&a · booklet printing or else double-sided, duplex (2-on-i) a4 printing {both four pages per...

38
Environmental Protection Agency Castlebar Regional Inspectorate Castlebar, Co. Mayo IPC Reg. NO. POO21-02 6th March 20 17 Reference: Response to EPA Monitoring Report SV11966 Please fmd below Masonites response to EPAs monitoring report €or samples taken on the 1 gth January 20 17 at emission point EO 1, Where EPA analysis have identified a parameter above the limit of detection Masonite have included these tests in assimilative calculations for the Shannon, In addition where EQS for freshwater exist the test results have been compared to these to ensure these are not been breached. A copy of this assessment has been included in Appendix A. The EQS have been obtained fkom the SEPA Guidance (WAT-SG-53), Environmental Quality Standards for Discharge to Surface Waters. A copy ofthis document is included in Appendix B. A review of the assimilative capacity calculations shows that the values of the parameters detected are exceptionally low and are contributing less than 3% of any of the freshwater EQS. These calculation results are reflected in the upstream and downstream values €or Chloride for example, which shows no change in concentration as a result of the discharge fiom EO I. Regards, /&A Brian Mallon Environmental Compliance Manager Masonite Ireland Dmrnsna, Carrick on Shannon, Co. Leitrim, Republic of ireland * Phone: 4-353 71 9659500 * Fax: +353 71 9659508 Directors: J. Kingry (U.S.A.); C. Kearns (Irish) www.rnaeonite-europe.com Registered in ireiand No. 229654/V.A.T. No. lE8229654U Registered Office: 6 Fitzwilliam Square, Dubljn 2 For inspection purposes only. Consent of copyright owner required for any other use. EPA Export 29-04-2017:03:18:36

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Page 1: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Environmental Protection Agency Castlebar Regional Inspectorate Castlebar Co Mayo

IPC Reg NO POO21-02

6th March 20 17

Reference Response to EPA Monitoring Report SV11966

Please fmd below Masonites response to EPAs monitoring report euroor samples taken on the 1 gth January 20 17 at emission point EO 1

Where EPA analysis have identified a parameter above the limit of detection Masonite have included these tests in assimilative calculations for the Shannon In addition where EQS for freshwater exist the test results have been compared to these to ensure these are not been breached

A copy of this assessment has been included in Appendix A The EQS have been obtained fkom the SEPA Guidance (WAT-SG-53) Environmental Quality Standards for Discharge to Surface Waters A copy ofthis document is included in Appendix B

A review of the assimilative capacity calculations shows that the values of the parameters detected are exceptionally low and are contributing less than 3 of any of the freshwater EQS

These calculation results are reflected in the upstream and downstream values euroor Chloride for example which shows no change in concentration as a result of the discharge fiom EO I

Regards

ampA Brian Mallon Environmental Compliance Manager

Masonite Ireland Dmrnsna Carrick on Shannon Co Leitrim Republic of ireland Phone 4-353 71 9659500 Fax +353 71 9659508

Directors J Kingry (USA) C Kearns (Irish)

wwwrnaeonite-europecom

Registered in ireiand No 229654VAT No lE8229654U Registered Office 6 Fitzwilliam Square Dubljn 2

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APPENDIX A

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EPA Export 29-04-2017031836

Table I I Shannon Assimilative Capacitv Bsed an euro01 Flow and EPA Test Results and euroPA Upstream Test ResuIts

Masonite Flow Limit (rn3day) 1200 Shannon 95 Flow at Masonite (m3day) Assi m i I ative Capacity

198720 1666

A Parameter

Chloride Aluminium An ti m o ny

Barium Boron

Cadmium Calcium Copper

Magnesium Potassium S t ro n ti u m Vanadium

Zinc

EPA Test ResuIt Assimilative Value U pstrearn Downstream Impact AA MAC Masonite ( U m (ugl) Ave (ugI) (ugI) (ugl) (ug4 Contribution

653000 391 96 142 3934 250000 NA 2 62 0372 0 0372 15 25 7 17 001 0 0 001 0 NA NA NA 110 0660 0 07 NA NA NA 340 20 0 20 2000 NA 010 002 000012 U 000012 008 05 003

11 0000 660 0 660 NA NA NA -

I 8 001 1 0 001 I NA 1 25000 150 0 150 NA NA NA 46000 276 0 276 NA NA NA 6300 38 0 38 NA NA NA I 5 0009 0 001 20 NA 005 48 0029 0 003 119 NA 024

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EPA Export 29-04-2017031836

APPENDIX B

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EPA Export 29-04-2017031836

E Scottish Enviroti tilent

Prutectian Agency

Water Use

S u p port i ng G U id a nce (WATwS G -53) Environmental Quality Standards and Standards for Discharges to Surface Waters

t

Version v6

Released Dec 2015

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EPA Export 29-04-2017031836

Copyright63 20d5 Scottish Environment Protection Agency (SEPA) All rights reserved No part of this document may be reproduced in any form or by any means electronic or mechanical including (but not limited to) photocopying recording or using any information storage and retrieval systems without the express permission in writing of SEPA

Disclaimer Whilst every effort has been made to ensure the accuracy of this document SEPA cannot accept and hereby expressly excludes all or any liability and gives no warranty covenant or undertaking (whether express or implied) in respect of the fitness for purpose ofb or any error omission or discrepancy in this document and reliance on contents hereof is entireEy at the users own risk

Registered Tradam arks All registered trademarks used in this document are used for reference purpose only Other brand and product names maybe registered tradernarks or trademarks of their respective holders

Update Summary

Version

vi0

V20

1130

V31

v40

v5 I

V 6

DescriDtion First issue for Water Use based on following UKTAG Reports

UK Environmenfal Standards and Conditions (Phase f amp 2) Proposals far Groundwater Classification System Proposals for Environrnenfal Qualjty Standards for Annex Vfll Substances

New base template applied links to docs revised for new SEPA website Nov 2008

Revised to reflect The Scoflaand River Basin Dfsfrlcf (Sudace Water Typology Environmental Standards Condition limits and Groundwater Threshold Values) Directions 2009 Non-Statutory Standards also added

Minor corrections toTable 1 Status amp Table 4 units

Expired CMS links reviewed and updated

Revised to reflect the Standards Direcfions 2024

Revised to reflect the Standards Direclions 2015 amp including Nav 2015 updates to Tables 34 5 amp 7

Notes References Linked references to other documents have been disabled in this web version of the document See the References section for details of all referenced documents

Printing the Document This document is uncontrolled if printed and is only intended fo be viewed online If you do need to print he document the best results are achieved using Booklet printing or else double-sided Duplex (2-on-I) A4 printing both four pages per A4

Always refer to the onllne document for accurate and up-to-date information sheel)

2 of 34 Uncontrofled if printed v6 Dec 201 5

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EPA Export 29-04-2017031836

A Key Points 4 2 Typolagy-specifie Einvi~onmental Quality Standards 5 3 Environmental Quality Standards for Surfgce Waters 6

Priority Substances d i 6

32 Speclfrc F d k h n t s 6

Substances under the repealed Dangerous Substances Directive 7

34 Non-statutory EQS 7

31 +

33

4 Operational Aquaculture Standards If 8

Annex 1 GIS Layer 9

Annex 2 List of Tables 10

References 33

v6 Dec 2015 Uncontrolled if printed 3 of34

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EPA Export 29-04-2017031836

The purpose of this guidance is to provide information on and access to the environmental and discharge standards for surface waters The standards are based on the latest scientific understanding of the UK Technioal Advisory Group (UKTAG) for the Water Framework Directive (WFD) The surfa~e water standards are available in the Standards Directions 2015 as follows

Water Quality Standards - Rivers and Lochs Schedule 2 Part CI Section I amp 2

H Water Quality Standards - Coastal and Transitional Waters Schedule 2 Part

BI Groundwater threshold values4 Schedule 6

c Section 3

Section 2 of this guidanee describes how to access typology-specific standards Section 3 of this guidance provides the numerical environmental standards for surface waters Section 4 of this guidance provides the numerical operational standards for aquaculture discharges

A separate S P A guidance note provides information on morphology standards WAT- SG-2 7 Envimnmsnfat Standards for River Morphology

These standards are only to be used in classifying groundwafer bodies and should not be used for the regulation of point source discharges into groundwater This is because the Water Framework Directive sets an additional objective fot groundwater that to prevent and limit the input of pollutants into groundwater This objective protects all groundwater from pollution and is assessed at a local scale whereas status mainly deals with large scale pressures on groundwater bodies Therefore under fhe Water Framework Directlve it is possible to have local pollution in a groundwater body of gopd chemical status The requirements to prevent or limit complement those for status Notwithstanding the time needed to enable the historicat legacy Qf releases to degrade or disperse if all the prevenf or limit requirements were met everywhere within a groundwater body if would be at good chemical status Because of this the prevent and limit objective will drive regulation of point source discharges to groundwater

4 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Some of the environmental standards are dependent on the type of surface water such as its altitude alkalinity and conceritration of dissolved organic carbon (DOG) The parameters requiring reference to the surface water typology include

W Dissolved oxygen (DO) stmdards for rivers (and in relation to short-term and

rn Dissolved oxygen standards for freshwater lochs

intermittent changes to DO)

Biochemical oxygen demand OD) standards for rivers (and in relation to short-term and intermittent changes to BOD)

BAmrnorija standards for rivers (induding standards for short-term and intermittent changes in ammonia Concentration)

H pH and acid neutralising capacity ANC) in rivers

For rivers the standards which require reference to the typology of the river are found on SEFAs GIs Pages (with t he exception of pH and ANC found in WAT-SG-53-TI Refer to Annex I for instructions on how to access the standards in GIs

WAT-SE53-T2 contains the fundarnenial intermittent and short term (99th percentile) standards for DO Bob a8d Ammonia These account for short term and intermittent discharges that can occur in wet weather Phosphorus (PI standards for rivers are no longer type-specific they are now location specific Phosphorus standards should be determined by staff using the Alkalinify Mapping Tool from the ESIU informatics hub and altitude for the site in question available from the GIS Idranet interactive map

v6 Dec 2015 Uncontrolled if printed 5 of 34

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EPA Export 29-04-2017031836

The WFD requires environmental quality standards (EQS) for polluting substances If these standards are exceeded they could result in adverse effects to ecosystems The following tables provide details of statutory and non-statutory substances For reference purposes the full list of substances that SEPA is required to take account of is found in WA T-SG-53- T3

3i Priority Substances The WFD priority substances list is a group of substances shown to be of major concern for European Waters due to their toxicity bio-accumulating properties andlor persistence in the environment SEPA is required to take account of these substances when assessing risks to the water environment classifying the status of water bodies and controlling discharges The tist of WFD priority substances is found in WAT-SG-53-7il This list includes Priority Hazardous Substances (PHS) and Other Pollutanfs (for which a European standard applies)

32 Specific Pollutants Specific Pollutants are substances that may have a harmful effect on biological quality and which have be jdentified by UKTAG as being discharged to the water environment in significant quantities in the UK The list of Specific Pollutants SEPA is required to take account of is found in WAT-SG-53-T5

321 Appticatiort of Marine Copper Standards I Note The poiicy guidance for apptication of marine copper standards is still under development and should be regarded as draft guidance Please contact the national water unit if you are dealing with an application that includes a condition for marine copper Ernail DL- WaterRegSuppsepa o q uk

The standards for freshwater and marine copper standards are listed in WAT-SG-53-75 for Specific Pollutants The marine copper standards are designed to take account of the effect of dissolved organic carbon (POC) on the availabjlity of copper to aquatic biota In high DOC environments copper is less bioavailable and the standard is adjusted accordingly In the absence of inforfiation on environmental background DOC (BDOC) andor discharge derived DOC (DDOC) an EQS of 509pgA will be applied (376ygA if Imown DOCS j)

Shotlld applicants intend to determine an adjusted site-specific EQS for the receiving water they must provide appropriate BDOC or DDOC data to SEPA Far BOOC the annual mean concentration of DOC for the receiving water is required For DDOC typical discharge concentrafttians for that sector will be required This data will be developed over time in consuitation with SEPA sector leads Sector DDOC data should meet the fallowing criteria

HA minimum of one years supply of data

8 of34 Unconfrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031836

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

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ectio

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pose

s only

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nt of

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

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ectio

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

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ectio

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

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ectio

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

For

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

For

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

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s only

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

For

insp

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 2: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

APPENDIX A

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EPA Export 29-04-2017031836

Table I I Shannon Assimilative Capacitv Bsed an euro01 Flow and EPA Test Results and euroPA Upstream Test ResuIts

Masonite Flow Limit (rn3day) 1200 Shannon 95 Flow at Masonite (m3day) Assi m i I ative Capacity

198720 1666

A Parameter

Chloride Aluminium An ti m o ny

Barium Boron

Cadmium Calcium Copper

Magnesium Potassium S t ro n ti u m Vanadium

Zinc

EPA Test ResuIt Assimilative Value U pstrearn Downstream Impact AA MAC Masonite ( U m (ugl) Ave (ugI) (ugI) (ugl) (ug4 Contribution

653000 391 96 142 3934 250000 NA 2 62 0372 0 0372 15 25 7 17 001 0 0 001 0 NA NA NA 110 0660 0 07 NA NA NA 340 20 0 20 2000 NA 010 002 000012 U 000012 008 05 003

11 0000 660 0 660 NA NA NA -

I 8 001 1 0 001 I NA 1 25000 150 0 150 NA NA NA 46000 276 0 276 NA NA NA 6300 38 0 38 NA NA NA I 5 0009 0 001 20 NA 005 48 0029 0 003 119 NA 024

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EPA Export 29-04-2017031836

APPENDIX B

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EPA Export 29-04-2017031836

E Scottish Enviroti tilent

Prutectian Agency

Water Use

S u p port i ng G U id a nce (WATwS G -53) Environmental Quality Standards and Standards for Discharges to Surface Waters

t

Version v6

Released Dec 2015

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EPA Export 29-04-2017031836

Copyright63 20d5 Scottish Environment Protection Agency (SEPA) All rights reserved No part of this document may be reproduced in any form or by any means electronic or mechanical including (but not limited to) photocopying recording or using any information storage and retrieval systems without the express permission in writing of SEPA

Disclaimer Whilst every effort has been made to ensure the accuracy of this document SEPA cannot accept and hereby expressly excludes all or any liability and gives no warranty covenant or undertaking (whether express or implied) in respect of the fitness for purpose ofb or any error omission or discrepancy in this document and reliance on contents hereof is entireEy at the users own risk

Registered Tradam arks All registered trademarks used in this document are used for reference purpose only Other brand and product names maybe registered tradernarks or trademarks of their respective holders

