Vitreous Materials Lab.

LaMaV

DEMa - UFSCar

lamav.weebly.com

…………………………………………………………………………………………..

Desafios...

• Adversidades despertam capacidades que, em outras circunstâncias, teriam ficado adormecidas...

• Estranhamente o Homem somente progride perante um ambiente desafiador. Se consegue, passo a passo, superar seus desafios, fica feliz e com mais energia e vontade de tentar novas soluções e novos projetos.

Fica divertido!

CeRTEV´s activities will focus on multidisciplinary, relevant glass science, useful technology and efficient education and outreach!

Edgar Dutra Zanotto

Center For Research, Technology and

Education in Vitreous Materials

SCOPE

CeRTEV will research and develop or improve glasses and glass-ceramics

presenting application-relevant functionalities, such as high mechanical strength

and electrical conductivity, biological, optical or catalytic activity, and/or

combinations of these properties.

A fundamental understanding of these properties will be sought on the basis of

the structural organization of these materials on different length scales. We will

apply state-of-the art NMR, EPR, EXAFS and vibrational spectroscopy to

characterize the local and medium-range order, as well as the full resolution

range of optical and electron microscopies, XRD and microanalyses for

elucidating nano- and microstructures. This comprehensive experimental

approach will be complemented by molecular dynamics simulations.

Using this experimental modeling strategy, we will further seek a fundamental

understanding of glass sintering and crystallization in terms of the mechanisms,

thermodynamics and kinetics of viscous flow, as well as crystal nucleation and

growth, enabling us to exercise control of these processes by developing

appropriate formation and thermal treatment protocols.

In a concerted effort, the participating laboratories will jointly investigate a

number of important benchmark systems, which are deemed particularly

promising for applications either as structural materials (e.g., dental and armor

glass-ceramics), bio active glasses and glass-ceramics, glass-ceramics for

architecture and construction, optical materials (e.g., laser glasses), materials for

electrochemical energy storage devices (electrolytes, high-temperature seals),

and catalytically active systems.

6

1

7

Dental Construction

Gratings

Glass-ceramics

Vice-director Manager

2 secretaries

1 informatics

Coordinador Tech &

Innovation Director

Coordinator

Education and

Outreach

14 professors FQV

~30 collaborators

~60 students

One of the largest academic glass R & D

of this planet!

• Leandro Innocentini L. de Faria, Manager, Scientometry

STRUCTURE • Hellmut Eckert Structure, NMR • José Fabián Schneider Structure, NMR • Claudio José Magon EPR • Jose Pedro Donoso Gonzalez EPR • Valmor Roberto Mastelaro EXAFS, XRD and laser crystallization • Paulo Sergio Pizani Raman spectroscopy • José Pedro Rino Molecular dynamics simulation

CRYSTALLIZATION + Thermal, Mechanical, Bio and Electrical properties • Edgar Dutra Zanotto Nucleation, growth, crystallization , glass-ceramics • Marcello Rubens Barsi Andreeta Laser crystallization, crystal growth techniques • Ana Cândida Martins Rodrigues Electrical properties, ionic conducting glass & GC • Oscar Peitl Bio active glasses and glass-ceramics • Eduardo Bellini Ferreira Nucleation, growth, crystallization, glass-ceramics

OPTICAL Properties • Andrea S. S. de Camargo Alvarez Bernardez Optical properties • Marcelo Nalin Optical and chemical properties

The Team 14

Ranking in the world (2013)

• A June 2013 search on the SCOPUS database for the number of published articles with relevant keywords indicates that some of CeRTEV´s faculty rank:

• first in the world with the keywords glass* and NMR*, • first with glass* and nucleation, • second with glass* and crystal growth, • fourth with glass* and crystallization, • 26th with bio* and glass-ceramic*, • 28thwith glass* and sinter*, • 31th with glass-ceramic*, • 43th with glass* and EXAFS.

