100268 - united states environmental protection agency · 100268 note: for calcium, magnesium and...

-, ENVIRONMENTAL PROTECTION AGENCY - HWl Sample Management Oifloa'. Box EiS - Alexandria, Yirj&inla 22311 - 703; S57-2490/FTS-8-557-2490

NO.INORGANICS ANALYSIS DATA SHEET

,O • C"T- &/0!T~ 3i

LABORATORY NAME &co< ( \Tp ft H > OJfcfi* /Jo.

LAB SAMPLE ID NO.________________ QC REPORT NO. I

TASK I (EkntentirtobaldsitHIcdcftime&aaed)'___ og/kgj-f'jzr — ~ —w —•» ^g_ j i - *Cclrcle one) circle one)

!• Aluminum yt&_________ 10. Nickel2. Chromium f 3> _________ H. .Manganese3. Barium ______ M 12. zinc

I3. Boron /v/I>Cadmium ____ |0>> U. Vanadium

6* ..Cobalt ______ fJ!> 15. Calcium 527". Copper ____ R3> ___________ 16. Magnesium8. l£22_____fb^___________ 17. Sodium______9. Lead_____yjT^_________

OTASK 2 (Element* to be identified and measured)

=P ~ og/kg Ofi/lx&r .ag/kgttScleone) ' Circle one)

I- Arsenic_____\\$ ______•• 5. Mercury2. Antimony___tA^_______ 6. Tin1. Selenium____t^^___________ 7. Silver ____Wjv. ThaUtu.-n____^S>___.____•

<"*' • 'TASK 3 (Elements to be identified and measured)

1.2,3.

Bg/l Of' Og/kg .(circle one)

AmmoniaCyanideSulfide

For IFB WA

*. Fluoridc5. pH6. TOC

80-C087 ONLY

mg/i or rag/kg' Units

ng/ 1 oc «as/kg

100268NOTE: For Calcium, Magnesiumand Sodium, report values in

or mg/kg.

u TAL PROTECTION AGENCY - HTH Sample Management Office. Alexandria, Virginia 223 13 - 703/ S57-2490/FTS-8-557-24SO

ORIGINALINORGANICS ANALYSIS DATA SHEET

PLABORATORY NAME

LAB SAMPLE ID NO.________________. QC REPORT NO.

TASK 1 (Element? tojto teitfflcd asrf rasasuradi)'

2. Chromium _____ fJ ________ II. Manganese3- Barium fJ > .12, Zinc

BeryUlum ijb 13. Boron

1. Arsenic ______ f</I> ________ 5. Mercury2. Antimony ^1. Selenium A -'*. Thalliu.Ti fs/O .

6. Tin7. Silver ft/I)

- < • .TASK 3 (Elements to be identified and measured)

SAMPLE' NO.-

ng/ks « j - « eg/kgircle one) Utrcle one)

1. Aluminum »Jt> ' 10. Nicke! tJ

S. Cadmium _____ rJ S> ________ U. Vanadium ____ »JD6* ..Cobalt _______ (J ________ 15. Caldum B . T-T. Coppo- ______ M ________ 16. Magnesium 5 -s ^ > **?/*<•• ii«i « Bi i*w <pM iMdUA

8- £22 ______ ^ _________ 17. Sodium 6.1 b"Lead ,

.TASK 2 (Elements to be Identified and measured) __

/ug?or tag/kg ' ftl* °S/J8m^ieone) ' Tcircle one)

i.2,3.

n

rag/i or ing/kg(circle one)

AmmoniaCyanideSulfide

For IFB WA 80-C087

ft. Fluoride5. pH6. TOC

ONLY

mg/1 or ng/kg

Unitsing/l or njj/kg

COMMENTS:

NOTE: For Calcium. MagnesiumAnd Sodium, report values InOK/ I or rog/kg.

.cKi'AL PROTECTION AGENCY - HOT Sample Management Office. - Alexandria, Virginia 22313 - 703/557-Z490/FTS-8-5S7-249Q OsBofc

jLABORATORY NAME

LAB SAMPLE ID MO.

*

L AluminumL Chromium5. Barium*. Beryllium3. Cadmiumfi. ..Cobalt7. Copper8. Iron9. Lead

Q

I. Arsenic2. AntimonyJ. SeleniumV. Thalliu.-n

1. Ammonia2* Cyanide3. Sulfide

nr»r »r| UK:r SAfPL.E

INORGANICS ANALYSIS DATA SHEET < ; -7^

fj2>& n/W ////r6- cAfefi? *Jo. l^c-QC REPORT NO. 1

TASK 1 (Efenveflf? to ba ideating €7*4 intttsurttd'-

Ve-Tfr

-

.

tcScleMe) NcTrcle one)M*> I0t Nickd jj*J3> If* • Manganese Co'1'J2* .12. Zinc N S|J£> 15. Boron . WS>|JJ> 14. Vanadium N) >»J 15. Calcium 3C.o (mg/l> ««J5> 16. Magnesium ?2.g < i>*r,

V S"0 17. Sodium T.I.O r LJf'*rii5 ^ _

TASK 2 (Elements to be Identified and measured)/*igZl'-i?r DK/kR • x<S£ZLs^ * wfc iwft/ Twfj C{ frfxCJTCffcle one) * **"

W5 5. Mercury fJ-3\J > 6. Tin f JI>Nl" 7. Silv*r C»LOKB>

* ^

TASK 3 (Elementi to be identified and measured)

IclrclVone) For IFB WA 8°-C087 «««

*. Fluor tdc m8/l o5. pH

**1/M

»1/*1

^A7

Jt eg/kg.e one)

Units6. TOG m«/l or n«/kg

/"~\ ———————————————————————————— ———————————————————————————————-COMMENTS:

NOTE: For Calcium, Magnesium . 10027$and Sodium, report value*} InOK/ I or rag/kg.

«tf EWTA1, PROTECTION AGENCY - HOT Sample Management Office.4. Alexandria, Virginia 22313 - 703;557-2490/FTS-8-557-2490

,0 • -INORGANICS ANALYSIS DATA SHEET 'c

SAfPL.E' NO.

LABORATORY NAME Q>c<i \M~tJ Pr fi*- CA^& tJo* flC

LAB SAMPLE ID NO.________________ QC REPORT NO. _]. •

TASCl (Etenentstojba fefeatifted andJfw ly/Gt tng/ks*vctecle one)

1. Aluminum_____y»^>_______ 10. Nlckd2. Chromium _____ KS> ________ 11. Manganese3* Barium _______ »3$> • 12. Zinc

Befyllium f > 13. BoronCadmium ______ OJ> _____ l«. Vanadium.Cobalt _______ £Z> 15. CaldumCopper ______ £J5 16. Magnesium M.Sg

8* Iron _______ t> 17. Sodium9. Lead

TASK 2 (Elements to be idsntttied and measured)

TASK 3 (Elements Co be identified and measured)

one) * one)•

K Araenlc _____ t^b ________ 5. Mercury _____ t/ 5> ___________2. Antimony ____ tJ\> __________ 6. TinJ. Selenlu.-n _____ i ___________ 7.'*. Thalliu.-n

iag/1 or mg/kg.{circle one)

1. Ammonia2. Cyanide3. Sulfide(

For IFB WA 80-C087

*• Fluoride5. pH6. TOC

OKLY

mg/i or mg/kg

Unitsmg/1 or njj/kg

*

100271NOTE: For Calcium, MagnesiumAnd Sodium, report values Inrax/1 or rag/kg.