Update Summary

Version

vi0

V20

1130

V31

v40

v5 I

V 6

DescriDtion First issue for Water Use based on following UKTAG Reports

UK Environmenfal Standards and Conditions (Phase f amp 2) Proposals far Groundwater Classification System Proposals for Environrnenfal Qualjty Standards for Annex Vfll Substances

New base template applied links to docs revised for new SEPA website Nov 2008

Revised to reflect The Scoflaand River Basin Dfsfrlcf (Sudace Water Typology Environmental Standards Condition limits and Groundwater Threshold Values) Directions 2009 Non-Statutory Standards also added

Minor corrections toTable 1 Status amp Table 4 units

Expired CMS links reviewed and updated

Revised to reflect the Standards Direcfions 2024

Revised to reflect the Standards Direclions 2015 amp including Nav 2015 updates to Tables 34 5 amp 7

Notes References Linked references to other documents have been disabled in this web version of the document See the References section for details of all referenced documents

Printing the Document This document is uncontrolled if printed and is only intended fo be viewed online If you do need to print he document the best results are achieved using Booklet printing or else double-sided Duplex (2-on-I) A4 printing both four pages per A4

Always refer to the onllne document for accurate and up-to-date information sheel)

2 of 34 Uncontrofled if printed v6 Dec 201 5

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EPA Export 29-04-2017031836

A Key Points 4 2 Typolagy-specifie Einvi~onmental Quality Standards 5 3 Environmental Quality Standards for Surfgce Waters 6

Priority Substances d i 6

32 Speclfrc F d k h n t s 6

Substances under the repealed Dangerous Substances Directive 7

34 Non-statutory EQS 7

31 +

33

4 Operational Aquaculture Standards If 8

Annex 1 GIS Layer 9

Annex 2 List of Tables 10

References 33

v6 Dec 2015 Uncontrolled if printed 3 of34

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EPA Export 29-04-2017031836

The purpose of this guidance is to provide information on and access to the environmental and discharge standards for surface waters The standards are based on the latest scientific understanding of the UK Technioal Advisory Group (UKTAG) for the Water Framework Directive (WFD) The surfa~e water standards are available in the Standards Directions 2015 as follows

Water Quality Standards - Rivers and Lochs Schedule 2 Part CI Section I amp 2

H Water Quality Standards - Coastal and Transitional Waters Schedule 2 Part

BI Groundwater threshold values4 Schedule 6

c Section 3

Section 2 of this guidanee describes how to access typology-specific standards Section 3 of this guidance provides the numerical environmental standards for surface waters Section 4 of this guidance provides the numerical operational standards for aquaculture discharges

A separate S P A guidance note provides information on morphology standards WAT- SG-2 7 Envimnmsnfat Standards for River Morphology

These standards are only to be used in classifying groundwafer bodies and should not be used for the regulation of point source discharges into groundwater This is because the Water Framework Directive sets an additional objective fot groundwater that to prevent and limit the input of pollutants into groundwater This objective protects all groundwater from pollution and is assessed at a local scale whereas status mainly deals with large scale pressures on groundwater bodies Therefore under fhe Water Framework Directlve it is possible to have local pollution in a groundwater body of gopd chemical status The requirements to prevent or limit complement those for status Notwithstanding the time needed to enable the historicat legacy Qf releases to degrade or disperse if all the prevenf or limit requirements were met everywhere within a groundwater body if would be at good chemical status Because of this the prevent and limit objective will drive regulation of point source discharges to groundwater

4 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Some of the environmental standards are dependent on the type of surface water such as its altitude alkalinity and conceritration of dissolved organic carbon (DOG) The parameters requiring reference to the surface water typology include

W Dissolved oxygen (DO) stmdards for rivers (and in relation to short-term and

rn Dissolved oxygen standards for freshwater lochs

intermittent changes to DO)

Biochemical oxygen demand OD) standards for rivers (and in relation to short-term and intermittent changes to BOD)

BAmrnorija standards for rivers (induding standards for short-term and intermittent changes in ammonia Concentration)

H pH and acid neutralising capacity ANC) in rivers

For rivers the standards which require reference to the typology of the river are found on SEFAs GIs Pages (with t he exception of pH and ANC found in WAT-SG-53-TI Refer to Annex I for instructions on how to access the standards in GIs

WAT-SE53-T2 contains the fundarnenial intermittent and short term (99th percentile) standards for DO Bob a8d Ammonia These account for short term and intermittent discharges that can occur in wet weather Phosphorus (PI standards for rivers are no longer type-specific they are now location specific Phosphorus standards should be determined by staff using the Alkalinify Mapping Tool from the ESIU informatics hub and altitude for the site in question available from the GIS Idranet interactive map

v6 Dec 2015 Uncontrolled if printed 5 of 34

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EPA Export 29-04-2017031836

The WFD requires environmental quality standards (EQS) for polluting substances If these standards are exceeded they could result in adverse effects to ecosystems The following tables provide details of statutory and non-statutory substances For reference purposes the full list of substances that SEPA is required to take account of is found in WA T-SG-53- T3

3i Priority Substances The WFD priority substances list is a group of substances shown to be of major concern for European Waters due to their toxicity bio-accumulating properties andlor persistence in the environment SEPA is required to take account of these substances when assessing risks to the water environment classifying the status of water bodies and controlling discharges The tist of WFD priority substances is found in WAT-SG-53-7il This list includes Priority Hazardous Substances (PHS) and Other Pollutanfs (for which a European standard applies)

32 Specific Pollutants Specific Pollutants are substances that may have a harmful effect on biological quality and which have be jdentified by UKTAG as being discharged to the water environment in significant quantities in the UK The list of Specific Pollutants SEPA is required to take account of is found in WAT-SG-53-T5

321 Appticatiort of Marine Copper Standards I Note The poiicy guidance for apptication of marine copper standards is still under development and should be regarded as draft guidance Please contact the national water unit if you are dealing with an application that includes a condition for marine copper Ernail DL- WaterRegSuppsepa o q uk

The standards for freshwater and marine copper standards are listed in WAT-SG-53-75 for Specific Pollutants The marine copper standards are designed to take account of the effect of dissolved organic carbon (POC) on the availabjlity of copper to aquatic biota In high DOC environments copper is less bioavailable and the standard is adjusted accordingly In the absence of inforfiation on environmental background DOC (BDOC) andor discharge derived DOC (DDOC) an EQS of 509pgA will be applied (376ygA if Imown DOCS j)

Shotlld applicants intend to determine an adjusted site-specific EQS for the receiving water they must provide appropriate BDOC or DDOC data to SEPA Far BOOC the annual mean concentration of DOC for the receiving water is required For DDOC typical discharge concentrafttians for that sector will be required This data will be developed over time in consuitation with SEPA sector leads Sector DDOC data should meet the fallowing criteria

HA minimum of one years supply of data

8 of34 Unconfrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031836

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

n pur

pose

s only

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nt of

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

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ectio

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pose

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

insp

ectio

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pose

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se

EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

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ectio

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pose

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nt of

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

n pur

pose

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

For

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 3: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Table I I Shannon Assimilative Capacitv Bsed an euro01 Flow and EPA Test Results and euroPA Upstream Test ResuIts

Masonite Flow Limit (rn3day) 1200 Shannon 95 Flow at Masonite (m3day) Assi m i I ative Capacity

198720 1666

A Parameter

Chloride Aluminium An ti m o ny

Barium Boron

Cadmium Calcium Copper

Magnesium Potassium S t ro n ti u m Vanadium

Zinc

EPA Test ResuIt Assimilative Value U pstrearn Downstream Impact AA MAC Masonite ( U m (ugl) Ave (ugI) (ugI) (ugl) (ug4 Contribution

653000 391 96 142 3934 250000 NA 2 62 0372 0 0372 15 25 7 17 001 0 0 001 0 NA NA NA 110 0660 0 07 NA NA NA 340 20 0 20 2000 NA 010 002 000012 U 000012 008 05 003

11 0000 660 0 660 NA NA NA -

I 8 001 1 0 001 I NA 1 25000 150 0 150 NA NA NA 46000 276 0 276 NA NA NA 6300 38 0 38 NA NA NA I 5 0009 0 001 20 NA 005 48 0029 0 003 119 NA 024

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EPA Export 29-04-2017031836

APPENDIX B

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EPA Export 29-04-2017031836

E Scottish Enviroti tilent

Prutectian Agency

Water Use

S u p port i ng G U id a nce (WATwS G -53) Environmental Quality Standards and Standards for Discharges to Surface Waters

t

Version v6

Released Dec 2015

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EPA Export 29-04-2017031836

Copyright63 20d5 Scottish Environment Protection Agency (SEPA) All rights reserved No part of this document may be reproduced in any form or by any means electronic or mechanical including (but not limited to) photocopying recording or using any information storage and retrieval systems without the express permission in writing of SEPA

Disclaimer Whilst every effort has been made to ensure the accuracy of this document SEPA cannot accept and hereby expressly excludes all or any liability and gives no warranty covenant or undertaking (whether express or implied) in respect of the fitness for purpose ofb or any error omission or discrepancy in this document and reliance on contents hereof is entireEy at the users own risk

Registered Tradam arks All registered trademarks used in this document are used for reference purpose only Other brand and product names maybe registered tradernarks or trademarks of their respective holders

Update Summary

Version

vi0

V20

1130

V31

v40

v5 I

V 6

DescriDtion First issue for Water Use based on following UKTAG Reports

UK Environmenfal Standards and Conditions (Phase f amp 2) Proposals far Groundwater Classification System Proposals for Environrnenfal Qualjty Standards for Annex Vfll Substances

New base template applied links to docs revised for new SEPA website Nov 2008

Revised to reflect The Scoflaand River Basin Dfsfrlcf (Sudace Water Typology Environmental Standards Condition limits and Groundwater Threshold Values) Directions 2009 Non-Statutory Standards also added

Minor corrections toTable 1 Status amp Table 4 units

Expired CMS links reviewed and updated

Revised to reflect the Standards Direcfions 2024

Revised to reflect the Standards Direclions 2015 amp including Nav 2015 updates to Tables 34 5 amp 7

Notes References Linked references to other documents have been disabled in this web version of the document See the References section for details of all referenced documents

Printing the Document This document is uncontrolled if printed and is only intended fo be viewed online If you do need to print he document the best results are achieved using Booklet printing or else double-sided Duplex (2-on-I) A4 printing both four pages per A4

Always refer to the onllne document for accurate and up-to-date information sheel)

2 of 34 Uncontrofled if printed v6 Dec 201 5

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EPA Export 29-04-2017031836

A Key Points 4 2 Typolagy-specifie Einvi~onmental Quality Standards 5 3 Environmental Quality Standards for Surfgce Waters 6

Priority Substances d i 6

32 Speclfrc F d k h n t s 6

Substances under the repealed Dangerous Substances Directive 7

34 Non-statutory EQS 7

31 +

33

4 Operational Aquaculture Standards If 8

Annex 1 GIS Layer 9

Annex 2 List of Tables 10

References 33

v6 Dec 2015 Uncontrolled if printed 3 of34

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EPA Export 29-04-2017031836

The purpose of this guidance is to provide information on and access to the environmental and discharge standards for surface waters The standards are based on the latest scientific understanding of the UK Technioal Advisory Group (UKTAG) for the Water Framework Directive (WFD) The surfa~e water standards are available in the Standards Directions 2015 as follows

Water Quality Standards - Rivers and Lochs Schedule 2 Part CI Section I amp 2

H Water Quality Standards - Coastal and Transitional Waters Schedule 2 Part

BI Groundwater threshold values4 Schedule 6

c Section 3

Section 2 of this guidanee describes how to access typology-specific standards Section 3 of this guidance provides the numerical environmental standards for surface waters Section 4 of this guidance provides the numerical operational standards for aquaculture discharges

A separate S P A guidance note provides information on morphology standards WAT- SG-2 7 Envimnmsnfat Standards for River Morphology

These standards are only to be used in classifying groundwafer bodies and should not be used for the regulation of point source discharges into groundwater This is because the Water Framework Directive sets an additional objective fot groundwater that to prevent and limit the input of pollutants into groundwater This objective protects all groundwater from pollution and is assessed at a local scale whereas status mainly deals with large scale pressures on groundwater bodies Therefore under fhe Water Framework Directlve it is possible to have local pollution in a groundwater body of gopd chemical status The requirements to prevent or limit complement those for status Notwithstanding the time needed to enable the historicat legacy Qf releases to degrade or disperse if all the prevenf or limit requirements were met everywhere within a groundwater body if would be at good chemical status Because of this the prevent and limit objective will drive regulation of point source discharges to groundwater

4 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Some of the environmental standards are dependent on the type of surface water such as its altitude alkalinity and conceritration of dissolved organic carbon (DOG) The parameters requiring reference to the surface water typology include

W Dissolved oxygen (DO) stmdards for rivers (and in relation to short-term and

rn Dissolved oxygen standards for freshwater lochs

intermittent changes to DO)

Biochemical oxygen demand OD) standards for rivers (and in relation to short-term and intermittent changes to BOD)

BAmrnorija standards for rivers (induding standards for short-term and intermittent changes in ammonia Concentration)

H pH and acid neutralising capacity ANC) in rivers

For rivers the standards which require reference to the typology of the river are found on SEFAs GIs Pages (with t he exception of pH and ANC found in WAT-SG-53-TI Refer to Annex I for instructions on how to access the standards in GIs

WAT-SE53-T2 contains the fundarnenial intermittent and short term (99th percentile) standards for DO Bob a8d Ammonia These account for short term and intermittent discharges that can occur in wet weather Phosphorus (PI standards for rivers are no longer type-specific they are now location specific Phosphorus standards should be determined by staff using the Alkalinify Mapping Tool from the ESIU informatics hub and altitude for the site in question available from the GIS Idranet interactive map

v6 Dec 2015 Uncontrolled if printed 5 of 34

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EPA Export 29-04-2017031836

The WFD requires environmental quality standards (EQS) for polluting substances If these standards are exceeded they could result in adverse effects to ecosystems The following tables provide details of statutory and non-statutory substances For reference purposes the full list of substances that SEPA is required to take account of is found in WA T-SG-53- T3

3i Priority Substances The WFD priority substances list is a group of substances shown to be of major concern for European Waters due to their toxicity bio-accumulating properties andlor persistence in the environment SEPA is required to take account of these substances when assessing risks to the water environment classifying the status of water bodies and controlling discharges The tist of WFD priority substances is found in WAT-SG-53-7il This list includes Priority Hazardous Substances (PHS) and Other Pollutanfs (for which a European standard applies)

