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A DYNAMIC LIFE CYCLE ASSESSMENT FRAMEWORK FOR WHOLE BUILDINGS INCLUDING INDOOR ENVIRONMENTAL QUALITY IMPACTS by William O. Collinge Bachelor of Science, University of Pittsburgh, 1997 Submitted to the Graduate Faculty of Swanson School of Engineering in partial fulfillment of the requirements for the degree of Doctor of Philosophy University of Pittsburgh 2013

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i

A DYNAMIC LIFE CYCLE ASSESSMENT FRAMEWORK FOR WHOLE BUILDINGS INCLUDING INDOOR ENVIRONMENTAL QUALITY IMPACTS

by

William O. Collinge

Bachelor of Science, University of Pittsburgh, 1997

Submitted to the Graduate Faculty of

Swanson School of Engineering in partial fulfillment

of the requirements for the degree of

Doctor of Philosophy

University of Pittsburgh

2013

ii

UNIVERSITY OF PITTSBURGH

SWANSON SCHOOL OF ENGINEERING

This dissertation was presented

by

William O. Collinge

It was defended on

March 12, 2013

and approved by

Vikas Khanna, PhD, Assistant Professor, Civil and Environmental Engineering Department

Jeen-Shang Lin, PhD, Professor, Civil and Environmental Engineering Department

Alex K Jones, PhD, Associate Professor, Electrical and Computer Engineering Department

Laura Schaefer, PhD, Associate Professor, Mechanical Engineering and Materials Science Dept.

Dissertation Director: Melissa Bilec, PhD, Assistant Professor, Civil and Environmental

Engineering Department

iii

Copyright © by William O. Collinge

2013

iv

Life cycle assessment (LCA) can aid in quantifying the environmental impacts of whole

buildings by evaluating materials, construction, operation and end of life phases with the goal of

identifying areas of potential improvement. Since buildings have long useful lifetimes, and the

use phase can have large environmental impacts, variations within the use phase can sometimes

be greater than the total impacts of other phases. Additionally, buildings are operated within

changing industrial and environmental systems; the simultaneous evaluation of these dynamic

systems is recognized as a need in LCA. At the whole building level, LCA of buildings has also

failed to account for internal impacts due to indoor environmental quality (IEQ). The two key

contributions of this work are 1) the development of an explicit framework for DLCA and 2) the

inclusion of IEQ impacts related to both occupant health and productivity. DLCA was defined as

“an approach to LCA which explicitly incorporates dynamic process modeling in the context of

temporal and spatial variations in the surrounding industrial and environmental systems.” IEQ

impacts were separated into three types: 1) chemical impacts, 2) nonchemical health impacts,

and 3) productivity impacts. Dynamic feedback loops were incorporated in a combined

energy/IEQ model, which was applied to an illustrative case study of the Mascaro Center for

Sustainable Innovation (MCSI) building at the University of Pittsburgh. Data were collected by a

system of energy, temperature, airflow and air quality sensors, and supplemented with a post-

occupancy building survey to elicit occupants’ qualitative evaluation of IEQ and its impact on

productivity. The IEQ+DLCA model was used to evaluate the tradeoffs or co-benefits of energy-

A DYNAMIC LIFE CYCLE ASSESSMENT FRAMEWORK FOR WHOLE BUILDINGS INCLUDING INDOOR ENVIRONMENTAL QUALITY IMPACTS

William O. Collinge, PhD

University of Pittsburgh, 2013

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savings scenarios. Accounting for dynamic variation changed the overall results in several LCIA

categories - increasing nonrenewable energy use by 15% but reducing impacts due to criteria air

pollutants by over 50%. Internal respiratory effects due to particulate matter were up to 10% of

external impacts, and internal cancer impacts from VOC inhalation were several times to almost

an order of magnitude greater than external cancer impacts. An analysis of potential energy

saving scenarios highlighted tradeoffs between internal and external impacts, with some energy

savings coming at a cost of negative impacts on either internal health, productivity or both.

Findings support including both internal and external impacts in green building standards, and

demonstrate an improved quantitative LCA method for the comparative evaluation of building

designs.

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TABLE OF CONTENTS

NOMENCLATURE .................................................................................................................. XII

PREFACE ................................................................................................................................. XIV

1.0 INTRODUCTION ........................................................................................................ 1

1.1 ADVANCING LCA METHODS FOR THE BUILT ENVIRONMENT ....... 1

1.2 RESEARCH GOALS AND OBJECTIVES ...................................................... 4

1.3 INTELLECTUAL MERIT ................................................................................. 5

2.0 BACKGROUND AND LITERATURE REVIEW .................................................... 6

2.1 DYNAMIC LIFE CYCLE ASSESSMENT FOR BUILDINGS ...................... 6

2.2 LCA AND INDOOR ENVIRONMENTAL QUALITY ................................... 7

2.3 ORGANIZATION OF THESIS ....................................................................... 10

3.0 DYNAMIC LIFE CYCLE ASSESSMENT MODEL WITH INITIAL RETROSPECTIVE AND PROSPECTIVE CASE STUDY........................................... 12

3.1 INTRODUCTION ............................................................................................. 12

3.1.1 Time in LCA................................................................................................... 13

3.1.2 Scope and functional unit of this study ........................................................ 15

3.2 METHODS ......................................................................................................... 15

3.2.1 Modeling approach ........................................................................................ 15

3.2.2 Case study ....................................................................................................... 20

3.2.3 Static and dynamic LCA comparisons ........................................................ 22

3.2.4 Data collection ................................................................................................ 24

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3.2.5 Future scenario analysis ................................................................................ 26

3.3 RESULTS AND DISCUSSION ........................................................................ 27

3.3.1 Static LCA validation .................................................................................... 27

3.3.2 DLCA and static LCA results for full lifetime analysis ............................. 29

3.3.3 DLCA and Static LCA results for remaining lifetime analysis ................. 35

3.3.4 Future scenario analysis ................................................................................ 35

3.3.5 Limitations ..................................................................................................... 40

3.4 CONCLUSION .................................................................................................. 43

4.0 INTEGRATING INDOOR ENVIRONMENTAL QUALITY INTO THE DLCA FRAMEWORK FOR WHOLE BUILDINGS ................................................................. 45

4.1 INTRODUCTION ............................................................................................. 45

4.2 METHODS ......................................................................................................... 47

4.2.1 General framework for Indoor Environmental Quality + Dynamic Life Cycle Assessment (IEQ+DLCA) ........................................................................ 47

4.2.2 Whole building exposure approach for chemical impacts ......................... 51

4.2.2.1 Estimating occupancy using CO2 concentrations ............................ 59

4.2.2.2 VOC Speciation and inhalation toxicity............................................ 61

4.2.3 Extending the IEQ+DLCA framework beyond chemical impacts ........... 63

4.2.3.1 Nonchemical health impacts .............................................................. 63

4.2.3.2 Performance and productivity impacts............................................. 66

4.2.4 Framework summary .................................................................................... 68

4.3 CONCLUSION .................................................................................................. 69

5.0 IN-DEPTH CASE STUDY: MASCARO CENTER FOR SUSTAINABLE INNOVATION .................................................................................................................... 70

5.1 DATA COLLECTION ...................................................................................... 70

5.2 RESULTS AND DISCUSSION ........................................................................ 77

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5.2.1 Occupancy and estimated internal impact .................................................. 77

5.2.2 Comparison of internal and external impact assessment results .............. 81

5.2.3 Absenteeism and productivity impacts ........................................................ 83

5.2.4 Limitations ..................................................................................................... 84

6.0 POST-OCCUPANCY SURVEY OF THE MCSI BUILDING .............................. 87

6.1 INTRODUCTION ............................................................................................. 87

6.2 METHODS ......................................................................................................... 88

6.3 SURVEY RESULTS .......................................................................................... 89

7.0 SCENARIO ANALYSIS: ENERGY-SAVING STRATEGIES ............................ 99

7.1 INTRODUCTION ............................................................................................. 99

7.2 METHODS ....................................................................................................... 100

7.3 RESULTS AND DISCUSSION ...................................................................... 104

7.3.1 Building-specific parametric relationships ............................................... 104

7.3.2 Energy savings and life cycle impacts ........................................................ 107

8.0 CONCLUSIONS ...................................................................................................... 113

8.1 SUMMARY ...................................................................................................... 113

8.2 FUTURE WORK ............................................................................................. 116

8.3 OUTLOOK ....................................................................................................... 117

APPENDIX A ............................................................................................................................ 119

APPENDIX B ............................................................................................................................ 135

APPENDIX C ............................................................................................................................ 152

BIBLIOGRAPHY ..................................................................................................................... 168

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LIST OF TABLES

Table 1. Categories of dynamic life cycle assessment (DLCA) parameters for buildings, examples, and data sources used in the case study. ............................................................... 21

Table 2 - Mass and energy inputs for static LCA model of the building materials and initial energy consumption. .............................................................................................................. 28

Table 3 - Summary of IEQ+DLCA framework data and calculations ......................................... 69

Table 4 - Relative productivity by room for the MCSI building .................................................. 84

Table 5 - Summary of post-occupancy survey question types ..................................................... 89

Table 6 - Breakdown of survey results by general category ......................................................... 90

Table 7 - Post-occupancy survey results: IEQ - thermal comfort ................................................. 92

Table 8 - Post-occupancy survey results: IEQ - air quality .......................................................... 92

Table 9 - Post-occupancy survey results: IEQ - lighting .............................................................. 93

Table 10 - Post-occupancy survey results: IEQ - acoustics .......................................................... 93

Table 11 - Post-occupancy survey results: productivity ............................................................... 95

Table 12 - Post-occupancy survey results: scenarios .................................................................... 96

Table 13 - Energy-saving scenarios and controlling criteria ...................................................... 103

Table 14 - Actual and estimated energy data for Benedum Hall. ............................................... 120

Table 15 - Mass and embodied energy inputs for static LCA model of Benedum Hall materials compared to two other studies ............................................................................................. 126

Table 16 - Results of life cycle impact assessment (LCIA) for Benedum Hall original construction and renovation materials. ................................................................................ 129

Table 17- Data organization and file structure ........................................................................... 137

Table 18 - List of VOCs, properties factors and reference values .............................................. 143

Table 19 - Post-occupancy survey questions and individual results........................................... 153

Table 20 - Post-occupancy open-ended questions and responses ............................................... 167

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LIST OF FIGURES

Figure 1 - Conceptual diagram of DLCA framework ................................................................... 18

Figure 2 - System boundary and dynamic modeling .................................................................... 23

Figure 3 - Comparison of results from static and DLCA models, using the TRACI method. ..... 30

Figure 4 – Cumulative time series of DLCA results in TRACI impact categories and nonrenewable energy use. Cumulative totals are normalized to year 2008 totals (prior to renovation). ............................................................................................................................ 34

Figure 5 - Comparison of predicted results for from static and DLCA models for the renovation and post-renovation operations. ............................................................................................. 37

Figure 6 - Time series of DLCA results for the sensitivity analysis, shown as cumulative percent deviations from the baseline scenario for the global warming potential and photochemical smog categories. .................................................................................................................... 38

Figure 7 - IEQ+DLCA framework. .............................................................................................. 48

Figure 8 - Flowchart showing inputs, calculation steps and outputs for internal human health-chemical impact categories and external LCA impact categories. ........................................ 50

Figure 9 - Schematic of multicompartment IAQ model. .............................................................. 52

Figure 10 - Data collection and flow for MCSI IAQ sampling. ................................................... 72

Figure 11 - Average weekday values by month for March-June 2012 for PM2.5, TVOC, and estimated occupancy based on CO2 measurements and HVAC system monitoring data. .... 78

Figure 12 - Relative VOC concentrations and toxicity potentials for March-June 2012 and reference studies. ................................................................................................................... 80

Figure 13 - Results of comparison of internal building impacts to external (conventional) LCA impacts. .................................................................................................................................. 82

Figure 14- Distribution of results for occupant satisfaction in IEQ categories. ........................... 91

Figure 15- Distribution of results for occupants’ perceived productivity impacts from IEQ. ...... 94

Figure 16- Distribution of results for occupants’ anticipated productivity impacts from scenarios. ............................................................................................................................................... 96

Figure 17 - Schematic of parametric energy model for the MCSI Annex .................................. 101

Figure 18 - MCSI Annex envelope heat transfer as a function of inside-outside temperature difference. ............................................................................................................................ 104

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Figure 19 - MCSI Annex supply and return fan power as a function of supply air mass flow. . 105

Figure 20 - Room-level empirical relationships for indoor/outdoor particle count ratio and economizer setting. .............................................................................................................. 107

Figure 21 - Scenario results for ventilation-related cooling energy consumption from March through October 2012. ......................................................................................................... 108

Figure 22 - Monthly baseline and scenario results for the MCSI annex in selected impact categories from the IEQ+DLCA model. .............................................................................. 111

Figure 23 - Full LCIA results for the MCSI annex scenario analysis from the IEQ+DLCA model. ............................................................................................................................................. 112

Figure 24 - Comparison of actual electrical usage and eQUEST model results for Benedum Hall. ............................................................................................................................................. 124

Figure 25 - Comparison of steam usage and eQUEST model results for Benedum Hall ........... 125

Figure 26 - Time series of derived emissions factors for fossil fuel electric power generation and Bellefield Boiler Plant (BBP) steam heat. ........................................................................... 128

Figure 27 - Normalized TRACI results from Benedum Hall original construction materials showing percentage contributions from unit processes. ...................................................... 130

Figure 28 - Normalized TRACI results from Benedum Hall renovation materials showing percentage contributions from unit processes. ..................................................................... 130

Figure 29 - (1 of 4) Time series of DLCA results for the sensitivity analysis, shown as cumulative percent deviations from the baseline scenario for the remaining categories not shown in Figure 6. ............................................................................................................... 131

Figure 30 - Floor plan of the MCSI annex showing data collection points. ............................... 136

Figure 31 - Linear regression of outdoor particle number from this study and particle mass from ACHD during the study time period .................................................................................... 138

Figure 32 - Cumulative distribution of indoor - outdoor PID equivalent TVOC concentrations from EPA BASE study ........................................................................................................ 142

Figure 33 - Cumulative distribution of indoor - outdoor effect factors from EPA BASE study 142

Figure 34 - Dynamic electrical generation mix at load point (courtesy of NREL) .................... 151

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NOMENCLATURE ACHD Allegheny County Health Department

AEC Architecture, Engineering and Construction

ASHRAE American Society of Heating, Refrigeration and Air conditioning Engineers

BASE Building Assessment and Survey Evaluation

BEES Building for Environmental and Economic Sustainability

BRI Building Related Illness

CAP Criteria Air Pollutant

CF Characterization Factor

DCV Demand Controlled Ventilation

DLCA Dynamic Life Cycle Assessment

EF Effect Factor

EIA Energy Information Administration

FF Fate Factor

IAQ Indoor Air Quality

IEQ Indoor Environmental Quality

iF intake Fraction

GHG Greenhouse Gas

GWP Global Warming Potential

HAP Hazardous Air Pollutant

HVAC Heating, Ventilating and Air Conditioning

LCA Life Cycle Assessment

LCI Life Cycle Inventory

LCIA Life Cycle Impact Assessment

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LEED Leadership in Energy and Environmental Design

MCSI Mascaro Center for Sustainable Innovation

NOx Nitrogen Oxides

NREL National Renewable Energy Laboratory

NREU Non Renewable Energy Use

PAQS Pittsburgh Air Quality Study

PID Photo Ionization Detector

PM Particulate Matter

PM2.5 Particulate Matter less than 2.5 µm in diameter

SETAC Society for Environmental Toxicity and Chemistry

SBS Sick Building Syndrome

TAWP Time Adjusted Warming Potential

TRACI The Tool for the Reduction and Assessment of Chemical and other environmental Impacts

TVOC Total Volatile Organic Compounds

UNEP United Nations Environmental Programme

USDOE United States Department of Energy

USEPA United States Environmental Protection Agency

USLCI United States Life Cycle Inventory

VAV Variable Air Volume

VOC Volatile Organic Compounds

XF Exposure Factor

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PREFACE

I am profoundly grateful to my dissertation director, Dr. Melissa Bilec, for her sincere support

and guidance throughout my graduate studies, as well as my dissertation committee and Dr. Amy

Landis for their additional feedback and guidance.

Special thanks to my colleagues and friends at the Mascaro Center for Sustainable Innovation

and Department of Civil and Environmental Engineering at Pitt. I also wish to thank Pitt’s

Facilities Management division for their assistance and information sharing, and acknowledge

the EPA STAR graduate fellowship.

Finally, my unending gratitude goes to Cassandra, my wife, and our two children Nia and Tyler

for putting up with me during this difficult journey, and for believing that Daddy goes to “work”.

Thank you.

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1.0 INTRODUCTION

1.1 ADVANCING LCA METHODS FOR THE BUILT ENVIRONMENT

The construction and operation of commercial and institutional buildings consumes a

large amount of energy and materials, both of which contribute to known environmental

problems in categories such as global climate change, human health, ecosystem services, and

resource depletion. In the United States, the entire building sector consumed 41% of total

primary energy in 2006, and the non-residential sector contributed approximately half of that

total (19%) (USDOE 2011a). Globally, buildings have been estimated to consume 40% of raw

materials annually (Young and Sachs 1994). However, buildings are perceived as a technological

sector where large improvements in performance in sustainability-related categories are

achievable (2030 2011; Griffith 2007; ILFI 2010; Levine 2007; USGBC 2012).

Life Cycle Assessment (LCA) provides a comprehensive and quantitative analysis of the

environmental impacts of a product or process throughout its entire lifecycle. LCA is a powerful

and widely used tool for measuring the environmental impact of an enterprise or concept and

informing decisions with respect to sustainability and environmental considerations. LCA

quantifies the environmental impacts of a product or process and can be a very helpful tool in

identifying the most benign technologies among an array of options. Through the use of LCA, it

is possible to observe which stage (i.e., creation, use, or end of life) causes the most impact and

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may offer suggestions to minimize impacts throughout a product’s lifetime. Established

guidelines for performing detailed LCAs are well documented by the Environmental Protection

Agency (EPA), Society for Environmental Toxicologists and Chemists (SETAC), and the

International Organization for Standardization (ISO) (Fava et al. 1991; ISO 2006; Vigon et al.

1992). As defined by the ISO 14040 series, LCA is an iterative four-stage process including: 1)

Scoping – defines the extent of analysis and the system boundaries; 2) Inventory Analysis –

documents material and energy flows which occur within the system boundaries (also called the

life cycle inventory or LCI); 3) Impact Assessment – characterizes and assesses the

environmental impacts using the data obtained from the inventory (also called the life cycle

impact assessment or LCIA); and 4) Interpretation and Improvement– identifies opportunities

to reduce the environmental burden throughout the product’s life.

Major reasons for conducting an LCA involve decision-making with respect to

improvement and comparison of products, processes, or activities. Impact-minimizing LCAs

provide information on which stage of production (creation, use, or disposal) causes the most

environmental impact and may offer suggestions to minimize those burdens. Comparative LCAs

can help to determine the environmentally preferable alternative when multiple alternatives exist.

LCA has historically been used primarily for consumer goods, though there are examples of

whole-building LCA studies in the literature. Whole-building LCAs have typically focused on

total energy usage, including energy required to operate the building as well as energy embodied

in the building materials (Junnila et al. 2006; Scheuer et al. 2003; Kofoworola and Gheewala

2008; Wu et al. 2011a). Some studies have examined waste generation and health-related air

pollution (Scheuer et al. 2003), or expanded the scope to include construction impacts (Bilec et

al. 2006; Bilec et al. 2010; Sharrard et al. 2008).

3

The goals typically outlined in high-performance or green building programs are broader

than building-cycle energy usage or direct waste and pollutant generation, reflecting a perception

among practitioners that, even from an environmental perspective, many other aspects are

important. Green building rating systems such as the U.S. Green Building Council’s (USGBC’s)

Leadership in Energy and Environmental Design (LEED) include categories not directly related

to the external environment, such as minimum ventilation and daylighting requirements, which

are believed to increase occupants’ health and productivity, and credit for low-emitting materials

(USGBC 2012). LEED and other systems also focus on sustainable building sites, recognizing

that the total impact of buildings extends beyond their walls (e.g. orientation) and even beyond

the site proper (e.g. connections to transport). Though commonly recognized as important,

internal building impacts are not captured in most LCAs. For example, an increase in building

ventilation, which improved indoor air quality but increased energy consumption, would appear

in most LCAs as a negative impact only, instead of a tradeoff with both costs and benefits.

An additional drawback of LCA as commonly practiced with respect to buildings, is that

it takes a static approach, essentially providing a “snapshot” of a building’s footprint. Dynamic

analysis is not often performed, yet buildings have the potential to undergo significant changes

during their long (50-100 year) lifetimes. These changes can occur simultaneously with changes

in the industrial or natural environment that also affect the ultimate environmental accounting.

Typically, dynamic information has not been included in LCA because of its increased data and

modeling requirements; however, as building automation becomes more common and

environmental sensing becomes ubiquitous, information about building performance over time

can be effectively incorporated into LCA.

4

1.2 RESEARCH GOALS AND OBJECTIVES

The goal of this research is to demonstrate an improved LCA method that includes

dynamic scenario modeling and internal building metrics, and is of value to practitioners in the

architecture, engineering, construction and management community. The specific research

questions are as follows:

1. What are the effects of including dynamic data for both building operations and

industrial/environmental systems on the results of LCA of buildings?

2. What are the effects of including whole-building internal human health impacts

into LCA?

3. Can we include internal building impacts that do not align with traditional LCIA

categories, such as health effects not related to specific chemicals, or impacts on

occupants’ productivity?

4. How do we apply this model to provide feedback on evaluating high performance,

green buildings?

The specific objectives to be achieved in answering these questions are:

1. Develop a dynamic LCA modeling framework that is capable of handling

dynamic variability in building operations and industrial/environmental systems,

with results including traditional LCA categories.

2. Develop a framework for including internal health impacts analogous to

traditional LCIA categories into LCA at the whole-building level.

3. Expand the framework to include non-chemical related health and productivity

impacts alongside the traditional LCA categories and internal chemical categories.

4. Apply the model to a case study of a high-performance building to evaluate the

life cycle impacts of different building improvement strategies, supplementing

physical data collection with qualitative data collected from a post-occupancy

survey.

5

1.3 INTELLECTUAL MERIT

This research is important because it provides a structure for an improved LCA method

for whole buildings. Two major categories of improvement are proposed: the incorporation of

dynamic life cycle data within a computational framework designed to handle this information,

and the inclusion of holistic IEQ impacts in the LCA framework. The latter category requires

extending the LCA coverage beyond traditional LCIA human health categories to include non-

chemical health and productivity impacts. The evaluation of IEQ impacts is further strengthened

by its incorporation into the dynamic framework, facilitating the evaluation of multiple scenarios

under differing forecasts of future condition. Particularly with respect to IEQ, the dynamic nature

of building operations and occupancy schedules suggests this approach; thus, the two

components are highly synergistic. The organization of the proposed research – first, providing

the dynamic, computational framework, and then including the additional IEQ impacts –

provides an achievable goal with several well-defined objectives, while the proposed case study

takes advantages of existing research relationships and large amounts of available data.

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2.0 BACKGROUND AND LITERATURE REVIEW

2.1 DYNAMIC LIFE CYCLE ASSESSMENT FOR BUILDINGS

Accurate and complete building assessments are hampered by shortcomings in LCA

techniques and data availability. Buildings are complex systems with long lifetimes; the ability to

model different scenarios representing system dynamics is recognized as a key need in LCA of

buildings (Scheuer et al. 2003). Dynamics of the environment and industrial systems have been

considered one of the outstanding problems in LCA (Reap et al. 2008). A number of recent

studies have investigated both system dynamics and the use of time horizons or discount rates in

the impact characterization step of LCA (Kendall et al. 2009; Levasseur et al. 2010; Pehnt 2006;

Struijs et al. 2010; Zhai and Williams 2010). Research has documented the prominence of the

operating phase of buildings in most environmental impact categories, but also significant

contributions from materials and construction processes which cannot be ignored.

Environmental and industrial dynamics operate on different time scales, all with some

relevance to building LCAs (Reap et al. 2008). Environmental dynamics may include long-term

or seasonal variation in pollutant fates or population exposures, while industrial dynamics may

include changes in the location or type of emissions from different industries, among other

factors. Industrial supply chains change their structure over the long term in response to

technological, economic and political factors, while shorter-term variations may occur with

7

demand, exemplified by the differences between base load and peak load electrical generation

mixes (USDOE 2011b). Environmental emission and consumption factors change over the long

term, based on technology and regulatory controls (USEPA 2009b). Long-term changes in

emission factors may be taken into account by updates in LCA databases or updates to

previously published studies, e.g. (Marceau et al. 2007; Nisbet et al. 2002). In some cases, LCA

tools may explicitly include long -term emission trends at the inventory stage (ANL 2010).

Short-term environmental dynamics are less often included in LCA, though seasonal and diurnal

variations of environmental dynamics are incorporated in some studies of life cycle impact

assessment (LCIA) characterization factors (Shah and Ries 2009), and are acknowledged as

critical in modeling the environmental impact of some pollutants of importance to many LCIA

categories (Bergin et al. 2007).

2.2 LCA AND INDOOR ENVIRONMENTAL QUALITY

Indoor environmental quality (IEQ) is a crucial area of health-related environmental

protection because of the large portion of time spent indoors by most people, whether at work,

home or in other buildings. IEQ can be affected by chemical pollutants emitted indoors by

materials and processes (e.g., carbon monoxide and volatile organic compounds or VOCs), and

intake of outdoor ambient pollutants through ventilation (e.g., ozone, nitrogen oxides or NOx,

and particulate matter or PM) (ASHRAE 2009). Concentrations of pollutants indoors can be

many times greater than outdoors, which compounds the effects of amounts of time spent inside

(USEPA 2009a). Reactions between outdoor air pollution and indoor materials can generate so-

called secondary indoor emissions, such as the effects of ozone on VOC release from otherwise

8

inert indoor materials. Human beings themselves are the source of infectious biological aerosols

(bacteria and virus particles), which cause a variety of acute respiratory illnesses (ARIs).

Moisture buildup can lead to the presence of molds and non-contagious biological contaminants,

which also affect respiratory function. Many potential exposure mechanisms linked to inadequate

ventilation in buildings but causing similar symptoms, such as headaches and respiratory

distress, are lumped together under the category of building related illness (BRI) or sick building

syndrome (SBS) (Fisk et al. 2009). Though the exact mechanisms are not known, relationships

between building variables and impacts on health and well-being have been empirically

quantified (Fisk et al. 2009; Seppänen et al. 2006a; Seppänen et al. 2006b) and thus can be

integrated into comprehensive environmental and health assessments of building performance.

The LCA field has recently begun to recognize the importance of indoor air pollution (Hellweg

2009; Humbert et al. 2011), but these efforts do not extend to indoor environmental quality

(IEQ) issues unrelated to pollutant concentrations.

To include IEQ in LCA, it is necessary to categorize its impacts in a manner comparable

to existing impact categories. Two major conceptual frameworks exist: the use of a separate

category for IEQ, and the integration of IEQ impacts into traditional categories. The former

concept has been used in the BEES model (Lippiatt). In BEES, the IEQ category is presented as

an additional midpoint alongside the remaining midpoint categories (e.g. global warming

potential, eutrophication) taken from TRACI (Bare et al. 2003). It is further limited to indoor air

quality (IAQ) and uses a proxy indicator - total VOC emissions per installation or replacement -

to model the off-gassing that occurs with certain newly installed products. The performance of

whole building systems with respect to IAQ is outside the implicit scope of BEES since it is

primarily used for product selection.

9

The second approach is favored by the midpoint-damage framework developed under the

United Nations Environmental Program – Society for Environmental Toxicology and Chemistry

(UNEP-SETAC) Life Cycle Initiative and the Impact 2002+/Impact North America life cycle

impact assessment method (Humbert et al. 2009; Jolliet et al. 2003; Jolliet 2004). This modeling

framework includes the human health midpoint categories of cancer toxicity, non-cancer

toxicity, respiratory inorganics, respiratory organics, ionizing radiation, ozone depletion, and

photochemical oxidation (smog) (Jolliet et al. 2003). Indoor impacts can be explicitly included in

the human health categories (Hellweg 2009), but studies using this approach as well as

documentation of emissions rates and indoor concentrations are lacking in the literature.

However, building systems contribute to occupants’ well-being in a number of ways beyond

inhaling or ingesting specific toxic chemical pollutants. Health effects of poor IAQ include acute

respiratory illnesses (cold and flu), respiratory allergies and asthma, sick building syndrome

(respiratory symptoms not associated with illness or allergies), depression, and stress (Fisk 2002;

Singh et al. 2010). The term IAQ is used to indicate the presence of moisture or contaminants in

the air (carbon dioxide, VOCs, mold spores, virus particles, etc.) and is a subset of IEQ, which

also includes temperature, lighting, acoustics and safety effects. The links between IEQ, health

effects and worker productivity has been increasingly studied recently. IEQ may affect

productivity through classifiable health effects or through other mechanisms not generally

classified as health-related; for instance, employee attitudes toward work. Fisk and others have

reviewed studies showing how building ventilation rates affect sick building syndrome (Fisk et

al. 2009); generally, increasing ventilation decreases sick building syndrome up to a point.

With respect to productivity, ventilation has been studied more often than other variables

with respect to productivity; Seppanen (Seppänen et al. 2006b) summarized nine previous

10

studies reporting quantitative results for the relationship of ventilation to productivity. Seppanen

found continuous increases in productivity with ventilation rates from 6.5 l/s/person up to up to

65 l/s/person, with statistically significant increases up to 15 l/s/person. Productivity increases

were generally in the vicinity of 1% to 3%, though some have reported higher results. Thermal

comfort - temperature, humidity and airflow speeds - has also been shown to have productivity

impacts (Seppänen et al. 2006a). The impact of lighting quantity and quality, including

daylighting, have been studied, but to a somewhat lesser degree. Abdou (Abdou 1997) and

Edwards (Edwards and Torcellini 2002) summarized literature relating to the effects of lighting

and daylighting on productivity, but did not attempt to develop quantitative relationships.

Heschong et al. showed daylighting improving outcomes in separate studies of retail and school

environments (Heschong et al. 2002a, b). A recent publication by Schuster (Schuster 2008)

surveys building users’ responses to daylighting, finding that perception of lighting quality in

day-lit spaces does not necessarily correspond with the lighting levels set for artificial lighting

conditions. Other studies have focused on occupants’ self-identification of increased productivity

due to improvements in general IEQ (Ries et al. 2006; Singh et al. 2010). To date, however, no

method has been proposed to incorporate productivity information into a life cycle assessment

framework.

2.3 ORGANIZATION OF THESIS

Chapter 3 addresses objective 1, which is to develop a dynamic LCA modeling framework that is

capable of handling dynamic variability in building operations and industrial/environmental

systems, with results including traditional LCA categories. The framework was developed and

11

then applied to a retrospective and prospective case study of Benedum Hall at the University of

Pittsburgh, evaluating the building’s performance compared to static LCAs conducted with

reference to several milestones (original construction and contemporary renovation). This work

was published in the International Journal of Life Cycle Assessment (Collinge et al. 2012b).

Chapters 4 and 5 address objectives 2 and 3, which are to develop IEQ metrics which

both complement and extend beyond traditional LCIA categories. Chapter 4 discusses the

methods used in the framework, while Chapter 5 discusses data collection and results of the in-

depth case study of the Mascaro Center for Sustainable Innovation (MCSI) building at the

University of Pittsburgh. The first portion of the framework, relating to indoor chemical impacts,

was published along with applicable results from the case study (Chapter 5) in the journal

Building and Environment (Collinge et al. 2012a). The remaining portion, relating to

nonchemical health impacts and productivity impacts, will be submitted along with additional

results from the case study (Chapter 5) for publication in a peer-reviewed journal.

Chapter 6 addresses a portion of objective 4, developing and implementing a post-

occupancy survey in the MCSI building to gather qualitative data on occupant perceptions of

IEQ and productivity aspects. Results of the survey are presented and compared to results from

other post-occupancy surveys. Survey results are also used to guide the development of the

scenario analysis focusing on energy-saving strategies, which is presented in Chapter 7. Chapter

7 applies the IEQ+DLCA framework and an empirical parametric energy model of the MCSI

building to evaluate strategies for reducing energy use in light of IEQ impacts.

Conclusions of the overall results of this dissertation and recommendations for future

work are discussed in Chapter 8.

12

3.0 DYNAMIC LIFE CYCLE ASSESSMENT MODEL WITH INITIAL

RETROSPECTIVE AND PROSPECTIVE CASE STUDY

The following chapter contains material reproduced from an article published in the journal

International Journal of Life Cycle Assessment with the citation:

Collinge, W.O., A.E. Landis, A.K. Jones, L.A. Schaefer and M.M. Bilec (2013), “Dynamic life

cycle assessment: framework and application to an institutional building.” International Journal

of Life Cycle Assessment, 18(3) pp. 538-552.

The article appears as published per the copyright agreement with Springer, publisher of

International Journal of Life Cycle Assessment.

Supporting Information submitted with the International Journal of Life Cycle

Assessment appears in Appendix A.

3.1 INTRODUCTION

Accurate whole-building LCA is limited by the standard practice of applying static

factors throughout the life cycle inventory (LCI) and life cycle impact assessment (LCIA) stages.

Since buildings have long useful lifetimes, and the use phase can have large environmental

13

impacts, variations within the use phase can sometimes be greater than the total impacts of

materials, construction or end-of-life phases (Aktas and Bilec 2012; Junnila et al. 2006; Scheuer

et al. 2003). The ability to accurately model future scenarios is critical for improved building

sustainability (Scheuer et al. 2003). Additionally, individual buildings are operated within

changing industrial and environmental systems; the simultaneous evaluation of these dynamic

interactions during product or building lifetimes is recognized as a key need in LCA (Reap et al.

2008). This chapter provides a framework for including dynamic changes both at the building

level and in background industrial and environmental systems.

3.1.1 Time in LCA

Time-related issues affect LCA in numerous ways; broadly, they can be categorized into

1) industrial and environmental dynamics and 2) time horizons and discounting of future

emissions (Reap et al. 2008). Temporal variations can be accounted for independently of any

discounting of future emissions, using the physical models underlying the inventory data and

impact assessment methods (Hellweg and Frischknecht 2004; Hellweg et al. 2003). For industrial

and environmental dynamics, one approach is to consider temporal and spatial variability as

components of parameter uncertainty in LCA and use probabilistic scenario analysis as a

technique for overcoming this uncertainty (Huijbregts 1998; Huijbregts et al. 2001). This

approach aggregates temporal and spatial variability with other sources of uncertainty, such as

different technologies in use at different industrial facilities, or inaccurate emissions

measurements. Another approach is to link explicit modeling of the primary systems of study

(e.g. a building or an industrial process) with traditional aggregated LCA datasets, and use

additional probabilistic analysis to characterize uncertainty in upstream or downstream material

14

flows or emissions (Reap et al. 2003; Ries 2003; Udo de Haes et al. 2004). Another approach is

to shift the focus away from a single product or functional unit to the entire in-use suite of

products to capture changes in technology or infrastructure over a given period of interest (Field

et al. 2000; Levine et al. 2007; Stasinopoulos et al. 2011).

Recent research has approached different aspects of the time-LCA problem. These

studies can be differentiated by whether dynamic methods are applied to the LCI or LCIA steps

in the analysis. Several studies have used dynamic LCI data to assess renewable energy systems,

considering past and potential technology improvements affecting production efficiencies (Pehnt

2006; Zhai and Williams 2010). For the LCIA step, studies have used atmospheric and other

environmental models to calculate time-dependent characterization factors (CFs) on both multi-

year scales (Seppälä et al. 2006; Struijs et al. 2010) and seasonal scales (Shah and Ries 2009).

The time-dependence of these CFs is a function of background pollutant concentrations or

climatic factors. Other studies have investigated the relative impact of emissions timing with

respect to a fixed time horizon (e.g. 100-year global warming potential) in the case of land-use

change and biofuels (Kendall et al. 2009; Levasseur et al. 2010); vehicle regulations (Kendall

and Price 2012) and the institutional building previously studied by Scheuer et al. 2003 (Kendall

2012). In these cases, emissions occurring farther in the future are effectively discounted by their

proximity to the overall study time horizon. This effective discounting is distinct from economic

discounting or pure time preference discounting. However, few studies so far combine dynamic

scenario analysis with temporally explicit LCI data or any type of temporally explicit LCIA

method.