Scientific papers - Ranking 1829-2013 • Russian Academy of Sciences(1,111 glass papers) • Kyoto University(849) • CeRTEV = USP(370)+ UNESP-(225)+ UFSCar (181) = 776 • Shanghai Institute of Optics and Fine Mechanics (759) • CNRS Centre National de la Recherche Scientifique(735) • Tokyo Institute of Technology(624) • University of Cambridge(574) • University of Tokyo(553) • Osaka University(550) • The State Scientific-Research Institute of Glass(550) • Friedrich Schiller Universität Jena(479) • Universite Pierre et Marie Curie(471) • Chinese Academy of Sciences(457) • Corning Incorporated(445) • Alcatel-Lucent Bell Labs(432) • Pennsylvania State University(426) • Argonne National Laboratory(423) • Massachusetts Institute of Technology(412) • S.I. Vavilov State Optical Institute(393) • National Institute of Advanced Industrial Science and Technology(383) • Universite de Rennes 1(375) • 22th USP(370) • Consiglio Nazionale delle Ricerche(366) • Universite Montpellier 2 Sciences et Techniques(363) • Indian Institute of Science(361) • Hokkaido University(358) • University of Sheffield(351) • Alfred University(343) • Kyushu University(341)

SCOPUS search

glass*+

vitreous+

amorphous+

non-crystalline -

( metal* and polymer*)

Ranking 2010-2013 • Shanghai Institute of Optics and Fine Mechanics CAS(201) • Russian Academy of Sciences(177) • CeRTEV = USP(67)+UFSCar(48)+UNESP(43) = 158 • Ningbo University(152) • Graduate University of Chinese Academy of Sciences(142) • CNRS Centre National de la Recherche Scientifique(137) • South China University of Technology(107) • Wuhan University of Technology(104) • Chinese Academy of Sciences(101) • Universite de Rennes 1(96) • University of Tokyo(94) • Friedrich Schiller Universität Jena(93) • Harbin Institute of Technology(91) • Sri Venkateswara University(85) • Universite Pierre et Marie Curie(82) • Kyoto University(82) • Tongji University(82) • National Research Center, Cairo(79) • University of Pardubice(78) • Sichuan University(77) • Consiglio Nazionale delle Ricerche(75) • Tohoku University(72) • Osaka University(72) • East China University of Science and Technology(71) • Pacific Northwest National Laboratory(71) • Tokyo Institute of Technology(71) • Universität Erlangen-Nürnberg(69) • Shanghai Institute of Ceramics Chinese Academy of Sciences(69) • Tsinghua University(68) • 30th Universidade de Sao Paulo(67) • Corning Incorporated(62)

glass*+

vitreous+

amorphous+

non-crystalline -

(metal* and polymer*)

Budget

~US$ 20 million from Fapesp for equipament, travel, materials and supplies spread over 11 years

(excluding salaries and students grants) But Fapesp expects us to get

complementary funding from other government agencies and industries...

International Advisory Board

• GOMD meeting, San Diego, June 2013

• Fran Serbena, Dick Brow, Bruce Aitken and Ed Zanotto.

• Credit ACerS

ICG, Prague, July 2013

Our philosophy

To pursue relevant research topics with well defined objectives.

To carry out long term basic research. To reach and expand the frontiers of knowledge in each one of the chosen subjects.

Maximize planning, calculation, simulation, literature search and study to optimize experimentation.

To publish original, accurate articles that push the frontiers of knowledge. Quality, and not quantity, is our goal.

Technological research via industrial interest that may lead to patents and eventually innovation

New glass research center in Brazil

2 universities, 14 profs, 11 years, $20 M

—one big impact!

Published on July 8th, 2013

by Eileen De Guire

The American Ceramic Society

LaMaV´s

International

NETWORK

Bio glass and GC

~15 institutions L. Hench, Boccacini

TC7 (1984)

IMI (2004)

Jena

1982

Russel

Grenoble

1984

Souquet

IVSO Inst.

1996

Fokin

Univ. Rostock

2001

Schmelzer

Erlangen

2003

Boccaccini

J. Mauro

Corning

J. Du

Univ. Texas

Rocherullè &

Rouxel

Rennes

J. Lumeau

Fresnel

CeRTEV

2012

Starting

in 2014

Selected papers published in 2013

Structure of vitreous materials

Ren, J., Eckert, H., Anion distribution in superionic Ag3PO4-AgI glasses revealed by dipolar solid-state

NMR, Journal of Physical Chemistry C 117 (47), pp. 24746-24751, 2013.

Schneider, J., Tsuchida, J., Eckert, H., Cation size effects in mixed-ion metaphosphate glasses: Structural

characterization by multinuclear solid state NMR spectroscopy, Physical Chemistry Chemical Physics 15

(34), pp. 14328-14339,2013.

