 61foptimized geometry, 59, 61f, 62f

methanol decomposition, 65f, 66morphology and geometry, 53cleavage energies, 55, 56tMg KLL Auger electron diffractionintensities, 55, 56f

nanosheets, 61, 63ftheoretical (111) surface, 64fwet chemical preparation, 60, 63f

MgO catalystssunflower oil, transesterification, 66, 67ttriglyceride and methanol,transesterification, 67f

Mn ions, 218Molybdenum sulfide nanoparticlescommercially available, 146f, 147dry milling process, 147f, 149hybrid milling process, 149f, 150f, 151synthesis, 144, 144fand tribological performance, 137wet milling process, 148f, 150

N

NanoActive MgO plus, 78, 80f, 81fNano-catalysts, 7Nanocrystalline metal oxides, 78air filtration, 81, 88chemically reactive atoms/ions, 82fclean coal technologies, 89, 94surfaces, edges and corners, 79

Nanocrystalline MgOFAST-ACT, 237, 239TEM images, 237fand TiO2, 83, 85t

Nanocrystalline sorbents, 78Nanocrystalline TiO2FAST-ACT, 237, 239and MgO, 83, 85tTEM images, 237f

Nanocrystalline zeolites, 17, 18fcharacterization, 19CO2 adsorption, 20, 21, 21f, 24fvibrational frequencies, 19, 19f

Nanocrystalline ZnO based sorbent, 92t, 93Nano-NaY zeolites, 20, 24fNanoparticles as moleculesligated nanoparticle, 39, 43f

stoichiometry, 39superlattices, 39, 42f, 44f

Nanoparticle solutions, 35Au/C12SH nanoparticle solubility, 44fequilibrium properties, 39interaction potential, 41, 46fnon-equilibrium properties, 42solubility phase diagrams, 41, 44fsynthetic methods, 36temperature quench experiments., 42,46f

Nanoparticulate lubrication additivesdevelopment, 141review, 141synthesis and tribological properties,142t

NanoScale’s FAST-ACT product, 83, 85tNanoscale TiO2, 18fbroncheoalvelolar lavage fluid exposure,27f

oxalic acid adsorption, 22, 25fsurface adsorption, 25toxicity, 23

Nanosize metal oxidesand chemical warfare agentscandidate sorbent properties, 129tCARC surface decontaminationefficacy testing, 133

reactivity testing, 128, 130tNiO(110)cleavage energies, 56, 57tCO orbital interaction, 58f

NiO(111), 52, 68cleavage energies, 56, 57tCO adsorption, 57methanol decomposition, 72fmorphology and geometry, 55nanosheet, 63fwet chemical preparation, 61, 63f

O

OdorKlenz-Air® technologyfiltration cartridge, 259, 260fhydrogen sulfide, 260f

Oxalic acid adsorption, 22, 25fOxide-based nanomaterials, 15engineered, 16environmental processes, 16, 31nanocrystalline zeolites, 24fnanoscale TiO2, 18fnatural, 16size-dependent properties, 16surface chemistry, 16

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P

Photocatalysis, 250Photocatalytic degradationand mesoporous TiO2, 111pollutants, 111

Photocatalytic nanomaterials, 11Photocatalytic particlesin packed beds, 255, 256findoor air concentration, 259, 260tmodeling and simulation studies,parameters use, 258t

pressure drop, 255, 257ton walls, 253indoor air concentration, 256tmass transfer coefficients, 254, 256t

Pollutants, photocatalytic degradationin gas, 114in water, 111

R

Rhodamine B, UV-Vis absorption spectra,201f, 202f

(111) Rocksalt metal oxides, 51theoretical studies, 53wet chemical preparation, 60

S

Semiconductor photocatalysis, 98environmental remediation, 110gas-phase pollutants, 114mechanism, 106water pollutants, 111

Silica-supported silver halidephotocatalystsBJH pore-size distribution, 196fcharacterization, 195gas-phase heterogeneous photocatalysis,199

liquid-phase heterogeneousphotocatalysis, 200

nitrogen adsorption-desorption isotherm,196f

synthesis, 194textural properties, 197tUV-Vis absorption spectra, 196f, 199fX-ray diffraction analysis, 195f

Silver halidesband gap energies, 199telectrochemical properties, 201, 202t

physical properties, 201, 202tthreshold wavelength, 199t

SMAD. See Solvated metal atom dispersionmethod

Solvated metal atom dispersion methodgold SMAD as-prepared, 36, 37freactor, 36, 36f

Sorbentsenvironmental remediation, 2impregnates, 82, 83t

SPC. See Stoichiometric particle compoundStoichiometric particle compound, 39, 43fSuper-base catalysts, 10

T

TIC. See Toxic industrial chemicalsTiO2-SiO2 aerogeldoping comparisonCO2 production, 213, 216fsurface area and pore size distributiondata, 211t

ESR spectra, 214, 217finfrared spectra, 214fmetal incorporated, 209PXRD patterns, 211f, 212synthesis, 209UV-Vis absorption spectra, 212f

TiO2-SiO2-Fe aerogeland acetaldehyde, 215finfrared spectra, 214fUV-Vis absorption spectra, 212f

TiO2-SiO2-Mn aerogeland acetaldehyde, 213, 215fagitation effect, 220, 221fapparent turnover frequency, 214,218t

quantum yield, 214, 218tvisible-light adsorption, 219f

air purification, 207ESR analysis, 214infrared spectra, 214fPXRD diffraction patterns, 211fUV-Vis absorption spectra, 212fand visible light induced air purification,207

Titanium dioxideoxalic acid adsorption, 25fphotocatalysts, 185f, 187semiconductor photocatalysis, 99synthesis, 100

TOF-SIMS analysis, tribofilm, 160, 160fToxic industrial chemicals, 81Tribofilm analysis

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Auger, 155, 156f, 158fTOF-SIMS analysis, 160, 160fXPS, 158, 159f

Tribological testing, 152Tribology, 138

U

UV light photocatalysisand 2-CEES, 181f

V

Visible light photocatalystsacetaldehye destruction, 183tsemiconductor photocatalysis, 109

W

Wet chemical preparation, (111) rock saltmetal oxides, 60

Wet milling process, 148f, 150

X

XPS analysis, tribofilms, 158f, 159f, 160

Z

Zeolites, 18fZero-valent metals, CCl4 reduction, 168s,169f, 170t, 173f, 174f

Zinc dialkyldithiophosphate formula, 145f

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