2017 singapore conference abstract - icmim 2018 · 2018-11-29 · 2017 singapore conference....
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2017 SINGAPORE CONFERENCE
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2017 SINGAPORE CONFERENCE
ABSTRACT
August 21-23, 2017
Shaw Foundation Alumni House
National University of Singapore, Singapore
Sponsored and Published by
Indexed by
www.cbees.org
http://www.cbees.org/
2017 SINGAPORE CONFERENCE
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Table of Contents
2017 Singapore Conference Introductions 8
Presentation Instructions 10
Keynote Speaker & Plenary Speaker Introductions 11
Brief Schedule for Conference 30
Detailed Schedule for Conference 32
Session 1
P0002: Preparation and Characterization of Chitosan/GPTMS Hydrogels by a Sol-Gel
Method
Mao-Chi Weng, Tsung-Sheng Chen and Shu-Ling Huang
34
P0004: Total Phenolic Content and Antioxidant Activity of Ginger Torch (Etlingera
elatior (Jack) R.M.Sm)
Tresna Lestari, Ruswanto, Tita Nofianti, Annisa Lestari, Siti Munawaroh, Hilda A
Badriah
35
P0005: Antitriglyceride Activity Test of Ethanol Extract Tamarind Leaf (Tamarindus
indica L.) against Strains Wistar Male Rats
Tita Nofianti
36
P0007: Recovery of Indium from Mobile Phone Touch Screen Using Adapted
Acidithiobacillus Ferrooxidans
Omid Rezaei, Seyyed Mohammad Mousavi and Fatemeh Pourhossein
37
P0008: An Amperometric Biosensor Based on Fumarate Reductase for Enzymatic
Properties and Electrical Behavior
Yemin Yu, Yonghong Hu, Tao Li, Wenge Yang, Yuhao zhang and Renlun Deng
38
P0009: Experimental Investigation of Injection Pressure Effect on the Natural Gas
Storage in Aquifers
E. Kazemi Tooseh, A. Jafari and A. Teymouri
39
P0011: Encapsulation, Properties, and Thermal Study of Red Biocolorant from Selected
Plants Obtained through Physical Extraction
Renny Indrawati, Diah Mustika Lukitasari, Yuyun Yuniati, Heriyanto and
Leenawaty Limantara
40
P1001: Molecular Aggregate Containing both Channels and Cages via Arrays of
Metallacyclodimers and Its Molecular Recognition via Photoluminescence
Jeong Jun Lee, Daseul Lee and Ok-Sang Jung
41
P1002: Solvent Effect of Crystal Structures of Cadmium(II) Chloride Containing
Di(pyridin-4-yl)silane
Minjoo Ryu, Daye Choi and Ok-Sang Jung
42
P1003: Sandwich-shaped Zn(II) Complex Containing Tridentate Silane Ligand:
Fluorescence Quenching Effect
Sangseok Lee, Seo Young Hwang and Ok-Sang Jung
43
2017 SINGAPORE CONFERENCE
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P3003: Microencapsulation of Kabocha Pumpkin Carotenoids
Naomi M. Mulyadi, Tri D. Widyaningsih, Novita Wijayanti, Renny Indrawati,
Heriyanto and Leenawaty Limantara
44
P0014: Synthesis, Characterization and Anticancer Activity of
1-Benzoyl-3-methylthiourea Derivatives
Ruswantoa, Amir M. Miftah , Daryono H. Tjahjono and Siswandonoc
45
P3004: Electro-Catalytic Behaviour of Pan-Ec-Pc-Tpai-I2 Gel Type Polymer
Electrolytes for Dye-Sensitized Solar Cell Application
Faisal I. Chowdhury, M. U. Khandaker and A. K. Arof
46
Session 2
J0002: A Structural Mechanics Approach for the Phonon Dispersion Analysis of
Grapheme
Xiuhui Hou and Zichen Deng
47
J0005: Investigation of the Intermediate Phase of NiFe/Bi2Se3 Ferromagnet/
Topological-insulator Heterostructure
Yu-Han Huang, Shu-Jui Chang , Yu-Jun Chen, Jung-Chun-Andrew Huang and
Yuan-Chieh Tseng
49
J0007: Epitaxial GdFe0.8Ni0.2O3 Multiferroic Thin Films Grown by Radio Frequency
Sputtering System
Ming-Han Chung, Shu-Jui Chang, Yen-Ting Liu, Hsin-Yi Lee and Yuan-Chieh Tseng
50
J0009: Multiplexing of Functionalized Carbon Nanotubes Sensors for Selective Water
Quality Sensing
Yaowu Zhang, Alfredo Gutierrez, Loic Loisel, Sasikumar Ramachandran,
Mallesham Godumala, Erick Merliot, Gal Zucchi and Brengre Lebental
51
J0026: Analyzing of a 2-D Magnet Array with Hexagon Magnet Based on
Superposition
Guangdou Liu, Xin Zhang, Xingping Xu and Xiaoyi Liu
52
J0031: Constitutive Modelling of Elastomer/Graphene Platelet Nanocomposites
Amir A. Abdelsalam, Sherif Araby, M.A. Hassan and A. A. El-Moneim
53
J0039: A Novel Technique for Producing Conductive Polyurethane Nanofibrous
Membrane for Flexible Electronics Applications
Ahmed Shaker Abdel Baset Ali, Ahmed Hassanin, Nageh Shaalan, Mohsen Hassan
and Ahmed Abd El-Moneim
54
J0059: An Improved Edge Detection Approach and its Application in Defect Detection
Vilas Haridas Gaidhane, Navdeep, Asha Rani and Vijander Singh
55
J2003: Spectroscopy Investigation and Energy Transfer by Lanthanide Activation in
Nanosized Bi2SiO5 Phosphor
Pushpa Kumari and Y. Dwivedi
56
J2005: Green Emitting Y4MoO9: Er3+
/Yb3+
Upconversion Phosphor for Temperature
Sensor and Optical Heater
Shriya Sinha and Kaushal Kumar
57
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Session 3
J0015: Evaluation of the Residual Stresses in 95wt% Al2O3-5wt% SiC Wear Protection
Coating using X-Ray Diffraction Technique
Adel K. Mahmoud, Zaid S. Hamoudi and Samah Rasheed
58
J0016: Sustainability Assessment of Shielded Metal Arc Welding (SMAW) Process
Ibrahim Alkahla and Salman Pervaiz
59
J0017: Study on Service Performance of 880 MPa-grade and 980 MPa-grade Rail Steels
Min Zhu, Guang Xu, Jianhua Zhou, Ruimin Wang and Xiaolong Gan
60
J0019: Influence of Two Activation Methods in the Chemical Composition and Oxide
Layer of a Novel TiHfNb-alloy Developed for Biomedical Applications
Virginia N. Paredes M., Emiliano Salvagni and Jos Mara Manero
61
J2008: Computer Aided System for Parametric Design of Combination Die
Vishal G Naranj, H M A Hussein and S. Kumar
62
J2012: Study of Wear Performance of Deep Drawing Tooling
Vishal G Naranje, Ram Karthikeyan and Vipin Nair
63
J2009: Industrial Wastewater Treatment Using Higher Aquatic Vegetation in the Former