-MENTAL PROTECTION AGENCY - HWl Simple Management Office4g - Alexandria, Virginia 22313 - 703; 557-2490/FTS-8-557-2490 T&OutJA

ORIGINAL SAhPLE* NO.-INORGANICS ANALYSIS DATA SHEET ^^ed) nc-|T7

)LABORATORY NAME

LAB SAMPLE ID NO._

1. Aluminum2. Chromium3. Barium4. Beryllium5. Cadmium6. .Cobalt

Q c JJlTrO VU ^ C4 ^ A-to. I~1COC REPORT NO. /

TASK 1 (Eismcnte to%ba idcntlQsd end roeaaawO* *

" IrS[e"one) MSEcle one)/°S> 10. Nickel tJ DH 11. ' Manganese fJ sh* . 12. Zinc /e4 13. Boron . N> C >/J^ JA. Vanadium f 5>r7 15. Calcium A' < 7£2- A«j

T. Copper f£> 16. Magnesium /J *£s/LJf **1/*18* Iron9. Lead

O

1. Arsenic2. AntimonyJ. Selenium4. Thalli'j.-n

1. Ammonia

^5>s)J

17. Sodium tf& « A~3r ** / 7

TASK 2 (Elements to bo Identified end measured)

^ icleone)8 ? * C ir5e one)5

H3> • 5. Mercury ft*3>H >M-2>

TASK 3 (Elements to bng/1 or mg/kg•(circle one)

2. Cyanide3. Sulfide

COMMENTS:

6. Tin A/*>7. Stlv-r rJ- >

e identified and measured)

For IFB WA 80-C087 ONLY

*. Fluoridc r>8/1 oc mR^R5. ?H • Units6. TOC rag/i or ns/kjj

100272NOTE: For Calcium. HagnesluraSodlun. report values In1 or mg/kg.

(Red)

INORGANICS QUALITY ASSURANCE

QC REPORT KEY;

Case §

Sanple § HC "_nc -

nc -O 6 -

n

CONTRACT REQUIRED DETECTION LIMITS;

Task I; Al SO i >0 Task II; As 10f,,«/iv Cr i8 o-o i n* Sb 20P9/ } Ba " « r-o Cvg/1) Se 10

Be .- -2- Tl 10Oi 5 Hg -f 2Go Ifr 5° Sn 26 5-0CXi 23 sT° Ag 20Pe 30 JT°Ni 26 .00 Task III: HH3 0.1Kn 10- S-o (mg/ll ^ J-J_Zn 10 L °'05B in oo . Cn 0.01y J5 0 F« within 0.1 pH unitsCa 1000 TOG 2^ - 100 .Ka 1000

(1) Spike less than 10 percent of sample concentration.(2) loss of analyte during digestion procedure resulted in

low recovery; analyte is volatile.(3) Detection limit raised due to sairple matrix interference;

actual detection limit is bracketed ( J. lA*J»yOSanple interference precluded analysis. A JO 2 73Results reported in brackets „( 1 reflect values calculatedbelow required detection limits; however, above instrumentaldetection limits.

?£§*— -. Q ----'—••»«-ik i K ••• ** i

f> r C'I • s i n - E*. i w as l n — _

!2i* 5 I s a i r S51 r is i * s

5 2 Rli ml 11 !(P 11! IJiIiKlilifeiiiikiifsTSK t f

\v\ i i i i *-i iw i i i i i i i i i i i i i . _t/1 1 1 1 1 m i i.rnrnrftitm+H+-u-4-4-LJJ I I II I MS 0" II I I I II I I II II ,

V

|.

Q iimrtnl i lw"'"''''"LL"'''-' sf|S(T]TnTrH44 U4-i4miJLa i PI i mlie

ORIGINAL

100276

INORGANICS QUALITY ASSURANCE !r5(Red)

o

CASE;?: l"7C.

= OF SAMPLES- "1

1AR. ti>CJC«< Mf M P

IINITIAL CALIBRATIONVERIFICATION

II.CONTINUINGCALIBRATIONVERIFICATION

...

III.DUPLICATESAMPLE RESULTS

IV.SPIKED

' SAMPLE RESULTS

•

"

-)_-,.

Lt* - BATCH S? :

REFERENCESTANDARD

SOURCE:,. — .

BLANK VALUEPREPARATIONBLANK 1PREPARATIONBLANK 2STANDARDSOLUTION I

SOURCE?

STANDARDSOLUTION 2

SOURCE:

STANDARDSOLUTJON 3

. . SOURCE;•STANDARDSOLUTION 4

SOURCE!

DUPLICATE!

SAMPLE MO H^M

DUPLICATE 2

z&ufirtta•

SPIKE 1

SAMPLE N0.*2~_r^

SPIKE 2

SAMPLE NO. ___

1

ul-S-'

•FOUND

TRUEv ecprti/CDV

RESULTS

RESULTS

RESULTS

FOUND

TRUEX RECOVERY

FOUND

TRUE

X RECOVERY

FOUNDTRUE '

X RECOVERY

FOUND

TRUEK RECOVERY

SAMPLE RESULT

DUPLICATE RESULT

RPOX

SAMPLE RESULT

DUPLICATE RESULT

RPDX

SAMPLE RESULT

SPIKE RESULT

SPIKE ADDED

X RECOVERY

SAMPLE RESULT

SPIKE RESULT

SPIKE ADDED

V RFttWPRY

TASK ll/COLD VAPORATOMIC ABSORPTION

HitoAl)

7*/&

_»

Mb

A/k

Mti1.1-1

100277

mtman

4>

i

P «ONMENTAL PROTECTION AGENCY . IfWf Sample 1III, Alexandria, VA 1211) * tt)/U>-OSS5

ORGANIC* ANALYSIS D/

ORIGINAL(Red)

Maryi emcfjt Off Ice t)&$*\rt(?i(]&P&t!O9

.BORATORV NAME PEDCo ENVIRONMENTAL, INC.

LAB:OCR

21 A22A24 AJIAJ«A57A58 A5*A

J>45A

IB5BtB>BI2B(IB»B!5BKB!7B*SBo<B70• *^™

va

SAMPLE ID NO. BX965AC, BX965BN

£PORTNO.r 1

CfD COMPOUNDS

2,*tC- trichlorophcnotD-chlor o-m-cre sot2- chtorophenol2.4-dichIorophenoI2,*- dimethylphenol2- nitre-phenol*> nltrophenol2,*- dinltrophenol%,6- dinhrO'O'Cresolpentachlorophenolphenol

EASE/NEUTRAL COMPOUNDS

•cenaphthenebenzldine1,2,*- trichlorobenzenebe xachlorobenzenebe xachloroe thaneb!s(2-chf oroe thyDether2-chloronaphtliatene••c dichlorobenzeneIj9*>o!chlorobcnzene1 §' "dichfof obcnzervc5 f"dichlofoboftzldir>c

> 2,4-0tnItroto!uefte2.6- tfinltrotolueM1,2- djplcnylh/dfazlne

_(a* atoScnrcftc)ihiorjinttcnc

UJ/J

N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.

N.D.

N.D.

N.D.N.D.

. N.D.N.D.N.D.

N.D.N.D.

N.D.N.D.N.D.

N.D. 'N.D.

N.D.N.D.


*JB 4-bromophenyl phenyl ether*26*3B?2B)B5«B?**KB4IBC2B»BKB*7B«B(SB70B7IB72B71B74B75B7<B77BytBT BIOBSIBS2R•in

bis (2*chlorofe0propyl) etherbis (2-chIoroethoxy) methanehexachforobutadienenexachlorocyctopentadieneitophoronenaphthalenenitrobenzeneN-ft!trosodimethyIam!neK-nltrosodiphenyla mineN-nltrosodi-n-propylamlnebis (2-ethyIhexyI) phthalatebutyl benzyl phthalatetfi-n-butyl phthalatedl-n-octy! phthalatediethyl phthatatedimethyl phthalatebenzo(a)anthracenebenzo(a)pyreneSjt-benzofluoranthenebenzo(k)fluoranthenechrysene•cenaphthytcneAnthracenebenzofehDpcrylenefluorene 1 ' P97 »phcnanlhrcncdtbcniioCa.hUntltracenelndcno( 1 ,2,l«cd)pyrene


N.D.N.D.N.D.N.D.K.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.

N.DN.D.N.D.

N.D.N.D.

N.D.

ORIGINAL

<^J ORGAMCS ANALYSIS

~ Sample NiKnkcr

DATA SHEET • P^c 1 «™17C"3 ———————

^ MORATORY NAME J»EDCo ENVIRONMENTAL, INC.

