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    PRODUCT IDENTITY: BUFFER, Standard and High Accuracy, pH 4.01 CATALOG NUMBER (S): 00654-00, 35654-00, 05942-21, 05942-22, 05942-24, 05942-25, 05942-26, 05942-27, 35653-0EFFECTIVE DATE: 03-20-2006 MSDS NUMBER 00506 Rev 3 Page 1 of 3

    FISHA DE DADOS MATERIAL DE SEGURANA

    Seco 1. Identificao do produto qumico e da empresaCatalogo Numeros

    00654-00, 05942-21, 05942-22, 05942-24, 05942-25, 05942-26, 05942-27, 35653-01, 35654-00Product Identity

    TAMPO, pH padro, 4.01; TAMPO, exatido elevada, pH 4.000 (cor codificada vermelho)Emergency Telephone Number (24 hr)Nome do fabricante

    RICCA CHEMICAL COMPANY CHEMTREC: 800-424-9300Endereo (nmero, rua, cidade, estado e CEP)

    P.O. Box 13090

    Telefone de Informao

    817-461-5601Data preparada

    Arlington, Texas 76094 3-7-2000

    Seco 2. Composio informao sobre os ingredientes

    Percentual

    Componente CAS Registry # Concentrao

    Limites de exposio

    ACGIH TLV OSHA PEL

    Ftalato cido de potssio 877-24-7 0.95 1.05 N/A N/A

    propridade

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    PRODUCT IDENTITY: BUFFER, Standard and High Accuracy, pH 4.01 CATALOG NUMBER (S): 00654-00, 35654-00, 05942-21, 05942-22, 05942-24, 05942-25, 05942-26, 05942-27, 35653-0EFFECTIVE DATE: 03-20-2006 MSDS NUMBER 00506 Rev 3 Page 2 of 3

    FICHA DE DADOS MATERIAL DE SEGURAN

    Section 4. First Aid Measures In all cases, seek qualified evaluation.

    Contato com os olhos: Irriga imediatamente com grande quantidade de gua pelo menos 15 minutos. Chame

    imediatamente um mdico se a irritao se desenvolve.

    INALAO: Remova para ar fresco. -Respirao artificial se necessrio. Se a respirao est difcil, d oxigSKIN CONTACT: Flush with plenty of water for at least 15 minutes. Call a physician if irritation develops.

    INGESTION: Dilute with water or milk. Call a physician if necessary.

    Section 5. Fire Fighting Measures

    FLAMMABLE PROPERTIES:

    FLASH POINT: N/A METHOD USED: N/AFLAMMABLE LIMITS

    LFL: N/A UFL: N/A

    EXTINGUISHING MEDIA: Use any means suitable for extinguishing surrounding fire.

    FIRE & EXPLOSION HAZARDS: Not considered to be a fire or explosion hazard.

    FIRE FIGHTING INSTRUCTIONS: Use normal procedures/instructions.

    FIRE FIGHTING EQUIPMENT: Use protective clothing and breathing equipment appropriate for the surrounding fire.

    Section 6. Accidental Release Measures

    Absorb with suitable material and dispose of in accordance with local regulations.

    Seo 7. Manuseio e armazenamento

    Como com todos os produtos qumicos, lave bem as mos aps o manuseio. Evite contato com olhos e pele. Protege

    contra danos fsicos e congelamento. CDIGO DE SEGURANA DE ARMAZENAMENTO: GERAL

    Seo 8. Controles de exposio proteo pessoal

    ENGINEERING CONTROLS: No specific controls are needed. Normal room ventilation is adequate.

    RESPIRATORY PROTECTION: Normal room ventilation is adequate.

    PROTEO da pele: Luvas resistentes a produtos qumicos.

    PROTEO para os olhos: culos de segurana ou de proteco.

    Seo 9. Propriedades fsicas e qumicas

    APARNCIA:ODOR:

    SOLUBILIDADE EM

    GUA: GRAVIDADE

    Claro, vermelhocolorido lquido inodoro

    infinito

    aproximadamente 1

    pH:PONTO DE EBULIO (OC):

    PONTO DE FUSO (OC):

    PRESSO DE VAPOR:

    4aproximadamente

    100 at

    aproximadamente 0

    Section 10. Stability and Reactivity

    CHEMICAL STABILITY: Stable under normal conditions of use and storage.

    INCOMPATIBILITY: Nitric Acid

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    PRODUCT IDENTITY: BUFFER, Standard and High Accuracy, pH 4.01 CATALOG NUMBER (S): 00654-00, 35654-00, 05942-21, 05942-22, 05942-24, 05942-25, 05942-26, 05942-27, 35653-0EFFECTIVE DATE: 03-20-2006 MSDS NUMBER 00506 Rev 3 Page 3 of 3

    MATERIAL SAFETY DATA SHEET

    HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of Carbon and Potassium.

    HAZARDOUS POLYMERIZATION: Will not occur.