32 Specific Pollutants Specific Pollutants are substances that may have a harmful effect on biological quality and which have be jdentified by UKTAG as being discharged to the water environment in significant quantities in the UK The list of Specific Pollutants SEPA is required to take account of is found in WAT-SG-53-T5

321 Appticatiort of Marine Copper Standards I Note The poiicy guidance for apptication of marine copper standards is still under development and should be regarded as draft guidance Please contact the national water unit if you are dealing with an application that includes a condition for marine copper Ernail DL- WaterRegSuppsepa o q uk

The standards for freshwater and marine copper standards are listed in WAT-SG-53-75 for Specific Pollutants The marine copper standards are designed to take account of the effect of dissolved organic carbon (POC) on the availabjlity of copper to aquatic biota In high DOC environments copper is less bioavailable and the standard is adjusted accordingly In the absence of inforfiation on environmental background DOC (BDOC) andor discharge derived DOC (DDOC) an EQS of 509pgA will be applied (376ygA if Imown DOCS j)

Shotlld applicants intend to determine an adjusted site-specific EQS for the receiving water they must provide appropriate BDOC or DDOC data to SEPA Far BOOC the annual mean concentration of DOC for the receiving water is required For DDOC typical discharge concentrafttians for that sector will be required This data will be developed over time in consuitation with SEPA sector leads Sector DDOC data should meet the fallowing criteria

HA minimum of one years supply of data

8 of34 Unconfrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031836

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

insp

ectio

n pur

pose

s only

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nt of

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uired

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se

EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

n pur

pose

s only

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nt of

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uired

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se

EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

insp

ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

insp

ectio

n pur

pose

s only

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nt of

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uired

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se

EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

insp

ectio

n pur

pose

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nt of

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uired

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se

EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

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pose

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

n pur

pose

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nt of

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

For

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

For

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 4: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

APPENDIX B

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EPA Export 29-04-2017031836

E Scottish Enviroti tilent

Prutectian Agency

Water Use

S u p port i ng G U id a nce (WATwS G -53) Environmental Quality Standards and Standards for Discharges to Surface Waters

t

Version v6

Released Dec 2015

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EPA Export 29-04-2017031836

Copyright63 20d5 Scottish Environment Protection Agency (SEPA) All rights reserved No part of this document may be reproduced in any form or by any means electronic or mechanical including (but not limited to) photocopying recording or using any information storage and retrieval systems without the express permission in writing of SEPA

Disclaimer Whilst every effort has been made to ensure the accuracy of this document SEPA cannot accept and hereby expressly excludes all or any liability and gives no warranty covenant or undertaking (whether express or implied) in respect of the fitness for purpose ofb or any error omission or discrepancy in this document and reliance on contents hereof is entireEy at the users own risk

Registered Tradam arks All registered trademarks used in this document are used for reference purpose only Other brand and product names maybe registered tradernarks or trademarks of their respective holders

Update Summary

Version

vi0

V20

1130

V31

v40

v5 I

V 6

DescriDtion First issue for Water Use based on following UKTAG Reports

UK Environmenfal Standards and Conditions (Phase f amp 2) Proposals far Groundwater Classification System Proposals for Environrnenfal Qualjty Standards for Annex Vfll Substances

New base template applied links to docs revised for new SEPA website Nov 2008

Revised to reflect The Scoflaand River Basin Dfsfrlcf (Sudace Water Typology Environmental Standards Condition limits and Groundwater Threshold Values) Directions 2009 Non-Statutory Standards also added

Minor corrections toTable 1 Status amp Table 4 units

Expired CMS links reviewed and updated

Revised to reflect the Standards Direcfions 2024

Revised to reflect the Standards Direclions 2015 amp including Nav 2015 updates to Tables 34 5 amp 7

Notes References Linked references to other documents have been disabled in this web version of the document See the References section for details of all referenced documents

Printing the Document This document is uncontrolled if printed and is only intended fo be viewed online If you do need to print he document the best results are achieved using Booklet printing or else double-sided Duplex (2-on-I) A4 printing both four pages per A4

Always refer to the onllne document for accurate and up-to-date information sheel)

2 of 34 Uncontrofled if printed v6 Dec 201 5

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EPA Export 29-04-2017031836

A Key Points 4 2 Typolagy-specifie Einvi~onmental Quality Standards 5 3 Environmental Quality Standards for Surfgce Waters 6

Priority Substances d i 6

32 Speclfrc F d k h n t s 6

Substances under the repealed Dangerous Substances Directive 7

34 Non-statutory EQS 7

31 +

33

4 Operational Aquaculture Standards If 8

Annex 1 GIS Layer 9

Annex 2 List of Tables 10

References 33

v6 Dec 2015 Uncontrolled if printed 3 of34

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EPA Export 29-04-2017031836

The purpose of this guidance is to provide information on and access to the environmental and discharge standards for surface waters The standards are based on the latest scientific understanding of the UK Technioal Advisory Group (UKTAG) for the Water Framework Directive (WFD) The surfa~e water standards are available in the Standards Directions 2015 as follows

Water Quality Standards - Rivers and Lochs Schedule 2 Part CI Section I amp 2

H Water Quality Standards - Coastal and Transitional Waters Schedule 2 Part

BI Groundwater threshold values4 Schedule 6

c Section 3

Section 2 of this guidanee describes how to access typology-specific standards Section 3 of this guidance provides the numerical environmental standards for surface waters Section 4 of this guidance provides the numerical operational standards for aquaculture discharges

A separate S P A guidance note provides information on morphology standards WAT- SG-2 7 Envimnmsnfat Standards for River Morphology

These standards are only to be used in classifying groundwafer bodies and should not be used for the regulation of point source discharges into groundwater This is because the Water Framework Directive sets an additional objective fot groundwater that to prevent and limit the input of pollutants into groundwater This objective protects all groundwater from pollution and is assessed at a local scale whereas status mainly deals with large scale pressures on groundwater bodies Therefore under fhe Water Framework Directlve it is possible to have local pollution in a groundwater body of gopd chemical status The requirements to prevent or limit complement those for status Notwithstanding the time needed to enable the historicat legacy Qf releases to degrade or disperse if all the prevenf or limit requirements were met everywhere within a groundwater body if would be at good chemical status Because of this the prevent and limit objective will drive regulation of point source discharges to groundwater

4 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Some of the environmental standards are dependent on the type of surface water such as its altitude alkalinity and conceritration of dissolved organic carbon (DOG) The parameters requiring reference to the surface water typology include

W Dissolved oxygen (DO) stmdards for rivers (and in relation to short-term and

rn Dissolved oxygen standards for freshwater lochs

intermittent changes to DO)

Biochemical oxygen demand OD) standards for rivers (and in relation to short-term and intermittent changes to BOD)

BAmrnorija standards for rivers (induding standards for short-term and intermittent changes in ammonia Concentration)

H pH and acid neutralising capacity ANC) in rivers

For rivers the standards which require reference to the typology of the river are found on SEFAs GIs Pages (with t he exception of pH and ANC found in WAT-SG-53-TI Refer to Annex I for instructions on how to access the standards in GIs

WAT-SE53-T2 contains the fundarnenial intermittent and short term (99th percentile) standards for DO Bob a8d Ammonia These account for short term and intermittent discharges that can occur in wet weather Phosphorus (PI standards for rivers are no longer type-specific they are now location specific Phosphorus standards should be determined by staff using the Alkalinify Mapping Tool from the ESIU informatics hub and altitude for the site in question available from the GIS Idranet interactive map

v6 Dec 2015 Uncontrolled if printed 5 of 34

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EPA Export 29-04-2017031836

The WFD requires environmental quality standards (EQS) for polluting substances If these standards are exceeded they could result in adverse effects to ecosystems The following tables provide details of statutory and non-statutory substances For reference purposes the full list of substances that SEPA is required to take account of is found in WA T-SG-53- T3

3i Priority Substances The WFD priority substances list is a group of substances shown to be of major concern for European Waters due to their toxicity bio-accumulating properties andlor persistence in the environment SEPA is required to take account of these substances when assessing risks to the water environment classifying the status of water bodies and controlling discharges The tist of WFD priority substances is found in WAT-SG-53-7il This list includes Priority Hazardous Substances (PHS) and Other Pollutanfs (for which a European standard applies)

32 Specific Pollutants Specific Pollutants are substances that may have a harmful effect on biological quality and which have be jdentified by UKTAG as being discharged to the water environment in significant quantities in the UK The list of Specific Pollutants SEPA is required to take account of is found in WAT-SG-53-T5

321 Appticatiort of Marine Copper Standards I Note The poiicy guidance for apptication of marine copper standards is still under development and should be regarded as draft guidance Please contact the national water unit if you are dealing with an application that includes a condition for marine copper Ernail DL- WaterRegSuppsepa o q uk

The standards for freshwater and marine copper standards are listed in WAT-SG-53-75 for Specific Pollutants The marine copper standards are designed to take account of the effect of dissolved organic carbon (POC) on the availabjlity of copper to aquatic biota In high DOC environments copper is less bioavailable and the standard is adjusted accordingly In the absence of inforfiation on environmental background DOC (BDOC) andor discharge derived DOC (DDOC) an EQS of 509pgA will be applied (376ygA if Imown DOCS j)

Shotlld applicants intend to determine an adjusted site-specific EQS for the receiving water they must provide appropriate BDOC or DDOC data to SEPA Far BOOC the annual mean concentration of DOC for the receiving water is required For DDOC typical discharge concentrafttians for that sector will be required This data will be developed over time in consuitation with SEPA sector leads Sector DDOC data should meet the fallowing criteria

HA minimum of one years supply of data

8 of34 Unconfrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031836

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

For

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ectio

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pose

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nt of

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

insp

ectio

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pose

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nt of

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se

EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

insp

ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

insp

ectio

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pose

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nt of

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uired

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se

EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

insp

ectio

n pur

pose

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nt of

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se

EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

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pose

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

For

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

For

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

For

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 5: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

E Scottish Enviroti tilent

Prutectian Agency

Water Use

S u p port i ng G U id a nce (WATwS G -53) Environmental Quality Standards and Standards for Discharges to Surface Waters

t

Version v6

Released Dec 2015

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EPA Export 29-04-2017031836

Copyright63 20d5 Scottish Environment Protection Agency (SEPA) All rights reserved No part of this document may be reproduced in any form or by any means electronic or mechanical including (but not limited to) photocopying recording or using any information storage and retrieval systems without the express permission in writing of SEPA

Disclaimer Whilst every effort has been made to ensure the accuracy of this document SEPA cannot accept and hereby expressly excludes all or any liability and gives no warranty covenant or undertaking (whether express or implied) in respect of the fitness for purpose ofb or any error omission or discrepancy in this document and reliance on contents hereof is entireEy at the users own risk

Registered Tradam arks All registered trademarks used in this document are used for reference purpose only Other brand and product names maybe registered tradernarks or trademarks of their respective holders

Update Summary

Version

vi0

V20

1130

V31

v40

v5 I

V 6

DescriDtion First issue for Water Use based on following UKTAG Reports

UK Environmenfal Standards and Conditions (Phase f amp 2) Proposals far Groundwater Classification System Proposals for Environrnenfal Qualjty Standards for Annex Vfll Substances

New base template applied links to docs revised for new SEPA website Nov 2008

Revised to reflect The Scoflaand River Basin Dfsfrlcf (Sudace Water Typology Environmental Standards Condition limits and Groundwater Threshold Values) Directions 2009 Non-Statutory Standards also added

Minor corrections toTable 1 Status amp Table 4 units

Expired CMS links reviewed and updated

Revised to reflect the Standards Direcfions 2024

Revised to reflect the Standards Direclions 2015 amp including Nav 2015 updates to Tables 34 5 amp 7

Notes References Linked references to other documents have been disabled in this web version of the document See the References section for details of all referenced documents

Printing the Document This document is uncontrolled if printed and is only intended fo be viewed online If you do need to print he document the best results are achieved using Booklet printing or else double-sided Duplex (2-on-I) A4 printing both four pages per A4

Always refer to the onllne document for accurate and up-to-date information sheel)

2 of 34 Uncontrofled if printed v6 Dec 201 5

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EPA Export 29-04-2017031836

A Key Points 4 2 Typolagy-specifie Einvi~onmental Quality Standards 5 3 Environmental Quality Standards for Surfgce Waters 6

Priority Substances d i 6

32 Speclfrc F d k h n t s 6

Substances under the repealed Dangerous Substances Directive 7

34 Non-statutory EQS 7

31 +

33

4 Operational Aquaculture Standards If 8

Annex 1 GIS Layer 9

Annex 2 List of Tables 10

References 33

v6 Dec 2015 Uncontrolled if printed 3 of34

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EPA Export 29-04-2017031836

The purpose of this guidance is to provide information on and access to the environmental and discharge standards for surface waters The standards are based on the latest scientific understanding of the UK Technioal Advisory Group (UKTAG) for the Water Framework Directive (WFD) The surfa~e water standards are available in the Standards Directions 2015 as follows

Water Quality Standards - Rivers and Lochs Schedule 2 Part CI Section I amp 2

H Water Quality Standards - Coastal and Transitional Waters Schedule 2 Part

BI Groundwater threshold values4 Schedule 6

c Section 3

Section 2 of this guidanee describes how to access typology-specific standards Section 3 of this guidance provides the numerical environmental standards for surface waters Section 4 of this guidance provides the numerical operational standards for aquaculture discharges

A separate S P A guidance note provides information on morphology standards WAT- SG-2 7 Envimnmsnfat Standards for River Morphology

These standards are only to be used in classifying groundwafer bodies and should not be used for the regulation of point source discharges into groundwater This is because the Water Framework Directive sets an additional objective fot groundwater that to prevent and limit the input of pollutants into groundwater This objective protects all groundwater from pollution and is assessed at a local scale whereas status mainly deals with large scale pressures on groundwater bodies Therefore under fhe Water Framework Directlve it is possible to have local pollution in a groundwater body of gopd chemical status The requirements to prevent or limit complement those for status Notwithstanding the time needed to enable the historicat legacy Qf releases to degrade or disperse if all the prevenf or limit requirements were met everywhere within a groundwater body if would be at good chemical status Because of this the prevent and limit objective will drive regulation of point source discharges to groundwater

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EPA Export 29-04-2017031836

Some of the environmental standards are dependent on the type of surface water such as its altitude alkalinity and conceritration of dissolved organic carbon (DOG) The parameters requiring reference to the surface water typology include

W Dissolved oxygen (DO) stmdards for rivers (and in relation to short-term and

rn Dissolved oxygen standards for freshwater lochs

intermittent changes to DO)

Biochemical oxygen demand OD) standards for rivers (and in relation to short-term and intermittent changes to BOD)

