sand and sulphur - mhisafety and sulphur msds book 2015 fi… · sand and sulphur index 2015 ......

Sand and Sulphur

2015 MSDS Collection

Sand and Sulphur Index 2015

Manufacturer Product Name Revision Date

Amerex Corporation. ABC Dry Chemical Fire Extinguishant

October 17, 2013

Brenntag Canada Inc Methanol January 10, 2014 Chevron Products Co. Regal R&O 22, 32, 46, 68,

100, 115, 150 April 21, 2015

Co-op Ltd Sonic ATF August 22, 2012

Co-op Ltd Sonic Blue Guard May 20, 2014

Co-op Ltd Sonic Moly Guard SL April 24, 2015 Co-op Refineries Ltd Diesel Distillate December 18, 2012

Co-op Refineries Ltd Sonic ATF Type F July 31, 2012 Co-op Refineries Ltd Sonic Industrial Gear Oil May 20, 2014

Co-op Refineries Ltd Sonic MP Gear Oil July 31, 2012

Co-op Refineries Ltd. D-MO November 13, 2012 Co-op Refineries Ltd Industrial Hydraulic Oil July 31, 2012

Degil safety Products Croc Bloc SPF30 Liquid Spray lotion

January 29, 2015

Degil safety Products Croc Bloc Insect Repellent Foam

January 29, 2015

Degil safety Products Croc Bloc Heavy duty Insect Repellent Aerosol

January 29, 2015

Federated Coop Trans Hydraulic Fluid September 20, 2012 Husky Oil Marketing Co.

Penetration Grade Asphalt Cement

PG 150/200A Asphalt: 0339

PG 46-37(300/400A) Asphalt Cement: 0320 PG 52-34(200/300A)

Asphalt Cement: 0341 PG 58-28 Asphalt

Cement: 0350 PG 58-28(120/150A)

Asphalt Cement: 0334 PG 58-31(120/150A)

Asphalt Cement: 0334

February 19, 2015

PG 64-22(80/100A) Asphalt Cement: 0330

PG 64-25(80/100A) Asphalt Cement: 0330 PG 67-22 (PG 64-22)

Asphalt Cement: 0351 PG 70-22 Asphalt

Cement: 0352

Nemco Resources Ltd. Windshield Washer Fluid WWAF-40&WWAF-35

August 01, 2013

Nemco Resources Ltd. Diesel Fuel Conditioner October 01, 2013

Nemco Resources Ltd. SR-1 Antifreeze and Coolant

October 01, 2013

Petro- Canada. Diesel Fuel May 14, 2015

Petro- Canada. Gasoline, Unleaded May 14, 2015 Petro- Canada. Propane March 30, 2015

Shell Canada Ltd. Regular Unleaded Gasoline

April 01, 2015

Shell Canada Ltd. Shell Thiopave Asphalt Mix Modifier

October 07, 2013

Tiger-Sul Products (Canada) Co.

TIGER Elemental Sulphur 99.5%

November 01, 2012

Discontinued or Out of Date

Manufacturer Product Name Last Revision Date

Chevron Products Co. Regal R&O ISO 220 – ISO 680

February 21, 2008

Co-op Ltd. Kerosene July 12, 2012 Co-op Ltd. Solvent July 12, 2012

Co-op Refineries Ltd. Gasoline – Ethanol Blended

July 19, 2012

Co-op Refineries Ltd. Industrial Hydraulic All-Weather SL

December 07, 2011

Co-op Refineries Ltd. Propane – Liquefied Petroleum Gas

July 19, 2012

Co-op Refineries Ltd. Trans Hydraulic Fluid December 07, 2011

Petro- Canada Petrosol 3355 June 22, 2012

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SAFETY DATA SHEET

Product Name: ABC Dry Chemical Fire Extinguishant Other Identifiers: Multi-purpose Dry Chemical Product Code(s): CH555, F13,F11 Model Code(s) of Extinguishers: 402, IS 18ABC, IS35ABC, IS 45ABC, 13ABC,

V25ABC, VH25ABC, V30ABC, VH30ABC, V50ABC, VS50ABC, VS75ABC, V250ABC

Recommended Use: Fire suppression, not for human or animal drug use. Manufacturer: AMEREX CORPORATION Internet Address: www.amerex-fire.com Address: 7595 Gadsden Highway, P.O. Box 81 Trussville, AL 35173-0081 Company Telephone: (205) 655-3271 E-mail Address: [email protected] Emergency Contacts: Chemtrec 1(800) 424-9300 or (703) 527–3887 Revised: October, 2013

GHS – Classification

Health Environmental Physical Acute Toxicity: Category 5 None None Skin Corrosion/Irritation: Category 3 None None Skin Sensitization: NO None None Eye: Category 2B None Warning Carcinogen: Category None None None GHS – Label Symbol(s): None Other Hazards Not Resulting in Classification: None

Section 1. PRODUCT AND COMPANY IDENTIFICATION

Section 2. HAZARDS IDENTIFICATION

http://www.amerex-fire.com/�

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GHS – Hazard Phrases GHS Hazard GHS Codes(s) Code Phrase(s)

Physical None Health H303

313 320 333

May be harmful if swallowed May be harmful in contact with skin Causes eye irritation May be harmful if inhaled

Environmental None Precautionary: General P101

102 If medical advice is needed, have product container or label at hand Keep out of reach of children

Prevention 234 251 261 264 270 281 285

Keep in original container Pressurized container; do not pierce or burn, even after use Avoid breathing dust Wash hands and face thoroughly after handling Do not eat, drink, or smoke when using this product Use personal protective equipment as required In case of inadequate ventilation, wear respiratory protection

Response P301+322+331 302+352

304+313+341

305+351+338

308+313 337+313

If swallowed, drink 2-3 glasses of water and do not induce vomiting If on skin, wash with soap and water If inhaled, and if distress occurs, remove victim to fresh air and keep at rest in a position comfortable for breathing. Seek medical advice/attention If in eyes, rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do, and continue to rinse If exposed or concerned, get medical advice/attention If eye irritation persists; get medical advice/attention

Storage P401+402+403 Store in original container or extinguisher in a dry, well ventilated place

Chemical Name EC No. REACH Reg. No. CAS-No. Weight % Classification Mono-ammonium phosphate NA NA 7722-76-1 90-97 NA Fullers earth magnesium aluminum silicate

NA Not Available 8031-18-3 >3 NA

Mica- potassium aluminum silicate

NA Not Available 12001-26-2 1-2 NA

Silicone oil methyl hydrogen polysiloxane

NA Not Available 63148-57-2 <1 NA

Calcium carbonate 215-279-6 Not Available 1317-65-3 <1 NA Amorphous silica precipitated synthetic zeolite

262-373-8 Not Available 112926-00-8 <1 NA

Yellow 14 pigment – di-azo dye 228-767-9 Not Available 5468-75-7 <1 NA

Emergency overview: Light yellow, fine solid powder, odorless. Adverse health effects and symptoms: Mild irritant to the respiratory system, eyes, and skin.

Symptoms may include coughing, shortness of breath, and irritation of the lungs, eyes, and skin.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS

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Ingestion, although unlikely, may cause cramps, nausea and diarrhea.

Cut-off Levels

Chemical Name Reproductive Toxicity

Carcinogenicity Mutagenicity Other Hazard Classes

Mono-ammonium Phosphate NA NA NA NA Fullers earth magnesium aluminum silicate

NA NA NA NA

Mica- potassium aluminum silicate

NA NA NA NA

Silicone oil methyl hydrogen polysiloxane

NA NA NA NA

Calcium carbonate NA NA NA NA Amorphous silica precipitated synthetic zeolite

NA NA NA NA

Yellow 14 pigment – di-azo dye NA NA NA NA

Eye Exposure: May cause irritation. Irrigate eyes with water and

repeat until pain free. Seek medical attention if irritation develops, or if vision changes occur.

Skin Exposure: May cause skin irritation. In case of contact, wash with plenty of soap and water. Seek medical attention if irritation persists.

Inhalation: May cause irritation, along with coughing. If respiratory irritation or distress occurs remove victim to fresh air. Seek medical attention if irritation persists.

Ingestion: Overdose symptoms may include numbness or tingling in hands or feet, uneven heart rate, paralysis, feeling faint, chest pain or heavy feeling, pain spreading to the arm or shoulder, nausea, diarrhea, sweating, general ill feeling, or seizure (convulsions). If victim is conscious and alert, give 2-3 glasses of water to drink. If conscious, do not induce vomiting. Seek immediate medical attention. Do not leave victim unattended. To prevent aspiration of swallowed product, lay victim on side with head lower than waist.

Medical conditions possibly aggravated by exposure: Inhalation of product may aggravate existing chronic

respiratory problems such as asthma, emphysema, or bronchitis. Skin contact may aggravate existing skin

Section 4. FIRST AID MEASURES

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disease. Chronic overexposure may cause pneumoconiosis (“dusty lung” disease).

Flammable Properties: Not flammable Flash Point: Not determined Suitable Extinguishing Media: Non-combustible. Use extinguishing media suitable for surrounding conditions. Hazardous Combustion Products: Carbon oxides Explosion Data: Sensitivity to Mechanical Impact: Not sensitive Sensitivity to Static Discharge: Not sensitive Unusual fire/explosion hazards: In a fire this material may decompose, releasing

oxides of carbon, potassium and nitrogen (see Section 10).

Protective Equipment and Precautions for Firefighters: As in any fire, wear self-contained breathing

apparatus pressure-demand. NIOSH (approved or equivalent) and full protective gear.

Personal Precautions: Avoid contact with skin, eyes, and clothing. Personal Protective Equipment: Minimum - safety glasses, gloves, and a dust respirator. Emergency Procedures: NA Methods for Containment: Prevent further leakage or spillage if safe to do so. Methods for Clean Up: Avoid dust formation; clean up released material

using vacuum or wet sweep and shovel to minimize generation of dust. Bag and transfer to properly labeled containers. Ventilate area and wash spill site after material pickup is complete.

Other: If product is contaminated, use PPE and containment appropriate to the nature of the most toxic chemical/material in the mixture.

Section 5. FIRE-FIGHTING MEASURES

Section 6. ACCIDENTAL RELEASE MEASURES

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Personal Precautions: Use appropriate PPE when handling or maintaining

equipment, and wash thoroughly after handling (see Section 8).

Conditions for Safe Storage: Keep product in original container or extinguisher. Contents may be under pressure – inspect for extinguisher rust periodically to ensure container integrity.

Incompatible Products: Do not mix with other extinguishing agents, particularly potassium bicarbonate and sodium bicarbonate. Incompatible with strong oxidizing agents and strong acids. Do not store in high humidity. Do not combine with chlorine compounds.

Chemical

Name OSHA PEL ACGIH TLV DFG MAK * EU BLV

Mono-ammonium phosphate

PNOC** Total dust, 15 mg/m3 Respirable fraction, 5 mg/m3

PNOC Total dust, 10 mg/m3 Respirable fraction, 3 mg/m3

PNOC Total dust, 4 mg/m3 Respirable fraction, 1.5 mg/m3

NA

Mica 6 mg/m3 3 mg/m3 ------- NA Fullers Earth PNOC**

Total dust, 15 mg/m3 Respirable fraction, 5 mg/m3


PNOC Total dust, 4 mg/m3 Respirable fraction,

1.5 mg/m3

Silicone oil

NR** NR

Calcium carbonate



-------

NA

Amorphous silica

143 mg/m3 80 mg/m3 or % SiO2

10 mg/m3 4 mg/m3 NA

Yellow 14 pigment

NR NR NR NA

*German regulatory limits **PNOC = Particulates not otherwise classified (ACGIH) also known as Particulates not otherwise regulated (OSHA) *** NR = Not Regulated. All values are 8 hour time weighted average concentrations. Engineering Controls: Showers Eyewash stations Ventilation systems

Section 7. HANDLING AND STORAGE

Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

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Personal Protective Equipment – PPE Code E:

Eye/Face Protection: Tightly fitting safety goggles Skin and Body Protection: Wear protective gloves/coveralls

Respiratory Protection: If exposure limits are exceeded or irritation is experienced, NIOSH approved respiratory protection should be worn. Use N95 dust mask for limited exposure, use air-purifying respirator (APR) with high efficiency particulate air (HEPA) filters for prolonged exposure. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. The need for respiratory protection is not likely for short-term use in well ventilated areas.

Hygiene Measures: Good personal hygiene practices essential, such as

avoiding food, tobacco products, or other hand-to-mouth contact when handling. Wash thoroughly after handling.

Appearance: Light yellow powder, finely divided odorless solid Molecular Weight: 115.03 Odor: Odorless Odor Threshold: No information available Decomposition Temperature OC: 100 - 120 Freezing Point OC: No information available Initial Boiling Point OC: No information available Physical State: Crystalline Powder pH: Approximately 4.4 to 4.9 Flash Point OC: None Autoignition Temperature OC: None Boiling Point/Range OC: Not Applicable

Section 9. PHYSICAL AND CHEMICAL PROPERTIES

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Melting Point/Range OC: 190 C Flammability Limits in Air OC: Upper – Not Flammable; Lower-Not Flammable Explosive Properties: None Oxidizing Properties: None Volatile Component (%vol) Not Applicable Evaporation Rate: Not Applicable MMHG @ 37.8 C : Not Applicable Vapor Density: Not Applicable Vapor Pressure: Not Applicable Specific gravity: Approximately 1.8 at 25 C Solubility: 40.4 g/100 ml Partition Coefficient: No Information Available Viscosity: Not Applicable

Stability: Stable under recommended storage and handling

conditions. Incompatibles: Strong oxidizing agents; Strong acids; sodium

hypochlorite and chlorine compounds. Protect from moisture

Conditions to Avoid: Storage or handling near incompatibles. Hazardous Decomposition Products: Carbon, nitrogen, and potassium oxides. Heat of fire

may release carbon monoxide. Possibility of Hazardous Reactions: None Hazardous Polymerization Does not occur

Likely Routes of Exposure: Inhalation, skin and eye contact. Symptoms:

Inhalation: Irritation, coughing. Eyes: Irritation. Skin: Irritation.

Acute Toxicity: Relatively non-toxic. Chronic Toxicity:

Short-term Exposure: None known. Long-term Exposure: As with all dusts, pneumoconiosis, or “dusty lung”

disease, may result from chronic exposure.

Section 10. STABILITY AND REACTIVITY

Section 11. TOXICOLOGICAL INFORMATION

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Acute Toxicity Values - Health Chemical Name

LD50 LC50 (Inhalation) Oral Dermal

Mono-ammonium phosphate 5750 mg/kg (rat) >7940 mg/kg (rabbit) Not available Mica None None None Fullers Earth None None None Silicone oil None None None Calcium carbonate 6450 mg/kg (rat) 500 mg/24 hr (rabbit) Not available Amorphous silica >5000 mg/kg (rat) >2000 mg/kg (rabbit) >2.2 mg/L (rat) Yellow 14 pigment >17000 mg/kg (rat) >3000 mg/kg (rat) >4448 mg/m3 (rat) Reproductive Toxicity: This product’s ingredients are not known to have

reproductive or teratogenic effects. Target Organs and Effects (TOST): Respiratory system (mild irritant). This product is a mild irritant to epithelial tissue,

(eyes, mucous membranes, skin) and may aggravate dermatitis. No information was found indicating the product causes sensitization.

Other Toxicity Categories

Chemical Name Germ Cell Mutagenicity

Carcino-genicity

Repro-ductive

TOST Single Exp

TOST Repeated Exp

Aspiration

Potassium Bicarbonate

None None None Cat 3 None None Fullers earth

None None None None None None

Mica


Silicone oil


Calcium carbonate None None None None None None Amorphous silica None None None None None None Yellow 14 pigment None None None None None None

Ecotoxicity: negative effects unknown. Provides nutrient nitrogen and phosphorus to plant life.

Persistence/Degradability: degrades rapidly in humid/wet environment. Bioaccummulation: extent unknown. Mobility in soil: slow evaporation rate; water soluble, may leach to

groundwater

Section 12. ECOLOGICAL INFORMATION

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Other Adverse Ecological Effects: No other known effects at this time Aquatic Toxicity Values – Environment – None Known

Chemical Name Acute (LC50) Chronic (LC50) Monoammonium phosphate N/A N/A Mica N/A N/A Fullers Earth N/A N/A Silicone oil N/A N/A Calcium carbonate N/A N/A Amorphous silica N/A N/A Yellow 14 pigment N/A N/A

Safe Handling Use appropriate PPE when handling, and wash thoroughly after handling (see Section 8).

Waste Disposal Considerations Dispose in accordance with federal, state, and local regulations.

Contaminated Packaging Dispose in accordance with federal, state, and local regulations.

NOTES: This product is not a RCRA characteristically hazardous or listed hazardous waste. Dispose of according to state or local laws, which may be more restrictive than federal laws or regulations. Used product may be altered or contaminated, creating different disposal considerations. UN Number: NA UN Proper Shipping Name: NA Transport Hazard Class: NA Packing Group: NA Marine Pollutant?: NO IATA Not regulated DOT Not regulated NOTES: This product is not defined as a hazardous material under U.S. Department of Transportation (DOT) 49 CFR 172, or by Transport Canada “Transportation of Dangerous Goods” regulations.

Section 13. DISPOSAL CONSIDERATIONS

Section 14. TRANSPORT INFORMATION

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Special Precautions for Shipping: If shipped in a stored pressure-type fire extinguisher, and pressurized with a non-flammable, non-toxic inert expellant gas, the fire extinguisher is considered a hazardous material by the US Department of Transportation and Transport Canada. The proper shipping name shall be FIRE EXTINGUISHER and the UN designation is UN 1044. The DOT hazard class is Limited Quantity when shipped via highway or rail. Use a Non-Flammable Gas label (class 2.2) when shipping via air.

International Inventory Status: All ingredients are on the following inventories

Country(ies) Agency Status United States of America TSCA Yes Canada DSL Yes Europe EINECS/ELINCS Yes Australia AICS Yes Japan MITI Yes South Korea KECL Yes REACH Title VII Restrictions: No information available Chemical Name Dangerous

Substances Organic Solvents

Harmful Substances Whose Names Are to be Indicated on Label

Pollution Release and Transfer Registry (Class II)

Pollution Release and Transfer Registry (Class I)

Poison and Deleterious Substances Control Law

Monoammonium Phosphate

Not Applicable

Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable

Section 15. REGULATORY INFORMATION

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Component ISHA – Harmful

Substances Prohibited for Manufacturing, Importing, Transferring, or Supplying

ISHA – Harmful Substances Requiring Permission

Toxic Chemical Classification Listing (TCCL) – Toxic Chemicals

Toxic Release Inventory (TRI) – Group I

Toxic Release Inventory (TRI) – Group II

Monoammonium Phosphate 7722-76-1

Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Fullers earth magnesium aluminum silicate 8031-18-3 (>4)


Mica- potassium aluminum silicate 120001-26-2 (>2)


Calcium carbonate 471-34-1


Amorphous silica 69012-64-2 Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Yellow 14 pigment 5468-75-7


European Risk and Safety phrases: EU Classification: Irritant R Phrases: 20 Harmful by inhalation. 36/37 Irritating to eyes, respiratory system. S Phrases: 22 Do not breath dust. 24/25 Avoid contact with skin and eyes

26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

36 Wear suitable protective clothing. U.S. Federal Regulatory Information:

SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) - This product does not contain and chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. None of the chemicals in this product are under SARA reporting requirements or have SARA threshold planning quantities (TPQs) or CERCLA reportable quantities (RQs), or are regulated under TSCA 8(d).

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SARA 311/312 Hazard Categories: Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard-* Yes Reactive Hazard No

* - Only applicable if material is in a pressurized extinguisher. Clean Water Act: This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPs) under Section 112 of the Clean Air Act Amendments of 1990. U.S. State Regulatory Information: Chemicals in this product are covered under specific State regulations, as denoted below: Alaska - Designated Toxic and Hazardous Substances: NoneCalifornia – Permissible Exposure Limits for Chemical Contaminants: None Florida – Substance List: Mica Dust Illinois – Toxic Substance List: None Kansas – Section 302/303 List: None Massachusetts – Substance List: Mica Dust Minnesota – List of Hazardous Substances: None Missouri – Employer Information/Toxic Substance List: None New Jersey – Right to Know Hazardous Substance List: None North Dakota – List of Hazardous Chemicals, Reportable Quantities: None Pennsylvania – Hazardous Substance List: None Rhode Island – Hazardous Substance List: Mica Dust Texas – Hazardous Substance List: No West Virginia – Hazardous Substance List: None Wisconsin – Toxic and Hazardous Substances: None California Proposition 65: No component is listed on the California Proposition 65 list. Other: Mexico – Grade No component listed Canada – WHMIS Hazard Class No component listed

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This SDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU regulations or standards, and conforms to the proposed 2003 ANSI Z400.1 format. Issuing Date 17-June-2012 Revision Date 17-October-2013 Revision Notes None The information herein is given in good faith but no warranty, expressed or implied, is made. Updated by William F. Garvin, CIH.

Section 16. OTHER INFORMATION

MATERIAL SAFETY DATA SHEET

METHANOL

3. HAZARDS IDENTIFICATION

Poison. May be fatal or cause blindness if swallowed. Can cause teratogenic effects. Causes eye irritation. Can cause skin irritation. Mists or sprays are irritating to eyes and respiratory tract. At elevated temperatures may cause irritation of the eyes and respiratory tract. See "Other Health Effects" Section. Flammable liquid and vapour. May cause flash fire or explosion. Can decompose at high temperatures forming toxic gases. Contents may develop pressure on prolonged exposure to heat.

EMERGENCY OVERVIEW:

POTENTIAL HEALTH EFFECTS

Contact with mist or spray will cause irritation of mucous membranes, coughing and difficulty in breathing. See "Other Health Effects" Section.

Inhalation:

EMERGENCY TELEPHONE NUMBER (For Emergencies Involving Chemical Spills or Releases)

1 855 273 6824

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Brenntag Canada Inc.43 Jutland Rd.Toronto, ONM8Z 2G6(416) 259-8231

Website: http://www.brenntag.ca

WHMIS#: 00060463Index:

2014 January 10

PRODUCT IDENTIFICATION

Methanol.Product Name:

2014 January 10Date of Revision:Effective Date:

GCD0167/14A

Methyl Alcohol.Chemical Name:

Methyl Hydrate; Wood Spirit; Carbinol; Colonial Spirit; Columbian Spirit; Methyl Hydroxide; Wood Naphtha; Wood Alcohol; Methanol with Additive; CCS 973 Solvent.

Synonyms:

Alcohol.Chemical Family:

CH3-OH.Molecular Formula:

Industrial solvent, cleaner, degreaser. Fuel for heaters and wick lamps. Automotive coolant/antifreeze. Chemical intermediate. Lacquer thinner.

Product Use:

WHMIS Classification / Symbol:

READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.

B-2: Flammable LiquidD-1B: Toxic (acute effects)D-2A: Very Toxic (teratogen)D-2B: Toxic (skin and eye irritant)

Ingredient CAS# ACGIH TLV (TWA) % Concentration

2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)

Methanol 67-56-1 200 ppm (Skin) 60 - 100

Skin Notation: Contact with skin, eyes and mucous membranes can contribute to the overall exposure and may invalidate the TLV. Considermeasures to prevent absorption by these routes.

Methanol Brenntag Canada Inc.Date of Revision: 2014 January 10WHMIS Number : 00060463

Page 2 of 8

4. FIRST AID MEASURES

FIRST AID PROCEDURES

Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Obtain medical attention IMMEDIATELY.

Inhalation:

Start flushing while removing contaminated clothing. Wash affected areas thoroughly with soap and water. If irritation, redness, or a burning sensation develops and persists, obtain medical advice.

Skin Contact:

Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during flushing. Take care not to rinse contaminated water into the unaffected eye or onto the face. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY.

Eye Contact:

Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material. IMMEDIATELY contact local Poison Control Centre. Vomiting should only be induced under the direction of a physician or a poison control centre. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus, rinse mouth and administer more water. IMMEDIATELY transport victim to an emergency facility.

Ingestion:

This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial resuscitation and appropriate chemotherapy if respiration is depressed.

When plasma methanol concentrations are higher than 20 mg/dL, when ingested doses are greater than 30 mL, and when there is evidence of acidosis or visual abnormalities, a 10% solution of ethanol in 5% aqueous dextrose, administered intravenously, is a safe, effective antidote. (3)

Medical conditions that may be aggravated by exposure to this product include neurological and cardiovascular disorders, diseases of the skin, eyes or respiratory tract, preexisting liver and kidney disorders.

Note to Physicians:

Prolonged and repeated contact may lead to dermatitis. May cause defatting, drying and cracking of the skin. Skin contact can cause irritation, especially under the finger nails (and other confined spaces such as under rings or watch bands).

Skin Contact:

May be absorbed through intact skin.Skin Absorption:

Vapours from this product are irritating to the eyes. Splashes to the eye may cause irritation, redness and pain. Product residues on fingers, hands or gloves may contact the eyes and cause eye irritation, redness and pain.

Eye Contact:

This product causes irritation, a burning sensation of the mouth and throat and abdominal pain.Ingestion:

Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation or onset of pain. Strict adherence to first aid measures following any exposure is essential.

May cause visual disturbances, blindness, photophobia, central nervous system (CNS) depression, liver damage, kidney damage, metabolic acidosis, endocrine effects, systemic poisoning and death. Mild blurring of vision to complete blindness may occur, including changes in colour perception and photophobia. Symptoms usually develop 12-18 hours after exposure. Abnormal sensitivity to light is termed photophobia. CNS depression is characterized by headache, dizziness, drowsiness, nausea, vomiting and incoordination. Severe overexposures may lead to coma and possible death due to respiratory failure. Liver damage is characterized by the loss of appetite, jaundice (yellowish skin colour), and occasional pain in the upper left-hand side of the abdomen. Signs and symptoms of kidney damage generally progress from oliguria, to blood in the urine, to total renal failure. Metabolic acidosis is a condition that describes a decreased pH and bicarbonate concentration in the body fluids.

Other Health Effects:

5. FIRE-FIGHTING MEASURES

Flashpoint (°C)AutoIgnition

Temperature (°C) LEL UEL

Flammability Limits in Air (%):

11 (3) 464 (3) 6 (3, 4) 36.5 (3)

B-2: Flammable LiquidFlammability Class (WHMIS):

Thermal decomposition products are toxic and may include formaldehyde and oxides of carbon.Hazardous Combustion Products:


Page 3 of 8

Vapours from this product are heavier than air, and may "travel" to a source of ignition (eg. pilot lights, heaters, electric motors) some distance away, and then "flash back" to the point of product discharge causing an explosion and fire. Closed containers exposed to heat may explode. Spilled material may cause floors and contact surfaces to become slippery.

Unusual Fire or Explosion Hazards:

Not expected to be sensitive to mechanical impact.Sensitivity to Mechanical Impact:

Not available.Rate of Burning:

Not available.Explosive Power:

Expected to be sensitive to static discharge when vapours are present between the lower and upper explosive limits.

Sensitivity to Static Discharge:

EXTINGUISHING MEDIA

Use carbon dioxide or dry chemical media for small fires. If only water is available, use it in the form of a fog. This material may produce a floating fire hazard in extreme fire conditions.

Fire Extinguishing Media:

FIRE FIGHTING INSTRUCTIONS

Use water spray to cool fire-exposed containers or structures. Use water spray to disperse vapours; re-ignition is possible.

Instructions to the Fire Fighters:

Use self-contained breathing apparatus and protective clothing.Fire Fighting Protective Equipment:

6. ACCIDENTAL RELEASE MEASURES

Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons, property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from region to region.

In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS. Wear protective clothing. Do not use combustible materials such as sawdust as an absorbent. Eliminate all sources of ignition. Collect product for recovery or disposal. For release to land, or storm water runoff, contain discharge by constructing dykes or applying inert absorbent; for release to water, utilize damming and/or water diversion to minimize the spread of contamination. Ventilate enclosed spaces. Notify applicable government authority if release is reportable or could adversely affect the environment.

Containment and Clean-Up Procedures:

7. HANDLING AND STORAGE

HANDLING

Ground and bond equipment and containers to prevent a static charge buildup. Use spark-resistant tools and avoid "splash-filling" of containers. Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be under internal pressure. These should be cooled and carefully vented before opening. A face shield and apron should be worn. Vent container frequently, and more often in warm weather, to relieve pressure. Absorption via contact with skin, eyes and mucous membranes can contribute to the overall exposure. Consider measures to prevent absorption by these routes.

Handling Practices:

See Section 8, "Engineering Controls".Ventilation Requirements:

Use only with adequate ventilation and avoid breathing vapours and aerosols. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling. Wash contaminated clothing thoroughly before re-use. Do not use cutting or welding torches on empty drums that contained this material/product. Store wiping rags and similar material in metal cans with tight fitting lids. Enforce NO SMOKING rules in area of use.

Other Precautions:

STORAGE

See below.Storage Temperature (°C):

Ventilation should be explosion proof.Ventilation Requirements:

Store in a cool, well-ventilated area. Keep away from heat, sparks and flames. Keep containers closed. Do not expose sealed containers to temperatures above 40° C. Avoid moisture contamination. Protect from direct sunlight. Protect against physical damage.

Storage Requirements:

Equipment for storage, handling or transport should NOT be made from the following material, or, where applicable, its alloys: lead, nickel, cast iron, copper, zinc, galvanized steel or aluminum. Confirm suitability of any material before using.

Special Materials to be Used for Packaging or Containers:


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8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace.

ENGINEERING CONTROLSLocal exhaust ventilation required. Ventilation should be explosion proof. Make up air should be supplied to balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as sumps or pits where dense vapours may collect.

For personnel entry into confined spaces (i.e. bulk storage tanks) a proper procedure must be followed. It must include consideration of, among other things, ventilation, testing of tank atmosphere, provision and maintenance of SCBA, and emergency rescue. Use the "buddy" system. The second person should be in view and trained and equipped to execute a rescue. (6)

Engineering Controls:

PERSONAL PROTECTIVE EQUIPMENT (PPE)

Safety glasses with side shields are recommended to prevent eye contact. Use chemical safety goggles when there is potential for eye contact. Contact lenses should not be worn when working with this material.

Eye Protection:

Gloves and protective clothing made from butyl rubber or viton should be impervious under conditions of use. Prior to use, user should confirm impermeability. Do not use gloves or protective clothing made from natural rubber, neoprene, nitrile rubber or polyvinyl alcohol (PVA). Discard contaminated gloves.

Skin Protection:

A NIOSH/MSHA-approved air-purifying respirator equipped with organic vapour cartridges for concentrations up to 200 ppm. A NIOSH/MSHA-approved full facepiece air-supplied respirator if concentrations are higher or unknown.

If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check to make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If the seal is no longer good, you may need a new respirator. (6)

Methanol: Immediately Dangerous to Life and Health (IDLH) value: 6 000 ppm. The purpose of establishing an IDLH value is to ensure that the worker can escape from a given contaminated environment in the event of failure of the most protective respiratory equipment. In the event of failure of respiratory protective equipment, every effort should be made to exit immediately. (4)

Respiratory Protection:

Wear an impermeable apron and boots. Locate safety shower and eyewash station close to chemical handling area. Take all precautions to avoid personal contact.

Clothing and footwear that is fire retardant and dissipates static electrical charges should be worn when handling flammable materials. Natural fibers (cotton, wool, leather and linen) should be selected in favour of synthetic materials (rayon, nylon and polyester).

Skin Notation: Contact with skin, eyes and mucous membranes can contribute to the overall exposure and may invalidate the TLV. Consider measures to prevent absorption by these routes.

Other Personal Protective Equipment:

EXPOSURE GUIDELINES

SUBSTANCE ACGIH TLV(STEL)

OSHA PEL(TWA) (STEL)

NIOSH REL(TWA) (STEL)

Methanol 250 ppm (Skin) 200 ppm --- 200 ppm (Skin) 250 ppm (Skin)

Liquid.Clear, colourless liquid.Mild alcohol odour.4.2 - 5 960. (3)64.7. (3)- 97.8. (3)96. (3)1.11. (3)0.791 - 0.793. (3)

Physical State:Appearance:Odour:Odour Threshold (ppm):Boiling Range (°C):Melting/Freezing Point (°C):Vapour Pressure (mm Hg at 20° C):Vapour Density (Air = 1.0):Relative Density (g/cc):

9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications)


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Not available.Not available.4.1. (3)Soluble in water. Hygroscopic (readily absorbs water).100.Not applicable.< 0. (3)100.

Bulk Density:Viscosity:Evaporation Rate (Butyl Acetate = 1.0):Solubility:% Volatile by Volume:pH:Coefficient of Water/Oil Distribution:Volatile Organic Compounds (VOC):

11 (3)Flashpoint (°C):

11. TOXICOLOGICAL INFORMATION

TOXICOLOGICAL DATA:

SUBSTANCE LD50 (Oral, Rat) LD50 (Dermal, Rabbit) LC50 (Inhalation, Rat, 4h)

Methanol 5 600 mg/kg (1) 15 800 mg/kg (1) 64 000 ppm (1)

The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.Carcinogenicity Data:

No adverse reproductive effects are anticipated.Reproductive Data:

No adverse mutagenic effects are anticipated.Mutagenicity Data:

Methanol may cause teratogenic/embryotoxic effects based on studies in laboratory animals. See "Other Studies Relevant to Material".

Teratogenicity Data:

None known.Respiratory / Skin Sensitization Data:

Alcohols may interact synergistically with chlorinated solvents (example - carbon tetrachloride, chloroform, bromotrichloromethane), dithiocarbamates (example - disulfiram), dimethylnitrosamine and thioacetamide. (6)

Synergistic Materials:

10. STABILITY AND REACTIVITY

CHEMICAL STABILITY

Stable.Under Normal Conditions:

Flammable.Under Fire Conditions:

Will not occur.Hazardous Polymerization:

High temperatures, sparks, open flames and all other sources of ignition.Conditions to Avoid:

Strong oxidizers. Lewis or mineral acids. Sulphuric Acid. Hydrogen Peroxide. Lead. Aluminum and its alloys. Magnesium. Platinum. Nickel. Cast Iron. Copper and its alloys. Zinc and its alloys. Galvanized Steel.

Mixtures or reactions of alcohols with the following materials may cause explosions: barium perchlorate, chlorine, hypochlorous acid, ethylene oxide, hexamethylene diisocyanate and other isocyanates, nitrogen tetroxide, permonosulfuric acid and tri-isobutyl aluminum. (4)

Materials to Avoid:

Thermal decomposition products are toxic and may include formaldehyde and oxides of carbon.Decomposition or Combustion Products:


Page 6 of 8

Methanol caused moderate skin and eye irritation in animal tests. A well-conducted oral study using rats suggests that methanol may be carcinogenic, but further studies are required before firm conclusions can be drawn. Limited inhalation studies using mice, rats and monkeys have not shown carcinogenicity. (4)

Methanol has produced fetotoxicity in rats and teratogenicity in mice exposed by inhalation to high concentrations that did no produce significant maternal toxicity. Mice were exposed by inhalation to 1000, 2000, 5000, 7500, 10000, or 15000 ppm of days 6-15 of pregnancy (7 hr/d). No visible signs of maternal toxicity were noted, but 1/30-40 mothers died in each group exposed to 7500 ppm and above. There was a dose-related significant decrease in the number of live pups/litter (post implantation mortality) at 7500 ppm and above. A significant increase in malformations (e.g. cleft palate, exencephaly, skeletal anomalies) was observed at 5000 ppm and above. Fetal body weights were significantly reduced at 10000 ppm and higher. (4)

The pathologic changes found in the tissues of animals exposed by inhalation to Methyl Alcohol are quite similar to those observed in animals following ingestion of this compound. In the eyes of dogs, hyperemia (increased amount of blood) of the choroid and edema of the ocular tissue with early signs of degeneration of the ganglionic cells of the retina and nerve fibers were found. The blood vessels of the choroid in poisoned animals were markedly congested, the entire retina was edematous and the ganglion cells were degenerated. Hemorrhage, edema, congestion and pneumonia were observed in the lungs of the various species that were exposed to vapours containing Methyl Alcohol. The livers and kidneys showed congestion, albuminous and fatty acid degeneration and fatty infiltration. Cardiac dilation and myocardial degeneration were observed in the hearts of the animals. (4)

The effects of alcohol on hearing were studied in the rat by examining the modification of the acoustic startle reflexes by pure tone pulses and by gaps in white noise. Groups of rats received four injections of 0. 0.25, 1 and 2 g/Kg of Methyl Alcohol or Ethyl Alcohol in increasing order at one hour intervals, loudness perception or temporal acuity was tested after 30 minutes. Both alcohols produced a dose dependent reduction in baseline startle amplitude that was greater during exposure Ethanol than in Methanol. Loudness functions associated with pulse intensity were not diminished by the alcohols, however inhibition produced by gap in noise reduced following the highest dose of either alcohol. (4)

Mature male rats were examined for alterations in circulating free testosterone, luteinizing hormone and follicle stimulating hormone after inhalation of Methanol vapour for six weeks at doses ranging from 200 ppm to 10,000 ppm. The most extensive effects were noticed after exposure to 200 ppm Methanol for six weeks, with serum levels of testosterone being 32 % of the controls. A significant change in luteinizing hormone concentration after exposure to 10,000 ppm of methanol for six weeks was also demonstrated while follicle stimulating and the elimination of testosterone from the blood remained unchanged throughout the experiment. (4)

The result of skin absorption experiments were described by stating that all animals subjected to the action of any amount of Methanol by skin absorption has died. The lowest lethal does was 0.5 ml / Kg for one monkey. It was reported that rabbits were far less susceptible to Methyl Alcohol poisoning by this route than monkeys or rats. In a study of the effects of continuous exposure to methanol, a known amount was dropped onto or injected into the gauze pads 4 times / day. All such treated monkeys displayed dilated pupils within 2 hours after one such administration of 1.3 mg / Kg Methanol. The minimum lethal dose was a total of four administrations of 0.5 ml / Kg of Methanol in one day. It was concluded that sufficient amounts of Methanol can be absorbed through the skin and that the threshold for immediate danger to monkeys was below the minimum lethal dose. (4)

A negative consensus resulted from all sister chromatid exchange tests when no exogenous metabolic activation system was used. A negative consensus resulted from both cell transformation in primary cells using limited lifetime strains and cell transformation via viral enhancement tests when no exogenous activation system was used. A negative consensus resulted from all Neurospera crassa tests when no exogenous metabolic activation system was used. (4)

Other Studies Relevant to Material:

12. ECOLOGICAL INFORMATION

Methanol:96-hour LC50 (Pimephales promelas) = 28 g/L. (3)96-hour LC50 (Lepomis macrochirus) = 15.4 g/L. (3)48-hour EC50 (Daphnia magna) = 24.5 g/L. (3)

Ecotoxicity:

If released to the atmosphere, methanol degrades via reactions with photochemically produced hydroxyl radicals with an approximate half-life of 17.8 days. Physical removal from air can occur via rainfall. If released to water, decomposition via biodegradation is expected to occur. If released to soil, methanol is expected to degrade via biodegradation and be susceptible to leaching. (4)

Can be dangerous if allowed to enter drinking water intakes. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds, or rivers.