    Section 11. Toxicological Information

    LD50, Oral, Rat: >3200 mg/kg (Potassium Acid Phthalate), details of toxic effects not reported other than lethal dosevalue.

    Section 12. Ecological Information

    ECOTOXICOLOGICAL INFORMATION: No information found.

    CHEMICAL FATE INFORMATION: No information found.

    Section 13. Disposal Considerations

    Dilute with water, neutralize with weak sodium hydroxide solution, and then flush to sewer if local regulations allow. If noallowed, save for recovery or recycling in an approved waste disposal facility. Always dispose of in accordance withlocal, state and federal regulations.

    Section 14. Transport Information (Not meant to be all inclusive)

    D.O.T. SHIPPING NAME: Not regulatedD.O.T. HAZARD CLASS: None

    U.N. / N.A. NUMBER: NonePACKING GROUP: None

    D.O.T. LABEL: None

    Section 15. Regulatory Information (Not meant to be all inclusive - selected regulation represented)

    OSHA STATUS: The above items either do not contain any specifically hazardous material or the potentially hazardousmaterial is present in such low concentration that the items do not present any immediate threat to health and safetyThese items do not meet the OSHA Hazard Communication Standard (29 CFR 1910.1200) definition of a hazardousmaterial.

    TSCA STATUS: All components of this solution are listed on the TSCA Inventory.

    CERCLA REPORTABLE QUANTITY:Not reportableSARA TITLE III:

    SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: No

    SECTION 311/312 HAZARDOUS CATEGORIES: No

    SECTION 313 TOXIC CHEMICALS: No

    RCRA STATUS: No

    CALIFORNIA PROPOSITION 65: Not listed

    Section 16. Other Information

    NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Special Notice Key: NoneHMIS Ratings: Health: 1 Flammability: 0 Reactivity: 0 Protective Equipment: B(Protective eyewear, gloves)

    Rev 1, 10-16-2000: (Section 1) added catalog number 35653-01.Rev 2, 03-25-2003: Reviewed and approved.Rev 3, 03-20-2006: Reviewed and approved.

    When handled properly by qualified personnel, the product described herein does not present a significant health or safety hazard. Alteration of itscharacteristics by concentration, evaporation, addition of other substances, or other means may present hazards not specifically addressed herein andwhich must be evaluated by the user. The information furnished herein is believed to be accurate and represents the best data currently available to usNo warranty, expressed or implied, is made and RICCA CHEMICAL COMPANY assumes no legal responsibility or liability whatsoever resulting from itsuse.

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    Page 1 of 3

    FICHA DE DADOS MATERIAL DE SEGURANA

    Section 1. Chemical Product and Company Identification

    Catalog Number(s)

    00654-04, 35654-04, 05942-41, 05942-42, 05942-44, 05942-45, 35653-02Product Identity

    TAMPO, padro, pH 7,00 (codificado em cor verde)Manufacturers Name Emergency Telephone Number (24 hr)

    RICCA CHEMICAL COMPANY CHEMTREC: 800-424-9300Address (Number, Street, City, State, and ZIP Code) Telephone Number For Information

    P.O. Box 13090 817-461-5601Date Prepared

    Arlington, Texas 76094 3-8-2000

    Seco 2. Composio informao sobre os ingredientesPercentual Exposure Limits

    Componente CAS Registry # Concentrao ACGIH TLV OSHA PEL

    Fosfato de sdio dibsico 7558-79-4 < 1 N/A N/A

    Fosfato de potssio monobsico 7778-77-0 < 1 N/A N/A

    Proprietary < 0.1 N/A N/AConservante(Sem mercrio compostos ou formaldedo)Corante inerte Proprietary < 0.1 N/A N/A

    gua desionizada 7732-18-5 Balance N/A N/A

    Section 3. Hazards Identification

    EMERGENCY OVERVIEW

    Non-flammable, non-toxic, non-corrosive. Does not present any significant health hazards. May cause irritation. Wash

    areas of contact with water

    POTENCIAIS EFEITOS NA SADE:

    RGOS alvo: olhos, pele.

    EYE CONTACT: May cause slight irritation.

    INHALATION: May cause allergic respiratory reaction to those allergic to phosphates.

    SKIN CONTACT: May cause slight irritation to those allergic to phosphates.

    INGESTION: Large doses may cause stomach upset.

    Seo 9. Propriedades fsicas e qumicas

    APARNCIA:

    ODOR:

    SOLUBILIDADE EM GUA:

    GRAVIDADE ESPECFICA:

    Inodoro lquidodesobstrudo, verdeInfinitoaproximadamente 1

    pH:

    BOILING POINT (OC):

    MELTING POINT (OC):

    VAPOR PRESSURE:

    7

    approximately 100

    approximately 0

    N/A

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    PRODUCT IDENTITY: BUFFER, Standard, pH 7.00 (Color Coded Green) CAT. NO (S): 00654-04, 05942-41, 35654-04, 05942-42, 05942-44, 05942-45, 35653-02EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00507 Rev 3 Page 2 of 3

    MATERIAL SAFETY DATA SHEET

    Section 4. First Aid Measures In all cases, seek qualified evaluation.

