3rd year (5th and 6 semesters) (effective from july – 2011) engg-phyc 5... · 10 patel s b,...

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SCHEME OF EXAMS. AND SYLLABI

5 Years (10 Semesters) Integrated M. Sc. (Engineering Physics)

for Session 2011-12

3rd Year (5th and 6th semesters)(Effective from July – 2011)

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5 Years (10 Semesters) – M.Sc. - Engineering Physics Degree(After 3 Years / 6 Semesters, students may be awarded B Sc -Engineering Physics Degree)

3rd Year5th Semester

Code Paper Marks Time (Hours)

PH - 501 Quantum and Laser Physics 50+10* 3 Hours

PH - 502 Nuclear Physics 50+10* 3 Hours

Hu- 501 Engineering Economics and Principle of Management Science

50+10* 3 Hours

CH- 501 Inorganic Chemistry-V 35+5* 3 HoursCH- 502 Physical Chemistry-V 35+5* 3 HoursCH- 503 Organic Chemistry-V 35+5* 3 HoursMT- 501 Engineering Mathematics - V 80+20* 3 HoursPH -Lab Physics Lab †CH -Lab Chemistry Lab †ES- 501 Environmental Science and

Engineering (qualifying)50+10*(Grade$)

3 Hours

Total 400*Internal Assessment marks$ Grade: A-Excellent (Marks above 60 %), B-Good (Marks below 60 % but above 40 %)†The practical Examination will be held in 6th semester

6th SemesterCode Paper Marks Time (Hours)

PH – 601 Solid State and Nano Physics 50+10* 3 HoursPH – 602 Atomic and Molecular

Spectroscopy50+10* 3 Hours

CH- 601 Inorganic Chemistry-VI 35+5* 3 HoursCH – 602 Physical Chemistry-VI 35+5* 3 HoursCH – 603 Organic Chemistry-VI 35+5* 3 HoursMT – 601

Engineering Mathematics-VI 80+20* 3 Hours

Tch – 601

Manufacturing Processes and Workshop Technology

50+10* 3 Hours

PH – Lab Physics Lab 100 6 HoursCH – Lab Chemistry Lab 100 6 HoursCS-601 Fundamental of Computers and

Programming in C (qualifying)50+10*(Grade$)

3 Hours

Total 600*Internal Assessment marks$ Grade: A-Excellent (Marks above 60 %), B-Good (Marks below 60 % but above 40 %)

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Syllabus-mscep-56 (111114)M. Sc. Engineering Physics

Semester-VPhysics – PH-501

Paper : Quantum and Laser PhysicsMax. Marks: 60

Theory: 50Internal Assessment: 10

Time: 3 hoursNote:-

1. Nine Questions will be set in total

2 Question number 1 will be compulsory and will be based on the conceptual aspects of entire syllabus. This question may have five parts and the answer should be in brief but not in Yes/ No.

3 Four more questions are to be attempted, selecting one question out of two questions set from each unit. Each question may contain two or more parts. All questions will carry equal marks.

4 20% numerical problems are to be set.

5 Use of scientific (non-programmable) calculator is allowed.

Unit IOrigin quantum physics (Experimental basis)Overview, scale of quantum physics, boundary between classical and quantum phenomena, Photon, Photoelectric effect, Compton effect (theory and result), Frank-Hertz experiment, de-Broglie hypothesis. Davisson and Germer experiment, ·G.P. Thomson experiment. Phase velocity, group velocity and their relation. Heisenberg's uncertainty principle. Time energy and angular momentum, position uncertainty. Uncertainty principle from de Broglie wave. (Wave-particle duality). Gamma Ray Microscope, Electron diffraction from a slit. Derivation of 1-D time-dependent Schrodinger wave equation (subject to force, free particle). Time-independent Schrodinger wave equation, eigen values, eigen functions, wave functions and its significance. Orthogonality and Normalization of function, concept of observer and operator. Expectation values of dynamical quantities, probability current density

Unit IIApplication of Schrodinger wave equation:

Free particle in one-dimensional box (solution of Schrodinger wave equation, eigen functions, eigen values, quantization of energy and momentum, nodes and anti nodes, zero point energy).

One dimensional step potential E > Vo (Reflection and Transmission coefficient)

One dimensional step potential E < Vo (penetration depth calculation).

One dimensional potential barrier, E > Vo (Reflection and Transmission coefficient)

One-dimensional potential barrier, E < Vo (penetration or tunneling coefficient).

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Solution of Schrodinger equation for harmonic oscillator (quantization of energy, Zero-point energy, wave equation for ground state and excited states).

Unit IIILaser Physics –IAbsorption and emission of radiation, Main features of a laser: Directionality, high intensity, high degree of coherence, spatial and temporal coherence, Einstein's coefficients and possibility of amplification, momentum transfer, life time of a level, kinetics of optical absorption (two and three level rate equation, Fuchbauer landerburg formula).population inversion: A necessary condition for light amplification, resonance cavity, laser pumping, Threshold condition for laser emission, line broadening mechanism, homogeneous and inhomogeneous line broadening (natural, collision and Doppler broadening).

Unit IVLaser Physics – II He-Ne laser and RUBY laser (Principle, Construction and working), Optical properties of semiconductor, Semiconductor laser (Principle, Construction and working), Applications of lasers in the field of medicine and industry.

References:1 L I Schiff, Quantum Mechanics2 Bransden B H and Joachain C J, Quantum Mechanics (2000), Pearson Education, New Delhi3 Liboff R L, Introductory Quantum Mechanics4 Eisberg R M and Resnick R, Quantum Physics of Atoms Molecules, Solids, Nuclei and Particles, Wiley Eastern Ltd, New Delhi5 Verdeyen J T, Laser Electronics PHI, New Delhi6 Thorenton S T and Rex A, Modern Physics, (2007) Cengage Learning, New Delhi7 Taylor J R, Zafiratos C D and Dubson M A, Modern Physics, 2nd Ed (2004), PHI, New Delhi8 Laud B B, Laser Physics

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M. Sc. Engineering PhysicsSemester-V

Subject: Physics (Paper Code: EP 502)Physics – PH-502

Paper : Nuclear PhysicsMax. Marks: 60


Time: 3 hoursNote:-

1 Nine Questions will be set in total





Unit I

Nuclear Structure and Properties of Nuclei

Nuclear composition (p-e and p-n hypotheses), Nuclear properties; Nuclear size, spin, parity, statistics, magnetic dipole moment, quadruple moment (shape concept). Determination of mass by Bain-Bridge, Bain-Bridge and Jordan mass spectrograph. Determination of charge by Mosley Law. Determination of size of nuclei by Rutherford Back Scattering. mass and binding energy, systematic of nuclear binding energy, nuclear stability

Unit II

Nuclear Radiation decay Processes

Alpha-disintegration and its theory. Energetics of alpha-decay, Origin of continuous beta spectrum (neutrino hypothesis), types of beta-decay and energetics of beta-decay. Nature of gamma rays, Energetics of gamma rays.