Environmental Fate:


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13. DISPOSAL CONSIDERATIONS

None required.Deactivating Chemicals:

Dispose of waste material at an approved (hazardous) waste treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Do not dispose of waste with normal garbage, or to sewer systems. Reevaluation of the product may be required by the user at the time of disposal since the product uses, transformations, mixtures and processes may influence waste classification.

Waste Disposal Methods:

See "Waste Disposal Methods".Safe Handling of Residues:

Empty containers retain product residue and can be dangerous. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. Do not expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury or death. Do not dispose of package until thoroughly washed out.

Disposal of Packaging:

14. TRANSPORTATION INFORMATION

CANADIAN TDG ACT SHIPPING DESCRIPTION:

METHANOL, Class 3(6.1), UN1230, PG II.

Label(s): Flammable Liquids, Toxic Substances. Placard: Flammable Liquids.

ERAP Index: -----. Exemptions: None known.

US DOT CLASSIFICATION (49CFR 172.101, 172.102):

METHANOL, Class 3(6.1), UN1230, PG II.

Label(s): Flammable Liquid, Poison. Placard: Flammable Liquid.

CERCLA-RQ: Methanol: 5 000 lb / 2 270 Kg.

Exemptions: Not applicable.

15. REGULATORY INFORMATION

CANADA

This material is included on the DSL under the CEPA.CEPA - NSNR:Methanol.CEPA - NPRI:

Controlled Products Regulations Classification (WHMIS):

16. OTHER INFORMATION

REFERENCES

RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS database.

1.

Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons, New York, 1981.

2.

USA

This material is included on the TSCA Inventory.Environmental Protection Act:

Flammable Liquid. Toxic. Teratogenic and Embryotoxic. Skin and Eye Irritant.OSHA HCS (29CFR 1910.1200):

Text22:NFPA: 1 Health, 3 Fire, 0 Reactivity (3)Text22:HMIS: 2 Health, 3 Fire, 0 Reactivity (3)

INTERNATIONAL

This product or its components are on the European inventory of existing commercial chemicals (EINECS).

B-2: Flammable LiquidD-1B: Toxic (acute effects)D-2A: Very Toxic (teratogen)D-2B: Toxic (skin and eye irritant)


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Supplier's Material Safety Data Sheet(s).3.

CHEMINFO chemical profile, Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.4.

Guide to Occupational Exposure Values, 2011, American Conference of Governmental Industrial Hygienists, Cincinnati, 2011.5.

Regulatory Affairs Group, Brenntag Canada Inc.6.

The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical Association, Ottawa, 1981.

7.

____________________________________________________________________________________________________________

The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may involve other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained herein. This Material Safety Data Sheet is valid for three years.____________________________________________________________________________________________________________

To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.

British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1 Phone: (604) 513-9009 Facsimile: (604) 513-9010

Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9 Phone: (780) 986-4544 Facsimile: (780) 986-1070

Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2 Phone: (204) 233-3416 Facsimile: (204) 233-7005

Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6 Phone: (416) 259-8231 Facsimile: (416) 259-5333

Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8 Phone: (514) 636-9230 Facsimile: (514) 636-0877

Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7 Phone: (902) 468-9690 Facsimile: (902) 468-3085____________________________________________________________________________________________________________

Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.

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Revision Number: 4

Revision Date: APRIL 21, 2015

1 of 7 Regal R&O 22, 32, 46, 68, 100, 115,150 MSDS : 23567

Material Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Regal R&O 22, 32, 46, 68, 100, 115, 150

Product Use: Turbine OilProduct Number(s): 273209, 273210, 273211, 273212, 273213, 277311, 277312, 278034, 278035,278036, 278048, 278049, 278050, 278051 Synonyms: Chevron Regal R&O 22, 32, 46, 68, 100, 115, 150, ISOCLEAN CertifiedCompany IdentificationChevron Canada Limited1050 West PenderVancouver, BC V6E 3T4Canadawww.chevronlubricants.com

Transportation Emergency ResponseCHEMTREC: (800) 424-9300 or (703) 527-3887Health EmergencyChevron Emergency Information Center: Located in the USA. International collect calls accepted. (800)231-0623 or (510) 231-0623Product Informationemail : [email protected] Information: (800) LUBE TEK

SECTION 2 HAZARDS IDENTIFICATION

************************************************************************************************************************EMERGENCY OVERVIEW

- HARMFUL TO AQUATIC ORGANISMS. MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THEAQUATIC ENVIRONMENT

************************************************************************************************************************

IMMEDIATE HEALTH EFFECTSEye: Not expected to cause prolonged or significant eye irritation.Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Contact with the skinis not expected to cause an allergic skin response. Not expected to be harmful to internal organs ifabsorbed through the skin. High-Pressure Equipment Information: Accidental high-velocity injection under

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the skin of materials of this type may result in serious injury. Seek medical attention at once should anaccident like this occur. The initial wound at the injection site may not appear to be serious at first; but, ifleft untreated, could result in disfigurement or amputation of the affected part.

Ingestion: Not expected to be harmful if swallowed.Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May causerespiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist atairborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritationmay include coughing and difficulty breathing.

SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT Highly refined mineral oil (C15 - C50) Mixture 60 - 100 %wt/wt Alkyl phenol Mixture 0.1 - < 1 %wt/wt

Information on ingredients that are considered Controlled Products and/or that appear on the WHMISIngredient Disclosure List (IDL) is provided as required by the Canadian Hazardous Products Act (HPA,Sections 13 and 14). Ingredients considered hazardous under the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200, are also listed. See Section 15 for additional regulatory information.

SECTION 4 FIRST AID MEASURES

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, andflush eyes with water.Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes ifcontaminated. To remove the material from skin, use soap and water. Discard contaminated clothing andshoes or thoroughly clean before reuse.Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, getmedical advice.Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air,move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs.Note to Physicians: In an accident involving high-pressure equipment, this product may be injected underthe skin. Such an accident may result in a small, sometimes bloodless, puncture wound. However,because of its driving force, material injected into a fingertip can be deposited into the palm of the hand.Within 24 hours, there is usually a great deal of swelling, discoloration, and intense throbbing pain.Immediate treatment at a surgical emergency center is recommended.

SECTION 5 FIRE FIGHTING MEASURES

Leaks/ruptures in high pressure system using materials of this type can create a fire hazard when in thevicinity of ignition sources (eg. open flame, pilot lights, sparks, or electric arcs).

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FLAMMABLE PROPERTIES:Flashpoint: (Cleveland Open Cup) 190 °C (374 °F) MinimumAutoignition: No data availableFlammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: NotApplicable

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

PROTECTION OF FIRE FIGHTERS:Fire Fighting Instructions: This material will burn although it is not easily ignited. See Section 7 for properhandling and storage. For fires involving this material, do not enter any enclosed or confined fire spacewithout proper protective equipment, including self-contained breathing apparatus.Combustion Products: Highly dependent on combustion conditions. A complex mixture of airbornesolids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compoundswill be evolved when this material undergoes combustion.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in vicinity of spilled material.Spill Management: Stop the source of the release if you can do it without risk. Contain release to preventfurther contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observingprecautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applyingnon-combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminatedsoil. Place contaminated materials in disposable containers and dispose of in a manner consistent withapplicable regulations.Reporting: Report spills to local authorities as appropriate or required.

SECTION 7 HANDLING AND STORAGE

Precautionary Measures: Do not get in eyes, on skin, or on clothing. DO NOT USE IN HIGH PRESSURESYSTEMS in the vicinity of flames, sparks and hot surfaces. Use only in well ventilated areas. Keepcontainer closed.Wash thoroughly after handling.General Handling Information: Avoid contaminating soil or releasing this material into sewage anddrainage systems and bodies of water.Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling thismaterial. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves,be sufficient. Review all operations which have the potential of generating and accumulating an electrostaticcharge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning,sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and useappropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR 1910.106,'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'RecommendedPractice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003,'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'. Container Warnings: Container is not designed to contain pressure. Do not use pressure to emptycontainer or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or exposesuch containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode andcause injury or death. Empty containers should be completely drained, properly closed, and promptlyreturned to a drum reconditioner or disposed of properly.

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SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, andother substances in the work place when designing engineering controls and selecting personal protectiveequipment. If engineering controls or work practices are not adequate to prevent exposure to harmfullevels of this material, the personal protective equipment listed below is recommended. The user shouldread and understand all instructions and limitations supplied with the equipment since protection is usuallyprovided for a limited time or under certain circumstances.

ENGINEERING CONTROLS:Use in a well-ventilated area.

PERSONAL PROTECTIVE EQUIPMENTEye/Face Protection: No special eye protection is normally required. Where splashing is possible, wearsafety glasses with side shields as a good safety practice.Skin Protection: No special protective clothing is normally required. Where splashing is possible, selectprotective clothing depending on operations conducted, physical requirements and other substances in theworkplace. Suggested materials for protective gloves include: 4H (PE/EVAL), Nitrile Rubber, Silver Shield,Viton. Respiratory Protection: No respiratory protection is normally required. If user operations generate an oil mist, determine if airborne concentrations are below the occupationalexposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protectionfrom the measured concentrations of this material. For air-purifying respirators use a particulate cartridge.Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may notprovide adequate protection.Occupational Exposure Limits:

Component Country/Agency

TWA STEL Ceiling Notation

Highly refined mineral oil (C15 - C50) ACGIH 5 mg/m3 10 mg/m3 -- --

NOTE ON OCCUPATIONAL EXPOSURE LIMITS: Consult local authorities for acceptable provincial valuesin Canada. Consult the Canadian Standards Association Standard 94.4-2002 Selection, Use and Care ofRespirators.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: ColorlessPhysical State: LiquidOdor: Petroleum odorpH: Not ApplicableVapor Pressure: <0.01 mmHg @ 37.8 °C (100 °F)Vapor Density (Air = 1): >1Boiling Point: 260°C (500°F)Solubility: Soluble in hydrocarbons; insoluble in water Freezing Point: Not ApplicableSpecific Gravity: 0.86 - 0.9 @ 15.6°C (60.1°F) / 15.6°C (60.1°F)Viscosity: 22 mm2/s @ 40°C (104°F) Minimum

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Odor Threshold: No data availableCoefficient of Water/Oil Distribution: No data available

SECTION 10 STABILITY AND REACTIVITY

Reactivity: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides,etc.Chemical Stability: This material is considered stable under normal ambient and anticipated storage andhandling conditions of temperature and pressure.Incompatibility With Other Materials: Not applicableHazardous Decomposition Products: None known (None expected)Hazardous Polymerization: Hazardous polymerization will not occur.Sensitivity to Mechanical Impact: No.

SECTION 11 TOXICOLOGICAL INFORMATION

IMMEDIATE HEALTH EFFECTSEye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or productcomponents. Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or productcomponents. Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials orproduct components. Acute Dermal Toxicity: LD50: >5g/kg (rabbit). The acute dermal toxicity hazard is based on evaluation ofdata for similar materials or product components.Acute Oral Toxicity: LD50: >5 g/kg (rat) The acute oral toxicity hazard is based on evaluation of data forsimilar materials or product components.Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similarmaterials or product components.For additional information on the acute toxicity of the components, call thetechnical information center.ADDITIONAL TOXICOLOGY INFORMATION: This product contains petroleum base oils which may be refined by various processes including severesolvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancerwarning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not beenlisted in the National Toxicology Program (NTP) Annual Report nor have they been classified by theInternational Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probablycarcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B).These oils have not been classified by the American Conference of Governmental Industrial Hygienists(ACGIH) as: confirmed human carcinogen (A1), suspected human carcinogen (A2), or confirmed animalcarcinogen with unknown relevance to humans (A3).

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITYThis material is expected to be harmful to aquatic organisms and may cause long-term adverse effects inthe aquatic environment. The ecotoxicity hazard is based on an evaluation of data for the components or asimilar material.

ENVIRONMENTAL FATE

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Ready Biodegradability: This material is not expected to be readily biodegradable. The biodegradabilityof this material is based on an evaluation of data for the components or a similar material.

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. Oil collection services are available for used oilrecycling or disposal. Place contaminated materials in containers and dispose of in a manner consistentwith applicable regulations. Contact your sales representative or local environmental or health authoritiesfor approved disposal or recycling methods. (See B.C. Reg. GY/92 Waste Management Act; R.R.O. 1990,Reg. 347 General-Waste Management; C.C.SM.c. W40 The Waste Reduction and Prevention Act; N.S.Reg. 51/95 and N.S. Reg. 179/96 for examples of Provincial legislation.)

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate DangerousGoods Regulations, for additional description requirements (e.g., technical name) and mode-specific orquantity-specific shipping requirements.

TC Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORTATIONUNDER TDG REGULATIONS

IMO/IMDG Shipping Description: PETROLEUM LUBRICATING OIL; NOT REGULATED ASDANGEROUS GOODS FOR TRANSPORT UNDER THE IMDG CODE

ICAO/IATA Shipping Description: PETROLEUM LUBRICATING OIL; NOT REGULATED ASDANGEROUS GOODS FOR TRANSPORT UNDER ICAO TI OR IATA DGR

DOT Shipping Description: PETROLEUM LUBRICATING OIL, NOT REGULATED AS A HAZARDOUSMATERIAL FOR TRANSPORTATION UNDER 49 CFR

SECTION 15 REGULATORY INFORMATION

REGULATORY LISTS SEARCHED: 01-1=IARC Group 1 01-2A=IARC Group 2A 01-2B=IARC Group 2B 35=WHMIS IDL

No components of this material were found on the regulatory lists above.

CHEMICAL INVENTORIES:All components comply with the following chemical inventory requirements: AICS (Australia), ENCS(Japan), IECSC (China), KECI (Korea), PICCS (Philippines), TSCA (United States). One or more components is listed on ELINCS (European Union). Secondary notification by the importermay be required. All other components are listed or exempted from listing on EINECS.

WHMIS CLASSIFICATION:This product is not considered a controlled product according to the criteria of the Canadian ControlledProducts Regulations.

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7 of 7 Regal R&O 22, 32, 46, 68, 100, 115,150 MSDS : 23567

This product has been classified in accordance with the hazard criteria of the Controlled ProductsRegulations and the MSDS contains all of the information required by those regulations. (See HazardousProducts Act (HPA), R.S.C. 1985, c.H-3,s.2).

MSDS PREPARATION:

This Material Safety Data Sheet has been prepared by the Toxicology and Health Risk Assessment Unit,ERTC, P.O. Box 1627, Richmond, CA 94804, (888)676-6183.


SECTION 16 OTHER INFORMATION

HMIS RATINGS: Health: 1 Flammability: 1 Reactivity: 0

LABEL RECOMMENDATION:Label Category : INDUSTRIAL OIL 1 - IND1

REVISION STATEMENT: This revision updates the following sections of this Material Safety Data Sheet:1,15,16

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: TLV - Threshold Limit Value TWA - Time Weighted Average

STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit

CAS - Chemical Abstract Service Number ACGIH - American Conference of GovernmentalIndustrial Hygienists

IMO/IMDG - International Maritime DangerousGoods Code

API - American Petroleum Institute MSDS - Material Safety Data Sheet

CVX - Chevron NFPA - National Fire Protection Association (USA)

DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)

IARC - International Agency for Research on Cancer OSHA - Occupational Safety and HealthAdministration

The above information is based on the data of which we are aware and is believed to be correct asof the date hereof. Since this information may be applied under conditions beyond our control andwith which we may be unfamiliar and since data made available subsequent to the date hereofmay suggest modifications of the information, we do not assume any responsibility for the resultsof its use. This information is furnished upon condition that the person receiving it shall make hisown determination of the suitability of the material for his particular purpose.


1. Product and Company Identification

Material name SONIC ATF

Version # 01

Issue date 08-22-2012

Revision date -

Supersedes date -

CAS # Mixture

Product code 1221

Product use Automatic Transmission Fluid.

Synonym(s) SONIC ATF DEXRON III/MERCON; SONIC ATF DEX III

Manufacturer information

Manufacturer CHS Inc.

Address P.O. Box 64089 - Mail station 525

St. Paul, MN 55164-0089

Telephone (651) 424-8438

Supplier Federated Co-operatives Limited

Address P. O. Box 1050; 401 - 22nd Street East

Saskatoon, SK S7K 3M9 Canada

Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec

2. Hazards Identification

Physical state Liquid.

Appearance Liquid.

Emergency overview Low hazard for usual industrial or commercial handling by trained personnel.

OSHA regulatory status This product is not hazardous according to OSHA 29CFR 1910.1200.

Potential health effects

Routes of exposure Eye contact. Skin contact. Ingestion. Inhalation.

Eyes Direct contact with eyes may cause temporary irritation.

Skin Prolonged skin contact may cause temporary irritation.

Inhalation May cause respiratory tract irritation.

Ingestion Under normal conditions of intended use, this material does not pose a risk to health.

Chronic effects No data available.

Potential environmental effects No special environmental precautions required.

Components CAS # Percent

3. Composition / Information on Ingredients

64742-65-0 60-100Distillates (petroleum), solvent-dewaxed heavy paraffinic

4. First Aid Measures

First aid procedures

Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if symptomsoccur.

Skin contact In case of contact, flush skin with plenty of water for at least 20 minutes, while removingcontaminated shoes and clothes. Wash contaminated skin with soap and water. Washcontaminated clothing before reuse. Thoroughly clean shoes before reuse. Get medical attentionif irritation develops and persists.

CPH MSDS NA

1 / 5

SONIC ATF CPH MSDS NA

910066 Version #: 01 Revision date: - Issue date: 08-22-2012

Inhalation If fumes or combustion products are inhaled move victim to fresh air. Get medical attention if anydiscomfort occurs.

Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medicalattention if any discomfort occurs.

Notes to physician Treat symptomatically.

General advice If you feel unwell, seek medical advice (show the label where possible).

5. Fire Fighting Measures

Extinguishing media

Suitable extinguishing

mediaExtinguish with water spray, carbon dioxide, dry chemical or material appropriate for thesurrounding fire.

Unsuitable extinguishing

mediaNone.

Protection of firefighters

Specific hazards arising

from the chemicalBy heating and fire, toxic vapors/gases may be formed.

Fire fighting

equipment/instructionsFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

Hazardous combustion

productsNo data available.

6. Accidental Release Measures

Personal precautions In case of spills, beware of slippery floors and surfaces. Wear suitable protective clothing andgloves.

Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a widearea (e.g. by containment or oil barriers).

Methods for containment Collect and dispose of spillage as indicated in Section 13 of the MSDS.

Methods for cleaning up Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.

Other information Clean up in accordance with all applicable regulations.

7. Handling and Storage

Handling Observe good industrial hygiene practices. Use appropriate Personal Protective Equipment.

Storage Store in original tightly closed container. Keep in a cool, well-ventilated place.

8. Exposure Controls / Personal Protection

Occupational exposure limits

US. ACGIH Threshold Limit Values

ValueType FormComponents

TWA 5 mg/m3 Inhalable fraction.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)


PEL 5 mg/m3 Mist.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)

Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)


STEL 10 mg/m3 Mist.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)

TWA 5 mg/m3 Mist.

CPH MSDS NA

2 / 5



Mexico. Occupational Exposure Limit Values


STEL 10 mg/m3 Mist.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)

TWA 5 mg/m3 Mist.

Engineering controls General ventilation is normally adequate.

Personal protective equipment

Eye / face protection Wear approved safety glasses or goggles.

Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.Neoprene or nitrile gloves are recommended.

Respiratory protection No personal respiratory protective equipment normally required.

General hygiene

considerationsHandle in accordance with good industrial hygiene and safety practices.

9. Physical & Chemical Properties

Appearance Liquid.


Form Liquid.

Color Red / yellow.

Odor Mild.

Odor threshold Not available.

pH Not available.

Vapor pressure < 0.13 kPa

Vapor density > 1 ( Air=1)

Boiling point Not available.

Melting point/Freezing point 5 °F (-15 °C)

Solubility (water) Partially soluble in cold and hot water.

Specific gravity 0.85 - 0.88

Flash point > 379.4 °F (> 193 °C) Closed Cup

Flammability limits in air,

upper, % by volume

Not available.


lower, % by volume

Not available.

Auto-ignition temperature > 500 °F (> 260 °C)

Evaporation rate < 1 (ether (anhydrous) = 1)

10. Chemical Stability & Reactivity Information

Chemical stability Material is stable under normal conditions. Handling temperatures should not exceed 175ºF (80ºC). Storage temperatures should not exceed 212º F (45º C).

Conditions to avoid No data available.

Incompatible materials None known.

Hazardous decomposition

productsNone expected under normal conditions of use.

Possibility of hazardous

reactionsUnder normal conditions of storage and use, hazardous polymerization will not occur.

11. Toxicological Information

Sensitization No data available.

Acute effects No data available.

Local effects None known.

Chronic effects Chronic effects are not expected when this product is used as intended.

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

CPH MSDS NA

3 / 5



Mutagenicity Not expected to be mutagenic.

Neurological effects No data available.

Reproductive effects Contains no ingredient listed as toxic to reproduction.

Teratogenicity Not classified.

12. Ecological Information

Ecotoxicity No data on possible environmental effects have been found.

Environmental effects The product components are not classified as environmentally hazardous. However, this does notexclude the possibility that large or frequent spills can have a harmful or damaging effect on theenvironment.

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulation /

AccumulationNot available.

13. Disposal Considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose inaccordance with all applicable regulations.

Waste from residues / unused

productsDispose of waste and residues in accordance with local authority requirements.

Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.

14. Transport Information

DOT

Not regulated as a hazardous material by DOT.

IATA

Not regulated as dangerous goods.

IMDG


TDG


15. Regulatory Information

US federal regulations This product is not hazardous according to OSHA 29CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)

None

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No

Section 302 extremely

hazardous substance (40

CFR 355, Appendix A)

No

Section 311/312 (40 CFR

370)No

Drug Enforcement

Administration (DEA) (21 CFR

1308.11-15)

Not controlled

WHMIS status Non-controlled

CPH MSDS NA

4 / 5



Inventory status

Country(s) or region Inventory name On inventory (yes/no)*

Australian Inventory of Chemical Substances (AICS) YesAustralia

Domestic Substances List (DSL) YesCanada

Non-Domestic Substances List (NDSL) NoCanada

Inventory of Existing Chemical Substances in China (IECSC) NoChina

European Inventory of Existing Commercial ChemicalSubstances (EINECS)

YesEurope

European List of Notified Chemical Substances (ELINCS) NoEurope

Inventory of Existing and New Chemical Substances (ENCS) YesJapan

Existing Chemicals List (ECL) YesKorea

New Zealand Inventory NoNew Zealand

Philippine Inventory of Chemicals and Chemical Substances(PICCS)

YesPhilippines

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)

Toxic Substances Control Act (TSCA) Inventory NoUnited States & Puerto Rico

State regulations

US - California Hazardous Substances (Director's): Listed substance

Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0)

Listed.

US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance

Not listed.

US - New Jersey RTK - Substances: Listed substance


Listed.

US. Massachusetts RTK - Substance List


Listed.

US. New Jersey Worker and Community Right-to-Know Act

Not regulated.

US. Pennsylvania RTK - Hazardous Substances

Not regulated.

16. Other Information

Further information HMIS® is a registered trade and service mark of the NPCA.

HMIS® ratings Health: 1Flammability: 1Physical hazard: 0

NFPA ratings Health: 1Flammability: 1Instability: 0

Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.

CPH MSDS NA

5 / 5




1. Product and Company IdentificationMaterial name SONIC BLUE GUARDVersion # 02

Issue date 19-September-2011

Revision date 20-May-2014

Supersedes date 19-September-2011

CAS # Mixture

Product code 1696

Product use Multi-purpose grease

Synonym(s) GREASE, MULTIPURPOSE

Manufacturer informationManufacturer CHS Inc.

Address P.O. Box 64089, Mail station 525

St. Paul, MN 55164-0089

Telephone (651) 355-8438


Address P.O. Box 1050, 401 - 22nd Street

East Saskatoon SK S7K 3M9 Canada

Telephone (306) 244-3447

24 Hour EmergencyTelephone

(613) 996-6666 - Canutec

2. Hazards IdentificationPhysical state Solid.

Appearance Gel-like solid.


OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.

Potential health effectsRoutes of exposure Eye contact. Skin contact.






Potential environmental effects The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.



64742-52-5 60-100Distillates (petroleum), hydrotreated heavy naphthenic

Composition comments * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume.

4. First Aid MeasuresFirst aid procedures

Eye contact Immediately rinse with water for several minutes.

Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.


SONIC BLUE GUARD CPH MSDS NA

904292 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 1 / 6




5. Fire Fighting MeasuresExtinguishing media

Suitable extinguishingmedia

Extinguish with water spray, carbon dioxide, dry chemical or material appropriate for thesurrounding fire.

Unsuitable extinguishingmedia

None.

Protection of firefightersSpecific hazards arisingfrom the chemical

By heating and fire, toxic vapors/gases may be formed.

Fire fightingequipment/instructions

Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.


Hazardous combustionproducts

No data available.

6. Accidental Release MeasuresPersonal precautions In case of spills, beware of slippery floors and surfaces. Wear suitable protective clothing and

gloves.

Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a wide area(e.g. by containment or oil barriers).




7. Handling and StorageHandling Observe good industrial hygiene practices. Use appropriate Personal Protective Equipment.


8. Exposure Controls / Personal ProtectionOccupational exposure limits


ValueType FormComponentsTWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),

hydrotreated heavynaphthenic (CAS64742-52-5)


ValueType FormComponentsPEL 5 mg/m3 Mist.Distillates (petroleum),


2000 mg/m3

500 ppm

Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

ValueType FormComponentsSTEL 10 mg/m3 Mist.Distillates (petroleum),


TWA 5 mg/m3 Mist.



Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)






TWA 5 mg/m3 Mist.




TWA 5 mg/m3 Mist.


Personal protective equipmentEye / face protection Wear approved safety glasses or goggles.

Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.


General hygieneconsiderations

Handle in accordance with good industrial hygiene and safety practices.

9. Physical & Chemical PropertiesAppearance Gel-like solid.

Physical state Solid.

Form Gel.

Color Blue.

Odor Slight petroleum odor.


pH Not available.

Vapor pressure < 0.13 kPa (< 1mm Hg)

Vapor density > 1 (Air = 1)

Boiling point > 600.8 °F (> 316 °C)

Melting point/Freezing point > 500 °F (> 260 °C)


Specific gravity 0.91

Flash point > 399.2 °F (> 204.0 °C) Pensky-Martens Closed Cup

Flammability limits in air,upper, % by volume

Not available.

Flammability limits in air,lower, % by volume

Not available.

Auto-ignition temperature Not available.

Evaporation rate < 1 (Ether = 1.0)

10. Chemical Stability & Reactivity InformationChemical stability Material is stable under normal conditions.

Conditions to avoid Prolonged excessive heat may cause product decomposition.



Incompatible materials Strong oxidizing agents.

Hazardous decompositionproducts

None expected under normal conditions of use.

Possibility of hazardousreactions

Will not occur.

11. Toxicological InformationSensitization Not a skin or respiratory sensitizer.

Acute effects May be harmful if swallowed.




ACGIH CarcinogensDistillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)

A4 Not classifiable as a human carcinogen.

IARC Monographs. Overall Evaluation of CarcinogenicityDistillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)

3 Not classifiable as to carcinogenicity to humans.



Reproductive effects Not classified.


12. Ecological InformationEcotoxicity No data on possible environmental effects have been found.



Bioaccumulation /Accumulation

Not available.

13. Disposal ConsiderationsWaste codes Not regulated.


Waste from residues / unusedproducts

Dispose of waste and residues in accordance with local authority requirements.


14. Transport InformationDOT


IATANot regulated as dangerous goods.

IMDGNot regulated as dangerous goods.

TDGNot regulated as dangerous goods.

15. Regulatory InformationUS federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.

All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.



Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListNot regulated.

CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)None

Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes

Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No

SARA 302 Extremely hazardous substanceNot listed.

SARA 311/312 Hazardouschemical

Yes

Drug EnforcementAdministration (DEA) (21 CFR1308.11-15)

Not controlled


Inventory statusCountry(s) or region Inventory name On inventory (yes/no)*




Inventory of Existing Chemical Substances in China (IECSC) YesChina


YesEurope


Inventory of Existing and New Chemical Substances (ENCS) NoJapan


New Zealand Inventory YesNew Zealand


YesPhilippines

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico

State regulations This product does not contain a chemical known to the State of California to cause cancer, birthdefects or other reproductive harm.

US - California Hazardous Substances (Director's): Listed substanceDistillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)

Listed.

US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.

US. Massachusetts RTK - Substance ListDistillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)

Listed.

US. New Jersey Worker and Community Right-to-Know ActNot listed.

US. Pennsylvania Worker and Community Right-to-Know LawNot listed.

16. Other InformationFurther information The classification for health and environmental hazards is derived by a combination of calculation

methods and test data, if available.



NFPA Ratings

01

1





1. Product and Company IdentificationSonic Moly Guard SLProduct identifier01Version #24-April-2015Issue date-Revision date-Supersedes dateMixtureCAS #1761Product codeMulti-purpose greaseProduct useGrease, Multi-purposeSynonym(s)

Manufacturer CHS Inc.Address P.O. Box 64089 - Mail station 525

St. Paul, MN 55164-0089Telephone (651) 424-8438Supplier Federated Co-operatives LimitedAddress P. O. Box 1050; 401 - 22nd Street East

Saskatoon, SK S7K 3M9 CanadaTelephone (306) 244-344724 Hour EmergencyTelephone

(613) 996-6666 - Canutec


2. Hazards IdentificationCAUTION!

May cause skin irritation.

Emergency overview

Potential health effectsSkin contact. Eye contact. Inhalation.Routes of exposureMay cause eye irritation.EyesMay cause skin irritation. Prolonged or repeated contact with skin may cause redness, itching,irritation, eczema/chapping and oil acne. The harmful effects may increase when exposed to usedgrease.

Skin

Mineral oil fume may cause irritation to the respiratory system. Inhalation of oil mist or vaporsformed during heating of the product will irritate the respiratory system and provoke coughing.

Inhalation

May cause discomfort if swallowed.IngestionProlonged and repeated contact with used grease may cause serious skin diseases, such asdermatitis and skin cancer.

Chronic effects

Prolonged or frequent contact may cause redness, itching and eczema/chaps. Direct contact witheyes may cause temporary irritation.

Signs and symptoms

Greases are generally hazardous to the environment.Potential environmental effects



64742-52-5 75-95Distillates (petroleum), hydrotreated heavy naphthenic

7620-77-1 >1Lithium 12-hydroxystearate


Move affected person into fresh air and keep warm. If breathing is difficult, give oxygen. Getmedical attention if any discomfort continues.

Inhalation

Sonic Moly Guard SL MSDS Canada

908002 Version #: 01 Revision date: - Issue date: 24-April-2015 1 / 6

Remove contaminated clothing. Wash with soap and water. Get medical attention promptly ifsymptoms occur after washing.

Skin contact

Flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present andeasy to do. Get medical attention if irritation develops and persists.

Eye contact

Immediately rinse mouth and drink plenty of water. Never give anything by mouth to anunconscious person. Get medical attention if any discomfort continues.

Ingestion

Treat symptomatically. The effects might be delayed.Notes to physicianFirst aid personnel must be aware of own risk during rescue.General advice

5. Fire Fighting MeasuresMaterial will burn in a fire.Flammable properties

Extinguishing mediaExtinguish with foam, carbon dioxide or dry powder.Suitable extinguishing

mediaWater Spray or Fog.Unsuitable extinguishing

mediaProtection of firefighters

Thermal decomposition may produce smoke, oxides of carbon and lower molecular weight organiccompounds whose composition have not been characterized.

Specific hazards arisingfrom the chemical

Selection of respiratory protection for firefighting: follow the general fire precautions indicated inthe workplace. Self-contained breathing apparatus, operated in positive pressure mode and fullprotective clothing must be worn in case of fire.

Protective equipment forfirefighters

Use standard firefighting procedures and consider the hazards of other involved materials.Fire fightingequipment/instructions

Move container from fire area if it can be done without risk. Cool containers exposed to flames withwater until well after the fire is out.

Specific methods

Explosion dataNot sensitive.Sensitivity to static

dischargeNot sensitive.Sensitivity to mechanical

impactMetal oxides. Carbon monoxide and carbon dioxide. Nitrogen oxides. Sulfur oxides. Boron oxides.Hydrogen sulfide. Alkyl mercaptans. Lithium oxides


Material will burn in a fire.General fire hazards

6. Accidental Release MeasuresKeep unnecessary personnel away. Wear appropriate protective equipment and clothing duringclean-up. In case of spills, beware of slippery floors and surfaces. Do not touch damagedcontainers or spilled material unless wearing appropriate protective clothing. Avoid inhalation ofvapors and contact with skin and eyes. Ensure adequate ventilation. Local authorities should beadvised if significant spillages cannot be contained. For personal protection, see section 8 of theMSDS.

Personal precautions

Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoiddischarge into drains, water courses or onto the ground. Do not contaminate water.

Environmental precautions

Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.Prevent entry into waterways, sewer, basements or confined areas.

Methods for containment

Should not be released into the environment.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earthand place into containers. Clean contaminated area with oil-removing material.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of theMSDS.

Methods for cleaning up

Clean up in accordance with all applicable regulations.Other information



7. Handling and StorageAvoid prolonged and repeated contact with grease, particularly used grease. Always removegrease with soap and water or skin cleaning agent, never use organic solvents. Wear appropriatepersonal protective equipment. Be aware of potential for surfaces to become slippery. Observegood industrial hygiene practices.

Handling

Keep container in a well-ventilated place. Store away from incompatible materials (See Section10).

Storage








TWA 5 mg/m3 Mist.

Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)






TWA 5 mg/m3 Mist.


ValueType FormComponentsPEL 5 mg/m3 Mist.Distillates (petroleum),


2000 mg/m3

500 ppm

ACGIH Threshold Limit Values for mineral oil mist:The 8-Hour Exposure Limit (TLV-TWA) is 5 mg/m3. The 15-minute STEL is 10 mg/m3.Provide adequate ventilation and minimize the risk of inhalation of vapors and oil mist. Provideaccess to washing facilities including soap, skin cleanser and fatty cream.

Engineering controls

Personal protective equipmentWear approved safety goggles.Eye / face protectionWear protective gloves. Be aware that the liquid may penetrate the gloves. Frequent change isadvisable. Suitable gloves can be recommended by the glove supplier. Wear appropriate clothingto prevent repeated or prolonged skin contact.

Skin protection



If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn. Use a NIOSH/MSHA approved airpurifying respirator as needed to control exposure. Consult with respirator manufacturer todetermine respirator selection, use, and limitations. Use positive pressure, air-supplied respiratorfor uncontrolled releases or when air purifying respirator limitations may be exceeded. Followrespirator protection program requirements (OSHA 1910.134 and ANSI Z88.2) for all respiratoruse.

Respiratory protection

9. Physical & Chemical PropertiesGray to black gel.AppearanceSolid.Physical stateGel.FormGray to black.ColorSlight oil-like.Odor


pH Not available.

Vapor pressure Not available.

Vapor density Not available.


Melting point/Freezing point Not available.

Solubility (water) Insoluble in water.


Flash point > 399.2 °F (> 204.0 °C) Closed Cup


Not available.


Not available.

Auto-ignition temperature 699.98 °F (371.1 °C)

VOC < 1 % v/v

Evaporation rate < 1 (Ether (anhydrous)=1)

Partition coefficient(n-octanol/water)

Not available.

10. Chemical Stability & Reactivity InformationThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityStable at normal conditions.Chemical stabilityHeat, sparks, flames, elevated temperatures. Contact with incompatible materials.Conditions to avoidOxidizing agents. Acids.Incompatible materialsThermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors.Hazardous decomposition

productsWill not occur.Possibility of hazardous

reactions

11. Toxicological InformationAcute effects Inhalation of oil mist or vapors formed during heating of the product will irritate the respiratory

system and provoke coughing. The harmful effects may increase when exposed to used grease.Ingestion may cause irritation and malaise. May cause eye irritation.

Sensitization Not a skin or respiratory sensitizer.

Local effects May cause eye, skin and respiratory tract irritation.

Chronic effects Prolonged or repeated contact with skin may cause redness, itching, irritation, eczema/chappingand oil acne.

Carcinogenicity Prolonged and repeated contact with used grease may cause serious skin diseases, such asdermatitis and skin cancer.



ACGIH CarcinogensDistillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)

A4 Not classifiable as a human carcinogen.

IARC Monographs. Overall Evaluation of CarcinogenicityDistillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)

3 Not classifiable as to carcinogenicity to humans.

May cause skin irritation.Skin corrosion/irritationDirect contact with eyes may cause temporary irritation.Serious eye damage/irritationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Mutagenicity

This product is not expected to cause reproductive or developmental effects.Reproductive effectsThis product is not reported to cause teratogenic effects in humans.Teratogenicity

Symptoms and target organs Prolonged or frequent contact may cause redness, itching and eczema/chaps. Direct contact witheyes may cause temporary irritation.

Synergistic materials None known.

Further information Pre-existing skin conditions including dermatitis might be aggravated by exposure to this product.Prolonged and repeated contact with used grease may cause serious skin diseases, such asdermatitis and skin cancer.

12. Ecological InformationNo ecotoxicity data noted for the ingredient(s).Ecotoxicological dataThe product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.Oil spills are generally hazardous to the environment.

Ecotoxicity

Not classified as an environmental hazard.Environmental effectsNot classified.Aquatic toxicityNo data is available on the degradability of this product.Persistence and degradabilityNo data available on bioaccumulation.Bioaccumulation /

accumulationThe product contains substances, which are insoluble in water and which may spread on watersurfaces.

Mobility in environmentalmediaOther adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation

potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal ConsiderationsDispose in accordance with applicable federal, state, and local regulations. Do not incineratesealed containers. Do not allow this material to drain into sewers/water supplies.

Disposal instructions

Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).


Empty packaging should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.

Contaminated packaging

14. Transport InformationTDG




15. Regulatory InformationThis product has been classified in accordance with the hazard criteria of the CPR and the MSDScontains all the information required by the CPR.

Canadian regulations




International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*






YesEurope






YesPhilippines



16. Other InformationThe classification for health and environmental hazards is derived by a combination of calculationmethods and test data, if available.

Further information

Health: 1Flammability: 1Instability: 0

NFPA ratings

To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.

Disclaimer

Not available.Prepared by





Material name D-MO

Version # 02


Revision date 11-13-2012

Supersedes date 01-04-2012

CAS # Mixture

Product code 189

Product use Lubrication oil.