DQ-DRENAR: a New NMR Technique to Measure Site-Resolved Magnetic Dipole-Dipole Interactions in

Multispin-1/2 Systems. Theory and Applications to Phosphate Materials, Ren,J.; Eckert, H. J. Chem. Phys.

138, 164201/1-16 (2013).

Sol-Gel preparation and structural characterization of mesoporous Al2O3-SiO2 glasses, Ren, J.; Zhang,

L.; Eckert, H. Sol Gel Sci Technol. 2014, in press.

Medium range order in sol-gel prepared Al2O3-SiO2 glasses: New results from solid State NMR, Ren, J.;

Zhang, L; Eckert, H. J. Phys. Chem. C 2014, in press.

Pontes, D.S.L.; Pontes, F.M.; da Silva, L.F.; Chiquito, A.J.; Pizani, P.S.; Longo, E. Influence of a co-

substituted A-site on structural characteristics and ferroelectricity of (Pb, Ba, Ca)TiO3 complex perovskites:

analysis of local-, medium- and long-range order. Journal of Sol-Gel Sci Technology, pp. 1-12. 2014.

Crystal Nucleation, Growth and Overall Crystallization

Fokin, V.M.; Reis, R.M.C.V.; Abyzov, A.S.; Chinaglia, C.R.; Zanotto, E.D. Nonstoichiometric

crystallization of lithium metasilicate-calcium metasilicate glasses. Part 1 - Crystal nucleation and

growth rates. Journal of Non-Crystalline Solids 362 (1), pp. 56-64. 2013.

Fokin, V.M.; Reis, R.M.C.V.; Abyzov, A.S.; Chinaglia, C.R.; Schmelzer, J.W.P.; Zanotto, E.D. Non-

stoichiometric crystallization of lithium metasilicate-calcium metasilicate glasses. Part 2 - Effect of

the residual liquid. Journal of Non-Crystalline Solids 379, pp. 131-144. 2013.

Cabral, A.A.; Ferreira, E.B.; Villas-Boas, M.O.C.; Zanotto, E.D. On the determination of the

concentration of crystal nuclei in glasses by DSC. Journal of the American Ceramic Society 96

(9), pp. 2817-2823. 2013.

Dyamant, I.; Abyzov, A.S.; Fokin, V.M.; Zanotto, E.D.; Lumeau, J.; Glebova, L.N.; Glebov, L.B.

Crystal nucleation and growth kinetics of NaF in photo-thermo-refractive glass. Journal of Non-

Crystalline Solids 378, pp. 115-120. 2013.

Zanotto, E.D. Glass Crystallization Research - A 36-Year Retrospective. Part I, Fundamental

Studies. International Journal of Applied Glass Science 4 (2), pp. 105-116. 2013.

Rodrigues, A.M.; Narváez-Semanate, J.L.; Cabral, A.A.; Rodrigues, A.C.M. Determination of

crystallization kinetics parameters of a Li1.5Al0.5Ge1.5(PO4)3 (LAGP) glass by differential

scanning calorimetry. Materials Research 16 (4) 2013.

Jasinevicius, R.G.; Duduch, J.G.; Pizani, P.S. Evidence of crystallographic orientation

dependence upon cyclic microindentation-induced recrystallization within amorphous surface

layer. Materials Letters 94, pp. 201-205. 2013.

Almeida, J.M.P., Tribuzi, V., Fonseca, R.D., Otuka, A.J.G., Ferreira, P.H.D., Mastelaro, V.R.,

Brajato, P., Hernandes, A.C., Dev, A., Voss, T., Correa, D.S., Mendonca, C.R., Femtosecond laser

processing of glassy and polymeric matrices containing metals and semiconductor

nanostructures, Optical Materials 35 (12), pp. 2643-2648, 2013.

Bioactive glasses and glass-ceramics

Souza, M.T.; Crovace, M.C.; Schröder, C.; Eckert, H.; Peitl, O.; Zanotto, E.D. Effect of magnesium ion incorporation on

the thermal stability, dissolution behavior and bioactivity in Bioglass-derived glasses. Journal of Non-Crystalline Solids 382,

pp. 57-65. 2013.

Renno, A.C.M.; Bossini, P.S.; Crovace, M.C.; Rodrigues, A.C.M.; Zanotto, E.D.; Parizotto, N.A. Characterization and in

vivo biological performance of biosilicate. BioMed Research International 2013, art. no. 141427. 2013.

