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Page 1: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

P're Design Report

S R O O I 9 I 7

Page 2: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

PREDESIGN REPORT

BLOSENSKI LANDFILLCHESTER COUNTY, PENNSYLVANIA

APPENDIX 5-1

Page 3: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

QBRiEN 5 GE

September 25, 1990

Mr. Lewis LuchieRegional Water Quality ManagerPennsylvania Department of Environmental Resources1875 New Hope StreetNorristown, PA 19401

Re: Blosenski Landfill Superfund SiteWest Cain TownshipChester County

File: 3277.001

Dear Mr. Luchie:

Enclosed are three copies of an "Application for Discharge of Groundwater to Surface Waters ofthe State of Pennsylvania" pertaining to an aquifer performance test to be conducted at the abovereferenced site. By this application, notification is provided of intent to conduct this testing fromOctober 16, 1990 to October 18, 1990.

Aquifer performance testing will be limited to one 56-hour period and will involve less than 135,000gallons of groundwater pumped from one test well. The groundwater may contain low ppm levelsof VOCs. Groundwater pumped during the aquifer performance test will be treated through an airstripper. Air stripper offgas will be treated by activated carbon adsorption. The maximumprojected release of VOCs to an unnamed, intermittent tributary of Indian Spring Run is expectedto be less than 5 pounds.

The on-site temporary groundwater treatment system will be supplied and operated by OBGTechnical Services, Inc., a subcontractor to O'Brien and Gere Engineers, Inc. O'Brien and GereEngineers has contracted with the U.S. Army Corps of Engineers to prepare pre-design documentsto be used for design of the site cleanup. Our scope of services for this project includes conductingthis short-term on-site testing to support the preliminary design of ground water recovery andtreatment facilities.

O'Brien & Gere Engineers, Inc., an O'Brien & Gere Limited Company"""00 3'ittonfieid Parkway / PO Box '—" -... -

anc offices in major U.S. cities

« «,,«.. v*. >^wii> i_iiv^tii\,^t^, iiiw., aii w uiiidi m V^K^IC i_nimeu wurnuany5000 Bnnonfield Parkway / PO Box 4873 / Syracuse. NV 13221 7(315) 437-6100 FAX (315) 4 3- 5 ^ I Q i Q

Page 4: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

Mr. Lewis LuchieSeptember 25, 1990Page -2-

Please contact me or John LaManche at (315) 437-6100 with any questions or comments.

Very truly yours,

O'BRIEN & GERE ENGINEERS, INC.

J. Kevin Farmer,Managing Engineer

cc: John J. Keegan, O'Brien and Gere Engineers, Inc.John J. LaManche, O'Brien and Gere Engineers, Inc.Geoffrey J. Seibel, O'Brien and Gere Engineers, Inc.James A. Fox, OBG Technical Services, Inc.

BROOI920

Page 5: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

9/25/90APPLICATION FOR DISCHARGE pp OROT7NDWATFP

TO SURFACE WATERS OF THE STATF pF

Name of Discharge Location: Blosenski Landfill Superfund Site

Location: West Cain Township, Chester County, Pennsylvania (40°0ri2" N, 75°54'33"W)

Description of Discharge: Treated groundwater discharge from 8 hour well drawdown test and 48hour aquifer pump test.

Operator of Discharge: OBG Technical Services, Inc., Syracuse, NY 13221

Location of Discharge Source: Test well located on the Blosenski Landfill Site (see enclosed figure).

Anticipated Date(s) of Discharge: October 16-18, 1990 (56 hours duration)

Receiving Water: Intermittent unnamed tributary of Indian Spring Run located 500 feet north ofthe site.

Anticipated Quality of Discharge Source (untreated): See Table 1 for anticipated characteristics.

Anticipated Quality of Discharge Source (treated): See Table 2 for anticipated characteristics.

Anticipated Quantity of Discharge: 33,600 gallons - 134,400 gallons (10-40 gpm; 56 hours)

Treatment Technologies for Groundwater: Air stripping and vapor phase carbon adsorption.

SROOI92I

Page 6: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

9/25/90

TABLE 1

BLOSENSKI LANDFILL SUPERFUND SITERAW GROUNDWATER CHARACTERISTICS

Substance Maximum Concentration fug/LV*

Benzene 11,000Toluene 600Ethylbenzene 54Total Xylenes 78Chlorofaenzene 341,1,1-Trichloroethane 4301,2-Dichloroethane 741,1-Dichloroethane 270Chloroethane 93Tetrachloroethane 5Trichloroethene 2601,2-Dichloroethene 8901,1-Dichloroethene 21Vinyl Chloride 450Chloroform 270Methylene Chloride 2,000Acetone 43,0002-Butanone 3502-Hexanone 214-Methyl-2-pentanone 7

* Maximum concentration taken from Table 1.0 of the September 29, 1986 United States EPASuperfund Record of Decision: Blosenski Landfill, PA (EPA/ROD/R03-86/029). These data weredeveloped from samples collected in late 1984 and early 1985 during the Remedial Investigation.The total mass of these substances in the untreated influent should not exceed 60 pounds and islikely to be considerably less.

ftROOI922

Page 7: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

9/25/90TABLE 2

BLOSENSKI LANDFILL SUPERFUND SUEANTICIPATED TREATED GROUNDWATER CHARACTERISTICS*

Substance Maximum Concentration (usfL) **BenzeneTolueneEthylbenzeneTotal Xylenes <50Chlorobenzene <51,1,1-Trichloroethane <501,2-Dichloroethane <501,1-Dichloroethane <50Chloroethane <50TetrachloroethaneTrichloroethene1,2-Dichloroethene1,1-DichloroetheneVinyl ChlorideChloroformMethylene Chloride

<°-Butanone2-Hexanone4-Methyl-2-pentanone

* Treatment to consist of air stripping and vapor phase carbon adsorption.

fTabS'Tt?0 56 ?ncentf ions derived ed on maximum influent concentrations{.lame 1), stopping column characteristics, air and wafpr fl™, ,* u- ^ T

flROOI923

Page 8: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

DIRECT LINE NO. (315) 463-7554

QBRHEN 5 GERE

DATE: IQ/-2.4

NUMBER OF PAGES BEING SENT 3 (INCLUDING THIS ONE).

TO: ___

COMPANY

TELEPHONE ) 27C -

F ROM: KeJ /AS/

MESSAGE:

fafc THC

•5>i6-4r37 -<*V

IF YOU DO NOT RECEIVE ANY OF THESE PAGES PLEASE CONTACTTHE TELECOPY OPERATOR AT {315} 437-1990 EXTENS10N1593 ASSOON AS POSSIBLE.

THANK YOU

TRANSMISSION COMPLETED AND CONFIRMED

DATE ____________ TIME _____SIGNATURE

O'Brien & Gv Engineers. Inc., an O'Brien & Gere Limited Company H B U ' 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554

Page 9: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

October 23, 1990

Mr. Lewis LuchieRegional Water Quality ManagerPennsylvania Department of Environmental Resources1875 New Hope StreetNorristown, PA 19401

Re: Blosenski Landfill Superfund SiteWest Cain TownshipChester County

File: 3277.001

Dear Mr. Luchie:

A letter to your department dated September 25, 1990 included three copies of an "Application forDischarge to Surface Waters of the State of Pennsylvania" pertaining to an aquifer performance testto be conducted at the above referenced site. Steve O'Neill of PADER has requested thatadditional information pertaining to the sampling of the air stripper influent and effluent aqueousstreams be provided. This letter contains the sampling plan approved by the U.S. Army Corps ofEngineers for the samples that will be collected during the aquifer performance test and indicatesthe analytical methods that will be used to conduct the analyses.

Samples will be collected from the air stripper influent and effluent aqueous streams for each ofeight air to liquid ratios to be investigated. These samples will be tested in the laboratory forvolatile organics by EPA Method 8010/8020. Air stripper influent and effluent aqueous sampleswill also be collected on two occasions and analyzed for pH, total suspended solids, chemical oxygendemand, biochemical oxygen demand, and total organic carbon. Air stripper influent and effluentaqueous samples will also be collected on one occasion and tested for priority pollutant metals,base/neutral/acid extractables (EPA Method 8270), pesticides/PCBs (EPA Method 8080), totalKjeldahl nitrogen, ammonia, oil and grease, phosphorus, chloride, sulfate, and total coliforms (EPAMethod 9131). The air stripper effluent aqueous stream from the stripper will also be analyzed onone additional occasion for base/neutral/acid extractables and pesticides/PCBs.

Aquifer pump testing is expected to commence on Tuesday, October 30,1990. It is anticipated thatthe samples will collected on October 30 and 31,1990 during daylight hours (7:00 a.m. to 7:00 p.m.).It is expected that two to four air stripper influent and effluent samples will be collected on October30 and four to six such samples will be collected on October 31.

O'Brien & Gere Engineers. Inc.. an O'Brien i Gere Limited Comoany " **5CCO Bm-onfieia Parkwav / FO Box-871 Sv~.c'_se. ',v ' 322' •": ~) -i^~-n".CZ

Page 10: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

Mr. Lewis LuchieOctober 23, 1990Page -2-

The analytical results generated by the sampling plan described above should provide sufficient datato characterize this discharge to surface water. Please feel free to contact me or John LaMancheat (315) 437-6100 with any questions or comments.

Very truly yours,

O'BRIEN & GERE ENGINEERS, INC.

7f • .- N ->~__ ,^/&^^_,———————

J. Kevin Farmer, PJE.Managing Engineer

wp-4

cc: John J. Keegan, O'Brien & Gere Engineers, Inc.John J. LaManche, O'Brien & Gere Engineers, Inc.Geoffrey J. Seibel, O'Brien & Gere Engineers, Inc.James A. Fox, OBG Technical Services, Inc.

SROOI926

Page 11: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

September 25, 1990

Mr. Thomas McGinleyEngineering Services ChiefPennsylvania Department of Environmental Resources1875 New Hope StreetNorristown, PA 19401

Re: Blosenski Landfill Superfund SiteWest Cain TownshipChester County

File: 3277.001

Dear Mr. McGinley:

Enclosed are three copies of a completed "Request for Determination of Requirement for PlanApproval/Operating Permit Application" pertaining to an aquifer performance test to be conductedat the above referenced site. By this application, an exemption is sought from plan approval andpermitting requirements for this source pursuant to the authority contained in 25 PA Code Section127.14(8).

Aquifer performance testing will be limited to one 56-hour period and will involve less than 135,000gallons of groundwater pumped from one test well. This temporary on-site testing is planned tocommence October 16, 1990 and end October 18, 1990. The groundwater may contain low ppmlevels of VOCs. Groundwater pumped during the aquifer performance test will be treated throughan air stripper. Air stripper offgas will be treated by activated carbon adsorption. The maximumprojected release of air toxics is less than 50 pounds.

The on-site temporary groundwater treatment system will be supplied and operated by OBGTechnical Services, Inc., a subcontractor to O'Brien and Gere Engineers, Inc. O'Brien and GereEngineers has contracted with the U.S. Army Corps of Engineers to prepare pre-design documentsto be used for design of the site cleanup. Our scope of services includes conducting thic short-termon-site testing to support the preliminary design of ground water recovery and treatment facilities.

O'Brien & Gere Engineers, Inc., an O'Brien & Gere Limited Company fl[ R 0 0 « J £• '5000 Britionfield Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-755'4

ana offices in ma/or U.S. cities

Page 12: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

Mr. Thomas McGinleySeptember 25, 1990Page -2-

Please contact me or John LaManche at (315) 437-6100 with any questions or comments.

Very truly yours,

O'BRIEN & GERE ENGINEERS, INC.

(_XJ. Kevin Farnfer, P.E.Managing Engineer

cc: John J. Keegan, O'Brien and Gere Engineers, Inc.John J. LaManche, O'Brien and Gere Engineers, Inc.Geoffrey J. Seibel, O'Brien and Gere Engineers, Inc.James A. Fox, OBG Technical Services, Inc.

flROOI928

Page 13: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

_ --17 R«v. 9/83 -

COMMONWEALTH OF PENNSYLVANIADEPARTMENT OF ENVIRONMENTAL RESOURCES

BUREAU OF AIR OUAUTY CONTROL

Request for Determination of Requirementfor Plan Approval/Operating Permit Application

(Submit In Triplicate)Blosenski Landfill GroundwaterAir Stripper Offgas _ , . „ . Oct. 16-18 1990p- tf Source: _______11____-—————'— Date of Installation: 10> iy*uU.S. Army Corps of Engineers for

of Sourea: Joseph M.. Blosenski. Jr. Employer l.D. No.: _JLS_________%0'Brien & Gere Engineers, Inc., 5000 Brittonfield Pkwy, P.O. Box 4873,

lihng Address: Syracuse. NY 1322l ___________________________________.

D———. J. Kevin Farmer______ Telephone: ' f3151 437-6100______U'Brien § Gere Engineers, Inc.

cation of Sourcata):

Kings Highway Route 540 Municipality: West Cain Township

tt ,ted Emissions: County: Chester County

Pouutant

IH»W

Q ntrty•us/yr

VOCs

0.85

48

Vice'^President, O'Brien § Gere Engineers,TitleSeptember 25, 1990_______________Date

OFFICIAL USE ONLY

Received: .«——•«_«»_ ________ — — —— Reviewed 3y:

r««rttto tft« autnomv contained in 23 PA Code «1 27.1-W8) ttw TtwcoureaO) do«nat oua«V *w txtmonon from crf«n aacraval/oor-ureaisi is txamottd from tft« aian aoortvii and gt> nutting rw mttnng rvouifaRMMia undtr PA Cod* i 1 27. 1 4(8) and oi»n aoorovai

to. This d«tim»inanon do«s not ucwnot ttt* sources) from aooticaeortsi must b« sutentnd. Th« Otoarcmont is oranibttad fromm ne* with all otfl«r aaoiicafit* air quality ragtjJaoons. acting on an aooiieanon until 30. davs after m« muntaoaiitv and

county hav« recaiv«d noofieaoon by ttw comoany. ?wtin«r« formsan anaehtd.

