3rd circular - chem.xmu.edu.cnchem.xmu.edu.cn/doc/d2220f8f-99c1-2981.pdf · phosphorus in organic...

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ICPC-2007

THE 17TH INTERNATIONAL CONFERENCE ON

PHOSPHORUS CHEMISTRY

April 15 - 19, 2007, Xiamen, China

Third and Final Circular

Sponsored by

International Union of Pure and Applied Chemistry

Chinese Chemical Society

Organized by Xiamen University

Acknowledgements to China Association for Science and Technology National Natural Science Foundation of China

Chinese Academy of Sciences Tsinghua University

Nankai University Zhengzhou University

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ORGANIZATION International Scientific Committee G.M. Blackburn (U.K.) G. Bertrand (USA) E. Breuer (Israel) F.H. Ebetino. (USA) R.R. Holmes (USA) V. I. Kalchenko (Ukraine) T. Kawashima (Japan) M.O. Lozinskii (Ukraine) M. Mikolajczyk (Poland) P. Metivier (France) L. Maier (Switzerland) F. Mathey (France) C.E. McKenna (USA) J.F. Nixon (U.K.) E. Niecke (Germany) M.A.Pudovik (Russia) M. Regitz (Germany) W.J. Stec (Poland) D.F. Wiemer (USA) M. Yoshifuji (Japan) C.Y. Yuan (China) Y. F. Zhao (China) Local Scientific Committee Ruyu Chen (Tianjin) Xinzi Chen (Hong Kong) Wanyi Chen (Beijing) Jinpei Cheng (Tianjin) Yunliu Fan (Beijing) Hongwu He (Wuhan) Peiqiang Huang (Xiamen) Zhengming Li (Tianjin) Yanmei Li (Beijng) Chengxin Pei (Beijing) Shigang Sun (Xiamen) Mingsheng Tang (Zhengzhou) Kemei Wei (Fuzhou) Xun Xu (Xiamen) Lianhui Xie (Fuzhou) Chengye Yuan (Shanghai) Huilin Wan (Xiamen) Yufen Zhao (Xiamen) Daoben Zhu (Beijing) Lihe Zhang (Beijing) Renxi Zhuo (Wuhan) Qilin Zhou (Tianjin) Steve C.F. Au-Yeung (Hong Kong) Chairperson: Prof. Yufen Zhao (Academician, Xiamen University) Co-Chairperson: Prof. Ruyu Chen (Academician, Nankai University), Prof. Chengye Yuan (Academician,

Shanghai Institute of Organic Chemistry)

Secretary General: Prof. Peiqiang Huang (Xiamen University) Secretary: Prof. Zhuangping Zhan, Associate Prof. Daxiong Han (Xiamen University)

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TENTATIVE SCHEDULE OF THE CONFERENCE

Date Morning Afternoon Evening Sun. (Apr. 15) Registration Reception

Mon. (Apr. 16) Opening Ceremony

Plenary Lecture

Keynote Lecture, Invited Lecture and Oral

Presentation

Tue. (Apr. 17) Keynote Lecture, Invited

Lecture and Oral Presentation

Excursion (Free)

Wed. (Apr. 18) Keynote Lecture Invited Lecture

and Oral Presentation Poster Session Music Party (Free)

Thu. (Apr. 19) Keynote Lecture Invited Lecture

and Oral Presentation

Keynote Lecture Invited Lecture

and Oral Presentation

Closing Ceremony&

Banquet

Fri. (Apr. 20) Tour to “Tulou” Building (Optional)

Post-conference (Zhengzhou)

*Attention!!! ICPC board member meeting: 12:00~14:00 on Apr. 18,

Location: Meeting Room No. 2, 3rd Floor, Keli Building

Note: 1. Registration: at the Lobby of Yifu Hotel Building; 09:00-21:00 2. Reception: at 2nd floor of Yifu Restaurant, 19:00p.m.. 3. Opening Ceremony, PL-1 & PL-2: at Keli Building, 09:00 – 12:00 4. Excursion: Gather before Jiageng Main Building; leaving time: 13:30 a.m.. 5. Music Party: at 3rd floor of Keli Building, start from 20:00p.m.. 6. Banquet: Picking up from Yifu and Hilford Hotels at 18:30 p.m.. Banquet Location: International Seaside Hotel Xiamen (5 star-hotel) 7. Tour to “Tulou” Building: Detail information will be notified at registration desk.

SCIENTIFIC PROGRAM Presentation: All Oral presentation time: 1. Plenary lecture (PL) time: 60 min (discussion included) 2. Keynote lecture (KL) time: 35 min (discussion included) 3. Invited lecture (IL) time: 25 min (discussion included) 4. Oral (O) time: 15 min (discussion included) Presentation Requirement

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1. Presentation files with MS Powerpoint (PC format) or Acrobat PDF slides for presentation on a LCD video projector are preferred

2. Internet linkage during presentation is not available 3. Any animations used should be embedded in MS Powerpoint 4. Speakers using Macintosh for their presentation are required to bring their own Macintosh notebooks Resources Available for Presentations 1. A computer running Windows XP Professional operating system, with MS Office 2003, Windows

Media Player, Acrobat Reader 7.0 installed 2. CD-R and USB compliant removable storage (e.g. Thumbdrive, external USB hard disk) 3. Laserpoint Submission of Materials For logistics purposes, we prefer that all presentation files be preloaded into our conference computers. Please email your digital images to [email protected] Submission deadline for preloading: April 15, 2007, 12:00 (China time). Early submission is required for us to preload the presentation files into the conference computers. The Conference Working Language: English. Poster Display Board: Poster presentation Time April 18, 2007, 14:00 – 17:50 Poster presentation Venue The 1st floor of new building of College of Chemistry and Chemical Engineering The Poster 1. A poster board will be provided to mount your poster. The maximum permitted dimensions should be

1189 x 841 mm or 46.81 x 33.11 inches (size A0). Please note that the width of the poster board may not be exceeded under any circumstances.

2. For logistics purposes, all posters must be pasted onto the board in advance, and the schedule for pasting poster is arranged on 18 April, 2007, 8:00-14:00. Your poster presentation code will be indicated on the board. Velcro adhesive will be provided at the conference to mount posters on the board.

Other Information 1. Presenters are responsible for the dismantling of their posters. Posters left behind after the stipulated

removal date and time will be disposed of and are not the responsibility of the organizer. 2. It is helpful to your colleagues when you provide a handout of your poster that includes your full

contact information so they have access to your important ideas after the conference. Please email your digital images to [email protected]

3. Among the posters, three of them will be selected for “The Best Poster Award”. The Award will be announced during the banquet.

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Keli Building

Monday April 16 09:00-09:30 Opening Ceremony

09:30-10:00 Photo and break

10:00-12:00 Chair Chengye Yuan

10:00-11:00 Plenary Lecture PL-1 Prof. Francois Mathey "Structure and Reactivity of Inorganic Phosphorus Compounds"

11:00-12:00 Plenary Lecture PL-2 Prof. George Micheal Blackburn "Phosphate - the Cornerstone of Life"

12:10 Lunch

Hall 1

Symposium 1. Phosphorus in Organic Synthesis & Stereochemistry; Structure and Reactivity of Organic Phosphorus Compounds

14:00-15:50 Chairs Dennis N. Kevill and I. L. Odinets 14:00-14:35 KL-1 Takayuki Kawashima Japan Chemistry of carbaphosphatranes

14:35-14:50 O-1 Aleksandr N.Kostyuk Ukraine Synthesis and properties of λ5-Phosphinines and

λ5-azaphosphinines

14:50-15:05 O-2 Amgalan Natsagdorj Mongolia The synthesıs and spectroscopıc propertıes of spiro-ansa-spiro

phosphazenes

15:05-15:20 O-3 Boris Ionin Russia Acetylenephosphonates: reactions with nucleophiles

