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Shell Canada, Sarnia Manufacturing Center December 2013 Phase 2 Toxic Substance Reduction Plans Page 15

Confidential Commercially Sensitive Information

8. Certification By Licensed Planner As of December 20, 2013, I, Melanie Hockin, certify that I am familiar with the processes at Shell SMC that use or create the toxic substances referred to below, that I agree with the estimates referred to in subparagraphs 7 iii, iv and v of subsection 4 (1) of the Toxics Reduction Act, 2009 that are set out in the plan dated October 1, 2013 and that the plans comply with that Act and Ontario Regulation 455/09 (General) made under that Act.

Toxic Substance Date of the Plan to which the Certification Applies

Acetone December 20,2013 TRS compounds December 20,2013

Hydrogen sulphide December 20,2013 1,2,4-trimethylbenzene December 20,2013

Ammonia December 20,2013 Cyclohexane December 20,2013

Diethanolamine December 20,2013 Ethylene December 20,2013 Iso-propanol December 20,2013

Isopropyl benzene (cumene) December 20,2013 N-Hexane December 20,2013 Propylene December 20,2013 Fluorene December 20,2013

Light Aliphatic Naphtha December 20,2013 Octane (all isomers) December 20,2013

Propane December 20,2013 Butane (all isomers) December 20,2013 Butene (all isomers) December 20,2013

Heptane (all isomers) December 20,2013 Pentane (all isomers) December 20,2013 Pentene (all isomers). December 20,2013

PM December 20,2013 PM10 December 20,2013 PM2.5 December 20,2013 NOx December 20,2013 SO2 December 20,2013 CO December 20,2013

Melanie Hockin Environmental Specialist LEHDER Environmental Services Limited Licence # TSRP0140

Toxic Reduction Plan Summary

SubstanceSubstance Name and CAS # Acetone 67-64-1

Substances for which other plans have been prepared

Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorine, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).

Beneficial Uses/Reasons for Use and Creation at Facility:

Acetone is a by-product incidentally created during the production of isopropyl alcohol

Previously Implemented Reduction Activities

Shell SMC has previously implemented the following reduction activities:

Spill Prevention and Containment Plan and LDAR (Leak Detection and Repair) program already established, all tanks have secondary containmentEngineering standards for pipe seal design etc. has been continuously improved to reduce leaksESP (Ensure Safe Production) in place, includes mandated/scheduled operator rounds (visual inspection etc.)LEL detection and alarmingIncident Investigation process - continuous improvementSafeguarding Reviews and Pressured Equipment Integrity Programs in placeLDAR leaker definition set at 1000 ppmMost tankage containing volatiles are IFRT, industry standard

Facility InformationCompany Name Shell Canada ProductsFacility Name Shell Sarnia Manufacturing Center

Facility Physical Address150 St. Clair ParkwayP.O.Box 2000Corunna, ON N0N 1G0

Facility Mailing Address Same as physical addressSpatial Coordinates of Facility 381535.44

Toxic Reduction Plan Summary, Continued ii

(UTM, NAD83) 4751009.02Number of Employees 289NPRI ID 3962

2 Digit NAICS Code 31-33

4 Digit NAICS Code 3241 / 3251


Parent Company Information

Parent Company Name Shell Canada Limited

Address400 4th Avenue SouthwestCalgary, ABT2P0J4

Percent Ownership 100%

Facility Contact

Public Contact Kristina Zimmer

Address150 St. Clair ParkwayP.O.Box 2000Corunna, ON N0N 1G0

emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Acetone in its operations because no further feasible options were identified. Whenever practicable, we will eliminate, or reduce the discharge of Acetone in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the creation of Acetone, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Acetone through current and future pollution prevention and best management practices.

Description of SubstanceAcetone is created in the production of iso-propyl alcohol.

Toxic Substance Reduction Option(s) To Be Implemented

Toxic Reduction Plan Summary, Continued iii

For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Acetone in its operations. There were no feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Acetone, prepared by Shell SMC, dated December 20, 2013.


