6

Cin-drive.rurusskii-izumrud.rudiary.ru happynews.com

1) - , , 2) - 3) 4) - + SN :R2C(OH)2 R2C=ORC(OH)3 RCOOH

:R2C=CR(OH) R2CH-CR=O

C -:Cl-CH2-CH2OH > CH3OH > CH3-CH2OH > > (CH3)2-CHOH > (CH3)3-COH W(2) = 10-14, () ~ 10-162ROH + 2Na 2RONa + H2 ROH + NaOH RONa + H2ORONa + H2O ROH + NaOH :2--2 > -CH2-CH2OH > Cl-CH2-CH2OH2--2 + NaOH 2-Na-2 + H2O

(SN) ( . +)3 + RCOOH RCOOCH3 + H2O2--2 + 3HNO3 CH2ONO2-CHONO2-CH2ONO2 + 3H2OPhOH + CH3I PhOCH3 + HIPhOH + CH3COCl PhOCOCH3 + HCl(PhOH + RCOOH ) ? ROH + HHal RHal + H2O5ROH + PHal5 5RHal + H3PO4 + H2Oorgchem.city.tomsk.net

C2H5OH + (HO)2SO2 (C2H5O)2SO2

totoCH2=CH2 C2H5-O-C2H5+ H2SO4H2O(.)H3OH + C2H5OH ? ? ?

+ uO ( ), ( )CH3-CHOH-CH3 + CuO CH3-CO-CH3 + Cu + H2O

+ KMnO4 K2Cr2O7 ( ), ( )25 + KMnO4 + H2SO4 CH3COOH + MnSO4 (+ K2SO4 + H2O)25 + KMnO4 CH3COOK + MnO2 (+ KOH + H2O)CH3-CHOH-CH3 + K2Cr2O7 + H2SO4 CH3-CO-CH3 + Cr2(SO4)3 (+ K2SO4 + H2O)[O]O CuO, KMnO4, K2Cr2O7

files.school-collection.edu.ru

(AE) (SN) =[H] - KBH4, LiAlH4: 4R2C=O + KBH4 + 4H2O = 4R2CH-OH + KB(OH)4 , , 3 + 22 = 3 (r2O3, ZnO, p, to) 6126 225 + 2 2pics.rbc.ruxa-xa.by

..---newchemistry.ru(-)(-)(-)

him.1september.ru

: Ph , , ? NaOH, ?PhOH + NaOH PhONa + H2O ( ):

: Ph.20% SE sciencemadness.orgseilnacht.com (, , )

: Ph SE

: Phforum.ximicat.com

PhCl + 2NaOH PhONa + NaCl + H2OPhSO3H + 3NaOH PhONa + Na2SO3 + 2H2O () Ph-CH(CH3)2 Ph-C(CH3)2OOH PhOH + (CH3)2C=O (to)Ph-N2+Cl- + 2 PhOH + N2 + HClsbras.nsc.ru

= 110-10 = 3,610-10 = 8,910-10 = 1,110-10