15:20-15:35 O-4 Christian V. Stevens Belgium

New insights in P-nucleophile additions onto unsaturated

imino derivatives for the synthesis of P-analogues of glutamic

acid

15:35-15:50 O-5 You Huang China

A facile and highly efficient method for α-amino phosphonates

via three-component reactions from aryl azides catalyzed by

iron-iodine in the absence of solvent

15:50-16:05 Tea and coffee break

16:05-18:00 Chairs Takayuki Kawashima and Li-Biao Han

16:05-16:20 O-6 Dennis N. Kevill USA Reaction mechanism studies of solvolytic displacement of

chloride from phosphorus

16:20-16:35 O-7 Elena Gavrilova Russia The new tipe of calix[4]resorcines bearing phosphonates and

phosphonium fragments at the lower rim

16:35-16:50 O-8 Ewa Żymańczyk-Duda Poland Microbial resolution of racemic phosphonates derivatives with

one or two stereogenic centres

16:50-17:05 O-9 I. L. Odinets Russia

Advantages of organophosphorus synthesis in ionic

liquids:“Green” approaches to useful phosphorus substituted

building-blocks

17:05-17:20 O-10 Elena Varaksina Russia

Synthesis and chemical properties of

benzo[e]-1,2-oxaphosphorinine derivatives – P-analogues of

coumarines

17:20-17:35 O-11 A.V. Bogdanov Russia

The reaction of 1,2-naphthoquinones with some P(III)

derivatives – a versatile sythetic approach to potentially useful

naphthoquinones and dihydroxynaphthale-nes containing

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phosphorus–carbon bond

17:35-18:00 IL-1 Li-Biao Han Japan

Metal-mediated P-H addition as a powerful tool for the

construction of C-P bonds: from academic interests to

practical applications

Tuesday April 17 09:00-10:20 Chairs M. A. Pudovik and Gerd Volker Röschenthaler

09:00-09:35 KL-2 M.A.Pudovik Russia

Development methods synthesis of polyheterophosphacyclanes

with endocyclic P-C bond on the basis of functionalized

alkylphosphonates(-phosphinates) 09:35-09:50 O-12 I.V. Shevchenko Ukraine Ylides and carbenes. The first carbene catalyzed reaction

09:50-10:05 O-13 Junji Kobayashi Japan Synthesis, optical properties and reactivities of a

dibenzophosphaborin and its derivatives

10:05-10:20 O-14 K. M. Pietrusiewicz Poland Phosphinous acid-boranes: an emerging class of

organophosphorus reagents


10:35-11:35 Chairs Yangjie Wu and I.V. Shevchenko

10:35-10:50 O-15 Andrey Prishchenko Russia Synthesis of new functionalized phosphorus substituted

derivatives of 2,6-di-tert-butyl-4-methylphenol

10:50-11:05 O-16 M. Klimek-Ochab Poland

Microbial desymmetrization of racemic mixture of

(1-hydroxyphenylmethyl)phenylphosphinate ethyl ester via

oxidation of one optical isomer

11:05-11:20 O-18 Gerd Volker Röschenthaler Germany Guanidinophosphazenes: design and synthesis of a novel

family of uncharged organic super bases

11:20-11:35 O-19 Katsuhiko Tsunashima Japan Preparation and characterization of novel room temperature

ionic liquids based on quaternary phosphonium cations

12:10 Lunch

13:30-17:30 Excursion (Free)

Wednesday April 18 09:00-10:25 Chairs S. Tschirschwitz and Shigeru Sasaki

09:00-09:25 IL-2 Oleg G. Sinyashin Russia New synthetic approaches to the chiral cyclic and macrocyclic

phosphine ligands

09:25-09:40 O-20 D. Andrew Knight USA Investigating the michaelis-becker reaction in phosphonium

and imidazolium ionic liquids

09:40-09:55 O-21 O. A. Shyshkov Germany A new useful synthetic pathway to trifluoromethyl phosphates

09:55-10:10 O-22 Oleg I. Kolodiazhnyi Ukraine New methods, and strategies for asymmetric synthesis of

organophosphorus compounds

10:10-10:25 O-23 Petro Onys’ko Ukraine Imidoyl chlorides: new promising building blocks in synthesis

of α-aminophosphoryl compounds


10:40-11:55 Chairs Oleg G. Sinyashin and D. Andrew Knight 10:40-10:55 O-24 Pradeep K. Sharma India Kinetics and mechanism of the oxidation of lower oxyacids of

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phosphorus by morpholinium chlorochromate

10:55-11:10 O-25 Rafael A. Cherkasov Russia Functionalized phosphoryl compounds: synthesis, extraction,

transport and ionophore properties

11:10-11:25 O-26 S. Tschirschwitz Germany Investigating the synthetic potential of

aminoalkylferrocenyldichlorophosphanes

11:25-11:40 O-27 Shigeru Sasaki Japan

Synthesis and redox properties of crowded diphosphines:

approaches toward phosphorus-phosphorus inter-valence

charge transfer systems

11:40-11:55 O-106 Tibor Novák Hungary Chiral P-heterocycles: efficient method for the optical

resolution of 3-methyl-3-phospholene 1-oxides

12:10 Lunch

14:00-17:30 Poster Session

Thursday April 19

09:00-10:20 Chairs Mitsuji Yamashita and V.F.Mironov 09:00-09:35 KL-3 John Nixon UK Rings and cages derived from phospha-alkynes

09:35-09:50 O-28 Janusz Rachon Poland

The organophosphorus sulfenyl bromides as versatile reagents

for cysteine derivatives functionalization by unsymmetrical

disulfide bond formation

09:50-10:05 O-29 Nissan Ashkenazi Israel Ambident electrophilicity of 5-membered ring phosphate

triesters

10:05-10:20 O-30 V.F.Mironov Russia

A new approach to the synthesis of phosphoranes on the basis

of the reaction of benzo[d]-1,3,2-dioxaphospholes, having β-

or γ-unsaturated group in substituent, with compounds

containing multiple bonds


10:35-11:50 Chairs John Nixon and Nissan Ashkenazi

10:35-10:50 O-31 Vladimir A. Alfonsov Russia Diastereoselective synthesis of enantiopure

α-aminophosphonic acids derivatives

10:50-11:05 O-32 Yuliya V. Rassukana Ukraine Phosphorylation of imino analogs of α-halocarbonyl

compounds

11:05-11:20 O-76 Rikard Wärme Sweden New reagents for halogenation of phosphorus

11:20-11:35 O-105 Mitsuji Yamashita Japan

Highly stereoselective and stereospecific epoxidation of

2-phospholenes and N-glycosides of phospha sugars and their

bioassays

11:35-11:50 O-107 Lee J. Higham UK Air-stable chiral primary phosphines

12:10 Lunch

Symposium 8. Special session to Professor L. Horner

14:00-17:30 Chairs Marian Mikolajczyk and Kuiling Ding 14:00-14:10 Memorial to Horner

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14:10-14:45 KL-4 Marian Mikolajczyk Poland Olefination reaction in organic sulfur chemistry and synthesis

of natural products

14:45-15:10 IL-3 Joachim Heinicke Germany 2-hydroxy- and 2-amino-functional arylphosphines-synthesis,

reactivity and use in catalysis

15:10-15:35 IL-4 Sylvain Juge France Enantioselective synthesis of P-chirogenic phosphorus

compounds via the ephedrine-borane complex methodology


15:50-16:15 IL-5 Wojciech Jacek Stec Poland Umpolung in Horner reaction: phosphoramidates as a source

of P-chiral organophosphates

16:15-16:40 IL-6 David Wiemer USA Synthesis and applications of phosphonates prepared from

electrophilic phosphorus reagents

16:40-17:05 IL-7 Kuiling Ding China Development of novel chiral phosphorus ligands for

enantioselective homogeneous and heterogeneous catalysis

17:05-17:30 IL-51 V.I.Kalchenko Ukraine Chiral phosphorus-contained calixarenes

19:00 Closing Ceremony& Banquet

Hall 2

Monday April 16

Symposium 2. Phosphorus Coordination Compounds and Their Use as Catalysis

14:00-16:40 Chairs Xumu Zhang and Didier Bourissou

14:00-14:35 KL-17 Xumu Zhang USA Innovative Chiral Phosphines for Hydrogenation and