15

3.1.2 Scope and functional unit of this study

The scope of this study was to establish a dynamic LCA (DLCA) approach and test this

approach with a case study of an existing institutional building. These results were compared

with LCA results from a static approach. The functional unit chosen for this study was an

institutional building (Benedum Hall at the University of Pittsburgh) over its assumed lifetime of

75 years (until 2045). Benedum Hall is an existing building that opened in 1971. The system

boundary for the study included primarily materials for construction and renovation, and

electricity/fuels for building operation. Two separate comparative static versus dynamic

analyses were constructed: one for the entire lifetime of the building assuming a 1971

perspective, and one for the remaining life of the building including an actual major renovation

and addition, assuming a 2009 perspective. A scenario and sensitivity analysis was conducted for

the 2009 dynamic perspective to elicit the effects of changing individual model parameters.

3.2 METHODS

3.2.1 Modeling approach

Heijungs and Suh (Heijungs and Suh 2002) developed a general equation for the

environmental impact of a product system for a process-based LCA approach. Mutel and

Hellweg restated this equation as shown in Equation 1 (Mutel and Hellweg 2008):

Equation 1

fh ×××= −1ABC

16

where h is a vector representing total environmental impacts of the studied system, in some

number of impact categories determined by the selected LCIA method; f represents the quantities

of outputs from the industrial supply chain (e.g. materials, fuels) required for a specified function

of the studied system; A is the technosphere matrix representing each unit of output as a function

of the inputs to the various processes needed to generate that output; B is the biosphere matrix

representing the environmental interventions (emissions and resource consumption) required for

each process in the supply chain; and C (originally W in Mutel and Hellweg; changed to C

herein) is a matrix of CFs which represent the magnitude of the effect of each quantity of

emission or other intervention in each impact category. C is given here as a matrix rather than a

vector or diagonal matrix, to efficiently account for the effect of some emissions in multiple

impact categories.

The static approach to LCA often assumes point values for all of the coefficients in the C,

B, and A matrices, and is usually structured such that the f vector represents a one-time output of

the system (quantity x of product y at an arbitrary time). By contrast, a building is an example of

a system whose input requirements vary with time and as a function of changes in its usage.

Thus, the demand vector f becomes ft at any point in time t, as a function of basic operating

variables (e.g. occupancy schedules, thermostat setpoints), which are not normally captured in

LCA. These operating variables may include material inputs during maintenance, various types

of energy inputs required for routine operations based on building schedule and seasons, and

replacement of materials and systems at periodic intervals.

Similarly, over the long life of a building, time-related changes may affect the other

variables in Equation 1. The technosphere matrix A may change over time due to product

substitutions, efficiency improvements, or other changes in the structure of the industrial supply

17

chain. The biosphere matrix B may also change over time for the above reasons, or due to

regulatory controls on emissions. Temporal changes in CFs in the C matrix are also possible as

evidenced by previous studies, e.g. (Kendall 2012; Seppälä et al. 2006; Shah and Ries 2009;

Struijs et al. 2010).

Given the potential for each term in Equation 1 to change over time, a simplified model

for DLCA is shown in Figure 1 and represented mathematically by the following:

Equation 2

ttt

te

ttt fh ×××= −∑ 1

0

ABC

where the t represents a point in time at which the values in the various terms are known, and t0

and te represent the beginning and ending time points of the analysis, usually the beginning and

end of the product or system life cycle. The t subscript does not imply that these terms are direct

mathematical functions of time; rather, they are functions of their underlying variables that can

be represented as a time series. Particularly, the matrix of CFs, Ct could encompass variations in

all the underlying variables (fate, exposure, and effect factors), which must be calculated for

each point in time by the physical models applicable to each category. Ct could also encompass

adjustments made to CFs for other reasons, such as proximity to the analysis time horizon, as in

Kendall (Kendall 2012). Separate types of changes to CFs could be explicitly documented by

constructing several separate C matrices (e.g. Ct, [fate] or Ct, [time horizon]) and combining these

matrices by scalar multiplication (Hadamard product) at the time of analysis.

18

Figure 1 - Conceptual diagram of DLCA framework

There are several considerations to this approach. First, this approach follows an

attributional, rather than consequential LCA structure (Ekvall and Weidema 2004). In

attributional LCA, the impact of an emission is considered to be the total impact of the product

system normalized to a functional unit,, whereas consequential LCA investigates the effects of

marginal choices. In the attributional formulation of the DLCA model, the aggregation is

performed at the time step level (variations at smaller scales are implicitly averaged). Thus, the

terms in eq. 2 are able to vary independently of each other. However, the use of dynamic

modeling of system interactions introduces the possibility of feedback loops in which changes

occurring in different parts of the system induce mutual changes in each other. The inclusion of

feedback loops between variables in Equation 2 (e.g. coefficient Ai,j relating process i to product

j as a function of fj, the quantity of product j required) would move the model partway toward a

consequential LCA structure (e.g. marginal effects on power or district heating generation from

adding a building to the utility grid). However, a fully consequential LCA requires a general

equilibrium economic model with many additional assumptions about changes in industrial

19

relationships based on additional or changed demand for goods and services. A fully

consequential LCA structure is sometimes used in large-scale policy analysis but may not be

appropriate for the study of individual buildings. For the current study, feedbacks are

hypothesized to be significant only within the systems captured by the building energy model

that produces the f vector. These feedbacks are briefly discussed in Section 2.4.1.

Another consideration is the issue of lag time in the supply chain, where lag time is

defined as the difference in timing of processes and emissions at multiple levels in the supply

chain (Levine et al. 2007). Some examples are the time difference between the production of a

building material and its installation at the construction site, or the time difference between fuel

extraction and combustion. For the simplified mathematical model in Equation 2, supply chain

functions must be assumed to occur simultaneously in order to invert the A matrix. A more

complete formulation would involve specifying the lag time for each supply-demand linkage,

which would require calculation using a tree structure rather than a matrix structure, as the

number of inputs at different time lags would multiply with each step back through the supply

chain. This approach could be implemented with an inventory or impact cutoff tolerance.

However, data limitations prevented the inclusion of lag times in this study as discussed further

in section 3.4.

A prototype DLCA model was constructed using Microsoft Excel and Visual Basic for

Applications (VBA). The model used Excel worksheets to store basic data such as process inputs

and outputs, emission factors and CFs, while VBA code was used to perform the matrix

calculations. The key difference between the prototype model and most standard LCA

applications was the use of time series tables to simulate dynamic variation in matrix coefficients

representing modeled relationships. With the time series enabled, any coefficient ci in a vector or

20

ci,j in a matrix can become ci,j,t, where i and j represent the coefficient’s position in the matrix in

question and t is the current model time step. The model explicitly considered four categories of

time series in the LCA calculation, corresponding with the four variables of Equation 2. These

categories are outlined in Table 1, along with illustrative examples. Any variable without a time

series available due to data limitations was assumed to have a constant value, as in a typical

static LCA calculation.

3.2.2 Case study

An existing institutional building – Benedum Hall at the University of Pittsburgh – was

selected as the case study for this project. Originally constructed in 1971 to house the

engineering program, the Benedum Hall complex includes a twelve-story tower housing

laboratories, offices and classrooms; two below-grade floors with additional office and

laboratory space, and a two-story auditorium. The two below-grade floors extend under the

footprints of both the tower and the auditorium, and support a first-floor level outdoor plaza. The

complex underwent a major renovation beginning in 2006, including the construction of a new

wing on the first, second and third floors; major upgrade of all mechanical systems; replacement

of all the windows and floor coverings; roof replacement including green roof spaces on both the

auditorium and a portion of the plaza; and numerous interior space renovations. The additional

wing and renovation of the 2nd floor of the tower were completed in November 2009; roof and

window replacement on the remaining structure and renovations of the below-grade floors,

ground floors and auditorium were completed by August 2010, and renovations of the 3rd-12th

floors of the tower are scheduled to be completed by the end of 2012. [UPDATE: 7th floor was

completed as of September 2012. Work continues on floor 8-12 as of this writing].

21

Since the original construction, steam for heating the building has been supplied by a

district heating system used by the University and several nearby institutions. Until June 2009,

steam was generated using a combination of coal-fired and natural gas-fired boilers at a single

plant; in June 2009, a second plant was added and the existing plant was converted to 100%

natural gas-fired boilers. Cooling was originally provided by a stand-alone chiller plant on the

building’s roof, which was replaced by a connection to a new district chilled water plant in 2002.

Table 1. Categories of dynamic life cycle assessment (DLCA) parameters for buildings, examples, and data sources

used in the case study.

Category [with parameter from Equation 2 in bracketsa]

Examples Data used in case study with associated time interval

Building Operations [ft]- initial construction activities; additions, renovations, or major component replacements; changes in usage patterns or energy consumption

Material required for initial construction; material required for replacement of components or reconfiguration of interior spaces; changes in energy consumption

-Benedum Hall original construction plans; 1971 (DRA 1965) -Benedum Hall utility usage (steam, electric, and water); 7/1992-12/2010

-Benedum Hall construction plans for renovation and addition; 2006-2010 (Edge 2007, 2008) -eQUEST model (projected); 2009-2045

Supply chain dynamics[At]- changes to upstream processes independent of building management decisions

Changes in fuel mix and efficiency of the electricity grid; changes in origin of natural gas and petroleum supplies; changes in regional waste treatment practices

-District heating plant fuel consumption and steam production; 1/2000-12/2010

-National annual and monthly electric power generation by fuel type; 1970-2008 (USDOE 2010b): (projected); 2009-2045 (USDOE 2010a)

Inventory dynamics [Bt]- changes in resource use or pollutant emissions by processes due to technology, regulation or other factors

Influence of environmental regulations on pollutant emissions; changes in efficiency of industrial processes

-National GHG emissions from electric power generation by fuel type and other major GHG sources; 1990-2008 (USEPA 2010) -National criteria air pollutant (CAP) and hazardous air pollutant (HAP) emissions; 1970-2008 (USEPA 2009, 2011b): (projected); 2009-2016 (USEPA 2011a)

Environmental system dynamics [Ct] – changes in background environmental systems affecting the fate, exposure and effects

Changes in system sensitivity due to background concentrations or distribution of populations; changes in ambient conditions affecting emission fates; consideration of an analysis time horizon

--Time adjusted (global) warming potentials (TAWPs); 2009-2045 (Kendall 2012) -Seasonal characterization factors for photochemical ozone; 2009-2045 (Shah and Ries 2008)

aParameter definitions: [ft]- vector of outputs from the industrial supply chain (e.g. materials, fuels); [At]- matrix representing each unit of output as a function of the inputs to the various processes needed to generate that output; [Bt]- matrix representing the environmental interventions (emissions and resource consumption) required for each

process; [Ct] – matrix of characterization factors representing the magnitude of the effect of each quantity of emission or other intervention in each impact category

22

3.2.3 Static and dynamic LCA comparisons

The DLCA model and a static LCA model were compared over two analysis time frames.

The first time frame consisted of the entire lifetime of the building and used a 1971 perspective;

while the second time frame consisted of the remaining life of the building using a 2009

perspective. We will refer to these as the “full lifetime” and “remaining lifetime” analyses

hereafter. The system boundary for both static and dynamic analyses included building materials

and operating fuels/electricity, as well as their respective upstream processes. The system

boundary of the DLCA model, including the extent of dynamic processes included, is shown in

Figure 2. Material transportation, on-site construction activities, routine maintenance and end-of-

life disposition were excluded from the study. Due to the complexity of modeling the entire

building, only major systems were selected from the initial construction, and a comparison was

made to two previous studies to assess the degree of completeness of the results (Junnila et al.

2006; Scheuer et al. 2003).

The full lifetime of Benedum Hall was assumed to be 75 years, consistent with its current

status (recently renovated at 40 years old) and one previous study of an institutional building

(Scheuer et al. 2003). It has been noted that arbitrary assumptions about building lifetime can

significantly affect LCA results (Aktas and Bilec 2012). The full lifetime DLCA encompassed

four distinct phases: 1) initial construction (1971); 2) initial operations (1971-2008); 3)

renovation activities (2006-2012); and 4) future operations (2009-2045). The renovation

activities were assumed to occur in 2009. Construction material quantities from the original

construction, renovation and addition were obtained from the construction drawings and

specifications for each project (DRA 1965; Edge 2007, 2008). The full lifetime static LCA

coupled the initial construction results with a projection of the initial year’s operations over the

23

75-year assumed building lifetime, and did not include the renovation/addition. The remaining

lifetime DLCA and static LCA included the renovation and future operations phases. The

remaining lifetime DLCA was used as the basis for the future scenario analysis (Section 2.5).

Figure 2 - System boundary and dynamic modeling

For this study, the DLCA model used a monthly time series for several reasons.

Historical values for the building’s utilities were available on a monthly basis, and fuel mixes for

the electricity grid (USDOE 2010) and heating plant were also available on a monthly basis

(Section 2.4.2). Annual aggregation of these values would potentially have masked variation in

the results due to the timing of variations in energy use and the fuel mix. Emissions factors were

typically annual values.

24

3.2.4 Data collection

Dynamic LCI - building-level data and modeling (ft) - Historical and future values for the

f vector were generated specifically for the case study building. Operating energy consumption

was taken from utility meter data for Benedum Hall. Data availability varied depending on the

individual variables; a summary is provided in Table 1 and a complete list is given in Table 14.

For years prior to data availability, the average of the first three available years was used. Future

energy consumption was estimated using the U.S. Department of Energy’s (USDOE) eQUEST

model (Hirsch 2010), adjusting model default parameters to reflect the specific conditions for

Benedum Hall. A qualitative comparison of the eQUEST model results and both the extensive

pre-renovation and limited post-renovation utility meter data was performed to verify the

model’s predictive capacity; results of this comparison are presented in Figure 24 and Figure 25.

Dynamic LCI - unit processes (At) - Temporally specific historical and projected future

unit processes for the A matrix were constructed from U.S. Energy Information Agency (EIA)

records and projections (USDOE 2010, 2011b) for the national electricity generation mix; and

meter data for the central campus steam plant (Table 14). Data sources for each process type are

provided in Table 1. Upstream processes without dynamic data available were referred to 1)

USLCI unit processes (NREL 2011), for energy and fuels; and 2) the ecoinvent v2.2 database

(ecoinvent 2010), for materials. Ecoinvent was chosen over USLCI for materials because some

material processes in the USLCI database do not explicitly link to upstream processes, but rather

aggregate emissions from all upstream processes into one list. Separation of upstream unit

processes was necessary to enable the DLCA model to function properly. However, because

ecoinvent consists of mainly European data and does not contain time series, several

modifications were made: 1) process electricity requirements from materials in ecoinvent were

25

referred back to the time series described above, and 2) other process energy (e.g. heat,

equipment fuel use) were referred to the USLCI energy unit processes. Thus, the material

processes used for the 1971 construction were the same as those used for the 2009

renovation/addition, with the exception of changing the fuel mix and emissions for the electricity

generation required by these processes.

Dynamic LCI - emissions factors (Bt) - Temporally specific emissions factors for the B

matrix were constructed from available industry and environmental data (USEPA 2009b, 2010,

2011b) and Allegheny County Health Department (ACHD) data for the central campus steam

plant (Kelly 2011). For example, emission factors for criteria air pollutants (CAPs) from electric

power generation were calculated by dividing U.S. Environmental Protection Agency (EPA)

historical emissions data (USEPA 2009b, 2011b)by the U.S. Energy Information Agency (EIA)

records of power generation by fuel type (USDOE 2011b). Data sources for each variable are

provided in Table 1; time series of emission factor results in each LCIA category are presented in

Figure 26. Where possible, these values were compared against the USLCI database (NREL

2010) for consistency within the time frames for which the USLCI database applies. Qualitative

results of this comparison are also presented in Figure 26.

Dynamic LCIA - characterization factors (Ct) - Temporally specific CFs are only

available in a few LCIA categories. Therefore, for the baseline full lifetime and remaining

lifetime DLCA calculations, static factors from the TRACI method were used (Bare et al. 2003).

Temporally specific CFs available in the literature include monthly CFs for photochemical ozone

in the U.S. (Shah and Ries 2009); annual global CFs for ozone depletion (Struijs et al. 2010),

decadal-scale CFs for acidification and eutrophication in Europe (Seppälä et al. 2006), time-

horizon adjusted CFs for acidification in Europe (Van Zelm et al. 2007), and time-horizon

26

adjusted CFs for global warming, e.g. (Kendall 2012). The European acidification and

eutrophication CFs are not adaptable to the U.S. due to the lack of a U.S.-based database of

ecosystem sensitivities (Norris 2003). The lack of any consistent set of temporally variable CFs

for the U.S. across multiple impact categories led to the decision not to include them in the

baseline analyses for this study. However, example calculations using two sets of dynamic CFs -

photochemical ozone from Shah and Ries (Shah and Ries 2009) and global warming (Kendall

2012) have been included in the future scenario analysis (Section 2.5). The compilation of a set

of temporally variable CFs across multiple impact categories and time scales for the U.S. is

planned as future work.

3.2.5 Future scenario analysis

A future scenario analysis was conducted to probe the sensitivity of the results to changes

in assumptions about future trends, building on the remaining lifetime DLCA calculation (2009-

2045). The individual and combined influence of end-use energy variations, fuel mixes, and

emissions controls was investigated by pairing different combinations of each variable in Eq. 1.

For ft, scenarios were generated using 10% increases and decreases in electricity consumption

and steam heat consumption separately. This range was anticipated to be within the capacity of

adjustments to existing set points and operating schedules, and thus allowed for some level of

uncertainty in occupant usage and behavior. For At, the EIA’s 47 projected cases from the

Annual Energy Outlook (AEO) were examined and the cases which resulted in the greatest

variation in generation mixes from the baseline were added to the analysis (USDOE 2010). For

Bt, a scenario without the EPA’s currently proposed regulations was examined, in which

emissions factors remained constant at 2009 levels. The scenario pairing no increase or decrease

27

in energy consumption with no new EPA rules was similar to the static LCA, except that even

the EIA’s baseline (Reference case) includes expected changes in the future generation mix and

is thus dynamic.

Finally, for Ct, calculations were constructed in the GWP category using time-adjusted

warming potentials (TAWPs) from Kendall 2012, and in the photochemical ozone category

using monthly factors for a typical year from Shah and Ries 2009. Shah and Ries developed CFs

at the midpoint level for nitrogen oxides (NOx) and volatile organic compounds (VOC) in terms

of ppb O3*km2*day/kg emission. To compare with the static TRACI CFs, which use a reference

unit of kg NOx eq., the Shah and Ries CFs were normalized by dividing the monthly values for

NOx and VOC by the annual average value for NOx from their own study.

3.3 RESULTS AND DISCUSSION

3.3.1 Static LCA validation

Total mass of the materials and embodied energy inputs of the static LCA for the original

construction were compared with two previous studies of commercial and/or institutional

buildings in the US (Junnila et al. 2006; Scheuer et al. 2003) to validate LCA inputs. Scheuer et

al. analyzed a 6-story combination academic and hotel building in Michigan, and Junnila et al.

analyzed a 5-story office building in the U.S. midwest. Results of the comparison are

summarized in Table 2. A complete comparison of LCI results is given in Table 15. Total

normalized mass of Benedum Hall was estimated to be 1,670 kg/m2 and total embodied energy

to be 5,080 MJ/ m2, compared to 2,000 kg/m2 and 6,250 MJ/m2 for Scheuer et al., and 1,290

28

kg/m2 and 11,900 MJ/m2 for Junnila et al. Total annual operating energy was 3,920 MJ/m2,

compared to 4,100 MJ/m2 for Scheuer et al. and 1,320 MJ/m2 for Junnila et al.

The results of this study agreed qualitatively with Scheuer et al. in most categories, and

with Junnila et al. in some categories. A significant degree of variation is expected even between

comparable buildings, due to differences in construction details, selection of system boundaries

and the use of different LCI databases. The material systems included in this study for Benedum

Hall represented 90% of the results of the Scheuer et al. study by mass, and 74% by embodied

energy.

Table 2 - Mass and energy inputs for static LCA model of the building materials and initial energy consumption.

Material and Energy Results

Case Study: Benedum Hall

Scheuer et al. (2003)

Junnila et al. (2006)

Mass/ area

(kg/m2)

Energy/ area

(MJ/m2)

Mass/ area

(kg/m2)

Energy/ area

(MJ/m2)

Mass/ area

(kg/m2)

Energy/ area

(MJ/m2) Total materials 1,670 5,080 2,000 6,250 1,360 11,920 Original construction materials

1,570 4,250 NG NG 1,290 7,060

Renovation/ addition materials

100 820 NG NG 70 4,860

Annual operating energy - total

- 3,920 - 4,100 - 1,360

Annual operating energy - electricity

- 3,340 - NG - 700

Annual operating energy - heat

- 580 - NG - 660

NA = Not applicable NG = Not given (results are presented graphically)

Embodied energy was calculated as total nonrenewable energy. Results from two other LCA studies of commercial

or institutional buildings in the US are presented for comparison and validation.

Mass results on a system-by-system basis were comparable to Scheuer et al. (more detail

provided in Table 15); the differences in embodied energy can be attributed primarily to 1) the

29

exclusion from this study of internal finish materials, such as carpet and ceiling tiles and 2) the

value for embodied energy for steel from the LCI databases used. Finish materials such as carpet

and ceiling tile have high embodied energy contents and frequent replacement intervals, and

account for a significant portion of the total embodied energy results in Scheuer et al. The

amounts of such materials in Benedum Hall are minor by comparison with most buildings and

were not considered in this study. Compared with Junnila et al, the lower embodied energy per

unit mass can also be attributed in part to the exclusion of interior finishes from this study, since

items such as structural steel and concrete had reasonably similar value for total embodied

energy per unit area of the building. However, Junnila et al. also used a hybrid process-based and

economic input-output (EIO) based LCA model, which may have contributed to the difference.

From comparison with both studies, future work on the dynamic LCA model should include

finish materials such as paint, carpet and tile for the sake of full compatibility with other studies

and to accommodate buildings with larger amounts of these materials than Benedum Hall.

3.3.2 DLCA and static LCA results for full lifetime analysis

The DLCA results were lower than static LCA results in most impact categories with the

exception of nonrenewable energy use (NREU; +12%), as shown in Figure 3. The factors

affecting the DLCA results in terms of eq. 2 were (1) the building’s end-use energy consumption

(included in ft), (2) the electrical generation fuel mix (included in At), (3) the steam generation

mix (also included in At), and (4) emissions factors for the national electrical grid (included in

Bt). The results showed reductions of more than half in the categories of acidification (-57%),

human health respiratory effects (-61%), photochemical ozone (-55%), eutrophication (-53%)

30

and carcinogens (-57%). Non-carcinogens and ecotoxicity were reduced by lesser amounts (-

27% and -9% respectively). Global warming potential (GWP) decreased by 2%.

Figure 3 - Comparison of results from static and DLCA models, using the TRACI method.

Results are normalized to the total static LCA results for each category. Static LCA results were calculated as the

total of the initial construction and projection of the initial year’s operating energy consumption for the 75-year life

of the building. DLCA results are classified into four categories: Original construction materials; Pre-renovation

operations (operating energy consumption through 2008); Renovation and addition materials; and Post-renovation

operations (operating energy consumption 2009 through end of lifetime).

The largest differences in the results were due to the lowering of emission factors for

CAPs from 1970 to the present, documented by EPA’s extensive historical estimation of CAP

trends and continuing projected reduction in the near future through 2015 due to the EPA’s

31

proposed Transport and Toxics Rules. Data for hazardous air pollutants (HAPs) also exist in

EPA’s historical estimates and future projections, though coverage dates are generally more

limited (1990-2008). No such national database for water pollution was found, though estimates

are noted in the literature (Bare 2011). Therefore, the water emissions estimated herein are

primarily static values from the ecoinvent and USLCI databases. Additionally, water pollution

related categories such as eutrophication and ecotoxicity may be under-represented because

wastewater from the building was not included in the study.

The three toxic pollutant LCIA categories (human health cancer, human health

noncancer, and ecotoxicity) are typically affected by both air and water emissions of hazardous

metals and organic compounds. However, air emissions of metals from coal combustion

dominated the results in the three toxics categories. In accordance with EPA modeling

documentation, combustion-related air emissions of metals were projected proportionately to

particulate matter <2.5 µm (PM2.5) and organic compounds were projected proportionately to

total VOCs (USEPA 2011a). Non-carcinogens and ecotoxicity were affected to a higher degree

than carcinogens by water emissions, and thus do not show as much reduction from historical

levels, due to the use of static data for water emissions. Material production processes for the

construction and renovation had a proportionately greater impact in the non-carcinogens and

ecotoxicity categories than the other categories; however, operating energy consumption still had

the greatest impact. For ozone depletion, all processes considered in this LCA are minor sources,

and thus neither the static nor dynamic results were considered to be significant.

Changes in emissions factors had the greatest influence on the LCIA results, but the

remaining variables in eq. 2 (ft, At) were also important, particularly in the GWP and NREU

categories. Figure 4 shows the DLCA results as cumulative time series in each LCIA category,

32

normalized to the cumulative totals in each category as of 2008. Impacts from construction and

renovation are represented at a single point in time; realistically, these impacts occur over the

span of several years. The time scale associated with these activities is shorter than that for

building operations, even when operations are classified into phases between major renovations.

Since the temporal changes incorporated into the current analysis are mainly gradual and on the

order of decades, the treatment of material- and construction-related emissions as pulses were not

expected to influence the overall results.

Electrical energy consumption increased gradually during the period of pre-renovation

meter data availability, growing 10% from 1993-1994 through 2007-2008. Steam consumption

remained essentially constant during this same period. The cause of the increased electrical usage

was not known, but it was assumed to be from increases in laboratory and office equipment

demand, including computers. If electrical energy consumption was due to increased use of the

overall building (e.g. extended hours, increased ventilation etc.), it would be expected to result in

an increase in steam use as well. For the renovated building, modeled energy consumption of

both types increased. An increase in overall building footprint, coupled with increased heating,

cooling and fan usage demands from increased space ventilation requirements were responsible

for the increased energy consumption.

In the GWP category, the increasing trend in energy consumption was offset by a

decreasing trend in greenhouse gas (GHG) emissions from the energy supply chain. While the

electrical generation mix continues to rely heavily on coal-fired power plants, GWP for the

electrical generation sector decreased 11% from 0.72 kg CO2 eq/kWh in 1970, to 0.64 kg CO2

eq/kWh in 2008. GWP of the district steam production decreased 39% from 2.3 to 1.4 kg CO2

eq/kg steam, following the switch from mixed coal- and gas-fired generation to 100% gas in June

33

2009. However, the modest decrease in GWP/kWh from electrical generation was offset by the

modest increase in electrical usage over the building’s lifetime to date, and the larger decrease in

GWP/kg steam was offset by the larger increase in projected steam usage following the

renovation as noted above. Because the heating fuel switch and renovations occurred at nearly

the same time, the slope of the NREU curve in Figure 4 is higher post-renovation than pre-

renovation, while the slope of the GWP curve in Figure 4 remains the same. Because natural gas

emits fewer CAPs and HAPs than coal, the heating fuel switch also affected the curves in Figure

4, combining with the reduced emissions factors from electric power generation to reduce the

slope of the future curves.

34

Figure 4 – Cumulative time series of DLCA results in TRACI impact categories and nonrenewable energy

use. Cumulative totals are normalized to year 2008 totals (prior to renovation).

35

3.3.3 DLCA and Static LCA results for remaining lifetime analysis

The DLCA results for the remaining lifetime analysis were lower than the static LCA

results in every impact category shown in Figure 5. As with the full lifetime analysis, the static

LCA used energy mixes and emission factors from the year of analysis (2009) projected through

the remaining lifetime. However in contrast with the full lifetime analysis, the building’s end use

energy consumption was the same for both static and dynamic analyses, since no actual energy

data were available yet. Reductions in impacts from largest to smallest were: acidification (-

17%), photochemical ozone (-16%), human health respiratory effects (-15%), eutrophication (-

14%), carcinogens (-5%), NREU (-4%), non-carcinogens (-3%), ecotoxicity (-3%), and GWP (-

2%). As with the full lifetime analysis, the largest decreases were caused by a reduction in

emissions factors following environmental regulations (the proposed EPA Transport and Toxics

rules). The reductions in global warming potential and nonrenewable energy use were due to

changes in the electrical fuel generation mix.

3.3.4 Future scenario analysis

The maximum variations from the baseline for the different DLCA scenarios are shown

as error bars on the DLCA results in Figure 5. These error bars represent the scenarios

contributing to the minimum and maximum impacts in each category. Other types of uncertainty

and variability (not shown) include parameter uncertainty (e.g. emissions factors) and spatial

variations. These uncertainties can be elicited by Monte Carlo analysis (e.g. Dale et al. 2013) and

could be shown as an additional set of error bars, applied to both the static and dynamic LCA

results. For the baseline energy use case, the minimum and maximum variability from the static

36

LCA due to combining variability in projected energy mixes and emissions factors were:

acidification (+39%/-18%), photochemical ozone (+36%/-15%), human health respiratory effects

(+35%/-22%), eutrophication (+32%/-20%), carcinogens (+20%/-34%), non-carcinogens

(+10%/-12%) and ecotoxicity (+9%/-9%). The minimum and maximum variability for categories

depending only on energy mixes were nonrenewable energy use (+7%/-15%) and global

warming potential (+10%/-17%).

Figure 6 shows selected time series for the global warming and photochemical ozone

impact categories, representing scenarios with different combinations of variation from the

baseline, for each term in eq. 2. The remaining series are presented in Figure 29. Of the

variations in the f vector, the 10%+/- electricity scenarios had greater influence than the 10% +/-

heat scenarios, due to 1) the larger overall energy use represented by electricity for this building,

and 2) the larger impact in most categories per unit energy of electricity, due to the use of coal as

a fuel. The variations in the f vector are a simple scaling of the baseline results, but are

qualitatively illustrative of uncertainty in building use, such as hours of operation, user behavior,

or HVAC system setpoints. They are also a point of reference in Figure 6 for the relative changes

in impact due to the scenarios representing variations of the A, B and C matrices.

37

Figure 5 - Comparison of predicted results for from static and DLCA models for the renovation and post-

renovation operations.

Error bars on the DLCA results indicate the minimum and maximum values associated with different scenarios from

the sensitivity analysis. For the GW and PO categories, the error bars include consideration of dynamic

characterization factors at the impact assessment step. Error bars for all other categories include only variation in the

life cycle inventory.

38

Figure 6 - Time series of DLCA results for the sensitivity analysis, shown as cumulative percent deviations

from the baseline scenario for the global warming potential and photochemical smog categories.

Time series plots of the deviations from baseline for the remaining TRACI impact categories are presented

in Figure 29.

Of the 47 electricity grid mix scenarios drawn from the EIA AEO (represented in the A

matrix), the greatest decrease in impact in most categories was the “GHG price economywide”

scenario, representing a future in which coal use drops steeply due its greater CO2 emissions than

other fuels. The AEO scenario with the greatest increase in impacts was the “low shale resource”

39

scenario, in which estimated unproven resources (EURs) are assumed to be half those in the

Reference case. The low availability of shale gas in this scenario leads to a reduced use of gas

and a corresponding increase in coal for electric power generation.

For any combination of f and A scenarios, eliminating the introduction of the new EPA

regulations (represented in the B matrix) showed increased impact in most categories associated

with CAPs (and some HAPs, such as metals from coal-fired power plants) compared to the

baseline DLCA case. Scenarios eliminating the new EPA regulations combined with low gas

resources - and hence increased coal use for power generation without significant new emission

controls - showed increased impacts in these categories compared even to the static LCA.

The effect of including dynamic CFs is shown in the odd-numbered curves in Figure 6,

and is reflected in the error bars in the global warming and photochemical ozone categories in

Figure 5. In both cases, the addition of dynamic CFs reduced the total impacts compared to static

CFs, though for different reasons. For global warming potential, the dynamic CFs, or TAWPs,

reduced the cumulative impacts for any combination of other variables by approximately 13% at

the year 2045. This reduction represents the application of a fixed 100-year time horizon for

integrating radiative forcing of GHGs, applied over the 36-year lifetime of the building. For

example, CO2 emissions in 2045 treated in this manner have a TAWP of 0.71, instead of 1. For

more information on TAWPs, see Kendall (2012). Although TAWPs for different GHGs vary

differently with time, CO2 was by far the dominant GHG in this analysis. Since the TAWP is

calculated on an annual basis, any process with a total lag time of less than 1 year is accurately

represented, which should capture the bulk of energy extraction and supply processes.

For photochemical ozone, the inclusion of dynamic CFs reduced the individual scenarios

resulting from the combination of the other variables by 26% to 50%. The reduction was lowest

40

for low emissions scenarios (e.g. Scenario 16 in Figure 6; 90% electricity with AEO GHG price

and new EPA rules) and highest for high emissions scenarios (e.g. Scenario 36; 110% electricity

with AEO low shale resources and no new EPA rules). The overall reductions are explained by

the fact that higher emissions of ozone precursors - mainly NOx in this case - occurred during

winter months, when the dynamic CFs are lowest. This was due to 1) overall increased demand

for energy in the winter, due to heating needs and 2) relatively constant year-round electrical

demand, but with a higher percentage of coal-fired power generation in winter months. Since the

photochemical ozone CFs vary on a scale of months, it is possible that including lag times could

affect this calculation. However, uncertainty in the supply chain required assuming an annual

average CF for all upstream processes, while using the monthly CFs for combustion. This

formulation implicitly resulted in a variable lag time of up to 1 year between upstream processes

and combustion.

3.3.5 Limitations

Additional dynamic CFs - CF variations were not considered in most categories because

no applicable source of temporally CFs was found in the literature. The lack of characterization

methods incorporating both short-term and long-term temporal variability is a shortcoming of

current LCA practice, and could be remedied by additional LCIA method development.

Temporally variable CFs need to take into account changes in background chemical

concentrations, environmental systems and the distributions of exposed populations, as well as

time horizon relevance. The examples used in this study represent one instance of a time horizon

related CF (TAWP) and one instance of a physical system variation (photochemical ozone). In

41

the case of the latter, additional investigation into the combination of daily, seasonal and long-

term factors is needed (Reap et al. 2008).

Data availability - Dynamic variation in industrial processes and emission factors is

hampered by a lack of available data. In this case study, unit energy use for industrial processes

and emissions factors from fuel use other than in electrical power plants, were not able to be

modeled dynamically. This resulted in lower energy use and emissions associated with building

material production for the initial construction. However, in LCIA categories that were highly

influenced by energy use, these contributions were small relative to the impacts of operating

energy. With respect to emissions factors, it is noted that continued increases in data quality are

expected to provide additional accuracy in results. Efforts to track and control toxic pollutants

have historically lagged behind CAPs, and thus there is greater uncertainty in the temporal trends

in toxic-related impact categories. With respect to lag times, the inclusion of supply chain lag

times as an additional variable in LCI databases is critical for the accurate application of

temporally varying CFs. However, the uncertainty related to upstream production functions may

require annual averaging of most processes except those occurring in the building itself, which

can be known with some detail, or those which are predictable based on system characteristics,

such as energy and fuel supplies.

Spatial variability - Significant spatial uncertainty exists in LCA. The definition proposed

herein for DLCA includes consideration of spatial variability, though it has not been directly

addressed yet in this analysis. Noting that the term dynamic usually connotes temporal changes,

it should be considered that spatial patterns of industrial activity and environmental impacts

change over time; the NEI and other databases provide explicit spatial detail related to emissions,

and LCIA methods with spatially explicit CFs are available. For North America, both TRACI

42

and Impact models have some spatial resolution, though additional detail is needed in most

categories. Related to spatial variation, it has been noted that there is extensive regional variation

in the electrical generation mix. The national generation mix has been used herein, but regional

or even sub-state-level mixes have been used in some studies. However, it has been shown that

power trading between regions tends to drive the mix toward a national average (Weber et al.

2010); thus, the use of non-spatially explicit factors may be warranted in this case. More so than

for electricity, the concentration of major producers in some industries (e.g. petroleum refineries,

mining) in specific regions with CFs different from the national average may lead to a case for

regionalization of LCA results even when the exact supply chain is uncertain.

Uncertainty of future scenarios - The outlook of this chapter comprises both historical

temporal variations and predicted future variations. However, it is likely that the primary use for

LCA of buildings will continue to be predictive. Uncertainty in future scenarios depends on both

building-level variables (e.g. occupancy levels, renovations) and external variables such as

emissions controls and environmental background conditions. Since Benedum Hall was recently

renovated, projection of past building-level trends into the future was limited to assuming as-is

operations of the building and district heating plants (since the building recently underwent a full

renovation), with variation in energy usage of +/-10% to accommodate occupant behavior.

