presentation on bioproducts

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  • 7/25/2019 Presentation on Bioproducts

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    Picture 1. Voikkaa paper mill.

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    Picture 1. Voikkaa paper mill.

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    Concomitant production of dissolving pu

    polymeric xylan and lignin from birch wo

    OBJECTIVES

    Examine how dissolving pulp,polymeric xylan and ligninproduction can be combined

    New value-added productsfrom noncellulosic sidestreams

    Taneli Rautio

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    Concomitant production of dissolving pu

    polymeric xylan and lignin from birch wo

    1. Process flowchart and structure

    2. Comparison with existing

    technology

    3. Feasibility and conclusion

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    1. Process flowchart

    Polymeric

    Xylan

    Dissolving

    PulpLignin

    Precipitation

    Washing ofsolid residue

    Pre-hydrolysis

    Alkaline pre-extraction

    Birch chips

    Nano- anddiafiltration

    SAQ pulping

    Overliming,DTAC

    Figure1. Hierarchy of combined production.

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    Process structure

    1. Mechanical treatment of birch

    2. Alkaline pre-extraction, NaOH/95oC3. Washing of solid residue

    4. Pre-hydrolysis of solid residue, 160-180oC

    Removal of hemicelluloses by autohydrolysis

    5. Soda-anthraquinone (SAQ) pulping, SAQ/160oC

    Delignification and bleaching to get dissolving Isolation of lignin from PHL with Overliming/D

    6. Nano- and diafiltration

    7. Precipitation

    Polymeric xylan

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    2. Comparison with existing technolo

    Benefits+ High-quality products

    + Products have diverseapplications and economicalvalue

    + Refining of all sidestreamscan be localized

    Transportation costs can beminimized

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    2. Comparison with existing technolo

    Benefits+ High-quality products

    + Products have diverseapplications and economicalvalue

    + Refining of all sidestreamscan be localized

    Transportation costs can beminimized

    Disadvantages- Dissolving pulp productrequires larger facilities tkraft pulp production

    - Pre-extraction affects

    dissolving pulp and polymxylan yield

    - Requires lots of optimiz

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    Figure 2. Graph showcasing the combined production.

    Birch Wood

    Pre-Extraction,

    Cooking andPulping

    New Products

    and

    Applications

    Dissolving

    PulpPolymeric

    XylanLignin

    3. CONCLUSION Alkaline production

    methods have pote

    Production of new pconsidered economfeasible

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    Figure 2. Graph showcasing the combined production.

    Birch Wood

    Pre-Extraction,

    Cooking andPulping

    New Products

    and

    Applications

    Dissolving

    PulpPolymeric

    XylanLignin

    3. CONCLUSION Alkaline production

    methods have pote

    Production of new pconsidered economfeasible

    Market succe More efficien

    processes

    FUTURE OUTLOO

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    Picture 2. nekoski Bioproduct mill

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    QUESTIONS?

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    References

    Testova, L., Roselli, A., Costabel, L., Kovasin, K., Tenkanen, M., Sixta, H., Combined Production of Polymeric Birch Xylan and Paper Pulp by Alkaline Pre-eFollowed by Alkaline Cooking, ACS Publications 2014

    Sixta, H., Handbook of Pulp, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 2006

    Kamm, B., Gruber, P., Kamm, M., Biorefineries

    Industrial Processes and Products. Status Quo and Future Directions. Vol. 1, WILEY-VCH Verlag GmbH &Weinheim 2006

    Shi, H., Fatehi, P., Xiao, H., Ni, Y.,A process for isolating lignin of pre-hydrolysis liquor of kraft pulping process based on surfactant and calcium oxide trBiochemical Engineering Journal 68 (2012) 19-24