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Resume

Dr. Michael G. Richmond Professor of Chemistry University of North Texas Denton, TX 76203 Points of Contact: Cobalt@unt.edu; 940-565-3548 (office); 940-565-4318 (fax) Education: State University of New York, College at Fredonia, 1975-79 B.S. in Chemistry The University of Alabama, 1979-83 Ph.D. in Organic Chemistry Advisors: Profs. Charles U. Pittman, Jr. and David C. Baker Title of Doctoral Dissertation:

“Catalytic Studies Using Homogeneous and Heterogeneous Inorganic Catalysts and Synthesis of Potential Cancer Chemotherapeutic Agents”

Postdoctoral Study: Indiana University/The University of Houston, 1983-86 Advisor: Prof. Jay K. Kochi Professional Experience: Department Chair, Chemistry, The University of North Texas, 2007-09; 2015-2018. Professor of Chemistry, The University of North Texas, 1998-present. Associate Professor of Chemistry, The University of North Texas, 1992-98. Assistant Professor of Chemistry, The University of North Texas, 1986-92. Visiting Assistant Professor of Chemistry, The University of Houston, 1984-86.

Postdoctoral Fellow, Indiana University/The University of Houston, 1983-84.

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Awards and Honors:

Visiting Research Scientist, Lund University, 2014.

Member, Editorial Advisory Board, Universal Organic Chemistry, 2013-present. Certificate of Excellence in Reviewing, Elsevier Publishers, 2012. Member, Editorial Advisory Board, Journal of Thermodynamics and Catalysis, 2012-present.

Wenner-Gren Visiting Fellow, Lund University, 2012-2013. Grete and Philip Sandblom Visiting Professor, Lund University, 2011. Visiting Scholar, Department of Chemistry, Texas A&M University, 2009-2014.

Member, Editorial Advisory Board, Journal of Organometallic Chemistry, 2008-present.

Member, Editorial Advisory Board, Organometallics, 2008-2010.

Member, Editorial Advisory Board, The Open Inorganic Chemistry Journal, 2007-2010.

Honorary Full Professor of Chemistry, Hebei University, 1997. University of North Texas Developing Scholars Award, 1996-97. Author, “Annual Survey of Organometallic Metal Cluster Chemistry,” for Coord. Chem. Rev. 1994-2003. Author, “Annual Survey of Ruthenium and Osmium,” for J. Organomet. Chem. 1988-93.

Outstanding Undergraduate Research Award, 1979, S.U.N.Y. at Fredonia Consultant:

LAM Research Corporation, 2005-07; Air Liquide Electronics, 2004; Takasago International Corporation, 1996-98.

Professional Affiliations: American Chemical Society (Inorganic Division)

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Research Background and Interests:

My current research interests are broad and centered on the study of P-C bond cleavage reactivity in polynuclear organometallic compounds, fluxional properties of cluster coordinated ligands, OMCVD precursors for use in the manufacture of semiconductor and metallic thin films, carbon dioxide reduction, hydrocarbon activation, organometallic redox reactions, photocatalytic processes employing transition metal compounds, and structure and bonding relationships in organometallic carbonyl and nitrosyl compounds using NMR spin-lattice relaxation measurements (T1) and 17O Quadrupole Coupling Constants (QCC). Computational analysis of fundamental bond activation reactions are currently under investigation.

Publications: Richmond, Michael G. 1. “Photoinitiated Hydrosilations Catalyzed by Heterometallic Tetrahedral Clusters.

Evidence for Cluster Catalysis,” C.U. Pittman, Jr., M.G. Richmond, M. Absi-Halabi, H. Vahrenkamp, F. Richter, H. Beurich, Angew. Chem. Int. Ed. Engl. 1982, 21, 786.

2. “Metal Cluster Catalysis: Hydroformylation Using Mixed-Metal Tetrahedral Clusters,”

M.G. Richmond, M. Absi-Halabi, C.U. Pittman, Jr. J. Mol. Catal. 1984, 22, 367. 3. C.U. Pittman, Jr., M.G. Richmond, G.M. Wilemon, M. Absi-Halabi, In Catalysis of

Organic Reactions, J.R. Kosak, Ed.; Marcel Dekker: New York; Vol. 18, 1984, Chapter 5. Invited Monograph.

4. “Rhodium-Catalyzed Hydroformylation of Unsaturated Nitrogen Heterocycles:

Regioselectivity in the Synthesis of Tropane and Piperidine Carboxaldehydes,” D. Banach, G.O. Evans, II, D.G. McIntyre, T. Predmore, M.G. Richmond, R.P. Stewart, J.H. Supple, J. Mol. Catal. 1985, 31, 15.

5. “Ligand-Induced Scission of the Metal-Metal Bond in a Bicapped Tetracobalt Cluster,”

M.G. Richmond, J.D. Korp, J.K. Kochi, J. Chem. Soc., Chem. Commun. 1985, 1102. 6. “The Catalytic Activity of Platinum- and Palladium-Containing Low-Oxidation State

Butterfly and Triangular Clusters,” C.U. Pittman, Jr., W. Honnick, M. Absi-Halabi, M.G. Richmond, P. Braunstein, R. Bender, J. Mol. Catal. 1985, 32, 177.

7. “Oxidation-Reduction and Electrocatalytic Ligand Substitution of Tetracobalt Clusters,”

M.G. Richmond, J.K. Kochi, Inorg. Chem. 1986, 25, 656. 8. “Structures and Mechanism of Multiple Ligand Substitution in Bicapped Tetracobalt

Clusters,” M.G. Richmond, J.K. Kochi, Inorg. Chem. 1986, 25, 1334. 9. “Ligand Bridging and Chelation of Tetracobalt Clusters with Difunctional Phosphines,”

M.G. Richmond, J.K. Kochi, Organometallics 1987, 6, 254.

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Publications: Richmond, Michael G. 10. “Site Selectivity in Carbonyl Reduction of Mixed Fe2Co2 Clusters. Formyl Intermediates

in the Formation of Hydrido Derivatives,” M.G. Richmond, J.K. Kochi, J. Organomet. Chem. 1987, 323, 219.

11. “Ligand-Induced Scission of Polyhedral Clusters. Synthesis, Structures, and Reactivity

of Fluorodiphosphine-Substituted Bis(arylphosphido)-Capped Tetracobalt Carbonyl Clusters,” M.G. Richmond, J.K. Kochi, Inorg. Chem. 1987, 26, 541.

12. “Nucleophilic Additions to Carbonyl Ligands on Tetracobalt Clusters. Formation of

Polynuclear Formyl and Carbene Complexes,” M.G. Richmond, J.K. Kochi, Organometallics 1987, 6, 777.

13. “Ligand Stereochemistry in the Multiple Substitution of Bicapped Tetracobalt Clusters,”

M.G. Richmond, J.K. Kochi, Inorg. Chim. Acta 1987, 126, 83. 14. “Hydride Addition to Ru3(CO)12. Synthesis and Characterization of the Transient Formyl

Cluster Complex Ru3(CO)11(CHO)-,” J.A. Partin, M.G. Richmond, J. Organomet. Chem. 1988, 353, C13.

15. “Synthesis of the Transient Formyl Complex [CH3N(PF2)2]3Co2(CO)(CHO)- and

Observation of Facile Decomposition to Give the Mixed-Valence Complex [CH3N(PF2)2]3Co2(CO)2

-•,” D.S. Dumond, M.G. Richmond, J. Am. Chem. Soc. 1988, 110, 7547.

16. “Carbon-13 Relaxation and Reorientational Dynamics in a Bicapped Tetracobalt

Cluster,” M. Schwartz, M.G. Richmond, A.F.T. Chen, G.E. Martin, J.K. Kochi, Inorg. Chem. 1988, 27, 4698.

17. “Synthesis and Reactivity of the Polynuclear Formyl Cluster PhCCo3(CO)8(CHO)-.

Evidence for Facile Metalloformyl C-H Bond Scission,” D.S. Dumond, S. Hwang, M.G. Richmond, Inorg. Chim. Acta 1989, 160, 135.

18. “Photochemical and Photocatalytic Studies of Fluorophosphine-Bridged Iron and Cobalt

Dimers,” M.G. Richmond, C.U. Pittman, Jr., J. Mol. Catal. 1989, 53, 79. 19. “The Structure of Co4(CO)8(µ4-PPh)2[P(OEt)3]2. Further Evidence for Thermodynamic

Product Control in Ligand Substitution Reactions Involving Co4(CO)10(μ4-PPh)2,” M.J. Don, M.G. Richmond, W.H. Watson, A. Nagl, Acta Cryst. 1989, C45, 736.

20. “Reaction of Bis(dimethylphosphino)ethane with the Tetracobalt Cluster Co4(CO)10(µ4-

PPh)2. Synthesis, Structure, and Solution Dynamics of Co4(CO)8(μ4-PPh)2(dmpe),” C.L. Schulman, M.G. Richmond, W.H. Watson, A. Nagl, J. Organomet. Chem. 1989, 368, 367.

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Publications: Richmond, Michael G. 21. “Carbon-13 Relaxation and Phenyl Group Rotation in a Benzylidyne-Capped Tricobalt

Cluster,” S.P. Wang, A.F.T. Chen, M.G. Richmond, M. Schwartz, J. Organomet. Chem. 1989, 371, 81.

22. “1-Pentene Hydroformylation Using the Mixed-Metal Cluster Fe2Co2(CO)11(µ4-PPh)2.

Cylindrical Internal Reflectance Evidence for Cluster Catalysis,” M.G. Richmond, J. Mol. Catal. 1989, 54, 199.

23. “Reaction of Ph2PH with the Tetracobalt Cluster Co4(CO)10(µ4-PPh)2. Kinetic Studies of

Sequential CO Replacement and X-ray Structure of Co4(CO)8(μ4-PPh)2(Ph2PH)2,” M.J. Don, M.G. Richmond, W.H. Watson, A. Nagl, J. Organomet. Chem. 1989, 372, 417.

24. “Reduction Pathways in Lateral and Diagonal (η5-C5Me5)Re(CO)2Br2. Synthesis,

Structure, and Reactivity of (η5-C5Me5)Re(CO)2Br-,” C.M. Nunn, A.H. Cowley, S.W. Lee, M.G. Richmond, Inorg. Chem. 1990, 29, 2105.

25. “Synthesis and Redox Reactivity of the Thermally Unstable Mixed-Metal Arachno

Cluster Fe2(CO)6(μ3-S)2CuCp*,” M.J. Don, M.G. Richmond, Inorg. Chim. Acta 1990, 173, 61.

26. "Competitive CO Attack in Fe(CO)5 Using Methanolic Et4NOH. IR Spectral

Observation and Reactivity Studies of Fe(CO)4(CO2X)- (X = OH and OMe)," S.W. Lee, W.D. Tucker, M.G. Richmond, Inorg. Chem. 1990, 29, 3053.

27. "Site Selectivity and Competitive CO Attack in Co4(CO)10(μ4-PPh)2 Using Methanolic

Et4NOH. Spectral Observation and Reactivity Studies of Co4(CO)9(CO2X)(μ4-PPh)2- (X

= OH and OMe)," J.A. Partin, M.G. Richmond, J. Organomet. Chem. 1990, 396, 339. 28. "IR Evidence for Competitive Li+ and R3B Coordination to Fe(CO)4(CHO)- and

Thermodynamic Evaluation of the Ion Pair Equilibrium," S.W. Lee, W.D. Tucker, M.G. Richmond, J. Organomet. Chem. 1990, 398, C6.

29. "Degradation of the Metal-Cyano Complex Tetracyanonickelate (II) by Cyanide-

Utilizing Bacterial Isolates," T. Silva-Avalos, M.G. Richmond, O. Nagappan, D.A. Kunz, Appl. Environ. Microbiol. 1990, 56, 3664.

30. "Accumulation of Apolar Glycopeptidolipid Resulting from Cycloserine Inhibition of

Polar Glycopeptidolipids in Mycobacterium Avium," E.L. Wright, M.G. Richmond, W.W. Barrow, Infect. Immun. (Life Sci. Adv.) 1991, 9, 47.

31. "Reaction of PhCCo3(CO)9 with Bis(dimethylphosphino)ethane and Crystal Structure of

PhCCo3(CO)5(dmpe)2•(toluene). Observation of Phosphine Bridging and Chelation," M.J. Don, M.G. Richmond, W.H. Watson, R.P. Kashyap, Acta Cryst. 1991, C47, 20.

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Publications: Richmond, Michael G. 32. "Reaction of Co4(CO)10(μ4-PPh)2 with Tricyclohexylphosphine and Crystal Structure of

Co4(CO)9(μ4-PPh)2(PCy3)•(toluene). μ4-Phenylphosphinidene Rotation as a Consequence of Thermodynamic Product Control," M.J. Don, M.G. Richmond, W.H. Watson, A. Nagl, Acta Cryst. 1991, C47, 93.

33. "Barrier to Internal Rotation in a Heterometallic Tetrahedrane Cluster. NMR Evidence

for Metal Cluster-Aryl Orbital Overlap," P. Yuan, M.G. Richmond, M. Schwartz, Inorg. Chem. 1991, 30, 588.

34. "Reorientational Dynamics and the Barrier to Internal Rotation in Cp2Co3(μ2-

CO)(CO)3(μ3-CPh)," P. Yuan, M.G. Richmond, M. Schwartz, Inorg. Chem. 1991, 30, 679.

35. "Annual Survey of Ruthenium and Osmium for the Year 1988," M.G. Richmond, J.

Organomet. Chem. 1991, 404, 213. Invited Review. 36. "Nucleophilic Discrimination in a Mixed-Metal Phosphinidene-Capped Cluster.

Formation of Anionic Phosphido and Cobalt-Acyl Derivatives," M.J. Don, M.G. Richmond, Inorg. Chem. 1991, 30, 1703.

37. "Reaction of Hydride with (η5-C9H7)Re(CO)3. Facile Formation of [H6Re4(CO)12

2-] and Indenide," S.W. Lee, M.G. Richmond, Inorg. Chem. 1991, 30, 2237.

38. "13C NMR Study of a Co2Ni Tetrahedral Cluster. Preferential π-Orbital Overlap and

Reorientational Dynamics in Co2NiCp(CO)6(μ3-CPh)," P. Yuan, M.J. Don, M.G. Richmond, M. Schwartz, Inorg. Chem. 1991, 30, 3704.

39. "Bis(dimethylphosphino)ethane Substitution in PhCCo3(CO)9. Synthesis and X-ray

Structure of the Phosphine-Bridged Cluster PhCCo3(CO)7(dmpe)," M.J. Don, M.G. Richmond, W.H. Watson, M. Krawiec, R.P. Kashyap, J. Organomet. Chem. 1991, 418, 231.

40. C.U. Pittman, Jr., H. Hilal, M.J. Don, M.G. Richmond, In Catalysis of Organic Reactions,

W. Pascoe, Ed.; Marcel Dekker: New York; Vol. 47, 1992, Chapter 27. Invited Monograph.

41. "Relaxation Mechanisms, Bonding, and Molecular Reorientation in CpRe(CO)3," P.