Tin*

Oan flRQQ1929

Page 14: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

,ton*u*a ww*~.—jr ow*.. .—.. ,-.-- - ............... _,,-_..„, ,, ,<at.~Ajdfy/t-

(Indude: procasa description, axhaust volume, stack data, schematic flow diagram, material data safaty sheet, steSee following sheets for Process description, etc.

OFFICIAL USE ONLY

Remarks:

SROOI930

Page 15: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

9/25/90

AIR DISCHARGE PROCESS DESCRIPTION. ETC.

Name of Discharge Location: Blosenski Landfill Superfund Site

Location: West Cain Township, Chester County, Pennsylvania (40°01'12" N, 75"54'33"W)

Description of Discharge: Treated offgas discharge from air stripping of pumped groundwaterdeveloped during 8 hour well drawdown test and 48 hour aquifer pumptest.

Operator of Discharge: OBG Technical Services, Inc., Syracuse, NY 13221

Anticipated Date(s) of Discharge: October 16-18, 1990 (56 hours duration)

Anticipated Quality of Groundwater Source (untreated): See Table 1 for anticipated characteristics.

Anticipated Quality of Groundwater Source (treated): See Table 2 for anticipated characteristics.

Anticipated Quantity of Discharge: 333,600 cubic feet - 6,720,000 cubic feet (100-2000 cfhi; 56hours)

Treatment Technologies for Ain Vapor phase carbon adsorption.

flROOI93l

Page 16: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

9/25/90

TABLE 1

BLOSENSKI LANDFILL STJPERFUND SITERAW GROUNDWATER CHARACTERISTICS

Substance Maximum Concentration fug/L)*

Benzene 11,000Toluene 600Ethylbenzene 54Total Xylenes 78Chlorobenzene 341,1,1-Trichloroethane 4301,2-Dichloroethane 741,1-Dichloroethane 270Chloroethane 93Tetrachloroethane 5Trichloroethene 2601,2-Dichloroethene 8901,1-Dichloroethene 21Vinyl Chloride 450Chloroform 270Methylene Chloride 2,000Acetone 43,0002-Butanone 3502-Hexanone 214-Methyl-2-pentanone 7

* Maximum concentration taken from Table 1.0 of the September 29, 1986 United States EPASuperfund Record of Decision: Blosenski Landfill, PA (EPA/ROD/R03-86/029). These data weredeveloped from samples collected in late 1984 and early 1985 during the Remedial Investigation.The total mass of these substances in the untreated influent should not exceed 60 pounds and islikely to be considerably less.

8ROQI932

Page 17: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

9/25/90TABLE 2

BLOSENSKI LANDFILL SUPERFUND SITEANTICIPATED TREATED GROUNDWATER CHARACTERISTICS* '

Substance Maximum Concentration fap/r ) **

BenzeneToluene <50EthylbenzeneTotal Xylenes <50Chlorobenzene <51,1,1-Trichloroethane <501,2-Dichloroethane <501,1-Dichloroethane ,,..50Chloroethane <50Tetrachloroethane < Trichloroethene <501,2-Dichloroethene <501,1-Dichloroethene <5Vinyl Chloride <50Chloroform <50Methylene Chloride <50Acetone <50QO2-Butanone <3QO2-Hexanone < in4-Methyl-2-pentanone <5

* Treatment to consist of air stripping and vapor phase carbon adsorption.

** 5PecJed discharge concentrations derived based on maximum influent concentrations(T?5. P' sfriPPkg c011111111 characteristics, air and water flow rates, Henry's Law constantssolubilities, temperatures, and other pertinent physical characteristics. These estimate dischargeconcentrations are very conservative. Actual discharge concentrations are expected to beconsiderably lower than the values identified above.

flROOI933

Page 18: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

COMMONWEALTH OF PENNSYLVANIADEPARTMENT OF ENVIRONMENTAL RESOURCES

E PENNSYLVANIA•••••HA 1875 New Hope StreetF fcr' —"* Norristown, PA 19401

215 270-1975I

October 29, 1990

I

I

I8

1I1

I

I

O'Brien and Gere Engineers, Inc.a 5000 Brittonfield ParkwayI P. 0. Box 4873

Syracuse, NY 13221

Attention: J. Kevin Farmer, P.E.Managing Engineer

Re: Blosenski Landfill Superfund SiteWest Cain TownshipChester County

Dear Mr. Farmer:

This is in reply to your September 25, 1990 and October 23, 1990 letters andyour October 22, 1990 telephone conversation with Steve O'Neil of my staffregarding your request to conduct a 8-hour well drawdown test and a 48-houraquifer pump test with temporary discharge of approximately 134,400 gallons oftreated water to an unnamed tributary of Indian Spring Run located to the northof the site.

Verbal approval of this temporary discharge was granted during the October 22,1990 telephone conversation with the understanding that a sampling plan would besubmitted. Your October 23, 1990 submission of the sampling plan satisfied thiscondition. You are hereby authorized to commence with the pump test andtemporary discharge in accordance with the outlines provided in the abovereferenced letters and you are requested to submit a report on the findings uponcompletion of the pump test and receipt of all sampling analyses.

Very truly yours,

tx'

I LEWIS LUCHIE, JR. (Regional Water Quality Manager

cc: Mr. DanyliwWest Cain TownshipOperations SectionRe 30 (3) 299

Page 19: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

- .-17 R«w. 9/8S

COMMONWEALTH OF PENNSYLVANIADEPARTMENT OF ENVIRONMENTAL RESOURCES

BUREAU OF AIR QUALITY CONTROL

Request for Determination of Requirementfor Plan Approval/Operating Permit Application

(Submit In Triplicate)Blosenski Landfill GroundwaterAir Stripper Off gas Oct 16-18Date of Installation: Uct' 16 18>U.S. Army Corps of Engineers for

ui • ai SmiPM. Joseph M. Blosensfc],, Jr, ftTin«««"«' «-O- No? MA

ifi at Parson; J, J£gvin Farmer .

ngineers, Inc., 5000 Brittonfield Pkwy, P.O. Box 4873,

Tfltonhnn«:O'Brien § Gere Engineers, Inc.

s. an of Sourcata):

rwr AHrirB,«. Kinps Highway Route 340 MnniHnaKtv

s itad Emissions:

s 'lutant VOCs

ifIbs/nr o.ss

Q rrtityIbs/yr 48

SEP 2 6 19903ta necflh/MJ;

uam torn* authority conuiiMd In 28 PA Cad«i12'urcaijj i* •xvmotad from tn« rtan aeeraval and p«rx* no. Th« detarmmanon de«« not wta*npttft« soumi no whn all atticr aeoiicaala .quality rtguiat

" - \Sv O\\ O-Vv^v ~ J*>C I1» ">i . . j

OCT1 5 1990

County:

Signature

Vice/W

f315) 437-6100

West Cain Township

Chester County

7 - • V - ext-,

' ' ' rsside^t, O'Brien S Gere Ena-ine^T

.Title September 25, 1990Date

OFFICIAL USE ONLY Request No. 15-A01-092

K ( \/IX ovKvV - ~~*\

M4(81tn« Tlwaaure sidOMnotaiiaifyfarnamption/ramoianaMco i BBf'mrttmg r»- timing njquiiwnwns under PA Cod* i127.1*<8J and sianaoarovaim<3) from aooteanonOJ must &• subnvtud. Th« Oaaanmant is orahibited fromion. •acting en an aoolieation untri 30. ctavs afTtf tn« muntooaiitv and

county have r*cnv«d noafieanon by tft* camganv. Pemn«nt farmsan attaencd.

, €^-~J — Sfmwiw

Q ."",f ' • •

.0«ra fl.ROO!935

Page 20: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

Sourca Description (attach additional sriaattsi if necessary):ndude: procasa daacription, axhaust volume, stack data, schematic flow diagram, material data safety sheet, tie.)

See following sheets for Process description, etc.

ocr i«aw

OFFICIAL USE ONLY

Page 21: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

PREDESIGN REPORT

BLOSENSKI LANDFILLCHESTER COUNTY, PENNSYLVANIA

APPENDIX 5-2

/IROOI937

Page 22: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

January 2, 1991

Mr. Lewis Luchie, Jr.Regional Water Quality ManagerPennsylvania Department ofEnvironmental Conservation1875 New Hope StreetNorristown, PA 19401

Re: Blosenski Landfill Superfund SiteWest Cain TownshipChester County, PA

File: 3277.001

Dear Mr. Luchie:

An "Application for Discharge of Groundwater to Surface Waters of the State ofPennsylvania" was completed and forwarded to your office on September 25,1990 pertainingto an aquifer performance test to be performed at the Blosenski Landfill Superfund Site.Verbal approval of the temporary discharge of groundwater to surface waters was relayedby Steve O'Neil of your staff with the stipulation that a sampling plan for the test besubmitted to your department. The submission of the sampling plan was completed onOctober 23, 1990, and written approval by your department was granted on October 29,1990 (Attachment A). This letter serves as the report required to be submitted to yourdepartment following completion of the aquifer performance test and receipt of all samplinganalyses.

The aquifer performance test was conducted at the Blosenski Landfill Superfund Site fromNovember 7, 1990 to November 9, 1990. Groundwater pumped to the surface during theaquifer performance test was treated and then discharged to surface waters of the State of

flROGI938

Page 23: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

Mr. Lewis Luchie, Jr.January 2, 1991Page 2

Pennsylvania (unnamed tributary of Indian Spring Run). The groundwater pumped duringthe aquifer performance test was treated through an air stripper, with air stripper offgastreatment by activated carbon adsorption. The gas to liquid ratios (G:L, dimensionless)utilized by the air stripper and associated durations were (in chronological order):

G:L Activity Operational Duration134:1 Well Development 1 hour447:1 Well Drawdown 0.5 hours224:1 Well Drawdown 1.5 hours157:1 Well Drawdown 2.7 hours147:1 Performance Test 1.5 hour128:1 Performance Test 1.5 hours119:1 Performance Test 1.5 hours108:1 Performance Test 1.25 hours101:1 Performance Test 1.5 hours89:1 Performance Test 2 hours68:1 Performance Test 1.25 hours52:1 Performance Test 1.5 hours147:1 Performance Test 36 hours

53.7 hours

For the development of the well, the volumetric air flowrate was set at the maximumachievable by the blower (628 cfrn) and the groundwater flowrate was constant (35 gpm).During the well drawdown test, the volumetric air flowrate was set at the maximumachievable by the blower (628 cfm), and the groundwater flowrate was manipulated by thehydrogeologists. During the air stripping pilot test portion of the 48-hour performance test,the groundwater flowrate was not adjusted, and the volumetric air flowrate was varied. Forthe remainder of the 48-hour performance test, the volumetric air flowrate was set at themaximum achievable by the blower (628 cfm). A total of 89,971 gallons of ground waterwas discharged during the well development, drawdown and aquifer performance test.

Attachment B contains the analytical schedule followed during the testing. EnvironmentalHealth Research and Testing, Inc. of Cincinnati, Ohio provided the analytical services.Volatile organics analyses (EPA Method 601/602) were completed for aqueous influent andeffluent samples at all air to liquid ratios utilized during the aquifer performance test.

flROO!939

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Mr. Lewis Luchie, Jr.January 2, 1991Page 3

Semi-volatile organics (EPA Method 625), PCB/pesticide (EPA Method 608), and indicatorparameter analyses were also completed during the course of the testing.

Attachment C contains a summary of detectable volatile organics in the aqueous influentand effluent samples. The average benzene concentration in the effluent aqueous streamfrom the air stripper was approximately 0.083 rng/L. The average effluent concentrationsfor each of the remaining volatile organics detected in the influent aqueous stream were lessthan 0.011 mg/L.

Indicator parameter analyses were completed and are summarized in Attachment D. Allpriority pollutant metals concentrations were below respective analytical method detectionlimits. All semi-volatile organics (EPA Method 625), and PCB/pesticide (EPA Method 608)concentrations were also below respective analytical method detection limits. AttachmentE contains copies of the analytical reports for the priority pollutant metals, semivolatiles andPCB/pesticide analyses.

The aquifer performance test was successful. The temporary treatment system was highlyeffective in transferring volatile organics to the air from the ground water. This air wassubsequently treated by activated carbon prior to discharge.

Please call me or John LaManche at (315) 437-6100 with any questions or comments.

Very truly yours,

O'BRIEN & GERE ENGINEERS, INC.

ys •-••' ••- V r-t^ ' *^

J. Kevin Farmer, P.E.Managing Engineer

cc: John J. Keegan, O'Brien & Gere Engineers, Inc.John J. LaManche, O'Brien & Gere Engineers, Inc.Geoffrey J. Seibel, O'Brien & Gere Engineers, Inc.

Page 25: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ATTACHMENT A

AROOI9IH

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COMMONWEALTH OF PENNSYLVANIADEPARTMENT OF ENVIRONMENTAL RESOURCES

1875 New Hope StreetNorristown, PA 19401

215 270-1975

October 29, 1990

O'Brien and Gere Engineers, Inc.5000 Brittonfield ParkwayP. 0. Box 4873Syracuse, NY 13221

Attention: J. Kevin Farmer, P.E.Managing Engineer

Re: Blosenski Landfill Superfund SiteWest Cain TownshipChester County

Dear Mr. Farmer:

o , Lre?i7 ?So£ m. **£**** 25, 1990 and October 23, 1990 letters andyour October 22, 1990 telephone conversation with Steve O'Neil of my staffregarding your request to conduct a 8-hour well drawdown test and a 48-houraquifer pump test with temporary discharge of approximately 134,400 gallons oftreated water to an unnamed tributary of Indian Spring Run located to the northor the site.

°f thlS ^ discharge was granted during the October 22,6 "S1! Sn "standing that a sampling plan would beYour October 23, 1 990 submission of the samplingllan satisfied this

condition. You are hereby authorized to commence with the pump test andtemporary discharge in accordance with the outlines provided in the above

f tfS and 70U arV«fl«st:ed to submit a report on the findings uponcompletion of the pump test and receipt of all sampling analyses.

