1S¿ďŘÇGƟƀŸÿ�ƤƟƀŸŻƖƛƋźƥžƝƣŘōšŘ� ƇƥƃظÊļťśChemTHEATREŔAIST-MeRAMŘå:'Ê�\ w1ƨ� l/2 ƨÖĝ6k3ƨTğą�4ƨ3îĖ«5ƨKğ��6ƨA�Ě�1

1 uPKS ¶]ÇGØSÔÛƁƣƃƥ 2 ɦ|ðè:ÔÛz 3 AÜÇGÔÛz ÇG�fÔÛƁƣƃƥ4 IJ�^KS ²ÉSĝ 5 �»KS �êÔÛħì¾ØSá 6 !eÒÜKSKSħ žƖƛơƥžƝƣSÔÛØ

Chemicals in the THEATRE (Tractable and Heuristic E-Archive for Traceability and Responsible-care Engagement)

ŖŋChemTHEATREľqõĽƪ

�RŘ1S¿ďŘÇG�¼dŗĤňŨtEřƨSðĊ�ĸŨĹř�ϬĤŘE<�ŔņŒĩQ1ŅũŒ

ĹŨŢŘŘƨŌŘŞŔŬŕřƆŷƀƈƏŭŰƠţųŸƁƠƏŭŰƠŔņŒ�RŅũŒĹŨŗęŀʼnƨƙƇƟƣŹ

ţƟƀŸù�ūïĺ�œřĿŪšŒ�ĹŗŁĹjhŗŒýġŅũŒĹŨĴ±�H0ÔÛţK±´ ÔÛŗ°

ŝŒCÅöªŘ1S´ Ř�¹ľKĿŁėũŒĹŨŘřƨ�¹ƙƇƠŘ�+Ƈƥƃţ¥þ��ŗŖŧpŨ

ƙƋƃƟƣŹƇƥƃľ��ŅũŒĹŖĹĽŦœĸŨĴŃŘťĺŗJİŘÔÛĎū~ŇŒpŦũōčĞŖÔÛx

�ľ2�$ŗ¸ÊŅũŒĹŖĹŘřKĿŖ�LœĸŨĴŃũŦŘčĞŖtEūZ�ŗŪōŐŒ�.¸Êň

Ũōšŗřƨ³ÊsŘıĹƇƥƃƒƥƀا߾qĮŘĈįœĸŨĴ

ŌŃœƨ2016bdťŧƨÇG�Ř1S¿ď¼dŗĤňŨtEū�Æņƨ�.ŗ¸ÊňŨōšŘƑƞƄƈƏŴƥƗاßŗÓ{ņōĴyĵřƨŃŘƑƞƄƈƏŴƥƗūĶChemTHEATREķƦźƗžŮƃƥƧŔ;�łƨĸŦŤŨ1S¿ďŘƙƋƃƟƣŹtEū7ġƤĥøœĿŨƇƥƃƒƥƀū¢ŔņŒƨ7ġtEū8÷1ļťśù�

ňŨƅƥƠūWòņōűŲƐ�ŘƑƞƄƈƏŴƥƗŘ*#ūÐ�ņŒĹŨĴ

2018b10�2�şœŗ73ƑƢſŲŸƈƦĺŏ68ƑƢſŲŸƈľĊ�Ƈƥƃƨ5ƑƢſŲŸƈľŵƥƑƣƇƥƃƧūÎġņƨ�ĢņŒĹŨĴ

ÈvƟƀŸÿ�ŜŘČÂ

ñÄƘƇůŮŔŘĕ�ŗťŨx�Ĝ�

ơƀƔƣžƐƠƤźŮ

Ø Èv¯sƇƥƃƒƥƀŔŘĕ0

Ø 1S¿ďŘƈơƥżƎƟƆůūÕ�Ø �ÅöªœŘ�ĪĠ$a�¹

Ø ƇƥƃŘ8÷1ƦúũŨCÅƧŗťŨx��Ģ

Ø ŵƥƑƣżŰųƣƀ1

Ø ô=Ř�ÊƤg¤ŗ�ĺÇG�ŜŘ�#Ġū}�ňŨ

Ø ÇGƤ�fŜŘƟƀŸƤU�sŗĤņŒƨē�sŘıĹtEĢ×ūïĺ

• źƗžŮƃƥƦChemTHEATREƧ http://chem-theatre.com/• ³ÊÈvƟƀŸÿ�ÞÆƅƥƠƦAIST-MeRAMƧ https://meram.aist-riss.jp/• uPKSÈ¿ÇGĀ�ƍƣŸƦes-BANKƧ http://esbank-ehime.com/dnn• 1S¿ďÇGWvĉ¡ƫ1S¿ďŔÇGƫ http://www.env.go.jp/chemi/kurohon.html

�ÔÛř��1S_¦4 LRIÝ6�NüÔÛŔņŒW�ŅũŒĹşňĴ

参照サイト �

�������������

1S¿ďŘsÁţƌŽƥƉƤ¯stEŖŕū7ġņōŘƇƥƃƒƥƀŔChemTHEATREūĕ0ŅŊŨŃŔŗťŧƨıàdĽőē�sŘıĹ1S¿ďŘƟƀŸÿ�ľ�nœĿŨ [1–4]ĴÄÁœřƨƇſƃƠŮƥŶŰƐŅũōÇG�1S¿ď¼dŘƇƥƃƁƄƈœĸŐŒŢƨÇG0vūù�Ƥ8÷1ňŨŗřJKŖŨ-+ūõ

ňŨľƨChemTHEATREŘ'ÊŗťŧÑ+1ľ8ëŔŖŨ�ƨ1S¿ďö(Ř�âŘ.�¥þļťś���¹ŗŢrÊ8ëœĸŨĴÇGÑľW�ņŒĹŨ1S¿ďÇGWvĉ¡Řä�řPDFƏŭŰƠœŘŠŘ�ĢŖōšƨƇƥƃūĐŃņŒChemTHEATREĽŦŘ�ĢūĢMņōĴ

Concentration

Experimental method

Sample info

Cross-referenceØ "����Ø ���

����!� ����

• ����• �����• ��# ��# �������

�������# �

%���&"�$!�%HQ&=�������%PEC&/������%PNEC&%���&��������%EPAF&= ∫ * + ,,- + .+∞

0

����������

ŵƥƑƣƇƥƃ

Ƈƥƃū�jņŒÎġ

ChemTHEATREūĔŇŒ�Ģ

Îġ

ÎġƇƥƃū¸ÊņŒƟƀŸ�V

ÇGÑŘĶ1S¿ďŔÇGķƨĹŪŤŨij�ƇƥƃŘĺŏ²ŔcďŘƇƥƃūĭ­Ē,�Ĵ

ÇG�¼dŘW¹�ƒƥƀœŘƟƀŸÿ�ľ8ëŗĴMeRAMœŌŘşşćŠđšŨjhœŘ¼dƇƥƃųŸƀƔƥƈ¬ëūĒ,�VĴ

Field Ć� �+ĬÐ W�

ProjectID āiňŨƑƢſŲŸƈŘID Ę>�œ�+ PRA000020

ChemicalID $�Yċ1:¿ÚŘID Ę>�œ�+ CH0000277

ChemicalName $�Yċ1:¿; Ę>�œ�+ Diclofenac

OfficialMethod �V· �V·ľĸŨF:řƨŌŘ;ÙŔID No

Extraction �#· Solvent, LLE, SPE/SPME, Soxhlet, PSE/ASE SPE

Extraction_details �#·ŘĂã Solvent, Cartridge, Gel, Shaking, Homogenization, Sonication, etc. Cartridge

Cleanup ŸƟƥƣŮƄƑ· LLE, Deproteination, Alkali saponific, Filteration/ultrafiltration, Chromatography

