3. treatment of primary effluentsepr-reactor.co.uk/ssmod/liblocal/docs/v3/volume 2... · 2007. 7....

SUB-CHAPTER: I.3 SECTION : I.3.3

PAGE : 1 / 21 UK-EPR

FUNDAMENTAL SAFETY OVERVIEW VOLUME 2: DESIGN AND SAFETY

CHAPTER I: AUXILIARY SYSTEMS

3. TREATMENT OF PRIMARY EFFLUENTS

3.0. SAFETY REQUIREMENTS

3.0.1. Safety functions

The Primary Effluent Treatment System (TEP [CSTS]) does not play a direct role in fulfilling the three basic safety functions.

However, since the TEP [CSTS] conveys a fluid containing radioactive products, its pressure envelope must be designed to contain radioactive products (containment barrier).

This system also plays a part in retaining radioactive materials in normal operation, and is thus important in reducing releases into the environment.

3.0.2. Functional criteria

Since the Primary Effluent Treatment System (TEP [CSTS]) does not fulfil an active safety function, there are no safety-related functional criteria.

3.0.3. Design requirements

3.0.3.1. Requirements derived from safety classifications

- Safety classifications

The Primary Effluent Treatment System is safety classified in accordance with the classification principles given in Chapter C.2.

- Single failure criterion (active and passive)

Not applicable

- Emergency electrical supplies

Not applicable

- Qualification to operating conditions

Not applicable

- Mechanical, electrical and instrumentation and control classification

The Primary Effluent Treatment System mechanical, electrical and instrumentation and control classification are determined according to the classification principles given in Chapter C.2.

- Seismic classification


PAGE : 2 / 21 UK-EPR FUNDAMENTAL SAFETY OVERVIEW

VOLUME 2: DESIGN AND SAFETY CHAPTER I: AUXILIARY SYSTEMS

The Primary Effluent Treatment System is not seismically classified.

- Periodic tests

The Primary Effluent Treatment System fulfils no active safety function and is designed for normal operation of the unit, during which it is regularly used. No need for periodic tests has been identified at this stage.

3.0.3.2. Other regulatory requirements

Not applicable

3.0.3.3. Internal/external hazards

Internal hazards: see Chapter C.4.

External hazards: see Chapter C.3.

3.1. ROLE OF THE SYSTEM

To simplify the description, the Primary Effluent Treatment System (TEP [CSTS]) is divided into four sub-systems: the coolant storage system, the coolant treatment system, the coolant purification system and the coolant degassing system.

Storage of the coolant

The coolant storage system fulfils the following functions:

- receipt and storage of the primary fluid from the RCV [CVCS] following changes in the boron content due to fuel burn-up during the cycle, load variations (including operation in load follow-up) and start-up and shutdown transients

- receipt and storage of primary effluents collected by primary recyclable drains of the nuclear vents and drains system (RPE [NVDS])

- receipt and storage of effluents collected by the nuclear vents and drains system (RPE [NVDS]) which cannot be transferred to the RPE [NVDS] primary drain tank in the event of excessive discharge of safety valves connected to the RPE [NVDS]

- storage of degassed demineralised water to supply the REA [RBWMS] water makeup system

Purification

The coolant purification system extracts impurities and fission and activation products upstream of the treatment system.

Treatment

The coolant treatment system fulfils the following functions:




- separation of effluents into borated water with 7000 ppm boron content (concentrates) and demineralised water (distillates) for re-use in the primary system

- degassing of distillates before re-injection into the primary system or their removal to the discharge system (in the event of high tritium content) and degassing of the SED demineralised water makeup needed to compensate for any discharges

Following separation into boric acid and demineralised water, the primary effluent, is re-introduced into the primary system via water and boron makeup (REA [RBWMS]) and the chemical and volume control system (RCV [CVCS]).

The gaseous effluent derived from degassing of distillates is transferred to the Gaseous Effluent Treatment System (TEG [GWPS]) where its activity is reduced before discharge.

