A review of atomic and molecular

research at the National Fusion Research Institute,

Korea (NFRI)October 05, 2009ADAS WORKSHOP

Mi-Young Song

National Fusion Research InstituteNational Fusion Research Institute

Purpose-Technology development for construction of Koorean fusion reactors and

commercialization of fusion energy as a world leader in fusion energy research and development

History1995. 12. The master plan of KSTAR project was approved by national fusion R&D committee1996. 1. The National Fusion R&D Center was established (in KBSI)2002. 9. The ceremony for the completion of KSTAR experimental building was held2005. 10. National Fusion Research Center (NFRC) was established2007. 9. KSTAR construction will be finished2007.10. National Fusion Research Institute (NFRI) was established2008. 07. KSTAR has successfully achieved its First Plasma 2008. 09. Dr. Gyung-Su Lee has been named the new President of the NFRI

Organization of NFRIOrganization of NFRI

Characteristics of plasma application technologies

- Plasma application technologies based on the specific properties of plasma.

- The operating conditions for plasma can be in various environments from Ultra low to atmospheric pressure.

-Plasma application technologies have been in application for pressure many industrial field such as BT,NT,IT,ET, and ST

- Information Technologies - Information Technologies (Data center for plasma (Data center for plasma properties, DCPP) properties, DCPP)

- - Plasma numerical simulator in Plasma numerical simulator in a Web a Web

- Construction of Atomic and - Construction of Atomic and Molecular Data BaseMolecular Data Base

Main idea of data center for plasma Main idea of data center for plasma propertiesproperties

All data, analysis and simulation codes, and visualization tolls will be

thought of as network services

Philosophy

Enable more efficient use of existing experimental facilities through more powerful data analysis for plasma experiments resulting in a greater number of experiments at less cost

Allowing more transparent access to analysis and simulation codes, data, and visualization tools, resulting in more researchers having access to more resources

Enable more effective integration of experiment, theory, & modeling. Facilitate multi–institution collaborations

Purpose

ReactionRate

Coefficient

SimulationSoftware

Documentation

ElectronImpact

IonImpact

HeavyParticleCollision

Visualization

PlasmaDatabase

Provide advantages in time to device maker and assist in USER (industry, Institute, University)

Integrated Device

Manufacturer

MainContents

• Making of national information resources on plasma properties by basic data research to be applied to nuclear fusion and industry and provision of infrastructures regarding design, operation and control technologies• Establish research and industrial support system throughout establishment of web-based simulation system

Research Activities IResearch Activities I

Standard Reference Data (SRD) Center for plasma Standard Reference Data (SRD) Center for plasma propertiesproperties

(Ministry of Knowledge Economy)

Certified Data

Standard reference values, specific to known

production batches Validated Data

Confirmed via correlations and models Qualified Data

Basic acceptance criteria satisfied

Three data evaluation principles

How well is the data generation described How do the data follow the known physical laws How do the data compare to other measurements or calculations of the same phenomena

Ref. Data

Data Spec.

Production method

Related Properties

Reproducibility

Consistency

Predictable

Expert evaluation

Certified DataSRD

Reject

Reject

Reject

Qualified Data

Validated Data

Reject N

N

N

N

N

N

N

Y

Y

Y

Y

Y

Y

Y

Y

Data Evaluation Levels

Data Evaluation SystemData Evaluation SystemData Evaluation SystemData Evaluation System

HH22 data evaluation data evaluation (with Prof. Itikawa)HH22 data evaluation data evaluation (with Prof. Itikawa)

published on Journal of Physical and

Chemical Reference Data

published on Journal of Physical and

Chemical Reference Data

State of current knowledge on electron collision State of current knowledge on electron collision data data