Filtration

Cleanup_details ŸƟƥƣŮƄƑ·ŘĂã Solvent, Acid, Alkali, Filter, Cartridge, Gel, etc. Filter

Derivatization Ą[�1 Ą[�1Āíƨ�ÊņŖĹF:řNone None

Chromatography ŸƢƕƈŹƞƏůƥ GC, LC, IC, TLC, Other, or None LC

Detector ¥#? HRMS, Q-MS, MS-MS, IT-MS, Tof-MS, Tof/tof, Q-tof, FID, ECD, or Other MS-MS

Ionization Űŵƣ1 EI, NCI, PCI, FI, ESI, APCI, APPI, MALDI, or Other ESI

Standard ©º= Āí;Ù Diclofenac sodium

Recovery_correction @7Ãó® @7Ãó®Ř�½Yes or No Yes

Calibration ŷƚƟƐơƥžƝƣ 1. External calibration, 2. Internal calibration (isotope dilution method),3. Matrix-matched external calibration, 4. Standard additions

2

LOD/MDL ¥#�Ħ� �� 0.65 ng/L

LOQ/MQL VĠ�Ħ� ��

Intra-day precision �"H0 �� 0.83%

Inter-day precision �ģH0 ��

Recovery_CRM ©ºĀ�Řăþ�ŔŘ` ��

Recovery_spike_relative "ĝ©ºœó®ņōoŘ©Ï¿ďŘ@7à �� 90 ± 0.81%

Recovery_spike_absolute "ĝ©ºœó®ňŨ)Ř©Ï¿ďŘ@7à ��

Recovery_IS "ĝ©ºŘæY@7à �� 80 ± 6.8%

ƇƥƃƕŰƋƣŹœřƨù�ŗ�ÊňŨƇƥƃŘďţĠľŌŘù

�ä�ŗKĿŁmīňŨĴChemTHEATREŗÎġŅũōƇƥƃřJ¨ŖƂƥƀË�ŘŢŘœĸŨōšƨƂƥƀńŔŗƇƥƃŘďřÌŖŧƨ

ƇƥƃƕŰƋƣŹŗ'ÊňŨĨŗřƨƜƥŽƥŘÐÏŗ:ŪŊŒ

Ƈƥƃūě&ňŨqõľĸŨĴŌŘōšŘŚŔőŘ%�DºŔņŒƨ

$�·ŗĤňŨtEū¼dƇƥƃŔŔŢŗ7ġňŨŃŔūÍ£ņōĴ

9ñřƨ$�·ŗĤňŨƆƥƐƠŘ5£ŔƨWĨŗChemTHEATREŗÎġŅũŒĹŨƑƢſŲŸƈƦPRA000020ƧœŘſŸƢƏŲƊŸŘ$�·ŗĤņŒtEū�+ņōW�œĸŨĴ

Z�Ïŗřƨ�+ŅũōƇƥƃŘ"Xŗ,Ļƨ�ĢŅũŨtEĠŢ

YċŗƀŻŮ1ņƨƇƥƃŘďūƞƣŸ�łňŨŃŔŢ¥ûņŒĹŨĴ

Ā�tEŘƆƥƐƠŢƨO�ńŔŗRBňŨÀÌÏŖtEŗőĹ

ŒŢÎġ8ëŖťĺŗ�®ņōĴŔŁŗƨij�ĉ¡ţC�ìµIľW

�ňŨƙƋƃƟƣŹĉ¡ä�œ�ĢŅũŒĹŨtEřçéœĿŨ

¨ŔņōĴĂãřhttp://chem-theatre.com/sampleĽŦĀ�ŘĂãtEƓƥſŗŒÕăņŒĹōŎĿōĹĴ

ñƩ$��·ļťśàdŗĤňŨtE

© 2016 DBCLS Togo TV / CC-BY-4.0

Licensed under a Creative Commonsñ×4.0AĨƞŰƁƣƀ(c) 2018 �\ wƦuPKSƤ¶]ÇGØSÔÛƁƣƃƥƧ