Substance

Substance Name and CAS # Reduced sulphur and compounds (No single CAS applies to this compound)


Lead, Mercury, Benzene, Toluene, Ethylbenzene , Naphthalene, Xylene, PAHs, Methanol, Asbestos, Sulphuric Acid, Tetrachloroethylene Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).

Beneficial Uses/Reason for Use or Creation at Facility

Reduced sulphur and compounds is a component of the crude input materialReduced sulphur and compounds are destroyed at the facility in order to reduce emissions and produce liquid sulphur, a valuable co-product of the refinery



Sulphur Recovery Unit utilizes a feedstock (reduced sulphur and compounds) that could otherwise be a waste stream

increased synthetic crude

Spill Prevention and Containment Plan and LDAR (Leak Detection and Repair) program already established, all tanks have secondary containment

Engineering standards for pipe seal design etc. has been continuously improved to reduce leaks

ESP (Ensure Safe Production) in place, includes mandated/scheduled operator rounds (visual inspection etc.)

LEL detection and alarming

OWS system captures leaks/spills, then recycled back into process

Incident Investigation process - continuous improvement

Safeguarding Reviews and Pressured Equipment Integrity Programs in place

LDAR leaker definition set at 1000 ppm


Most tankage containing volatiles are IFRT, industry standard



Facility Mailing Address Same as physical addressSpatial Coordinates of Facility (UTM, NAD83)

381535.444751009.02

Number of Employees 289NPRI ID 3962








Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of reduced sulphur and compounds in its operations because it is a naturally occurring component of the feedstock. Whenever practicable, we will eliminate, or reduce the discharge of Reduced sulphur and compounds in full compliance with all Federal and Provincial Regulations.


Plan ObjectivesWhile Shell SMC does not intend to reduce the use of Reduced sulphur and compounds,the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Reduced sulphur and compounds through current and future pollution prevention and best management practices.

Description of SubstanceReduced sulphur and compounds is naturally present in very small concentrations in the raw material, crude oil.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of reduced sulphur and compounds in its operations because it is a naturally occurring component of the feedstock. In the past, SMC has installed the Sulphur Recovery Unit which utilizes reduced sulphur and compounds to produce liquid sulphur a valuable co-product. Additionally, multiple activities have been implemented to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Reduced sulphur and compounds, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Hydrogen Sulphide 7783-06-4


Lead, Mercury, Benzene, Toluene, Ethylbenzene , Naphthalene, Xylene, PAHs, Methanol, Asbestos, Sulphuric Acid, Tetrachloroethylene Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, reduced sulphur and compounds, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).


Hydrogen sulphide is a component of the crude input materialHydrogen sulphide is destroyed at the facility in order to reduce emissions and produce liquid sulphur, a valuable co-product of the refinery



Sulphur Recovery Unit utilizes a feedstock(hydrogen sulphide) that could otherwise be a waste stream

increased synthetic crude














381535.444751009.02









Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of hydrogen sulphide in its operations because it is a naturally occurring component of the feedstock. Whenever practicable, we will eliminate, or reduce the discharge of Hydrogen sulphide in full compliance with all Federal and Provincial Regulations.

Plan Objectives


While Shell SMC does not intend to reduce the use of Hydrogen sulphide, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Hydrogen sulphide through current and future pollution prevention and best management practices.

Description of SubstanceHydrogen sulphide is naturally present in very small concentrations in the raw material, crude oil.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of hydrogen sulphide in its operations because it is a naturally occurring component of the feedstock. In the past, SMC has installed the Sulphur Recovery Unit which utilizes hydrogen sulphide to produce liquid sulphur a valuable co-product. Additionally, multiple activities have been implemented to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Hydrogen sulphide, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # 1,2,4-Trimethylbenzene 95-63-6


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).

Beneficial Uses/Reasons for Use and Creation at Facility

1,2,4 Trimethylbenzene is a component of the crude raw material1,2,4 Trimethylbenzene is created and used as a component of gasoline and jet fuel












Effort to control de-salter upsets to reduce oil into OWS

Improved Decontamination Procedures which may include removal with Vacuum trucks for reprocessing via slop tank and optimized residual transfer in shut-down and decontamination procedures.