Hydroformylation

14:35-14:50 O-35 Heinrich Heydt Germany Synthesis of strained-ring phosphorus heterocycles from

phosphatriafulvenes and phosphaheptafulvenes

14:50-15:05 O-36 Martin B. Smith UK Highly functionalised phosphorus ligands: synthesis and

diverse coordination chemistry


15:20-15:45 IL-11 Jingxing Gao China Synthesis and asymmetric catalysis of new chiral tetradentate

aminophosphine ligands

15:45-16:00 O-37 T. Arun Luiz India P* chiral aminophosphine complexes of Copper (I): Synthesis

and X-ray structural characterization

16:00-16:15 O-38 David Virieux France Phosphorus trivalent reagents: Efficient tools for

multicomponent and organocatalytic reactions

16:15-16:40 IL-8 Didier Bourissou France Ambiphilic phosphine/borane derivatives: synthesis and

coordination properties

Tuesday April 17

09:00-10:55 Chairs Pascal Metivier and Qilin Zhou

09:00-09:35 KL-5 Qilin Zhou China Design and synthsis of spiro phosphorus ligands for

asymmetric catalysis

09:35-09:50 O-109 Shigekazu Ito Japan Design, synthesis, and application of phosphaalkenes to

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unique palladium and gold catalysts


10:05-10:30 IL-40 Tingbin Wen China Synthesis and Chemistry of Metallabenzyne

10:30-10:55 IL-13 Pascal Metivier UK Phosphorus chemistry & sustainable development

12:10 Lunch


Wednesday April 18 09:00-11:15 Chairs Edgar Niecke and Andy Hor

09:00-09:35 KL-15 Edgar Niecke Germany My excursion to the chemistry of stable diradicals :

diphosphetanediyles

09:35-09:50 O-41 F. D. Sokolov Russia Complexes of crown-containing N-phosphorylthioureas with

Ni(II) cation

09:50-10:05 O-42 György Keglevich Hungary Novel heterocyclic P-ligands: Synthesis and application in

Pt(II) complexes


10:20-10:35 O-43 D. Bradley G. Williams South Africa DoM chemistry of phosphinic amides: synthesis of ligands

and their application in robust high performance catalysts

10:35-10:50 O-52 Dietrich Gudat Germany Bond activation processes in N-heterocyclic phosphines

10:50-11:15 IL-14 Andy Hor Singapore Phosphine and phosphine-mimic complexes in catalysis

12:10 Lunch


Thursday April 19

Symposium 5. Theoretical Aspects of Phosphorus Chemistry ; 31P NMR in Biological Systems

09:00-10:30 Chairs R.N.Naumov and Jon Waltho 09:00-09:35 KL-7 Martin J. Field France Molecular simulation studies of protein kinases

09:35-09:50 O-44 Wolfgang W. Schoeller Germany 1.3-Diphosphacyclobutane-diyls as building blocks for

extended structures

09:50-10:05 O-45 Yohsuke Yamamoto Japan

Development of a bidentate ligand based on

decafluoro-3-phenyl-3-pentanol: steric effect of

pentafluoroethyl groups on the stereomutation of oequatorial

c-apical spirophosphoranes

10:05-10:30 IL-16 GuanHua Chen China Photophysics of DNA and light harvesting systems


10:45-11:55 Chairs Martin J. Field and Yohsuke Yamamoto 10:45-11:00 O-46 Ya.A. Vereshchagina Russia Conformational analysis of 1,4-heterophosphinanes

11:00-11:15 O-47 R.N.Naumov Russia Stereoselective synthesis and interconversions of

1,9-diaza-3,7,11,15-tetraphosphacyclohexadecanes

11:15-11:30 O-48 K. A. Burkov Russia Reactions of phosphonic acids with bases in aqueous

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solutions

11:30-11:55 IL-15 Jon Waltho UK NMR investigations of phosphate transfer enzymes

12:10 Lunch

14:00-16:35 Chairs Steve C.F. AU-Yeung and Charles E. Webster

14:00-14:35 KL-8 Steve C.F. Au-yeung HK, China From powder NMR tensor to 3D molecular structure,

promises or illusion - A 31P and 13C case study on Cimitidine

14:35-15:00 IL-18 Charles E. Webster USA QM-MM computation of phosphate transfer by enzymes

15:00-15:15 O-50 Tamas Veszpremi Hungary Dimerization and trimerization of phosphaacetylene. A

mechanistic study


15:30-15:45 O-53 Ewa Rudzińska Poland Determination of optical purity of aminophosphonates by

means of NMR spectroscop

15:45-16:00 O-54 László Nyulászi Hungary Phosphorus stabilizes and can be stabilized

16:00-16:35 KL-6 Tsuneo Imamoto Japan Synthesis and application of new P-chiral phosphine ligands


Hall 3

Monday April 16

Symposium 6. Phosphorus Compound and Medicinal Chemistry

14:00-15:45 Chairs Yoshihiro Hayakawa and K. Lammertsma

14:00-14:35 KL-9 F. H. Ebetino USA

A correlation of antiresorptive structure activity relationships

in nitrogen-containing bisphosphonates Co-Crystalized in

farnesyl diphosphate synthase suggests their binding mode

14:35-15:00 IL-19 Takeshi Wada Japan Stereocontrolled synthesis of phsophorothioate DNA and RNA

by the oxazaphospholidine approach

15:00-15:15 O-56 Paul-Alain Jaffrès France Cationic lipids based on phosphonate & phosphoramidate

chemistry: synthesis and application to gene therapy

15:15-15:30 O-57 Ping Lu China

Enantiomeric Separation of a novel α-anminophosphonates

containing benzothiazol moiety by liquid chromatography

using amylose stationary phase

15:30-15:45 O-58 Xianbin Yang USA Bead-based approaches to develop thioaptamers for

diagnostics and therapeutics


16:00-17:55 Chairs F. H. Ebetino and Ji-Sheng Chen 16:00-16:15 O-59 Anna Czernicka Poland Design and construction of diagnostic chips for cancers

16:15-16:30 O-62 Z. Xia UK

Factors that may predict clinical potencies of

nitrogen-containing bisphosphonates; novel methods

dissociate enzyme- and hydroxyapatite-binding affinities

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16:30-16:55 IL-20 Yoshihiro Hayakawa Japan 3',5'-cyclic diguanylic acid and related compounds: synthesis,

chemical properties, and biological activities

16:55-17:20 IL-48 K. Lammertsma Netherlands New organophosphorus reagents and products

17:20-17:55 KL-21 Li Chen China Kinase and kinase inhibitor as anticancer therapeutics

Tuesday April 17

09:00-10:15 Chairs E. E. Nifantyev and Li Yan-Mei 09:00-09:35 KL-10 Ming-Daw Tsai USA Specificity of phosphothreonine recognition by FHA domains

09:35-10:00 IL-25 Jyoti Chattopadhyaya Sweden All phosphates are not born chemically equal in RNA

10:00-10:15 O-63 Łukasz Berlicki Poland Novel organophosphorus inhibitors of glutamine synthetase


10:30-11:35 Chairs Ming-Daw Tsai and Jyoti Chattopadhyaya 10:30-10:55 IL-64 E. E. Nifantyev Russia Studying the phosphorylation of flavonoids

10:55-11:20 IL-24 Li Yan-Mei China The effects of revisible phosphorylation on peptide and

protein local structure

11:20-11:35 O-67 H. J. Groombridge UK Investigations into the oxidative stability of hydroxymethyl- and

bis(hydroxymethyl)phosphines

12:10 Lunch


Wednesday April 18

09:00-10:25 Chairs Charles E. McKenna and Breuer Eli 09:00-09:35 KL-18 Charles E. McKenna USA Phosphonate analogs for drug design