Mining Company of the Far Eastern Federal District
L. T. Krupskaya, V. P. Zvereva, K. E. Gula, L. P. Gul, D. A. Golubev and M. Yu.
Filatova
64
J2011: Prediction of Multi Performance Characteristics of Wire EDM Process Using
Grey ANFIS
Somasundaram Kumanan and Anish Nair
65
J0032: Investigation on Burrs in Micro Milling of Stainless Steel 310S
YUAN Meixia, LIU Shaonan, Xue Hongxi, Tang Boyan and Zhao Linlin
66
J0052: Comparison of Tool Life and Surface Roughness with MQL, Flood Cooling, and
Dry Cutting Conditions with P20 and D2 Steel
S.W.M.A.I. Senevirathne and H.K.G. Punchihewa
67
Session 4
J0003: Flame Retardancy Synergism of Zinc Borate and an Organophosphorus
Compound in Polyamide and its Composite
Osman Polat and Cevdet Kaynak
68
J0018: Effect of Commercial SiO2 and SiO2 from Rice Husk Ash Loading on
Biodegradation of Poly (Lactic Acid) and Crosslinked Poly (Lactic Acid)
Chana Prapruddivongs, Manlida Apichartsitporn and Thapanee Wongpreedee
70
J0021: Developing Silicone Rubber Nanocomposites with Much Improved Tensile &
Tear Properties
Suzhu Yu, Cheng Ning Wong and Li Zan Chan
71
J0033: Investigation of the Fatigue Crack Propagation Behaviour in the Al alloy/ Hybrid
MMC Bi-layer Material
AKM Asif Iqbal and Yoshio Arai
72
J0036: Thermal Properties of Biopolyol from Oil Palm Fruit Fibre (OPFF) Using 73
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Solvolysis Liquefaction Technique
Shaharuddin Kormin, Anika Zafiah Mohd Rus and Mohd Syafiq Mohd Azahari
J0037: Acoustic Properties of Polymer Foam Composites Blended with Different
Percentage Loadings of Natural Fiber
Muhammad Shafiq Mohd Azahari, Anika Zafiah Mohd Rus, Shaharuddin Kormin
and Muhammad Taufiq Zaliran
74
J0055: Wear Properties of 10 vol.% Silicon Carbide Particulate-Reinforced Aluminum
Composite Fabricated by Powder Injection Molding
Tapany Patcharawit, Arada Ngeekoh and Nutthita Chuankrerkkul
75
J0057: Enhancement of Mechanical Properties of Porous Aluminum By Silica sand
Particles
Sunisa Khamsuk, A Joosawat, N Panomtang and K Wongtimnoi
76
J3009: Preliminary Investigation of Fabrication Composite Structures by Using Shape
Memory Alloys
Wojciech Klein and O Dudek
77
Session 5
J0014: Design and Implementation of a Cyber-Physical Production System for
Personalized Skin Care: A Microservices Approach
Michael Christian Oberle
78
J0034: Environmental Stress Crack Resistance of Virgin Geomembranes, Installed and
Exposed geomembranes by Considering Depletion Lifetime through Index Tests
Han-Yong Jeon
79
J0035: Thermal Deformation Analysis of Spliced High Energy Laser Emission Window
Xutang Liu, Diansheng Cao and Guangdou Liu
80
J0054: Energy Optimization for Efficient Transport and Processing of Coal Fly Ash
Vighnesh Prasad, Prachi Thareja and Surya Pratap Mehrotra
81
J0058: Social Aspects of Automation: Some Critical Insights
Ibrahim Nouzil, Ali Raza and Salman Pervaiz
82
J1002: Nanosheet-Structured Boron Carbon Nitride Spheres as Stable Electrocatalyst
Support for Oxygen Reduction Reaction
Fei Liu, Yaqi Ren, and Xixi Ji
83
J3004: Development of Low Temperature Spatial Atmospheric Atomic Layer
Deposition Head for Al2O3 Thin Film
Hyunbeom Kim, Mohammad Mutee ur Rehman, Jae-Wook Lee and Kyung-Hyun
Choi
84
J3007: Buildup Factor and Mechanical Properties of High-Density Cement Mixed with
Crumb Rubber and Prompt Gamma Ray Study
Pawitra Aim-O, Doonyapong Wongsawaeng, Somchai Tancharakorn and Methee
Sophon
85
J3013: The Improved Corrosion Resistance of a Zn-Al Layered Double Hydroxides
Films with Doping of Graphene Oxide
Luchun Yan, Meng Zhou, Xiaolu Pang and Kewei Gao
86
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J0066: Application of Porous Medium for Efficiency Improvement of a Concentrated
Solar Air Heating System
Boonrit Prasartkaew
87
Poster Session
J0004: A New Three-dimensional Manufacturing Service Composition Method under
Various Structures Using Improved Flower Pollination Algorithm
Wenyu Zhang, Yushu Yang and Shuai Zhang
88
J0010: Effect of Solvent Vapor Annealing on TiOPc Ultrathin Films and the
Application on Hybrid Solar Cells
Rongbin Ye, Koji Ohta and Mamoru Baba
89
J0011: Development of Cost Effective and Low Temperature Spatial Atmospheric
Atomic Layer Deposition System for Al2O3 Thin Film
Jae-Wook Lee, Woo-Seok Lee, Hyen-Bum Kim, Jong-Hwan Lim and Kyung-Hyun
Choi
90
J0040: Osteogenic Differentiation of Human Turbinate Mesenchymal Stem Cells in an
Injectable Hydrogel
Malgeum Kim, Seung Hun Park, Jihoon Park and Moon Suk Kim
91
J0041: Injectable Dexamethasone-loaded Microsphere/Hydrogel Combination System
for Sustained Drug Release
Jiyeon Heo, Seunghun Park, Jihoon Park and Moon Suk Kim
92
J0042: Extrusin/Injection Processing and the Mechanical and Thermal Properties of
Bamboo/Kenaf/Recycled PP Hybrid Composites
Changhun Ha, Jinsil Cheon and Donghwan Cho
93
J0043: Effect of Acrylonitrile-Butadiene-Styrene Composition Ratio on the Properties
of Carbon Fiber/ABS Composites Prepared Using LFT Pellets
Hee Sook Lee and Donghwan Cho
94
J0044: Preparation of Crosslinked Polyester Copolymers with Ionic Functional Groups
by Electrostatic Interaction
Hye Yun Lee, Ji Hoon Park, Hai Bang Lee and Moon Suk Kim
95
J0045: Effects of MWCNT on the Frictional and Mechanical Properties of Single-Plied
Carbon Fabric/Phenolic Composites
Jinsil Cheon, Dongkyu Lee, Heesook Lee, Changhun Ha, Jae Kyu Cho and
Donghwan Cho
96
J0046: Characterization of Chopped Carbon Fiber/ABS Composites Containing
MWCNT Prepared by Extrusion and Injection Molding Processes
Dongkyu Lee and Donghwan Cho
97
J2004: Influence of Cryogenic Cooling Rate on Mechanical Properties of Tool Steels
Gedalya Mazor, Itzhak Ladizhensky and Alex Shapiro
98
J3006: Segmented Highly Branched Polymer-peptide Conjugates as 19
F MRI Agent for
Cancer Specific Targeting
Laila Alhaidari and Seb Spain
99
J3011: The Analysis of Anti-fouling Properties According to the Annealing Temperature 100
2017 SINGAPORE CONFERENCE
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Bowen Shan, Byeong Chul Lee, Jong Kug Park, Hyunil Kang and Wonseok Choi
J3012: Properties of Carbon Nanowalls According to the Thin Film Deposition
Hyunil Kang, Jong Kug Park, Seok Hun Kwon, Hyun-Suk Hwang and Wonseok Choi
101
J3014: Artificial Light Harvesting System Carried by Micelles
Samira Hussein and Lance Twyman
102
P0008: An Amperometric Biosensor Based on Fumarate Reductase for Enzymatic
Properties and Electrical Behavior
Yemin Yu, Yonghong Hu, Tao Li, Wenge Yang, Yuhao zhang and Renlun Deng
103
One Day Visit & Tour 104
Conference Venue 106
Note 108
Feedback Information 115
2017 SINGAPORE CONFERENCE
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2017 Singapore Conference Introductions Welcome to CMS-CBEES 2017 conference in Singapore. The conference is held annually with high quality. The objective of the Singapore conference is to provide a platform for researchers, engineers, academicians as well as industrial professionals from all over the world to present their research results and development activities in Materials and Intelligent Manufacturing & Advances in Biology and Chemistry.
2017 International Conference on Materials and Intelligent Manufacturing (ICMIM 2017)
Papers will be published in:
IOP Conference Series: Materials Science and Engineering (ISSN:
1757-899X), which is indexed by EI Compendex, Scopus, Thomson Reuters
(WoS), Inspec, et al.
Conference website and email: http://www.icmim.org/; [email protected]
2017 4th International Conference on Advances in Biology and Chemistry (ICABC 2017)
Papers will be published in one of the following journals:
International Journal of Bioscience, Biochemistry and Bioinformatics (IJBBB,
ISSN: 2010-3638), which will be indexed by Electronic Journals Library,
Chemical Abstracts Services (CAS), Engineering & Technology Digital Library,
Google Scholar, and ProQuest.
International Journal of Chemical Engineering and Applications (IJCEA,
ISSN:2010-0221), which will be indexed by Chemical Abstracts Services
(CAS), Ulrich's Periodicals Directory, CABI, DOAJ, Electronic Journals
Library, Google Scholar, Engineering & Technology Digital Library, ProQuest
and Crossref.
Conference website and email: http://www.icabc.org/; [email protected]
2017 SINGAPORE CONFERENCE
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CMS Mission
The mission of HKCBEES Chemistry and Materials Society (CMS) is to meet the engineers and the scholars in the Chemistry and Materials discipline. CMS offers a platform for them to communicate and exchange idea. HKCBEES Chemistry and Materials Society hold annually scheduled conferences and workshops on the Chemistry and Materials related topics, it serves as a forum for idea exchange, networking, information sharing and problem solving for the Chemistry and Materials community. HKCBEES Chemistry and Materials Society play an important role in the academic community.
About HKCBEES
The Hong Kong Chemical, Biological & Environmental Engineering Society (HKCBEES) was founded in 2007. It is an independent and scientific research and development organization. The Service can be traced back to the first work in 1999.
HKCBEES plays an influential role in promoting developments in Chemical, Biological & Environmental Theory and Applications in a wide range of ways. The mission of HKCBEES is to foster and conduct collaborative interdisciplinary research in state-of-the-art methodologies and technologies within its areas of expertise.
Good news! To join in HKCBEES member is free now. Please check the information on the website: http://www.cbees.org/list-33-1.html if you are interested in. Any question regarding to membership, please feel free to contact [email protected].
mailto:[email protected]
2017 SINGAPORE CONFERENCE
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Presentation Instructions
Instructions for Oral Presentations
Devices Provided by the Conference Organizer:
Laptop Computer (MS Windows Operating System with MS PowerPoint and Adobe Acrobat
Reader)
Digital Projectors and Screen
Laser Sticks
Materials Provided by the Presenters:
PowerPoint or PDF Files (Files should be copied to the Conference laptop at the beginning of
each Session.)
Duration of each Presentation (Tentatively):
Regular Oral Presentation: about 12 Minutes of Presentation and 3 Minutes of Question and
Answer
Keynote Speech: about 30 Minutes of Presentation and 5 Minutes of Question and Answer
Plenary Speech: about 20 Minutes of Presentation and 5 Minutes of Question and Answer
Invited Speech: about 15 Minutes of Presentation and 5 Minutes of Question and Answer
We would appreciate if all presenters can adhere strictly to this time limit.
Instructions for Poster Presentations
Materials Provided by the Conference Organizer:
The place to put poster
Materials Provided by the Presenters:
Home-made Posters
Maximum poster size is A1
Load Capacity: Holds up to 0.5 kg
Best Presentation Award One Best Oral Presentation will be selected from each presentation session, and the
Certificate for Best Oral Presentation will be awarded at the end of each session on August 21
and 22, 2017.