Very truly yours,

LEWIS LUCHIE, JR.Regional Water Quality Manager

cc: Mr. DanyliwWest Cain TownshipOperations SectionRe 30 (3) 299

Page 27: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ATTACHMENT B 12/21/90

BLOSENSKI LANDFILL SUPERFUND SITEWEST CALN, PENNSYLVANIA

AIR STRIPPER PILOT TEST ANALYTICAL PROGRAM

SAMPLES COLLECTED 11/7/90 - 11/9/90

G:L SAMPLE ANALYSESRATIO ID*

=====================r=================s==r===============s==============

AS-I-150 |EPA 601,602,625,608,Priority Pollutant Metals,TSS,BOD5,JTOC,COD,TKN,NH3,O&G,Phosphorus,Chloride,Sulfate

AS-E-150 JEPA 601,602,625,608,Priority Pollutant Metals,TSS,BOD5,jTOC,COD,TKN,NH3,O&G,Phosphorus,ChIoride,SuI fate

AS-I-1500 JEPA 601,602AS-E-150D JEPA 601,602AS-I-130 JEPA 601,602AS-E-130 jEPA 601,602AS-I-120 JEPA 601,602AS-E-120 JEPA 601,602,625,608,Priority Pollutant MetalsAS-E-120D JEPA 601,602AS-I-100 JEPA 601,602AS-E-100 JEPA 601,602AS-I-90 JEPA 601,602AS-E-90 JEPA 601,602AS-I-80 JEPA 601,602,TSS,BODS,TOC,CODAS-E-80 JEPA 601,602,TSS,8005,TOC,CODAS-I-60 JEPA 601,602AS-E-60 JEPA 601,602AS-I-50 |EPA 601,602AS-E-50 JEPA 601,602

147:1

147:1

147:1147:1128:1128:1119:1119:1119:1108:1108:1101:1101:189:189:168:168:152:152:1

AS-I,E - Number Letter

~ ' t * \Air Influent or G:L D - DuplicateStripper Effluent

ARQGI91+3

Page 28: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ATTACHMENT C 12/21/90BLOSENSKI LANDFILL SUPERFUND SITE

AIR STRIPPING PILOT TESTSELECTED VOLATILE ORGANICS ANALYTICAL RESULTS

SAMPLES COLLECTED 11/7/90 - 11/9/90

WATER WATER WATER WATERG:L PARAMETER INFLUENT INFLUENT EFFLUENT EFFLUENTRATIO DUPLICATE DUPLICATE

=—ssssss sssssssssssssssssssssssssssssrsssssssssssssssssssssssssasug/L ug/L ug/L ug/L

147:1 Carbon Tetrachloride 0.50 * 19.76 0.50 * 0.50 *Chlorobenzene 17.35 17.55 1.86 1.55Chloroethane 7.04 7.53 0.50 * 0.5 *Chloroform 128.59 132.27 11.70 10.351,1-DiChloroethane 47.83 49.82 3.21 2.901,2-Dichloroethane 0.50 * 0.84 0.50 * 0.50 *1,1-Dichloroethene 14.02 14.89 0.50 * 0.50 *trans-1,2-Dichloroethene 130.81 \ 137.03 9.81 9.30Tetrachloroethene 1.27 1.29 0.50 * 0.50 *1,1,1-Trichloroethane 112.91 117.48 6.33 7.18Trichloroethene 56.83 59.00 3.00 4.98Vinyl Chloride 12.54 13.79 0.50 * 0.50 *Benzene 1022.00 1290.00 81.67 80.85

128:1 Carbon Tetrachloride 0.50 * - 0.50 *Chlorobenzene 17.42 - 1.44Chloroethane 8.20 - 0.50Chloroform 114.97 - 8.201,1-Dichloroethane 45.15 - 2.301,2-Dichloroethane 0.50 * - 0.50 *1,1-Dichloroethene 11.83 - 0.50 *trans-1,2-Dichloroethene 126.78 - 7.55Tetrachloroethene 1.04 - 0.50 *1,1,1-Trichloroethane 104.93 - 4.62Trichloroethene 51.34 - 2.64Vinyl Chloride 13.99 - 0.50 *Benzene 1320.00 - 60.75

119:1 Carbon Tetrachloride 0.50 * - 0.50 * 0.50 *Chlorobenzene 17.43 - 1.60 1.64Chloroethane 0.50 * - 0.50 * 0.50 *Chloroform 100.27 - 8.11 8.121,1-OiChloroethane 39.82 - 2.32 2.331,2-Dichloroethane 0.50 * - 0.50 * 0.50 *1,1-Dichloroethene 9.35 - 0.50 * 0.50 *trans-1,2-Dichloroethene 109.97 - 7.64 7.45Tetrachloroethene 1.28 - 0.50 * 0.50 *1,1,1-Trichloroethane 98.22 - 4.91 5.50Trichloroethene 49.55 - 0.50 * 0.50 *Vinyl Chloride 10.61 - 0.50 * 0.50 *Benzene 1294.00 - 65.71 68.33

108:1 Carbon Tetrachloride 0.50 * - 0.50 *Chlorobenzene 16.35 - 1.87Chloroethane 0.50 - 0.5 *•Chloroform .. 86.63 - 9.881,1-Dichloroethane 32.25 - 3.131,2-Dichloroethane 0.50 * - 0.50 *1,1-Dichloroethene 6.40 - 0.50 *trans-1,2-Dichloroethene 93.19 - 10.22Tetrachloroethene 0.5 * - 0.50 *1,1,1-Trichloroethane 86.58 - 5.41Trichloroethene 47.69 - 0.50 *Vinyl Chloride 0.50 * - 0.50 *Benzene 1261.00 - 74.08

* - less than

flROOI9l*l*

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ATTACHMENT C 12/21/90BLOSENSKI LANDFILL SUPERFUND SITE

AIR STRIPPING PILOT TESTSELECTED VOLATILE ORGANICS ANALYTICAL RESULTS

SAMPLES COLLECTED 11/7/90 - 11/9/90

WATER WATER WATER WATERG:L PARAMETER INFLUENT INFLUENT EFFLUENT EFFLUENTRATIO DUPLICATE DUPLICATE

ug/L ug/L ug/L ug/L==SS333S=S3S3SS33SS3S3=S==3333=S33333S=33S3S3S333S3333333333=3333333=S3333S33333:!

101:1 Carbon Tetrachloride 5.00 * - 0.50 *Chlorobenzene 17.20 - 1.96Chloroethane 5.00 * - 0.5 *Chloroform 98.10 - 9.621,1-Dichloroethane 37.40 - 3.121,2-Dichloroethane 5.00 * - 0.50 *1,1-Dichloroethene 9.50 - 0.50 *trans-1,2-Dichloroethene 110.20 - 9.74Tetrachloroethene 5.00 * - 0.50 *1,1,1-Trichloroethane 131.40 • 6.13Trichloroethene 55.50 - 3.11Vinyl Chloride 5.00 * - 0.50Benzene 1201.10 - 81.50

89:1 Carbon Tetrachloride 5.00 * - 0.50 *Chlorobenzene 17.20 - 2.43Chloroethane 5.00* - 0.50Chloroform 95.20 - 12.061,1-Dichloroethane 36.20 - 3.631,2-Dichloroethane 5.00 * - 0.50 *1,1-Dichloroethene 5.00 * - 0.50 *trans-1,2-Dichloroethene 106.60 - 12.22Tetrachloroethene 5.00 * - 0.501,1,1-Trichloroethane 124.30 - 6.29Trichloroethene 59.10 - 3.63Vinyl Chloride 5.00 * - 0.50 *Benzene 1267.80 - 94.53

68:1 Carbon Tetrachloride 5.00 * - 0.50 *Chlorobenzene 22.10 - 2.94Chloroethane 5.00 * - 0.50 *Chloroform 96.60 -. 17.051,1-Dichloroethane 34.10 - 5.041,2-Dichloroethane 5.00 * - 0.50 *1,1-Dichloroethene 5.00 * - 0.50 *trans-1,2-Dichloroethene 103.70 - 18.00Tetrachloroethene 5.00 * - 0.50 *1,1,1-Trichloroethane 135.90 - 7.15Trichloroethene 68.60 - 4.40Vinyl Chloride 5.00 * - 0.50 *Benzene 1286.70 - 122.61

52:1 Carbon Tetrachloride 5.00 * - 0.50 *Chlorobenzene 17.30 - 1.98Chloroethane 5.00 * - 0.50 *Chloroform 85.40 - 10.921,1-Dichloroethane 30.00 - 3.231,2-Dichloroethane 5.00 * - 0.50 *1,1-Dichloroethene 5.00 * - 0.50 *trans-1,2-Dichloroethene 91.50 - 11.61Tetrachloroethene 5.00 * - 0.50 *1,1,1-Trichloroethane 117.70 - 4.44Trichloroethene 37.10 - 0.50 *Vinyl Chloride 5.00 * - 0.50 *Benzene 1210.70 - 81.19

* - less than

Page 30: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ATTACHMENT C 12/21/90BLOSENSKI LANDFILL SUPERFUND SITE

AIR STRIPPING PILOT TESTSELECTED VOLATILE ORGANICS ANALYTICAL RESULTS

SAMPLES COLLECTED 11/7/90 - 11/9/90

WATER WATER WATER WATERG:L PARAMETER INFLUENT INFLUENT EFFLUENT EFFLUENTRATIO DUPLICATE DUPLICATE

ug/L ug/L ug/L ug/L

AVERAGES Carbon Tetrachloride 2.75 - 0.50Chlorobenzene 17.79 - 2.01Chloroethane 4.53 - 0.50Chloroform 100.72 - 10.941,1-Dichloroethane 37.84 - 3.251,2-Dichloroethane 2.75 - 0.501,1-Dichloroethene 8.26 - 0.50trans-1,2-Dichloroethene 109.09 - 10.85Tetrachloroethene 3.01 - 0.501,1,1-Trichloroethane 113.99 - 5.66Trichloroethene 53.21 - 2.29Vinyl Chloride 7.21 - 0.50Benzene 1232.91 - 82.76

* - less than

flROOJ9ti6

Page 31: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

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S ————————— V "\ k_j2 j r: ^

5 S j 5 S s s

Page 32: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ATTACHMENT E

flROOI9l*8

Page 33: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

«i r\L. , .^-vwi. , . .—._M !oi i mtu i L:O iSEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELU

PLE SOURCE: Blosenski Landfill________

WORK ORDER NO.: _N/A________________ EHRT PROJECT NO.: J2307

DATE EXTRACTED: 11-12-90_____________ DATE ANALYZED: J1-1MO

SAMPLE TYPE: Water Sample__________ SAMPLE VOLUME: _ 500.00

ANALYST: K. Nusekabel_____________ FINAL VOLUME: 1.00

CUSTOMER SAMPLE NO.: AS-l-150______________ EHRT SAMPLE NO.: 29360

LAB NOTEBOOK NO.: 149. Pq. 83_____________ METHOD NO.: EPA 625

RESULTCOMPOUNDS___________ ug/L

1. Phenol < e.OO2. Bis(2-Chloroethyl) Ether < 4.003. 2-Chlorophenol < 4.004. 1,3-Dichlorobenzene < 12.005. 1,4-Dichlorobenzene < 12.006. Benzyl Alcohol < 6.007. 1,2-Dichlorobenzene < 12.008. 2-Methylphenol < 6.009. Bis-(2-Chloroisopropyl) Ether < 8.0010. 4-Methylphenol < 6.0011. N-Nitroso-Di-n-Propylamine < 8.0012. Hexachloroethane < 12.0013. Nitrobenzene < 6.0014. Isophorone < 4.0015. 2-Nitrophenol < 8.0016. 2,4-Dlmethylphenol < 6.0017. Benzole Acid < 40.0018. Bis(2-Chloroethoxy)Methane < 4.0019. 2,4-Dichlorophenol < 8.0020. 1,2,4-Trichlorobenzene < 12.0021. Naphthalene < 2.0022. 4-Chloroaniline < 20.0023. Hexachlorobutadiene < 24.0024. 4-Chloro-3-Methylphenol < 6.0025. 2-Methyinaphthalene < 2.0026. Hexachlorocyclopentadiene < 24.0027. 2,4,5-Trichlorophenol < 10.0028. 2,4,6-Trichlorophenol

Pann 1

Page 34: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

(Jl JSTOMER SAMPLE NO.: AS-i-150 ____________ EHRT SAMPLE NO

29.30.31.32.33.34.35.36.37.38.39.40.41.42.43.44.45.46.47.48.49.50.51.52.53.54.55.56.57.58.59.60.61.62.63.64.65.

2-Chloronaphthalene2-NitroanilineDimethylphtrialateAcenaphthylene2,6-Dinitrotoluene3-NitroaniiineAcenaphthene2,4-Dinitrophenol4-NitrophenolDibenzofuran2,4-DinitrotolueneDiethyiphthalate4-Chlorophenyl-PhenyletherRuorene4-Nitroaniline4,6-Dinitro-2-MethylphenolN-Nitrosodiphenyiamine4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneDi-n-ButyphthalateRuoranthenePyreneButylbenzylphthalate3,3'-DichlorobenzidineBenzo(a)AnthraceneChryseneBis(2-Ethylhexyl)PhthaJateDi-n-OctyiphthalateBenzo(b) RuorantheneBenzo(k) RuorantheneBenzo(a) PyreneIndeno(1 ,2,3-cd) PyreneDibenzo(a,h)AnthraceneBenzo(g,h,i)Perylene

SURROGATE COMPOUND

Nitrobenzene-d52-RuorobiphenylTerphenyl-d14

Phenol-d52-Ruorophenol2,4,6-Tribromophenol

< 6.00< 20.00< 6.00 < 4.00 m< 12.00 ^< 20.00< 4.00< 80.00< 40.00< 12.00< 12.00< 4.00< 12.00< 6.00< 40.00< 40.00< 6.00< 12,00< 10.00< 40.00< 4.00< 4.00< 2.00< 4.00 < 4.00 m< 6.00< 20.00< 6.00< 6.00

6.92< 4.00< 20.00< 20.00< 12.00< 20.00< 20.00< 20.00

PERCENT RECOVERY

58.50%52.70%37.10%

10.00% *10.00% * 418.30% ^

' A low recovery was obtained on the phenol surrogates. The surrogate recovery was also very low on the matrixSee and matrix spike duplicate. The sample matrix is probably responsible for these low recoveries sroe it Q C A

i reduces on 3 analyses of the same sample. Paqe 2 fl T\ u \T f 3 <J u

Page 35: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.PESTICIDES - PCB ANALYSIS

. JSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELU

\MPLE SOURCE: Blosenski Landfill

WORK ORKER NO.: N/A_____________ EHRT PROJECT NO.: 12307

-ATE EXTRACTED: 11-09-90___________ DATE ANALYZED: 11-09-90

\MPLETYPE: Water Sample_______ METHOD NO.: EPA 608

ANALYST: M. Cooper_________ LAB NOTEBOOK NO.: 158. Pg. 54

^JSTOMER SAMPLE NO.: AS-l-150___________ EHRT SAMPLE NO.: 29360

RESULTCOMPOUNDS .