09:35-10:10 KL-20 Chengye Yuan China Chiral functionalized phosphonates with biological

significance

10:10-10:25 O-69 Paweł Kafarski Poland Organophosphonate inhibitors of cathepsins


10:40-12:00 Chairs Chengye Yuan and Charles E. McKenna

10:40-10:55 O-70 F. Zeuner Liechtenstein Synthesis and dental aspects of

1,3-bis(methacrylamido)propane-2-yl dihydroxyphosphate

10:55-11:10 O-71 Ming-Wu Ding China

New efficient synthesis of 2-substituted

benzothieno[3,2-d]pyrimidin-4(3h)-ones via an

iminophosphorane

11:10-11:35 IL-26 Ruyu Chen

Zhiwei Miao China

Design, synthesis and biological activity of

α-amino-substituted thiophosphate-phosphonates and novel

naphthoquinone fused phosphorus heterocycles

11:35-12:00 IL-27 Eli Breuer Israel

Recent advances in carbamoylphosphonate based matrix

metalloproteinase (MMP) inhibitors. A class of non-toxic

in-vivo active drug candidates

12:10 Lunch


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Thursday April 19

Symposium 3. Structure and Reactivity of Inorganic Phosphorus Compounds

09:00-10:05 Chairs Masaaki Yoshifuji and Derek P. Gates

09:00-09:35 KL-11 Robert Holmes USA

Biologically relevant phosphoranes: structural characterization

of glucofuranose and xylofuranose phosphoranes as applied to

phosphoryl transfer enzymes

9:35-9:50 O-72 A.S. Vilesov Russia Influence of media components on processes of

radiation-indused polymerization of white phosphorus

9:50-10:05 O-73 Andrey A. Karasik Russia An effective methodology of P,N-macrocycles design


10:20-11:40 Chairs Robert Holmes and Andrey A. Karasik

10:20-10:35 O-74 Christopher W. Allen USA The mechanism of the reaction of alkali metal phenoxides

with hexahalocyclotriphosphazenes

10:35-11:50 O-75 Derek P. Gates Canada Strained P2C and P2C2 cyclic cations from phosphaalkenes

10:50-11:05 O-93 M.V. Sukhanov Russia Surface properties and catalytic activity of sodium zirconium

phosphate in dehydration of methanol

11:05-11:40 KL-19 Masaaki Yoshifuji Japan Studies on stable 1,3-diphosphacyclobutane-2,4-diyls

12:10 Lunch

14:00-15:20 Chairs Régis Réau and Liang-nian He

14:00-14:25 IL-50 N.P. Tarasova Russia Radiation-induced synthesis of polymers on the basis of

elemental phosphorus

14:25-14:50 IL-32 Rainer Streubel Germany New synthetic useful concepts in P,N-heterocyclic chemistry

14:50-15:05 O-79 Dmitry Yakhvarov Russia Bimetallic activation of white phosphorus

15:05-15:20 O-81 Hiroshi Nakazawa Japan Transition metal complexes containing phosphenium and

phosphite ligands: formation and theoretical approach


15:35-16:45 Chairs N.P. Tarasova and Rainer Streubel

15:35-15:50 O-80 Liang-nian He China Environmentally benign chemical conversion of CO2 into

organic carbonates catalyzed by phosphinium salts

15:50-16:05 O-82 Manfred Scheer Germany

The formation of spherical giant molecules and dynamic

behaviour of supramolecular assemblies based on pn ligand

complexes

16:05-16:20 O-84 Vasilii A. Milyukov Russia Synthesis and chemical properties of some alkali metals

polyphosphides

16:20-16:45 IL-31 Régis Réau France Organophosphorus Pi-conjugated materials for optoelectronic

applications


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Hall 4

Monday April 16

Symposium 7. Phosphorus Chemistry in Agriculture, Industry and Materials Sciences

14:00-15:45 Chairs Roger Hall and Hongwu He

14:00-14:35 KL-12 Philip W. Lee USA Overview on OP metabolism chemistry and its relationship to

biological and toxic actions

14:35-15:00 IL-33 Canping Pan China Food safety: Monitoring of organophosphate pesticide residues

in crops and food.

15:00-15:15 O-85 Budnikova Yu.H Russia “Green” ways of phosphorus compounds preparation

15:15-15:30 O-86 Dirk Freese Germany Phosphate - an important element in the agricultural and

environmental sphere

15:30-15:45 O-88 Liang Lv China Phosphate removal and recovery with calcined layered double

hydroxides as an adsorbent


16:00-17:35 Chairs Philip W. Lee and Dirk Freese

16:00-16:15 O-90 Thomas Q. Hu Canada Bleaching chemisty of tris(hydroxymethyl)phosphine and

tetrakis(hydroxymethyl)phosphonium sulfate

16:15-16:30 O-91 Valery P. Nesterenko Belarus Use of ion exchange composites based of Titanium and

Zirconium phosphates for cleaning of water solutions

16:30-16:45 O-108 Zhongdong Liu China Study on the preparation of wheat starch phosphate with low

degree of substitution

16:45-17:10 IL-34 Roger Hall Switzerland The role of phosphorus in crop protection: Experimental and

commercial disease and weed control agents

17:10-17:35 IL-35 Hongwu He China The use of OP and development of new organophosphorus

agrochemicals in China

Tuesday April 17 09:00-09:55 Chairs William H. Hendrix and Ernesto Brunet

09:00-09:25 IL-36 Mitsuru Sasaki Japan Current status of organophosphorus insecticide and

stereochemistry

09:25-09:40 O-89 Ranbir Padda UK Development, scaleup and commercialisation of catalyst lignds

09:40-09:55 O-92 Kevin Blann South Africa Selective chromium oligomerisation catalysts with various

phosphorus ligands


10:10-11:05 Chairs Li Zhengming and Mitsuru Sasaki

10:10-10:25 O-94 Wen-Jing Xiao China An efficient catalytic asymmetric synthesis and biological

evaluation of α-substituted aroyloxyl phosphonates

10:25-10:40 O-95 Ernesto Brunet Spain

Controlled synthesis of organic-inorganic materials derived

from phosphorous compounds. Variable porosity, photoinduced

electron-transfer and hydrogen storage

10:40-11:05 IL-37 William H. Hendrix USA Global use of organophosphorus pesticides

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12:10 Lunch


Wednesday April 18

Symposium 4. Nucleotides and Oligonucleotides-From Basics to Medicinal Applications; Biological Aspects of Phosphorus Chemistry

09:00-10:15 Chairs Renxi Zhuo

09:00-09:35 KL-14 Carston R. Wagner USA The Chemical Biology of Histidine Triad Nucleoside Binding

Proteins

09:35-10:00 IL-41 Alexander G. Gabibov Russia Study of artificially selected biocatalysts covalently modified

by Organophosphorus compounds

10:00-10:15 O-103 Chen Xiaolan China Synthesis of phosphorylated isoflavone and ESI investigation

of non-covalent complexes with protein


10:30-12:10 Chairs Carston R. Wagner and Alexander G. Gabibov 10:30-11:05 KL-42 Renxi Zhuo China Polyphosphates for drug and gene delivery

11:05-11:20 O-96 Alan H. Shih USA

Perifosine inhibits multiple signaling pathways in glial

progenitors and cooperates with temozolomide to arrest cell

proliferation in gliomas in vivo

11:20-11:35 O-97 Artur Mucha Poland A low-molecular phosphinic inhibitor of leucine

aminopeptidase of potential medical significance

11:35-12:10 KL-40 Wojciech Jacek Stec Poland Stereochemistry of enzyme-assisted P-N bond cleavage in

adenosine 5'-phosphoramidates and -phosphoramidothioates

12:10 Lunch


Thursday April 19

09:00-10:00 Chairs Serge L. Beaucage and Zhen Xi

09:00-09:35 KL-46 Marvin Caruthers USA Synthesis and biochemical activity of new oligonucleotide

analogs

09:35-10:00 IL-49 Xiang Zhou China Synthesis and biological studies of telomerase inhibitors


