Ion Chemistry Conference

Lake

Arrow head

2000 Conference on Ion Chemistry and Mass Spectrometry

January 28–30, 2000 UCLA, Conference Center, Lake Arrowhead, California

Schedule of Presentations

Friday, January 28

3:30 PM CHECK-IN AND ROOM ASSIGNMENTS

5:30 – 6:30 SOCIAL HOUR

6:30 - 7:30 DINNER

SESSION I Presider: Mary T. Rodgers 7:40 - 8:05 “Dynamics of a CID Process: Cr(CO)6

+”, Felician Muntean and P. B.

Armentrout, University of Utah, Salt Lake City, UT.

8:05 - 8:30 “A Reappraisal of the Photochemistry of the O2+ Ion in the Lower Ionosphere”,

Laurence Angel and Kent M. Ervin, University of Nevada, Reno, NV.

8:30 – 8:55 “The Advanced Space Particle Analyzer (“Dustbuster”): A Compact Time-of-

Flight Mass Spectrometer for in situ Studies of Interplanetary Dust”, Daniel Austin and J. L.

Beauchamp, California Institute of Technology, Pasadena, CA.

8:55 – 9:20 “Sigma Bond Activation by First Row Transition Metal Ions: Potential Energy

Surfaces”, Q. Zhang, P. Kemper, and M. T. Bowers, University of California, Santa Barbara,

CA.

9:20 – 9:45 “Ion-Molecule Complexes of Bridgehead Halides”, Colleen K. Regan and John I.

Brauman, Stanford University, Stanford, CA.

9:45 – 11:00 POSTER SESSION, DRINKS AND DISCUSSION

2POSTER PRESENTATIONS

1. “Determination of Alkali Metal-Benzene Ion Binding Energies by Guided Ion Beam Mass

Spectrometry”, Jay C. Amicangelo and P. B. Armentrout, University of Utah, Salt Lake

City, UT.

2. “Interstellar Ion Chemistry”, V. M. Bierbaum, V. Le Page, and T. P. Snow, University of

Colorado, Boulder, CO.

3. “Molecular Bondage: Determination of the Mutual Binding Sites in Binary and Ternary

Complexes of p19 Tumor Suppressor Protein, Cyclin-Dependent Kinase 6, and Cyclin D2

(the Control Step for Cell Division) by Solution-Phase H/D Exchange and ESI FT-ICR Mass

Spectrometry”, Fei He and Alan G. Marshall, National High Magnetic Field Laboratory,

Tallahassee, FL.

4. “Ion Mobility Measurements of Metal Ligated Monosaccharide Diastereomers”, M. D.

Leavall, S. P. Gaucher, J. A. Taraszka, D. E. Clemmer, and J. A. Leary, University of

California, Berkeley, CA.

5. “Lithium and Sodium Binding Affinities of Glycine and its Components”, Bob Moision and

P. B. Armentrout, University of Utah, Salt Lake City, UT.

6. “Activation of Methane by W+”. Saeyoung Shin, Rohana Liyanage, and P. B. Armentrout,

University of Utah, Salt Lake City, UT.

7. “Microsolvation of Metalated Crown Ethers in FT-ICR Mass Spectrometry”, Sarah N.

Ward and David V. Dearden, Brigham Young University, Provo, UT.

8. “Reactivity and Thermochemistry of Methane with Single Platinum Ions”, Xiao-Guang

Zhang, Rohana Liyanage, and P. B. Armentrout, University of Utah, Salt Lake City, UT.

9. “Investigations in Charged Droplet Breakup and Ion Formation in Electrospray Ionization”,

Jim N. Smith, Ron L. Grimm and J. L. Beauchamp, California Institute of Technology,

Pasadena, CA.

3Saturday, January 23

8:00 - 8:30 BREAKFAST

SESSION II Presider: David V. Dearden 8:30 – 8:55 “Chemistry in Nanodroplets: FT-ICR Studies of Highly Solvated Species”,

Heather Cox, Sang-Won Lee, and J. L. Beauchamp, California Institute of Technology,

Pasadena, CA.

8:55 - 9:20 “Extraction and Assignment of Gas-Phase H/D Exchange Site-Specific Rate

Constants: Application to Dipeptides”, Fei He, Michael A. Frietas, and Alan G. Marshall,

National High Magnetic Field Laboratory, Tallahassee, FL.