Radiation interaction

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Interaction of heavy charged particles (Alpha particles); Energy loss of heavy charged particle (idea of Bethe formula, no derivation), Range and straggling of alpha particles. Geiger-Nuttal law. Interaction of light charged particle (Beta-particle), Energy loss of beta-particles (ionization), Range of electrons, absorption of beta-particles. Interaction of Gamma Ray; Passage of Gamma radiations through matter (Photoelectric, Compton and pair production effect) electron-positron annihilation. Absorption of Gamma rays (Mass attenuation coefficient) and its application.

Unit III

Nuclear Accelerators

Linear accelerator, Tendem accelerator, Cyclotron and Betatron accelerators.

Nuclear Radiation Detectors.Gas filled counters; Ionization chamber, proportional counter, G.M. Counter (detailed study), Scintillation counter and semiconductor detector.

Unit IV:Nuclear reactions.Nuclear reactions, Elastic scattering, Inelastic scattering, Nuclear disintegration, Photonuclear reaction, Radiative capture, Direct reaction, Heavy ion reactions and spallation Reactions. Conservation laws, Q-value and reaction threshold.

Nuclear Reactors.Nuclear Reactors, General aspects of Reactor Design. Nuclear fission and fusion reactors, (Principle, construction, working and use).

References:

1 Kaplan I, Nuclear Physics, 2nd Ed (1962), Oxford and IBH, New Delhi

2 Sriram K, Nuclear Measurement Techniques, (1986), AEWP, New Delhi

3 Tayal D C, Nuclear Physics (1994), HPH, Bombay

4 Ghoshal S N, Atomic and Nuclear Physics Vol II (1994), S Chand & Co New Delhi

5 Srivastava B N, Basic Nuclear Physics, (1993), Pragati Prakashan Meerut

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6 Halliday, Introductory Nuclear Physics, Asia Publishing House, New Delhi

7 Sood D D, Ready A V R and Ramamoorthy, Fundamentals of Radiochemistry,

IANCAS (2007), BARC, Bombay

8 Cohen B L, Comcepts of Nuclear Physics (1998), Tata Mc Graw Hill, New Delhi

9 Krane K S, Introductory Nuclear Physics (1988), John Wiley & Sons New Delhi

10 Patel S B, Nuclear Physics (1992), Wiley Eastern Ltd, New Delhi

11 Roy R R and Nigam B P, Nuclear Physics (1993), Wiley Eastern Ltd New Delhi.

M. Sc. Engineering PhysicsSemester-V

Subject: Humanities (Paper Code: Hu 501Paper: Engineering Economics and Principle of Management Science

Max. Marks: 60Theory : 50

Internal Assessment: 10Time: 3 hours

Note:-1. Nine questions will be set in total. 2. Question no. 1 will be compulsory and based on the conceptual aspects of the entire

syllabus. This question may have 5 parts and the answer should be in brief but not in Yes/No.

3. Four more questions are to be attempted, selecting one question out of two questions set from each unit. Each question may contain two or more parts. All questions will carry equal marks.

Unit1:

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IntroductionNature and significance of Economics, Meaning of Science, Engineering and Technology and their relationship with economic development

Unit2Basic ConceptThe concept of demand and supply, Elasticity of Demand and Supply, Indifference Curve analysis, Price Effect, income Effect and Substitution Effect Unit3Money and BankingFunctions of money, Value of Money, Inflation and measures to Control it, Brief idea of functions of banking system, viz, Commercial and central banking, business fluctuations.

Unit4Principle of Management ScienceIntroductions Definition, Nature and Significance of Management, Evaluation of management through, Contributions of Max Weber, Taylar and fayal

References Books:1.Dewtt, K.K, Modern Economic Theory, S. Chand & Co.2.Luthers Fred, Organizational Behavior.3.Prasad L.M, Principals of Management.4.A.W. Stonier & D.C Horgne, A. Text Book of Economic Theory, Oxford Publishing House Pvt. Ltd.

M. Sc. Engineering PhysicsSemester – V

Subject: Chemistry (Paper Code: CH-501)Paper: Inorganic Chemistry-V

Max. Marks: 40 Theory: 35

Internal Assessment: 5 Time: 3 hrs.




Unit I

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Metal-ligand Bonding in Transition Metal ComplexesLimitations of valence bond theory, an elementary idea of crystal-field theory, crystal field splitting in octahedral, tetrahedral and square planar complexes, factors affecting the crystal-field parameters.

Unit IIThermodynamic and Kinetic Aspects of Metal ComplexeA brief outline of thermodynamic stability of metal complexes and factors affecting the stability, substitution reactions of square planar complexes of Pt(II).

Unit IIIMagnetic Properties of Transition Metal ComplexeTypes of magnetic behaviour, methods of determining magnetic susceptibility, spin-only formula. L-S coupling, correlation of s and eff values, orbital contribution to magnetic moments, application of magnetic moment data for 3d-metal complexes.

Unit IVElectron Spectra of Transition Metal ComplexesTypes of electronic transitions, selection rules for d-d transitions, spectroscopic ground states, spectrochemical series. Orgel-energy level diagram for d1 and d9 states, discussion of the electronic spectrum of [Ti(H2O)6]3+ complex ion.

References:-1. Concise Inorganic Chemistry by: J. D. Lee.2. Inorganic Chemistry by: Puri, Sharma and Kalia.