Cross section H2 N2 O2 Ar Xe CF4 C2F6 C3F8 C4F8 CHF3 CF3I CCl2F2 SF6

Total

Q/C Q/V Q/V V V V V V V 　 　 Q V

0.02-0.2/0.4-1000

0.02-0.1, 1000-5000/

0.1-1000

1100-5500/0.1-1000

0.08-6000 0.5-50000.003-4000

0.05-50000.025-3000

1-3000 　 　 0.1-4000 0.8-4000

Elastic scattering

Q/V V Q/V Q/V Q V Q Q V V 　 Q Q

0.02-1100-1000/

1-1000.55-1000

200-1000/1.25-100

20-3000/0.08-20

0.67-10000

0.003-10000

0.01-500 1.5-100 1.5-100 1.5-500 　 0.5-9.5 0.3-700

Momentum transfer

Q/V Q/V Q/V Q/V Q V Q Q V V 　 　 Q

0.0003-0.01/0.01-200

100-400/0.001-100

200-1000/0.01-100

0.001-0.05/

0.05-100.01-100 0.001-700 0.01-500 1.5-100 1.5-100 1.5-500 　 　 2.75-700

Total ionization

Q Q/V Q/V Q/V V V V V Q V Q V Q

16-50001200-20000/

16-1000

1200-20000/13-998

1000-5300/

16-100012-1000 17-1000 16-1000 13-100 16-100 16-100 10-70 15-1000 17-1000

cross section

H2 N2 O2 Ar Xe CF4 C2F6 C3F8 C4F8 CHF3 CF3I CCl2F2 SF6

Partial ionization

Q V V Q/V Q/V Q V Q Q Q Q Q Q

H2+,H+

N2+, N+, N2+

+,N++

O2+,O+,O2++,

O++

Ar+Ar2+Ar3+

Xe+Xe2+Xe3+Xe4+

CF3+,CF2+,CF+,C+,F+,

CF3++,CF2++

C2F5+,CF3+,CF2+,CF+,C+,F+

C3F7+,C2F5+,C2F4+,CF3+,CF2+,CF+

CF3+,CF2+,CF+,F+,

C2F4+,C2F3+,C2F2+,C2F+,

C3F5+,C3F4+,C3F3+,C3F2+,C3F+

CF3+,CF2+,CF+,CH+,F+,C+,H+,HF+,

CHF2+,CHF+

CF3+,CF2+,CF+,

CF3I+,CF2I+,

I+

CCl2F+,CClF2+,CClF+,CF+,Cl+,C+,F+,

CF2++CCl+

SF5+,SF4+,SF3+,SF2+,SF+,S+,F+,

SF3++,SF2++,SF++

16-3000/19-1906

16-1000/30-1000/70-1000

13-998/23-998/73-998

1000-5000/17-

100045-5000/

100-5000/

1000-5000/12-

10001000-

5000/40-1000

800-5000/130-1000/

17-900/26-900/30-900/41-900/35-900/45-900/51-900/

16-1000/16-1000/20-1000/20-1000/45-1000/45-1000

18-100/14-100/16-100/16-100/30-100/25-100

16-100/20-100/16-100/50-100/16-100/25-100/40-100/40-100/16-100/40-100/50-100/40-100/50-100

16-85/20-85/20-85/20-85/25-85/20-85/20-85/20-85/20-85/20-85/

12-70/20-70/22-70/10-70/16-70/14-70

20-1000/15-1000/25-1000/25-1000/25-1000/35-1000/40-1000/20-1000

18-1000/22.5-1000/32.5-1000/40-1000/40-1000/50-1000/60-1000/60-1000/60-1000

Total dissociation

Q Q 　 　 Q Q Q Q Q 　 　 　

12-1000 13.5-198.5 　 　 4.3-10.5 10.2-700 10-300 10-120 20-300 　

Dissociation into neutrals

　 　 Q 　 　 　 　 　 　 　

　 　 　 　 　 12.5-600 　 　 　 　 　 　 　

cross section

H2 N2 O2 Ar Xe CF4 C2F6 C3F8 C4F8 CHF3 CF3I CCl2F2 SF6

Total attachment

　 Q Q Q Q 　 　 　 　

　 　 　 　 　 12.5-500 2-10 0.8-6.5 0.01-11.5 　 　 　 　

Dissociative attachment

Q 　 V 　 　 　 　 　 　 　 　 　 　

H- 　 O- 　 　 　 　 　 　 　 　 　 　

3.5-18 　 4.3-9.9 　 　 　 　 　 　 　 　 　 　

Ion-pair formation

Total vibrational excitation

Direct vibrational excitation

Q/V Q/V Q

0-1

0-1/0-2/0-3/0-4

0-1/0-2/0-3/0-4

　 　 　 　 　 　 　 　 　 　

15-100/0.5-10

30-74/0.5-301.9-3/1.9-3/

2.1-2.6/

5-20/6-15/7-15/7-15/

　 　 　 　 　 　 　 　 　 　