Degassing

The purpose of the degassing function is to extract the gases dissolved in the primary fluid which cannot be extracted by ion exchange or filtering for direct re-injection via the RCV [CVCS] with no change to the boron content. The degassing is generally performed:

- before the Primary System (RCP [RCS]) is opened for refuelling or intervention in order to avoid discharge of active gas into the containment atmosphere

- after the Primary System is closed after a plant shutdown, to remove the oxygen dissolved in the coolant, which could lead to corrosion of the materials in the RCP [RCS]

- when the plant is operating, for reducing the concentration of noble gases and other gases, if the primary coolant design activity limit is being approached, or if it is required to maintain the required coolant chemical composition

3.2. DESIGN BASIS

3.2.1. Coolant storage and treatment systems

The coolant storage and treatment systems are designed for normal operation of the plant. Base load operation, load follow operation and transient conditions are taken into account.

3.2.1.1. Sizing of the storage system

Independently of the plant operating conditions, the following transients are considered in the design of the storage system:

- brief hot shutdown of about 6-8 hours (restarting at maximum xenon)

- long hot shutdown of about 90 hours (restarting without xenon)

- cold shutdown (restarting without xenon)

- shutdown for refuelling (with pressure testing before plant restart)




The total storage capacity is governed by the quantity of demineralised water needed for an immediate return to full power following cold shutdown without xenon, close to end-of-cycle conditions. The volume of coolant discharged during the start-up transient (heating, dilution) must be taken into account.

The full treatment capacity is assumed to be in operation during the start-up transient,.

The storage capacity is required to be sufficient to allow load follow for two days with the effluent treatment system unavailable.

In addition, it must be possible to achieve immediate restart from hot shutdown to full power throughout a cycle (restrictions are acceptable for shutdowns of <8 hrs at FDC [EOC] conditions. In this case, bearing in mind the rapidity of the transient, the treatment system is not considered).

Finally the storage system must also allow an immediate return to cold shutdown from any normal operating condition. The following requirements are defined relating to the storage capacity:

- permanent storage of water reserves to compensate for contraction of the primary fluid

- sufficient permanent storage capacity to accept discharge of primary fluid for boration

To prevent air dissolving in the primary fluid and to prevent the accumulation of flammable gas mixtures in the system free volumes, the tanks are constantly swept with nitrogen taken from the gaseous effluent treatment system (TEG [GWPS]).

The tanks are operated at a pressure slightly lower than atmospheric pressure (0.8 bar) to avoid hydrogen leakages from the system. The storage tanks are equipped with a safety valve for protection against excess pressure.

For storage of effluents, since the maximum boron content is less than 1766 ppm, no specific measures are taken to prevent boron crystallization.

3.2.1.2. Sizing of the treatment system

The treatment capacity must satisfy the primary system demand for fluid resulting from the following:

- daily burn-up of fuel up to FDC [EOC] conditions

- load follow operations for up to 80% of the cycle length

For load follow operation over 0 to 80% of the cycle length, a standard variations of 60 to 100% PN [nominal power] are considered for design purposes.

For load follow programmes that may be stricter and may involve power levels in the range of 25%to 60% PN [nominal power] (operation in abnormal load follow) and/or several cycles per day, restrictions are permitted.

The treatment must be efficient enough to allow production of concentrates (boric acid at 7000 ppm) and distillates (demineralised water with content less than 5 ppm) of the quality required for recycling to the primary system.




The decontamination factor for degassing within the treatment process allows re-use of distillates in the primary system or discharge to the KER [LRMDS] discharge system (in the case of high tritium content).

To prevent air dissolving in the primary fluid and to prevent the accumulation of flammable gas mixtures in the system free volumes, the tanks are constantly purged with nitrogen taken from the gaseous effluent treatment system (TEG [GWPS]) when the system is shutdown.

The treatment system equipment is fitted with a safety valve for protection against excess pressure.

Downstream of the evaporator, the boric acid content is around 7000 ppm (4%). The corresponding crystallization temperature is 15°C and the parts of the system in which boric acid circulates must be kept above this temperature. The ventilation system ensures an ambient temperature above this value.

Since the primary fluid in the RCP [RCS] contains about 1.8 to 4.5 ppm of H2, the gas extracted will be almost entirely composed of hydrogen. To avoid the risk of explosions, the hydrogen is mixed with an inert gas (mainly nitrogen) provided either by the gaseous effluent treatment system or by the nitrogen distribution system, immediately at the outlet of the degassing equipment. Thus the hydrogen content is kept well below detonation and explosion limits.