Synonym(s) SAE 10W, 20W-20, 30, 40, 50, Sonic D-MO


Manufacturer Consumers' Co-operative Refineries Limited

Address P.O. Box 260; 9th Avenue North

Regina, SK S4P 3A1 Canada

Telephone (306) 721-5353


Address P.O. Box 1050, 401 - 22nd Street East

Saskatoon SK S7K 3M9 Canada

Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec



Appearance Oily liquid.

Emergency overview WARNING

Causes skin and eye irritation.




Eyes Causes eye irritation.

Skin Causes skin irritation.


Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.





68649-42-3 1-5Zinc Alkyldithiophosphate




CPH MSDS NA

1 / 5

D-MO CPH MSDS NA

906163 Version #: 02 Revision date: 11-13-2012 Issue date: 01-04-2012







Extinguishing media




mediaNone.




Fire fighting















Occupational exposure limits No exposure limits noted for ingredient(s).






General hygiene





Form Liquid.

Color Brown.

Odor Mild.


CPH MSDS NA

2 / 5

D-MO CPH MSDS NA


pH Not available.




Melting point/Freezing point -4 °F (-20 °C)

Solubility (water) Slight


Flash point > 296.6 °F (> 147 °C) Open Cup


upper, % by volume

Not available.


lower, % by volume

Not available.

Auto-ignition temperature 775.4 °F (413 °C)


Chemical stability Material is stable under normal conditions.

Conditions to avoid Contact with incompatible materials.





reactionsWill not occur.



Acute effects Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Local effects Causes skin and eye irritation.











Bioaccumulation /








DOT


CPH MSDS NA

3 / 5

D-MO CPH MSDS NA


IATA


IMDG


TDG



US federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.


Not regulated.


Not regulated.

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration

Zinc Alkyldithiophosphate (CAS 68649-42-3) 1.0 % N982

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance

Zinc Alkyldithiophosphate (CAS 68649-42-3) N982 Listed.


None






No


370)No

Drug Enforcement


1308.11-15)

Not controlled

Canadian regulations Canadian NPRI: The following components are listed: Zinc.

WHMIS status Controlled

WHMIS classification D2B - Other Toxic Effects-TOXIC

WHMIS labeling

Inventory status







YesEurope




CPH MSDS NA

4 / 5

D-MO CPH MSDS NA





YesPhilippines



State regulations


Zinc Alkyldithiophosphate (CAS 68649-42-3) Listed.


Not listed.




Not regulated.


Zinc Alkyldithiophosphate (CAS 68649-42-3) 500 LBS


Not regulated.



HMIS® ratings Health: 2Flammability: 1Physical hazard: 0Personal protection: X


Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable.

CPH MSDS NA

5 / 5

D-MO CPH MSDS NA




Material name SONIC ATF TYPE F

Version # 01


Revision date -

Supersedes date -

CAS # Mixture

Product code 181

Product use Automatic Transmission Fluid.





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec















The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.







CPH MSDS NA

1 / 5

SONIC ATF TYPE F CPH MSDS NA





Extinguishing media




mediaNone.




Fire fighting





















General hygiene





Form Liquid.

Color Clear red.

Odor Oil.


pH Not available.



Boiling point 543.2 - 773.6 °F (284 - 412 °C)

Melting point/Freezing point -38.2 °F (-39 °C)



CPH MSDS NA

2 / 5





upper, % by volume

Not available.


lower, % by volume

Not available.
























Bioaccumulation /








DOT


IATA


IMDG


TDG


CPH MSDS NA

3 / 5






Not regulated.


Not regulated.


None






No


370)No

Drug Enforcement


1308.11-15)

Not controlled


Inventory status







YesEurope






YesPhilippines



State regulations


Not listed.


Not regulated.


Not regulated.


Not regulated.




CPH MSDS NA

4 / 5





CPH MSDS NA

5 / 5




1. Product and Company IdentificationMaterial name SONIC INDUSTRIAL GEAR OILVersion # 02Issue date 19-September-2011Revision date 20-May-2014Supersedes date 19-September-2011CAS # -Product code 182Product use Gear lubricantSynonym(s) ISO GRADES 100, 150, 220, 320, 460

Manufacturer informationManufacturer Consumers' Co-operative Refineries LimitedAddress P.O. Box 260; 9th Avenue North

Regina, SK S4P 3A1 CanadaTelephone (306) 721-5353 -or- (306) 719-4353Supplier Federated Co-operatives LimitedAddress P.O. Box 1050, 401 - 22nd Street East

Saskatoon SK S7K 3M9 CanadaTelephone (306) 244-344724 Hour EmergencyTelephone

(613) 996-6666 - Canutec

2. Hazards IdentificationPhysical state Liquid.Appearance Dark viscous liquid.Emergency overview Low hazard for usual industrial or commercial handling by trained personnel.OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.

Potential health effectsRoutes of exposure Eye contact. Skin contact. Ingestion.Eyes Direct contact with eyes may cause temporary irritation.Skin Prolonged skin contact may cause temporary irritation.Inhalation May cause respiratory tract irritation.Ingestion Under normal conditions of intended use, this material does not pose a risk to health.

Chronic effects No data available.Potential environmental effects The product is not classified as environmentally hazardous. However, this does not exclude the

possibility that large or frequent spills can have a harmful or damaging effect on the environment.



64742-62-7 100Residual oils (petroleum), solvent-dewaxed


Eye contact Immediately rinse with water for several minutes.Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.Inhalation If fumes or combustion products are inhaled move victim to fresh air. Get medical attention if any

discomfort occurs.Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical

attention if any discomfort occurs.

SONIC INDUSTRIAL GEAR OIL CPH MSDS NA904240 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 1 / 5

Notes to physician Treat symptomatically.General advice If you feel unwell, seek medical advice (show the label where possible).





None.





Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.Hazardous combustionproducts

No data available.


gloves.Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a wide area

(e.g. by containment or oil barriers).Methods for containment Collect and dispose of spillage as indicated in Section 13 of the MSDS.Methods for cleaning up Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.Other information Clean up in accordance with all applicable regulations.

7. Handling and StorageHandling Observe good industrial hygiene practices. Use appropriate Personal Protective Equipment.Storage Store in original tightly closed container. Keep in a cool, well-ventilated place.



ValueType FormComponentsPEL 5 mg/m3 Mist.Residual oils (petroleum),

solvent-dewaxed (CAS64742-62-7)Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

ValueType FormComponentsSTEL 10 mg/m3 Mist.Residual oils (petroleum),

solvent-dewaxed (CAS64742-62-7)

TWA 5 mg/m3 Mist.

Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)



TWA 5 mg/m3 Mist.




TWA 5 mg/m3 Mist.SONIC INDUSTRIAL GEAR OIL CPH MSDS NA904240 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 2 / 5




TWA 5 mg/m3 Mist.Engineering controls General ventilation is normally adequate.

Personal protective equipmentEye / face protection Wear approved safety glasses or goggles.Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.Respiratory protection No personal respiratory protective equipment normally required.General hygieneconsiderations


9. Physical & Chemical PropertiesAppearance Dark viscous liquid.Physical state Liquid.Form Liquid.Color Dark.Odor Slight.


pH Not available.

Vapor pressure < 0 mm Hg (20 °C)



Solubility (water) Nil in water.


Flash point > 294.0 °F (> 145.6 °C)


Not available.


Not available.

Auto-ignition temperature 755 °F (401.67 °C)

VOC Nil.

Viscosity 2636 SUS (100 °F)491.4 cSt (40 °C)

Pour point 15.8 °F (-9 °C)

Bulk density 7.42 lb/gal

Molecular weight 690 g/mol

10. Chemical Stability & Reactivity InformationChemical stability Material is stable under normal conditions.Conditions to avoid Prolonged excessive heat may cause product decomposition.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts



Will not occur.

11. Toxicological InformationSensitization Not a skin or respiratory sensitizer.

Acute effects May be harmful if swallowed.





Mutagenicity Not expected to be mutagenic.Neurological effects No data available.

Reproductive effects Not classified.Teratogenicity Not classified.



Persistence and degradability No data is available on the degradability of this product.Bioaccumulation /Accumulation

Not available.

13. Disposal ConsiderationsWaste codes Not regulated.Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in

accordance with all applicable regulations.Waste from residues / unusedproducts




Not regulated as a hazardous material by DOT.IATA

Not regulated as dangerous goods.IMDG

Not regulated as dangerous goods.TDG



All components are on the U.S. EPA TSCA Inventory List.TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)

NoneSuperfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No

SARA 302 Extremely hazardous substanceNot listed.

SARA 311/312 Hazardouschemical

Yes


Not controlled




Australian Inventory of Chemical Substances (AICS) YesAustraliaDomestic Substances List (DSL) YesCanadaNon-Domestic Substances List (NDSL) NoCanadaInventory of Existing Chemical Substances in China (IECSC) YesChinaEuropean Inventory of Existing Commercial ChemicalSubstances (EINECS)

YesEurope

European List of Notified Chemical Substances (ELINCS) NoEuropeInventory of Existing and New Chemical Substances (ENCS) NoJapanExisting Chemicals List (ECL) YesKoreaNew Zealand Inventory YesNew ZealandPhilippine Inventory of Chemicals and Chemical Substances(PICCS)

YesPhilippines




US - California Hazardous Substances (Director's): Listed substanceResidual oils (petroleum), solvent-dewaxed (CAS64742-62-7)

Listed.

US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceNot listed.

US. Massachusetts RTK - Substance ListResidual oils (petroleum), solvent-dewaxed (CAS64742-62-7)

Listed.

US. New Jersey Worker and Community Right-to-Know ActResidual oils (petroleum), solvent-dewaxed (CAS 64742-62-7)

US. Pennsylvania Worker and Community Right-to-Know LawResidual oils (petroleum), solvent-dewaxed (CAS 64742-62-7)

16. Other InformationFurther information The classification for health and environmental hazards is derived by a combination of calculation

methods and test data, if available.

NFPA Ratings

01

1





Material name SONIC MP GEAR OIL

Version # 01


Revision date -

Supersedes date -

CAS # Mixture

Product code 183

Product use Gear lubricant.

Synonym(s) SAE GRADES 75W90, 80W90, 85W140





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec





















CPH MSDS NA

1 / 5

SONIC MP GEAR OIL CPH MSDS NA






Extinguishing media




mediaNone.




Fire fighting





















General hygiene





Form Liquid.

Color Brown.

Odor Mild.


pH Not available.




Melting point/Freezing point 5 - -22 °F (-15 - -30 °C)

CPH MSDS NA

2 / 5







upper, % by volume

Not available.


lower, % by volume

Not available.
























Bioaccumulation /








DOT


IATA


IMDG


TDG


CPH MSDS NA

3 / 5






Not regulated.


Not regulated.


None






No


370)No

Drug Enforcement


1308.11-15)

Not controlled


Inventory status







YesEurope






YesPhilippines



State regulations


Not listed.


Not regulated.


Not regulated.


Not regulated.




CPH MSDS NA

4 / 5





CPH MSDS NA

5 / 5





Material name INDUSTRIAL HYDRAULIC OIL

Version # 02


Revision date 07-31-2012

Supersedes date 07-31-2012

CAS # Mixture

Product code 184

Product use Hydraulic oil.

Synonym(s) ISO GRADES 22, 32, 46, 68, 100, 150, MV22, HVI 36





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec





















CPH MSDS NA

1 / 5

INDUSTRIAL HYDRAULIC OIL CPH MSDS NA






Extinguishing media




mediaNone.




Fire fighting





















General hygiene





Form Liquid.

Color Brown.

Odor Mild.


pH Not available.




CPH MSDS NA

2 / 5



Melting point/Freezing point 14 °F (-10 °C)





upper, % by volume

Not available.


lower, % by volume

Not available.
























Bioaccumulation /








DOT


IATA


IMDG


CPH MSDS NA

3 / 5



TDG





Not regulated.


Not regulated.


None






No


370)No

Drug Enforcement


1308.11-15)

Not controlled


Inventory status







YesEurope






YesPhilippines



State regulations


Not listed.


Not regulated.


Not regulated.


Not regulated.

CPH MSDS NA

4 / 5








CPH MSDS NA

5 / 5



MATERIAL SAFETY DATA SHEET 12435 INSECT REPELLENT HD AEROSOL 1 of 2

DEGIL SAFETY PRODUCTS 200 ZENWAY BLVD. UNIT 1 PH. 905-856-1511

www.degilsafety.com VAUGHAN, ON CANADA L4H 0L6 FAX. 905-856-1694SECTION ONE PRODUCT IDENTIFICATIONTRADE NAME CROC BLOC HEAVY DUTY INSECT REPELLENT AEROSOL UPC CODE

CHEMICAL FAMILY N,N-DIETHYL m-TOLUAMIDE (DEET)

PRODUCT USE Packaging

MOLECULAR WEIGHT NOT APPLICABLE 24 CANS / CASE

FORMULA NOT APPLICABLE

CNFC SECTION 3 3.5 LEVEL 3

NFPA CODE 30B LEVEL 3

T.D.G. CLASS ORM-D CONSUMER COMMODITY (AEROSOLS, UN1950, CLASS 2.1)

WHMIS CLASSIFICATION NOT APPLICABLE

HMIS RATING: FLAMMABILITY 4 SEVERE HAZARD

HMIS RATING: HEALTH 2 MODERATE HAZARD

HMIS RATING: REACTIVITY 0 MINIMAL HAZARD

SECTION TWO COMPOSITION / INFORMATION INGREDIENTSHazardous Ingredients % T.L.V. C.A.S. # LD/50, Route, Species LC/50, Route, Species

N,N-DIETHYL m-TOLUAMIDE 28.5 N/A 134-62-3 2000 mg/kg ORAL - RAT 5950 mg/kg INHAL - RAT

ETHANOL 30 - 60 1000ppm 64-17-5 7060mg/kg ORAL - RAT 31623ppm (4hr) INHAL - RAT

ISOBUTANE 10 - 30 1000ppm 75-28-5 NOT AVAILABLE 142500 ppm (4hr) INHAL - RAT

PROPANE 1 - 5 1000ppm 74-98-6 >5000mg/kg DERMAL-RABBITS NOT AVAILABLE

SECTION THREE PHYSICAL DATAPHYSICAL STATE AEROSOLAPPEARANCE CLEAR - COLOURLESSODOR FRAGRANTODOR THRESHOLD NOT AVAILABLEBOILING POINT (° C)(CONC) 78.5°CEVAPORATION RATE GREATER THAN 1VAPOUR PRESSURE (PSIG) AEROSOL 40 - 50 @ 20° CVAPOUR DENSITY (AIR=1) GREATER THAN 1AEROSOL % VOC (w/w) 79 - 80AEROSOL % VOLATILE 79 - 80SOLUBILITY IN WATER NOT AVAILABLEpH NOT APPLICABLESPECIFIC GRAVITY (LIQUID) 0.83 - 0.87SPECIFIC GRAVITY (AEROSOL) 0.75 - 0.79COEFFICIENT OF WATER/OIL DIST NOT AVAILABLEFREEZING POINT: (° C) NOT AVAILABLESECTION FOURAEROSOL FLAME PROJECTION > 15cm BUT < 100cm

FLASHBACK NOT APPLICABLE

FLAMMABILITY EXTREMELY FLAMMABLE

IF YES, UNDER WHICH CONDITIONS EXCESSIVE HEAT, SPARKS AND OPEN FLAME

AUTO IGNITION TEMPERATURE (° C) LOWEST KNOWN VALUE IS 422°C (ETHANOL)

EXTINGUISHING MEDIA CARBON DIOXIDE, DRY CHEMICAL, FOAM

UPPER FLAMMABLE LIMIT 19.0 (% BY VOLUME)

LOWER FLAMMABLE LIMIT 3.3 (% BY VOLUME)

EXPLOSION DATA

SENSITIVITY TO STATIC DISCHARGE NOT APPLICABLE

SENSITIVITY TO IMPACT NOT APPLICABLE

HAZARDOUS COMBUSTION

PRODUCTS HYDROCARBON FUMES AND SMOKE, CARBON MONOXIDE WHERE

COMBUSTION IS INCOMPLETE.

FLASH POINT (° C) TAG CLOSED CUP - LOWEST KNOWN VALUE IS ETHANOL @ 13°C

(CONCENTRATE)

SPECIAL PROCEDURES WATER FROM FOGGING NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS

TO PREVENT BUILD UP IF EXPOSED TO EXTREME TEMPERATURES. FULL

PROTECTIVE EQUIPMENT INCLUDING SELF CONTAINED BREATHING APPARATUSSHOULD BE WORN IN A FIRE INVOLVING THIS MATERIAL.

INSECTICIDE

FIRE & EXPLOSION HAZARD DATA

Reviewed On: 1/29/201511:22 AM ITEM# 12435 DEGIL SAFETY PRODUCTS

MATERIAL SAFETY DATA SHEET 12435 INSECT REPELLENT HD AEROSOL 2 of 2

SECTION FIVE STABILITY AND REACTIVITYHAZARDOUS PRODUCTS OFDECOMPOSITION HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE

COMBUSTION IS INCOMPLETECHEMICAL STABILITY YES

UNDER NORMAL CONDITIONSCOMPATABILITY WITH OTHERSUBSTANCES - NO, WHICH ONES? STRONG OXIDIZING AGENTSREACTIVITY CONDITIONS? NOT APPLICABLESECTION SIX HEALTH DATAROUTE OF ENTRY

INGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING & WEAKNESS

INHALATION INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLENT IS SIMPLE ASPHYXIANT

EYE CONTACT MAY CAUSE IRRITATION

SKIN CONTACT MAY CAUSE IRRITATION

EFFECTS OF ACUTE EXPOSURE DIZZINESS, NAUSEA, IRRITATION TO SKIN & EYES

EFFECTS OF CHRONIC EXPOSURE SOLVENTS MAY CAUSE DEFATTING DERMATITIS

EXPOSURE LIMIT OF MATERIAL SEE SECTION TWO

CARCINOGENICITY OF MATERIAL THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS

CARCINOGENS BY NTP, (NATIONAL TOXICOLOGY PROGRAM), NOT

REGULATED AS CARCINOGENS BY OSHA, (OCCUPATIONAL SAFETY

AND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED BY

IARC, (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR

BYACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL

INDUSTRIAL HYGIENISTS).

REPRODUCTIVE EFFECTS NO INFORMATION IS AVAILABLE AND NO ADVERSE RESPRODUCTIVE

EFFECTS ARE ANTICIPATED.

IRRITANCY OF MATERIAL SLIGHT

TERATOGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENICITY


MUTAGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC


SYNERGISTIC MATERIALS NONE KNOWN

SECTION SEVEN EXPOSURE CONTROLS/PERSONAL PROTECTIONGLOVES CHEMICAL RESISTANT GLOVES

RESPIRATORY IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE

RESPIRATOR (NIOSH/MSHA TC-23C OR EQUIVALENT) IS RECOMMENDED.

EYE SAFETY GLASSES

ENGINEERING CONTROLS VENTILATION - LOCAL (MECHANICAL IF INDOORS ON A CONTINUOUS BASIS)

FOOTWEAR NOT NORMALLY REQUIRED

OTHER NOT REQUIRED

SECTION EIGHTLEAK / SPILL REMOVE ALL SOURCES OF IGNITION, USE AN INERT ABSORBENT MATERIAL AND NON -

SPARKING TOOLS. VENTILATE AREA. PREVENT FROM ENTERING A WATERCOURSE

STORAGE NEEDS KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMS

HANDLING PROCEDURES AND STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C.

EQUIPMENT

SHIPPING INSTRUCTIONS SEE SECTION ONE TDG CLASSIFICATION

WASTE DISPOSAL DO NOT PUNCTURE OR INCINERATE PACKAGES EVEN WHEN EMPTY. DISPOSE OF IN

ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONS

SECTION NINEEMERGENCY FIRST AID PROCEDURE

SECTION TEN ADDITIONAL INFORMATIONThis document has been prepared using data from sources considered technically reliable.

It does not constitute a warranty, express or implied, as to the accuracy of the information

contained herein. Actual conditions of use and handling are beyond seller's control.

User is responsible to evaluate all available information when using product for any

particular use and to comply with all Federal, State, Provincial and local laws and

regulations.

Prepared By: Maureen Kayum 1-800-332-1810 REVIEWED ON: JANUARY 29/2015

INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR. IF

SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION.

HANDLING AND STORAGE

FIRST AID MEASURES IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF

WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. FOR

SKIN, WASH THOROUGHLY WITH SOAP AND WATER. IF AFFECTED BY

Reviewed On: 1/29/201511:22 AM ITEM# 12435 DEGIL SAFETY PRODUCTS

MATERIAL SAFETY DATA SHEET 12415 INSECT REPELLENT FOAM 1 of 2

1/29/201510:57 AM ITEM# 12415 DEGIL SAFETY PRODUCTS

DEGIL SAFETY PRODUCTS 200 ZENWAY BLVD. UNIT 1 PH. 905-856-1511

www.degilsafety.com VAUGHAN, ON CANADA L4H 0L6 FAX. 905-856-1694SECTION ONE PRODUCT IDENTIFICATIONTRADE NAME CROC BLOC INSECT REPELLENT FOAM UPC CODE

CHEMICAL FAMILY N,N-DIETHYL m-TOLUAMIDE (DEET)

PRODUCT USE Packaging

MOLECULAR WEIGHT NOT APPLICABLE 48 CANS / CASE

FORMULA NOT APPLICABLE

CNFC SECTION 3 3.5 LEVEL 1

NFPA CODE 30B LEVEL 1

T.D.G. CLASS ORM-D CONSUMER COMMODITY

WHMIS CLASSIFICATION NOT APPLICABLE

HMIS RATING: FLAMMABILITY 1 SLIGHT HAZARD

HMIS RATING: HEALTH 2 MODERATE HAZARD

HMIS RATING: REACTIVITY 0 MINIMAL HAZARD

SECTION TWO COMPOSITION / INFORMATION INGREDIENTSHazardous Ingredients % T.L.V. C.A.S. # LD/50, Route, Species LC/50, Route, Species

N,N-DIETHYL m-TOLUAMIDE 9.50 N/A 134-62-3 2000 mg/kg ORAL - RAT 5950 mg/kg INHAL - RAT

ISOPROPYL MYRISTATE 1.5 N/A 110-27-0 NOT AVAILABLE NOT AVAILABLE INHAL - RAT

ISOBUTANE 3 - 7 N/A 75-28-5 NOT AVAILABLE 142500 ppm (4hr) INHAL - MOUSE

PROPANE 1 - 5 1000ppm 74-98-6 NOT AVAILABLE NOT AVAILABLE

SECTION THREE PHYSICAL DATAPHYSICAL STATE AEROSOLAPPEARANCE OFF-WHITE LIQUIDODOR INSECTICIDEODOR THRESHOLD NOT AVAILABLEBOILING POINT (° C)(CONC) 100EVAPORATION RATE LESS THAN 1VAPOUR PRESSURE (PSIG) AEROSOL 55 - 65 @ 20° CVAPOUR DENSITY (AIR=1) GREATER THAN 1AEROSOL % VOC (w/w) 24.25AEROSOL % VOLATILE NOT AVAILABLESOLUBILITY IN WATER SOLUBLEpH 7.3 - 8.3SPECIFIC GRAVITY (LIQUID) 0.98 - 1.02SPECIFIC GRAVITY (AEROSOL) 0.90 - 0.94COEFFICIENT OF WATER/OIL DIST NOT AVAILABLEFREEZING POINT: (° C) NOT AVAILABLESECTION FOURAEROSOL FLAME PROJECTION CLASSIFIED AS 0 Cm

FLASHBACK NOT APPLICABLE

FLAMMABILITY NOT A FLAMMABLE PRODUCT (AS PER CANADIAN AEROSOL REGULATIONS)

IF YES, UNDER WHICH CONDITIONS EXCESSIVE HEAT, SPARKS AND OPEN FLAME

AUTO IGNITION TEMPERATURE (° C) NOT AVAILABLE

EXTINGUISHING MEDIA CARBON DIOXIDE, DRY CHEMICAL, FOAM

UPPER FLAMMABLE LIMIT 9.5 (% BY VOLUME)

LOWER FLAMMABLE LIMIT 0.8 (% BY VOLUME)

EXPLOSION DATA

SENSITIVITY TO STATIC DISCHARGE NOT APPLICABLE

SENSITIVITY TO IMPACT NOT APPLICABLE

HAZARDOUS COMBUSTION

PRODUCTS HYDROCARBON FUMES AND SMOKE, CARBON MONOXIDE WHERE

COMBUSTION IS INCOMPLETE.

FLASH POINT (° C) NOT AVAILABLE

(CONCENTRATE)

SECTION FIVE STABILITY AND REACTIVITYHAZARDOUS PRODUCTS OFDECOMPOSITION HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE

COMBUSTION IS INCOMPLETECHEMICAL STABILITY YES

UNDER NORMAL CONDITIONSCOMPATABILITY WITH OTHERSUBSTANCES - NO, WHICH ONES? STRONG OXIDIZING AGENTSREACTIVITY CONDITIONS? NOT APPLICABLE

INSECTICIDE

FIRE & EXPLOSION HAZARD DATA

MATERIAL SAFETY DATA SHEET 12415 INSECT REPELLENT FOAM 2 of 2

1/29/201510:57 AM ITEM# 12415 DEGIL SAFETY PRODUCTS

SECTION SIX HEALTH DATAROUTE OF ENTRY

INGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING & WEAKNESS

INHALATION INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLENT IS SIMPLE ASPHYXIANT

EYE CONTACT VAPOURS MAY IRRITATE

SKIN CONTACT MAY CAUSE IRRITATION

EFFECTS OF ACUTE EXPOSURE DIZZINESS, NAUSEA, IRRITATION TO SKIN & EYES

EFFECTS OF CHRONIC EXPOSURE SOLVENTS MAY CAUSE DEFATTING DERMATITIS

EXPOSURE LIMIT OF MATERIAL SEE SECTION TWO

CARCINOGENICITY OF MATERIAL THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS

CARCINOGENS BY NTP, (NATIONAL TOXICOLOGY PROGRAM), NOT

REGULATED AS CARCINOGENS BY OSHA, (OCCUPATIONAL SAFETY

AND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED BY

IARC, (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR

BYACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL

INDUSTRIAL HYGIENISTS).

REPRODUCTIVE EFFECTS NO INFORMATION IS AVAILABLE AND NO ADVERSE RESPRODUCTIVE


IRRITANCY OF MATERIAL SLIGHT

TERATOGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENICITY


MUTAGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC


SYNERGISTIC MATERIALS NONE KNOWN

SECTION SEVEN EXPOSURE CONTROLS/PERSONAL PROTECTIONGLOVES CHEMICAL RESISTANT GLOVES

RESPIRATORY IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE

RESPIRATOR (NIOSH/MSHA TC-23C OR EQUIVALENT) IS RECOMMENDED.

EYE SAFETY GLASSES

ENGINEERING CONTROLS VENTILATION - LOCAL (MECHANICAL IF INDOORS ON A CONTINUOUS BASIS)

FOOTWEAR NOT NORMALLY REQUIRED

OTHER NOT REQUIRED

SECTION EIGHTLEAK / SPILL REMOVE ALL SOURCES OF IGNITION, USE AN INERT ABSORBENT MATERIAL AND NON -

SPARKING TOOLS. AVOID BREATHING FUMES, VENTILATE AREA

STORAGE NEEDS KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMS

HANDLING PROCEDURES AND STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C.

EQUIPMENT

SHIPPING INSTRUCTIONS SEE SECTION ONE TDG CLASSIFICATION

WASTE DISPOSAL DO NOT PUNCTURE OR INCINERATE PACKAGES EVEN WHEN EMPTY. DISPOSE OF IN

ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONS

SECTION NINEEMERGENCY FIRST AID PROCEDURE

SECTION TEN ADDITIONAL INFORMATIONThis document has been prepared using data from sources considered technically reliable.

It does not constitute a warranty, express or implied, as to the accuracy of the information

contained herein. Actual conditions of use and handling are beyond seller's control.

User is responsible to evaluate all available information when using product for any

particular use and to comply with all Federal, State, Provincial and local laws and

regulations.

Prepared By: Maureen Kayum 1-800-332-1810 REVIEWED JANUARY 29/2015

INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR. IF

SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION.

HANDLING AND STORAGE

FIRST AID MEASURES IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF

WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. FOR

SKIN, WASH THOROUGHLY WITH SOAP AND WATER. IF AFFECTED BY

M A T E R I A L S A F E T Y D A T A S H E E T

Original Date: 3/28/13 Revision Date: 1/29/15

S e c t i o n 1 - I d e n t i f i c a t i o n

PRODUCT NAME: Croc Bloc SPF30 Spray Lotion Broad Spectrum

FORMULA: 12330-10 Proprietary Cosmetic Mixture Containing Active Ingredients: Octinoxate, Octisalate, Avobenzone,

Octocrylene, and Benzophenone-3

PRODUCT USE DESCRIPTION: Sunscreen MANUFACTURER: Croc Bloc Products Inc. 200 Zenway Blvd. Unit #1 Vaughan, ON, Canada L4H 0L6 Phone 800 332 1810 EMERGENCY (24 HOUR) PHONE: Emergency Chemical Response 800 535 5053

S e c t i o n 2 – H a z a r d ( s ) I d e n t i f i c a t i o n NFPA Hazard Classification Health: 0 Fire: 0 Reactivity: 0 Specific Hazard: None

ACUTE INHALATION: Low volatility makes vapor inhalation unlikely. ACUTE SKIN CONTACT: Product assumed to be practically non-irritating to minimally irritating ACUTE EYE CONTACT: Product assumed to be minimally to slightly irritating INGESTION: Product assumed to be practically non-toxic CHRONIC OVEREXPOSURE: N. Av.

RESPONSE: INHALATION: Not expected route of exposure. If vapors or mist cause irritation or distress, remove subject to fresh air. Give oxygen or

artificial respiration if needed. SKIN CONTACT: Remove contaminated clothing and wash contact area with soap and fresh water. EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. If eye irritation persists, seek medical attention. INGESTION: No harmful affects expected. Drink water or milk to calm stomach.

S e c t i o n 3 – C o m p o s i t i o n / I n f o r m a t i o n o n I n g r e d i e n t s APPEARANCE:

White to Off-White Uniform Spray Lotion

PH: 6.5 to 7.5 SPEC. GRAVITY: 1.020 +/- 0.020 @ 25C FREEZING POINT: N. Av. VAPOR PRESSURE: N. Av. BOILING POINT: 100 C + VAPOR DENSITY: N. Av. WATER SOLUBILITY: Partly Miscible EVAP. RATE: N. Av.

S e c t i o n 4 – F i r s t - A i d M e a s u r e s INHALATION:

Not expected route of exposure. If vapors or mist cause irritation or distress, remove subject to fresh air. Give oxygen or artificial respiration if needed.

SKIN CONTACT: Remove contaminated clothing and wash contact area with soap and fresh water.

EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. If eye irritation persists, seek medical attention.

INGESTION: No harmful affects expected. Drink water or milk to calm stomach.

S e c t i o n 5 – F i r e - F i g h t i n g M e a s u r e s FLASH POINT: >200 F A.I. TEMPERATURE: N. Av. EXTINGUISHING MEDIA: Use water spray, foam, CO2, or dry chemical extinguishing media SPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL HAZARDS: None

S e c t i o n 6 – A c c i d e n t a l R e l e a s e M e a s u r e s GENERAL: Spills should be contained. Absorb with inert material and collect for disposal. Flush area with water. Prevent

washing from entering waterways.

WASTE DISPOSAL: Dispose in accordance with Local, State, and Federal regulations.

CONTAINER DISPOSAL: Dispose in accordance with Local, State, and Federal regulations.

S e c t i o n 7 – H a n d l i n g a n d S t o r a g e GENERAL: Store in a cool dry place. Keep containers tightly closed when not in use. Avoid contact with eyes. Avoid freezing and localized overheating. OTHER PRECAUTIONS: None known

S e c t i o n 8 – E x p o s u r e C o n t r o l s / P e r s o n a l P r o t e c t i o n CLOTHING: Gloves, coveralls, aprons, boots as necessary to minimize contact

EYES: Chemical goggles, full face shield

RESPIRATION: If vapors or mist are generated, wear an approved respirator

VENTILATION: Use adequate exhaust to control vapor/mist

EXPLOSION PROOFING: None required

S e c t i o n 9 – P h y s i c a l a n d C h e m i c a l P r o p e r t i e s Appearance: White to Off-White Uniform Spray Lotion Odor: Matches Standard Odor Threshold: N.Av. Vapor Pressure: N.Av. Vapor Density: N.Av. pH: 6.5 to 7.5 Relative Density: 1.020 +/- 0.020 @25C Melting Point/Freezing Point: N.Av. Solubility(ies): Partly Miscible in water Initial Boiling Point and Boiling Range: 100C+ Flash Point: >200F Evaporation Rate: N.Av. Flammability (solid, gas): N.Av. Upper/Lower Flammability or Explosive Limits: N.Av. Auto-ignition Temp: N.Av. Partition Coefficient:(n-octanol/water) N.Av. Decomposition Temp: N.Av. Viscosity: SP #2 @10rpm: 50 to 2000

S e c t i o n 1 0 – S t a b i l i t y a n d R e a c t i v i t y STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: None INCOMPATIBILITY: None HAZARDOUS DECOMPOSITION PRODUCTS: None

S e c t i o n 1 1 – T o x i c o l o g i c a l I n f o r m a t i o n No data is available on the mixture.

S e c t i o n 1 2 – E c o l o g i c a l I n f o r m a t i o n No data is available on the mixture.

S e c t i o n 1 3 – D i s p o s a l C o n s i d e r a t i o n s WASTE DISPOSAL:

Dispose in accordance with Local, State, and Federal regulations.

CONTAINER DISPOSAL: Dispose in accordance with Local, State, and Federal regulations.

S e c t i o n 1 4 – T r a n s p o r t I n f o r m a t i o n DOT Hazard Class: Non-Regulated DOT Shipping Name: N/A

S e c t i o n 1 5 - R e g u l a t o r y I n f o r m a t i o n We certify that all components of this mixture are listed on the TSCA inventory.

S e c t i o n 1 6 – O t h e r I n f o r m a t i o n The information herein is given in good faith but no warranty is expressed or implied. History: Original. Rev 1: Changed Formula Number Rev 2: Changed Formula Number End of Report


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Chevron Regal® R&O ISO 220 - ISO 680

Product Use: Industrial Oil Product Number(s): CPS273214, CPS273215, CPS273275, CPS277313 Synonyms: Regal® R&O ISO 220, Regal® R&O ISO 320, Regal® R&O ISO 460, Regal® R&O ISO 680 Company Identification Chevron Products Company a division of Chevron U.S.A. Inc. 6001 Bollinger Canyon Rd. San Ramon, CA 94583 United States of America www.chevronlubricants.com Transportation Emergency Response CHEMTREC: (800) 424-9300 or (703) 527-3887 Health Emergency Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800) 231-0623 or (510) 231-0623 Product Information email : [email protected] Product Information: (800) LUBE TEK MSDS Requests: (800) 414-6737

SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT

Highly refined mineral oil (C15 - C50) Mixture 80 - 100 %weight

SECTION 3 HAZARDS IDENTIFICATION

IMMEDIATE HEALTH EFFECTS Eye: Not expected to cause prolonged or significant eye irritation. Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Not expected to be harmful to internal organs if absorbed through the skin. Ingestion: Not expected to be harmful if swallowed. Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritation may include coughing and difficulty breathing.

Order Chevron Lubricants: www.alexisoil.com/chevron-lubricants

Alexis Oil Company | 1-888-717-4355 | [email protected]

vvesperr

Alexis Logo

SECTION 4 FIRST AID MEASURES

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with water. Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse. Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get medical advice. Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs.

SECTION 5 FIRE FIGHTING MEASURES

FIRE CLASSIFICATION: OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible. NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0 FLAMMABLE PROPERTIES: Flashpoint: (Cleveland Open Cup) 235 °C (455 °F) (Min) Autoignition: No Data Available Flammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: Not Applicable EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: This material will burn although it is not easily ignited. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in vicinity of spilled material. Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802 as appropriate or required.

SECTION 7 HANDLING AND STORAGE

General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but



may not, by themselves, be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'. Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS: Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. ENGINEERING CONTROLS: Use in a well-ventilated area. PERSONAL PROTECTIVE EQUIPMENT Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice. Skin Protection: No special protective clothing is normally required. Where splashing is possible, select protective clothing depending on operations conducted, physical requirements and other substances in the workplace. Suggested materials for protective gloves include: Nitrile Rubber, Silver Shield, Viton, 4H (PE/EVAL). Respiratory Protection: No respiratory protection is normally required. If user operations generate an oil mist, determine if airborne concentrations are below the occupational exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge. Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide adequate protection. Occupational Exposure Limits: Component Agency TWA STEL Ceiling Notation Highly refined mineral oil (C15 - C50)

ACGIH 5 mg/m3 10 mg/m3 -- --

Highly refined mineral oil (C15 - C50)

OSHA Z-1 5 mg/m3 -- -- --

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification. Color: Brown



Physical State: Liquid Odor: Petroleum odor pH: Not Applicable Vapor Pressure: <0.01 mmHg @ 37.8 °C (100 °F) Vapor Density (Air = 1): >1 Boiling Point: >315°C (599°F) Solubility: Soluble in hydrocarbons; insoluble in water Freezing Point: Not Applicable - Viscosity: 210 cSt @ 40°C (104°F) (Min) Evaporation Rate: No Data Available

SECTION 10 STABILITY AND REACTIVITY

Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Incompatibility With Other Materials: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. Hazardous Decomposition Products: None known (None expected) Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

IMMEDIATE HEALTH EFFECTS Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product components. Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product components. Skin Sensitization: No product toxicology data available. Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar materials or product components. Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials or product components. Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials or product components. ADDITIONAL TOXICOLOGY INFORMATION: This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). These oils have not been classified by the American Conference of Governmental Industrial Hygienists (ACGIH) as: confirmed human carcinogen (A1), suspected human carcinogen (A2), or confirmed animal carcinogen with unknown relevance to humans (A3).

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY The toxicity of this material to aquatic organisms has not been evaluated. Consequently, this material should be kept out of sewage and drainage systems and all bodies of water.



ENVIRONMENTAL FATE This material is not expected to be readily biodegradable.

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. Oil collection services are available for used oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent with applicable regulations. Contact your sales representative or local environmental or health authorities for approved disposal or recycling methods.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific shipping requirements.

DOT Shipping Description: PETROLEUM LUBRICATING OIL, NOT REGULATED AS A HAZARDOUS MATERIAL FOR TRANSPORTATION UNDER 49 CFR Additional Information:NOT HAZARDOUS BY U.S. DOT. ADR/RID HAZARD CLASS NOT APPLICABLE.