Dress Code Please wear formal clothes or national representative of clothing.
2017 SINGAPORE CONFERENCE
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Keynote Speaker & Plenary Speaker
Introductions
Keynote Speaker I
Prof. Shen-Ming Chen
National Taipei University of Technology, Taiwan
Dr. Shen-Ming Chen (h-index > 60) received his PhD degrees in chemistry from National Taiwan
University, Taipei, Taiwan. He was a visiting postdoctoral fellow with the Institute of Inorganic Chemistry,
Friedrich-Alexander University Erlangen-Nuremberg, Germany in 1997. He joined Department of
Chemical Engineering, National Taipei Institute of Technology, Taipei, Taiwan in 1985. He had been an
associate professor of Department of Chemical Engineering, National Taipei Institute of Technology, Taipei,
Taiwan from 1991 to 1997. Since August 1997, he has been a full professor of Department of Chemical
Engineering and Biotechnology, National Taipei University of Technology. He has been the Dean (Curator)
of library, National Taipei University of Technology, Taiwan from 2000 to 2006 and the Director of
Extracurricular Activity, office of student affairs, National Taipei University of Technology, Taiwan from
1995 to 2000.
Prof. Shen-Ming Chen has published over 500 research and review papers in internationalSCI journals.
Some of their papers have been selected as the most cited papers in theJournal of Electroanalytical
Chemistry and Biosensor & Bioelectronics. He received threetimes Distinguish Professor awards. He also
received three times Outstanding Research Award from National Taipei University of Technology, Taiwan.
He have edited or attended two books for NOVA publications titled Nanostructured Materials for
Electrochemical Biosensors and Biosensors: Properties, Materials and Applications and contributed four
book chapters.
His research interest includes nanocomposites, bionanomaterials, bionanotechnology, electrochemical
biosensor, biosensors, bioelectrochemistry,, chemical materials, electroanalytical Chemistry,
electrocatalysis and electroanalysis, photoelectrochemistry, metalloproteins, metalloporphyrins,
nanotechnology, spectroscopic techniques, scanning probe techniques, quartz crystal microbalance,
materials research, fuel cells, solar cell and photovoltaic cells.
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Topic: Electrochemistry, Biosensors and Nanotechnology: Advances and Relevance
Shen-Ming Chen
Department of Chemical Engineering and Biotechnology, National Taipei University of
Technology, Taiwan
Abstract- We investigated the direct electrochemistry of glucose oxidase (GOx) and
cholesterol oxidase (ChOx) at multiwalled carbon nanotubes (MWCNTs) modified electrode.
GOx was covalently immobilized onto MWCNT modified GCE through the well known
glutaraldehyde (GAD) chemistry displayed. A cholesterol biosensor of ChOx/MWCNT
containing MWCNTs and ChOx has been synthesized on electrode. The electrocatalytic
responses of ChOx/MWCNTs film were investigated with various analytes by cyclic
voltammetry (CVs) and amperometry (AMP). The ChOx/MWCNTs/GCE has electrocatalytic
active response to cholesterol. We also immobilized poly(neutral red) (PNR) and flavin
adenine dinucleotide (FAD) hybrid film (PNR/FAD) by electrochemical methods. The
PNR/FAD hybrid film can be easily prepared on electrode surface involving
electropolymerization of neutral red (NR) monomers and the electrostatic interaction between
the positively charged PNR and the negatively charged FAD. Particularly, the PNR/FAD
hybrid film has potential to replace some hemoproteins to be a cathode of biofuel cells and
provide the biosensing system for glucose and ethanol. Bimetallic hybrid film, PtAu was
synthesized by the electrochemical deposition of Pt and Au nanoparticles with L-Cysteine on
glassy carbon electrode. The Au and Pt particle size range was 50-80 nm and 200-300 nm
respectively. The electrochemical studies of the film has been studied for the determination of
dopamine, ascorbic acid and uric acid both individually and simultaneous determination in a
mixture of these species. The PtAu hybrid film modified electrode showed good sensitivity and
stability. The MWCNTs/GOx film modified GCE effectively exhibits the electro oxidation
signals for the detection of glucose. MWCNTs provided large surface area for GOx base on
modified electrode. The cyclic voltammetry (CVs) has been used for the measurement of
electroanalytical properties of analytes by means of modified electrodes. The power densities
of glucose biofuel cell based on the MWCNTs/GOx electrode was determined. Reduction of
dioxygen catalyzed by Laccase was studied at platinum nanoparticles (PtNPs) modified
electrodes. PtNPs with Laccase are directly fabricated on electrodes. The PtNPs/Laccase
modified GCE effectively exhibits the electroreduction signals for the detection of oxygen.
PtNPs provided large surface area for Laccase base on modified electrode. The PtNPs present
on the electrode provided electrical connectivity between the electrode and the enzyme active
sites. The power densities of biofuel cell was determined. The biofuel cell showed highly
stable output in long-term performance.
Recently, many investigations have been carried out for the fabrication of chemically
modified electrodes on the use of micro and nanocomposites for different applications.
Possibly nanomaterials modified electrodes are emerging as a real candidate for verity of
potential applications due to its high surface area and biocompatibility along with better
antifouling ability. The emerging applications of modified electrodes are in the fabrication of
devices for biosensors and environmental sensors. Since, the environmental pollution has
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become a worldwide problem and the wastewater from the industries contains many organic
pollutants and heavy metal ions which cause serious effect on the environment. Hence, we
have prepared different chemically modified electrodes on the use of micro and nanomaterials
for electrochemical sensing of biomolecules and environmental pollutants. For instance, the
-cyclodextrin entrapped graphite modified screen printed carbon electrode (SPCE) can
selectively detect the dopamine (DA) with the low limit of detection (LOD) of 11 nM.1 The
biomass-derived activated carbons, fullerene-C60/Pd nanoparticles and fullerene C60
wrapped graphene oxide composite modified electrodes show the LOD of 4.5 5.6 and 8 nM,
respectively for DA.24 The aforementioned modified electrodes can detect the DA in the
real samples such as snail hemolymph, human blood serum, rat brain solution and commercial
DA injection samples.
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Keynote Speaker II
Assoc. Prof. GAUTAM SETHI
National University of Singapore, Singapore
After completion of his postdoctoral training at University of Texas MD Anderson Cancer
Center, Dr. Gautam Sethi joined Department of Pharmacology, Yong Loo Lin School of
Medicine, National University of Singapore in 2008 as an Assistant Professor and was
promoted to Associate Professor in 2015. The focus of his research over the past few years
has been to elucidate the mechanism (s) of activation of oncogenic transcription factors such
as NF-kB/STAT3 by carcinogens and inflammatory agents and the identification of novel
inhibitors of these proteins for prevention of and therapy for cancer. The findings of his
research work have so far resulted in more than two hundred scientific publications in high
impact factor peer reviewed journals (with h index = 67) and several international awards. He
currently serves as an Academic Editor for PLOS, editorial board member of Scientific
Reports, Pharmacological Research, Frontiers in Pharmacology, Frontiers in Oncology, and
ad-hoc reviewer for several prestigious international journals.
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Topic: Potential Therapeutic Application of Tocotreinols for Cancer Treatment
Gautam Sethi
National University of Singapore, Singapore
Abstract- Gamma-tocotrienol, a member of Vitamin E superfamily has attracted great
attention of late for its anti-proliferative and anti-carcinogenic potential against different
cancers. For example, our group has recently reported that anti-proliferative and
chemosensitizing effects of g-tocotrienol are associated with its ability to suppress activation
of signal transducers and activator of transcription 3 (STAT3), a pro-inflammatory
transcription factor that plays a pivotal role in the survival, proliferation, angiogenesis and
chemoresistance of hepatocellular carcinoma. However, the potential of gamma-tocotrienol to
overcome chemoresistance in gastric cancer, which is one of the deadliest cancers in
Asia-pacific region, has never been explored before. Hence, we investigated the efficacy of
gamma-tocotrienol in combination with capecitabine to modulate tumor growth and survival
in xenograft mouse model. Gamma-tocotrienol also inhibited expression of various oncogenic
proteins, induced PARP cleavage and inhibited NF-B activation in gastric cancer cells. In
vivo studies using xenograft model of human gastric cancer demonstrated that
gamma-tocotrienol alone suppressed tumor growth and this effect was further potentiated in
conjunction with capecitabine. As compared to the vehicle control, gamma-tocotrienol further
suppressed the NF-B activation and expression of cyclin D1, COX-2, ICAM-1, MMP-9 and
survivin in tumor tissues obtained from treatment groups. Additionally we noted, that gamma
tocotrienol can function as a potent inhibitor of angigogenesis in both HUVEC and HCC cells.
Overall our results suggest for the first time that gamma-tocotrienol can potentiate the effects
of chemotherapy through modulation of multiple biomarkers of proliferation, and
angiogenesis in diverse cancers.
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Keynote Speaker III
Prof. Kien Wen Sun
National Chiao Tung University, Hsinchu, Taiwan
Dr. Kien Wen Sun was born in Taipei, Taiwan. He holds a PhD from the Department of
Electrical Engineering at Princeton University in New Jersey, United States. From 1995-2000,
he was on the faculty of the Electronic Engineering at Feng Chia University, Taiwan. He
jointed the faculty of Department of Physics as a professor at National Dong Hwa University,
Hualien, Taiwan, from 2000-2005. Since year 2005, he became a professor of Department of
Applied Chemistry at National Chiao Tung University, Hsinchu, Taiwan. During his
sabbatical in 2012, he was a visiting professor at Department of Electrical and Computer
Engineering of University of Waterloo, Canada. Dr. Sun was appointed as the Department
Chair of Applied Chemistry at NCTU from 2012-2014. He is also currently a Joint
Appointment Professor at Department of Elecronics Engineering and the Director of the
Center of Nano Science and Technology at National Chiao Tung University. His research
interests include femtosecond laser and laser spectroscopy in III-V compound semiconductors,
spintronics, nanoimprint, nanolithography, nanoelectronics, nanodiamonds, thermal transport
in nanostructures, organic/inorganic solar cells, and chemical sensor technology. He has
published more than 100 journal papers in above research fields. He was awarded for the Prof.