Additionally the system is operated at pressure of 0.8 bar. As a result of these measures the probability of accumulation of H2 in compartments following a gas leak is insignificant and therefore no other specific measures are taken against the H2 risk.

3.2.2. Purification

The purification system requirements are:

- Removal of the activation and fission products which have not been retained in the RCV [CVCS] purification demineraliser

- Removal of ionic and colloidal impurities to avoid an increase in the concentration of impurities in the treatment plant and to prevent their being transferred into the primary system

The mixed-bed ion exchanger is designed to accommodate the treatment plant supply pump flow rate.

Since resins are sensitive to high temperatures, measures are taken to prevent the temperature of effluents from exceeding 60°C using the RCV [CVCS] high-pressure heat exchangers.

The cartridge filter downstream of the mixed-bed ion exchanger helps trap resin particles coming from demineralisers in order to avoid any return of impurities into the primary system.

3.2.3. Degassing

The effectiveness of degassing depends on the following:

- the decontamination factor of the degassing process

- the purification rate supplied by the RCV [CVCS]




- the rate of release of gaseous fission products

The decontamination factor of the chosen degassing process is higher than 100.

The rate of release of gaseous fission products considered is commensurate with that on 1400 MWe plants.

The effectiveness of the extraction of gas from the primary fluid depends mainly on the rate of purification, which is determined by the ratio between the RCV [CVCS] discharge rate and the mass of primary fluid to be degassed.

For effective degassing, before the primary system is opened, two trains of RCV [CVCS] discharge must be operating in parallel to ensure that the required purification rate is achieved., The degassing system is able to process the maximum RCV [CVCS] discharge flow rate that may occur during start-up of the reactor from cold shutdown to full power.

Operation of the Degassing System ensures that the target activity concentration for the primary system liquid phase are reached before the vessel head is removed. The combined operation of the degassing system and purge system using the RPE [NVDS] enable rapid and effective reduction of the primary system activity.

3.3. DESCRIPTION AND CHARACTERISTICS OF EQUIPMENT

3.3.1. Storage of the coolant

The storage system comprises mainly the following:

- six identical storage tanks

- one borated water line (primary effluents)

- one degassed demineralised water line

Each tank may hold effluents (received via the borated water line) or demineralised water (received via the demineralised water line). The tanks are pressurised cylinders.

The transfer from one tank to another is made through a bypass line between the borated water line and the demineralised water line, using the treatment plant supply pumps.

To prevent accumulation of flammable gas mixtures in the system free volumes, the tanks are constantly swept with nitrogen taken from the gaseous effluent treatment system (TEG [GWPS]).. Additionally the tanks are operated at pressure lower than atmospheric pressure (0.8 bar) to avoid hydrogen leakages from the system.

System inputs

The effluents admitted into the borated water line come from:

- the chemical and volume control system (RCV [CVCS]) via the 3-way valve upstream of the Volume Control Tank

- the RPE [NVDS] vents and drains system (recyclable primary drains)




The primary effluent collected by the nuclear vents and drains system (RPE [NVDS]) that cannot be transferred to the RPE [NVDS] primary bleed tank in the event of excessive discharge of safety valves connected to the RPE [NVDS], is transferred directly to two dedicated tanks out of the six.

The demineralised water admitted into the demineralised water line comes from:

- the coolant treatment system which recycles borated water by separation into boric acid and demineralised water

- the Demineralised Water Distribution System (SDD), for the first filling of tanks

System outputs

The effluent stored in the tanks may be sent to the coolant treatment system for separation into boric acid and demineralised water by connecting each tank to the treatment plant supply pumps via the borated water line.

The demineralised water stored can be directed to the water and boron makeup (REA [RBWMS]) by connecting the tanks to the REA [RBWMS] pumps via the demineralised water line.

3.3.2. Purification

The purification system comprises mainly the following:

- one mixed-bed ion exchanger filled with resins loaded with H+ and OH-

- one cartridge filter (resin trap)

The mixed-bed ion exchanger and the resin trap are placed between the storage tanks and the treatment system.

3.3.3. Treatment

Separation of demineralised water and boric acid as well as degassing are performed by a single 100% train. However, for reasons of availability, the active components that are important for the process (pumps and regulating valves) are have redundancy.