However, exact knowledge of future occupant needs or renovation schedules will not usually be

available to the LCA practitioner, even with DLCA modeling. There are also predictive

assumptions built into the models used by EIA and EPA to forecast future energy mixes and

emissions. Though uncertainty in prediction cannot be fully avoided, considering multiple future

scenarios can illuminate possible environmental tradeoffs; for example, the often-cited tradeoff

between embodied energy in construction materials and use-phase operating energy is changed

43

somewhat when a DLCA model with varying energy supply background conditions is used.

Alternatively, a conditional probability approach could be used - explicitly accounting for the

choice of externally imposed scenarios to generate a scenario-independent DLCA result which

would include the other types of uncertainty (e.g. spatial, parameter) while still eliciting expected

changes from a static LCA over time (e.g. building systems performance).

3.4 CONCLUSION

This chapter explicitly uses dynamic LCA (DLCA) and illustrates the potential

importance of the method using a simplified case study of an institutional building. The results

show that the environmental impacts of the building over its lifetime vary significantly from

what would be predicted if temporal changes were not taken into account. Particularly, the

results indicate the importance of changes in building usage, energy sources and environmental

regulations in calculating the overall environmental impacts of the building. Given that temporal

changes are rarely accounted for in LCA practice, it seems clear that LCA could be improved by

incorporating a more dynamic focus. Previous whole-building LCAs have demonstrated the

relative importance of the operations phase in most impact categories, compared to the materials,

construction and end-of-life phases. The DLCA results suggest an additional conclusion; that in

some cases, changes in building usage, or changes in external conditions such as energy mixes or

environmental regulations during a building’s lifetime, can influence the LCA results to a greater

degree than the material and construction phases. Correspondingly, adapting LCA to a more

dynamic approach as demonstrated herein seems likely to increase the usefulness of the method

in assessing the performance of buildings and other complex systems in the built environment.

44

Future research needs include characterization of uncertainty related to building systems

modeling (e.g. future occupant needs and maintenance/renovation schedules); additional

exploration of the interactions with dynamic, temporally evolving (and themselves uncertain)

LCI and LCIA background variables, and development of additional dynamic CFs and dynamic

parameters for LCI databases.

Establishing a DLCA framework for whole buildings was considered to be an essential

prerequisite for incorporating indoor environmental quality (IEQ) effects into whole-building

LCA. The factors affecting IEQ impacts, particularly occupancy and operational schedules, are

subject to significant changes on daily and seasonal bases, as well as over the long term. The

following chapters deal with the incorporation of IEQ into the DLCA model and comparison of

internal to external effects.

45

4.0 INTEGRATING INDOOR ENVIRONMENTAL QUALITY INTO THE DLCA

FRAMEWORK FOR WHOLE BUILDINGS

The following chapter contains material reproduced from an article published in the journal

Building and Environment with the citation:

Collinge, W.O., A.E. Landis, A.K. Jones, L.A. Schaefer and M.M. Bilec (2013), “Indoor

Environmental Quality in a Dynamic Life Cycle Assessment Framework for Whole Buildings:

Focus on Human Health Chemical Impacts.” Building and Environment 62 pp. 182-190.

The article appears as published per the copyright agreement with Elsevier, publisher of

Building and Environment.

Portions of the Supporting Information submitted with Building and Environment appear

in this chapter and Chapter 5, and the remaining portions appear in Appendix B.

4.1 INTRODUCTION

The aim of this chapter is to outline a framework for incorporating IEQ into whole-

building LCA. Methods for empirically quantifying IEQ impacts generally fall into two types:

single variable relationships between building-related parameters and measured occupant health

46

or performance outcomes (Fisk and Mirer 2009; Heschong et al. 2002a; Mendell and Mirer

2009; Milton 2000; Seppänen et al. 2006c; Sahakian et al. 2009; Mendell 2003) and multivariate

indices with single-value or reduced-parameter predictors of occupant outcomes (Mendell 2003;

Sekhar et al. 2003; Sofuoglu and Moschandreas 2003; Wong et al. 2007).

Recent research integrating IEQ in LCA has focused on incorporating indoor chemical

pollutant intake into the existing human health toxicity life cycle impact assessment (LCIA)

categories (Demou et al. 2009; Hellweg et al. 2009; Humbert et al. 2011; Wenger et al. 2012). In

these approaches, the impacts of indoor pollutant emissions are estimated based on emission

rates from indoor materials or processes and building-level variables, such as ventilation and

occupancy rates. A benefit of these approaches is integration within existing conventional LCIA

categories. However, when extending the approach to consider whole-building IEQ features,

additional factors need to be included. These factors can be grouped into three categories: 1)

indoor intake of outdoor pollution due to a building’s location and ventilation characteristics, 2)

indoor generation of biological/biochemical contaminants, and 3) non-IAQ related influences on

occupants’ health and productivity (e.g. eye strain and mood impacts due to poor lighting

quality). Though the latter two factors may extend the boundaries of conventional LCA practice,

there is precedent for inclusion of similar effects in the LCA literature; e.g. noise, workplace

accidents (Cucurachi et al. 2012; Pettersen and Hertwich 2008). In the case of whole buildings

and other built environment systems, the case for including these system-dependent impacts is

made stronger by the function of the system under study (e.g. housing or transporting human

beings).

The overarching goal of this research project is to develop a dynamic LCA (DLCA) tool

for building analysis that incorporates metrics of relevance to building design. In Chapter 3, a

47

working definition of DLCA was proposed as “an approach to LCA which explicitly

incorporates dynamic process modeling in the context of temporal and spatial variations in the

surrounding industrial and environmental systems”, and its application was evaluated with a

simplified case study. The research questions addressed in the next two chapters are: “How do

we incorporate IEQ into LCA, and how significantly does IEQ affect conventional LCA

results?” To answer these questions, we developed a framework for including IEQ impacts in

whole-building LCA, separating chemical-specific impacts that align with traditional LCIA

categories from non chemical-specific impacts, and identifying potential gaps or overlaps.

Chapter 4 outlines the complete framework, and Chapter 5 applies the framework to a case study

of an existing LEED Gold academic building. We then compare these internal impacts to the

external impacts resulting from the DLCA model applied to the building’s energy use.

4.2 METHODS

4.2.1 General framework for Indoor Environmental Quality + Dynamic Life Cycle

Assessment (IEQ+DLCA)

The indoor environmental quality + dynamic life cycle assessment (IEQ+DLCA)

framework developed herein is illustrated in Figure 7. Beginning at the top of the figure, the first

distinction is between internal and external building impacts, which is a crucial element of the

framework. Internal impacts are defined as those occurring within the study building, whereas

external impacts are those occurring outside of the study building.

48

Figure 7 - IEQ+DLCA framework.

External LCA impact categories are shown on the left; internal impact categories are shown on the right.

For external impacts, shown on the left side of Figure 7, the IEQ+DLCA framework

builds on the dynamic LCA (DLCA) model developed in the previous chapter (Collinge et al.

2012a). A dynamic approach, considering the time variation in building-related measurements,

can reduce the uncertainty introduced by static estimates of building usage, as well as accounting

for variation in industrial and environmental systems. Inputs to the DLCA model are typical for

LCA - quantities of energy or materials required for building operations and maintenance - but

are input as time series to maintain correspondence with dynamic unit processes and emissions

factors. The DLCA model contains a standard set of impact assessment categories based on

TRACI 2.0 (Bare 2011), with optional dynamic characterization factors (CFs) limited to those

few categories for which values are available in the literature. Dynamic CFs are not currently

Toxicology-based: same units, directly comparable Empirically-based parametric relationships

IEQ+DLCA Framework

Internal impactsExternal impacts

Traditional LCIA human health

categories

Traditional LCIA categories outside

human health

Human health -chemical

• Cancer toxicity• Internal• External

• Noncancer toxicity• Internal• External

• Respiratory effects (particulates)

• Internal• External

Based on TRACI 2/ USE-Tox

Productivity and performance

Human health -nonchemical

• Global warming

• Acidification

• Eutrophication

• Ozone depletion

• Photochemical ozone

• Ecotoxicity

Based on TRACI 2

• Sick building syndrome symptoms (SBS)

• Allergies and asthma

• Building-related illnesses

• Other illnesses (e.g. stress, mood disorders)

• Sick leave,• At-work

productivity

Based on Fisk et al 2011

Legend

Potentially overlapping categories

Currently included Currently excluded

Category currently excluded due to lack of literature data

49

available for human health categories. TRACI 2.0 employs CFs from the UseTox model for

cancer and noncancer toxicity (Rosenbaum 2008b; Rosenbaum et al. 2011), and its own CFs for

respiratory effects, all of which are static values. If dynamic CFs for these categories are

developed in the future (e.g. seasonal and spatial variation in fate and exposure factors), these

could be incorporated into the DLCA model. With respect to human health, external impacts

could include impacts inside other buildings, such as occupational exposures related to industrial

processes in the supply chain. However, most LCIA methods do not yet explicitly consider such

impacts, though research is being undertaken toward this goal (Demou et al. 2009; Hellweg et al.

2009; Humbert et al. 2011); thus, their inclusion is not examined here.

Internal impacts are limited to human health impacts, since the remaining categories in

conventional LCA accrue to species or environmental systems (e.g. global climate). As defined

herein, internal impacts - shown on the right side of Figure 7 - affect users or occupants of the

building, during the time they are inside the building. In the external categories, human health

impacts accrue to either the global or continental population as specified in the underlying Use-

Tox LCIA model (Rosenbaum 2008b). Since the internal impacts are specific to the population

of occupants of the subject building, there will be some finite but small overlap between these

populations. Herein we assume that this overlap is negligible, and its potential effects are

discussed in the next section.

Internal impacts are further separated into three types; 1) human health chemical impacts,

2) human health nonchemical impacts, and 3) performance or productivity impacts. For all three

categories, a specific set of dynamic building data is required (Figure 8), including indoor and

outdoor air temperatures (ambient and supply air); ventilation and recirculation airflows and

filtration or other treatments; humidity; lighting; and noise levels. Evaluation of chemical

50

impacts also requires indoor pollutant emissions, or indoor and outdoor pollutant concentrations.

For all types of internal impacts, the dynamic estimation of building occupancy levels is critical

to calculate temporally specific exposures. Chemical impacts are disaggregated into 3 categories;

respiratory effects, cancer toxicity, and noncancer toxicity. These categories are the same in

terms of dose-response or effect factors as their external (conventional) counterparts (Figure 8),

but with different methods used to calculate exposure, described in more detail in section 4.2.2.

Figure 8 - Flowchart showing inputs, calculation steps and outputs for internal human health-chemical impact

categories and external LCA impact categories.

LegendData flow Data or steps not included in this study Data from reference sourcesData which can be measured or calculated from other variables

Internal human health chemical

impacts

Productivity and performance

Human health -nonchemical

Dynamic impact assessment –

external impactsDynamic inventory

analysis

Unit processes

Emissions factors

Exposure factors

Intake fractions(exposure + fate)

Empirical parametric

relationships

Dynamic building occupancy data

Energy use

Dynamic pollutant dataInternal emissions

OR Indoor concentrations

Outdoor concentrations

Dynamic operating dataAirflows

Temperature HumidityLighting

AcousticsOutdoor climate

Dynamic exposure estimates

Water use

Material use

Dynamic impact assessment –

internal impacts

External human health chemical

impacts

External other impacts

Effect factors

Fate factors

51

4.2.2 Whole building exposure approach for chemical impacts

The general approach to LCIA consists of multiplying emissions collected in the LCI by

CFs, which relate emissions to health impacts through the use of fate, exposure and effect

modeling (Rosenbaum et al. 2011). This approach is incorporated in the IEQ+DLCA framework

for internal and external chemical impacts, as shown in Figure 8. The CFs can be broken down

into a fate factor (FF), an exposure factor (XF), and an effect factor (EF). The expression FF x

XF is often defined as the intake fraction (iF) - the total fraction of an emission inhaled or

ingested through multiple exposure pathways (Bennett et al. 2002). An advantage of the iF

approach is that it combines temporally and spatially explicit environmental (fate and exposure)

modeling into a single parameter, while maintaining the use of separate EFs derived from

toxicological studies.

However, emissions factors for indoor materials and processes during a building’s use

phase are often lacking in LCA (Verbeeck and Hens 2010a, b). Conditions under which

contaminants are emitted from building materials or indoor processes may be highly site-

specific, and may depend on reactions with outdoor pollution, sunlight, humidity or other factors.

Herein, the single-compartment box model developed by Hellweg et al. (Hellweg et al. 2009) is

modified to use measured concentrations as opposed to emissions factors, and expanded to

permit the use of a multi-compartment model appropriate for a standard modern office building

with separate ducted supply and return air systems. It is possible to consider such a building as a

set of well-mixed compartments where the infiltration, exfiltration and inter-compartment air

exchange rates are small in comparison to the mechanical air circulation rate (ASHRAE 2009).

Typically, interior air is circulated to a central air handler through the return ductwork, where

some fraction of the return air is exhausted to the outdoors and the remainder is combined with

52

fresh outdoor air. The mixed air is filtered or otherwise treated to remove contaminants and then

supplied to the interior space, with the supply and return air to each compartment approximately

balanced to avoid inter-compartment mixing (ASHRAE 2009). Figure 9 shows a schematic of

this type of system.

Figure 9 - Schematic of multicompartment IAQ model.

Variables are the following: Q = airflows (m3/min), C = concentrations (ppm or µg/m3), G = emissions rate (g/min),

R = removal rate (g/min), N = persons, subscript x denotes a specific contaminant, and the subscript s, r, m, ex and

oa denote supply air, return air, mixed air, exhaust air and outside air, respectively.

Beginning with the single-compartment box model, the steady-state intake fraction for

indoor emissions is written by Hellweg et al. (Hellweg et al. 2009):

53

Equation 3

NkV

IRNQIRIRN

GQGIRN

GCiF

exx

x

x

x

×==×

∂∂

=×∂∂

=)/(

where Cx is the concentration of airborne contaminant x (kg/m3) in the compartment, Gx is the

emission of contaminant x in the compartment (kg/day), N is the number of persons exposed, IR

is the average inhalation rate (m3/person*day), Q is the ventilation rate (m3/day), V is the volume

of the compartment (m3), and kex is the air exchange rate (day-1). This terminology is extended to

express the total impact hx for contaminant x in a single LCIA category by Equation 4:

Equation 4

EFNkV

IRGEFiFGhex

xxx ××

×=××=

If the variables N, IR and EF in Equation 4 are known, and can be supplemented with

measured concentrations Cx, then by the definitions in Equation 3, Equation 4 can be rewritten:

Equation 5

xxx EFNIRCh ×××=

One potential advantage of a measured-concentration approach is its ability to

incorporate indoor exposure from outdoor ambient pollution. Indoor exposure may occur

because of the intake of outdoor contamination into the building, such as combustion emissions

from nearby roadway traffic. This contamination depends upon the building’s location and is the

result of many processes both related and unrelated to the life cycle of the building. However, for

whole-building LCA we may wish to estimate the building-specific exposure due to intake of

outdoor emissions, regardless of the source. This exposure, while not attributable to individual

54

building materials, can be considered part of the LCA of the building for the purpose of

comparison to a baseline, or the evaluation of alternative building designs.

For a multi-compartment model, a modified version of Equation 5 can be written:

Equation 6

∑ ×××=ti

xtitixx EFNIRCh,

,,,

where the subscript i refers to individual compartments in the building, and the subscript t refers

to the time interval at which the concentrations and occupancy are measured. In the case of

internal building emissions vented to the outdoor environment, additional populations may be

exposed. The multi-compartment model can be extended to this case by considering an

additional compartment to represent the local environment, with an effective mixing volume

based on local meteorological characteristics. In the multi-compartment model, using indoor

emissions factors instead of measured concentration data requires additional computation, since

in the case of air recirculation, the concentration in every compartment is related to emissions in

each other compartment.

Figure 9 shows the case of a typical office building with separate ducted supply and

return air systems. We consider the building as a set of well-mixed compartments where the

inter-compartment air exchange rate is small in comparison to the mechanical air circulation rate.

Typically, interior air is brought back to a central air handler through the return ductwork, where

some fraction of it is exhausted to the outdoors and the remainder is combined with fresh outdoor

air. The mixed air is filtered to remove contaminants and then supplied to the interior space, with

the supply and return air to each compartment approximately balanced to maintain similar space

pressures, thereby avoiding inter-compartment mixing.

55

Assuming negligible pressure differences throughout, so that mass flows can be

considered proportional to measured volumetric flows, we can write a mass balance for the

whole building:

Equation 7

exrcoarcrs QQQQQQ +=+==

where Qs is the supply air flow from the air handler, Qr is the return air flow from all

compartments, Qrc is the recirculated air flow, Qoa is the outside air intake, and Qex is the exhaust

air flow to the outdoors. With balanced compartments, the supply and return flow to each

compartment i will be Qi.

The concentration of any given contaminant x in compartment i is Cx,i, and is affected by

the concentrations in the recirculated air (Cr) and the outdoor air (Coa), as well as the indoor

emissions Gx,i in compartment i, removal Rx,i in compartment i due to settling, adsorption,

chemical reaction or other means. We can perform a mass-balance for contaminant x in

compartment i as the following:

Equation 8

ixisxiixixiixix CQCQRGV

dtdC

dtdm

,,,,,,

−+−==

where mx,i is the mass of contaminant x in compartment i and Vi is the mixed volume of the

compartment. We assume each compartment is well-mixed, such that the concentration in the

exhaust air stream is equal to the concentration in the compartment Cx,i. The concentration in the

return air at the air handler will be the weighted average by flow of the concentrations in the

individual compartments:

56

Equation 9

r

iixi

rxQ

CQC

∑=

,

,

The concentration of contaminant in the supply air will be influenced by the building-

wide ratio of recirculated air to outside air, as well as filtration or other removal at the air handler

or in the ductwork:

Equation 10

xs

oaoaxrcrxsx FF

QQCQCC ,,

,+

=

where the term FFx represents the fraction of contaminant retained in the supply airstream after

filtration or other removal.

Combining Equation 8 through Equation 10, we can write the mass balance for

compartment i:

Equation 11

−+

+−=

ixxs

oaoaxrcr

iixi

iixixiix CFF

Q

QCQQ

CQ

QRGVdt

dC,

,

,

,,,

Solution in the case of known concentrations and flows- For steady-state conditions,

dC/dt = 0 and if the Q and C terms are known, Equation 12 can be solved straightforwardly to

obtain G - R. For a time-varying condition, if the concentrations Cx,i and Qi are measured at some

time interval Δt, an approximate solution for the quantity Gx,i - Rx,i representing net emissions of

contaminant x in compartment i can be written as the following:

57

Equation 12

−+

+−=− ∆−∆−

ttixxts

toatoaxrctr

itixti

titixtixittixtix CFFQ

QCQQ

CQ

QRGVCC ,,,

,,,,

,,,

,,,,,,,,, )(

In some cases, it may be practical to ignore compartmental removal rates Rx,i and

consider the emissions equal to the net emissions. This is the case in the example of measuring

occupancy levels from CO2 concentrations and airflows, discussed below.

Intake fraction solution in the case of known emission rates- While Equation 12 can be

solved separately for (G - R) for each compartment given values for the C and Q terms, it is not

possible to solve it for C given G, R and Q. For steady state conditions, expanding the

summation term in Equation 11, substituting Qr = Qs and rearranging yields:

Equation 13

0... ,,,1,1,, =−

+++− + ixix

s

ioaoaxnxn

s

rcx

s

rcixix CQFF

QQQCCQ

QQCQ

QQRG

Writing Equation 13 for each compartment i = 1,2,3…n results in a system of n linear

equations and n unknown concentrations, assuming net generation and removal rates are known

along with compartment sizes, airflows and the outdoor concentration Cx,oa. The system can be

solved simultaneously to yield concentrations. Equation 13 can be rewritten for the whole

building in matrix notation:

Equation 14

0Acrg =−−

where g, r, and c are nx1 vectors representing the emissions, removal and concentration in the n

compartments and A is an nxn matrix of the coefficients applied to the concentration terms,

58

calculated from the remaining flow and ratio terms in Equation 13. If in-compartment removal

rates area small, r can be neglected, and solving for the vector of concentrations c yields:

Equation 15

gAc 1−=

To obtain the whole-building intake fraction for emissions in any compartment we first

must calculate the change in the concentration vector as a function of the change in Gx,i:

Equation 16

ixix Gg

Gc

,, ∂∂

=∂∂ −1A

All terms in the right hand side of Equation 16 are zero (since the emission rates in the

different compartments are independent) except for the term related to Gx,i (since ∂Gx,i/ ∂Gx,i =

1); thus:

Equation 17

1A −=∂∂

iixG

c,

where Ai

-1 represents row i of the A-1 inverse matrix.

The intake fraction associated with an emission in compartment i is calculated by combining

Equations 3 and 17, where n is now a vector of the number of persons in each compartment:

Equation 18

IRIRG

ciF iix

×=×∂∂

= − nAn 1

,

Outdoor and indoor exposure and overlaps - Impacts of indoor emissions vented to the

outdoors could be represented by the addition of an outdoor compartment with mixing

characteristics established from local meteorology, along with local population data.

59

There will be some finite overlap of the population exposed to indoor pollution and the

population exposed to outdoor pollution. We can consider a building located in a default

continental or urban box as outlined by the Use-Tox model (Hellweg et al. 2009). The external

intake is thus life cycle emissions x per capita intake fraction x external(urban or continental)

population. Concurrently, the internal intake considering exposure to outdoor pollution, is indoor

concentration x per capita indoor intake x internal population (occupancy). The key to the

overlap being small is that internal population must be small compared to external population,

and the life cycle emissions within the continental or urban box volume must be small compared

to the ambient pollution levels. The internal to external population ratio is further reduced by the

ratio of the average amount of time the occupants spend indoors versus outdoors. In the case of a

geographically isolated building with high on-site emissions, the overlap would be substantial. In

the case of a medium-sized building in a large urban area, with a spatially diverse supply chain

(e.g. the electrical grid) the overlap would be small, which is the case represented in the current

chapter.

4.2.2.1 Estimating occupancy using CO2 concentrations

A measurement or estimate of occupancy is necessary to calculate intake fractions or

total intakes by Equation 3 and Equation 5. Occupancy can be calculated using measured CO2

concentrations, HVAC system airflows and known values of human respiratory CO2 output, as

long as no other significant sources or sinks of CO2 exist within the compartment (e.g.

combustion or passive ventilation). Equation 12 can be used to determine CO2 emissions in each

compartment given RCO2 = 0 (no interior removal) and FFCO2 = 1 (no filtration). Rewritten

explicitly for CO2, Equation 12 becomes:

60

Equation 19

−+

+=− ∆−∆−

ttiCOts

toatoaCOrctr

itiCOti

titiCOittiCOtiCO CQ

QCQQ

CQ

QGVCC ,,,

,,,,

,,,

,,,,,,, 2

2

2

222 )(

The rate of CO2 production (rCO2)due to human respiration under office building-type

conditions is approximately 0.026 kg CO2/hr, with a low estimate of 0.018 kg/hr and a high

estimate of 0.036 kg/hr (Emmerich and Persily 1997).

Equation 19 was solved for each 20-minute time step corresponding to the OptiNet

sampling rate. Due to the scope of the data collection, several additional assumptions were made:

• The air handler serving the 2nd and 3rd floors of the MCSI addition also feeds other areas of

the building, some of which are monitored for CO2 concentration and some of which are not.

The concentration of CO2 in the return air at the air handler (corresponding to the summation

term in Equation 19 divided by Qr) was not directly measured, but was assumed to be the

same as calculated applying the same formula to the sample of rooms where the in-room

concentrations were monitored. In other words, the average concentration in non-monitored

areas was assumed to be the same as the average concentration in monitored areas, for the

same time step.

• Outside air and recirculated airflows were not directly measured, but were estimated based

on the total supply airflow and the economizer percent open (EO%) at the air handler, which

varied from its preset minimum of 20% outside air to 100% outside air under favorable

outside temperatures. The concentration of CO2 (CCO2,s) in the supply air was calculated by:

Equation 20

%,%,, )1( EOQCEOQCC soaxsrxsx ×+−×=

After solving Equation 19 for GCO2,i,t, the number of persons in each compartment (Ni,t)

was calculated by Equation 21:

61

Equation 21

2

2 ,,,CO

tiCO

rGtNi =

4.2.2.2 VOC Speciation and inhalation toxicity

The USE-Tox model, developed for the UNEP-SETAC Life Cycle Initiative, contains

estimates of human toxicity in cancer and noncancer effects categories (Rosenbaum 2008a).

USE-Tox calculates intake fractions (iF) and effect factors (EF) for use in Eq. 2. In the indoor

model, iFs are calculated from primary data, but require the use of independent EFs to aggregate

the effects from multiple substances into these categories. The same substance-specific EFs are

used in Eq. 3 to calculate impacts in the multicompartment model with known concentrations

and occupancy. The USE-Tox model documentation provides a list of already-calculated EFs for

many common organic (including VOCs) and inorganic substances, and is available at

www.usetox.org. A list of the USE-Tox EFs for all VOCs in this study is given in Table 18.

To estimate the overall inhalation toxicity of an air volume, the individual VOC mass

concentrations were multiplied against their EF (cases/mass inhaled) to give a result in terms of

cases/volume of air inhaled, which can be considered an ambient air-specific EF:

Equation 22

∑ ×=x

xxair EFCMEF

where EFair is the ambient air-specific EF, CMx is the mass/volume concentration of contaminant

x, and EFx is the effect factor for contaminant x in either the carcinogen or non-carcinogen

category.

The 10.6 electron-volt (eV) photoionization detector used in the OptiNet system

generates a total VOC (TVOC) reading in equivalent ppm of isobutylene. For individual species,

62

conversion factors may be applied to estimate the equivalent TVOC reading generated by a

known concentration. PID conversion factors are listed in Table 18.

The equivalent TVOC measurement in ppm isobutylene for a given mixture of VOCs is

given by Equation 23:

Equation 23

∑ ×=x

xxTVOC PIDCC

where Cx is the concentration in ppm of each VOC species x and PIDx is the corresponding PID

equivalency factor. If concentrations are given in mass units, e.g. μg/m3, the conversion

becomes :

Equation 24

∑ ××=x x

xxTVOCMW

PIDCMC 024.0

where MWx is the molecular weight in g/mol. A list of the applied PID equivalency factors and

molecular weights of all VOCs in this study is given inTable 18.

We separately estimated speciation of indoor and outdoor VOCs using measurements

available from other sources:

• Pittsburgh Air Quality Study (PAQS); (Millet et al. 2005) - All outdoor VOCs.

• Allegheny County Health Department’s (ACHD) 2010 Annual Air Quality Report (data

from 2009 and 2010) - Hazardous outdoor VOCs (ACHD 2011).

• EPA BASE Study - Indoor VOCs (USEPA 2005).

The two outdoor studies were selected based on the regional location of the data

collection, while the BASE study was selected for indoor comparison due to its large number of

building sites in many locations. None of these studies includes every possible VOC species that

could be encountered in the indoor or outdoor air mixture. Instead, the combination of VOC

63

species from all three studies was used to generate a master list of probable VOCs for this study,

which is the list in Table 18. The process used to generate probable VOC concentrations from

each reference is described in Appendix B.

4.2.3 Extending the IEQ+DLCA framework beyond chemical impacts

4.2.3.1 Nonchemical health impacts

For chemical impacts, the LCIA model TRACI 2 incorporates CFs from the UNEP-

SETAC life cycle initiative, or USE-Tox, human and ecological toxicity model (Rosenbaum

2008a; Rosenbaum et al. 2011). The USE-Tox human toxicity CFs or human toxicity potentials

(HTPs) can be separated into fate factors (FFs), exposure factors (XFs) and effect factors (EFs).

The units for HTP are disease cases/kg emitted, and the units for EFs are disease cases/kg intake

(generally inhalation or ingestion). Other LCIA methods have attempted to represent varying

disease severities, but due to high uncertainty in this area, the USE-Tox authors decided not to

weight cases by severity. Thus, when assessing probable impacts, a case of one type of disease

carries equal weight to a case of another type of disease, except that cancer is given its own

category. Typical LCIA results in TRACI/USE-Tox will show one total for cancer cases and one

total for noncancer cases.

The use of cases in TRACI/USE-Tox may represent an opportunity to bring “non-

chemical” impacts into the LCIA toolbox for whole building LCA, or for LCA of any built

environment system where impacts can be considered internal or external. For instance, the

design and operation of buildings can influence transmission of pathogens, thus making cases of

contagious illness a possible metric of building performance (Sundell et al. 2011). Previous work

relating IAQ to incidence of disease or illness of different types has used “avoided cases” as a

64

metric to describe the benefit of IAQ improvements (Fisk 2002). Recent work has also expressed

benefits in terms of relative symptom prevalence (RSP) in building occupants, in which

“symptom” is analogous to “case” (Fisk et al. 2011). In the absence of severity weighting, it

seems reasonable to include several other categories of human health impacts alongside cancer-

related and noncancer-related chemical toxicity in the LCIA framework for whole buildings (e.g.

contagious illnesses, mood disorders).

Sick building syndrome - Sick building syndrome (SBS) includes “eye, nose, or throat

irritation, headache, and fatigue, that are associated with occupancy in a specific building” (Fisk

et al. 2009). Though it has been frequently studied, no clear cause of SBS has been identified,

though its occurrence has been associated with buildings with low ventilation rates (Fisk et al.

2009). Reduction of SBS symptoms is a quantified benefit of several of the IAQ improvement

strategies exploredd by Fisk et al. (Fisk et al. 2011) related to ventilation and thermal comfort.

However, SBS symptoms overlap strongly with the reported symptoms from toxicological

testing of many of the chemicals classified in the noncancer toxicity category in USE-Tox.

Although no single chemical compound or group of compounds has been deemed causal to SBS,

it is possible that many instances of SBS are related to one or more of the compounds

characterized in USE-Tox noncancer toxicity. Due to this potential overlap and the desire to

retain the USE-Tox noncancer toxicity category as an internal building metric to match the

external metric, an SBS category was not included in our framework at this time.

Allergies and asthma - Though different, allergies and asthma are sometimes grouped

together as a category of IAQ impacts (Fisk 2002) due to similarity of triggers and symptoms.

Many common triggers for these illnesses are generated or enhanced by indoor conditions; e.g.

environmental tobacco smoke, dust mites, pet dander. Studies have shown that at least in

65

residences, inadequate ventilation is associated with increased prevalence of these symptoms

(Sundell et al. 2011). However, few enough studies exist and no general relationship has been

developed between ventilation or other building variables and allergies or asthma. It is noted that

lists of asthmagens - asthma-inducing substances, including chemical and biological substances -

exist, but a substance-specific approach to this category was precluded by the potential overlap

of substances (e.g. formaldehyde, toluene, particulate matter) and symptoms to those included in

the USE-Tox database. It is expected that a full investigation of the toxicological basis of this

overlap would be required, which was beyond the scope of this study.

Building-related illnesses - This term sometimes includes SBS, allergies and asthma, but

is often more narrowly used to describe illnesses caused by infectious agents which can be

related to the building; e.g. pathogens in air conditioning systems. A subset of these illnesses is

communicable (acute) respiratory infections such as the common cold and various types of

pneumonia. The agents causing these illnesses are biological and are thus excluded from

potential overlaps with USE-Tox or other LCIA databases. It has been demonstrated in some

cases that building conditions have led to above average rates of infection (Sundell et al. 2011),

usually by building elements harboring pathogens or by insufficient ventilation (which mimics

an “overcrowded” condition). However, no empirical relationships were found in the literature to

link any specific building parameters to rates of infection of these types. (Absenteeism, which

may be a proxy for acute respiratory illnesses is discussed in a later section).

Noncommunicable, non-inhalation illnesses - There are many conditions or illnesses that

could potentially be attributed to building conditions, which are not physically communicable

and for which inhalation is not the primary trigger. Excluding ingestion of toxins or pathogens

(the former of which is covered in USE-Tox), some brief examples are: mood effects of poor

66

lighting or insufficient daylighting (Singh et al. 2011); eyestrain or headache effects from

lighting; discomfort due to temperature or work positions; or relationships mediated through an

understood physiological mechanism, such as health effects of insufficient vitamin D in office

workers (Vu et al. 2011). scant quantitative literature exists on these topics, and no meta analyses

or other literature summaries were encountered. Further research on these topics would be

beneficial to IEQ+DLCA, because potentially significant effects from plausible pathways exist

which do not correspond to any impact category in conventional LCIA.

4.2.3.2 Performance and productivity impacts

Absenteeism - Absenteeism, or sick leave, is a potential proxy for multiple IEQ effects in

workplaces, though it seems plausible that it more strongly represents acute illnesses, particularly

respiratory illnesses, e.g. colds, influenza - than long term conditions such as SBS (Fisk 2002).

Absenteeism also represents a real economic loss to the employer in a work situation, and in

cases where it represents some level of incapacitation, an economic loss to the employee as well.

It is also easily quantified in many workplaces with regular or mandatory schedules. Milton et al.

(Milton 2000) provide a quantitative reference for a relationship between ventilation and short-

term sick leave, based on a large cross-sectional study of 40 buildings with different

characteristics. Milton et al. also found a relationship between IEQ complaints and short-term

sick leave; IEQ complaints were also associated with SBS. Particularly in light of the exclusion

of SBS and allergies/asthma categories due to potential overlaps with established LCIA

categories, sick leave category in the IEQ+DLCA framework was included.

Productivity - There is extensive literature on IEQ and performance or productivity

(hereafter, productivity) impacts, e.g. (Heschong et al. 2002a, b; Seppänen et al. 2006c, a).

Though productivity impacts require different measurement units than health impacts, and may

67

accrue to different entities (an employer’s economic bottom line vs. an individual’s health), there

is potential to include productivity impacts in LCA of buildings. When comparing different

design or operational decisions, the relative impacts on productivity and the internal and external

environment can be simultaneously evaluated and tradeoffs identified. Perhaps as important,

productivity impacts may be a partial proxy for health impacts, as illnesses affecting building

occupants during work hours may impact productivity even at levels below those required for a

health diagnosis. Another way to say this is that overlaps between nonchemical health impacts

and productivity impacts may exist, such as reduced productivity due to working while sick. One

advantage of including both productivity and absenteeism as hybrid metrics representing health

and economic impacts is that they are mutually exclusive; studies establishing IEQ/productivity

relationships have typically excluded missed workdays from the analysis.

Inclusion of metrics in the framework - Given the types of impacts discussed, only two

metrics were added beyond human health chemical impacts: absenteeism and productivity. This

represents a significant exercise of judgment, and other researchers may come to different

conclusions. the potential overlap of SBS and allergy/asthma impacts with the TRACI/USE-Tox

categories of respiratory effects and noncancer toxicity was an influencing factor. By

comparison, communicable illnesses (BRI) and noncommunicable, non-inhalation illnesses

represent two additional categories which could be included given sufficient additional case

study data, though likely a choice between the BRI and absenteeism categories would have to be

made. The categories and their status within the framework pursuant to this discussion are listed

at the bottom of Figure 7.

Equations used to relate IEQ parameters with internal building impacts are incorporated

from reference sources as cited in Fisk et al. 2011 and are the following:

68

• Ventilation and performance (Seppänen et al. 2006b)

Equation 25

475.6];1000/)87.3)ln(78.038.76exp[( 01 <<−+−−= − vyvvxvRWPv

Equation 26

10;87.3)ln(78.038.76 ,,,,1

,0 =+−−= −WPrWPrWPrWPrWPr VVVVVy

• Temperature and performance (Seppänen et al. 2006a)

Equation 27

5.3115;1023.61083.5165.0469.0 3525 <<+−+−= −− TTXTxTRWPT

• Ventilation and absenteeism (Milton 2000)

Equation 28

12;2412);(029. ,, =<<−−= SLrSLrv VvVvRSLR

In the above equations, RWPv is relative work performance related to ventilation rate v in

L/sec/person, y0 is the reference point for RWPv, Vr,WP is the reference ventilation rate for work

performance of 10 l/s/person, RWPv is relative work performance related to temperature T in

degrees C, RSLRv is the relative sick leave rate related to v, and Vr,WP is the reference ventilation

rate for sick leave of 12 l/s/person (Fisk et al. 2011; Milton 2000).

4.2.4 Framework summary

A recap of the framework and summary of the data used herein is presented in Table 3.