Total rotational excitation

　 　 　 　 　 　 　 　 　 　 　 　 　

　 　 　 　 　 　 　 　 　 　 　 　 　

Rotational excitation

V Q 　 　 　 　 　 　 　 　 　 　 　

0-2/1-3/2-4/3-5

0-2 　 　 　 　 　 　 　 　 　 　 　

0.04-15/0.09-15/0.1-15/0.1-15

0.0015-1.25 　 　 　 　 　 　 　 　 　 　 　

Total electric excitation

　 　 　 　 　 　 　 　 　 　 　 　 　

　 　 　 　 　 　 　 　 　 　 　 　 　

cross section H2 N2 O2 Ar Xe CF4 C2F6 C3F8 C4F8 CHF3 CF3I CCl2F2 SF6

Total electric excitation

　 　 　 　 　 　 　 　 　 　 　 　 　

　 　 　 　 　 　 　 　 　 　 　 　 　

Electric excitation

Q Q/V Q/V 　 　 　 　 　 　 　 　 　 　

　 　 　 　 　 　 　 　 　 　 　 　

12-3000/11.8-200/9.2-100/11.5-50/

12.4-3000/12-3000

50-1000/13-50100-1000/8-10050-200/7.65-50

50-200/8-5050-200/11-5050-200/8.9-5050-200/9-50

/9-20/9-25

/11.9-50

/0.98-20/1.63-20

70-500/4.23-45　 　 　 　 　 　 　 　 　 　

ug

ug

ug

ug

gg

ug

FEX

CX

cX

bX

aX

BX

11

11

31

31

31

11

,

g3

g1

u3

g1

u'1

g1

u3

g1

u1

g1

u3

g1

g3

g1

u3

g1

g3

g1

g"1

g1

ΣEΣX

ΣBΣX

ΣaΣX

ΔWΣX

ΔwΣX

ΠCΣX

ΠBΣX

ΣAΣX

ΠaΣX

ΣaΣX

u

u

ug

gg

gg

c

C

AX

bX

aX

1

3

33

13

13

Plasma property data (A&M) collection for plasma Plasma property data (A&M) collection for plasma application industryapplication industry

(Ministry of Public Administration and Security)

Research Activities IIResearch Activities II

Material Gas

Si CF4/O2, CF2Cl2, CF3Cl, SF6/O2/Cl2, Cl2/H2/C2F6/CCl2, C2ClF5/O2, SiF4/O2, NF3,

ClF3, CCl4, CCl3F5, C2ClF5/SF6, C2F6/CF3Cl, Br2, CF3Cl/Br2, CCl2F2, Cl2

SiO2 CF4/H2, C2F6, C3F8, CHF3/O2

Si3N4 CF4/O2/CBrF3, CF4/O2/H2, C2F6, C3F8, CHF3,CH2F2, SF6, Cl2/NF3

Organic Solids (resist)

O2, CF4/O2, SF6/O2

Silicide CF4/O2, NF3, SF6/Cl2, CF4/Cl2, CCl4/O2, CCl2F2

Al BCl3, BCl3/Cl2, CCl4/Cl2/BCl3, SiCl4/Cl2

Cr Cl2, CCl4/Cl2Mo, Nb, Ta,

Ti, W CF4/O2, SF6/O2, NF3/H2

Au C2Cl2F4, Cl2, CClF3

GaAs BCl3/Ar, Cl2/O2/H2, CCl2F2/O2/Ar/He, CCl4

InP CH4/H2, C2H6/H2, Cl2/Ar

A&M Data for IndustryA&M Data for Industry A&M Data for IndustryA&M Data for Industry

Gas Reaction

Ar Ionization, Excitation, De-Excitation, Ion wall Recombination

Cl2Ionization, Dissociation, Attachment, Ion-Ion Reaction, Neutral-Neutral Recombination,Ion wall Recombination

O2

Ionization, Excitation, De-Excitation, Dissociation, Attachment, Charge Exchange Ion-Ion Reaction, Neutral-Neutral Reaction, Ion wall Recombination

CF4

Ionization, Dissociation, Attachment, Ion-Ion Reaction, Charge Exchange, Ion-Neutral Reaction, Neutral-Neutral Reaction, Ion wall Recombination