Subject: Chemistry (Paper Code: CH-502)Paper: Physical Chemistry-V






Unit I

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Quantum Mechanics-IBlack-body radiation, Plank’s radiation law, photoelectric effect, heat capacity of solids, Compton effect, wave function and significance of , postulates of quantum mechanics, quantum mechanical operator, commutation relations, Hamiltonian operator, Hermitian operator, average value of square of Hermitian as a positive quantity, Role of operators in quantum mechanics, To show quantum mechanically that position and momentum cannot be predicated simultaneously, Determination of wave function & energy of a particle in one dimensional box, Pictorial representation and its significance,

Unit IIPhysical Properties and Molecular StructureOptical activity, polarization – (clausius – Mossotti equation). Orientation of dipoles in an electric field, dipole moment, induced dipole moment, measurement of dipole moment-temperature method and refractivity method, dipole moment and structure of molecules, Magnetic permeability, magnetic susceptibility and its determination. Application of magnetic susceptibility, magnetic properties – paramagnetism, diamagnetism and ferromagnetics.

Unit IIISpectroscopy:Introduction: Electromagnetic radiation, regions of spectrum, basic features of spectroscopy, statement of Born-oppenheimer approximation, Degrees of freedom.

Rotational SpectrumDiatomic molecules. Energy levels of rigid rotator (semi-classical principles), selection rules, spectral intensity distribution using population distribution (Maxwell-Boltzmann distribution), determination of bond length, qualitative description of non-rigid rotor, isotope effect.

Unit IVVibrational spectrumInfrared spectrum: Energy levels of simple harmonic oscillator, selection rules, pure vibrational spectrum, intensity, determination of force constant and qualitative relation of force constant and bond energies, effects of anharmonic motion and isotopic effect on the spectra., idea of vibrational frequencies of different functional groups.

Raman Spectrum:

Concept of polarizibility, pure rotational and pure vibrational Raman spectra of diatomic molecules, selectin rules, Quantum theory of Raman spectra.

References:-1. Book of Physical Chemistry (vol. II) by: K. L. Kapoor2. Introduction to Chemical Thermodynamics by R P Rastogi and R R Mishra3. Physical Chemistry by: O. P. Aggarwal.4. Thermodynamics by I M Klotz and R N Resenbess

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Subject: Chemistry (Paper Code: CH-503)Paper: Organic Chemistry-V






Unit I

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NMR SpectroscopyPrinciple of nuclear magnetic resonance, the PMR spectrum, number of signals, peak areas, equivalent and nonequivalent protons positions of signals and chemical shift, shielding and deshielding of protons, proton counting, splitting of signals and coupling constants, magnetic equivalence of protons.

Unit IIPMR spectraDiscussion of PMR spectra of the molecules: ethyl bromide, n-propyl bromide, isopropyl bromide, 1, 1-dibromoethane, 1,1,2-tribromoethane, ethanol, acetaldehyde, ethyl acetate, toluene, benzaldehyde and acetophenone. Simple problems on PMR spectroscopy for structure determination of organic compounds.

Unit IIICarbohydrates Classification and nomenclature. Monosaccharides, mechanism of osazone formation, interconversion of glucose and fructose, chain lengthening and chain shortening of aldoses. Configuration of monosaccharides. Erythro and threo diastereomers. Conversion of glucose into mannose. Formation of glycosides, ethers and esters. Determination of ring size of glucose and fructose. Open chain and cyclic structure of D(+)-glucose & D(-) fructose. Mechanism of mutarotation. Structures of ribose and deoxyribose.

Unit IVDisaccharides and PolysaccharidesAn introduction to disaccharides (maltose, sucrose and lactose) and polysaccharides (starch and cellulose) without involving structure determination.

Organometall ic CompoundsOrganomagnesium compounds: the Grignard reagents-formation, structure and chemical reactions. Organozinc compounds: formation and chemical reactions. Organolithium compounds: formation and chemical reactions. References:-

6 Organic Chemistry by: Morrison Boyd.7 Advanced Organic Chemistry (vol. I & II) by: I. L. Finar.8 Introduction to Spectroscopy by Y R Sharma9 Introduction to spectroscopy by D L Pavia, G M George and s Kriz10 Advanced Organic Chemistry by F a Carey and R J Suns

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Subject: Mathematics (Paper Code: MT-501)Paper: (Engineering Mathematics-V)






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Unit-1Set TheoryIntroduction to set theory, Set operations, Algebra of sets, combination of sets, Duality, Finite and Infinite sets, Classes of sets, Power Sets, Multi sets, Cartesian Product, Representation of relations, Types of relation, Binary Relations, Equivalence relations and partitions, Partial ordering relations and lattices, Mathematics Induction, Principle of Inclusion & Exclusion, Propositions.

Function and its types, Composition of function and relations, Cardinality and inverse relations. Functions & Pigeo principles.

Unit-2Propositional CalculusBasic operations: AND(^), OR(v), NOT(~), Truth value of a compound statement, propositions, tautologies, contradictions.

Techniques Of CountingRules of Sum of products, Permutations with and without repetition, Combination.

Recursion And Recurrence RelationPolynomials and their evaluation, Sequences, Introduction to AP, GP and AG series, partial fractions, linear recurrence relation with constant coefficients, Homogeneous solutions, Particular solutions, Total solution of a recurrence relation using generating functions.

Unit-3Algebric StructuresDefinition, elementary properties of algebric structures, examples of a Monoid, Submonoid, Semigroup, Groups and rings, Homomorphism, Isomorphism and Automorphism, Subgroups and Normal subgroups, Cyclic groups, Integral domain and fields, Cosets, Lagrange’s theorem, Rings, Division Ring.Unit-4Graphs And TreesIntroduction to graphs, Directed and Undirected graphs, Homomorphic and Isomorphic graphs, Subgraphs, Cut points and Bridges, Multigraph and Weighted graph, Paths and circuits, Shortest path in weighted graphs, Eurelian path and circuits, Hamilton paths and circuits, Planar graphs, Euler’s formula, Trees, Rooted Trees, Spanning Trees & cut-sets, Binary trees and its traversals

Reference Book:1 Elements of Discrete Mathematics C.L Liu, 1985, McGraw Hill2 Concrete Mathematics: A Foundation for Computer Science, Ronald Graham, Donald Knuth and Oren Patashik, 1989, Addison-Wesley.3 Mathematical Structures for Computer Science, Judith L. Gersting, 1993, Computer Science Press. 4 Applied Discrete Structures for Computer Science, Doerr and Levasseur, (Chicago: 1985,SRA5 Discrete Mathematics by A. Chtewynd and P. Diggle (Modular Mathematics series), 1995, Edward Arnold, London,

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6 Schaums Outline series: Theory and problems of Probability by S. Lipshutz, 1982, McGraw-Hill Singapore7 Discrete Mathematical Structures, B. Kolman and R.C. Busby, 1996, PHI8 Discrete Mathematical Structures with Applications to Computers by Tembley & Manohar, 1995, Mc Graw Hill.9 Discrete Mathematics & Structure, Satyender Bal Gupta, 2nd Ed., Luxmi Pub.