381535.444751009.02









Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of 1,2,4 Trimethylbenzene in its operations because it is a naturally occurring component of the feedstock and an end product. Whenever practicable, we will eliminate, or reduce the discharge of 1,2,4-Trimethylbenzene in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use or creation of 1,2,4-Trimethylbenzene,the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; and


we will continue to manage releases of 1,2,4-Trimethylbenzene through current and future pollution prevention and best management practices.

Description of Substance1,2,4-Trimethylbenzene is a component in the crude and is also produced in process streams that are blended into gasoline and jet fuel, which are sold as products.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of 1,2,4-Trimethylbenzene in its operations because it is a naturally occurring component of the feedstock and an end product. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for 1,2,4-Trimethylbenzene, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Ammonia 7664-41-7


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).


Ammonia is used in the Jet TreaterAmmonia is created in the refining process



PLC program utilized to automate dosing and prevent overuse

Spill Prevention and Containment Plan already established, material storage has secondary containment

Dedicated storage vessels utilized, therefore no cleanouts/waste product

Specific Operating Procedures in place due to handling hazards




381535.444751009.02










Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meetings its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of Ammonia in its operations because no feasible options were identified. Whenever practicable, we will eliminate, or reduce the discharge of ammonia in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use or creation of Ammonia, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Ammonia through current and future pollution prevention and best management practices.

Description of SubstanceAmmonia is used in the Jet Treater. It is also created in the crude units during the refining process.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of Ammonia in its operations because it plays a critical role in the process. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.


Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Ammonia, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Cyclohexane 110-82-7


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).


Cyclohexane is utilized in the azeotropic distillationof iso-propyl alcoholCyclohexane is not created



PLC program utilized to automate dosing and prevent overuse







LDAR leaker definition set at 1000 ppmMost tankage containing volatiles are IFRT, industry standard





381535.444751009.02









Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meetings its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of cyclohexane in its operations because no feasible options were identified. Whenever practicable, we will eliminate, or reduce the discharge of Cyclohexane in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use of Cyclohexane, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Cyclohexane through current and future pollution prevention and best management practices.


Description of SubstanceCyclohexane is used as a processing aid in the azeotropic distillation of iso-propyl alcohol. Therefore it is an integral part of the manufacturing process.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of Cyclohexane in its operations because it plays a critical role in the process. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Cyclohexane, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Diethanolamine 111-42-2


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).

Beneficial Uses/Reasons for Use and Creation at Facility:

Diethanolamine is essential to the Girbitol process to remove H2S from gas streams



improved reliability of Girbitol system to prevent process upsets PLC program utilized to automate dosing and prevent overuseSpill Prevention and Containment Plan already established, material storage has secondary containmentDedicated storage vessels utilized, therefore no cleanouts/waste productSpecific Operating Procedures in place due to handling hazards




381535.444751009.02










Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of Diethanolamine in its operations because no further feasible options were identified.Whenever practicable, we will eliminate, or reduce the discharge of Diethanolamine in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use of Diethanolamine, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Diethanolamine through current and future pollution prevention and best management practices.

Description of SubstanceDiethanolamine is used in the Girbitol process to remove H2S from gas streams

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of Diethanolamine in its operations because it plays a critical role in the process. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.


Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Diethanolamine, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Ethylene 74-85-1


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).


There are no beneficial uses for ethylene at SMCEthylene is a byproduct of the refining operation














381535.444751009.02

Number of Employees 289


NPRI ID 3962








Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Ethylene in its operations because no feasible options were identified which have not already been implemented. Whenever practicable, we will eliminate, or reduce the discharge of Ethylene in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the creation of Ethylene, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Ethylene through current and future pollution prevention and best management practices.


Description of SubstanceEthylene is a by-product created in the refining process.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Ethylene in its operations. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Ethylene, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Iso-propanol 67-63-0


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).

