37039 11111111111111111111111111111111111 alamos national labs/ta 54/37039.pdfo march 27, 2015 hsg...
TRANSCRIPT
ESHID-600320
From: Haagenstad, Mark P Sent: Friday, March 27, 201S 3:18 PM To: [email protected]; [email protected]; John Kieling; [email protected]; [email protected]; [email protected]; [email protected]; [email protected]; [email protected]; [email protected]; [email protected]; Cobrain, Dave, NMENV; [email protected] Cc: Pete Maggiore; Silas DeRoma; Cummings, Lisa K; Nickless, David J; Bishop, M. Lee; Turner, Gene E; Armijo, Karen (CONTR); Wallace, Terry C; Torres, Enrique; Woitte, Deborah Kay; Clemmons, Steve; Allen, Don; Brandt, Michael Thomas; Sharp-Geiger, Raeanna Racine; Dorries, Alison Marie; Grieggs, Tony; Bacigalupa, Gian A; Vigil-Holterman, Luciana R; Alexander, Rick A; Baumer, Andy; Martinez, Saundra; Sauer, Selena Z; Schreiber, Arleen Thorn; Maestas, Pamela Therese; Hargis, Kenneth Marshall; Cabbil, Cheryl Denise; Young, Steven L; Erickson, Randy; Funk, David John; Alexander, Rick A; Frederici, Dave; Robinson, Bruce Alan; Lansing, Michael Alan; Tymkowych, John M; Diaz, Tammy; Branch, Yvette S; Guffee, Debi; Juarez, Catherine L; Armijo, Karen (CONTR); Haagenstad, Mark P Subject: Daily Technical Submission - March 27, 201S
Attached is the written daily technical submission for today. The Permittees are submitting the attached information pursuant to: Section 19 of the May 19, 2014, Administrative Order; the July 10, 2014 letter from NMED regarding Modification to May 19, 2014, Administrative Order; and Section IX of the September 19, 2014, LANL Nitrate Salt-Bearing Waste Container Isolation Plan, Revision 2.
Please contact me if additional information would be helpful.
Mark Haagenstad Environmental Protection Division Compliance and Permitting Group Los Alamos National Laboratory Office: (SOS) 66S-2014 Mobile: (SOS) 699-1733
1 37039
11111111111111111111111111111111111
NMED I LANL Technical Summary
March 27, 2015
LANL Technical Update:
• Location of Nitrate Salt-Bearing Wastes
o Remediated nitrate salt-bearing waste containers. • All containers remain in the 375 Permacon.
o Unremediated nitrate salt-bearing waste containers. • All containers remain in the 231 Permacon.
o Newly suspect nitrate salt-bearing waste containers. • Two containers are located in Dome 232 and two containers are located Dome
153. • All entry into the domes is currently restricted.
• Planning is underway to move the containers into the 375 Pennacon.
• Monitoring - Daily Temperature
o Temperatures remain below 90°F. • Previous day's temperature data attached.
• Monitoring - Visual Inspections
o No abnormal conditions were observed.
• Monitoring - headspace gas (HSG) o Containers (SWBs) 68685 and SB50522.
• Continue daily head space gas (HSG) sample collection. • March 27, 2015 HSG data attached.
o lb, CO, C02 and N20 o Other containers:
• A minimum of once per month HSG sampling will be conducted. • To date in March, LANL has conducted HSG sampling on 55 SWBs.
• Additional measures currently underway
o As a conservative measure, LANL is currently conducting additional monitoring. This additional monitoring includes:
• Containers (SWB) 68685 and SB50522. • LANL continuing solid phase micro-extraction. • Hourly temperature measurements are currently being performed on SWB
68685 and SB50522.
• Five (5) other SWB overpacks (containing 55-gallon drums of remediated nitrate salt-bearing waste).
• Continue twice-weekly HSG sample collection. • March 26, 2015 HSG data attached.
1
o l-h, CO, C02 and N10 • Newly suspect nitrate salt-bearing waste containers located in Domes 232 and 153
• HSG sample collection began on March 26, 2015 o March 27, 2015 HSG data attached.
• H2, CO, C02 and N20
• Anticipated Changes to Nitrate Salt-Bearing Waste Containers (e.g. movement, repackaging)
o Currently, no further movements or re-packaging are occurring.
Other:
• At approximately 12:00 PM today (March 27, 2015). the four newly identified suspect nitrate salt-bearing waste containers were moved from Domes 153 and 232 into Dome 375 Permacon Cell 3 and are currently under isolation. LANL will be providing to NMED-HWB a revision to the Revised LANL Nitrate Salt-Bearing Waste Container Isolation Plan that incorporates proposed changes for the four newly identified suspect nitrate salt-bearing waste containers currently in isolation in the Dome 375 Permacon.