LAB SAMPLE ID NO. „ BX965 V, BX965 Feet

OC REPORT NO. r 1

IVIV»V;v'VovIVJY«V5V^WJVJV)V»vIVVVVVVVV

VVV•M

VfV

VOLAT1LES

•eroleln•crylonltrllebentenecarbon tetrachloridechlorobenzene(2-4ichIoroe thane,t, Mr ichloroethane,t-dichloroethane.1 ,2-tr ichloroethane

- ,I,2,?-tetrachIoroeth»ne— fhloroethane

2-chIoroethyIvInyI etherchloroform1 . 1 *dichloroethy Icne1.2-trans-dichIoroethyIeneI ,2-<5ichIorof>ropanel.5-dichloropropyleneethylbentenemethylene chloridemethyl chloridemethyl bromidebromoformtfichforobromomethanetrkhlorofluoromethanedlchlorodlfluoromethaneCfvtorodlbromomethane

LJftrachloroethylenetoluenetftChlorocthvlenevinyl dtlorlde

Vt/l

KDNDND.NDNDKDKDKDKD

NDNDNDNDNDNDNDKDND

NDNDNDNDNDNDNDND

NDNDND

ND

PESTICIDESI9P AldrlnK»P tfietdrlnflP chlortfane' f2P *.*«-DDTtIP 4.*'-DDEf *P M»-DDDt P «cndosu1fanKP -endosulfant7P cndosulfan tulfate>SP *ndrlnf9P endrin aldehydeIOOP heptachlor10 IP heptachlor epoxldeJ02P .6HC103P HCJ04P »6HCI05P -EHCIOCP PCB-1242I07P PCB-I25(fJOSP PCB-122!709P PCB-1232HOP PCB-I248HIP PCB-1260 .II2P PCB-IOU ••I UP foxaphene

D10XINS

1295 2,9,r,S-tetracMoro4ibcf. D-dloxIn•Less than 10 ug/1

&nNDKDKDKDKDKDKDKDKDKDKDKDKDfcDKDKD

KDKDKDKDKDKDKD

NDND

ao. 100*79ND

ORIGINAL(Red)

ORGANICS ANALYSIS DATA SHEET - Pioe 3PEDCo Environmental ________ _____ ________.

Simple NumberReport No._____1_________________;________ i?c-3

A. SURROGATE SPIKE RESULTS

COMPOUNDPentafluorobenzene

Dg-PvridineI>5-Nitrobenzene2-Fluorobiphenyl

2-FluorophenolD«-Phenol

?—F1 »ofoHiphf»ny1

FractionVOA

B/KB/NB/N

*

ACAC

PE

Cone. (ug/1)99.2

9.146.442.2

22.752.2

NO

(Surrogates only)&pUe

Added (us /I)97.2

110.8105.6120.8

103.2162.0

Recovery102

84435

2233

r~\ B. TENTATIVELY IDENTIFIED COMPOUNDSV>

1.2.3.4.5.6.7.8.9-10.11.12.13.o15.16.17,18.

CAS f

1609-10-516747-30-11927-69-154004-40-952414-91-25364-83-0103-65-1

17851- 5-54316-65-8517-25-9764-42-167-64-1430-51-3565-69-5

COMPOUND NAME

3-Bromo-Pentane2 , 4 , 4-Trimethyl-Hcxane2- (1, 1-Diroethylethoxy) Tetranyciro- H-pyran3-Methyl-2-Propyl-l-Pentanol4-Ethyl-S-Methyl-Thiazole( 1-Propeny 1 ) -CyclohexanePropyl-Benzenesassssss ropy xescer-x * <c-iienzene-

3,5. 5-Trimethyl-l-HexencTrinitro-Me thane(E) -2-Butenedinitrile2-Propanoncl-Fluoro-2-Propanone2-Methyl-3-Pentanone

FractionAC

ACACACACAC

ACENBN

VVVVV

Fit875823877712836898892820896821800930791906.

local1

J.$. ENVIRONMENTAL PROTECTION AGENCY • 1 (Wl Sample 1\CXpk III, Alexandria, VA 22919 * W/m-Om

-x ' ORGANIC5 ANALYSIS D/1.; ( \ - _.,. — ,. ---

MawuLemrnl Office /)cn AtWS)&$feiwa.Ni«nber

«_.t60RATORY NAME PEDCo ENVIROKKENTAL, INC.

LAB SAMPLE ID NO. BX966AC, BX966BN

OC REPORT NO. , 1

2IA22A24A9IAS«A57A52A59A<OA40 A«0

IB5BSBfB12BIIB20B25B2CB27B2IB95B

•

»yn• •— ion

CID COMPOUNDS

2,*.€- trlchlwophcnole-chloro-m-cre»ol2- chlorophenel2,* -dichlor ophenol2.*- dlmethylphenof2- nltropheno!t> nitrophenol2,*- dinltrophenol•,€- dinltro-o-cresolpentachlorophenolphenol

BASE/NEUTRAL COMPOUNDS

•cenaphthenebenztdineJ,2,»- trichlorobenzenehe xachlorobenzenehe xachloroe thanebis(2H*loroethy|>elher2-chIorona phtltatene1,2-dichlorobcftzcneI.VdichlorobcnztneIt4-dichlorobcnzencI3'«d!ch!orobcnz!dine2,*- dtnltrotoJuefte2,t- dtnltrotolucne1,2- dipdcnjrth/dratlnefa« ozobcnr.cftc)Ihifirontlicnc4- dilorojrf««nvl Dfyfivl -tftr

UJ/1

NDNDNDNDNDNDND

NDND

NDND

NDNDNDNDNDNDNDNDND

NDND

NDND

NDNDND


* I B *>bromophenyl phenyl ether*2BOB

- 52B5IBKB55BKBCIBC2BOB£€B€7B(SBC9B70B71B72B7)B74B75B76B77BTIB79BSOB

. SIB«*VI3f\

•* .

bis (2-chIorot$opropyI) etherbis (2-chIoroethoxy) methanehexachlorobutadienehe xachlorocy clopentadienebophoronenaphthalenenitrobenzeneN-nltrosodimethylamlneN-nltrosodiphenylamlneN-nltrosodi-n-propylamlnebis (2-ethyIhexyI) phthelatebutyl benzyl phthalatedi-n-butyt phthalatedi-n-octyl phthalatediethyl phthalatedimethyl phthalatebenzo(a)anthra cenebenzo(a)pyrenel.l-bcnzofluoranthenebenzo(lc)fluorantheneehrytene•cenaphthylcneanthracenebenzofehDperytenefluorcnc

_phcnanlhrcnc 100dibeftrota.hkntliraccncIndcnoCl ,2,l-cd)py rcncpyrcne

t*/l

r:DKDKDKDKD1>T»KDKDKDKDKDKDKDKDKDKDKDKDKDNDKDKDKD

KD •NDKD

281 ,*>NDND

V&

,,-t. ___

OMSGIfJAl

ORGAN1CS ANALYSIS

(rr.i Tampie"

fkAYA ClirfTT , tTk*r — J-'C~*

Number

-.b^ATORYNAMEPEDCO ENVIRONMENTAL, INC.