Rudolph A. Marcus Award 2016 by Publishing Division of Cognizure and LOGNOR. He has
served as reviewers and editorial board members for numerous high-impact international
journals. He is now a senior editor of Science Advances Today and a Fellow Member for
Hong Kong Chemical, Biological & Environmental Engineering Society (HKCBEES).
2017 SINGAPORE CONFERENCE
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Topic: A Review on Biological and Chemical Applications of Diamond Nanomaterials
Kien Wen Sun
National Chiao Tung University, Hsinchu, Taiwan
Abstract- Among the carbon based nanomaterials, diamond is known to be an outstanding
material in terms of superior hardness and Youngs modulus, biocompatibility, optical and
chemical properties. The nitrogen vacancy (NV-) color centers of nanodiamond lead the
specific role in recent bio-imaging and biosensor studies. On the other hand, diamond
nanoparticles can also act as an important carrier in many delivery systems. Furthermore, due
to their outstanding opto-electronic and mechanical properties diamond nanoparticles (DNDs)
have also grown its -state-of-the-art- platform in many emerging applications such as catalysis,
energy transfer, semiconductors, solar energy conversion, chromatography and AFM Tips.
This presentation outlined the important potential applications of the diamond nanomaterials.
2017 SINGAPORE CONFERENCE
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Keynote Speaker IV
Prof. Jun Ding
National University of Singapore, Singapore
Dr. Jun DING obtained his Diplom Physics from University of Wuppertal in 1986, and PhD
degree from Ruhr University Bochum, Germany in 1990. He has been working on magnetic
and nanostructured materials for more than 25 years. He is currently working as Professor at
Department of Materials Science & Engineering, National University of Singapore. He has
published over 350 journal papers with a total citation > 9000 and H-Index = 52.
Research Interests
Additive Manufacturing (3D Printing): Recently, Prof Ding Juns research has been
concentrated on additive manufacturing. His research has been focused on the development of
starting mateirals for fabrication of multi-functioanal devices/structures of metal, ceramics,
polymer and composite.
Nanomagnetics/spintronics and their applications: Prof Ding Jun has been working in the area
of nanomagnetics and spintronics for many years. Recently, he has paid a particular attention
on these materials and devices in different applications, including spintronic structures in
information storage, nanoparticles in biomedical and environmental applications, magnetic
sensors, magnetic energy harvesters and metamaterials. 3D printing will be used in the device
fabrication.
2017 SINGAPORE CONFERENCE
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Topic: Functional Structures by Additive Manufacturing and Their Applications
Jun DING
Department of Materials Science & Engineering
National University of Singapore, Singapore
Abstract- Recently, our research work has been extended into the area of additive
manufacturing (3D printing) which fabricates structures through a unique approach
layer-by-layer formation. Additive manufacturing has attracted a significant attention
because of its great potential in engineering applications, particularly for fabrication of
components with complex geometries and interior structures. 316L stainless steel microlatties
and micromeshes have been studied as electrode for water splitting. Compared to metal
forms, these cellular structures made by selective laser melting have shown excellent
mechanical and electrochemical properties. We have investigated to use micorlattices and
micromeshes in removal of heavy metal ions. 316L stainless steel meshes have shown great
potential for electrochemical winning of heavy metal ions, particularly after surface coating of
graphene. We have developed a novel magnetic filter based on micormeshes of
softmagnetic ferrite. Together with quasi-superparamagnetic Fe3O4 nanoparticles, the
system has been demonstrated as an effective separator for heavy metal ions from
contaminated water under a very low magnetic field (well below 1000 Oe). In addition,
magnetic filters and magnetic particles can be easily recovered and regenerated for re-use, so
that second pollution can be avoided.
2017 SINGAPORE CONFERENCE
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Keynote Speaker V
Prof. Yoshihiro Sugi
Gifu University, Japan
Dr. Yoshihiro Sugi was born in Japan and obtained both his Master in Engineering and PhD
from Tohoku University, Japan. He was in National Institute of Material Chemical Research
from 1971 to 1994 and worked as a Professor of Chemistry in the Engineering Faculty at Gifu
University from 1994 to 2009. He joined National Chemical Laboratory, Japan, where he
worked till 1995. Professor Sugi joined Prof. Ajayan Vinus research group as a Visiting
Professor at AIBN (Australian Institute for Bioengineering and Nanotechnology).
Research Interests
Synthesis, characterisation and application of micro- and meso-porous materials as catalyst
for organic reactions.
2017 SINGAPORE CONFERENCE
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Topic: Zeolite as Molecular Reactor. The Isopropylation of Biphenyl over H-Mordenite
Yoshihiro Sugi, Stalin Joseph, Kavitha Ramadass, and Ajayan Vinu
Gifu University, Japan
Abstract- These instructions give you guidelines for preparing pa H-Mordenite (MOR), with
dealumination, only worked as molecular reactor for the selective formation of the least bulky
4,4-diisopropylbiphenyl (4,4-DIPB) in the isopropylation of biphenyl (BP) among
12-membered zeolites. 4,4-DIPB formed selectively through 4-isopropylbiphenyl (4-IPBP),
the least bulky among IPBP isomers, due to the differentiation from the other bulky isomers
by the MOR channels. The formation of 4,4-DIPB occurred in the channels: the channels
selectively allow the transition state to 4,4-DIPB from 4-IPBP due to their steric restriction.
The decreases of the selectivities for 4,4-DIPB occurred at high temperatures and/or by using
large amounts of the catalysts: these are due to the isomerization of 4,4-DIPB, once formed
in the channels, to 3,4- and 3,3-DIPB at the external acid sites. Y-zeolitre (FAU) and
Zeolite- (BEA) have the wide channels to accommodate the bulkier isomers, which allow the
transition states to bulkier isomers with 2- and 3-isopropyl moieties: they worked under
kinetic and/or thermodynamic controls.
2017 SINGAPORE CONFERENCE
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Keynote Speaker VI
Prof. Lei Jiang
Chinese Academy of Sciences, China
Dr. Lei Jiang received his B.S. degree in solid state physics (1987), and M.S. degree in physical chemistry
(1990) from Jilin University in China. From 1992 to 1994, he studied in the University of Tokyo in Japan
as a China-Japan joint course Ph.D. student and received his Ph.D. degree from Jilin University of China
with Prof. Tiejin Li. Then, he worked as a postdoctoral fellow in Prof. Akira Fujishimas group in the
University of Tokyo. In 1996, he worked as researcher in Kanagawa Academy of Sciences and Technology,
Prof. Hashimotos project. In 1999, he joined Institute of Chemistry, Chinese Academy of Sciences (CAS).
In 2015, he moved to the Technoligical Institute of Physics and Chemistry, CAS. Since 2008, he also
served as the dean of School of Chemistry and Environment in Beihang University. He was elected as
members of the Chinese Academy of Sciences and The World Academy of Sciences in 2009 and 2012. In
2016, he also elected as a foreign member of the US National Academy of Engineering.
Research Interests
1. Structural Effect on Wettabilitys of Natural Materials
To reveal the relationship between the special wettability and the unique micro- or nanostructures of
organism surfaces in nature (lotus leaves, rice leaves, water-striders legs, cicada wings, butterfly wings, et
al.).
2. Design and Fabrication of Bio-Inspired Surfaces with Special Wettability To construct hierarchical
micro- and nanostructures through physical or chemical method, and adjust the surface free energy, reach
the special wettability (superhydrophilicity, superoleophilicity, superhydrophobicity, or superoleophobicity).
3. Bio-Inspired, Smart Interfacial Materials
To focus on the design and fabrication of smart interfacial materials (thermo-, photo-, electro-, pH-,
solvent-, or stress-responsive, et al). For example, under certain circumstances, a surface wettability can
switch between superhydrophilicity and superhydrophobicity, just like in Chinese ancient Taiji philosophy
that Yin and Yang, the two opposing fundamental properties of nature, are switchable.
4. Ion Channels
To construct responsive nanopore channels and nanocompartment through the assembly of functional DNA
molecules. This may be used to develop remotely tunable controlled release of small molecules through
DNA channels, which has great potential in drug delivery and nanomedicine.
2017 SINGAPORE CONFERENCE
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Topic: Smart Interfacial Materials from Super-Wettability to Binary Cooperative
Complementary Systems
Lei Jiang
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China
School of Chemistry and Environment, Beihang University, China
Abstract- Learning from nature and based on lotus leaves and fish scale, we developed
super-wettability system: superhydrophobic, superoleophobic, superhydrophilic,
superoleophilic surfaces in air and superoleophobic, superareophobic, superoleophilic,
superareophilic surfaces under water. Further, we fabricated artificial materials with smart
switchable super-wettability, i.e., nature-inspired binary cooperative complementary
nanomaterials (BCCNMs) that consisting of two components with entirely opposite
physiochemical properties at the nanoscale, are presented as a novel concept for the building
of promising materials.
The smart super-wettability system has great applications in various fields, such as
self-cleaning glasses, water/oil separation, anti-biofouling interfaces, and water collection
system.