1. Alpha-BHC < 0.00142. Beta-BHC < 0.00083. Delta-BHC < 0.00064. Gamma-BHC < 0.00065. Heptachlor < 0.00206. Aldrin < 0.00167. Heptachlor Epoxide < 0.00148. Endosulfanl < 0.00089. Dieldrin < 0.000410. 4,4'-DDE < 0.000411. Endrin < 0.000612. Endosulfanll < Q.0213. 4i4'-DDD < 0.0214. Endosulfan Sulfate . < 0.000415. 4,4'-DDT < Q.001216. Methoxychlor < 0.000417. Endrin Ketone < o.0418. Chlordane < o.2019. Toxaphene < 3.00

flROO!95i

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jSTOMER SAMPLE NO.: AS-l-150___________ EHRT SAMPLE NO.: 29360

20. Aroclor-1016 < 95021. Arocior-1221 < 0.5022. Aroclor-1232 < Q$Q23. Arodor-1242 < 0.5024. Aroclor-1248 < g.5025. Aroclor-1254 < g.5026. Arocior-1260 < g.50

SURROGATE RECOVERY

Dibutyichlorendate - ___ 99.00%

flROOI952Pane 2

Page 37: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. • MR. MIKE PETTERELU

PLE SOURCE: Blosenski Landfill

WORK ORDER NO.: _N/A________________ EHRT PROJECT NO.: 12307

DATE EXTRACTED: 11-12-90______________ DATE ANALYZED: 11-13-90

SAMPLE TYPE: Water Sample__________ SAMPLE VOLUME: 1000.00

ANALYST: K. Nusekabel___________ RNAL VOLUME: 1.00

CUSTOMER SAMPLE NO.: AS-E-150_____________ EHRT SAMPLE NO.: 29361

LAB NOTEBOOK NO.: 149. Pg. 83____________ METHOD NO.: EPA 625

RESULTCOMPOUNDS___________ ug/L

1. Phenol < 3002. Bis(2-Chloroethyl) Ether < 2.003. 2-Chlorophenol < £.004. 1,3-Dichiorobenzene < 5005. 1,4-Dlchlorobenzene " < §006. Benzyl Alcohol < 3007. 1,2-Dlchlorobertzene < QQQ8. 2-Methylphenol < 3 009. Bis-(2-Chloroisopropyl) Ether < 4.0010. 4-Methylphenol < 30011. N-Nitroso-Di-n-Propylamine < 4.0012. Hexachloroethane < g.OO13. Nitrobenzene < 30014. Isophorone < 2.0015. 2-Nitrophenol < 4>0o .16. 2,4-Dimethylphenol < 3.0017. Benzole Acid < 20.0018. Bis(2-Chloroethoxy)Methane < 2.0019. 2,4-Dichlorophenol < 4.0020. 1,2,4-Trichlorobenzene < e.0021. Naphthalene < I.QQ22. 4-Chloroanillne < iQ.OO23. Hexachlorobutadiene < 12.0024. 4-Chloro-3-Methylphenol < 3.0025. 2-Methylnaphthalene < 1.0026. Hexachlorocyclopentadiene < 12.0027. 2,4,5-Trichlorophenol < SQQ

flROOI953 < 5-°°

Page 38: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-E-150

29.30.31.32.33.34.35.36.37.38.39.40.41.42.43.44.45.46.47.48.49.50.51.52.53.54.55.56.57.58.59.60.61.62.63.64.65.

2-Chloronaphthalene2-NitroanilineDimethylphthalateAcenaphthyiene2,6-Dinitrotoluene3-NitroanilineAcenaphthene2,4-Dinitrophenol4-NitrophenoiDibenzofuran2,4-DinitrotdueneDiethylphthalate4-Chlorophenyl-PhenyletherRuorene4-NitroaniIine4,6-Dinitro-2-MethylphendN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneDi-n-ButyphthalateRuoranthenePyreneButylbenzylphtnalate3,3'-DichlorobenzidineBenzo(a)AnthraceneChryseneBis(2-Ethylhexyl)PhthalateDi-n-OctyiphthalateBenzo(b)RuorantheneBenzo(k)RuorantheneBenzo(a)Pyrenelndeno(1 ,2,3-cd)PyreneDibenzo(a,h)AnthraceneBenzo(g,h,i)Perylene

SURROGATE COMPOUND

Nitrobenzene-d52-RuorobipnenylTerphenyl-d14

Phenol-d52-Ruorophenol2,4,6-Tribromophenol

< 3.00< 10.00< 3.00 < 2.00 M< 6.00< 10.00< 2.00< 40.00< 20.00< 6.00< 6.00< 2.00< 6.00< 3.00< 20.00< 20.00< 3.00< 6.00< 5.00< 20.00< 2.00< 2.00< 1.00< 2.00 M< 2.00 < 3.00< 10.00< 3.00< 3.00< 2.00< 2.00< 10.00< 10.00< 6.00< 10.00< 10.00< 10.00

PERCENT RECOVERY

72.00%57.40%50.90%

10.00% *10.00% * m12.20% ^

A low recovery was obtained on the phenol surrogates due to the sample matrix.

Pane?

Page 39: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.PESTICIDES - PCS ANALYSIS

JSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

,MPLE SOURCE: Blosenski Landfill _______________

WORK ORKER NO.: N/A_____________ EHRT PROJECT NO.: 12307

TE EXTRACTED: 11-09-90___________ DATE ANALYZED: 11-09-90

MPLETYPE: Water Sample_______ METHOD NO.: EPAj308_

ANALYST: M. Cooper__________ LAB NOTEBOOK NO.: 158, Pg. 54

-JSTOMER SAMPLE NO.: AS-E-150___________ EHRT SAMPLE NO.: 29361

RESULTCOMPOUNDS

1. Alpha-BHC < 0.00142. Beta-BHC < 0.00083. Delta-BHC < 0.00064. Gamma-BHC * < 0.00065. Heptachlor < 0.00206. Aldrin < 0.00167. Heptachlor Epoxide < 0.00148. Endosuifanl < 0.00089. Dieldrin < 0.000410. 4,4'-DDE < 0.000411. Endrin < 0.000612. Endosulfanll < 0.0213. 4,4'-DDD < 0 0214. Endosulfan Suifate < 0.000415. 4,4'-DDT " < 0.001216. Methoxychlor < 0.000417. Endrin Ketone < o.0418. Chlordane < 0.2019. Toxaphene < 3.00

aROOI955Paae 1

Page 40: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

• JSTOMER SAMPLE NO.: AS-E-150___________ EHRT SAMPLE NO.: 29361

20. Aroclor-101621. Aroclor-1221 < '22. Aroclor-1232 <23. Arodor-1242 < Q^24. Arodor-1248 < Q'25. Aroclor-1254 < '26. Aroclor-1260 <

SURROGATE RECOVERY

Dibutylchlorendate - 166.00%

AROQI956Pa no n

Page 41: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

COVER PfiGE - INDRGflNIC ANALYSES DfiTfi PACKAGE

-z 'jamg; ENVIR. _HEAi_TH_RESEARCH_TE Contract: QBG

D C.-c=: w38 __ Case No.: BLOSE 3AS No.: 123iZi7_ SDG Mo.

EPfl Samp is No. La/b gampiB ID.flSE150 , q

Were ICP iritsralsmer-t corrections applied ? Yes/No YES

Were ICP background corrections applied ? Yes/No YESIf yes - were raw data generated beforeapplication of background corrections ? Yes/No NO

Comment 5:

Rei-=ase of the data contained in this hardcopy data package and in thecoiJtpuTsr-^sadable data submitted on floppy diskette has been authorized b%the Lsijoratory Manager or the Manager's designee, as verified by thefollowing signature.

Lafc Manager:

:OVER PA5E - IN

flROOI957

Page 42: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

1 EPA SAMPLE NO.INORGANIC ANALYEE5 DATA SHEET

! II ASE150 I

_ = - .-••-: ENVIR. _HEflLTH_RE5SARCH_TE Cortrsct; QBG_____ i___________!

_a= :.-G5: was__ Case No.: SLOSH SPS No.: 1£307_ SDS No.: £00000

Plat'.--- ^=-oil/watsr:v : WATER Lab Sample ID: £9351___

Le-<=: (ic-w/med;: ___ Date Received: ll/06/9i2i

Concentration Units (ug/L c-- mg/kg% dry weight): UB/L_

uc i ;•,-• •?•=->" re:

Color After-;

Comments:

1iCAS No,1: 7i£9-9S-5i "-40-36-8; -443-30-2i 7- -0-39-3: 74413-41-7: 7440- 3-91 7440-70-5I 7*40-47-317 40-48-4; 7440-50-3i 7439-89-51 7439-92- i; 439-95-4I 7439-95-517439-97-6; 7440-02-01 7440-09-7i 7782-49-2i 7 40-22-4i 7440-£3-51 7440-23-01 7440-62-81 7440-66-5!

;

i i! Analyts ! Concent Ti iiAluiiunum !i. Antimony ii Arsenic !.'Barium 11 Bery 1 1 i urn ii Cadmium ii Calcium1 Chromium ii Co bait i1 Cop per i1 Iron !1 Lead i1 Mannes i urn iIManaanesel1 Mercury _ !1 Nickel !1 Potassium1 Selenium !! Silver :1 Sod i urn 1i Th a 1 1 i i-.m_ : _____I Vanac i urn !1 Zinc ;ICvaniae i1 !

Clarity Before

Clarity A^ter:

'atio

10.72.2

S.481.8

5.3

5.0

Ifl. 9

•7i <"-'. j.

4. fi

.-, 4L_ • *4 /->i . r

95.5

2. 4

.

t I

n ! C 1 G! 11 1IU!IU!1 iIU!I U I! iiU!! 1IU!I II U I1 I1 !

i U II U Ii !l U i!UI1 II U I1 !I U I

i 11 i

1 1!M 11 iINR:iP 1IF !I N R IIP !IP iINRIIP IINRIIP IINR!IP ;! NR 1INR!1 CV 1IP !I N R IIF iIP :INRIIP !INR:IP 1INR!I 1

Texture:

Artifacts:

U

~DR(« : - IN

Page 43: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

1 -EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

I ASI150LSD -Jame: ENVIR. _HEALTH_RESEARCH_TE Contract: OB6_____ I________

Lafc Code: W8S__ Case No.: BLOSE SAS No.: 1S307_ SDS No.: 000000

Matrix (soil/watsr): WATER Lab Sample ID: 293S8A__

Level (low/med): ___ Date Received: 11/0S/9®

*• C C11 1 u 5 • _.___ _____ __

Concentration Units (ug/L or rng/kg dry weight): UG/L_

11

ICflS No.i17423-90-5i 7440-35-01 7440-33-c17440-35-3(7440-41-71 7440-43-91 7440-70-2! 7440-47-3; 7440-48-4i 7*40-50-817439-89-6i 7*39-32-117439-95-4! 7439-95-51 7439-97-6i 7440-02-0i 7440-09-71 7782-49-21 744S-£2-41 7 -40-23-5i 7440-23-0I 7448-G2-21 7 40-56-51

1

i i! Analyte 1 Concent r1 " i1 Aluminum i1 Ant i mony I' Arsenic 1! Barium 11 Bery Hi urn II Cadmium i! Calcium !! Chromium 11 Cobalt !1 Cop per 1! Iron !I Lead 1I Magnesium I1 Manqanese 1I Mercury 11 Nickel 11 Potassium!1 Selenium 1I Silver 11 Sod i urn 1I Thallium !I Vanad i urn I!Zinc 1(Cyanide I1 1

•at ion

10.72.2

0. 40

1.3

5.3

5.0

10.9

0. 14.5

2. 11.9

95.5

£.4

! 1IC1 Q1 iI 1IU!IUI1 1I U II U I1 IIUI1 1IUII 1iUI1 11 1I U II U I1 1IUIIUI! IIUI1 1I U I1 !1 1

i 1IM 1I 1INRIIP iIF 1! NR !IP !IP iINR:IP iINRIIP !INR!IP 1iNR!INR!I CV 1IP !1 MR 1IF iIP 1INRIIP i; NR iIP 1INR!1 I

Color Esfors: ,„ _____ Clarity Before:

AS-I-150

Color After: _______ Clarity After: ____ Artifacts:

Comment s :

FORM I - INftROOl959

Page 44: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

&• EPA SAMPLE NO.DU

•--.--.-: INvI

:.:=: W88

":,. .soii/w

'?ii-fr for S

Co

1 • • i1 i

ip' :itfi,'iim !

1 Arsenic I1 Bar i urn 1! Bery Hi urn i(Cadmium 'i Calcium ii Chromium 1I Co 55 it 1

•i Copper 11 Iron 11 Lead i

i Plane; =ii!5=5iIMsrcurv i. NiCHel I

Ssier i um _!1 £ 1 1 ••. sr ' ;'Sec urn •

i - 1 r.c i!Cy5"-l_!S• i

R. HEALTH RESEARCH ~E Conr

Case No.

atcr>: WATER

SK-ple: ___

ncsnt rat i on Jn its

1 1Control ! iLimit i I Sam pi

! 11 1

58.0 I I10.0 1 1

! 15.0 1 I5 . 0 II

! i10. 0 ! 1

I !£5. 0 I I

1 !5. 1? ! 1

1 !1 1

0. 2 i 1MZl. 3 ;

: I5. 3 i 1

.1C. 0 i! i

1S.O Mi 1t i

£0. 3 1 Ii 1i j

. Dl PCST: DLi_cc

(ug/L ; 'ng

! i1 !

e (S) Cl 1! 1

1 : i10. ~800 mi i2. £858 ! U 1 1

1 ! 18. 4C80 i U i i1.S0881U! 1

i ' !