    EYE CONTACT: Irrigate immediately with large quantity of water for at least 15 minutes. Call a physician if irritationdevelops.

    INHALATION: Remove to fresh air. Give artificial respiration if necessary. If breathing is difficult, give oxygen.

    SKIN CONTACT: Flush with plenty of water for at least 15 minutes. Call a physician if irritation develops.

    INGESTION: Dilute with water or milk. Call a physician if necessary.

    Section 5. Fire Fighting Measures

    FLAMMABLE PROPERTIES:

    FLASH POINT: N/A METHOD USED: N/AFLAMMABLE LIMITS

    LFL: N/A UFL: N/A

    EXTINGUISHING MEDIA: Use any means suitable for extinguishing surrounding fire.

    FIRE & EXPLOSION HAZARDS: Not considered to be a fire or explosion hazard.

    FIRE FIGHTING INSTRUCTIONS: Use normal procedures/instructions.

    FIRE FIGHTING EQUIPMENT: Use protective clothing and breathing equipment appropriate for the surrounding fire.

    Section 6. Accidental Release Measures

    Absorb with suitable material (vermiculite, clay, etc.) and dispose of in accordance with local regulations. Check withlocal agencies for the proper disposal of phosphate containing solutions.

    Section 7. Handling and Storage

    As with all chemicals, wash hands thoroughly after handling. Avoid contact with eyes and skin. Protect from freezing and

    physical damage. SAFETY STORAGE CODE: GENERAL

    Section 8. Exposure Controls / Personal Protection

    ENGINEERING CONTROLS: No specific controls are needed. Normal room ventilation is adequate.

    RESPIRATORY PROTECTION: Normal room ventilation is adequate.

    SKIN PROTECTION: Chemical resistant gloves.

    EYE PROTECTION: Safety glasses or goggles.

    Section 9. Physical and chemical Properties

    APPEARANCE: Clear, green liquidODOR: Odorless

    SOLUBILITY IN WATER: InfiniteSPECIFIC GRAVITY: approximately 1

    Section 10. Stability and Reactivity

    CHEMICAL STABILITY: Stable under normal conditions of use and storage.

    INCOMPATIBILITY: None identified.

    HAZARDOUS DECOMPOSITION PRODUCTS: Phosphorus oxides may form when heated to decomposition.

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    PRODUCT IDENTITY: BUFFER, Standard, pH 7.00 (Color Coded Green) CAT. NO (S): 00654-04, 05942-41, 35654-04, 05942-42, 05942-44, 05942-45, 35653-02EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00507 Rev 3 Page 3 of 3

    MATERIAL SAFETY DATA SHEET

    HAZARDOUS POLYMERIZATION: Will not occur.

    Section 11. Toxicological Information

    LD50, Oral, Rat: (Sodium Phosphate Dibasic) 17 gm/kg; LD50, Dermal, Rabbit: (Potassium Phosphate Monobasic)>4640 mg/kg; details of toxic effects not reported other than lethal dose value.

    Section 12. Ecological Information

    ECOTOXICOLOGICAL INFORMATION: No information found.

    CHEMICAL FATE INFORMATION: No information found.

    Section 13. Disposal Considerations

    Dilute with water, then flush to sewer if local regulations allow for the flushing of phosphate containing solutions. If noallowed, save for recovery or recycling in an approved waste disposal facility. Always dispose of in accordance withlocal, state and federal regulations.

    Section 14. Transport Information (Not meant to be all inclusive)

    D.O.T. SHIPPING NAME: Not regulatedD.O.T. HAZARD CLASS: None

    U.N. / N.A. NUMBER: NonePACKING GROUP: None

    D.O.T. LABEL: None

    Section 15. Regulatory Information (Not meant to be all inclusive - selected regulation represented)

    OSHA STATUS: The above items either do not contain any specifically hazardous material or the potentially hazardousmaterial is present in such low concentration that the items do not present any immediate threat to health and safetyThese items do not meet the OSHA Hazard Communication Standard (29 CFR 1910.1200) definition of a hazardousmaterial.

    TSCA STATUS: All components of this solution are listed on the TSCA Inventory or are mixtures (hydrates) of items listedon the TSCA Inventory.CERCLA REPORTABLE QUANTITY:Sodium Phosphate, Dibasic - 5,000 pounds.SARA TITLE III:

    SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: No

    SECTION 311/312 HAZARDOUS CATEGORIES: No

    SECTION 313 TOXIC CHEMICALS: No

    RCRA STATUS: No

    CALIFORNIA PROPOSITION 65: Not listed.

    PENNSYLVANIA: Sodium Phosphate Dibasic is listed as an environmental hazard on the state Hazardous Substance list.