BAmrnorija standards for rivers (induding standards for short-term and intermittent changes in ammonia Concentration)

H pH and acid neutralising capacity ANC) in rivers

For rivers the standards which require reference to the typology of the river are found on SEFAs GIs Pages (with t he exception of pH and ANC found in WAT-SG-53-TI Refer to Annex I for instructions on how to access the standards in GIs

WAT-SE53-T2 contains the fundarnenial intermittent and short term (99th percentile) standards for DO Bob a8d Ammonia These account for short term and intermittent discharges that can occur in wet weather Phosphorus (PI standards for rivers are no longer type-specific they are now location specific Phosphorus standards should be determined by staff using the Alkalinify Mapping Tool from the ESIU informatics hub and altitude for the site in question available from the GIS Idranet interactive map

v6 Dec 2015 Uncontrolled if printed 5 of 34

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EPA Export 29-04-2017031836

The WFD requires environmental quality standards (EQS) for polluting substances If these standards are exceeded they could result in adverse effects to ecosystems The following tables provide details of statutory and non-statutory substances For reference purposes the full list of substances that SEPA is required to take account of is found in WA T-SG-53- T3

3i Priority Substances The WFD priority substances list is a group of substances shown to be of major concern for European Waters due to their toxicity bio-accumulating properties andlor persistence in the environment SEPA is required to take account of these substances when assessing risks to the water environment classifying the status of water bodies and controlling discharges The tist of WFD priority substances is found in WAT-SG-53-7il This list includes Priority Hazardous Substances (PHS) and Other Pollutanfs (for which a European standard applies)

32 Specific Pollutants Specific Pollutants are substances that may have a harmful effect on biological quality and which have be jdentified by UKTAG as being discharged to the water environment in significant quantities in the UK The list of Specific Pollutants SEPA is required to take account of is found in WAT-SG-53-T5

321 Appticatiort of Marine Copper Standards I Note The poiicy guidance for apptication of marine copper standards is still under development and should be regarded as draft guidance Please contact the national water unit if you are dealing with an application that includes a condition for marine copper Ernail DL- WaterRegSuppsepa o q uk

The standards for freshwater and marine copper standards are listed in WAT-SG-53-75 for Specific Pollutants The marine copper standards are designed to take account of the effect of dissolved organic carbon (POC) on the availabjlity of copper to aquatic biota In high DOC environments copper is less bioavailable and the standard is adjusted accordingly In the absence of inforfiation on environmental background DOC (BDOC) andor discharge derived DOC (DDOC) an EQS of 509pgA will be applied (376ygA if Imown DOCS j)

Shotlld applicants intend to determine an adjusted site-specific EQS for the receiving water they must provide appropriate BDOC or DDOC data to SEPA Far BOOC the annual mean concentration of DOC for the receiving water is required For DDOC typical discharge concentrafttians for that sector will be required This data will be developed over time in consuitation with SEPA sector leads Sector DDOC data should meet the fallowing criteria

HA minimum of one years supply of data

8 of34 Unconfrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031836

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

For

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ectio

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pose

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

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ectio

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pose

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nt of

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se

EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

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pose

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

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ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

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ectio

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pose

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se

EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

insp

ectio

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pose

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nt of

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se

EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 6: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Copyright63 20d5 Scottish Environment Protection Agency (SEPA) All rights reserved No part of this document may be reproduced in any form or by any means electronic or mechanical including (but not limited to) photocopying recording or using any information storage and retrieval systems without the express permission in writing of SEPA

Disclaimer Whilst every effort has been made to ensure the accuracy of this document SEPA cannot accept and hereby expressly excludes all or any liability and gives no warranty covenant or undertaking (whether express or implied) in respect of the fitness for purpose ofb or any error omission or discrepancy in this document and reliance on contents hereof is entireEy at the users own risk

Registered Tradam arks All registered trademarks used in this document are used for reference purpose only Other brand and product names maybe registered tradernarks or trademarks of their respective holders

Update Summary

Version

vi0

V20

1130

V31

v40

v5 I

V 6

DescriDtion First issue for Water Use based on following UKTAG Reports

UK Environmenfal Standards and Conditions (Phase f amp 2) Proposals far Groundwater Classification System Proposals for Environrnenfal Qualjty Standards for Annex Vfll Substances

New base template applied links to docs revised for new SEPA website Nov 2008

Revised to reflect The Scoflaand River Basin Dfsfrlcf (Sudace Water Typology Environmental Standards Condition limits and Groundwater Threshold Values) Directions 2009 Non-Statutory Standards also added

Minor corrections toTable 1 Status amp Table 4 units

Expired CMS links reviewed and updated

Revised to reflect the Standards Direcfions 2024

Revised to reflect the Standards Direclions 2015 amp including Nav 2015 updates to Tables 34 5 amp 7

Notes References Linked references to other documents have been disabled in this web version of the document See the References section for details of all referenced documents

Printing the Document This document is uncontrolled if printed and is only intended fo be viewed online If you do need to print he document the best results are achieved using Booklet printing or else double-sided Duplex (2-on-I) A4 printing both four pages per A4

Always refer to the onllne document for accurate and up-to-date information sheel)

2 of 34 Uncontrofled if printed v6 Dec 201 5

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EPA Export 29-04-2017031836

A Key Points 4 2 Typolagy-specifie Einvi~onmental Quality Standards 5 3 Environmental Quality Standards for Surfgce Waters 6

Priority Substances d i 6

32 Speclfrc F d k h n t s 6

Substances under the repealed Dangerous Substances Directive 7

34 Non-statutory EQS 7

31 +

33

4 Operational Aquaculture Standards If 8

Annex 1 GIS Layer 9

Annex 2 List of Tables 10

References 33

v6 Dec 2015 Uncontrolled if printed 3 of34

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EPA Export 29-04-2017031836

The purpose of this guidance is to provide information on and access to the environmental and discharge standards for surface waters The standards are based on the latest scientific understanding of the UK Technioal Advisory Group (UKTAG) for the Water Framework Directive (WFD) The surfa~e water standards are available in the Standards Directions 2015 as follows

Water Quality Standards - Rivers and Lochs Schedule 2 Part CI Section I amp 2

H Water Quality Standards - Coastal and Transitional Waters Schedule 2 Part

BI Groundwater threshold values4 Schedule 6

c Section 3

Section 2 of this guidanee describes how to access typology-specific standards Section 3 of this guidance provides the numerical environmental standards for surface waters Section 4 of this guidance provides the numerical operational standards for aquaculture discharges

A separate S P A guidance note provides information on morphology standards WAT- SG-2 7 Envimnmsnfat Standards for River Morphology

These standards are only to be used in classifying groundwafer bodies and should not be used for the regulation of point source discharges into groundwater This is because the Water Framework Directive sets an additional objective fot groundwater that to prevent and limit the input of pollutants into groundwater This objective protects all groundwater from pollution and is assessed at a local scale whereas status mainly deals with large scale pressures on groundwater bodies Therefore under fhe Water Framework Directlve it is possible to have local pollution in a groundwater body of gopd chemical status The requirements to prevent or limit complement those for status Notwithstanding the time needed to enable the historicat legacy Qf releases to degrade or disperse if all the prevenf or limit requirements were met everywhere within a groundwater body if would be at good chemical status Because of this the prevent and limit objective will drive regulation of point source discharges to groundwater

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EPA Export 29-04-2017031836

Some of the environmental standards are dependent on the type of surface water such as its altitude alkalinity and conceritration of dissolved organic carbon (DOG) The parameters requiring reference to the surface water typology include

W Dissolved oxygen (DO) stmdards for rivers (and in relation to short-term and

rn Dissolved oxygen standards for freshwater lochs

intermittent changes to DO)

Biochemical oxygen demand OD) standards for rivers (and in relation to short-term and intermittent changes to BOD)

BAmrnorija standards for rivers (induding standards for short-term and intermittent changes in ammonia Concentration)

H pH and acid neutralising capacity ANC) in rivers

For rivers the standards which require reference to the typology of the river are found on SEFAs GIs Pages (with t he exception of pH and ANC found in WAT-SG-53-TI Refer to Annex I for instructions on how to access the standards in GIs

WAT-SE53-T2 contains the fundarnenial intermittent and short term (99th percentile) standards for DO Bob a8d Ammonia These account for short term and intermittent discharges that can occur in wet weather Phosphorus (PI standards for rivers are no longer type-specific they are now location specific Phosphorus standards should be determined by staff using the Alkalinify Mapping Tool from the ESIU informatics hub and altitude for the site in question available from the GIS Idranet interactive map

v6 Dec 2015 Uncontrolled if printed 5 of 34

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EPA Export 29-04-2017031836

The WFD requires environmental quality standards (EQS) for polluting substances If these standards are exceeded they could result in adverse effects to ecosystems The following tables provide details of statutory and non-statutory substances For reference purposes the full list of substances that SEPA is required to take account of is found in WA T-SG-53- T3

3i Priority Substances The WFD priority substances list is a group of substances shown to be of major concern for European Waters due to their toxicity bio-accumulating properties andlor persistence in the environment SEPA is required to take account of these substances when assessing risks to the water environment classifying the status of water bodies and controlling discharges The tist of WFD priority substances is found in WAT-SG-53-7il This list includes Priority Hazardous Substances (PHS) and Other Pollutanfs (for which a European standard applies)

32 Specific Pollutants Specific Pollutants are substances that may have a harmful effect on biological quality and which have be jdentified by UKTAG as being discharged to the water environment in significant quantities in the UK The list of Specific Pollutants SEPA is required to take account of is found in WAT-SG-53-T5

321 Appticatiort of Marine Copper Standards I Note The poiicy guidance for apptication of marine copper standards is still under development and should be regarded as draft guidance Please contact the national water unit if you are dealing with an application that includes a condition for marine copper Ernail DL- WaterRegSuppsepa o q uk

The standards for freshwater and marine copper standards are listed in WAT-SG-53-75 for Specific Pollutants The marine copper standards are designed to take account of the effect of dissolved organic carbon (POC) on the availabjlity of copper to aquatic biota In high DOC environments copper is less bioavailable and the standard is adjusted accordingly In the absence of inforfiation on environmental background DOC (BDOC) andor discharge derived DOC (DDOC) an EQS of 509pgA will be applied (376ygA if Imown DOCS j)

Shotlld applicants intend to determine an adjusted site-specific EQS for the receiving water they must provide appropriate BDOC or DDOC data to SEPA Far BOOC the annual mean concentration of DOC for the receiving water is required For DDOC typical discharge concentrafttians for that sector will be required This data will be developed over time in consuitation with SEPA sector leads Sector DDOC data should meet the fallowing criteria

HA minimum of one years supply of data

8 of34 Unconfrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031836

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

For

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ectio

n pur

pose

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uired

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

insp

ectio

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pose

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nt of

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se

EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

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pose

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se

EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

insp

ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

insp

ectio

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pose

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se

EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

insp

ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

For

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

For

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 7: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

A Key Points 4 2 Typolagy-specifie Einvi~onmental Quality Standards 5 3 Environmental Quality Standards for Surfgce Waters 6

Priority Substances d i 6

32 Speclfrc F d k h n t s 6

Substances under the repealed Dangerous Substances Directive 7

34 Non-statutory EQS 7

31 +

33

4 Operational Aquaculture Standards If 8

Annex 1 GIS Layer 9

Annex 2 List of Tables 10

References 33

v6 Dec 2015 Uncontrolled if printed 3 of34

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EPA Export 29-04-2017031836

The purpose of this guidance is to provide information on and access to the environmental and discharge standards for surface waters The standards are based on the latest scientific understanding of the UK Technioal Advisory Group (UKTAG) for the Water Framework Directive (WFD) The surfa~e water standards are available in the Standards Directions 2015 as follows

Water Quality Standards - Rivers and Lochs Schedule 2 Part CI Section I amp 2

H Water Quality Standards - Coastal and Transitional Waters Schedule 2 Part

BI Groundwater threshold values4 Schedule 6

c Section 3

Section 2 of this guidanee describes how to access typology-specific standards Section 3 of this guidance provides the numerical environmental standards for surface waters Section 4 of this guidance provides the numerical operational standards for aquaculture discharges

A separate S P A guidance note provides information on morphology standards WAT- SG-2 7 Envimnmsnfat Standards for River Morphology

These standards are only to be used in classifying groundwafer bodies and should not be used for the regulation of point source discharges into groundwater This is because the Water Framework Directive sets an additional objective fot groundwater that to prevent and limit the input of pollutants into groundwater This objective protects all groundwater from pollution and is assessed at a local scale whereas status mainly deals with large scale pressures on groundwater bodies Therefore under fhe Water Framework Directlve it is possible to have local pollution in a groundwater body of gopd chemical status The requirements to prevent or limit complement those for status Notwithstanding the time needed to enable the historicat legacy Qf releases to degrade or disperse if all the prevenf or limit requirements were met everywhere within a groundwater body if would be at good chemical status Because of this the prevent and limit objective will drive regulation of point source discharges to groundwater

4 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Some of the environmental standards are dependent on the type of surface water such as its altitude alkalinity and conceritration of dissolved organic carbon (DOG) The parameters requiring reference to the surface water typology include

W Dissolved oxygen (DO) stmdards for rivers (and in relation to short-term and

rn Dissolved oxygen standards for freshwater lochs

intermittent changes to DO)

Biochemical oxygen demand OD) standards for rivers (and in relation to short-term and intermittent changes to BOD)

BAmrnorija standards for rivers (induding standards for short-term and intermittent changes in ammonia Concentration)

H pH and acid neutralising capacity ANC) in rivers

For rivers the standards which require reference to the typology of the river are found on SEFAs GIs Pages (with t he exception of pH and ANC found in WAT-SG-53-TI Refer to Annex I for instructions on how to access the standards in GIs

WAT-SE53-T2 contains the fundarnenial intermittent and short term (99th percentile) standards for DO Bob a8d Ammonia These account for short term and intermittent discharges that can occur in wet weather Phosphorus (PI standards for rivers are no longer type-specific they are now location specific Phosphorus standards should be determined by staff using the Alkalinify Mapping Tool from the ESIU informatics hub and altitude for the site in question available from the GIS Idranet interactive map

v6 Dec 2015 Uncontrolled if printed 5 of 34

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EPA Export 29-04-2017031836

The WFD requires environmental quality standards (EQS) for polluting substances If these standards are exceeded they could result in adverse effects to ecosystems The following tables provide details of statutory and non-statutory substances For reference purposes the full list of substances that SEPA is required to take account of is found in WA T-SG-53- T3