SiH4Ionization, Dissociation, Ion-Neutral Reaction, Neutral-Neutral Reaction, Ion wall Recombination

H2Ionization, Dissociation, Neutral-Neutral Reaction, Ion wall Recombination

SF6

Ionization, Dissociation, Attachment, Ion-Ion Reaction, Neutral-Neutral Reaction, Ion wall Recombination

O2/ArIonization, Excitation, De-Excitation, Dissociation, Attachment, Ion-Ion Reaction,Neutral-Neutral Reaction, Ion wall Recombination

O2/F2

Ionization, Excitation, De-Excitation, Dissociation, Attachment, Charge Exchange,Ion-Ion Reaction, Neutral-Neutral Reaction, Ion wall Recombination

c-C4F8Ionization, Dissociation, Ion-Ion Reaction, Neutral-Neutral Reaction, Ion wall Recombination

CF4/ArIonization, Dissociation, Attachment, Ion-Ion Reaction, Ion-Neutral Reaction, Neutral-Neutral Reaction, Ion wall Recombination

SiH4/O2/ArIonization, Excitation, De-Excitation, Dissociation, Charge Exchange Ion-Neutral Reaction, Neutral-Neutral Reaction, Ion wall Recombination

Material Contents

Si - Silicon Ge - Germanium GaP - Gallium Phosphide GaAs - Gallium Arsenide InAs - Indium Arsenide C - Diamond GaSb - Gallium Antimonide InSb - Indium Antimonide InP - Indium Phosphide GaAs1-xSbx - Gallium Arsenide Antimonide AlxGa1-xAs - Aluminium Gallium Arsenide     AlN - Aluminium Nitride InN - Indium Nitride BN - Boron Nitride GaN - Gallium Nitride GaxIn1-xAsySb1-y - Gallium Indium Arsenide Antimonide GaxIn1-xP - Gallium Indium Phosphide GaxIn1-xAs - Gallium Indium Arsenide GaxIn1-xSb - Gallium Indium Antimonide InAs1-xSbx - Indium Arsenide Antimonide GaxIn1-xAsyP1-y - Gallium Indium Arsenide Phosphide Si1-xGex - Silicon Germanium SiC - Silicon Carbide 

• Basic Parameters at 300 K• Band structure and carrier concentration   - Basic Parameters of Band Structure and carrier concentration - Temperature Dependences - Energy Gap Narrowing at High Doping Levels - Effective Masses and Density of States - Donors and Acceptors•Electrical Properties   - Basic Parameters of Electrical Properties   - Mobility and Hall Effect   - Transport Properties in High Electric Fields   - Impact Ionization   - Recombination Parameters•Optical properties•Thermal properties   - Basic parameters   - Thermal conductivity   - Lattice properties•Mechanical properties, elastic constants, lattice vibrations   - Basic Parameters   - Elastic Constants   - Acoustic Wave Speeds   - Phonon Frequencies•References

Material Data for IndustryMaterial Data for IndustryMaterial Data for IndustryMaterial Data for Industry

DATACross sectiondata

Rate coefficient

Structure

Spectrum

SimulationCode

Selection/evaluation

development Data analysis

Graphicinterface

Simulation/AnalysisProgram

DB

Technical information

Educationprogram

monitoring

Searching

Community

Plasma DB SystemPlasma DB System

WEB based Database - Graphic interface- Information Searching- KISTI web

WEB based Database - Graphic interface- Information Searching- KISTI web

WEB based Simulation- Interactive Code System- Super com. (KISTI)

WEB based Simulation- Interactive Code System- Super com. (KISTI)

USERUSER

Univ., Industry, etcUniv., Industry, etc

• Data generation/providing• International R&D network

• Data generation/providing• International R&D network

• Simulation code generation• International R&D network

• Simulation code generation• International R&D network

Methods Methods Methods Methods

Univ., Industry, etcUniv., Industry, etc

Period: 2006-2009

DB record: 145,517 recordNumber of A&M : 475 Journal : 30

Research activities IIIResearch activities III

R&D Program of NFRIR&D Program of NFRI

X-Ray Crystal Spec.Soft X-Ray Spec.

VUV Survey Spec.