IMO/IMDG Shipping Description: PETROLEUM LUBRICATING OIL; NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT UNDER THE IMDG CODE

ICAO/IATA Shipping Description: PETROLEUM LUBRICATING OIL; NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT UNDER ICAO TI OR IATA DGR

SECTION 15 REGULATORY INFORMATION EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: NO 2. Delayed (Chronic) Health Effects: NO 3. Fire Hazard: NO 4. Sudden Release of Pressure Hazard: NO 5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED: 01-1=IARC Group 1 03=EPCRA 313 01-2A=IARC Group 2A 04=CA Proposition 65 01-2B=IARC Group 2B 05=MA RTK 02=NTP Carcinogen 06=NJ RTK 07=PA RTK

No components of this material were found on the regulatory lists above.

CHEMICAL INVENTORIES: All components comply with the following chemical inventory requirements: AICS (Australia), DSL (Canada), EINECS (European Union), ENCS (Japan), IECSC (China), KECI (Korea), PICCS (Philippines), TSCA (United States).



NEW JERSEY RTK CLASSIFICATION: Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to be identified as follows: PETROLEUM OIL (Lubricating oil)

WHMIS CLASSIFICATION: This product is not considered a controlled product according to the criteria of the Canadian Controlled Products Regulations.

SECTION 16 OTHER INFORMATION

NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0

HMIS RATINGS: Health: 1 Flammability: 1 Reactivity: 0 (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings). LABEL RECOMMENDATION: Label Category : INDUSTRIAL OIL 1 - IND1

REVISION STATEMENT: This is a new Material Safety Data Sheet. Revision Date: February 21, 2008

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT: TLV - Threshold Limit Value TWA - Time Weighted Average STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit CAS - Chemical Abstract Service Number

ACGIH - American Conference of Government Industrial Hygienists

IMO/IMDG - International Maritime Dangerous Goods Code

API - American Petroleum Institute MSDS - Material Safety Data Sheet CVX - Chevron NFPA - National Fire Protection Association (USA) DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA) IARC - International Agency for Research on Cancer

OSHA - Occupational Safety and Health Administration

Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS Standard (Z400.1) by the Chevron Energy Technology Company, 100 Chevron Way, Richmond, California 94802.

The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose.




1. Product and Company IdentificationMaterial name KeroseneRevision date 10-25-2011Version # 01Product code 106Product use Heating and illuminating oil.Synonym(s) VARSOL 3139 SOLVENT

(613) 996-6666 - Canutec(306) 244-3447

Federated Co-operative Limited(416) 968-4415Toronto, ON M5W 1K3111 ST. Clair Avenue WestImperial Oil; Chemical Division


Telephone

AddressSupplierTelephone

AddressManufacturer

P.O. Box 1050, 401 - 22nd StreetEast Saskatoon SK S7K 3M9 Canada

2. Hazards IdentificationPhysical state Liquid.Appearance Clear liquid.Emergency overview WARNING! Combustible liquid and vapor. Harmful if swallowed - may enter lungs if swallowed or

vomited. May cause skin irritation. May cause central nervous system effects. May cause damageto the kidneys.

OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.Potential health effects

Routes of exposure Inhalation. Skin contact. Ingestion.Eyes Direct contact with eyes may cause temporary irritation.Skin Prolonged or repeated contact may dry skin and cause irritation.Inhalation Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, and

respiratory tract irritation.Ingestion Swallowing or vomiting of the liquid may result in aspiration into the lungs.

Chronic effects Exposure over a long period of time may cause central nervous system effects. Symptoms maybe delayed.

Signs and symptoms Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, andrespiratory tract irritation. Prolonged or repeated contact may dry skin and cause irritation.Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Potential environmental effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.



8052-41-3 60-100Stoddard solvent

64742-47-8 30-60Distillates, (petroleum), Hydrotreated Light

95-63-6 1-51,2,4-Trimethylbenze ne

100-41-4 0.1-1Ethylbenzene

91-20-3 0.1-1Naphthalene

1330-20-7 0.1-1Xylene

Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume.

CPH MSDS NA

1 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-2011

07-12-2012

Contact supplier for current manufacturer.

07-12-201207-12-2012


Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.

Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.Inhalation If symptomatic, move to fresh air. Get medical attention if symptoms persist.Ingestion Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fully

conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Ifvomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything bymouth to an unconscious person.


5. Fire Fighting MeasuresFlammable properties Combustible liquid and vapor. Material will float and may ignite on surface of water. Containers

may explode when heated.Extinguishing media


Carbon dioxide (CO2). Foam. Dry chemical. Water fog.


None known.


Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Specific methods Cool containers exposed to heat with water spray and remove container, if no risk is involved.Hazardous combustionproducts

Carbon oxides.

6. Accidental Release MeasuresPersonal precautions Ensure adequate ventilation. Wear suitable protective clothing. See Section 8 of the MSDS for

Personal Protective Equipment.Environmental precautions Collect and dispose of spillage as indicated in Section 13 of the MSDS.Methods for containment Eliminate all ignition sources. Dike the spilled material, where this is possible. Prevent entry into

waterways, sewer, basements or confined areas.Methods for cleaning up Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Use a non-combustible

material like vermiculite, sand or earth to soak up the product and place into a container for laterdisposal.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece).

Never return spills to original containers for re-use. Following product recovery, flush area withwater. Clean surface thoroughly to remove residual contamination.

Other information Absorb spill with vermiculite or other inert material, then place in a container for chemical waste.

7. Handling and StorageHandling Use only with adequate ventilation. Wash thoroughly after handling. Observe good industrial

hygiene practices.Storage Keep container tightly closed and in a well-ventilated place. Store in closed original container at

room temperature. Store away from incompatible materials.


US. ACGIH Threshold Limit ValuesValueTypeComponents

1,2,4-Trim ethyl benze ne (95-63-6)

TWA 25 ppm

Ethylbenze ne (100-41-4) TWA 20 ppmNaphthalen e (91-20-3) STEL 15 ppm

TWA 10 ppmStoddard solvent (8052-41-3)

TWA 100 ppm

CPH MSDS NA

2 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-2012 07-12-2012

US. ACGIH Threshold Limit ValuesValueTypeComponents

Xylene (1330-20-7) STEL 150 ppmTWA 100 ppm

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)ValueTypeComponents

Ethylbenze ne (100-41-4) PEL 435 mg/m3100 ppm

Naphthalen e (91-20-3) PEL 50 mg/m310 ppm

Stoddard solvent (8052-41-3)

PEL 2900 mg/m3

500 ppmXylene (1330-20-7) PEL 435 mg/m3

100 ppmCanada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

FormValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)

TWA 123 mg/m3

25 ppmDistillate s, (petroleum ),Hydrotreat ed Light (64742-47-8)

TWA 200 mg/m3 Vapor.

Ethylbenze ne (100-41-4) STEL 543 mg/m3125 ppm

TWA 434 mg/m3100 ppm

Naphthalen e (91-20-3) STEL 79 mg/m315 ppm

TWA 52 mg/m310 ppm


TWA 572 mg/m3

100 ppmCanada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health andSafety Regulation 296/97, as amended)

FormValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)

TWA 25 ppm

Distillate s, (petroleum ),Hydrotreat ed Light (64742-47-8)

TWA 200 mg/m3 Non-aerosol.

Ethylbenze ne (100-41-4) STEL 125 ppmTWA 100 ppm

Naphthalen e (91-20-3) STEL 15 ppmTWA 10 ppm


STEL 580 mg/m3

TWA 290 mg/m3Xylene (1330-20-7) STEL 150 ppm

TWA 100 ppmCanada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents)

ValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)

TWA 123 mg/m3

25 ppmEthylbenze ne (100-41-4) STEL 540 mg/m3

125 ppmTWA 435 mg/m3

100 ppm

CPH MSDS NA


Canada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents)ValueTypeComponents

Naphthalen e (91-20-3) STEL 78 mg/m315 ppm

TWA 52 mg/m310 ppm


TWA 525 mg/m3

Xylene (1330-20-7) STEL 650 mg/m3150 ppm

TWA 435 mg/m3100 ppm

Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)ValueTypeComponents

1,2,4-Trim ethyl benze ne (95-63-6)

TWA 123 mg/m3



100 ppmNaphthalen e (91-20-3) STEL 79 mg/m3

15 ppmTWA 52 mg/m3

10 ppmStoddard solvent (8052-41-3)

TWA 525 mg/m3

100 ppmXylene (1330-20-7) STEL 651 mg/m3


100 ppmMexico. Occupational Exposure Limit Values

ValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)

STEL 170 mg/m3

35 ppmTWA 125 mg/m3



100 ppmNaphthalen e (91-20-3) STEL 75 mg/m3

15 ppmTWA 50 mg/m3

10 ppmStoddard solvent (8052-41-3)

STEL 1050 mg/m3


100 ppmXylene (1330-20-7) STEL 655 mg/m3


100 ppmEngineering controls Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of

inhalation of vapors.Personal protective equipment

Eye / face protection Use approved safety goggles or face shield.Skin protection Wear appropriate chemical resistant clothing to prevent any possibility of skin contact.Respiratory protection In case of inadequate ventilation, use respiratory protection.

CPH MSDS NA



Always observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants.

9. Physical & Chemical PropertiesAppearance Clear liquid.

Color Clear, colorless.

Odor Mild. Petroleum.



Form Liquid.

pH Not applicable.

Melting point < -65.2 °F (< -54 °C)

Freezing point < -65.2 °F (< -54 °C)

Boiling point 327.2 - 397.4 °F (164 - 203 °C)

Flash point 116.6 °F (47 °C) Closed Cup

Evaporation rate 0.01 (Butyl acetate = 1)

Flammability limits in air, upper,% by volume

6 %

Flammability limits in air, lower,% by volume

1.1 %

Vapor pressure 0.03 kPa

Vapor density 5

Specific gravity 0.8 (15.5°C)

Solubility (water) Very slightly soluble in the following materials: cold water and hot water.


Not available.


Decomposition temperature Not available.

VOC 0.81 % w/w

Percent volatile 100 % w/w

10. Chemical Stability & Reactivity InformationChemical stability Material is stable under normal conditions.Conditions to avoid Heat, sparks, flames. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts

No hazardous decomposition products are known.


Will not occur.

Toxicological data


Product Test Results

Acute Dermal LD50 Rabbit: 471.476 g/kg estimatedKerosene

Acute Dermal LD50 Rat: 4714.7574 g/kg estimatedAcute Inhalation LC50 Rat: 86434.1588 ppm estimatedAcute Inhalation LC50 Rat: 86434.1588 mg/l estimatedAcute Other LD50 Mouse: 22579.9501 mg/kg estimated

Components Test Results

Acute Dermal LD50 Rabbit: > 5000 mg/kgEthylbenzene (100-41-4)

Acute Oral LD50 Rat: 5.46 g/kg

CPH MSDS NA

5 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-201207-12-2012

Components Test Results

Acute Oral LD50 Rat: 4300 mg/kgXylene (1330-20-7)

Acute Dermal LD50 Rabbit: > 2 g/kgNaphthalene (91-20-3)

Acute Oral LD50 Rat: 490 mg/kgAcute Dermal LD50 Rabbit: > 3160 mg/kg1,2,4-Trimethylbenzene (95-63-6)

Acute Inhalation LC50 Rat: 18000 mg/m3 4 hoursAcute effects Harmful if swallowed - may enter lungs if swallowed or vomited. Prolonged or repeated contact

may dry skin and cause irritation. Overexposure to mists/vapours of this product may causeheadache, dizziness, nausea, and respiratory tract irritation.

Local effectsUS ACGIH Threshold Limit Values: Skin designation

Naphthalene (CAS 91-20-3) Can be absorbed through the skin.Sensitization None known.Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

ACGIH CarcinogensEthylbenzene (CAS 100-41-4) A3 Confirmed animal carcinogen with unknown relevance to

humans.Naphthalene (CAS 91-20-3) A4 Not classifiable as a human carcinogen.Xylene (CAS 1330-20-7) A4 Not classifiable as a human carcinogen.

IARC Monographs. Overall Evaluation of CarcinogenicityEthylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans.Naphthalene (CAS 91-20-3) 2B Possibly carcinogenic to humans.Stoddard solvent (CAS 8052-41-3) 3 Not classifiable as to carcinogenicity to humans.Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.

US NTP Report on Carcinogens: Anticipated carcinogenNaphthalene (CAS 91-20-3) Anticipated carcinogen.

Ecotoxicological data


Product Test Results

EC50 Daphnia: 267.4925 mg/l 48 hours estimatedKeroseneComponents Test Results

EC50 Water flea (Daphnia magna): 1 - 4 mg/l 48 hoursEthylbenzene (100-41-4)LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss): 4mg/l 96 hoursLC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss): 8mg/l 96 Hours

Xylene (1330-20-7)

EC50 Water flea (Daphnia magna): 1.09 - 3.4 mg/l 48 hoursNaphthalene (91-20-3)LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss):0.91 - 2.82 mg/l 96 hoursLC50 Fathead minnow (Pimephales promelas): 7.19 - 8.28 mg/l96 hours

1,2,4-Trimethylbenzene (95-63-6)

Ecotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Persistence anddegradability

No data available.


No data available.


Not available.

Mobility in environmentalmedia

No data available.

CPH MSDS NA


13. Disposal ConsiderationsWaste codes D001: Waste Flammable material with a flash point <140 °FDisposal instructions Must be incinerated in a suitable incineration plant holding a permit delivered by the competent

authorities. Do not allow this material to drain into sewers/water supplies. Do not contaminateponds, waterways or ditches with chemical or used container. When this product as supplied is tobe discarded as waste, it may meet the definition of a RCRA waste under 40 CFR 261.





Basic shipping requirements:UN1268UN numberPetroleum distillates, n.o.s.Proper shipping nameCombustible LiquidHazard classIIIPacking group3Labels required

Additional information:144, T11, TP1, TP8Special provisions150Packaging exceptions201Packaging non bulk243Packaging bulk128ERG number

IATABasic shipping requirements:

1268UN numberPetroleum distillates, n.o.s. (Stoddard solvent)Proper shipping name3Hazard classIIIPacking group

Additional information:3HERG code

IMDGBasic shipping requirements:

1268UN numberPETROLEUM DISTILLATES, N.O.S. (Stoddard solvent)Proper shipping name3Hazard classIIIPacking groupF-E, S-EEmS No.

TDGBasic shipping requirements:

PETROLEUM DISTILLATES, N.O.S. (Stoddard solvent)Proper shipping name3Hazard classUN1268UN numberIIIPacking group·Marine pollutant


All components are on the U.S. EPA TSCA Inventory List.TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D)

Not regulated.US CAA Section 112 Hazardous Air Pollutants (HAPs) List

ETHYLBENZENE (CAS 100-41-4)M-XYLENES (CAS 1330-20-7)NAPHTHALENE (CAS 91-20-3)

CPH MSDS NA


US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration1,2,4-Trimethylbenzene (CAS 95-63-6) 1.0 %Ethylbenzene (CAS 100-41-4) 0.1 %Naphthalene (CAS 91-20-3) 0.1 %Xylene (CAS 1330-20-7) 1.0 %

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Xylene (CAS 1330-20-7) Listed.

CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)Ethylbenze ne: 1000Naph thalene: 100Xylen e: 100

Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes

Delayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No

Section 302 extremelyhazardous substance (40CRF 355, Appendix A)

No

Section 311/312 (40 CFR370)

No


Not controlled

Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDScontains all the information required by the CPR.

WHMIS status ControlledWHMIS classification B3 - Flammable/Combustible

D2A - Other Toxic Effects-VERY TOXICD2B - Other Toxic Effects-TOXIC

WHMIS labeling


YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical

Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)

YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances

(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

State regulations WARNING: This product contains chemicals known to the State of California to cause cancer.

CPH MSDS NA


US - California Hazardous Substances (Director's): Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.Xylene (CAS 1330-20-7) Listed.

US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceEthylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substanceEthylbenzene (CAS 100-41-4) Listed: June 11, 2004 Carcinogenic.Naphthalene (CAS 91-20-3) Listed: April 19, 2002 Carcinogenic.

US - Massachusetts RTK - Substance: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Distillates, (petroleum), Hydrotreated Light (CAS64742-47-8)

Listed.

Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.

US - New Jersey Community RTK (EHS Survey): Reportable threshold1,2,4-Trimethylbenzene (CAS 95-63-6) 500 LBSDistillates, (petroleum), Hydrotreated Light (CAS64742-47-8)

10000 LBS

Ethylbenzene (CAS 100-41-4) 500 LBSNaphthalene (CAS 91-20-3) 500 LBSXylene (CAS 1330-20-7) 500 LBS

US - New Jersey RTK - Substances: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.Xylene (CAS 1330-20-7) Listed.

US - Pennsylvania RTK - Hazardous Substances: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Distillates, (petroleum), Hydrotreated Light (CAS64742-47-8)

Listed.

Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.Xylene (CAS 1330-20-7) Listed.

16. Other InformationHMIS® ratings Health: 2

Flammability: 2Physical hazard: 0




CPH MSDS NA


07-12-2012


1. Product and Company IdentificationMaterial name SOLVENTRevision date 09-16-2011Version # 01CAS # 8052-41-3Product code 2183Product use Solvent. Fuel. Diluter Feedstock.Synonym(s) VARSOL 3139 SOLVENT

(613) 996-6666 - Canutec(306) 244-3447

Federated Co-operative Limited-Richmond, BC V6X 1W5 Canada9800 Van Home WayUnivar Canada Ltd.


Telephone


AddressManufacturer

P.O. Box 1050, 401 - 22nd StreetEast Saskatoon SK S7K 3M9 Canada

2. Hazards IdentificationPhysical state Liquid.Appearance Clear liquid.Emergency overview WARNING! Combustible liquid and vapor. Harmful if swallowed - may enter lungs if swallowed or

vomited. May cause skin irritation. May cause central nervous system effects. May cause damageto the kidneys.

OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.Potential health effects

Routes of exposure Inhalation. Skin contact. Ingestion.Eyes Direct contact with eyes may cause temporary irritation.Skin Prolonged or repeated contact may dry skin and cause irritation.Inhalation Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, and

respiratory tract irritation.Ingestion Swallowing or vomiting of the liquid may result in aspiration into the lungs.

Chronic effects Exposure over a long period of time may cause central nervous system effects. Symptoms maybe delayed.

Signs and symptoms Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, andrespiratory tract irritation. Prolonged or repeated contact may dry skin and cause irritation.Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Potential environmental effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.



8052-41-3 60-100Stoddart solvent



Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.

CPH MSDS NA

1 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-2011

Contact supplier for current manufacturer.

07-12-2012

07-12-2012 07-12-2012

Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.Inhalation If symptomatic, move to fresh air. Get medical attention if symptoms persist.Ingestion Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fully

conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Ifvomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything bymouth to an unconscious person.


5. Fire Fighting MeasuresFlammable properties Combustible liquid and vapor. Material will float and may ignite on surface of water. Containers

may explode when heated.Extinguishing media


Carbon dioxide (CO2). Foam. Dry chemical. Water fog.


None known.


Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Specific methods Cool containers exposed to heat with water spray and remove container, if no risk is involved.Hazardous combustionproducts

Carbon oxides.

6. Accidental Release MeasuresPersonal precautions Ensure adequate ventilation. Wear suitable protective clothing. See Section 8 of the MSDS for

Personal Protective Equipment.Environmental precautions Collect and dispose of spillage as indicated in Section 13 of the MSDS.Methods for containment Eliminate all ignition sources. Dike the spilled material, where this is possible. Prevent entry into

waterways, sewer, basements or confined areas.Methods for cleaning up Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Use a non-combustible

material like vermiculite, sand or earth to soak up the product and place into a container for laterdisposal.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece).

Never return spills to original containers for re-use. Following product recovery, flush area withwater. Clean surface thoroughly to remove residual contamination.

Other information Absorb spill with vermiculite or other inert material, then place in a container for chemical waste.

7. Handling and StorageHandling Use only with adequate ventilation. Wash thoroughly after handling. Observe good industrial

hygiene practices.Storage Keep container tightly closed and in a well-ventilated place. Store in closed original container at

room temperature. Store away from incompatible materials.


US. ACGIH Threshold Limit ValuesValueTypeMaterial

Stoddart solvent (8052-41-3)

TWA 100 ppm

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)ValueTypeMaterial


PEL 2900 mg/m3

500 ppmCanada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

ValueTypeMaterialStoddart solvent (8052-41-3)

TWA 100 ppm

CPH MSDS NA

2 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-201107-12-2012 07-12-2012

Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)ValueTypeMaterial572 mg/m3

Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health andSafety Regulation 296/97, as amended)


TWA 290 mg/m3

STEL 580 mg/m3Canada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents)


TWA 525 mg/m3

Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)ValueTypeMaterial


TWA 100 ppm

525 mg/m3Mexico. Occupational Exposure Limit Values


TWA 100 ppm

STEL 1050 mg/m3200 ppm

TWA 523 mg/m3Engineering controls Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of

inhalation of vapors.Personal protective equipment

Eye / face protection Use approved safety goggles or face shield.Skin protection Wear appropriate chemical resistant clothing to prevent any possibility of skin contact.Respiratory protection In case of inadequate ventilation, use respiratory protection.General hygieneconsiderations

Always observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants.

9. Physical & Chemical PropertiesAppearance Clear liquid.

Color Clear, colorless.

Odor Mild. Petroleum.



Form Liquid.

pH Not applicable.

Melting point -72.4 °F (-58 °C)

Freezing point Not available.

Boiling point 316.4 - 383 °F (158 - 195 °C)

Flash point 109.4 °F (43 °C) Closed Cup

Evaporation rate 0.1 (Butyl acetate = 1)


13.3 %


1 %

Vapor pressure 0.04 kPa

Vapor density 5

Specific gravity 0.79 (15.5°C)

CPH MSDS NA

3 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-201107-12-201207-12-2012

Solubility (water) Not available.


Not available.



VOC 100 %

10. Chemical Stability & Reactivity InformationChemical stability Material is stable under normal conditions.Conditions to avoid Heat, sparks, flames. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts

No hazardous decomposition products are known.


Will not occur.

11. Toxicological InformationAcute effects Harmful if swallowed - may enter lungs if swallowed or vomited. Prolonged or repeated contact

may dry skin and cause irritation. Overexposure to mists/vapours of this product may causeheadache, dizziness, nausea, and respiratory tract irritation.

Sensitization None known.Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

IARC Monographs. Overall Evaluation of CarcinogenicityStoddart solvent (CAS 8052-41-3) 3 Not classifiable as to carcinogenicity to humans.

12. Ecological InformationEcotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Persistence anddegradability

No data available.


No data available.


Not available.


No data available.

13. Disposal ConsiderationsWaste codes D001: Waste Flammable material with a flash point <140 °FDisposal instructions Must be incinerated in a suitable incineration plant holding a permit delivered by the competent

authorities. Do not allow this material to drain into sewers/water supplies. Do not contaminateponds, waterways or ditches with chemical or used container. When this product as supplied is tobe discarded as waste, it may meet the definition of a RCRA waste under 40 CFR 261.




14. Transport InformationProduct Specific Note: This product meets the limited quantities exception as follows:

IMDG: Limited quantities up to 5 liters.Otherwise, the above descriptions apply.

DOTBasic shipping requirements:

UN1268UN numberPetroleum distillates, n.o.s. or Petroleum products, n.o.s. (Solvant Stoddard)Proper shipping name3Hazard classIIIPacking group

CPH MSDS NA


3Labels requiredAdditional information:

144, B1, IB3, T4, TP1, TP29Special provisions150Packaging exceptions203Packaging non bulk242Packaging bulk128ERG number

IATABasic shipping requirements:

UN1268UN numberPetroleum distillates, n.o.s. or Petroleum products, n.o.s. (Solvant Stoddard)Proper shipping name3Hazard classIIIPacking group3Labels required

Additional information:150Packaging exceptions203Packaging non bulk242Packaging bulk

IMDGBasic shipping requirements:

1268UN numberPETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (Solvant Stoddard)Proper shipping name3Hazard classIIIPacking groupF-E, S-EEmS No.

TDGBasic shipping requirements:

Petroleum distillates, n.o.s. or Petroleum products, n.o.s. (Solvant Stoddard)Proper shipping name3Hazard classUN1268UN numberIIIPacking group

Additional information:144, B1, IB3, T4, TP1, TP29Special provisions

Basic shipping requirements:3Labels required

Additional information:150Packaging exceptions203Packaging non bulk242Packaging bulk


All components are on the U.S. EPA TSCA Inventory List.TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D)

Not regulated.CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)

NoneSuperfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No


No

Section 311/312 (40 CFR370)

No

CPH MSDS NA



Not controlled


WHMIS status ControlledWHMIS classification B3 - Flammable/Combustible

D2B - Other Toxic Effects-TOXICWHMIS labeling


YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical

Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)

YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances

(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory



US - California Hazardous Substances (Director's): Listed substanceStoddart solvent (CAS 8052-41-3) Listed.

US - Massachusetts RTK - Substance: Listed substanceStoddart solvent (CAS 8052-41-3) Listed.

US - New Jersey RTK - Substances: Listed substanceStoddart solvent (CAS 8052-41-3) Listed.

US - Pennsylvania RTK - Hazardous Substances: Listed substanceStoddart solvent (CAS 8052-41-3) Listed.

16. Other InformationHMIS® ratings Health: 2

Flammability: 2Physical hazard: 0




CPH MSDS NA


07-12-2012



Material name GASOLINE - ETHANOL BLENDED

Version # 01


Revision date -

Supersedes date -

CAS # Mixture

Product code 2738

Product use Motor fuels.

Synonym(s) Unleaded Gasoline * Gasoline * Regular Gasoline * Premium Gasoline * Premium UnleadedGasoline * Mid Grade Gasoline * Gasoline (Export) * Petroleum Naphtha * Alkylate





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec



Appearance Amber liquid.

Emergency overview DANGER!Extremely flammable liquid and vapor - vapor may cause flash fire or explosion. Staticaccumulating flammable liquid can become electrostatically charged even in bonded andgrounded equipment.

Harmful if inhaled, absorbed through skin, or swallowed. Aspiration may cause lung damage.Irritating to eyes, respiratory system and skin. In high concentrations, vapors and spray mists arenarcotic and may cause headache, fatigue, dizziness and nausea. Cancer hazard. May causeheritable genetic damage. Toxic to aquatic organisms. May cause long-term adverse effects in theaquatic environment.

OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).


Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact.

Eyes Contact may irritate or burn eyes. Eye contact may result in corneal injury.

Skin Harmful if absorbed through skin. Irritating to skin. Frequent or prolonged contact may defat anddry the skin, leading to discomfort and dermatitis.

Inhalation Harmful if inhaled. Irritating to respiratory system. In high concentrations, vapors and spray mistsare narcotic and may cause headache, fatigue, dizziness and nausea. May cause breathingdisorders and lung damage. May cause cancer by inhalation. Prolonged inhalation may beharmful.

Ingestion Harmful if swallowed. Ingestion may result in vomiting; aspiration (breathing) of vomitus into lungsmust be avoided as even small quantities may result in aspiration pneumonitis. Irritating to mouth,throat, and stomach.

Target organs Blood. Eyes. Liver. Respiratory system. Skin. Kidneys. Central nervous system.

CPH MSDS NA

1 / 9

GASOLINE - ETHANOL BLENDED CPH MSDS NA


Chronic effects Cancer hazard. Contains material which may have reproductive toxicity, teratogenetic ormutagenic effects. Liver injury may occur. Kidney injury may occur. May cause central nervoussystem disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mentalconfusion and blurred vision) and/or damage. Frequent or prolonged contact may defat and drythe skin, leading to discomfort and dermatitis.

Signs and symptoms Irritation of nose and throat. Irritation of eyes and mucous membranes. Skin irritation.Unconsciousness. Corneal damage. Narcosis. Cyanosis (blue tissue condition, nails, lips, and/orskin). Decrease in motor functions. Behavioral changes. Edema. Liver enlargement. Jaundice.Conjunctivitis. Proteinuria. Defatting of the skin. Rash.

Potential environmental effects Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.



86290-81-5 60-100Gasoline

64-17-5 5-10Ethanol

71-43-2 1-5Benzene




Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention.

Skin contact Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water.Get medical attention if irritation develops or persists. Wash clothing separately before reuse.Destroy or thoroughly clean contaminated shoes.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.Get medical attention if discomfort develops or persists.

Ingestion Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. Ifvomiting occurs, keep head low so that stomach content does not get into the lungs. Get medicalattention immediately.

Notes to physician In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation.Symptoms may be delayed.

General advice If exposed or concerned: get medical attention/advice. Ensure that medical personnel are awareof the material(s) involved, and take precautions to protect themselves. Show this safety datasheet to the doctor in attendance. Wash contaminated clothing before re-use.


Flammable properties Extremely flammable liquid and vapor - vapor may cause flash fire.

Extinguishing media


mediaWater. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).


mediaDo not use a solid water stream as it may scatter and spread fire.



from the chemicalVapor may cause flash fire. Vapors can flow along surfaces to distant ignition source and flashback. Sensitive to static discharge.

Protective equipment and

precautions for firefightersWear full protective clothing, including helmet, self-contained positive pressure or pressuredemand breathing apparatus, protective clothing and face mask.

Fire fighting

equipment/instructionsWear full protective clothing, including helmet, self-contained positive pressure or pressuredemand breathing apparatus, protective clothing and face mask. Withdraw immediately in case ofrising sound from venting safety devices or any discoloration of tanks due to fire. Fight fire frommaximum distance or use unmanned hose holders or monitor nozzles. Move containers from firearea if you can do it without risk. In the event of fire, cool tanks with water spray. Cool containersexposed to flames with water until well after the fire is out. For massive fire, use unmanned hoseholders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Vapors mayform explosive air mixtures even at room temperature. Prevent buildup of vapors or gases toexplosive concentrations. Some of these materials, if spilled, may evaporate leaving a flammableresidue. Water runoff can cause environmental damage.

CPH MSDS NA

2 / 9



Specific methods In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopenedcontainers.


productsCarbon monoxide. Carbon Dioxide. Sulfur oxides. Nitrogen oxides (NOx). Hydrocarbons.


Personal precautions Keep unnecessary personnel away. Local authorities should be advised if significant spillagescannot be contained. Keep upwind. Keep out of low areas. Ventilate closed spaces beforeentering. Do not touch damaged containers or spilled material unless wearing appropriateprotective clothing. See Section 8 of the MSDS for Personal Protective Equipment.

Environmental precautions If facility or operation has an "oil or hazardous substance contingency plan", activate itsprocedures. Stay upwind and away from spill. Wear appropriate protective equipment includingrespiratory protection as conditions warrant. Do not enter or stay in area unless monitoringindicates that it is safe to do so. Isolate hazard area and restrict entry to emergency crew.Flammable. Review Firefighting Measures, Section 5, before proceeding with clean up. Keep allsources of ignition (flames , smoking, flares, etc.) and hot surfaces away from release. Containspill in smallest possible area. Recover as much product as possible (e.g. by vacuuming). Stopleak if it can be done without risk. Use water spray to disperse vapors. Spilled material may beabsorbed by an appropriate absorbent, and then handled in accordance with environmentalregulations. Prevent spilled material from entering sewers, storm drains, other unauthorizedtreatment or drainage systems and natural waterways. Contact fire authorities and appropriatefederal, state and local agencies. If spill of any amount is made into or upon navigable waters, thecontiguous zone, or adjoining shorelines, contact the National Response Center at1-800-424-8802. For highway or railways spills, contact Chemtrec at 1-800-424-9300.

Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leakif you can do so without risk. This material is a water pollutant and should be prevented fromcontaminating soil or from entering sewage and drainage systems and bodies of water. Dike thespilled material, where this is possible. Prevent entry into waterways, sewers, basements orconfined areas.

Methods for cleaning up Small Spills: Absorb spill with vermiculite or other inert material, then place in a container forchemical waste. Clean surface thoroughly to remove residual contamination. This material and itscontainer must be disposed of as hazardous waste.

Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the productand place into a container for later disposal. Prevent product from entering drains. Do not allowmaterial to contaminate ground water system. Should not be released into the environment.



Handling Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Avoidcontact with eyes, skin, and clothing. Do not taste or swallow. Avoid prolonged exposure. Useonly with adequate ventilation. Wash thoroughly after handling. The product is flammable, andheating may generate vapors which may form explosive vapor/air mixtures. DO NOT handle, storeor open near an open flame, sources of heat or sources of ignition. Protect material from directsunlight. Take precautionary measures against static discharges. All equipment used whenhandling the product must be grounded. Use non-sparking tools and explosion-proof equipment.When using, do not eat, drink or smoke. Avoid release to the environment.

Storage Flammable liquid storage. Do not handle or store near an open flame, heat or other sources ofignition. This material can accumulate static charge which may cause spark and become anignition source. The pressure in sealed containers can increase under the influence of heat. Keepcontainer tightly closed in a cool, well-ventilated place. Keep away from food, drink and animalfeedingstuffs. Keep out of the reach of children.




ValueTypeComponents

STELBenzene (CAS 71-43-2) 2.5 ppm

TWA 0.5 ppm

STELEthanol (CAS 64-17-5) 1000 ppm

STELGasoline (CAS 86290-81-5) 500 ppm

TWA 300 ppm

CPH MSDS NA

3 / 9



US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

ValueTypeComponents

STELBenzene (CAS 71-43-2) 5 ppm

TWA 1 ppm


ValueTypeComponents

PELEthanol (CAS 64-17-5) 1900 mg/m3

1000 ppm

US. OSHA Table Z-2 (29 CFR 1910.1000)

ValueTypeComponents

CeilingBenzene (CAS 71-43-2) 25 ppm


ValueTypeComponents

STELBenzene (CAS 71-43-2) 8 mg/m3

2.5 ppm

TWA 1.6 mg/m3

0.5 ppm

TWAEthanol (CAS 64-17-5) 1880 mg/m3

1000 ppm


TWA 300 ppm

Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and

Safety Regulation 296/97, as amended)

ValueTypeComponents


TWA 0.5 ppm



TWA 300 ppm


ValueTypeComponents


TWA 0.5 ppm



TWA 300 ppm


ValueTypeComponents

STELBenzene (CAS 71-43-2) 15.5 mg/m3

5 ppm

TWA 3 mg/m3

1 ppm


1000 ppm


ValueTypeComponents

STELBenzene (CAS 71-43-2) 16 mg/m3

5 ppm

TWA 3.2 mg/m3

1 ppm


1000 ppm

Engineering controls Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaustventilation, or other engineering controls to control airborne levels below recommended exposurelimits. Use explosion-proof equipment.


Eye / face protection Wear safety glasses. If splash potential exists, wear full face shield or chemical goggles.

Skin protection Wear chemical-resistant, impervious gloves. Full body suit and boots are recommended whenhandling large volumes or in emergency situations. Flame retardant protective clothing isrecommended.

CPH MSDS NA

4 / 9



Respiratory protection Wear a NIOSH-approved (or equivalent) full-facepiece airline respirator in the positive pressuremode with emergency escape provisions.

General hygiene

considerationsAvoid contact with skin. Keep away from food and drink. Provide eyewash station and safetyshower. Handle in accordance with good industrial hygiene and safety practice.


Appearance Amber liquid.


Form Liquid.

Color Amber.

Odor Gasoline-like.

Odor threshold < 0.25 ppm

pH Not available.

Vapor pressure > 1 (Air=1)

Vapor density 3 - 4 ( Air=1)

Boiling point 77 - 392 °F (25 - 200 °C)

Melting point/Freezing point Not available.

Solubility (water) Insoluble


Flash point < -40 °F (< -40 °C) Closed Cup


upper, % by volume

7.1 %


lower, % by volume

1.2 %

Auto-ignition temperature 842 °F (450 °C)

VOC 100 %

Evaporation rate 4 (Butyl acetate = 1)


Chemical stability Stable under normal temperature conditions and recommended use.

Conditions to avoid Heat, flames and sparks. Ignition sources. Contact with incompatible materials. Do not pressurize,cut, weld, braze, solder, drill, grind or expose empty containers to heat, flame, sparks, staticelectricity, or other sources of ignition; they may explode and cause injury or death.



productsCarbon monoxide. Carbon dioxide. Sulfur oxides. Hydrocarbons.


reactionsHazardous polymerization does not occur.


Test Results

Toxicological data

Components Species

Ethanol (CAS 64-17-5)

LC50 Rat

Inhalation

Acute

20000 mg/l, 10 Hours

LD50 Rat

Oral

7060 mg/kg

Sensitization This substance may have a potential for sensitization which may provoke an allergic reactionamong sensitive individuals.

Acute effects Harmful if inhaled, absorbed through skin, or swallowed. Harmful: may cause lung damage ifswallowed. Irritating to eyes, respiratory system and skin. In high concentrations, vapors andspray mists are narcotic and may cause headache, fatigue, dizziness and nausea.

CPH MSDS NA

5 / 9



Local effects


Benzene (CAS 71-43-2) Can be absorbed through the skin.

Chronic effects Prolonged and repeated exposure to benzene may cause serious injury to blood forming organsand is associated with anemia and to the later development of acute myelogenous leukemia(AML). Danger of serious damage to health by prolonged exposure. Prolonged or repeatedoverexposure may cause central nervous system, kidney, liver, and lung damage.

Subchronic effects Subchronic inhalation of benzene by rats produced decreased white blood cell counts, decreasedbone marrow cell activity, increased red blood cell activity and cataracts. Blood disorders mayoccur after prolonged inhalation, prolonged skin contact and/or ingestion. Liver and kidneydamage may occur after prolonged and repeated exposure.

Carcinogenicity Cancer hazard. Contains benzene, a classified IARC 1 chemical (Known Human Carcinogen).

ACGIH Carcinogens

Benzene (CAS 71-43-2) A1 Confirmed human carcinogen.

Ethanol (CAS 64-17-5) A3 Confirmed animal carcinogen with unknown relevance tohumans.

Gasoline (CAS 86290-81-5) A3 Confirmed animal carcinogen with unknown relevance tohumans.

IARC Monographs. Overall Evaluation of Carcinogenicity

Benzene (CAS 71-43-2) 1 Carcinogenic to humans.

Gasoline (CAS 86290-81-5) 2B Possibly carcinogenic to humans.

US NTP Report on Carcinogens: Known carcinogen

Benzene (CAS 71-43-2) Known To Be Human Carcinogen.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Benzene (CAS 71-43-2) Cancer hazard.

Epidemiology Contains benzene. Human epidemiology studies indicate that prolonged and/or repeatedoverexposure to benzene may cause damage to the blood-producing system and serious blooddisorders, including leukemia. Animal tests suggest that prolonged and/or repeated overexposureto benzene may damage the embryo/fetus. The relevance of these animal studies to humans hasnot been fully established.

Mutagenicity May cause heritable genetic damage.

Neurological effects Central and/or peripheral nervous system damage. May cause central nervous system disorder(e.g., narcosis involving a loss of coordination, weakness, fatigue) and/or damage.