Yuan, M.G. Richmond, M. Schwartz, J. Organomet. Chem. 1992, 424, 331. 42. "Modified Lymphocyte Response to Mitogens Induced by Lipopeptide fragment Derived

from Mycobacterium Avium Serovar-Specific Glycopeptidolipids," S.K. Tassell, M. Pourshaffe, E.L. Wright, M.G. Richmond, W.W. Barrow, Infect. Immun. 1992, 60, 706.

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Publications: Richmond, Michael G. 43. "In Situ Cluster Stability Studies Explored by Cylindrical Internal Reflectance (CIR)

Spectroscopy. 1-Pentene Hydroformylation Using Phosphine-Substituted Co4(CO)8P2(μ4-PPh)2 Clusters," M.J. Don, M.G. Richmond, J. Mol. Catal. 1992, 73, 181.

44. "13C NMR Study and Observation of Restricted Phenyl Rotation in the Alkyne Complex

Co2(CO)6(μ-PhC≡CH)," P. Yuan, M.-J. Don, M.G. Richmond, M. Schwartz, Inorg. Chem. 1992, 31, 3491.

45. "Annual Survey of Ruthenium and Osmium for the Year 1989," M.G. Richmond, J.

Organomet. Chem. 1992, 432, 215. Invited Review. 46. "NMR Evidence for the Existence of a π-Accepting PMe3 Ligand. Estimates of the

Magnitude of π Effects in WL(CO)5 Complexes," S.P. Wang, M.G. Richmond, M. Schwartz, J. Am. Chem. Soc. 1992, 114, 7595.

47. "1,1'-Bis(diphenylphosphino)ferrocene Ligand Substitution in the Benzylidyne-Capped

Cluster PhCCo3(CO)9. Synthesis, X-ray Structure, and Redox Properties of PhCCo3(CO)7(dppf)," W.H. Watson, A. Nagl, S. Hwang, M.G. Richmond, J. Organomet. Chem. 1993, 445, 163.

48. "Synthesis of the Thermally Unstable Arachno Cluster Fe2(CO)6(μ3-S)2Ni(1,5-COD),”

M.J. Don, M.G. Richmond, Inorg. Chim. Acta 1993, 210, 129. 49. "Bidentate Ligand Substitution in PhCCo3(CO)9. Synthesis, Molecular Structure, and

Redox Reactivity of PhCCo3(CO)7(cis-Ph2PCH=CHPPh2)," K. Yang, S.G. Bott, M.G. Richmond, J. Organomet. Chem. 1993, 454, 273.

50. "Tetrahedrane Cluster and Phosphorus Ligand Activation in the Reaction Between

PhCCo3(CO)9 and 2,3-Bis(diphenylphosphino)maleic Anhydride. Molecular Structure of Co3(CO)6(μ2,η2,η1-C(Ph)C=C(PPh2)C(O)OC(O))(μ2-PPh2)," K. Yang, J.M. Smith, S.G. Bott, M.G. Richmond, Inorg. Chim. Acta 1993, 212, 1. Invited Manuscript.

51. "Annual Survey of Ruthenium and Osmium for the Year 1990," M.G. Richmond, J.

Organomet. Chem. 1993, 457, 121. Invited Review. 52. "Phosphorus-Carbon Bond Cleavage and Tetrahedrane Cluster Activation in the Reaction

Between Bis(diphenylphosphino)maleic Anhydride (BMA) and PhCCo3(CO)9. Synthesis, Kinetic Studies, and X-ray Diffraction Structures of PhCCo3(CO)7(bma) and Co3(CO)6(μ2,η2,η1-C(Ph)C=C(PPh2)C(O)OC(O))(μ2-PPh2)," K. Yang, J.M. Smith, S.G. Bott, M.G. Richmond, Organometallics 1993, 12, 4779.

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Publications: Richmond, Michael G. 53. "Hydroformylation Catalysis Explored by Cylindrical Internal Reflectance Spectroscopy.

Spectroscopic Evidence for the Fragmentation of the Benzylidyne Cluster PhCCo3(CO)9," M.-J. Don, H.-Y. Chien, M.G. Richmond, J. Mol. Catal. 1994, 88, 133.

54. "Cylindrical Internal Reflectance (CIR) Evidence for the Facile Fragmentation of

PhCCo3(CO)7(cis-Ph2PCH=CHPPh2) During the Hydroformylation of 1-Pentene," K. Yang, H.-Y. Chien, M.G. Richmond, J. Mol. Catal. 1994, 88, 159.

55. "Intramolecular Phosphine Attack on a Coordinated Alkyne Ligand in Co2(CO)4(μ-

PhC≡CH)(bma). Characterization of the Zwitterionic Hydrocarbyl Complex Co2(CO)4[μ-η2,η2,η1,-PhC=C(H)PPh2C=C(PPh2)C(O)OC(O)],” K. Yang, S.G. Bott, M.G. Richmond, Organometallics 1994, 13, 3767.

56. “Reversible Chelate-to-Bridge Ligand Exchange in Co2(CO)4(μ-PhC≡CPh)(bma) and

Alkyne-Diphosphine Ligand Coupling. Synthesis, Reactivity, and Molecular Structures of Co2(CO)4(μ-PhC≡CH)(bma), Co2(CO)4(μ-PhC≡CH){(Z)- Ph2PCH=CHPPh2}, and Co2(CO)4{μ-η2,η2,η1,η1-(Z)-Ph2PC(Ph)=(Ph)C- C=C(PPh2)C(O)OC(O)},” K. Yang, S.G. Bott, M.G. Richmond, Organometallics 1994, 13, 3788.

57. "Annual Survey of Ruthenium and Osmium for the Year 1991," M.G. Richmond, J.

Organomet. Chem. 1994, 477, 173. Invited Review. 58. "Annual Survey of Ruthenium and Osmium for the Year 1992," M.G. Richmond, J.

Organomet. Chem. 1994, 477, 219. Invited Review. 59. “Synthesis, Molecular Structure, and Electrochemical Investigation of the 1,2,5-

Thiadiazole-3,4-dithiolate-Substituted Complex Cp*Ru(NO)(tdas). Evidence for Nitrosyl Bending During Reduction,” C.-G. Xia, S.G. Bott, M.G. Richmond, Inorg. Chim. Acta 1994, 226, 267. Invited Review.

60. “Synthesis, X-ray Structure, and Redox Properties of Cp*Ru(NO)(mnt),” K. Yang, S.G.

Bott, M.G. Richmond, J. Organomet. Chem. 1994, 483, 7. 61. “Hydride Reduction of diag-(η5-C5H5)Re(CO)2Br2: Ring Attack vs. Metal-Halogen

Exchange,” S.-W. Lee, M.G. Richmond, Bull. Korean Chem. Soc. 1994, 15, 1013. 62. “CO Substitution and Diphosphine Ligand Chelation in the Reaction Between 4,5-

Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (BPCD) and Re2(CO)8(μ-H)(μ,η1,η2-C≡CPh),” C.-G. Xia, S.G. Bott, M.G. Richmond, Inorg. Chim. Acta 1995, 230, 45.

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Publications: Richmond, Michael G. 63. “One-Pot Synthesis of CpRe(CO)2H2 and trans-CpRe(CO)2(SnPh3)2 from cis- and trans-

CpRe(CO)2Br2 and Ph3SnH. Involvement of a Radical-Chain Sequence in the Formation of CpRe(CO)2H2,” S.-W. Lee, K. Yang, J.A. Martin, S.G. Bott, M.G. Richmond, Inorg. Chim. Acta 1995, 232, 57.

64. "Annual Survey of Ruthenium and Osmium for the Year 1993," M.G. Richmond, Coord.

Chem. Rev. 1995, 141, 63. Invited Review. 65. “Polyhedral Cluster Expansion in Co3(CO)6[μ2-η2,η1- C(Ph)C=C(PPh2)C(O)OC(O)](μ2-PPh2). Characterization of the Hypho Cluster

Co3(CO)5(μ-CO)(PMe3)[μ2-η2,η1-C(Ph)C=C(PPh2)C(O)OC(O)](μ2-PPh2) and the Phosphine-Substituted Arachno Cluster Co3(CO)5(PMe3)[μ2-η2,η1- C(Ph)C=C(PPh2)C(O)OC(O)](μ2-PPh2),” K. Yang, S.G. Bott, M.G. Richmond, Organometallics 1995, 14, 919.

66. “Synthesis, Redox Reactivity, and X-Ray Diffraction Structures of the Rhenium

Carbonyl Complexes fac-ReBr(CO)3(bma) and [fac-ReBr(CO)3(bma)][Cp2Co]. Structural Consequences of Electron Accession in fac-ReBr(CO)3(bma),” K. Yang, S.G. Bott, M.G. Richmond, Organometallics 1995, 14, 2387.

67. “Directional Effects of CO π Bonding in Group 6 Pentacarbonyl Amines,” K.S. Wang, D.

Wang, K. Yang, M.G. Richmond, M. Schwartz, Inorg. Chem. 1995, 34, 3241. 68. “μ2-η2,η1-Benzylidene(diphenylphosphino)maleic Anhydride-Mediated PMe3 Addition to

the Tricobalt Cluster Co3(CO)6[μ2-η2,η1-C(Ph)C=C(PPh2)C(O)OC(O)](μ2-PPh2). Structure and Redox Properties of the Arachno Cluster Co3(CO)4(PMe3)2[μ2-η2,η1-C(Ph)C=C(PPh2)C(O)OC(O)](μ2-PPh2),” K. Yang, S.G. Bott, M.G. Richmond, Organometallics 1995, 14, 2718.

69. “X-Ray Diffraction Structure of the 1,1'-Bis(diphenylphosphino)ferrocene (dppf)-Bridged

Complex [(dppf)AgCl]2. An Unexpected Product From the Reaction Between cis-(bpy)2RuCl2 and dppf in the Presence of AgBF4,” K. Yang, S. Bott, M.G. Richmond, J. Chem. Crystallogr. 1995, 25, 263.

70. “Synthesis and Reactivity Investigation on Iridium Maleonitriledithiolate Complexes.

Redox Studies and Extended Hückel Molecular Orbital Calculations on Cp*IrL(mnt) (where L = PMe3, PPh3, CN-t-Bu),” K. Yang, M.-J. Don, D.K. Sharma, S.G. Bott, M.G. Richmond, J. Organomet. Chem. 1995, 495, 61.

71. “13C NMR Study of Reorientational Dynamics in Ru3(CO)9(μ3-CO)(μ3-NPh). Relaxation

Time Analysis in the Non-Motional Narrowing Regime,” D. Wang, H. Shen, M.G. Richmond, M. Schwartz, Inorg. Chim. Acta 1995, 236, 1.

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Publications: Richmond, Michael G. 72. “Synthesis, Extended Hückel Molecular Orbital Calculations, and X-Ray Diffraction

Structure of the Pentamethylcyclopendienylruthenium Complex Cp*Ru(NO)(2,3-quinoxalinediolate),” K. Yang, S.G. Bott, M.G. Richmond, J. Chem. Crystallogr. 1995, 25, 283.

73. “Carbonyl Fluxionality in the Nido Cluster Ru3(CO)9(μ3-CO)(μ3-NPh). NMR Evidence

and Mechanism for the Exchange of the Triply-Bridging CO with the Terminal CO Groups,” D. Wang, H. Shen, M.G. Richmond, M. Schwartz, Organometallics 1995, 14, 3636.

74. “Synthesis of the Pentamethylcyclopentadienylruthenium Thiolate Complex

Cp*Ru(NO)(dmit). Electrochemical Properties and Extended Hückel Molecular Orbital Calculations,” H. Shen, R.A. Senter, S.G. Bott, M.G. Richmond, Inorg. Chim. Acta 1995, 238, 57.

75. “Ruthenium-TPPTS Catalyzed Reduction of Nitrobenzene to Aniline. A Highly

Selective Water-Soluble Catalyst System,” C.-G. Xia, M.G. Richmond, J. Natur. Gas Chem. 1995, 4, 393.

76. “Diastereoselectivity and Regioselectivity in the Intramolecular Phosphine Attack on a

Coordinated Alkyne Ligand in Co2(CO)4(bmf)(μ-PhC≡CH). Formation of the Chiral Hydrocarbyl Complex Co2(CO)4[μ-η2,η2,η1,η1- PhC=C(H)PPh2C=C(PPh2)C(O)OCH(OMe)],” K. Yang, S.G. Bott, M.G. Richmond, Organometallics 1995, 14, 4977.

77. “Photochemically Activated Phosphorus-Carbon Bond Cleavage in the Binuclear

Ruthenium Complex Ru2(CO)6(bpcd). Redox Reactivity, Molecular Orbital Properties, and X-ray Diffraction Structures of Ru2(CO)6(bpcd) and Ru2(CO)6[μ-C=C(PPh2)C(O)CH2C(O)](μ2-PPh2),” H. Shen, S.G. Bott, M.G. Richmond, Organometallics 1995, 14, 4625.

78. “Ligand Substitution of the Redox-Active Diphosphine 4,5-Bis(diphenylphosphino)-4-

cyclopenten-1,3-dione (bpcd) in the Alkynyl-Bridged Cluster Ru3(CO)9(μ2-H)(μ3-η2-C≡CBut). Synthesis, X-Ray Structure, and Electrochemical Properties of Ru3(CO)7(μ2-H)(μ3-η2-C≡CBut)(bpcd),” H. Shen, T. J. Williams, S. G. Bott, M.G. Richmond, J. Organomet. Chem. 1995, 505, 1.

79. “Materials for Electrochemical Energy Storage and Conversion: Batteries, Capacitors,

and Fuel Cells,” O. Chyan, J.J. Chen, M. Liu, M.G. Richmond, K. Yang, Mater. Res. Soc. Symp. Proc. 1995, 393, 265.

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Publications: Richmond, Michael G. 80. “Basal Site Substitution in the Sulfido-Bridged Cluster Ru3(CO)9(μ3-S)2 by the Redox-

Active Diphosphine 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Synthesis, X-Ray Structure, and Electrochemical Properties of Ru3(CO)7(bpcd)(μ3-S)2,” H. Shen, S.G. Bott, M.G. Richmond, Inorg. Chim. Acta 1996, 241, 71.

81. “Regioselective and Stereoselective PPh3 Substitution in the Imido-Capped Cluster

Ru3(CO)10(μ3-NPh). Electrochemical Properties and X-Ray Diffraction Structures of Ru3(CO)9(PPh3)(μ3-NPh) and Ru3(CO)8(PPh3)2(μ3-NPh),” H. Shen, R.A. Senter, S.G. Bott, M.G. Richmond, Inorg. Chim. Acta 1996, 247, 161.