M. Sc. Engineering PhysicsSemester – VI

Subject: Environmental Studies (Paper Code: ES-501)Paper : ENVIRONMENTAL SCIENCE AND ENGINEERING


Internal Assessment: 10 Time: 3 hrs




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Unit IENVIRONMENT, ECOSYSTEMS AND BIODIVERSITYDefinition, scope and importance of environment – need for public awareness – concept of an ecosystem – structure and function of an ecosystem – producers, consumers and decomposers – energy flow in the ecosystem – ecological succession – food chains, food webs and ecological pyramids – Introduction, types, characteristic features, structure and function of the (a) forest ecosystem (b) grassland ecosystem (c) desert ecosystem (d) aquatic ecosystems (ponds, streams, lakes, rivers, oceans, estuaries) – Introduction to biodiversity definition: genetic, species and ecosystem diversity – biogeographical classification of India – value of biodiversity: consumptive use, productive use, social, ethical, aesthetic and option values – Biodiversity at global, national and local levels – India as a mega-diversity nation – hot-spots of biodiversity – threats to biodiversity: habitat loss, poaching of wildlife, man-wildlife conflicts – endangered and endemic species of India – conservation of biodiversity: In-situ and exsitu conservation of biodiversity. Field study of common plants, insects, birds Field study of simple ecosystems – pond, river, hill slopes, etc.

Unit IIENVIRONMENTAL POLLUTION Definition – causes, effects and control measures of: (a) Air pollution (b) Water pollution (c) Soil pollution (d) Marine pollution (e) Noise pollution (f) Thermal pollution (g) Nuclear hazards – soil waste management: causes, effects and control measures of municipal solid wastes – role of an individual in prevention of pollution – pollution case studies – disaster management: floods, earthquake, cyclone and landslides. Field study of local polluted site – Urban / Rural / Industrial / Agricultural.

Forest resources: Use and over-exploitation, deforestation, case studies- timber extraction, mining, dams and their effects on forests and tribal people – Water resources: Use and over-utilization of surface and ground water, floods, drought, conflicts over water, dams-benefits and problems – Mineral resources: Use and exploitation, environmental effects of extracting and using mineral resources, case studies – Food resources: World food problems, changes caused by agriculture and overgrazing, effects of modern agriculture, fertilizer-pesticide

problems, water logging, salinity, case studies – Energy resources: Growing energy needs, renewable and non renewable energy sources, use of alternate energy sources. case studies – Land resources: Land as a resource, land degradation, man induced landslides, soil erosion and desertification – role of an individual in conservation of natural resources – Equitable use of resources for sustainable lifestyles. Field study of local area to document environmental assets – river / forest / grassland / hill / mountain.

Unit IIISOCIAL ISSUES AND THE ENVIRONMENT From unsustainable to sustainable development – urban problems related to energy – water conservation, rain water harvesting, watershed management – resettlement and rehabilitation of people; its problems and concerns, case studies – role of nongovernmental organization- environmental ethics: Issues and possible solutions – climate change, global warming, acid rain, ozone layer depletion, nuclear accidents and holocaust, case studies. – wasteland reclamation – consumerism and waste products – environment production act – Air (Prevention and Control of Pollution) act – Water (Prevention and control of Pollution) act – Wildlife protection act – Forest conservation act – enforcement machinery involved in environmental legislation- central and state pollution control boards- Public awareness.

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Unit IVHUMAN POPULATION AND THE ENVIRONMENT Population growth, variation among nations – population explosion – family welfare programme – environment and human health – human rights – value education – HIV / AIDS – women and child welfare – role of information technology in environment and human health – Case studies.

Reference Books1. Gilbert M.Masters, ‘Introduction to Environmental Engineering and Science’, 2nd edition, Pearson Education (2004).2. Benny Joseph, ‘Environmental Science and Engineering’, Tata McGraw-Hill, New Delhi, (2006).3. R.K. Trivedi, ‘Handbook of Environmental Laws, Rules, Guidelines, Compliances and Standards’, Vol. I and II, Enviro Media.4. Cunningham, W.P. Cooper, T.H. Gorhani, ‘Environmental Encyclopedia’, Jaico Publ., House, Mumbai, 2001.5. Dharmendra S. Sengar, ‘Environmental law’, Prentice hall of India PVT LTD, New Delhi, 2007.6. Rajagopalan, R, ‘Environmental Studies-From Crisis to Cure’, Oxford University Press (2005)

M. Sc. Engineering PhysicsSemester-VI


Paper: Solid State and Nano PhysicsMax. Marks: 60


Time: 3 hoursNote:-



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Unit ICrystal Structure I Crystalline and glassy forms, liquid crystals, crystal structure, periodicity, lattice and basis, crystal translational vectors and axes. Unit cell and Primitive Cell, Winger Seitz primitive Cell, symmetry operations for a two dimensional crystal, Bravais lattices in two and three dimensions. Crystal planes and Miller indices, Interplaner spacing, Crystal structures of Zinc Sulphide, Sodium Chloride and Diamond.

Unit II

Crystal Structure II

X-ray diffraction, Bragg's Law and experimental X-ray diffraction methods. K-space and reciprocal lattice and its physical significance, reciprocal lattice vectors, reciprocal lattice to a simple cubic lattice, b.c.c. and f.c.c.

Unit III

Super conductivity

Historical introduction, Survey of superconductivity, Super conducting systems, High Tc Super conductors, Isotopic Effect, Critical Magnetic Field, Meissner Effect, London Theory and Pippards’ equation, Classification of Superconductors (type I and Type II), BCS Theory of Superconductivity, Flux quantization, Josephson Effect (AC and DC), Practical Applications of superconductivity and their limitations, power application of superconductors.