Next Call: Tuesday, March 31, 2015
2
Summary Chart - Requested Information I Pending Issues:
'''"NNNl
Requested Information ! Actionee i 1
NMED contact I process for LANL to notify NMED NMED under the Revised Isolation Plan (e.g.,
: 24"~ol1.r.n~tic~s,2:~ ,,,.~A ' .. ~lj~1 .. ~.?.c ... ~914
Keep NMED informed on the status of on- LANL Complete going chemistry I analytical work.
"'A' June.?~. 2Q14
3. . i On upcoming daily call, provid~ ~dditional .LANL Complete discussion on the potential for liquids in the
' 350 post-1991 cemented containers (including • July6,2014 a discussion of the review of RTR tapes). , (Discussion on call)
;
' i July 18, 2014 1
~Meeting held) 4. On upcoming call, provide additional LANL ·Complete
: discussion on why 231 and 375 Permacon fire suppression systems are not part of the LANL June 5, 2014 RCRA Hazardous Waste Facility Pennit
I • Contmgency Plan. . . . ...
5. Send copy of June 4, 2014 written daily Complete submission to Trais Kliphuis. Also, include her on fu~~re .daily submissions. June 5, 2014
' ' mm.o""vo~ "'
6. Provide LANL procedures and example LANL • Complete . records associated with post-1991 T A-55 1 cementation r.i:.ocess discussed on June 6. . July\.?914
7. Provide infotmation on numbers of containers LANL •Complete : in the post-1991 cemented waste streams from 1 the T A-55 process discussed on June 6 .. This June 17, 2014 · should include numbers regarding RTR status
(Supplemental Info : (RTR'd, meet WIPP criteria, requiring .. remediationL ..
provided July 3) . ..
Provide RTR video and pre-screening LANL Complete • information associated with those containers i requiring remediation from the post-1991 : July3,2014 : cemented waste streams from the T A-55 i process discussec,f on June 6.
Provide copy of CCP/LANL Interface Document.
· June 9, 2014 10. Provide a list of the analytes for which LANL LANL ··complete
is sampling HSG (C02 and LFL analytes). ·June 11, 2014
, 'm ,,,.,
11. Discuss potential sampling ofHSG for NOx. LANL . Co~plet~
1 JuneJ6~}Q14 ..
3
Requested Information
, «"<-m»i<i~!M~!>i>'>~>~> '''" /
12. · Follow-up with Tim Hall regarding LANL Hazardous Waste Facility Pennit and
. procedures that LANL is developing for • possible future sampling of empty parent ' containers and unremediated nitrate salt-1 bearing containers at LANL.
Actionee
LANL
. Completion •Date
Complete
Empty Parent June 16, 2014
Unremediated August 14, 2014 (Supplemental information discussed on sampling of parent containers)
August 26, 2014 (Letter on applicability of LANL HWFP for opening waste containers)
4
Status ···········rc~~ptetion
I Date --~~·~•···~-m•=••••~=-•••••%==-•%%=-•~••»•=~=m·••••~•~=4'==••••••••»-=-=-4'==-=-=-=-=-=-=-•w••~~tj&~ ~~~••••••==-~
Respond to NMED email request for infonnation associated with the nitrate saltbearing parent and daughter waste containers.
WIPP Recovery Daily Meeting Action List item #84 - NMED requested a copy of the LANL remediation records for waste stored in Panel 6 (Trais Kliphuis)- is a subset of the information in item 5 of this action.
Complete July 9, 2014 (Letter sent addressing items 1-4 and 6-9 of the email request)
July 17. 2014 (Letter sent with updated spreadsheet)
August 7, 2014 (First submittal in response to i tern 5)
August 14, 2014 (Letter addressing items 2&8 - Second submittal in response to item 5)
August 18, 2014 (Third submittal in response to item 5)
August2L2014 (Fourth submittal in
, response to item 5)
August 27, 2014 (Fiflh submittal in response to item 5)
September 4, 2014 (Sixth submittal in response to item 5)
September 9. 2014 (Seventh submittal in response to item 5)
September 11,2014 (Eighth submittal in response to item 5)
September 22, 2014 (Ninth submittal in response to i tern 5)
September 23. 2014 (Tenth submittal in response to item 5)
October I, 2014
(Eleventh submittal in response to item 5)
October 8, 2014
(Twelflh submittal in response to item 5)
October 16, 2014
(Thirteenth submittal in response to item 5)
October 23, 2014
(Fourteenth submittal in response to item 5)
October 27. 2014
(Filleenth submittal in response to item 5)
October 28, 2014 (Sixteenth submittal in response to item 5)
November 3, 2014 (Seventeenth submittal in response to item 5)
5
1 Requested Information i Actionee Status ' Completion
'Date ''>'<''-~"'''·'>''ili»»>'' ,,,,,,<,N!-0.W~>iw'>~>'»>'''' <~!~>'%--
14. NMED will review the Round Sheets NMED NMED has reviewed Complete (provided in June 11 summary) and infonn Round Sheets - no
, LANL if these should be attachments to the I comments I direction at June 23, 2014 Revised Plan, or if they fall under the : this time. NMED will
provision in Section I of the Revised Isolation address any comments in their formal response to
Plan and their identification during this Revised Container technical call is sufficient. Isolation Plan.