    Section 16. Other Information

    NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Special Notice Key: NoneHMIS Ratings: Health: 1 Flammability: 0 Reactivity: 0 Protective Equipment: B

    (Protective eyewear, gloves)Rev 1,8-25-2000: (Section 2) corrected concentration of preservative from 1 2 to < 0.1%.Rev 2, 03-25-2003: Reviewed and approved, (Section 15) added CERCLA reportable quantity.Rev 3, 03-20-2006: Reviewed and approved.

    When handled properly by qualified personnel, the product described herein does not present a significant health or safety hazardAlteration of its characteristics by concentration, evaporation, addition of other substances, or other means may present hazards nospecifically addressed herein and which must be evaluated by the user. The information furnished herein is believed to be accurate andrepresents the best data currently available to us. No warranty, expressed or implied, is made and RICCA CHEMICAL COMPANYassumes no legal responsibility or liability whatsoever resulting from its use.

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    FICHA DEMATERIAL DADOS DE SEGURAN

    Section 1. Chemical Product and Company Identification

    Catalog Number(s)

    00654-08, 35654-08, 05942-61, 05942-62, 05942-64, 05942-65, 05942-66, 05942-67, 35653-03Product Identity

    TAMPO, pH padro, 10.00; TAMPO, exatido elevada, pH 10.000 (cor codificada azul)Manufacturers Name Emergency Telephone Number (24 hr)

    RICCA CHEMICAL COMPANY CHEMTREC: 800-424-9300Address (Number, Street, City, State, and ZIP Code) Telephone Number For Information

    P.O. Box 13090 817-461-5601Date Prepared

    Arlington, Texas 76094 3-8-2000

    Seco 2. Composio informao sobre os ingredientesPercentual Exposure Limits

    Componente CAS Registry # Concentrao ACGIH TLV OSHA PEL

    Carbonato de sdio 497-19-8 < 1 N/A N/A

    Bicarbonato de sdio 144-55-8 < 1 N/A N/A

    proprietary < 0.1 N/A N/AConservante(Sem compostos de mercrio ouformaldedo) Corante inerte proprietary < 0.1 N/A N/A

    gua desionizada 7732-18-5 Balance N/A N/A

    Section 3. Hazards Identification

    EMERGENCY OVERVIEW

    Non-flammable, non-toxic, non-corrosive. Does not present any significant health hazards. Wash areas of contact withwater.

    POTENCIAIS EFEITOS NA SADE:RGOS alvo: olhos, pele.Contato com os olhos: Pode causar irritao ligeira.INALAO: No provvel que seja perigoso por inalao.

    Contacto com a pele: Pode causar irritao ligeira.INGESTO: Grandes doses podem causar nuseas, vmitos, diarria e clicas.

    Seo 9. Propriedades fsicas e qumicas

    APARNCIA:

    ODOR:SOLUBILIDADE em

    WATESeo 9.

    Claro, azul cor lquido

    inodoroInfinitoaproximadamente 1

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    PRODUCT IDENTITY: BUFFER, Standard and High Accuracy, pH 10.00 CATALOG NUMBER (S): 00654-08, 35654-08, 05942-61, 05942-62, 05942-64, 05942-65, 05942-66, 05942-67, 35653-03EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00509 Rev 3 Page 2 of 4

    MATERIAL SAFETY DATA SHEET

    REPRODUCTION INFORMATION:

    Reproductive data cited in Registry of Toxic Effects of Chemical Substances for Sodium Bicarbonate and SodiumCarbonate in mice.

    Section 4. First Aid Measures In all cases, seek qualified evaluation.

    EYE CONTACT: Irrigate immediately with large quantity of water for at least 15 minutes. Call a physician if irritationdevelops.

    INHALATION: Remove to fresh air. Give artificial respiration if necessary. If breathing is difficult, give oxygen.

    SKIN CONTACT: Flush with plenty of water for at least 15 minutes. Call a physician if irritation develops.

    INGESTION: Dilute with water or milk. Call a physician if necessary.

    Section 5. Fire Fighting Measures

    FLAMMABLE PROPERTIES:

    FLASH POINT: N/A METHOD USED: N/AFLAMMABLE LIMITS

    LFL: N/A UFL: N/A

    EXTINGUISHING MEDIA: Use any means suitable for extinguishing surrounding fire.

    FIRE & EXPLOSION HAZARDS: Not considered to be a fire or explosion hazard.

    FIRE FIGHTING INSTRUCTIONS: Use normal procedures/instructions.

    FIRE FIGHTING EQUIPMENT: Use protective clothing and breathing equipment appropriate for the surrounding fire.

    Section 6. Accidental Release Measures

    Absorb with suitable material and treat as normal refuse. Small amounts of the liquid may be flushed to the drain withexcess water. Always dispose of in accordance with local regulations.

    Section 7. Handling and Storage

    As with all chemicals, wash hands thoroughly after handling. Avoid contact with eyes and skin. Protect from freezing andphysical damage. SAFETY STORAGE CODE: GENERAL

    Section 8. Exposure Controls / Personal Protection

    ENGINEERING CONTROLS: No specific controls are needed. Normal room ventilation is adequate.