10:15-11:35 Chairs Marvin Caruthers and Xiang Zhou 10:15-10:40 IL-44 Zhen Xi China Non Watson-Crick structure recognition and its applications

10:40-10:55 O-100 Piotr Mlynarz Poland

The aza-α-aminophosphonate macrocycles as potential

supramolecular hosts for metal ions and biologically important

molecules

10:55-11:10 O-167 Qiang Xiao China Synthesis of bicyclic furopyrimidine deoxynucleosides

conjugated with N-diisopropylphosphoryl amino acids

11:10-11:35 IL-42 Serge L. Beaucage USA Thermosensitive phosphate/thiophosphate protecting groups

and the development of thermolytic oligonucleotide prodrugs

15

12:10 Lunch

14:00-16:25 Chairs Lihe Zhang and Karol Bruzik 14:00-14:35 KL-16 Lihe Zhang China Studies on modified oligonucleotides

14:35-15:00 IL-45 Karol Bruzik USA Probing mechanisms of phosphotransferases with thio effects

15:00-15:15 O-98 Barbara Nawrot Poland Mapping of the functional phosphate groups in the catalytic

core of deoxyribozyme 10-23


15:30-15:45 O-101 Renata Hiresova Sweden Studies on the condensation of H-phosphonate monoesters with

S-nucleophiles

15:45-16:00 O-104 Yong Ju China Synthesis of novel steroidal bioconjugates with AZT and

phosphorus

16:00-16:25 IL-47 Muthiah Manoharan USA RNA interference: the new paradigm of drug discovery based

on nature's phosphorous chemistry


Poster Session (April 18, 14:00-17:30)

Number First Author Nationality Title

P-1 A. D. Sinitsa Ukraine α-iminotrifluoroethyl phosphonate – the first representative of C-phosphorylated

N-H Imines

P-2 A. R. Burilov Russia Synthesis of calix[4]resorcins, containing phosphoryl fragments on the bottom

rim of the molecule

P-3 V. Kalchenko Ukraine Calixarene methylenebisphosphonic acids: alkaline phosphatase inhibition and

docking studies

P-4 A.E. Shipov Russia Interaction of 3-alkyl-2-alkoxy-1,3,2-oxazaphosphinanes with

alkylchloroformates

P-5 Oleg I. Kolodiazhnyi Ukraine α-(N-benzylamino)benzylphosphonic acids: stereoselectivity of binding to

prostatic acid phosphatase

P-6 A.V.Bogdanov Russia 2,2,2-tribromonaphtho[2,3-d]-1,3,2-dioxaphosphole: obtaining and reaction with

phenylacetylene

P-7 Aibing Xia Canada Synthesis, characterization and applications of novel iminophosphinites

P-8 Aiping LIU China Structural characteristic and electrode activities of phosphorus incorporated

tetrahedral amorphous carbon films

P-9 Ai-Yun Peng China Synthesis and reactions of phosphaisocoumarins

P-10 Alexandra C. Gledhill UK Designing new metallo-organic catalysts for the asymmetric phospho-Aldol

reaction

P-11 Andrew J. Wiemer USA Geranyl and farnesyl bisphosphonates inhibit protein geranylgeranylation

through Ggpp depletion

P-13 Bin Wang China Synthesis and cytotoxic evaluation of novel naphthoquinone fused phosphorus

heterocycles

16

P-14 Zhengjie He China Nucleophilic phosphine-catalyzed [3+2] cycloaddition of allenes with

N-(thio)phosphoryl imines: facile synthesis of substituted 3-pyrrolines

P-15 Budnikova Yu.H Russia Electrosynthesis of metal phosphides on the basis of white phosphorus

P-16 Chen Zhao China 1,3,4-oxazodizaole containing cyclo- and polyphosphazene

P-17 Chen-Wei Liu China Diselenophosphates: synthesis, reaction with electrophiles, and p-se bond

cleavage

P-18 D.V.Kulikov Russia Novel 36- and 38-membered P,N-containing cyclophanes with large hydrophobic

cavities

P-19 De-Qing Shi China

Stereoselective synthesis and biological activities of

o-(e)-1-{1-[(6-chloropyridin-3-yl)methyl]-5-methyl-1h-1, 2,

3-triazol-4-yl}ethyleneamino o-ethyl o-aryl phosphorothioates

P-20 Paul-Alain Jaffrès France Phosphorus functionalised carbenes: synthesis and coordination properties

P-22 Felix D. Sokolov Russia Extraction properties of 1,10-da-18-crown-6, modified by exocyclyc chelating

groups

P-23 Ferdinand Belaj Austria Tricycles synthesized by the reaction of PCl5 with open-chained molecules

P-24 Qi-Lin Zhou China Monodentate spiro phosphonites: highly efficient ligands for asymmetric

hydrogenation of non-acylated enamines

P-25 György Keglevich Hungary Microwave-assisted synthesis in organophosphorus chemistry

P-26 Qi-Lin Zhou China Chiral spiro monophosphites for Rh-catalyzed asymmetric addition of

arylboronic acids to aldehydes, ketones and imines

P-27 Kui Lu China The influential factor of temperature on synthesis of L-Arginine oligo-peptides

mediated by phosphorus oxychloride

P-29 Hong-wu He China Molecular docking of substituted alkylphosphonates to pyruvate dehydrogenase

P-30 Hideaki Miyake Japan Synthesis and properties of pentacoordinate phosphorus compounds containing a

pentacoodinate silicon atom

P-31 Hideaki Yamamichi Japan Synthesis of a novel apical–equatorial–equatorial type tridentate ligand and

construction of pentacoordinate phosphorus compounds

P-32 Ren-Zhong Qiao China A practical route to synthesis some phosphorylated prodrug

P-33 HongYu Zhang China The chemical synthesis of oligonucleotide phosphoramidates

P-34 Hui Wang China The catalytic ring-closure reaction in the presence of phosphorous oxychloride

P-35 Il’yas S. Nizamov Russia Dithiophosphorylation of cyclic monoterpenes

P-36 Ildar Magdeev Russia Backgrounds for the technology for the preparation of organophosphorous

precursors

P-37 Inga M.Aladzheva Russia Synthesis of 1,2-azaphosphetidines with amino acid fragment

P-38 Oleg I. Kolodiazhnyi Ukraine Asymmetric syntheses of new phosphonotaxoids

P-39 Jean-luc Pirat France Preparation of new [1,4,2]-oxazaphosphinanes : potentially antidepressive agent

P-40 Yu-bin Ji China Antitumor effect of betaine and its impact on the phosphorylation process of rats

bearing S180

P-41 Jian-chen Zhang China Studies on the self-assembly of L-Serine into L-Serine phosphopeptide mediated

by phosphorus oxychloride

17

P-42 Jian-chen Zhang China X-ray crystal structure of hydrolysates of triphenylphosphine dichloride

P-43 Jian-feng Zhang China Synthesis of N-protected o-hydroxyl-phenyl - α-aminophosphonic monoester

P-44 Ji-hong Liu China A novel mechanism about the cleavge of N-glycosidic bond in electrospray

ionization tandem mass spectra of nucleotide

P-45 José S. Yu USA Synthesis of isoprenoid olefin isomers via phosphonium and phosphoryl

stabilized carbanions

P-46 Zhi-yu Ju China The synthesis of 7,11,18,21-tetraoxa-1,3,5,13,15,17-hexaaza-2,4,6λ5,12λ5,

14,16-hexaphosphatrispiro[5.2.2.5.2.2]heneicosa-1,3,5,12,14,16-hexaene

P-47 Julia Frant Israel P-nitrophenoxycarbonylphosphonate diesters-potent reagents for the synthesis of

hindered carbamoylphosphonates

P-48 Xin-cheng Liao China Phosphorylation of dihydroxy anthraquinones by Atherton-Todd reaction

P-49 Shuang-xi Shao China Decomposition reaction of tetra-hydroxymethyl phosphonium chloride