AB SAMPLE ID NO. BX966 Y« BX966 Pest•C REPORT NO. , i

VOLATTLES

/ acroleln/ •crylonltrllef benzene/ carbon tetrachloridet chlorobenrene>V ,2-dichloroethaneV .I.Utrichloroethane-V tl-dichloroethaneV ,1,2-trfchIoroethtneV .1,2,2-tetrachforoe thaneV -ghloroe thaneNT Wi<h!oroethylvlnyl etherV chloroformV l.l-dich!oroethyfeneV 1.2-tran*-dichloroethyleneV I,?-6*ich!oropropaneV |,9-<5ich!oropropyleneV ethylbenzeneV methylene chlorideV methyl chlorideV methyl bromide/ bromoform/ cnchlorobromomethine/ trlchloroflooromethane/ tfichlorodlfluoromethane/ chlorodlbromomethane/ tetrtchforoethylcne/ J>!uene/ trfchtorocthylene/ vinyl diforlde

i«/l

JNDNDNDNDNDNDNDNDNDNDNDNDND

NDNDNDND

NDNDNDND

NDNDNDNDND

NDNDND

PESTICIDES

S9P aldrln•OP dleldrin•IP chlordanenP 4.*'-DDTnP *.i'-DDEt«P t.r-DDDf5P *endosu!fan•6P *endosu!f&n97 P endosulfan sutfttetSP endrin99P endrin aldehydeIOOP heptachlor10 IP heptachlor epoxldeI02P .BHCI03P -BHCIOQP »fcHCI05P .BKCIO£P PCB-1242I07P PCB-125Q10SP PCB-1221I09P PCB-123?HOP PCB-1248JIIP PCB-12W .1I2P PCB-lOIt •'•IIJP toxaphene

QlOXtNS

I29B i t-tetrachlorodibenxo.e-dloxtn

•Leu than 10 ux/l

og/lNDNDNDNDNDNDNDNDNDND

NDNDND*NDNDNDNDNDNDNDNDNDNDND

ND

ND

.p.ctr.1 criteria *"but »ot Rt criteria.

.. „»*

ORGANICS ANALYSIS DATA SHEET - Page 3PEDCo Environmental

I Sample Number17C-4


COMPOUNDPen t a f 1 uoroben zenev

D«|-PyridineDj Nitrobenzene5— Fluorobiphenyl

2-FluorophenolDg-Phcnol

5— P5 uftT>r»b$ph'*i"iy5

FractionVGA

B/NB/NB/N

ACAC

PE

Cone, (ug/1)92.6

3.844.244.5

20.342.1

NP

(Surrogetes only)Spike

Added (ug/1)97.2

110.8105.6120.8

103.2162.0

tRecovery95

44235

2026

B. TENTATIVELY IDENTIFIED COMPOUNDSJ1.2.3.4.5.6.7.8.9.10.11.12.13.M.>JJt16.17,18.10

CAS f

1942-42-317851-53-51634-04-42987-06-6589-34-4

54986-61-717851-53-5131-16-8

13475-78-024071-57-6122-79-2

COMPOUND NAME

2 , 3-Dimethyl-Trans-CyclobutanoneButy 12-Metnyipropyj.ester- 1 , 2-t>enzene-dicarboxvlicacid2-Methoxy-2-Methyl-Propane4- (Phenylmethoxy)-Cyclohexanone3-Methyl-Hexane5-Methoxy-i- ipnenylmethyl) -In-benssi-midazol-4-OLBv»tyl2-Met]?ylpropyiester-x , z-aenzene-DiprQpylester-1 , 2-Benzenedicarboxyli-

5-Ethyl-2-Methyl-Heptane1 , l-Dibromo-2-CftJ.oro- -i'iuoro-uycxo-propanePhenylester-Aceticacid

FractionAC

ACACACACBNBN

BNBN

VV

1002)

Fit788

770818856841832942762899967836

o

H ENVIRONMENTAL TROTECTION AGENCY • ItVJ Sample 1£ltex III, Alexandria* VA 22113 * ttJ/tD-MS*

Q ORCANICS ANALYSIS D/

LABORATORY NAME PEDCo ENVIRONMENTAL, INC.

LAB 2QCR]

21 A22A24A91 A34 A57AJSA59A«OA

». ,

IB5BSBfB12BIIB20B25B26B27B2IBJ*B

*u,I/O

*&n

AMPLE It) NO. BX966ACD, BX966BND

EPORTNO. i

ftCID COMPOUNDS

2.4,6- trichlorophcnolp-ch!oro-m-cre*ol2- chlorophenol2.4 -dichlorophenol2.4- dime thy Iphenol2- nltrophenol*> nltrophenol2.4- dinltrophenolt,€- din!tro-o-creso1pentachlorophenolphenol


•cenaphthenebenzidine1,2,4- trichlorobenzenehexachlorobenzenehexachloroethineb!s(2-chloroethy!)e ther2-chIoronaphtIialene1 ,2-dichIof obcnrcncl,J-d7chforobcnzcr»e1.4 •dichlorobcnzenc*•* '"CicW orobonztdi nc2,4.d!nltrotoluene2.6- tfinttrotolucfte1,2- dipfcnylhydrttlne

huoranttcnc4-€*iliroiil «J

U£/l

NDNDNDND

NDNDNDNDNDND

ND

NDNDNDNDND

NDNDNDNDNDNDND

NDND

2JD—

ORIGINALHarwi mcnl Olfle^^^.

LTA ttirrr . ,D.uPlicate

17C4-B/N Duplicate17C4-AC Duplicate

£L•r

EASE/NEUTRAL COMPOUNDS l*/l

• IB t-bromophenyl phenyl ether ND42B*3B

' ?2B33B54B55B5€BCIB(2B63BKB€76MBC9B70B21B22B23B24 B23B2 BW 9 CV

fA Ej

wTf Cv

IOBSIBI2AI3Htin

bis (2-chtoroIsopropyI) etherbis (2»ch!oroethoxy) methanehexachlorobutadienenexachlorocyclopentadieneisophoronenaphthalenenitrobenzeneK-n!trosodimethylam!neN-nltrosodiphenylamineN-nltrosodi-n-propyIam!nebis (2-ethyIhexyl) phthalatebutyl benzyl phthalatedi-r»-txjtyl phthatatedi-n-octyl phthatatedie thy 1 phthatatedimethyl phthatatebenzo(a)anthracenebenzo(a)pyrene3*4 -benzof luoranthenebenzoCkHluoranthenechrysene•cenaphthylcne•nthracenebenzotthDpcryleneiluorcnc -i A A o fl phcnanthrcncdibenfoCa.hUntliraccneindcnoCl ,2,3«J)pyrcftcpyrcne

NDKDNDNDNT)NDNDKDKDND*

KDKDNDNDKDKDKDKD-NDKDKDKDKD

KDKDKD

KD~KD

ND

ORIGINAL ______(Red) Sample Number

•"•

f, -v_____________ORCAN1CS ANALYSIS DATA SHEET.Page 2 • Duplicate^•O= . =^RORATORY NAME PEDCo EKVIRONHENTAL, INC. 17C3-VOA Duplicate

LAP SAMPLE ID NO. BX965 VD, BX967PEST Pup. 17C5- Pest Duplicate

3C REPORT NO.

0VIVsv*v5V

.l.l»trichloroethane ______ND f>P

CVQdiloroethane ______________ 2P_ »9P endrin •IdehydeND

3V l.?-tr«nt-dlchtorc>cthylene ______ Np_ IQ3P »BHC>V i.?-dicMoropropane NDIV 1.5-dichloropropylene ND |0?P >BHCJV ethylbeotene ND J06P PCB-124?,V methylene chloride ND I07P>V methyl dilor ide • ND I08P PCB-1221;V methyl bromide ____________ ND^ I09P PCB-I232

V trkhlcrofluofomethtne ND U2P PCB-IOI6ND

V cMorodlbromomcthtne ________ NDV tctrachlofoethyleftc N QIOXtNS

tftehlorocthylene ND p-dloglnV vlnjr! dilor Ide _____ ; _______ ND ^eu than 10n . (ocktlcidcft leu than 5 (£/!)> Peak cet »•• «pectr*l criteria

VOLATHES jig/l PESTICIDES

IV •croleln______________ KD t»P •Idrin________________NDIV acrylonUrlle______________Np_ fOP dietdrln_______________ND\\ bentene________________ND f JP chlordanc______________ND;V orboo tctr^chloride_________ND . • f?P ».*'-DDT___________ ND*V chlocobentene_____________ND f3P ».»'>DDE______________ND

,2-dichloroethane___________ND fftP ^.^^DDD_______________ND

,l"tfichloroe thane__________ND f6P «endosulfan ND,1,2-trlcMofoethine_________ND^ f7P endotulfen tulftte _ _ ND,lt?t?-tetr>chlof0€thar>e ______ND fSP endrln _ __._ ND

7V g-dilofoethylvlnyl ether ________ ND^ JOOP hepttChlor ______________ ND}V chlofotorm ______________ ND_ IOIP heptaehlor epoxlde ND9V l.l-dichloroethylene ND IQ2P >BHC

'V bromoform ____________ ND HOP PC6-l?ftE _____________ _KD' "

ND UP PCB-1760 .