    RESPIRATORY PROTECTION: Normal room ventilation is adequate.

    SKIN PROTECTION: Chemical resistant gloves.

    EYE PROTECTION: Safety glasses or goggles.

    Section 9. Physical and chemical Properties

    pH: 10BOILING POINT (

    OC): approximately 100

    MELTING POINT (OC): approximately 0

    VAPOR PRESSURE: N/A

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    PRODUCT IDENTITY: BUFFER, Standard and High Accuracy, pH 10.00 CATALOG NUMBER (S): 00654-08, 35654-08, 05942-61, 05942-62, 05942-64, 05942-65, 05942-66, 05942-67, 35653-03EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00509 Rev 3 Page 3 of 4

    MATERIAL SAFETY DATA SHEET

    Section 10. Stability and Reactivity

    CHEMICAL STABILITY: Stable under normal conditions of use and storage.

    INCOMPATIBILITY: Acids

    HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of Sodium.

    HAZARDOUS POLYMERIZATION: Will not occur.

    Section 11. Toxicological Information

    LD50, Oral, Rat: 4090 mg/kg (Sodium Carbonate), 4220 mg/kg (Sodium Bicarbonate), details of toxic effects noreported other than lethal dose value.

    Section 12. Ecological Information

    ECOTOXICOLOGICAL INFORMATION: No information found.

    CHEMICAL FATE INFORMATION: No information found.

    Section 13. Disposal Considerations

    Dilute with water, then flush to sewer if local regulations allow. If not allowed, save for recovery or recycling in anapproved waste disposal facility. Always dispose of in accordance with local, state and federal regulations.

    Section 14. Transport Information (Not meant to be all inclusive)

    D.O.T. SHIPPING NAME: Not regulatedD.O.T. HAZARD CLASS: None

    U.N. / N.A. NUMBER: NonePACKING GROUP: None

    D.O.T. LABEL: None

    Section 15. Regulatory Information (Not meant to be all inclusive - selected regulation represented)

    OSHA STATUS: The above items either do not contain any specifically hazardous material or the potentially hazardousmaterial is present in such low concentration that the items do not present any immediate threat to health and safetyThese items do not meet the OSHA Hazard Communication Standard (29 CFR 1910.1200) definition of a hazardousmaterial.TSCA STATUS: All components of this solution are listed on the TSCA Inventory.

    CERCLA REPORTABLE QUANTITY:Not reportableSARA TITLE III:

    SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: No

    SECTION 311/312 HAZARDOUS CATEGORIES: No

    SECTION 313 TOXIC CHEMICALS: No

    RCRA STATUS: No

    CALIFORNIA PROPOSITION 65: Not listed.

    Section 16. Other Information

    NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Special Notice Key: NoneHMIS Ratings: Health: 1 Flammability: 0 Reactivity: 0 Protective Equipment: B

    (Protective eyewear, gloves)Rev 1, 01-15-2003: added catalog number 35653-03.Rev 2, 03-25-2003: Reviewed and approved.Rev 3, 03-20-2006: Reviewed and approved.

    When handled properly by qualified personnel, the product described herein does not present a significant health or safety hazard. Alteration of itscharacteristics by concentration, evaporation, addition of other substances, or other means may present hazards not specifically addressed herein and

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    PRODUCT IDENTITY: BUFFER, Standard and High Accuracy, pH 10.00 CATALOG NUMBER (S): 00654-08, 35654-08, 05942-61, 05942-62, 05942-64, 05942-65, 05942-66, 05942-67, 35653-03EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00509 Rev 3 Page 4 of 4

    MATERIAL SAFETY DATA SHEETwhich must be evaluated by the user. The information furnished herein is believed to be accurate and represents the best data currently available to usNo warranty, expressed or implied, is made and RICCA CHEMICAL COMPANY assumes no legal responsibility or liability whatsoever resulting from itsuse.

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    PRODUCT IDENTITY: ELECTRODE CLEANER CATALOG NUMBER (S): 00653-06, 35655-06EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00533 Rev 2 Page 1 of 4

    FICHA DE DADOS MATERIAL DE SEGURAN

    Seco 1. Identificao do produto qumico e da empresaCatalog Number(s)

    00653-06, 35655-06

    Identidade do produto:

    lquido de limpeza de elctrodoManufacturers Name Emergency Telephone Number (24 hr)

    RICCA CHEMICAL COMPANY CHEMTREC: 800-424-9300Address (Number, Street, City, State, and ZIP Code) Telephone Number For Information

    P.O. Box 13090 817-461-5601Date Prepared

    Arlington, Texas 76094 4-20-2000

    Seco 2. Composio informao sobre os ingredientesPercentual Exposure Limits

    Componente CAS Registry # Concentrao ACGIH TLV OSHA PEL

    Pepsina 9001-75-6 0.9 1.1 N/A N/A

    cido clordrico 7647-01-0 < 1 5 ppm 5 ppm

    gua desionizada 7732-18-5 Balance N/A N/A

    Seco 3. Identificao de perigos

    VISO GERAL DE EMERGNCIANo apresenta quaisquer riscos significativos para a sade. Pode causar irritao e reao alrgica. reas de contactocom a gua de lavar. Se ingerido, dar grandes quantidades de gua. No induza o vmito. Chame imediatamente ummdico se necessrio.