P-50 Kirill E. Metlushka Russia Phosphonilation of 1,3-diaryl-2,3-dihydro-1н-naphth[1,2-е][1,3]oxazine by

dialkyl and diaryl phosphonates

P-51 Oleg I. Kolodiazhnyi Ukraine Dimenthyl (2r)-2-hydroxy-3-chloropropylphosphonate – accessible chiron for the

asymmetric synthesis of hydroxyphosphonates

P-52 Kui Lu China Investigation on interaction of L-methionine dipeptide with ct-dna by ultraviolet

spectroscopy method

P-53 He-ping Li China Ultrasonic photocatalytic degradation of the pesticide “methyl parathion”

P-54 Li Ma China Synthesis and seperation of L-Trytophan oligo-peptides assisted by phosphorus

oxychloride

P-55 Xiao-lan Chen China Synthesis N-phosphorylated chrysin-7-yl amino acid esters

P-56 Shuang-xi Shao China Application of tetrakis hydroxymethyl phosphonium in leather production

P-57 Liang-nian He China Applications of Lawasson’s reagent in synthesis of biologically active

phopshorus-heterocycles

P-58 Yong Ye China The synthsis of tripyrrole peptide containing phosphonyl

P-59 Li-ming Hu China Synthesis of o,o-dialkyl-2-oxo-2-(4-(selenomor

pholinosulfonyl)phenylamino)ethylphosphonate

P-60 Li-ming Qiang China Electrospray ionization tandem mass spectrometry Of N-phosphoryl-α-, β- and γ-

amino acids

P-61 Ling-lin Zhang China Remineralization effects of honeysuckle flower solution on initial enamel carious

lesions in vitro

P-62 Li-ping Zhang China Phosphorous acid nucleophilic addition at carbonyl groups

P-63 Zhuan-xi Luo China Sediment phosphorus buffering capacity in drainage ditch in hilly area of Purple

Soil, China

P-64 M.A.Pudovik Russia The synthesis of tetracyclic phosphorate

P-65 M.O.Lozinsky Ukraine Abnormal reactivity of arylaminomethylene¬bisphos¬pho¬nates.

aminomethylation on benzene ring in base medium

P-66 M.O.Lozinsky Ukraine Thioureido derivatives of methylenebisphosphonic acid as potential inhibitors of

alkaline phosphatases

P-67 M.V. Makarov Russia Phosphoryl substituted 3,5-bis(arylidene)-4-piperidones posessing high antitumor

activity

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P-69 Michael Salt UK The preparation of nitrogen-containing heteroaryoylphosphonates and their

reactions with trialkyl phosphites

P-71 Mikhail A.Pudovik Russia

Reaction of racemic and non-racemic silylated (1-phenyl)ethylamine with

o-phenylchloromethylisothiocyanatothiophosphonat. Synthesis of optically active

1,3,4-thiazaphosphole

P-72 Ming-xiu Lv China Self-assembly of L-glutamine into oligo-peptides mediated by phosphoric

chloride

P-73 Boris Ionin Russia Study of reaction of acetylenic phosphonates with carbanionic nucleophiles

P-74 Na Zuo China Synthesis and biological activity of α-hydroxyphosphonates

P-75 Nichola E. Cosgrove UK The phospho-Aldol reaction and complexes of aluminium containing salcyan and

related ligands

P-76 O. G. Sinyashin Russia Novel synthetic routes to phosphorus organic compounds on the basis of the

elemental phosphorus (P4)

P-77 Paul-Alain Jaffrès France New polyamines phosphoramidate vectors for gene therapy

P-78 Qing-yun Ren China Synthesis of 2-substitued-pyrano[2,3-d]pyrimidin- 4(3h)-one derivatives using

iminophosphorane

P-79 Jin-Jun Qiu China Synthesis and drug release behavior of unsaturated polyphosphoester

P-80 Jin-Jun Qiu China In vitro degradation properties of unsaturated polyphosphoester/β-tricalcium

phosphate composites

P-81 Ling-bo Qu China Synthesis of solanesyl phosphonate

P-82 Rafael A. Cherkasov Russia The synthesis, acid-basic and membrane-transport properties of the

phosphorylated amines

P-83 Rui Bao China Liquid crystalline behavior of cyclotriphosphazene

P-84 Kui Lu China Monitoring influence of reaction conditions on self-assembly into oligo-peptides

for three sulf-amino acids by using esi-ms

P-85 V. Kalchenko Ukraine Bio-relevant derivatives of calixarene phosphonic acids

P-86 M.I.Povolotskii Ukraine Synthesys and structural peculiarities of phosphorus pentachloride complexes

with 4-dimethylaminopyridine and n-methylimidazole

P-87 Shigekazu Ito Japan Chemistry of fulvene-type P-heterocyclic compounds

P-89 Shin-ya Nakafuji Japan Synthesis and complexations of a novel stable carbene bearing a phosphorus

ylide

P-90 Shu-xia Cao China Isolation and determination of diastereoisomers of amino acid hydridophorane by

hplc-esi-ms

P-91 Tao Wang China An efficient synthesis of α-(substituted phenoxy acetoxy)alkyl phosphinates

sodium salts

P-93 V.A. Kozlov Russia Phosphorylacetic acid thioamides as key substancesfor phosphorylated

heterocycles

P-94 V.F.Mironov Russia The formation of ion-radical salts in the reaction of fullerene C60 with

Phosphorus (III) amides

P-95 Oleg I. Kolodiazhnyi Ukraine New method for the asymmetric reduction of ketophosphonates

P-96 Vladimir A. Alfonsov Russia Diastereoselective synthesis of enantiopure cyclic α- aminophosphonic acids

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P-97 Vladimir A. Alfonsov Russia Synthesis of long chair organophosphorus compounds on the basis of industrial

fractions of higher olefins

P-98 Vladimir A. Alfonsov Russia Stereoselective synthesis of organophosphorus compounds on the basis of chiral

amino alcohols and amino acids

P-99 Vladimir F. Mironov Russia Reaction of 2-R-benzo[d]-1,3,2-oxazaphosphorin-6-ones with hexafluoroacetone

P-100 Wei-na Cao China Studies on the synthesis and separation of isoleucine oligopeptides assisted by

phosphorus oxychloride

P-101 Wen-hu Wang China Synthesis of bis(phosphonates) pyrrolidines derivatives

P-102 Wen-jie Zhao China Identification of self-assembly products of valine mediated by phosphorus

trichloride by ESI mass spcetrometry

P-103 Wen-jie Zhao China Mechanism of amino acids mediated oligomerization into peptides by

phosphorus trichloride

P-104 Wen-yan Mo China Synthesis of novel bicycli caged phosphate derivatives

P-105 Qi-lin Zhou China Synthesis of chiral spirobitetraline phosphoramidite ligands

P-106 Xiao Han UK The synthesis and reactions of alkyl 2,3,3-tris(dialkoxyphosphoryl)propionates

and alkyl 2,3,3-tris(dialkoxyphosphoryl)acrylates

P-107 De-qing Shi China

Synthesis and biological activities of o,o-dialkyl 1-((2-chlorothiazol-5-yl or

6-chloropyridin-3-yl) methyl -4-methyl-1h-1, 2, 3-triazol-4-yl-5-carbonyloxy

substituted methyl phosphonates

P-108 Li-Biao Han Japan Discovery of alkenylphosphorus compounds as a new class of cytotoxic agents

for cancer cells

P-109 Yong Ye China The synthesis of n-hydroxymethyl-3-(dialkylphosphono) propionamide

P-110 Hong-xue Xie China Determination of orgranophosphorous pesticides using phosphorous ionic

P-111 Hong-wu He China

Synthesis and thermal property of

bis(1-oxo-2,6,7-trioxo-1-phosphabicyclo[2,2,2]octane-4-methanoic)-2,2-dimethy

l-1,3-propanediester

P-112 Xin-peng Ma China Reactions between N-(thio)phosphoryl imines and diethylzinc

