1 st and 2 nd laws are fundamental unifying principles of thermodynamics energy is conserved heat is...
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1st and 2nd laws are fundamental unifying principles of thermodynamics
Energy is conserved
Heat is a form of energy transfer
Restrictions on the energy transfer
Kelvin statement of the second law:
Second Law of Thermodynamics
There is no process whose only effect is to accept heat from a single heat reservoir and transform it entirely into work.
Clausius statement of the second law:
There is no process whose only effect is to accept heat from a colder reservoir and transform it to a hotter one.
Lord Kelvin (William Thomson) (1824-1907)
Rudolf Clausius (2.1.1822 -24.8.1888)
Hypothetical devices violating the 2nd Law
Alternative Kelvin statement:
Note the careful wording:
Kelvin statement of the second law:
There is no process whose only effect is to accept heat from a single heat reservoir and transform it entirely into work.
x
T=const
V
V0V~V~d
nRTW
0V
VlnnRT
V
Why is this no contradiction
Because: Transformation of heat work is not the only effect (piston moved)
inQ
Note: In a cyclic process engine remains unchanged only
Clausius statement of the second law:
There is no process whose only effect is to accept heat from a colder reservoir and transform it to a hotter one.
Again: A refrigerator accepts heat from a colder reservoir and transfers heat to the hotter reservoir
Why is this no contradiction
Because: This is not the only thing a refrigerator does. It uses electrical or mechanical energy.
Alternative Clausius statement
Michael Flanders and Donald Swan
The First Law of Thermodynamics:Heat is work and work is heat.Very good!
The Second Law of Thermodynamics:Heat cannot of itself pass from one body to a hotter body.Heat won’t pass from a cooler to a hotter.You can try it if you like, but you far better notter,Cause the cold in the cooler will get hotter as a ruler,Cause the hotter body’s heat will pass to the cooler.First law: Heat is work and work is heat.Heat will pass by conduction,And heat will pass by convection,And heat will pass by radiation,And that’s a physical law.Heat is work and work’s a curse,And all the heat in the universe is gonna to cool down,Cause it can’t increase,And then there’ll be no more work and there’ll be perfectpeace.Really!Yeah, that’s entropy man.And all because of the second law of thermodynamics whichlays down that:You can’t pass heat from a cooler to a hotter.You can try it if you like, but you’d far better notter,Cause the cold in the cooler will get hotter as a ruler,Cause the hotter body’s heat will pass to the cooler.And that’s a physical law.Ooh, I’m hot!Hot! That’s because you’ve been working!That’s the first and second law of thermodynamics.
We show with the help of the Kelvin statement that:
All 2-temperature engines accept heat at the hotter reservoir and reject heat at the colder reservoir
Indirect proof:
Contradiction of
(*)
(*): There is at least one 2-temperature engine which acceptsheat from the colder reservoir and rejects heat to the hotter reservoir
Tc
Th
W
Test engine
testhQ
Copperrod
rodhQ =
e.g., by adjusting copper rod
Let’s call it test engine
Tc
Th
W
Test engine
testhQ
Copperrod
rodhQ =
e.g., by adjusting copper rod
Q T
W
Non-Kelvindevice
Since the Kelvin statement rules out the possibility of the device
Q T
W
Contradiction of (*) False
(*) trueAll 2-temperature engines accept heat at the hotter reservoir and reject heat at the colder reservoir
Equivalence of the Clausius and Kelvin statements
Logical structure of the proof of equivalence:
1
2
possibility I
Kelvin-statement
Clausius-statement
true
true
II
false
true
III
true
false
IV
false
false
We show:
Kelvin-statement false Clausius-statement false
Clausius-statement false Kelvin-statement false
The decision between possibility I and IV is made by experimental experience
1 Kelvin-statement false
Clausius-statement false
There is a non-Kelvin engine
Let’s combine this non-Kelvin engine with a heat pump (which we know to exist)
There is a non-Clausius engine