Renno, A.C.M.; Nejadnik, M.R.; Van De Watering, F.C.J.; Crovace, M.C.; Zanotto, E.D.; Hoefnagels, J.P.M.; Wolke,

J.G.C.; Jansen, J.A.; Van Den Beucken, J.J.J.P. Incorporation of bioactive glass in calcium phosphate cement: Material

characterization and in vitro degradation. Journal of Biomedical Materials Research - Part A 101 A (8), pp. 2365-2373.

2013.

Desimone, D.; Li, W.; Roether, J.A.; Schubert, D.W.; Crovace, M.C.; Rodrigues, A.C.M.; Zanotto, E.D.; Boccaccini, A.R.

Biosilicate®-gelatine bone scaffolds by the foam replica technique: Development and characterization. Science and

Technology of Advanced Materials 14 (4), art. no. 045008. 2013.

Pinto, K.N.Z.; Tim, C.R.; Crovace, M.C.; Matsumoto, M.A.; Parizotto, N.A.; Zanotto, E.D.; Peitl, O.; Rennó, A.C.M. Effects

of biosilicate® scaffolds and low-level laser therapy on the process of bone healing. Photomedicine and Laser Surgery 31

(6), pp. 252-260. 2013.

Renno, A.C.M.; Van De Watering, F.C.J.; Nejadnik, M.R.; Crovace, M.C.; Zanotto, E.D.; Wolke, J.G.C.; Jansen, J.A.; Van

Den Beucken, J.J.J.P. Incorporation of bioactive glass in calcium phosphate cement: An evaluation. Acta Biomaterialia 9

(3), pp. 5728-5739. 2013.

Kido, H.W.; Oliveira, P.; Parizotto, N.A.; Crovace, M.C.; Zanotto, E.D.; Peitl-Filho, O.; Fernandes, K.P.S.; Mesquita-

Ferrari, R.A.; Ribeiro, D.A.; Renno, A.C.M. Histopathological, cytotoxicity and genotoxicity evaluation of Biosilicate® glass-

ceramic scaffolds. Journal of Biomedical Materials Research - Part A 101 A (3), pp. 667-673. 2013.

Siqueira, R.L.; Zanotto, E.D. The influence of phosphorus precursors on the synthesis and bioactivity of SiO2-CaO-P2O5

sol-gel glasses and glass-ceramics. Journal of Materials Science: Materials in Medicine 24 (2), pp. 365-379. 2013.

Daguano, J.K.M.F., Rogero, S.O.,Crovace, M.C., Peitl, O., Strecker, K.,Dos Santos, C., Bioactivity and cytotoxicity of glass

and glass-ceramics based on the 3CaO•P2O5-SiO2-MgO system, ournal of Materials Science: Materials in Medicine 24

(9), pp. 2171-2180, 2013.

Brandão, S.M., Schellini, S.A.,Padovani, C.R., Peitl, O., Hashimoto, E., Análise da biocompatibilidade de cones de

biovidro e biovitrocerâmico (Biosilicato®) em cavidade eviscerada de coelho | [Biocompatibility analisys of Bioglass® 45S5

and Biosilicate® cone in rabbit eviscerated cavity], Revista Brasileira de Oftalmologia72 (1), pp. 21-25, 2013.

Other types of glass-ceramics

Zanotto, E.D. Glass Crystallization Research - A 36-Year

Retrospective. Part II, Methods of Study and Glass-

Ceramics. International Journal of Applied Glass Science 4

(2), pp. 117-124. 2013.

Soares, V.O.; Peitl, O.; Zanotto, E.D. New sintered Li2O -

Al2O3- SiO2 ultra-low expansion glass-ceramic. Journal of

the American Ceramic Society 96 (4), pp. 1143-1149. 2013.

Kjeldsen, J.; Yue, Y.; Bragatto, C.B.; Rodrigues,

A.C.M. Electronic conductivity of vanadium-tellurite glass-

ceramics. Journal of Non-Crystalline Solids 378, pp. 196-

200. 2013.

Optical Properties

De Queiroz, T.B., Botelho, M.B.S., De Boni, L., Eckert, H., De Camargo,

A.S.S., Strategies for reducing dye aggregation in luminescent host-guest

systems: Rhodamine 6G incorporated in new mesoporous sol-gel hosts,

Journal of Applied Physics 113 (11) , art. no. 113508, 2013.