Reproductive effects Animal studies of benzene have shown testicular effects, alterations in reproductive cycles,chromosomal aberrations and embryo/fetotoxicity. May damage fertility or the unborn child. Cancause adverse reproductive effects - such as birth defects, miscarriages, or infertility. Avoidexposure to women during early pregnancy. Avoid contact during pregnancy/while nursing.

Further information Symptoms may be delayed.


Ecotoxicological data

Components Test ResultsSpecies

Benzene (CAS 71-43-2)

Aquatic

EC50Crustacea 8.76 - 15.6 mg/l, 48 hoursWater flea (Daphnia magna)

LC50Fish 5.3 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)

Ethanol (CAS 64-17-5)

Aquatic

EC50Crustacea 7.7 - 11.2 mg/l, 48 hoursWater flea (Daphnia magna)

LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas)

Ecotoxicity Contains a substance which causes risk of hazardous effects to the environment.

Environmental effects The product contains a substance which is toxic to aquatic organisms and which may causelong-term adverse effects in the aquatic environment.

Aquatic toxicity Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

Persistence and degradability Not available.

CPH MSDS NA

6 / 9



Bioaccumulation /


Partition coefficient

Ethanol -0.31

Benzene 2.13


Waste codes D001: Waste Flammable material with a flash point <140 °FD018: Waste Benzene

Disposal instructions Dispose in accordance with all applicable regulations. Dispose of this material and its container tohazardous or special waste collection point. Incinerate the material under controlled conditions inan approved incinerator. Do not allow this material to drain into sewers/water supplies. Do notcontaminate ponds, waterways or ditches with chemical or used container.


DOT

UN1203UN number

Basic shipping requirements:

Gasoline, MARINE POLLUTANTProper shipping name

3Hazard class

IIPacking group

YesMarine pollutant

Environmental hazards

144, 177, B1, B33, IB2, T4, TP1 Special provisions

Additional information:

150Packaging exceptions

202Packaging non bulk

242Packaging bulk

IATA

UN1203UN number

GasolineUN proper shipping name

3Transport hazard class(es)

IIPacking group

YesEnvironmental hazards

3HERG code

IMDG

UN1203UN number

GASOLINE, MARINE POLLUTANTUN proper shipping name

3Transport hazard class(es)

IIPacking group

YesMarine pollutant

Environmental hazards

F-E, S-EEmS No.

TDG

GASOLINE, MARINE POLLUTANTProper shipping name

3Hazard class

UN1203UN number

IIPacking group

YesMarine pollutant

17, 82, 88Special provisions


US federal regulations


Not regulated.


Benzene (CAS 71-43-2)


Benzene (CAS 71-43-2) 0.1 %

CPH MSDS NA

7 / 9




Benzene (CAS 71-43-2) Listed.


Gasoline: 100Benzene: 10


Hazard categories Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - No




No


370)Yes

Drug Enforcement


1308.11-15)

Not controlled


WHMIS classification B2 - Flammable LiquidsD1A - Immediate/Serious-VERY TOXICD2A - Other Toxic Effects-VERY TOXICD2B - Other Toxic Effects-TOXIC

WHMIS labeling

Inventory status







YesEurope






YesPhilippines



State regulations



Ethanol (CAS 64-17-5) Listed.



US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

Benzene (CAS 71-43-2) Listed: February 27, 1987 Carcinogenic.

US - California Proposition 65 - CRT: Listed date/Developmental toxin

Benzene (CAS 71-43-2) Listed: December 26, 1997 Developmental toxin.

CPH MSDS NA

8 / 9



US - California Proposition 65 - CRT: Listed date/Male reproductive toxin

Benzene (CAS 71-43-2) Listed: December 26, 1997 Male reproductive toxin.




US - Pennsylvania RTK - Hazardous Substances: Special hazard

Benzene (CAS 71-43-2) Special hazard.





Benzene (CAS 71-43-2) 500 LBS




Gasoline (CAS 86290-81-5) Listed.



HMIS® ratings Health: 2*Flammability: 4Physical hazard: 0



CPH MSDS NA

9 / 9




1. Product and Company IdentificationMaterial name INDUSTRIAL HYDRAULIC ALL-WEATHER SLRevision date 12-07-2011

Version # 01

CAS # Mixture

Product code 1282

Product use Hydraulic oil.

Synonym(s) 22, 32 Grade

(613) 996-6666 - Canutec

(306) 244-3447

Federated Co-operative Limited

(306) 721-5353


P.O. Box 260; 9th Avenue North

Consumers Co-operative Refineries Limited


Telephone


AddressManufacturer

P.O. Box 1050, 401 - 22nd Street East


2. Hazards IdentificationPhysical state Liquid.




Potential health effectsRoutes of exposure Eye contact. Skin contact. Ingestion. Inhalation.







3. Composition / Information on IngredientsThe manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.








CPH MSDS NA

1 / 5

INDUSTRIAL HYDRAULIC ALL-WEATHER SL

906159 Version #: 01 Revision date: 12-07-2011 Print date: 12-07-2011





None.







No data available.


gloves.







8. Exposure Controls / Personal ProtectionOccupational exposure limits No exposure limits noted for ingredient(s).







9. Physical & Chemical PropertiesAppearance Oily liquid.

Color Straw/yellow.

Odor Slight hydrocarbon.



Form Liquid.

pH Not available.

Melting point -65.2 °F (-54 °C)




Evaporation rate Not available.


Not available.

CPH MSDS NA

2 / 5




Not available.




Solubility (water) Sligthly soluble in cold and hot water


Not available.









Will not occur.

11. Toxicological InformationAcute effects No data available.











Persistence anddegradability

No data is available on the degradability of this product.


No data available.


Not available.


No data available.

13. Disposal ConsiderationsDisposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in

accordance with all applicable regulations.




CPH MSDS NA

3 / 5



14. Transport InformationDOTNot regulated as dangerous goods.




15. Regulatory InformationUS federal regulations This product is not hazardous according to OSHA 29CFR 1910.1200.


TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D)Not regulated.


Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - No



No

Section 311/312 (40 CFR370)

No


Not controlled



NoAustralia Australian Inventory of Chemical Substances (AICS)

NoCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

NoChina Inventory of Existing Chemical Substances in China (IECSC)

NoEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

NoJapan Inventory of Existing and New Chemical Substances (ENCS)

NoKorea Existing Chemicals List (ECL)

NoNew Zealand New Zealand Inventory

NoPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)

NoUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory


16. Other InformationFurther information HMIS® is a registered trade and service mark of the NPCA.

HMIS® ratings Health: 0Flammability: 1Physical hazard: 0Personal protection: G

CPH MSDS NA

4 / 5






CPH MSDS NA

5 / 5





Material name PROPANE- LIQUEFIED PETROLEUM GAS

Version # 01


Revision date -

Supersedes date -

CAS # Mixture

Product code 127

Product use Various.

Synonym(s) Unstenched Propane * Stenched Propane * HD-5 Propane * Standard Propane





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec


Physical state Gas.

Appearance Colorless liquefied gas.

Emergency overview DANGER

Extremely flammable gas. High pressure gas. Gas reduces oxygen available for breathing.

Contact with liquefied gas might cause frostbites, in some cases with tissue damage. In a fire or ifheated, a pressure increase will occur and the container may burst or explode.Static accumulating flammable materials can become electrostatically charged even in bondedand grounded equipment. Sparks may ignite material and vapor may cause flash fire (orexplosion).



Routes of exposure Inhalation. Eyes. Skin.

Eyes Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn").

Skin Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn").

Inhalation Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygenbelow safe breathing levels. Nasal and respiratory tract irritation, central nervous system effectsincluding excitation, euphoria, contracted eye pupils, dizziness, drowsiness, blurred vision,fatigue, nausea, headache, loss of reflexes, tremors, convulsions, seizures, loss ofconsciousness, coma, respiratory arrest and sudden death could occur as a result of long termand/or high concentration exposure to vapors. May also cause anemia and irregular heart rhythm.

Ingestion This material is a gas under normal atmospheric conditions and ingestion is unlikely.

Target organs Respiratory tract. Eyes. Central nervous system.

Chronic effects May cause central nervous system effects. Components have been shown to be weak cardiacsensitizers which can result in cardiac arrhythmia and ventricular fibrillation.

Potential environmental effects Not expected to be harmful to aquatic organisms.

CPH MSDS NA

1 / 6

PROPANE- LIQUEFIED PETROLEUM GAS CPH MSDS NA




74-98-6 100Propane

75-08-1 0.005Ethanethiol



Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention immediately.

Skin contact Wash frost-bitten areas with plenty of water. Do not remove clothing. Get medical attentionimmediately.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.Call a physician or poison control center immediately.

Ingestion Ingestion is not a typical route of exposure for gases or liquefied gases.



Flammable properties Extremely flammable gas. Gas forms mixtures with air which can catch fire and burn withexplosive violence. Vapors are heavier than air and invisible mixture spreads easily and mayaccumulate in low or confined areas, travel considerable distance to source of ignition and flashback. Runoff to sewer may create fire or explosion hazard.

Extinguishing media


mediaDry chemical, CO2, water spray, fog, or foam.

Fire fighting

equipment/instructionsSelf-contained breathing apparatus, operated in positive pressure mode and full protectiveclothing must be worn in case of fire.

Move container from fire area if it can be done without risk.

Do not extinguish fires unless gas flow can be stopped safely; explosive re-ignition may occur.Promptly isolate the scene by removing all persons from the vicinity of the incident. No actionshall be taken involving any personal risk or without suitable training. For fires involving thismaterial, do not enter any enclosed or confined fire space without proper protective equipment,including self-contained breathing apparatus. Stop flow of material. Use water to keep fireexposed containers cool and to protect personnel effecting shutoff. If a leak or spill has notignited, use water spray to disperse the vapors and to protect personnel attempting to stop leak.Prevent runoff from fire control or dilution from entering streams, sewers or drinking water supply.


productsCarbon oxides.


Personal precautions Evacuate the area promptly. No action shall be taken involving any personal risk or withoutsuitable training. Keep unnecessary personnel away.

Ensure adequate ventilation. In case of inadequate ventilation, use respiratory protection. Wearappropriate personal protective equipment (See Section 8).

Environmental precautions Should not be released into the environment. Prevent further leakage or spillage if safe to do so.Prevent from entering into soil, ditches, sanitary sewers, waterways and/or groundwater.

Methods for cleaning up Ventilate well, stop flow of gas or liquid if possible. Immediately contact emergency personnel.


Handling Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment.These alone may be insufficient to remove static electricity.Wear appropriate personal protective equipment (See Section 8). Eating, drinking, and smokingshould be prohibited in areas where this material is handled, stored, and processed. Do notbreathe gas. Do not get in eyes, on skin, on clothing. Use only with adequate ventilation.

Storage Store in accordance with local, regional, national, and international regulations. Secure cylindersin an upright position at all times, close all valves when not in use. Store in a cool, dry,well-ventilated place. Keep container tightly closed and sealed until ready for use. Protectcylinders from damage.

CPH MSDS NA

2 / 6






ValueTypeComponents

TWAPropane (CAS 74-98-6) 1000 ppm


ValueTypeComponents

PELPropane (CAS 74-98-6) 1800 mg/m3

1000 ppm


ValueTypeComponents


Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and

Safety Regulation 296/97, as amended)

ValueTypeComponents



ValueTypeComponents



ValueTypeComponents

TWAPropane (CAS 74-98-6) 1800 mg/m3

1000 ppm

Engineering controls Use process enclosures, local exhaust ventilation, or other engineering controls to controlairborne levels below recommended exposure limits. The engineering controls also need to keepgas, vapor, or dust concentrations below any lower explosive limits.



Skin protection Wear protective clothing appropriate for the risk of exposure.

Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn.

General hygiene

considerationsDo not eat, drink or smoke when using the product. Wash thoroughly after handling. Provideeyewash station and safety shower. Handle in accordance with good industrial hygiene and safetypractices.


Appearance Colorless liquefied gas.

Physical state Gas.

Form Compressed liquefied gas.

Color Colorless

Odor Boiling cabbage if stenched.

Odor threshold 4800 ppm

pH Not available.

Vapor pressure 1034.1 - 1241 kPa

Vapor density 1.6

Boiling point -43.6 °F (-42 °C)

Melting point/Freezing point -292 °F (-180 °C) / -302.6 °F (-185.89 °C)

Solubility (water) 6.5 % v/v (20 °C)


Flash point -150 °F (-101.1 °C) Pensky-Martens Closed Cup


upper, % by volume

9.5 %

CPH MSDS NA

3 / 6




lower, % by volume

2.2 %


VOC 100 %

Evaporation rate > 1 (Ether (anhydrous)=1)

Molecular weight 44.11 g/mol

Molecular formula C3-H8

Other data

Critical temperature 205.9 °F (96.6 °C)


Chemical stability Stable under normal temperature conditions and recommended use.

Conditions to avoid In a fire or if heated, a pressure increase will occur and the container may burst or explode.

Incompatible materials Oxidizing agents. Reducing agents. Acids. Alkalis.


productsNone known.


reactionsPolymerization will not occur.


Test Results

Toxicological data

Components Species

Propane (CAS 74-98-6)

LC50 Rat

Inhalation

Acute

> 1442.847 mg/l, 15 Minutes

Sensitization Not available.

Acute effects Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygenbelow safe breathing levels. Exposure to rapidly expanding gas or vaporizing liquid may causefrostbite ("cold burn").

Chronic effects May cause central nervous system effects.


Ecotoxicity Not expected to be harmful to aquatic organisms.

Persistence and degradability Not available.

Bioaccumulation /


Partition coefficient

Propane 2.36


Waste codes D001: Waste Flammable material with a flash point <140 °F

Disposal instructions Dispose in accordance with all applicable regulations. Empty containers may contain productresidues. Do not puncture or incinerate even when empty. This material and/or its container mustbe disposed of as hazardous waste. Return the empty cylinder to the supplier.


DOT

UN1978UN number

Basic shipping requirements:

PropaneProper shipping name

2.1Hazard class

19, T50Special provisions

Additional information:

306Packaging exceptions

CPH MSDS NA

4 / 6



304Packaging non bulk

314, 315Packaging bulk

100Reportable quantity

IATA

UN1978UN number

PropaneUN proper shipping name

2.1Transport hazard class(es)

10LERG code

IMDG

UN1978UN number

PROPANEUN proper shipping name

2.1Transport hazard class(es)

F-D, S-UEmS No.

TDG

PROPANEProper shipping name

2.1Hazard class

UN1978UN number

NoMarine pollutant


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.


Not regulated.


Not regulated.


Propane: 100


Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - YesReactivity Hazard - No




Yes


370)Yes

Clean Water Act (CWA) Section

112(r) (40 CFR 68.130)Hazardous substance

Drug Enforcement


1308.11-15)

Not controlled



WHMIS classification A - Compressed GasB1 - Flammable Gases

WHMIS labeling

CPH MSDS NA

5 / 6



Inventory status







YesEurope






YesPhilippines



State regulations


Not listed.


Propane (CAS 74-98-6) Listed.




Propane (CAS 74-98-6) 500 LBS








CPH MSDS NA

6 / 6




1. Product and Company IdentificationMaterial name TRANS HYDRAULIC FLUIDRevision date 12-07-2011

Version # 01

CAS # Mixture

Product code 62

Product use Transmission and hydraulic oil.

Synonym(s) (NO DYE)

(613) 996-6666 - Canutec

(306) 244-3447

Federated Co-operative Limited

(306) 721-5353


P.O. Box 260; 9th Avenue North

Consumers Co-operative Refineries Limited


Telephone


AddressManufacturer

P.O. Box 1050, 401 - 22nd Street East


2. Hazards IdentificationPhysical state Liquid.





Potential health effectsRoutes of exposure Eye contact. Skin contact. Ingestion. Inhalation.














CPH MSDS NA

1 / 5

TRANS HYDRAULIC FLUID









None.







No data available.


gloves.







8. Exposure Controls / Personal ProtectionOccupational exposure limits No exposure limits noted for ingredient(s).







9. Physical & Chemical PropertiesAppearance Oily liquid.

Color Brown.

Odor Mild.



Form Liquid.

pH Not available.

Melting point -40 °F (-40 °C)



CPH MSDS NA

2 / 5




Evaporation rate Not available.


Not available.


Not available.




Solubility (water) Sligthly soluble in cold and hot water


Not available.









Will not occur.

11. Toxicological InformationAcute effects Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious

chemical pneumonia.











Persistence anddegradability

No data is available on the degradability of this product.


No data available.


Not available.


No data available.

13. Disposal ConsiderationsDisposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in

accordance with all applicable regulations.



CPH MSDS NA

3 / 5




14. Transport InformationDOTNot regulated as dangerous goods.






TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D)Not regulated.

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentrationZinc Alkyldithiophosphate (CAS 68649-42-3) 1.0 % N982

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substanceZinc Alkyldithiophosphate (CAS 68649-42-3) N982 Listed.


Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - No



No

Section 311/312 (40 CFR370)

No


Not controlled



WHMIS labeling


YesAustralia Australian Inventory of Chemical Substances (AICS)

YesCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)

YesEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

NoJapan Inventory of Existing and New Chemical Substances (ENCS)

YesKorea Existing Chemicals List (ECL)

CPH MSDS NA

4 / 5



Country(s) or region Inventory name On inventory (yes/no)*YesNew Zealand New Zealand Inventory

YesPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory


State regulationsUS - California Hazardous Substances (Director's): Listed substance


US - New Jersey Community RTK (EHS Survey): Reportable thresholdZinc Alkyldithiophosphate (CAS 68649-42-3) 500 LBS

US - New Jersey RTK - Substances: Listed substanceZinc Alkyldithiophosphate (CAS 68649-42-3) Listed.

16. Other InformationFurther information HMIS® is a registered trade and service mark of the NPCA.

HMIS® ratings Health: 2Flammability: 1Physical hazard: 0Personal protection: X




CPH MSDS NA

5 / 5



PETROSOL 3355

W215

This product is an aliphatic solvent that can also be used as kerosene (fuel for non-vented space heaters and wick-fed illuminating lamps).

Petro-Canada: 403-296-3000Canutec Transportation: 613-996-6666Poison Control Centre: Consult local telephone directory for emergency number(s).

PETRO-CANADAP.O. Box 2844150 –6th Avenue South-WestCalgary, AlbertaT2P 3E3


Product name

Material uses

Manufacturer

Code

In case of emergency

Product and company identification

PETROSOL 3355

:

:

:

:

:

1 .

Dermal contact. Eye contact. Inhalation. Ingestion.

Emergency overview

Hazards identification

Routes of entryPotential acute health effects

Inhalation of this product may cause respiratory tract irritation and Central NervousSystem (CNS) Depression, symptoms of which may include; weakness, dizziness,slurred speech, drowsiness, unconsciousness and in cases of severe overexposure;coma and death.

May cause eye irritation.

Ingestion of this product may cause gastro-intestinal irritation. Aspiration of this productmay result in severe irritation or burns to the respiratory tract.

Moderately irritating to the skin.

EyesSkin

Inhalation

Ingestion

Physical state Clear liquid.

CAUTION!

COMBUSTIBLE LIQUID AND VAPOUR. MAY CAUSE SKIN IRRITATION.

Combustible liquid. Moderately irritating to the skin. Keep away from heat, sparks andflame. Avoid breathing vapour or mist. Avoid contact with eyes, skin and clothing. Useonly with adequate ventilation. Wash thoroughly after handling.

:

:

:

::

:

:

Medical conditionsaggravated by over-exposure

Repeated skin exposure can produce local skin destruction or dermatitis.:

Odour : Hydrocarbon.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).

2 .

Potential chronic health effects

Carcinogenicity : Contains material which may cause cancer, based on animal data.

Mutagenicity : No known significant effects or critical hazards.

Teratogenicity : No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards.

Chronic effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

WHMIS (Canada) :

Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C(200°F).Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).

Date of issue : 6/22/2012. Internet: www.petro-canada.ca/msds Page: 1/7TM Trademark of Suncor Energy Inc. Used under licence.Petro-Canada is a Suncor Energy business

PETROSOL 3355 Page Number: 2

Hazards identification2 .See toxicological information (Section 11)

Kerosine (petroleum), hydrodesulfurized 64742-81-0 99 - 100

Composition/information on ingredientsName CAS number %

3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reporting inthis section.

Wash out mouth with water. Do not induce vomiting unless directed to do so by medicalpersonnel. Never give anything by mouth to an unconscious person. Get medicalattention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of waterfor at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medicalattention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minuteswhile removing contaminated clothing and shoes. Wash skin thoroughly with soap andwater or use recognised skin cleanser. Wash clothing before reuse. Clean shoesthoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attentionimmediately.

First-aid measuresEye contact

Skin contact

Inhalation

Ingestion

No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.

Notes to physician

:

:

:

:

:

4 .

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It maybe dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Use dry chemical, CO2, water spray (fog) or foam.

Flammable in presence of open flames, sparks and heat. May accumulate in confinedspaces. This product can accumulate static charge and ignite. Vapours are heavier thanair and may travel considerable distance to sources of ignition and flash back.

Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat orsources of ignition.

Fire-fighting measures

Extinguishing media

Special remarks on firehazards

Special remarks onexplosion hazards

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool.

Class II - combustible liquid (NFPA).

Special protectiveequipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

:

:

5 .

Special exposure hazards :Do not use water jet.

Suitable :Not suitable :

Products of combustion : Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur oxides (SOx), unidentifiedorganic compounds, smoke and irritating vapours as products of incomplete combustion.

Flammability of the product :



No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilt material. Shut off all ignition sources. Noflares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach the release fromupwind. Prevent entry into sewers, water courses, basements or confined areas. Washspillages into an effluent treatment plant or proceed as follows. Contain and collectspillage with non-combustible, absorbent material e.g. sand, earth, vermiculite ordiatomaceous earth and place in container for disposal according to local regulations(see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of viaa licensed waste disposal contractor. Contaminated absorbent material may pose thesame hazard as the spilt product. Note: see section 1 for emergency contact informationand section 13 for waste disposal.


Accidental release measures

: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains andsewers. Inform the relevant authorities if the product has caused environmental pollution(sewers, waterways, soil or air).

Personal precautions :

Large spill :

6 .

Stop leak if without risk. Move containers from spill area. Dilute with water and mop upif water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material andplace in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

Small spill :Methods for cleaning up

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see section 10) and food and drink. Eliminateall ignition sources. Separate from oxidizing materials. Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabelled containers.Use appropriate containment to avoid environmental contamination. Ensure the storagecontainers are grounded/bonded.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking and smoking.Remove contaminated clothing and protective equipment before entering eating areas.Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour ormist. Use only with adequate ventilation. Wear appropriate respirator when ventilationis inadequate. Do not enter storage areas and confined spaces unless adequatelyventilated. Keep in the original container or an approved alternative made from acompatible material, kept tightly closed when not in use. Store and use away from heat,sparks, open flame or any other ignition source. Use explosion-proof electrical(ventilating, lighting and material handling) equipment. Use non-sparking tools. Takeprecautionary measures against electrostatic discharges. To avoid fire or explosion,dissipate static electricity during transfer by earthing and bonding containers andequipment before transferring material. Empty containers retain product residue and canbe hazardous. Do not reuse container.

Handling and storageHandling

Storage

:

:

7 .

Kerosine (petroleum), hydrodesulfurized ACGIH TLV (United States). Absorbed through skin.TWA: 200 mg/m³ 8 hour(s).

Exposure controls/personal protection

Consult local authorities for acceptable exposure limits.

8 .Ingredient Exposure limits



Exposure controls/personal protection8 .

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator. Recommended: organic vapour cartridge orcanister may be permissible under certain circumstances where airborne concentrationsare expected to exceed exposure limits. Protection provided by air-purifying respiratorsis limited. Use a positive-pressure, air-supplied respirator if there is any potential foruncontrolled release, exposure levels are unknown, or any other circumstances whereair-purifying respirators may not provide adequate protection.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.

Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.

Personal protection

Eyes

Skin

Respiratory

:

:

:

Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.Recommended: polyvinyl alcohol (PVA), Viton®. Consult your PPE provider forbreakthrough times and the specific glove that is best for you based on your usepatterns. It should be realized that eventually any material regardless of theirimperviousness, will get permeated by chemicals. Therefore, protective gloves should beregularly checked for wear and tear. At the first signs of hardening and cracks, theyshould be changed.

Hands :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas,vapour or dust concentrations below any lower explosive limits. Use explosion-proofventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.

Recommended monitoringprocedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.

150 to 300°C (302 to 572°F)

Clear liquid.

Not available.

Not available.

Not available.

Hydrocarbon.

Clear and bright

Boiling/condensation pointMelting/freezing point

Physical and chemical propertiesPhysical state

pHOdour thresholdOdourColour

:

::

:::

:

Flash point : Closed cup: >43°C (>109.4°F) [Tag Closed Tester (ASTM D56).]

210°C (410°F):Auto-ignition temperatureFlammable limits : Lower: 0.7%

Upper: 5%

9 .



Physical and chemical properties9 .

<1 (water = 1).Low volatility at ambient temperature and pressure, and much lower than gasoline.

0.8 to 0.82 kg/L @ 15°C (59°F)

4.5 [Air = 1]

1.4 kPa (10.5 mm Hg) @ 37.8°C (100°F)

Insoluble in water. Partially miscible in some alcohols. Miscible with other petroleumsolvents.

Not available.

1.0 - 1.9 cSt @40°C (104°F)

Relative densityVapour pressure

Vapour densityVolatility

Evaporation rateViscosity

Solubility

::

::

::

:Pour point <-51°C (<-60°F):

The product is stable.

Reactive with oxidising agents.

Under normal conditions of storage and use, hazardous polymerisation will not occur.

May release COx, NOx, SOx, unidentified organic compounds, smoke and irritatingvapours when heated to decomposition.

Stability and reactivityChemical stability

Materials to avoidHazardous decompositionproducts

Hazardous polymerisation:

::

:

10 .

Toxicological information11 .

Acute toxicity

Kerosine (petroleum), hydrodesulfurized LD50 Dermal Rabbit >2000 mg/kg -LD50 Oral Rat >5000 mg/kg -LC50 InhalationVapour

Rat >5200 mg/m³ 4 hours

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary : Not available.

Chronic toxicityConclusion/Summary : Not available.

CarcinogenicityConclusion/Summary : Not available.

MutagenicityConclusion/Summary : Not available.

TeratogenicityConclusion/Summary : Not available.

Reproductive toxicityConclusion/Summary : Not available.

Classification

Kerosine (petroleum), hydrodesulfurized A3 - - - - -

Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA

Irritation/CorrosionConclusion/Summary : Not available.

SensitiserConclusion/Summary : Not available.



Ecological informationEnvironmental effects : No known significant effects or critical hazards.

12 .

Aquatic ecotoxicityConclusion/Summary : Not available.

BiodegradabilityConclusion/Summary : Not available.

The generation of waste should be avoided or minimised wherever possible. Significantquantities of waste product residues should not be disposed of via the foul sewer butprocessed in a suitable effluent treatment plant. Dispose of surplus and non-recyclableproducts via a licensed waste disposal contractor. Disposal of this product, solutionsand any by-products should at all times comply with the requirements of environmentalprotection and waste disposal legislation and any regional local authority requirements.Waste packaging should be recycled. Incineration or landfill should only be consideredwhen recycling is not feasible. This material and its container must be disposed of in asafe way. Care should be taken when handling emptied containers that have not beencleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphereinside the container. Do not cut, weld or grind used containers unless they have beencleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contactwith soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

:

13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees.

Transport information

Not available. -DOT Classification

TDG Classification 3

Not available. -

UN1223 KEROSENE III

Regulatoryinformation

UN number Proper shippingname

Classes PG* Label Additionalinformation

Not available.

-

14 .

PG* : Packing group

Combustible liquidIrritating material

HCS Classification

Regulatory information

WHMIS (Canada) Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C(200°F).Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).

International regulations

:

:

Canada

United States

15 .

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations andthe MSDS contains all the information required by the Controlled Products Regulations.

United States inventory(TSCA 8b)

All components are listed or exempted.

Canada inventory : All components are listed or exempted.

:

Europe inventory : All components are listed or exempted.



Available upon request.TM Trademark of Suncor Energy Inc. Used under licence.

Other information

References

Hazardous MaterialInformation System (U.S.A.)

2

2

0

0

2

2

National Fire ProtectionAssociation (U.S.A.)

Health

Special

Instability

Flammability

HealthFlammabilityPhysical hazards

COMBUSTIBLE LIQUID AND VAPOUR. MAY CAUSE SKIN IRRITATION.Label requirements :

Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.

Date of printingDate of issueDate of previous issue

6/22/2012.:::

:

:

:

16 .

Indicates information that has changed from previously issued version.

22 June 2012

6/18/2010.

For Copy of (M)SDS : Internet: www.petro-canada.ca/msds

Canada-wide: telephone: 1-800-668-0220; fax: 1-800-837-1228

For Product Safety Information: (905) 804-4752

Product Safety - JDWResponsible name :

Personal protection H




Material name SONIC TRANSHYDRAULIC

Version # 01


Revision date -

Supersedes date -

CAS # Mixture

Product code 2682

Product use Transmission and hydraulic oil.





Telephone (306) 721-5353




Telephone (306) 244-3447

24 Hour Emergency

Telephone

(613) 996-6666 - Canutec








Routes of exposure Eye contact. Skin contact.













CPH MSDS NA

1 / 5

SONIC TRANSHYDRAULIC CPH MSDS NA








Extinguishing media




mediaDo not use water jet as an extinguisher, as this will spread the fire. Avoid spraying water directlyinto storage container due to the danger of boilover.




Fire fighting




productsIncomplete combustion may produce: Carbon oxides. Sulphur oxides. Phosphorus oxides.

















General hygiene





Form Liquid.

Color Brown.

Odor Mild.


CPH MSDS NA

2 / 5



pH Not available.




Melting point/Freezing point -40 °F (-40 °C)


Specific gravity 0.89 (15.6°C / 60°F)



upper, % by volume

Not available.


lower, % by volume

Not available.












Acute effects Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.












Bioaccumulation /








DOT


CPH MSDS NA

3 / 5



IATA


IMDG


TDG



US federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.


Not regulated.


Not regulated.


Zinc Alkyldithiophosphate (CAS 68649-42-3) 1.0 % N982


Zinc Alkyldithiophosphate (CAS 68649-42-3) N982 Listed.


None


Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No




No


370)Yes

Drug Enforcement


1308.11-15)

Not controlled



WHMIS labeling

Inventory status







YesEurope





CPH MSDS NA

4 / 5





YesPhilippines



State regulations




Not listed.




Not regulated.


Zinc Alkyldithiophosphate (CAS 68649-42-3) 500 LBS


Not regulated.






CPH MSDS NA

5 / 5



Husky Energy Asphalt Cements – Non-Modified SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: February 19, 2015

Page 1 of 11 Deerfoot Consulting Inc.

Section 1: IDENTIFICATION

Product Name: Asphalt Cements – Non-Modified

Synonyms: Penetration Grade Asphalt Cement PG 150/200A Asphalt: 0339 PG 46-37(300/400A) Asphalt Cement: 0320 PG 52-34(200/300A) Asphalt Cement: 0341 PG 58-28 Asphalt Cement: 0350 PG 58-28(120/150A) Asphalt Cement: 0334 PG 58-31(120/150A) Asphalt Cement: 0334 PG 64-22(80/100A) Asphalt Cement: 0330 PG 64-25(80/100A) Asphalt Cement: 0330 PG 67-22 (PG 64-22) Asphalt Cement: 0351 PG 70-22 Asphalt Cement: 0352

Product Use: Paving asphalt.

Restrictions on Use: Not available.

Manufacturer/Supplier: Husky Oil Operations Ltd. PO Box 6525 Station 'D' Calgary, Alberta

Phone Number: 403-298-6111

Emergency Phone: 403-262-2111

Date of Preparation of SDS: February 19, 2015

Section 2: HAZARD(S) IDENTIFICATION

GHS INFORMATION

Classification: Carcinogenicity, Category 2

LABEL ELEMENTS Hazard Pictogram(s):

Signal Word: Warning

Hazard Statements:

Suspected of causing cancer.

Precautionary Statements Prevention: Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing, eye protection and face protection.

Response: If exposed or concerned: Get medical advice/attention.

Storage: Store locked up.



Disposal: Dispose of contents/container in accordance with applicable regional, national and local laws and regulations.

Hazards Not Otherwise Classified: Not applicable.

Ingredients with Unknown Toxicity: 100% of this product mixture consists of ingredient(s) of unknown acute toxicity.

This material is considered hazardous by the OSHA Hazard Communication Standard, (29 CFR 1910.1200).

Section 3: COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Ingredient(s) Common name / Synonyms

CAS No. % wt./wt.

Asphalt Not available. 8052-42-4 100 Polycyclic Aromatic Hydrocarbons Not available. 130498-29-2 variable Hydrogen sulfide (H2S) Hydrogen sulphide 7783-06-4 Trace

Section 4: FIRST-AID MEASURES

Inhalation: If inhaled: Call a poison center or doctor if you feel unwell.

Acute and delayed symptoms and effects: May cause respiratory irritation. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. This product may contain small amounts of Hydrogen sulphide which may accumulate in confined spaces. Inhalation of Hydrogen sulphide may cause loss of sense of smell, major irritation of the respiratory tract, headache, nausea, vomiting, dizziness, and fluid buildup in the lungs (pulmonary edema), which can be fatal. At 300 ppm unconsciousness may occur after 20 minutes. From 300 to 500 ppm, death can occur within 1 to 4 hours of continuous exposure. At 500 ppm the respiratory system is paralyzed, the victim collapses almost instantaneously, and death can occur after exposure of only 30 to 60 minutes. Above 500 ppm Hydrogen sulphide may cause immediate loss of consciousness; death is rapid, and possibly immediate.

Eye Contact: If in eyes: Rinse cautiously with water for at least 30 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor.

Acute and delayed symptoms and effects: May cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Hot liquid product may cause serious thermal burns on direct contact.

Skin Contact: If on skin (or hair): Rinse skin with water/shower. Get immediate medical advice/attention. Remove non-adhering contaminated clothing. Cool adherent materials and burned areas with ice and/or cold water. Do not remove adherent material or clothing. Do not use solvents to remove asphalt from the skin. Wash contaminated clothing before reuse.



Acute and delayed symptoms and effects: May cause skin irritation. Signs/symptoms may include localized redness, swelling, and itching. Hot liquid product may cause serious thermal burns on direct contact. Asphalt fumes can increase susceptibility to sunburn.

Ingestion: If swallowed: Rinse mouth. Immediately call a poison center or doctor. If vomiting occurs naturally, have victim lean forward to reduce the risk of aspiration. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.

Acute and delayed symptoms and effects: Hot product may cause thermal burns. Signs/symptoms may include severe mouth, throat and abdominal pain, nausea, vomiting, and diarrhea, blood in the feces and/or vomitus may also be seen. If swallowed in large quantities, Asphalt can obstruct the intestine.

General Advice: In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible).

Note to Physicians: Symptoms may not appear immediately.

Section 5: FIRE-FIGHTING MEASURES

FLAMMABILITY AND EXPLOSION INFORMATION Not flammable or combustible by OSHA/WHMIS criteria. Substance may be transported hot. When heated, this material may evolve toxic and flammable Hydrogen sulphide.

If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

Fire involving Tanks or Car/Trailer Loads: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

Sensitivity to Mechanical Impact: This material is not sensitive to mechanical impact. Sensitivity to Static Discharge: This material is sensitive to static discharge at temperatures

at or above the flash point.

MEANS OF EXTINCTION Suitable Extinguishing Media: Small Fire: Dry chemical, CO2, water spray or regular foam.

Large Fire: Water spray, fog or regular foam. Move containers from fire area if you can do it without risk.

Unsuitable Extinguishing Media: Do not use straight streams. Do not spray water onto burning product as this may cause spattering and spreading of the flame.

Products of Combustion: Oxides of carbon. Oxides of sulphur.

Protection of Firefighters: Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic



gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection.

Section 6: ACCIDENTAL RELEASE MEASURES

Emergency Procedures:

As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded.

Personal Precautions: Do not touch or walk through spilled material. Use personal protection recommended in Section 8.

Environmental Precautions: Prevent entry into waterways, sewers, basements or confined areas.

Methods for Containment: Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. Contain hot liquid by dyking and allow to cool and solidify. Do not flush to sewer or allow to enter waterways.

Methods for Clean-Up: Sweep up and shovel into suitable containers for disposal. Use clean non-sparking tools to collect absorbed material.

Other Information: See Section 13 for disposal considerations.

Section 7: HANDLING AND STORAGE

Handling: Do not swallow. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wash thoroughly after handling. Grounding of containers/pouring equipment is necessary when transferring hot liquid product. See Section 8 for information on Personal Protective Equipment. Storage: Store locked up. Store away from incompatible materials. See Section 10 for information on Incompatible Materials. Keep out of the reach of children. Asphalt contains trace amounts of Hydrogen sulfide which can accumulate in vapour space of tanks and containers.

Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines Component

Asphalt [CAS No. 8052-42-4]

ACGIH: 0.5 mg/m³ (TWA); A4; BEI; Inhalable fraction; For Asphalt (Bitumen) fume, as benzene-soluble aerosol

OSHA: No PEL established.



Polycyclic Aromatic Hydrocarbons [CAS No. 130498-29-2]

ACGIH: A2; BEI; Exposure by all routes should be carefully controlled to levels as low as possible (1990); For Benz[a]anthracene

OSHA: 0.2 mg/m³ (TWA); For benzene-soluble fraction.

Hydrogen sulfide (H2S) [CAS No. 7783-06-4]

ACGIH: 1 ppm (TWA); 5 ppm (STEL); (2009);

OSHA: 20 ppm (C); 50 ppm (Peak) (Maximum duration: 10 mins. once only if no other meas. exp. occurs.) 10 ppm (TWA); 15 ppm (STEL) [Vacated];

PEL: Permissible Exposure Limit TLV: Threshold Limit Value TWA: Time-Weighted Average STEL: Short-Term Exposure Limit C: Ceiling

Engineering Controls: Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapour, gas, etc.) below recommended exposure limits.

PERSONAL PROTECTIVE EQUIPMENT (PPE)

Eye/Face Protection: Wear chemical safety goggles. If product is hot, wear full face-shield. Use equipment for eye protection that meets the standards referenced by CSA Standard CAN/CSA-Z94.3-92 and OSHA regulations in 29 CFR 1910.133 for Personal Protective Equipment.

Hand Protection: Wear protective gloves. If product is hot, thermally protective gloves are recommended. Consult manufacturer specifications for further information.

Skin and Body Protection: Wear protective clothing. Clothing with full length sleeves and pants should be worn.

Respiratory Protection: If engineering controls and ventilation are not sufficient to control exposure to below the allowable limits then an appropriate NIOSH/MSHA approved air-purifying respirator that meets the requirements of CSA Standard CAN/CSA-Z94.4-11, or self-contained breathing apparatus must be used. Supplied air breathing apparatus must be used when oxygen concentrations are low or if airborne concentrations exceed the limits of the air-purifying respirators.

