4d printing srp & smp

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4D PRINTING SRP & SMP 01-2021

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4D PRINTING

SRP & SMP

0 1 - 2 0 2 1

Additive ManufacturingDigital to Physical

M. Young, ALL3DP Company, 2016.

Additive Manufacturing4D PRINTING OF STIMULI-RESPONSIVE AND SHAPE MEMORY POLYMERS USING THE FFF TECHNOLOGY

A. Stern1,3,N. Dresler1, A. Ulanov1, Y. Aharoni1 , M. Aviv1, and D. Ashkenazi2

1School of Mechanical Engineering, Afeka Academic College of Engineering, Tel Aviv 6910717, Israel

2School of Mechanical Engineering, Tel Aviv University, Ramat Aviv 6997801, Israel

3Department of Materials Engineering, Ben-Gurion University of the Negev, Beer Sheva 8410501, Israel

In the last few years four-dimensional (4D) printing technologies have attained growing worldwide interest and they are

considered the "next big thing". The aim of this presentation is to provide three examples of stimuli-responsive polymer (SRP)

applications additively manufactured (AM) by the fused filament fabrication (FFF) technique and two examples of PLA based

shape memory polymer (SMP) applications. A CCT BLUE filament of thermo-responsive polymer was chosen to produce a

water temperature indicator, which changes the color when the temperature is increased; a CCU RED filament of photo-

responsive polymer was used to produce a sunlight / UV indicator bracelet; a transparent PLA CLEAR polymer, a CCU RED

photo-responsive polymer, and an electrically conductive PLA polymer were selected to produce a business card stand. A PLA

based filament of eSUN SMP was used to print two preliminary applications: a spring and a vase. We trust that these examples

will help to increase the interest in FFF 4D printed stimuli-responsive polymers and shape memory polymers possible

applications. Much R&D remains to be done in designing the objects and develop the FFF printing parameters taking advantage

of SRPs and SMPs being developed for this technology.

Let’s Start with 2D Printing (ADOBE)

Digital to Physical

➢ Additive Manufacturing process

Overview of Additive Manufacturing

Additive Manufacturing

Process

Subtractive Manufacturing

Process

ECONOMICS OF AM

AM – GE - FUEL NOZZLE

Additive Manufacturing

In his 2013 TED Talk (TED stands for technology, entertainment, and

design), Skylar Tibbits, the co-director of the MIT Self-Assembly Lab and

a pioneer of 4D printing, demonstrated how 3D-printed materials can

adapt to their surroundings (water, in his example)

FUSED DEPOSITION MODELING

3D PRINTINGVS4D PRINTING

3D or 4D

STIMULI-RESPONSIVE POLYMERS (SRPS)

WAYS TO ACTIVATION OF SRPS

• * Light induced SRPs

• * Thermal responsive SRPs

• * Electrical induced SRPs

• Magnetically induced SRPs

• Ultrasound activated SRPs

• Water/Solvent activated SRPs

צבעמשנההמדגיםUVלחשיפת כתגובה

intense sun light low sun light

Graphite based

Conductive Polymer

Graphite ~10-5 ρ (Ω•m)

SPLINT - SUPPORT FOR A BROKEN BONE WHILE IT HEALS

FDMטכנולוגיה •

ABSM30I(Stratasys)חומר •

שעות14זמן הדפסה •

Stratasys Fortusמדפסת • 450mc

Synergy3DMed

דוגמא לסד ידקצירטלידיעלבוצע הבנייהתהליך

Synergy3DMed

למוליכיםלותתע :דד יספסים מחליפי צבע

במגע עם היד

~36C

SHAPE MEMORY POLYMERS (SMPS)

SHAPE -MEMORY POLYMERS (SMPS)

SHAPE MEMORY POLYMERS (SMPS)

SHAPE MEMORY POLYMER

• SMPeSUN 4D filament e4D-1

white (Esun Industrial Co., Ltd)

filament diameter 1.75 mm, and

spool weight of 0.5 kg.

FUSED DEPOSITION MODELING (MP)

SHAPE MEMORY POLYMER(MECHANICAL PROPERTIES)

DENSITY ~1.19 g/cc

SHAPE MEMORY POLYMER

SHAPE MEMORY POLYMER

ECONOMICS OF AM

Something That Moves Something, created by Ohad Meyuhas, architect

Thank you for your attention!

4D Printing SRP & SMP

4D Printing SRP & SMP

[email protected]