P-113 Xin-peng Ma China Aza-Henry reaction between N-thiophosphoryl imines and nitromethane

P-114 Wen-Jing Xiao China Organocatalytic asymmetric synthesis of α- hydroxy phosphonates

P-115 Xin-yuan Xu China The aza-morita-baylis-hillman reaction of N-thiophosphoryl imines catalyzed by

1,3,5-triaza-7-phosphaadmantane

P-116 Gui-rong Qu China The improved method for the industrial scale preparation of adenosine

cyclophosphate (camp)n

P-117 Rui-dong Xu China Study on structure and properties of amorphous Ni-Cu-P alloy coatings prepared

by electroless plating

P-118 Ya.A. Vereshchagina Russia Polarity and conformations of 1,2,4,5-tetra(tert-butylphospha)cyclohexanes in

solution

P-119 Guang-Ao Yu China Novel ionic phosphine ligands: their synthesis and application in Suzuki coupling

reaction in ionic liquid

P-120 Yong Ju China Synthesis and characterization of novel bile acids derived H-phosphonates

conjugates

P-121 Yan-chun Guo China Study of the reaction between N- (O, O-diisopropyl) phosphoryl amino acids and

20

the mixed nucleotides

P-122 Hong-wu He China Synthesis and herbicidal activity of α- [2-( fluoro-substituted

phemoxy)propionyloxy] alkylphosphonates

P-123 Yan-mei Li China Effects of phosphorylation on the conformation of peptide and protein

P-124 Kui Lu China Synthesis and purification of l-hydroxyproline oligo-peptides assisted by

phosphorus oxychloride

P-125 Ye-zhen Feng China Self-assembly of L-glutamic acid into oligo-peptides mediated by phosphorus

oxychloride

P-126 Hong-wu He China Synthesis, crystal structure and bioactivities of

dimethyl[(3,7-dichloroquinolin-8-yl carbonyloxy)

P-127 Wen-jing Xiao China Organocatalytic friedel-crafts alkylations of indoles with dialkyl

P-128 Kui Lu China The influential factor on synthesis of l-phe oligo-peptides mediated by pocl3

P-129 Ying-yan Yao China Synthesis of L-phenylalanine dipeptide mediated by phosphorus oxychloride and

separation by using RPLC

P-130 Xiao-lan Chen China Synthesis of some new 2-(bis-β-chloroethylamin) 7-methoxyl-3-substituted

phenyl-4-methyl-1, 3, 2-benzoxazaphosphorin 2-oxides

P-131 Yuan-ming Huang China Long-persistent fluorescent films of europium and dysprosium co-doped

aluminates

P-132 Yuen-Ki Cheong UK The reaction of pyrrole-2,5-diones and their halogenated derivatives with

trivalent phosphorus compounds

P-133 Yu Zhang China Ab initio study on the toxicity of organic phosphorus agrochemical

P-134 Zhi-wei Miao China Synthesis of diphenyl α-(o-phenyl

bis(2-chloroethyl)amidophosphorylamino)phosphonates

P-135 Jin-yun Zheng China Design and synthesis of 5’-fluorescently labeled nucleosides

P-136 Zhen-ying Liu China Pattern of sediment phosphorus fractions in a shallow Wuliangsuhai lake, China:

effects of macrophytes

P-137 György Keglevich Hungary Can four membered heterophosphete structures exist? “Heterogen” hetero

antiaromaticity as a destabilizing effect

P-138 Oleg I. Kolodiazhnyi Ukraine Modified alkaloids as organocatalysts for the asymmetric synthesis of

organophosphorus compounds

P-139 Chaobiao Huang China Determination of dexamethasone sodium phosphate in medicament by

fluorescence probe of Tb3+-tiron complex

P-140 Zhe Wang China Microwave-assisted syntheses of 2',3'-o-isopropylidene ribonucleoside

5'-monophosphates

P-141 Yu-yang Jiang China The correlation between the estimated partition coefficient P and capacity factor

k of amino acids and phosphoryl amino acids

P-142 Gareth Williams UK Developing a simple assay to screen for organophosphatases

P-143 Yu-yang Jiang China The pharmacokinetics analysis of the phosphoryl peptides in MCF-7/adr cells

P-144 A. V. Aleksandrova Russia Reactions of aminoacetylenephosphonates with N-nucleophilic reagents

P-145 Paul-Alain Jaffrès France New phosphoramidate dicationic vectors fo gene therapy

P-146 Boris A. Kashemirov USA Fluorescently labeled risedronate and related analogs: novel synthesis and

evaluation as imaging probes

P-147 Larryn W. Peterson USA Novel cidofovir prodrugs: conceptual and synthetic strategies

P-148 Thomas G. Upton USA Synthesis of α,β-difluoromethylenebisphosphonate analogs of dntps: probes for

21

DNA polymerase β

P-149 Hua Fang China Syntheses and characterizations of α-aminophosphonic acids and their

derivatives

P-150 Mei-juan Fang China

Ligand-protein inverse docking as a potential tool in the computer search of

protein targets of mycoediketopiperazine, a novel fungal metabolite from a

papularia sp

P-151 Pu-qin Cai China Synthesis of mopholino oligonucleotide with normal phosphate backbone by

phosphoramidite methodology

P-152 Wei-zhu Chen China Electrospray ionization mass spectra of amino acid methyl ester

5'-phosphoramidates of 2', 3'-isopropylideneuridine

P-153 Nan Zhang China Synthesis and bioactivity of six-ring nucleoside modified SIRNA

P-154 Edgar Niecke Germany Template-directed synthesis of phosphorous containing

macrocycles:structure/reactivity-relationships

P-155 Jian-bo Hou China Synthesis and mechanism studies on dipeptide bond by

hexamethylphosphoramide(HMPA)

P-156 Tong-jian Wang China A novel synthesis of o-phosphorylated N-menthoxy- carbonyl tyrosine

P-158 Nan Zhang China Antisense therapy targeting pokemon oncogene in MCF-7 cell

P-157 Nan Zhang China Inhibition of pokemon gene expression by antisense oligonucleotides

P-159 Shigeru Sasaki Japan Synthesis and structure of thiophene, selenophene, and related compounds

carrying four phosphoryl groups

P-161 Yi-xiang Ding China Synthesis and mechanism of phosphaisoquinolin-1-ones by pd(ii)-catalyzed

cyclization of o-(1-alkynyl)phenylphosphonamide monoesters

P-162 Yuan Ma China The positive and negative electrospray ionization (ESI) mass spectrometry of

1-(n-ethoxycarbonylamino)arylmethylphosphonic monoesters

P-163 M.A. Khusainov Russia Interaction of 2H-1,2,3-diazaphosphole with diols

P-164 N.G. Khusainova Russia Synthesis of new β-amino-derivatives of alkenylphosphonates

P-165 Il’yas S. Nizamov Russia Bisdithiophosphonic acids in metal complex formation reactions

P-166 Krasnova N.S Russia New functionalized phosphoryl membrane carriers of organic and nonorganic

substrates

P-167 Qiang Xiao China Synthesis of bicyclic furopyrimidine deoxynucleosides conjugated with

N-diisopropylphosphoryl amino acids

P-168 Ting Zhang China Effects of chrysin and its tetraethyl bis-phosphoric ester in the cell cycle and P21/WAF1 proteins of the human cervical carcinoma cell line Hela

P-169 Feng Ni China Locating the reaction paths of N-(dialkyloxyphosphoryl) amino acids by nudged

elastic band(neb) method

P-170 Jia-ning Wang China The peptide bond formation reaction with peptides and proteins in aqueous

solution by inducement of N-phosphoryl α-amino acids

P-171 Feng Ni China Green synthesis of phosphoramides by trimetaphosphate(P3m)

P-172 An-fu Hu China The synthesis and resolution of the opticle active derivatives of