The treatment system comprises the following:

- two evaporator supply pumps (2 x 100%)

- a regenerating effluent/boric acid heat exchanger, a pre-heater, an evaporator, an electrical heater, a boric acid column, two circulation pumps (2 x 100%) and an associated boric acid content measuring system, steam compressors and their sealing tank, sealing pumps and a sealing heat exchanger, a distillate collector, a condensate cooling exchanger, a condenser, a distillate tank, a gas cooler and a distillate cooling heat exchanger

- two boric acid supply pumps (2 x 100%)

- two distillate pumps (2 x 100%)




- one degasser comprising an electric heater, a degassing column, a steam condenser and a gas cooler

- one degassed water extraction pump

There are three possible operating modes:

- “separation and degassing” mode: in this mode the evaporator separtes boric acid (concentrates) and demineralised water (distillates) from the effluent contained in the storage tanks and distillate degassing takes place. The non-recycled distillates is degassed to extract noble gases before they are discharged to the KER [LRMDS] and the recycled distillates are periodically degassed during full-power operation and at the end of outages to remove oxygen before primary system filling. The evaporator and the degasser are operated sequentially

- “separation” mode: this mode which is used when the activity of noble gases in the primary fluid is low, involves recycling of boron and demineralised water from the effluent contained in the storage tanks (the degasser is thus bypassed)

- “degassing only” mode: here degassing of demineralised water from the SDD (Demineralised Water Distribution System) is carried out for water makeup

Degassing in aerated mode (used when the primary system is open or purged) may be carried out by the storage and treatment system without implementation of specific operating measures. This is allowabbe since the nitrogen sweeping and the catalytic recombination of oxygen and hydrogen ensure oxygen and hydrogen levels below the values specified for all operating conditions.

System inputs

The borated water is transferred from the storage tanks via the borated water line to the evaporator supply pump suction.

The demineralised water of the SDD demineralised water distribution system is transferred to the degassing column before transfer to the storage tanks.

System outputs

The boric acid obtained after separation is transferred to the boric acid tanks of the water and boron makeup system (REA [RBWMS]).

The demineralised water may be:

- either transferred to the storage tanks via the demineralised water line for re-use in the primary system

- or transferred to the system for collection, control and discharge of liquid effluents (KER [LRMDS]) if it is not recycled

The dissolved gases from treatment of the evaporator and/or degasser are cooled before being transferred to the gaseous effluent treatment system (TEG [GWPS]).




3.3.4. Degassing

Degassing is not used constantly and is performed by a single 100% train without redundancy..

The coolant degassing system comprises four equipment groups:

- a degassing column with an evaporator and the circulation pump

- a steam condenser and gas cooler

- a degassed water extraction pump

- a vacuum pump

The primary fluid from the RCV [CVCS] discharge is channelled to the top of the degassing column. The fluid in the gaseous section of the degassing column is then swept with nitrogen from the TEG [GWPS] gaseous effluent treatment system or the SGN nitrogen distribution system (this also enables adjustment of the pressure). The degassed fluid is transferred to the RCV [CVCS] discharge line by the extraction pump.

The vacuum pump, which circulates the gases in the system, is normally connected to the gaseous effluent treatment system but may also be connected to the ventilation system. The discharge from this pump is also swept with nitrogen.

To enable the vacuum pump to provide the necessary negative pressure in the degassing column, cooling water at a temperature of 6°C is required.

3.4. OPERATING CONDITIONS

The Primary Effluent Treatment system is designed to be operated during normal operation of the plant.

3.4.1. Storage

During normal operation of the plant, a storage tank is permanently connected to the borated water line and another to the demineralised water line. Thus the header tanks are always available to accommodate effluents (via the borated water line) or provide demineralised water (via the demineralised water line).

During power operation of the plant, the total volume stored must not exceed the volume of five tanks, to enable permanent storage of effluents in an emergency shutdown of the plant; the remaining volume of one tank (which may be distributed between two tanks) prevents mixing of the effluents with demineralised water.

If necessary, it is possible to transfer the entire contents of one tank to another. The transfer from one tank to another is carried out using a bypass line downstream of the treatment plant supply pumps. Extraction of the fluid (effluents or demineralised water) is performed through the boron line. The extracted fluid is circulated by the treatment plant supply pumps and is delivered by the demineralised water line.