ORGANICS ANALYSIS DATA SHEET - P«ge 3flame PEPCo Environmental ____m_______._________

PReport No..imple Number

17C3 Duplicate


COMPOUNDPenta f 1 uoroben zene

-

D5-Pvridinep^ -Nitrobenzene2-Fluorobiphenyl

2-FluorophenolP -Phenol

_2— PI uofohiphpny'

FractionVOA

B/NB/NB/N

*

ACAC

PE

Cone, (ug/1)90.4

025.12ft. 7

36.972.7

ND

(Surrogates only)£pike

Added (i/s/1)97.2

110.8105.6i3»n.R

103.2162.0

JRecovery

93

024•>&

3645

B. TENTATIVELY IDENTIFIED COMPOUNDSJ

1.2.3.4.5.6.7.8.9.10.11.12.13.VV16.17r18.10

CAS f

•

-

.

COMPOUND NAME

•

.

Fraction FU

100

—

286

. t^WONMENTAl;««JTJCTK>N AGENCY • IfWI Sampfe Marw^emcnt Off Ice XL* /. P^^•.fo< til, Aletandrla, VA 2«1J . 70>/tU-OtS5 * * nmrirfi&5%$*p:. &C££l' K MJ, M\ >. j fSnjpjeNumber

LABORATORY NAME PEDCo ENVIRONMENTAL,

LAB SAMPLE ID NO. BX967AC,

X REPORT NO. 1

ACfD COMPOUNDS

'1A 2.4.6- trichlorophcnol•2A p-chloro-m-cre$ol'4 A 2- ChlorophenolI A 2.4-dichforophenol•4 A 2.4- dimethylphenol7A 2- nltrophenol8 A *- nltrophenol9A 2,4- dinltrophenolOA 1.6- dinhro»o»cresol4 A pentachloropheno!5A phenol


B ftcenaphthene5 benzldineB 1.2,4- trichlorobenzeneB hexachlorobenzene2B he xachloroe thaneSB bh(2-chforoethyt)ether5B 2-chloronaphtliatene5B l«2*dichlorobonzcneSB liVdichlorobcnzenerfi til-dlchlorobcnzeneIB J.V-dicWorobcmzldincSB 2,4-dinltrotolueneiL -2,6- dinttrotoluenerO 1,2- di>!cftythydr«t!nc

(as azobcnrcnc)1l\ Irufirontlcmc<!L. A- £»!«L9J!'«!nyt frfrtiyj etlrr

BX967BN

UJ/1

N.D.


N.D.N.D.N.D.

N.D.N.T».

N.D.N.D.N.D.N.D.N.D.N.D.

N.D.N.D.

N.D.N nN.n.

XNC.

&ASE/NEUTRAL COMPOUNDS

* IB 4-bromophenyl phenyl ether42B bis (2-chlorolsopropyI) ether43B bis (2-chloroethoxy) methane*

32B nexachlorobutadiene33 B hexachlorocyclopentatfiene54 B Hophorone33 B naphthalene36 B nitrobenzene(IB N-nltrosodimethylamlne62 B N-nltrosodiphenylamlneC)B N-nltrosodi-n-propylamine«B bis (2-ethythexyI) phthatate67 B butyl benzyl phthalate42 B di-rv-butyl phthalate49 B di-n-octyl phthalate70B diethyl phthalate71 B dimethyl phthalate72B benzo(a)anthracene7JB benzo(a)pyrene74 B 9,4-benzofluoranthene73B benzo(k)fJuoranthene76 B chrysene77 B acenaphthylcne71 B anthracene79 B benzofehDpcfyleneSOB fluorcne lAAOftry• - —— - ———— J-UUiSo?SIB phcranthrcncS2A dlbcnroCa.HUnttiraceneS3fi lr*Jcno(l,2,3-c<f}pyrcr»c•45 yrcrte

WJ/1

N.D.N.D.N.D.N.D.

N.D.N.D.N.D.

N.D,

N.D.

N.D.

N.D.N.D.

N.D.*

N.D.

N.D.N.D.

N.T>-

N.D.

N.n.N.D.N.D.

N.D.

N.D.

W f>

N.n.N.DN. ,_

N.D.t.

.. __ N.D..

/ ORIGINAj

ff|f ORGAMCSpLJ ———————— , . „, . .. , ———— . ————————————————————————— = ————— = ——

ANALYSIS

(Red)

DATA SHEET -f>«je 2

(ample Number17C-5

_.BORATORVNAMEPEDCO ENVIRONMENTAL, INC.

.AB SAMPLE ID NO.. R 7 vr JRY^>C REPORT NO. , i

VOLATTLES

'V acrolelnV ecrylonitrileV benzeneV carbon tctrachlorideV chlorobenzene0V ,2-dichJoroe thaneIV ,1.1-trichtoroethane3V ,1-dichIoroethaneIV ,1,2-trtchIoroethine5V .1,2,2-tetrachIoroethaneSVQphloroethane7V 2-chloroethylvinyI etherIV chloroform'V Itl-dichloroethylene>V 1.2-trans-dlchIoroethytene'V 1.2-dichIoropropaneV l.3-<fichloropropyleneV ethylbenxeneV cnethylene chlorideV methyl chlorideV methyl bromideV bromofcrmV dlchlorobromomethineV trkhlorefluoromethftneV tflchtorodlfluoromethjineV chlorodTbromomethineV etrachloroethyleneV toluene/ trtchforocthyleneV vinyl dtlorldc

7 Pest

Itt/l

NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND.ND

NDNDNDNDND

NIJIfDNDND

ND

PESTICIDESI9P ftldrinfOP tfietdrinfIF chlortfane.f2P I.*»-DDTf3P A. '-DDEfftP M'-DDDt5P «endosulfanf£P •endosulfan97P endosulfen tuUateftp endrin»9P endrin aldehydeIOOP heptachlor101 P heptachlor epoxideJ02P .BHCI03P -BHCI0ft P »BHC105P .BHClOgP PCB-12«2I07P PCB-1254J08P PCB-I221I09P PCB-1232HOP PCB-I24SHIP PCB-1J60 •1I2P PCB-1016 ••1I3P toxaphene

ittfl

1O»~

!OS3!0SDjf-.

10!CS31CKD2 32OKDK3K3

!»T5KDK3K3K3KDK3

DIOXtNS

I29B 2,3lrlt-tctf achlcx-CKfibcfirH {) QQQ £CMfloxtn "O

•Leu than 10 oj/1• Peak act UM-spectral criteria fr»tldcci

ORIGINAL(Red)

ORGANICS ANALYSIS DATA SHEET - Page 3Name .____ PEDCo Environmental_____________________ ———--—-_-_

( N u m b e r17C-5



D5-PvridineDj-Nitrobcnzene.2— Fluorobiphenvl

2-FluorophenolDg-Phenol

_2-PJ «oroh$ phf»nyl

FractionVGA

B/NB/NB/N

•

ACAC

PE

Cone, (ug/1)98.8

58.563.560.5

27.457.6

wn

(Surrogates only)Spike

Added (ug/1)97.2

110.8105.6120.8

103.2162.0

Recovery102

536050

2736

.(IB. TENTATIVELY IDENTIFIED COMPOUNDS^

1.2.3.4.5.6.7.6.9.10.11.12.13.'15.16.17,IB.