15. NMED has requested 'copies of any waste LANL . Complete . processing, treatment, characterization stop
: June 13, 2014 orders issued since Feb 14, 2014.' • (Included w/ daily ! summary)
. June 16, 2014 • (Discussed current I T A-54 & WCRRF
' NMED reque~ted information on the location operations)
16. LANL Complete I
• of drums 68327 and 68328. Request made June 14. June 14, 2014
17. Update on LANL efforts - including LANL LANL/ Complete teams. (On June 20 call. LANL offered to NMED
• schedule an update meeting). July 2, 2014 "
18. Neutralizer use in association with container LANL Complete S855793 (parent of 68660 and 68685).
June 25, 2014 19. List of nitrate salt-bearing waste containers •LANL Complete
that LANL records indicate contain absorbed liquids with the same neutralizer, as discussed September 30, during June 25 technical call. 2014
(with August 26, 2014 response)
20. Schedule follow-on update on LANL efforts - I LANL/ Complete ; including teams. '.NMED
·August 14,2014 (Meeting held).
21. NMED requested information on document LANL Complete approval I review (as discussed on July 3 call). Jt11:y29~}Q14
22. What analyses will be conducted on samples LANL . Complete : taken from empty drums that previously
contained nitrate salt-bearing waste. JuJx?: 2014 . 23. NMED requested the following information LANL Complete
on cemented waste containers generated from T A-55, that are currently stored above-ground July 17,2014
l at Area G: container id number; location; . (Letter sent w/
form (cans or monoliths); and type of 1
information)
concrete. Additionally, NMED requested I July 18,2014 information on pH adjustment during waste
generation process, and information on · (Meeting held)
. anticipated pH of free liquids (and rationale).
6
NMED requested the procedure for sampling empty parent drums that previously contained
. nitrate salt-bearing waste.
'h''
NMED requested an additional discussion on LANL a future technical call regarding C02,
including data.
w~" M •"
26. NMED requested additional discussion on CIN-01 waste containers and absorbent, including confirmation and extent of use.
27. , NMED requested historic analytical LANL ; information on pH ofliquids associated with
.... f WP~ll!!~~~.mented wast~: .... 28. : NMED requested link to pdf of Actinide LANL
J Quarterly edition (3rd Q 2008). i
29. • NMED requested a ~opy of lessons learned
30. NMED request regarding empty drum sampling presentation.
: Respond to NMED email request dated · 8/12/2014 for information associated with the ' nitrate salt-bearing waste containers.
32. : NMED request regarding technical · presentation.
LANL
• LANL
LANL
33. · NMED request regarding literature review of LANL ! catalytic reactions.
34. LANL requested to schedule a meeting with NMED on remediation planning and schedules.
35 .• Schedule a third update on LANL efforts -'. including teams.
LANL/ NMED
LANL/ NMED
Status .
! Completion ·Date
EP-AREAG-WO-DOP- Complete 1245 is included in
Enclosure 1 to LANL's July 8, 2014 July 3, 2014 Response
to Request for Information on
Management ~{Waste at LANL.
, Complete
! August 14, 2014 , ... ,. i .. (M(!~!i'-1~.~.el~)
i Complete
I July 18, 2014 . ... J (Meetin~held)
•Complete
Presentation is a pre
' Augl)st 7, ?914 Complete
. decisional draft/working • August 25, 2014 document not for external release
Presentation is a pre-
: September 11, 2014
decisional draft/working • August 25, 2014 document not for external release
Literature review is a pre-decisional , August 25, 2014
draft/working document : not for external release
Complete September 29, 2014 (~eeting held) Complete
' October 20, 2014
7
~
Requested Information
36. NMED request regarding LANL Causal LANL Analysis associated with processing of nitrate salt-bearing waste at WCRRF - when document is Final.
37. NMED requested a diagram illustrating the • LANL current locations within the 375 Permacon of the 55 SWBs that contain the 57 remediated nitrate salt-bearing waste containers. NMED also requested a list of these 55 SWBs and the waste drums within each S WB (including the container numbers and waste stream type).