69

Table 3 - Summary of IEQ+DLCA framework data and calculations

Impact type Trigger variable Equations

Respiratory PM2.5 Equation 5 (EF = 1) Cancer toxicity

VOC Equation 5 Equation 34, Equation 35 for EF Noncancer toxicity

Absenteeism Ventilation Equation 28

Productivity Ventilation Equation 25, Equation 26

Temperature Equation 27

4.3 CONCLUSION

This chapter outlined the framework for including IEQ impacts in the DLCA model,

addressing both chemical-specific impacts aligned with traditional LCIA categories, as well as

health and productivity effects beyond the traditional categories. Some non chemical-specific

health categories were excluded from consideration in the model at this time, based on potential

overlap with chemical-specific categories. Chapter 5 illustrates the application of the framework

to a detailed case study of the MCSI building at the University of Pittsburgh, with a focus on

comparing internal to external effects in the chemical-specific categories.

70

5.0 IN-DEPTH CASE STUDY: MASCARO CENTER FOR SUSTAINABLE

INNOVATION

The following chapter contains material reproduced from an article published in the journal

Building and Environment with the citation:

Collinge, W.O., A.E. Landis, A.K. Jones, L.A. Schaefer and M.M. Bilec (2013), “Indoor

Environmental Quality in a Dynamic Life Cycle Assessment Framework for Whole Buildings:

Focus on Human Health Chemical Impacts.” Building and Environment 62 pp. 182-190.

The article appears as published per the copyright agreement with Elsevier, publisher of

Building and Environment.

Portions of the Supporting Information submitted with Building and Environment appear

in this chapter and Chapter 5, and the remaining portions appear in Appendix B.

5.1 DATA COLLECTION

The Mascaro Center for Sustainable Innovation (MCSI) building at the University of

Pittsburgh was chosen as an illustrative case study for the IEQ+DLCA framework. MCSI is a

LEED Gold certified facility combining 1,900 m2 of new construction with 2,300 m2 of

71

renovation of the second floor of an existing building, Benedum Hall. As a part of this research,

the MCSI building was equipped with an advanced energy consumption and indoor air quality

sensing system. Energy consumption is sensed with multiple panel-based electrical meters and

HVAC system flowmeters, while IEQ data are collected using the AirCuity OptiNet system

(AirCuity). OptiNet is an indoor air quality sensing system which features a central sensor suite

and unique structured cables housing air sampling tubes and control wires. Vacuum pumps

continuously bring air from the sample locations through the tubes to the sensor suite for

analysis.

The OptiNet system was selected due to its compatibility with the existing campus-wide

building automation system and its ability to measure air quality data at a high level of temporal

resolution at multiple locations within the building. A drawback of the system is that the level of

chemical detail captured by the system’s sensors is less than that required by LCIA methods;

thus, additional data sources were required to provide LCI-ready data, as outlined in Chapter 4

and again in this chapter. Figure 10 provides an overview of the OptiNet system and the

collection of necessary supplementary data. The types of supplementary data used are either

reference studies or air quality monitoring data. These types of data are available for many urban

areas in the US via the US Environmental Protection Agency (USEPA), and thus could be used

in applying this framework to other locations.

72

Figure 10 - Data collection and flow for MCSI IAQ sampling.

The MCSI building comprises the MCSI addition (3 floors, shown in the foreground) and the renovated 2nd floor of

the Benedum Hall tower (shown at upper right). Only the addition was used in this study.

For this study, the MCSI building and the outdoor air were monitored for CO2, particulate

matter less than 2.5 µm in diameter (PM2.5), total volatile organic compounds (TVOC); HVAC

system data including airflows, temperature and humidity; and energy consumption for heating,

cooling and electricity use. The study time period was January 1, 2012, to December 31, 2012,

although some measurements were not available for all portions of that period, as described in

the following paragraphs. All measurements were taken at 20-minute or smaller intervals. Six

indoor sample points (four open offices and two conference rooms), one outdoor sample point

and one sample point for filtered outdoor air were monitored.

Centrally located sensor suite in MCSI addition

Air Data Router Air Data Router

Outdoor sample port

Indoor sample port(s)

Indoor sample port(s)

Supply air sample port

Additional data

Supply and return airflows; room

sizes

ACHD1 PM2.5 mass monitoring

data

VOC speciation estimates (PAQS2, ACHD1, BASE3)

CO2 PM2.5 (Count) TVOC (PID)

Occupancy PM2.5 for LCI

VOCs for LCI

OptiNetstructured cable

Benedum Hall Tower(2nd fl renovated for

MCSI)

MCSI addition (new construction)

73

External LCIA categories - External impacts from the building in human health

respiratory effects, cancer toxicity and noncancer toxicity LCIA categories were calculated using

the DLCA model (Collinge et al. 2012a), updated to include characterization factors for human

toxicity from TRACI/Use-Tox (Bare 2011; Rosenbaum 2008a). TRACI results for the human

health respiratory category are expressed in PM2.5 equivalents (eq), aggregating direct PM10

and PM2.5 with secondary PM from SO2, NOx and NH3 emissions. Because this TRACI

category extends only to the reference substance midpoint of PM2.5 eq, the intake fractions for

PM from Humbert et al. (Humbert et al. 2011) were subsequently applied to the TRACI results.

DLCA results in the selected categories were compared to the analogous internal categories. The

DLCA model was evaluated for the upstream impacts of the case study building’s energy

consumption during the study time period. Building materials, construction and end-of-life

impacts were excluded due to the short time frame, and since the authors’ previous study as well

as several earlier studies indicated the generally lower impacts of these processes compared to

operating energy use (Junnila et al. 2006; Scheuer et al. 2003; Aktas and Bilec 2012;

Rajagopalan et al. 2009). To evaluate the uncertainty in the spatial location of upstream

processes, the calculation was repeated assuming 100% rural, 100% urban, or 50% rural/50%

urban upstream emissions to air (emissions to water are not separated by a rural/urban distinction

in TRACI/UseTox).

Occupancy Measurement - Occupancy data is necessary to calculate impacts in all of the

internal IEQ+DLCA categories. Occupancy was estimated using ventilation rates from the MCSI

building automation system (BAS) and CO2 concentrations measured by OptiNet. CO2

concentration data were available for March 1-June 30 and September 1-December 31, 2012.

Equation 19 and Equation 20 were used to estimate CO2 emissions rates in each compartment at

74

an hourly time step, where each hourly value was determined as the average for samples taken in

the previous or following 30 minutes. A reference value of 0.026 kg CO2/hr/person was used to

convert emissions estimates into occupancy rates (Emmerich and Persily 1997) (see Equation

21). This method provides an approximate estimate of occupancy using the mass balance of CO2

in each compartment (inflow - outflow = net generation). The compartments are assumed to be

well-mixed, such that outflow can be calculated by assuming the exhaust air concentration is the

same as the concentration in the compartment. Inflow is calculated by an airflow-weighted

average of exhaust air concentrations and the outdoor air concentration, in accordance with

Figure 9.

Internal Respiratory Effects - Particulate matter (PM2.5) was measured by OptiNet’s

optical particle counter, which has a range of 0.3 to 2.5 µm. PM2.5 concentration data were

available for March 1-June 30 and Sept 1-Dec 31, 2012. Since most LCI databases report PM2.5

measurements in mass units, correlation factors for mass and particle number were obtained by

performing a linear regression of the measured outdoor data against hourly PM2.5 mass data

from the Allegheny County Health Department’s (ACHD) Lawrenceville (Pittsburgh),

Pennsylvania site, located approximately 2.4 km from MCSI, during the aforementioned period

(see B.2.2). This linear relationship was applied to the outdoor particle counts to estimate

outdoor mass concentration at the study site. The outdoor mass estimates were scaled by the

hourly indoor/outdoor particle count ratios from the OptiNet data to generate indoor mass

concentration estimates. PM2.5 mass intake was estimated using the derived occupancy rates, the

indoor mass concentration estimates, and a reference respiration rate of 0.54 m3/person/hour

(Humbert et al. 2011). The use of the measured indoor/outdoor particle count ratio may

overestimate PM2.5 mass intake, since the filters should have a higher efficiency toward the

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large end of the 0.3 to 2.5 µm range. To account for this potential bias, a lower bound estimate of

indoor PM2.5 mass was constructed by applying a 95% removal rate to the outdoor particle

count before converting to mass, consistent with the high end of the efficiency range for the

building’s ASHRAE 52.2 MERV 13 air filters. An alternate scenario of a lower-performance

building was constructed using an indoor/outdoor mass ratio of 0.56, the median value from the

EPA BASE study.

Internal Cancer and Noncancer Toxicity - VOC concentrations were measured by

OptiNet’s photo ionization detector (PID), which reports total VOCs (TVOC) as equivalent parts

per million by volume (ppm) of isobutylene. TVOC concentration data from the PID were

available for March 1-June 30, 2012. Because the concentrations of individual VOCs were not

known, a sample of possible representative VOCs of both outdoor and indoor origin was

constructed as described in Chapter 4. For species of outdoor origin, data from the Pittsburgh Air

Quality Study (PAQS) (Millet et al. 2005) and ACHD annual monitoring data (ACHD 2011)

were used. For species of indoor origin, EPA BASE Study data (USEPA 2005) were used. The

fractional composition of TVOC levels for outdoor air was assumed to be equal to the

combination of PAQS and ACHD data, whereas indoor air composition was assumed to be

represented by the distribution of BASE study buildings. For each reference study,

concentration-adjusted toxicity potentials were constructed (cases/m3 inhaled x ppm as

isobutylene - see Equation 34 and Equation 35). Published PID correction factors (Table 18)

were used to convert the VOC species concentrations to equivalent PID readings. The results

were then summed to create a PID-equivalent TVOC value (ppm as isobutylene) for each

reference study.

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Effect factors (EFs) from the TRACI/UseTox model (Bare 2011; Rosenbaum 2008a) for

each VOC species were used to calculate human health cancer and noncancer toxicity potentials

(cases/m3 inhaled) for each reference study. The toxicity potentials were divided by the PID-

equivalent TVOC values to obtain the normalized toxicity potentials. Estimated occupancy rates

and the reference respiration value were used to estimate the total volume of indoor air inhaled

during the study period. Due to the uncertainty of the building-specific speciation for VOCs of

indoor origin, a range of toxicity potentials from the BASE study was used representing the 25th,

50th and 75th percentile values from all buildings in the dataset. Finally, normalized toxicity

potentials for each relevant reference (PAQS + ACHD for outdoor; BASE 25%/50%/75% for

indoor) were multiplied by the actual TVOC readings from the OptiNet system, the estimated

occupancy rates and the reference respiration rate, to calculate the estimated health impacts.

Estimating data for missing periods - In order to provide a complete, year-round analysis,

data were estimated for periods when specific datapoints were unavailable. Estimates were

generated by season and hour of the day. For CO2-based occupancy, January and February levels

were estimated for each hour and day of the week based on the average readings at those times

and weekdays for December 1-21 and March 1-11 and 17-21 (to avoid including the Christmas

holiday and the University spring break in the averages); and July and August were estimated in

the same manner using data from June 1-30. Outdoor PM2.5 readings were estimated similarly to

CO2 except the full months of December and March were used. For indoor PM, the relationship

to the economizer described in Section 7.3.1 was applied to the estimated outdoor data. For

outdoor and indoor TVOC, the hourly and weekday averages were computed from March 1

through June 30 and applied to the remainder of the year.

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5.2 RESULTS AND DISCUSSION

Results for the illustrative case study building illustrated the feasibility of including one

component of IEQ into LCA - whole-building chemical impacts. During the study time period,

internal human health chemical impacts in the three categories varied from lower to higher than

external results in the analogous categories. Primary measured or estimated results of the internal

building monitoring are discussed first, followed by results of the comparison between internal

and external impacts. Figure 11 shows average weekday profiles of the results of measurements

and estimated occupancy from the study period.

5.2.1 Occupancy and estimated internal impact

Estimated occupancy rates ranged from zero at night to an average of just over 30 people

near mid-day on weekdays, and from zero to 5 on weekends, see Figure 11. The average

weekday occupancy rates agreed qualitatively with the building’s size and the number of

employees housed.

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Figure 11 - Average weekday values by month for March-June 2012 for PM2.5, TVOC, and estimated occupancy

based on CO2 measurements and HVAC system monitoring data.

PM2.5 and occupancy are shown on the left axis and TVOC is shown on the right axis.

PM2.5 was primarily of outdoor origin due to the similarity between interior

measurements and measurements of the filtered supply airstream, in contrast to the much greater

outdoor levels, also illustrated in Figure 11. Outdoor particle counts peaked on weekdays near

8AM, suggesting a possible correlation with nearby traffic sources. Otherwise, particle counts

were generally lower during the daytime and higher at night. The mean and median ratio of

indoor to outdoor particle count was 0.14, and it varied depending on the economizer use. This

result is consistent with the MERV 13 (ASHRAE 52.2) filters installed at MCSI, which are

designed to have a removal of >75% for particulates greater than 0.3 µm, the smallest size

79

sensed by the OptiNet system (ASHRAE 2010). The lack of a much greater (>90%) removal

may indicate the majority of particles were at the smaller end of the range of 0.3 to 2.5 µm,

which is consistent with the results of Stanier et al’s previous study for the Pittsburgh region

(Stanier et al. 2004). Though Stanier et al. did not find a correlation between particle number and

particle mass for the Pittsburgh region, the linear regression fit to mass concentrations from the

ACHD site yielded a statistically significant correlation (p < 0.05), with an R2 value of 0.39.

TVOC was of majority outdoor origin with some indoor contribution, as indicated by

indoor levels consistently similar to but slightly higher than outdoor levels (Figure 11). As with

PM2.5, outdoor VOC levels were generally higher at night than during the daytime, and had a

mean value of 0.15 ppm as isobutylene. Some background indoor sources of VOCs, such as

building materials, are suggested by the small but nearly uniform increase in indoor average

TVOC measurements compared to outdoors, approximately 0.01 ppm as isobutylene. Another

potential indoor VOC source was correlated with occupancy in the form of a mid-weekday

increase of an additional 0.01 to 0.02 ppm. Whether this source is related to indoor processes

(e.g. office or laboratory equipment) or the occupants themselves (e.g. personal care products) is

not known, as source verification was not part of the study. VOC speciation estimates from

Millet et al. (Millet et al. 2005) and ACHD annual monitoring reports for hazardous air

pollutants (HAPs) (ACHD 2011) are shown along with concentration-weighted effect factors

(EFs) from Use-Tox for cancer and noncancer toxicity in Figure 12.

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Figure 12 - Relative VOC concentrations and toxicity potentials for March-June 2012 and reference studies.

For each category 1-4 on the x-axis, results were normalized to the highest of the 3 reference studies (BASE, PAQS

and ACHD). No result is shown under 1) for this study since mass concentrations were not directly measured.

Toxicity potentials 3) and 4) were estimated for this study by combining TVOC measurements 2) with toxicity

potentials from reference studies. Toxicity potentials shown from the BASE study are median values.

Total VOC mass intake was estimated after species estimation and calculation of PID

equivalencies. The PID-equivalent outdoor TVOC concentration from the PAQS was 0.15 ppm

(Millet et al. 2005), which was identical to the average outdoor concentration measured in this

study. TVOC measurements of filtered outdoor air were nearly identical to the unfiltered air,

suggesting very little removal of these compounds by adsorption onto the filters.

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5.2.2 Comparison of internal and external impact assessment results

A comparison of the estimated building-specific internal results to the external results is

shown in Figure 13. Internal building results in the human health respiratory effects category

(representative of PM2.5 intake by the building’s occupants) were 2.6x10-5 kg inhaled,

approximately 2.3% of the external results (representing external PM2.5 intake due to the

building’s energy supply processes) of 1.1x10-3 kg inhaled. Internal building results for cancer

toxicity were 5 times greater than external results (5.7x10-4 cases vs. 1.1x10-4 cases), but

external results for noncancer toxicity were an order of magnitude higher than internal results

(1.7x10-2 cases vs. 1.2x10-4 cases).

For internal impacts alone, the source of contaminants resulting in indoor exposure varied

between categories. Internal building respiratory effects were predominantly of outdoor origin

and noncancer toxicity was estimated at 90% outdoor origin; the source of these effects was the

intake of outdoor air for ventilation. The internal respiratory impacts were noticeable alongside

external impacts in spite of outdoor air filtration and negligible internal emissions, due to the

relatively high outdoor air concentrations at the building’s urban location. For noncancer

toxicity, the chemical causing the majority of the noncancer toxicity was acrolein. Though the

higher levels of pollutants in the outdoor air are not attributable to the building’s supply chain,

the impacts of their intake on the building’s occupants are allocated to the building’s operations,

since they are highly influenced by design and operating parameters. Cancer toxicity was

estimated at 90% indoor origin; due to estimated levels of formaldehyde based on the BASE

study-derived correlation for formaldehyde to the measured total VOC reading. Indoor sources

of formaldehyde are diverse, but include building materials and furnishings, such as compressed

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wood products, insulation, carpets, adhesives and fabrics for partitions and chairs. The remaining

10% of cancer toxicity estimated of outdoor origin was 46% of the external result.

Figure 13 - Results of comparison of internal building impacts to external (conventional) LCA impacts.

All values are normalized to the highest in each category of external vs. total internal. Error bars represent the

following: Internal respiratory effects - efficiency of particle mass removal by size range, with point value shown at

85% removal,lower bound at 95% removal, and upper bound (dashed) illustrating a lower-performing building

corresponding to the median 0.56 indoor/outdoor PM2.5 mass concentration ratio from the BASE study; Internal

cancer and noncancer effects - 25th to 75th percentile toxicity of TVOC mixture from the BASE study, with point

value shown at the median; External (conventional) LCA - uncertainty in the spatial distribution of emissions, from

100% rural to 100% urban, with the point value shown at 50/50.

Uncertainty in the comparative results was modeled by including factors believed to

account for significant variation in the fate and exposure assessment steps, including the

geographic location of upstream emissions, VOC speciation estimates, and particle number to

mass ratios. For the external categories, point estimates in Figure 13 represent an assumption of

50% urban/50% rural location of air emissions, whereas the lower and upper bounds represent

100% rural and 100% urban emission locations. For internal building respiratory effects, the

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point estimate represents assuming the mass/particle number ratio of indoor PM2.5 was the same

as outdoor PM2.5 and thus that the calculated filtration rate of 86% by particle number could be

applied to the mass as well. The lower bound represents the assumption that the filters removed

95% of outdoor PM2.5 by mass. The upper bound illustrates a scenario of a lower-performance

building, represented by the median BASE study indoor/outdoor PM2.5 mass ratio of 0.56. The

lower bound, point estimate and upper bound for indoor sources of VOC in the cancer and

noncancer toxicity categories represent the 25th, 50th and 75th percentile toxicity values for

indoor sources calculated from the BASE study. For respiratory effects, the internal impacts

from the lower-performing building scenario exceeded the lower bound of the external impacts,

indicating the possibility of buildings whose internal impacts are greater than external.

5.2.3 Absenteeism and productivity impacts

Absenteeism and productivity impacts were calculated according to Equation 25 through

Equation 28. Ventilation rates did not fall below the 24 l/s/person upper limit of Equation 28

during the study period, so the relative absenteeism rate was calculated to be zero. Calculated

productivity (relative work performance) rates by location within the building are shown in

Table 4. Room temperatures were maintained within a range that kept them near the maximum

relative productivity value of 1.003, which occurs at 21.8º C (Seppänen et al. 2006a). Ventilation

rates were generally above the 47 l/s/person necessary for the maximum relative productivity

value of 1.0264, but dipped below this rate at times of peak occupancy in warmer weather, when

the economizer was at its minimum setting of 20%, suggesting that adding a demand-controlled

ventilation (DCV) feature could potentially improve productivity slightly.

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Table 4 - Relative productivity by room for the MCSI building

Room Productivity Metrics 225A 225E 225N 341B 341C 341N Total Temperature-related productivity ratio (RWP -Equation 27) Mean 1.001 0.998 1.002 1.002 1.002 1.001 1.001 Std Dev 0.001 0.002 0.001 0.001 0.001 0.002 0.002 Ventilation-related productivity ratio (RWP -Equation 25) Mean 1.017 1.024 1.025 1.023 1.021 1.026 1.023 Std Dev 0.051 0.033 0.030 0.033 0.023 0.006 0.032

5.2.4 Limitations

Limitations of the DLCA portion of the framework were discussed in Section 3.3.5.

Limitations of the IEQ portion include the occupancy estimate based on CO2 alone, the PM2.5

particle count/mass estimation, and the assumed VOC speciation from reference sources.. For

occupancy, a more robust estimate would combine CO2 with other proxy indicators of

occupancy, such as thermal load, acoustical measurements, or network and workstation use - as

well as a validation period against directly observed occupancy; see e.g. (Dong et al. 2010 (In

Press)). For internal building PM2.5 intake, the conversion from PM2.5 to particle number was

based on a site-specific, empirical relationship to outdoor levels. As previously mentioned this

may bias the results since filtration will likely reduce mass to a greater extent than particle

number. Further investigation at this and other building sites could include using mobile devices

to develop particle number to mass relationships or size distributions for both outdoor and indoor

air; e.g. (Wang et al. 2010). On the other hand, recent literature indicates that particle number

intake may be as important for respiratory effects as particle mass for some types of health

impacts (Atkinson et al. 2010). If LCA research moves toward incorporating particle number

effects, the need to convert to mass-based data could become less important.

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For VOC related impacts, the lack of site-specific speciation data could be overcome by

performing spot-checks on the TVOC composition using mobile devices or grab samples; e.g.

(Wu et al. 2011b). The priority of testing could be indicated by the prevalence of certain species

in the available estimates of outdoor and indoor air referenced in this chapter, i.e. the compounds

listed in Figure 5. Care would need to be taken to distinguish between indoor VOC sources

contributing to baseline (24-hour) levels, and sources contributing to fluctuating levels as

discussed above. The dominance of formaldehyde in the cancer toxicity category is due to its

high effect factor in Use-Tox and relative prominence in both the ACHD and BASE study data.

Additional research is needed to determine the correlation between formaldehyde levels and

TVOC readings, since formaldehyde is not detected by the PID. Seasonal variation in all types of

impacts could be explored through additional data collection.

Another limitation of this study and the overall framework is that it is a comparison

between estimated results based on actual measurement of indoor pollutants, with verifiable

exposure factors, against model results invoking highly aggregated pollutant concentrations and

exposure factors. Although many other significant sources of uncertainty exist along the LCA

calculation chain (e.g. emissions factors, dose-response functions), it is at least in theory possible

to reduce the uncertainty associated with indoor exposure in a specific building by directly

measuring it. Although herein the exposure has only been estimated, its verifiability results in a

qualitatively large discrepancy in uncertainty between internal and external impacts.

For productivity impacts, the empirical relationships used herein are quantitative, but are

based on limited data. Since the calculated changes in productivity are small even for a tightly

regulated building such as MCSI, more application-specific relationships would be warranted.

Sensor information related to zone temperatures and ventilation airflows is relatively sparse -

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ideally, a characterization of these variables would be undertaken at an individual occupant level,

such as in Choi et al. (Choi et al. 2012). However, Choi et al. did not measure productivity or

attempt to develop quantitative relationships. Also, the temperature-performance relationship

expressed in Equation 27 appears to be mainly based on cold-weather heating applications, and

conflicts somewhat with the recommendation from Choi et al. to increase warm weather (air

conditioning) set point temperatures relative to current practice. In order to better characterize

the potentially site-specific productivity impacts from the MCSI building on its occupants, a

post-occupancy survey was carried out, and is discussed in Chapter 6.

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6.0 POST-OCCUPANCY SURVEY OF THE MCSI BUILDING

6.1 INTRODUCTION

A post-occupancy survey was developed and administered to MCSI building occupants

to collect data about occupant perceptions of the building’s IEQ performance. Post-occupancy

surveys, also known as occupant satisfaction surveys, are used to provide feedback about the

occupants’ perceptions of a building’s performance, generally focusing on indoor comfort and

satisfaction aspects (Frontczak et al. 2012). These surveys are used to help evaluate the

performance of individual buildings as well as for more basic research, and are often coupled

with physical measurements of indoor conditions (Choi et al. 2012). Surveys have the advantage

of being less expensive and easier to implement than physical data collection, as well as a focus

on outcomes; however they are subjective, reflecting differences in occupant’s perception due to

factors which may not be controllable or related to the building under study.

The survey undertaken here was modeled after similar surveys conducted by the authors,

e.g. Ries et al. 2006, with modifications designed for specifics of the MCSI building. These

surveys share many characteristics with a variety of surveys which have been used by

researchers (Peretti and Schiavon 2011). The survey was approved by the University of

Pittsburgh’s Institutional Review Board and administered via email to occupants of the MCSI

building, both the Annex and the 2nd floor of the Benedum Hall tower. The main research

88

question addressed by the survey and coupled analysis is “How can qualitative data related to

occupant perceptions be synthesized with physical measurements in an LCA framework?”

6.2 METHODS

Development of the survey questionnaire was guided by available reference materials and

prior experience, e.g. (Ries et al. 2006). General data were collected such as age, gender, job title

(faculty, graduate student, staff, undergraduate student, or researcher), length of job tenure and

number of hours worked per week. General data about the work location were also collected:

part of the building (1st, 2nd or 3rd floor Annex, 2nd floor tower East or North offices, and wet

lab), space type (open floor plan, private office, or laboratory area), and proximity to windows.

Detailed questions regarding IEQ satisfaction were grouped under four headings: thermal

comfort, air quality, lighting/daylighting, and acoustics. After answering the IEQ questions,

occupants were asked to evaluate 1) their perception of IEQ impacts on their productivity and 2)

their estimation of how potential IEQ-related changes to the building (scenarios) would affect

their productivity. IEQ and productivity questions used a 7-point, Likert-type scale, with

responses arranged from “strongly disagree” or “strong negative effect”, through neutral or “no

effect”, to “strongly agree” or “strong positive effect.” The scenario-related questions used the

same 7-point scale, except an additional option of “I don’t know” was provided in order to allow

survey respondents to use the “neutral” rating to indicate anticipation that the change would not

have an effect on their productivity. The structure of the survey is summarized in Table 5 and the

complete text of the survey and all responses, except for age, gender and length of job tenure, are

given in Appendix C.

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Table 5 - Summary of post-occupancy survey question types

Section topic Question format

Number of questions

General questions (age, gender, title, job tenure, work area descriptions)

Multiple choice 11

IEQ satisfaction - thermal comfort 7 point Likert-

type (1-7)

10 IEQ satisfaction - air quality 4 IEQ satisfaction - lighting 6 IEQ satisfaction - acoustics 5 IEQ and productivity 6

IEQ and productivity - scenarios

7 point Likert-type (1-7) with “Don’t know”

option

7

6.3 SURVEY RESULTS

The survey was sent to 74 occupants, with 48 completed surveys returned, a 65%

response rate. The breakdown of responses by general category is given in Table 6. There is

significant overlap between job titles, location in the building, space types and where applicable,

window direction, due to the assignment of space by duties. Generally, faculty and staff offices

are private offices on either the 1st floor of the Annex or the 2nd floor of the tower; the remaining

spaces are primarily occupied by graduate students, with some undergraduate students and

research assistants, as well as several visiting scholars who are identified as faculty.

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Table 6 - Breakdown of survey results by general category

Question Number of responses Categories and number of responses in category

What is your age? 48 Under 21 21 to 30 31 to 40 41 to 50 51 to 60 61 to 65 1 28 9 7 2 1

What is your gender? 48 Male Female 35 13

How long have you been working in the MCSI building?1

49 Less than 1 year

1 to 2 years

2 to 3 years

More than 3 years or since the building was opened

7 11 8 23 What is your job title? 48

Staff Graduate student Faculty

Postdoctoral researcher

Undergraduate student Other2

4 31 10 2 1 1 How many hours a week do you spend at MCSI?

49 <10 10-20 20-30 30-40 >40

0 6 6 17 20 In which area of the building is your primary work area located?

49

First floor MCSI wing1

2nd floor MCSI wing1

3rd floor MCSI wing1

2nd floor Benedum Hall - Wet Lab

2nd floor Benedum Hall - East offices1

2nd floor Benedum Hall - North offices1

3 15 16 8 3 4 Which option best describes your work area?

48 Laboratory benches

Open office with partitions

Private office

Other (please specify)3

8 29 9 2 Do you have outside views from your work area while either standing or seated?3

49 Yes No

41 8 Which direction does the window face?

44 North (O’Hara Street)

East (Thackeray Street)

South (Fifth Avenue)

West (Bouquet Street)

33 7 3 1 Is there a corridor or hallway between your seat and the nearest window?

49 Yes No

12 37 In my work area, I can personally adjust or control the following. (Check all that apply):

Daylight level i.e., with window blinds or shades 33

Electric light level, i.e., with a switch or dimmer 29 Air supply temperature i.e., with a thermostat 8 Air supply volume and/or direction i.e., with an

adjustable vent 3 None of the above 10 Other 0

1. Research assistant (1 response) 2. Open laboratory (1 response); Reception area (1 response)

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IEQ Results - Results for the IEQ questions are summarized in Tables 5-8, and

distributions of results for key questions are presented in Figure 14. Occupants were generally

neutral relating to thermal comfort, somewhat more satisfied with air quality and lighting, and

neutral to moderately satisfied with acoustics. Some categories had noticeable variation across

the different areas of the building; temperature and thermal comfort were rated higher by

occupants of the Annex (mean 4.4) than the tower offices or wet lab (3.1 and 3.6 respectively).

Air quality was rated positively by Annex and wet lab occupants (5.6, 5.3) and slightly

negatively by tower office occupants (3.9). Lighting quality was rated higher by Annex and

tower office occupants (5.4, 5.6) than wet lab occupants (3.9), Acoustical quality decreased from

Annex to tower offices and again to the wet lab (4.6, 4.0, 2.9).

Figure 14- Distribution of results for occupant satisfaction in IEQ categories.

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Table 7 - Post-occupancy survey results: IEQ - thermal comfort

Question Number

of responses

Mean (Median)

Mean responses by area

Annex: All floors (1st 2nd, 3rd floors)

Tower offices

Wet lab

During warmer weather, I am satisfied with the temperature in my work area. 48 3.7 (4.0) 4.1 (4.0, 3.9, 4.2) 2.6 3.0

During cooler weather, I am satisfied with the temperature in my work area. 48 4.0 (4.0) 4.1 (3.5, 3.7, 4.6) 3.4 4.1

I am generally satisfied with the temperature in my work area. 47 3.9 (4.0) 4.1 (4.0, 3.8, 4.5) 3.6 3.4

During warmer weather, I believe the air is too humid in my work area. 48 3.0 (3.0) 2.8 (3.0, 2.5, 2.9) 3.6 3.8

During cooler weather, I believe the air is too dry in my work area. 48 3.7 (4.0) 3.6 (5.0, 3.3, 3.6) 4.0 3.9

I am generally satisfied with the humidity in my work area. 47 4.9 (5.0) 5.1 (4.0, 5.6, 4.8) 4.7 4.5

During warmer weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

48 4.6 (5.0) 4.7 (4.5, 4.7, 4.8) 4.9 3.9

During cooler weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

47 4.7 (5.0) 4.8 (4.5, 4.9, 4.8) 4.8 4.1

I am generally satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

47 4.7 (5.0) 4.8 (4.5, 4.9, 4.8) 4.7 4.1

Recalling the previous questions related to temperature, humidity, and air flow speed, I am generally satisfied with the thermal comfort in my work area.

48 4.1 (4.0) 4.4 (4.0, 4.0, 4.8) 3.1 3.6

Table 8 - Post-occupancy survey results: IEQ - air quality

Question Number

of responses

Mean (Median)

Mean responses by area

Annex: All floors (1st 2nd, 3rd floors)

Tower offices

Wet lab

I believe the air in my work area is not stuffy or stale. 48 5.3 (6.0) 5.5 (5.5, 5.3, 5.7) 4.7 5.1

I believe the air in my work area is clean. 48 5.3 (6.0) 5.6 (5.0, 5.6, 5.8) 4.3 4.9 I believe the air in my work area is generally free from odors. 48 5.2 (6.0) 5.5 (5.0, 5.4, 5.8) 3.7 5.3

Recalling the previous questions related to stuffiness/staleness, cleanliness and odor, I am generally satisfied with the air quality in my work area.

48 5.3 (6.0) 5.6 (5.5, 5.5, 5.8) 3.9 5.3

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Table 9 - Post-occupancy survey results: IEQ - lighting

Question Number

of responses

Mean (Median)

Mean responses by area

Annex: All floors (1st 2nd, 3rd floors)

Tower offices

Wet lab

My work area is too bright. 48 2.7 (2.0) 2.6 (2.0, 2.9, 2.5) 2.4 3.4 My work area is too dark. 48 2.8 (2.0) 2.6 (2.0, 2.5, 2.7) 2.0 4.4 There is an adequate amount of daylight in my area (leave blank if none). 44 5.3 (6.0) 5.4 (6.5, 5.1, 5.4) 5.4 4.8

There is an adequate amount of electric light in my area. 48 5.7 (6.0) 5.9 (6.0, 5.8, 5.9) 5.9 5.1

There is a problem with glare, reflections or contrast in my work area. 48 3.1 (3.0) 3.3 (3.0, 2.5, 4.0) 2.6 2.9

Recalling the previous questions related to lighting and daylighting, I am generally satisfied with the lighting quality in my work area.

48 5.2 (5.5) 5.4 (5.5, 5.3, 5.5) 5.6 3.9

Table 10 - Post-occupancy survey results: IEQ - acoustics

Question Number

of responses

Mean (Median)

Mean responses by area

Annex: All floors (1st 2nd, 3rd floors)

Tower offices

Wet lab

My work area is too loud due to other people’s conversations. 48 4.0 (4.0) 3.9 (5.5, 3.8, 3.6) 4.3 4.3

My work area is too loud due to background noise other than conversations (e.g. mechanical equipment, outdoor noises).

48 4.2 (5.0) 4.1 (4.5, 4.0, 4.1) 3.3 5.6

My work area is too quiet. 48 2.5 (2.0) 2.5 (2.0, 2.4, 2.8) 2.7 2.0 There is a problem with acoustics in my work area other than generally too loud or too quiet.

48 2.9 (2.0) 2.4 (2.0, 2.7, 2.3) 3.7 4.0

If you agree, please explain:1 6 Recalling the previous questions related to acoustics, I am generally satisfied with the acoustical quality in my work area.

48 4.2 (5.0) 4.6 (4.0, 4.6, 4.6) 4.0 2.9

Productivity results - Results for the productivity questions are summarized in Table 11

and a distribution of responses is shown in Figure 15. Overall, occupants rated IEQ as having a

near-neutral effect on their productivity, thermal comfort and acoustics as having a slight

negative effect, air quality as having a slight positive effect, and lighting and outdoor views as

having a stronger positive effect. Annex occupants’ mean rankings in every category were higher

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than tower office or wet lab occupants’ rankings. For thermal comfort, Annex occupants gave

neutral ratings, while both tower office and wet lab occupants gave somewhat negative ratings.

Air quality was rated to have a positive effect by Annex occupants, neutral by wet lab occupants

and a negative effect by tower office occupants. Lighting and outdoor views were rated to have

positive effects by Annex and tower office occupants, and having a negative effect by wet lab

occupants. Acoustics was rated near neutral by Annex and tower office occupants and having a

negative effect by wet lab occupants.

Figure 15- Distribution of results for occupants’ perceived productivity impacts from IEQ.

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Table 11 - Post-occupancy survey results: productivity

Question Number

of responses

Mean (Median)

Mean responses by area

Annex: All floors (1st 2nd, 3rd floors)

Tower offices

Wet lab

How does the thermal comfort (remember, this includes temperature, humidity and airspeed) in your work area affect your productivity?

48 3.8 (4.0) 4.0 (4.0 4.1 3.9) 3.1 3.4

How does the air quality (remember, this includes stuffiness/staleness, cleanliness and odors) in your work area affect your productivity?

48 4.5 (4.0) 4.9 (4.0, 5.0, 4.9) 3.0 4.1

How does the lighting quality (remember, this includes both daylighting and artifical - both overhead, and task-based) in your work area affect your productivity?

48 4.9 (5.0) 5.4 (5.0, 5.5, 5.3) 4.6 3.3

How does the outdoor view, or lack of an outdoor view, in your work area affect your productivity?

48 4.8 (5.0) 5.2 (5.0, 5.1, 5.3) 4.6 3.6

How does the acoustical quality or noise level in your work area affect your productivity?

48 3.9 (4.0) 4.2 (3.5, 4.5, 4.0) 3.9 2.8

Recalling the previous questions related to indoor environmental quality (including thermal comfort, air quality, lighting and acoustics), how does the overall indoor environmental quality in your work area affect your productivity?