3.4.2. Purification

The mixed-bed ion exchanger is filled with resins loaded with H+ and OH-. It is used to remove Lithium, Caesium and other isotopes not removed by the RCV [CVCS] purification demineraliser as well as ionic and colloidal impurities to prevent them from concentrating in the treatment plant and being recycled to the primary system.

A cartridge filter retains resin particles from the demineraliser. These two tasks are necessary to avoid recycling impurities back to the reactor.

3.4.3. Treatment

The fluid to be processed arrives via the borated water line and after purification is transferred to the evaporation plant by the evaporator supply pumps.

The effluent is separated into a solution of boric acid with concentration of 4% H3BO3 and demineralised water by evaporation in the evaporation column: The boric acid remains in the column and the water is removed as steam. The steam is then compressed in the compressors and then condensed in the evaporator (the heat removed is recycled to heat the concentrates), to produce demineralised water. If degassing is required, the distillates are transferred to the upper part of the degasser instead of being returned directly to the storage tanks. The electrical heaters in the lower part of the degasser provide the energy needed to increase and maintain the demineralised water at boiling point. The steam generated is cooled at the top of the degasser by the condenser to separate out incondensable gases. The incondensable gases are cooled before being discharged to the TEG [GWPS].

The degassed and demineralised water is removed by the degassed water extraction pump before being transferred to the tanks. It may also be transferred to the KER [LRMDS].

If no degassing is required, the degassing plant is bypassed and the demineralised water is transferred directly to the storage tanks by the condensate pumps.

The transfer of boric acid to the REA [RBWMS] is performed by one of the two boric acid discharge pumps via the regenerative pre-heater. The boric acid is thus cooled to around 50°C using the supply flow to the evaporation column. The discharge rate is controlled using regulating valves to produce a 4% boric acid solution.

A fraction of the demineralised water is injected upstream of the compressors to saturate the steam downstream of the compressors. Another fraction is transferred to the top of the boric acid column to purify the steam.

At start-up of the evaporator, an electrical heater downstream of the circulation pumps is used to heat the water when no steam is available from the boric acid column.

The incondensable gases are cooled by the gas cooler heat exchanger before being discharged to the TEG [GWPS]. Since the incondensable gas extracted is made up predominantly of hydrogen, permanent sweeping with nitrogen is performed to avoid any risk of explosion.

When the treatment system stops, purging with nitrogen in the boric acid column removes all the hydrogen which may remain after condensation of the steam.

In order to maintain the necessary quantity of water in the tanks, make-up of diminerised water to the SDD may be carried out. The make-up water is heated and transferred to the degasser before being transferred to the storage tanks.




The pre-heated SDD demineralised water may also be transferred directly to the REA [RBWMS] boric acid mixture unit for the preparation of boric acid.

3.4.4. Degassing

3.4.4.1. Reduction of the activity or the hydrogen content in normal operation or before a shutdown

Primary fluid from the RCV [CVCS] is transferred to the top of the degassing column at a temperature of about 50°C and passes in counter-current flow through the rising steam. An operating pressure of 0.125 bar is necessary to bring the fluid to boiling., Most of the gases dissolved in the coolant are released by this method.

The degassed fluid is transferred to the RCV [CVCS] discharge line by the extraction pump. Downstream of the pump, there is a minimum flow rate line connected to the degassing column.

A mixing pump circulates fluid recovered at the bottom of the degassing column through an electrical heater to the top of the column.

The steam released is cooled at the top of the degasser by a condenser. The temperature of condensate is kept close to the boiling point so that gases are not re-dissolved in the water. The gas cooler downstream cools and dries the gases extracted.

The vacuum required in the degassing column is created by the vacuum pump which also extracts gaseous discharges from the column. These gaseous discharges are mixed with nitrogen injected by the TEG [GWPS], and the mixture is then transferred to the TEG [GWPS] for treatment.

Two injection locations from the TEG [GWPS] are provided:

- to the degassing column to control the operating pressure of the column

- to the discharge of the vacuum pump to reduce the hydrogen content

The nitrogen injection ensures the hydrogen content in the piping is kept well below detonation and explosion limits.

The demineralised water in the sealing system of the vacuum pump is separated from the gases entrained into the system in the sealing liquid tank. The water and gas are separated in the inlet nozzle of this tank by a centrifugal droplet separating device. The sealing liquid is then circulated to the vacuum pump via a cooling heat exchanger and a filter.