General Hygiene Considerations: Handle according to established industrial hygiene and safety practices. Consult a competent industrial hygienist to determine hazard potential and/or the PPE manufacturers to ensure adequate protection.



Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Black viscous material.

Colour: Black.

Odour: Asphalt.

Odour Threshold: Not available.

Physical State: Liquid.

pH: Not available.

Melting Point / Freezing Point:

> 31 °C (87.8 °F)

Initial Boiling Point: Not available.

Boiling Range: > 228 °C (442.4 °F) (1 atm)

Flash Point: 243 °C (469.4 °F) (COC)

Evaporation Rate: Not available.

Flammability (solid, gas): Not applicable.

Lower Flammability Limit: Not available.

Upper Flammability Limit: Not available.

Vapor Pressure: Not available.

Vapor Density: Not available.

Relative Density: 1.020 to 1.045 (Water = 1) at 21.1 °C (70 °F) (1 atm)

Solubilities: Insoluble in water.

Partition Coefficient: n-Octanol/Water:

Not available.

Auto-ignition Temperature: Not available.

Decomposition Temperature:

Not available.

Viscosity: Not available.

Percent Volatile, wt. %: Not available.

VOC content, wt. %: Not available.

Density: Not available.

Coefficient of Water/Oil Distribution:

Not available.



Section 10: STABILITY AND REACTIVITY

Reactivity: Contact with incompatible materials. Sources of ignition. Exposure to heat.

Chemical Stability: Stable under normal storage conditions.

Possibility of Hazardous Reactions:

Contact between heated Asphalt and water can cause a violent eruption.

Conditions to Avoid: Contact with incompatible materials. Sources of ignition. Exposure to heat.

Incompatible Materials: Acids. Bases. Oxidizers. Halogens.

Hazardous Decomposition Products: Hazardous sulphur dioxide, and related oxides of sulphur may be generated upon combustion.

Section 11: TOXICOLOGICAL INFORMATION

EFFECTS OF ACUTE EXPOSURE

Product Toxicity

Oral: Not available.

Dermal: Not available.

Inhalation: Not available.

Component Toxicity Component CAS No. LD50 oral LD50 dermal LC50 Asphalt 8052-42-4 Not available. Not available. Not available. Polycyclic Aromatic Hydrocarbons

130498-29-2 Not available. Not available. Not available.

Hydrogen sulfide 7783-06-4 Not available. Not available. 444 ppm (rat); 4H Likely Routes of Exposure: Eye contact. Skin contact. Inhalation. Ingestion.

Target Organs: Skin. Eyes. Gastrointestinal tract. Respiratory system. Bone marrow. Liver. Central nervous system.

Symptoms (including delayed and immediate effects) Inhalation: May cause respiratory irritation. Signs/symptoms may include cough, sneezing,

nasal discharge, headache, hoarseness, and nose and throat pain. This product may contain small amounts of Hydrogen sulphide which may accumulate in confined spaces. Inhalation of Hydrogen sulphide may cause loss of sense of smell, major irritation of the respiratory tract, headache, nausea, vomiting, dizziness, and fluid buildup in the lungs (pulmonary edema), which can be fatal. At 300 ppm unconsciousness may occur after 20 minutes. From 300 to 500 ppm, death can occur within 1 to 4 hours of continuous exposure. At 500 ppm the respiratory system is paralyzed, the victim collapses almost instantaneously, and death can occur after exposure of only 30 to 60 minutes. Above 500 ppm Hydrogen sulphide may cause immediate loss of consciousness; death is rapid, and possibly immediate.



Eye: May cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Hot liquid product may cause serious thermal burns on direct contact.

Skin: May cause skin irritation. Signs/symptoms may include localized redness, swelling, and itching. Hot liquid product may cause serious thermal burns on direct contact. Asphalt fumes can increase susceptibility to sunburn.

Ingestion: Hot product may cause thermal burns. Causes burns to nose, mouth, throat, and digestive tract. Signs/symptoms may include severe mouth, throat and abdominal pain, nausea, vomiting, and diarrhea, blood in the feces and/or vomitus may also be seen. If swallowed in large quantities, Asphalt can obstruct the intestine.

Skin Sensitization: Not available.

Respiratory Sensitization: Not available.

Medical Conditions Aggravated By Exposure:

Not available.

EFFECTS OF CHRONIC EXPOSURE (from short and long-term exposure) Target Organs: Skin. Eyes. Gastrointestinal tract. Respiratory system. Bone marrow.

Liver. Kidneys. Central nervous system.

Chronic Effects: Prolonged or repeated contact may dry skin and cause irritation. This product contains Polycyclic Aromatic Hydrocarbons. Prolonged contact with these compounds has been associated with the induction of skin and lung tumours, anemia, disorders of the liver, bone marrow and lymphoid tissues. Hydrogen sulphide may reduce lung function; cause neurological effects such as headaches, nausea, depression and personality changes; eye and mucous membrane irritation; and damage to cardiovascular system.

Carcinogenicity: May cause cancer. Long-term or repeated exposures to Asphalt fumes are possibly carcinogenic to humans.

Component Carcinogenicity Component ACGIH IARC NTP OSHA Prop 65 Asphalt A4 Group 2B Not listed. OSHA Carcinogen. Listed. Polycyclic Aromatic Hydrocarbons

A2 Not listed. List 2 OSHA Carcinogen. Listed.

Mutagenicity: Not available.

Reproductive Effects: Not available.

Developmental Effects Teratogenicity: Not available.

Embryotoxicity: Not available.

Toxicologically Synergistic Materials: Not available.



Section 12: ECOLOGICAL INFORMATION

Ecotoxicity: Not available.

Persistence / Degradability: Not available.

Bioaccumulation / Accumulation: Not available.

Mobility in Environment: Not available.

Other Adverse Effects: Not available.

Section 13: DISPOSAL CONSIDERATIONS

Disposal Instructions: Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements.

Section 14: TRANSPORT INFORMATION U.S. Department of Transportation (DOT) Proper Shipping Name: UN3257, ELEVATED TEMPERATURE LIQUID, N.O.S.

(Asphalt), 9, PG III

Class: 9 UN Number: UN3257

Packing Group: III

Label Code:

Canada Transportation of Dangerous Goods (TDG) Proper Shipping Name: Not regulated. Class: Not applicable. UN Number: Not applicable.

Packing Group: Not applicable.

Label Code: Not applicable.

Section 15: REGULATORY INFORMATION

Chemical Inventories

US (TSCA) The components of this product are in compliance with the chemical notification requirements of TSCA.

Canada (DSL) The components of this product are in compliance with the chemical notification requirements of the NSN Regulations under CEPA, 1999.



Federal Regulations

Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

WHMIS Classification: Class D2A - Carcinogenicity.

Hazard Symbols:

United States This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA Title III Component Section

302 (EHS) TPQ (lbs.)

Section 304 EHS RQ (lbs.)

CERCLA RQ (lbs.)

Section 313

RCRA CODE

CAA 112( r ) TQ (lbs.)

Polycyclic Aromatic Hydrocarbons

Not listed. Not listed. Not listed. 313 Not listed. Not listed.

Hydrogen sulphide 500 100 100 313 U135 10000 State Regulations Massachusetts US Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations Section 670.000) Component CAS No. RTK List Asphalt 8052-42-4 Listed. Polycyclic Aromatic Hydrocarbons 130498-29-2 Listed. Hydrogen sulphide 7783-06-4 E

Note: E = Extraordinarily Hazardous Substance New Jersey US New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5) Component CAS No. RTK List Asphalt 8052-42-4 Listed. Hydrogen sulphide 7783-06-4 SHHS

Note: SHHS = Special Health Hazard Substance Pennsylvania US Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323) Component CAS No. RTK List Asphalt 8052-42-4 Listed. Polycyclic Aromatic Hydrocarbons 130498-29-2 Listed. Hydrogen sulphide 7783-06-4 E

Note: E = Environmental Hazard



California California Prop 65:

WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm.

Component Type of Toxicity Asphalt cancer Polycyclic Aromatic Hydrocarbons cancer

Section 16: OTHER INFORMATION

Disclaimer: The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for their own particular use. Date of Preparation of SDS: February 19, 2015

SDS Expiry Date (Canada): February 18, 2018

Version: 2.0

GHS SDS Prepared by: Deerfoot Consulting Inc.

Phone: (403) 720-3700

http://www.aegisreg.com/

NEMCO RESOURCES LTD. Page 1 of 8 Diesel Fuel Conditioner

Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666


1. Product and company identification

PRODUCT NAME : Diesel Fuel Conditioner

PRODUCT CODE : 0518

SUPPLIER : NEMCO RESOURCES LTD.

25 Midland Street

Winnipeg, Manitoba

R3E 3J6 Canada

Date Issued : October, 2013

Emergency (call collect) : 204-788-1030

CANUTEC : 613-996-6666

2. Hazards identification

EMERGENCY OVERVIEW : Causes severe eye irritation. Vapours are extremely irritating to eyes and respiratory tract. Mists or sprays are irritating to eyes and respiratory tract. At elevated temperatures may cause irritation of the eyes and respiratory tract. Flammable liquid and vapour. May cause flash fire or explosion. Can decompose at high temperatures forming toxic gases. Contents may develop pressure on prolonged exposure to heat.

Inhalation : Contact with mist or spray may cause irritation of mucous membranes, coughing and difficulty in breathing. Remove from further exposure. For those providing assistance, avoid exposure to yourself and others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or mouth-to-mouth resuscitation and obtain immediate medical attention.

Ingestion : Seek immediate medical attention. DO NOT induce vomiting without supervision of medical personel, because of danger of aspirating liquid into lungs. Physician assessment is mandatory.

Eye : Causes severe eye irritation. May cause corneal damage and conjunctivitis. Vapours from this product are irritating to the eyes. Check for and remove any contact lenses. IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. DO NOT use an eye ointment. Seek medical attention if irritation persists.

Skin : This product may cause mild, transient irritation. Skin contact can cause irritation, especially under the finger nails (and other confined spaces such as under rings or watch bands). May cause defatting, drying and cracking of the skin. Prolonged and repeated contact may lead to dermatitis.Remove contaminated clothing - launder before reuse. Wash gently and thoroughly the contaminated skin with running water and non-abrasive soap. Get medical attention if redness or irritation occurs.



3. COMPOSITION/INFORMATION ON INGREDIENTS

Component TWA (ppm) Conentration

Solvent 100 45-55%

Isopropanol 200 40-50%

Inhibitor N/A 8-12%


Inhalation : Remove from further exposure. For those providing assistance, avoid exposure to yourself and others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or mouth-to-mouth resuscitation and obtain immediate medical attention.

Ingestion : Seek immediate medical attention. DO NOT induce vomiting without supervision of medical personel, because of danger of aspirating liquid into lungs. Physician assessment is mandatory.

Eye : Check for and remove any contact lenses. IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. DO NOT use an eye ointment. Seek medical attention if irritation persists.

Skin : Remove contaminated clothing - launder before reuse. Wash gently and thoroughly the contaminated skin with running water and non-abrasive soap. Get medical attention if redness or irritation occurs.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician : This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial resuscitation and appropriate chemotherapy if respiration is depressed. Isopropanol: Metabolism of isopropanol forms acetone, which may be detected in the urine and expired air. In contrast to diabetic acidosis, acidosis will occur in the absence of hyperglycemia. Haemodialysis should be considered in severe, acute intoxications. Medical conditions that may be aggravated by exposure to this product include neurological and cardiovascular disorders, diseases of the skin, eyes or respiratory tract, preexisting liver and kidney disorders.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA : (non-polar/water-immiscible). CAUTION: DO NOT use water jet. This product has a low flash point, use of water spray when fighting fire may be inefficient. Use water fog, foam dry chemical or Carbon Dioxide to extinguish flames.

AUTO-IGNITION TEMP. : Not available




FLAMMABILITY CLASS(WHMIS) : B-2:Flammable Liquid Flammable limits : Solvent: LEL: 0.8%, UEL: 5.6%

IPA: LEL:2%, UEL: 12% SPECIAL FIRE FIGHTING PROCEDURES

: Use water spray to cool fire-exposed containers or structures. Use water spray to disperse vapours; reignition is possible. Isolate materials that are not involved in the fire and protect personnel. Cool containers with flooding quantities of water until well after the fire is out. Notes: Flammable/combustible liquid. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (0.5 mile) in all directions; also, consider initial evacuation for 800 meters (0.5 mile) in all directions. DO NOT extinguish a leaking gas flame unless leak can be stopped. Shut off fuel to fire if it is possible to do so without hazard. If this is impossible, withdraw from area and let fire burn out under controlled conditions. Withdraw immediately in case of rising sound from venting safety device or any discolouration of tank due to fire. Cool containing vessels with water spray in order to prevent pressure build-up, autoignition or explosion. Avoid flushing spilled material into sewers, streams or other bodies of water. Self-contained breathing apparatus (SCBA) will be required if approaching the fire from downwind, or to enter enclosed areas or buildings.

RISK OF EXPLOSION : Do not cut, weld, heat, or drill empty containers. Vapours are heavier than air and may travel considerable distance to sources of ignition and flash back Runoff to sewer may create fire or explosion hazard.

Fire Fighting Protective Equipment

: Use self-contained breathing apparatus and protective clothing.

Fire Extinguishing Media : Alcohol resistant foam. Water fog. Use carbon dioxide or dry chemical media for small fires. If only water is available, use it in the form of a fog. This material may produce a floating fire hazard in extreme fire conditions. Do not use high volume water jet.

6. ACCIDENTAL RELEASE MEASURES In Case of Spill : Eliminate all sources of ignition such as flares, flames (including pilot lights), and

electrical sparks. Ventilate the area. Wear proper protective equipment (Section 8). Avoid breathing vapors. Collect with an inert absorbant and dispose of properly.

7. HANDLING AND STORAGE HANDLING

Handling Practices : Ground and bond equipment and containers to prevent a static charge buildup. Use spark-resistant tools and avoid "splash-filling" of containers. Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be under internal pressure. These should be cooled and carefully vented before opening. A face shield and apron should be worn. Vent container frequently, and more often in warm weather, to relieve pressure. Enforce NO SMOKING rules in area of use. Electrostatic charges may be generated during pumping. Electrostatic discharge may cause fire. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<= 10 m/sec).




Ventilation Requirements : Ventilation should be explosion proof

Other Precautions : Use only with adequate ventilation and avoid breathing vapours or mists. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling. Wash contaminated clothing thoroughly before re-use. Do not use cutting or welding torches on empty drums that contained this material/product. Store wiping rags and similar material in metal cans with tight fitting lids.

STORAGE

Ventilation Requirements : Ventilation should be explosion proof

Storage Requirements : Store in a cool, well-ventilated area. Keep away from heat, sparks and flames. Keep containers closed. Do not expose sealed containers to temperatures above 40° C. Protect from direct sunlight. Protect against physical damage. Isopropanol can form unstable peroxides on prolonged exposure to air and heat.

Special Materials to be Used for Packaging or Containers

: Materials of construction for storing the product include: mild steel or stainless steel. Equipment for storage, handling or transportation should NOT be made of: plastics or neoprene. At elevated temperatures: Aluminum and its alloys should not be used in equipment for storage, handling or transportation. Attacks some types of rubber, plastics and coatings. Confirm suitability of any material before using

8. EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION : No specific guidelines available. Do not use compressed oxygen in hydrocarbon

atmospheres. A NIOSH/MSHA-approved air-purifying respirator equipped with organic vapour cartridges for concentrations up to 1 000 ppm. An air-supplied respirator if concentrations are higher or unknown. Immediately Dangerous to Life and Health (IDLH) value: 2 000 ppm. The purpose of establishing an IDLH value is to ensure that the worker can escape from a given contaminated environment in the event of failure of the most protective respiratory equipment. In the event of failure of respiratory protective equipment, every effort should be made to exit immediately. If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check to make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If the seal is no longer good, you may need a new respirator..

Engineering controls Local exhaust ventilation required. Ventilation should be explosion proof. Make up air should be supplied to balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as sumps or pits where dense vapours may collect. For personnel entry into confined spaces (i.e. bulk storage tanks) a proper procedure must be followed. It must include consideration of, among other things, ventilation, testing of tank atmosphere, provision and maintenance of SCBA, and emergency rescue. Use the "buddy" system. The second person should be in view and trained and equipped to execute a rescue.

EYE/FACE PROTECTION : Gloves and protective clothing made from butyl rubber, nitrile rubber, viton, neoprene, PVC should be impervious under conditions of use. Attacks some types of rubber, plastics and coatings. Prior to use, user should confirm impermeability

SKIN/HAND PROTECTION : Safety glasses with side shields. Use full face-shield or chemical safety goggles when there is potential for contact. Contact lenses should not be worn when working with this material



8. EXPOSURE CONTROLS/PERSONAL PROTECTION Other Personal Protective Equipment:

:

Wear an impermeable apron and boots. Locate safety shower and eyewash station close to chemical handling area. Take all precautions to avoid personal contact. Clothing and footwear that is fire retardant and dissipates static electrical charges should be worn when handling flammable materials. Natural fibers (cotton, wool, leather and linen) should be selected in favour of synthetic materials (rayon, nylon and polyester).

9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE : Liquid

ODOR : Mild

pH : Not available

BOILING POINT C (F) : Not available

MELTING POINT C (F) : Not available

VAPOR PRESSURE -mmHg 20 C

: Not available

VAPOR DENSITY: : Not available

RELATIVE DENSITY, 15 C : 0.78-0.80

EVAPORATION RATE : Not available

Freezing Point, °C : <-76 FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING EPRESENTATIVE

10. STABILITY AND REACTIVITY CHEMICAL STABILITY : Stable under normal handling conditions

INCOMPATIBILITY (MATERIALS TO AVOID)

: Avoid contact in uncontrolled conditions with: strong oxidizing agents..

HAZARDOUS DECOMPOSITION PRODUCTS

: Thermal decomposition products are toxic and may include oxides of carbon and irritating gases.

HAZARDOUS POLYMERIZATION

: Product will not undergo hazardous polymerization

Conditions to Avoid : High temperatures, sparks, open flames and all other sources of ignition. Isopropanol can form unstable peroxides on prolonged exposure to air and heat.

Materials to Avoid : Strong oxidizers. Lewis or mineral acids. Aldehydes. Halogens. Halogenated compounds. Mixtures or reactions of alcohols with the following materials may cause explosions: barium perchlorate, chlorine, hypochlorous acid, ethylene oxide, hexamethylene diisocyanate and other isocyanates, nitrogen tetroxide, permonosulfuric acid and tri-isobutyl aluminum. At elevated temperatures: Aluminum and its alloys.

11. TOXICOLOGICAL DATA

ACUTE TOXICOLOGY

Oral LD 50 (RAT) : Greater than 5000 mg/kg

Dermal LD50 (RABBIT) : Greater than 2000 mg/kg

ROUTES OF ENTRY : Skin & eye contact, inhalation and ingestion



11. TOXICOLOGICAL DATA

Synergistic Materials

Alcohols may interact synergistically with chlorinated solvents (example - carbon tetrachloride, chloroform, bromotrichloromethane), dithiocarbamates (example - disulfiram), dimethylnitrosamine and thioacetamide.

REMARK

Minimally toxic by inhalation, based on test data for structurally similar materials. Negligible hazard of irritation by inhalation at ambient/normal handling temperatures, based on test data for structurally similar materials. Minimally toxic by ingestion, based on test data for structurally similar materials (LD50 >5000mg/kg). Minimally toxic by skin, based on test data for structurally similar materials (LD50 >3160 mg/kg). Irritating to the skin, based on test data for structurally similar materials. May cause shortlasting discomfort to the eyes, based on test data for structurally similar materials.

12. ECOLOGICAL INFORMATION Ecotoxicity : Solvent:

This material should not be released to sewage, draining systems or any body of water exceeding concentrations of approved limits under applicable regulations and permits Isopropanol: 96-hour LC50 (Pimephales promelas) = 9 640 - 10 400 mg/l 48-hour EC50 (Daphnia magna) = 7 550 - 13 299 mg/l No food chain concentration potential.

13. DISPOSAL CONSIDERATIONS Waste Disposal Methods : Dispose of waste material at an approved (hazardous) waste treatment/disposal

facility in accordance with applicable local, provincial and federal regulations. Do not dispose of waste with normal garbage, or to sewer systems. Reevaluation of the product may be required by the user at the time of disposal since the product uses, transformations, mixtures and processes may influence waste lassification

Disposal of Packaging : Empty containers retain product residue (liquid and/or vapour) and can be dangerous. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. Do not expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury or death. Do not dispose of package until thoroughly washed out

14. TRANSPORT INFORMATION DOT : Class 3, Flammable Liquid. The DOT Classification for shipping is dependant on

quantity, type of packaging or method of shipment.

TDG: : Class 3, Flammable Liquid. The DOT Classification for shipping is dependant on quantity, type of packaging or method of shipment




Solvent: TDG road / rail : Class 3: Flammable liquid with a flash point less than or equal to 60.5 C(140.9 F).

Closed cup test method. Canada WHMIS

: CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-2B: Material causing other toxic effects (TOXIC).

Isopropanol:

16. OTHER INFORMATION ********************************************************************** Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses, which infringe valid patents, or as extending license under valid patents. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Nemco assumes no responsibility for accuracy of information unless the document is the most current available from an official Nemco distribution system. Nemco neither represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any country except Canada. **********************************************************************



16. OTHER INFORMATION FOR FURTHER INFORMATION, CONTACT: Date of printing : October, 2013

Date of issue : October, 2013

Supplier : Nemco Resources Ltd

Address : 25 Midland Street Winnipeg, Manitoba R3E 3J6 CANADA

Telephone : 204-788-1030

Fax : 204-788-1593

NEMCO RESOURCES LTD. Page 1 of 13 SR-1 Antifreeze & Coolant Pure




PRODUCT NAME : SR-1 Antifreeze & Coolant Pure

PRODUCT CODE : 0696


25 Midland Street

Winnipeg, Manitoba

R3E 3J6 Canada

Date Issued : October, 2013


CANUTEC : 613-996-6666


EMERGENCY OVERVIEW

Slight odor.

May be fatal if swallowed.

Vapors can cause eye irritation.

Lowest Known LD50 (Oral) 107-21-1 >5000 mg/kg (Rats)

Lowest Known LD50 (Skin) 107-21-1 >8000 mg/kg (Rabbits)

HAZARD RATING SYSTEM

NFPA: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0

HMIS: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0

KEY: 0 – Minimal 1 – Slight 2 - Moderate 3 - Serious 4 - Severe

POTENTIAL ACUTE HEALTH EFFECTS

Inhalation : At room temperature, exposures to vapors are minimal due to physical properties; higher temperatures may generate vapor levels sufficient to cause adverse effects.

Ingestion : Single dose oral toxicity is considered to be moderate. Excessive exposure may cause central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney failure. Small amounts swallowed incidental to normal handling operations are not likely to cause injury; however, swallowing amounts larger than that may cause serious injury, even death



Eye : May cause slight transient (temporary) eye irritation. Corneal injury is unlikely. Vapors or mists may cause eye irritation.


Skin : Prolonged or repeated exposure not likely to cause significant skin irritation. A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. Repeated skin exposure may result in absorption of harmful amounts. Massive contact with damaged skin or of material sufficiently hot to burn skin may result in absorption of potential lethal amounts.

Systemic (Other Target Organ) Effects

: The signs and symptoms in ethylene glycol poisoning are those of metabolic acidosis, central nervous system depression and kidney injury. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. Treatment with ethanol to inhibit the metabolism of glycol to oxalate.Early administration of ethanol may counter the toxic effects of ethylene glycol (cardiopulmonary effects attributed to metabolic acidosis and renal damage). Hemodialysis or peritoneal dialysis have been of benefit. Pre-existing respiratory and skin disorders may be aggravated by over-exposure to this product. Treat symptomatically and supportively.

Cancer Information : Based on data from long-term animal studies, ethylene glycol is not believed to pose a carcinogenic risk to man.

Teratology (Birth Defects) : Exposure to ethylene glycol has caused birth defects in laboratory animals only at doses toxic to the mother.

Reproductive Effects : Ethylene glycol has not interfered with reproduction in animal studies except at very high doses.

CHRONIC, PROLONGED OR REPEATED OVEREXPOSURE

Effects of Repeated Overexposure

: Repeated inhalation of ethylene glycol mist may produce signs of central nervous system involvement, particularly dizziness and nystagmus.

Other Effects of Overexposure : repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less than 1% with the undiluted material.

3. COMPOSITION/INFORMATION ON INGREDIENTS Material CAS# % by Wt PEL (OSHA) TLV (ACGIH) Ethylene Glycol 107-21-1 >95 50 ppm 50 ppm


EYE CONTACT : Immediately flush eyes with large amounts of water for 15 minutes, lifting lower and upper lids. Get medical attention as soon as possible. Contact lenses should never be worn when working with this chemical.

SKIN CONTACT : Flush area of skin contact immediately with large amounts of water for at least 15 minutes while removing contaminated clothing. If irritation persists after flushing, get medical attention promptly. Wash clothing before re-use.

INHALATION : If inhaled, immediately remove victim to fresh air and call emergency medical care. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

INGESTION : Obtain medical attention immediately. If patient is fully conscious, give two glasses of water. Do not induce vomiting. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a few ounces), then give three to four ounces of hard liquor, such as whisky. For children, give proportionally less liquor, according to weight.



4. FIRST AID MEASURES Notes to physician : It is estimated that the lethal oral dose to adults is of the order of 1.0 ml/kg. Ethylene glycol is

metabolized by alcohol dehydrogenate to various metabolites including glyceraldehydes, glycolic acid and oxalic acid which cause an elevated anion-gap metabolic acidosis and renal tubular injury. The signs and symptoms in ethylene glycol poisoning are those of metabolic acidosis, CNS depression, and kidney injury. Urinalysis may show albuminuria, hematuria and oxaluria. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. The currently recommended medical management of ethylene glycol poisoning includes elimination of ethylene glycol and metabolites, correction of metabolic acidosis and prevention of kidney injury. It is essential to have immediate and follow up urinalysis and clinical chemistry. There should be particular emphasis on acid-base balance and renal function tests. A continuous infusion of 5% sodium bicarbonate with frequent monitoring of electrolytes and fluid balance is used to achieve correction of metabolic acidosis and forced diuresis. As a competitive substrate for alcohol dehydrogenase, ethanol is antidotal. Given in the early stages of intoxication, it blocks the formulation of nephrotoxic metabolites. A therapeutically effective blood concentration of ethanol is in the range 100-150 mg/dl, and should be achieved by a rapid loading dose and maintained by intravenous infusion. For severe and/or deteriorating cases, hemodialysis may be required. Dialysis should be considered for patients who are symptomatic, have severe metabolic acidosis, a blood ethylene glycol concentration greater than 25 md/dl, or compromise of renal functions. A more effective intravenous antidote for physician use is 4-methylpyrazole, a potent inhibitor of alcohol dehydrogenases, which effectively blocks the formation of toxic metabolites of ethylene glycol. It has been used to decrease the metabolic consequences of ethylene glycol poisoning before metabolic acidosis coma, seizures, and renal failure have occurred. A generally recommended protocol is a loading dose of 15 mg/kg followed by 10 mg/kg every 12 hours for 4 doses and then 15 mg/kg every 12 hours until ethylene glycol concentrations are below 20 mg/100 ml. Slow intravenous infusion is required. Since 4-methyplyrozole is dialyzable, increased dosage may be necessary during hemodialysis. Additional therapeutic measures may include the administration of cofactors involved in the metabolism of ethylene glycol. Thiamine (100 mg) and pyridoxine (50 mg) should be given every six hours. Pulmonary edema with hypoxemia has been described in a number of patients following poisoning with ethylene glycol. The mechanism of production has not been elucidated, but it appears to be non-cardiogenic in origin in several cases. Respiratory support with mechanical ventilation and positive end expiratory pressure may be required. There may be cranial nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In particular, effects have been reported involving the seventh, eighth and ninth cranial nerves, presenting with bilateral facial paralysis, diminished hearing and dysphasia..




Flammable Properties : Flash Point: None, since % of water is over 20. Autoignition Temperature: Autoignition temperature for 100% ethylene glycol is 398C (748F).

Flammability Limits : % of vapor concentration at which product can ignite in presence of spark. Lower Flammability Limit: Not determined Upper Flammability Limit: Not determined

Flammability limits are not determined on this product because the solution consists of 50% water. If and when the water evaporates and 100% glycol is left, the upper and lower flammability limits would be 3.2% and 15.3% (the same as concentrated Ethylene glycol).

HAZARDOUS PRODUCTS OF COMBUSTION

: Hazardous combustion products may include and are not limited to carbon monoxide, carbon dioxide and trace amounts of aldehydes and organic acids. When available oxygen is limited, as in a fire or when heated to very high temperatures by a hot wire or plate, carbon monoxide and other hazardous compounds such as aldehydes might be generated.

EXTINGUISH MEDIA : Water fog or fine spray. Alcohol resistant foams (ATC type) are preferred if available. General purpose synthetic foams (including AFFF) or protein foams may function, but much less effectively. Carbon dioxide. Dry chemical. Do not use direct water stream. May spread fire.

FIRE FIGHTING INSTRUCTIONS : No fire and explosion hazards expected under normal storage and handling conditions (i.e. ambient temperatures). However, ethylene glycol or solutions of ethylene glycol and water can form flammable vapors with air if heated sufficiently. Keep people away. Isolate fire area and deny unnecessary entry.

PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS

: Wear positive-pressure, self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire-fighting helmet, coat, pants, boots and gloves).


PROTECT PEOPLE : Material is moderately toxic when ingested. Take adequate precautions to keep people, especially children away from spill site. PVC-coated rubber gloves and monogoggles or face shield can be used during cleanup of spill site. Product on surfaces can cause slippery conditions. Practice reasonable care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at temperatures below -18oC (0oF). Do not store near food, foodstuffs, drugs or potable water supplies.

PROTECT ENVIRONMENT : Do not dump used product or diluted material into sewers, on the ground, or into any body of water. .

CLEANUP : Small spills: Soak up with absorbent material. Large spills: Dike and pump into suitable containers for disposal. Ensure compliance with all applicable statues that require notification of appropriate government officials



7. HANDLING AND STORAGE HANDLING : Put on appropriate personal protective equipment (see section 8). Eating,

drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

STORAGE : Keep container closed when not in use. Store away from heat or open flame. Product on surfaces can cause slippery conditions. Practice reasonable care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at temperatures below -37oC (-34oF). Do not store near food, foodstuffs, drugs or potable water supplies.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS : Use general or local exhaust ventilation to meet TLV requirements.

RESPIRATORY PROTECTION : Respiratory protection is required if airborne concentration exceeds TLV. At any detectable concentration any self-contained breathing apparatus with a full face piece and operated in a pressure-demand or other positive pressure mode or any supplied-air respirator with a full face piece and operated in a pressure-demand or other positive pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive pressure mode..

EYE PROTECTION : Safety goggles and face shield. Emergency eyewash should be available. Contact lenses should not be worn when working with this chemical.

SKIN PROTECTION : Protective gloves recommended when prolonged skin contact cannot be avoided. Polyethylene; Neoprene; Nitrile; Polyvinyl alcohol; Natural Rubber, Butyl Rubber. Safety shower should be available.

HAND PROTECTION : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. >8 hours (breakthrough time): nitrile rubber

EXPOSURE LIMITS Component Exposure Limits Skin Form Ethylene glycol 100 mg/m3 CEILING ACGIH Aerosol Ethylene glycol 125 mg/m3 CEILING OSHA-vacated 50 ppm CEILING OSHA – vacated 100 mg/m3 CEILING UCC Aerosol and Vapor Diethylene glycol 50 ppm TWA8 AIHA WEEL Aerosol and Vapor Diethylene glycol 10 mg/m3 TWA8 AIHA WEEL Aerosol In the Exposure Limits Chart above, if there is no specific qualifier (i.e., Aerosol) listed in the Form Column for a particular limit, the listed limit includes all airborne forms of the substance that can be inhaled. A “blank” in the Skin column indicates that exposure by the cutaneous (skin) route is not a potential significant contributor to overall exposure.



9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE : Clear viscous liquid

ODOR THRESHOLD-ppm : Odorless.

pH : 7.5-11

BOILING POINT C (F) : 107°C (226°F)

FREEDZING POINT C (F) : -37°C (-34°F)

FLASH POINT C (F) : Not Established

FLAMMABILITY : Not Established

WATER SOLUBILITY : Complete Soluble in water

VOC CONTENT : Not Established

VAPOR PRESSURE -mmHg 20 C

: <0.1

VAPOR DENSITY: : Not Established

EVAPORATION RATE : Nil

FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING EPRESENTATIVE

10. STABILITY AND REACTIVITY STABILITY (THERMAL, LIGHT, ETC.)

: Stable

CONDITION OF INSTABILITY : Keep away from flame

INCOMPATIBILITY (MATERIALS TO AVOID)

: Strong acid or oxidizing agents

HAZARDOUS DECOMPOSITION PRODUCTS

: Incomplete combustion may produce CO gas.

HAZARDOUS POLYMERIZATION

: Will not occur



11. TOXICOLOGICAL DATA Skin: The dermal LD50 has not been determined. Ingestion: The lethal dose in humans is estimated to be 100 ml (3 ozs.). The oral LD50 for rats is in the 6000-13,000-mg/kg range. Hydrated Inorganic Acid Sodium Salt: The lowest dose of a similar compound reported to produce death in humans was estimated to be 709 mg/kg body weight for a person weighing 150 pounds, this would be equivalent to swallowing about one-tenth (.1) of a pound of the dry material in a short period of time. Acute oral LD50s for a similar compound = 2,650 mg/kg (rats) 2,000 mg/kg (mice) Mutagenicity (The Effects on Genetic Material): In vitro mutagenicity studies were negative. Animal mutagenicity studies were negative. Significant Data with Possible Relevance to Humans: Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a preliminary study to asses the effects of exposure of pregnant rats and made to aerosis at concentrations of 150, 1000 and 25000 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol percutaneous absorption of ethylene glycol from contaminated skin, or swallowing ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal toxicity (1000 and 25000 mg/m3) and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity. The major route for producing developmental toxicity is perorally. Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence of carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. A chronic dietary feeding study of diethylene glycol with rats showed mild kidney injury at 1%, while concentrations of 2% and 4% caused more marked kidney injury. In addition, at 2% and 4% of diethylene glycol in the diet, some rats developed benign papillary tumors in the urinary bladder. These have been attributed to the presence of urinary bladder calcium oxalate stones. No evidence for carcinogenicity was found with a chronic skin-painting study with diethylene glycol in mice. The absence of a direct chemical carcinogenic effect addords with the results in vitro genotoxicity studies that show that it does not produce mutagenic or clastogenic effects. A feeding study employing up to 5.0% diethylene glycol in the diet failed to produce any teratogenic effects. In a mouse continuous breeding study with large doses of diethylene glycol in drinking water, there was evidence for reproductive toxicity at 3.5% (equivalent to 6.1 g/kg/day) as reduced number of litter, live pups per litter and live pup weight. No such effects were seen at 1.75% (approximately 3.05 g/kg/day). The relevance of these very high dosages to human health is uncertain. Pregnant rats receiving undiluted diethylene glycol by gavage over the period of organogenesis had toxic effects at 4.0 and 8.0 ml/kg/day as mortality, decreased body weight, decreased food consumption increased water consumption and increased liver and kidney weights. Fetotoxicity was seen only at these maternally toxic dosages. Decreased fetal body weight occurred at 8.0 ml/kg/day, and increased skeletal variants at 4.0 and 8.0 ml/kg/day. No embryotixic or teratogenic effects were seen. Neither maternal toxicity nor fetotoxicity occurred at 1.0 ml/kg/day. In a study with mice also receiving undiluted diethylene glycol over the period of organogenesis, maternal toxicity occurred at 2.5 and 10.0 ml/kg/day, but not at 0.5 ml/kg/day. Definitive developmental toxicity was not seen in this species. ACUTE TOXICITY Peroral: The lethal dose in humans is estimated to be 3 oz. or 100 ml. Rat: LD50 (6000 – 13000) mg/kg



Percutaneous: Rabbit: LD50 = >22270 mg/kg; 24 h occluded Inhalation: Rat: 8-hour exposure, substantially saturated vapor studies, dynamic generation method Mortality: 0/6 Inhalation: Mist/vapor study, rat, at 170C, 8-hour exposure = 2.2 mg/l Mortality: 0/6 Inhalation: Rat: 8-hour exposure, fog = 10000 ppm; 65 - 70C Mortality: 0/6 IRRITATION Skin: Rabbit: 24-hour occluded contact, 0.5 ml Results: Minor erythema and edema Skin: Human: Primary irritation patch test, 48-hour occluded, 0.2 ml Results: Evidence of irritation Eye: Rabbit: 0.1 ml Results: Minor transient iritis, conjunctival irritation with discharge REPEATED EXPOSURE In a 7-day dietary study with rats, a significant increase in kidney weights in females was observed at 5.0 gm/kg. The NOEL was 2.5 gm/kg. In a 24-month dietary study with rats, increased mortality in males was observed at the highest dose, 1.0 gm/kg/day. There were multiple signs: mineralization of several organs, including the cardiac vessels, cardiac muscle, vas deferens, stomach and pulmonary vessels; cellular hyperplasia of the parathyroids, hemosiderosis of the spleen, myocardial fibrosis, portal fibrosis of the liver, bile duct hyperplasia and hydronephrosis and oxylate nephrosis of the kidneys. Ethylene glycol was not oncogenic. In a 90-day dietary study with dogs, repeated exposures to 2.5 gm/kg resulted in acute renal failure and deaths. The NOAEL was 1.0 gm/kg. SENSITIZATION (ANIMAL AND HUMAN STUDIES) Repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less than 1% with the undiluted material. REPRODUCTIVE TOXICITY A three-generation study indicated that ethylene glycol did not affect reproductive parameters at dietary concentrations up to 1.0 gm/kg/day in any generation. CHRONIC TOXICITY AND CARCINOGENICITY Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in



tumor incidence or a different pattern of tumors compared with untreated controls. The absence of a carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. GENETIC TOXICOLOGY In Vitro: Ethylene glycol was devoid of genotoxic activity in an Ames test, forward gene mutation and sister chromatid exchange (SCE) studies in Chinese Hamster Ovary (CHO) cells and an in vitro cytogenetics study. In Vivo: Ethylene glycol by three different routes (intravenous, peroral and percutaneous) demonstrates apparent first-order pharmacokinetic behavior for the disposition in and the elimination from the plasma. Dose-dependent changes occur for the elimination of metabolites in the urine and as 14CO2 after single doses for the intravenous and peroral, but not the percutaneous route. The hypothesis from literature sources exists that developmental toxicity is caused by a metabolite of ethylene glycol, called glycolic acid, and not parent ethylene glycol. Under most conditions of ethylene glycol exposure, the glycolic acid metabolite is present in the blood in very low levels. However, it can become the major metabolite following large doses of ethylene glycol due to saturation of glycolic acid oxidation and/or elimination. When levels of this acidic metabolite exceed the capacity of maternal blood buffers to neutralize it, a maternal metabolic acidosis ensues, which has been hypothesized to be the true agent responsible for ethylene glycol induced developmental toxicity. Research suggests that ethylene glycol developmental toxicity is due to a dose-rate dependent toxicokinetic shift leading to glycolate accumulation and metabolic acidosis. ADDITIONAL STUDIES Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a preliminary study to assess the effects of exposure of pregnant rats and mice to aerosols at concentrations of 150, 1000 and 2500 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol, percutaneous absorption of ethylene glycol from contaminated skin, or swallowing of ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal toxicity (1000 and 2500 mg/m3) and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to the skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity.