82. “Regioselective Phosphine Attack on the Coordinated Alkyne in Co2(μ-alkyne)

Complexes. Reactivity Studies and X-Ray Diffraction Structures of Co2(CO)4(bma)(μ-HC≡CBut) and the Zwitterionic Hydrocarbyl Complexes Co2(CO)4[μ-η2:η2:η1:η1-RC=C(R’)PPh2C=C(PPh2)C(O)OC(O)],” K. Yang, S.G. Bott, M.G. Richmond, J. Organomet. Chem. 1996, 516, 65.

83. “X-Ray Diffraction Structure of the Oxalate-Substituted

Pentamethylcyclopentadienylruthenium Complex Cp*Ru(NO)(ox),” K. Yang, S.G. Bott, M.G. Richmond, J. Chem. Crystallogr. 1996, 26, 5.

84. “PhPMe2 Ligand Substitution in the Tetracobalt Cluster Co4(CO)10(μ4-PPh)2. X-Ray

Diffraction Structure of Co4(CO)8(PPhMe2)2(μ4-PPh)2,” W.H. Watson, A. Nagl, M.-J. Don, M.G. Richmond, J. Chem. Crystallogr. 1996, 26, 75.

85. “Reaction of Cp*Ru(NO)Cl2 with 2,2-dicyano-1,1-ethylenedithiolate (i-mnt). Redox

Chemistry and X-Ray Diffraction Structure of Cp*Ru(NO)[S2C=C(CN)2],” K. Yang, R.L. Verran, S.G. Bott, M. G. Richmond, J. Coord. Chem. 1996, 38, 75.

86. “Diyne and Phosphorus-Carbon Bond Reactivity in the Reaction Between

[Co2(CO)6]2(PhC4Ph) and 2,3-Bis(diphenylphosphino)maleic Anhydride (bma). Syntheses, Molecular Orbital Properties, and X-Ray Diffraction Structures of Co2(CO)4[μ,η2,η2,η1,η1-(Z)-Ph2P(Ph)C=C(PhC2)C=C(Ph2P)C(O)OC(O)], Co2(CO)2(bma)2•CH2Cl2, and Co2(CO)2(bma)[μ- C=C(Ph2P)C(O)OC(O)](μ2-Ph2P)•C6H14,” K. Yang, J.A. Martin, S.G. Bott, M.G. Richmond, Organometallics 1996, 15, 2227.

87. “P-C Bond Activation and Phenyl Group Transfer in the Reaction of

Co4(CO)9(mesitylene) with 2,3-Bis(diphenylphosphino)maleic Anhydride (bma). X-ray Diffraction Structures and Redox Properties of Co3(CO)7[μ2-η2,η1- P(Ph)C=C(PPh2)C(O)OC(O)] and Co3(CO)6(PPh3)[μ2-η2,η1- P(Ph)C=C(PPh2)C(O)OC(O)],” C.-G. Xia, K. Yang, S.G. Bott, M.G. Richmond, Organometallics 1996, 15, 4480.

12

Publications: Richmond, Michael G. 88. “Organometallic Metal Cluster Chemistry for the Year 1994,” M.G. Richmond, J. Coord.

Chem. 1996, 156, 91. Invited Review. 89. “Reaction of FcCCo3(CO)9 with 2,3-bis(diphenylphosphino)maleic anhydride (bma). X-

Ray diffraction structure and redox properties of Co3(CO)6[μ2-η2,η1- C(Fc)C=C(PPh2)C(O)OC(O)](μ2-PPh2),” H. Shen, S.G. Bott, M.G. Richmond, Inorg.

Chim. Acta 1996, 250, 195. Invited Manuscript. 90. “Synthesis, Redox Properties, and X-Ray Diffraction Structure of the Platinum

Catecholate Complex Pt(1,5-COD)(1,2-O2C6H4),” M.-J. Don, K. Yang, S.G. Bott, M.G. Richmond, J. Chem. Crystallogr. 1996, 26, 335.

91. “Ph2PPy Replacement of the 1,5-COD Ligand in the Sulfido-Capped Cluster Fe2(CO6(μ3-

S)2Pt(1,5-COD). X-Ray Diffraction Structure and Redox Behavior of Fe2(CO6(μ3-S)2Pt(Ph2PPy)2,” M.-J. Don, K. Yang, S.G. Bott, M.G. Richmond, J. Coord. Chem. 1996, 40, 273.

92. “Reaction of Dimethylamine with 4,5-Dichloro-4-cyclopenten-1,3-dione. X-Ray

Diffraction Structure and Cyclic Voltammetric Data for ClC=C(NMe2)C(O)CH2C(O),” H. Shen, S.G. Bott, M.G. Richmond, J. Chem. Crystallogr. 1997, 27, 19.

93. “Cp*Ru(NO)(catecholate) Compounds. Synthesis, Redox Behavior, Extended Hückel

Molecular Orbital Calculations, and X-Ray Diffraction Structure of the Pentamethylcyclopendienylruthenium Complex Cp*Ru(NO)(2,3-naphthalenediolate)•CH2Cl2,” K. Yang, J.A. Martin, S.G. Bott, M.G. Richmond, Inorg. Chim. Acta 1997, 254, 19.

94. “Acetylene Substitution in the Triruthenium Clusters Ru3(CO)12-n(MeCN)n (where n = 0,

2). X-Ray Diffraction Structures for Ru3(CO)9(μ2-H)(μ3-η2-C≡CC6H4Me-4) and Ru4(CO)12(μ4-η2-HC≡CPh),” H. Shen, S.G. Bott, M.G. Richmond, J. Chem. Crystallogr. 1997, 27, 25.

95. “Organometallic Metal Cluster Chemistry for the Year 1995,” M.G. Richmond, J. Coord.

Chem. 1997, 160, 237. Invited Review. 96. “Redox Investigation and X-ray diffraction structure of the dimeric rhodium

maleonitriledithiolate complex [Cp*Rh(mnt)]2. Confirmation of bridging and chelating mnt ligands in the solid-state structure,” M.-J. Don, K. Yang, S.G. Bott, M.G. Richmond, J. Organomet. Chem. 1997, 544, 15.

13

Publications: Richmond, Michael G. 97. “CO Replacement in Ru3(CO)12 by 2,3-bis(diphenylphosphino)maleic anhydride (bma).

X-Ray Structures of Ru3(CO)10(bma)•H2O and Ru2(CO)6[μ-C=C(PPh2)C(O)OC(O)](μ2-PPh2),” H. Shen, J.-C. Wang, S.G. Bott M.G. Richmond, J. Chem. Crystallogr. 1997, 27, 649.

98. “Site-Selective PMe3 Addition to the Donor-Acceptor Complex Ru2(CO)6[(Z)-

Ph2PCH=CHPPh2]. X-ray Diffraction Structure of Ru2(CO)5(PMe3)[(Z)-Ph2PCH=CHPPh2],” H. Shen, S.G. Bott, M.G. Richmond, Inorg. Chim. Acta 1998, 267, 223.

99. “Organometallic Metal Cluster Chemistry for the Year 1996,” M.G. Richmond, J. Coord.

Chem. 1998, 168, 177. Invited Review. 100. “Regiospecific Ligand Addition to the Donor-Acceptor Compound Ru2(CO)6(bpcd).

Syntheses and X-ray Diffraction Structures of Ru2(CO)5L(bpcd) and Ru2(CO)5L[μ-C=C(PPh2)C(O)CH2C(O)](μ2-PPh2) (where L = PMe3 and tBuNC),” H. Shen, S.G. Bott, M.G. Richmond, J. Chem. Crystallogr. 1998, 28, 385.

101. “Reaction of Bis(dimethoxyphosphino)dimethylhydrazine (dmpdmh) with PhCCo3(CO)9.

Synthesis and X-Ray Characterization of the dmpdmh-Bridged Polymorphs of PhCCo3(CO)7[(MeO)2PN(Me)N(Me)P(OMe)2],” S.G. Bott, J.-C. Wang, M.G. Richmond, J. Chem. Crystallogr. 1998, 28, 401.

102. “Organometallic Metal Cluster Chemistry for the Year 1997,” M.G. Richmond, J. Coord.

Chem. 1998, 175, 271. Invited Review. 103. “An EPR Study of 2,3-Bis(diphenylphosphino)maleic Anhydride (BMA) Complexes and

the BMA Radical Anion,” N.W. Duffy, R.R. Nelson, M.G. Richmond, A.L. Rieger, P.H. Rieger, B.H. Robinson, D.R. Tyler, J.C. Wang, K. Yang, Inorg. Chem. 1998, 37, 4849.

104. “Synthesis of a Mixed Cluster/Binuclear Compound. Electrochemical Properties and X-

ray Diffraction Structure of Co3(CO)9[μ3-CCO2CH2CCH{Co2(CO)6}],” M.P. Castellani, S.G. Bott, M.G. Richmond, J. Chem. Crystallogr. 1998, 28, 693.

105. “Chelation of a Diphosphine Ligand at FeCo2(CO)9(μ3-S). Spectroscopic and X-Ray

Diffraction Data for FeCo2(CO)7(bpcd)(μ3-S),” S. G. Bott, J. C. Wang, H. Shen, M.G. Richmond, J. Chem. Crystallogr. 1999, 29, 391.

106. “Reaction of Bis(dimethoxyphosphino)dimethylhydrazine (dmpdmh) with Ru3(CO)12.

Evidence for Facile Ligand Fragmentation in Ru3(CO)10(dmpdmh) to Give Ru4(CO)12[μ-N(Me)N(Me)], Ru3(CO)11[P(OMe)3], and Ru3(CO)9[μ-P(OMe)3],” S.G. Bott, J.-C. Wang, M.G. Richmond, J. Chem. Crystallogr. 1999, 29, 587.

14

Publications: Richmond, Michael G. 107. “Room Temperature Ligand Fragmentation in the Reaction Between PhCCo3(CO)9 and

Ph2PN(Me)N(Me)PPh2. X-Ray Diffraction Structure of PhCCo3(CO)8[Ph2PP(O)Ph2],” S.G. Bott, J.-C. Wang, M.G. Richmond,” S.G. Bott, J.-C. Wang, M.G. Richmond, J. Chem. Crystallogr. 1999, 29, 603.

108. “Reaction of Ethyl Diazoacetate with Co3(CO)9(μ3-CCl): Isolation and X-ray Structures

of Co3(CO)9(μ3-CCO2Et), Co3(CO)9(μ3-CCH2CO2Et), and [Co3(CO)9(μ3-CCHCO2Et)]2,” M.P. Castellani, W.G. Smith, N.G. Patel, S.G. Bott, M.G. Richmond, J. Chem. Crystallogr. 1999, 29, 609.

109. “Synthesis, Redox Chemistry, and X-ray Structure of the Mixed-Metal Cluster

Fe2(CO)6(μ3-S)2Ni(dppf),” W.H. Watson, A. Nagl, M.-J. Don, M.G. Richmond, J. Chem. Crystallogr. 1999, 29, 871.

110. “Organometallic Metal Cluster Chemistry for the Year 1998,” M.G. Richmond, J. Coord.

Chem. 2000, 209, 333. Invited Review. 111. “Photochemically Mediated Alkyne Metalation in the Donor-Acceptor Complexes

Ru2(CO)6(μ-P-P) [where P-P = bpcd, (Z)-Ph2PCH=CHPPh2]. X-ray Diffraction Structure of the Zwitterionic Compound Ru2(CO)6[μ-(Z)-MeO2CC=CCO2Me](μ-bpcd),” S.G. Bott, H. Shen, M.G. Richmond, Inorg. Chim. Acta 2000, 300-302, 1077. Invited Manuscript.

112. “X-Ray Diffraction Structure of the Phosphido-bridged Mixed-metal Cluster

Fe2(CO)6(μ3-PPh)2Pt(dppe),” W.H. Watson, A. Nagl, M.-J. Don, M.G. Richmond, J. Chem. Crystallogr. 2000, 30, 233.

113. “Selective Diphosphine Ligand Chelation and π Bond Coordination in CoRu(CO)7(μ-

PPh2): Kinetics and X-ray Structure of CoRu(CO)4(μ-bma)(μ-PPh2),” S.G. Bott, K. Yang, J.-C. Wang, M.G. Richmond, Inorg. Chem. 2000, 39, 6051.

114. “X-ray Diffraction Structure of Co2(CO)4(μ-PhC≡CH)[(Z)-Ph2PCH=CHPPh2]. Proof for

Diphosphine Ligand Chelation,” S.G. Bott, K. Yang, M.G. Richmond, J. Chem. Crystallogr. 2000, 30, 627.

115. “Organometallic Metal Cluster Chemistry for the Year 1999,” M.G. Richmond, J. Coord.

Chem. 2001, 214, 1. Invited Review. 116. “CO Substitution in PhCCo3(CO)9 by 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-

dione (bpcd). Ligand Fluxionality, Kinetics, and X-ray Structures of PhCCo3(CO)7(bpcd) and Co3(CO)6[μ2-η2,η1-C(Ph)C=C(PPh2)C(O)CH2C(O)](μ2-PPh2),” S.G. Bott, H. Shen, M.G. Richmond, Struct. Chem. 2001, 12, 225. Invited William H. Watson Commemorative Manuscript.

15

Publications: Richmond, Michael G. 117. “Ligand-Promoted Transformation of the μ3-η2-Vinylidene Ligand in the Reaction

Between RuCo2(CO)9(μ3-η2-C=CHPh) and 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). X-ray Structure of RuCo2(CO)7(bpcd)(μ3-η2-C=CHPh),” S.G. Bott, H Shen, M.G. Richmond, Struct. Chem. 2001, 12, 237. Invited William H. Watson Commemorative Manuscript.

118. “X-ray Diffraction Structure of Re2(CO)8[(Z)-Ph2PCH=CHPPh2]. Proof for Diphosphine

Ligation Across the Re-Re Bond,” S.G. Bott, K. Yang, M.G. Richmond, J. Chem. Crystallogr. 2001, 31, 485.

119. “Ion-Pairing Thermodynamics for (η5-pentadienyl)Fe(CO)2

- (pentadienyl = MeCp, C5Me5, C5Ph5, C9H7) and X-ray Crystal Structure of [(η5-C5Ph5)Fe(CO)2][PPN],” M.P. Castellani, S. Hwang, S.E. Longacre, A.L. Rheingold, M.G. Richmond, Organometallics, 2002, 21, 373.

120. “Reduction and Oxidation of the Arachno Clusters Fe2(CO)6(μ-S)2PtL2: Characterization

of Distinct One- and Two-Electron Transfer Sites in Heteropolynuclear Compounds,” A. Morneau, W.E. Geiger, M.G. Richmond, M.-J. Don, W.H. Watson, A. Nagl, Organometallics, 2002, 21, 1247.

121. “Organometallic Metal Cluster Chemistry for the Year 2000,” M.G. Richmond, J. Coord.