48 4.3 (4.0) 4.8 (4.0, 5.1, 4.7) 3.4 3.3

Scenario results - Results indicated somewhat positive impacts from raising summer

temperatures, moderate to strong negative effects from lowering winter temperatures or

decreasing daylighting (nearly uniform across building areas), somewhat negative effects from

decreasing ventilation (also uniform), moderate to strong positive effects from including

operable windows and increasing daylighting, and perceived neutral to slightly positive effects

from reducing overhead lighting when sufficient daylight was present (daylighting controls).

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Figure 16- Distribution of results for occupants’ anticipated productivity impacts from scenarios.

Table 12 - Post-occupancy survey results: scenarios

Question Number

of responses

Mean (Median)

Mean responses by area

Annex: All floors (1st 2nd, 3rd floors)

Tower offices

Wet lab

How do you think increasing the temperature in your work area by several degrees in warmer weather would affect your productivity?

48 4.6 (4.0) 4.6 (3.5, 4.9, 4.7) 5.1 4.0

How do you think decreasing the temperature in your work area by several degrees in cooler weather would affect your productivity?

48 2.9 (2.5) 3.1 (4.5, 3.1, 2.9) 2.9 2.0

How do you think decreasing the ventilation in your work area would affect your productivity?

48 3.5 (3.0) 3.4 (3.0, 3.3, 3.6) 3.6 3.4

How do you think including operable windows in your work area would affect your productivity?

47 4.8 (4.0) 4.8 (5.5, 4.6, 4.8) 5.4 4.2

How do you think decreasing the amount of daylighting in your work area would affect your productivity?

47 2.5 (2.0) 2.5 (2.5 2.6 2.4) 2.1 2.9

How do you think increasing the amount of daylighting in your work area would affect your productivity?

48 5.3 (5.0) 5.5 (5.0 6.0 5.1) 4.7 5.0

How do you think automatically turning off overhead lighting in your work area when there is sufficient daylight would affect your productivity?

48 4.1 (4.0) 4.4 (4.5 4.7 4.1) 3.4 3.8

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Raising summer temperatures was rated positively in the Annex and tower offices and

neutral in the wet lab. The anticipated negative effects from lowering winter temperatures or

decreasing daylighting were nearly uniform across building areas, as were the somewhat

negative effects from decreasing ventilation. Increasing daylighting was rated highest in the

Annex, while including operable windows was rated highest in the tower offices. Daylighting

controls were rated positively in the Annex, negatively in the tower offices, and near neutral in

the wet lab.

Results by identifying characteristic - Several of the results were stratified by identifying

characteristics, where evidence from previous studies or the researchers’ judgment suggested a

possible relationship. Choi et al. suggest that “gender matters - increase summer set points”

(Choi et al. 2012). In the MCSI building, the mean satisfaction with temperature in warmer

weather was 2.8 for female occupants (n=12) and 3.9 (n=35) for male occupants, which was

significant at a 90% confidence level (p = 0.07 using a two-tailed t-test assuming unequal

variances). Mean satisfaction in cooler weather was 3.9 for both genders, and 3.5 female/4.1

male overall, though the overall value was not statistically significant. This result corroborates

the findings of Choi et al. Frontczak et al. find that “Office workers will be most satisfied with

their workspace and building when located close to a window in a private office” (Frontczak et

al. 2012). Statistically significant differences were found between open office occupants (n=29)

and private occupants (n=9) for thermal comfort impacts on productivity (p=0.04), air quality

effects on productivity (p=0.001) and overall IEQ impacts on productivity (p=0.05), with the

open office occupants reporting more positive effects for all three questions. No statistically

significant differences were found between open office and private office occupants’ responses

to questions about IEQ perception not related to productivity. These results suggest that in this

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case, there may be factors other than office type and location that influence occupants’

perception of IEQ impacts on their productivity. Possible factors include job status (e.g. most

open office occupants are graduate students, and most private office occupants are facults), or an

inverted building-specific relationship of office type and percieved IEQ (poorer in the tower

offices). The wet lab area was not included in this comparison.

Overall, the survey results indicated general satisfaction with lighting and daylighting

aspects, and some dissatisfaction with acoustics and thermal comfort aspects, with near neutral

results for air quality. Open-ended responses for possible building improvements included

reducing echoes and mechanical noise, providing better control over temperature including too-

cold temperatures in the summer, mitigating cooking odors from a basement-level restaurant, and

increasing automatic lighting shut-off delay.

Results of the survey were used to qualitatively inform the scenario analysis described in

Chapter 7; i.e. to provide additional support for scenarios which were identified as positive or

neutral – e.g. raising summer temperature set points, using daylighting controls, and demand-

controlled ventilation, but disallowing scenarios that were identified as negative – e.g. lowering

winter temperature set points or reducing ventilation. Operable windows were not able to be

analyzed using the empirical energy model developed herein, whereas general increases or

decreases in daylighting were not considered in the scenario analysis because they would require

extensive modifications to the building.

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7.0 SCENARIO ANALYSIS: ENERGY-SAVING STRATEGIES

7.1 INTRODUCTION

A scenario analysis was conducted using the IEQ+DLCA model, along with empirically-

derived energy and IEQ relationships for the MCSI building, to explore the tradeoffs or

synergies resulting from changes in building operating parameters. Saving energy - thus reducing

external impacts - while reducing or maintaining constant internal impacts was the main criterion

for the scenarios. Four scenarios were investigated: 1) demand-controlled ventilation (DCV),

which ties outdoor air intake to occupancy levels; 2) raising the cooling season (warm weather)

indoor temperature set point; 3) adding daylighting controls to dim overhead lighting when

adequate daylight was present, and 4) a combined scenario using all three options.

For all scenarios, energy savings were estimated with an empirically-derived energy

model, and IEQ impacts were calculated using parametric relationships developed herein. These

energy savings were input into the DLCA model to calculate the external impacts. Internal

chemical impacts were calculated using the derived building-specific parametric relationships,

and internal non-chemical impacts were limited to ensuring no decrease in relative productivity.

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7.2 METHODS

The data collection and analysis described in Section 5.1 were used to establish building-

specific parametric relationships. Herein, the development of these relationships is restricted to

the new construction portion, or “annex”. The parametric relationships were used to model the

energy and IEQ consequences of possible building operation scenarios designed to save energy.

Empirical energy model – An empirical energy model was constructed for the MCSI

annex, using the available measurement data. A schematic of the model is shown in Figure 17,

and a summary-level relationship for the model is expressed in Equation 34:

Equation 29

FANHHWSAVENTINTE qqqqqq ,++++=

where qE is the estimated heat gain through the building envelope, qINT is the summary of all

internal heat gains (electrical appliances, lighting, and occupants), qVENT is the heat gain from

conditioning the ventilation (outdoor) air to the internal conditions, qSA is the additional heat gain

from conditioning the supply air (outdoor + recycled), qHW is the hot water space heating gain

(supply air reheat terminals and radiators), and qH,FAN is the heat gain from the supply fan at the

air handler (all q terms are in units of power, typically kW). qSA represents the sum of cooling

coil (chilled water) and heating coil (steam) loads, which are mutually exclusive.

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Figure 17 - Schematic of parametric energy model for the MCSI Annex

The air handler serving the MCSI annex is a return air system with economizer (Figure

9), which also serves other portions of the Benedum Hall complex. Airflows were measured both

at the air handler and at the variable-air-volume (VAV) units serving the different compartments

of the MCSI space. Loads measured at the air handler (cooling water use, steam use and fan

electrical consumption) were allocated to the MCSI annex by multiplying them by the ratio of

the total airflow at the MCSI VAV units to the total airflow at the air handler. The ventilation

rate was calculated by multiplying the airflow by the economizer percent open, which was

measured by a sensor. During warm weather, the economizer was operated at 20% open.

The variable heat gain associated with ventilation air was calculated using the enthalpy

difference of the outdoor air and indoor air, multiplied by the ventilation mass flow rate. Even at

zero ventilation, further cooling is required in moderate and warm weather to offset heat gain at

the building envelope and indoor thermal loads, such as appliances and occupants, as well as

heat gain introduced by the supply fan. This cooling was calculated using the enthalpy difference

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of the indoor air and supply air, multiplied by the supply air mass flow rate, and is independent

of the ventilation rate:

Equation 30

OARAOAVENT mhhq *)( −=

where h is the enthalpy of moist air, calculated in accordance with the ASHRAE handbook

(ASHRAE 2009). Assuming conduction through the building envelope as the primary pathway

for the additional cooling, the calculated load was expressed as a function of the temperature

difference between the outdoor and indoor air, and linear regression was used to estimate the

coefficients.

Ventilation and indoor particulate intake - Indoor particle concentrations were observed

to be almost always lower than outdoor concentrations, and to be highly correlated with outdoor

concentrations. Since the building’s MERV 13 air filters are capable of reducing the majority of

PM2.5, it was hypothesized that the ratio of indoor particle levels to outdoor particle counts was

dependent on the status of the economizer. Least-squares regression was performed to establish a

relationship between economizer percent open and indoor/outdoor particle count ratio. This

relationship was used in the subsequent scenario analysis to estimate changes in occupant intake

of particulate matter due to changes in ventilation.

Indoor TVOC emissions - Indoor TVOC emissions were calculated by the same method

used to calculate CO2 emissions and occupancy (Equation 19). Using the measured outdoor and

indoor TVOC concentrations and the airflow rates, a quasi-steady state mass balance model was

used to estimate the TVOC emissions in each compartment as the mass accumulation after

inflow and outflow. TVOC emissions estimated in this way were compared against occupancy

and ventilation rates to determine if any relationship could be found.

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Scenarios - Four scenarios were investigated: 1) demand-controlled ventilation (DCV),

which ties outdoor air intake to occupancy levels; 2) raising the summer temperature set point by

1.1º C (2º F); 3) adding daylighting controls to dim overhead lighting when adequate daylight

was present, and 4) a combined scenario using all three options. Scenarios and controlling

criteria are outlined in Table 13.

Table 13 - Energy-saving scenarios and controlling criteria

Scenario Controlling parameters Parameter values

1 - DCV Ventilation rate 0.3 l/s/m2 floor area; 45 l/s/person

2 - Summer temperature Indoor temperature set point

Recorded range (Mean 21.5, Std dev 0.88) + 1.1 deg C

3 - Daylighting control Lighting power load

Hourly maximum of: • Actual recorded value • Mean daily minimum +

0.75*mean daily range 4 - Combined All of the above All of the above

For the DCV scenario, inspection of the building operating data, described in detail in the

results section, showed that the building was usually operated at ventilation rates higher than the

upper limits in Equation 25 and Equation 28. The DCV scenario attempted to maintain the

ventilation at 45 l/s/person to achieve maximum productivity according to Eq. 1, given the

occupancy calculated from the CO2 data. An area-specific minimum ventilation rate of 0.3

l/s/(m2 floor area) was added in accordance with ASHRAE Standard 62.1-2010 (ASHRAE

2010).

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7.3 RESULTS AND DISCUSSION

7.3.1 Building-specific parametric relationships

Energy – Building-specific parametric relationships were developed for the relationship

of envelope heat transfer (QE) and indoor/outdoor temperature difference (Figure 18), and AHU

fan power and mass flow rate (Figure 19).

Figure 18 - MCSI Annex envelope heat transfer as a function of inside-outside temperature difference.

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Figure 19 - MCSI Annex supply and return fan power as a function of supply air mass flow.

Least-squares regression was used to fit a linear relationship for heat gain and

temperature difference (Equation 31), and a parabolic relationship for supply fan power and mass

flow (Equation 32):

Equation 31

5)(55.12)(*42.3

−>−+−=

io

ioE

TTTTQ

Equation 32

50070.11*1059.1 5

>+×= −

SA

SASF

mmQ

Both relationships were determined to be statistically significant at the 95% level using

the F-test. Although a statistically significant relationship for return fan power was also

established, extrapolating it below the empirically established range resulted in physically

impossible negative values, and therefore it was not used in the scenario analysis.

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IAQ - The building-specific parametric relationships for ventilation and indoor/outdoor

particle count ratios are shown in Figure 20 and have the form:

Equation 33

bSAOAOutIn mmaPMPM )/(*5.2/5.2 =

where the quantity mOA/mSA is equivalent to the economizer percent open, and the

coefficients a and b varied somewhat between individual compartments in the model, with b

approximately equal to 0.5 in most cases. All of these relationships were determined to be

statistically significant at the 95% level using the F-test. No statistically significant relationships

were found for indoor VOC emissions when evaluated agains either occupancy or ventilation

rate.

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Figure 20 - Room-level empirical relationships for indoor/outdoor particle count ratio and economizer setting.

7.3.2 Energy savings and life cycle impacts

Figure 21 shows a time-series comparison of the cooling savings from the baseline for

each of the four scenarios. Scenario 1 saved 50% of the building’s ventilation-related cooling

demand, by reducing the ventilation rate generally during hot summer nights, when the building

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was virtually unoccupied. Even at the relatively high rate of 45 l/s/person used to maintain

productivity in accordance with Equation 25, the summertime maximum (daytime) ventilation

for the rarely exceeded the baseline scenario ventilation. The reduction in ventilation rate

allowed a reduction in the overall supply air demand, reducing supply fan power, with a

corresponding reduction in heating of the supply air stream at the fan (see the recursive loop in

Figure 17). The combined effects of these reductions resulted in a total savings of 11% of total

cooling energy and 6% of total electricity use (from cooling and fans).

Figure 21 - Scenario results for ventilation-related cooling energy consumption from March through October 2012.

Although measured temperatures in occupied spaces rarely varied from a narrow range

around the optimum performance temperature in Equation 27, feedback from the occupant

survey indicated an acceptable increase in space temperature in warmer weather. Scenario 2,

modeling a 1.1º C (2º F) increase in indoor temperature when temperatures outside were higher

than inside, resulted in a 24% reduction in cooling energy and a 9% reduction in total electricity

use. The cooling energy reduction was slightly offset by an increase in supply fan energy to take

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advantage of the additional range of free cooling. Scenario 3, allowing electric light levels to dim

when daylight was available during cooling season led to an 8% decrease in lighting energy use

and a corresponding 2% decrease in cooling energy use, for a total reduction of 4% of total

electric use. When the three strategies were combined - Scenario 4 - the savings were 8%, 29%,

19% and 14% for lighting, chilled water, supply fan and total electricity respectively.

Monthly time series of IEQ+DLCA model results are shown in Figure 22 for selected

impact categories. External impacts of all types were reduced by decreasing the energy

consumption and generally followed the monthly distribution shown for global warming, for a

total reduction of approximately 14%, with some categories affected slightly more than others by

the timing of the reductions with respect to the dynamic electrical grid mix. The slightly greater

reduction in the photochemical ozone category of 15%, and the different monthly distribution

was due to the use of dynamic CFs from Shah et al. 2008, which are higher in the summer

months, corresponding to the timing of the larger reductions.

Internal respiratory impacts were increased from baseline for all but Scenario 1, because

the lower cooling demand meant that less air recirculation was necessary to meet the cooling

needs at a constant supply air enthalpy. Less air recirculation, while reducing the overall air flow

rate, increased the economizer open percent and increased the average indoor particle count in

accordance with Equation 33 and Figure 20. Increases were 5.5%, 1.8% and 4.5% for Scenarios

2, 3 and 4, respectively. Conversely, estimated internal cancer and noncancer impacts due to

internal VOC sources were reduced by the increased economizer settings in all but Scenario 1.

Changes in these two categories were 22%, -6.3%, -2.1%, and 18% in Scenarios 1, 2, 3 and 4

respectively. From a seasonal standpoint, indoor respiratory impacts were greatest during cool to

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moderate weather, when outdoor air supply was the greatest, and indoor VOC effects were

greatest during hot weather when outdoor air supply was the lowest.

Figure 23 shows the full summary of results from the IEQ+DLCA model for the study

period, including all external and internal chemical categories. Productivity categories -

absenteeism and at-work performance - are not included in Figure 23 because the baseline

conditions for the MCSI building were near the upper limits for the ventilation-based

relationships, and near the optimum value for the temperature-based relationships included in the

model. A condition of “no change relative to baseline” can be assumed for all scenarios in the

productivity categories. For this case study and time period (~1 year), dynamic variation LCI and

LCIA data did not strongly affect the differences between scenarios. Internal cancer impacts

from indoor sources were sufficiently greater than external cancer impacts, that variations

between scenarios were of the same magnitude as the total external impacts.

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Figure 22 - Monthly baseline and scenario results for the MCSI annex in selected impact categories from the

IEQ+DLCA model.

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Figure 23 - Full LCIA results for the MCSI annex scenario analysis from the IEQ+DLCA model.

Results are normalized to the internal + external total from the baseline scenario.

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8.0 CONCLUSIONS

8.1 SUMMARY

The goal of this study was to improve LCA methods for whole buildings by developing a

dynamic model and integrating building-level indoor environmental impacts, including both

human health and productivity. The first portion of this study developed the basic dynamic LCA

(DLCA) framework and illustrated the potential importance of the method using a simplified

retrospective and prospective case study of an institutional building (Benedum Hall). The results

showed that the environmental impacts of the building over its lifetime varied from what would

be predicted if temporal changes were not taken into account. Particularly, the results indicated

the importance of changes in building usage, energy sources and environmental regulations in

calculating the overall environmental impacts of the building. Given that temporal changes are

rarely accounted for in LCA practice, it seems clear that LCA could be improved by moving to a

more dynamic framework. Previous whole-building LCAs have demonstrated the relative

importance of the operations phase in most impact categories, compared to the materials,

construction and end-of-life phases. The DLCA results suggested an additional conclusion; that

in some cases, changes in building usage, or changes in external conditions such as energy mixes

or environmental regulations during a building’s lifetime, can influence the LCA results to a

greater degree than the material and construction phases. Correspondingly, adapting LCA to a

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more dynamic approach as demonstrated herein seems likely to increase the usefulness of the

method in assessing the performance of buildings and other complex systems in the built

environment.

The second portion of this work outlined a framework for including whole-building IEQ

effects in LCA. The framework added three types of impacts to the LCA matrix: internal

chemical impacts, internal non-chemical health impacts, and performance/productivity impacts.

Indoor chemical impacts included impacts from indoor emissions as well as the intake of outdoor

pollution. Indoor chemical impacts were categorized so as to be directly comparable to existing

LCIA categories, which are conventionally used for external impacts only. These categories are

respiratory effects, cancer toxicity and noncancer toxicity. Indoor nonchemical impacts were

disaggregated into health and productivity impacts. After analysis of the potential overlap

between chemical-specific health effects and the remaining health effects, it was concluded that

some categories of nonchemical health impacts (e.g. SBS) could not be included in the

framework without potential double-counting. Furthermore, the remaining nonchemical health

impacts (e.g. BRI and impacts not related to air quality) have not been studied sufficiently to

permit the development of empirical parametric relationships for inclusion in the framework.

However, productivity impacts related to absenteeism and at-work performance were able to be

included, and could potentially capture some of the missing health impacts.

The complete IEQ+DLCA framework was evaluated using a case study of a LEED Gold

academic building - the MCSI building at the University of Pittsburgh, a combination annex to

and renovation of a portion of Benedum Hall, the subject of the first case study. Extensive data

were collected on energy consumption and IEQ variables, and a post-occupancy survey was

performed to evaluate occupant perceptions of IEQ and its effects on productivity. Results of the

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case study suggest that in some instances, internal effects can be comparable to internal effects.

For internal building respiratory effects, the performance of the mechanical filtration system can

influence the results by several orders of magnitude. For example, although the internal

respiratory effects in this study were lower than the external respiratory effects, they would have

been greater without the building’s MERV 13 filters; for instance, many commercial buildings

may only employ a MERV 8 filter, which has minimal removal of PM2.5. An illustrative

scenario of a lower-performing building showed that internal effects could be greater than

external effects in some cases. This could be due to some combination of poor filtration and/or

indoor sources of particulate matter. For cancer toxicity, the estimated internal effects were

greater than external effects. In other words, the estimated exposure of building occupants, even

in a building achieving LEED certification, could be greater than the total exposure of external

populations due to the upstream processes of the building’s operating energy supply.

Indoor source control via low-VOC building materials, furnishings and maintenance

items is believed to be very important for VOC exposure; this was corroborated by the relatively

low indoor contribution to TVOC levels for the case study building compared to the BASE

study. This was expected since as a LEED Gold building the case study was designed with

indoor source control as a key element. Ventilation complements indoor source control by

removing internally generated pollutants from both occupants and building materials; however,

increased ventilation without much greater attention to filtration or other treatment of outdoor

and recirculated air carries the risk of increased impacts in some categories (e.g., respiratory

effects and non-carcinogenic toxicity) offsetting gains in other categories (e.g. carcinogens).

These relationships are site-specific, so tradeoffs will vary on a case-by-case basis. Incorporating

both chemical and non-chemical health and productivity impacts into the IEQ+DLCA

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framework demonstrated the need to carefully consider IEQ consequences when making

decisions related to energy savings. Limits on operational changes were revealed, underscoring

the potential importance of design features.

The post-occupancy survey supplemented the physical analysis of the building and the

existing literature on occupants’ perceptions of IEQ and its relationship to their productivity.

Previously documented relationships between IEQ and productivity indicate a positive

correlation with ventilation and an optimal temperature range. However, the survey results

suggested some degree of flexibility with respect to indoor temperature set points during the

cooling season, which corresponded with the results of another previous qualitative study.

Daylighting was confirmed to be a critical variable for IEQ satisfaction. As with the chemical

impacts, the non-chemical health and productivity impacts may be site and population-specific,

varying with the setting and occupant type, even when building design features are similar.

8.2 FUTURE WORK

Future research needs include aspects of both the dynamic features and IEQ categories in

LCA, as well as refinements to the underlying human health functions. For DLCA, additional

needs are characterization of uncertainty related to building systems modeling (e.g. future

occupant needs and maintenance/renovation schedules); additional exploration of the interactions

with dynamic, temporally evolving (and themselves uncertain) LCI and LCIA background

variables; and development of additional dynamic CFs and dynamic parameters for LCI

databases. The variability in these tradeoffs may support greater attention to the development of

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more sophisticated building modeling and the application of regional criteria in green building

rating systems.

With respect to IEQ, overlaps between chemical-specific, toxicologically-based effect

factors from LCIA methods, and empirically derived relationships from the IAQ literature,

indicate a need for interdisciplinary efforts targeted at merging the two knowledge bases. There

is a need for serious consideration of threshold doses in LCIA models so that insignificant

increases in impact can be excluded as negligible.

Future work on the current project includes the exploration of an additional high-

performance building case study - the Center for Sustainable Landscapes at Phipps Conservatory

in Pittsburgh, as well as the continued development of the IEQ+DLCA model toward a building-

level dashboard system, with improvements from both a sensing and computational standpoint.

A long-term goal is to develop a reference set of estimates using data from studies such as this

and the BASE study to provide design-level estimates of the tradeoffs between internal and

external impacts.

8.3 OUTLOOK

Overall, LCA could be improved as a design tool for whole buildings by including a

thorough analysis of the IEQ effects of design decisions, as well as internal and external system

changes over a building’s lifetime. Understanding the uncertainties with respect to both LCIA

internal building results and external (conventional) LCA results, we conclude that for LCA of

whole buildings, including dynamic modeling and building-level IEQ categories is important.

The findings of this study, while underscoring the importance of internal impacts, may support

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the use of green building rating systems, which include the benefits of enhanced IEQ from better

filtration, indoor chemical source control and attention to non-chemical environmental variables

such as lighting and acoustics. As these impacts accrue to different populations (building

occupants versus the world at large), the overall vision is to reduce environmental impacts

related to the built environment.

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APPENDIX A

INPUTS AND RESULTS FOR INITIAL DLCA CASE STUDY

A.1 BUILDING MATERIAL AND ENERGY DATA

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Table 14 - Actual and estimated energy data for Benedum Hall.

Month and Year

Boiler Plant Data Benedum Hall Consumption eQUEST Simulated Data(4)

Steam Generation (Gg)

Coal for steam (Gg)

Gas for steam (106 m3)

Steam energy content (MJ/kg)(1)

Steam (Mg)(3)

Electricity (MWh)(3)

Steam (GJ)(3)

Steam (Mg)

Electricity (MWh)

Steam (GJ)

Jul‐92 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐(2) 260 1090 690 400 1060 1060 Aug‐92 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 250 820 670 401 1090 1060 Sep‐92 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 210 1050 580 591 1130 1650 Oct‐92 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 410 860 1090 589 930 1570 Nov‐92 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 710 880 1850 867 800 2260 Dec‐92 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 980 790 2550 1324 780 3430 Jan‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1010 750 2640 1673 720 4370 Feb‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1030 840 2700 1536 740 4050 Mar‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 810 870 2100 885 920 2300 Apr‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 520 870 1420 546 910 1490 May‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 320 810 860 413 870 1130 Jun‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 250 1010 740 394 1050 1150 Jul‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 180 1170 480 398 1060 1060 Aug‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 210 1070 560 401 1090 1060 Sep‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 220 1080 620 591 1130 1650 Oct‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 380 880 1010 589 930 1570 Nov‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 710 840 1850 867 800 2260 Dec‐93 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1220 800 3160 1324 780 3430 Jan‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1340 830 3490 1673 720 4370 Feb‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1000 860 2630 1536 740 4050 Mar‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 750 1050 1940 885 920 2300 Apr‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 430 930 1160 546 910 1490 May‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 380 890 1030 413 870 1130 Jun‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 290 1190 840 394 1050 1150 Jul‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 290 940 780 398 1060 1060 Aug‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 330 1040 860 401 1090 1060 Sep‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 250 900 710 591 1130 1650 Oct‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 320 790 860 589 930 1570 Nov‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 500 900 1310 867 800 2260 Dec‐94 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 720 630 1860 1324 780 3430 Jan‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1010 820 2640 1673 720 4370 Feb‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1010 710 2670 1536 740 4050 Mar‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 850 970 2200 885 920 2300 Apr‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 610 790 1650 546 910 1490 May‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 280 750 780 413 870 1130 Jun‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 230 1100 680 394 1050 1150 Jul‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 230 890 600 398 1060 1060 Aug‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 180 1170 480 401 1090 1060 Sep‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 170 920 480 591 1130 1650 Oct‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 360 870 970 589 930 1570 Nov‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 900 880 2350 867 800 2260 Dec‐95 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1150 720 2990 1324 780 3430 Jan‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1210 650 3150 1673 720 4370 Feb‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1010 810 2670 1536 740 4050 Mar‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 970 720 2520 885 920 2300 Apr‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 580 720 1580 546 910 1490 May‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 320 800 880 413 870 1130 Jun‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 230 850 670 394 1050 1150 Jul‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 230 1080 620 398 1060 1060 Aug‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 250 820 670 401 1090 1060

121

Table 14 (Continued)

Sep‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 330 840 910 591 1130 1650 Oct‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 420 930 1130 589 930 1570 Nov‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 950 700 2470 867 800 2260 Dec‐96 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 990 720 2560 1324 780 3430 Jan‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1020 870 2660 1673 720 4370 Feb‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 860 710 2260 1536 740 4050 Mar‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 790 810 2050 885 920 2300 Apr‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 610 870 1660 546 910 1490 May‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 320 760 880 413 870 1130 Jun‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 310 790 890 394 1050 1150 Jul‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 340 1020 900 398 1060 1060 Aug‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 300 810 790 401 1090 1060 Sep‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 320 970 890 591 1130 1650 Oct‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 510 840 1370 589 930 1570 Nov‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 870 770 2260 867 800 2260 Dec‐97 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1000 830 2580 1324 780 3430 Jan‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 970 740 2520 1673 720 4370 Feb‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 880 770 2330 1536 740 4050 Mar‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 820 890 2140 885 920 2300 Apr‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 400 840 1080 546 910 1490 May‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 200 790 550 413 870 1130 Jun‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 180 850 520 394 1050 1150 Jul‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 200 1080 530 398 1060 1060 Aug‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 290 970 760 401 1090 1060 Sep‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 290 1030 800 591 1130 1650 Oct‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 480 930 1290 589 930 1570 Nov‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 960 920 2490 867 800 2260 Dec‐98 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 960 910 2490 1324 780 3430 Jan‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1280 760 3350 1673 720 4370 Feb‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1060 940 2800 1536 740 4050 Mar‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1290 920 3360 885 920 2300 Apr‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 680 850 1860 546 910 1490 May‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 540 890 1460 413 870 1130 Jun‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 410 1120 1200 394 1050 1150 Jul‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 460 980 1230 398 1060 1060 Aug‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 460 1070 1220 401 1090 1060 Sep‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 610 1130 1700 591 1130 1650 Oct‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 910 1010 2430 589 930 1570 Nov‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 980 940 2540 867 800 2260 Dec‐99 ‐‐‐ ‐‐‐ ‐‐‐ ‐‐‐ 1310 1040 3400 1324 780 3430 Jan‐00 98.61 4.95 3.49 2.61 1420 1020 3690 1676 720 4370 Feb‐00 79.11 4.33 2.86 2.75 1610 1010 4420 1475 740 4050 Mar‐00 65.13 4.53 1.71 2.73 1280 1130 3510 841 920 2300 Apr‐00 50.85 3.25 1.61 2.80 1220 950 3420 531 910 1490 May‐00 31.77 2.21 1.06 3.01 760 860 2290 375 870 1130 Jun‐00 24.28 1.65 0.91 3.13 420 1170 1310 367 1050 1150 Jul‐00 27.34 1.26 1.15 2.76 460 940 1260 382 1060 1060 Aug‐00 26.64 1.14 1.15 2.72 440 1060 1200 389 1090 1060 Sep‐00 28.95 1.56 1.18 2.91 510 1040 1480 566 1130 1650 Oct‐00 46.17 3.21 1.31 2.82 730 980 2060 558 930 1570 Nov‐00 73.27 4.45 2.23 2.67 1450 910 3890 844 800 2260 Dec‐00 107.17 6.04 3.75 2.75 1510 860 4160 1249 780 3430 Jan‐01 99.28 6.33 2.73 2.64 1660 950 4370 1655 720 4370 Feb‐01 80.34 5.18 2.08 2.60 1390 890 3610 1558 740 4050

122

Table 14 (Continued)

Mar‐01 85.55 4.90 2.15 2.39 1440 880 3440 963 920 2300 Apr‐01 51.18 3.40 1.29 2.62 840 1120 2190 568 910 1490 May‐01 35.89 2.66 0.71 2.60 720 890 1880 434 870 1130 Jun‐01 27.76 1.73 0.76 2.61 410 1150 1060 441 1050 1150 Jul‐01 25.88 1.87 0.52 2.57 400 940 1030 410 1060 1060 Aug‐01 24.45 1.46 0.72 2.61 450 1140 1170 405 1090 1060 Sep‐01 28.88 1.40 1.06 2.61 540 1040 1400 630 1130 1650 Oct‐01 47.63 3.11 1.20 2.59 900 930 2330 606 930 1570 Nov‐01 56.74 3.71 1.38 2.56 1010 900 2590 883 800 2260 Dec‐01 78.12 5.60 1.56 2.55 1140 800 2910 1344 780 3430 Jan‐02 86.31 6.18 1.82 2.59 1350 1070 3500 1689 720 4370 Feb‐02 79.40 5.03 2.05 2.57 1220 630 3120 1579 740 4050 Mar‐02 76.95 5.30 1.92 2.67 1160 850 3100 862 920 2300 Apr‐02 54.70 4.06 1.30 2.76 1300 1090 3570 540 910 1490 May‐02 45.66 3.15 1.04 2.59 1140 350 2950 435 870 1130 Jun‐02 29.59 2.28 0.86 3.03 540 1030 1630 380 1050 1150 Jul‐02 25.54 1.17 0.99 2.62 90 940 230 402 1060 1060 Aug‐02 26.65 1.29 0.95 2.57 190 1100 480 410 1090 1060 Sep‐02 25.48 1.59 0.85 2.83 190 1060 540 581 1130 1650 Oct‐02 53.47 3.36 1.44 2.60 930 920 2420 606 930 1570 Nov‐02 74.67 5.30 1.58 2.58 1280 850 3300 875 800 2260 Dec‐02 97.35 5.79 2.52 2.47 1870 810 4630 1387 780 3430 Jan‐03 115.57 6.08 3.37 2.43 2300 820 5590 1800 720 4370 Feb‐03 99.65 5.38 3.05 2.52 2140 810 5380 1609 740 4050 Mar‐03 77.02 5.03 1.98 2.61 1820 660 4760 881 920 2300 Apr‐03 53.68 3.80 1.31 2.70 1470 560 3970 551 910 1490 May‐03 41.78 3.23 0.91 2.76 940 990 2600 410 870 1130 Jun‐03 33.26 2.50 0.91 2.92 560 1320 1650 394 1050 1150 Jul‐03 28.59 2.06 0.93 3.05 530 850 1620 346 1060 1060 Aug‐03 30.07 1.88 0.97 2.79 570 1000 1580 378 1090 1060 Sep‐03 34.31 2.11 1.00 2.65 690 950 1830 621 1130 1650 Oct‐03 55.79 3.52 1.34 2.49 1190 900 2980 630 930 1570 Nov‐03 65.11 4.48 1.54 2.62 1250 850 3270 861 800 2260 Dec‐03 96.29 5.96 2.60 2.58 2030 780 5220 1331 780 3430 Jan‐04 118.24 6.12 4.09 2.61 2160 820 5660 1671 720 4370 Feb‐04 95.15 5.84 2.54 2.55 1940 800 4940 1590 740 4050 Mar‐04 78.54 5.48 2.02 2.72 1560 560 4250 845 920 2300 Apr‐04 59.64 4.51 1.22 2.66 1190 560 3170 558 910 1490 May‐04 38.68 2.71 0.78 2.51 640 560 1610 449 870 1130 Jun‐04 31.46 2.20 0.75 2.65 330 560 880 433 1050 1150 Jul‐04 27.97 1.79 0.84 2.75 130 670 350 383 1060 1060 Aug‐04 29.71 1.52 1.00 2.56 160 1000 400 413 1090 1060 Sep‐04 30.66 1.60 0.98 2.53 300 950 750 651 1130 1650 Oct‐04 46.02 3.16 1.16 2.67 970 900 2590 588 930 1570 Nov‐04 65.31 4.33 1.61 2.59 1480 850 3840 870 800 2260 Dec‐04 94.89 5.80 2.78 2.64 1930 780 5100 1298 780 3430 Jan‐05 106.15 5.61 3.79 2.68 2110 720 5660 1628 720 4370 Feb‐05 89.25 5.00 3.28 2.80 1830 810 5120 1446 740 4050 Mar‐05 94.94 4.74 3.46 2.64 1790 560 4730 871 920 2300 Apr‐05 55.96 2.85 2.14 2.73 960 560 2620 544 910 1490 May‐05 46.00 2.31 1.65 2.62 920 560 2420 431 870 1130 Jun‐05 32.32 1.64 1.12 2.59 490 560 1260 444 1050 1150 Jul‐05 33.29 2.15 0.75 2.47 360 560 900 427 1060 1060 Aug‐05 33.16 2.18 0.71 2.46 350 1000 860 428 1090 1060

123

Table 14 (Continued)

Sep‐05 35.52 2.45 0.80 2.57 380 920 980 640 1130 1650 Oct‐05 52.88 2.80 1.80 2.62 1010 900 2650 599 930 1570 Nov‐05 73.06 4.16 2.35 2.65 1260 900 3350 852 800 2260 Dec‐05 108.15 5.03 4.33 2.69 2150 890 5800 1274 780 3430 Jan‐06 90.78 4.23 3.50 2.64 1720 860 4550 1655 720 4370 Feb‐06 95.60 4.16 3.85 2.63 1700 830 4470 1541 740 4050 Mar‐06 88.14 4.35 3.28 2.65 1490 920 3960 867 920 2300 Apr‐06 57.02 3.31 1.87 2.70 890 920 2400 551 910 1490 May‐06 46.73 2.69 1.45 2.62 710 900 1850 431 870 1130 Jun‐06 36.58 2.11 1.17 2.67 380 810 1000 431 1050 1150 Jul‐06 35.51 2.40 1.06 2.83 360 800 1020 373 1060 1060 Aug‐06 34.77 2.14 1.06 2.69 330 880 900 392 1090 1060 Sep‐06 38.82 2.50 1.12 2.71 370 880 1010 607 1130 1650 Oct‐06 59.15 3.92 1.76 2.79 910 910 2530 564 930 1570 Nov‐06 71.48 3.21 2.61 2.52 1170 950 2940 896 800 2260 Dec‐06 86.54 4.68 2.95 2.65 850 840 2250 1293 780 3430 Jan‐07 84.52 4.78 2.80 2.68 960 880 2580 1631 720 4370 Feb‐07 110.86 4.53 4.68 2.64 1090 950 2880 1537 740 4050 Mar‐07 84.37 4.65 2.93 2.70 800 930 2160 851 920 2300 Apr‐07 70.26 4.46 2.00 2.67 720 910 1920 557 910 1490 May‐07 45.59 3.04 1.15 2.63 360 970 930 430 870 1130 Jun‐07 37.27 2.68 0.97 2.78 280 810 770 414 1050 1150 Jul‐07 35.00 2.46 0.91 2.74 230 800 620 384 1060 1060 Aug‐07 33.79 2.28 0.94 2.74 190 880 520 384 1090 1060 Sep‐07 35.44 1.74 1.33 2.66 210 870 570 618 1130 1650 Oct‐07 47.27 2.34 1.68 2.59 400 1020 1030 606 930 1570 Nov‐07 79.30 4.35 2.72 2.68 810 920 2180 843 800 2260 Dec‐07 105.27 5.69 3.67 2.68 1080 860 2900 1278 780 3430 Jan‐08 100.10 5.28 3.52 2.66 1100 950 2920 1642 720 4370 Feb‐08 98.39 4.96 3.59 2.65 990 960 2630 1528 740 4050 Mar‐08 103.33 5.36 3.66 2.65 960 880 2530 868 920 2300 Apr‐08 66.85 3.98 1.99 2.62 570 990 1500 567 910 1490 May‐08 55.46 3.36 1.71 2.69 310 850 830 420 870 1130 Jun‐08 40.88 2.62 1.22 2.74 140 840 370 420 1050 1150 Jul‐08 40.51 2.54 1.43 2.91 110 940 330 362 1060 1060 Aug‐08 40.79 2.14 1.30 2.53 120 830 300 418 1090 1060 Sep‐08 41.56 2.42 1.20 2.55 50 890 120 644 1130 1650 Oct‐08 65.33 3.49 2.26 2.66 350 980 920 592 930 1570 Nov‐08 93.61 4.81 3.45 2.69 600 820 1620 839 800 2260 Dec‐08 117.56 5.81 4.46 2.69 840 800 2260 1277 780 3430 Jan‐09 105.32 5.47 3.63 2.61 1880 950 4900 2519 750 6580 Feb‐09 88.84 4.63 3.00 2.59 1260 1740 3270 2583 780 6690 Mar‐09 97.21 4.82 3.37 2.57 1260 560 3250 1562 960 4010 Apr‐09 74.93 4.18 2.28 2.56 760 910 1940 1123 940 2870 May‐09 53.89 3.32 1.48 2.59 610 770 1570 624 900 1610 Jun‐09 38.79 1.91 1.50 2.70 390 850 1070 527 1130 1420 Jul‐09 44.35 0 3.30 2.86 370 990 1060 468 1130 1340 Aug‐09 40.33 0 2.99 2.85 290 910 830 445 1170 1270 Sep‐09 45.07 0 3.19 2.71 290 700 780 801 1200 2170 Oct‐09 69.24 0 5.18 2.87 550 1360 1580 977 970 2810 Nov‐09 70.60 0 5.14 2.79 840 930 2340 1488 830 4160 Dec‐09 68.76 0 5.05 2.82 1430 1050 4030 1988 810 5600 Jan‐10 77.89 0 5.75 2.83 1810 920 5140 2323 750 6580 Feb‐10 73.55 0 5.42 2.83 4470 920 12620 2367 780 6690

124

Table 14 (Continued)

Mar‐10 52.58 0 3.79 2.77 1860 920 5150 1449 960 4010 Apr‐10 36.03 0 2.57 2.74 1410 1090 3860 1048 940 2870 May‐10 25.21 0 1.83 2.79 1270 920 3530 579 900 1610 Jun‐10 24.79 0 1.79 2.76 1040 1060 2870 515 1130 1420 Jul‐10 24.51 0 1.75 2.74 1050 1030 2880 489 1130 1340 Aug‐10 22.08 0 1.52 2.65 1100 980 2900 478 1170 1270 Sep‐10 25.37 0 1.95 2.95 1150 1050 3390 737 1200 2170 Oct‐10 43.49 0 3.21 2.83 1460 960 4140 992 970 2810 Nov‐10 59.39 0 4.42 2.85 2170 1010 6210 1456 830 4160 Dec‐10 80.70 0 5.99 2.85 2900 1030 8260 1968 810 5600 Jan‐11 78.21 0 5.76 2.83 3020 970 8540 2330 750 6580 Feb‐11 61.29 0 4.48 2.81 2460 1000 6910 2384 780 6690

Table 14 Notes:

1) Steam energy content was calculated using values of 24.8 MJ/kg for coal and 38.4 MJ/m3 for gas. This represents primary energy content and includes all energy losses during steam generation, distribution and use. 2) For the years 1971 through 1999, steam energy content was assumed to be the average of years 2000‐2002 on a

month‐by‐month basis. 3) For the years 1971 through June 1992, electrical and steam usage were assumed to be the average of years 1993‐

1995 on a month‐by‐month basis. 4) The eQUEST model was constructed for the original building and compared with actual data from years 1993‐

2001 (prior to removal of electric chillers from the building's roof). Once this model was completed, the renovation changes were added and results of the renovated building model were used from March 2011 onward.