12. ECOLOGICAL INFORMATION (Concentrated Ethylene Glycol)

13. DISPOSAL CONSIDERATIONS DO NOT discharge to sewer. Wear appropriate personal protection. Take up with sand, vermiculite, or similar inert material. Dispose in accordance with federal, state and local regulations.



14. TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION Non-Bulk Not regulated by the US D.O.T. (in quantities under 5,000 lbs in any one inner package) Bulk Proper Shipping Name: Environmentally Hazardous Substance, LIQUID N.O.S. (ETHYLENE GLYCOL) Technical Name: ETHYLENE GLYCOL ID Number: UN 3082 Hazard Class: 9 Packing Group: PG III Reportable Quantity: 5,000 lb. IATA Non-Bulk Not Regulated by IATA IMDG Non-Bulk Not regulated by IMDG (in quantities under 5,000 lbs in any one inner package)


THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS.

Chemical Name Cas Number Ethylene Glycol 107-21-1

United States - TSCA Inventory: Listed Water Standards: No data available Atmospheric Standards: Clean Air Act (1990) - List of Hazardous Air Contaminants: listed CERCLA: Reportable Quantity (RQ): 5,000 pounds (532 gallons) OSHA Hazard Communication Standard: This product is a “hazardous chemical” as defined by the OSHA

Hazard Communication Standard, 29 CFR 1910.1200.



15. REGULATORY INFORMATION SARA Title III: Section 311/312 - Categories: Acute hazard; chronic hazard

Section 312 - Inventory Reporting: Ethylene glycol is subject to Tier I and/or Tier II annual inventory reporting. Section 313 - Emission Reporting: Ethylene glycol is subject to Form R reporting requirements. Section 302 - Extremely Hazardous Substances: Ethylene glycol is not listed.

State Right-To-Know:

California - Exposure Limits - Ceilings: vapor-50 ppm ceiling; 125 mg/m3 ceiling Director's List of Hazardous Substances: listed Florida - Hazardous Substances List: listed Massachusetts - Right-to-Know List: listed Minnesota - Haz. Subs. List: listed (particulate and vapor) New Jersey - Right-to-Know List (Total): Present greater than 1.0% Pennsylvania Right-to-Know List: environmental hazard

Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required. WHMIS Information: D2A - material has potential toxic effects. Refer elsewhere in the MSDS for specific warnings and safe handling information. Refer to the employer's workplace education program. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986): The normal consumer use of this product does not result in exposure to chemicals known to the state of California to cause Cancer and/or reproductive harm above the significant risk level for carcinogens or the maximum allowable dose levels for reproductive toxins. Warnings are not required for consumer packaging. However, industrial or other occupational use of this product at higher frequency and using larger quantities of this product may result in exposures exceeding these levels and are labeled accordingly. California SCAQMD Rule 443.1 (South Coast Air Quality Management District Rule 443.1, Labeling of Materials Containing Organic Solvents): VOC: Vapor pressure 0.06 mmHg at 20°C 1113.38 g/l



16. OTHER INFORMATION ********************************************************************** Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses, which infringe valid patents, or as extending license under valid patents. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Nemco assumes no responsibility for accuracy of information unless the document is the most current available from an official Nemco distribution system. Nemco neither represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any country except Canada. ********************************************************************** FOR FURTHER INFORMATION, CONTACT: Date of printing : October, 2013

Date of issue : October, 2013



Telephone : 204-788-1030

Fax : 204-788-1593

NEMCO RESOURCES LTD. Page 1 of 6 Windshield Washer Fluid WWAF-40 & WWAF-35

Date of issue: August, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-966-6666



PRODUCT NAME : Windershield Washer Fluid WWAF-40&WWAF-35

PRODUCT CODE : 0800, 0790


25 Midland Street

Winnipeg, Manitoba

R3E 3J6 Canada

Date Issued : August, 2013


CANUTEC : 613-996-6666


NFPA HAZARD RATING

HEALTH 1

FLAMMABILITY 3

REACTIVITY 0

OTHER NOT APPLICABLE

OSHA

PERMISSIBLE EXPOSURE LIMIT* NIOSH REL

ACGIN THRESHOLD LIMIT

VALUE

IDLH

(NIOSH)

200 ppm (260 mg/m3 ) 8-Hour

TWA (Skin

200 ppm (260 mg/m3) 8-Hour

TWA 250 ppm (310

mg/m3) Ceiling (Skin)

200 ppm (260 mg/m3) 8-Hour TWA

250 ppm (310 mg/m3) Short-term Exposure

Limit (15-minute TWA) (Skin)

6,000 ppm (0.6 percent

in air)

* This MSDS contains the 1989 PEL’s and from the June 1993 Air Contaminants Final Rule, specified in Tables Z-1, Z-2, and Z-3 [Federal Register; 58(124):35338-35351; June 30, 1993].




Component CASRN Concentration*

WWAF -40

Methanol VARIOUS

45 min

Water 53 max

Inhibitor PROPRIETARY 2 max

WWAF -35

Methanol VARIOUS

42 min

Water 56 max

Inhibitor PROPRIETARY 2 max

*: By Vol%

4. FIRE FIGHTING MEASURES Flammable Limits : UEL - 36 percent for methanol LEL - 6 percent for methanol

Auto ignition Temperature : 878ºF for methanol

Extinguishing Media for Methanol:

Small Fires: Dry chemical, carbon dioxide, water spray or alcohol resistant foam. Large Fires: Water spray, fog or alcohol-resistant foam

Special Fire Fighting Procedures:

Move container away from fire area if you can do so without risk. Dike fire control water for later disposal; do not scatter the material. Apply cooling water to the sides of containers exposed to flames until well after the fire is out.

Unusual Fire and Explosion Hazards for Methanol

Flammable/combustible material; may be ignited by heat, spark or flame. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

5. REACTIVITY DATA Stability/Polymerization : In a closed container, methyl alcohol is stable at room emperature and it is stable

under routine handling and storage. Hazardous polymerization will not occur.

Incompatibility (Material to Avoid)

: Incompatible with beryllium dihydride; metals; oxidants; potassium tertbutoxide; carbon tetrachloride + metals; dichloromethane. Can react vigorously with oxidizing materials. Explosive reaction with chloroform + sodium methoxide; diethyl zinc. Violent reaction with alkyl aluminum salts; acetyle bromide; chloroform + sodium hydroxide; CrO3; cyanuric chloride; (I + ethanol + HgO); Pb(CIO4)2; HCIO4; P2O3; (KOH + CHCI2); nitric acid.1

Hazardous Decomposition or By-products

: When methanol is heated to decomposition, carbon dioxide and carbon monoxide may be produced, as well as formaldehyde may be produced, and it emits acrid smoke and irritating fumes

Note: This product does NOT contain any hazardous substances reportable under CERCLA.



6. HEALTH HARZARD DATA Routes of Entry (Methanol) : The primary routes of entry are inhalation, ingestion, and absorption

Health Hazards and Signs and Symptoms of Exposure (Methanol)

: Irritant to eyes, skin, and upper respiratory system. Headaches, drowsiness, dizziness, vertigo, light-headed, nausea, and vomiting. Visual disturbance, optic nerve damage, and blindness. Skin exposure hazard

Target Organs : Central nervous system, digestive tract, eyes, and skin

Acute Effects : Eye irritation. Inhalation can result nose irritation, headache, fatigue, nausea, visual impairment or complete and possible blindness, acidosis, convulsions, circulatory collapse, respiratory fatigue, and death. Ingestion can cause gastrointestinal (GI) irritation followed by the symptoms described for inhalation and possible kidney impairment. Skin contact results in a cold sensation, dryness, and cracking, possibly leading to dermatitis. Methyl alcohol may be absorbed through the skin and may cause headache, fatigue, and visual disturbances. Eye contact results in irritation with lacrimation, inflamed lids, and photophobia.

Chronic Effects : Chronic exposure may result in visual impairment or blindness

Medical Conditions Generally Aggravated by Exposure

: Ocular, respiratory, or dermal disorders may be aggravated by methanol exposure

Emergency and First Aid Procedures:

Eyes : Rinse with water 15 to 20 minutes, seek medical assistance

Skin : Flush with water for 15 minutes

Inhalation : Remove from source to fresh air, provide respiratory support as needed

Ingestion : Call Physician, hospital emergency room or Poison Control Center immediately

GET PROMPT MEDICAL ATTENTION

7. HANDLING AND STORAGE Steps to be Taken in Case Material is Released or Spilled

• Keep unnecessary people away; isolate hazard area and deny entry. • Stay upwind; keep out of low areas. • Shut off ignition sources; no flares, smoking or flames in hazard area. • Positive pressure self-contained breathing apparatus and chemical protective clothing is recommended for personnel involved in clean-up procedures with no fire. • Do not walk through spilled material; stop leak if it can be done without risk. • Water spray may reduce vapor; but it will not prevent ignition in closed spaces.

Waste Disposal Method : Dispose of in accordance with federal, state and local regulations. EPA Designations:

RCRA Hazardous Waste (40 CFR 261.33)

: Hazardous Waste No. U154

CERCLA Hazardous Substance (40 CFR 302.4)

: Not Listed

SARA Extremely Hazardous Substance (40 CFR 355)

: Not Listed




SARA Toxic Chemical (40 CFR 372.65)

: Not Listed

DOT Designation : Based on flash point and alcohol content, this is a Class 3, flammable liquid.

8. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION : Under normal use conditions (outdoor windshield cleaning),

respiratory protection is not justified.

EYE PROTECTION : Splash goggles are recommended when handling the solution. Contact lens use is not recommended.

PROTECTIVE CLOTHING : The selection of protective clothing and gloves is dependent upon anticipated exposure. As reported by the manufacturer, Best Glove style 725R (PVC) offers excellent protection for up to 240 minutes of complete immersion.

9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE : Liquid/Blue

pH : Not available

BOILING POINT °C : 64.6 at 760mmHg( Methanol)

MELTING POINT C (F) : Not available

FLASH POINT C (F) : Not available

FLAMMABILITY : Not established

OXIDIZING PROPERTIES : Not available

VAPOR PRESSURE -mmHg 21.2 C

: 100( Methanol)

VAPOR DENSITY: : 1.11( Methanol)

RELATIVE DENSITY, 15 C : Not available

SOLUBILITY IN WATER : SOLUBLE

EVAPORATION RATE : Not established

Pour Point, °C : Not available

FREEZING POINT °C : WWAF -40:-40, WWAF-35:-35

FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING EPRESENTATIVE



10. OTHER HAZARD INFORMATION AND DEFINITION OSHA PEL : The Occupational Safety and Health Administration’s Permissible Exposure

Limit, which is defined as the maximum concentration of contaminant to which a normal healthy individual may be exposed 8-hours per day, 40-hours per week, without experiencing adverse health effects over a working lifetime.

ACGIH TLV : American Conference of Governmental Industrial Hygienist’s Threshold Limit Value, similar to the OSHA PEL but not considered a legal standard.

11. TRANSPORT INFORMATION DOT HAZARDOUS DESCRIPTION

: Flammable liquid n.o.s. (methanol)

MSDS Prepared by : NEMCO RESOURCES LTD Judgements as to the suitability herein for the user’s

In Inner Packaging No More Than 5.0 L:

Proper Shipping Name: Consumer Commodity ORM-D Per 49 CFR Part 173.10 (PG III, inner packaging no more than 5.0L)

In Packaging Over 5.0 L: Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol) ID #: UN 1993 Class: 3 Hazard Label: Flammable Liquid PG: III

(IATA) International Air Dangerous Good Regulations: Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol) ID #: UN 1993 Class: 3 Hazard Label: Flammable Liquid PG: III Ltd. Qty. Packaging Instruction: Y309 (Max qty. per package 10L) Special Provision: A3



12. OTHER INFORMATION ********************************************************************** Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses, which infringe valid patents, or as extending license under valid patents. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Nemco assumes no responsibility for accuracy of information unless the document is the most current available from an official Nemco distribution system. Nemco neither represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any country except Canada. ********************************************************************** FOR FURTHER INFORMATION, CONTACT: Date of printing : August, 2013

Date of issue : August, 2013



Telephone : 204-788-1030

Fax : 204-788-1593


DIESEL FUEL 000003000395

Version 1.0 Revision Date 2015/05/14 Print Date 2015/05/14

Internet: www.petro-canada.ca/msds Page: 1 / 11 Petro-Canada is a Suncor Energy business. TM Trademark of Suncor Energy Inc. Used under licence.

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : DIESEL FUEL Synonyms : Seasonal Diesel, #1 Diesel, #2 Heating Oil, #1 Heating Oil,

D50, Arctic Diesel, Farm Diesel, Marine Diesel, Low Sulphur Diesel, LSD, Ultra Low Sulphur Diesel, ULSD, Mining Diesel, Naval Distillate, Dyed Diesel, Marked Diesel, Coloured Diesel, Furnace special, Biodiesel blend, B1, B2, B5, Diesel Low Cloud (LC). Marine Gas Oil

Product code : 101802, 100107, 100668, 100658, 100911, 100663, 100652,

100460, 100065, 101796, 101793, 101795, 101792, 101794, 101791, 100768, 100643, 100642, 100103, 101798, 101800, 101797, 101788, 101789, 101787, 102531, 100734, 100733, 100640, 100997, 100995, 100732, 100731, 100994

Manufacturer or supplier's details Petro-Canada P.O. Box 2844, 150 - 6th Avenue South-West

Calgary Alberta T2P 3E3 Canada Emergency telephone number

Suncor Energy: +1 403-296-3000; Poison Control Centre: Consult local telephone directory for emergency number(s).

Recommended use of the chemical and restrictions on use

Recommended use : Diesel fuels are distillate fuels suitable for use in high and medium speed internal combustion engines of the compression ignition type. Mining diesels, marine diesels, MDO and naval distillates may have a higher flash point requirement.

Prepared by : Product Safety: +1 905-804-4752

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview Appearance

Bright oily liquid.

Colour

Clear to yellow (This product may be dyed red for taxation purposes).

Odour

Mild petroleum oil like.

Hazard Summary

Combustible liquid. May cause cancer. Irritating to eyes and skin.





Potential Health Effects Primary Routes of Entry

: Eye contact Ingestion Inhalation Skin contact Skin Absorption

Target Organs

: Skin Eyes Respiratory Tract

Inhalation

: May cause respiratory tract irritation. Inhalation may cause central nervous system effects. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

Skin

: Causes skin irritation.

Eyes

: Causes eye irritation.

Ingestion

: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Aspiration hazard if swallowed - can enter lungs and cause damage.

Aggravated Medical Condition

: None known.

Carcinogenicity: IARC

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture

: Mixture

Hazardous components

Chemical Name CAS-No. Concentration (%)

kerosine (petroleum), hydrodesulfurized 64742-81-0 70 - 100 %

kerosine (petroleum) 8008-20-6

fuels, diesel 68334-30-5

fuel oil no. 2 68476-30-2

Alkanes, C10-20-branched and linear 928771-01-1 0 - 25 %

Soybean oil, Methyl ester 67784-80-9 0 - 5 %

Rape oil, Methyl ester 73891-99-3





Fatty acids, tallow, Methyl esters 61788-61-2

SECTION 4. FIRST AID MEASURES

If inhaled

: Move to fresh air. Artificial respiration and/or oxygen may be necessary. Seek medical advice.

In case of skin contact

: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash clothing before reuse. Seek medical advice.

In case of eye contact

: Remove contact lenses. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention.

If swallowed

: Rinse mouth with water. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Seek medical advice.

Most important symptoms and effects, both acute and delayed

: First aider needs to protect himself.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media

: Dry chemical Carbon dioxide (CO2) Water fog. Foam

Unsuitable extinguishing media

: Do NOT use water jet.

Specific hazards during firefighting

: Cool closed containers exposed to fire with water spray.

Hazardous combustion products

: Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur oxides (SOx), sulphur compounds (H2S), smoke and irritating vapours as products of incomplete combustion.

Further information : Prevent fire extinguishing water from contaminating surface water or the ground water system.

Special protective equipment : Wear self-contained breathing apparatus for firefighting if





for firefighters

necessary.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions.


: If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and materials for containment and cleaning up

: Prevent further leakage or spillage if safe to do so. Remove all sources of ignition. Soak up with inert absorbent material. Non-sparking tools should be used. Ensure adequate ventilation. Contact the proper local authorities.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling

: For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Use only with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Avoid contact with skin, eyes and clothing. Do not ingest. Keep away from heat and sources of ignition. Keep container closed when not in use.

Conditions for safe storage

: Store in original container. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in a dry, cool and well-ventilated place. Keep in properly labelled containers. To maintain product quality, do not store in heat or direct sunlight.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type (Form of exposure)

Control parameters / Permissible concentration

Basis

kerosine (petroleum), 64742-81-0 TWA 200 mg/m3 ACGIH





hydrodesulfurized (As total hydrocarbon vapour)

TWA 200 mg/m3 (As total hydrocarbon vapour)

ACGIH

TWA 200 mg/m3 (As total hydrocarbon vapour)

ACGIH

kerosine (petroleum) 8008-20-6 TWA 200 mg/m3 (As total hydrocarbon vapour)

CA BC OEL

Engineering measures : Use only in well-ventilated areas. Ensure that eyewash station and safety shower are proximal to the work-station location.

Personal protective equipment Respiratory protection

: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Filter type

: organic vapour cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstances where air-purifying respirators may not provide adequate protection.

Hand protection Material : neoprene, nitrile, polyvinyl alcohol (PVA), Viton(R). Consult

your PPE provider for breakthrough times and the specific glove that is best for you based on your use patterns. It should be realized that eventually any material regardless of their imperviousness, will get permeated by chemicals. Therefore, protective gloves should be regularly checked for wear and tear. At the first signs of hardening and cracks, they should be changed.

Remarks

: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Eye protection

: Wear face-shield and protective suit for abnormal processing problems.

Skin and body protection

: Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to





the specific work-place.

Protective measures

: Wash contaminated clothing before re-use.

Hygiene measures

: Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash face, hands and any exposed skin thoroughly after handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Bright oily liquid.

Colour : Clear to yellow (This product may be dyed red for taxation purposes).

Odour : Mild petroleum oil like.

Odour Threshold : No data available

pH : No data available

Pour point : No data available

Boiling point/boiling range : 150 - 371 °C (302 - 700 °F)

Flash point : > 40 °C (104 °F) Method: closed cup

Auto-Ignition Temperature : 225 °C (437 °F)

Evaporation rate : No data available

Flammability : Flammable in presence of open flames, sparks and heat. Vapours are heavier than air and may travel considerable distance to sources of ignition and flash back. This product can accumulate static charge and ignite.

Upper explosion limit : 6 %(V)

Lower explosion limit : 0.7 %(V)

Vapour pressure : 7.5 mmHg (20 °C / 68 °F)

Relative vapour density : 4.5

Relative density : 0.8 - 0.88

Solubility(ies)

Water solubility : insoluble

Partition coefficient: n-octanol/water

: No data available

Viscosity

Viscosity, kinematic : 1.3 - 4.1 cSt (40 °C / 104 °F)





Explosive properties : Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Runoff to sewer may create fire or explosion hazard.

SECTION 10. STABILITY AND REACTIVITY

Possibility of hazardous reactions

: Hazardous polymerisation does not occur. Stable under normal conditions.

Conditions to avoid

: Extremes of temperature and direct sunlight.

Incompatible materials

: Reactive with oxidising agents and acids.

Hazardous decomposition products

: May release COx, NOx, SOx, H2S, smoke and irritating vapours when heated to decomposition.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

: Eye contact Ingestion Inhalation Skin contact Skin Absorption

Acute toxicity

Product: Acute oral toxicity

: Remarks: No data available

Acute inhalation toxicity


Acute dermal toxicity


Components:

kerosine (petroleum), hydrodesulfurized: Acute oral toxicity : LD50 Rat: > 5,000 mg/kg,

Acute inhalation toxicity : LC50 Rat: > 5.2 mg/l Exposure time: 4 hrs Test atmosphere: dust/mist

Acute dermal toxicity : LD50 Rabbit: > 2,000 mg/kg,

kerosine (petroleum): Acute oral toxicity : LD50 Rat: > 5,000 mg/kg,

Acute inhalation toxicity : LC50 Rat: > 5 mg/l





Exposure time: 4 h Test atmosphere: dust/mist


fuels, diesel: Acute oral toxicity : LD50 Rat: 7,500 mg/kg,

Acute dermal toxicity : LD50 Mouse: 24,500 mg/kg,

fuel oil no. 2: Acute oral toxicity : LD50 Rat: 12,000 mg/kg,

Acute inhalation toxicity : LC50 Rat: 4.1 mg/l Exposure time: 4 h Test atmosphere: dust/mist

Skin corrosion/irritation

Product: Remarks: No data available

Serious eye damage/eye irritation

Product:

Remarks: No data available

Respiratory or skin sensitisation

No data available

Germ cell mutagenicity

No data available

Carcinogenicity

No data available

Reproductive toxicity

No data available

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Aspiration toxicity

No data available





SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Product: Toxicity to fish : Remarks: No data available

Toxicity to daphnia and other aquatic invertebrates


Toxicity to algae


Toxicity to bacteria


Persistence and degradability

Product: Biodegradability


Bioaccumulative potential No data available

Mobility in soil No data available

Other adverse effects No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Offer surplus and non-recyclable solutions to a licensed disposal company. Waste must be classified and labelled prior to recycling or disposal. Send to a licensed waste management company. Dispose of as hazardous waste in compliance with local and national regulations. Dispose of product residue in accordance with the instructions of the person responsible for waste disposal.

Contaminated packaging : Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

International Regulation

IATA-DGR

UN/ID No. : 1202





Proper shipping name : Diesel fuel

Class : 3

Packing group : III

Labels : 3

Packing instruction (cargo aircraft)

: 366

IMDG-Code

UN number : 1202

Proper shipping name : DIESEL FUEL

Class : 3

Packing group : III

Labels : 3

EmS Code : F-E, S-E

Marine pollutant : no

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable for product as supplied.

TDG UN number : 1202

Proper shipping name : DIESEL FUEL

Class : 3

Packing group : III

Labels : 3

ERG Code : 128


Special precautions for user

Not applicable

SECTION 15. REGULATORY INFORMATION

WHMIS Classification : B3: Combustible Liquid D2A: Very Toxic Material Causing Other Toxic Effects D2B: Toxic Material Causing Other Toxic Effects

This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR.

The components of this product are reported in the following inventories: DSL On the inventory, or in compliance with the inventory TSCA All chemical substances in this product are either listed on the

TSCA Inventory or are in compliance with a TSCA Inventory exemption.

EINECS On the inventory, or in compliance with the inventory

SECTION 16. OTHER INFORMATION


Canada-wide: telephone: 1-800-668-0220; fax: 1-800-837-





1228 For Product Safety Information: 1 905-804-4752

Prepared by : Product Safety: +1 905-804-4752 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.


GASOLINE, UNLEADED 000003000644




Product name : GASOLINE, UNLEADED Synonyms : Regular, Unleaded Gasoline (US Grade), Mid-Grade, Plus,

Super, WinterGas, SummerGas, Supreme, SuperClean, SuperClean WinterGas, RegularClean, PlusClean, Premium, marked or dyed gasoline, TQRUL, transitional quality regular unleaded, BOB, Blendstock for Oxygenate Blending, Conventional Gasoline, RUL, MUL, SUL, PUL.

Product code : 100126, 101823, 100507, 101811, 101814, 100141, 101813,

101810, 101812, 100063, 101822, 100138, 101821, 100064, 101820, 101819, 100506, 101818, 101816, 101817, 100488

Manufacturer or supplier's details Petro-Canada P.O. Box 2844, 150 - 6th Avenue South-West




Recommended use : Unleaded gasoline is used in spark ignition engines including motor vehicles, inboard and outboard boat engines, small engines such as chain saws and lawn mowers, and recreational vehicles.




Clear liquid.

Colour

Clear to slightly yellow or green, undyed liquid. May be dyed red for taxation purposes.

Odour

Gasoline

Hazard Summary

Flammable liquid Irritating to eyes and skin. May cause cancer. May cause heritable genetic damage.

Potential Health Effects Primary Routes of Entry : Eye contact





Ingestion Inhalation Skin contact

Target Organs

: Blood Immune system

Inhalation

: Inhalation may cause central nervous system effects. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

Skin

: May irritate skin.

Eyes

: May irritate eyes.

Ingestion

: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Aspiration hazard if swallowed - can enter lungs and cause damage.

Chronic Exposure

: Chronic exposure to benzene may result in increased risk of leukemia and other blood disorders.


: None known.


Group 1: Carcinogenic to humans

Benzene

71-43-2

ACGIH

Confirmed human carcinogen

Benzene

71-43-2

Confirmed animal carcinogen with unknown relevance to humans

Ethanol

64-17-5

Gasoline, natural

8006-61-9


Substance / Mixture

: Mixture







gasoline 86290-81-5 95 - 100 %

toluene 108-88-3 1 - 40 %

benzene 71-43-2 0.5 - 1.5 %

ethanol 64-17-5 0.1 - 0.3 %


If inhaled

: Artificial respiration and/or oxygen may be necessary. Move to fresh air. Seek medical advice.


: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash clothing before reuse. Seek medical advice.



If swallowed

: Rinse mouth with water. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Seek medical advice.





: Dry chemical Carbon dioxide (CO2) Water fog. Foam


: Do NOT use water jet.


: Cool closed containers exposed to fire with water spray.


: Carbon oxides (CO, CO2), nitrogen oxides (NOx), polynuclear aromatic hydrocarbons, phenols, aldehydes, ketones, smoke and irritating vapours as products of incomplete combustion.








: Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions.




: Prevent further leakage or spillage if safe to do so. Remove all sources of ignition. Soak up with inert absorbent material. Non-sparking tools should be used. Ensure adequate ventilation. Contact the proper local authorities.



: For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Use only with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Avoid contact with skin, eyes and clothing. Do not ingest. Keep away from heat and sources of ignition. Keep container closed when not in use.


: Store in original container. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in a dry, cool and well-ventilated place. Keep in properly labelled containers. To maintain product quality, do not store in heat or direct sunlight.





Basis





gasoline 86290-81-5 TWA 300 ppm CA AB OEL

STEL 500 ppm CA AB OEL

TWA 300 ppm CA BC OEL

STEL 500 ppm CA BC OEL

TWA 300 ppm ACGIH

STEL 500 ppm ACGIH

toluene 108-88-3 TWA 50 ppm 188 mg/m3

CA AB OEL


TWAEV 50 ppm 188 mg/m3

CA QC OEL

TWA 20 ppm ACGIH

benzene 71-43-2 TWA 0.5 ppm 1.6 mg/m3

CA AB OEL

STEL 2.5 ppm 8 mg/m3

CA AB OEL

TWA 0.5 ppm CA BC OEL

STEL 2.5 ppm CA BC OEL

TWA 0.5 ppm CA ON OEL

STEL 2.5 ppm CA ON OEL

TWAEV 1 ppm 3 mg/m3

CA QC OEL

STEV 5 ppm 15.5 mg/m3

CA QC OEL

TWA 0.5 ppm ACGIH

STEL 2.5 ppm ACGIH

ethanol 64-17-5 TWA 1,000 ppm 1,880 mg/m3

CA AB OEL

STEL 1,000 ppm CA BC OEL

TWAEV 1,000 ppm 1,880 mg/m3

CA QC OEL

STEL 1,000 ppm ACGIH

Biological occupational exposure limits Components CAS-No. Control

parameters Biological specimen

Sampling time

Permissible concentration

Basis

Toluene 108-88-3 Toluene In blood Prior to last shift of workweek

0.02 mg/l ACGIH BEI

Toluene Urine End of shift (As soon as possible after exposure ceases)

0.03 mg/l ACGIH BEI

Engineering measures : Use only in well-ventilated areas. Ensure that eyewash station and safety shower are proximal to the work-station location.






: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Filter type

: A NIOSH-approved air-purifying respirator with an organic vapour cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstances where air-purifying respirators may not provide adequate protection.

Hand protection Material : polyvinyl alcohol (PVA), Viton(R). Consult your PPE provider

for breakthrough times and the specific glove that is best for you based on your use patterns. It should be realized that eventually any material regardless of their imperviousness, will get permeated by chemicals. Therefore, protective gloves should be regularly checked for wear and tear. At the first signs of hardening and cracks, they should be changed.

Remarks


Eye protection



: Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place.

Protective measures

: Wash contaminated clothing before re-use.

Hygiene measures



Appearance : Clear liquid.

Colour : Clear to slightly yellow or green, undyed liquid. May be dyed red for taxation purposes.

Odour : Gasoline








Boiling point/boiling range : 25 - 225 °C (77 - 437 °F)

Flash point : -50 - -38 °C (-58 - -36 °F) Method: Tagliabue.



Flammability : Extremely flammable in presence of open flames, sparks, shocks, and heat. Vapours are heavier than air and may travel considerable distance to sources of ignition and flash back. Rapid escape of vapour may generate static charge causing ignition. May accumulate in confined spaces.

Upper explosion limit : 7.6 %(V)


Vapour pressure : < 802.5 mmHg (20 °C / 68 °F)

Relative vapour density : 3

Relative density : 0.685 - 0.8

Solubility(ies)

Water solubility : insoluble


: No data available

Viscosity

Explosive properties : Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Containers may explode in heat of fire. Vapours may form explosive mixtures with air.




Conditions to avoid

: Extremes of temperature and direct sunlight.


: Reactive with oxidising agents, acids and interhalogens.


: May release COx, NOx, phenols, polycyclic aromatic hydrocarbons, aldehydes, ketones, smoke and irritating vapours when heated to decomposition.







: Eye contact Ingestion Inhalation Skin contact

Acute toxicity







Components:

gasoline: Acute oral toxicity : LD50 Rat: 13,600 mg/kg,


toluene: Acute oral toxicity : LD50 Rat: 5,580 mg/kg,

Acute inhalation toxicity : LC50 Rat: 7585 ppm Exposure time: 4 h Test atmosphere: dust/mist

Acute dermal toxicity : LD50 Rabbit: 12,125 mg/kg,

benzene: Acute oral toxicity : LD50 Rat: 2,990 mg/kg,

Acute inhalation toxicity : LC50 Rat: 13700 ppm Exposure time: 4 h Test atmosphere: dust/mist


ethanol: Acute oral toxicity : LD50 Rat: 7,060 mg/kg,

Acute inhalation toxicity : LC50 Rat: > 32380 ppm Exposure time: 4 h Test atmosphere: vapour






Product: Remarks: No data available Components:

gasoline: Result: Moderate skin irritant

toluene: Result: Moderate skin irritant

benzene: Result: Moderate skin irritant

ethanol: Result: Skin irritation


Product:


Components:

gasoline: Result: Mild eye irritation

toluene: Result: Mild eye irritation

benzene: Result: Moderate eye irritation

ethanol: Result: Eye irritation


No data available


No data available

Carcinogenicity

No data available


No data available


No data available






No data available

Aspiration toxicity

No data available


Ecotoxicity




Toxicity to algae







Bioaccumulative potential No data available




Disposal methods


Contaminated packaging : Do not re-use empty containers.







IATA-DGR

UN/ID No. : 1203

Proper shipping name : Gasoline

Class : 3

Packing group : II

Labels : 3


: 364

IMDG-Code

UN number : 1203

Proper shipping name : GASOLINE

Class : 3

Packing group : II

Labels : 3

EmS Code : F-E, S-E





Proper shipping name : GASOLINE

Class : 3

Packing group : II

Labels : 3

ERG Code : 128



Not applicable


WHMIS Classification : B2: Flammable liquid D2A: Very Toxic Material Causing Other Toxic Effects D2B: Toxic Material Causing Other Toxic Effects











Canada-wide: telephone: 1-800-668-0220; fax: 1-800-837-1228 For Product Safety Information: 1 905-804-4752



PROPANE 000003000646




Product name : PROPANE Synonyms : Propane HD-5, Propane commercial, Liquified Petroleum

Gas (LPG), C3H8, CGSB Propane Grade 1, CGSB Propane Grade 2, odorized propane, stenched propane, automotive propane.

Product code : 100139 Manufacturer or supplier's details Petro-Canada P.O. Box 2844, 150 - 6th Avenue South-West




Recommended use : Propane is used as a fuel gas, refrigerant and as a raw material for organic synthesis. It is also used as a laboratory gas. The grade determines the propane content. It is supplied as pressurized liquid in tanks.




Gas at room temperature; liquid when stored under pressure.

Colour

colourless

Odour

Propane is an odourless gas. Odourized propane will contain up to 30 g Ethyl Mercaptan per 1000 L of propane.

Hazard Summary

Flammable gas High pressure gas.

Potential Health Effects Primary Routes of Entry

: Eye contact Inhalation Skin contact

Inhalation

: Inhalation may cause central nervous system effects. May cause respiratory tract irritation. Inhalation of vapours may cause drowsiness, headache,


PROPANE 000003000646



dizziness, and disorientation.

Skin

: Contact with rapidly expanding gas may cause burns or frostbite.

Eyes

: Contact with rapidly expanding gas may cause burns or frostbite.

Ingestion

: Exposure by this route unlikely.


: Overexposure may lead to cardiac sensitization.


No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.


Substance / Mixture

: Mixture



propane 74-98-6 90 - 100 %

propylene 115-07-1 1 - 5 %

butane 106-97-8 1 - 2.5 %

ethane 74-84-0 1 - 1.5 %

methane 74-82-8 0.1 - 0.2 %


If inhaled

: Move to fresh air. Artificial respiration and/or oxygen may be necessary. Seek medical advice.


: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash contaminated clothing before reuse. Seek medical advice.


PROPANE 000003000646





If swallowed

: Not a significant route of exposure.





: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.


: No information available.


: If the product release cannot be shut off safely, allow the product to burn itself out. Cool closed containers exposed to fire with water spray.


: Carbon oxides (CO, CO2), smoke and irritating vapours as products of incomplete combustion.


Special protective equipment for firefighters

: Wear self-contained breathing apparatus and full protective wear. Wear a positive-pressure supplied-air respirator with full facepiece.



: Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. In case of inadequate ventilation wear respiratory protection. Remove all sources of ignition.




: Prevent further leakage or spillage if safe to do so. Ensure adequate ventilation. Use explosion-proof ventilation equipment. Non-sparking tools should be used. Contact the proper local authorities.


PROPANE 000003000646





: For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin, eyes and clothing. Avoid breathing gas. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Use only with adequate ventilation. Keep away from heat and sources of ignition. Keep container closed when not in use. Do not use sparking tools. Do not enter areas where used or stored until adequately ventilated.


: Store in original container. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in a dry, cool and well-ventilated place. Keep in properly labelled containers. To maintain product quality, do not store in heat or direct sunlight. Keep away from sources of ignition - No smoking. Ensure the storage containers are grounded/bonded.





Basis

propane 74-98-6 TWA 1,000 ppm CA AB OEL

TWA 1,000 ppm CA BC OEL

TWAEV 1,000 ppm 1,800 mg/m3

CA QC OEL

propylene 115-07-1 TWA 500 ppm 860 mg/m3

CA AB OEL


TWA 500 ppm ACGIH

butane 106-97-8 TWA 1,000 ppm CA AB OEL


STEL 750 ppm CA BC OEL

TWAEV 800 ppm 1,900 mg/m3

CA QC OEL

ethane 74-84-0 TWA 1,000 ppm CA AB OEL

TWA 1,000 ppm CA BC OEL

Engineering measures : Use only in well-ventilated areas. Use explosion-proof ventilation equipment.


PROPANE 000003000646



Adequate ventilation to ensure that Occupational Exposure Limits are not exceeded.


: Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Filter type

: Always wear NIOSH-approved self-contained breathing apparatus when handling this material.

Hand protection Material : Wear insulated gloves to prevent frostbite. Remarks


Eye protection



: Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place.

Protective measures

: Wash contaminated clothing before re-use. Wear suitable protective equipment.

Hygiene measures



Appearance : Gas at room temperature; liquid when stored under pressure.

Colour : colourless

Odour : Propane is an odourless gas. Odourized propane will contain up to 30 g Ethyl Mercaptan per 1000 L of propane.




Boiling point/boiling range : -42 °C (-44 °F)

Flash point : -104 °C (-155 °F) Method: closed cup

Fire Point : No data available


PROPANE 000003000646





Flammability : Extremely flammable in presence of open flames, sparks, and heat. Vapours are heavier than air and may travel considerable distance to sources of ignition and flash back. Rapid escape of vapour may generate static charge causing ignition. May accumulate in confined spaces.

Upper explosion limit : 9.5 %(V)


Vapour pressure : 10,763 mmHg (38 °C / 100 °F)

Relative vapour density : 1.56

Relative density : No data available

Density : No data available

Solubility(ies)

Water solubility : No data available


: No data available

Viscosity

Viscosity, kinematic : No data available

Explosive properties : Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Containers may explode in heat of fire. Vapour explosion hazard indoors, outdoors or in sewers. Propane may form explosive mixtures with air.




Conditions to avoid

: Heat, flames and sparks.


: Reactive with oxidising agents and halogenated compounds.


: May release COx, smoke and irritating vapours when heated to decomposition.