9:20 – 9:45 “The Effects of Solvent on the Electrospray Charge State Distributions of

Proteins”, Anthony T. Iavarone, John C. Jerchen and Evan R. Williams, University of

California, Berkeley, CA.

9:45 – 10:10 “Enhanced Cleavage at Protonated Histidine”, Vicki H. Wysocki, George

Tsaprailis, Wendy Zhong, and Hari Nair, University of Arizona, Tucson, AZ.

10:10 - 10:20 BREAK

10:20 - 10:45 . “Chiral Selectivity of Amino Acids with Cyclic and Linear Oligosaccharide

Hosts”, Seonghee Ahn and Carlito B. Lebrilla, University of California, Davis, CA.

10:45 - 11:10 .“Cations from Tritium Decay: Neutral Products from Their Gas Phase Reactions

with Allyl Trimethyl Silane”, Philip S. Mayer and Thomas H. Morton, University of California,

Riverside, CA

11:10 - 11:35 “Salt Bridges or Charge Solvation Structures of Alkali Metal Cationized Amino

Acids: Which and Why”, T. Wyttenbach, M. Witt, and M. T. Bowers, University of California,

Santa Barbara, CA.

11:35 – 12:00 “Separation of Peptides by Using Capillary Electrophoresis with MALDI FT-

MS”, Jun Liu and Carlito B. Lebrilla, University of California, Davis, CA.

12:00 - 2:30 LUNCH AND FREE TIME

4SESSION III Presider: J. C. Poutsma

2:30 – 2:55 “Potential Energy Surfaces of Ions Derived from Sulfuric Acid”, Cynthia A.

Pommerening and Lee S. Sunderlin, Northern Illinois University, De Kalb, IL.

2:55 - 3:20 “Dipolar Effects on the Acidity of Carboxylic Acids”, Jianhua Ren and Robert

R. Squires, Purdue University, West Lafayette, IN.

3:20 – 3:45 “Diasteroselectivity and Enantioselectivity in Gas-Phase Nucleophilic Addition

Reactions of Ketones”, Alexander Artau, Jun Hu, and Robert R. Squires, Purdue University,

West Lafayette, IN.

3:45 - 4:10 “Enthalpies of Formation of Biradicals, Carbenes, and Carbynes”, Brian T. Hill,

Harvey A. Lardin, Paul G. Wenthold, and Hilkka I. Kenttämaa, Purdue University, West

Lafayette, IN.

4:10 - 4:25 BREAK

4:25 – 5:00 “The Reaction of Vibrationally State-Selected Ammonia Ions with Methylamine”,

Jonathon E. Flad, J. C. Poutsma, M. E. Everest, and R. N. Zare, Stanford University, Stanford,

CA.

5:00 - 5:25 “Thermochemistry of Nitriles from Collision-Induced Dissociation Threshold

Measurements”, Paul G. Wenthold, Purdue University, West Lafayette, IN.

5:25 – 5:50 “The C-H Bond Dissociation Energies of Naphthalene”, Harvey A. Lardin, Paul

G. Wenthold, and Robert R. Squires, Purdue University, West Lafayette, IN.

55:50 – 6:15 “Gas Phase Acidity and Bond Dissociation Energy of Diacetylene”, Kent M.

Ervin and Yang Shi, University of Nevada, Reno, NV.

6:30 - 8:00 DINNER

8:00 - 9:00 SATURDAY EVENING

“CELEBRATION OF THE LIFE AND

CAREER OF ROBERT R. SQUIRES”

Presider: Jack Beauchamp Michael T. Bowers, “Presentation of the Special Issue of the International Journal

of Mass Spectrometry in Honor of the Life and Career of Robert R. Squires”,

Hilkka Kenttämaa

Veronica M. Bierbaum

Jun Hu

Susan Graul

Lee S. Sunderlin

9:00 - 12:00 PARTY

Sunday, January 24

8:00 – 8:30 BREAKFAST

6

SESSION IV Presider: Jun Hu 8:30 – 8:55 “Energy Resolved Experiments in FT-ICR Mass Spectrometry”, Martin K.

Beyer, Christian B. Berg, and Julie A. Leary, University of California, Berkeley, CA.

8:55 - 9:20 “DNA Melting Curves Measured with Nano Electrospray Ionization Mass

Spectrometry”, John C. Jurchen, Anthony T. Iavarone, and Evan R. Williams, University of

California, Berkeley, CA.