5. 3880 mi i- i i

c- 3S7SIUI '! i !

18. ?SiZi81U! i) • i

t i8. 1308m; if. £02811' ,

i i

L. -4£0'L;; iL. 3£<D3 i U i !

i i I95. fS38;iJ! !

i i i2. •~C8£;LH :

i :i i

ract: GBG

3 AS No. : l£387_

Leva 1

'/. Solids for

/kg ciry weight) :

I1

Duplicate (D) Cl!

1 110. 7008i'Ji£. £858 1 U 1

i i8. 4888 i UI1.8000 IUI

5. 3808 lUli 1

5. 8878! UIi i

18. 90801 U!1 i; !

0. 18881 L;4. 5880! UI

1 !2. 1 420 1 U 11.3888 IUI

1 I95.3888MJ1

i i2. 4808 | U I

1 i,' 'i

i ASI150D 11 1

SDB No. : 0880128

(low/med) : —— — -™_.

Duplicate: ___

UG/L_

1 M l !1 I 1 1 I1 RPD 1 IQI Ml1 i l l !1 II ! NR 11 1 I IP i1 1 1 IF !i M l M P1 M '0 ,1 N I P :1 Ml NR i1 M ! P ii ! 1 I NR :

1 1 I P '1 II ! NR i1 M : P •1 i ! i NP1 I I ! N R ;I ! 1 ' CY •I M , P •1 I I i N R i! ! 1 1 F '1 U IP lj I • :r,'Ri! I I I ? !

1 ! i i!M?l: 1 1 : P :i II i MR :I H i !

flROQ!960

Page 45: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

£AJITIAL AND CONTINUING CALIBRATION VERIFICATION

-ic M=.-*e: ENVIR._HEAL7H_RESEARCH_TE Contract: 05S.

L.«fc -Iocs: *IS£__ Case No.: BLQSE 3AS No.; 1£387_ SDG No.: 838880

Initial Col:.sr.=tion Scares: SPE'<_______

ionti ruling Calibration Source: SPEX_____

Concentration Units: ua/L1 111 ;

'final yes !l |i Glum :n urn 'lAntin-cnyJ1 Arsenic >'i Bar i urn !i Beryl 1 i'.imii Cadmium i1 Calcium !j Chromium.,:iCoPalt ~!:'C;-oner i! Iron !: Lead '; Magnesium!: rianq = ns=e •i Mercurv i! NICKS! _ I1 Pot <?.3S i urn i•Selenium _i: Silver ;1 Sod i urn 1i Thallium J! Vanadium :I Zinc '! Cyanide ii :

* „ i T - 1t n 1 : i 3 i

7--'ue

533.58,

588.588.

588.

5'38.

588.

'J*

538.

— _10-" 183.

_1 80C.

-588.

iC' 18 i

10 !8 1

!0 i

!8 1

I.3 !

1i

12 i•2 i

i0 !3 1

li

8 !1

8 1i1

i

Calibration iPound :/.RCi.'' i

i1

587,50!47.981

!

476. 38 1498. 48 !

1549. 08 1

11

439.80!1

483. £81!1

5.481498. 70 1

I10.58!97. 18!

!9 6.58!

1494.901

I!

i181.5!95. 3 1

i_95. 3 !J98. 1 1

I189.31

!_97. 3 i

i36.6!

189. £i98. 1 1

i185.8!97. 1!

194.51

199.81

11

Continuing Calibration i ; iTrue Found tfRii) Found SRCDM M!

1 |

58S.58.

588.588.

580.

588.

588.

5.588.

£8.188.

..1008.

588.

iS !8 !

10 i

8 i:

8 !1

8 1I

8 !It

8 !8 i

18 i8 !

i8 i

18 1

11

583.49.

471.483.

548.

479.

47S.

5.483.

19.96.

961.

493.

138138!

!

38158!

178 i

i38!

148!

1i

38!£8!

198170!

198!

1781

1I

1

181._99.

_94.j95.

189.

,.95.

_35.

186._S6.

.99.96.

95.

93.

1-? ri i6 i

ii4171

17!

I01

i

7!Ii

816i

15!7!

1I

£!1

71I!

l ! ;.': :i I I P -

1 i ! NR !1 MP 1! i iP !i I iiNR! Mr!i i I N R 1; MP:! Mr-.-RiI I I P !i i i NR :i I INR!

I 1 CMI 1 !P !1 1 i NR 1! i IF :i I I P !! I I N R I1 MP :! i 1 NR !i i .a :i ! NR i1 i ;

:i) Control Limits: Mercury 88-l£0> Other Metals 98-110! C>snide 35-115

FORM II (PART 1) - :-N

SRGOI961

Page 46: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

£AINITIAL AND CONTINUING CALIBRATION VERIFICATION

:jf«=: EfiVIR. _-iEAL PH _RESEARCH_TE. Contract: DBS.

Case No.: BLDSE SS5 No.: 1£3Q7 SD5 "Jo.: 088088

In i-i = i Cal ir.ratior; Source:

C on* in i.'.i rig

t i

1

iAl..':-v.:p !1 Ant ir;o •'••'-, '! Av-se-'-iic !; B~.vi:..n 'il Berv Hi urn ii Cacr.ii urn i! CoO. c i j'"i '•:Ch»-.;mi^T iiCc.nalr !'Cipzsr! Ir:r, i: L=-?c • •:s/bc-asi-.-m!

•1-7! '] = .•"= = 3'

M=>-c'.:ry !N-z:-'=l

' p,- -.-,— • :;r.- .•' Eel =r.i ..m :! S i 1 ,'.=r i! SOG i ur,i r:Th = lli;.;r- '' Vanad i :-x !: Z i f ic ;iCyanir.3 1' i

Ca 1 i brat i on Source : 5PE.V

Cone snt ration Unit

I nit:, si Calibration !True round #R(D! True

1 i i !12388.3 i 11753.331 98. 3 l l£S33. 3 :

! ' l ii : 1

13C0. 3 t 983.3®. 95.3! 1888.3 :1083.8 . 1825.231 10£. 5: 1C3C. 0 !

! ' { '£8CG.3 '• 1919.08: 95. j! iCGS. 3 1

'• I ' :irAOil- ^ C'"-'-1- ' t"1! ' 1 <?,£ 'J' •' = " - 7 -TI ijOil'v. J • Jil.r3. W"J i 1'it, <•• r -••tti-i'. kj ;

> i i t' 1 r

£88. C1 ! 531.58! 95.'"" 53C. •-? !i l .

i i •

5CS:8. C ' ^347.38!_9a. i; S088. 0 iI |

i ! ! i£383.3 1 1973.38! 58. y- £083.'? !

i ' i£083.8 i £855.88! 10:. 2' £388.8 i

! i i4(3158.3 : 4135. 381 183. 4 : 4308.2 !

i i i '! ; ;

s; ug/L.

Cont inuing Cal i brat ionFound tfRd; Found %R •'

; I 1

l S. 38! 131.4! ii ' 11 J i

iei7.C3!l3i.7! I1074.30I1S7. :i| 1

1 i !1971.38! 95. £: i

! ' !w^filF^T. W'i1 f * i-1 / , ._• 1

' i 1

£39. 931 181. £i !1 I; i1 i

8090. 30! 101. 1! !! ! !i ! !

202£.00I101.3I !i 1 1

2118.301135.9! i1 i

4£55. 80! 135.41 1i i 11 1 1

! r ti !

I ' t

1 !»•'='

| - ,

• -:~ i

; I N R I• ! P '

! IP '! 1 "•£ .

1 • - '

• INF,!! IP .! 1 MC '

1 iP !! ! r-.'R !i iNR!M'jRi' : r t

! I NR 1I 1 NR ;M~ '1 1 Nfi i: IP: IMP,I I P !1 I N R i( !

(I.1 Control :_:r;iit = : Mercury 38-lcv? Ifsr ""etais 98-110? -vanids 35-115

AR001962

Page 47: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

BLANKS

_=- Name: ENVIR. _HEAL7H_RE=EARCH_-E Contract: 055

_sb LOSS: W1

3 •-•• a n s -'• — T " ."".v"!« sr p z\ r ~ \r A ' - > i

— ""5D-5'.~ ~,t icn

1

1

i r-.luriiiriLirf ilAr'timony !s-r-sviiu i:3c>>HiMi ii.:5""y' i - 1 Ufn iCacrn i uni i

~"• w i'__ vfl'

; Chromium ii C D sv • ~ I

; Coccsr Ii iron !' L=ac! i'Magnesium!' Manganese li Mercury..,. 11 Nickel !i Potassium!i Selenium !! Silver "lSod i urn i— i- - i l ..... ;' : i Icli A - '.I III . i

' Vanadium _!Ilinc i'Cyamds-.... !' !

33 __

B 1 ?"ik

Blank.

Case No. 5 BLOSE SflS No. : 1£I£7_ 3DG No. ; 01Z300S

Mat r i x i so i 1 / wat er > : WfiTER

Ccncsritrst ion Units Oag/L or nig/kg. ; 'S/L

T ,. 4 4- .' - '•» :' ' 1 1 1 s. in . i i t.M =: A A U .

Blankiug/L;

10.£.

3.^ •

__ _ „•-'•

cr•._/«

10.

8.4.

£•4X •

•"=",*W •

."•.£.«

«;w

-Ta "w

•3

q

4X

s1J.•3

VJ

4.

J

(

1Ci

1i !!U'IU!I i;_r• U!. i .Ji U i1 11 1

IUII !1 i

.J _;! 1

":uiILMi !1 1 1 11 U 1

i ' ' 1_ ' 'W 1i i

"" ! ' ;(

IUI.J J

• !

i ii !

Continuing Calibration M Prspa-Blank. (ug/L) i ! ration

i C £ C 3 CM Blank1 :

13.c!.

3.1.

C1w> •

c-u*

18.

3.4.

.•"r£.•

•1i •

l_jSff

.»,Uri

-T/

C

u

3

w.'

3

9

<5.

4i

g

w*

4

1 !!UI;uii iI U iIUI1 !i U iI IIBIf I1 1

i Ii iI 1IU!IUI! 1iUI!U!' i: I-.1 1IU!! 11 1

i ; i MI i i M 13.i i : i ; 2 .I ! • Mi i ! 1 i 3.1 i I I I 1 .I ! 1 ! II I ; 1 ; 5 .I I 1 I II I 1 i i 5 .! ! i ! !II : 1 ! 18.! i ; ! I1 ; i ! i1 ! 1 ! ! 3.i i I I ! 4 .I I I I Ii 1 I I I 2 .i 1 ! i i 1.! ! I l lI I I I I 9 5 .I I ! I !I I 1 M 2 .

' • 1 1 ! II I i M

738£88

488388

t1

.- :

!

I ;> i

I U IIUI!_:IU!IU!I I

388 1 U i1 i

818

938

188583

148988

588

408

IB!1 i! J1 1i !

IUII U II iIUIIUIl_!I !t t

1 JIUI:_ii |

i

i•-4

i:

iNFIP; ~

INR_I P! f"i [-

INRIPINRiPi NIC

i r

!NF

INR! CV_IPINRIFIPINRi ni r

INRiP1 NF _

i

i

i

i

i

11

11i

i1

11

FORM III - IN

aROOI963

Page 48: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

1C? INTERFERENCE CHECK SAMPLE

_=u -..vis: ENVIR. _HEALTH_FE3EflRCH_TE Contract: -3-ES

i_ac '.ode: W88—— Case No.: SLOSE SAS No: 1£387_ SDG No.: 003383

1C? ID NuiiiBai-: £433______ ICS Source: _________

Corvcs-Mtrat ion units: ug/L

l TrSol.

• Ana./ts AiIAlurnir.:.mi_.533E30l! Antimony i 1i A--'=s''". ic ; li Bar i urr i I1 E@rv i 1 i am : !!CadrijM 1 1!Caiciur.i._ 1538838!1 Chromium ' IlEobait ' '•i Coppsr 1 l1 1 r ?n : 230000 1i -.sad i i! Magnes i urn 1 560 36 'if"a'.".ga"-ssel i!*"<='"- :ry : :"nicxel .' 1

: 'r:t ?.==.-. tmi3=le*njri! ' iISilvjy : ;1 Sod i urn ' !iThslliu^ ;! .'=."tsaium ' 1'Zinc 1 li ' i

1us :Sol. 1AB 1

1

_500000 11i

50015001100BI

500000 !50015001500!

_200003 !10001

_500000 15001

1

:338!i•ii1

500110001

1

Initial FoundSo i . So 1 .A AB

_4Sl403!_4326i33.l

15£~.

....... 1 459.i 910.

_4S79'38!_455888.4=2.

1 557,423.

_1"4833! 191163.| oq:_

_48ai36! 533383.1 =37.!

1 35a.

982.t

i

1 571.

1

3111;

01313101010131013:3131

3!

i01

'

i

3131

1

••'.R

_95.

105.97.91.97.93.

113._84.3="- _• .JQ....

130.101.

QC

_98.

114.0.

Ii Final round1 Sol. Sol.1 A AB %R1

5 1 _455388 1l' i

2181 131

_4S0530.1

1 529.490.

1 924.3i_475£C!3!_4S£338.A| l~ 494.41 101bl 1762081217 1 _492900 141

i :i ;

6 'i iii2! 1

11 1

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1 1

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1 1012._58£730.: 560.

1 932.

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01013101010101

1013101

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_95.

185.33.92.

_97.98.106.80.

101.133.196.;-• —

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i

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4 I41

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1 11 538.

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107.95.