Figure 24 - Comparison of actual electrical usage and eQUEST model results for Benedum Hall.

Actual usage from 2002-2011 does not include cooling since the building was connected to the central campus

chilled water plant in 2002.

125

Figure 25 - Comparison of steam usage and eQUEST model results for Benedum Hall

126

A.2 LIFE CYCLE INVENTORY

Table 15 - Mass and embodied energy inputs for static LCA model of Benedum Hall materials compared to two

other studies

Case Study: Benedum Hall Scheuer 2003 Junnila 2006

Building lifetime

75 Years Building lifetime 75 Years Building lifetime

50 Years

Floor area 37,000 m2 Floor area 7,300 m2 Floor area 4,400 m2

Mass/area (kg/m2)

Energy/area (MJ/m2)

Materials Mass/area (kg/m2)

Energy/area (MJ/m2)

Materials Energy/area (MJ/m2)

Structural steel (piling and rebar)

77 1,870 Steel, electric arc furnace

65 790 Rebar and steel stairs

1,080

Structural concrete

1180 820 Cement (in concrete) Sand (concrete and backfill) Gravel (concrete)

180 1100 320

670 660 64

Concrete 700

Concrete masonry unit walls

250 190 NA2 NA NA NA NA

Steel studs, doors, and frames3

22 600 Steel, primary, cold rolled Steel, secondary, hot rolled

12 10

322 139

Steel studs, doors, frames and grid

890

Steel piping and ductwork (galvanized and stainless)

18 600 Steel, primary, electrogalvanized

10

319

Steel, piping and ductwork

1,400

Cast iron piping3

6.7 160 Cast iron 6.7 220 Incl. in steel piping

NA

Copper tubing and wire3

4.5 140 Copper, primary, extruded Copper tube

2.9 1.6

206 108

Copper tubing and wire

250

Aluminum (window frames, cladding panels)

0.49 56 Aluminum, primary

2.1 425 Aluminum 18

Exterior masonry (limestone)

86 2.4 Exterior masonry (brick)

53 143 NA NA

Resilient floor tile

3.2 190 NA NA NA Ceramic tile 250

Glass (windows)

5.5 71 Glass 6.4 44 Glass 780

Gypsum board

5.4 31 Kraft paper Gypsum, primary Gypsum, secondary

8.4 10 10

315 8 0

Gypsum board Mineral fiber board ceiling tile

340 210

127

Table 15 (Continued)

Extruded polystyrene insulation

0.19 20 Polyisocyanurate Polystyrene

1.2 0.8

86 78

Extruded polystyrene insulation

20

Fiberglass insulation

0.45 21 Glass fiber, primary

2.9 51 Fiberglass insulation

710

HVAC multizone units

10 270 NA NA NA HVAC multizone units

420

GFRC panels 0.04 0.14 NA NA NA NA NA Polyethylene (cladding panels)

0.2 16 NA NA NA NA NA

Total materials

1670 5,080 Total materials 2,000 6,250 Total materials

11,900

Original construction materials

1570 4,250 Original construction materials

7,060

Renovation materials

100 820 Renovation materials

4,860

Total shown here4 1,780 4,640 Total shown here4

7,100

% Total shown here

90% 74% % Total shown here

59%

Total operating energy

3,920 Total operating energy

4,100 Total operating energy

1,360

Electricity 3,340 700 Heating 580 660

Table 15 Notes:

1.This table attempts to provide comparable items in rows going across, where possible. There is overlap between

some categories across the studies, but not within studies.

2. NA = Not applicable - generally, not present in the subject building.

3. Values from Scheuer et al. for mass/area were used herein for these material categories.

4. Major items excluded from “Total shown here” are the following: For Scheuer et al. - carpet, roofing materials,

fireproofing and paint; For Junnila et al. - carpet, roofing materials, ceiling tile, elevator and paint. Fireproofing is

NA for Benedum Hall; carpeting and ceiling tile are minimal, and roofing and paint were excluded due to lack of

data.

128

Figure 26 - Time series of derived emissions factors for fossil fuel electric power generation and Bellefield

Boiler Plant (BBP) steam heat.

TRACI categories are shown except for ozone depletion.

Figure 26 Notes:

1) Electric power generation quantities by fuel type from EIA and emissions totals from EPA.

129

2) Years outside EPA HAP emission estimates (pre-1998, and post-2005 for some HAPS were calculated by

assuming constant relationships between organic gases/ total VOCs, and non-mercury metallic haps/PM2.5.

3) BBP emissions data from Allegheny County Health Department for the years 2000-2010.

4) US LCI totals (for combustion only, not including upstream processes) are shown for qualitative comparison.

USLCI totals are arbitrarily shown at the year 2000.

A.3 LIFE CYCLE IMPACT ASSESSMENT

Table 16 - Results of life cycle impact assessment (LCIA) for Benedum Hall original construction and renovation

materials.

TRACI Category

Global Warming

Acidification Carcinogens Non carcinogens

Respiratory effects

Eutrophication Ozone depletion

Ecotoxicity Smog

Units kg CO2 eq H+ moles eq kg benzene eq kg toluene eq kg PM2.5 eq kg N eq kg CFC-11 eq

kg 2,4-D eq kg NOx eq

Original construction – Unit processes by LCA data source (1) ecoinvent - air 8.1E+06 6.9E+05 1.0E+04 3.3E+07 1.1E+04 4.6E+02 0.0E+00 1.8E+06 1.0E+04

ecoinvent - water 0.0E+00 0.0E+00 1.8E+02 4.7E+06 0.0E+00 2.7E+01 0.0E+00 1.8E+04 0.0E+00

uslci - air 6.4E+06 1.8E+06 3.3E+03 3.9E+06 3.7E+03 7.8E+02 8.4E-03 1.2E+05 1.8E+04 uslci - water 0.0E+00 0.0E+00 1.6E+03 3.9E+07 0.0E+00 1.6E+02 0.0E+00 1.0E+06 0.0E+00

Renovation – Unit processes by LCA data source (1) ecoinvent - air 7.1E+05 1.2E+05 1.1E+04 1.6E+07 2.8E+03 6.6E+01 0.0E+00 7.1E+05 1.5E+03

ecoinvent - water 0.0E+00 0.0E+00 7.5E+01 2.2E+06 0.0E+00 9.2E+00 0.0E+00 3.2E+03 0.0E+00

uslci - air 9.6E+05 2.9E+05 4.6E+02 4.9E+05 6.5E+02 1.1E+02 5.4E-04 1.8E+04 2.6E+03 uslci - water 0.0E+00 0.0E+00 2.8E+02 6.5E+06 0.0E+00 2.8E+01 0.0E+00 1.7E+05 0.0E+00

Table 16 Notes:

LCA data source categories are as follows: ecoinvent – air and ecoinvent – water represent emissions from material

production to air and water respectively, excluding emissions from fuel used in material production; uslci – air and

uslci – water represent emissions from fuel consumption used in material production, such as direct fuel combustion

or electricity use. This method was used for two reasons: a) take advantage of ecoinvent’s larger database of

material processes and b) maintain the use of US-specific data for emissions from fuel combustion.

130

Figure 27 - Normalized TRACI results from Benedum Hall original construction materials showing percentage

contributions from unit processes.

Figure 28 - Normalized TRACI results from Benedum Hall renovation materials showing percentage contributions

from unit processes.

131

Figure 29 - (1 of 4) Time series of DLCA results for the sensitivity analysis, shown as cumulative percent

deviations from the baseline scenario for the remaining categories not shown in Figure 6.

132

Figure 29 - (2 of 4) Time series of DLCA results for the sensitivity analysis, shown as cumulative percent

deviations from the baseline scenario for the remaining categories not shown in Figure 6.

133

Figure 29 - (3 of 4) Time series of DLCA results for the sensitivity analysis, shown as cumulative percent

deviations from the baseline scenario for the remaining categories not shown in Figure 6.

134

Figure 29 - (4 of 4) Time series of DLCA results for the sensitivity analysis, shown as cumulative percent

deviations from the baseline scenario for the remaining categories not shown in Figure 6.

135

APPENDIX B

DATA COLLECTION FOR THE IN-DEPTH MCSI CASE STUDY

B.1 MCSI BUILDING DATA

B.1.1 Data collection and organization

A floor plan of the MCSI annex is shown in Figure 30 on the following page. Raw data and

model calculations from the study period are organized in a series of text (.csv) files and Excel

spreadsheets, as indicated in Table 17.

136

Figure 30 - Floor plan of the MCSI annex showing data collection points.

137

Table 17- Data organization and file structure

138

B.2 EXTERNAL REFERENCE DATA FOR IEQ MODEL

B.2.1 Allegheny County Health Department (ACHD) PM2.5

Figure 31 shows the correlation obtained from a linear least-squares fit of the ACHD hourly

particle mass monitoring data versus the hourly average outdoor particle count from this study.

The best-fit line shown in Figure 31 was applied to the hourly outdoor particle counts to generate

hourly PM2.5 outdoor mass estimates. The mass estimates were further multiplied by the ratio at

each hourly interval of the indoor particle count in each compartment to the outdoor particle

count, to generate indoor mass concentration estimates for each compartment. The indoor mass

concentration estimates were multiplied by the occupancy estimates and respiration rate in order

to estimate intake in each compartment at each interval.

Figure 31 - Linear regression of outdoor particle number from this study and particle mass from ACHD during the

study time period

139

B.2.2 VOC SPECIATION

Table 18 gives the master list of VOCs used in this study. It represents a compilation of all

VOCs listed in the ACHD, PAQS and BASE reference studies, along with parameters necessary

for conversion of TVOC readings to LCIA results: molecular weights, PID correction factors,

and USE-Tox effect factors, and calculated values for TVOC equivalents and toxicity potentials.

Outdoor Estimate - The average outdoor TVOC concentration from this study was 0.15

ppm, and the calculated value from the PAQS was also 0.15 ppm. From this comparison, we

assumed that the PAQS data were reasonably representative of the concentrations of outdoor

species during our study period. The majority of the estimated PID reading for the PAQS data

was comprised of butane and isobutane, two relatively nontoxic species. By contrast, the ACHD

report lists only hazardous air pollutants (HAPs), and does not include butane, isobutane or other

species not listed as HAPs by EPA. The total estimated PID reading for the ACHD data was

0.012 ppm, of which 92% was comprised of the compounds also found in the PAQS data, which

in turn was 95% of the estimated PID reading from the PAQS data for those compounds.

Given the strong similarities across individual compound concentrations between the

PAQS and ACHD data, we assumed that these data represented separate samples of a very

similar population of VOCs, with one sample (PAQS) focused on mass and one sample (ACHD)

focused on toxicity. We note that if one simply added the PID equivalents of the remaining

HAPs from ACHD to the PAQS total, the result would be the same to two significant digits.

Equation 34 was used to calculate the ambient outdoor air EFs for cancer and noncancer

effects based on the speciation of the ACHD data:

140

Equation 34

∑ ×=x

xACHDxPAQSTVOC

toaTVOCtoa EFCM

CCEF ,

,

,,

,

where EFoa,t is the estimated effect factor for cancer or noncancer effects for the outdoor

air in our study at time t, CTVOC,oa,t is the outdoor air TVOC reading at time t, CTVOC,PAQS is the

PID equivalent TVOC concentration for the PAQS (0.13 ppm), and CMx,ACHD is the mass

concentration of VOC species x from the ACHD data. With the time-averaged value CTVOC,oa

equal to CTVOC,PAQS, the average estimated values for EFoa for this study were 2.3 x 10-9 cases/m3

inhaled for cancer effects and 4.5 x 10-9 for noncancer effects. Over 99% of the cancer value was

due to formaldehyde, while 91% of the noncancer value was due to acrolein.

Indoor Estimate - We obtained the EPA BASE study raw data from the EPA’s Indoor

Environments Division. BASE study VOC sampling was conducted at 100 buildings with

typically 2 outdoor and 4 indoor time-integrated samples conducted at each site. A total of 80

VOCs (including formaldehyde and acetaldehyde, which are labeled aldehydes and not VOCs in

BASE study terminology) were analyzed, though not every building was tested for every VOC.

All 80 of these VOCs are listed in Table 18.

EPA provided a breakdown of indoor and outdoor VOC concentrations by 5-percentile

increments across the sample population (Min, 5th%, 10th%...95th%, Max) but did not report the

quantity [Indoor - Outdoor] for each site. Since indoor concentrations for most VOCs at most

sites were higher than outdoor concentrations, we computed the quantity [Average Indoor -

Average Outdoor] concentration for each VOC at each site. Equation 24 was then used to

estimate PID equivalent TVOC concentrations as ppm isobutylene for each site. The median PID

equivalent concentration for the BASE study was 0.027 ppm, whereas the measured average

141

value for our study was 0.028 ppm (Figure 12). A cumulative distribution of the estimated PID

values from the BASE study is shown in Figure 32.

The ambient air effect factors EFair were calculated for each building using Equation 20

for the outdoor and [indoor - outdoor] concentrations for each VOC species. The outdoor values,

while of interest, were not used further in this study due to the existence of the location-specific

PAQS and ACHD datasets. A cumulative distribution of the EFair values for cancer and

noncancer effects is shown in Figure 33. The median EFs were 1.1 x 10-8 cases/m3 inhaled for

cancer effects and 3.6 x 10-10 for noncancer effects.

Equation 35 was used to calculate compartment and time specific EFs for this study:

Equation 35

oiBASEBASETVOC

toaTVOCtiTVOCti EF

CCCEF −

−= ,

,

,,,,

),(

where CTVOC,BASE and EFBASE,i-o are the median values reported above.

142

Figure 32 - Cumulative distribution of indoor - outdoor PID equivalent TVOC concentrations from EPA

BASE study

Figure 33 - Cumulative distribution of indoor - outdoor effect factors from EPA BASE study

Compound CAS Number Mol. Wt PID CorrectionUSE-Tox EF Cancer

USE-Tox EF Noncancer

CF Cancer Urban Air

CF Cancer Rural Air

CF Noncancer Urban Air

CF Noncancer Rural Air

Units-> g/molppm isobuylene (isobutylene)/ cases/kg inhaled cases/kg inhaled

cases/kg emitted

cases/kg emitted cases/kg emitted cases/kg emitted

1,1,1-Trichloroethane 71-55-6 133 Not detected 0.00E+00 1.08E-04 0.00E+00 0.00E+00 1.90E-08 1.64E-08

1,1,2,2-Tetrachloroethane 79-34-5 168 Not detected 5.33E-02 n/a 2.04E-06 7.50E-07 n/a n/a

1,1,2-Trichloro-1,2,2-trifluoroethane 76-13-1 187 Not detected 0.00E+00 1.14E-04 0.00E+00 0.00E+00 4.12E-07 4.09E-07

1,1,2-Trichloroethane 79-00-5 133 Not detected 3.71E-02 1.16E-01 1.52E-06 6.16E-07 4.73E-06 1.92E-06

1,1-Dichloroethane 75-34-3 99 Not listed 0.00E+00 n/a 0.00E+00 0.00E+00 n/a n/a

1,1-Dichloroethylene 75-35-4 97 0.82 5.90E-02 9.45E-03 1.47E-06 9.59E-08 2.36E-07 1.54E-08

1,2,4-Trichlorobenzene 120-82-1 181 0.46 n/a 8.59E-03 n/a n/a 3.43E-07 1.35E-07

1,2,4-Trimethylbenzene 95-63-6 120 Not listed 2.63E-04 n/a 5.89E-09 1.59E-10 n/a n/a

1,2-Dibromoethane 106-93-4 188 1.7 7.25E-01 4.71E-03 2.84E-05 1.08E-05 1.84E-07 7.01E-08

1,2-Dichloro-1,1,2,2-tetrafloroethane 76-14-2 171 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

1,2-Dichlorobenzene 95-50-1 147 0.47 0.00E+00 1.48E-03 0.00E+00 0.00E+00 5.75E-08 2.16E-08

1,2-Dichloroethane 107-06-2 99 Not detected 1.42E-02 n/a 5.87E-07 2.43E-07 n/a n/a

1,2-Dichloropropane 78-87-5 113 0 7.39E-03 1.03E+00 2.82E-07 1.02E-07 3.92E-05 1.43E-05

1,3,5-Trimethylbenzene 108-67-8 120 0.35 n/a n/a n/a n/a n/a n/a

1,3-Butadiene 106-99-0 54 0.85 5.65E-02 8.45E-02 1.13E-06 1.66E-08 1.68E-06 2.49E-08

1,3-Dichlorobenzene 541-73-1 147 0 n/a n/a n/a n/a n/a n/a

1,4-Dichlorobenzene 106-46-7 147 Not listed 7.53E-03 2.23E-03 3.06E-07 1.24E-07 9.13E-08 3.72E-08

1-butanol 71-36-3 74 4.7 n/a 2.03E-03 n/a n/a 5.27E-08 5.03E-09

1-butene 106-98-9 56 0.9 Not listed Not listed Not listed Not listed Not listed Not listed

1-Ethyl-4-methylbenzene 622-96-8 120 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

1-pentene 109-67-1 70 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 286 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

2,2,4-trimethyl-1,3-pentanediol monoisobutyrate 25265-77-4 216 Not listed n/a n/a n/a n/a n/a n/a

2-butoxyethanol 111-76-2 118 1.2 1.19E-03 7.92E-03 2.93E-08 2.49E-09 2.02E-07 2.40E-08

2-ethyl-1-hexanol 104-76-7 130 1.9 1.21E-03 n/a 3.07E-08 2.66E-09 n/a n/a

2-methyl-1-butene 563-46-2 70 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

2-methyl-1-propanol 78-83-1 74 Not listed n/a 8.04E-04 n/a n/a 2.14E-08 2.45E-09

2-methylpropene 115-11-7 56 1 3.23E-04 n/a 6.75E-09 1.23E-10 n/a n/a

3-methyl-1-butene 563-45-1 70 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

3-methylfuran 930-27-8 82 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

4-phenylcyclohexene 4994-16-5 158 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

Acetaldehyde 75-07-0 44 6 7.49E-03 3.85E-02 1.81E-07 9.18E-09 9.29E-07 4.71E-08

Acetone 67-64-1 58 1.1 n/a 2.82E-04 n/a n/a 9.67E-09 2.83E-09

Acetonitrile 75-05-8 41 Not detected 0.00E+00 2.79E-03 0.00E+00 0.00E+00 9.72E-08 2.96E-08

Acrolein 107-02-8 56 3.9 0.00E+00 5.97E+01 0.00E+00 0.00E+00 1.41E-03 5.56E-05

Acrylonitrile 107-13-1 53 Not detected 1.28E-01 3.52E-01 3.54E-06 4.89E-07 9.68E-06 1.27E-06

a-pinene 80-56-8 136 0.31 n/a n/a n/a n/a n/a n/a

Benzene 71-43-2 78 0.53 1.47E-02 3.72E-03 4.74E-07 1.20E-07 1.20E-07 3.04E-08

Benzyl chloride 100-44-7 127 0.6 3.32E-02 n/a 9.52E-07 1.56E-07 n/a n/a

Bromodichloromethane 75-27-4 164 Not listed 4.28E-02 5.05E-02 2.23E-06 1.20E-06 2.64E-06 1.41E-06

Bromoform 75-25-2 253 2.5 1.77E-03 1.42E-02 7.80E-08 3.51E-08 6.26E-07 2.82E-07

Bromomethane 74-83-9 95 1.7 0.00E+00 1.51E+00 0.00E+00 0.00E+00 1.14E-04 7.72E-05

Butanal 123-72-8 72 1.8 n/a n/a n/a n/a n/a n/a

Butane 106-97-8 58 67 Not listed Not listed Not listed Not listed Not listed Not listed

Butyl acetate 123-86-4 116 2.6 n/a n/a n/a n/a n/a n/a

Butylated hydroxytoluene 128-37-0 220 Not listed 3.13E-03 n/a 7.83E-08 7.37E-09 n/a n/a

c-2-butene 107-01-7 56 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

Carbon disulfide 75-15-0 76 1.2 n/a 2.64E-01 n/a n/a 5.31E-05 4.67E-05

Carbon tetrachloride 56-23-5 154 Not detected 1.08E-01 3.58E-01 4.80E-05 4.54E-05 1.59E-04 1.50E-04

Chlorobenzene 108-90-7 113 0.4 4.64E-03 4.81E-03 1.61E-07 4.89E-08 1.67E-07 5.06E-08

Chloroethane 75-00-3 65 Not detected 1.13E-03 4.18E-05 4.42E-08 1.68E-08 1.64E-09 6.25E-10

Chloroethene 75-01-4 63 2 1.93E-01 6.69E-02 5.03E-06 4.63E-07 1.74E-06 1.61E-07

Chloroform 67-66-3 119 Not detected 5.64E-03 3.25E-02 2.99E-07 1.62E-07 1.71E-06 9.27E-07

Chloromethane 74-87-3 50 Not detected n/a 8.84E-03 n/a n/a 6.56E-07 4.41E-07

cis-1,2-dichloroethene 156-59-2 97 0.8 Not listed Not listed Not listed Not listed Not listed Not listed

cis-1,2-Dichloroethene 540-59-0 97 0.8 n/a n/a n/a n/a n/a n/a

cis-1,3-Dichloro-1-propene 52-75-6 111 0.96 Not listed Not listed Not listed Not listed Not listed Not listed

cis-1,3-dichloropropene 10061-01-5 111 Not listed n/a n/a n/a n/a n/a n/a

Cyclohexane 110-82-7 84 1.4 n/a 8.26E-04 n/a n/a 2.14E-08 1.86E-09

Use-Tox Effect and Characterization Factors

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Table 18 - List of VOCs, properties factors and reference values
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Compound CAS Number Mol. Wt PID CorrectionUSE-Tox EF Cancer

USE-Tox EF Noncancer

CF Cancer Urban Air

CF Cancer Rural Air

CF Noncancer Urban Air

CF Noncancer Rural Air

Units-> g/molppm isobuylene (isobutylene)/ cases/kg inhaled cases/kg inhaled

cases/kg emitted

cases/kg emitted cases/kg emitted cases/kg emitted

Use-Tox Effect and Characterization Factors

Cyclopentane 287-92-3 70 15 n/a n/a n/a n/a n/a n/a

Cyclopentene 142-29-0 68 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

Dibrochloromethane 124-48-1 208 5.3 1.47E-02 1.19E-02 6.72E-07 3.16E-07 5.44E-07 2.55E-07

Dichlorodifluoromethane 75-71-8 121 Not detected 0.00E+00 8.47E-03 0.00E+00 0.00E+00 2.32E-05 2.30E-05

dimethy disulfide 624-92-0 94 0.2 Not listed Not listed Not listed Not listed Not listed Not listed

Dimethylsulfide 75-18-3 62 0.44 n/a n/a n/a n/a n/a n/a

d-limonene 5989-27-5 136 0.33 5.62E-03 n/a 8.59E-08 6.68E-10 n/a n/a

Ethanol 64-17-5 46 10 1.26E-04 n/a 3.64E-09 6.38E-10 n/a n/a

Ethyl acetate 141-78-6 88 4.6 n/a 2.82E-04 n/a n/a 8.63E-09 1.82E-09

Ethylbenzene 100-41-4 106 0.52 2.36E-02 3.85E-04 6.13E-07 5.55E-08 1.01E-08 9.44E-10

Formaldehyde 50-00-0 30 Not detected 1.06E+00 8.47E-03 2.54E-05 1.39E-06 2.67E-07 7.54E-08

Heptane 142-82-5 100 2.8 n/a n/a n/a n/a n/a n/a

Hexachloro-1,3-butadiene 87-68-3 261 Not listed 1.74E-02 n/a 2.10E-06 1.68E-06 n/a n/a

Hexanal 66-25-1 100 Not listed n/a n/a n/a n/a n/a n/a

Hexane 110-54-3 86 4.3 6.74E-05 9.16E-03 1.79E-09 1.93E-10 2.44E-07 2.62E-08

Isobutane 75-28-5 58 100 Not listed Not listed Not listed Not listed Not listed Not listed

Isopentane 78-78-4 72 8.2 Not listed Not listed Not listed Not listed Not listed Not listed

Isoprene 78-79-5 68 0.63 7.45E-03 n/a 1.35E-07 1.46E-09 n/a n/a

Isopropyl alcohol 67-63-0 60 6 0.00E+00 n/a 0.00E+00 0.00E+00 n/a n/a

m & p- Xylene 1330-20-7 106 0.44 Not listed Not listed Not listed Not listed Not listed Not listed

Methacrolein 78-85-3 70 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

Methanol 67-56-1 32 Not detected n/a 5.08E-04 n/a n/a 1.63E-08 4.13E-09

Methyl butyl ketone 591-78-6 100 Not listed n/a n/a n/a n/a n/a n/a

Methyl ethyl ketone 78-93-3 72 0.9 n/a 3.02E-05 n/a n/a 1.27E-09 5.38E-10

Methyl isobutyl ketone 108-10-1 100 0.8 n/a 1.63E-04 n/a n/a 3.98E-09 2.16E-10

Methyl tert-butyl ether 1634-04-4 88 0.9 3.86E-03 6.46E-04 1.10E-07 1.77E-08 1.85E-08 2.99E-09

Methylene chloride 75-09-2 85 Not detected 1.86E-03 2.17E-02 8.92E-08 4.42E-08 1.04E-06 5.16E-07

Methylpentanes 96-14-0 86 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

Methylvinylketone 78-94-4 70 Not listed n/a n/a n/a n/a n/a n/a

naphthalene 91-20-3 128 0.42 5.19E-02 7.19E-02 1.22E-06 5.15E-08 1.68E-06 6.40E-08

n-decane 124-18-5 142 1.4 n/a n/a n/a n/a n/a n/a

n-dodecane 112-40-3 170 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

n-heptanal 111-71-7 114 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

n-nonanal 124-19-6 142 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

n-octane 111-65-9 114 1.8 n/a n/a n/a n/a n/a n/a

nonane 111-84-2 128 1.4 Not listed Not listed Not listed Not listed Not listed Not listed

n-undecane 1120-21-4 156 2 Not listed Not listed Not listed Not listed Not listed Not listed

o-xylene 95-47-6 106 0.46 n/a n/a n/a n/a n/a n/a

o-Xylene 1330-20-7 106 0.46 Not listed Not listed Not listed Not listed Not listed Not listed

Pentanal 110-62-3 86 Not listed n/a n/a n/a n/a n/a n/a

Pentane 109-66-0 72 8.4 n/a n/a n/a n/a n/a n/a

phenol 108-95-2 94 1 0.00E+00 3.29E-03 0.00E+00 0.00E+00 8.41E-08 1.32E-08Propane 74-98-6 44 Not detected Not listed Not listed Not listed Not listed Not listed Not listedPropene 115-07-1 42 1.4 0.00E+00 n/a 0.00E+00 0.00E+00 n/a n/a

Propionaldehyde 123-38-6 58 1.9 n/a n/a n/a n/a n/a n/a

Propyne 74-99-7 40 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

Styrene 100-42-5 104 0.4 4.92E-02 9.84E-03 1.01E-06 1.66E-08 2.01E-07 3.32E-09

t-2-pentene 646-04-8 70 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

Tetrachloroethylene 127-18-4 165 0.57 8.50E-03 3.23E-02 4.29E-07 2.23E-07 1.62E-06 8.40E-07

Tetrahydrofuran 109-99-9 72 1.7 2.82E-03 n/a 6.79E-08 3.39E-09 n/a n/a

Toluene 108-88-3 92 0.5 0.00E+00 3.64E-03 3.17E-12 3.18E-12 9.62E-08 9.90E-09

trans-1,3-dichloropropene 10061-02-6 111 Not listed Not listed Not listed Not listed Not listed Not listed Not listed

Trichloroethylene 79-01-6 131 0.54 1.72E-03 n/a 5.06E-08 9.36E-09 n/a n/a

Trichlorofluoromethane 75-69-4 137 Not listed 0.00E+00 1.46E-03 0.00E+00 0.00E+00 1.81E-06 1.77E-06

TOTALS

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Table 18 (Continued)
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144

Compound CAS Number

Units->

1,1,1-Trichloroethane 71-55-6

1,1,2,2-Tetrachloroethane 79-34-5

1,1,2-Trichloro-1,2,2-trifluoroethane 76-13-1

1,1,2-Trichloroethane 79-00-5

1,1-Dichloroethane 75-34-3

1,1-Dichloroethylene 75-35-4

1,2,4-Trichlorobenzene 120-82-1

1,2,4-Trimethylbenzene 95-63-6

1,2-Dibromoethane 106-93-4

1,2-Dichloro-1,1,2,2-tetrafloroethane 76-14-2

1,2-Dichlorobenzene 95-50-1

1,2-Dichloroethane 107-06-2

1,2-Dichloropropane 78-87-5

1,3,5-Trimethylbenzene 108-67-8

1,3-Butadiene 106-99-0

1,3-Dichlorobenzene 541-73-1

1,4-Dichlorobenzene 106-46-7

1-butanol 71-36-3

1-butene 106-98-9

1-Ethyl-4-methylbenzene 622-96-8

1-pentene 109-67-1

2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0

2,2,4-trimethyl-1,3-pentanediol monoisobutyrate 25265-77-4

2-butoxyethanol 111-76-2

2-ethyl-1-hexanol 104-76-7

2-methyl-1-butene 563-46-2

2-methyl-1-propanol 78-83-1

2-methylpropene 115-11-7

3-methyl-1-butene 563-45-1

3-methylfuran 930-27-8

4-phenylcyclohexene 4994-16-5

Acetaldehyde 75-07-0

Acetone 67-64-1

Acetonitrile 75-05-8

Acrolein 107-02-8

Acrylonitrile 107-13-1

a-pinene 80-56-8

Benzene 71-43-2

Benzyl chloride 100-44-7

Bromodichloromethane 75-27-4

Bromoform 75-25-2

Bromomethane 74-83-9

Butanal 123-72-8

Butane 106-97-8

Butyl acetate 123-86-4

Butylated hydroxytoluene 128-37-0

c-2-butene 107-01-7

Carbon disulfide 75-15-0

Carbon tetrachloride 56-23-5

Chlorobenzene 108-90-7

Chloroethane 75-00-3

Chloroethene 75-01-4

Chloroform 67-66-3

Chloromethane 74-87-3

cis-1,2-dichloroethene 156-59-2

cis-1,2-Dichloroethene 540-59-0

cis-1,3-Dichloro-1-propene 52-75-6

cis-1,3-dichloropropene 10061-01-5

Cyclohexane 110-82-7

Median, ppt IQR, d ppt Median, ppt IQR,d

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

57 40 – 83 62 44 – 88 59.5 5.36E-05 0.0% 0.136 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

36 24 – 56 20 14 – 32 28 0.00E+00 0.0% 0.080 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

16 11 – 25 42 22 – 74 29 0.00E+00 0.0% 0.083 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

38 32 – 51 NQf NQf 38 3.80E-05 0.0% 0.087 2.81E-14 0.00E+00

6 5 – 10 19 12 – 35 12.5 0.00E+00 0.0% 0.036 0.00E+00 0.00E+00

<DLg <DLg 10 6 – 16 10 0.00E+00 0.0% 0.034 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