    POTENCIAIS EFEITOS NA SADE:RGOS alvo: olhos, pele, sistema respiratrio.

    EYE CONTACT: May cause irritation, redness and pain.INHALATION: May cause mild irritation.

    SKIN CONTACT: May cause mild irritation and allergic reaction.

    INGESTION: Large doses may cause nausea, vomiting and diarrhea.

    CHRONIC EFFECTS / CARCINOGENICITY:

    REPRODUCTION INFORMATION:

    Reproductive effects cited in Registry of Toxic Effects of Chemical Substances for Hydrochloric Acid.

    Seo 4. Propriedades fsicas e qumicas

    APARNCIA:

    ODOR:

    SOLUBILIDADE EMGUA:

    GRAVIDADE ESPECFICA:

    Inodoro de lquido amarelo

    plido ao infinito

    ligeiramente pungente

    Aproximadamente 1

    pH:

    BOILING POINT (OC):

    MELTING POINT (OC):

    VAPOR PRESSURE:

    Approximately 1

    Approximately 100

    Approximately 0N/A

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    PRODUCT IDENTITY: ELECTRODE CLEANER CATALOG NUMBER (S): 00653-06, 35655-06EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00533 Rev 2 Page 2 of 4

    MATERIAL SAFETY DATA SHEET

    Section 4. First Aid Measures In all cases, seek qualified evaluation.

    EYE CONTACT: Irrigate immediately with large quantity of water for at least 15 minutes. Call a physician if irritationdevelops.

    INHALATION: Remove to fresh air. Give artificial respiration if necessary.

    SKIN CONTACT: Flush with plenty of soap and water for at least 15 minutes. Call a physician if irritation develops.

    INGESTION: Dilute with water or milk. Do not induce vomiting. Call a physician if necessary.

    Section 5. Fire Fighting Measures

    FLAMMABLE PROPERTIES:

    FLASH POINT: N/A METHOD USED: N/AFLAMMABLE LIMITS

    LFL: N/A UFL: N/A

    EXTINGUISHING MEDIA: Use any means suitable for extinguishing surrounding fire (water, dry chemical, chemical foam).

    FIRE & EXPLOSION HAZARDS: Not considered to be an explosion hazard.

    FIRE FIGHTING INSTRUCTIONS: Use normal procedures/instructions.

    FIRE FIGHTING EQUIPMENT: Use protective clothing and NIOSH-approved self-contained breathing apparatus appropriatefor the surrounding fire.

    Section 6. Accidental Release Measures

    Cover the spill with Sodium Carbonate or a soda ash-slaked lime mixture (50:50). Mix and add water to form slurryDecant the liquid to the drain with excess water. Treat the solid residue as normal refuse. Wash site with soda ashsolution. Always dispose of in accordance with local regulations.

    Section 7. Handling and Storage

    As with all chemicals, wash hands thoroughly after handling. Avoid contact with eyes and skin. Protect from freezing andphysical damage. Store in the refrigerator. SAFETY STORAGE CODE: GENERAL

    Section 8. Exposure Controls / Personal Protection

    ENGINEERING CONTROLS: No specific controls are needed. Normal room ventilation is adequate.

    RESPIRATORY PROTECTION: Normal room ventilation is adequate.

    SKIN PROTECTION: Chemical resistant gloves, Nitrile Rubber or Neoprene.

    EYE PROTECTION: Safety glasses or goggles.

    Section 10. Stability and Reactivity

    CHEMICAL STABILITY: Stable under normal conditions of use and storage.

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    PRODUCT IDENTITY: ELECTRODE CLEANER CATALOG NUMBER (S): 00653-06, 35655-06EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00533 Rev 2 Page 3 of 4

    MATERIAL SAFETY DATA SHEET

    INCOMPATIBILITY: Most metals, Alkalis, active metals, Cyanides, Sulfides, Sulfites, Metal Oxides, Formaldehyde, strongOxidizers, salts of heavy metals, Tannins.

    HAZARDOUS DECOMPOSITION PRODUCTS: Fumes of Hydrogen Chloride and Hydrogen in contact with metals, Chlorine gasfrom Oxidizers. Carbon Monoxide, Carbon Dioxide and Nitrogen Oxides may be produced in a fire.

    HAZARDOUS POLYMERIZATION: Will not occur.

    Section 11. Toxicological Information

    LD50, Oral, Rabbit (Hydrochloric Acid) 900 mg/kg; Details of toxic effects not reported other than lethal dose valueLCLo, inhalation, human: 3000 ppm/5 minutes: No toxic effects noted. Pepsin is investigated as a mutagen.