De Queiroz, T.B., Botelho, M.B.S., Fernández-Hernández, J.M., Eckert,

H., Albuquerque, R.Q., De Camargo, A.S.S., New luminescent host-

guest system based on an iridium(III) complex: Design, synthesis, and

theoretical-experimental spectroscopic characterization, Journal of

Physical Chemistry C 117 (6), pp. 2966-2975, 2013.

Santos, W.Q., De Camargo, A.S.S.,Wu, D., Silva, W.F., Zhang, L.,

Jacinto, C., Cooperative upconversion, radiation trapping, and self-

quenching effects in highly Yb3+-doped oxyfluoride glasses, Science of

Advanced Materials 5 (12) , pp. 1948-1953, 2013.

Optical Properties

Manzani, D.; Almeida, J.M.P.; Napoli, M.; De Boni, L.; Nalin, M.; Afonso,

C.R.M.; Ribeiro, S.J.L.; Mendonça, C.R. Nonlinear optical properties of tungsten

lead-pyrophosphate glasses containing metallic copper

Nanoparticles. Plasmonics 8 (4), pp. 1667-1674. 2013.

Valle, P.S.; Montesso, M.; Nalin, M.; Donoso, J.P.; Silva, I.D.A.; Magon,

C.J. Influence of silver precursors on growth of metallic nanoparticles in heavy

metal oxide glasses. Quimica Nova 36 (7), pp. 967-971, 2013.

Avila, L.F.; Almeida, J.M.P.; Gonçalves, M.S.; Valle, P.S.; Nalin, M.; Mendonça,

C.R.; Cescato, L. Design and fabrication of two-dimensional hexagonal photonic

crystals with a linear waveguide in erbium doped GeO2-Bi2O 3-PbO-TiO2

glasses. Proceedings of SPIE - The International Society for Optical

Engineering 8776, art. no. 87760L, 2013.

Avila, L.F.; Nalin, M.; Cescato, L. Self diffraction holographic techniques for

investigation of photosensitive materials. Proceedings of SPIE - The

International Society for Optical Engineering 8776, art. no. 87760G, 2013.

Glasses on the Nanoscale, Eckert, H. Ribeiro, S.J.L.; Santagneli, S. H.; Nalin,

M.; Poirier, G.; Messaddeq,Y. Handbook of Nanomaterials, R. Vajtai, ed. Springer-

Verlag Berlin, 665-692 (2013).

Advanced NMR Spectroscopy of Glasses (Review), Eckert, H. to be published in

“Modern Glass Characterization”, M. Affatigato, ed., John Wiley and Sons 2014.

Bioactive Glass-Ceramics for Load-Bearing Applications - Oscar Peitl, Edgar D

Zanotto, Francisco C Serbena and Larry L Hench) - “An Introduction to

Bioceramics”, 2nd Edition Edited by: L. L. Hench, ed., World Scientific (2013)

Zanotto E.D. et al- DSC techniques for the study of glass crystallization, in

“Glassy, Amorphous and Nano-Crystalline Materials” ed. J. Sestak, J. Mares, P.

Hubik , Springer (2013)

Nucleation, Growth and Overall Crystallization, Zanotto, E.D et al., to be published

in “Glass Encyclopedia” , P. Richet, ed., John Wiley and Sons 2014

Stress-induced Pore Formation and Phase Selection in a Crystallizing Stretched

Glass, Fokin V.M., Karamanov A., Abyzov A.S, Schmelzer J. W.P., Zanotto E.D,

Chapt.8 to be published in “Glass: Selected Properties and Crystallization”, J.

Schmelzer, ed., De Gruyter 2014

Book Chapters

Planned books

• Crystals in glass – Wiley, Oct. 2013

. Experimental techniques for characterization glass structure and crystallization - start 2014

(CeRTEV team) • Fundamentals of glass crystallization start

2014 (Zanotto, Fokin & Schmelzer)

Internationalization

Visiting professors in 2013

Vladimir Fokin – St. Petersburg, Russia, one year

Jean Louis Souquet- Grenoble, France, 6 months

Juern Schmelzer, Rostok, Germany, 1 week

Alexander Priven, Korea, 1 week

Post-docs and students

2 undergrads from the USA

2 MSc students from Colombia

1PhD student from Iran (sanduiche)

2 post-docs from India

Organization of Congresses, etc...