The concept of BCCNMs was further extended into 1D system. Energy conversion systems
that based on artificial ion channels have been fabricated. Also, we discovered the spider
silks and cactus's amazing water collection and transportation capability, and based on these
nature systems, artificial water collection fibers and oil/water separation system have been
designed successfully.
Learning from nature, the constructed smart multiscale interfacial materials system not only
has new applications, but also presents new knowledge: Super wettability based chemistry
including basic chemical reactions, crystallization, nanofabrication arrays such as small
molecule, polymer, nanoparticles, and so on.
2017 SINGAPORE CONFERENCE
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Keynote Speaker VII
Assoc. Prof. Pan Jisheng
Institute of Materials Research and Engineering/ National University of Singapore (NUS),
Singapore
Dr. Jisheng Pan received his B. Sc in Physics from Zhejiang University in 1985 and his M. Sc in Nuclear
Physics in 1988 from Shanghai Institute of applied Physics, Chinese Academy of Sciences, where he
worked for 6 years in nuclear technology. He graduated in 1998 with his PhD in surface science from
National University of Singapore. Currently, he is a senior scientist and photoemission spectroscopy (PES)
group leader in Institute of Materials Research & Engineering, Agency for Science, Technology and
Research (A*Star), Singapore. He is also an Adjunct Associate Professor in the Department of Physics,
National University of Singapore. His areas of research interest are photoemission technique development,
2D materials for nanodevice application, surface nanostructure formation, characterization and application
on catalysis, growth and characterization of thin films for microelectronic device fabrication, Ion beam
pattern of semiconductor surfaces. Dr. Pan has authored or co-authored more than 250 refereed journal
articles, one patent, two know-hows and given more than 80 presentations at international conferences. He
has also provided surface analysis and consulting service to many local and international companies in
Singapore. In the past 10 years his research team has studied many material system interfaces such as
metal/semiconductor, semiconductor/semiconductor, high-k insulator/semiconductor using PES technique.
In addition, His team developed various models for different interfaces to eliminate possible photoemission
charge effect in affecting the data analysis to obtain accurate band alignment information. The knowledge
in this area can significantly contribute to the understanding of the mechanisms governing the properties of
semiconductor interface. Dr. Pan has received many awards including achievement award from A*Star
Aerospace Programme, 2015; Assessor Award (Silver) from Singapore Accreditation Council, 2015; Best
of session paper accreditation at Semicon West Exhibition (San Jose, USA) in 2002; the Natural Science
Award of Chinese Academy of Sciences in 1991. He is a technical assessor of Singapore Accreditation
Council (SAC); a technical committee member of ISO/TC 201 surface chemical analysis, Singapore; an
associate editor of Surface and Interface Analysis; an editorial board member of Journal of Spectroscopy.
He is also a member of many professional societies such as AVS (USA), MRS (Singapore), IPS (Singapore)
and NSC (China).
Research Interests
2D materials for nanodevice application, Surface nanostructure growth and characterization, Growth and
characterization of thin film for microelectronic device fabrication, Low energy ion beam modification and
patterning of semiconductor and polymer surfaces, Gas absorption on metal and semiconductor single
crystals as well as on surfaces of catalyst, Industry surface analysis and consulting service.
2017 SINGAPORE CONFERENCE
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Topic: Surface and Interface Studies of Nanostructured Materials by X-ray Photoemission
Spectroscopy (XPS)
J. S. Pan
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology
and Research), Singapore
Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore
Abstract- It is well known that XPS is a very powerful tool for understanding the nature of
solid surfaces. Although advances in existing and newly developing tool with high spatial
resolution receive a good deal of press if they improve the analysis quality of individual
nanosized features of materials. XPS is an important, established and frequently essential tool
for understanding several important aspects of nanostructured natural that cannot easily be
obtained using other techniques. However, the question of how the nanosized sample features
impact XPS data have been heavily debated in the scientific community, which limits its
application in characterization of nanostructured materials. For example, there is consistent
observation of cluster-size-dependent binding energy (BE) shifts. But there is substantial
disagreement over the assignment of these shifts to initial or final state effects. As a result, the
measured PES data cant directly match to the electronic property of clusters because among
the initial and final state effects, only the initial state effect involves information of changes in
the electronic structure before photoemission, and hence is directly related to nanostructured
material properties and is relevant for understanding other chemical process and reactions. In
the first part of the presentation, I will talk to you some general information about XPS. The
issues raised specifically for XPS analysis of nanostructured materials and some limitations
will be discussed in second part. Finally, I will provide you some examples of application of
XPS to study nanostructured materials (nanolayers and nanoparticles).
2017 SINGAPORE CONFERENCE
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Plenary Speaker
Assoc. Prof. Md. Eaqub Ali
University of Malaya, Malaysia
Dr. Md. Eaqub Ali is an Associate Professor of Nanobiotechnology in the University of
Malaya. He received his BSc (Biochemistry) from Dhaka University, MSc (Chemistry) from
Concordia University and PhD (Nanobiotechnology) from University Malaysia Perlis. His
outstanding contributions include CNT and Graphene Hybrids for Water Purification and
Multicomponent Systems for Food Security Detection. Dr. Ali has produced 2 patents, 125
journal papers, 40 conference papers, 2 key notes and 18 invited lectures. He also won
prestigious Atlas Award in 2015 from Elsevier for ground breaking research on desalination
technology (Atlas Award: Quenching the world's thirst for seawater Elsevier:
https://www.elsevier.com/connect/atlas-award-quenching-the-worlds-thirst-for-seawater) and
ACS PressPacs in 2016 from the American Chemical Society for outstanding research on
food fraud detection (Frankfurter fraud: Finding out what's in your hot dog American
Chemical Society: https://www.acs.org/content/acs/en/pressroom/
presspacs/2016/acs-presspac-august-10-2016/frankfurter-fraud-finding-out-whats-in-your-hot-
dog.html). Dr. Ali also received many regional and national level awards such as BioMalaysia
Gold and Silver Awards for 2011 and 2012. He is a member of the Royal Society of
Chemistry, International Association for Food Protection, AOAC International, Malaysian
Institute of Chemistry and Malaysian Nanotechnology Association.
2017 SINGAPORE CONFERENCE
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Topic: Multicomponent Systems for Food and Water Security: Making a Difference and
Global Impact through Need Based Research
Md. Eaqub Ali
University of Malaya, Malaysia
Abstract- Many scientists do research but very few of them get recognized. Novelty is an
important issue in scientific publications but it may not necessarily address the needs that we
really needs. You might be successful in publishing in high impact journals but it does not
warrant that it will make you known. You might have good citations but it may not make you
the headline in Worlds News. In fact, research that does not address needs and does not have
applications in real-world do not have merit of making you known. The bottom line of
recognition is how your research is going to address the needs of the real-world problems.
Water and Food are two fundamental needs of not only human but also all the living beings on
this beautiful planet. Global warming and money first pursuits are increasingly putting our
water and food security at the riskier boundaries. This lecture will describe a multicomponent
system that can ensure better security and safety standard of the water and food that are the
blood line of our health and economic security. These researches have already impacted the
world and we were awarded Elseviers Atlas in 2015 for ground breaking work on water
security and ACS PressPac 2016 for food fraud detection.
2017 SINGAPORE CONFERENCE
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Invited Speaker
Assoc. Prof. HAJIME HIRAO
City University of Hong Kong, Hong Kong
Dr. Hajime Hirao received his BEng and MEng degrees from Kyoto University and his PhD
from The University of Tokyo. He underwent his postdoc training at The Hebrew University
of Jerusalem, Emory University, and Kyoto University. Prior to that, he worked for three
years on computer-assisted drug design at the Novartis institute in Japan. Before joining City
University of Hong Kong, he worked as faculty at Nanyang Technological University in
Singapore. Over the years, he has been interested in computational and theoretical aspects of
chemistry, especially chemical reactions. One of the major goals of his research is to figure
out how difficult chemical transformations can be achieved using simple catalytic platforms
built from earth-abundant elements.
Dr. Hiraos research applies quantum chemistry, multiscale models, and many other
computational chemistry techniques to a variety of complex molecular systems of practical
importance such as transition-metal catalysts, metalloenzymes, drugs/drug targets, porous
materials, and nanomaterials. Using computational approaches and often with experimental
collaborators, his group seeks to derive key insights into chemical reaction mechanisms and
bonding patterns of complex molecules, with the ultimate aim of designing new functional
molecules and materials. He is also interested in developing new concepts and computational
methods that may enhance our understanding of chemistry or improve the efficiency of
computational analyses.
2017 SINGAPORE CONFERENCE
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Topic: Computational Studies of Chemical Reactions on Biological and Non-biological
Catalytic Platforms
HAJIME HIRAO
City University of Hong Kong, Hong Kong
Abstract- The physical principles used in computational chemistry underlie all branches of
chemistry; as such, computational chemistry has unlimited potential to contribute to the
advancement of fundamental chemistry in every different subdiscipline as well as to finding
solutions to critical challenges that humankind faces today, such as healthcare and
energy/environmental issues. With this in mind, our computational exploration of chemistry
applies quantum chemistry, multiscale QM/MM and QM/QM approaches, and many other
advanced computational chemistry techniques to a broad range of complex molecular systems
such as metalloenzymes, transition-metal catalysts, drugs/drug targets, metal-organic
frameworks (MOFs), and nanomaterials. In particular, using computational approaches and
often with experimental collaborators, we seek to derive information about chemical reaction
mechanisms and bonding patterns of these complex molecules. We are also developing
efficient computational methods and algorithms, in the hope that our new computational
methods will expand the capability of computational chemistry and thereby enable one to
simulate the behavior of complex molecular systems with higher reliability and predictability
in the future.