    Section 12. Ecological Information

    ECOTOXICOLOGICAL INFORMATION: Hydrogen Chloride has slight acute and chronic toxicity to aquatic life.

    CHEMICAL FATE INFORMATION: Virtually 100% of Hydrogen Chloride will eventually end up in the air.

    Section 13. Disposal Considerations

    Cover the spill with Sodium Carbonate or a soda ash-slaked lime mixture (50:50). Mix and add water to form slurryDecant the liquid to the drain with excess water. Treat the solid residue as normal refuse. Always dispose of inaccordance with local, state and federal regulations.

    Section 14. Transport Information (Not meant to be all inclusive)

    D.O.T. SHIPPING NAME: Not regulatedD.O.T. HAZARD CLASS: None

    U.N. / N.A. NUMBER: NonePACKING GROUP: None

    D.O.T. LABEL: None

    Section 15. Regulatory Information (Not meant to be all inclusive - selected regulation represented)

    OSHA STATUS: The above items either do not contain any specifically hazardous material or the potentially hazardousmaterial is present in such low concentration that the items do not present any immediate threat to health and safetyThese items do not meet the OSHA Hazard Communication Standard (29 CFR 1910.1200) definition of a hazardousmaterial.

    TSCA STATUS: All components of this solution are listed on the TSCA Inventory.

    CERCLA REPORTABLE QUANTITY:Hydrochloric Acid RQ 5000 poundsSARA TITLE III:

    SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: No

    SECTION 311/312 HAZARDOUS CATEGORIES: Acute: Yes Chronic, Fire, Pressure, Reactivity: No

    SECTION 313 TOXIC CHEMICALS: No

    RCRA STATUS: No

    CALIFORNIA PROPOSITION 65: Not listedFLORIDA: Hydrochloric Acid is listed on Florida's Toxic Substances List.

    PENNSYLVANIA: Hydrochloric Acid is listed as an Environmental Hazard on the state's Hazardous Substances List.

    Section 16. Other Information

    NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Special Notice Key: NoneHMIS Ratings: Health: 1 Flammability: 0 Reactivity: 0 Protective Equipment: B

    (Protective eyewear, gloves)Rev 1, 03-25-2003: Reviewed and approved, (Section 7) added refrigeration.Rev 2, 03-20-2006: Reviewed and approved.

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    PRODUCT IDENTITY: ELECTRODE CLEANER CATALOG NUMBER (S): 00653-06, 35655-06EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00533 Rev 2 Page 4 of 4

    MATERIAL SAFETY DATA SHEET

    When handled properly by qualified personnel, the product described herein does not present a significant health or safety hazardAlteration of its characteristics by concentration, evaporation, addition of other substances, or other means may present hazards nospecifically addressed herein and which must be evaluated by the user. The information furnished herein is believed to be accurate andrepresents the best data currently available to us. No warranty, expressed or implied, is made and RICCA CHEMICAL COMPANYassumes no legal responsibility or liability whatsoever resulting from its use.

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    PRODUCT IDENTITY: pH ELECTRODE STORAGE SOLUTION CATALOG NUMBER (S): 00653-04, 35655-04EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00517 Rev 2 Page 1 of 3

    FICHA DE MATERIAL DADOS DE SEGURNAA

    Seco 1. Identificao do produto qumico e da empresaCatalog Number(s)

    00653-04, 35655-04

    Identidade do produto

    SOLUO de armazenamento de eletrodo de pHManufacturers Name Emergency Telephone Number (24 hr)

    RICCA CHEMICAL COMPANY CHEMTREC: 800-424-9300Address (Number, Street, City, State, and ZIP Code) Telephone Number For Information

    P.O. Box 13090 817-461-5601Date Prepared

    Arlington, Texas 76094 3-24-2000

    Seco 2. Composio informao sobre os ingredientesPercent Exposure Limits

    Component CAS Registry # Concentration ACGIH TLV OSHA PEL

    gua desionizada 7732-18-5 99 N/A N/A

    Esta uma formulao patenteada que no contm quaisquer ingredientes perigosos de acordo com a OSHA.

    Seco 3. Identificao de perigos

    EMERGENCY OVERVIEW

    Clear, colorless liquid. Non-flammable, non-toxic, non-corrosive. Does not present any significant health hazards.

    POTENTIAL HEALTH EFFECTS:

    TARGET ORGANS:eyes, skin.

    EYE CONTACT: May cause slight irritation.

    INHALATION: Not likely to be hazardous by inhalation.

    SKIN CONTACT: May cause slight irritation.

    INGESTION: Large doses may cause stomach upset.

    CHRONIC EFFECTS / CARCINOGENICITY:

    IARC No

    NTP NoOSHA No

    TERATOLOGY (BIRTH DEFECT) INFORMATION:

    No information found in Registry of Toxic Effects of Chemical Substances or other information sources.