Unit IV

Introduction to Nano Physics

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Definition, Length scale, Importance of Nano-scale and technology, History of Nan-technology, Benefits and challenges in molecular manufacturing. Molecular assembler concept, Understanding advanced capabilities. Vision and objective of Nano-technology, Nanotechnology in different field, Automobile, Electronics, Nano-biotechnology, Materials, Medicine.

References:

1 C. Kittel, Introduction to Solid State Physics, 7th Ed (1996) John Wiley & Sons, New

Delhi.

2 H. Ibach and H. Lüth, Solid State Physics, An Introduction to Theory and Experiment,

Springer-Verlag, Berlin, 1991

3 Pillai O S, Solid State Physics, New Age International Publishers (2007) New Delhi

4 Mark R and Denial R, Nano-tecnology – A Gentle Introduction to the Next Big Idea

(2002)

5 M. Tinkham, Introduction to Superconductivity, McGraw-Hill, New York, 1975

6 Dekkar A J, Solid State Physics (2000), Mc Millan India Ltd New Delhi

7 Ascroft N W and Mermin N D, Solid State Physics (2003) Harcourt Asia, Singapore

8 Keer H V, Solid State Physics (1993), Wiley Eastern Ltd, New Delhi

9 Kachhava C M, Solid State Physics (1990) Tata Mc Graw Hill Co Ltd, New Delhi

10 Gupta, Solid State Physics (1995) Vikas Publishing House Pvt Ltd, New Delhi

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M. Sc. Engineering PhysicsSemester-VI


Paper: Atomic and Molecular SpectroscopyMax. Marks: 60


Time: 3 hoursNote:-






Unit – I

Historical background of atomic spectroscopy

Introduction of early observations, emission and absorption spectra, atomic spectra, wave number, spectrum of Hydrogen atom in Balmer series, Bohr atomic model(Bohr’s postulates) , spectra of Hydrogen atom , explanation of spectral series in Hydrogen atom, un-quantized states and continuous spectra, spectral series in absorption spectra, effect of nuclear motion on line spectra (correction of finite nuclear mass), variation in Rydberg constant due to finite mass, short comings of Bohr’s theory, Wilson sommerfeld quantization rule, de-Broglie interpretation of Bohr quantization law, Bohr’s corresponding principle, Sommerfeld’s extension of Bohr’s model, Sommerfeld relativistic correction, Short comings of Bohr-Sommerfeld theory, Vector atom model; space quantization, electron spin, coupling of orbital and spin angular momentum, spectroscopic terms and their notation, quantum numbers associated with vector atom model, transition probability and selection rules.

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Unit –II

Vector Atom Model (single valance electron)

Orbital magnetic dipole moment (Bohr megnaton), behavior of magnetic dipole in external magnetic filed; Larmors’ precession and theorem.

Penetrating and Non-penetrating orbits, Penetrating orbits on the classical model; Quantum defect, spin orbit interaction energy of the single valance electron, spin orbit interaction for penetrating and non-penetrating orbits. quantum mechanical relativity correction, Hydrogen fine spectra, Main features of Alkali Spectra and their theoretical interpretation, term series and limits, Rydeburg-Ritze combination principle, Absorption spectra of Alkali atoms. observed doublet fine structure in the spectra of alkali metals and its Interpretation, Intensity rules for doublets, comparison of Alkali spectra and Hydrogen spectrum .

UNIT-III

Vector Atom model (two valance electrons)

Essential features of spectra of Alkaline-earth elements, Vector model for two valance electron atom: application of spectra.

Coupling Schemes;LS or Russell – Saunders Coupling Scheme and JJ coupling scheme, Interaction energy in L-S coupling (sp, pd configuration), Lande interval rule, Pauli principal and periodic classification of the elements. Interaction energy in JJ Coupling (sp, pd configuration), equivalent and non-equivalent electrons, Two valance electron system-spectral terms of non-equivalent and equivalent electrons, comparison of spectral terms in L-S And J-J coupling. Hyperfine structure of spectral lines and its origin; isotope effect, nuclear spin.

Unit –IV

Atom in External Field

Zeeman Effect (normal and Anomalous),Experimental set-up for studying Zeeman effect, Explanation of normal Zeeman effect(classical and quantum mechanical), Explanation of anomalous Zeeman effect( Lande g-factor), Zeeman pattern of D1 and D2 lines of Na-atom, Paschen-Back effect of a single valence electron system. Weak field Stark effect of Hydrogen atom.

Molecular Physics

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General Considerations, Electronic States of Diatomic Molecules, Rotational Spectra (Far IR and Microwave Region), Vibrational Spectra (IR Region), Rotator Model of Diatomic Molecule, Raman Effect, Electronic Spectra.

References

1 Beiser A, Concept of Modern Physics (1987), Mc Graw Hill Co Ltd, New Delhi

2 Rajab J B, Atomic Physics (2007), S Chand & Co, New Delhi

3 Fewkes J H and Yarwood J Atomic Physics Vol II (1991) Oxford University Press

4 Bransden B H and Joachain C J, Physics of Atoms and Molecules 2nd Ed (2009),

Pearson Education, New Delhi.

5 Banwell, Molecular Spectroscopy

6 Ghoshal S N, Atomic and Nuclear Physics Vol I (1996) S Chand & Co, New Delhi

7 Gopalkrishnan K, Atomic and Nuclear Physics (1982), Mc Millan India New Delhi

8 Raj Kumar, Atomic and Moleculer Spectra:Laser , Kedarnath Ram nathpub.

9 S.L.Gupta, V.Kumar,R.C.Sharma, Elements of Spectroscopy,Pragati Prakashan.

M Sc. Engineering PhysicsSemester – VI

Subject – Chemistry (Paper Code: CH-601)Paper: Inorganic Chemistry-VI

Max. Marks: 40Theory: 35

Internal Assessment: 5Time: 3 hrs.


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Unit IOrganometallic ChemistryDefinition, nomenclature and classification of organometallic compounds. Preparation, properties, and bonding of alkyls of Li, Al, Hg, and Sn a brief account of metal-ethylenic complexes, mononuclear carbonyls and the nature of bonding in metal carbonyls.

Unit IIAcids and Bases, HSAB ConceptArrhenius, Bronsted – Lowry, the Lux – Flood, Solvent system and Lewis concepts of acids & bases, relative strength of acids & bases, Concept of Hard and Soft Acids & Bases.