9:20 – 9:45 “Cluster Assisted Sigma Bond Activation: Zr+(H2)n; Insertion and Uninsertion”,

J. E. Bushnell and M. T. Bowers, University of California, Santa Barbara, CA.

9:45 – 10:10 “Geometry Dependent Reaction Thermochemistries: A Study of Lactones and

Lactone Enolates in the Gas Phase”, Joel M. Karty and John I. Brauman, Stanford University,

Stanford, CA.

10:10 - 10:25 BREAK

10:25 – 10:50 “Possible Effects of Magnetron Motion on FT-ICR Signal”, Katherine A.

Kellersberger and David V. Dearden, Brigham Young University, Provo, UT.

10:50 – 11:15 “Proton and Hydrogen Atom Adducts to Heterocycles. Formation and

Energetics”, F. Tureček, M. Polasek, A. J. Frank, and J. K. Wolken, University of Washington,

Seattle, WA.

11:15 – 11:40 “A General Mass Spectrometry Method for the Rapid Determination of

Enantiomeric Excess in Mixtures of D, L-Amino Acids”, Gabriela Grigorean and Carlito B.

Lebrilla, University of California, Davis, CA.

11:30 - 12:00 CHECK OUT

12:00 - 1:00 LUNCH AND DEPART

7Participants at the

2000 Conference on Ion Chemistry and Mass Spectrometry January 28 - 30, 2000

UCLA, Conference Center Lake Arrowhead, California Seonghee Ahn One Shields Avenue Department of Chemistry University of California Davis, CA 95616

(530) 752-5504 FAX (530) 752-8995 sahn@ucdavis.edu Jay Amicangelo 315 S. 1400 E. RM Dock Department of Chemistry University of Utah Salt Lake City, UT 84112-0850

(801) 581-7901 FAX (801) 581-8433 jamicang@chemistry.utah.edu Joseph Anderson C100 Benson Science Building Department of Chemistry Brigham Young University Provo, UT 84602-5700

(801) 378-5383 FAX (801) 378-5474 jdanderson@chemdept.byu.edu Laurence Angel Department of Chemistry/216 University of Nevada Reno, NV 89557-1339

(775) 784-1339 FAX (775) 784-6804 angel@chem.unr.edu

Peter B. Armentrout 315 S. 1400 E. RM Dock Department of Chemistry University of Utah Salt Lake City, UT 84112-0850

(801) 581-7885 FAX (801) 581-8433 armentrout@chemistry.utah.edu Alexander Artau 1393 Brown Building, Box 484 Department of Chemistry Purdue University West Lafayette, IN 47907-1393

(765) 494-7359 FAX (765) 494-0239 aartau@purdue.edu Daniel Austin Department of Chemistry 127-72 California Institute of Technology Pasadena, CA 91125

(626) 395-6543 FAX (626) 585-9021 austin@caltech.edu Jack Beauchamp Department of Chemistry 127-72 California Institute of Technology Pasadena, CA 91125

(626) 395-6525 FAX (626) 568-8641 jlbchamp@cco.caltech.edu Patricia Beauchamp 4800 Oak Grove Drive

8Jet Propulsion Laboratory Pasadena, CA 91109

(818) 393-0529 FAX (818) 393-4773 pbeaucha@pop.jpl.nasa.gov Summer Bernstein Department of Chemistry University of California Santa Barbara, CA 93106

(805) 893-2673 FAX (805) 893-8703 summer@gaucho.ucsb.edu Martin K. Beyer Department of Chemistry University of California Berkeley, CA 94720-1460

(510) 642-0701 FAX (510) 642-9295 m_b@uclink4.berkeley.edu Veronica M. Bierbaum Department of Chemistry Department University of Colorado Boulder, CO 80309-0215

(303) 492-7081 FAX (303) 492-5894 veronica.bierbaum@colorado.edu Michael T. Bowers Department of Chemistry University of California Santa Barbara, CA 93106

(805) 893-2893 FAX (805) 893-8703 bowers@chem.ucsb.edu John Bushnell Department of Chemistry

University of California Santa Barbara, CA 93106

(805) 893-2673 FAX (805) 893-8703 bushnell@chem.ucsb.edu Catie Carpenter Department of Chemistry University of California Santa Barbara, CA 93106

(805) 893-2673 FAX (805) 893-8703 carpenter@chem.ucsb.edu Xin Chen Department of Chemistry Stanford University Stanford, CA 94305-5080

(650) 497-3410 FAX (650) 725-0259 chstar@leland.stanford.edu Heather Cox Department of Chemistry 127-72 California Institute of Technology Pasadena, CA 91125