    Section 4. Physical and chemical Properties

    InodLquido claro, incolororolquido desobstrudo, incolorinfinitoaproximadamente 1.0

    APARNCIA:

    ODOR:

    SOLUBILIDADE EM GUA:

    GRAVIDADE ESPECFICA:

    pH:

    BOILING POINT (OC):

    MELTING POINT (OC):

    VAPOR PRESSURE:

    N/A

    approximately 100

    approximately 0

    N/A

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    PRODUCT IDENTITY: pH ELECTRODE STORAGE SOLUTION CATALOG NUMBER (S): 00653-04, 35655-04EFFECTIVE DATE: 3-20-2006 MSDS NUMBER 00517 Rev 2 Page 2 of 3

    MATERIAL SAFETY DATA SHEET

    SKIN CONTACT: Flush with plenty of water for at least 15 minutes. Call a physician if irritation develops.

    INGESTION: Dilute with water or milk. Call a physician if necessary.

    Section 5. Fire Fighting Measures

    FLAMMABLE PROPERTIES:FLASH POINT: N/A METHOD USED: N/A

    FLAMMABLE LIMITS

    LFL: N/A UFL: N/A

    EXTINGUISHING MEDIA: Use any means suitable for extinguishing surrounding fire.

    FIRE & EXPLOSION HAZARDS: Not considered to be a fire or explosion hazard.

    FIRE FIGHTING INSTRUCTIONS: Use normal procedures/instructions.

    FIRE FIGHTING EQUIPMENT: Use protective clothing and breathing equipment appropriate for the surrounding fire.

    Section 6. Accidental Release MeasuresAbsorb with suitable material (paper towels, etc.) and dispose of in accordance with local regulations. Small amountsmay be flushed to the sewer with plenty of water.

    Section 7. Handling and Storage

    As with all chemicals, wash hands thoroughly after handling. Avoid contact with eyes and skin. Protect from freezing andphysical damage. SAFETY STORAGE CODE: GENERAL

    Section 8. Exposure Controls / Personal Protection

    ENGINEERING CONTROLS: No specific controls are needed. Normal room ventilation is adequate.

    RESPIRATORY PROTECTION: Normal room ventilation is adequate.

    SKIN PROTECTION: Normal room ventilation is adequate.

    EYE PROTECTION: Safety glasses or goggles.

    Section 10. Stability and Reactivity

    CHEMICAL STABILITY: Stable under normal conditions of use and storage.

    INCOMPATIBILITY: None identified.

    HAZARDOUS DECOMPOSITION PRODUCTS: None identified.

    HAZARDOUS POLYMERIZATION: Will not occur.

    Section 11. Toxicological Information

    Details of toxic effects not reported other than lethal dose value (>3200 mg/kg) per "Registry of Toxic Effects oChemical Substances".

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    MATERIAL SAFETY DATA SHEET

    Section 12. Ecological Information

    ECOTOXICOLOGICAL INFORMATION: No information found.

    CHEMICAL FATE INFORMATION: No information found.

    Section 13. Disposal ConsiderationsDilute with water and flush to sewer. Absorbent material may be treated as normal refuse. Always dispose of inaccordance with local, state and federal regulations.

    Section 14. Transport Information (Not meant to be all inclusive)

    D.O.T. SHIPPING NAME: Not regulatedD.O.T. HAZARD CLASS: None

    U.N. / N.A. NUMBER: NonePACKING GROUP: None

    D.O.T. LABEL: None

    Section 15. Regulatory Information (Not meant to be all inclusive - selected regulation represented)

    OSHA STATUS: The above items either do not contain any specifically hazardous material or the potentially hazardous

    material is present in such low concentration that the items do not present any immediate threat to health and safetyThese items do not meet the OSHA Hazard Communication Standard (29 CFR 1910.1200) definition of a hazardousmaterial.

    TSCA STATUS: All components of this solution are listed on the TSCA Inventory.

    CERCLA REPORTABLE QUANTITY:Not reportableSARA TITLE III:

    SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: No

    SECTION 311/312 HAZARDOUS CATEGORIES: No

    SECTION 313 TOXIC CHEMICALS: No

    RCRA STATUS: No

    CALIFORNIA PROPOSITION 65:Not listed.

    Section 16. Other Information

    NFPA Ratings: Health: 0 Flammability: 0 Reactivity: 0 Special Notice Key: NoneHMIS Ratings: Health: 0 Flammability: 0 Reactivity: 0 Protective Equipment: B

    (Protective eyewear, gloves)

    Rev 1, 03-25-2003: Reviewed and approved.Rev 2, 03-20-2006: Reviewed and approved.

    When handled properly by qualified personnel, the product described herein does not present a significant health or safety hazardAlteration of its characteristics by concentration, evaporation, addition of other substances, or other means may present hazards nospecifically addressed herein and which must be evaluated by the user. The information furnished herein is believed to be accurate andrepresents the best data currently available to us. No warranty, expressed or implied, is made and RICCA CHEMICAL COMPANY

    assumes no legal responsibility or liability whatsoever resulting from its use.