Unit IIIBioinorganic ChemistryEssential and trace elements in biological processes, metalloporphyrins with special reference to haemoglobin and myoglobin. Biological role of alkali and alkaline earth metal ions with special reference to Ca2+. Nitrogen fixation.

Unit IVSilicones and PhosphazenesSilicones and phosphazenes as examples of inorganic polymers, nature of bonding in triphosphazenes.

References:-

1. Concise Inorganic Chemistry by: J. D. Lee.2. Inorganic Chemistry: Principle of Structure and Reactivity by: Huheey, Keiter & Keiter.3. Inorganic Chemistry by: Puri, Sharma and Kalia.4. Text Book of Macro- and Micro Quantitative Analysis by A I Vogel


Subject-Chemistry (Paper Code: CH-602)Paper: Physical Chemistry-VI




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Unit IElectronic SpectrumConcept of potential energy curves for bonding and antibonding molecular orbitals, qualitative description of selection rules and Franck- Condon principle. Qualitative description of sigma and pie and n molecular orbital (MO) their energy level and respective transitions.

Unit - IIPhotochemistryInteraction of radiation with matter, difference between thermal and photochemical processes. Laws of photochemistry: Grotthus-Drapper law, Stark-Einstein law (law of photochemical equivalence) Jablonski diagram depiciting various processes occurring in the excited state, qualitative description of fluorescence, phosphorescence, non-radiative processes (internal conversion, intersystem crossing), quantum yield, photosensitized reactions-energy transfer processes (simple examples).

Unit - IIISolutions Dilute Solutions and Colligative Properties Ideal and non-ideal solutions, methods of expressing concentrations of solutions, activity and activity coefficient. Dilute solution,Colligative properties, Raolut’s law, relative lowering of vapour pressure, molelcular weight determination, Osmosis law of osmotic pressure and its measurement, determination of molecular weight from osmotic pressure. Elevation of boiling point and depression of freezing point, Thermodynamic derivation of relation between molecular weight and elevation in boiling point and depression in freezing point. Experimental methods for determining various colligative properties. Abnormal molar mass, degree of dissociation and association of solutes.

Unit - IVPhase EquilibriumStatement and meaning of the terms – phase component and degree of freedom, thermodynamic derivation of Gibbs phase rule, phase equilibria of one component system –Example – water and Sulpher systems. Phase equilibria of two component systems solid-liquid equilibria, simple eutectic Example Pb-Ag system, desilerisation of lead

References:-1. Book of Physical Chemistry (vol. I, II, III & IV) by: K. L. Kapoor2. An Introduction to Chemical Thermodynamics by R P Rastogi and R R Mishra3. Principles of Physical Chemistry by Puri and Sharma

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4. Electrochemistry by S Glasstone5. Physical Chemistry by: O.P.Aggarwal.


Subject – Chemistry (Paper Code: CH-603)Paper: Organic Chemistry-VI



Note:-1. Nine questions will be set in total.

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2. Question no. 1 will be compulsory and based on the conceptual aspects of the entire syllabus. This question may have 5 parts and the answer should be in brief but not in Yes/No.


Unit IOrganosulphur CompoundsNomenclature, structural features, Methods of formation and chemical reactions of thiols, thioethers, sulphonic acids, sulphonamides and sulphaguanidine. Synthetic detergents alkyl and aryl sulphonates.

Unit - IIHeterocyclic CompoundsIntroduction: Molecular orbital picture and aromatic characteristics of pyrrole, furan, thiophene and pyridine. Methods of synthesis and chemical reactions with particular emphasis on the mechanism of electrophilic substitution. Mechanism of nucleophilic substitution reactions in pyridine derivatives. Comparison of basicity of pyridine, piperidine and pyrrole. Introduction to condensed five and six- membered heterocycles. Prepration and reactions of indole, quinoline and isoquinoline with special reference to Fisher indole synthesis, Skraup synthesis and Bischler-Napieralski synthesis. Mechanism of electrophilic substitution reactions of, quinoline and isoquinoline.

Unit - IIIOrganic Synthesis via EnolatesAcidity of α-hydrogens, alkylation of diethyl malonate and ethyl acetoacetate. Synthesis of ethyl acetoacetate: the Claisen condensation. Keto-enol tautomerism of ethyl acetoacetate. Amino Acids, Peptides& Proteins Classification, of amino acids. Acid-base behavior, isoelectric point and electrophoresis. Preparation of α-amino acids. Structure and nomenclature of peptides and proteins. Classification of proteins. Peptide structure determination, end group analysis, selective hydrolysis of peptides. Classical peptide synthesis, solid–phase peptide synthesis. Structures of peptides and proteins: Primary & Secondary structure.

Unit - IVSynthetic PolymersAddition or chain-growth polymerization. Free radical vinyl polymerization, ionic vinyl polymerization, Ziegler-Natta polymerization and vinyl polymers. Condensation or step growth polymerization. Polyesters, polyamides, phenol formaldehyde resins, urea formaldehyde resins, epoxy resins and polyurethanes. Natural and synthetic rubbers.

References:-

1. Organic Chemistry by: Morrison Boyd.2. Advanced Organic Chemistry (vol. I & II) by: I. L. Finar.3. Introduction to Spectroscopy by D L Parlia G M George and S Kriz

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4. Spectroscopy by Jagmohan5. Advanced Organic Chemistry :Reactions, Mechanism and Structures by J March.


Subject: Mathematics (Paper Code: MT-601)Paper: (Engineering Mathematics-VI)



Note:-1. Nine questions will be set in total.2. Question no. 1 will be compulsory and based on the conceptual aspects of the entire

syllabus. This question may have 5 parts and the answer should be in brief but not in

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Yes/No.3. Four more questions are to be attempted, selecting one question out of two questions set

from each unit. Each question may contain two or more parts. All questions will carry equal marks.