• Internal workshops – yearly starting 2013 • Invention & Innovation – Sept. 2013 • Sol-gel workshop – Oct. 2013 • Rede BioNetec Meetings – yearly starting Nov. 2013

• X Brazilian Symposium on Glass – Oct. 2014 • São Paulo School on Glasses and CG – Feb. 2015

• Education and Outreach about glass – 2015 • Flow and Fracture in Glass – 2016 (?) • XI Brazilian Symposium on Glass – 2017 • “Glass frontiers” jointly with the World Congress of

Ceramics, Iguassu Falls - 2018

Invited talks 2013 • Hellmut Eckert

• A homonuclear version of REDOR for recoupling dipolar interactions in multi-spin systems:

Applications to inorganic phosphorus clusters and networks, International Symposium of

Magnetic Resonance (ISMAR), Rio de Janeiro, May 2013.(Invited)

• Introduction into Solid State NMR Spectroscopy, workshop, SBQ meeting, Aguas Lindoias, May

2013. (Invited)

• Modern Solid State NMR Strategies for Studying Structural Transformations in Non-Siliceous

Sol-Gel – Glass Systems, SBPMAT, Campos de Jordão, September 2013.(Invited)

• Ed Zanotto

• Iron Phosphate Glasses and Melts - A US-Brazil Research Collaboration on Novel Materials

for Nuclear Waste Remediation - 37th International Conference & Exposition on Advanced

Ceramics & Composites, Daytona Beach, USA, Jan. 24-28, 2013 (delivered by R.K.

Brow) (Invited)

• The relationship between molecular structure and nucleation mechanism in glass, ICG 2013,

Prague Czech Republic, July 1-6 2013 (Invited)

• LaMaV/ UFSCar - 36 anos de ensino, ciência e inovação - II Workshop UEPG, Ponta Grossa,

PR, August 13-14, 2013 (Opening Talk)

• LaMaV – UFSCar / 36 anos interagindo com empresas, 22 Encontro Técnico da ABIVIDRO, São

Paulo, Oct. 2, 2013 (Invited)

Advances in glass crystallization and glass-ceramics- 19th Larson Workshop on Crystallization

Technology, Indianapolis, USA, October 5-10, 2013 (Invited)

• 36 years of science, technology and art - Magna lecture - Admiral Álvaro Alberto Award cerimony

- CNPq, Brasília, October 23 , 2013 (Invited)

• Vitrocerâmicas - passado, presente e futuro - Workshop CEFET, São Luiz, MA, 3 Nov.

2013 (Invited)

• LaMaV - 3,5 décadas de invenções. Aprendendo com os erros - I EEAEM, UFSCar, 28

Nov. 2013 (Invited)

• J. P. Rino

• "Atomistic Simulation of Advanced Materials” International Conference on Materials for

Editorship of periodicals

-Solid State Nuclear Magnetic Resonance

Hellmut Eckert – Editor

-Journal of Non-Crystalline Solids

Edgar D. Zanotto - Editor

-Int. Journal of Applied Glass Science, USA- IAB

-Materials Research, Brazil - IAB

-Ceramica y Vidrio, Spain - IAB

-Cerâmica, Brazil – IAB

-The Open Crystallography Journal –

Marcello R. Barsi Andreeta - Associate Editor

Technology

Coordinator – Prof. Eduardo B. Ferreira,

EESC- USP

O-I TAB meeting,

Perrysburg, USA, March 2014

• Review and make recommendations on

O-I´s technology portfoglio

• EDZ´s talk about CeRTEV

Glassman South America , March 2014

• 9h30 Opening Show: Glassman South America Lucien Belmonte / Greg Morris Abividro

• 9h40 Cleanfire GC Edson E. Basilio Air Products

• 10h Heat Recovery Fabio Guastini Area Impianti

• 10h20 New cost efficient solution for glass moulds Sergio Simones Hoganas

• 10h40 Hot Bottom Repair Cristina Sanches Fosbel

• 11h New Material for Glass Melting Eletrodes Elisio Ferreira Neto Plansee

• 11h20 Defeitos no vidro vs. refratários Marcelo Guerra SEFPRO

• 1h20 An introduction to the FleXinspect Michael G. Rentschler Buch Emhart Glass

• 1h40 Glass Sand Manoel J. B. Cordova Mineração Jundu

• 2h Inovation on glass packaging Daniel Amaral OI

• 2h20 Soda-ash Tarcisio Neves /Walter Shultz (ANSAC)

