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Smells Unit – Investigation II Lesson 3: Connect the Dots

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Smells Unit – Investigation II. Lesson 3: Connect the Dots. ChemCatalyst. This is a drawing of the structural formula of a methane molecule. The lines represent bonds. Explain what you think a bond is. The Big Question. How can Lewis dot symbols help us to understand and predict bonding?. - PowerPoint PPT Presentation

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Page 1: Smells Unit – Investigation II

Smells Unit – Investigation II

Lesson 3:Connect the Dots

Page 2: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

ChemCatalyst

• This is a drawing of the structural formula of a methane molecule. The lines represent bonds. Explain what you think a bond is.

C H

H

H

H

Page 3: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

The Big Question

• How can Lewis dot symbols help us to understand and predict bonding?

Page 4: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

You will be able to:

• Draw the Lewis dot symbol for an element and predict how many covalent bonds it will make.

Page 5: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

• A covalent bond is a connection that forms between two atoms when those atoms are sharing a pair of electrons between them.

Notes

(cont.)

Page 6: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

• When we draw an atom using dots to represent the valence electrons it is called a Lewis dot symbol.

• When we draw a molecule using dots to represent the valence electrons it is called a Lewis dot structure.

Notes (cont.)

(cont.)

Page 7: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

• Nitrogen, with five valence electrons, would be drawn as follows:

N N N N Nstart here

• Notice that the Lewis dot symbol of nitrogen has three unpaired electrons and one electron pair. This means that nitrogen has three electrons that can potentially be paired up with electrons from other atoms.

Notes (cont.)

(cont.)

Page 8: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

C H

H

H

H

CH

H

H

H

CH H

H

H

CH

H

H

H

Notes (cont.)

Page 9: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

• HONC 1234 is a simple, catchy phrase reminding us about the bonding of hydrogen, oxygen, nitrogen and carbon. This easy-to-remember phrase reminds us how many bonds each element usually makes within a molecule.

Notes

(cont.)

Page 10: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Activity

Purpose: In this lesson you will begin to understand why atoms connect to each other the way they do. You will be introduced to a tool, called Lewis dot symbols, which will assist you in building molecules and predicting how many bonds an element will have.

(cont.)

Page 11: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

C N O F Ne

Si P S Cl Ar

(cont.)

(cont.)

Page 12: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Group number IV V VI VII VIII

Number of bonds

First row elements C N O F Ne

Second row elements Si P S Cl Ar

(cont.)

(cont.)

Page 13: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

CH4 + CH

H

H

H

NH3 +

OH2 +

(cont.)

Page 14: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Making Sense

• Based on what you’ve learned in this lesson, explain why the HONC 1234 rule works.

Page 15: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

C HON

CH O N

(cont.)

Notes

Page 16: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

• Bonded pair refers to a pair of electrons that are involved in bonding between two different atoms.

• Lone pair refers to a pair of electrons that are not involved in bonding but are paired up within an atom.

• A single electron is sometimes referred to as an unpaired electron.

N H

H

H

lone pair of electrons

bonded pair of electrons

Notes (cont.)

Page 17: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Check-In

• Draw the Lewis dot symbol for the element I, iodine. Explain how you arrived at your particular drawing.

• How many covalent bonds does iodine make?

Page 18: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Wrap-Up

• A covalent bond is one in which two atoms share valence electrons.

• In a Lewis dot structure, pairs of electrons that are not bonded are referred to as lone pairs.

• HONC 1234 indicates how many unpaired electrons are associated with hydrogen, oxygen, nitrogen and carbon.

Page 19: Smells Unit – Investigation II

Smells Unit – Investigation II

Lesson 4:Eight is Enough

Page 20: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

ChemCatalyst

• Draw the Lewis dot structure for the following covalently bonded molecule. Explain how you arrived at your answer.

Cl2

Page 21: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

The Big Question

• How can we use Lewis dot structures to help draw structural formulas?

Page 22: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

You will be able to:

• Predict whether a given compound would be stable and likely to be found in nature.

Page 23: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Cl Cl+ Cl Cl

Notes

Page 24: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Activity

Purpose: In this lesson you will use Lewis dot structures to create structural formulas of molecules containing elements in addition to H, O, N, and C. You will look for patterns in the number of electrons surrounding each atom in a Lewis dot structure in order to develop further understanding of bonding.

(cont.)

Page 25: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Br2 H2S PH3 SiH4

(cont.)

(cont.)

Page 26: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

CCl4 C+

Cl

Cl

Cl

Cl

P F+ 3 P

F

FF

P F

F

F

(cont.)

Page 27: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Making Sense

• The noble gases do not form bonds with other atoms (except under very extreme conditions). Explain why you think this might be true (use your Lewis dot structures).

Page 28: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

• Atoms of most elements are very reactive.• They become stable (the opposite of

reactive) when they combine with other atoms to form compounds.

• The more stable a molecule is, the more likely we are to find that it exists in nature.

• The octet rule states that atoms tend to form bonds by sharing valence electrons until eight valence electrons surround each atom.

Notes

Page 29: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Check-In• Which of the following formulas satisfy

the HONC 1234 rule?• Which of the following formulas satisfy

the octet rule?• Which of the following formulas

represent stable compounds we might find in the world around us?

a) CH3 b) CH4

Page 30: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Wrap-Up

• Elements form bonds by sharing electrons until each atom has the same number of valence electrons as the noble gas in the same row of the periodic table — this is called the octet rule.

Page 31: Smells Unit – Investigation II

Smells Unit – Investigation II

Lesson 5:Dots, Dots, and More Dots

Page 32: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

ChemCatalyst

• Here are the structural formulas for N2 (nitrogen gas), O2 (oxygen gas), and F2 (fluorine gas). Draw the Lewis dot structures for these three molecules.

N N O O F F

Page 33: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

The Big Question

• How do we draw a Lewis dot structure for a molecule?

Page 34: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

You will be able to:

• Use Lewis dot symbols to draw a possible structure for a C2H4O2 molecule.

Page 35: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Draw Lewis dot symbols for C and two O atoms:

Bring atoms together:

Create double bonds:

C O Oand and

CO O

CO O

Notes

Page 36: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Activity

Purpose: In this lesson you will work to create structural formulas for various molecules. You will start with the Lewis dot structures of individual atoms. These atoms can then be arranged in more than one way to create molecules. Finally, structural formulas will be translated from the Lewis dot representations. (cont.)

Page 37: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Start with these atoms…

Draw the Lewis structure for the starting atoms

Add hydrogen atoms to satisfy

the octet rule

How many H’s are

needed?

Draw the structural formula for the molecule

Write the molecular

formula for the molecule

2 carbon atoms bonded together

1 carbon atom and 1 oxygen

atom

1 carbon atom and 1 nitrogen

atom

1 carbon atom and 2 oxygen

atoms

(cont.)

Page 38: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Making Sense

• Explain how HONC 1234 assists you in checking out the structural formulas you create.

Page 39: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Check-In

• We know two things about a certain molecule. We know that its molecular formula is C2H4O2 and we know that it has one C=O in it. Using Lewis dot symbols and the octet rule to guide you, draw at least one possible structure for this molecule. (There are a total of three possible.)

Page 40: Smells Unit – Investigation II

Unit 2 • Investigation II

© 2004 Key Curriculum Press.

Wrap-Up

• Atoms can form double and triple bonds to satisfy the octet rule.