51c- ;

1

Page 49: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

H AND TESTING, INC.SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLJ

MPLE SOURCE: Blosenski Landfill _____________________

WORK ORDER NO.: N/A________________ EHRT PROJECT NO.: 12319

DATE EXTRACTED: 11-12-90______________ DATE ANALYZED: 11-13-90

SAMPLE TYPE: Water Sample______________ SAMPLE VOLUME: 1000.00

ANALYST: K. Nusekabel___________ FINAL VOLUME: _LOO

CUSTOMER SAMPLE NO.: AS-E-120___________ EHRT SAMPLE NO.: 29453

LAB NOTEBOOK NO.: 149, Pg. 83____________ METHOD NO.: EPA 8270

RESULTCOMPOUNDS____________ ug/L

1. Phenol < 3.002. Bis(2-Chloroethyl)Ether < 2.003. 2-Chlorophenol < 2.004. 1,3-Dichlorobenzene < 6.005. 1,4-Dichlorobenzene < 6.006. Benzyl Alcohol < 3.007. 1,2-Dichlorobenzene . < 6.008. 2-Methylphenol < 3.009. Bis-(2-Chloroisopropyl) Ether < 4.0010. 4-Methylphenol < 3.0011. N-Nitroso-Di-n-Propylamine < 4.0012. Hexachloroethane < 6.0013. Nitrobenzene < 3.0014. Isophorone < 2.0015. 2-Nitrophenol < 4.0016. 2,4-Dimethylphenol < 3.0017. Benzole Acid > < 20.0018. Bis(2-Chloroethoxy)Methane < 2.0019. 2,4-Dichlorophenol < 4.0020. 1,2,4-Trichlorobenzene < 6.0021. Naphthalene < 1.0022. 4-Chloroaniline < 10.0023. Hexachlorobutadiene < 12.0024. 4-Ch!oro-3-Methylphenol < 3.0025. 2-Methylnaphthalene < 1.0026. Hexachlorocyclopentadiene < 12.0027. 2,4,5-Trichlorophenol < 5.0028. 2,4,6-Trichlorophenol < 5.00

flROOi965

Page 50: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-E-120______________ EHRT SAMPLE NO.:

29.30.31.32.33.34.35.36.37.38.39.40.41.42.43.44.45.46.47.48.49.50.51.52.53.54.55.56.57.58.59.60.61.62.63.64.65.

2-Chloronaphthalene2-NitroaniiineDimethyfphthalateAcenaphthylene2,6-Dinitrotoluene3-NrtroanilineAcenaphthene2,4-Dinrtrophenol4-NltrophenolDibenzofuran2,4-DinitrotolueneDiethylphthalate4-Chlorophenyl-PhenyletherRuorene4-Nitroaniline4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneDi-n-ButyphthalateRuoranthenePyreneButylbenzyiphthalate3,3'-DichlorobenzidineBenzo(a)AnthraceneChryseneBis(2-Ethylhexyl) PhthalateDi-n-OctylphthalateBenzo(b) RuorantheneBenzo(k)RuorantheneBenzo(a)Pyrenelndeno(1 ,2,3-cd) PyreneDibenzo(a,h)AnthraceneBenzo(g,h,i)Perylene

SURROGATE COMPOUND

Nitrobenzene-d52-RuorobiphenylTerphenyi-d14

Phenol-d52-Ruorophenol2,4,6-Tribromophenol

< 3.00< 10.00< 3.00 ^< 2.00 V< 6.00< 10.00.< 2.00< 40.00< 20.00< 6.00< 6.00< 2.00< 6.00< 3.00< 20.00< 20.00< 3.00< 6.00< 5.00< 20.00< . 2.00< 2.00< 1.00< 2.00 M< 2.00 < 3.00< 10.00< 3.00< 3.00< 2.00< 2.00< 10.00< 10.00< 6.00< 10.00< 10.00< 10.00

PERCENT RECOVERY

68.50%58.70%56.00%

10.00%* ^10.00% * M13.80%

* A recovery lower than 10% was obtained on surrogates due to heavy emulsion „ n , -, - -AROOI966

Page 51: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.PESTICIDES - PCS ANALYSIS

JSTOMER NAME: PEG LABORATORIES. INC. • MR. MIKE PETTEREL

V1PLE SOURCE: Blosenski Landfill

WORK ORKER NO.: N/A_____________ EHRT PROJECT NO.: 12319

UHTE EXTRACTED: 11-13-90__________ DATE ANALYZED: 11-13-90

MPLETYPE: Water Sample_______ METHOD NO.: EPA 608

AMALYST: M. Cooper__________ LAB NOTEBOOK NO.: 158. Pg. 56

CUSTOMER SAMPLE NO.: AS-E-120___________ EHRT SAMPLE NO.: 29453

RESULTCOMPOUNDS ug/L

1. Alpha-BHC < 0.00142. Beta-BHC < 0.00083. Delta-BHC < 0.00064. Gamma-BHC < 0.00065. Heptachlor < 0.00206. Aldrin < 0.00167. Heptachlor Epoxide < 0.00148. Endosulfan I < 0.00089. Dieldrin < 0.000410. 4,4'-DDE < 0.000411. Endrin < 0.000612. Endosulfan II < Q.0213. 4,4'-DDD < 0.0214. Endosulfan Sulfate < 0.000415. 4,4'-DDT - < 0.001216. Methoxychlor < 0.000417. Endrin Ketone < . o.0418. Chlordane < o.2019. Toxaphene < 3.00

flROOI967

Page 52: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

JSTOMER SAMPLE NO.: AS-E-120___________ EHRT SAMPLE NO.: 29453

20.21.22.23.24.25.26.

Aroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260

< 0.50< 0.50< 0.50< 0.50< 0.50< 0.50< 0.50

SURROGATE RECOVERY

Dibutylchlorendate - ____65.30%

AROOI968Pans?

Page 53: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

COVER PAGE - IMORGAN1C ANALYSES DATA PACKAGE

;rM5: EN'.'Ifi. _HEALTH_iE5EARCH_TE Contract: DBG

_ac I.-ce: -'26__ ."35.25 No. : 3LG5E SAS No. : 1£319_ SDG No. : 888388

OU Mo.: ___

EPP Samale No. i_s_D Sample ID._AS£i£3_ £3453

Wers ICP inter 5 lenient correct ions acpiied ? v==/No V'EE

Were ICP background corrections applied 7 Yes/No Y'EEIf yes - were raw data generated beforeapplication of background corrections ? Yes/No NO

Cornnisnt =;CE-5_L ABO RATQRI E=_-_BLOSENSK I _LANDF I LL_DATE_DF_ANAL YS IS 11 /12/ 99___ICP_S.STAKE_MBl55_P346_rtETHOD_S01«/_FURNflCi_P. BARNWELL_NB154_PG£2___~ O R _ J . RADER_NB157_P6c2_METHOD_7470_____

Rel=5=? of th= data contaiisd in this hardcopy data package and in thecofnD:.:t5r->-=5d.3uis "5ta submitted on floDpy diskette has been author:z=cth= i.sbcrat.-r-y Manager or the "tanapsr's designee, as verified by thef•: 1 lew; rig =; i3t:at:-!»*5.

Lab Manager:

Osta:COVER 3P3E - IN

flRQOI969

Page 54: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET __

i ASE120_.-.c J------ : ENVIR. _KEALTH_RESEARCH_TE Contract: QB5_____ i__________

Case No.: BLG5E SA5 No.: 12319_ 5D6 No.: 008000

Matrix 'soil/water,' : WATER Lab Sample ID: 25453

Level • lo^/mec) : ___ Date Received: i 1/09/90

'.-. ' -•.- D.--

Concentrat ion

ii!CA3 No.

! 7429-33-517440-35-iZi1 7440-3 E-2! 7 40-39-317440-4 1-717440-42-rI 7440-70-217443-47-3I 744:3-4.9-4! 7440-53-317439-69-617439-92-11 7439-95-4! 7439-96-5i 7439-97-6

17732- 5-2i 7440-22-41 744i?-23-5i 744i?-2S-3i 7440-62-21 7440-56-61i

ore s

:=r :

Units (ug/L or r.ig.'kg dry

i : ii Ana i , t s ; Concent rat i on iI •: ii Alu.TiiiV.iM I! Ant ;mony i 13. 7 ii Arsenic i 2. 2 !(Barium '• •.i Beryllium; 0. -M3 '! Cad mum i 1.6 1iCaiciui" i i1 Chromium i 5. 3 ii Cobalt i • I.'Copper ! 5. 0 ii Iron I !I Lead i 10.9 1IMaqnesiumi iIManqanesei i! Mercury ! 0. 1 1i Nicks I ! 4.6 ;1 Pot as si urn; if Selenium : 2. 1 !! Silver \ 1.9 !! So a i urn i |! Thallium • 35.5 I1 Vanadium i iiZinc ! £.411C van ids i i! ... ..... 1 1

Clarity Before:

Clarity After:

weight;1

i

r1 ' nj!

UiUI!

UIUi

1U!

!

UI1

Ui11!

UIUI

1UIUi

iUI

1

UI:i

: L'G/L_

j

' f:1 •'

i i-NR!i p !

•F ;INR!IF iIP !!NRiIPI N R Ii Ei N R iIP ii NR i! NR !ICVIIP i!NR!, r iIP iI N R IIP IINR!IP iINR!i i

Texture:

Artifacts:

i .'™'

: - INflROOI970

Page 55: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPfi - CLP

£AINITIAL AND CONTINUING CALIBRATION VERIFICATION

LSD Name: ENV'Ifi. _HEALTH_RESEARCH_TE Contract: OBG

Lab Cods: Wfl3__ Case No.: BLOSE SAS No.: li£319_ 5DG No.: 000000

Initial Calibration Source: SPEX

Cont iryjinn Cs : i brat i on Source: SPEX

Concent rat i on Un i t

i IlAnalyte f! Ii 01 -..mi n urn '! Antimony !i Arsenic 1i Ban urn !i Bery Hi urn i! Cadmium i'Calcium 1I Chromium 'i Co bait 1! Copper ii Iron 1! Lead iIMaqnesiurnli Manqanese i1 Mercury 1(Nickel 1! Potassium!1 Selenium !1 Silver 1i Sod i urn 1i Thallium 1I Vanad i urn 1IZinc li Cyanide ii l

InitialTrue

i500. 0 !50.3 !

I

500.0 !300.0 i

1500.0 <•

1500.0 !

i530. 0 !

11

5.0 150Q.0 1

I10.0 !

100.3 !i

1000.3 !i

500.0 :!i

Cai ibrat ionFound ;'.R(i)

15S7.50J 101. 547.90! 95.3

i476.30! 95.3490.401 98.1

I549. 00! 10S. 8

I489.001 97.3

1483.201 96.6

• !It

5.481109.6490.70! 98. 1

110.501105.097. 10! 97. 1

1946.50! 94.6

1494. 90! 99.0

I1

I11 Truei1 11 500.0 !

1 50. 0 1! 1i__500. 0_!i 500.0 I

1 11 500.0 I

1 1I 500.0 I

1 I1 500.0 1

I 1I 11 5.0 i1 500.0 11 11 20.0 !1 100.0 II 1!_1000. 0 11 "l1 500. 0 1

1 !1 1

s: ug/L

Cont i nu i no Ca 1 i brat i onFound #Rrt) Found

i I508.301101.7!49.301 99.5!

I i471.80! 34.4!483.60! 96.71

1 !548. 70! 109. 7!

'1 I479.80! 96.01

I l478.401 95.71

I 11 !

5.301106.0!483.20! 95.6!

1 !19.901 99.5!96.701 96.71

! i951.90! 96.2!

1 !493.701 98.7!

! 1I 1

1 i !i 1 !

•/.R (1)1! Ml! 1 ;

1 I I NR 1i f 1 P f

i IF iI ! NR II IP i! IP 11 ! NR !1 IP i1 1 N.9 11 IP !

1 1 1 NR !1 I IP i1 i ! NR !1 I ! NR I! i f CV !1 I I P !1 i 1 NR I1 IIP !1 I I P !1 I I N RIi : i P i! I I N R If I I P !I i ! NR i! 1 1 !

•:i) Control Limits: Mercury 80-126! Other Metals 90-110! Cyanide 85-115

~ORM II (PART 1) - IN _ ,SROOI971

Page 56: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

2AINITIAL AND CONTINUING CALIBRATION VERIFICATION

_rr •;=:=: ENVIR. _HEALTH_RESEARCH_7E Contract: DBG

-r« I-;-as: jJ88 Case No.

x nitiai Hal

: BLQSE 3AS No. : J

i r-r at i on Source : SPEX

.2319_ SDG No. : 000000

Cont i.''.:i rig Calibration Source: SPEX

1

i

iifi

i

j

i

!

1!11

1

i

Anai/te ii

Aluminum 1Ant : ri:ony_ 1

Barium !Bery 1 1 i urn 1Cadmium. ICa-lciurn !Chromium_lCobalt lCo --per !I >*,;.,•; !

Leas ___ IMagnesium!Manganese-'Me'' cur. _. i

Pot as si urn 1Selsrdun- _!Silver 1Sod . urn 1Tha Hi. ,,-;!_!Variaa i urn iZinc 1Cyan ice !

t

Concent

Initial CalibrTrue Found

I12000.0 111760.

J

i

108C. 0 1 988._lSi3l2,(ZM_10£S.

"l "20-30,8 i 1919.

I5030.0 1 5299.

I500.0 1 581.

!i»

88C0. 3 i 7847.!I

2000.0 i 1978.1

2000. 0 1 2065.1

4030.3 1 4125.11

00

00

00

00

00

50

00

00

00

00

ration LSf'its: uo.-'L

: ! iat ion • • Continuing Calibration !!•/.R(l)f True Found %R'1> Found '-'.Rd;!.1 M

i 1 I

i 98.

ij

i 95.I 102.l

i 96.1! 10S.II 96.

i

! 98.111.98.I1103.

1103.1i

i31 12000.

I:

3!_1000.ai 1300.

101 2300.

01 5000.I

91 £00.i!!

1 I 3000.11

9! 2000.1

2 1 _230S.i

4 I _4000.

1

: !

0 '12170.00!l 1i j

0 ! 1017.00!3 i 1074.001

i 13 1 1971.001

! 10 ! 5364,00!

: i3 i 609.90!

I if 1

! 1| j

0 I 3030.00!| !

I I

0 j 2026.00!j j

0 ! 2118.001i I

0 : 4255.00!1 1!• !

J

101.41i

i I l i N R; i IP! 1 ! NR

!T111

1! i i 1 NR i

101.71107.41

198.61

1107.3!

I101.61

i11

101. 1 11

1

101.3!1

105.9!1

105.411!