538 403 – 729 1559 1103 – 2150 1048.5 6.29E-03 4.2% 1.887 1.41E-11 7.26E-11

943 655 – 1385 4031 3128 – 4894 2487 2.74E-03 1.8% 5.900 0.00E+00 1.67E-12

NQf NQf 131 105 – 155 131 0.00E+00 0.0% 0.220 0.00E+00 6.12E-13

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

<DLg <DLg 16 10 – 29 16 4.96E-06 0.0% 0.089 0.00E+00 0.00E+00

279 231 – 355 215 143 – 405 247 1.31E-04 0.1% 0.788 1.16E-11 2.93E-12

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

NQf NQf 91 64 – 122 91 1.64E-04 0.1% 0.268 0.00E+00 0.00E+00

1333 978 – 1799 632 375 – 1106 982.5 6.58E-02 43.8% 2.331 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

27 18 – 44 20 15 – 28 23.5 0.00E+00 0.0% 0.054 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

11 10 – 13 17 13 – 30 14 0.00E+00 0.0% 0.068 3.84E-13 2.21E-12

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Summer WinterAnnual Median

Concentration, ppt

PID Equivalent Concentration,

ppm isobutylene

PAQS (Millet et al) data and calculationsAnnual Median

Mass concentration

µg/m3

Noncancer toxicity potential

(Cases/m3 air inhaled)

Cancer toxicity potential

(Cases/m3 air inhaled)

% Total PID Value

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Table 18 (Continued)
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145

Compound CAS Number

Units->

Cyclopentane 287-92-3

Cyclopentene 142-29-0

Dibrochloromethane 124-48-1

Dichlorodifluoromethane 75-71-8

dimethy disulfide 624-92-0

Dimethylsulfide 75-18-3

d-limonene 5989-27-5

Ethanol 64-17-5

Ethyl acetate 141-78-6

Ethylbenzene 100-41-4

Formaldehyde 50-00-0

Heptane 142-82-5

Hexachloro-1,3-butadiene 87-68-3

Hexanal 66-25-1

Hexane 110-54-3

Isobutane 75-28-5

Isopentane 78-78-4

Isoprene 78-79-5

Isopropyl alcohol 67-63-0

m & p- Xylene 1330-20-7

Methacrolein 78-85-3

Methanol 67-56-1

Methyl butyl ketone 591-78-6

Methyl ethyl ketone 78-93-3

Methyl isobutyl ketone 108-10-1

Methyl tert-butyl ether 1634-04-4

Methylene chloride 75-09-2

Methylpentanes 96-14-0

Methylvinylketone 78-94-4

naphthalene 91-20-3

n-decane 124-18-5

n-dodecane 112-40-3

n-heptanal 111-71-7

n-nonanal 124-19-6

n-octane 111-65-9

nonane 111-84-2

n-undecane 1120-21-4

o-xylene 95-47-6

o-Xylene 1330-20-7

Pentanal 110-62-3

Pentane 109-66-0

phenol 108-95-2Propane 74-98-6Propene 115-07-1

Propionaldehyde 123-38-6

Propyne 74-99-7

Styrene 100-42-5

t-2-pentene 646-04-8

Tetrachloroethylene 127-18-4

Tetrahydrofuran 109-99-9

Toluene 108-88-3

trans-1,3-dichloropropene 10061-02-6

Trichloroethylene 79-01-6

Trichlorofluoromethane 75-69-4

TOTALS

Median, ppt IQR, d ppt Median, ppt IQR,d

Summer WinterAnnual Median

Concentration, ppt

PID Equivalent Concentration,

ppm isobutylene

PAQS (Millet et al) data and calculationsAnnual Median

Mass concentration

µg/m3

Noncancer toxicity potential

(Cases/m3 air inhaled)

Cancer toxicity potential

(Cases/m3 air inhaled)

% Total PID Value

53 35 – 92 47 36 – 72 50 7.50E-04 0.5% 0.143 0.00E+00 0.00E+00

NQf NQf 3 0 – 8 3 0.00E+00 0.0% 0.008 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

NQf NQf 7 5 – 10 7 3.08E-06 0.0% 0.018 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

989 673 – 1416 1722 1017 – 3567 1355.5 1.36E-02 9.0% 2.550 3.21E-13 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

47 34 – 69 71 44 – 141 59 3.07E-05 0.0% 0.256 6.03E-12 9.86E-14

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

34 22 – 52 NQf NQf 34 0.00E+00 0.0% 0.139 0.00E+00 0.00E+00

147 116 – 199 129 81 – 231 138 5.93E-04 0.4% 0.485 3.27E-14 4.45E-12

668 479 – 953 323 212 – 634 495.5 4.96E-02 33.0% 1.175 0.00E+00 0.00E+00

575 448 – 809 649 409 – 1139 612 5.02E-03 3.3% 1.802 0.00E+00 0.00E+00

<DLg <DLg 619 153 – 1475 619 3.90E-04 0.3% 1.722 1.28E-11 0.00E+00

131 86 – 199 235 147 – 432 183 1.10E-03 0.7% 0.449 0.00E+00 0.00E+00

113 76 – 176 163 89 – 306 138 6.07E-05 0.0% 0.598 0.00E+00 0.00E+00

<DLg <DLg 266 178 – 366 266 0.00E+00 0.0% 0.762 0.00E+00 0.00E+00

3760 2347 – 5773 10717 7122 – 14601 7238.5 0.00E+00 0.0% 9.474 0.00E+00 4.82E-12

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

215 153 – 299 559 408 – 674 387 3.48E-04 0.2% 1.140 0.00E+00 3.44E-14

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

10 7 – 14 31 19 – 61 20.5 1.85E-05 0.0% 0.074 2.85E-13 4.76E-14

NQf NQf 79 48 – 145 79 0.00E+00 0.0% 0.275 5.10E-13 5.97E-12

268 203 – 368 276 183 – 506 272 0.00E+00 0.0% 0.957 0.00E+00 0.00E+00

<DLg <DLg 463 273 – 665 463 0.00E+00 0.0% 1.326 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

60 41 – 89 52 29 – 93 56 2.58E-05 0.0% 0.243 0.00E+00 0.00E+00

NQf NQf 137 98 – 193 137 0.00E+00 0.0% 0.482 0.00E+00 0.00E+00

355 279 – 493 352 213 – 613 353.5 2.97E-03 2.0% 1.041 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+002960 2087 – 4307 1787 992 – 3540 2373.5 0.00E+00 0.0% 4.271 0.00E+00 0.00E+00214 147 – 306 219 159 – 336 216.5 3.03E-04 0.2% 0.372 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

29 22 – 40 7 5 – 12 18 0.00E+00 0.0% 0.029 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

19 12 – 33 44 33 – 62 31.5 0.00E+00 0.0% 0.090 0.00E+00 0.00E+00

18 12 – 25 22 13 – 41 20 1.14E-05 0.0% 0.135 1.15E-12 4.36E-12

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

331 248 – 494 443 274 – 902 387 1.94E-04 0.1% 1.456 0.00E+00 5.29E-12

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.150 100% 43.53 4.73E-11 1.05E-10

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Table 18 (Continued)
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146

Compound CAS Number

Units->

1,1,1-Trichloroethane 71-55-6

1,1,2,2-Tetrachloroethane 79-34-5

1,1,2-Trichloro-1,2,2-trifluoroethane 76-13-1

1,1,2-Trichloroethane 79-00-5

1,1-Dichloroethane 75-34-3

1,1-Dichloroethylene 75-35-4

1,2,4-Trichlorobenzene 120-82-1

1,2,4-Trimethylbenzene 95-63-6

1,2-Dibromoethane 106-93-4

1,2-Dichloro-1,1,2,2-tetrafloroethane 76-14-2

1,2-Dichlorobenzene 95-50-1

1,2-Dichloroethane 107-06-2

1,2-Dichloropropane 78-87-5

1,3,5-Trimethylbenzene 108-67-8

1,3-Butadiene 106-99-0

1,3-Dichlorobenzene 541-73-1

1,4-Dichlorobenzene 106-46-7

1-butanol 71-36-3

1-butene 106-98-9

1-Ethyl-4-methylbenzene 622-96-8

1-pentene 109-67-1

2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0

2,2,4-trimethyl-1,3-pentanediol monoisobutyrate 25265-77-4

2-butoxyethanol 111-76-2

2-ethyl-1-hexanol 104-76-7

2-methyl-1-butene 563-46-2

2-methyl-1-propanol 78-83-1

2-methylpropene 115-11-7

3-methyl-1-butene 563-45-1

3-methylfuran 930-27-8

4-phenylcyclohexene 4994-16-5

Acetaldehyde 75-07-0

Acetone 67-64-1

Acetonitrile 75-05-8

Acrolein 107-02-8

Acrylonitrile 107-13-1

a-pinene 80-56-8

Benzene 71-43-2

Benzyl chloride 100-44-7

Bromodichloromethane 75-27-4

Bromoform 75-25-2

Bromomethane 74-83-9

Butanal 123-72-8

Butane 106-97-8

Butyl acetate 123-86-4

Butylated hydroxytoluene 128-37-0

c-2-butene 107-01-7

Carbon disulfide 75-15-0

Carbon tetrachloride 56-23-5

Chlorobenzene 108-90-7

Chloroethane 75-00-3

Chloroethene 75-01-4

Chloroform 67-66-3

Chloromethane 74-87-3

cis-1,2-dichloroethene 156-59-2

cis-1,2-Dichloroethene 540-59-0

cis-1,3-Dichloro-1-propene 52-75-6

cis-1,3-dichloropropene 10061-01-5

Cyclohexane 110-82-7

2009 2009 2010 2010

Average (ppb)24-Hour Maximum (ppb) Average (ppb)

24-Hour Maximum (ppb)

0.02 0.08 0.02 0.03 0.02 0.00E+00 0.0% 0.109 0.00E+00 1.17E-14

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.13 0.25 0.1 0.14 0.115 0.00E+00 0.0% 0.880 0.00E+00 1.00E-13

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.01 0.01 0 0.01 0.005 2.30E-06 0.0% 0.037 0.00E+00 3.18E-13

0.07 0.45 0.06 0.28 0.065 0.00E+00 0.0% 0.319 8.41E-14 0.00E+00

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.02 0.03 0.02 0.03 0.02 0.00E+00 0.0% 0.140 0.00E+00 0.00E+00

0 0.02 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.02 0.03 0.02 0.04 0.02 0.00E+00 0.0% 0.081 1.15E-12 0.00E+00

0 0.02 0.01 0.02 0.005 0.00E+00 0.0% 0.023 1.71E-13 2.38E-11

0.02 0.12 0.02 0.06 0.02 7.00E-06 0.1% 0.098 0.00E+00 0.00E+00

0.06 0.32 0.06 0.2 0.06 5.10E-05 0.4% 0.133 7.48E-12 1.12E-11

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.06 0.27 0.07 0.2 0.065 0.00E+00 0.0% 0.391 2.94E-12 8.72E-13

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.02 0.13 0.02 0.18 0.02 0.00E+00 0.0% 0.098 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.78 1.63 0.9 1.84 0.84 5.04E-03 42.3% 1.512 1.13E-11 5.81E-11

1.93 5.58 1.86 4.68 1.895 2.08E-03 17.5% 4.495 0.00E+00 1.27E-12

0.14 0.28 0.3 0.75 0.22 0.00E+00 0.0% 0.369 0.00E+00 1.03E-12

0.02 0.09 0.04 0.14 0.03 1.17E-04 1.0% 0.069 0.00E+00 4.10E-09

0.03 0.1 0.01 0.09 0.02 0.00E+00 0.0% 0.043 5.55E-12 1.53E-11

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.41 1.55 0.36 1.72 0.385 2.04E-04 1.7% 1.228 1.80E-11 4.56E-12

0 0.01 0 0.04 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.01 0.01 0.01 0.03 0.01 0.00E+00 0.0% 0.067 2.87E-12 3.39E-12

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.01 0.02 0.01 0.02 0.01 1.70E-05 0.1% 0.039 0.00E+00 5.87E-11

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.02 0.07 0.02 0.09 0.02 2.40E-05 0.2% 0.062 0.00E+00 1.64E-11

0.11 0.13 0.1 0.12 0.105 0.00E+00 0.0% 0.661 7.14E-11 2.37E-10

0 0.01 0 0.02 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.01 0.06 0.07 0.12 0.04 0.00E+00 0.0% 0.106 1.20E-13 4.45E-15

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.03 0.08 0.03 0.06 0.03 0.00E+00 0.0% 0.146 8.23E-13 4.74E-12

0.69 0.84 0.67 0.86 0.68 0.00E+00 0.0% 1.391 0.00E+00 1.23E-11

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.05 0.18 0.04 0.14 0.045 6.30E-05 0.5% 0.155 0.00E+00 1.28E-13

2009-2010 Average

ppb

PID Equivalent Concentration,

ppm isobutylene% Total

PID Value

Annual Median Mass

concentration µg/m3

Cancer toxicity potential

(Cases/m3 air inhaled)

Noncancer toxicity potential

(Cases/m3 air

ACHD Air Quality Report Data

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Table 18 (Continued)
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147

Compound CAS Number

Units->

Cyclopentane 287-92-3

Cyclopentene 142-29-0

Dibrochloromethane 124-48-1

Dichlorodifluoromethane 75-71-8

dimethy disulfide 624-92-0

Dimethylsulfide 75-18-3

d-limonene 5989-27-5

Ethanol 64-17-5

Ethyl acetate 141-78-6

Ethylbenzene 100-41-4

Formaldehyde 50-00-0

Heptane 142-82-5

Hexachloro-1,3-butadiene 87-68-3

Hexanal 66-25-1

Hexane 110-54-3

Isobutane 75-28-5

Isopentane 78-78-4

Isoprene 78-79-5

Isopropyl alcohol 67-63-0

m & p- Xylene 1330-20-7

Methacrolein 78-85-3

Methanol 67-56-1

Methyl butyl ketone 591-78-6

Methyl ethyl ketone 78-93-3

Methyl isobutyl ketone 108-10-1

Methyl tert-butyl ether 1634-04-4

Methylene chloride 75-09-2

Methylpentanes 96-14-0

Methylvinylketone 78-94-4

naphthalene 91-20-3

n-decane 124-18-5

n-dodecane 112-40-3

n-heptanal 111-71-7

n-nonanal 124-19-6

n-octane 111-65-9

nonane 111-84-2

n-undecane 1120-21-4

o-xylene 95-47-6

o-Xylene 1330-20-7

Pentanal 110-62-3

Pentane 109-66-0

phenol 108-95-2Propane 74-98-6Propene 115-07-1

Propionaldehyde 123-38-6

Propyne 74-99-7

Styrene 100-42-5

t-2-pentene 646-04-8

Tetrachloroethylene 127-18-4

Tetrahydrofuran 109-99-9

Toluene 108-88-3

trans-1,3-dichloropropene 10061-02-6

Trichloroethylene 79-01-6

Trichlorofluoromethane 75-69-4

TOTALS

2009 2009 2010 2010

Average (ppb)24-Hour Maximum (ppb) Average (ppb)

24-Hour Maximum (ppb)

2009-2010 Average

ppb

PID Equivalent Concentration,

ppm isobutylene% Total

PID Value

Annual Median Mass

concentration µg/m3

Cancer toxicity potential

(Cases/m3 air inhaled)

Noncancer toxicity potential

(Cases/m3 air

ACHD Air Quality Report Data

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.65 0.74 0.61 0.72 0.63 0.00E+00 0.0% 3.118 0.00E+00 2.64E-11

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.02 0.15 0.03 0.15 0.025 1.15E-04 1.0% 0.090 0.00E+00 2.54E-14

0.05 0.32 0.06 0.19 0.055 2.86E-05 0.2% 0.238 5.62E-12 9.19E-14

1.49 4.27 1.85 5.33 1.67 0.00E+00 0.0% 2.049 2.17E-09 1.74E-11

0.07 0.33 0.09 1.02 0.08 2.24E-04 1.9% 0.327 0.00E+00 0.00E+00

0.01 0.01 0 0.01 0.005 0.00E+00 0.0% 0.053 9.30E-13 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.2 1.27 0.21 1.46 0.205 8.82E-04 7.4% 0.721 4.86E-14 6.61E-12

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.36 1.06 0.32 0.99 0.34 2.04E-03 17.1% 0.834 0.00E+00 0.00E+00

0.06 0.41 0.06 0.23 0.06 2.64E-05 0.2% 0.260 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.01 0.04 0.01 0.05 0.01 0.00E+00 0.0% 0.041 0.00E+00 0.00E+00

0.28 0.68 0.34 1.47 0.31 2.79E-04 2.3% 0.913 0.00E+00 2.76E-14

0.01 0.06 0.02 0.06 0.015 1.20E-05 0.1% 0.061 0.00E+00 1.00E-14

0 0.01 0 0.01 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.19 0.47 0.24 1.87 0.215 0.00E+00 0.0% 0.747 1.39E-12 1.62E-11

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.16 1.14 0.16 0.67 0.16 7.36E-05 0.6% 0.694 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+000 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+000 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.17 0.39 0.19 0.36 0.18 3.42E-04 2.9% 0.427 0.00E+00 0.00E+00

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.03 0.13 0.03 0.13 0.03 1.20E-05 0.1% 0.128 6.28E-12 1.26E-12

0 0 0 0 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.03 0.14 0.03 0.17 0.03 1.71E-05 0.1% 0.202 1.72E-12 6.54E-12

0.01 0.05 0.01 0.07 0.01 1.70E-05 0.1% 0.029 8.29E-14 0.00E+00

0.51 2.81 0.46 2.22 0.485 2.43E-04 2.0% 1.825 0.00E+00 6.64E-12

Not listed Not listed Not listed Not listed 0 0.00E+00 0.0% 0.000 0.00E+00 0.00E+00

0.02 0.75 0.01 0.05 0.015 8.10E-06 0.1% 0.080 1.38E-13 0.00E+00

0.32 0.48 0.3 0.35 0.31 0.00E+00 0.0% 1.737 0.00E+00 2.53E-12

0.012 100% 27.23 2.31E-09 4.64E-09

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Table 18 (Continued)
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148

Compound CAS Number

Units->

1,1,1-Trichloroethane 71-55-6

1,1,2,2-Tetrachloroethane 79-34-5

1,1,2-Trichloro-1,2,2-trifluoroethane 76-13-1

1,1,2-Trichloroethane 79-00-5

1,1-Dichloroethane 75-34-3

1,1-Dichloroethylene 75-35-4

1,2,4-Trichlorobenzene 120-82-1

1,2,4-Trimethylbenzene 95-63-6

1,2-Dibromoethane 106-93-4

1,2-Dichloro-1,1,2,2-tetrafloroethane 76-14-2

1,2-Dichlorobenzene 95-50-1

1,2-Dichloroethane 107-06-2

1,2-Dichloropropane 78-87-5

1,3,5-Trimethylbenzene 108-67-8

1,3-Butadiene 106-99-0

1,3-Dichlorobenzene 541-73-1

1,4-Dichlorobenzene 106-46-7

1-butanol 71-36-3

1-butene 106-98-9

1-Ethyl-4-methylbenzene 622-96-8

1-pentene 109-67-1

2,2,4-trimethyl-1,3-pentanediol diisobutyrate 6846-50-0

2,2,4-trimethyl-1,3-pentanediol monoisobutyrate 25265-77-4

2-butoxyethanol 111-76-2

2-ethyl-1-hexanol 104-76-7

2-methyl-1-butene 563-46-2

2-methyl-1-propanol 78-83-1

2-methylpropene 115-11-7

3-methyl-1-butene 563-45-1

3-methylfuran 930-27-8

4-phenylcyclohexene 4994-16-5

Acetaldehyde 75-07-0

Acetone 67-64-1

Acetonitrile 75-05-8

Acrolein 107-02-8

Acrylonitrile 107-13-1

a-pinene 80-56-8

Benzene 71-43-2

Benzyl chloride 100-44-7

Bromodichloromethane 75-27-4

Bromoform 75-25-2

Bromomethane 74-83-9

Butanal 123-72-8

Butane 106-97-8

Butyl acetate 123-86-4

Butylated hydroxytoluene 128-37-0

c-2-butene 107-01-7

Carbon disulfide 75-15-0

Carbon tetrachloride 56-23-5

Chlorobenzene 108-90-7

Chloroethane 75-00-3

Chloroethene 75-01-4

Chloroform 67-66-3

Chloromethane 74-87-3

cis-1,2-dichloroethene 156-59-2

cis-1,2-Dichloroethene 540-59-0

cis-1,3-Dichloro-1-propene 52-75-6

cis-1,3-dichloropropene 10061-01-5

Cyclohexane 110-82-7

Median Indoor Median Outdoor

Median In-Median Out

Median Indoor

Median Outdoor

Median In-Median

3.1 0.63 2.47 5.1 0.9 4.7 0.000 0.0% 0.00E+00 5.08E-13

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

1.9 0.97 0.93 3.1 2.1 1.5 0.000 0.0% 3.92E-13 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

0.54 0.24 0.3 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

0.54 < LOQ 0.54 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

2.1 < LOQ 2.1 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

0.77 0.33 0.44 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

0.74 < LOQ 0.74 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

2.5 < LOQ 2.5 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

5.5 < LOQ 5.5 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

1.2 < LOQ 1.2 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

7.2 2.6 4.6 7.2 3.4 3.4 0.011 42.4% 2.53E-11 1.30E-10

30 7.8 22.2 43.0 21.1 18.9 0.009 33.0% 0.00E+00 5.35E-12

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

0.57 < LOQ 0.57 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

3.6 2.9 0.7 3.5 2.7 0.6 0.000 0.4% 8.44E-12 2.14E-12

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

1.5 < LOQ 1.5 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ 0.98 0 1.6 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

2.5 2.3 0.2 2.5 2.2 0.2 0.000 0.0% 0.00E+00 1.33E-12

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Noncancer toxicity potential

(Cases/m3 air % Total

PID Value

Reported BASE Study concentrations, µg/m3Recalculated BASE Study

concentrations, µg/m31 BASE In-Out PID eq ppm

as isobutylene

Cancer toxicity potential

(Cases/m3 air

EPA BASE Study Data

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Table 18 (Continued)
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149

Compound CAS Number

Units->

Cyclopentane 287-92-3

Cyclopentene 142-29-0

Dibrochloromethane 124-48-1

Dichlorodifluoromethane 75-71-8

dimethy disulfide 624-92-0

Dimethylsulfide 75-18-3

d-limonene 5989-27-5

Ethanol 64-17-5

Ethyl acetate 141-78-6

Ethylbenzene 100-41-4

Formaldehyde 50-00-0

Heptane 142-82-5

Hexachloro-1,3-butadiene 87-68-3

Hexanal 66-25-1

Hexane 110-54-3

Isobutane 75-28-5

Isopentane 78-78-4

Isoprene 78-79-5

Isopropyl alcohol 67-63-0

m & p- Xylene 1330-20-7

Methacrolein 78-85-3

Methanol 67-56-1

Methyl butyl ketone 591-78-6

Methyl ethyl ketone 78-93-3

Methyl isobutyl ketone 108-10-1

Methyl tert-butyl ether 1634-04-4

Methylene chloride 75-09-2

Methylpentanes 96-14-0

Methylvinylketone 78-94-4

naphthalene 91-20-3

n-decane 124-18-5

n-dodecane 112-40-3

n-heptanal 111-71-7

n-nonanal 124-19-6

n-octane 111-65-9

nonane 111-84-2

n-undecane 1120-21-4

o-xylene 95-47-6

o-Xylene 1330-20-7

Pentanal 110-62-3

Pentane 109-66-0

phenol 108-95-2Propane 74-98-6Propene 115-07-1

Propionaldehyde 123-38-6

Propyne 74-99-7

Styrene 100-42-5

t-2-pentene 646-04-8

Tetrachloroethylene 127-18-4

Tetrahydrofuran 109-99-9

Toluene 108-88-3

trans-1,3-dichloropropene 10061-02-6

Trichloroethylene 79-01-6

Trichlorofluoromethane 75-69-4

TOTALS

Median Indoor Median Outdoor

Median In-Median Out

Median Indoor

Median Outdoor

Median In-Median

Noncancer toxicity potential

(Cases/m3 air % Total

PID Value

Reported BASE Study concentrations, µg/m3Recalculated BASE Study

concentrations, µg/m31 BASE In-Out PID eq ppm

as isobutylene

Cancer toxicity potential

(Cases/m3 air

EPA BASE Study Data

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

6.8 4.4 2.4 6.3 4.3 1.7 0.000 0.0% 0.00E+00 1.44E-11

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

7.1 0.19 6.91 7.7 0.0 6.2 0.000 1.4% 3.46E-11 0.00E+00

79 25 54 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

2 0.26 1.74 2.0 0.0 1.9 0.002 9.2% 0.00E+00 5.40E-13

1.5 0.7 0.8 2.6 0.0 0.8 0.000 0.3% 1.79E-11 2.92E-13

15 3 12 15.5 3.1 9.9 0.000 0.0% 1.05E-08 8.41E-11

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

4.1 0.5 3.6 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

2.5 1.3 1.2 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

30 3.5 26.5 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

2.6 1.4 1.2 5.0 3.5 1.0 0.000 1.1% 0.00E+00 2.87E-14

1 < LOQ 1 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

2.9 < LOQ 2.9 3.3 0.0 1.5 0.000 0.0% 2.76E-12 3.23E-11

1.4 0.82 0.58 1.9 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

0.73 0.22 0.51 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

2.9 0.48 2.42 4.7 2.2 2.5 0.001 2.3% 0.00E+00 0.00E+00

3.5 < LOQ 3.5 6.9 0.0 4.7 0.000 0.0% 0.00E+00 0.00E+00

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

3.6 0.94 2.66 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

0.85 0.25 0.6 1.3 0.0 1.0 0.000 1.4% 0.00E+00 0.00E+00

0.94 0.28 0.66 1.4 0.0 0.7 0.000 0.7% 0.00E+00 0.00E+00

4 0.31 3.69 7.8 3.5 3.3 0.001 3.8% 0.00E+00 0.00E+00

2.1 0.89 1.21 3.0 1.7 1.7 0.000 0.7% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

1.2 < LOQ 1.2 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

1.8 1.1 0.7 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

0.91 0.24 0.67 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

1.5 0.56 0.94 4.0 0.0 2.1 0.000 0.7% 1.75E-11 6.64E-11

Not listed Not listed 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

8.7 3.7 5 16.9 9.6 5.4 0.001 2.7% 0.00E+00 1.98E-11

< LOQ < LOQ 0 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

0.29 < LOQ 0.29 0.0 0.0 0.0 0.000 0.0% 0.00E+00 0.00E+00

3.9 < LOQ 3.9 4.3 0.0 3.0 0.000 0.0% 0.00E+00 4.41E-12

257.080 68.790 189.270 160.404 60.058 76.433 0.027 100% 1.06E-08 3.62E-10

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Table 18 (Continued)
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150

151

B.3 LIFE CYCLE INVENTORY

B.3.1 National Renewable Energy Laboratory (NREL) dynamic grid mix

Figure 34 - Dynamic electrical generation mix at load point (courtesy of NREL)

152

APPENDIX C

POST-OCCUPANCY SURVEY QUESTIONS AND RESPONSES

RespondentID 2468709672 2467042000 2465413150 2465307176 2424782001 2463689908 2463645788What is your job title? Response Staff Graduate student Graduate student Graduate student Graduate student Graduate student Graduate student

Other (please specify)

How many hours a week do you spend at MCSI?

Response 10-20 >40 30-40 >40 30-40 30-40 30-40

In which area of the building is your primary work area located?

Response 2nd floor Benedum Hall - Wet Lab

2nd floor MCSI wing (grad student space or dry lab)

3rd floor MCSI wing (grad student space)

2nd floor Benedum Hall - Wet Lab

2nd floor MCSI wing (grad student space or dry lab)

3rd floor MCSI wing (grad student space)

2nd floor Benedum Hall - Wet Lab

Which option best describes your work area?

Response Laboratory benches

Laboratory benches

Open office with partitions

Laboratory benches

Open office with partitions

Open office with partitions

Laboratory benches

Other (please specify)

Do you have outside views from your work area while either standing or seated, including windows above eye level?

Response Yes No Yes Yes Yes Yes No

Which direction does the window face?

Response North (O’Hara Street)

East (Thackeray Street)

North (O’Hara Street)

South (Fifth Avenue)

North (O’Hara Street)

North (O’Hara Street)

West (Bouquet Street)

Is there a corridor or hallway between your seat and the nearest window?

Response No Yes No No No No No

In my work area, I can personally adjust or control the following. (Check all that apply):

Daylight level i.e., with window blinds or shades

x x x x

Electric light level, i.e., with a switch or dimmer

x x x

Air supply temperature i.e., with a thermostatAir supply volume and/or direction i.e., with an adjustable vent

x

None of the above x x xOther

During warmer weather, I am satisfied with the temperature in my work area.

3 6 1 5 3 5 1

During cooler weather, I am satisfied with the temperature in my work area.

3 6 3 6 4 5 1

I am generally satisfied with the temperature in my work area.

3 2 4 6 5 1

During warmer weather, I believe the air is too humid in my work area.

3 2 1 4 2 3 4

During cooler weather, I believe the air is too dry in my work area.

4 2 6 4 2 3 4

I am generally satisfied with the humidity in my work area.

4 6 1 6 7 5 6

During warmer weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

3 6 2 6 6 5 1

During cooler weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

5 6 2 6 6 5 1

I am generally satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

5 6 2 6 6 5 1

Recalling the previous questions related to temperature, humidity, and air flow speed, I am generally satisfied with the thermal comfort in my work area.

3 6 2 5 2 5 1

I believe the air in my work area is not stuffy or stale.

5 6 3 6 1 5 7

I believe the air in my work area is clean.

4 6 4 6 7 5 7

I believe the air in my work area is generally free from odors.

5 6 3 6 7 5 6

Recalling the previous questions related to stuffiness/staleness, cleanliness and odor, I am generally satisfied with the air quality in my work area.

5 6 3 6 7 5 6

What type of lighting is provided at your work area? (Check all that apply.)

Daylighting (sunlight entering the building through windows, glass roof, or glass doors)

x x x x x

Overhead lighting (lighting provided by the fixtures on the ceiling or on the walls)

x x x x x x x

Task lighting (lighting provided by personal fixtures at one's work area, such as desk lights)

x x

Other (please specify)My work area is too bright. 4 2 5 3 5 3 5My work area is too dark. 4 7 1 3 1 5 3There is an adequate amount of daylight in my area (leave blank if none).

4 5 7 7 5

There is an adequate amount of electric light in my area.

5 3 4 7 7 5 5

There is a problem with glare, reflections or contrast in my work area.

5 1 6 3 2 5 5

Recalling the previous questions related to lighting and daylighting, I am generally satisfied with the lighting quality in my work area.

4 4 5 6 7 4 4

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

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Table 19 - Post-occupancy survey questions and individual results
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RespondentID 2468709672 2467042000 2465413150 2465307176 2424782001 2463689908 2463645788My work area is too loud due to other people’s conversations.

5 5 4 4 5 3 5

My work area is too loud due to background noise other than conversations (e.g. mechanical equipment, outdoor noises).

5 4 6 6 2 3 5

My work area is too quiet. 3 3 4 4 1 2 1There is a problem with acoustics in my work area other than generally too loud or too quiet.

4 2 4 4 1 3 5

If you agree, please explain: generally noisy or loud

Recalling the previous questions related to acoustics, I am generally satisfied with the acoustical quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

4 6 5 5 6 5 3

How does the thermal comfort (remember, this includes temperature, humidity and airspeed) in your work area affect your productivity?

3 5 3 4 2 4 2

How does the air quality (remember, this includes stuffiness/staleness, cleanliness and odors) in your work area affect your productivity?

3 5 3 4 7 4 5

How does the lighting quality (remember, this includes both daylighting and artifical - both overhead, and task-based) in your work area affect your productivity?

3 3 3 4 7 3 3

How does the outdoor view, or lack of an outdoor view, in your work area affect your productivity?

2 3 5 6 7 5 4

How does the acoustical quality or noise level in your work area affect your productivity?

2 4 3 3 5 6 3

Recalling the previous questions related to indoor environmental quality (including thermal comfort, air quality, lighting and acoustics), how does the overall indoor environmental quality in your work area affect your productivity?

2 6 5 4 6 5 3

How do you think increasing the temperature in your work area by several degrees in warmer weather would affect your productivity?

2 5 7 4 7 3 6

How do you think decreasing the temperature in your work area by several degrees in cooler weather would affect your productivity?

3 4 3 4 2 3 2

How do you think decreasing the ventilation in your work area would affect your productivity?

3 4 3 4 2 4 4

How do you think including operable windows in your work area would affect your productivity?

5 5 0 5 2 2 0

How do you think decreasing the amount of daylighting in your work area would affect your productivity?

3 3 3 3 1 2 4

How do you think increasing the amount of daylighting in your work area would affect your productivity?

5 5 5 6 7 6 5

How do you think automatically turning off overhead lighting in your work area when there is sufficient daylight would affect your productivity?

4 4 0 4 3 4 4

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive effect

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive

effect; 0 = I don't know

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

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RespondentIDWhat is your job title? Response

Other (please specify)

How many hours a week do you spend at MCSI?

Response

In which area of the building is your primary work area located?

Response

Which option best describes your work area?

Response

Other (please specify)

Do you have outside views from your work area while either standing or seated, including windows above eye level?

Response

Which direction does the window face?

Response

Is there a corridor or hallway between your seat and the nearest window?

Response

In my work area, I can personally adjust or control the following. (Check all that apply):

Daylight level i.e., with window blinds or shades

Electric light level, i.e., with a switch or dimmerAir supply temperature i.e., with a thermostatAir supply volume and/or direction i.e., with an adjustable vent

None of the aboveOther

During warmer weather, I am satisfied with the temperature in my work area.

During cooler weather, I am satisfied with the temperature in my work area.

I am generally satisfied with the temperature in my work area.During warmer weather, I believe the air is too humid in my work area.

During cooler weather, I believe the air is too dry in my work area.I am generally satisfied with the humidity in my work area.During warmer weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

During cooler weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

I am generally satisfied with the air flow speed (not too drafty or too stagnant) in my work area.Recalling the previous questions related to temperature, humidity, and air flow speed, I am generally satisfied with the thermal comfort in my work area.I believe the air in my work area is not stuffy or stale.I believe the air in my work area is clean.I believe the air in my work area is generally free from odors.Recalling the previous questions related to stuffiness/staleness, cleanliness and odor, I am generally satisfied with the air quality in my work area.What type of lighting is provided at your work area? (Check all that apply.)

Daylighting (sunlight entering the building through windows, glass roof, or glass doors)Overhead lighting (lighting provided by the fixtures on the ceiling or on the walls)Task lighting (lighting provided by personal fixtures at one's work area, such as desk lights)Other (please specify)

My work area is too bright.My work area is too dark.There is an adequate amount of daylight in my area (leave blank if none).There is an adequate amount of electric light in my area.There is a problem with glare, reflections or contrast in my work area.Recalling the previous questions related to lighting and daylighting, I am generally satisfied with the lighting quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2463595868 2463456757 2459886333 2457993679 2457977220 2456121623 2453710317Graduate student Graduate student Graduate student Graduate student Graduate student Graduate student Graduate student

30-40 10-20 30-40 30-40 10-20 >40 20-30

2nd floor MCSI wing (grad student space or dry lab)

2nd floor MCSI wing (grad student space or dry lab)

3rd floor MCSI wing (grad student space)

2nd floor MCSI wing (grad student space or dry lab)

2nd floor Benedum Hall - Wet Lab

2nd floor Benedum Hall - Wet Lab

3rd floor MCSI wing (grad student space)

Open office with partitions

Open office with partitions

Open office with partitions

Open office with partitions

Laboratory benches

Laboratory benches

Open office with partitions

Yes Yes Yes Yes No Yes Yes

North (O’Hara Street)

North (O’Hara Street)

North (O’Hara Street)

North (O’Hara Street)

South (Fifth Avenue)

North (O’Hara Street)

No Yes Yes No Yes Yes Yes

x x x

x x x

x

x x x

4 2 6 2 2 6 4

4 3 7 5 6 6 6

4 3 7 4 4 6 6

4 2 4 2 5 4 1

5 2 4 4 5 5 1

5 6 7 6 5 3 7

5 3 7 2 5 5 6

5 3 7 5 5 5 6

5 3 7 3 5 5 6

5 2 7 3 5 6 6

6 6 6 7 6 3 7

6 6 5 7 3 6 7

6 6 6 6 3 6 7

6 6 6 7 4 6 7

x x x x x x

x x x x x x x

2 2 4 1 5 2 12 1 4 1 4 5 46 6 5 6 4 2

6 6 6 7 7 5 7

2 1 1 1 2 2 2

6 6 6 7 3 4 4

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Table 19 (Continued)
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155

RespondentIDMy work area is too loud due to other people’s conversations.My work area is too loud due to background noise other than conversations (e.g. mechanical equipment, outdoor noises).My work area is too quiet.There is a problem with acoustics in my work area other than generally too loud or too quiet.