Unit-IScientific ComputingIntroduction, Computational Problems, General Strategy, Approximations in Scientific Computation, Sources of Approximation, Absolute Error and Relative Error, Data Error and Computational Error, Truncation Error and Rounding Error, Forward and Backward Error, Sensitivity and Conditioning, Stability and Accuracy, Computer Arithmetic, Floating-Point Numbers, Normalization, Properties of Floating-Point Systems, Rounding, Machine Precision, Subnormals and Gradual Underflow, Exceptional Values, Floating-Point Arithmetic, Cancellation, Other Arithmetic Systems, Complex Arithmetic, Mathematical Software, Mathematical Software Libraries, Scientific Computing Environments, Extended Arithmetic Packages, Practical Advice on Software

Unit-IIInterpolationInterpolation, Existence, Uniqueness, and Conditioning, Polynomial Interpolation, Monomial Basis, Lagrange Interpolation, Newton Interpolation, Orthogonal Polynomials, Interpolating Continuous Functions, Piecewise Polynomial Interpolation, Hermite Cubic Interpolation, Cubic Spline Interpolation, B-splines, Software for Interpolation, Software for Special Functions

Numerical Integration and DifferentiationIntegration, Existence, Uniqueness, and Conditioning, Numerical Quadrature, Newton-Cotes Quadrature, Clenshaw-Curtis Quadrature, Gaussian Quadrature, Progressive Gaussian Quadrature, Composite Quadrature, Adaptive Quadrature, Other Integration Problems, Tabular Data, Improper Integrals, Double Integrals, Multiple Integrals, Integral Equations, Numerical Differentiation, Finite Difference Approximations, Automatic Differentiation, Richardson Extrapolation, Software for Numerical Integration and Differentiation

UNIT-IIIProbability DistributionsProbability, Baye’s theorem, Discrete & Continuous probability distributions, Moment generating function, Probability generating function, Properties and applications of Binomial, Poisson and normal distributions.

UNIT-IVLinear Programming Linear programming problems formulation, Solution of Linear Programming Problem using Graphical method, Simplex Method, Dual-Simplex Method.

Reference Book1Scientific Computing 2nd Ed Michael T Heath , Mec Graw Hill Book Co Ltd, New Delhi

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2. Higher Engg. Mathematics : B.S. Grewal3. Advanced Engg. Mathematics : E. Kreyzig4. Operation Research : H.A. Taha5. Probability and statistics for Engineer : Johnson. PHI.


Subject: Mechanical Engineering (Paper Code: Tech-601)Paper: Manufacturing Processes and Workshop Technology



Note:-1 Nine questions will be set in total. 2 Question no. 1 will be compulsory and based on the conceptual aspects of the entire


30

Yes/No. 3 Four more questions are to be attempted, selecting one question out of two questions

set from each unit. Each question may contain two or more parts. All questions will carry equal marks.

4Unit-IIntroductionIntroduction to Manufacturing Processes and their Classification. Industrial Safety; Introduction, Types of Accidents, Causes and Common Sources of Accidents, Methods of Safety, First Aid.

Engineering MaterialsGeneral Properties and Applications of Engineering Materials, Mild Steel, Medium Carbon Steel, High Carbon Steel, High Speed Steel and Cast Iron.

Unit-IIFoundryIntroduction to Casting Processes, Basic Steps in Casting Process, Pattern, Types of Patterns, Pattern Allowances, Risers, Runners, Gates, Moulding Sand and its composition, Sand Preparation, Molding Methods, Core Sands and Core Making, Core Assembly, Mold Assembly, Melting ( Cupola) and Pouring, Fettling, Casting Defects and Remedies.

Unit-IIICold Working ( Sheet Metal Work )Sheet Metal Operations, Measuring, Layout Marking, Shearing, Punching, Blanking, Piercing, Forming, Bending and Joining Advantages and Limitations.

Hot Working ProcessesIntroduction to Hot Working, Principles of Hot Working Processes, Forging, Rolling, Extrusion, Wire Drawing. Plant Layout, Objectives of Layout, Types of Plant Layout and their Advantages.

Unit-IVIntroduction to Machine ToolsSpecifications and Uses of commonly used Machine Tools in a Workshop such as Lathe, Shaper, Planer, Milling, Drilling, Slotter, Introduction to Metal Cutting. Nomenclature of a Single Points Cutting Tool and Tool Wear. Mechanics of Chips Formations, Type of Chips , Use of Coolants in machining.

WeldingIntroduction to Welding, Classification of Welding Processes, Gas Welding: Oxy-Acetylene Welding, Resistance Welding; Spot and Seam Welding, Arc Welding: Metal Arc, TIG & MIG Welding, Welding Defects and Remedies, Soldering & Brazing.

Reference Books :

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1. Workshop Technology Vol. I &II - Hazra & Chaudhary, Asian Book Comp., New Delhi.2. Process and Materials of Manufacture-Lindberg, R.A. Prentice Hall of India, New Delhi.3. Principles of Manufacturing Materials and Processes- Campbell, J.S.- McGraw- Hill.4. Manufacturing Science-Amitabha Ghosh & Ashok Kumar Malik, - East-West Press.5. Manufacturing Process and Systems - Ostwald, Munoz , John Wiley.6. Workshop Technology, Vol. 1, 2 & 3 – Chapman, WAJ, Edward Arnold.


Subject: Computer Science (Paper Code: CS-601)Paper : Fundamental of Computers and Programming in C



Note:-1 Nine questions will be set in total. 2 Question no. 1 will be compulsory and based on the conceptual aspects of the entire


32

Yes/No. 3 Four more questions are to be attempted, selecting one question out of two questions

set from each unit. Each question may contain two or more parts. All questions will carry equal marks.

Unit-1An Overview of Computer SystemAnatomy of a digital Computer, Memory Units, Main and Auxiliary Storage Devices, Input Devices, Output Devices, Classification of Computers. Radix number system: Decimal, Binary, Octal, Hexadecimal numbers and their inter-conversions; Representation of information inside the computers. Operating System Basics: Introduction to PC operating Systems: DOS, Unix/Linux, Windows 2000.

Unit-2Programming LanguagesMachine-, Assembly-, High Level- Language, introduction to Assembler, Compiler, Interpreter, Debuggers, Linker and Loader. Programming fundamentals: problem definition, algorithms, flow charts and their symbols.

Internet basicsHow Internet works, Major features of internet, Emails, FTP, Using the internet.

Unit-3C Programming languageC fundamentals, formatted input/ output, expressions, selection statements, loops and their applications; Basic types, arrays, functions, including recursive functions, program organization: local and external variables and scope & arrays.