: Eye contact Inhalation


PROPANE 000003000646



Skin contact

Acute toxicity







Components:

butane: Acute inhalation toxicity : LC50 Rat: 658 mg/l

Exposure time: 4 h Test atmosphere: gas


Product: Remarks: No data available


Product:



No data available


No data available

Carcinogenicity

No data available


No data available


No data available


No data available

Aspiration toxicity

No data available



PROPANE 000003000646



Ecotoxicity




Toxicity to algae







Bioaccumulative potential Components: butane : Partition coefficient: n-octanol/water

: log Pow: 2.89




Disposal methods




IATA-DGR

UN/ID No. : 1978

Proper shipping name : Propane

Class : 2.1


PROPANE 000003000646



Packing group : Not Assigned

Labels : 2.1


: 200

IMDG-Code

UN number : 1978

Proper shipping name : PROPANE

Class : 2.1


Labels : 2.1

EmS Code : F-D, S-U





Proper shipping name : PROPANE

Class : 2.1


Labels : 2.1

ERG Code : 115



Not applicable


WHMIS Classification : A: Compressed Gas B1: Flammable gas







Canada-wide: telephone: 1-800-668-0220; fax: 1-800-837-1228 For Product Safety Information: 1 905-804-4752


PROPANE 000003000646




Regular Unleaded Gasoline

Version 1.2

Effective Date 2015-01-04

Material Safety Data Sheet According to the Controlled Product Regulations

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1. MATERIAL AND COMPANY IDENTIFICATION

Material Name : Regular Unleaded Gasoline Uses : Fuel for spark ignition engines designed to run on unleaded

fuel. Product Code : 002D1972

Manufacturer/Supplier : Shell Canada Products

400 - 4th Avenue S.W Calgary AB T2P 0J4 Canada

Telephone : (+1) 8006611600 Fax : (+1) 4033848345

Emergency Telephone Number

: Shell Canada: (+1) 800-661-7378 CANUTEC (24 hr): (+1) 613-996-6666


Mixture Description : Complex mixture of hydrocarbons consisting of paraffins, cycloparaffins, aromatic and olefinic hydrocarbons with carbon numbers predominantly in the C4 to C12 range. Includes benzene at 1.5% v/v maximum. May also contain several additives at <0.1% v/v each.

WHMIS Controlled Ingredients Chemical Identity CAS No. Conc. W/W Gasoline, low boiling point naphtha 86290-81-5 90.00- 100.00 % Contains Benzene, CAS # 71-43-2. Contains Toluene, CAS # 108-88-3. Contains Ethylbenzene, CAS # 100-41-4. Contains n-Hexane, CAS # 110-54-3. Contains Xylene (Mixed Isomers), CAS # 1330-20-7. Contains Naphthalene, CAS # 91-20-3. Contains Cyclohexane, CAS# 110-82-7. Contains Tri-methyl-benzene (all isomers), CAS# 25551-13-7. Dyes and markers can be used to indicate tax status and prevent fraud. Refer to Chapter 8 for Occupational Exposure Guidelines.


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WHMIS Class/Description : Class B2 Flammable Liquid

Class D2A Other Toxic Effects - Carcinogen/Mutagen Class D2A Other Toxic Effects - Reproductive Toxicity Class D2B Other Toxic Effects - Skin Irritant Class D2B Other Toxic Effects - Narcotic effects.

Routes of Exposure : Exposure may occur via inhalation, ingestion, skin absorption, skin or eye contact, and accidental ingestion.

Health Hazards

: Vapours may cause drowsiness and dizziness. Slightly irritating to respiratory system. Irritating to skin. Moderately irritating to eyes. Harmful: may cause lung damage if swallowed. Possibility of organ or organ system damage from prolonged exposure; see Chapter 11 for details. Target organ(s): Blood-forming organs. Peripheral nervous system. May cause heritable genetic damage. Possible risk of harm to the unborn child. A component or components of this material may cause cancer. This product contains benzene which may cause leukaemia (AML - acute myelogenous leukaemia). May cause MDS (Myelodysplastic Syndrome).

Signs and Symptoms : Skin irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blisters. Eye irritation signs and symptoms may include a burning sensation and a temporary redness of the eye. If material enters lungs, signs and symptoms may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, and/or fever. The onset of respiratory symptoms may be delayed for several hours after exposure. Breathing of high vapour concentrations may cause central nervous system (CNS) depression resulting in dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness and death. Damage to blood-forming organs may be evidenced by: a) fatigue and anemia (RBC), b) decreased resistance to infection, and/or excessive bruising and bleeding (platelet effect). Peripheral nerve damage may be evidenced by impairment of motor function (incoordination, unsteady walk, or muscle weakness in the extremities, and/or loss of sensation in the arms and legs). Auditory system effects may include temporary hearing loss and/or ringing in the ears.

Safety Hazards : Extremely flammable. Electrostatic charges may be generated during handling. Electrostatic discharge may cause fire. Liquid evaporates quickly and can ignite leading to a flash fire, or an explosion in a confined space.


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Environmental Hazards : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Additional Information : This product is intended for use in closed systems only.


Inhalation : Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional treatment.

Skin Contact : Remove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment. When using high pressure equipment, injection of product under the skin can occur. If high pressure injuries occur, the casualty should be sent immediately to a hospital. Do not wait for symptoms to develop.

Eye Contact : Flush eyes with water while holding eyelids open. Rest eyes for 30 minutes. If redness, burning, blurred vision, or swelling persist transport to the nearest medical facility for additional treatment.

Ingestion : If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the nearest medical facility: fever greater than 101° F (38.3°C), shortness of breath, chest congestion or continued coughing or wheezing.

Advice to Physician : Treat symptomatically.


Clear fire area of all non-emergency personnel. Flash point : < -40 °C / -40 °F Upper / lower Flammability or Explosion limits

: 1 - 8 %(V)

Auto ignition temperature : Hazardous Combustion Products and Specific Hazards

: Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. The vapour is heavier than air, spreads along the ground and distant ignition is possible. Will float and can be reignited on surface water.

Suitable Extinguishing Media

: Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.

Unsuitable Extinguishing Media

: Do not use direct water jets on the burning product as they could cause a steam explosion and spread of the fire. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.


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Protective Equipment for Firefighters

: Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space.

Additional Advice : If the fire cannot be extinguished the only course of action is to evacuate immediately. Keep adjacent containers cool by spraying with water. If possible remove containers from the danger zone. Contain residual material at affected sites to prevent material from entering drains (sewers), ditches, and waterways.


Protective Measures : Vapour can travel for considerable distances both above and below the ground surface. Underground services (drains, pipelines, cable ducts) can provide preferential flow paths. Do not breathe fumes, vapour. Take measures to minimise the effects on groundwater. Contain residual material at affected sites to prevent material from entering drains (sewers), ditches, and waterways. Shut off leaks, if possible without personal risks. Remove all possible sources of ignition in the surrounding area. Use appropriate containment (of product and fire fighting water) to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Attempt to disperse the vapour or to direct its flow to a safe location for example by using fog sprays. Take precautionary measures against static discharge. Ensure electrical continuity by bonding and grounding (earthing) all equipment.

Clean Up Methods : For large liquid spills (> 1 drum), transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal. Do not flush away residues with water. Retain as contaminated waste. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely. For small liquid spills (< 1 drum), transfer by mechanical means to a labelled, sealable container for product recovery or safe disposal. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely.

Additional Advice : Notify authorities if any exposure to the general public or the environment occurs or is likely to occur. Local authorities should be advised if significant spillages cannot be contained. Maritime spillages should be dealt with using a Shipboard Oil Pollution Emergency Plan (SOPEP), as required by MARPOL Annex 1 Regulation 26.


General Precautions : Avoid breathing vapours or contact with material. Only use in well ventilated areas. Wash thoroughly after handling. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. Use the


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information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Air-dry contaminated clothing in a well-ventilated area before laundering. Contaminated leather articles including shoes cannot be decontaminated and should be destroyed to prevent reuse. Turn off all battery operated portable electronic devices (examples include: cellular phones, pagers and CD players) before operating gasoline pump. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Prevent spillages. For comprehensive advice on handling, product transfer, storage and tank cleaning refer to the product supplier. Do not use as a cleaning solvent or other non-motor fuel uses.

Vehicle fueling and vehicle workshop areas - Avoid inhalation of vapours and contact with skin, when filling or emptying a vehicle.

Handling : When using do not eat or drink. Extinguish any naked flames. Do not smoke. Remove ignition sources. Avoid sparks. Never siphon by mouth. The vapour is heavier than air, spreads along the ground and distant ignition is possible. Avoid exposure.

Storage : Drum and small container storage: Keep containers closed when not in use. Drums should be stacked to a maximum of 3 high. Use properly labelled and closeable containers. Packaged product must be kept tightly closed and stored in a diked (bunded) well-ventilated area, away from, ignition sources and other sources of heat. Take suitable precautions when opening sealed containers, as pressure can build up during storage. Tank storage: Tanks must be specifically designed for use with this product. Bulk storage tanks should be diked (bunded). Locate tanks away from heat and other sources of ignition. Cleaning, inspection and maintenance of storage tanks is a specialist operation, which requires the implementation of strict procedures and precautions.

Product Transfer : Electrostatic charges may be generated during pumping. Electrostatic discharge may cause fire. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<= 1 m/sec until fill pipe submerged to twice its diameter, then <= 7 m/sec). Avoid splash filling. Do NOT use compressed air for filling, discharging, or handling operations. Wait 2 minutes after tank filling (for tanks such as those on road tanker vehicles) before opening hatches or manholes. Wait 30 minutes after tank filling (for large storage tanks) before opening hatches or manholes.

Recommended Materials : For container and container linings, use mild steel or aluminium. Aluminium may also be used for applications where it does not present an unnecessary fire hazard. Examples of suitable materials are: high density polyethylene (HDPE), polypropylene (PP), and Viton (FKM), which have been specifically tested for compatibility with this product. For


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container linings, use amine-adduct cured epoxy paint. For seals and gaskets use: graphite, PTFE, Viton A, Viton B.

Unsuitable Materials : Some synthetic materials may be unsuitable for containers or container linings depending on the material specification and intended use. Examples of materials to avoid are: natural rubber (NR), nitrile rubber (NBR), ethylene propylene rubber (EPDM), polymethyl methacrylate (PMMA), polystyrene, polyvinyl chloride (PVC), polyisobutylene. However, some may be suitable for glove materials.

Container Advice : Do not cut, drill, grind, weld or perform similar operations on or near containers. Gasoline containers must not be used for storage of other products. Containers, even those that have been emptied, can contain explosive vapours.

Additional Information : Ensure that all local regulations regarding handling and storage facilities are followed.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this document, it is provided for information only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation Gasoline, low boiling point naphtha

ACGIH TWA 300 ppm

ACGIH STEL 500 ppm

Naphthalene ACGIH TWA 10 ppm

ACGIH STEL 15 ppm

ACGIH SKIN_DES Can be absorbed

through the skin.

Cyclohexane

ACGIH TWA 100 ppm

Xylene ACGIH TWA 100 ppm

ACGIH STEL 150 ppm

Toluene ACGIH TWA 20 ppm

Benzene

ACGIH TWA 0.5 ppm

ACGIH STEL 2.5 ppm


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through the skin.

SHELL IS TWA 0.5 ppm 1.6 mg/m3

SHELL IS STEL 2.5 ppm 8 mg/m3

n-hexane ACGIH TWA 50 ppm


through the skin.

Ethylbenzene ACGIH TWA 20 ppm

Trimethylbenzene, all isomers

ACGIH TWA 25 ppm

Consult local authorities for acceptable exposure limits within their jurisdiction. Additional Information : SHELL IS is the Shell Internal Standard. Skin notation means

that significant exposure can also occur by absorption of liquid through the skin and of vapour through the eyes or mucous membranes.

Biological Exposure Index (BEI) - See reference for full details

Material Determinant Sampling Time BEI Reference

Benzene S-

Phenylmercaptu

ric acid in

Creatinine in

urine

Sampling time: End of shift.

25 µg/g ACGIH BEL

(2011)

t,t-Muconic acid

in Creatinine in

urine


500 µg/g ACGIH BEL

(2011)

n-hexane 2,5-Hexanedion,

without

hydrolysis in

Urine

Sampling time: End of shift at end of work week.

0.4 mg/l ACGIH BEL

(2011)

Toluene toluene in Urine Sampling time: End of shift.

0.03 mg/l ACGIH BEL

(2011)


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toluene in Blood Sampling time: Prior to last shift of work week.

0.02 mg/l ACGIH BEL

(2011)

o-Cresol, with

hydrolysis in

Creatinine in

urine


0.3 mg/g ACGIH BEL

(2011)

Ethylbenzene Sum of mandelic

acid and

phenylglyoxylic

acid in

Creatinine in

urine


0.7 g/g ACGIH BEL

(2011)

Ethyl benzene in

End-exhaled air Sampling time: Not critical.

ACGIH BEL

(2011)

Xylene Methylhippuric

acids in

Creatinine in

urine


1.5 g/g ACGIH BEL

(2011)

Naphthalene 1-

Hydroxypyrene,

with hydrolysis

(1-HP) in Urine


ACGIH BEL

(2011)

Exposure Controls : The level of protection and types of controls necessary will vary

depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Use sealed systems as far as possible. Adequate explosion-proof ventilation to control airborne concentrations below the exposure guidelines/limits. Local exhaust ventilation is recommended. Eye washes and showers for emergency use.

Personal Protective Equipment

: Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers.

Respiratory Protection : If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Where air-filtering respirators are unsuitable (e.g. airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. All respiratory protection equipment and


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use must be in accordance with local regulations. Hand Protection : Personal hygiene is a key element of effective hand care.

Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Select gloves tested to a relevant standard (e.g. Europe EN374, US F739). When prolonged or frequent repeated contact occurs, Nitrile gloves may be suitable. (Breakthrough time of > 240 minutes.) For incidental contact/splash protection Neoprene, PVC gloves may be suitable.

Eye Protection : Chemical splash goggles (chemical monogoggles). Protective Clothing : Chemical resistant gloves/gauntlets, boots, and apron (where

risk of splashing). Monitoring Methods : Monitoring of the concentration of substances in the breathing

zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate.

Environmental Exposure Controls

: Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour.


Appearance : Colourless. Pale straw. Pale yellow. Liquid. Odour : Hydrocarbon. Odour threshold : < 0.25 ppm pH : Not applicable. Initial Boiling Point and Boiling Range

: 25 - 210 °C / 77 - 410 °F

Freezing Point

: Data not available

Vapour pressure : < 800 hPa at 37.8 °C / 100.0 °F Specific gravity : 0.74 Density : Typical 0.72 - 0.76 g/cm3 at 15 °C / 59 °F n-octanol/water partition coefficient (log Pow)

: 2 - 6

Kinematic viscosity : 0.5 - 0.75 mm2/s at 40 °C / 104 °F Vapour density (air=1) : 3.5 Evaporation rate (nBuAc=1) : Data not available


Stability : Stable under normal conditions of use. Conditions to Avoid : Avoid heat, sparks, open flames and other ignition sources. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products

: Hazardous decomposition products are not expected to form during normal storage. Thermal decomposition is highly


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dependent on conditions. A complex mixture of airborne solids, liquids and gases, including carbon monoxide, carbon dioxide and other organic compounds will be evolved when this material undergoes combustion or thermal or oxidative degradation.

Hazardous Polymerisation

: No

Sensitivity to Mechanical Impact

: No

Sensitivity to Static Discharge

: Yes


Basis for Assessment : Information given is based on product data, a knowledge of the components and the toxicology of similar products.


Acute Oral Toxicity : Low toxicity: LD50 >2000 mg/kg , Rat. Aspiration into the lungs when swallowed or vomited may

cause chemical pneumonitis which can be fatal. Acute Dermal Toxicity : Low toxicity: LD50 >2000 mg/kg , Rabbit. Acute Inhalation Toxicity : Low toxicity: LC50 >5 mg/l , 4.00 h , Rat. High concentrations may cause central nervous system

depression resulting in headaches, dizziness and nausea; continued inhalation may result in unconsciousness and/or death.

Skin Irritation : Irritating to skin. Eye Irritation : Expected to be slightly irritating. Respiratory Irritation : Based on human experience, breathing of vapours or mists

may cause a temporary burning sensation to nose, throat and lungs.

Sensitisation : Not expected to be a skin sensitiser. Repeated Dose Toxicity : Kidney: caused kidney effects in male rats which are not

considered relevant to humans Peripheral nervous system: repeated exposure causes

peripheral neuropathy in animals. (n-hexane) Mutagenicity : May cause heritable genetic damage. (Benzene) Mutagenicity

studies on gasoline and gasoline blending streams have shown predominantly negative results.

Carcinogenicity : Known human carcinogen. (Benzene) May cause leukaemia (AML - acute myelogenous leukemia). (Benzene) Inhalation exposure to mice causes liver tumours, which are not considered relevant to humans.

Reproductive and Developmental Toxicity

: Causes foetotoxicity at doses which are maternally toxic. (Toluene)

May impair fertility at doses which produce other toxic effects. (n-hexane)

Many case studies involving abuse during pregnancy indicate that toluene can cause birth defects, growth retardation and learning difficulties. (Toluene)


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Additional Information : Exposure to very high concentrations of similar materials has been associated with irregular heart rhythms and cardiac arrest. Prolonged and repeated exposures to high concentrations have resulted in hearing loss in rats. Solvent abuse and noise interaction in the work environment may cause hearing loss. Abuse of vapours has been associated with organ damage and death. May cause MDS (Myelodysplastic Syndrome).


Fuels are typically made from blending several refinery streams. Ecotoxicological studies have been carried out on a variety of hydrocarbon blends and streams but not those containing additives. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Acute Toxicity : Toxic:LL/EL/IL50 1-10 mg/l(to aquatic organisms)(LL/EL50

expressed as the nominal amount of product required to prepare aqueous test extract.)

Mobility : Floats on water. Contains volatile constituents. Evaporates

within a day from water or soil surfaces. Large volumes may penetrate soil and could contaminate groundwater.

Persistence/degradability : Major constituents are expected to be inherently biodegradable. The volatile constituents will oxidize rapidly by photochemical reactions in air.

Bioaccumulation : Contains constituents with the potential to bioaccumulate. Other Adverse Effects : Films formed on water may affect oxygen transfer and damage

organisms.


Material Disposal

: Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Waste arising from a spillage or tank cleaning should be disposed of in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand. Do not dispose into the environment, in drains or in water courses. Do not dispose of tank water bottoms by allowing them to drain into the ground. This will result in soil and groundwater contamination.

Container Disposal : Drain container thoroughly. After draining, vent in a safe place away from sparks and fire. Residues may cause an explosion hazard. Do not, puncture, cut, or weld uncleaned drums. Send to drum recoverer or metal reclaimer. Do not pollute the soil, water or environment with the waste container.


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Local Legislation

: Disposal should be in accordance with applicable regional, national, and local laws and regulations. Local regulations may be more stringent than regional or national requirements and must be complied with.

14. TRANSPORT INFORMATION

Canadian Road and Rail Shipping Classification UN/NA Number UN 1203 Proper shipping name GASOLINE Class Division 3 Packing group II Shipping Description GASOLINE, Class 3, UN 1203, PG II Additional Information Marine pollutant MARPOL Annex 1 rules apply for bulk shipments by sea.


The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Class/Description : Class B2 Flammable Liquid

Class D2A Other Toxic Effects - Carcinogen/Mutagen Class D2A Other Toxic Effects - Reproductive Toxicity Class D2B Other Toxic Effects - Skin Irritant Class D2B Other Toxic Effects - Narcotic effects.

Inventory Status DSL : All components

listed.


Additional Information : This document contains important information to ensure the safe storage, handling and use of this product. The information in this document should be brought to the attention of the person in your organisation responsible for advising on safety matters.

MSDS Version Number

: 1.2

MSDS Effective Date

: 2015-01-04

MSDS Revisions

: A vertical bar (|) in the left margin indicates an amendment from the previous version.

MSDS Regulation

: The content and format of this (M)SDS is in accordance with the Controlled Product Regulations.


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MSDS Prepared By : Shell Product Stewardship; 1-800-661-1600 Uses and Restrictions : This product must not be used in applications other than those

recommended in Section 1, without first seeking the advice of the supplier.This product is not to be used as a solvent or cleaning agent; for lighting or brightening fires; as a skin cleanser.This product is designed only to suit automotive applications and no provision is made for the requirements of aviation applications.

MSDS Distribution

: The information in this document should be made available to all who may handle the product.

Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product.

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1. MATERIAL AND COMPANY IDENTIFICATION

Material Name : Shell Thiopave Asphalt Mix Modifier

Manufacturer/Supplier : Shell Canada Products 400 - 4th Avenue S.W Calgary AB T2P 0J4 Canada

Telephone : (+1) 8006611600 Fax : (+1) 4033848345

Emergency Telephone Number

: Shell Canada: (+1) 800-661-7378 CANUTEC (24 hr): (+1) 613-996-6666


WHMIS Controlled Ingredients Chemical Identity CAS No. Conc. W/W Sulphur 7704-34-9 >= 90.00 % Carbon black 1333-86-4 1.00- 5.00 % Contains hydrogen sulphide, CAS # 7783-06-4. Refer to Chapter 8 for Occupational Exposure Guidelines.


WHMIS Class/Description : Class D2A Other Toxic Effects - Carcinogen Routes of Exposure : Exposure may occur via inhalation, ingestion, skin absorption,

skin or eye contact, and accidental ingestion. Health Hazards

: Hydrogen sulphide is highly toxic and may be fatal if inhaled. Hydrogen sulphide (H2S), an extremely flammable and toxic gas, and other hazardous vapours may evolve and collect in the headspace of storage tanks, transport vessels and other enclosed containers. May dull the sense of smell and has a high odour threshold, so do not rely on odour as an indication of hazard. Contact with hot material can cause thermal burns which may result in permanent skin damage. Hot product may cause severe eye burns and/or blindness.




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Signs and Symptoms : Skin irritation signs and symptoms may include a burning sensation, redness, or swelling. H2S has a broad range of effects dependent on the airborne concentration and length of exposure: 0.02 ppm odour threshold, smell of rotten eggs; 10 ppm eye and respiratory tract irritation; 100 ppm coughing, headache, dizziness, nausea, eye irritation, loss of sense of smell in minutes; 200 ppm potential for pulmonary oedema after >20-30 minutes; 500 ppm loss of consciousness after short exposures, potential for respiratory arrest; >1000ppm immediate loss of consciousness, may lead rapidly to death, prompt cardiopulmonary resuscitation may be required. Do not depend on sense of smell for warning. H2S causes rapid olfactory fatigue (deadens sense of smell). There is no evidence that H2S will accumulate in the body tissue after repeated exposure.

Safety Hazards : Not classified as flammable but will burn. Accumulation of dust can create an explosion hazard. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air-vapour mixtures can occur.


General Information : Vaporisation of H2S that has been trapped in clothing can be dangerous to rescuers. Maintain respiratory protection to avoid contamination from the victim to rescuer. Mechanical ventilation should be used to resuscitate if at all possible.

Inhalation : Remove to fresh air. Do not attempt to rescue the victim unless proper respiratory protection is worn. If the victim has difficulty breathing or tightness of the chest, is dizzy, vomiting, or unresponsive, give 100% oxygen with rescue breathing or CPR as required and transport to the nearest medical facility.

Skin Contact : Cold product - Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Hot product - If contact with hot product, immediately cool the burn area by flushing or immersing the affected area with water for at least 15 to 20 minutes. Do not attempt to remove anything from the burn area or apply burn creams or ointments. During transport do not cover the wound with dressing or sheet since these may adhere to the product.

Eye Contact : Cold product - Flush eye with copious quantities of water for at least 15 minutes. If persistent irritation occurs, obtain medical attention. Hot product - If contact with hot product, immediately cool the burn area by flushing or immersing the affected area with water for at least 15 to 20 minutes. Do not attempt to remove anything from the burn area or apply burn creams or ointments. During transport do not cover the wound with




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dressing or sheet since these may adhere to the product. Ingestion : In general no treatment is necessary unless large quantities

are swallowed, however, get medical advice. Advice to Physician : Hydrogen sulphide (H2S) - CNS asphyxiant. May cause

rhinitis, bronchitis and occasionally pulmonary oedema after severe exposure. CONSIDER: Oxygen therapy. Consult a Poison Control Center for guidance. Exposure to hydrogen sulphide at concentrations above the recommended occupational exposure standard may cause headache, dizziness, irritation of the eyes, upper respiratory tract, mouth and digestive tract, convulsions, respiratory paralysis, unconsciousness and even death. Call a doctor or poison control center for guidance.


Clear fire area of all non-emergency personnel. Flash point : > 160 °C / 320 °F (Cleveland Open Cup) Upper / lower Flammability or Explosion limits


Auto ignition temperature : Data not available Hazardous Combustion Products and Specific Hazards

: Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Oxides of sulphur. Hydrogen sulphide (H2S) and toxic sulphur oxides may be given off when this material is heated. Do not depend on sense of smell for warning. Accumulation of dust can create an explosion hazard.

Suitable Extinguishing Media

: Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.

Unsuitable Extinguishing Media

: Do not use water in a jet.

Protective Equipment for Firefighters

: Proper protective equipment including chemical resistant gloves are to be worn; chemical resistant suit is indicated if large contact with spilled product is expected. Self-Contained Breathing Apparatus must be worn when approaching a fire in a confined space. Select fire fighter's clothing approved to relevant Standards (e.g. Europe: EN469).


Protective Measures : Avoid contact with skin, eyes and clothing. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers.

Clean Up Methods : For solids, shovel into a suitable clearly marked container for disposal or reclamation in accordance with local regulations.

Additional Advice : Local authorities should be advised if significant spillages cannot be contained.




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General Precautions : Avoid contact with skin, eyes and clothing. Handling : Avoid prolonged or repeated contact with skin. Avoid

generation or accumulation of dusts as it can generate an explosion hazard Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Keep container tightly closed and in a cool, well-ventilated place. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air-vapour mixtures can occur. Be aware of handling operations that may give rise to additional hazards that result from the accumulation of static charges. These include but are not limited to pumping (especially turbulent flow), mixing, filtering, splash filling, cleaning and filling of tanks and containers, sampling, switch loading, gauging, vacuum truck operations, and mechanical movements. These activities may lead to static discharge e.g. spark formation. Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<= 1 m/s until fill pipe submerged to twice its diameter, then <= 7 m/s). Avoid splash filling. Do NOT use compressed air for filling, discharging, or handling operations.

Storage : Store separately from oxidising agents. Electrostatic charges will be generated during pumping. Electrostatic discharge may cause fire. Ensure electrical continuity by bonding and grounding (earthing) all equipment to reduce the risk. Refer to section 15 for any additional specific legislation covering the packaging and storage of this product.

Product Transfer : Keep containers closed when not in use. Even with proper grounding and bonding, this material can still accumulate an electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air-vapour mixtures can occur. Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<= 1 m/s until fill pipe submerged to twice its diameter, then <= 7 m/s). Avoid splash filling. Do NOT use compressed air for filling, discharging, or handling operations. Even when the product is not itself flammable, such vapours may be present as a result of operations involving a previously handled product, or faulty vapour recovery systems.

Recommended Materials : Synthetic or paper sacks. Container Advice : Containers, even those that have been emptied, can contain

explosive vapours. Additional Information : Hydrogen sulphide (H2S or Sour Gas) may be present when

loading and unloading transport vessels. Stay upwind and away from newly opened hatches and allow to vent thoroughly before handling material. Steam may be used to vent hatches. Keep all sources of ignition away from loading area.




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When combined with hydrocarbons at elevated temperature (above 140°C) hydrogen sulphide (H2S) is formed A specific assessment of the risk of dust explosion with mechanical handling and of the risk associated with H2S emissions at elevated temperatures should be carried out.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this document, it is provided for information only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation Carbon black ACGIH TWA(Inhala

ble fraction.)

3 mg/m3

Consult local authorities for acceptable exposure limits within their jurisdiction. Exposure Controls : The level of protection and types of controls necessary will vary

depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Eye washes and showers for emergency use. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or for subsequent recycle.

Personal Protective Equipment

: Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. The provided information is made in consideration of the PPE directive (Council Directive 89/686/EEC) and the CEN European Committee for Standardisation (CEN) standards.

Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If air-filtering respirators are suitable for conditions of




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use: Select a filter suitable for combined particulate/inorganic gases and vapours.

Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material.

Eye Protection : Dust-tight monogoggles Safety spectacles (safety glasses). Approved to EU Standard EN166.

Protective Clothing : Chemical resistant gloves/gauntlets, boots, and apron (where risk of splashing).

Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and samples analysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or contact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods http://www.cdc.gov/niosh/ Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods http://www.osha.gov/

Environmental Exposure Controls

: Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. Take appropriate measures to fulfil the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water.




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Appearance : Grey. Black. Granules. Odour : Slight. Odour threshold : Data not available pH : Data not available Initial Boiling Point and Boiling Range

: > 400 °C / 752 °F estimated value(s)

Freezing point : Data not available

Vapour pressure : Data not available Specific gravity : Data not available Density : Data not available Water solubility : Negligible. Solubility in other solvents : Data not available

n-octanol/water partition coefficient (log Pow)


Kinematic viscosity : Not applicable. Vapour density (air=1) : Data not available Electrical conductivity : Low conductivity: < 100 pS/m, The conductivity of this material

makes it a static accumulator., A liquid is typically considered nonconductive if its conductivity is below 100 pS/m and is considered semi-conductive if its conductivity is below 10 000 pS/m., Whether a liquid is nonconductive or semi-conductive, the precautions are the same., A number of factors, for example liquid temperature, presence of contaminants, and anti-static additives can greatly influence the conductivity of a liquid.

Evaporation rate (nBuAc=1) : Data not available


Stability : No hazardous reaction is expected when handled and stored according to provisions.

Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products

: Hazardous decomposition products are not expected to form during normal storage.

Hazardous Polymerisation


Sensitivity to Mechanical Impact

: Not applicable.

Sensitivity to Static Discharge

: Yes


Basis for Assessment : Information given is based on data on the components and the toxicology of similar products.

Unless indicated otherwise, the data presented is




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representative of the product as a whole, rather than for individual component(s).


Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat. Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat. Acute Inhalation Toxicity : Low toxicity by inhalation. (Sulphur) Fatal if inhaled. LC50 > 100 - <= 500 ppmV (Hydrogen

Sulphide) Skin Irritation : Causes skin irritation. Contact with hot material can cause

thermal burns which may result in permanent skin damage and/or blindness.

Eye Irritation : Expected to be non-irritating to eyes.Hot product may cause severe eye burns and/or blindness.

Respiratory Irritation : Not expected to be a respiratory irritant. Sensitisation : Not expected to be a sensitiser. Repeated Dose Toxicity : Not expected to be a hazard. Mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : An ingredient in this product has been classified as possibly

carcinogenic to humans. (Carbon black)

Material : Carcinogenicity Classification Sulphur : GHS / CLP: No carcinogenicity classification

Carbon black : ACGIH Group A3: Confirmed animal carcinogen with unknown relevance to humans.

Carbon black : IARC 2B: Possibly carcinogenic to humans.

Carbon black : GHS / CLP: No carcinogenicity classification

Reproductive and Developmental Toxicity

: Not expected to impair fertility. Not expected to be a developmental toxicant.

Additional Information : Classifications by other authorities under varying regulatory frameworks may exist.


Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Acute Toxicity : LL/EL50 expressed as the nominal amount of product required

to prepare aqueous test extract. Fish : Expected to be not toxic at limit of water solubility. Aquatic crustacea : Expected to be not toxic at limit of water solubility. Algae/aquatic plants : Expected to be not toxic at limit of water solubility.

Chronic Toxicity

Fish : Expected to be not toxic at limit of water solubility. Aquatic crustacea : Expected to be not toxic at limit of water solubility.




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Mobility : Adsorbs to soil and has low mobility. Sinks in water. Persistence/degradability : Not readily biodegradable. Bioaccumulation : Does not have the potential to bioaccumulate significantly.


Material Disposal

: Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses.

Container Disposal : Dispose in accordance with prevailing regulations, preferably to a recognised collector or contractor. The competence of the collector or contractor should be established beforehand.

Local Legislation

: Disposal should be in accordance with applicable regional, national, and local laws and regulations.

14. TRANSPORT INFORMATION

Canadian Road and Rail Shipping Classification This product is not regulated under the Canadian Transportation of Dangerous Goods Regulations for transport by road and rail.


The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Class/Description : Class D2A Other Toxic Effects - Carcinogen


SDS Version Number

: 1.1

SDS Effective Date

: 2013-07-10

SDS Revisions

: A vertical bar (|) in the left margin indicates an amendment from the previous version.

SDS Regulation

: The content and format of this (M)SDS is in accordance with the Controlled Product Regulations.

SDS Prepared By : Shell Product Stewardship; 1-800-661-1600 Uses and Restrictions : This product must not be used in applications other than those

recommended in Section 1, without first seeking the advice of the supplier.




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SDS Distribution

: The information in this document should be made available to all who may handle the product.

Disclaimer : The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of these data or the results to be obtained from the use of the product.

Section I: Product Identification and Uses

Common Trade Name: Elemental Sulphur 99.5%

Synonym: prilled sulphur

Chemical Family: Elemental sulphur

Reportable Quantity: None

Marine Pollutant: No

US and Canadian Shipments: None regulated as per schedule 2 section 33 (b) exemption for sulphur

International Shipments:

AIR(IATA): Exempted under special provision A 105 SEA (IMGD): Exempted as per sulphur observations part 1 & 2

Appearance: Specifically formed product in the shape of pastilles.

Section II: Hazardous Ingredients (Mixtures Only)

material components with chlorates, nitrates or other oxidizing agents may be explosive. Sulphur with alkalis or

alkaline earth.

Notice: the data and information presented herein are based upon tests, research and reports which are

considered by us to be reliable and accurate. The data and information is presented without warranty, guarantee

or liability on our part, and are presented to the customer for his/her own consideration, investigation and

verification.

Material Safety Data Sheet Elemental Sulphur 99.5%

Tiger-Sul Products (Canada) Co. Tiger-Sul Products, LLC

6444 -42 St. S.E. Post Office Box 5

Calgary, AB T2C 2V1 CANADA Atmore, AL 36502 USA

Telephone: (403) 279-2616 Telephone: (251) 368-2560

Fax: (403) 236-9049 Fax: (251) 368-4964

Tiger-Sul Products, LLC

65 Stork Rd

Stockton, CA, 95203

Telephone: (209) 943-0478

Fax: (209) 943-5470

Emergency Phone numbers:

For shipments coming from Calgary, AB, Canada or Stockton, CA, USA Call collect— 403-279-2616 (8am –4pm, Mon-Fri) or CANTEC 613-996-6666 (24 hours)

For Shipments coming from Atmore, AL, USA Call collect—251-368-2560 (8am– 4pm, Mon-Fri) or Chemtrec 800-424-9300 (24 hours)

Section III: Hazardous Ingredients

Name CAS No. Concentration

Sulphur 7704-34-9 99.5%

Update Nov/12

Page 1.

Section V. Fire and Explosion Data

This Product is: Not Combustible

Flash Points: Pure liquid S- 188°C (370°F), Impure liquid– 168°C, (335°F)

Flammable Limits: LEL 35 gm/m³

UEL 1400 gm/m³ (dust)

Auto-Ignition temperature: Dust clouds 190°C (374°F), Undispersed Dust 220°C, (428°F)

Flammable Limits in Air (% by VOL)

Minimum explosion concentration is approximately 35gm per cu. Meter

(0.035 oz per cu. ft.) Maximum

Explosive concentration lies between 1000-2000 (probably about 1400 gm/m³) (1.4 oz per cu ft)

Basic Firefighting Procedures: * Fire

Extinguishing Agents Recommendations 1. A fine water spray or fog is recommended

2. C02 or dry chemical

3. Small fires may be smothered with sand or soil sulphur

*Fire Extinguishing Agents to AVOID—Hoses and extinguishers with pressure streams should be avoided where

solid sulphur is dusty or where it may create a further hazard by raising more dust clouds

*Special Fire Fighting Precautions: because burning sulphur evolves sulphur dioxide, breather apparatus or gas

masks approved for use in acid-gas atmosphere should be used. Fumes from unprotected sulphur fires shall be

avoided, if possible, by approaching for the upwind side.

Fire degradation products: Combustion may produce sulphur dioxide

Flammability: Condition to avoid: Heat, sparks, open flame, static electricity or any other potential ignition source

should be avoided. Avoid contact with incompatible materials.

Unusual fire and explosion hazards: Dust suspended in air is readily ignited by flames, static electricity or friction

spark. Every reasonable step must be taken to minimize dust formation. Dust tight castings should be equipped with

explosion relief vents. Sparkles electrical equipment is recommended. Handling equipment must be grounded or bonded

to avoid static electricity. Keep away from source of flame or sparks. Detailed recommendations in Manufacturing

Chemists Association SD-74 and National Safety Council 612 Bulletins covering “Sulphur’ should be followed when handling elemental sulphur 99.5%

Section IV: Physical Data

Boiling Point: 444°C (832°F)

Melting Point: 119°C (246°F)

Vapor Density: >1

Solubility in Water (% by weight): Insoluble

Physical State and Appearance: Bright Yellow in colour. May have a slight sulphur odor. Pellet or pastille in shape.

Odor threshold: slight sulphur odor

Specific Gravity: solid, 2.07 gm/ml

Vapor Pressure (mm Hg at 20°C): Solid: Less than 0.0001 mm. Hg at 20°C (68° F)

Volatiles by Volume: N/A

Evaporation Rate (Butyl Acetate=) (Ether=): N/A

Page 2.

Section VIII: First Aid

Eye Contact: Irrigate thoroughly with copious quantities plain water

Skin Contact: Wash with mild soap and water

Ingestion: If swallowed, induce vomiting only if victim is conscious. DO NOT attempt to give anything by mouth to an

unconscious person.

Section IX: Precautionary Measures:

Respiratory Protection: Dust-type respirators shall be provided for dusty conditions. Breathing apparatus must be

available for emergency use in case of fire.

Eye & Face Protection: Dust-tight goggles with plastic or rubber frames may be helpful in dusty conditions.

Hands, Arms and Body Protection: Workers whose skin may be sensitive to sulphur dust should button collars, roll

sleeves down, and gather trousers at the ankle. Gloves may be helpful.

Other Clothing and Equipment: Hard hat and safety shoes. Fire-retardant fabrics is recommended. Sulphur

impregnated clothing should not be worn.

Storage: Solid becomes corrosive to metals when stored wet. Sulphur fertilizer will physically break down

when exposed to moisture or water.

Ventilation: Local exhaust if dusty conditions prevail

Normal Handling: Avoid breathing dust and keep clothing as free from dust as possible.

Spill or Leak: Shovel into disposal containers to cover with tarp. For landfill disposal, mix with limestone 3 times the

weight of sulphur

Special Precautions/Procedures/Label Instructions: Eye wash equipment near the work area.

Section VII: Health Hazard Information & technology of Components

Primary Routes of Entry: Inhalation: Sulphur dust may irritate the mucous membranes of the respiratory passage

Ingestions: Minimal toxicity, Irritating to mouth, throat and stomach. May cause digestive

tract disorder/damage.

Skin: Frequent or prolonged contact may irritate the skin. Low toxicity

Eyes: sulphur dust is capable of irritating the inner surfaces of the eyelids. Permissible Concentration: None Established

Toxicological Information: Unusual Chronic Toxicity: N/A

Page 3.

Section VI: Reactivity Information

Stability: Stable

Conditions to avoid: The main hazards are fire and dust explosions

Hazardous Polymerization: Will not occur

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