If you agree, please explain:

Recalling the previous questions related to acoustics, I am generally satisfied with the acoustical quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

How does the thermal comfort (remember, this includes temperature, humidity and airspeed) in your work area affect your productivity?

How does the air quality (remember, this includes stuffiness/staleness, cleanliness and odors) in your work area affect your productivity?

How does the lighting quality (remember, this includes both daylighting and artifical - both overhead, and task-based) in your work area affect your productivity?How does the outdoor view, or lack of an outdoor view, in your work area affect your productivity?How does the acoustical quality or noise level in your work area affect your productivity?Recalling the previous questions related to indoor environmental quality (including thermal comfort, air quality, lighting and acoustics), how does the overall indoor environmental quality in your work area affect your productivity?How do you think increasing the temperature in your work area by several degrees in warmer weather would affect your productivity?

How do you think decreasing the temperature in your work area by several degrees in cooler weather would affect your productivity?How do you think decreasing the ventilation in your work area would affect your productivity? How do you think including operable windows in your work area would affect your productivity?

How do you think decreasing the amount of daylighting in your work area would affect your productivity?

How do you think increasing the amount of daylighting in your work area would affect your productivity?

How do you think automatically turning off overhead lighting in your work area when there is sufficient daylight would affect your productivity?

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive effect

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive

effect; 0 = I don't know

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2463595868 2463456757 2459886333 2457993679 2457977220 2456121623 24537103172 3 4 3 1 7 1

2 5 5 4 7 6 1

6 2 4 2 1 2 62 2 4 2 2 4 1

6 6 5 5 2 2 6

6 3 5 4 3 5 4

6 6 7 6 4 5 4

6 5 7 7 3 3 6

6 4 4 7 2 4 6

6 4 7 6 4 1 4

6 6 6 6 3 3 4

3 5 0 6 4 0 4

3 2 6 4 1 0 4

4 2 4 3 3 0 3

4 4 5 4 0 0 7

1 3 6 1 1 3 2

7 5 6 6 7 4 7

5 5 5 6 6 3 6

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Table 19 (Continued)
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156

RespondentIDWhat is your job title? Response

Other (please specify)

How many hours a week do you spend at MCSI?

Response

In which area of the building is your primary work area located?

Response

Which option best describes your work area?

Response

Other (please specify)

Do you have outside views from your work area while either standing or seated, including windows above eye level?

Response

Which direction does the window face?

Response

Is there a corridor or hallway between your seat and the nearest window?

Response

In my work area, I can personally adjust or control the following. (Check all that apply):

Daylight level i.e., with window blinds or shades

Electric light level, i.e., with a switch or dimmerAir supply temperature i.e., with a thermostatAir supply volume and/or direction i.e., with an adjustable vent

None of the aboveOther

During warmer weather, I am satisfied with the temperature in my work area.

During cooler weather, I am satisfied with the temperature in my work area.

I am generally satisfied with the temperature in my work area.During warmer weather, I believe the air is too humid in my work area.

During cooler weather, I believe the air is too dry in my work area.I am generally satisfied with the humidity in my work area.During warmer weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

During cooler weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

I am generally satisfied with the air flow speed (not too drafty or too stagnant) in my work area.Recalling the previous questions related to temperature, humidity, and air flow speed, I am generally satisfied with the thermal comfort in my work area.I believe the air in my work area is not stuffy or stale.I believe the air in my work area is clean.I believe the air in my work area is generally free from odors.Recalling the previous questions related to stuffiness/staleness, cleanliness and odor, I am generally satisfied with the air quality in my work area.What type of lighting is provided at your work area? (Check all that apply.)

Daylighting (sunlight entering the building through windows, glass roof, or glass doors)Overhead lighting (lighting provided by the fixtures on the ceiling or on the walls)Task lighting (lighting provided by personal fixtures at one's work area, such as desk lights)Other (please specify)

My work area is too bright.My work area is too dark.There is an adequate amount of daylight in my area (leave blank if none).There is an adequate amount of electric light in my area.There is a problem with glare, reflections or contrast in my work area.Recalling the previous questions related to lighting and daylighting, I am generally satisfied with the lighting quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2453034559 2452104034 2452005526 2451968040 2451873253 2449203632 2435366623Faculty Graduate student Postdoctoral

researcherGraduate student Faculty Staff Faculty

30-40 30-40 30-40 >40 >40 30-40 >40

2nd floor Benedum Hall - East offices (facing plaza & Thackeray Street)

3rd floor MCSI wing (grad student space)

2nd floor Benedum Hall - North offices (facing O'Hara Street)

2nd floor Benedum Hall - Wet Lab

2nd floor Benedum Hall - East offices (facing plaza & Thackeray Street)

First floor MCSI wing (Mascaro suite)

2nd floor Benedum Hall - North offices (facing O'Hara Street)

Private office Open office with partitions

Laboratory benches

Open office with partitions

Laboratory benches

Other (please specify)

Private office

reception area

Yes Yes Yes No Yes Yes Yes

East (Thackeray Street)

North (O’Hara Street)

North (O’Hara Street)

East (Thackeray Street)

North (O’Hara Street)

North (O’Hara Street)

No No Yes No No No No

x x x x x

x x x x x x

x x x

x

x

5 5 1 2 2 2 2

5 5 5 2 2 2 2

5 5 5 2 3 2 2

2 3 5 4 4 4 1

3 3 7 4 2 4 1

5 6 3 4 3 4 7

5 4 3 2 4 3 7

5 4 3 2 3 7

5 4 3 2 4 3 7

5 6 3 2 2 2 3

6 5 3 4 2 5 7

6 6 2 4 1 4 7

5 6 3 5 1 4 7

5 6 3 5 1 5 7

x x x x x x

x x x x x x x

2 2 1 1 4 2 11 1 1 7 4 2 16 7 7 3 7 7

6 7 7 2 2 6 7

2 5 4 2 6 4 1

6 7 7 1 3 5 7

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Table 19 (Continued)
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157

RespondentIDMy work area is too loud due to other people’s conversations.My work area is too loud due to background noise other than conversations (e.g. mechanical equipment, outdoor noises).My work area is too quiet.There is a problem with acoustics in my work area other than generally too loud or too quiet.

If you agree, please explain:

Recalling the previous questions related to acoustics, I am generally satisfied with the acoustical quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

How does the thermal comfort (remember, this includes temperature, humidity and airspeed) in your work area affect your productivity?

How does the air quality (remember, this includes stuffiness/staleness, cleanliness and odors) in your work area affect your productivity?

How does the lighting quality (remember, this includes both daylighting and artifical - both overhead, and task-based) in your work area affect your productivity?How does the outdoor view, or lack of an outdoor view, in your work area affect your productivity?How does the acoustical quality or noise level in your work area affect your productivity?Recalling the previous questions related to indoor environmental quality (including thermal comfort, air quality, lighting and acoustics), how does the overall indoor environmental quality in your work area affect your productivity?How do you think increasing the temperature in your work area by several degrees in warmer weather would affect your productivity?

How do you think decreasing the temperature in your work area by several degrees in cooler weather would affect your productivity?How do you think decreasing the ventilation in your work area would affect your productivity? How do you think including operable windows in your work area would affect your productivity?

How do you think decreasing the amount of daylighting in your work area would affect your productivity?

How do you think increasing the amount of daylighting in your work area would affect your productivity?

How do you think automatically turning off overhead lighting in your work area when there is sufficient daylight would affect your productivity?

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive effect

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive

effect; 0 = I don't know

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2453034559 2452104034 2452005526 2451968040 2451873253 2449203632 24353666236 3 1 3 7 6 5

5 6 1 7 7 4 1

3 4 7 2 1 2 21 2 1 6 7 2 5

mechanical noises from HVAC

Hallway outside office seems to resemble a reverberation chamber

4 4 6 1 1 4 3

4 5 2 4 3 4 3

4 5 2 4 1 4 4

3 6 7 2 3 5 5

4 6 2 4 6 5 7

4 4 7 3 1 4 3

4 6 3 4 3 4 4

2 5 7 6 4 5 7

3 5 6 1 4 5 1

4 3 4 5 3 0 4

4 0 7 4 7 4 4

4 2 1 4 3 2 2

4 5 7 4 5 4 4

4 5 4 1 1 5 4

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Table 19 (Continued)
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158

RespondentIDWhat is your job title? Response

Other (please specify)

How many hours a week do you spend at MCSI?

Response

In which area of the building is your primary work area located?

Response

Which option best describes your work area?

Response

Other (please specify)

Do you have outside views from your work area while either standing or seated, including windows above eye level?

Response

Which direction does the window face?

Response

Is there a corridor or hallway between your seat and the nearest window?

Response

In my work area, I can personally adjust or control the following. (Check all that apply):

Daylight level i.e., with window blinds or shades

Electric light level, i.e., with a switch or dimmerAir supply temperature i.e., with a thermostatAir supply volume and/or direction i.e., with an adjustable vent

None of the aboveOther

During warmer weather, I am satisfied with the temperature in my work area.

During cooler weather, I am satisfied with the temperature in my work area.

I am generally satisfied with the temperature in my work area.During warmer weather, I believe the air is too humid in my work area.

During cooler weather, I believe the air is too dry in my work area.I am generally satisfied with the humidity in my work area.During warmer weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

During cooler weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

I am generally satisfied with the air flow speed (not too drafty or too stagnant) in my work area.Recalling the previous questions related to temperature, humidity, and air flow speed, I am generally satisfied with the thermal comfort in my work area.I believe the air in my work area is not stuffy or stale.I believe the air in my work area is clean.I believe the air in my work area is generally free from odors.Recalling the previous questions related to stuffiness/staleness, cleanliness and odor, I am generally satisfied with the air quality in my work area.What type of lighting is provided at your work area? (Check all that apply.)

Daylighting (sunlight entering the building through windows, glass roof, or glass doors)Overhead lighting (lighting provided by the fixtures on the ceiling or on the walls)Task lighting (lighting provided by personal fixtures at one's work area, such as desk lights)Other (please specify)

My work area is too bright.My work area is too dark.There is an adequate amount of daylight in my area (leave blank if none).There is an adequate amount of electric light in my area.There is a problem with glare, reflections or contrast in my work area.Recalling the previous questions related to lighting and daylighting, I am generally satisfied with the lighting quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2434857673 2434505183 2433360907 2431206899 2427574863 2427444506 2427321634Graduate student Graduate student Graduate student Faculty Faculty Graduate student Faculty

10-20 10-20 >40 >40 >40 20-30 >40

2nd floor MCSI wing (grad student space or dry lab)

2nd floor MCSI wing (grad student space or dry lab)

3rd floor MCSI wing (grad student space)

2nd floor MCSI wing (grad student space or dry lab)

2nd floor Benedum Hall - North offices (facing O'Hara Street)

2nd floor MCSI wing (grad student space or dry lab)

2nd floor Benedum Hall - North offices (facing O'Hara Street)

Open office with partitions

Open office with partitions

Open office with partitions

Private office Private office Open office with partitions

Private office

No Yes Yes Yes Yes Yes Yes

North (O’Hara Street)

North (O’Hara Street)

North (O’Hara Street)

East (Thackeray Street)

North (O’Hara Street)

North (O’Hara Street)

North (O’Hara Street)

No No No No No No No

x x x x x x

x x x x

x

x

5 4 4 4 1 6 4

4 4 6 4 5 6 4

4 4 5 4 3 6 5

2 3 4 5 6 2 3

2 3 4 5 6 2 5

6 5 4 5 6 6 5

6 4 5 5 6 6 5

6 4 5 5 5 6 5

6 5 5 5 5 6 5

7 5 5 4 2 6 5

6 5 6 5 5 6 6

6 5 6 5 5 5 6

4 5 6 5 2 6 5

6 5 6 5 2 6 5

x x x x x x

x x x x x x x

x x

2 3 2 3 4 2 12 3 3 6 4 2 12 5 6 5 6 5 7

4 5 6 6 6 7 7

2 4 5 4 3 2 1

6 5 6 4 5 6 7

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Table 19 (Continued)
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159

RespondentIDMy work area is too loud due to other people’s conversations.My work area is too loud due to background noise other than conversations (e.g. mechanical equipment, outdoor noises).My work area is too quiet.There is a problem with acoustics in my work area other than generally too loud or too quiet.

If you agree, please explain:

Recalling the previous questions related to acoustics, I am generally satisfied with the acoustical quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

How does the thermal comfort (remember, this includes temperature, humidity and airspeed) in your work area affect your productivity?

How does the air quality (remember, this includes stuffiness/staleness, cleanliness and odors) in your work area affect your productivity?

How does the lighting quality (remember, this includes both daylighting and artifical - both overhead, and task-based) in your work area affect your productivity?How does the outdoor view, or lack of an outdoor view, in your work area affect your productivity?How does the acoustical quality or noise level in your work area affect your productivity?Recalling the previous questions related to indoor environmental quality (including thermal comfort, air quality, lighting and acoustics), how does the overall indoor environmental quality in your work area affect your productivity?How do you think increasing the temperature in your work area by several degrees in warmer weather would affect your productivity?

How do you think decreasing the temperature in your work area by several degrees in cooler weather would affect your productivity?How do you think decreasing the ventilation in your work area would affect your productivity? How do you think including operable windows in your work area would affect your productivity?

How do you think decreasing the amount of daylighting in your work area would affect your productivity?

How do you think increasing the amount of daylighting in your work area would affect your productivity?

How do you think automatically turning off overhead lighting in your work area when there is sufficient daylight would affect your productivity?

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive effect

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive

effect; 0 = I don't know

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2434857673 2434505183 2433360907 2431206899 2427574863 2427444506 24273216345 4 4 7 3 2 1

5 3 4 7 3 2 1

2 3 1 1 4 3 12 3 1 7 4 2 1

Echos, conversations, etc. -- sometimes its hard to concentrate

4 5 5 1 6 6 7

5 4 4 4 3 5 3

5 4 4 5 3 4 3

7 4 6 6 6 6 4

7 4 6 7 7 4 4

7 4 5 7 6 4 4

7 4 5 6 3 4 4

0 5 3 4 7 3 4

0 2 3 4 2 4 3

3 3 0 4 4 3 3

6 5 6 4 4 5 7

3 1 2 6 3 1

6 7 6 6 4 5 4

7 5 4 5 4 5 4

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160

RespondentIDWhat is your job title? Response

Other (please specify)

How many hours a week do you spend at MCSI?

Response

In which area of the building is your primary work area located?

Response

Which option best describes your work area?

Response

Other (please specify)

Do you have outside views from your work area while either standing or seated, including windows above eye level?

Response

Which direction does the window face?

Response

Is there a corridor or hallway between your seat and the nearest window?

Response

In my work area, I can personally adjust or control the following. (Check all that apply):

Daylight level i.e., with window blinds or shades

Electric light level, i.e., with a switch or dimmerAir supply temperature i.e., with a thermostatAir supply volume and/or direction i.e., with an adjustable vent

None of the aboveOther

During warmer weather, I am satisfied with the temperature in my work area.

During cooler weather, I am satisfied with the temperature in my work area.

I am generally satisfied with the temperature in my work area.During warmer weather, I believe the air is too humid in my work area.

During cooler weather, I believe the air is too dry in my work area.I am generally satisfied with the humidity in my work area.During warmer weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

During cooler weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

I am generally satisfied with the air flow speed (not too drafty or too stagnant) in my work area.Recalling the previous questions related to temperature, humidity, and air flow speed, I am generally satisfied with the thermal comfort in my work area.I believe the air in my work area is not stuffy or stale.I believe the air in my work area is clean.I believe the air in my work area is generally free from odors.Recalling the previous questions related to stuffiness/staleness, cleanliness and odor, I am generally satisfied with the air quality in my work area.What type of lighting is provided at your work area? (Check all that apply.)

Daylighting (sunlight entering the building through windows, glass roof, or glass doors)Overhead lighting (lighting provided by the fixtures on the ceiling or on the walls)Task lighting (lighting provided by personal fixtures at one's work area, such as desk lights)Other (please specify)

My work area is too bright.My work area is too dark.There is an adequate amount of daylight in my area (leave blank if none).There is an adequate amount of electric light in my area.There is a problem with glare, reflections or contrast in my work area.Recalling the previous questions related to lighting and daylighting, I am generally satisfied with the lighting quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2427240007 2427136288 2427076875 2427012322 2426972792 2426438141 2426408347Staff Graduate student Graduate student Graduate student Staff Graduate student Faculty

>40 30-40 >40 >40 20-30 >40 >40

2nd floor MCSI wing (grad student space or dry lab)

2nd floor MCSI wing (grad student space or dry lab)

2nd floor MCSI wing (grad student space or dry lab)

3rd floor MCSI wing (grad student space)

First floor MCSI wing (Mascaro suite)

2nd floor MCSI wing (grad student space or dry lab)

2nd floor MCSI wing (grad student space or dry lab)

Open office with partitions

Open office with partitions

Open office with partitions

Private office Open office with partitions

Private office

Yes Yes Yes Yes No Yes Yes

North (O’Hara Street)

North (O’Hara Street)

North (O’Hara Street)

North (O’Hara Street)

North (O’Hara Street)

East (Thackeray Street)

Yes No No No Yes Yes No

x x x x x

x x x x x

x

x

1 4 6 3 3 6

1 2 3 1 5 2

1 3 3 1 4 5

4 4 2 3 1 2

6 3 5 3 1 2

6 3 5 5 7 5

1 3 6 5 6 5

1 3 6 5 6 5

1 6 5 6 5

1 3 4 2 5 4

4 3 6 7 6 6

4 4 6 7 6 4

1 4 6 7 7 5

1 4 6 7 6 5

x x x x x

x x x x x

x

7 6 4 1 2 22 2 4 1 2 24 5 3 7 6 6

4 7 6 7 6 6

1 7 3 1 2 2

6 2 4 7 6 6

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Table 19 (Continued)
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161

RespondentIDMy work area is too loud due to other people’s conversations.My work area is too loud due to background noise other than conversations (e.g. mechanical equipment, outdoor noises).My work area is too quiet.There is a problem with acoustics in my work area other than generally too loud or too quiet.

If you agree, please explain:

Recalling the previous questions related to acoustics, I am generally satisfied with the acoustical quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

How does the thermal comfort (remember, this includes temperature, humidity and airspeed) in your work area affect your productivity?

How does the air quality (remember, this includes stuffiness/staleness, cleanliness and odors) in your work area affect your productivity?

How does the lighting quality (remember, this includes both daylighting and artifical - both overhead, and task-based) in your work area affect your productivity?How does the outdoor view, or lack of an outdoor view, in your work area affect your productivity?How does the acoustical quality or noise level in your work area affect your productivity?Recalling the previous questions related to indoor environmental quality (including thermal comfort, air quality, lighting and acoustics), how does the overall indoor environmental quality in your work area affect your productivity?How do you think increasing the temperature in your work area by several degrees in warmer weather would affect your productivity?

How do you think decreasing the temperature in your work area by several degrees in cooler weather would affect your productivity?How do you think decreasing the ventilation in your work area would affect your productivity? How do you think including operable windows in your work area would affect your productivity?

How do you think decreasing the amount of daylighting in your work area would affect your productivity?

How do you think increasing the amount of daylighting in your work area would affect your productivity?

How do you think automatically turning off overhead lighting in your work area when there is sufficient daylight would affect your productivity?

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive effect

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive

effect; 0 = I don't know

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2427240007 2427136288 2427076875 2427012322 2426972792 2426438141 24264083475 4 3 4 5 2

7 4 2 1 5 2

1 4 3 1 2 26 4 2 1 2 2

constant noise from air duct that supply the whole floor MCSI and Benedum; poor workmanship (sound insulation) of the duct itself plus gaps and unsealed duct joints

1 4 5 6 5 6

1 6 4 3 6 3

2 6 5 6 6 4

5 7 4 6 7 4

4 7 3 6 7 5

1 4 5 4 3 4

1 6 5 5 6 4

3 7 5 7 7 2

5 7 1 1 2 2

0 6 3 3 0 3

4 4 5 4 7 4

0 7 1 1 1 4

0 7 7 6 7 4

4 5 6 4 2 4

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RespondentIDWhat is your job title? Response

Other (please specify)

How many hours a week do you spend at MCSI?

Response

In which area of the building is your primary work area located?

Response

Which option best describes your work area?

Response

Other (please specify)

Do you have outside views from your work area while either standing or seated, including windows above eye level?

Response

Which direction does the window face?

Response

Is there a corridor or hallway between your seat and the nearest window?

Response

In my work area, I can personally adjust or control the following. (Check all that apply):

Daylight level i.e., with window blinds or shades

Electric light level, i.e., with a switch or dimmerAir supply temperature i.e., with a thermostatAir supply volume and/or direction i.e., with an adjustable vent

None of the aboveOther

During warmer weather, I am satisfied with the temperature in my work area.

During cooler weather, I am satisfied with the temperature in my work area.

I am generally satisfied with the temperature in my work area.During warmer weather, I believe the air is too humid in my work area.

During cooler weather, I believe the air is too dry in my work area.I am generally satisfied with the humidity in my work area.During warmer weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

During cooler weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

I am generally satisfied with the air flow speed (not too drafty or too stagnant) in my work area.Recalling the previous questions related to temperature, humidity, and air flow speed, I am generally satisfied with the thermal comfort in my work area.I believe the air in my work area is not stuffy or stale.I believe the air in my work area is clean.I believe the air in my work area is generally free from odors.Recalling the previous questions related to stuffiness/staleness, cleanliness and odor, I am generally satisfied with the air quality in my work area.What type of lighting is provided at your work area? (Check all that apply.)

Daylighting (sunlight entering the building through windows, glass roof, or glass doors)Overhead lighting (lighting provided by the fixtures on the ceiling or on the walls)Task lighting (lighting provided by personal fixtures at one's work area, such as desk lights)Other (please specify)

My work area is too bright.My work area is too dark.There is an adequate amount of daylight in my area (leave blank if none).There is an adequate amount of electric light in my area.There is a problem with glare, reflections or contrast in my work area.Recalling the previous questions related to lighting and daylighting, I am generally satisfied with the lighting quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2425689242 2425258234 2425246112 2425204363 2425191480 2425175758 2425022099Undergraduate student

Graduate student Graduate student Graduate student Graduate student Graduate student

research associate

10-20 >40 30-40 30-40 20-30 30-40 30-40

3rd floor MCSI wing (grad student space)

3rd floor MCSI wing (grad student space)

3rd floor MCSI wing (grad student space)

3rd floor MCSI wing (grad student space)

3rd floor MCSI wing (grad student space)

3rd floor MCSI wing (grad student space)

2nd floor Benedum Hall - Wet Lab

Open office with partitions

Open office with partitions

Open office with partitions

Open office with partitions

Open office with partitions

Open office with partitions

Other (please specify)Open laboratory space

Yes Yes Yes Yes No Yes No

North (O’Hara Street)

North (O’Hara Street)

North (O’Hara Street)

North (O’Hara Street)

North (O’Hara Street)

No Yes No No No No No

x x x x x

x x x x

2 6 5 3 5 4 1

2 5 6 3 5 3 5

2 6 6 4 5 3 3

3 3 1 3 2 2 4

3 6 2 3 2 2 2

5 3 6 3 6 6 4

5 5 6 5 4 3 5

5 5 6 6 4 3 5

5 5 6 6 4 3 5

3 6 7 4 5 3 3

6 6 7 5 5 6 6

6 6 7 6 5 6 5

6 6 7 5 5 6 5

6 6 7 5 5 6 5

x x x x x x

x x x x x x x

x x

2 5 3 2 1 2 33 3 3 2 4 2 55 6 7 6 2 6 5

5 5 7 6 6 6 5

1 7 3 3 5 6 1

5 5 7 6 3 6 4

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Table 19 (Continued)
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163

RespondentIDMy work area is too loud due to other people’s conversations.My work area is too loud due to background noise other than conversations (e.g. mechanical equipment, outdoor noises).My work area is too quiet.There is a problem with acoustics in my work area other than generally too loud or too quiet.

If you agree, please explain:

Recalling the previous questions related to acoustics, I am generally satisfied with the acoustical quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

How does the thermal comfort (remember, this includes temperature, humidity and airspeed) in your work area affect your productivity?

How does the air quality (remember, this includes stuffiness/staleness, cleanliness and odors) in your work area affect your productivity?

How does the lighting quality (remember, this includes both daylighting and artifical - both overhead, and task-based) in your work area affect your productivity?How does the outdoor view, or lack of an outdoor view, in your work area affect your productivity?How does the acoustical quality or noise level in your work area affect your productivity?Recalling the previous questions related to indoor environmental quality (including thermal comfort, air quality, lighting and acoustics), how does the overall indoor environmental quality in your work area affect your productivity?How do you think increasing the temperature in your work area by several degrees in warmer weather would affect your productivity?

How do you think decreasing the temperature in your work area by several degrees in cooler weather would affect your productivity?How do you think decreasing the ventilation in your work area would affect your productivity? How do you think including operable windows in your work area would affect your productivity?

How do you think decreasing the amount of daylighting in your work area would affect your productivity?

How do you think increasing the amount of daylighting in your work area would affect your productivity?

How do you think automatically turning off overhead lighting in your work area when there is sufficient daylight would affect your productivity?

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive effect

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive

effect; 0 = I don't know

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2425689242 2425258234 2425246112 2425204363 2425191480 2425175758 24250220993 7 3 3 2 3 3

3 5 4 6 2 6 3

3 2 1 6 5 2 23 4 1 2 2 2 3

6 4 6 5 5 2 5

3 5 4 3 3 3 2

5 6 4 5 5 6 4

5 6 6 7 2 6 4

5 4 6 7 2 5 5

4 4 4 3 4 5 5

4 5 5 5 3 4 4

6 3 4 6 3 4 1

1 5 4 2 1 2 1

4 4 5 3 4 5 1

4 4 5 4 6 1

3 3 2 3 2 2 1

4 3 3 4 7 5 5

3 4 4 4 0 4 4

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Table 19 (Continued)
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RespondentIDWhat is your job title? Response

Other (please specify)

How many hours a week do you spend at MCSI?

Response

In which area of the building is your primary work area located?

Response

Which option best describes your work area?

Response

Other (please specify)

Do you have outside views from your work area while either standing or seated, including windows above eye level?

Response

Which direction does the window face?

Response

Is there a corridor or hallway between your seat and the nearest window?

Response

In my work area, I can personally adjust or control the following. (Check all that apply):

Daylight level i.e., with window blinds or shades

Electric light level, i.e., with a switch or dimmerAir supply temperature i.e., with a thermostatAir supply volume and/or direction i.e., with an adjustable vent

None of the aboveOther

During warmer weather, I am satisfied with the temperature in my work area.

During cooler weather, I am satisfied with the temperature in my work area.

I am generally satisfied with the temperature in my work area.During warmer weather, I believe the air is too humid in my work area.

During cooler weather, I believe the air is too dry in my work area.I am generally satisfied with the humidity in my work area.During warmer weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

During cooler weather, I am satisfied with the air flow speed (not too drafty or too stagnant) in my work area.

I am generally satisfied with the air flow speed (not too drafty or too stagnant) in my work area.Recalling the previous questions related to temperature, humidity, and air flow speed, I am generally satisfied with the thermal comfort in my work area.I believe the air in my work area is not stuffy or stale.I believe the air in my work area is clean.I believe the air in my work area is generally free from odors.Recalling the previous questions related to stuffiness/staleness, cleanliness and odor, I am generally satisfied with the air quality in my work area.What type of lighting is provided at your work area? (Check all that apply.)

Daylighting (sunlight entering the building through windows, glass roof, or glass doors)Overhead lighting (lighting provided by the fixtures on the ceiling or on the walls)Task lighting (lighting provided by personal fixtures at one's work area, such as desk lights)Other (please specify)

My work area is too bright.My work area is too dark.There is an adequate amount of daylight in my area (leave blank if none).There is an adequate amount of electric light in my area.There is a problem with glare, reflections or contrast in my work area.Recalling the previous questions related to lighting and daylighting, I am generally satisfied with the lighting quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2424969194 2424967816 2424902461 2424885322 2424821753 2424790460 2424784869Graduate student Postdoctoral

researcherGraduate student Faculty Graduate student Faculty Faculty

30-40 >40 20-30 >40 20-30 >40 >40

2nd floor Benedum Hall - Wet Lab

3rd floor MCSI wing (grad student space)

3rd floor MCSI wing (grad student space)

3rd floor MCSI wing (grad student space)

2nd floor MCSI wing (grad student space or dry lab)

2nd floor Benedum Hall - East offices (facing plaza & Thackeray Street)

First floor MCSI wing (Mascaro suite)

Open office with partitions

Open office with partitions

Open office with partitions

Open office with partitions

Open office with partitions

Private office Private office

Yes Yes Yes Yes Yes Yes Yes

South (Fifth Avenue)

North (O’Hara Street)

North (O’Hara Street)

East (Thackeray Street)

North (O’Hara Street)

East (Thackeray Street)

North (O’Hara Street)

No No No Yes No No No

x x x x x

x x x x

x x x

x

4 5 7 2 3 3 6

4 5 7 4 2 1 5

4 5 7 3 2 2 6

2 3 7 4 1 4 2

3 5 7 4 5 4 6

4 4 4 6 4 4

4 5 7 2 7 4 6

4 5 7 2 6 4 6

4 5 7 2 6 4 6

4 5 7 3 3 2 6

4 6 7 4 7 4 6

4 6 7 4 7 3 6

6 6 7 4 7 3 6

5 6 7 4 7 4 6

x x x x

x x x x x x x

x x

4 2 1 4 1 4 24 2 1 4 1 2 24 7 7 4 5 2 6

5 6 7 4 7 6 6

3 5 5 4 4 1 2

5 6 7 4 5 4 6

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Table 19 (Continued)
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165

RespondentIDMy work area is too loud due to other people’s conversations.My work area is too loud due to background noise other than conversations (e.g. mechanical equipment, outdoor noises).My work area is too quiet.There is a problem with acoustics in my work area other than generally too loud or too quiet.

If you agree, please explain:

Recalling the previous questions related to acoustics, I am generally satisfied with the acoustical quality in my work area.

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

How does the thermal comfort (remember, this includes temperature, humidity and airspeed) in your work area affect your productivity?

How does the air quality (remember, this includes stuffiness/staleness, cleanliness and odors) in your work area affect your productivity?

How does the lighting quality (remember, this includes both daylighting and artifical - both overhead, and task-based) in your work area affect your productivity?How does the outdoor view, or lack of an outdoor view, in your work area affect your productivity?How does the acoustical quality or noise level in your work area affect your productivity?Recalling the previous questions related to indoor environmental quality (including thermal comfort, air quality, lighting and acoustics), how does the overall indoor environmental quality in your work area affect your productivity?How do you think increasing the temperature in your work area by several degrees in warmer weather would affect your productivity?

How do you think decreasing the temperature in your work area by several degrees in cooler weather would affect your productivity?How do you think decreasing the ventilation in your work area would affect your productivity? How do you think including operable windows in your work area would affect your productivity?

How do you think decreasing the amount of daylighting in your work area would affect your productivity?

How do you think increasing the amount of daylighting in your work area would affect your productivity?

How do you think automatically turning off overhead lighting in your work area when there is sufficient daylight would affect your productivity?

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive effect

1 = Strong negative effect; 4 = Neutral; 7 = Strong positive

effect; 0 = I don't know

1 = Strongly disagree; 4 = Neutral; 7 = Strongly agree

2424969194 2424967816 2424902461 2424885322 2424821753 2424790460 24247848696 5 5 4 2 7 5

6 5 1 7 6 5 5

1 1 1 1 1 1 24 1 2 4 1 7 2

too many hard reflective surfaces - entire area echoes

1 3 6 1 3 1 4

4 4 6 4 3 4 4

4 5 6 4 4 4 4

4 5 7 4 4 4 5

2 7 6 4 2 2 5

1 4 2 1 3 2 3

3 5 6 2 3 3 4

5 4 4 7 6 5 2

2 4 1 1 2 1 4

4 4 0 2 0 3 3

6 6 5 4 6 5 7

4 2 1 2 2 1 3

4 6 4 5 5 5 6

4 6 4 1 4 0 4

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Question Number of responses

You should ask what the occupants of the building think of those who designed the building. My opinion of them is strongly negative. The building might be friendly to environment but it is unfriendly, almost hostile to the occupants.

Dimming light switches or automated dimming. Lower air flow rate (?) for less noisy air flow. Warmer temperatures in warm months, usually I am to cold in the office during warm months. During cold months, I am not too warm. I am sometimes still cold, but can add clothing and drink hot beverages. Also, modifying workspace orientation to use daylighting but reduce glare my be helpful.Noise reduction, better thermal control.N/AIt is typically too cold most of the year, though it has been slightly better lately. There is constant white noise from possibly air vents that can be bothersome at times. It may be nice if we were allowed to dim the lights.The cubicles on the right side of the 3rd floor grad space often need electric lighting even though there is enough day lighting present. Theres a wide mismatch between day lighting present in cubicles by the window and those not by the windowThe timer on the motion sensor lighting is wayyy too short. It's very annoying to have to get up everyday when I'm working at my desk and put the lights back on.Auto light shut off in corridors and esp bathrooms is dangerous. In offices it is annoying to wave my arms around every 5 minutes. Sound is horrendous. Smells from Basement food court (burnt bagels) every morning makes me nauseous.Probably make it more scenic. As in put some plants around the building. Looking at concrete doesn't increase productivity for sure.The sensors on the automatic bathroom fixtures seem to be using more water than previous hand fixtures (ie. the toilet flushes multiple times for a single person's use)1. I would prefer to have a control over over my temperature directly in my office. (It is typically very cold in the summer.) 2. The odor of the cooking food from the kitchen downstairs is often way too strong and offensive (especially in the mornings). I often get severe headaches from the strong odors --It does impact my productivity.The kitchen on the basement that dumps strong odour and smoke of burning food. There is no ventilation on the kitchen area, so the second floor smell really bad for hours per day. Temperature difference between office (appr 70F), corridor (appr 60F) and bathroom (sometime 80F) do not create healthy environment. My place do not have temperature control, so I'm at mercy other's lab dwellers.

I wish I could open the windows.

label the switches for the ceiling lights.It often feels too cold in the summer, when people are dressed for warmer weather anyway.

More individual thermostat, lighting and, if possible, window control. Less fan noise and drafts.Turn the temperature up during cooler months. The lighting timing is fine (automatics) - although the lights themselves burn out a lot. I'm not sure if that is the type of light or the contractor used.Too noisy

Response text

Ventilation seems to be fine. I don't mind the room being a bit warmer and "normal" in the summer and a bit "cooler" than normal in the winter, but the problem I have is that the floor heating next to the window doesn't seem to be adequate, so in (very) cold weather the ventilation heating does not compensate for the heat loss through the windows, and the room is cold. Otherwise I'm happy with the conditions and control that i have in the room (the adjustable vent is nice to have).

Do you have any other suggestions for improving the MCSI building? If so, what are they?

It didn't take 30 minutes, that was somewhat misleading to me, so the updated communication was helpful and encouraged me to participate knowing 15-20minutes was a more manageable expectation.

8

23

Do you have any suggestions for improving this survey? If so, what are they? N/A

Discuss cleanliness, elevator malfunctions, bathrooms, water fountains, staircases, open spaces.The MCSI building has a conference rooms at each floor that are not included in survey Would be interesting to see correlation between how green occupants are (their knowledge about green buildings or how important they think energy use is) and how they respond to certain questionssuggestions for common areas for leftover food, cutlery, etc; students in this area are very good about re-distributing, but collection of give-aways has become high with graduating students.

There were no questions regarding raising the temperature in the winter (ie. problem with building being too cold in winter).

better noise insulation between external classroom area and office spaceImprove operation of HVAC system. Check if the level of noise in the office areas are within the safety limits established by OSHA.Provide more non-sky outside views in 2nd floor dry lab workspaces. Reduce vent noise in same area ceiling, which sounds like an rain storm at times.

Too many to list - many aspects of the design have proven to be a dismal failure; not least of which is the net loss of space used to support the school missions when the intent of the renovation scheme was to increase space.

I think having better food preparation and storage areas would improve user eating habits.

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Table 20 - Post-occupancy open-ended questions and responses
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168

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