Document is currently Draft.
l
Completion Date
Complete October 27, 2014 (Diagram submitted)
November 3, 2014
; (Table submitted)
November 20, 2014 (Revised table submitted)
8
.... : Requested Info~lllation
38. NMED requested documentation regarding CINOI.001 waste containers that are not part of the September 19, 2014 Nitrate SaltsBearing Waste Container Isolation Plan, Revision 2.
39. i NMED requested a diagram of the location of . 1 thethe!1110C().uples on 68685 and SB50522.
40. i NMED requested a copy of the safety basis : document for remediation planning when it is · finalized.
41 . Trending and correlation of temperature and · HSG monitoring data.
42. • Schedule a fourth update on LANL efforts -· including teams.
Acti.;~e~·T Status I Completion '1
I ' I I , 1 ; Date :
,,\ »>$>->i'M''"'".-_"'-i''"i''W/;.> .. ;w .. ;W#¥/#..<W•V'fo-'y y,1,,;. .. ,,,,,..,,,,,~,'>i>."<.<:'.<X::$N>~>m:.i~IM>M'-''W-"0.<:-<«'''"''~''', ,"''"'""'--! LANL 1 In Progress i Submitted I 00 out I
LANL
LANL
:LANL
LANL/ NMED
LANL will submit this I of 586 RTRs and · documentation in I documentation on
batches as it is becomes I October 3, 2014· i Submitted
available. ! documentation for
''''"v' ''
Document is currently in Draft.
[n progress
i 101-200 containers on October 10, 2014. Submitted documentation for 201-300 containers on October 16, 2014. Submitted documentation for 301-400 containers on October 23, 2014. Submitted documentation for 401-500 containers on October 27, 2014. Submitted documentation for 501-586 containers on November 12, 2014. Submitted RTR Videos 101-150 on
• November 12, • 2014. • Submitted RTR . Videos l 5 l-200 on
November 20, 2014 .
• Submitted RTR Videos 201-250 on December I, 2014.
: Submitted RTR Videos 251-300 on
. December 19, 2014 .
. Submitted RTR Videos 301-312 on
• Janu.ci~yl5, 2915. •Complete • October 27. 2014
•Complete • November 3,
2014
9
1 Request~d l~form~ti~n·
Schedule a fifth update on LANL efforts -. including teams.
,. 'N• ' ~ ,,, ',. ~ •A, '
44. ; Schedule a sixth update on LANL efforts -
iri,clud!!l.~~(lll!S· .............. . NMED requested documentation regarding CINOl drums.
46. NMED requested documentation regarding ... L~l!:P!i~~.t~.drum number. . .
47. i NMED requested the ESS plan for ; temperature control and sampling once I finalized.
48. Schedule a seventh update on LANL efforts -: including teams.
49. Fire suppression repair plan for Dome 231
. . . 50. ; NMED requested information regarding
1 solution packages 36, 37, 57 and 78.
51. • NMED requested copies of any procedures regarding cementation in bags.
1 Actionee
LANL/ • NMED
• LANL/ NMED
1 LANL
LANL
LANL/ NMED
•LANL
LANL
LANL
52. NMED requested information on the LANL percentage of the 55 SWBs that, based on
. S WB HSG data, appear to have chemical ! reactions occurring .within the wast.e.
53. NMED requested the document ''T A-55 LANL ! Cement Fixation Drum Logbook'' referenced . in the CCP AK document.
Status
......•...........•.......
" " "~'~
Document is currently in Draft.
, Completion •Date
Complete ; November 20, '2014
''' 'w ua ',v
Complete ; December
Complete • Email- February • 3, 2015 • Letter- February
12,.2015 ..
Complete .. · .. January 29, 2015
In progress
In pro!:,rress
; This repair plan is · no longer
necessary because · drum movement · did not occur · during the repair
process. Repair is •complete:
Complete. Email - February 17, 2015. LetterMarch 19,2015. March 19, 2015 Confirmation that no specific procedure can be located for cementation in Q(lgs.
10
Remediated Nitrate Salt Container Headspace Gas Analysis
68685 5850522 87823
Date H2ppm CO ppm C02ppm N20ppm H2ppm CO ppm C02ppm N20ppm H2ppm CO ppm C02ppm N20 ppm
03/27/15 122 414 8906 2206 2361 504 36100 1061 187 164 4431 506
Page 1of2
Remediated Nitrate Salt Container Headspace Gas Analysis
87825 87826 87827
Date H2 ppm CO ppm C02 ppm N20ppm H2 ppm CO ppm C02 ppm N20ppm H2 ppm CO ppm C02 ppm N20ppm
03/27/15 209 219 7182 892 218 271 9460 920 46 0 2686 242
Page 2 of 2
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