CAS f

1927-69-12370-14-154950-56-02177-82-415370-85-1

79-31-228822-73-31072-16-?37148-65-537148-65-537148-65-537148-65-513475-78-06006-01-51620-66-214984-21-522711-21-324071-57-6

COMPOUND NAME2- (l,l-D±metftyietlioxy}Tetranyaro- tt-Pyran2 , 2-Dimethyl-l-Octanol4-Methyl-2-Pentadecyl-l , 3-Dioxolane4-Methyl-Methylester Hexanoicacid2 , 3-D/Pyridazine-5 (6H) -Thione Pyrido2-Methyl-Propanoicacid4-(l,2-Dihydroxyethyi)-, {/)-!, 2-Bpny#»npdiol2, 7-Dimethvl-Octane3,4-5ris7lTrimethylsilyl)U /-,Ti:i-methvIsilv-Benzeneaceticacid Alpha3,4-TriB/(Trimethyisiiyi>oxx/-,xra.-methvlsilv-Benzeneaceticacid AlphaSame As AboveSame As Above5-Ethvl-2-Methvl-Heotane4,!},12-Trimethyl-3,7,ll-Tridecatriene-2,2'- )ithiobis/6- (1 , 1-Dimethylethyl) -4lMP^SyT-PhenolBis (4-Phenoxyphenyl)-Methanone(4-Methoxyphenyl)Phenyl-Ethanedione1 , l-Dibromo-2-Chloro-2-Fiuoro-Cyclo-_pane

FractionAC

ACACACAC

ACACACBNBNBNBN

BNBNBNBNBN\7

Fit892920791827748

842728666847832823827906«W«722861841act

289

ORIGINALU.V£tfVlRONMENTAl PROTECTION AGENCY * I RTf Sample «ahAM>mml Office

US, AfeiantfrlB, VA 2 Ml> . 7*>/tS)-OU* *

17C-6

•..t&OR ATORY NAME , PEDCo ENVIRONMENTAL , INC .

LAB SAMPLE ID NO. BX968AC, BX968BN

OC REPORT NO. 1

21 A22A24A>1AKA57A52 A59A*DA

0

IB>BSBtBI2BJIB20B?»..

276

ftCfD COMPOUNDS

2.4.C- trlchJorophcnoIp-chloro-m-cretot2* chlorophenol2.4-dicMorophenoI2,*- dime thy Iphenol2- nitrophenot4- nitrophenol2,ft- dinitrophenol4,6- dinitro-o-cresolpentachloropSenoIphenol

^ASE/NEUTRAL COMPOUNDS

acenaphthenebenzidine1.2,*- trichforobenzenehexachlorobenzenehe xachloroe thaneb!s(2 hloroe thyOether2-diforonaphtIiaIene1 ,2-dichf orobcnzcneliVdichlorobcnzcoel«4-tfitihtorobenzene

2IB f.f'-tfichlorobcnzfdine***W^170

fvn4011

2,4-dtnItrotoIuefte2,€- tfinltrotolucne1,2- diplcnythydrazlre(as.&zobcnrene)fhifif ontlcnc

N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.

N.D.


N.D.N.D.

N.D.

N.D.N.n.

EASE/NEUTRAl COMPOUNDS

4 1 B 4 -bromophe nyl phenyl ethe r42BOBJ2B>3B54B55B56BilB62 B*3B«B67BiSB49 B70BTIB72B73B74 B75B76B77BTIB79BSOBSIBS25sinpin

bis (2-chIoroIsopropyl) etherbis (2-chIoroethoxy) methanehexachlorobutadienehe xa chlorocy clopenta dienebophoronenaphthalenenitrobenzeneN-nitrosodimethylamineN-n!trosodipheny!amineN-nltrosodi-n-propylamlritbis (2-ethyIhexyI) phthal&tebutyl benzyl phthalatedi-n-butyl phthalatedi-n-octyl phthalatediethyl phthatatedimethyl phthalatebenzo(a)anfhracenebenzo(a)pyrenel,*-bcntofluoranthenebenzo(k)f 1 uoran t he neehrytcne•ccnaphthylcneanthracenebenzoC hOpcrylenefluorcnc *| f)i)&Qftphcnanthrcnodiben»o(a.hhntliracenclndcno(l,2(|.cd)pyrcnepyrcne

N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.D.

N.D.N.D.

N.D.

N.D.N.D.N.D.N.D.N.D.N.D.N.D.N.n.N.D.

N.D ——

N.D.

._H.D. -

Jr ORCANICSANALYSIS DATA SHEET . Fa e 2

J. MORATORY NAME PEDCo ENVIRONMENTAL ,ZNC.

ORIGINAL(Red)Sample Number

_.. 17P-6

1AB SAMPLE ID NO. BX968 V, BX968 Pest

OC REPORT NO. , 1

VOLATILE*

2V acroleinIV acrylooltrlleIV benrene5V carbon tetraehloride'V ehlorobenreneiOV ,2-dichIoroethaneIV ,1,1-trichIoroethane3V ,1-dichIoroethane4V ,I,2-trichIoroeth*ne5V ,1,2,2-tetrachloroethane€O chloroctnane9 2-chIoroethy|vIny! ether3V chloroform9V 1.1-dichloroethylene0V J.2-trans-dichIoroethyIene2V l.2-dichloropropane3V I.J-dichloropropylene8V ethylbenzene«V methylene chloride5V methyl chlorideJV methyl bromide'V bromoformIV dichlorobromomethaneIV trlchiorefluoromethane)V dlchtorodlfluoromethaneIV chlorodlbromomcthaneJV tetrachloroethyrene;V tolocnc7/ trlchlorocthyleneIV vinyl dilorlde

utflND

NDNDND

KDNDNDNDNDNDNDNDNDND

NDNDNDNDND

1 NDNDNDNDNDNDNU

NDNDNDND

PESTICIDES

S9P aldrlnfOP dieldrintip chlordane

• . t2P M'-DDTf3P M'-DDEfftP M'-DDD9>P -endosulfanf6P •endosulfan>7P endosulfan »utfate9SP endrin99 P endrin aldehydeIOOP heptachlorI01P heptachior epoxideJ02P .BHCI03P .BHC104P .BHC105P .BHCI06P PCB-124?I07P PCB-125;JOSP PCB-122II09P PCB-1232HOP PCB-1248IMP PCB- 1260 .II2P PCB-IOI6 ••II3P toxaphene

DIOX1KS

I29fi 2,Vit-tctrachIoro.dloxtn

•Less than 10 us/1m . • • • * **

&4KDKDKDKDKDKDKDKDKDKDKDKDKD•KD

NDKDKDKDKDKDKDKDNDKDND

100291tfibenio-

ND

» Peat «et «a.« .peetr.l criteria <*""*» k« than

OftlGfNALX ORGANICS ANALYSIS DATA SHEET - Page 3 (Red)

Lab' Name PEDCoI Simple

Report No._____1_________________________ 17C-6

. SURROGATE SPIKE RESULTS


Dj-PyridineJig-Nitrobenzene5-Fluorobiohenvl

2-FluorophenolD*-Phenol

^2— Fl urtrohi phf»ny 1

FractionVGA

B/NB/NB/N

•

ACAC

PF

-

Cone, (ug/1)91.2

6.045.741.6

23.555.9

wn

(Surrogates or.l>; ;Spue

Added ( ug/l)97.2

110.8105.6120.8

103.2162.0

Rece.e-*Cf

5 14324

2335 |

B. TENTATIVELY IDENTIFIED COMPOUNDS< s

1.2.3.4.5.6.7.e.9.10.11.12.13.

< i

16.1'f18.