! 1 IPi ! IPI 1 iNRi IIPi 1 1 NR1 1 IP1 f INR1 MP1 1 INR1 1 INR1 i 1 NR! IIP1 1 1 NR1 1 INR! IIPI I I N R! IIPI ! I NRI I IP1 i INR

! 1

i!

1

|

j

I

1

11

1

I

1

1

1

1

1

!1:

(1) Control Limits: Mercury 80-120' Other Metals 90-1105 Cyanide 85-115

Page 57: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

BLANKS

« Name: ENVIR. _HEAL7H_FE5EARCH_TE Contract: OBG

Las Cods: Wi

Prspa^rtion

Pveparat ion

i li I1 1! iIPnalyte i1 !'Aluminum 1! Antimony 1(Arsenic iI Barium 1f Beryllium!1 Cadmium 11 Calcium 1i Chromium !, /-t _ •. • _ ,i L'-<o<sit !! Copper 1! Iron 1! Leadi Magnesium i> Manganese 1I Mercury i(Nickel i1 Pot as si urn!i Selenium !! S i 1 ver 1! Sodium I! Thallium 1I Vanad i urn iI Zinc 11 Cyanide I1 I

38 __ Ca

Blank Matrix (

Blank Concentr

11

Initial . !Caiib. !Blank 1(us/L) Cl

11 !

10.7 IU!2.2 IUi

1 I0.4 IUI1.8 IUI

I i5.3 IUI..

1 !5. 0 IUI

I 110. 9 ! 1

1 iI I

0.1 ;ui_4.6 IUI

1 I2.1 IUI ._1.9__IUI_

1 I95.5 I I

1 1£.4 IUI _

1 1I I

se No. : BLOSE SAS No. : 1£Z

soil ./water): WATER

at ion Units (ug/L or nig /kg) :

Cont inuing Cal i brat ionBlank. (ug/L)

1 C 2 C 3

i i 1 !10.7 IU! 1£. £ IUI 1

I I !0. 4 IUI 11.8 IUI I

I i !5.3 IUI I

1 ! 1 15.0 IB! I 1

I I I I10. 9 1 1 I !

! 1 I !1 ' I !

0. 1 ! U 1 II4.5 IU! 1 1

1 ! 1 i2. 1 I U 1 111.9 IUI I 1

1 ! I I95. 5 1 f •• II

I I 1 1£ . 4 I U I . 1 1

I I I I! I 1 I

19_ 3DS No. : 000000

UG/L_

I! I!M II !I i Prepa- 1 1!! ration M I

C! i Blank Cl i MM I I !

I l l I I I N R i1 M 10. 700IUMP ff ! ! S. 200 i U ! ! F 1! ! I 1 ! 1 NR 11 II 0.400 IUI IP

! 1! 1.S00IUIIP !i l l 1 I I N R !Ili 5. 300 1 U 1 ! P 1III i ! ! NR1 II 5. =310161 IP IIII ! 1 ! NR Ii l l 1 0 . 9001 M P 1III 1 1 INR 1I I I I I N R 1I I 0 . 10CIUI I C V 11 | 4.600IUMP 11 I 1 MNR 1II 2. 140 IUI IF 1I ( 1.980IUI IP__II I 1 M N R 1i | 95.5001 MP_!Ill 1 I INR !! M £.400IUIIP_Ii l l ! 1 I N R !I i! ! M 1

FORM III - IN

flROOI973

Page 58: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

PREDESIGN REPORT

BLOSENSKI LANDFILLCHESTER COUNTY, PENNSYLVANIA

APPENDIX 5-3

ftRQOI97l+

Page 59: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

Environmental Health Research and Testing, Inc.

3235 Omni Drive Cincinnati, Ohio 45245 (513) 752-2950 FAX (513) 752-2261

January 8, 1991 xjT c '\

O'BRIEN AND GERE ENGINEERS, INC.ATTN: Mr. Tee Tong-ngork5000 Brittonfield Pkwy - Suite 300P.O. Box 4942Syracuse, New York 13221

Dear Mr. Tong-ngork:

Please find enclosed the results of analysis for the 13 samples received on January 2, 1991.

If you have any further questions, please feel free to contact me at (513) 752-2950.

Sincerely,

Mona Risk, Ph.D.Director of Chemistry

MR:jw

Enclosures

cc: Charles McGuth

NATIONAL OFFICES

Cincinnati, Ohio • Lexington, Kentucky • Research Triangle Park, North Carolina • _Denver, Colorado • Birmingham, Alabama • Philadelphia, Pennsylvania • San Francisco, California * Mflnfi) I{fy(d)i j Q ~j S

Page 60: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

'

flROOI976

Page 61: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CHAIN OF CUSTODY RECORD

LABORATORIES, INC.

METHOD OF SHIPMENT:

OBG Laboratories, Inc., an O'Brien & Gere Limited Company5000 Brittonfield Parkway / Suite 300 / PO Box 4942 / Syracuse, NY 13221 / (315) 437-0200 ftROO i 977

Page 62: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CHAIN OF CUSTODY RECORD

LABORATORIES, INC.

SURVEY:

LOCATION:

SAMPLED BY:

ORGAN.ZATION: 0 .

STATIONNUMBER SAMPLE LOCATION DATE

COLLECTEDTIME

COLLECTEDSAMPLEMATRIX

COMP.OR GRAB

NO. OFCONTAINERS

ANALYSISREQUIRED

METHOD OF SHIPMENT: r^- \ a f^

T

OBG Laboratories, Inc., an O'Brien & Gere Limited Company5000 Brittonfield Parkway / Suite 300 / PO Box 49421 Syracuse, NY 13221 / (315) 437-0200 - n n n , A -. -978

Page 63: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

COVER PAGE - INORGANIC ANALYSES DATA PACKAGE

Lab Name: ENVIR._HEALTH_RESEARCH_TE Contract: QBG____

Lab Code: W88__ Case No.: BLOSE SAS No.: 1£495_ SDB No. : 000000

SOW No.: ___

EPA Sample No. Lab Sample ID._NCC100_ 30654_____NCC105_ 30655_____NCC85__ 30651____NCC90__ 30652_____NCC95__ 30653_____NCC95D_ 30656____NCL100_ 30660____NCL105_ 30661ft____NCL105D 3066 IB____NCL105S_ 30661____NCL85__ 30657_____NCL90__ 30658_____NCL95__ 30659_____NCRAW__ 306££____

NCRAWF 30663

Were ICP interelement corrections applied ? Yes/No YES

Were ICP background corrections applied ? Yes/No YESIf yes - were raw data generated beforeapplication of background corrections ? Yes/No N0_

Comments:BLOSENSKI J.ANDF I LL_DATE_OF_ANALYS I S_JANUARY_4, _1991 ______________ICP_G.STAKE_NB156_PG78 METHOD_6010/ FURNACE_P.BARNWELL 169 PG3 METHODAS7060/ COLD VflPOR M. COOPER NB157 PG48 METHOD 7470

Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on floppy diskette has been authorized bythe Laboratory Manager or the Manager's designee, as verified by thefollowing signature. L Q 'A

Lab Manager:

Date: l\COVER PAGE - IN 7/87

flROOI979

Page 64: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS. INC.

SAMPLE SOURCE: N/A

WORK ORDER NO.: N/A PROJECT NO.: 12495

ANALYSIS PERFORMED: Total Suspended Solids Analysis

ANALYSIS METHOD: Std. Method 209C

ANALYST: M. Reddy

DATE ANALYZED: 01 -03-91

LAB NOTEBOOK NO.: 137, Pg. 80

SAMPLE NO.EHRT NO. CUSTOMER NO.

30651 NC-C-8.5

30652 NC-C-9.0

30653 NC-C-9.5

30654 NC-C-10.0

30655 NC-C-10.5

30656 NC-C-9.5-D

30657 NC-L-8.5

30658 NC-L-9.0

30659 NC-L-9.5

30660 NC-L-10.0

30661 NC-L-10.5

30662 NC-RAW

RESULTS(mq/L)

146

164

182

174

172

142

188

312

452

502

310

134

Detection Limit: < 20 mg/L

Page1 flROOI980

Page 65: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET _____

I II NCC85 I

Lab Name: ENVIR. _HEALTH_RESEflRCH_TE Contract: OBG_____ I___________I

Lab Code: W88__ Case No.: BLOSE SAS No.: 1£495_ SDG No.: 000000

Matrix (soil/water): WATER Lab Sample ID: 30651___

Level (low/med): ___ Date Received: 01/02/91

% Solids: ___

Concentration Units (ug/L or mg/kg dry weight): UG/L_

Color Before:

Color After:

Comments:

1ICAS No.

1I74S9-90-51 7440-36-01 7440-38-21 7440-39-317440-41-71 7440-43-91 7440-70-2| 7440-47-31 7440-48-41 7440-50-81 7439-89-617439-92-117439-95-41 7439-96-51 7439-97-61 7440-02-01 7440-09-7

1 7782-49-21 7440-22-41 7440-23-51 7440-28-0

1 7440-62-21 7440-66-611

1 1 I I1 Analyte IConcentrationlCI Q1 1 I I1 Aluminum 11 Antimony 11 Arsenic 1

1 Barium 11 Beryl Ii urn 11 Cadmium 1(Calcium 11 Chromium 11 Cobalt 11 COD oer 11 Iron 1! Lead 1I Magnesium)1 Manganese 11 Mercury 1INickel 11 Potassium!(Selenium 11 Silver 1

1 Sodium 1(Thallium 1

1 Vanad i urn 1(Zinc 1(Cyanide 11 1

Clarity

Clarity

1 11 1

2.2 IUI1 11 1

1.3 iUI1 1

5.3 IUI1 11 11 1

10.9 IUI1 11 i

0. 1 IUI '4.6 IUI

1 If 11 11 11 I1 11 11 !1 1

Before:

After:

i 1IM 11 1INRIINRIIF IINRIINRIIP 1

_INRIIP 1INRIINRIINRIIP 1INRIINRI1CVIIP 1INRIINRIINRIINRIINRIINRIINRIINRI1 1

Tex'

Art

NC-C-8. 5POST DIGEST SPIKE (ARSENIC) = 103'/. RECOVERY

FORM I - IN 7/87

&ROQ1981

Page 66: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP.

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

Name: ENVIR. _HEALTH_RESEARCH_TE

Code: W88 Case No. : BLOSE

rix (soil/water): WATER

?1 (low/med) :

olids: ___

Concentration Units (ug/L

1 11 NCC90 1

Contract: OBG 1 I

SAS No. : 12495_ SDG No. : 000000

Lab Sample ID: 30652

Date Received: 01/02/91

or rng/kg dry weight): UG/L_

1 1 1 1 1 1 1ICAS No. 1. Analyte IConcentrationlCI Q IM 1

1 1 1 1 1 1 117429-90-5 1 Aluminum 117440-36-0 (Antimony 117440-38-2 (Arsenic i17440-39-3 1 Barium 117440-41-7 1 Beryllium!17440-43-g | Cadmium 117440-70-2 1 Calcium 117440-47-3 1 Chromium 117440-48-4 1 Cobalt I17440-50-8 1 Copper 117439-89-6 I Iron 117439-92-1 ILead I1 7439-95-4 1 Magnes i urn 117439-96-5 (Manganese!17439-97-6 1 Mercury 117440-02-0 (Nickel 11 7440-09-7 1 Pot ass i urn 117782-49-2 1 Selenium 117440-22-4 (Silver 117440-23-5 (Sodium 117440-28-0 1 Thai Hum 117440-62-2 1 Vanadium 117440-66-6 (Zinc 11 ICvanide 11 I 1

or Before: Clarity

or After: Clarity

merits:

I I INRII I INRI

2. 2 IUI IF 1I I INRII I INRI

1.3 IUI IP 1. ! 1 INRI

5.3 IUI IP II I INRI1 1 INRII I INRI

10.9 IUI IP 1I I INRII I INRI

0.1 IUI ICVI4. 6 IUI IP 1

1 1 INRII I INRII f INRII I INR!I I INRI1 I INRII I I N R 1I I INRII I I I

Before: Texture:

After: Artifacts:

NC-C-9. 0

FORM I - IN 7/87

fiROQI982

Page 67: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPfl SAMPLE NO.INORGANIC ANALYSES DATA SHEET

i Name: ENV!

