reu summer 2004
TRANSCRIPT
Designing and creating the ultimate x-
ray diffractometer
By Robert Morien under supervision of Prof. Paul Lyman
REU PROGRAM
SUMMER 2004
Outline
UWM’s x-ray machine
What is x-ray radiation and what is it used for
Types of x-ray diffractometers
Kappa reconfiguration
Diffraction pattern of Si
Pentacene used for OTFT’s
X-ray diffractometry is used for:
A non-destructive technique in analyzing semi-conductor
wafers and thin films for contamination and atomic
spacings
Determination of substrate and film coherence
Information concerning the stresses and strains
between lattice and film mismatches
Primary method for determining molecular structure of
proteins, particularly DNA which was determined by use
of x-ray diffraction
Analysis of crystalline phases present in any sample
How are x-ray photons developed?
X-rays are developed in an evacuated x-ray tube
The tube is made of two electrodes, the anode and the cathode
The cathode is usually constructed of a tungsten filament held at a high negative potential
The anode is held at ground potential
The cathode is heated producing thermionic emission
Electrons are accelerated towards the anode ejecting electrons of the anode material
The hole of the ejected electron is filled by an outer shell electron which creates x-ray radiation – the x-ray source
Energy and thus the wavelength of the x-ray beam is dependent upon material selected for the anode
Types of x-ray diffractometers
Picker 2 circle 2 axes of rotation
limited only to powder diffraction
Standard four circle with eularian cradle 4 axes of rotation
Can diffract powders or crystals
Kappa 4 axes of rotation
Allows better access to sample (no obstructing chi circle)
Addition of the fifth circle will allow an additional degree of
freedom to detect out-of-surface plane scattering vectors
Can use additional constraint to use grazing incidence
angles for surface diffraction
Diffraction pattern for Si powder I ran on the 4-
circle Eularian X-ray diffractometer during REU
x-ray diffraction pattern
0
200
400
600
800
0 20 40 60
two-theta
c.p.
s.
Detector
d1 @ 1.28° = 34.06Ǻ = d
d2 @ 14.1° = 3.16Ǻ = d111
d3 @ 17.95° = 2.5Ǻ = d012
d4 @ 23.6° = 1.92Ǻ = d022
a
dhkl =
aSi = 5.4305Ǻ
222 lkh
a
1.54λαk Ǻ
Pentacene is a promising molecule for growth on crystalline
substrates.
Currently we are growing pentacene crystals at UWM using
molecular beam epitaxy (MBE). Paul Lyman will take these crystals
with him as he leaves for Sabbatical at CERN to determine its
crystalline structure using synchrotron radiation