Beneficial Uses at Facility/Reasons for Use and Creation

Iso-propanol is created and sold as an end-productIso-propanol is also used in small amounts in the BTX Unit



Spill Prevention and Containment Plan and Leak Detection And Repair program already established, all tanks have secondary containment




OWS system captures leaks/spills, and Iso-propanolwill be processed at WWTP






Facility Mailing Address Same as physical addressSpatial Coordinates of Facility 381535.44


(UTM, NAD83) 4751009.02Number of Employees 289NPRI ID 3962








Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of Iso-propanol in its operations because it is an end product. Whenever practicable, we will eliminate, or reduce the discharge of Iso-propanol in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use or creation of Iso-propanol, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Iso-propanol through current and future pollution prevention and best management practices.

Description of SubstanceIso-propanol is created as an end product and used as a processing aid in the reforming process.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of Iso-propanol in its operations because it is an end product. In the past, SMC has implemented multiple programs to reduce spills/leaks and


discharges. There were no further feasible (technical and economical) reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Iso-propanol, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Isopropyl Benzene 98-82-8


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).


Isopropyl Benzene is a component of the crude raw materialIsopropyl Benzene is and used as a component ofmany end products


















381535.444751009.02









Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or of Isopropyl Benzene in its operations because it is a naturally occurring component of the feedstock and an end product. Whenever practicable, we will eliminate, or reduce the discharge of Isopropyl Benzene in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use of Isopropyl Benzene, the plan wasdeveloped with the following objectives:



we will continue to manage releases of Isopropyl Benzene through current and future pollution prevention and best management practices.

Description of SubstanceIsopropyl Benzene is a component in the crude and exists in many end products.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of Isopropyl Benzene in its operations because it is a naturally occurring component of the feedstock and an end product. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Isopropyl Benzene, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # n-Hexane 110-54-3


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).


n-Hexane is a component of the crude raw materialn-Hexane is created and used as a component of gasoline and other products


















381535.444751009.02









Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of n-Hexane in its operations because it is a naturally occurring component of the feedstock and an end product. Whenever practicable, we will eliminate, or reduce the discharge of n-Hexane in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use or creation of n-Hexane , the plan was developed with the following objectives:



we will continue to manage releases of n-Hexane through current and future pollution prevention and best management practices.

Description of Substancen-Hexane is a component in the crude as well as created and used as a component of gasoline and other products

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of n-Hexane in its operations because it is a naturally occurring component of the feedstock and an end product. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for n-Hexane, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Propylene 115-07-1


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).

Beneficial Uses at Facility/Reasons for Use and Creation

Propylene is a key intermediate in the production of Isopropanol (a core product of SMC)



Spill Prevention and Containment Plan and Leak Detection And Repair program already established, all tanks have secondary containment




OWS system captures leaks/spills, and Propylenewill be processed at WWTP







Facility Mailing Address Same as physical address


Spatial Coordinates of Facility (UTM, NAD83)

381535.444751009.02









Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of Propylene in its operations because it is a key intermediate in the production of Isopropanol, a core end product. Whenever practicable, we will eliminate, or reduce the discharge of Propylene in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use or creation of Propylene, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Propylene through current and future pollution prevention and best management practices.

Description of SubstancePropylene is a key intermediate in the production of Isopropanol.

Toxic Substance Reduction Option(s) To Be Implemented


For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of Propylene in its operations because it is a key intermediate in the production of Isopropanol, an end product. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible (technical and economical) reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Propylene, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Fluorene 86-73-7


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).


Fluorene is a naturally occurring component of crudeFluorene has no beneficial use at this facility



Spill Prevention and Containment Plan and LDAR (Leak Detection and Repair)program already established, all tanks have secondary containment










381535.444751009.02



2 Digit NAICS Code 31-334 Digit NAICS Code 3241 / 32516 Digit NAICS Code 324110 / 325190





Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of fluorene in its operations because it is a naturally occurring component of the feedstock.Whenever practicable, we will eliminate, or reduce the discharge of Fluorene in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use of Fluorene, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Fluorene through current and future pollution prevention and best management practices.