Chem. 2002, 228, 19. Invited Review. 122. “Phosphine Ligand Attack at Both the Methylidyne Cap and the CpNi Center in

HCCo2NiCp(CO)6 by 2,3-Bis(diphenylphosphino)maleic anhydride (bma). P-C Bond Cleavage Reactivity, Kinetics, and X-ray Structures of the Zwitterionic Clusters Co2NiCp(CO)4(μ-CO)[μ2,η2,η1-C(H)PPh2C=C(PPh2)C(O)OC(O)] and Co2NiCp(CO)4[μ2,η2,σ-C(H)PPh2C=CC(O)OC(O)](μ2-PPh2),” S.G. Bott, K. Yang, K. Talafuse, M.G. Richmond, Organometallics 2003, 22, 1383.

123. “Acetylide Participation in Ligand Substitution and P-C Bond Cleavage in the Reaction

Between HRu3(CO)9(μ3,η2,η2,η1-C≡CPh) and 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Syntheses and X-ray Structures of HRu3(CO)7[μ3,η2,η2,η1,η1,η1-Ph2PC=CC(O)CH2C(O)PPh2C=CPh] and Ru3(CO)6(μ,η2,η1-PhC=CHPh)[μ2,η2,η1-PPhC=CC(O)CH2C(O)PPh2], S.G. Bott, H. Shen, R.A. Senter, M.G. Richmond, Organometallics 2003, 22, 1953.

124. “ETC and Thermal Ligand Substitution in PhCCo3(CO)9 with 2,3-

Bis(diphenylphosphino)-N-phenylmaleimide (bppm). X-ray Diffraction Structure of Co3(CO)6[μ2,η2,η1-C(Ph)C=C(PPh2)C(O)NPhC(O)](μ2-PPh2)," W.H. Watson, S.G. Bodige, J. Liu, M.G. Richmond, Struct. Chem. 2003, 14, 367.

16

Publications: Richmond, Michael G. 125. “CO Substitution in Ru3(CO)12 by 2,3-Bis(diphenylphosphino)-N-phenylmaleimide

(bppm). X-ray Diffraction Structure of Ru2(CO)6(bppm),” W.H. Watson, K. Ejsmont, J. Liu, M.G. Richmond, J. Chem. Crystallogr. 2003, 33, 541.

126. "Reaction of 2,3-Bis(diphenylphosphino)maleic acid-thioanhydride (bmata) with

PhCCo3(CO)9. X-ray Diffraction Structure of Co3(CO)6[μ2,η2,η1-C(Ph)C=C(PPh2)C(O)SC(O)](μ2-PPh2)," S.G. Bott, T. Múnoz, M.G. Richmond, J. Chem. Crystallogr. 2003, 33, 549.

127. “X-ray Diffraction Structure of (5S)-3,4-Dichloro-5-menthoxy-2(5H)-furanone,” S.G.

Bott, K. Yang, M.G. Richmond, J. Chem. Crystallogr. 2003, 33, 585. 128. “Organometallic Metal Cluster Chemistry for the Year 2001,” M.G. Richmond, J. Coord.

Chem. 2003, 241, 273. Invited Review. 129. “X-ray Structure and Redox Chemistry of the Heptacobalt Cluster Co3(CO)9[μ3-

CCO2CH2CCH{Co4(CO)10}],” W.H. Watson, S. Bodige, J.-C. Wang, M.G. Richmond, J. Chem. Crystallogr. 2003, 33, 673.

130. “Regiospecific CO Substitution in (μ-H)Ru3(μ3-η3-CHCHCMe)(CO)9 by 4,5-

Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). X-ray Structure of (μ-H)Ru3(μ3-η3-CHCHCMe)(CO)7(bpcd)•MeOH,” C.-G. Xia, S.G. Bott, M.G. Richmond, J. Chem. Crystallogr. 2003, 33, 681.

131. “Bridging and Chelating Diphosphine Ligands in (μ-H)Ru3(CO)8(P-P)(μ-NCPh2). X-ray

Diffraction Structures of (μ-H)Ru3(CO)8(dmpe)(μ-NCPh2) and (μ-H)Ru3(CO)8(bpcd)(μ-NCPh2),” W.H. Watson, Y. Zhao, M.G. Richmond, J. Chem. Crystallogr. 2003, 33, 765.

132. “Site-Selective Ligand Substitution in CoRu(CO)7(μ-PPh2) using (Z)-Ph2PCH=CHPPh2

and Reactivity of DMAD with CoRu(CO)5[(Z)-Ph2PCH=CHPPh2](μ-PPh2). X-ray Structures of CoRu(CO)5[(Z)-Ph2PCH=CHPPh2](μ-PPh2) and CoRu(CO)3(μ-CO)[(Z)-Ph2PCH=CHPPh2][μ,η3-Ph2PC(CO2Me)C(CO2Me)],” W.H. Watson, J. Liu, M.G. Richmond, J. Chem. Crystallogr. 2003, 33, 775.

133. “Construction of a Hexanuclear Cluster Composed of Spatially Separated Co3 and Ru3

Units. X-ray Diffraction Structure of Co3(CO)9[μ3-CCO2CH2CC{HRu3(CO)9}],” W.H. Watson, J.-C. Wang, M.G. Richmond, J. Chem. Crystallogr. 2003, 33, 957.

134. “Ortho-Metalation and Carboxylate Coordination in the Reaction Between the

Dipotassium Salt of Phthalic Acid and Cp*Ir(PMe3)Cl2: X-ray Diffraction Structure of Cp*Ir(PMe3)[C6H3(CO2)(CO2H)],” W.H. Watson, M.-J. Don, M.G. Richmond, J. Chem. Crystallogr. 2003, 33, 963.

17

Publications: Richmond, Michael G. 135. “Sequential Reaction of p-Toluidine with 2,3-Dichloromaleic Anhydride: Synthesis and

Molecular Structure of 2-Chloro-3-p-toluidino-N-p-tolylmaleimide,” W.H. Watson, G. Wu, M.G. Richmond, J. Chem. Crystallogr. 2003, 33, 983.

136. “Unusual Chemical Reactivity in the Reactions of Re2(CO)8(μ-H)(μ-η1,η2-CH=CHBu)

with 2,3-Bis(diphenylphosphino)maleic Anhydride (bma) and Re2(CO)8(bma) with Ni(cod)2: X-ray Diffractions Structures of Re2(CO)8(bma), Zwitterionic Re(CO)4[Re(CO)4(bma)], and the Phosphido-bridged Complex Re2(CO)8[μ-η1,η1-C=C(PPh2)C(O)OC(O)](μ-PPh2),” S.G. Bott, K. Yang, M.G. Richmond, J. Organomet. Chem. 2004, 689, 791.

137. “Reaction of 1,2-Bis(diphenylphosphino)cyclobutenedione (bpcbd) with fac-

BrRe(CO)3(THF)2: X-ray Diffraction Structure of the Dimeric Complex [BrRe(CO)3]2(bpcbd)•CH2Cl2,” S.G. Bott, K. Yang, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 127.

138. “Thermally Induced Dual P-C Bond Cleavage Routes from the Imido-capped Cluster

Ru3(CO)7(μ3-CO)(μ3-NPh)(bpcd). Synthesis, Spectroscopic Properties, and X-ray Diffraction Structures of Ru3(CO)7(μ3-CO)(μ3-NPh)(bpcd), Ru3(CO)5(μ2-CO)2(μ3-NPh)(μ2-PPh2)[μ-η1,η1-C=C(PPh2)C(O)CH2C(O)], Ru3(CO)6(μ2-CO)(μ3-NPh)(μ-PhCO)[μ2-η2,η1-PPhC=C(PPh2)C(O)CH2C(O)], and Ru3(CO)9(μ3-NPh)(μ3-PPh),” S.G. Bott, H. Shen, M.G. Richmond, J. Organomet. Chem. 2004, 689, 3426.

139. “Organometallic Metal Cluster Chemistry for the Year 2002,” M.G. Richmond, J. Coord.

Chem. 2004, 248, 881. Invited Review. 140. “Reaction of the Dicobalt Alkyne Compound Co2(CO)6(μ-dmad) with the Diphosphine

Ligand 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Spectroscopic Properties, X-ray Diffraction Data, and Thermal Reactivity of the Chelating Isomer of Co2(CO)4(bpcd)(μ-dmad),” C.-G. Xia, S.G. Bott, G. Wu, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 513.

141. “Unexpected Chlorine Substitution by Hydrogen in the Reaction of 2-Chloro-3-p-

toluidino-N-p-tolylmaleimide with DBU: Synthesis and Molecular Structure of 2-p-toluidino-N-p-tolylmaleimide,” W.H. Watson, G. Wu, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 621.

142. “Ligand Substitution in the Halo-bridged Diruthenium Compound [Ru(CO)3Cl2]2 by 4,5-

Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Synthesis, Spectral Properties, and X-ray Diffraction Structures of RuCl2(CO)2(bpcd) and cis-RuCl[C(O)Et](CO)2(bpcd),” W.H. Watson, S.-H. Huang, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 627.

18

Publications: Richmond, Michael G. 143. “Reaction of Dichloromaleic Anhydride and 1,8-Diaminonaphthalene: Synthesis and X-

ray Diffraction Structure of 8,9-Dichloropyrrolo[1,2-a]perimidin-10-one,” W.H. Watson, T. Chen, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 697.

144. “New Polydentate Sulfide Ligands: Synthesis, Redox Properties, and Molecular

Structure of 4,5-Bis(p-tolylthio)-4-cyclopenten-1,3-dione,” W.H. Watson, G. Wu, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 709.

145. “Reaction of o-Phenylenediamine with 2,3-Dichloromaleic Anhydride: Synthesis of N-

Substituted Maleimide Derivatives and 2,3-Dichloropyrrolo[1,2-a]benzimidazol-1-one. X-ray Structures of 2,3-Dichloro-N-o-C6H4(NH2)maleimide and N,N’-o-C6H4-Bis(2,3-dichloromaleimide),” W.H. Watson, G. Wu, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 757.

146. “Synthesis, Redox Properties, and X-ray Diffraction Structure of 2,3-Bis(ethylthio)-N-(p-

MeOC6H4)maleimide,” W.H. Watson, T. Chen, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 765.

147. “New Sulfur Derivatives of 2,3-Dichloropyrrolo[1,2-a]benzimidazol-1-one.

Demonstration of Regioselective Thiolate Addition and X-ray Diffraction Structures of 2-chloro-3-methylthiopyrrolo[1,2-a]benzimidazol-1-one and 2,3-Di(benzylthio)pyrrolo[1,2-a]benzimidazol-1-one,” W.H. Watson, G. Wu, S.-H. Huang, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 773.

148. “Diphosphine Ring Expansion and π-Bond Reduction in the Reaction Between 1,2-

Bis(diphenylphosphino)cyclobutenedione (bpcbd) and Ru3(CO)10(MeCN)2: X-ray Diffraction Structures of Ru3(CO)10[2,3-bis(diphenylphosphino)succinic anhydride]•CH2Cl2 and Ru2(CO)6(bma),” W.H. Watson, T. Chen, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 797.

149. “CO Substitution in the Mixed-metal Clusters PhCCo2Ni(CO)6Cp and

PhCCo2Mo(CO)8Cp by (Z)-Ph2PCH=CHPPh2. X-ray Diffraction Structures and Proof of Ligand Bridging in PhCCo2Ni(CO)4[(Z)-Ph2PCH=CHPPh2]Cp and PhCCo2Mo(CO)6[(Z)-Ph2PCH=CHPPh2]Cp,” S.G. Bott, K. Yang, S.-H. Huang, M.G. Richmond, J. Chem. Crystallogr. 2004, 34, 883.

150. “Thermolysis of the Tetrahedrane Cluster PhCCo3(CO)3(μ-CO)Cp2 with the Unsaturated

Diphosphine Ligands (Z)-Ph2PCH=CHPPh2 and 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Redox Properties and Molecular Structure of PhCCo3(CO)(μ-CO)[(Z)-Ph2PCH=CHPPh2]Cp2,” W.H. Watson, S. Kandala, M.G. Richmond, J. Chem. Crystallogr. 2005, 35, 157.

19

Publications: Richmond, Michael G. 151. “Polyene Ring Attack in diag-CpRe(CO)2Br2 by Hydride and Cyclopentadiene

Displacement to Furnish trans(Br)-[Re(CO)4Br2]- Under CO. X-ray Diffraction Structure of trans(Br)-[Re(CO)4Br2][PPh4],” S.G. Bott, S.-W. Lee, K. Yang, M.G. Richmond, J. Chem. Crystallogr. 2005, 35, 203.

152. “Alkyne Insertion and Coupling Reactions of Methyl Propiolate with the Heterometallic

Dimers CoRu(CO)7(μ-PPh2) and CoRu(CO)5[(Z)-Ph2PCH=CHPPh2](μ-PPh2): X-ray Diffraction Structures of CoRu(CO)4(μ-CO)[μ-PPh2C(O)CH(CCO2Me)C(O)CHC(CO2Me)] and CoRu(CO)3(μ-CO)[(Z)-Ph2PCH=CHPPh2][μ-PPh2C(O)C(CO2Me)CH],” W.H. Watson, J. Liu, M.G. Richmond, J. Chem. Crystallogr. 2005, 35, 249.

153. “Ligand Substitution in the Mixed-Metal Cluster PhCCo2Ni(CO)6Cp by 2,3-

Bis(diphenylphosphino)maleic Anhydride (bma): An Intimate Picture Involving the Stepwise Conversion of the Trinuclear Cluster PhCCo2Ni(CO)4(η2-bma)Cp to the Mononuclear Metallocyclic Compound CpNi[PPh2CPhC=C(PPh2)(O)OC(O)], S.G. Bott, K. Yang, M.G. Richmond, J. Organomet. Chem. 2005, 690, 3067.

154. “Synthesis, X-ray Diffraction Structure, and Redox Chemistry of Re2(CO)8(bmf),” S.G.

Bott, K. Yang, M.G. Richmond, J. Chem. Crystallogr. 2005, 35, 709. 155. “Organometallic Metal Cluster Chemistry for the Year 2003,” M.G. Richmond, J. Coord.

Chem. 2005, 249, 2763. Invited Review. 156. “Reversible Aryl C-H Bond Activation in the Reaction Between HRu3(CO)9,10(μ-PPh2)

and the Diphosphine Ligand 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): X-ray Diffraction Structures of H2Ru3(CO)7(bpcd)[μ,σ-PPh(C6H4)] and Ru3(CO)6(μ-CO)(μ-PPh2)[μ,η2,η1-PPhC=C(PPh2)C(O)CH2C(O)],” S.G. Bott, H. Shen, M.G. Richmond, J. Organomet. Chem. 2005, 690, 3838.

157. “Dimethyl Acetylenedicarboxylate (dmad) Reactivity with the Mixed-Metal Cluster

Co2Rh2(CO)12: Facile Cluster Fragmentation and Highly Specific Metal Redistribution to Give the Butterfly Cluster Co3Rh(CO)10(μ-dmad) and the Planar Cluster CoRh3(CO)9(μ-dmad)3,” W.H. Watson, B. Poola, M.G. Richmond, Organometallics 2005, 24, 4687.