CAS f

5455-24-320812-04-817851-53-56726-50-76006-01-554986-61-717851-53-56137-11-74170-84-74316-65-83790-71-424071-57-61838-59-167-71-0506-77-4565-69-5

107-81-3

COMPOUND NAME

4 , 5-Octanedione2-Butylidene-HydrazinecarbothioamideButyl2-Metfcypr<?pylester-l,2-Benzene-dicarboxvlicacioi4 , 6-DihydroT 3 , 4-Dimethyl-Pyrazoio/ , ±-C/-As-Triazine4 « 8 , 12-Trimethyl-3 , 7 , n-Triaecatnene-nitrile5-Methoxv-l- (Phenylmetnyi) -iti-Benziini-dazoI-4-OLButyl2— Methylpropyiester— x»^— uenzene-

4-Methyl-3-Heptanone( 1 , 1-Diethy Ipropy 1 ) -Benzene3,5, 5-Tr line thy 1-1-Hexene3,7,11-Trimetnyx-, i»,tj-2, 6,10-Dodecat r len- 1-DL1 , l-Dibromo-2-Chloro-2-Fiuoro-L:ycxo-propane2-Propenylester-FormicacidSulfonvlbis-MethaneCyanogenchloride2-Methyl- 3-Pentanone2-Bromo-Pentane

FractionAC

ACACACACBNBNBNBNBN

BNVVV

VV

V

Fit724

704£81£15674£21S4S€45766£55£20SS7514 \

« 554 Jl(fn£iE£0 *

soo 1

L<tNViRONMENTAL PROTECTION AGENCY * IHTJ Sample MartAgcmrnt Office-.«_'••• Af.... U VA»lf% - »At/£tt-Att« *

IMatrix gsi

. AI««*I«, VA row. WWIMIW(Red)

_jU wnwnr«iw^ nr«r»b>iI»L> vr

._.*&OR ATORY NAME PEDCo ENVIRONMENTAL, INC.

LAB;OCR

21 A22A24A31 A34A57A«A39A«OA

*M>4.

IB5B•B9BI2BIIB20B25B26B27B2*B35B3^3/0

IR'L

SAMPLE ID NO, BX968ACMS, BX968BNMS

EPORTNO. 1

ACID COMPOUNDS

2.4,6- trlchlorophcnolp-ch!oro-m»cretol2- thl orophenol2.4 -dichtorophenol2.4- dimethylphenof2- nltrophenol4- nltrophenol2,4- dinltrophenol4,6- djnltro-o-cresolpentachlorophenofphenol

RASE/NEUTRAL COMPOUNDS

•cenaphthenebenzldine1,2,4- trichlorobenzenehe ta chlorobenzenehexachloroethsrvebh(2-chloroethyl)cther2»chforonaphtlialeneI(2-dichtorobcnzcne1, -dJchJorobcnzcneIi4 -diditorobcnzenc3*3>-d1chtorobcnzfdinc2|4- tfinltrotofuene2,6- dtnltrototucfveIg2- dipYtcnyfhydrAzIntCat fizobcnxcnc)uorantlcnc

4)» dtlir tf trt Ji• - • •- «SfL'a5£31)r* J* "inyl ct*cr

WJ/I

K.D.17.4K.D.N.D.N.D.N.D.7.1

N.D.N.D.7.9

21.7

N.D.N.D.34.6N.D.N.D.N.D.N.D.N.D.

N.D.22.5N.D.16.1N.D.

N.D.N.D.

N.D.

i i A »ncc i -

D/N — J. /C~bAC - 17C-6


IIB 4 -bromoDhenyl phenyl e the r42 BOB52B3JB34B35BKBCIB62BOBKB67B(SB^p 7 C*

70 B7IB72B73B74B75B76 B77 BTIB79BSOBSIBS2Rssnt*n

bh (2-chlof olsopropyl) etherbis (2-thIoroethory) methanebejcachlorobotadienehexachforocyclopentadiene{sophoronenaphthalenenitrobenzeneN-n!trosodimethy la mi neN-nhrosodiphenyla mineN-nltrosodi-n-propyUminebis (2-ethyIhexyI) phthalatebutyl benzyl phthalatedt-n-buty) phthalatedi-n-octyl phthalatediethyl phthalatedimethyl phthalatebenzo(a)anthracenebenzo(a)pyrene3.4 -bcnzof luoranthenebenzoCk)fluorantheneChrytcne•ccnaphthylcne•nthracenel*nzofehi)pcrylcnetluorene 100E93phcnanthrcncdibcnr.o(a,hyantliraccncIndorwdAJ pyrcoewrrcnc

•

«l/l

K.D.

K.D.K.D.K.D.K.D.K.D.K.D.K.D.K.D.K.D.28.2*

K.D.2.2

K.D.K.D.K.D.K.D.K.D.K.D.K.D.K.D.K.D.K.O.K.D.

K.D.K.D.

K._D

K.D.

__13.«.

ORCAN1CS ANALYSIS

Viviunir(Red)

DATA SHEET- P<e 2

Jjmplc NumberMatrix Spike

^. MORATORY NAME PEDCo ENVIRONMENTAL, INC. YOA Matrix Spike 17C-5

LAB SAMPLE ID NO.. BX967 VMS

^C REPORT NO. . 1

VOLATIIES

IV acrolelnIV •crylonltrlle»V benzene»V carbon tetrachloride'V chlorobenzene0V ,2-dichIoroeth&neIV ,1,1-trichloroe thane3V ,1-dichIoroethane4V ,1.2-trIchIoroethane5V ,lj2,2-tetrachtoroethanet\"~~*\ chloroetrtane9* 2-chIoroethyIvInyI ether3V chloroform9V ItUdichloroethylene9V 1.2-trans-dichloroethylene2V f.2-6*ichloroprop&neIV I(3-<fichloropropyleneSV ethylbenzene<V methylene chloride5V methyl chlorideW methyl bromide'V bromoformiV rfichlorobromomethane»V trlchlorofiuoromethane)V dichlorodifluoromethane.V chforotflbromomcthane»V tetrachtoroethylene">V -> tolueneIV trlchlorocthyleneIV vinyl diloride

vr.fiNDND

25.7ND

27.8NDNDNDNDNDNDNDNDNDNDND 'NDNDNDNbNDJNL)

NDNDNDNDND

25.1

ND

ND

Pest Matrix

PESTICIDES

S9P aldrlnfOP tfieldrin•IP chlordanef2P li**-DDTf3P 4,*'-DDEf«P *.*'.DDDf5P -endosulfanf€P «endosulfan97P endosulfan tulfate9SP endrin99 P endrin aldehydeIOOP heptachlor101 P heptachlor eporideI02P .BHCI03P HC10<t P -BHC105P .BHCIOCP PCB-12C2J07P PCB-125«»JOSP PCB-122IJ09P PCB-1232HOP PCB-1248II IP PCB-1260 .II2P PCB-101C ••II)P toxaphene

DIOXINS

I29B 2,3l7lt-tctrach!oro

•Leu than 10 ug/{

Spike 17C-3 .

3.883.58NDKDNDNDNDNDNDNDND

4.05NDKDNDKDKDKDKD

NDNDNDNDNDKD

100294rfibcnzo-

> Peak «*t *aa. .pectral criteria feticide.but not RT

Lab Name

ORIGINALORGANICS ANALYSIS DATA SHEET - Page 3 (fte(jj

PEDCo Env^ Y-r»nTn*»n4-_»1

I No. 1Sample Number

Matrix Spa

A. SURROGATE SPUE RESULTS

1

L


Dg-PyriflineDe-Nitrobenzene2" Pluorobiphenyl

2-FluorophenolDf-Phenol

^2—M uorobi phe»nyl. •

FractionVOA

B/NB/NB/N

ACAC

PP,

Cone, (wg/1)90.5

2.640. 834.8

32.365.3

NT>


Added (wg/1)97.2

110.8105.6120.8

103.2162.0

tRecovery93

23929

3140

-. B. TENTATIVELY IDENTIFIED COMPOUNDSJ

1.2.3.4.5.6.7.e.9.10.11.12.13.*.15.16."r18.

' CAS t

•

COMPOUND NAME

•

•

Fraction

i />/ft7 &— A mrfao

Fit

£

. tN3«SONMENTAL PROTECTION AGENCY . IfWI Sample Man««mml Office /? V, ^

. I*oic SIS, Alexandria, VA 22W . 70>/tt)-OSS5 r * -JS£&£<y_.t___nDir-it,,, $An Tc Number

— ————————————— - ————————————————————————————— ; ————— ——tftORATORY NAME PEDCo ENVIRONMENTAL, INC.