(626) 395-2778 FAX (626) 585-9021 cox@its.caltech.edu David V. Dearden C100 Benson Science Building Department of Chemistry Brigham Young University Provo, UT 84602-5700

(801) 378-2355 FAX (801) 378-5474 david_dearden@byu.edu Moses Dogbevia Department of Chemistry/216

9University of Nevada Reno, NV 89557-1339

(775) 784-1339 FAX (775) 784-6804 dmoses@chem.unr.edu LaVone Dyer One Shields Avenue Department of Chemistry University of California Davis, CA 95616

(530) 750-1013 FAX (530) 752-8995 clstasik@ucdavis.edu Kent M. Ervin Department of Chemistry/216 University of Nevada Reno, NV 89557-0020

(775) 784-6676 FAX (775) 784-6804 ervin@chem.unr.edu Jonathan Flad Department of Chemistry Stanford University Stanford, CA 94305-5080

(650) 723-4332 FAX (650) 725-0259 jflad@leland.stanford.edu Jennifer Gidden Department of Chemistry University of California Santa Barbara, CA 93106

(805) 893-2673 FAX (805) 893-8703 gidden@chem.ucsb.edu Susan Graul Department of Chemistry

Carnegie Mellon University Pittsburgh, PA 15213

(412) 268-1441 FAX (412) 268-1061 sgraul@andrew.cmu.edu Gabriela Grigorean One Shields Avenue Department of Chemistry University of California Davis, CA 95616

(530) 752-5504 FAX (530) 752-8995 ggrigore@ucdavis.edu Ron L. Grimm Department of Chemistry 127-72 California Institute of Technology Pasadena, CA 91125

(626) 395-6543 FAX (626) 578-0471 grimm@caltech.edu Eric Handberg C100 Benson Science Building Department of Chemistry Brigham Young University Provo, UT 84602-5700

(801) 378-5383 FAX (801) 378-5474 jdanderson@chemdept.byu.edu Fei He Center for Interdisciplinary Magnetic Resonance National High Magnetic Field Laboratory Tallahassee, FL 32306-3006

(850) 644-1319 FAX (850) 644-1366 he@magnet.fsu.edu Brian T. Hill 1393 Brown Building, Box 484

10Department of Chemistry Purdue University West Lafayette, IN 47907-1393

(765) 494-7359 FAX (765) 494-0239 hill@purdue.edu David K. Hill Department of Chemistry University of California Pierce Hall # 1423 Riverside, CA 92521-0403

(909) 787-3657 FAX (909) 787-4713 dkhill@ucrac1.ucr.edu Jun Hu Department of Chemistry University of Akron Akron, OH 44325-3601

(330) 972-5343 FAX (330) 972-7370 jhu@chemistry.uakron.edu Anthony T. Iavarone 409 Hildebrand College of Chemistry University of California Berkeley, CA 94720

(510) 642-6240 FAX (510) 642-8369 spin_forbidden@yahoo.com John Jurchen 409 Hildebrand College of Chemistry University of California Berkeley, CA 94720

(510) 642-6240 FAX (510) 642-8369 jurchen@uclink4.berkeley.edu Joel M. Karty Department of Chemistry

Stanford University Stanford, CA 94305-5080

(650) 723-0316 FAX (650) 725-0259 jkarty@leland.stanford.edu Katherine A. Kellersberger C100 Benson Science Building Department of Chemistry Brigham Young University Provo, UT 84602-5700

(801) 378-5383 FAX (801) 378-5474 kakeller@chemgate.byu.edu Paul Kemper Department of Chemistry University of California Santa Barbara, CA 93106

(805) 893-2673 FAX (805) 893-8703 kemper@chem.ucsb.edu Hilkka Kenttämaa 1393 Brown Building Department of Chemistry Purdue University West Lafayette, IN 47907-1393

(765) 494-0882 FAX (765) 494-0239 hilkka@purdue.edu Harvey Lardin 1393 Brown Building, Box 484 Department of Chemistry Purdue University West Lafayette, IN 47907-1393

(765) 494-7359 FAX (765) 494-0239 lardin@purdue.edu Michael Leavell Department of Chemistry

11University of California 8 Lewis Berkeley, CA 94720

(510) 642-0701 FAX (510) 642-9295 mleavell@pequoid.cchem.berkeley.edu Carlito B. Lebrilla One Shields Avenue Department of Chemistry Department University of California Davis, CA 95616