158. “Reversible Isomerization of a Diphosphine Ligand About a Triosmium Cluster:

Synthesis, Kinetics, and X-ray Structures for the Bridging and Chelating Isomers of Os3(CO)10[(Z)-Ph2PCH=CHPPh2],” W.H. Watson, G. Wu, M.G. Richmond, Organometallics 2005, 24, 5431.

20

Publications: Richmond, Michael G. 159. “Reaction of 2,3-Bis(methylthio)pyrrolo[1,2-a]benzimidazol-1-one with

BrRe(CO)3(THF)2. X-ray Diffraction Structure, Redox Chemistry, and Luminescence Behavior of fac-BrRe(CO)3{N,S-2,3-bis(methylthio)pyrrolo[1,2-a]benzimidazol-1-one},” G. Wu, D.R. Glass, D. May, W.H. Watson, D. Wiedenfeld, M.G. Richmond, J. Organomet. Chem. 2005, 690, 4993.

160. “Photochemically Induced Metallization of Surface Silicon Using Dinuclear Metal

Carbonyl Compounds. Anchoring of Ruthenium to a Si(111) Surface Through Covalent Ru-Si Bond Formation,” P. Nalla, S.-H. Huang, Y. Zhang, O. Chyan, M.G. Richmond, M. El Bouanani, Chem. Mater. 2005, 17, 5951.

161. “Synthesis of the Chiral Tetrahedral Clusters RCCo2NiCp(CO)4(bmf) (R = H, Ph) and

Thermally Promoted Diphosphine Ligand Activation: Regiospecific P-C Bond Scission and X-ray Diffraction Structure of Co2NiCp(CO)4[μ2,η2,η1-C(H)C=C(PPh2)C(O)OCH(OMe)](μ-PPh2),” S.G. Bott, K. Yang, M.G. Richmond, J. Organomet. Chem. 2006, 691, 20.

162. “Synthesis, Redox Properties, and Molecular Structure of 4,5-Diethylthio-4-cyclopenten-

1,3-dione: Cyclic Voltammetric Evidence for a Kinetically Stable Radical Anion,” W.H. Watson, G. Wu, P. Vadapally, M.G. Richmond, J. Chem. Crystallogr. 2006, 36. 55.

163. “Chlorine-Atom Abstraction and Cluster Fragmentation in the Reaction of

H3Re3(CO)10(MeCN)2 with the Diphosphine Ligand 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): X-ray Diffraction Structure of fac-ClRe(CO)3(bpcd),” W.H. Watson, S. Kandala, M.G. Richmond, J. Chem. Crystallogr. 2006, 36, 71.

164. “Syntheses and X-ray Structures of the Bridging and Chelating Isomers of

Os3(CO)10(dmpe),” W.H. Watson, B. Poola, M.G. Richmond, J. Chem. Crystallogr. 2006, 36, 123.

165. “Diphosphine Isomerization and C-H and P-C Bond Cleavage Reactivity in the

Triosmium Cluster Os3(CO)10(bpcd): Kinetic and Isotope Data for Reversible Ortho Metalation and X-ray Structures of the Bridging and Chelating Isomers of Os3(CO)10(bpcd) and the Benzyne-substituted Cluster HOs3(CO)8(μ3-C6H4)[μ2,η1-PPhC=C(PPh2)C(O)CH2C(O)],” W.H. Watson, G. Wu, M.G. Richmond, Organometallics 2006, 25, 930. Recognized as one of the twelve most-cited articles published in Organometallics in 2006 based on data from Thomson ISI.

166. “Dynamic Behavior of the Diphosphine Ligand in H4Ru4(CO)10(dppe) Revisited: Kinetic

Data Supporting a Nondissociative Isomerization of the Dppe Ligand,” S. Kandala, M.G. Richmond, Inorg. Chem. 2006, 45, 5976.

21

Publications: Richmond, Michael G. 167. “Ligand Substitution in HC(O)CCo3(CO)9 with 4,5-Bis(diphenylphosphino)-4-

cyclopenten-1,3-dione (bpcd): Diphosphine Ligand Fluxionality, Decarbonylation of the Formyl Moiety and Competitive P-Ph Bond Cleavage Reactivity,” W.H. Watson, S G. Bodige, K. Ejsmont, J. Liu, M.G. Richmond, J. Organomet. Chem. 2006, 691, 3609.

168. “Regiospecific and Sequential P-C Bond Activation/Cluster Transformations in the

Reaction of PhCCo2MoCp(CO)8 with the Diphosphine Ligands 2,3-Bis(diphenylphosphino)maleic anhydride (bma) and 3,4-Bis(diphenylphosphino)-5-methoxy-2(5H)-furanone (bmf),” S.G. Bott, K. Yang, M.G. Richmond, J. Organomet. Chem. 2006, 691, 3771.

169. “CO Replacement in the Tetrahedrane Cluster MeC(O)CCo3(CO)9 by the Diphosphine

Ligand 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Diphosphine Ligand Isomerization and X-ray Structure of the Bridged Cluster MeC(O)CCo3(CO)7(bpcd),” W.H. Watson, K. Ejsmont, J. Liu, M.G. Richmond, J. Chem. Crystallogr. 2006, 36, 509.

170. “Synthesis and Diphosphine Ligand Fluxionality in Os3(CO)10(bmi): Kinetic Evidence

for Nondissociative Diphosphine Isomerization and X-ray Crystal Structure of 1,1-Os3(CO)10(bmi),” W.H. Watson, B. Poola, M.G. Richmond, J. Organomet. Chem. 2006, 691, 4676.

171. “Diverse Ligand Substitution Behavior in the Reaction of H4Os4(CO)12 with 4,5-

bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) and Me3NO: Spectroscopic Characterization of the Diphosphine Chelating and Bridging Isomers H4Os4(CO)10(bpcd) and the X-ray Diffraction Structures of the Tetraosmium Clusters H4Os4(CO)11(NMe3) and H4Os4(CO)10(NMe3)(η1-bpcd),” W.H. Watson, S. Kandala, M.G. Richmond, J. Chem. Crystallogr. 2006, 36, 605.

172. “Knoevenagel Condensation of the Diphosphine Ligand 4,5-bis(diphenylphosphino)-4-

cyclopenten-1,3-dione with 9-Anthracenecarboxaldehyde: Synthesis of the Second-Generation Ligand 2-(Anthracen-9-ylidene)-4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione,” W.H. Watson, B. Poola, M.G. Richmond, J. Chem. Crystallogr. 2006, 36, 715.

173. “Diphosphine Ligand Substitution in H4Ru4(CO)12. X-ray Diffraction Structures and

Reactivity Studies of the Cluster Compounds H4Ru4(CO)10(P-P) [where P-P = (Z)-Ph2PCH=CHPPh2, bpcd],” W.H. Watson, S. Kandala, M.G. Richmond, J. Chem. Crystallogr. 2006, 36, 813.

174. “Ligand-induced Polyhedral Opening in the Mixed-metal Cluster MeCCo2NiCp(CO)6 by

4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): X-ray Structure of Co2NiCp(CO)4[μ2,η2,η1-C(Me)C=C(PPh2)C(O)CH2C(O)](μ2-PPh2),” W.H. Watson, K. Ejsmont, J. Liu, M.G. Richmond, J. Chem. Crystallogr. 2006, 36, 823.

22

Publications: Richmond, Michael G. 175. “Ligand Substitution in the Tetrahedrane Clusters RCCo2Mo(η5-indenyl)(CO)8 with 4,5-

Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Influence of the Carbyne and Indenyl Ligands on the Stability of the Substitution Products and X-ray Diffraction Structures of HCCo2Mo(η5-indenyl)(CO)6(μ-bpcd) and CoMo(η5-indenyl)(μ-CPh)(CO)2(μ-bpcd)Cl,” W.H. Watson, B. Poola, M.G. Richmond, J. Organomet. Chem. 2006, 691, 5579.

176. “Ligand Chelation, P-C Bond Cleavage, and Phenyl-Group Transfer in the Reaction

Between RCCo3(CO)9 and 1,8-Bis(diphenylphosphino)naphthalene (dppn): Syntheses and X-ray Diffraction Structures of PhCCo3(CO)4(μ-CO)3(dppn) and PhCCo3(CO)8[η1-PPh(OH)C10H6P(O)Ph2],” W.H. Watson, S. Kandala, M.G. Richmond, J. Organomet. Chem. 2007, 692, 968.

177. “Ligand Degradation and Phosphorus Scavenging in the Reaction Between 1,2-

Bis(diphenylphosphino)benzene (dppbz) and Ru6(μ6-C)(CO)17: Synthesis and X-ray Structure of the Edge-bridged Square-pyramidal Cluster HRu6(μ5-C)(μ3-P)(CO)14(dppbz),” W.H. Watson, S. Kandala, M.G. Richmond, J. Organomet. Chem. 2007, 692, 1648.

178. “Regiospecific Alkyne Insertion into the Co-Co Bond of the Mixed-metal Cluster

Co2Rh2(CO)12 by an Electron-poor Alkyne: X-ray Diffraction Structure of the Butterfly Cluster Co2Rh2(CO)10(μ-HCCCO2Me),” W.H. Watson, B. Poola, M.G. Richmond, Polyhedron 2007, 26, 1117.

179. “Photochemical Reactivity of the Triosmium Cluster 1,1-Os3(CO)10(bpcd) in the

Presence of P(OEt)3 and X-ray Crystal Structure of HOs3(CO)7[P(OEt)3][μ-{PPh(C6H4)}C=C(PPh2)C(O)CH2C(O)]: Evidence for Ortho Metalation and Cluster Face Capping by a Diphosphine Ligand,” W.H. Watson, A. Strugatskiy, G. Wu, M.G. Richmond, J. Chem. Crystallogr. 2007, 37, 247.

180. “Pincer Ligand Coordination at a Triosmium Cluster: X-ray Structures of 1,2-

Os3(CO)10[4,6-bis(diphenylphosphinomethyl)-m-xylene] and 1,2-Os3(CO)10[1-diphenylphosphino-1-{(2,4-dimethyl-5-diphenylphosphinomethyl)phenyl}-propan-2-ol],” V. Nesterov, B. Poola, X. Wang, M.G. Richmond, J. Organomet. Chem. 2007, 692, 1806. Invited Gulya Palyi Commemorative Manuscript.

181. “Pincer Ligand Coordination at Co3 and Ru6 Clusters: Syntheses, Reactivity Studies, and

X-ray Diffraction Structures of [PhCCo3(CO)8]2(dppx) and [Ru6(μ6-C)(CO)16]2(dppx),” W.H. Watson, B. Poola, J. Liu, M.G. Richmond, J. Chem. Crystallogr. 2007, 37, 349.

182. “Reaction of HRu3(CO)10(μ-COMe) with bma: NMR and X-ray Structural Evidence for

the Formation of the Ph2PH-substituted Cluster HRu3(CO)8(PHPh2)[μ-PPh2C=CC(O)OC(O)],” S.G. Bott, H. Shen, S. Kandala, N.H. Phan M.G. Richmond, J. Coord. Chem. 2007, 60, 1223.

23

Publications: Richmond, Michael G. 183. “Synthesis and Characterization of the Osmium Compound cis(CO)-

ClOs(CO)2(bpcd)[C(O)Et],” W.H. Watson, S.-H. Huang, M.G. Richmond, J. Chem. Crystallogr. 2007, 37, 479.

184. “Photochemically Promoted Regiospecific P-C Bond Cleavage in the Diruthenium

Compound Ru2(CO)2(bmf): X-ray Diffraction Structure of Ru2(CO)6[μ-C=C(PPh2)C(O)OCH(OMe)](μ-PPh2),” S.G. Bott, H. Shen, M.G. Richmond, J. Coord. Chem. 2007, 60, 1457.

185. “α-Diimine Chelation at a Triosmium Cluster: Synthesis and X-ray Structure of 1,1-

Os3(CO)9(μ-CO)(1,10-phen),” B. Poola, X. Wang, M.G. Richmond, J. Chem. Crystallogr. 2007, 37, 641.

186. “Synthesis, Electrochemistry, MO Properties, and X-ray Diffraction Structures of the

New redox-active Diphosphine Ligand 2-(2-Thienylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (tbpcd) and fac-BrRe(CO)3(tbpcd),” W.H. Watson, D. Wiedenfeld, A. Pingali, B. Poola, M.G. Richmond, Polyhedron, 2007, 26, 3577.

187. “Synthesis and Reactivity Studies of the Diphosphine Ligand 2-(Ferrocenylidene)-4,5-

bis(diphenylphosphino)-4-cyclopenten-1,3-dione (fbpcd): Bridge-to-Chelate Ligand Isomerization Kinetics in Os3(CO)10(fbpcd) and X-ray Diffraction Structure of the Ortho-Metalated Cluster HOs3(CO)9[μ-PhP(C6H4)C=C(PPh2)C(O)C=CH(C5H4FeCp)C(O)] ,” W.H. Watson, B. Poola, M.G. Richmond, Polyhedron 2007, 26, 3585.

188. “CO Substitution in H4Ru4(CO)12 by the Diphosphine Ligands 1,2-

Bis(diphenylphosphine)benzene (dppbz) and 1,8-Bis(diphenylphosphino)naphthalene (dppn): X-ray Diffraction Structures of the Diphosphine-chelated Clusters 1,1-H4Ru4(CO)10(dppbz) and 1,1-H4Ru4(CO)10(dppn),” V. Nesterov, W.H. Watson, S. Kandala, M.G. Richmond, Polyhedron 2007, 26, 3602.

189. “PMe3-induced CO Insertion and CO Deinsertation in the Zwitterionic Hydrocarbyl

Complex Co2(CO)4[μ-PhC=C(H)PPh2C=C(PPh2)C(O)OC(O)]. Syntheses and X-ray Structures of Co2(CO)3(PMe3)[μ-PhC(CO)=C(H)PPh2C=C(PPh2)C(O)OC(O)] and Co2(CO)3(PMe3)[μ-PhC=C(H)PPh2C=C(PPh2)C(O)OC(O)],” S.G. Bott, K. Yang, M.G.

Richmond, Polyhedron 2007, 26, 3737. 190. “CO Substitution and Cluster-Ligand Reductive Coupling in the Reaction of 2,3-

Bis(diphenylphosphino)maleic Anhydride (bma) with the Mixed-metal Clusters PhCCo2MCp(CO)8 (where M = Cr, W): Synthesis and X-ray Diffraction Structures of the Phosphido-bridged Clusters Co2MCp(CO)5[μ2,η2,η1-C(Ph)C=C(PPh2)C(O)OC(O)](μ-PPh2),” W. Zhang, W.H. Watson, M. G. Richmond, J. Chem. Crystallogr. 2008, 38, 9.