-AB SAMPLE ID NO. BX9 6 9AC ,

XT REPORT NO. 1

ACID COMPOUNDS

flA 2.4,6- tricMorophenol7 A e-chtoro-m-eresot'4 A 2- chtorophenolif A 2.4-dichIorophenol4>A 2.4- dimethyfchenot•7 A 2- frftrophenol8 A 4- tkltrophenol9A 2.4- dinltrophenolOA 4,6- dmUro-o-cre»oI4 A pentachlorophenot5/C Jphenol


B acenaphtheneB benzldtneB 1.2,4- trlchlorobenzeneB hexachlorobenzene2B hexachloroethaneSB bls(2-chloroethylktherOB 2-chIoronapht)iaIene5B t.2-dichlorobcnzene6B tif-dichlorobenzene7B |kl-dlchtorobcnzeneSB ).)' !ch!orobenzldinc5B 2,4- tfinltrololucae6f 2.€- dlnltrotolucne70 1,2* dip! icnylhydra zinc. (at azobcrtxertc)

yn huoronttcnc.*.:.. .~ si'iii.'af'jiyfi jKf oyi ctiicr> t ftftk •»«! *U»«B •« ««...n ._i

BX969BN

•«/»"

N.D.

N.D.. N.D.

N.D.N.D.N.D.N.D.N.D.

N.D.N.D.N.D.

N.D.N.D.N.D.N.D.

N.D.

N.D.N.D.N.D.N.D.N.D.

N.D.

N.D.

N.D.

N.D.Nr\

N.D.j.__j _ t .-j

BASE/NEUTRAL COMPOUNDS vt/1

41B 4-bromophenyI phenyl ether N.D.WB bis (2-ch!oroIsopropy!) ether N.D.4)6 bis (2-chIoroethoxy) methane N.D.•52B hexachlorobutadiene N.D.55B hexachlorocyclopentadlene N.D.54 B feophorone N.D.55B naphthalene N.D.56 B nitrobenzene N.D.41 B N-nltrosodimethylamlne v ,62 B N-nltrosodiphenylamine N.D.OB N-nltrosodi-n-propylamine N.D.46 B bis (2-ethyIhexyI) phthalate N.D.67 B butyl benzyl phthatate N.D.4S B di-n-butyl phthalate N.D.69 B dt-n-octy! phthatate N.D.70B diethyt phthatate v.r.21 B dimethyl phthalate v -72B benzo(a)anthracene N.D.73B benzoCa)pyrene N.D.74B 9.4-benzofiuoranthene N.D.75B benzoCk)fIuoranthene N.D.76B ehrytene N.D.

•

77 B acenaphthylene v.r._2S B ainthra cene N . D . _29B benzoCehDperyterte N.D.SOB fluorene N.D.SIB phcrunthrcnc t^O^OG K'~L'-S2fi 4ibcnr.o(a.h)antliracene N. _SJn lndcno(l(2tl-cd)pyrcne N-Di_•4H pyrerte »;.->.

i_ ~.A- +*rn __J^- — *-

V* ORGANICS ANALYSIS 1I ! ————————————————————————————————————————————— - . . ..

vitiwiitrn

fv*TA CtlBtUT t»*.m*. % m.3AT A ariECT • Pa{e Z •

Sample Number17C-7• • • "

. .MORATORY NAME PEDCo ENVIRONMENTAL, INC.

LAB SAMPLE ID NO.. gfl9$? V

DC REPORT NO.. 1

yOLATILES

tV acrotelnIV acrylonltrjle•V bentene;V carbon tetrachloride'V chlorobentene0V ,2-dichIoroethaneIV ,1,1-trichloroethane3V .l-dichloroelhane*V .1,2-trichIoroethane5V ' ,1 ,2f2-tetr»chlor octhane6V "\ chloroe thane7*""* 2-chloroethyIvInyI ether3V chloroform9V l,l-dichloroethylene)V I.2-tran*-dichloroethylene»V 1.2-dlchloropropaneJV 1.3-dIchJoropropyleneIV ethylbenzeneV methylene chloride'V methyl chloride•V methyl bromideV bromoformV dichlorobromomethaneV trkhlorofluoromethaneV dlchtorodifluoromethaneV chlorodlbromomethaneV tetrachloroethyleneV toloeneY trtehlorocthvleneV Vlfiyl ditorlde> Peak *et feats apectral

, BX969 Pest

Itt/l

WDNDND

NDNDNDNDNDNDNDNDNDNDNDNDNDNDND

* "• • ND

ND •NDND

NDNDNDNDNDNDND

criteria

PESTICIDES

I9P aldrinfOP dleldrintIP chtordanef2P %.*'-DDTf3P t.4f-DDEt*P M'-DDD9>P -endosulfanf6P -endosulfan97P endosulfan fulfate9SP endrin99 P endrin aldehydeIOOP heptachlorIOIP heptachlor epoxideJ02P .BHCI03P .BHC104 P .BHCI05P .BHCI06P PCB-1242I07P PCB-1254IOSP PCB-1221I09P PCB-1232HOP PC6-I24SIMP PCB-1260 .H2P PCB-IOIC ••1I3P toxaphene

QIOXINS

I29B 2,3l7l|.tetrachlorodi

•Leu than 10 ug/1

^NDNDKDNDNDNDNDNDNDNDNDKDNDNDNDNDNDNDNDNDND

NDNDND

100237

bcnzo-ND

ro

ORIGINAL(Red)

ORGANICS ANALYSIS DATA SHEET - Page 3Lab Name PEDCO Environmental __ _ ____^

I Sample N u m b e r I17C-7 I



Dg-PyridineD5«Nitrobenzene2— Fluorobiphenyl

2-FluorophenolDg-Phenol

9— FJ iinrofc>iph*»nyl

FractionVOA

B/N

B/NB/N

ACAC

PF

Cone. (ug/1)98.6

50.666.565.9

46.891.7

ND


Added (vg/1)97.2

110.8105.6120.8

103.2162.0

1Recovery101

466355

4557

B. TENTATIVELY I DEKT I FIED COMPOUNDSV

1*

Jr

l.2.3.4.5.6.7.e.9.10.11.12T13.i.

Ik.16.17r18.

CAS f

1634-04-450746-53-716850-00-3

37148-65-555712-48-6629-82-3

52806-37-854965-43-43074-77-93790-71-4625-95-6

52805-95-556908-99-7144-62-7

24071-57-6628-16-067-64-1

109-99-9

COMPOUND NAME

2-Methoxy-2-Hethyl-Propanel-Methyl-2- (2-Propenyl) -Trans-cycio-pentane3-Mercapto-Benzylester-Propionicacid3 , 4-Tris/ (Trimethylsilyl ) O Y/-, Trx-roethylsIly-Benzeneacetlcacid, AlphaAcetate (Ester ) -1 , 2-Benzisotniazoj.e-.i-

1 t 1 • -Oxybis-Octahe(4 1 5-Da.methoxy-2-Metnyj.pneny.u i j, 4-D< m^thovyphenyl ) — Me thanonef. "p-Bisii j 1-DinethyAethyl) -4-wydroxy-, 4-CvcIonexaa:.en-l-One3-Ethvl-4-Methyl-Hexane3,7,11-Trimethyl-, (Z,E)-2,t>,lU-Doae-catrlen-I-OLl-Iodo-3-Methyl-Benzene1,4-Bis {Trimethylsilyl) -IH-Pyrazole3, 4-Bis (Trimethylsilyl) -IH-PyrazoleEthanedioicacid1 , l-Dibromo-2-Chloro-2-Fluoro-Cyclo-prnpanp ———————————————————————1 , 5-Hexadiyne2-PropanoneTetrahvdro-Furan

FractionAC

ACACBNBNBNBNBNBN

BNBNBNBNV

vVVV

Fit766

924892776860921818633886923941857838933

955r^ w&930985

ORIGINAL(Red)

v«\

cj A«"%W«>A

Ta \_fc_ J* c vdc -V

\C it Vvte\< \ oot

Ct C.VWW- o6Q.-NX 0-S C\) - vjitW (v«-( •* 2.)

* ra \

100268 - united states environmental protection agency · 100268 note: for calcium, magnesium and...

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