MM-Wave InterferometerReflectometer

MIRECEI

Tangential FIR Interferometer(laser input)

MD Feedthrough

Survey IR TVInspection IlluminatorVisible/H-alpha TV

MSE

Visible Survey Spec.H-alpha Monitor

Visible Brem. ArrayVisible Filterscope

LIF (optics)Diag. Neutral Beam

ECE Hetero. Radiometer

ECE Grating Polycromator

Bolometer ArrayThomson Scatt. Laser input

CX-NPA

MD FeedthroughInspection Illuminator

CES / MSE / BESThomson Scatt.

Divertor Thomson (optics)

MD Feedthrough

Survey IR TVMovable Lanmuir Probe

Inspection IlluminatorSurvey IR TV

Visible/H-alpha TVSoft X-Ray Array

X-Ray PHAImpurity Pellet Injector

Recip. Lanmuir Probe(Movable)X-Ray Pinhole Camera

Bolometer Array

X-Ray Crystal Spec.

MD Feedthrough

Survey IR TV

Inspection IlluminatorVisible/H-alpha TV

CES Background

A

BC

DE HGF

I

JK

NM

LP

OEdge reflectometer

Thomson scattering(beam dump)

ICRH/FWCD

LHCD

ECHNBI I

NBI II

PUMPING

DUCT

PUMPING DUCT

Escaping fast-ion detector

KSTAR DiagnosticsKSTAR DiagnosticsKSTAR DiagnosticsKSTAR Diagnostics

How to ?How to ?

e-Plasma Data Analysis & Application Systeme-Plasma Data Analysis & Application System

Atomic Data

Molecular Data

SpectrumData

Chemical ReactionData

Structure Data

DatabaseDatabase

+ Plasma Source Simulator+ Plasma Source Simulator

+ Surface & Profile Simulator+ Surface & Profile Simulator

+ Other Simulation Code+ Other Simulation Code

Fusion materialData

Tech.Info.

• Spectrum data analysis• Fusion diagnostic data analysis• ... ...

• Spectrum data analysis• Fusion diagnostic data analysis• ... ...

+International DB network+

+International DB network+

NIFS, JAEA, IAEA, ORNL, GA

NIFS, JAEA, IAEA, ORNL, GA

e + atom collision systeme + atom collision system

e + molecule collision system

e + molecule collision system

Integrated data analysis system

Integrated data analysis system

Research activities IVResearch activities IV

Asia-Pacific Atomic Data Network(A-PAN)Asia-Pacific Atomic Data Network(A-PAN) : a network for dissemination of collisional data

relevant to plasmas, discharges, materials & biosciences

DATA DATA NETWORKNETWORK

Needs for an actionNeeds for an action

Plasma applications are increasing.

Plasma applications want to know plasma properties.

Need to organize the data activities.

Conduct and promote the measurement and calculation of atomic data of relevance to applications in discharge and plasma physics, materials and biomedical science

Provide a mechanism for the efficient compilation, assessment, and critical evaluation of atomic and molecular data

Assess emerging areas of need for atomic data

Provide a strong regional focus on collaborative research in atomic and molecular physics

Provide a link between researchers in A&M Physics and potential end-users of data

Expected EffectExpected Effect

Standard Reference Data (SRD) Center for plasma properties Standard Reference Data (SRD) Center for plasma properties

Plasma property data (A&M) collection for plasma application industry Plasma property data (A&M) collection for plasma application industry

A&M DB for fusion Fusion material database A&M DB for fusion Fusion material database

SummarySummary

Construction of data evaluation system Data evaluation, generation(New TCS) Registration of SRD

Molecule data collection for industryDevelopment of web-based information system

e-Integrated Plasma Research SystemBasic research of atomic and molecular processes in plasma Diagnostic data analysis (Integrated data analysis system of KSTAR)

Our vision !Our vision !Our vision !Our vision !

NFRIproductionevaluationstandard

Data Production

USER

Plasma Property

Data Center

Evaluation + Compilation + Standards + Maintenance

IndustrySemiconductor &

Display Manufacturers, Equipment

manufacturers,…

Univ.Students

…

InstituteNational Labs

…

ASIAR&D Hub

Databasenetwork

NFRIKRISSKISTI

DB standard

Thank You.

http://plasma.kisti.re.krhttp://plasma.kisti.re.krhttp://dcpp.nfri.re.krhttp://dcpp.nfri.re.kr