24

Publications: Richmond, Michael G. 191. “Diphosphine Chelation and Bridging and Regiospecific Ortho Metalation in the

Reaction of 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) with Ir4(CO)12: X-ray Diffraction Structures of Ir4(CO)7(μ-CO)3(bpcd), Ir4(CO)5(μ-CO)3(bpcd)(μ-bpcd), and HIr4(CO)4(μ-CO)3(bpcd)[μ-PhP(C6H4)C=C(PPh2)C(O)CH2C(O)],” W.H. Watson, G. Wu, M.G. Richmond, J. Organomet. Chem. 2008, 693, 1439. Invited Contribution to the Special F.A. Cotton Memorial Issue.

192. “Diphosphine Substitution and Carbyne Ligand Transfer in the Reaction of 2,3-

Bis(diphenylphosphino)maleic Anhydride (bma) with the Methylidyne-capped Clusters HCCo2MCp(CO)8 (where M = Mo, W): Synthesis and X-ray Diffraction Structures of the Vinylidene-bridged Clusters Co2MCp(CO)6[μ-C=C(H)CH2C(PPh2)C(PPh2)C(O)OC(O)],” W. Zhang, W.H. Watson, M.G. Richmond, J. Chem. Crystallogr. 2008, 38, 437.

193. “CO Substitution in HRu3(CO)10(μ-COMe) by the Unsaturated Diphosphine Ligand 4,5-

Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Synthesis and Reactivity Studies of the Face-capped Cluster Ru3(CO)7(μ3-COMe)[μ-P(Ph)C=C(PPh2)C(O)CH2C(O)],” S.G. Bott, H. Shen, S.-H. Huang, M.G. Richmond, J. Organomet. Chem. 2008, 693, 2327.

194. “Reaction of 6-Methyl-2,2'-bipyridine with 1,2-Os3(CO)10(MeCN)2: Syntheses,

Reductive Elimination/Ligand Displacement Kinetics, and X-ray Diffraction Structures of the Isomeric Clusters HOs3(CO)9(μ2-N2C11H9) and H2Os3(CO)8(μ3-N2C11H8),” C. J. Carrano, B. Poola, M.G. Richmond, Organometallics 2008, 27, 3018.

195. “New Platinum Compounds Containing the Diphosphine Ligand 2-(Ferrocenylidene)-

4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (fbpcd): Synthesis, Redox Behavior, and X-ray Diffraction Structures of PtCl2(fbpcd) and Pt(mnt)(fbpcd),” B. Poola, S. Hunt, X. Wang, M.G. Richmond, Polyhedron 2008, 27, 3693.

196. “Synthesis, Reactivity Investigation, and X-ray Diffraction Structures of New

Platinum(II) Compounds Containing Redox-Active Diphosphine Ligands,” S.W. Hunt, X. Wang, M.G. Richmond, J. Mol. Struct. 2009, 919, 34.

197. “Transfer of Amide and 2-Methoxyethoxy Groups and Sodium Encapsulation in the

Reaction of TaCl3[N(TMS)2]2 with Sodium Bis(2-methoxyethoxy)aluminum Hydride: X-ray Structure of [NaAl{N(TMS)2}(OCH2CH2OMe)3]2,” S.-H. Huang, X. Wang, M.G. Richmond, J. Chem. Crystallogr. 2009, 39, 428.

198. “Preparation and Reactivity of the Heterobimetallic ReIr Face-shared Bioctahedral

Compounds Cp*Ir(μ-Cl)3Re(CO)3 and Cp*Ir(μ-SC6H4Me-4)3Re(CO)3: X-ray Diffraction Structures and Redox Behavior,” X. Wang, C. Hammons, M.G. Richmond, Polyhedron 2009, 28, 2294.

25

Publications: Richmond, Michael G. 199. “Syntheses, Spectroscopic Data, and X-ray Diffraction Structures of the Heterometallic

RuRe Face-shared Bioctahedral (η6-cymene)Ru(μ-Cl)3Re(CO)3 and MnRu2 Edge-shared Trioctahedral [fac-ClRu(CO)3]2(μ-Cl)4Mn(H2O)2 Complexes,” X. Wang, S.W. Hunt, M.G. Richmond, J. Chem. Crystallogr. 2009, 39, 589.

200. “New Rhenium(I) Compounds Containing the Donor-Acceptor Diphosphine Ligands 2-

(ferrocenylidene)-4,5-bis(diphenylphosphino)4-cyclopenten-1,3-dione (fbpcd) and 2-(3-ferrocenylprop-2-ynylidene)-4,5-bis(diphenylphosphino)4-cyclopenten-1,3-dione (fpbpcd): Electrochemical Behavior, MO Properties, and X-ray Diffraction Structure of fac-BrRe(CO)3(fpbpcd),” B. Poola, X. Wang, M.G. Richmond, Polyhedron 2009, 28, 2619.

201. “Ligand Substitution Chemistry of the Diphosphine Ligand endo,endo-2,3-

Bis(diphenylphosphinomethyl)-5-norbornene (dpmn): Syntheses and X-ray Diffraction Structures of PtCl2(dpmn) and PtMe2(dpmn),” W.H. Watson, S.-H. Huang, L. Yang, M.G. Richmond, J. Chem. Crystallogr. 2009, 39, 740.

202. “Spectroscopic and X-ray Diffraction Data on Three Novel Trimetallic Clusters from

Thermally Promoted Ligand Substitution in the Tetrahedrane Clusters MeCCo2MoCp(CO)8 and PhCCo2Mo(η5-C5H4CHO)(CO)8,” W. Zhang, W.H. Watson, M.G. Richmond, J. Chem. Crystallogr. 2009, 39, 812.

203. “α-Diimine Ligand Coordination and C-H Bond Activation in the Reaction of

Os3(CO)10(MeCN)2 with 6-R-2,2'-Bipyridine (where R = Et, Ph): X-ray Diffraction Structures of the Ortho-Metalated Hydride Clusters HOs3(CO)9(N2C10H6-6-R),” C.J. Carrano, X. Wang, B. Poola, C.B. Powell, M.G. Richmond, J. Chem. Crystallogr. 2009, 39, 820.

204. “Directed Synthesis of the Triangular Mixed-Metal Cluster H2RhRe2Cp*(CO)9: Ligand

Fluxionality and Facile Cluster Fragmentation Induced by CO, Halogenated Solvents, and Thiols,” S.-H. Huang, W.H. Watson, C.J. Carrano, X. Wang, M.G. Richmond, Organometallics 2010, 29, 61.

205. “Synthesis of the Donor-Acceptor Ligand 2-(4-dimethylaminobenzylidene)-4,5-

bis(diphenylphosphino)-4-cyclopenten-1,3-dione (dbpcd) and X-ray Diffraction Structure of the Platinum(II) Compound PtCl2(dbpcd),” S. Atim, X. Wang, M.G. Richmond, Inorg. Chim. Acta 2010, 363, 418.

206. “Ligand Substitution Behavior of Ru6(μ6-C)(CO)17 with Unsaturated Diphosphines:

Facile Capping of a Polyhedral Face and Photochemically Promoted P-C Bond Cleavage in the Cluster Ru6(μ6-C)(CO)14(μ3-bpcd),” S, Kandala, C. Hammons, W.H. Watson, X. Wang, M.G. Richmond, J. Chem. Soc., Dalton Trans. 2010, 39, 1620.

26

Publications: Richmond, Michael G. 207. “Chloride Metathesis and Dimethylamide Transfer in the Reaction of TaCl(NMe2)4 with

ZnMe2 and MeMgCl: Spectroscopic Studies and X-ray Diffraction Structures of TaCl(Me)(NMe2)3 and ZnCl2(NHMe2)2,” X. Wang, S.-H. Huang, M.G. Richmond, J. Chem. Crystallogr. 2010, 40, 173.

208. “Diphosphine- and CO-Induced Fragmentation of Chloride-bridged Dinuclear Complex

and Cp*Ir(μ-Cl)3Re(CO)3 and Attempted Synthesis of Cp*Ir(μ-Cl)3Mn(CO)3: Spectroscopic Data and X-ray Diffraction Structures of the Pentamethylcyclopentadienyl Compounds [Cp*IrCl{(Z)-Ph2PCH=CHPPh2}][Cl]∙2CH2Cl2 and Cp*Ir(CO)Cl2,” C. Hammons, X. Wang, V. Nesterov, M.G. Richmond, J. Chem. Crystallogr. 2010, 40, 453.

209. “New Octahedral Ta(V) Hydrazido-substituted Compounds for Atomic Layer

Deposition: Syntheses, X-ray Diffraction Structures of TaCl(NMe2)3[N(TMS)NMe2] and Ta(NMe2)4[N(TMS)NMe2], and Fluxional Behavior of the Amido and Hydrazido Ligands in Solution,” S.-H. Huang, T. Pilvi, X. Wang, M. Leskelä, M.G. Richmond, Polyhedron 2010, 29, 1754.

210. “Isomerization of the Diphosphine Ligand 3,4-Bis(diphenylphosphino)-5-methoxy-

2(5H)-furanone (bmf) at a Triosmium Cluster and P-C Bond Cleavage in the Unsaturated Cluster 1,1-Os3(CO)9(bmf): Synthesis, Kinetics, and X-ray Diffraction Structures of the Isomeric Os3(CO)10(bmf) Clusters and HOs3(CO)9(μ-C6H4)[μ-PhPC=C(Ph2P)CH(OMe)OC(O)],” S. Kandala, L. Yang, C.F. Campana, V. Nesterov, X. Wang, M.G. Richmond Polyhedron 2010, 29, 2814.

211. “New Pt(II)(dithiolate) Compounds Possessing an Energetically Accessible Diphosphine-

based LUMO. Syntheses, Redox Properties, and Solid-State Structures of PtCl2(pbpcd), Pt(tdt)(pbpcd), and Pt(tdt)(bpcd),” S.W. Hunt, L. Yang, X. Wang, V. Nesterov, M.G. Richmond, J. Inorg. Organomet. Polym. Mater. 2010, 20, 457. Invited Charles U. Pittman, Jr., Commemorative Manuscript.

212. “Ortho-Metalation Dynamics and Ligand Fluxionality in the Conversion of

Os3(CO)10(dppm) to HOs3(CO)8[µ-PhP(C6H4-µ2,η1)CH2PPh2]: Experimental and DFT Evidence for the Participation of Agostic C-H and π-Aryl Intermediates at an Intact Triosmium Cluster,” S.-H. Huang, J.M. Keith, M.B. Hall, M.G. Richmond, Organometallics 2010, 29, 4041.

213. “Experimental and Computational Studies of the Isomerization Reactions of Bidentate

Phosphine Ligands in Triosmium Clusters: Kinetics of the Rearrangements from Bridged to Chelated Isomers and X-ray Structures of the Clusters Os3(CO)10(dppbz), 1,1-Os3(CO)10(dppbzF4), HOs3(CO)9[µ-1,2-PhP(C6H4-η1)C6H4PPh2], and HOs3(CO)9[µ-1,2-PhP(C6H4-η1)C6F4PPh2],” X. Zhang, S. Kandala, L. Yang, W.H. Watson, X. Wang, D.A. Hrovat, W.T. Borden, M.G. Richmond, Organometallics 2011, 30, 1253.

27

Publications: Richmond, Michael G. 214. “New Osmium Cluster Compounds Containing the Heterocyclic Ligand 2,3-

Bis(diphenylphosphino)quinoxaline (dppq): Ligand Isomerization and Crystal Structures of dppq, the Isomeric Clusters Os3(CO)10(dppq), and HOs3(CO)9[μ-2,3- PhP(η1-C6H4)(Ph2P)quinoxaline],” S.W. Hunt, L. Yang, X. Wang, M.G. Richmond, J. Organomet. Chem. 2011, 696, 1432.

215. “Allyl Ligand Reactivity in Tantalum(V) Compounds: Experimental and Computational

Evidence for Allyl Transfer to the Formamidinate Ligand in fac-Ta(NMe2)3(η1-allyl)[iPrNC(H)NiPr] via a Metallo-Claisen Rearrangement,” S.-H. Huang, X. Wang, V. Nesterov, D.A. Hrovat, M.B. Hall, M.G. Richmond, Organometallics 2011, 30, 5832.

216. “Phosphinoborane-induced Fragmentation of the Unsaturated Hydride

H2Re2(CO)8: X-ray Structure of HRe(CO)4(κB,P-Ph2PCH2CH2BR2) (where BR2 = 9-borabicyclo[3.3.1]nonanyl) and DFT Evaluation of Hydride versus CO Coordination by the Ancillary Borane,” S.-H. Huang, X. Wang, M.G. Richmond, J. Organomet. Chem. 2012, 700, 103.

217. “Ligand substitution in 1,2-Os3(CO)10(MeCN)2 by the diphosphine

(PhO)2PN(Me)N(Me)P(OPh)2: X-ray diffraction structure of 1,2-Os3(CO)10[(PhO)2PN(Me)N(Me)P(OPh)2] and DFT investigation of the isomeric Os3(CO)10[(PhO)2PN(Me)N(Me)P(OPh)2] clusters,” S.W. Hunt, V. Nesterov, M.G. Richmond, J. Mol. Struct. 2012, 1010, 91.

218. “Structural Characterization of Cis-2,6-(E,E)-Bis(ferrocenylidene)-N-methyl-4-

piperidone and DFT Evaluation of Alternative Polymorphic Modifications via Ferrocene Rotation,” V.V. Nesterov, V.N. Nesterov, M.G. Richmond, Polyhedron 2012, 35, 124.

219. “Synthesis and Structural Characterization of the Pentanuclear Tantalum Cluster Ta5(µ5-

N)(µ3-iPr)2(µ2-iPr)6(η1-NiPr)4(η1-NHiPr)2 from the Reaction of PDMAT and iPrNH2: Unprecedented Formation of a Hinged-Butterfly Cluster Containing an Interstitial Nitride, Imido Groups, and Amido Groups,” S.-H. Haung, V.N. Nesterov, M.G. Richmond, J. Chem. Crystallogr. 2012, 42, 916.

220. “CO Substitution in HOs3(CO)10(μ-SC6H4Me-4) by the Diphosphine Ligand

4,5-Bis(diphenylphosphino)-4-cyclopentadiene-1,3-dione (bpcd): Structural and DFT Evaluation of the Isomeric Clusters HOs3(CO)8(bpcd)(μ-SC6H4Me-4),” L. Yang, V.N. Nesterov, X. Wang, M.G. Richmond, J. Cluster Sci. 2012, 23, 685. Invited Richard D. Adams Commemorative Manuscript.

28

Publications: Richmond, Michael G. 221. “Backbone Modified Small Bite-angle Diphosphines: Synthesis, Structure and

Regioselective Thermal Rearrangements of Os3(CO)10{µ-Ph2PCH(Me)PPh2},” S. Ghosh, G. Hogarth, S.E. Kabir, A.K. Raha, M.G Richmond, J.C. Sarker, J. Cluster Sci. 2012, 23, 781. Invited Richard D. Adams Commemorative Manuscript.

