Structural Chemistry2016

Solutions of Homework 3 ProblemsChapter 5 & Chapter 6

Keisuke Goda Department of Chemistry

University of Tokyo

Problem 1 Rotational Spectrum of Spherical Rotor Molecules

Problem 1 Rotational Spectrum of Spherical Rotor Molecules

Problem 2 Centrifugal Distortion

Problem 3Rotational Raman Spectrum

2

Problem 3Rotational Raman Spectrum

Problem 4 Moment of Inertia(From PW Atkins, “Physical Chemistry”, Problem 13.21)

Problem 5 Moment of Inertia(From PW Atkins, “Physical Chemistry”, Problem 13.4)

Problem 5

Problem 6 Morse Oscillator

Problem 7Vibration Spectroscopy(From WS Struve, “Fundamentals of Molecular Spectroscopy”, Problem 3.3)

Problem 7

Problem 7

Problem 7

where

Problem 8 Vibration Spectroscopy(From WS Struve, “Fundamentals of Molecular Spectroscopy”, Problem 10.19)

Problem 9Vibration Spectroscopy(From PW Atkins, “Physical Chemistry”, Problem 13.14)

Problem 9

Problem 9Vibration Spectroscopy(From PW Atkins, “Physical Chemistry”, Problem 13.14)

Problem 10Vibration Spectroscopy(From PW Atkins, “Physical Chemistry”, Problem 13.12)

Problem 10