3i Priority Substances The WFD priority substances list is a group of substances shown to be of major concern for European Waters due to their toxicity bio-accumulating properties andlor persistence in the environment SEPA is required to take account of these substances when assessing risks to the water environment classifying the status of water bodies and controlling discharges The tist of WFD priority substances is found in WAT-SG-53-7il This list includes Priority Hazardous Substances (PHS) and Other Pollutanfs (for which a European standard applies)

32 Specific Pollutants Specific Pollutants are substances that may have a harmful effect on biological quality and which have be jdentified by UKTAG as being discharged to the water environment in significant quantities in the UK The list of Specific Pollutants SEPA is required to take account of is found in WAT-SG-53-T5

321 Appticatiort of Marine Copper Standards I Note The poiicy guidance for apptication of marine copper standards is still under development and should be regarded as draft guidance Please contact the national water unit if you are dealing with an application that includes a condition for marine copper Ernail DL- WaterRegSuppsepa o q uk

The standards for freshwater and marine copper standards are listed in WAT-SG-53-75 for Specific Pollutants The marine copper standards are designed to take account of the effect of dissolved organic carbon (POC) on the availabjlity of copper to aquatic biota In high DOC environments copper is less bioavailable and the standard is adjusted accordingly In the absence of inforfiation on environmental background DOC (BDOC) andor discharge derived DOC (DDOC) an EQS of 509pgA will be applied (376ygA if Imown DOCS j)

Shotlld applicants intend to determine an adjusted site-specific EQS for the receiving water they must provide appropriate BDOC or DDOC data to SEPA Far BOOC the annual mean concentration of DOC for the receiving water is required For DDOC typical discharge concentrafttians for that sector will be required This data will be developed over time in consuitation with SEPA sector leads Sector DDOC data should meet the fallowing criteria

HA minimum of one years supply of data

8 of34 Unconfrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031836

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

insp

ectio

n pur

pose

s only

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nt of

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uired

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se

EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

n pur

pose

s only

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nt of

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

insp

ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

insp

ectio

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pose

s only

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nt of

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uired

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se

EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

insp

ectio

n pur

pose

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nt of

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se

EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

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pose

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

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pose

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

For

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 8: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

The purpose of this guidance is to provide information on and access to the environmental and discharge standards for surface waters The standards are based on the latest scientific understanding of the UK Technioal Advisory Group (UKTAG) for the Water Framework Directive (WFD) The surfa~e water standards are available in the Standards Directions 2015 as follows

Water Quality Standards - Rivers and Lochs Schedule 2 Part CI Section I amp 2

H Water Quality Standards - Coastal and Transitional Waters Schedule 2 Part

BI Groundwater threshold values4 Schedule 6

c Section 3

Section 2 of this guidanee describes how to access typology-specific standards Section 3 of this guidance provides the numerical environmental standards for surface waters Section 4 of this guidance provides the numerical operational standards for aquaculture discharges

A separate S P A guidance note provides information on morphology standards WAT- SG-2 7 Envimnmsnfat Standards for River Morphology

These standards are only to be used in classifying groundwafer bodies and should not be used for the regulation of point source discharges into groundwater This is because the Water Framework Directive sets an additional objective fot groundwater that to prevent and limit the input of pollutants into groundwater This objective protects all groundwater from pollution and is assessed at a local scale whereas status mainly deals with large scale pressures on groundwater bodies Therefore under fhe Water Framework Directlve it is possible to have local pollution in a groundwater body of gopd chemical status The requirements to prevent or limit complement those for status Notwithstanding the time needed to enable the historicat legacy Qf releases to degrade or disperse if all the prevenf or limit requirements were met everywhere within a groundwater body if would be at good chemical status Because of this the prevent and limit objective will drive regulation of point source discharges to groundwater

4 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Some of the environmental standards are dependent on the type of surface water such as its altitude alkalinity and conceritration of dissolved organic carbon (DOG) The parameters requiring reference to the surface water typology include

W Dissolved oxygen (DO) stmdards for rivers (and in relation to short-term and

rn Dissolved oxygen standards for freshwater lochs

intermittent changes to DO)

Biochemical oxygen demand OD) standards for rivers (and in relation to short-term and intermittent changes to BOD)

BAmrnorija standards for rivers (induding standards for short-term and intermittent changes in ammonia Concentration)

H pH and acid neutralising capacity ANC) in rivers

For rivers the standards which require reference to the typology of the river are found on SEFAs GIs Pages (with t he exception of pH and ANC found in WAT-SG-53-TI Refer to Annex I for instructions on how to access the standards in GIs

WAT-SE53-T2 contains the fundarnenial intermittent and short term (99th percentile) standards for DO Bob a8d Ammonia These account for short term and intermittent discharges that can occur in wet weather Phosphorus (PI standards for rivers are no longer type-specific they are now location specific Phosphorus standards should be determined by staff using the Alkalinify Mapping Tool from the ESIU informatics hub and altitude for the site in question available from the GIS Idranet interactive map

v6 Dec 2015 Uncontrolled if printed 5 of 34

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EPA Export 29-04-2017031836

The WFD requires environmental quality standards (EQS) for polluting substances If these standards are exceeded they could result in adverse effects to ecosystems The following tables provide details of statutory and non-statutory substances For reference purposes the full list of substances that SEPA is required to take account of is found in WA T-SG-53- T3

3i Priority Substances The WFD priority substances list is a group of substances shown to be of major concern for European Waters due to their toxicity bio-accumulating properties andlor persistence in the environment SEPA is required to take account of these substances when assessing risks to the water environment classifying the status of water bodies and controlling discharges The tist of WFD priority substances is found in WAT-SG-53-7il This list includes Priority Hazardous Substances (PHS) and Other Pollutanfs (for which a European standard applies)

32 Specific Pollutants Specific Pollutants are substances that may have a harmful effect on biological quality and which have be jdentified by UKTAG as being discharged to the water environment in significant quantities in the UK The list of Specific Pollutants SEPA is required to take account of is found in WAT-SG-53-T5

321 Appticatiort of Marine Copper Standards I Note The poiicy guidance for apptication of marine copper standards is still under development and should be regarded as draft guidance Please contact the national water unit if you are dealing with an application that includes a condition for marine copper Ernail DL- WaterRegSuppsepa o q uk

The standards for freshwater and marine copper standards are listed in WAT-SG-53-75 for Specific Pollutants The marine copper standards are designed to take account of the effect of dissolved organic carbon (POC) on the availabjlity of copper to aquatic biota In high DOC environments copper is less bioavailable and the standard is adjusted accordingly In the absence of inforfiation on environmental background DOC (BDOC) andor discharge derived DOC (DDOC) an EQS of 509pgA will be applied (376ygA if Imown DOCS j)

Shotlld applicants intend to determine an adjusted site-specific EQS for the receiving water they must provide appropriate BDOC or DDOC data to SEPA Far BOOC the annual mean concentration of DOC for the receiving water is required For DDOC typical discharge concentrafttians for that sector will be required This data will be developed over time in consuitation with SEPA sector leads Sector DDOC data should meet the fallowing criteria

HA minimum of one years supply of data

8 of34 Unconfrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031836

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

n pur

pose

s only

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nt of

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uired

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se

EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

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ectio

n pur

pose

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se

EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

insp

ectio

n pur

pose

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nt of

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se

EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

insp

ectio

n pur

pose

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nt of

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se

EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

n pur

pose

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nt of

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

n pur

pose

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nt of

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

For

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

For

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 9: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Some of the environmental standards are dependent on the type of surface water such as its altitude alkalinity and conceritration of dissolved organic carbon (DOG) The parameters requiring reference to the surface water typology include

W Dissolved oxygen (DO) stmdards for rivers (and in relation to short-term and

rn Dissolved oxygen standards for freshwater lochs

intermittent changes to DO)

Biochemical oxygen demand OD) standards for rivers (and in relation to short-term and intermittent changes to BOD)

BAmrnorija standards for rivers (induding standards for short-term and intermittent changes in ammonia Concentration)

H pH and acid neutralising capacity ANC) in rivers

For rivers the standards which require reference to the typology of the river are found on SEFAs GIs Pages (with t he exception of pH and ANC found in WAT-SG-53-TI Refer to Annex I for instructions on how to access the standards in GIs

WAT-SE53-T2 contains the fundarnenial intermittent and short term (99th percentile) standards for DO Bob a8d Ammonia These account for short term and intermittent discharges that can occur in wet weather Phosphorus (PI standards for rivers are no longer type-specific they are now location specific Phosphorus standards should be determined by staff using the Alkalinify Mapping Tool from the ESIU informatics hub and altitude for the site in question available from the GIS Idranet interactive map

v6 Dec 2015 Uncontrolled if printed 5 of 34

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EPA Export 29-04-2017031836

The WFD requires environmental quality standards (EQS) for polluting substances If these standards are exceeded they could result in adverse effects to ecosystems The following tables provide details of statutory and non-statutory substances For reference purposes the full list of substances that SEPA is required to take account of is found in WA T-SG-53- T3

3i Priority Substances The WFD priority substances list is a group of substances shown to be of major concern for European Waters due to their toxicity bio-accumulating properties andlor persistence in the environment SEPA is required to take account of these substances when assessing risks to the water environment classifying the status of water bodies and controlling discharges The tist of WFD priority substances is found in WAT-SG-53-7il This list includes Priority Hazardous Substances (PHS) and Other Pollutanfs (for which a European standard applies)

32 Specific Pollutants Specific Pollutants are substances that may have a harmful effect on biological quality and which have be jdentified by UKTAG as being discharged to the water environment in significant quantities in the UK The list of Specific Pollutants SEPA is required to take account of is found in WAT-SG-53-T5

321 Appticatiort of Marine Copper Standards I Note The poiicy guidance for apptication of marine copper standards is still under development and should be regarded as draft guidance Please contact the national water unit if you are dealing with an application that includes a condition for marine copper Ernail DL- WaterRegSuppsepa o q uk

The standards for freshwater and marine copper standards are listed in WAT-SG-53-75 for Specific Pollutants The marine copper standards are designed to take account of the effect of dissolved organic carbon (POC) on the availabjlity of copper to aquatic biota In high DOC environments copper is less bioavailable and the standard is adjusted accordingly In the absence of inforfiation on environmental background DOC (BDOC) andor discharge derived DOC (DDOC) an EQS of 509pgA will be applied (376ygA if Imown DOCS j)

Shotlld applicants intend to determine an adjusted site-specific EQS for the receiving water they must provide appropriate BDOC or DDOC data to SEPA Far BOOC the annual mean concentration of DOC for the receiving water is required For DDOC typical discharge concentrafttians for that sector will be required This data will be developed over time in consuitation with SEPA sector leads Sector DDOC data should meet the fallowing criteria

HA minimum of one years supply of data

8 of34 Unconfrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031836

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

insp

ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

insp

ectio

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pose

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

insp

ectio

n pur

pose

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nt of

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

n pur

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

n pur

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

For

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 10: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

The WFD requires environmental quality standards (EQS) for polluting substances If these standards are exceeded they could result in adverse effects to ecosystems The following tables provide details of statutory and non-statutory substances For reference purposes the full list of substances that SEPA is required to take account of is found in WA T-SG-53- T3

3i Priority Substances The WFD priority substances list is a group of substances shown to be of major concern for European Waters due to their toxicity bio-accumulating properties andlor persistence in the environment SEPA is required to take account of these substances when assessing risks to the water environment classifying the status of water bodies and controlling discharges The tist of WFD priority substances is found in WAT-SG-53-7il This list includes Priority Hazardous Substances (PHS) and Other Pollutanfs (for which a European standard applies)

32 Specific Pollutants Specific Pollutants are substances that may have a harmful effect on biological quality and which have be jdentified by UKTAG as being discharged to the water environment in significant quantities in the UK The list of Specific Pollutants SEPA is required to take account of is found in WAT-SG-53-T5

321 Appticatiort of Marine Copper Standards I Note The poiicy guidance for apptication of marine copper standards is still under development and should be regarded as draft guidance Please contact the national water unit if you are dealing with an application that includes a condition for marine copper Ernail DL- WaterRegSuppsepa o q uk

The standards for freshwater and marine copper standards are listed in WAT-SG-53-75 for Specific Pollutants The marine copper standards are designed to take account of the effect of dissolved organic carbon (POC) on the availabjlity of copper to aquatic biota In high DOC environments copper is less bioavailable and the standard is adjusted accordingly In the absence of inforfiation on environmental background DOC (BDOC) andor discharge derived DOC (DDOC) an EQS of 509pgA will be applied (376ygA if Imown DOCS j)

Shotlld applicants intend to determine an adjusted site-specific EQS for the receiving water they must provide appropriate BDOC or DDOC data to SEPA Far BOOC the annual mean concentration of DOC for the receiving water is required For DDOC typical discharge concentrafttians for that sector will be required This data will be developed over time in consuitation with SEPA sector leads Sector DDOC data should meet the fallowing criteria

HA minimum of one years supply of data

8 of34 Unconfrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031836

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

insp

ectio

n pur

pose

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

n pur

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nt of

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 11: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Fslccrim ampcnn Environmental Quality Standards for Surface Waters

Derived from at least 5 sites with similar attributes For example for a Scottish Water discharge this would be sites with similar treatment PE and influent composition Other sectors for which typical dlscharge information may be required includes shipyards1 docks slipways distilling brewing landfifts aquaculture and petroleum products

A look-up table and calculator for applying either the unadjusted or a DOC-adjusted marine copper standard is found in WAT-SG-53-Ri This will enable operations staff to then establish an appropriate discharge limit to apply to the ficence condition

SEPA initiated variations should be driven by the objectives of the RBMP and not by changes ofthe standards If an operator wishes to apply for an increased discharge to make use of t h e more relaxed standard SEFA will determine the application by applying the standard alongside the principles of allocation of environmental capacity (found in WAT-RM-2 3 )

33 Substances under the repealed Dangerous Subs tan ces Directive

The Dangerous Substances Directive (DSD) was repealed in 2013 WAT-SG-53-T7 lists those former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD However the standards listed for these have been determined using the rigorous process required of WFD substances and shouId be applied if necessary

34 Non-statutory euroQS WAT--SG-53-T8 contains non-statutory EQS These are not set out in legislation OF the Directions but are the best available at this time It should be noted that these standards may not meet the requirements of the Technical Guidance Document on risk assessment used to derive EQS under fhe WFD so should be used with caution If you are planning to use these standards for the regulation of a new licence please contact the Science Advice Helpdesk to ensure that this is still the most appropriate standard to use

w6 Dec 201 5 Uncontrotted if printed 7 of34

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EPA Export 29-04-2017031836

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

a

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

s only

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nt of

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 12: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