Unit-4StringsStrings literals, string variables, I/O of strings, arrays of strings; applications. Structures, Unions and Enumerations: Structure variables and operations on structures; Structured types, nested array structures; unions; enumeration as integers, tags and types. Standard library: Input / output; streams, file operations, formatted I/O, character I/O, line I/O, block, string I/O, Library support for numbers and character data, error handling:

Reference Books:1. Using Information Technology, 5th Edi, Brian K Williams & Stacey C. Sawyer, 2003, TMH2. The C Programming Language by Dennis M Ritchie, Brian W. Kernigham, 1988, PHI.3. C Programming – A modern approach by K.N. King, 1996, WW Norton & Co.4. Information technology, Dennis P. Curtin, Kim Foley, Kunal Sen, Cathleen Morin, 1998, TMH5. Theory and problem of programming with C, Byron C Gottfried, TMH6. Teach yourself all about computers by Barry Press and Marcia Press, 2000, IDG Books India.7. Using Computers and Information by Jack B. Rochester, 1996, Que Education & Training.

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M.Sc- Engineering PhysicsSemester- VI

Paper: PH Lab (Physics Lab Practicals)

Max. Marks: 100 Time: 3+3 hours (on two days)

Special Note: -

1. Do any eight experiments from each Section. 2. The students are required to calculate the error involved in a particular experiment. 3. The Practical examination will be held in two sessions of 3 hours each (first session in the

evening of first day and the second session in the morning of the next day).

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Distribution of Marks:

Experiments 25+25 50 marksViva- voce 15+15 30 marksLab. Record 20 marks Total 100 marks

Section A

(i) Electronics, Solid State and Nuclear Physics– 4 Experiments1 Determine e/m by Thomson’s method2 Study the C B transistor amplifier3 Study the C E transistor amplifier4 Study the B H curve using oscilloscope5 Study the Hall effect6 Measurement of energy band gap of Ge/Si by four probe method7 (a) Draw the plateau using G M counter (b) Determine the mass attenuation coefficient by G M counter

Section A (ii) Computer experiments –4 Experiments8 Compute the product of two matrices of different dimension using DO loop9 Numerical integration by Simpson 1/3 rule10 Fitting of a straight line using Least-Square method 11 Using array variable, find out the average and standard deviation12 Compute the sum of a finite series up to correct three decimal place13 With the help of a program arrange the marks in ascending of descending order14 Write a program to evaluate the function Y=1 / [ C ( 1 + e Cos θ ) ] and V=√ [ C M G ( e2 + e Cos θ + 1 ) ] e = 1.1, C = 3.0(E+08), M = 5.893(E+24), G = 6.67(E-11) for varying value of θ from 0 to π.

Section B

15 Determine the λNa by Fresnel Byprism16 Determine the velocity of ultrasonic in the Kerosene oil17 Diameter of a Lycopodium powder using corona rings18 Study double slit interference by He-Ne laser19 Determine the diameter of a wire using (He-Ne Laser) diffraction method20 Determine the Young modulus ‘Y’ by Searl’s interference method21 Determine the resolving power of a prism22 Thickness of a paper using interference fringes in an air wedge23 Determine the resolving power of a transmission grating24 Determine the RH by grating and Hydrogen tube

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References:1 Worshnop and Flint, Advanced Practical Physics2 Nelkon M and Ogborn, Advanced Level Practical Physics, Heinemann Education Books Ltd, New Delhi3 Srivastava S S and Gupta M K, Experiments in Electronics, Atma Ran & Sons, Delhi4 Gupta S L and Kumar V, Practical Physics, Pragati Prakashan, Meerut.

M.Sc- Engineering PhysicsSemester- VI

Paper: CH Lab (Chemistry Lab Practicals)

Max. Marks: 100 Time: 3+3 hours (on two days)

Note:-

1. The Practical examination will be held in two sessions of 3 hours each (first session in the evening of first day and the second session in the morning of the next day).

Distribution of marks

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Section I 20 marksSection II 20 marksSection III 20 marksViva-voce 20marksLab Record 20 marks.

SECTION – I (Inorganic)

Semimicro qual i ta t ive analys is of mixture containing not more than four radicals ( including interfer ing, Combinat ions and excluding insoluables) :

Pb 2 + , Hg 2 + , Hg22+ , Ag + , Bi 3 + , Cu 2 + , Cd 2 + , As 3 + , Sb 3 + , Sn 2 + , Fe 3 + , Cr 3 + , Al 3 + ,

Co 2 + , Ni 2 + , Mn 2 + , Zn 2 + , Ba 2 + , Sr 2 + , Ca 2 + , Mg 2 + , NH 4+ , CO 3

2 - , S 2 - , SO 32 - ,

S 2 O 32 - , NO 2

- , CH 3 COO - , Cl - , Br - , I - , NO 3- , SO 4

2 - , C 2 O 42 - , PO 4

3 - , BO 33 -

Section-B (Physical)1 To determine the strength of the given acid solution (mono and dibasic acid)

conductometrically.

2 To determine the solubility and solubility product of a sparingly soluble electrolyte conductometrically

3 To determine the strength of given acid solution (mono and dibasic acid) potentiometrically.

4 To determine the molecular weight of a non-volatile solute by Rast method.

5 To standardize the given acid solution (mono and dibasic acid) pH metrically.

Section-C (Organic)1. Laboratory Techniques

(a) Steam dist i l lat ion (non evaluat ive)

Naphthalene from i ts suspension in water

Separat ion of o -and p -ni t rophenols

(b) Column chromatography (non evaluat ive)

Separat ion of f luorescein and methylene blue

Separat ion of leaf pigments f rom spinach leaves

2. Thin Layer ChromatographyDeterminat ion of R f values and identif icat ion of organic compounds

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Separat ion of green leaf pigments (spinach leaves may be used)

(b) Separat ion of a mixture of coloured organic compounds using common organic solvents .

3. Synthesis of the following organic compounds:(a) To prepare o-chlorobenzoic acid from anthranilic acid.

(b) To prepare p-bromoaniline from p-bromoacetanilide.

(c) To prepare m-nitroaniline from m-dinitrobenzene.

(d) To prepare S-Benzyl-iso-thiouronium chloride from thiourea.

References:-

1. Inorganic Chemstry Practicals by: Gurdeep Raj Chatwal.2. Vogel’s Text book of Quantitative Chemical Analysis.3. Vogel’s Text book of Qualitative Chemical Analysis.

3rd year (5th and 6 semesters) (effective from july – 2011) engg-phyc 5... · 10 patel s b,...

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