g5.-DEC--?WA A9136 FROt't 6? 27 653?Fe,66 TO 59A9502 P,6?

SAFETYDATA SHEETHARZ{DOUS SUBSTANCE PROCEDURE SHEDT

N,N-T,IMETHYLAItf U,INDAooording to EC Dircctivc 9l/lSSiEEC

F ffitlg Date : l2lttL 200j

l. ldontiffcrtio! ofthc sub$tancelde nlifrcation ofthe productProduct namc I N,N-Din:ethyleniljne

Uee of the substaacelpteparctronChcmical for synthesls

2.Corlpo$tlon/l onmtionSynottyntDirn€thyl sminobenzone

CAS-No.MFormula l{illChemicalformuls

3. H8zard! Id.niincation

on lngrgdlonts

:1Ll.69-7: 12l.lE g/moli CSH1 lNi C6H5N(CH])2

8C-Index-rr-o,ICSC No.RT€CS No.U.l.l. Code

612-016-00-008718x472500

INTUUTIONT Mtf deprcsg the central nervous E stcm (CNS) a.nd decrease the abiliry of thell::1:: ":qel:

o*,s wirh btood hemoerobrn ,. ro,rn ,r",r,**1ioi,rr lrrii an"_'i"r"r,cannor panrcrpatc rn or)gcn llanspon. Sufficienl i:oncentmlion$ oimelhemoslohjll in tbcblood can rcsul( in suffocarion in ihe presencc ot oxygen.

.trr/M CoDtact may cause j}liratior. Skin absorpdon ofN,N-dimcthylnniline may resuh jncyanosis rind CNS dcprcssion.

LYSI Contar* may cause ilritation. product can be rapidlr, abrorbed throtg{r n.uco.'u;mcmbranes eod ski! causiog CNS deprcssitn 6na lypo*i, 1"yan;"j. "

,EC-ZMA A9130 FHll 62 21 6536066 T0 5989562 F.03

,LVGESflOtr'r hEestion will causc hForia and Cr.-S depr€ssion.

SIGNS AND SYMPTOMS: MelhemoglobinemiB can cau$e blu€ coloradon ofrhe Iips, nail bedssr1d cyelids (cyaaosis flom reduced hemoglobin in rhc blood). headache, dizzjrless, weakness,1'ast Iabored breatiing, itcreasad pulse, lcthErg/, Iols of coordinati on, cerdiac arest, com4 anddselh,

MEDICAI CONDITTONS AQORAVATED BY E"YPO-SI/RE| Anemid and orher blooddisardcls,

CJIRO,V/C: Long-lerm cxposMe may advcFely affect the ljve., spleen, kidneys. and blood.

TITRGET ORGANS: BIood, liverj kidneyc. CvS, Cr.vS

4. FirEt Aid Me.sur.,rINH|LAT|OII: kemovc to fresh air, lf brcafiing i6 diffculr, oxyger should be administered bya qualified professiooal. If breathing has stopped, a cerrilicd professiorral shoull givc CpR.Scck immediale mcdisgl ansntion,

.fff,ry: lmmediaEly rcmove contimitrated clothing and ritrse skiD rhorouetrlv with laroeDounts ofwater for at least 15 minutes. Tborowh cleonsing ofenrirc r.intaminaterl arca

inciuding halr, scalg nails, nosEils snd e{ canals, is ofutlnost i&portancc. Ifirritadon persrss,or .xposure is exte$ive or of Long duration, seek medical attention.

tyli: Flush eyes with large amouots of lukcw€.m watcr fhr l -5 minules. IfiEirarioR persisls.$!ek rnedical artention.

,VCESnO:lrrlstedistclyinduc€votnirintsiftictimjsconscious.Vomidngismosrcffqcriveil'induccd wirhin 30 rninures following ilg€sdon. Scck irnmcdjarc nedica.l irtendon.

Nou to Phltician: Blood meticmoglobin if exposure or degre€ ofcyarosis is in do$bt. Avoidaspirin o! €spidnlite pmducts for complaints ofheadaohe. Advise padcnr to avoi,j a.lcohol fo,2': days. ln case ofskin .bsorptio& symptorns rDay be deldyod. M;hernpgobinemia nMyrcquir€ treasnefl wirh methylene blue. Exchango lransfusion may be rcquiired in severe orurucspoltsivE cas€s.

t Fl re-ligbtlng mEssurer&lit4ble e\tinguishlng hed:4; powder, foanL spray \{arer.

Spaclal rlcts: Combustiblc. Formation ofcxpiosi.!€ mixhrrcs possiblc wjth air. Developmdnrof hazardous combustion gascs or vapouls possible in the event gf !ire. Thc following maydelelop iD evenr offilc: nitroged oxid€s.