Description of SubstanceFluorene is a component in the crude and thus present in the manufacturing process.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of Fluorene in its operations because it is a naturally occurring component of the feedstock. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary Statement


This plan summary accurately reflects the content of the toxic substance reduction plan for Fluorene, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Light Aliphatic Naphtha 64742-89-8


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).

Beneficial Uses/Reasons for Useand Creation at Facility

Light Aliphatic Naphtha is created from crude oil raw material during the refining process Light Aliphatic Naphtha is a component of several SMC solvent products

















381535.444751009.02









Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Light Aliphatic Naphtha in its operations because it is a byproduct of reactions within the crude refining processes at the site. Whenever practicable, we will eliminate, or reduce the discharge of Light Aliphatic Naphtha in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the creation of Light Aliphatic Naphtha, the plan was developed with the following objectives:



we will continue to manage releases of Light Aliphatic Naphtha through current and future pollution prevention and best management practices.

Description of SubstanceLight Aliphatic Naphtha is created from crude oil raw material during the refining process.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Light Aliphatic Naphtha in its operations because it is abyproduct of reactions within the crude refining processes at the. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Light Aliphatic Naphtha, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Octane and its isomers NA-1903


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers).


Octane and its isomers are a component of the crude raw material














Facility Physical Address 150 St. Clair ParkwayP.O.Box 2000


Corunna, ON N0N 1G0


381535.444751009.02









Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of Octane and its isomers in its operations because it is a naturally occurring component of the feedstock. Whenever practicable, we will eliminate, or reduce the discharge of Octane and its isomers in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use of Octane and its isomers, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Octane and its isomers through current and future pollution prevention and best management practices.

Description of Substance


Octane and its isomers are a naturally occurring component of the feedstock.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use of Octane and its isomers in its operations because it is a naturally occurring component of the feedstock. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Octane and its isomers, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Speciated VOC (various CAS)

CAS #:

Propane 74-98-6Butane and its isomers No single CAS appliesButene and its isomers No single CAS appliesHeptane and its isomers No single CAS appliesPentane and its isomers No single CAS appliesPentene and its isomers No single CAS applies


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, PM, PM10, PM2.5, NOx, SO2, CO, light aliphatic naphtha, octane (all isomers)


Some Speciated VOC are naturally occurring components of crude.Some Speciated VOC are used in product blending.



Spill Prevention and Containment Plan and LDAR (Leak Detection and Repair)program already established, all tanks have secondary containment









Facility Mailing Address Same as physical address


Spatial Coordinates of Facility (UTM, NAD83)

381535.444751009.02

Number of Employees 289NPRI ID 39622 Digit NAICS Code 31-334 Digit NAICS Code 3241 / 32516 Digit NAICS Code 324110 / 325190





Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of speciated VOC in its operations because it is a naturally occurring component of the feedstock and byproduct of processes at the site.. Whenever practicable, we will eliminate, or reduce the discharge of Speciated VOC in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the use or creation of Speciated VOC, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Speciated VOC through current and future pollution prevention and best management practices.

Description of SubstanceSpeciated VOC is a component in the crude and other feedstock and thus present in the manufacturing process. Some are also used in blends to increase end product octane.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the use or creation of Speciated VOC in its operations because it is a naturally


occurring component of the feedstock and byproduct of reactions within the processes at the site. In the past, SMC has implemented multiple programs to reduce spills/leaks and discharges. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Speciated VOC, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Particulate Matter and Size Fractions (PM, PM10, PM2.5)CAS #: No single CAS # applies to these substances


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene,ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers),Criteria Air Contaminants


Particulate Matter and Size Fractions are created at this facilityParticulate Matter and Size Fractions have no beneficial use at this facility



Road paving

Catalyst handling procedures to minimize particulate emissions

Reducing liquid fuel combustion




381535.444751009.02







Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Particulate Matter and Size Fractions because no feasible options are available.Whenever practicable, we will eliminate, or reduce the discharge of Particulate Matter and Size Fractions in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the creation of Particulate Matter and Size Fractions, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Particulate Matter and Size Fractionsthrough current and future pollution prevention and best management practices.