(530) 752-6364 FAX (530) 752-8995 cblebrilla@ucdavis.edu Jun Liu One Shields Avenue Department of Chemistry Department University of California Davis, CA 95616

(530) 752-5504 FAX (530) 752-8995 juliu@ucdavis.edu Philip Mayer Department of Chemistry University of California Pierce Hall # 1423 Riverside, CA 92521-0403

(909) 787-3657 FAX (909) 787-4713 pmayer@citrus.ucr.edu Bob Moision 315 S. 1400 E. RM Dock Department of Chemistry University of Utah Salt Lake City, UT 84112-0850

(801) 581-7901 FAX (801) 581-8433 moision@chemistry.utah.edu Thomas Morton Department of Chemistry

University of California Pierce Hall # 1423 Riverside, CA 92521-0403

(909) 787-4735 FAX (909) 787-4713 morton@ucrac1.ucr.edu Felician Muntean 315 S. 1400 E. RM Dock Department of Chemistry University of Utah Salt Lake City, UT 84112-0850

(801) 581-7901 FAX (801) 581-8433 fmuntean@mail.physics.utah.edu J. C. Poutsma 801 Stuart Circle College of William and Mary Williamsburg, VA 23185

(757) 221-2548 FAX (757) 221-2715 jcpout@wm.edu Colleen K. Regan Department of Chemistry, Box 57 Stanford University Stanford, CA 94305

(650) 723-0316 FAX (650) 725-0259 ckregan@leland.stanford.edu Jianhua Ren Department of Chemistry Stanford University Stanford, CA 94305-5080

(650) 723-0316 FAX (650) 725-0259 jhren@leland.stanford.edu Mary T. Rodgers 5101 Cass Avenue, 33 Chemistry

12Department of Chemistry Wayne State University Detroit, MI 48202

(313) 577-2431 FAX (313) 577-8822 mrodgers@chem.wayne.edu Sae Young Shin 315 S. 1400 E. RM Dock Department of Chemistry University of Utah Salt Lake City, UT 84112-0850

(801) 581-7901 FAX (801) 581-8433 saeyoung@chemistry.utah.edu Lee Sunderlin Department of Chemistry Northern Illinois University DeKalb, IL 60115-2862

(815) 753-6870 FAX (815) 753-4802 sunder@niu.edu Frantisek Tureček Department of Chemistry Department Box 351700 University of Washington Seattle, WA 98195-1700

(206) 685-2041 FAX (206) 685-3478 turecek@chem.washington.edu Petra vanKoppen Department of Chemistry University of California Santa Barbara, CA 93106

(805) 893-2673 FAX (805) 893-8703 petra@chem.ucsb.edu Sarah N. Ward C100 Benson Science Building

Department of Chemistry Brigham Young University Provo, UT 84602-5700

(801) 378-5383 FAX (801) 378-5474 smeibos@yahoo.com Paul Wenthold 1393 Brown Building Department of Chemistry Purdue University West Lafayette, IN 47907-1393

(765) 494-0475 FAX (765) 494-0239 pgw@purdue.edu Evan R. Williams 409 Hildebrand College of Chemistry University of California Berkeley, CA 94720

(510) 643-7161 FAX (510) 642-8369 erw@socrates.berkeley.edu Yongsheng Wu Department of Chemistry Stanford University Stanford, CA 94305-5080

(650) 723-0316 FAX (650) 725-0259 yswu@leland.stanford.edu Ronald Wysocki Vicki Wysocki Department of Chemistry University of Arizona Tucson, AZ 85721-0041

(520) 621-2628 FAX (520) 621-8407 vwysocki@u.arizona.edu Thomas Wyttenbach Department of Chemistry

13University of California Santa Barbara, CA 93106

(805) 893-2673 FAX (805) 893-8703 wyttenbach@chem.ucsb.edu Yongming Xie One Shields Avenue Department of Chemistry Department University of California Davis, CA 95616

(530) 752-5504 FAX (530) 752-8995 yxie@ucdavis.edu Qiang Zhang Department of Chemistry University of California Santa Barbara, CA 93106

(805) 893-2673 FAX (805) 893-8703 qzhang@chem.ucsb.edu Xiao-Guang Zhang 315 S. 1400 E. RM Dock Department of Chemistry Department University of Utah Salt Lake City, UT 84112-0850

(801) 581-7901 FAX (801) 581-8433 xgzhang@chemistry.utah.edu