2017 SINGAPORE CONFERENCE
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Brief Schedule for Conference
Day 1
August 21, 2017 (Monday) 9:00~18:30
Venue: Basil (Level 2)
Arrival Registration, Keynote Speeches, Plenary Speech, Invited Speech and
Conference Presentations
Registration
Venue: Outside of the Basil (Level 2)
Arrival Registration 9:00~18:00
Afternoon Conference
Venue: Basil (Level 2)
Keynote Speech I 13:00~13:35
Prof. Shen-Ming Chen, National Taipei University of Technology, Taiwan
Plenary Speech 13:35~14:00
Assoc. Prof. Md. Eaqub Ali, University of Malaya, Malaysia
Invited Speech 14:00~14:20
Assoc. Prof. HAJIME HIRAO, City University of Hong Kong, Hong Kong
Coffee Break & Group Photo Taking 14:20~14:40
Keynote Speech II 14:40~15:15
Assoc. Prof. GAUTAM SETHI, National University of Singapore, Singapore
Session 1: 15:15~18:30
13 presentations-Topic: Chemistry and Chemical Engineering
Day 2
August 22, 2017 (Tuesday) 8:35~18:20
Venue: Clove & Lemongrass (Level 2)
Arrival Registration, Keynote Speeches and Conference Presentations
Morning Conference
Venue: Clove & Lemongrass (Level 2)
Opening Remark 8:35~8:40
Assoc. Prof. Pan Jisheng, Institute of Materials Research and Engineering/
National University of Singapore, Singapore
Keynote Speech III 8:40~9:15
Prof. Kien Wen Sun, National Chiao Tung University, Hsinchu, Taiwan
Keynote Speech IV 9:15~9:50
Prof. Jun Ding, National University of Singapore, Singapore
Coffee Break & Group Photo Taking 9:50~10:15
2017 SINGAPORE CONFERENCE
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Day 2
Keynote Speech V 10:15~10:50
Prof. Yoshihiro Sugi, Professor Emeritus, Gifu University, Japan
Keynote Speech VI 10:50~11:25
Prof. Lei Jiang, Chinese Academy of Sciences, China
Keynote Speech VII 11:25~12:00
Assoc. Prof. Pan Jisheng, Institute of Materials Research and Engineering/
National University of Singapore, Singapore
Lunch: 12:00~13:00 Venue: KENT RIDGE GUILD HOUSE
Afternoon Conference
Session 2: 13:00~15:30
Venue: Clove
10 presentations-Topic: Materials
Physics and Computational Materials
Science
Session 3: 13:00~15:30
Venue: Lemongrass
10 presentations-Topic: Material
Processing and Surface Treatment
Coffee Break: 15:30~15:50
Session 4: 15:50~18:05
Venue: Clove
9 presentations-Topic: Polymers and
Composites
Session 5: 15:50~18:20
Venue: Lemongrass
10 presentations-Topic: Materials
Science and Manufacturing
Engineering
Poster session 9:00~18:20 Venue: Clove & Lemongrass
Dinner: 18:30 Venue: KENT RIDGE GUILD HOUSE
Day 3 August 23, 2017 (Wednesday) 9:30~17:00 Academic Visit
Tip: Please arrive at the Conference Room 10 minutes before the session begins, and upload
PPT/ PDF file into the conference laptop.
2017 SINGAPORE CONFERENCE
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Detailed Schedule for Conference
August 21, 2017 (Monday)
Venue: Outside of the Basil (Level 2)
9:00~18:00 Arrival and Registration
Note: (1) The registration can also be done at any time during the conference.
(2) The organizer doesnt provide accommodation, and we suggest you make an early reservation.
(3) One Best Oral Presentation will be selected from each oral presentation session. The Certificates
for Best Oral Presentation will be awarded at the end of each session on August 21 and 22, 2017.
August 21, 2017 (Monday)
Venue: Basil (Level 2)
13:00~13:35
Keynote Speech I
Prof. Shen-Ming Chen
National Taipei University of Technology, Taiwan
Topic: Electrochemistry, Biosensors and Nanotechnology: Advances and
Relevance
13:35~14:00
Plenary Speech
Assoc. Prof. Md. Eaqub Ali
University of Malaya, Malaysia
Topic: Multicomponent Systems for Food and Water Security: Making a
Difference and Global Impact through Need Based Research
14:00~14:20
Invited Speech
Assoc. Prof. HAJIME HIRAO
City University of Hong Kong, Hong Kong
Topic: Computational Studies of Chemical Reactions on Biological and
Non-biological Catalytic Platforms
14:20~14:40 Coffee Break & Group Photo Taking
14:40~15:15
Keynote Speech II
Assoc. Prof. GAUTAM SETHI
National University of Singapore, Singapore
Topic: Potential Therapeutic Application of Tocotreinols for Cancer Treatment
15:15~18:30 Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
2017 SINGAPORE CONFERENCE
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August 22 2017 (Tuesday)
Venue: Clove & Lemongrass (Level 2)
8:35~8:40
Opening Remark
Assoc. Prof. Pan Jisheng
Institute of Materials Research and Engineering/ National University of Singapore, Singapore
8:40~9:15
Keynote Speech III
Prof. Kien Wen Sun
National Chiao Tung University, Hsinchu, Taiwan
Topic: A Review on Biological and Chemical Applications of Diamond
Nanomaterials
9:15~9:50
Keynote Speech IV
Prof. Jun Ding
National University of Singapore, Singapore
Topic: Functional Structures by Additive Manufacturing and Their Applications
9:50~10:15 Coffee Break & Group Photo Taking
10:15~10:50
Keynote Speech V
Prof. Yoshihiro Sugi
Gifu University, Japan
Topic: Zeolite as Molecular Reactor. The Isopropylation of Biphenyl over
H-Mordenite
10:50~11:25
Keynote Speech VI
Prof. Lei Jiang
Chinese Academy of Sciences, China
Topic: Smart Interfacial Materials from Super-Wettability to Binary Cooperative
Complementary Systems
11:25~12:00
Keynote Speech VII
Assoc. Prof. Pan Jisheng
Institute of Materials Research and Engineering/ National University of Singapore
(NUS), Singapore
Topic: Surface and Interface Studies of Nanostructured Materials by X-ray
Photoemission Spectroscopy (XPS)
12:00~13:00 Lunch
13:00~15:30 Session 2: 10 presentations-Topic: Materials Physics and Computational Materials Science
Session 3: 10 presentations-Topic: Material Processing and Surface Treatment
15:30~15:50 Coffee Break
15:50~18:20 Session 4: 9 presentations-Topic: Polymers and Composites
Session 5: 10 presentations-Topic: Materials Science and Manufacturing Engineering
18:30 Dinner
2017 SINGAPORE CONFERENCE
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Session 1 Tips: The schedule for each presentation is for reference only. In order not to miss your presentation,
we strongly suggest you attend the whole session.
Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P0002 Presentation 1 (15:15~15:30)
Preparation and Characterization of Chitosan/GPTMS Hydrogels by a Sol-Gel Method
Mao-Chi Weng, Tsung-Sheng Chen and Shu-Ling Huang
National United University, Taiwan
AbstractApH responsive chitosanand GPTMS (3-Glycidyloxypropyltrimethoxysilane)
hydrogel was synthesized by the sol-gel cross-linkingreaction. GPTMSwere introduced to
influence several behaviors of thechitosan hydrogels, such asthe swelling ratio, mechanical
properties, swelling thermodynamics and kinetics expansion mechanism.The functional
groups of Chitosan/GPTMS hybrid hydrogelswere verified bya FT-IR spectrometer.Using
the differential scanning calorimetry(DSC) analyzedthe thermal behavior of water
molecules,the expansion of thermodynamics, as well as the content of water molecules in the
hydrogel.The results showthat when chitosanhydrogel add 50mol% of
GPTMS(CG-50%),whichhave good mechanical propertiesand sensitivity to pH response
characteristics inthe acidic/alkalinebuffer solution. In addition, the interaction
parameter()was obtainedthrough the DSC diagramand water uptake experiment.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P0004 Presentation 2 (15:30~15:45)
Total Phenolic Content and Antioxidant Activity of Ginger Torch (Etlingera elatior (Jack)
R.M.Sm)
Tresna Lestari, Ruswanto, Tita Nofianti, Annisa Lestari, Siti Munawaroh, Hilda A Badriah
Sekolah Tinggi Ilmu Kesehatan Bakti Tunas Husada
AbstractGinger torch is a herb that potentially active as natural antioxidant. The compound
that is suspected to be responsible for antioxidant activity from ginger torch is phenolic group.
The antioxidant study was conducted against 1,1-diphenyl-2-picrylhidrazil for in vitro activity
and by measuring the level of superoxide dismutase enzyme of animal test for in vivo activity.
The result showed that antioxidant activity was higher on methanol extract (IC50 19.919
g/ml) compared to ethanol extract (IC50 36.810 g/ml) and acetic acid extract (IC50 23.233
g/ml). This was in line with total phenolic content that was higher on methanol extract
(1.114 g GAE/100 g extract) rather than ethanol extract (0.788 g GAE/100 g extract) and
acetic acid extract (0.812 g GAE/100 g extract). In vivo antioxidant activity test gave
information that giving 2 mg/mL methanol extract against white rat could increase superoxide
dismutase level by 1,3183 U/mL that was significant to normal group (1,1159 U/mL) and
negative control group (1,0178 U/mL).