N-thiophosphoramidate derivatives

P-173 Xing-hai Liu China High throughput screening under Zinc-database and synthesis a

dialkylphosphinic acid as a potential KARI inhibitor

P-174 J. Heinicke Germany Novel Pyrido- and benzo-annulated 1,3-azaphospholes

P-175 J. Heinicke Germany Phosphinoglycines and phosphinoglycolates

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P-176 A. Colson France New ferrocenyl phosphino-aminoacids as modular electrochemical biomarker for

csf114(glyco)peptides

P-177 C. Darcel France Designing phosphorus ligands at the P-center for asymmetric reactions catalyzed

by Rh or Pd complexes

P-178 H. Lauréano France Stereospecific preparation of P-chirogenic phosphide boranes from the

corresponding chlorophosphines

P-179 M. L. Auclair France Recent progresses on P-chirogenic phosphine synthesis

P-181 Ruo-yu Liu China A study on the organic compounds containing germanium and phosphours using

EI mass spectrometry

P-182 Ruo-yu Liu China 31P NMR assay of the enantiomeric excess by using quinine as chiral solvating

agent

P-183 Ruo-yu Liu China A study on the nucleoside analogs using electrospray ionization mass

spectrometry

P-184 Xiao-xia Liu China Studies on the noncovalent bonding between ATP and α-aminophosphonic acids

derivatives by ESI-MS and molecular modeling

P-185 Xiao-xia Liu China Peptide bond formation on C-terminal of peptides in organic solution by

inducement of N-phosphoryl amino acid

P-186 A. P. Marchenko Ukraine Synthesis of hexaisopropyltriamidephosphite: myth or reality?

P-187 Liu-ji Zhang China A convenient method for the synthesis of cyclophosphamide analogues

P-188 Tao Ji China Convenient synthesis of α-hydroxyphosphinate

P-189 Xian-tong Huang China Investigation on a hydroxyl oxygen migration of N-phosphoryl dipeptides by

electrospray ionization mass spectrometry

P-190 Kan Lin China Synthesis of N-(diisopropyloxyphosphoryl)dipeptides in a one-pot method

P-191 Qin Tao China Organophosphorus compounds as small molecular catalysts in the direct

asymmetric aldol reaction

P-192 Xiang Gao China Investigation on the peptides formation from amino acids reacted with

trimetaphosphate by LC-MS

P-193 Wei-zhu Chen China Synthesis of amino acid methyl ester 5'-phosphoramidates of

2',3'–isopropylideneuridine

SOCIAL PROGRAM

23

A programme of events has been designed for accompanying persons whilst the conference is in session. The tours offer an introduction to the culturally and historically rich area of Xiamen. A taste of what each tour offers appears below. The Registration Fee is USD 100 per person (Lunch included).

Date Morning Afternoon Evening Sun. (Apr. 15) Registration Reception

Mon. (Apr. 16)

PROGRAM 1: Sightseeing Xiamen University and Nanputuo Temple

Free time PROGRAM 5: Chinese

Painting and Tea party

Tue. (Apr. 17) Free time PROGRAM 4: Excursion Free time

Wed. (Apr. 18)

PROGRAM 2: Sightseeing the Hulishan Fortress and the Island Ring Road

Free time PROGRAM 6:

Music Party

Thu. (Apr. 19)

PROGRAM 3: Shopping at the Zhongshan Road

Free time PROGRAM 7: Banquet

Fri. (Apr. 20) PROGRAM 8: Tour to “Tulou” Building (Optional)

Note: 1. Registration: at the Lobby of Yifu Hotel Building; 09:00-21:00 2. Reception: at 2nd floor of Yifu Restaurant, 19:00p.m.. 3. PROGRAM 1-3: Gather at Lobby of Yifu Hotel; leaving time: 9:00 a.m.. 4. PROGRAM 4: Gather before Jiageng Main Building; leaving time: 13:30 a.m.. 5. PROGRAM 5: Chinese Painting and Tea party, at Room 602 in Jiageng No. 2 building, 19:00 - 22:30

6. PROGRAM 6: Music Party, at 3rd floor of Keli Building, start from 20:00p.m.. 7. PROGRAM 7: Banquet, picking up from Yifu and Hilford Hotels at 18:30 p.m.. Banquet Location: International Seaside Hotel Xiamen (5 star-hotel) 8. PROGRAM 8: Tour to “Tulou” Building. Detail information will be notified at registration desk.

GENERAL INFORMATION Venue and Accommodation (see following form) The accommodation is assigned to “Hilford” hotel. Hotel information is browsed in the website: http://www.hilford.com.cn/en/main.asp. The room rate is USD 60-100 per room per night. For young scientists (postdocs and students) the rate is USD 30-35 per person per night for a shared room. During the Conference, the Organizing Committee will arrange lunch for the participants. Registration Registration Desk will be settled in the lobby of Yifu Building of Xiamen University from 9:00 to 21:00

24

April 15 for participants. On-site registration and distribution of conference package will proceed at the registration desk. The Registration Fee at local: Delegates (USD 500) , IUPAC Members (USD 450) and Students (USD 250).

• Fees for the active participants will cover the payments for the participation in all scientific sessions, a copy of the Abstract Book and all printed materials of the conference, a welcome reception, lunches and social events.

• IUPAC Affiliates should send a copy of their IUPAC Affiliate Membership Certificate with their registration.

• Students should send their registration with a letter from their supervisor. Their fees will cover the same benefits as for the active participants.

• The payment of the registration fee should be made in US dollars.

• The Conference Banquet Time: 19:00 to 22:00 on April 19, 2007 Location: International Seaside Hotel Xiamen (5 star-hotel) Fee: USD50 (Including tickets of dinner, round trip transportation between Xiamen University and banquet site, and traditional Chinese performance show.)

i) by bank transfer:

Name of Account: Xiamen University Account No.: 840062414508096014 Account Opening Bank: The Bank of China, Xiamen Branch, Xiamen University Branch Address: Xiamen University, Xiamen, Fujian, PRC, 361005

Please write your name and " ICPC2007" on your bank transfer

ii) by mail to:

Baoyu Zheng Secretary of ICPC2007 The Key Laboratory for Chemical Biology of Fujian Province Xiamen University, Xiamen, 361005, China

Please write your name and "ICPC2007" on your draft

LOCAL TRAVEL INFORMATION

25

Arrival in Xiamen

Participants can make their own way to the Hilford Hotel or Xiamen University by taxi. The distance from Xiamen international airport to Xiamen University is about 30 km and the fare is about USD 9 (RMB 60-70). The note below will help you to get to Xiamen University:

请您送我到厦门希尔福大酒店

Please take me to Xiamen Hilford Hotel

Tel: (0592)-2082222

请您送我到厦门大学逸夫楼

Please take me to YiFu Building at Xiamen University

Tel: (0592)-2182623

Post-conference Tours (See following form)

A few Post-conference tours, as well as Accompanying Person Tours, have been arranged. Please visit the Web Site for details: http://icpc2007.xmu.edu.cn.

Exhibition An exhibition of scientific instruments and equipment by leading manufacturers, as well as books and journals, will take place during the Conference. Interested companies should contact the Secretariat of ICPC2007.

CORRESPONDENCE The Key Laboratory for Chemical Biology of Fujian Province Xiamen University, Xiamen, 361005, China Tel.:(0086)-(592)-2185610, Fax: (0086)-(592)-2186292 http://icpc2007.xmu.edu.cn

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Email: [email protected], [email protected]

Note: The conference programme is not yet finalized at this stage and the organizers reserve the right to amend timings, content and speakers without prior notice

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ap

of Xia

men

Islan

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To Hilford Hote

NanPuTuo Gate And Bus Stop

KeLi Hotel (Open ceremony) (music party)

YiFu Hotel

(Dining Hall) (registration)

FuRong Lake

ICPC2007 Meeting Site QunXian Building 2

Map of Xiamen Univ.

Poster hall Chemistry New Building

To New Campus Gate

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3rd circular - chem.xmu.edu.cnchem.xmu.edu.cn/doc/d2220f8f-99c1-2981.pdf · phosphorus in organic...

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