Description of SubstanceParticulate Matter and Size Fractions are created in combustion processes and catalyst handling.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Particulate Matter and Size Fractions in its operations because no feasible options were identified. In the past, SMC has implemented multiple programs to minimize emissions of Particulate Matter and Size Fractions. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Particulate Matter and Size Fractions, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Sulphur DioxideCAS #: 7446-09-5


Benzene, ethylbenzene, naphthalene, toluene, xylene, cadmium, lead, mercury, various PAH's, methanol, sulphuric acid, tetrachloroethylene, fluorene, acetone, TRS compounds, hydrogen sulphide, 1,2,4-trimethylbenzene, ammonia, cyclohexane, diethanolamine, ethylene, iso-propanol, isopropyl benzene (cumene), n-hexane, propylene, light aliphatic naphtha, octane (all isomers), propane, butane (all isomers), butene (all isomers), heptane (all isomers), pentane (all isomers), pentene (all isomers),Criteria Air Contaminants


Sulphur Dioxide is created in combustion processes at this facilitySulphur Dioxide has no beneficial use at this facility



Sulphur Recovery Unit

Switched to lower sulphur fuels

Increased processing of synthetic crude




381535.444751009.02







Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creationof Sulphur Dioxide because no further feasible options are available. Whenever practicable,we will eliminate, or reduce the discharge of Sulphur Dioxide in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the creation of Sulphur Dioxide, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Sulphur Dioxide through current and future pollution prevention and best management practices.

Description of SubstanceSulphur Dioxide is created in combustion processes.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Sulphur Dioxide in its operations because no feasible options were identified. In the past, SMC has implemented multiple programs to minimize emissions of Sulphur Dioxide. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Sulphur Dioxide, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Nitrogen OxidesCAS #: 11104-93-1




Nitrogen Oxides are created in combustion processes at this facilityNitrogen Oxides have no beneficial use at this facility



Energy recovery projects reducing fuel consumption

Low-NOx burners installed on ~25% heaters




381535.444751009.02







Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creationof Nitrogen Oxides because no further feasible options are available. Whenever practicable,we will eliminate, or reduce the discharge of Nitrogen Oxides in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the creation of Nitrogen Oxides, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Nitrogen Oxides through current and future pollution prevention and best management practices.

Description of SubstanceNitrogen Oxides are created in combustion processes

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Nitrogen Oxides in its operations because no feasible options were identified. In the past, SMC has implemented programs to minimize emissions of Nitrogen Oxides. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Nitrogen Oxides, prepared by Shell SMC, dated December 20, 2013.


SubstanceSubstance Name and CAS # Carbon MonoxideCAS #: 630-08-0




Carbon Monoxide is created in combustion processes at this facilityCarbon Monoxide is utilized as an energy source in the CO boilers



Burner optimization is an ongoing program to reduce emissions through optimization of parameters and combustion conditions




381535.444751009.02







Facility Contact



emailPhone (519)481-1135Fax (519)481-1288

Statement of IntentShell is responsible for meeting its environmental commitments. For the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Carbon Monoxide because no further feasible options are available. Whenever practicable, we will eliminate, or reduce the discharge of Carbon Monoxide in full compliance with all Federal and Provincial Regulations.

Plan ObjectivesWhile Shell SMC does not intend to reduce the creation of Carbon Monoxide, the plan was developed with the following objectives:

we will continue to operate in full compliance with all applicable environmental regulations; andwe will continue to manage releases of Carbon Monoxide through current and future pollution prevention and best management practices.

Description of SubstanceCarbon Monoxide is created in combustion processes.

Toxic Substance Reduction Option(s) To Be ImplementedFor the purposes of the Toxics Reduction Act, SMC will not be implementing any options to reduce the creation of Carbon Monoxide in its operations because no feasible options were identified. In the past, SMC has implemented multiple programs to minimize emissions of Carbon Monoxide. There were no further feasible reduction options identified.

Plan Summary StatementThis plan summary accurately reflects the content of the toxic substance reduction plan for Carbon Monoxide, prepared by Shell SMC, dated December 20, 2013.

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