6. Accidcutal Ralrrre M...ur.rEvacuatr and isolalc hazald a!ca, Deny cntry to ursuthorized and unprotecred iudividtuls.Clcar.tp pcrsoBel should wear penonal protectivc cquipmca! approptale for rhe magnirudeofexpoaule. Ventilare ar€a and stay upwind. .Absorb small spills wirh suilabte ir'tert sorbentrnEtcrial (i.9. Speedy dry, venniculite, etc ) Scoop, sbovel, or s\,veep into cloan, dry tightlyclosed cottailtr fof latcr disposa.l. Absorbcd matdial fu|s larne heal$ and fire haT,ards alploduct, handlc aod dispose arcordingly. Dike largc spills $cll ahead of liquid for later recycleor disposel, Rinsc arca ofspill wkh watcr. Do not allow spillcd producr or clean-up watef,s to

\r gotc! walolwayg aod s€wcrg.

7, l{sldlhg rlld 3torageH rdlirg !Noler Iat safe hatdliag: Avoid ggnglation ofvapours/aercsols. Work ltnde! hood. Do DoLirrhalc substance.

StoragerTighdyclosed.Lnawell"venlilatedplace.AF1Jdegreeto.r.2ide8r€€,.

E. Expoouro con trnolr/p€rrorsl protcctlo!SpealJic c o ntro I. paramc terEC

NameCarci$ogenic i C 3 towitg possible ca.rcioogenic effecb tbr man.

'

Perso nal proteuive e4 uipnent :Proteqive clothing should be selcctcd spccificaUy for lhe working place, depcnding oncoruenbarion and qualtiry oftbe hazardous substance$ handled. The rcsistarce qltlleFotective ol0thing t0 chemic&ls should be asc€rrailcd with the rpspecdvg supp]i€r,

RespiruIory protection rcqdred when vlpours/acrosols arc gcncrarcd. Filter A (acc. toDIN 3181) for vapurs oforganic coorpounds.

Eye prctectioni rc4rkeA

Hand proteclion:In full contact: Glove tBaterial; buryl rubber

Layer thickness: 0.7 mlllEreak*uough timc: >480 Min,

r N,N-Dimerhylaniline

-DEC-2@A 49t37 FRtl'l 52 21 653S5666 IE 59s95A2

In splaih conract: Glwc nrarerial: narural latexLaycr fticknessi 0.6mmBreaktlrowh time: >60 Min.

Explosion limitsii

VapoLE prEssule ,

uPDcr.":, - 7 Vol%,., (2odcSr.t); . 0,s3 hPe

F. @5

PH value 1.:j

At l-2gAI{2O .. ,,r(20 desr€e}: '.1.4viscosity dyndmic . . ilo a.g!€j t.2o mpa"sMctting point':i:, . r . 1.,,:.; : l,... ZIS: L Jc.gre;Boilinfioinr ' : (t0r3 hpd). 192-1ts ;6;;Ignhion remperature . 3?0 ocieeIgnition rempelature .: ,,r ; 3?0 dclEe (DIN5l79a)Flash poinr .: ?5. u"io iofN sits8)

. 85 deorce o c.i ., 'EJI . degree o.c1, o.c.

.1

Relarive vapour'&iuir!(20 dcsr.r). .0.53'. .:.: - t!1Kelalrvevapour'd,onsrly :.i -,4,17,

!*li v i. . . (20 dcgrd) 0.96 gcmlSolubility in ;'.- .,.,..Wsrcr ,... , I20 dggrcc) Li'(lu osgcc) t.2 EJIEthalol iiecly sotubleEthcr ft€ety $olublc

LogPow: : ..,j,.,,., 2.31. : (experimental)

.D..-&Jd OSIJZ l-ld-!'l 62 21 b5Jtbu/:b TO 59tF:5ti2 P.86

10. Slability tEd rercrivityConditior,s to be avoidedStroug hcating.

Subt/4l','ces to be ayoldedOxidizjlg agoDt, acid$, acid haiido!, adydddrs, halogms, nitriles, oirrous acid.

I lazdrdow decompos it io h pr oduct sIn the evcnt offirc

Furthet tnJbnationLight-sensitiveExplesiblc with ah h a vaporous/gaseous sraid.

ll, Toxicological in lnlornstiooAafie todcitt

LCJ0 (inhalation, rat): >5.1 mgil/4 h.LD50 (dcrmal, rabbit): 1700 mg/l..g.LD50 (oral, rar): t 120 Erg&g.LDLo (oral, hrrn€n)j 50 !B/kg.

Spccific symptoms in animal srudies:F,yc hritatio$ test (rabbit)i l"rritaiiolls.Skir ilritsrion tesr (rabbit)r Slighr iritarions.

v Il]9 ]!krln'* d"".i"iilabl€ ro us do nor conform wi$ rhr labclting prrscribed by rhr EC. The!U tus oossrcrl whlch have Dor been published.

g"bact!,e ro lhronic toxici!y

The calsiltogenic potcntiai rcquiles ifther clarifcujon,

Bactcrial murageDicity: Ames &sr: lregative.

Fu het pticologbal infot matiottAffcr irhalatiotr ofvapou.rs/acrosols: Risk of absoFtion,Aftsr skin contsct Rist of absoryrion. Sligh iri:aiion sympton$.Aner eye contact: lrntadonG.Affc! swallowing: Naus€!, vomiting, Loss ofwcighq cj,anosi6, abso.ptiou.