• 2h40 Brazilian Climate Changes Stefan David Abividro

• 3h Oxygen Enhanced Nox Reduction Abilio Tasca Praxair – White

• 3h20 Quality Control of Cullet Marcos Gibim Verallia – CETEV

• ----------------------------------------------------------------------------------------------------------------------------------

• 9h40 Made in Germany for Glass People K. Rudolph GPS - Verallia

• 10h Speedline - Evolution in IS machines Rainer Heidemann Heye International

• 10h20 Brazilian Law on Wastes Ana Paula Bernardes Abividro

• 10h40 CeRTEV- Center for Research, Technology and Education in Vitreous Materials

Edgar Zanotto CeRTEV/UFSCar

Corning Inc. Research Summit,

Corning, USA June 2014

• EDZ talk

LaMaV

industry net

NSG, Japan

viscous flow

CTA, Brazil

Armor GC

Vitrovita & DMC, Brazil

bioG and CG Optigrate, USA

PTRG

AGY, USA

special fibers

Saxon Glass?

chem. tough

Neogres?

sintered G & GC

Ivoclar?

Dental GC

Corning, USA

GR Status & trends

Current projects with companies

Ongoing

GC Armors, CTA, Brazil

Bioactive GC for dental and medical use – Vitrovita / DMC, Brazil

Photo-thermo-crystallization PTRG – OptiGrate, USA

Viscous flow and crystal growth in glasses, NSG, Japan

Special glass fibers , AGY, USA

Glass containers , O-I, USA

In negociation

Dental GC - Ivoclar, Liechtenstein (NDA signed)

LGLT GC – Phillips, Netherlands (testing)

Chemically toughened glass- Saxon Glass, USA (neg.)

Sintered GC / GC tiles - UNIGRES, Brazil (negociation)

Example - Bio G and GC technologies being developed

Manta Flexível

Pós Grânulos Prótese Ocular Implantes Recobertos

Scaffolds Prótese de Ouvido Médio

Recent CeRTEV Patents

• Leo et al – Armor transparent GC (2013)

• Marina et al – New bioactive fiberizable GC (2013)

• Clever et al – Bioactive coating for Ti (2014)- deposited

• Marina et al – Fiber drawing machine (2014) -

• Zanotto et al.- “REFORMIX Glass - Software for formulation of glass compositions having combined properties” (2014)

• EDZ - The best putter in the world (2014)!

Education and Outreach

Discussion group / Brazilian glass researchers and

engineers – active

Kit for demonstration of optical phenomena for

undergraduate or high school students - ready

Colored glass kits - ready

Web-site with educational videos - ready

Virtual museum of glass (under construction)

EDUCATION AND OUTREACH

Creation of the first technical course in South

America

Being aware of the lack of professional

training course dedicated to the glass industry,

with the partnership of Paula Souza Center,

we proposed to create a technical course to

provide trained professionals for the glass

industry.

EDUCATION AND OUTREACH

What we have done so far:

First meeting: presentation of our project CeRTEV and Education and

outreach project to ABIVIDRO

Second Meeting: Joint meeting with ABIVIDRO and Paula Souza Center

- ABIVIDRO confirmed to Paula Souza Center the urgent need for

professional qualification, specially at technical level, to the glass industry.

Paula Souza Center asked to describe all technical positions (cargos

técnicos)

Third meeting: we described the technical positions for the glass (flat and

hollow ) fabrication , glass transformation, and also glass specification for

construction

Next step: a memorandum of agreement between ABIVIDRO, Paula

Souza Center and CeRTEV, aiming the consolidation of this new technical

course must be prepared and signed

EDUCATION AND OUTREACH

Already done:

-ACIEPE: Engineers and Scientists of the Future - UFSCar

program aiming to demonstrate to elementary school students of

São Carlos the basis of “scientific thinking”, aiming to attract them

to the field of engineering and hard sciences.

-Meeting and agreement with the Secretary of Science and

Technology of São Carlos: participation in the program “Science

at School”

Same program with Araraquara

-School visits to LaMaV – glass melting, short talks and video

demonstrations to hundreds of high school students from all over

the State of São Paulo… (UFSCar open day and more…)

-Produce a video-course for architects about the fundamentals of

glasses and its specifications for architectural building.