WA T-SG-53-TQ contains SEPA operational standards specifically for the regulation of fish farm chemicals These have been derived in-house for our own regulatory purposes

8 of34 Uncontroikd if printed v6 Dec 2015

a

For

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EPA Export 29-04-2017031836

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

For

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

For

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ny ot

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

For

insp

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ny ot

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

For

insp

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Conse

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uired

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

insp

ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

n pur

pose

s only

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nt of

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

insp

ectio

n pur

pose

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nt of

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se

EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

insp

ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

insp

ectio

n pur

pose

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nt of

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se

EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

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pose

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

n pur

pose

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nt of

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

For

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

For

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pose

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ny ot

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

s only

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 13: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

The GIS browser allows you to view the standards and typologies applicable at any given point on the map To view the information

I Start the Interactive Map application from the GIS homepage 2 Zoom To a water body ID or Zoom In to a point on the map 3 Select WFD Standards from the Themes drop-down list and press the Add

button 4 Make this the active theme by clicking the box next to its name (just above) 5 To view chemistry standards click on the square check box next to it in the list

of layers (Top right hand corner) This will draw the intercatchment areas (on which the rivet sub typologies are based) on the browser map They will appear as thin black lines

6 Select the Identify tool from the toolbox on the left side of the browser window 7 Click on a point on the map to display the standards applicable to it As the

standards are dependent on the intercatchment sub typology one river water body may have mofe than one standard which applies to it The typology is based on the inter-catchment area so there is a standard for any point in Scotland

The standards will be displayed under the map in a window with a scroll bar

v6 Dec 2015 Uncontrolled if printed 9 of34

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EPA Export 29-04-2017031836

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

For

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

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pose

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

insp

ectio

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pose

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

insp

ectio

n pur

pose

s only

Conse

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

insp

ectio

n pur

pose

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nt of

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

n pur

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nt of

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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pose

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 14: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Table

WA TuSG-53-T3

l 3 WAT-SG-ST4

WA T-SG-53-75

WAT-SG-SJ-T6

WA T-SG-53-77

1 WAT-SG-53-79 1 I

Title

pH and ANC Standards

Fundamental Intermittent and 99th percentile Standards

List of Substances

WFD Priority Substances Priority Hazardous Substances and Other Pollutants

WFD UK Specific Pollutants

Application of Marine Copper Standards

Former Dangerous Subdartces Directive List

Non-Statutory Substances

Operational Standards for Aquaculture

Marine Copper Standards Calculator (use withWAT-SQ-53-TG)

10of34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

For

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

For

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ectio

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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ectio

n pur

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

For

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

For

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 15: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

SEPAW

Class

High

Annex 2 List of Tables SxLA Errdcrmrtii trukcrirn Awns

C [ear wafers Humic waters

pH I ANC pH ANC 660 80 510 SO

Good 595 I 40 Moderate 1 544 15 Poor I 489 I - 0

-

Table 2 Fundamental Intermittent and Short Term Standards

455 50 422 I I O 403 5

For the purposes of this Table F has the value (i) Zero when the concurrent concentration of un-ionised ammonia is 5 002 rngl (ii) (097 x log(concentration of NH3-N in rng per litre) + 38) when the concurrent

concentration of un-ionised ammonia is 2 002 rngA and 5 01 5 mgll Qi) 2 when the concurlent concentration of un-ionised ammonia fs 2 015 mgll or (iv) 3 for salmonid spawning groGnds

Table 2b Standards for biochemicaf oxygen demand [BOD) in rivers in relation to short-term and intermittent changes in BOD concentrations

Concentration of biochemical oxygen demand (BOD) as a 991h percentile

Column I Column 2 Column 3

Types 424 and 6 Types 3s and 7

K JCantrel1 S MSerkiz and E M Perdue Evaluation of Add Neutra[blngCapacltyData forSolutions Coneuroalnlng Natural Organickids Geochim Cosrnochfrn Acta 541247-12254 [1990)

~

v6 Dec 2015 Uncontrolled if printed 11 of 34

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EPA Export 29-04-2017031836

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

For

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

For

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

insp

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

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pose

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

insp

ectio

n pur

pose

s only

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nt of

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

insp

ectio

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pose

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

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ectio

n pur

pose

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nt of

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

n pur

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

n pur

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

For

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 16: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

5mUli t r d r ~ I h n 4 i Supporting Guidance (WAT-SG-53) Icicuo~l Agency

High 7

Good 9

Moderate 14

Poor 16

1 9

11

14

19

Column I Galurnn 2 Column 3

Total ammonia (rngJ) as a 99lsquordquo percentile

Types ll 2 4 Types and 6 385

and 7

Table 2d Un-ionised ammonia standards for rivers in relation to short-term and

Column 4

Un-ionised ammonia (mgl) as a 9gih percentile

All types

The value of F is deljendent upon concentration of dissolved oxygen pH and temperature F is calculated as in I-viii below depending on the value pf those variables

i YJi when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is 2 5 degrees Centigrade

ii 00003 x (pH)4rsquo71J when the concurrent concentration of dissolved oxygen is 2 5 mgA pM is 7 and temperature is L 5 degrees Centigrade

iii 05rdquo when the concurrent concentration of dissolved oxygen is 2 5 mgll pH is 2 7 and temperature is lt 5 deg

High

Goad

Moderate

iv 00003 x x 05rdquo when the concurrent concentration of dissolved oxygen is I 5 rngll pH is lt 7 and temperature is 5 degrees Centigrade

05 07

07 15 004

13 26

-

12 of 34 Uncontrolled if printed v6 Dec 20j5

Poor 26 I 60 -

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EPA Export 29-04-2017031836

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

For

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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pose

s only

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 17: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

SEEAW Annex 2 List of Tables

v 00126 x (concentration of dissolved oxygen tn mgl)272rsquo1 when the concurrent concentration of dissolved oxygen is 2 5 mgA pH is 2 7 and temperature is 2 5 degrees Centigrade

vi 50126 x (concentration of dissolved oxygen in rng1)272 x 00003 x (PHJ~rsquo~rsquorsquo when the concurrent concentration of dissolved oxygen is lt 5 mgll pH Is c 7 and temperature is 15 degrees Centigrade

vii 00126 x (concentration of dissolved oxygen in ~ ~ g l ) ~ rdquo ~ x 05 when the concurrent concentration of dissolved oxygen is lt 5 mgll pH is 2 7 and temperature is lt 5 degrees Centigrade

x 00003 x (pHI4l7 x 05ldquo when the concurrent concentration of dissolved oxygen is lt 5 mgl pi4 is 7 and temperature 1s lt 5 degrees Centigrade

viii 00126 x (concentration of dissolved oxygen in

Uncontrolled if printed 13 of 34 v6 Dec 2015

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EPA Export 29-04-2017031836

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

For

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

insp

ectio

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pose

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

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pose

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ny ot

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

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ectio

n pur

pose

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

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ectio

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pose

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

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ectio

n pur

pose

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nt of

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 18: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Tabfe 3 List of Substances

1 Z-Trichloraethane

I 2-Dichloroethane

79-005 Farmer DSD List T7

107-06-2 WFD PSPHSOP T4

1 Ammonia (unionised) I 7664-41-7 I WFD UK Specific Pollutanf I T5

2-Chlorophenol

34-Dichloraaniline

44 of 34 Uncontrolled if printed u6 Dec 2015

- 95-57-8 Former DSO List T7

554-00-7 WFD UK Specific Pollutant T5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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uired

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ny ot

her u

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 19: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Annex 2 List of Tables

Benzo(ghi)perylene 191 -24-2 WFD PSlPHSlOP

Benzo(k)fluoranthene 207-08-9 WFD w w s i w Benzylbutylpfhalate 85-68-7 WFD UK Specific Pollutant

Bifenux 42576-02-3 WFD PSIPHSIOP

Biphenyl 92-52-4 Former DSD List

Boron (total) 7440-42-8 Non-statutory

Brominated diphenylether (pentaBDE only) 32534-81-9 WFD PSIPHSIOP

T4

T4

T5

T4

f 7

T8

T4

Bromine

Bromoxynil 1689-84-5 Non-statutory

I 7726-95-8 I Non-statutory

T8

I T8 I

Callcide (water) (active ingredient Tbflubenzeron) 83121-1 8-0 SEPA operational aquaculture

Bronopol 52-51-7 SEPA operational aquaculture I T9

CIO-13 Chloroalkanes 85535-84-8 I WFD PSPHSOP 7-4

T9

Carbendazim WFD UK Specific Pollutant

Cadmium

TS

~ I 7440-43-9 1 WFD PSPHSOP ~

Carbon tetrachloride 56-23-5 WFD PSPHSOP

I-- T4

T4

Galbide (sediment) active Ihgredient Teflubenzeron)

Chlorfenvinphos 470-90-6 WFD PSPHSOP

SEPA operatiohal aquaculture

T4

Chloride 16887-00-6 Non-statutory T8

Chlorine 7782-50-5 WFD UK Specific Pollutant T5

hpper 1 7440-50-8 I WFD UK Specific Pollutant I T5

Zhloroform (Trichloromethane) 67-66-3 WFD PSIPHSIOP T4

v6 Dec 2015 Uncontrolled if printed I5 of 34

hloronltrotoluenes 25567-88-4 Former DSD List

h[oroprapham 104-21-3 Non-statutory

2hlorothalanil 1847-45-6 WFD VK Specific Pollutant

2 hlorotoluron - 15545-48-9 Non-statutory 4

T7

T8

T5

T8

Xromium Ill j6065-83-1 WFD UK Specific Pollutant

gthrq-nium V1 I 8540-29-9 W O UK Specific Pollutant

hbalt 7440-48-4 Non-statutory

T5

T5

T8

ournaphos 56-72-4 Non-statutory

yanide 57-12-5 WFD UK Speclfic Pollutant

T8

T5

For

insp

ectio

n pur

pose

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EPA Export 29-04-2017031836

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

n pur

pose

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ny ot

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EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

insp

ectio

n pur

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

n pur

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 20: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Suppotling Guidance (WAT-SG-53)

Cybutyrne

Cyclodiene pesticides (aldrin dieldrin endrin isodrh)

Cyfluthrin

WFD PSlPHSlOP T4

NA WFD UK Specific Pollutant TS

68359-37-5 Non-statutory T8

Cypermethrin

DDT total

5231 5-07-8 WFD UK Specific Pollutant T5

WFD PSlPHSIOP T4h a until 22122018 I from 22f 220

WFD PSlPHSlOP T-4

DEHP (Di(2-ethylhexy1)phthalate)

Derneton

Dlchloromethane I 75-09-2 1 WFI3 PSlPHSlOP

117-81-7 WFD PSlPHSlOP T4

919-86-8 Former BSD List T7

I3i(2-ethylh~xyl)phthalate (DEHP)

Diazinon

Dibutylphlhalate (DBP)

Dichlo tobenzene

117-81-7 WFD PSlPHSlOP T4

333-41-5 WFD UK Specific Pollutant T5

84-74-2 Noh-statutory T8

25321-22-6 Non-statutory T8

Dicofol i 4 5-32-2 WFD PSlPHSlUP T4

3 oram ectin

Dicyclohexylphthalate (DCHP)

I l7704-25- Non-statutory I

84-61-7 Non-statutory T8

I T8

Iiethylphthalate (DEP) 84-66-2 Non-statutory

3Hlubenzuron 35367-38-5 Non-statutory

Dimethoate 60-51-5 WFD UK Specific Pollutant

T8

TE

T5

1 26225-79-6 I Non-statutory I

3imethylphfhalate (DMP)

Iioctylphthalafe (BOP)

131-1 1-3 Non-statutory T8

117-84-0 Non-statutory T8

enitrothion I 122-14-5 Former DSDLbt I n

~

3ioxins

3iuron 1

16 of 34 Uncontrolled if printed v6 Dec ZOl5

WFD PSlPHSlOP T4

330-54-1 WFD PSIPHSIOP T4 I I

ZDTA 60-00-4 Non-statutory T8

Zndosulfan 4 15-29-7 WFD PSPHSlOP T4

3Wyl benzene

xcis (active ingradient cypermethrin)

enchlorphos

100-41-4 Non-statutory T8

5231 5-07-8 SEPA operational aquaculture T9

299-84-3 Non-statutory Ti3

For

insp

ectio

n pur

pose

s only

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nt of

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se

EPA Export 29-04-2017031836

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

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ectio

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pose

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

insp

ectio

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pose

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se

EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

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ectio

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pose

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

For

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ectio

n pur

pose

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se

EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

For

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ectio

n pur

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

For

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 21: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Flucofuron

Flurnethrin

Fluoranthene

Fluoride I 16984-48-8 I Non-statutory T8 I

370-50-3 Non-statutory T8

69770-45-2 Non-statutory P8

2Q6-44-0 WFB PSIPHSIOP 7-4

Plusilazole 85509-1 9-9 Non-statutory T8

Formaldehyde - 50-00-0

Ralafhion I I -~ I I

Non-statutory f8

1 f21-75-5 I Former dSD List I Ti I

Glyphosate 38641-94-0 WFD UK Specific Pollutant 55 I I

Heptachlor and heptachlor epoxide I 1024-57-3 1 WFD PSPHSOP

v6 Dec 2015 Uncontrolled if printed 17 of 34

T4

Hexabrornocyclo dodecane (HBCDD)-

Hexachlorobenzene (HCB)

Hexachlorobutadlene (HCBD)

Hexachlorocyclohexane (HCH)

Hydrogen cyanide

Hydrogen sulphide

I mazethapyr

I hdeno(1ZBcd)pyrene

oxynil

ron

soproturon

vermectin

vermectin (fish farm)

indane (included ih HCH)

ead

Inuron

dalachlte Ereen -

nalachite Green (fish farm)

25637-99- WFD PSPHSOP 74

1 18-74-i WFD PSPHSOP T4

87-68-3 WFD PSlPHSlOP T4

608-79-1 WFD PSIPHSIOP T4

74-90-8 WFD UK Specific Pollutant T5

7783-06-4 Non-statutory T8

81 334-34-4 Non-statutory T8

193-39-5 WFD PSIPHSIOP T4

1689-83-4 don-sfatutory T8

7439-89-6 WFD UK Speclfic Pollutant T5

34123-59-6 WFD PSlPHSlOP T4

70288-86-7 Non-sfatutory T8

70288-86-7 SEPA operational aquaculture T9

7439-92-1 WFD PSlP HSlOP T4

608-73-1 WFD PSlPHSlOP r4

330-55-2 WFD UK Specific Pollutant T5

569-64-2 on-statutory T8 I

569-64-2 SEPA operational aquaculture -I-9

ilancozeb 801 8-OT-7 Non-statutory TB

rlaneb

danganese

ACPA

ilecoprop

12427-38-2 Non-statutory T8

7439-96-5 WFD UK Specific Pollutant T5

94-74-6 Non-statutory r a 93-65-2 WFD UK SpecIfic Pollutant T5

For

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ectio

n pur

pose

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EPA Export 29-04-2017031836

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

insp

ectio

n pur

pose

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nt of

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 22: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

rrst3r billsmngtt Supporfing Guidance (WAT-SG-53) Ir~twtlunmcnq

7439-97-8 WFD PSIPHSlOP

2032-65-7 WFD UK Specific Pollutant

Mercury

Methiocatb

T4

T5

UncontroHed if printed v6 Dec 201 5 I8 of 34

For

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EPA Export 29-04-2017031836

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

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ectio

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pose

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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right