To reach a service pressure of 0.125 bar in the column, the saturation steam pressure of the sealing liquid must be lower than the suction pressure of the vacuum pump. In order to achieve this, the heat exchanger cools the sealing liquid to a temperature of about 20°C.

3.4.4.2. Extraction of air from the primary fluid after refuelling

Operation of the degassing portion is similar to that described above, except for the connections with the gaseous effluent treatment system.

The gaseous effluents are sent to the DWN [nuclear auxiliary building ventilation] system if their activity is not too high and if the oxygen level in the TEG [GWPS] system must be reduced.




Injection of nitrogen by the SGN [nitrogen distribution system] is required if the nitrogen from the TEG [GWPS] is not available at a sufficiently low oxygen content.

The gas injection points are identical for the two operating modes i.e:

- the top of the degassing column to control the operating pressure

- the discharge of the vacuum pump

3.5. PRELIMINARY SAFETY ANALYSIS

3.5.1. Compliance with regulations

To follow.

3.5.2. Compliance with functional criteria

Accidnets and failures within the TEP [CSTS] have no impact on the safety of the nuclear steam supply system. At most, total and prolonged non-availability of the system might possibly lead to the shutdown of the reactor.

The Primary Effluent Treatment System therefore does not play a direct role in fulfilling the three main safety functions. There are thus no safety-related functional criteria (see 3.0.1 and 3.0.2 within Sub-chapter I.3).

3.5.3. Compliance with design requirements

3.5.3.1. Safety classifications

Compliance of design and manufacture of materials and equipment with requirements derived from classification rules is detailed in Chapter C.2.

3.5.3.2. CDU [SFC] or Redundancy

The Single Failure Criterion does not apply to the TEP [CSTS].

However, the pumps and regulating valves of the treatment system have redundancy for the purposes of availability and are supplied by two different electrical trains. The active equipment in the storage, purification and degassing plant is not redundant.

3.5.3.3. Qualification to operating conditions

Not applicable

3.5.3.4. Instrumentation and control

Compliance of design and manufacture of instrumentation and control with requirements derived from classification rules is detailed in Chapter C.2.

UK-


PAGE : 13 / 21 EPR FUNDAMENTAL SAFETY OVERVIEW


There is no specific provision for the system with regard to internal and external hazards.

3.5.3.6. Hazards

Not applicable

3.5.3.5. Emergency electrical supplies

3.7. FUNCTIONAL FLOW DIAGRAM (SMF)

Since the Primary Effluent Treatment System is used regularly during normal operation and fulfils no active safety function, no periodic testing is performed.

The Primary Effluent Treatment System is designed to allow inspection during operation; preventive maintenance operations must be possible during operation of the plant.

3.6. TESTS, INSPECTIONS AND MAINTENANCE

- The system complete functional flow diagram is provided in I.3.3 FIG 1 below.

SUB-CHAPTER: I.3

SECTION : I.3.3

UK-EPRFUNDAMENTAL SAFETY OVERVIEW

VOLUME 2: DESIGN AND SAFETY FIGURE : 1 PAGE :15 / 21 CHAPTER I: AUXILIARY SYSTEMS

FIG 1: FUNCTIONAL FLOW DIAGRAM OF THE TEP [CSTS] – COOLANT STORAGE AND PURIFICATION SYSTEM (PAGE 1/4)

SUB-CHAPTER: I.3

SECTION : I.3.3


VOLUME 2: DESIGN AND SAFETY FIGURE : 1 PAGE : 17/ 21 CHAPTER I: AUXILIARY SYSTEMS

FUNCTIONAL FLOW DIAGRAM OF THE TEP [CSTS] – COOLANT TREATMENT SYSTEM (PAGE 2/4)

SUB-CHAPTER: I.3

SECTION : I.3.3



FUNCTIONAL FLOW DIAGRAM OF THE TEP [CSTS] – COOLANT TREATMENT SYSTEM (PAGE 3/4)

SUB-CHAPTER: I.3

SECTION : I.3.3



FUNCTIONAL FLOW DIAGRAM OF THE TEP [CSTS] – COOLANT DEGASSING SYSTEM (PAGE 4/4)

3. treatment of primary effluentsepr-reactor.co.uk/ssmod/liblocal/docs/v3/volume 2... · 2007. 7....

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