222. “DFT Investigation of the Mechanism of Phosphine-Thioether Isomerization in

Os3(CO)10(Ph2PCH2CH2SMe): Migratory Preference for the Formation of Edge-Bridged Thioether Versus Phosphine Moieties,” D.A. Hrovat, E. Nordlander, M.G. Richmond, Organometallics 2012, 31, 6608.

223. “Re2(CO)6(µ-thpymS)2(thpymSH = pyrimidine-2-thiol) as a versatile precursor to mono-

and polynuclear complexes: X-ray crystal structures of fac-Re(CO)3(PPh3)(κ2-thpymS) and two isomers of ReRu3(CO)13(µ3-thpymS),” Md. Faruque Ahmad, J.C. Sarker, S. Ghosh, G. Hogarth, K.A. Azam, S.E. Kabir, T.A. Siddiquee, M.G. Richmond, J. Organomet. Chem. 2013, 728, 30.

224. “Synthesis, Characterization and Dynamic Behaviour of Triosmium Clusters Containing

the Tridentate Ligand {Ph2PCH2CH2}2S (PSP),” R. Persson, M.J. Stchedroff, R. Gobetto, C.J. Carrano, M.G. Richmond, M. Monari, E. Nordlander, Eur. J. Inorg. Chem. 2013, 2447.

225. “Models of the iron-only hydrogenase: A comparison of chelate and bridge isomers of

Fe2(CO)4{Ph2PN(R)PPh2}(µ-pdt) as proton-reduction catalysts,” S. Ghosh, G. Hogarth, N. Hollingsworth, K.B. Holt, I. Richards, M.G. Richmond, B.E. Sanchez, D. Unwin, Dalton Trans. 2013, 42, 6775.

226. “Cis-Trans Isomerism at Square-Planar MN2S2 Centers (M = Pd, Pt): Crystal Structures

of N-phenyl-N-(2-thiazoyl)thiourea Complexes of trans-Pd(S2N3C10H8)2 and cis-Pt(S2N3C10H8)2 and Density Functional Calculations,” S.A. Al-Jibori, N.A. Dayaaf, M.Y. Mohammed, K. Merzweiler, C.Wagner, G. Hogarth, M.G. Richmond, J. Chem. Crystallogr. 2013, 43, 365.

227. “2-[(Diphenylphosphino)methyl]-6-methylpyridine (PN) coordination chemistry at

triosmium clusters: Regiospecific ligand activation and DFT evaluation of the isomeric Os3(CO)10(PN) clusters,” C.-H. Lin, V.N. Nesterov, M.G. Richmond, J. Organomet. Chem. 2013, 744, 24. Invited W.A. Herrmann Commemorative Manuscript.

228. “Structural and computational features of four highly polar quinolin-2(1H)-ylidene

derivatives: equilibrium preference for enamine, enaminone, and enaminothione tautomeric structures,” V.V. Nesterov, L. Yang, V.N. Nesterov, M.G. Richmond, J. Mol. Struct. 2013, 1054-1055, 262.

29

Publications: Richmond, Michael G. 229. “Reaction of 4-(2,2-dimethylhydrazino)dimethylhydrazone-3-penten-2-one with

BrRe(CO)5 and fac-BrRe(CO)3(THF)2: Synthesis, Structural Characterization, and DFT Examination of the β-Diketimine-substituted Compound fac-BrRe(CO)3[(Me2NNCMe)2CH2], C.-H. Lin, H. Pan, V.N. Nesterov, M.G. Richmond, J. Organomet. Chem. 2013, 748, 56. Invited Contribution to the Special Issue on Theory and Mechanistic Studies in Organometallic Chemistry.

230. “Bimetallic Osmium-Tin Complexes: Stannylene and Hydrostannylene Clusters upon

Addition of Ph3SnH to Unsaturated [(μ-H)2Os3(CO)8(μ-diphosphine)] (diphosphine = dppm, dppf),” J.C. Sarker, K.-M Uddin, M.-H. Saifur Rahman, S. Ghosh, T.A. Siddiquee, D.A. Tocher, M.G. Richmond, G. Hogarth, S.E. Kabir, Inorg. Chim. Acta 2014, 409, 320.

231. “Backbone modified small bite-angle diphosphines: Synthesis, structure, and DFT

evaluation of the thermal rearrangements found in Os3(CO)10{µ-Ph2PC(Me)2PPh2},” A.K. Raha, J.C. Sarker, S. Ghosh, G. Hogarth, S.E. Kabir, M.G. Richmond, J. Organomet. Chem. 2014, 750, 49.

232. “Unusual chemical transformations of acetone thiosemicarbazone mediated by

ruthenium: C-H bond activation, thiolation, and C-N bond cleavage,” P. Paul, D.K. Seth, M.G. Richmond, S. Bhattacharya, RSC Adv. 2014, 4, 1432.

233. “A comparative study of the reactivity of the lightly-stabilized cluster [Os3(CO)8{µ3-

Ph2PCH2P(Ph)C6H4}(µ-H)] towards tri(2-thienyl)-, tri(2-furyl)- and triphenyl-phosphine,” A.K. Raha, S. Ghosh, Md.N. Uddin, M.G. Richmond, D.A. Tocher, E. Nordlander, G. Hogarth, S.E. Kabir, J. Organomet. Chem. 2014, 751, 399. Invited Contribution to the 50th Anniversary Issue of JOMC.

234. “Iridium-mediated N-H and C-H bond activations in N-(2,6-dimethylphenyl)pyrrole-2-

aldimine: Synthesis, characterization and catalytic applications,” P. Paul, M.G. Richmond, S. Bhattacharya, J. Organomet. Chem. 2014, 751, 760. Invited Contribution to the 50th Anniversary Issue of JOMC.

235. “New azido-substituted tantalum compounds: synthesis and DFT examination of

nitrogen-rich mono-, di-, and trinuclear tantalum(V) compounds,” S.-H. Huang, V.N. Nesterov, M.G. Richmond, Dalton Trans. 2014, 49, 3453.

236. “Bio-inspired Hydrogenase Models: Mixed-valence Triiron Complexes

[Fe3(CO)7-x(PPh3)x(µ-SCH2CH2S)2] (x = 0, 1, 2) as Proton Reduction Catalysts,” A. Rahaman, S. Ghosh, D. Unwin, S. Basak-Modi, K.B. Holt, S.E. Kabir, E. Nordlander, M.G. Richmond, G. Hogarth, Organometallics 2014, 33, 1356.

30

Publications: Richmond, Michael G. 237. “Synthesis of [Ru3(CO)9(µ-dppf){P(C4H3E)3}] (E = O, S) and thermally induced

cyclometalation to form [(µ-H)Ru3(CO)7(µ-dppf){µ3-(C4H3E)2P(C4H2E)}] (dppf = 1,1’-bis(diphenylphosphino)ferrocene),” M.K. Hossain, S. Rajbangshi, A. Rahaman, M.A.H. Chowdhury, T.A. Siddiquee, S. Ghosh, M.G. Richmond, E. Nordlander, G. Hogarth, S.E. Kabir, J. Organomet. Chem. 2014, 760, 231.

238. “Synthesis and Characterization of Dimethyldi(2-pyridyl)borate Nickel(II) Complexes: A

Unimolecular Square Planar to Square Planar Rotation Around Nickel(II),” J.A. Celaje, M.K. Pennington-Boggio, R.W. Flaig, M.G. Richmond, T.J. Williams, Organometallics 2014, 33, 2019.

239. “Diastereomer Control of Enantioselectivity: Evidence for Metal Cluster Catalysis,” A.F.

Abdel-Magied, A.K. Singh, M. Haukka, M.G. Richmond, E. Nordlander, Chem Comm. 2014, 50, 7705.

240. “Experimental and computational studies on the reactivity of silanes with the

diphosphine-bridged triruthenium clusters [Ru3(CO)10(µ-dppf)], [Ru3(CO)10(µ-dppm)], and [Ru3(CO)9{µ3-PPhCH2PPh(C6H4)}],” M.J. Hossain, S. Rajbangshi, M.M.M. Khan, S. Ghosh, G. Hogarth, E. Rosenberg, K.I. Hardcastle, M.G. Richmond, S.E. Kabir, J. Organomet. Chem. 2014, 767, 185.

241. “DFT examination of rare α-SiMe3 abstraction in Ta(NMe2)4[N(SiMe3)2]: Formation of

the imide compound Ta(=NSiMe3)(NMe2)3 and its trapping to give guanidinate imides,” M.G. Richmond, Z.-L. Xue, Dalton Trans. 2014, 43, 12390.

242. “Cycloruthenation of N-(naphthyl)salicylaldimine and Related Ligands: Utilization of

Ru-C Bond in Catalytic Transfer Hydrogenation,” J. Dutta, M.G Richmond, S. Bhattacharya, Eur. J. Inorg. Chem. 2014, 4600.

243. Synthesis, Structure, and Conformational Dynamics of Rhodium and Iridium Complexes

of Dimethyldi(2-pyridyl)borate,” M.K. Pennington-Boggio, B.L. Conly, M.G. Richmond, T.J. Williams, Polyhedron 2014, 84, 24. Invited John Bercaw Commemorative Manuscript.

244. “Phenazine-substituted polynuclear osmium clusters: Synthesis and DFT evaluation of

the C-metalated derivatives Os3(CO)9(μ3,η2-C12H7N2)(μ-H) and Os3(CO)9(μ3,η2-C12H6N2)(μ-H)2,” Md. A.H. Chowdhury, S. Rajbangshi, M.G. Richmond, S.E. Kabir, J. Organomet. Chem. 2015, 779, 21.

31

Publications: Richmond, Michael G. 245. “Synthesis of the Stereoisomeric Clusters 1,2-Os3(CO)10(μ-trans-dpmn) and 1,2-

Os3(CO)10(μ-cis-dpmn) (where dpmn = 2,3-bis(diphenylphosphinomethyl)-5-norbornene): DFT Evaluation of the Isomeric Clusters Os3(CO)10(μ-dpmn) and Isomer-dependent Diphosphine Ligand Activation,” L. Yang, V.N. Nesterov, X. Wang, M.G. Richmond, J. Cluster Sci. 2015, 26, 93 Invited Contribution to the Special Edition on Recent Studies of Metal Cluster Complexes.

246. "Electrocatalytic proton reduction catalysed by the low-valent tetrairon-oxo cluster

[Fe4(CO)10(κ2-dppn)(μ4-O)]2- [dppn = 1,1′-bis(diphenylphosphino) naphthalene]," S. Ghosh, K.B. Holt, S.E. Kabir, M.G. Richmond, G. Hogarth, Dalton Trans. 2015, 44, 5160. Invited Contribution to the Special Kenneth Wade Memorial Issue.

247. “Reaction of ethyl (2Z)-cyano-6-methoxyquinolin-2(1H)-ylidene-ethanoate (L) with

BrRe(CO)5 and cis-BrRe(CO)3(THF)2: Structural and computational studies on the rhenium(I) compound cis-BrRe(CO)4L,” L. Yang, V.N. Nesterov, M.G. Richmond, Polyhedron 2015, 94, 83.

248. “Reactivity of [CpMo(CO)2]2 towards heterocyclic thiols: synthesis, structure, and

bonding in the sulfido-ligated cluster Cp3Mo3(μ-CO)2(μ-κ2-C7H4NS)(μ-S)(μ3-S),” M.A.H. Chowdhury, S. Rajbangshi, M. Karim, S. Ghosh, S.E. Kabir, T.A. Siddiquee, V.N. Nesterov, M.G. Richmond, Inorg. Chim. Acta 2015, 434, 97.

249. “Synthesis, structure and bonding of new mono- and dinuclear molybdenum complexes

containing pyridine-2-thiolate (pyS) and different P-donors,” Md. R. Haque, S. Ghosh, M.G. Richmond, S.E. Kabir, Inorg. Chim. Acta 2015, 434, 150.

250. “Palladium(0)-mediated C-H bond activation of N-(naphthyl)salicylaldimine and related

ligands: Utilization of the resulting organopalladium complexes in catalytic C-C and C-N coupling reactions,” J. Dutta, M.G. Richmond, S. Bhattacharya, Dalton Trans. 2015, 44, 13615.

251. “Non-Heme Fe(IV)-oxo Complexes of Two New Pentadentate Ligands and Their

Reactivities Towards Hydrogen- and Oxygen-Atom Transfer Reactions,” M. Mitra, H. Nimir, S. Demeshko, M. Haukka, J. Lloret-Fillol, F. Meyer, A.A. Shteinman, W.R. Browne, D.A. Hrovat, M.G. Richmond, M. Costas, E. Nordlander, Inorg. Chem. 2015, 54, 7152.

252. “Syntheses and Characterization of Alkyl and Amide Complexes

TaX2(=NSiMe3)[N(SiMe3)2] (X = Me, CH2Ph, NMe2, NEt2). Unusual α-SiMe3 Abstraction by an Amide Ligand to Give an Imide Ligand,” S.C. Hunter, S.-J. Chen, M.G. Richmond, Z.L. Xue, Organometallics 2015, 34, 5687.

32

Publications: Richmond, Michael G. 253. “Iron carbonyl complexes bearing phenazine and acridine ligands: X-ray structures of

Fe(CO)3(η4-C12H8N2), Fe(CO)2{P(OMe)3}(η4-C12H8N2), Fe(CO)2(PPh3)(η4-C13H9N) and Fe(CO)2(κ1-dppm)(η4-C12H8N2),” M.A.H. Chowdhury, M.S. Rahman, M.R. Islam, S. Rajbangshi, S. Ghosh, G. Hogarth, L. Yang, M.G. Richmond, S.E. Kabir, Manuscript, J. Organomet. Chem. 2016, 805, 34.

254. “Thermal transformations of tris(2-thienyl)phosphine (PTh3) at low-valent ruthenium

cluster centres: Carbon-hydrogen, carbon-phosphorus and carbon-sulfur bond activation yielding [(µ-H)Ru3(CO)8L{µ-Th2P(C4H2S)}] (L = CO, PTh3), [Ru3(CO)6(µ-PTh2)2(µ3-η2-C4H2S)], [Ru4(CO)9(µ-CO)2(µ4-η2-C4H2S)(µ4-PTh)] and [Ru5(CO)11(µ-PTh2)(µ4-η4-C4H3)(µ4-S)],” M.M. Uddin, N. Begum, S. Ghosh, J.C. Sarker, D.A. Tocher, G. Hogarth, M.G. Richmond, E. Nordlander, S.E. Kabir, J. Organomet. Chem. 2016, 812, 197. Invited Contribution to the Special Jack Lewis Memorial Issue.

255. “Biomimetics of the iron-only hydrogenase enzyme: Evaluation of the small bite-angle

diphosphine complex Fe2(CO)4{κ2-Ph2PC(Me2)PPh2}(µ-pdt) as a proton-reduction catalyst,” S. Ghosh, B.E. Sanchez, I. Richards, M.N. Haque, K.B. Holt, M.G. Richmond, G. Hogarth, J. Organomet. Chem 2016, 812, 247. Invited Contribution to the Special Lord Jack Lewis Memorial Issue.