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uired

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ny ot

her u

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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pose

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 23: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Quinaxyfen 124495-1 8- WFD PSIPMSIOP 7

Satmosan (active ingredient Atamethiphos) 35575-96-3 SEPA operational aquaculture

Silver 7440-22-4 Non-statutory

T4

T9

T8

Simazine 122-34-9 WFD PSIPHSIOP

Slice (sediment) (active ingredient Emamectin 37512-74- SEPA operational aquaculture Senzoate) 4

T4

T9

Slice (water) (active ingredient Emamectin Benzoate)

Sodium

Styrene

Sulcofuron (sutcofuran sodium) I

roluene

137512-74- SEPA operational aquaculture T9

7440-23-5 Non-statutory TB

4

4 00-42-5 Non-statutory T8

3567-25-7 Non-statutory T8 t

rrialate

rriazophos

iributyl phosphate

Sulphate I NA 1 Non-statutory

ldquorichloro benzenes

-richloroethylena

rsquorichloromethane (Chloroform) =

T8

lsquoriclosan

Tecnazene I 17-1 8-0 1 Non-statutory

Terbutryn 886-50-0 WFD PSlPHSlOP

Tetrachloroethane 79-34-5 WFD UK Specific Pollutant

T8

T4

T5

I WFD UK Specific Pollutant

- Tetrachloroethylene 127-1 8-4 WFD PSlPHSlOP T4

Thiabendazole 148-79-8

Tin 7440-33-5

v6 Dec 201 5 Uncontrolled if printed 190f34

Non-statutory T8

Non-statutory I T8 I 108-88-3 WFD UK Specific Pollutant

2303-17-5 Non-statutory

24017-47-8 Former DSD List

126-73-8 Non-statutory

36843-28-4 WFD PSIPHSIOP

92002-48-3 WFD PSIPHSIOP

79-01-6 WFD PSIPHSIOP

67-66-3 WFD PSIPHSlQP

T5

T8

T7

TB

T4

T4

T4

T4

rsquorifluralin 1582-09-8 WFD PSIPHSIOP T4

-riphenyl tin NA

ranadium 7440-62-2

Former DSD List T7

Non-statutory T8

$lene 1330-20-7 Former DSD List T7

iC 7440-66-6 WFD UK Specific Pollutant f5

For

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EPA Export 29-04-2017031836

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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pose

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 24: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

ate4 MAC

07

01

20

50

Ma AA

03

0f

06

a

S45 (class 4 ) 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

02

S E PAW

ole 4 EQS for WFD Priority Substances (including PHS) and qer PoIlutanfs (U Standards)

Ta Of

I Substance Statutory Instrument

Environm Fresh1

AA

Alachlor 281 5 SG Direction

2015 SG Direction

~

0014 00085

03 Alithracene d1

2015 SG Direction Atrazine 06

I d 201 5 SG Direction Benzene

Brominated I 014 201 5 SG Direction diphen y let her Cadmiu rn (dissol~ed)~~ 201 5 SG Direction 5045

(class 41 045 (class 2) 06 (class 3) 09 (class 4) i 5 class 5)

5008 (class 1) 008 (chis 2) 009 class 3) 01 5 (class 4) 025 (class 5 )

2015 SG Direction Carbon tetrachloride

CZ 0-1 3 Chloroalkanes 12

04

I

201 5 SG Direction ~

Chtorfenvinphos 0j 201 5 S G Direction

003 201 5 SG Direction Chlorp yrifos (C hlorpyrifos-eth yl) Cydocjien e pesticides (Aldrin Dieldrin Endrin I sodrin) DOT totalv

~

2015 SG Direction ~ = 0 0 1 z=0005

11025 2045 SG Direction

2015 SG Direction

0025

001

$0

20

13

18 02

001 00005

012 00063

005

12-Dichloroethane

Dichlorom ethane

Dj(2-ethyl hexyl)phthalafe

Diuron (DEW)

20 15 SO Direction

2015 SG Direction

1015 SG Direction

201 5 SG Direction

O

20

13

02 + 0604 Endosulfan 0005 I

012 1 30 iOZ 5 SG Direction 00063 Fluoranthene

Hexachlarobenzene 005 j 10 iOf5 SG Direction

20 of 34 Uncontrolled i f printed u6 Dec 2045

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EPA Export 29-04-2017031836

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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ectio

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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pose

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 25: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Annex 2 List of Tables icQlill Etyianrnt~ll Prokcwl kflnc

Hexach iorobutadlene

Hexachlorecyclohexane

lsoproturoll

Lead

06 I 1 06 55 201 5 SG Direction

002 201 5 SG Dlrection

I O 201 5 SG Direction

2Ot 5 SG Direction i4+

002 I 004 I 0002

03 1 O I 03 1 in

007 Mercury

Naphthalene

Nickel 23

130 2

R I 86 34r

Nonylphenol(4- l4 1 Nonylphenol)

OctyIphenol((4-(1133- 25 I tetrametfiylbutyl)-phe~ol))

Pentachlorobenzene 6 Pentachlorophenol 7 Pdyaromatic hydrocarbons (PAHs)Viii

3enzo(a)pyrene

Benzo(b)f[uoranthene

201 5 SC Direction

201 5 SG Direction

027

viii 001 7

0047 viii

alit 82 x 10 201 5 SG Direction

viii nla viii

Simazine

Tetrachfarot5thylene

4 4 I

10 10

10 40

00002 0001 5 00002 I I Trichlorobenzenes l l 04 04

25 25 I

- 1 _ 1 Trichloromethane chloroform

Trif turalin t 1

003 I [ Dicofol i4

perfluorooctane sulfonic acid and its derivatives

054 I I2015 SQ Direction 01 5 27 001 5

v6 Dec 201 5 Uncontrolled if printed 21 of34

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EPA Export 29-04-2017031836

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

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pose

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EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 26: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

AA -Annual Average MAC - Maxtmum Allowable Concentration

201 5 SG Difeckjon

2015 SG Direction

2015 SG Direction

201 5 8G Direction

2015 SG Direction

2015 SG Direction

2015 SG Direction

205 SG Direction

Notes 1 Directive 2008105EC of the European Parllament and of the Council on Environmental Quality

Standards in the Field of Water Policy amending and subsequently repealing Dlrectives 82176EEC 83513EEC 84156EEC 84f491fEEC and 86280fEEC and amending Directive 200060EC December 2008

2 The Scotland River Basin District (Standards) Amendment Directions 201 5

i Applies to all rivers and freshwater lochs ii Applies to all transitional waters and coastal waters iii Except where otherwise Indicated biota EQS relate to fish An alternative biota taxon or

another rnatrlx may be monitored if the EQS applied provides an equivalent level of protection for substances No 15 (fluoranthene) and No 28 (PAHs) the biota EQS refers to crustaceans and molluscs For the purpose of assessing chemical status monitoring of fluoranthene and PAWS in fish is not appropriate For substance No 37 (dioxins and dioxinlike compounds) the biota EQS relates to fish crustaceans and molluscs

iv Applies to congeners 284799 100 153 and 154 (pentabrornodiphenytether) v For Cadmium and its compounds the annual mean values vary dependent on the hardness of

the water as specified in five class categories (Class 1 i 40 mg CaC031 Class 2 40 to 50 rng CaCOSI Class 3 50 to lt I 00 rng CaC0311 Class 4 $00 to lt 200 mg CaCOJIt and Class 5 2 200 rng CaC03A) =

vi DDT total comprises the sum of the isomers I dl-klchloro-22 bis (p-chlorophenyl) ethane (CAS number 50-29-3 EU number 200-024-3) I I I-trichloro-i (o-chlorophenyl)-Z(p- chlorophenyl) ethane (CAS number 789-02-6 EU Number 222-332-5) 1 1-dichloro-22 bis (p chlorophenyl) ethylene (CAS number 72-55-9 EU Number 200-784-6) and I l-dlchtoro-22 bis [p-chlorophenyl) ethane (CAS number 72 54-8 EU Number 200-783-0)

Bfoavailable refers to the fraction of dlssolved metal that has the potential to contribute to toxic effects in aquatic animals or plants as determined in accordance with the method metals bioavailabllity assessment too$

viii For the group of priority substances of polyatomaBc hydrpcarbons (PAH) (No Z8gt the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene on the toxicity of which they are based Benzo(a)pyrene can be conddered as a marker for the other

vii Dissolv8d refers to the portion remaining following filtration through a 045pm membrane

22 of34 Uncontrolled if prihted v6 Dec 2015

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EPA Export 29-04-2017031836

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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ectio

n pur

pose

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nt of

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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insp

ectio

n pur

pose

s only

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nt of

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r req

uired

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ny ot

her u

se

EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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ectio

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uired

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se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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ectio

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 27: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

PAHs hence only benzo(afpyrene needs to be monitored for comparison with the biota EQS or the corresponding AA- EQS in water

ix These standards will be applied immediately to new applications (generally more cost effective for a new application to install treatment systems to meet these new standards rather than require changes before 22 December 2018) for existing discharges operators are to work towards these standards so that these standards are fully implemented from 22 December 20f8

x Dioxins comprise a number of PCDD polychlorinated dlhenzo-p-dioxins PCDF polychlorinated dibenzofurans PCEDL dioxin-like polychlorinated biphenyls a complete list can be found in the 2015 SG Rireotions TEQ toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors

xi Until 22d December 201 8 cypermethrin is classified as a specific pollufant The applicable standard until this date Is found in Table 5 for EQS for WFD UK Specific Pollutants

xii HBCDD isomers refers to I 35791 I-Hexabromocyctodadecane (CAS 25637-99-4) I 256910- Hexabromocyclododecane (CAS 31 94-55-6) cr-Hexabromacyclododecane (CAS 134237-50-6) P-Hexabromacyclododecane (CAS T34237-51-7) and y- ~exabromocyclododecane (CAS I 34237-52-8)

3 UKTPIQ (2014) River and Lake Assessment Method Specific Pollutants (Metals) Metal Bioavailabiiity Assessment Tool (M-BAT)ISBN 978-1 -906934-57-8

t

v6 Dec 201 5 Uncontrolled if printed 23 of 34

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EPA Export 29-04-2017031836

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

s only

Conse

nt of

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

For

insp

ectio

n pur

pose

s only

Conse

nt of

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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ectio

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nt of

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r req

uired

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ny ot

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se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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se

EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 28: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Table 5 EQS for WFD UK Specific Pollutants (UK standard^)^ - --

Environmental Quality Standard amptgi)

Freshwater Marine

_ _

AA SS-ile AA 85=ile - -- - See 21 Section 2

50 25

75 51 075 10

015 07

-

~- -

-

2i 111 oiii I _--

- -- _ _ 0035 12

34 06

32 47

1

32 - -

- _ I

376 + (2677 x ((DOC2) - 05)) where DOC = 1 ingll - -

- 1 5 1 5

00001 00004 00001 00004 1

001 002 001

42 140 0042 6

03 I 3 03 I 3

___

026 _ _ -

_ _ -

~

54 02 54 2 -

02

048 4 048 4

1 398 196 398

1000 io00

-

-

- -

2014 SG Direction Ammonia (unionised)

Arsenic (dlssofved) 2014 SG Direction

2014 SG Direction Benzyl butyl phthalate

Carbendazin 201 4 SG Direction

Chlorine 2014 SG Direction

Chlorothalonil 2014 SG Direction

2014 SG Direction Chromium VI (dissolved) ~

2014 SG Direction Chromium 111 (dtssolved) iv

Copper (bioavalahte in freshwater dissolved in marine) IJ

2014 SG Direction 376 where - DOG54 mgll 1 I

~ ~~

Cyanide (hydrogen cyanide) 201 4 SG Direction

2044 SG Direction Cypermethrin

2014 SG Direction Diazinon

24-DiclilorophenoI 2014 SG Direction

2014 SG Direction

2014 SG Direction

2014 SG Direction Dimethoate

2014 SG Direction Glyphosate

Iron (dissolved) iv 2034 SG Direction

Proposals for Environmental Quality Standards f i r Annex Vii Substwces UK TAG

The Scotland River Basin District (Surface Water Typology Envlronmental Standards Condition Limits an Groundwater Threshold Values) Direations 2014

Cypermethrjn sianda-d applied to existing discharges For new or varied applicatioos 5

refer to Table 4 EQS for WFD Priority Substances From 22 December 201 8 cypermethrin is classified as a Priority Substance

v6 Dec 20 15 24 of 34 Uncontrolled if printed

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EPA Export 29-04-2017031836

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

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ectio

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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uired

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ny ot

her u

se

EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

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ectio

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uired

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ny ot

her u

se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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ectio

n pur

pose

s only

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ny ot

her u

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

s only

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nt of

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uired

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se

EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

For

insp

ectio

n pur

pose

s only

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nt of

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right

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

For

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nt of

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for a

ny ot

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se

EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 29: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Manganese (bioavailable)v

M ecoprop

Methiocarb

Pendimethalin

Permethrin

Zinc (bioavailable in

AA - Annual Average

I23

18

001

03

0004

09

1 87

077

058

001

46

184

amp

028

Notes I Applies to all rivers and freshwater lochs

11 Applies to all transitional waters and coastal waters 111 Freshwater standards are for total available chlorine marine standards are for total residual

oxidant IV Pissolved refers to the portion remaining following filtration through a 045prn membrane V For capper zinc and manganese fhe annual averape standards for freshwater refer tu the

concentration of bioavallabfe metal This is the fraction of dissolved metal has the potential to contribute to toxic effects in aquaUc animals or plants as determined in accordance with the method metals bioavailability assessment tool(6) Refer to Table 10 for application of the marine copper standard

UKTAG (2Ct14) River and Lake Assessment Method Speciflc Pollutants (Metals)) Meial Bloavaitailily 6