-Offer the first class of the Paula Souza Center technical course in

2015

-Create a collection of demonstrational functional glasses

such as: electrically conducting glass, fotosensitive (PTRG) glass,

invisible gass, optical fiber, thermal strain in glass, metallic glass,

sugar glass…

How to use these functional glasses outside our classroom?

Physical Museum – planed for 2015

São Paulo (International) School of Structure, Crystallization and

Properties of Glasses – planed for 2015

Plans for 2014-2015

Aknowledgements

• São Paulo Research Foundation FAPESP

Grant # 2013/07199-6

37 years of equilibrium between

science & technology

LaMaV

Edgar D. Zanotto

LaMaV’s mission

TO EDUCATE excellent engineers and researchers

via good research and teaching

TO EXPAND the frontiers of knowledge /

via basic research / excellent publications!

TO ASSIST companies beyond their expectations / by

consulting + applied research

TO INNOVATE in the field of glass and related materials / via technological research

La MaV

NETWORK

Bio glass and GC

~15 instituições

Mastelaro/ Sneid, IFSC/ USP

P. C. Soares, UFPR

A. A. Cabral, CEFET, MA

E.B. Ferreira, EESC

J. Daguano- UFABC

F. Serbena e V.Soares - UEPG

Sheffield

1979

P. James*

Jena

1982

C. Russel

Grenoble

1984

J. L. Souquet

TC 7 / ICG

1985

Arizona

1987

M. Weinberg*

Florida

1994

L. Hench

Cyted/ CNPq, 1998

ICV - A. Duran

U. Medellin – C.

Paucar

IVSO Institute

1996, V. M. Fokin

CNEA, 1998

M. Prado

BAM, 1999

R. Muller

Bulg. Acad. Sci.

I. Avramov 2001

Univ. Rostock

J. Schmelzer 2001

ADEMAT, 2003

IC - A. Boccaccini

Max Plank –

A. Pyzalla

IMI

2004

Clausthal

J. Deubener

2005

CREOL/ UCF

L. Glebov

2005

UMR

R. Brow

2005

Douhausie

J. Zwanziger

2005

Optigrade, NSG, AGY, Vitrovita,Saxon, CTA

LaMaV´s

Brazilian

NETWORK

Bio glass and GC

~15 institutions

H.E., Mastelaro &

Schneider , Magon

IFSC

Ferreira

EESC

Soares

PUC-PR

Cabral

CEFET

Serbena &

Oliveira

UEPG e UEMA

Daguano

UFABC

CeRTEV

2012

TEAM ANNUAL BUDGET

Permanent

E.D. Zanotto / Crystallization & thermo-mechanical properties

O. Peitl - Bio glasses/ Chemical and thermo-mechanical properties

A.C.M. Rodrigues / Electrical properties

1 technician (Zé) ........................................... .............

US$ 430,000

Temporary

4 post docs

9 PhD students

2 MSc students

10 Internship students

1 secretary ........................................... 400,000

Materials & Supplies .......................................... 200,000

US$ 1,030,000.00

TOTAL NORMALIZED by PPP (1.0147/0.5336) ~2,000,000

Muito obrigado!

• Thank you very much!

• Vielen Dank! • Dziękuję !

• Hjärtligt tack ! • Muchas gracias!

• Merci beaucoup!

• Grazie mille!

University Ranking 1937-2013 glass*+vitreous+amorphous+non-crystalline

• > Tohoku University (1,660) + Tohoku University(1,287 ) Inoue’s • > Kyoto University(1,265)

• > CeRTEV: USP (476) + UNESP (278) + UFSCar (275) = 1029

• > Osaka University(938) • > Tokyo Institute of Technology(901) • > University of Cambridge(855) • > University of Tokyo(736) • > Massachusetts Institute of Technology(686) • > Friedrich Schiller Universität Jena(601) • > Pennsylvania State University(600) • > Universite Pierre et Marie Curie(572) • > Tsinghua University(571) • > University of Sheffield(525) • > Stanford University(516) • > California Institute of Technology(488) • > MoskovskijGosudarstvennyjUniversitet(483) • > Universite de Rennes 1(480) • > USP (476) • > Imperial College London(473) • > Kyushu University(460) • > Universite Montpellier 2 Sciences et Techniques(441) • > Hokkaido University(433) • > Nagoya University(430) • > University of Science and Technology Beijing(403) • > Wuhan University of Technology(403) • > Alfred University(401)