synthetic condensation polymers: dacron & nylon 6as group 3 kitty au-yeung giselle ho rachel...
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Synthetic Condensation polymers: Dacron & Nylon
6AS Group 3 Kitty Au-Yeung Giselle Ho
Rachel ChuiCici Tam
Angela Tsui
Positive impacts of development of polymers on our society
Plastics have replaced an increasing number of natural substances
Synthetic textile fibers have revolutionized the textile industry
the low cost, light weight, strength and design adaptability of plastics meet a variety of applications
Nylon replaced silk in military applications such as parachute and flak vests, and was used in many types of vehicle tires
A synthetic fiber manufacturing facility occupies a much smaller area of ground than would be needed to produce an equal quantity of natural fibers, such as cotton, wool or silk.
Negative impacts of development of polymers on our society
Birds may eat the plastic scraps mistakenly and dieFishing gear tangles up to form a net and kill sea creatures
Negative impacts of development of polymers on our society
Various nylons break down in fire and form hazardous smoke, and toxic fumes or ash, containing hydrogen cyanide
Some plastic contains toxic chemicals such as Phthalates which cause reproductive disorders
Some polymers are non-biodegradable and become solid waste which occupy many spaces in the landfill
The effect of structures on the properties of nylon
Hardness and rigidityable to crystallize mostly because of
strong intermolecular hydrogen bonds through the amide groups and because of Van der waal’s forces between the methylene chains
Crystallinity of nylons can be controlled by nucleation, i.e., seeding the molten polymer to produce uniform sized smaller spherulites
Hardness and rigidityIncrease with crystallinityReason for high crystallinity: 1. Polar planar amide (-CO-NH-)
groups result in multiple hydrogen bonds among adjacent strands of nylon
2. Nylon backbone is regular and symmetrical
Crystal structure of nylon 6 and nylon 6.6
Hardness and rigidityNylon 6.6:Have multiple parallel strands aligned with
their neighbouring peptide bonds at coordinated separations
the chains have no directionalityCarbonyl oxygens and amide hydrogens form
interchain hydrogen bonds repeatedly
Hardness and rigidityNylon 5,10:Have coordinated runs on 5 and 8 carbonsParallel strands participate in an extended, unbroken,
strong and tough super- molecular structureNylon 6:Form uninterrupted hydrogen-bonded sheets with
mixed directionalitiesadjacent chains are anti-parallel and the hydrogen
bonding is between adjacent chains within the same sheet (bisecting the CH2 angles
the chains are parallel and the hydrogen bonding is between chains in adjacent sheets
Hardness and rigidityWhen extruded into fibres…Individual polymer chains align because of
viscous flowFibres align further in the cold drawing
afterwardsCrystallinity is increased and hence hardness
as well as rigidity
Hydrolysis and degradabilityAll nylons are susceptible to hydrolysis(Strong acids
and water at high temperatures)Lower members of the nylons (such as nylon 6) are
affected more than higher members (such as nylon 12)Cannot be used in contact with sulphuric acid for
example, such as the electrolyte used in lead-acid batteries
Must be dried to prevent hydrolysis in the moulding machine barrel
By adding heat stabilizer can allow usage at elevated temperature for long-term performance
By adding carbon black can reduce the radiation degradation
Tensile strengthThe strength of nylon comes from amide groups in its
molecular chainA very regular shapeWell suited to create fabrics designed to stand up to
intense forcesUltra drawing of solidified crystalline material induces a
high degree of chain extension , which leads to very high tensile strength
Major material used in parachutes and ropes during the Second World War
Bullet-proof vests and other hard wearing items now
Model of extended molecule chain in
superdrawing fibre
The End