Assessment Tool (M-BATJISBN 978-1-905934-57-6

v6 Dec 2015 Uncontrolled if prinfed 25 of34

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

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r req

uired

for a

ny ot

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EPA Export 29-04-2017031836

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

For

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ectio

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pose

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nt of

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uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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insp

ectio

n pur

pose

s only

Conse

nt of

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right

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

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nt of

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right

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 30: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

h n h l l brirmlritlll Supporting Guidance (WAT-SG-53) rte1ecllim Iblinci

Table 6 Application of Marine Copper Standards

Copper standard applicable depending on the information available on DOC

Yes No Yes

i ldquoBackground DOC concentrationrdquo (3DCiC) means the annual mean concentration of dissolved organic carbon (DOC) in the receiving water body in rngll

ii ldquoDischarge-derived DOC concentrationrdquo (DDOC) means the concentration of DOC at the edge of the mixing zone of a discharge in in mgA

ili ldquoDissolvedrdquo means the portion remaining following filtration through a 045pm membrane

iv In the absence of sitespecific data on either BDOC or DDOC SEPA will operate on the basis that the combhation of BDOC and DDCUC produces a concentration of 2 mgll in estuaries and coastal waters in Scotland

The standard is interpreted as follows 1) In the absence of information on BDOC and DDOC SEPA will apply the standard of 509 ugl in column A when determining applications

2) If applicants provide appropriate DDOC or BDOC information SEPA will take this into account in determining application For new discharges the estimated DDOC concentration should be derived using measured concentrations of DDOC at existing and suitably comparable discharges Where appropriate SEPA may agree typfcal DDOC concentrations on a sector by sector basis This document will be updated once any sector-wide estimates are in place However if in doubt the coordlnating officer should contact the relevant SEPA sector lead 3) Where

(a) in the absence of suitable ampfa SEPA has to assess the risk posed by a proposal using a copper standard based onrsquoan assumed BDDC or DDOG concentration and

(b) a proposal would cause that standard to be breached the coordinating officer should advisethe applicant that SEPA can only grant the application if (i) the applicant provides appropriate BDOC or DDOC information and 01) the copper standard derived using that information in accordance with Table 6 would not be breached

26 of 34 Uncontrolled if printed v6 Dec 20 rsquoi 5

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ectio

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 31: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Annex 2 List of Tables

25

Table 7 EQS for former DSD substances which are no longer considered to be discharged in significant quantities and as such no longer considered under WFD

-

Azinphos-methyl I 001 I

Bentazane 500

Biphenyl 25

C hloronitrotaluenes IQ

40

50

05

001

002

0005

100

300

0006

4-Chloro-3-methylphenol

2-C hlorophenol

Demeton 05

-

-

I

Fenifrothion I 001 l -

Triazophos

1 I I-Trtchloroethane

I i 2-Trichloroethane

Triphenyltin

Malathion 001

Ornethaate 001 - 0005 -

1 U0 -

400 002 -

Xylene I s o I - L4 - Annual Average MAC - Maximum Allowable Concentration

x

v6 Dec 2015 Uncontrolled if printed 27 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

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ectio

n pur

pose

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nt of

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uired

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EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

s only

Conse

nt of

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r req

uired

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ny ot

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se

EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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ectio

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nt of

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ny ot

her u

se

EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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ectio

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pose

s only

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nt of

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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ectio

n pur

pose

s only

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nt of

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 32: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

5 E PAP 5mHM Fniwmml Supporting Guidance VAT-33-53) Protraitxi

Fable 8 Non-statutory EQS values for other substances 1

Subs tan ce

15 (pW65) IO (pHs65) c 25 (pW65)

DETR (I 998)

EAlSNlFFER (1 998)

DETR 1998

HMSO (1489) (statutory in EbW

EA (1 997)

Abamectin 001 0003

Aluminium (reactive) -1 5 25

1005 Azamethiphes 002 005

I O (Total residual oxidant)

i 000 (interim guideline)

002

7000 Boron (total) 2000

Bromine 2 (Total residual oxidant)

5 (Total residua oxidant)

DOE (1 995) Bromexynll 4 00 1000 100 (interim guidellne)

EA (1 992 and 1999)

DOE (1 995)

Chloride 250000

40 (interim guideline)

10 (interim guideline)

2 (interim guideline)

Xoropropham

hiorotoluron

40

EA (I 996) 2 (interim guideline)

20 (interim guideline)

DETR (I 998) i 00 3 too 3 Zobalt dissolved)

Zoumaphos 003 01 003 01 euroSNIFFER (2000)

3yfluthrin 0001 (95ile) 0001 (95 He)

HMSO (1989) (statutory in LBrW)

DETR (1998) 45 8 40 3ibutylphthdate DBP)

3ichlorobenzene dissolved sum of all somers)

8

DETR 1998 20 2110 2b 200

~

NoEQS 1 proposed

DETR (5998) ~icyclohexylphthalate DCHP)

No EQS proposed

No EQS pmposed

200

No EQS proposed

DETR (1 998) gtietJIylphthallate DEP)

200 000

TI 4000 I

DETR (99973 d015

4000

0005 ago1

800

Iiflubenzuron

limethylphthalate DMP)

DETR (1998)

28 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

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r req

uired

for a

ny ot

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se

EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

For

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ectio

n pur

pose

s only

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nt of

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uired

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ny ot

her u

se

EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 33: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Dloctylphthalate 20 40 20 40 (DUP)

Dioxins No EQS No EQS NoEQS NoEQS proposed proposed proposed proposed

Doramectin 0001

EDTA 400

Ethofurn ssate No EQS

~

proposed

4000 400 140210 I I

Ethylbenzene

No EQS proposed

20 I I

004 0001 001

I I

Fenchlorphos 003

3000(lt50mg 15000 1 i5OOO CaC03lj 15000 (lt50 mg CaC03A)

I

1 (95ile) - I (95ilef

Flumethrin No EQS proposed

No EQS praaposed

I00

NoEQS NoEQS proposed proposed

guideline)

Fluoride (dissolved)

Flusilazole ~

Formaldehyde

Hydrogen sulphide (undissociated)

1000 (60 mg CaC0311) 5000 (gt50 rng CaC031)

No EQS proposed

5

025

No EQS proposed

NoEQS NoEQS proposed proposed

I

50

DETA (1 998)

NoPQS NoEQS proposed proposed

1

~

EAlSNlFFKR (1 999)

DETR (I 998)

DETR (1997)

No EQS proposed

I 0 0

DETR (1 997)

NoEQS NoEQS proposed proposed

10 (interim 100 guideline) (interim

guideline)

ENSNIFFER (ZOOT)

ENSNIFFER (2000)

I D

HMSO (1 989) (statutory in EampW

I O

~~

ENSNIFFER

loxyni I

Ivetrnectin

Malachite Green

ENSNIFFER (1 998)

proposed

10

00001

05

DETR (1998)

0001 00001 0001

DOE (I 993)

Mancozeb

Maneb

MCPA

Doe (I 993)

2

3

12 (pHx7) 80 (pH17)

DETR (4998)

90

DOE (1995)

2 20

DETR (I 998)

a0

Doamp (I 993)

3 30

DETR (2 997)

3ETR (j997)

3ETR 120 (pHlt7) 800 (pHgt7)

-1MSO (1 998~)

80 800

I

300 100 300

M evinphos -

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031836

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

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insp

ectio

n pur

pose

s only

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nt of

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r req

uired

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ny ot

her u

se

EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

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ectio

n pur

pose

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nt of

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r req

uired

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ny ot

her u

se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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pose

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uired

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 34: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

10000 3000

No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe) -

~

505 ~

0015 005 DETR (1997)

40 4 40 I I

DETR (1998)

500

5 (95lle)

50 (interim 500 EA (1 995) guideline) (interim

guideline]

25 HMSO ( 3 989) (95lIe) (statutory in EampW

NoEQS - proposed

io I (interim I O (interim guideline) guideline)

1 I

EA (1 999)

DOE i 9)

Monochlorobenzene No EQ5 proposed

DOE (1989) 1 No EQS proposed

250

No EQS proposed

50

No EQS proposed

Monochlorophenols (3-chloraphenol 4- chlorophenol)

250 ENSNIFFER 1997

I I

30000 DETR (1997) ~ ~

NTA 1000

Uxblinic acid 1 DOE (1994) No EQS proposed

No EQS proposed

No EQS proposed

No EQS proposed

005 (95iIe)

6

Oxytetracycline DOE (1 994)

PCSDs HMSO ($989) (statutory in EampW)

DETR (1997) Pendimethalin I 5

Pirimicarb 5

Pirirniphos-methyl 001 5

4 Prochloraz

Propetamphos

Propyzarn [de

003 01

I00 i o 0 1000 DETR (I 998) I I I

Silver (dissolved) 005 DOE (1 996)

Sodium EA (I 999) No EQS proposed

Vo EQS

Styrene 50

Sulcofuron

Sulphate 1

400000

rechzizene (i) I

rhlabendazole 5 50 (interim DOE (I 995) guideline) I 5 (interim

guideline) 50

I 1 0 1 - 1 DOE (1989) Fin (total for reshwater dissolved br marine

rrjallate + 025 325 5 DETR (1 998)

rributyl phosphate 1 500 1 50 DETR (1 9931 500

30 of 34 Uncontrolled if printed v6 Dec 20 15

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insp

ectio

n pur

pose

s only

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nt of

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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pose

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nt of

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right

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r req

uired

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ny ot

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se

EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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ectio

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nt of

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uired

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ny ot

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se

EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 35: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Vanadium (total) (ii) 20 (class 1) I 0 0 60 (class 2)

Table 9 Operational Standards for Aquaculture

Table 9a Operational Water Quafity Standards used by SEPA for regulating

HMSO (1 989) (statutory in EampW)

the use of ch

Pyceze (active ingredient Branopol)

Excis (active ingredient Cypermethrin)

Aquaguard (active ingredient Dichlorvos)

Slice (actlve ingreblent Emamectin Benzoate)

lverm ectin

Malachite Green

AMX (active ingredient Delrnethrin)

Calicide (actlve Ingredient Tef lubenzeron)

micais in i paculture

Use not permitted

1 I I

0OOdZZ 2 I f I I

Use not permitted

Use not permitted

90 (after 3 hrs) 60 (after 6 hrs) 40 (after I 2 hrs) 20 (after 24 hrs)

Oa3 ng

Reference

SEPA Polcy 17 (I 998)

~

SEPA Guidance (2002)

SEPA Policy 30 (4 998)

DOE (1991)

SEPA Recommendation (1 949)

SEPA Guidance (2002)

SEPA Guidance (2008)

SEPA Policy 29 (I 999)

v6 Dec 20d5 Unconttolled if printed 31 of 34

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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ectio

n pur

pose

s only

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nt of

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right

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r req

uired

for a

ny ot

her u

se

EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

For

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ectio

n pur

pose

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nt of

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uired

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ny ot

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se

EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 36: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

kSiiill 5nilrnHlcll Supporting Guidance (WAT-SG-53) Prslcaunn Aqcnc

Table 9b Operational Sediment Quality Standards used by SEPA for regulating She

Slice (active ingredient Ernameclin Benzoate)

Caiicide (active ingredient feflftubenzeron)

se of chemicals I aquaculture

AA

100 mglkg-dry weight (5cm core depth applied withh the immediate under cage impact zone up to 25m from cage edges)

0763 pglkg-wet weight (5cm core depth outside zone of effects area 1 OOM from edge of cages increased up to 150m whera sltong directional currents exist)

20 pglkg-dry weight (5cm core depth outstde zone of effects area 1 OOm from edge of cages increased up to 1501-11 where strong directional currents exist)

SEPA Recommendation (I 999)

SEPA Policy 29 (19991

AA - Annual Average MAC - Maximum Allowable Concentration

WAT-Se-53-CALC Marine Copper Standards Calculator (use With WAT-SG-53-TG)

This document not available for SEFA website users For information this is a dedicated spreadsheet in which you can enter the corresponding DDOC andlot BDOG values to calculate the DOC-adjusted marine copper standard

32 of 34 Uncontrolled if printed v6 Dec 2015

For

insp

ectio

n pur

pose

s only

Conse

nt of

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right

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r req

uired

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ny ot

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se

EPA Export 29-04-2017031837

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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ectio

n pur

pose

s only

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nt of

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r req

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ny ot

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 37: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

See the Water gtGuidance pages of the SEPA website for Guidance and other docurn en tation (www sepa ofg ulutvaferw~afer_regolationguidance aspx)

All references to externd documents are listed on this page along with an indicafive URL to help locate the document The full path is not provided as SEPA can not guarantee its future location

Key Documents m GIs Pages SEPA lnfranet E Science Advice Helpdesk details on Science Advice page SEPA fntranef

Standards Direcfions (on SEPA lnfranet euronvironmental Standards page)

I WAT-SG-21 Environments Standards for River Morphology

Scottish Government Publications The Scatland River Basin Districf (Surface Water Typdugy Environmental Standards Condition Limits and Groundwater Threshold Values) Directions 2014 (Aug ZOI4)

Environrnenfal Standards Condition limits m d Gmundwater Threshold Values) (Scofaand) Directions 2014 (Aug 201 4)

J Scotland River Basin Rjsfrkf (Standards) Amendment Directions 20f5 (Sep 2015)

Solway Tweed (Standards) Amendment Directions 2015 (Sep 2015)

H The Solway Tweed River Basin District (Swface Water Typofogy

European Legislation

Annex X offhe Wafer Framework Directive CELEX 32001 D2455 (httpleur-

I Technical Guidance Dswmenf on risk assessment

lexeurapaeuhomepage html)

In support of Commisdon Directive 9367EEC on risk assessment for new notified substances Coinmission Regulation (EC) No 448894 on risk assessment for existing substances Directive 9818EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Part II 2003 Cat No LB-NB-204 1 8-EN-C (h~psboohshop europa euemhome)

v6 Dec 201 5 Uncontrolled if printed 33 of 34

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nt of

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EPA Export 29-04-2017031837

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables
Page 38: &A · Booklet printing or else double-sided, Duplex (2-on-I) A4 printing {both four pages per A4 Always refer to the onllne document for accurate and up-to-date information. sheel)

Smiidi biirmmtnl Supporting Guidance VAT-SO-53) Protulios hac

- eurond of Document -

lt

34 of 34 Uncontrolled if printed v6 Dec 2015

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EPA Export 29-04-2017031837

  • 3 Environmental Quality Standards for Surfgce Waters
    • Priority Substances di
    • 32 Speclfrc Fdkhnts
    • Substances under the repealed Dangerous Substances Directive
    • 34 Non-statutory EQS
      • 4 Operational Aquaculture Standards If
      • Annex 1 GIS Layer
      • Annex 2 List of Tables