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P0005 Presentation 3 (15:45~16:00)
Antitriglyceride Activity Test of Ethanol Extract Tamarind Leaf (Tamarindus indica L.)
against Strains Wistar Male Rats
Tita Nofianti
Sekolah Tinggi Ilmu Kesehatan Bakti Tunas Husada Tasikmalaya, Indonesia
AbstractThis research aimed to determine the antitriglyceride activity of the ethanol extract
of Tamarind Leaf (Tamarindus indica L.) on white male rats strain of Wistar hyperlipidemia
with normal group, negative control group, positive control group, and the first group test
dose of 1,748 mg/200g BW rats, the second test dose of 3,497 mg /200g BW rats, and the
third test dose of 6,994 mg /200g BW rats. The ethanol extract of Tamarind Leaf
(Tamarindus indica L.) was given orally for 14 days using PTU induced of 1.8 mg/200g
BW rats and egg yolks 10 mL/Kg BW. Triglyceride levels were measured with the
Colorimetric Enzymatic Test GPO (Glycerol-3-Phosphat Oxidase). The result of the research
analyzed using statistic test that ethanol extract of Tamarind Leaf (Tamarindus indica L )
give an effect on the decline average in triglyceride levels white male Wistar rats at the first
dose (1,748 mg/200g BW rats) of 18.94%, the second dose (3,497 mg /200g BW rats) of
31.89%, and the third dose (6,994 mg /200g BW rats) of 38.78%. The most effective dose is
the third dose (0.074 gram/200g BB rats) with the decline presentation of 38.70%.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P0007 Presentation 4 (16:00~16:15)
Recovery of Indium from Mobile Phone Touch Screen Using Adapted Acidithiobacillus
Ferrooxidans
Omid Rezaei, Seyyed Mohammad Mousavi and Fatemeh Pourhossein
Tarbiat Modares University, Iran
AbstractThe toxicity of heavy metals has important role in thermophilic microorganism
growth in bioleaching of e-waste. The mobile phone touch screen has high concentration of
several heavy metals that caused negative effect on bacterial activity and metals recovery. In
the present investigation, Acidithiobacillus ferrooxidans was adapted to powder of mobile
phone touch screen. The serial subculturing approach was used for bacterial adaptation with
heavy metals. The experiments began with 0.1 wt/vol.% pulp density eventually increase to
2.5 wt/vol.%. All experiment conducted in 100 ml 9k medium at the initial pH 2 and 2%
(v/v) inoculums. The effective parameters such as pH, Eh, Fe3+, cell concentration were
studied and the results confirmed as well as each other. Indium recovery for adapted cell,
non-adapted cell and control were 100%(adapted) , 10%(non-adapted) , 1%(control).,
respectively. Finally, it is essential that the bacteria become adapted with the heavy metals
and consequently an acceptable bioleaching process will be achieved.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P0008 Presentation 5 (16:15~16:30)
An Amperometric Biosensor Based on Fumarate Reductase for Enzymatic Properties and
Electrical Behavior
Yemin Yu, Yonghong Hu, Tao Li, Wenge Yang, Yuhao zhang and Renlun Deng
Nanjing Tech University, China
AbstractIn this paper, the production of fumarate reductase was studied. Through ultrasonic
separation, gel chromatography and 65% ammonium sulfate fractionation, the fumarate
reductase specific activity reached to 106 U/mg, the purification ratio was 12.8 times and the
recovery was 24%. Fumarate reductase was fixed on electrode, which was modified
polyethyleneimine reductive graphene composites, through covalent bonding and electrostatic
adsorption. The electrode was used to replace coenzyme NADH in the cell inside metabolism,
constructing a fumarate reductase catalytic system based on electrical driving.
The results showed that fumaric acid reductase immobilized on the electrode not only
maintained a certain biological activity, but also could catalyze the metabolism of fumaric
acid. Thus, the electrical catalysis of fumarate reductase/polyethyleneimine reductive
graphene composites/glassy carbon electrode and the substrate of fumaric acid based on
fumarate reductase were studied, providing a scientific theoretical basis for the production of
succinic acid in vitro.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P0009 Presentation 6 (16:30~16:45)
Experimental Investigation of Injection Pressure Effect on the Natural Gas Storage in
Aquifers
E. Kazemi Tooseh, A. Jafari and A. Teymouri
Tarbiat Modares University
AbstractStoring natural gas in underground reservoirs is a key element in the gas supply
market. Depleted oil and gas reservoirs, salt caverns and aquifers are major candidates for
natural gas storage, and between them aquifers have a high potential for effective balancing
of a variable demand market. Aquifers are underground water bearing formations which may
extend over distances of several miles, and in the absence of depleted reservoirs, saline
aquifers are a proper option for underground gas storage. Because of water and gas
movements in the reservoir, it is worth to know about the flow behavior across the porous
medium. The behavior of natural gas in contact with brine has not been considered widely in
the literature, and the effect of injection pressure on the process has not been studied
experimentally before. Therefore, for the first time in this research the natural gas storage
capacity at different pressures were calculated and gas and water flow behavior under high
injection pressures in a low permeability rock is investigated by experimental tests.
Natural gas flooding experiments were performed using a core flood set up at constant
temperature 46 C, and in each test the low permeability core sample taken from an Iranian
aquifer was cleaned by methanol injection for 24 hours. Then it was dried in oven at 90 for
12 hours. After that the core was vacuumed for 8 hours and saturated by two pore volume of
the synthetic brine with 210000 ppm salt concentration. After that natural gas was injected at
a constant flow rate into the core plug saturated with brine, and at the gas breakthrough time
experiments were stopped and the storage capacity of sample was measured by comparing its
weight difference before and after the test. Obtained results illustrate that the injection
pressure plays an important role in the gas storage process, and increasing the pressure
improves the sweep efficiency and water withdrawal. In other words, by doubling the
injection pressure from 80 to 160 bar the gas storage capacity enhances about 7%.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P0011 Presentation 7 (16:45~17:00)
Encapsulation, Properties, and Thermal Study of Red Biocolorant from Selected Plants
Obtained through Physical Extraction
Renny Indrawati, Diah Mustika Lukitasari, Yuyun Yuniati, Heriyanto and Leenawaty
Limantara
Ma Chung Research Center for Photosynthetic Pigments, Universitas Ma Chung, Indonesia
AbstractThe human perception on food is closely associated with its color. Since the
standard manufacturing procedure often causes partial even total degradation of natural
pigments, resulting in color fading, the addition of colorants becomes necessary. Natural
colorant, produced from plants or animals, has health promoting effects, better safety, and
need not any specific toxicity evaluation. However, the extraction method will be crucial in
determining the properties of this biocolorant. In the present study, red biocolorant was
prepared from selected local plants i.e., red spinach, red cabbage, beetroot, and dragon fruit,
through physical extraction in order to avoid the using of organic solvents. Then, we applied
the encapsulation technique and evaluated its coloring and antioxidant properties, as well as
its stability against thermal treatment. The results showed that the encapsulated biocolorant
of red spinach and beetroot exhibited red hue at pH range 2-11, whereas those of red cabbage
and dragon fruit indicated color alteration at different pH. The prominent red hue intensity
was found at pH 4 for encapsulated beetroot extract, which endured up to 10 days at aqueous
buffered solution when stored in the dark at 200C. In addition, it underwent merely low
encapsulated biocolorant of beetroot was comparable to that of red cabbage, being higher
than the others.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P1001 Presentation 8 (17:00~17:15)
Molecular Aggregate Containing both Channels and Cages via Arrays of Metallacyclodimers
and Its Molecular Recognition via Photoluminescence
Jeong Jun Lee, Daseul Lee and Ok-Sang Jung
Pusan National University, Republic of Korea
AbstractSelf-assembly of ZnX2 (X = Cl, Br, and I) with new
2,3-bis(4-nicotiamidephenoxy)naphthalene (L) with as a hemi-circular bidentate ligand
containing a chromophore moiety yields a systematic 46-membered metallacyclodimeric
unit, [ZnX2L]2. These cyclodimers constitute, via interdigitated interactions in a
staggered fashion, a characteristic ensemble forming both channels and cages. This stable
ensemble can then be employed as an unusual "small molecule-reservoir within the channel
and the cage" host-guest system. The ensemble with channel and cage significantly stabilizes
the unstable CH2I2 molecules. Furthermore, [Zn2Cl4L2]6CH3CN significantly recognizes
CH2I2 via photoluminescence. These three complexes have significant halogen effects on the
photoluminescence (PL), thermal properties, and host-guest inclusion in addition to structural
difference.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P1002 Presentation 9 (17:15~17:30)
Solvent Effect of Crystal Structures of Cadmium(II) Chloride Containing
Di(pyridin-4-yl)silane
Minjoo Ryu, Daye Choi and Ok-Sang Jung
Pusan National University, Republic of Korea
AbstractA close insight into a systematic solvent-template effect on self-assembly of
cadmium(II) chloride with new di(pyridin-4-yl)silane ligand (L) has been achieved. Each
reaction gives rise to the 1 : 2 composition of Cd(II) : L, but shows significant solvent
template effects on the formation of topology. The reaction in MeOH and in MeCN yields
1D loop chain, respectively, containing the solvate molecules whereas the same treatment in
the relatively bulky solvents such as EtOH, n-PrOH, and i-PrOH yields interpenetrated 2D
sheet. Thus, construction and packing of each structure are determined by solvent templates
rather than synthetic methodology. Solvate MeOH molecules of [CdCl2L2]4MeOH crystals
in MeCN media are perfectly exchanged to MeCN molecules and the solvate MeCN
molecules of [CdCl2L2]2MeCN crystals in MeOH media are exchanged into MeOH
molecules as solvate, indicating that the solvate molecules do not interact significantly with
the skeletal structures.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P1003 Presentation 10 (17:30~17:45)
Sandwich-shaped Zn(II) Complex Containing Tridentate Silane Ligand: Fluorescence
Quenching Effect
Sangseok Lee, Seo Young Hwang and Ok-Sang Jung
Pusan National University, Republic of Korea
AbstractSelf-assembly of Zn(ClO4)2 with 1,3,5-tris(dimethyl(pyridin-3-yl)silyl)benzene
(L) as new C3 -donor gives rise to a discrete sandwich-shaped M3L2
architecture, [Zn3(-OH)3L2](ClO4)34CH3CN2H2O. The 1H chemical shifts of
[Zn3(-OH)3L2]-(ClO4)34CH3CN2H2O show up-field shift relative to L and its 1H NMR
spectrum in acetone is consistent with its crystal structure. However, the addition of Me2SO
to the acetone solution initiates dynamic molecular behavior (10 : 2) and then, finally,
dissociation (> 10 : 4). Its blue photoluminescence is significantly quenched by only CH2I2
among the various small molecules, CH2Cl2, CH2Br2, CHCl3, 1,2-dichloroethane, EtOH,
MeOH, CH3CN, benzene, toluene, and phenol. According to the results, the fluorescence
quenching follows the dynamic quenching mechanism. These results could provide important
clues to the design of capsule-like self-assemblies having potential catalysts, sensor, and
recognition applications.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P3003 Presentation 11 (17:45~18:00)
Microencapsulation of Kabocha Pumpkin Carotenoids
Naomi M. Mulyadi, Tri D. Widyaningsih, Novita Wijayanti, Renny Indrawati, Heriyanto
and Leenawaty Limantara
Universitas Ma Chung, Indonesia
AbstractKabocha pumpkin (Curcubita maxima [Duchesne ex Lamb.]) is a potential source
of carotenoids. However, the usage of carotenoids is limited due to their instability and also
their susceptible degradation against harmful conditions such as base and acidic conditions,
oxidation, and illumination. In this study, kabocha carotenoids were incorporated into
microencapsulation containing chitosan, sodium alginate and sodium tripolyphosphate. The
objective of this study is to determine the formulation of coating agents, carotenoid stability
in acidic conditions for mimicking the microencapsulation process, and to characterize the
microencapsulated carotenoids including the determination of the efficiency of carotenoid
incorporation into microencapsulates. A mixture of sodium alginate, chitosan and sodium
tripolyphosphate (0.19 g : 1.92 g : 0.24 g, w/w/w) was the best of coating agents according to
the physical characteristics and also its moisture content. Microcapsules obtained with and
without addition of carotenoids were determined to be a microparticle size by SEM analysis.