256. Microwave-induced dppm ligand substitution in triosmium clusters: Structural and DFT

evaluation of Os3 clusters containing multiply activated dppm ligands through cyclometalation, ortho metalation, and P-C bond cleavage,” J.Y. Jung, D.K. Kempe, S.-H. Yoon, N. Gwini, A.G. Fikes, D.M. Marolf, M.L. Parker, J.E. Johnstone, G.L. Powell, L. Yang, V.N. Nesterov, M.G. Richmond, J. Organomet. Chem. 2016, 813, 15.

257. “Isomerisation of the osmium-tellurium cluster Os3(µ-TeR)2(CO)10: A kinetic and

computational study,” E.K.S. Shim, W.K. Leong, Y.-Z. Li, M.G. Richmond, Dalton Trans. 2016, 45, 7158.

258. “Hydrogenase biomimetics with redox-active ligands: Electrocatalytic proton reduction

by [Fe2(CO)4(κ2-diamine)(µ-edt)] (diamine = 2,2′-bipy, 1,10-phen),” S. Ghosh, A. Rahaman, K.B. Holt, E. Nordlander, M.G. Richmond, S.E. Kabir, G. Hogarth, Polyhedron 2016, 116, 127. Invited Contribution to the Malcolm Green Commemorative Manuscript.

259. “Diphosphine-bridged digold(I) compounds: Structural and computational studies on the

aurophilic interaction in Au2Cl2(µ-bpcd) and Au2Cl2(µ-bmi),” R. Nyamwihura, L. Yang, V.N. Nesterov, M.G. Richmond, J. Mol. Struct. 2017, 1129, 188.

260. “Catalytic C-H oxidations by non-heme mononuclear Fe(II) complexes of pentadentate

ligands: Evidence for Fe(IV) oxo intermediate,” M. Mitra, H. Nimir, D.A. Hrovat, A.A. Shteinman, M.G. Richmond, M. Costas, E. Nordlander, J. Mol. Catal. A 2017, 426, 350.

33

Publications: Richmond, Michael G. 261. “5,7-Dihydroxy-2-(4-hydroxyphenyl)chroman-4-one (naringenin): X-ray diffraction

structures of the naringenin enantiomers and DFT evaluation of the preferred ground-state structures and thermodynamics for racemization,” V.V. Nesterov, L.N. Zakharov, V.N. Nesterov, J.G. Calderon, A. Longo, K. Zaman, F.K. Choudhury, W. Farrell, V. Shulaev, M.G. Richmond, J. Mol. Struct. 2017, 1130, 994.

262. “Reversible C-H bond activation at a triosmium centre: A comparative study of the

reactivity of unsaturated triosmium clusters Os3(CO)8(μ-dppm)(μ-H)2 and Os3(CO)8(μ-dppf)(μ-H)2, with activated alkynes” M.A.H. Chowdhury, M.R. Haque, S. Ghosh, S.M. Mobin, D.A. Tocher, G. Hogarth, M.G. Richmond, S.E. Kabir, H.W. Roesky, J. Organomet. Chem. 2017, 836-837, 68.

263. “Mixed Main Group Transition Metal Clusters: Reactions of [Ru3(CO)10(μ-dppm)] with

Ph3SnH,” M.M.M. Khan, S. Ghosh, G. Hogarth, D.A. Tocher, M.G. Richmond, H.W. Roesky, S.E. Kabir, J. Organomet. Chem. 2017, 840, 47.

264. “Reactions of [Ru3(CO)10(μ-dppm)] with Ph3GeH: Ge–H and Ge–C bond cleavage of

Ph3GeH at a triruthenium cluster,” M.M.M. Khan, S. Ghosh, A. Rahaman, D.A. Tocher, M.G. Richmond, S.E. Kabir, J. Organomet. Chem. 2017, 843, 75.

265. “Syntheses and catalytic oxotransfer activities of oxidomolybdenum(VI) complexes of a

new aminoalcohol phenolate ligand,” M.K. Hossain, M. Haukka, R. Sillanpää, D.A. Hrovat, M.G. Richmond, E. Nordlander, A. Lehtonen, Dalton Trans. 2017, 46, 7051.

266. “Ambidentate ligand reactivity with the rhenium(I) compounds [BrRe(CO)4]2 and cis-

BrRe(CO)4L: A kinetic and mechanistic study,” D. Mayberry, V.N. Nesterov, M.G. Richmond, Eur. J. Inorg. Chem. 2017. 3990.

267. “The reactions of Os3(CO)12 with triphos {MeC(CH2PPh2)3}: A case of multiple C-P and

C-H bond activations,” J.Y. Jung, D.M. Marolf, S.-H. Yoon, C.B. Powell, G.L. Powell, L. Yang, V.N. Nesterov, M.G. Richmond, J. Organomet. Chem. 2017, 849-850, 125. Invited Richard D. Adams 70th Birthday Commemorative Manuscript.

268. “Reactions of the face-capped benzothiazolate-substituted clusters Os3(CO)9(µ3,η2-

C7H3NSR)(µ-H) (R = H, Me) with PPh3: Kinetic formation of Os3(CO)9(PPh3)(µ,η2-C7H3NSR)(µ-H) and thermally induced ligand isomerization” Md. A.H. Chowdhury, S.A. Begum, S. Ghosh, D.A. Tocher, M.G. Richmond, E. Rosenberg, S.E. Kabir, J. Organomet. Chem. 2017, 849-850, 337. Invited Richard D. Adams 70th Birthday Commemorative Manuscript.

34

Publications: Richmond, Michael G. 269. “Alkyne activation and polyhedral reorganization in benzothiazolate-capped osmium

clusters on reaction with diethyl acetylenedicarboxylate (DEAD) and ethyl propiolate,” K.M. Uddin, M.A.H. Chowdhury, M.K. Hossain, S. Ghosh, D.A. Tocher, M.G. Richmond, S.E. Kabir, Dalton Trans. 2017, 46, 13597.

270. “Synthesis and redox properties of fac-BrRe(CO)3[1,2-(PPh2)2-closo-1,2-C2B10H10]: the

first structurally characterized rhenium carbonyl containing a carboranyl-based diphosphine ligand,” C.-H. Lin, V.N. Nesterov, M.G. Richmond, J. Mol. Struct. 2018. 1156, 397.

271. “Electrocatalytic proton reduction catalysed by thiolate-capped triiron clusters

[Fe3(CO)9(μ3-SR)(μ-H)] (R = iPr, tBu),” S. Ghosh, S. Basak-Modi, M.G. Richmond, E. Nordlander, G. Hogarth, Inorg. Chim. Acta 2018, 480, 47.

272. “Synthesis and molecular structures of the 52-electron triiron telluride clusters

[Fe3(CO)8(µ3-Te)2(κ2-diphosphine)] - electrochemical properties and activity as proton reduction catalysts,” A. Rahaman, G.C. Lisensky, D.A. Tocher, M.G. Richmond, G. Hogarth, E. Nordlander, J. Organomet. Chem. 2018, 867, 381. Invited Irina Beletskaya 85th Birthday Commemorative Manuscript.

273. “Ligand-induced thiolate-bridge scission of [Re(CO)3(μ-thpymS)]2 (where thpymS =

1,4,5,6-tetrahydropyrimidine-2-thiolate): Structural and computational studies of configurational isomers of [Re(CO)3(κ2-thpymS)]2(dppe)],” M.R. Moni, S. Ghosh, S.M. Mobin, D.A. Tocher, G. Hogarth, M.G. Richmond, S.E. Kabir, J. Organomet. Chem. 2018, 871, 167.

274. “Mixed-valence dimolybdenum complexes containing hard oxo and soft carbonyl

ligands: Synthesis, structure and electrochemistry of Mo2(O)(CO)2(μ-к2-S(CH)nS)2(к2-diphosphine),” M.R. Haque, S. Ghosh, T.A. Siddiquee, V.N. Nesterov, M.G. Richmond, G. Hogarth, S.E. Kabir, Dalton Trans. 2018, 47, 10102.

275. “A diphosphine-carbonyl complex of ruthenium: An efficient precursor for new

complexes and C-C and C-N bond coupling catalysis,” A. Mukherjee, D.A. Hrovat, M.G. Richmond, S. Bhattacharya, Dalton Trans. 2018, 47, 10264.

276. Synthesis of the labile rhenium(I) complexes fac-Re(CO)3(L)[κ2-O,O-FcC(O)CHC(O)Me]

(where Fc = ferrocenyl; L = THF, H2O, alkyne) and alkyne addition to the diketonate ligand,” S. Atim, L. Yang, V.V. Nesterov, X. Wang, M.G. Richmond, J. Organomet. Chem. 2018, 874, 1.

277. Experimental and computational preference for phosphine regioselectivity and

stereoselective tripodal rotation in HOs3(CO)8(PPh3)2(µ-1,2-η1,κ1-C7H4NS),” S.A. Begum, M.A.H. Chowdhury, S. Ghosh, D.A. Tocher, L. Yang, M.G. Richmond, K.I. Hardcastle, E. Rosenberg, S.E. Kabir, RSC Adv. 2018, 8, 32672.

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Publications: Richmond, Michael G. 278. “Hydrogenase biomimetics with redox-active ligands: Synthesis, structure and

electrocatalytic studies on Fe2(CO)4(κ2-dppn)(µ-edt) (edt = ethanedithiolate; dppn = 1,8-bis(diphenylphosphino)naphthalene),” S. Ghosh, S. Rana, N. Hollingsworth, M.Richmond, S.E. Kabir, G. Hograth, Inorganics 2018, 6, 122.

279. “Highly efficient electrocatalytic proton-reduction by coordinatively and electronically

unsaturated Fe(CO)(κ2-dppn)(κ2-tdt),” S. Ghosh, S. Rana, S.E. Kabir, M.G. Richmond, G. Hogarth, Inorg. Chim. Acta 2019, 486, 435. Invited Malcolm Green Commemorative Manuscript.

280. “Chalcogenide-capped triiron clusters [Fe3(CO)9(µ3-E)2], [Fe3(CO)7(µ3-CO)(µ3-E)(µ-

dppm)] and [Fe3(CO)7(µ3-E)2(µ-dppm)] (E = S, Se) as proton-reduction catalysts,” A. Rahaman, S. Ghosh, S. Basak, A. Adbel-Magied, S.E. Kabir, M. Haukka, M.G. Richmond, G. Lisensky, E. Nordlander, G. Hogarth, J. Organomet. Chem. 2019, 880, 213. Invited Richard J. Puddphatt 75th Birthday Commemorative Manuscript.

281. “Activation of thiosaccharin at a polynuclear osmium center,” M.M. Rahman, T. Pinky,

M.M. Alam, S. Ghosh, K.A. Azam, D.A. Tocher, M.G. Richmond, S.E. Kabir, J. Organomet. Chem. 2019, 880, 233. Invited Richard J. Puddphatt 75th Birthday Commemorative Manuscript.

282. “Hydrogenase biomimetics containing non-innocent redox-active ligands: Fe2(CO)4(µ-

edt)(κ2-bpcd) with electron-withdrawing 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) acting as an [Fe4-S4]H surrogate,” S. Ghosh, N. Hollingsworth, M. Warren, M.G. Richmond, G. Hogarth, Manuscript, Submitted to Dalton Trans. 2018.

283. “Synthesis and computational investigation of the new ß-diketiminidate-substituted

tantalum(V) compounds TaL(NMe2)3[κ2-N(Pri)C(Me)CHC(Me)N(Pri)] (where L = Cl, NMe2, and allyl),” L.Yang, S.-H. Huang, V.N. Nesterov, M.G. Richmond, Manuscript, In Preparation.

284. “Reactivity of Mo(CO)3(NCMe3) towards pyrimidine-2-thiol (pymSH) and thiophenol

(PhSH) in the presence of triphenylphosphine and dppm auxiliary ligands: Synthesis of bi- and mononuclear complexes bearing κ2 and µ-κ2-pymS coordination motifs,” X.X. Roknuzzaman, S.M.T. Abedin, M.R. Haque, S. Ghosh, D. Tocher, M.G. Richmond, S.E. Kabir, Manuscript, In Preparation.

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Biographical Sketch Michael G. Richmond was born in New York and attended the State University of New York College at Fredonia, from which he received a B.S. degree in Chemistry in 1980. Dr. Richmond next pursued his graduate studies at the University of Alabama under the joint supervision of Drs. Charles U. Pittman, Jr., and David C. Baker. Dr. Richmond received his Ph.D. in Organic Chemistry in December, 1983. After serving as a postdoctoral fellow with Dr. Jay K. Kochi at Indiana University/University of Houston during the period of September, 1983, to August, 1984, Dr. Richmond accepted an appointment as a Visiting Assistant Professor of Chemistry at the University of Houston. This position was held from September, 1984, to August, 1986, and carried with it the responsibility for the direction of the Kochi laboratory, including complete control over the day-to-day operation, maintenance, and supervision of all graduate and postdoctoral personnel working for Jay K. Kochi. Dr. Richmond accepted the position of Assistant Professor of Chemistry at the University of North Texas in 1986. In September of 1992, Dr. Richmond was promoted to Associate Professor of Chemistry at the University of North Texas, followed by promotion to Professor of Chemistry in 1998. Starting in 2015, Dr. Richmond reassumed the positon of Chair of the Department of Chemistry until 2018, a post he has previously held from 2007-2009. Dr. Richmond has been engaged in research involving platinum group metals for the last several years; the majority of this research has dealt with the syntheses and ligand activation studies of mono- and polynuclear organometallic compounds. The redox properties, dynamic ligand behavior, and catalytic reactivity of platinum group metal complexes have also been explored. Currently, high-pressure catalytic investigations of selected platinum metal cluster compounds are being studied by in situ Cylindrical Internal Reflectance (CIR) Spectroscopy in order to accurately assess the nature of the active catalyst in hydroformylation and hydrogenation reactions. Dr. Richmond’s current research interests are centered on the study of P-C bond cleavage on metal clusters, carbon dioxide reduction, hydrocarbon activation, organometallic redox reactions, and photocatalytic processes employing transition metal complexes. New materials capable of serving as single-source precursors for the deposition of TaN, Ru, and Lu thin films remaining under active investigation, as well as the computational investigation of fundamental processes involved in catalysis and bond-activation processes. Currently, Dr. Richmond is the author of over 275 publications and two chapters in the monograph series “Catalysis of Organic Reactions.” From 1988 through 1993, Dr. Richmond served as the author for the Annual Survey of Ruthenium and Osmium Chemistry for the Journal of Organometallic Chemistry at the invitiation of Prof. R. Bruce King. From 1994 to 2003, Dr. Richmond has served as the author for the Annual Review of Organometallic Cluster Chemistry for Coordination Chemical Reviews. Presently, Dr. Richmond serves, or has served on, the editorial advisory boards of the journals Organometallics, Journal of Organometallic Chemistry, Open Journal of Inorganic Chemistry, Journal of Thermodynamics and Catalysis, and Universal Organic Chemistry.