I l-l' ,:ij:,1, 1 '' i;;Aii"r'r II JAkAnrA 'l

,t .. ,' '- '

. -DLC-ZVAA U9rJ2 FREt'r 6? 27 653EE866 '1l] =9d1*2 P.A?

olhcr notes:Th€ following Epllies tc 4romatic a$ines in gcdcrdl: systemic cflect: oethaemoglobinaemia

witl headeche, cerdiac d'$hythnta, droP in blood !r.sstl!e, dyspno"o, aod spasms' pnncipal

symptom: ryarpsis (blue discolgralio[ of tbe blood).

The product should be handlcd with thr care usual whcn d€alilg \"ith chtmicals

I 2. Ecological hiorm{llolrBiologic dogradation.Biodoradation:ro% /28 d Zsl$-Wellens tesr. Easily €liminablc.

Biodegradable.

\1trc[ inuoduccd propsrly, no impaiments in the function of adapted biologieal

wa.ite.qfler-E€au:ent plants arE tir be cxpccted,

Bchavior in ervircnme ntel companments:

Slightly bioaccwnulativi (DCF<30).

Dislribulion: tog p(o/w): 2.3 I (expelimcntal)

No apl,recisbla boatcumulaiiol pstenlial is to be extcotcd (log P(o/w) 1-3).

Ecotoxic effec'ts:Toxic for sque'tic orgenisms. May oause loog_term advclsg eflects in thc aquaric snvironmcnt-

Biological Btrec6:

Fisb toxicity:,P.gomela5 LC50: 65 6 mgn /96 h

Daphoia loxicity: Daphnia magna EC50: 5mgll /48 h.

Algcal toxicity: Desmode$mus sub$picatus lC50: 340 mg/l /96 h

Bactsial roxicity: Pholobcctedunr Phospbore{m EC 50: I ! 6 mg4 130 inin microtox te$!

trlher ccologic dinc:

8OD 10 7o from TOD /5 d; COD 96 9/o from TOD; TODr 2.640 mgg.

Do not allow !o cntgr waters, \ta$e waRr, or sojl!

13, Disposul co$idcrrtiong

Chpmicals mEsl be disposocl of in conlliance with the rcspgglivd national r€8ulatiotls,

Packagiltg,Ploducr packsging flust be disposrd of in comPlidncc with thc country'speci:nc rsgulglions ormust br passcd to a packaging retrtn sy8teF.

F-,:li"i.gg

Ir-DEC-znE A9t32 FR}I 62 21 6$45065 10 59aa54?

14. Trrtr.tDort lntortttstioni*J t"""t1-n e^nn. ruD - LJN 2253 N,N-DII{FTHYLAITLII\' 6 l '

'! ranspon by rivct AND, ADNR not tasted

'Iranspolt by s.a IMDO, GGvSec -lN 2253 N,N'DlMtTlIYLANlLiN' 6 1' nEms 6.1'0

Traosport by air CAO, PAX - N,N'DIMETIIYLAMLIN, 6' 1' UN'- 2253' ll

The traDsro{ reguleti{rns are citc.d according to infeflationdl logul*tian$ and in the form

apqrticatti h G;unsny (GGVSE) Possiblc national dcvisiions ir other coufltries ore not

considered.

15, Regul.torY iolormrdonLalglllng according lo EC Dlrectl\esSvmbol I T Toxic' N DanEerou€ lbr the cnvironmer:l

R-nhrascs: 2tt24/25-4()'51153 Toxic by jnhaladon, in co[racl with skin ajrd ifLimired evidence of a c8rcinogenic effecL Toxic to

aquatic crgtllishs' may cause long-te l everce eilects inthe aqualic envitorunent'

s-nhrases: 28-3613745-61 AJler cooract wilh sKn, wash imoediaeli:wirh plcnry ofwarcr. Weor suitable plcnty of watir. W.qr $uittrblg p$tecdve clothing and gloves ln

cese of acctrtent or ifyou icel unwell, scck medical Ed"icr immcdiately (show the

lab€l whore po6slblg). Avoid rclease to the cnviro[mcnt Refc! 1o lpecitl

instructiontsafety data

shccrs-

EC-No.: 204'493'5

Re&/ced labelling ( I 999/4 S/DC'Ar t. I 0'4)

S\rbol: T Toxic' N Dangcrous ftrt thc cnviroruncnt

R.DhnNes: 23n4D5-40 Toxic by inhrlEtio& in contact taith slin and if' swallowcd, Limited Qvidenc€ of a crtcinogmic effect

EC label

Vf*-^"

aers FRo'r 6221 EE36ec6 TO 59tl95tE P -49

S-phrase$: 36R7-45. Wear suitabte ProEcrive clofiing and glovcs, ln casc ofaccidenror ifyou fe€l unwell, seek melical advice irDmediarely (show the label wherepossible),

llTTfiT.Tn:il,h{iA I

L_ Jr.ian ra J

TOIFL P- @9