The products of microencapsulated carotenoids have the water content of around 5.4% to
7.1%.The highest efficiency of microencapsulation obtained was 91% at the carotenoid
concentration of 117.98 g g1 (0.5 %, w/v), although the efficiency was decreased with
increasing carotenoids added to the microcapsules probably due to over loading of
carotenoids used. The pattern of this efficiency was in line with L* and hue values, whereas
not only a*, b*, and chroma values, but total carotenoids, and total provitamin A also
increased.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P0014 Presentation 12 (18:00~18:15)
Synthesis, Characterization and Anticancer Activity of 1-Benzoyl-3-methylthiourea
Derivatives
Ruswantoa, Amir M. Miftah , Daryono H. Tjahjono and Siswandonoc
Bakti Tunas Husada Health Science College, Indonesia
AbstractThiourea is an organic compound made up of carbon, hydrogen, nitrogen, and
sulphur atoms. This compound is similar to urea except that the oxygen atom is replaced by
sulphur. Thiourea and its derivatives appear as white, lustrous crystals or flaky solids and are
useful in pharmaceutical applications, such as anti-cancer drugs.
The acylation reaction was performed between benzoyl chloride derivatives and N-methyl
thiourea in tetra hydro furan solvent with tri ethyl amine as the catalyst under reflux
conditions at 100 oC. The purity was analysed by thin layer chromatography and melting
point measurement. The structures were confirmed using IR, MS and 1H/
13C-NMR.
Anti-cancer activity against HeLa, MCF-7, T47D and WiDr cell lines was evaluated by the
standard MTT assay.
We report that 1-benzoyl-3-methylthiourea derivatives could be made from the reaction
between benzoyl chloride derivatives and N-methylthiourea. Most of the compounds
exhibited more potent anti-cancer activity in HeLa, MCF-7, T47D and WiDr cell lines as
compared with hydroxyurea.
Our results showed that 1-(2,4-dichlorobenzoil)-3-methylthiourea could become a new lead
compound for further optimization for cancer treatment.
2017 SINGAPORE CONFERENCE
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Afternoon, August 21, 2017 (Monday)
Time: 15:15~18:30
Venue: Basil (Level 2)
Session 1: 13 presentations-Topic: Chemistry and Chemical Engineering
Session Chair: Prof. Shen-Ming Chen
P3004 Presentation 13 (18:15~18:30)
Electro-Catalytic Behaviour of Pan-Ec-Pc-Tpai-I2 Gel Type Polymer Electrolytes for
Dye-Sensitized Solar Cell Application
Faisal I. Chowdhury, M. U. Khandaker and A. K. Arof
University of Malaya, Malaysia
AbstractPolyacrylonitrile (PAN) based gel type polymer electrolytes (GPEs) with
plasticizers such as ethylene carbonate (EC) / propylene carbonate (PC) and various
compositions of tetrapropylamonium iodide (TPAI) have been prepared and characterized.
Electrochemical impedance spectroscopy (EIS) as well as linear sweep voltammetry (LSV)
measurements have been conducted using non-blocking Pt-electrode symmetric cells. The
limiting current (Jlim), apparent diffusion coefficient of triiodide ion ( ) and exchange
current are 12.76 mA/cm-2
, 23.4110-7
cm2 s
-1 and 11.22-14.24 mA/cm
-2, respectively for
30 % of TPAI containing GPE which are the highest values among the other GPEs. To
measure the ionic conductivity behaviour, EIS technique has been employed at blocking
electrodes. From this EIS study the lowest bulk impedance, Rb (22 ), highest ionic
conductivity (3.62 103
S cm1
) and lowest activation energy have been observed for the
GPE containing 30 wt. % TPAI.
2017 SINGAPORE CONFERENCE
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Session 2 Tips: The schedule for each presentation is for reference only. In order not to miss your presentation,
we strongly suggest you attend the whole session.
Afternoon, August 22, 2017 (Tuesday)
Time: 13:00~15:30
Venue: Clove (Level 2)
Session 2: 10 presentations- Topic: Materials Physics and Computational
Materials Science
Session Chair: Prof. Lei Jiang
J0002 Presentation 1 (13:00~13:15)
A Structural Mechanics Approach for the Phonon Dispersion Analysis of Grapheme
Xiuhui Hou and Zichen Deng
Northwestern Polytechnical University, China
AbstractGraphene with honeycomb lattice structures exhibits excellent mechanical
properties and thus presents important application values in the fields of wave propagation.
However, existing numerical methods for the dynamic properties analysis of nanostructures,
including the molecular dynamics method, which simulates the motion of every atom,
resulting in huge amount of computation efforts, and thus is greatly limited both in space and
time scales. Other methods such as the continuum mechanics method ignores the molecular
structure of the graphene, and thus is difficult to take into account the influence of atomic
scale details. The molecular structure mechanics method, which is based on the atomistic
simulation method and the continuum mechanics method, can combine the molecular
structure and the macroscopic characteristics, and replace the discrete molecular structure
with the molecular structure mechanics model, and thus is deemed as a more efficient method
in deducing the phonon dispersion relation of graphene.
A molecular structural mechanics model for the numerical simulation of phonon dispersion
relations of graphene is developed by relating the C-C bond molecular potential energy to the
strain energy of the equivalent beam-truss space frame. With the stiffness matrix known and
further based on the periodic structure characteristics, the Bloch theorem is introduced to
develop the dispersion relation of graphene sheet. Being different from the existing structural
mechanics model, interactions between the fourth-nearest neighbor atoms are further
simulated with beam elements to compensate the reduced stretching stiffness, where as a
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result not only the dispersion relations in the low frequency field are accurately achieved, but
results in the high frequency field are also reasonably obtained. This work is expected to
provide new opportunities for the dynamic properties analysis of graphene and future
application in the engineering sector.
2017 SINGAPORE CONFERENCE
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Afternoon, August 22, 2017 (Tuesday)
Time: 13:00~15:30
Venue: Clove (Level 2)
Session 2: 10 presentations- Topic: Materials Physics and Computational
Materials Science
Session Chair: Prof. Lei Jiang
J0005 Presentation 2 (13:15~13:30)
Investigation of the Intermediate Phase of NiFe/Bi2Se3 Ferromagnet/ Topological-insulator
Heterostructure
Yu-Han Huang, Shu-Jui Chang , Yu-Jun Chen, Jung-Chun-Andrew Huang and Yuan-Chieh
Tseng
National Chiao Tung University, Taiwan
AbstractThe combination of topological-insulators (TI) and ferromagnets (FM) can enable
ultrahigh efficiency of the TI in converting electrical charge current into spin accumulation.
Various kinds of synchrotron x-ray techniques were used to explore the intermediate phase
effects in the vicinity of the TI-FM epitaxial junction. This issue is essential because the
intermediate phase would tremendously affect the TIs electronic behavior such as the
fascinating spin transfer/orbital torque and spin-momentum locking effects. The results po