Code: W88_

rix (soil/i

B! (low/mec

olids:

Cc

or Before:

or After:

ments:

IR. HEALTH RESEARCH TE Contract: OB6

1 11 NCC95 i1 1

_ Case No. : BLOSE SAS No. : 12495_ SD6 No. : 000000

nater) : WATER Lab Sample ID: 30653 ___

1) : ___ Date Received: 01/02/91

mcentration Units (ug/L or mg/kg dry weight): UG/L_

1ICAS No.11 7429-90-51 7440-36-01 7440-38-21 7440-39-317440-41-71 7440-43-91 7440-70-217440-47-3| 7440-48-41 7440-50-81 7439-89-617439-92-11 7439-95-41 7439-96-51 7439-97-61 7440-02-01 7440-09-71 778£-49-21 7440-22-4

1 7440-23-51 7440-28-01 7440-62-21 7440-66-611

1 I I . I1 Analyte (Concent rat ionlCI QI 1 I I(Aluminum 1 1 1(Antimony 1 1 1(Arsenic 1 2.2 IUI(Barium I ! 1(Beryllium! 1 11 Cadmium 1 1.8 IU I1 Calcium 1 1 11 Chromium 1 5. 3 IUII Cobalt 1 1 11 Copper 1 1 I1 Iron 1 1 1ILead 1 10.9 IUIIMaqnesiumi 1 1

1 Manqanese 1 1 11 Mercury 1 0. 1 1 U 1(Nickel 1 4.6 IUI(Potassium! 1 11 Selenium 1 1 11 Silver 1 1 11 Sodium 1 1 11 Thai Hum 1 1 11 Vanadium 1 1 1I Zinc 1 1 1(Cyanide I 1 I1 • I I I

Clarity Before:

Clarity After:

1 1IM 1! 1INRIINRIIF 1INR!INRIIP 1INR!IP 1INRIINRIINRIIP 1INRIINRIICVIIP 1INRIINR!INR!INRIINR!INRIINRIINRI1 1

Texture:

' Artifacts: __

NC-C-9. 5

FORM I - IN 7/87

flROOI983

Page 68: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

Name: ENVIR. HEALTH RESEARCH TE

Code: W88 __ Case No. : BLOSE

*ix (soil/water): WATER

;1 (low/med): ___

Dlids: ___

Concentration Units (ug/L

1 11 NCC10J0 1

Contract: OBG I 1

SAS No. : 12495_ SDG No. : 000000

Lab Sample ID: 30654 ___

Date Received: 01/02/91

or mg/kg dry weight): UG/L_

I 1 I 1 1 1 IICAS No. 1 Analyte IConcentrationIC! Q IM 11 1 1 1 1 1 117429-90-5 1 Aluminum 11 7440-36-0 1 Ant i mony 117440-38-2 I Arsenic 117440-39-3 1 Barium 117440-41-7 (Beryllium I17440-43-9 I Cadmium 117440-70-2 1 Calcium 117440-47-3 1 Chromium !17440-48-4 1 Cobalt 117440-50-8 (Copper 117439-89-6 I Iron 117439-92-1 (Lead 117439-95-4 1 Magnesium 117439-96-5 1 Manganese!17439-97-6 I Mercury 117440-02-0 1 Nickel 117440-09-7 1 Potassium!17782-49-2 1 Selenium I17440-22-4 (Silver 117440-23-5 1 Sodium 117440-28-0 I Thai Hum 117440-62-2 I Vanadium 117440-66-6 IZinc I

1 1 Cyanide 11 1 1

or Before: Clarity

or After: Clarity

ment s :

I I INR!I I INRI

2.2 IUI IF II I INRI1 1 INRI

1.8 IUI IP 11 1 INR!

5.3 IUI IP 11 f INR!I I INRII I INRI

10.9 IUI IP II ! INRI1 I INRI

0. 1 1 U 1 1 CV 14.6 IUI IP 1

1 1 . INRI1 I INRII I INR!I 1 INRII I INRI1 1 INRI1 1 INRII I INRII I I I

Before: Texture:

After: Artifacts:

NC-C-10.0

FORM I - IN 7/87

Page 69: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORBANIC ANALYSES DATA SHEET

I II NCC105 I

Lab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: OBG_____ I___________I

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDG No.: 000000

Matrix (soil/water): WATER Lab Sample ID: 30655____

Level (low/med): ___ Date Received: 01/02/91

% Solids: ___

Concentration Units (ug/L or mg/kg dry weight): UG/L_

1 1 1 M i lICAS No. 1 Analyte 1 Concent rat ionlCI Q IM 11 1 1 1 1 1 I17429-90-5 1 Aluminum 1 1 117440-36-0 1 Antimony 1 1 117440-38-2 1 Arsenic 1 2.2 IUI17440-39-3 1 Barium 1 1 117440-41-7 IBervlliuml 1 117440-43-g (Cadmium 1 1.8 IUI17440-70-2 1 Calcium I I I17440-47-3 | Chromium 1 5.3 IUI17440-48-4 1 Cobalt 1 1 117440-50-8 (Copper 1 1 117439-89-6 1 Iron I I I17439-92-1 ILead I 10.9 IUI17439-95-4 IMaqnesiuml 1 117439-96-5 IManaanese! 1 11 7439-97-6 1 Mercury 1 0. 1 1 U 117440-02-0 1 Nickel I 4.6 IUI17440-09-7 1 Pot ass i urn 1 1 117782-49-2 1 Selenium 1 I I17440-22-4 (Silver 1 1 117440-23-5 1 Sodium 1 I I17440-28-0 1 Thai Hum 1 I I17440-62-2 1 Vanadium I 1 117440-66-6 IZinc 1 I I1 ICvanide 1 1 11 1 1 I I

or Before: Clarity Before:

or After: Clarity After:

ments:

INRIINRIIF 1INRIINRIIP 1INRIIP 1INRIINRIINRIIP 1

__ INRIINR!ICV!IP 1INRIINRIINRIINRIINRIINRIINRIINRI1 1

Texture:

Artifacts:

NC-C- 10.5

FORM I - IN 7/87

flROOJ985

Page 70: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

I NCC95DLab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: OBG______ I_______

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDG No. : 000000

Matrix (soil/water): WATER Lab Sample ID: 30656___

Level (low/med): ___ Date Received: 01/02/91

•/. Solids: ___

Concentration Units (ug/L or rng/kg dry weight): UG/L_

1 1 1 I IICAS No. 1 Analyte 1 Concent r at i on ICI Q1 I I I I17429-90-5 1 Aluminum 117440-36-0 (Antimony 117440-38-2 1 Arsenic I17440-39-3 1 Barium 117440-41-7 | Beryl Hum!17440-43-9 1 Cadmium 117440-70-2 1 Calcium 117440-47-3 (Chromium 117440-48-4 I Cobalt 117440-50-8 1 Copper 117439-39-6 1 Iron 117439-92-1 ILead 117439-95-4 IMaonesiuml1 7439-96-5 1 Mannanese 117439-97-6 1 Mercury 117440-02-0 1 Nickel 11 7440-09-7 1 Pot ass i urn 117782-49-2 (Selenium 117440-22-4 (Silver 117440-23-5 1 Sodium 117440-28-0 1 Thai Hum 117440-62-2 1 Vanadium 117440-66-6 IZinc 11 1 Cyanide I1 I I

I 11 1

2.2 IUI1 1I 1

1.8 IUI1 I

5.3 IUI1 11 11 1

10.9 IUI1 !1 1

0.1 IUI4.6 IU!

I 1I 11 11 11 11 11 11 11 1

1 1IM 11 1INRIINRIIF 1INRIINRIIP 1INR!IP IINRIINRIINRIIP 1INRIINRIICV!IP 1INR!INRIINRIINRIINRIINRIINRIINRI1 1

Color Before: ______ Clarity Before: _______ Texture:

Color After: ______ Clarity After: ____ Artifacts:

Comments:

NC-C-9.5-D

FORM I - IN 7/87

flROOJ986

Page 71: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

Name: ENVIR. HEALTH RESEARCH TE

Code: W88 Case No. : BLOSE

rix (soil/water): WATER

=1 (low/med): ___

olids: _____

Concentration Units (ug/L

1 11 • NCL85 1

Contract: OBG 1 |

SAS No. : 1£495_ SDS No. : 000000

Lab Sample ID: 30657 ___

Date Received: 01/02/91

or mg/kg dry weight): UG/L_

1 I ! 1 1 1 1ICAS No. 1 Analyte 1 Concent r at ionlCI Q !M 11 1 1 I 1 1 117429-90-5 1 Aluminum 117440-36-0 1 Antimony 117440-38-2 1 Arsenic 117440-39-3 1 Barium 117440-41-7 1 Beryllium!17440-43-9 1 Cadmium 117440-70-2 i Calcium I17440-47-3 1 Chromium 117440-48-4 1 Cobalt 117440-50-8 1 Copper 117439-89-6 1 Iron 117439-92-1 ILead 117439-95-4 1 Magnesium!17439-96-5 1 Manganese!17439-97-6 1 Mercury 117440-02-0 1 Nickel 11 7440-09-7 1 Pot ass i urn I17782-49-2 1 Selenium 117440-22-4 (Silver 117440-23-5 1 Sodium 117440-28-0 (Thallium 117440-62-2 1 Vanadium 117440-66-6 I Zinc 11 1 Cyanide 11 1 i

or Before: Clarity

or After: Clarity

rnents:

I I INRII I INRI

2.2 IUI IF 1I I INRII I INRI

1.3 IUI IP 1I 1 INRI

5.3 IUI IP 1I I INRI1 1 INRI( I INRI

10.9 IUI IP 1I I INRI1 1 INR!

0. 1 1 U 1 1 CV 14.6 IUI IP 1

I I INRII I INRII I INRII f INRII I INRI1 1 INR!I I INRII I INRII I I I

Before: Texture:

After: Artifacts:

NC-L-8. 5

FORM I - IN 7/87

AROOI987

Page 72: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET ____

I NCL90Lab Name: ENVIR._HEALTH_RESEARCH_TE Contract: OBG_______ I________

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDG No. : 000000

Matrix (soil/water): WATER Lab Sample ID: 30658___

Level (low/med): ___ Date Received: 01/02/91

% Solids: ___

Concentration Units (ug/L or mg/kg dry weight): UG/L_

Color Before:

Color Afters

Comments!

1ICAS No.I1 7429-90-51 7440-36-01 7440-38-21 7440-39-317440-41-71 7440-43-91 7440-70-2| 7440-47-31 7440-48-41 7440-50-81 7439-89-617439-92-11 7439-95-41 7439-96-51 7439-97-6

1 7440-02-01 7440-09-71 7782-49-21 7440-22-41 7440-23-51 7440-28-017440-62-21 7440-66-61I

1 i I I1 Analyte (Concent rati on ICI Q

I 1 I I1 Aluminum 1 1 11 Ant i mony I 1 11 Arsenic 1 2.2 IUI1 Barium 1 1 11 Beryl liuml 1 11 Cadmium I 1.8 IUI(Calcium 1 1 11 Chromium 1 5. 3 IUI1 Cobalt 1 1 I1 Copper I 1 1llron 1 1 1(Lead 1 10.9 I UIIMaanesiuml 1 11 Manganese 1 1 11 Mercury I 0.1 IUI1 Nickel 1 4. 6 IUI1 Potassium! 1 1ISelenium 1 1 I1 Silver 1 1 11 Sodium 1 1 11 Thai Hum 1 1 1(Vanadium 1 1 1IZinc 1 1 11 Cyanide 1 1 11 1 I I

Clarity Before:

Clarity After:

1 11M 11 IINRIINRIIF 1INRIINRIIP 1INRIIP 1INR!INRIINRIIP 1INR!INRIICVIIP IINRI

_INR!INRIINR!INRIINRIINRIINRI1 1

Texture:

Artifacts:

NC-L-9.0

FORM I - IN 7/87

AROOI988

Page 73: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET ____ __

I NCL95 ILab Name: ENVIR._HEALTH_RESEARCH_TE Contract: OBG_____ I___________I

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDB No. : 000000

Matrix (soil/water): WATER Lab Sample ID: 30659___

Level (low/med): ___ Date Received: 01/02/91

% Solids: ___

Concentration Units (ug/L or mg/kg dry weight): UG/L_

1 1 1 I I I !ICAS No. 1 Analyte IConcentrationlCI Q IM 11 1 f I I I !17429-90-5 1 Aluminum 117440-36-0 (Antimony I17440-38-2 (Arsenic I(7440-39-3 1 Barium 117440-41-7 1 Beryl Hum!17440-43-g | Cadmium 117440-70-2 (Calcium 117440-47-3 1 Chromium 117440-48-4 1 Cobalt 117440-50-8 ICopoer 117439-89-6 1 Iron 117439-92-1 I Lead 117439-95-4 IMaqnesiumi17439-96-5 1 Manqanese 117439-97-6 1 Mercury 117440-02-0 1 Nickel 11 7440-09-7 1 Pot ass i urn 117782-49-2 1 Selenium 117440-22-4 1 Silver 117440-23-5 (Sodium 117440-28-0 (Thallium 117440-62-2 (Vanadium 117440-66-6 (Zinc 11 1 Cyanide 11 1 1

1 11 1

2.2 IUI1 I1 1

1.8 IUI1 1

5.3 IUII 11 11 1

10.9 IUI1 11 1

0.1 IUI

4.6 iUI1 11 II 11 !1 11 1I 11 11 1

INRIINRIIF 1INRIINR!IP IINRIIP 1INRIINRIINRIIP 1INRIINRIICVIIP IINRIINRIINRIINRIINRIINRIINRIINRII 1

Color Before: _______ Clarity Before: _______ Texture:

Color After: ______ Clarity After: ____ Artifacts:

Comments:

NC-L-9. 5POST DIGEST SPIKE (ARSENIC) = 107/4 RECOVERY

FORM I - IN 7/87

flROOI989

Page 74: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET ___________

II NCL100

Lab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: OBG______ I________

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDG No. : 000000

Matrix (soil/water): WATER Lab Sample ID: 30660___

Level (low/med): ___ Date Received: 01/02/91

% Solids: ___

Concentration Units (ug/L or rng/kg dry weight): UG/L_

I 1 1 I IICAS No. 1 Analyte (Concent r at ion 1C I Q1 1 1 I I17429-90-5 1 Aluminum 117440-36-0 1 Antimony 117440-38-2 1 Arsenic 117440-39-3 1 Barium 117440-41-7 | Beryl Hum!17440-43-9 1 Cadmium 117440-70-2 1 Calcium 117440-47-3 1 Chromium 117440-48-4 1 Cobalt 117440-50-8 1 Copper 117439-89-6 1 Iron 117439-92-1 ILead I1 7439-95-4 1 Maqnesi urn 117439-96-5 IMannanesel17439-97-6 1 Mercury 117440-02-0 1 Nickel 117440-09-7 1 Potassium 117782-49-2 1 Selenium 1(7440-22-4 1 Silver 117440-23-5 1 Sodium 117440-28-0 1 Thai Hum I17440-62-2 I Vanadium 117440-66-6 IZinc 11 (Cyanide 11 1 1

1 11 1

2.2 IUI1 11 1

1.8 IUI1 1

5.3 IUI1 11 1I 1

10.9 IUI1 11 I

0.3 1 I4.6 IUI

1 1I 11 11 I1 11 11 11 11 1

I 1!M 11 1INR!INRIIF 1INRIINRI

_JPJINRIIP 1INRIINRIINRIIP 1INRIINRIICVIIP 1INR!INRIINR!INRIINRIINRIINR!INRI1 1

Color Before: ______ Clarity Before: ____ Texture:

Color After: _______ Clarity After: ____ Artifacts:

Comments:

NC-L-10.0

FORM I - IN 7/87

flROOI990

Page 75: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET ____________

I II NCL105 I

Lab Name: ENVIR._HEALTH_RESEARCH_TE Contract: OBG_____ I___________I

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDG No. : 000000

Matrix (soil/water): WATER Lab Sample ID: 30661A__

Level (low/med): ___ Date Received: 01/02/91

% Solids: ___

Concentration Units (ug/L or mg/kg dry weight): UG/L_

1ICAS No.i17429-90-51 7440-36-01 7440-38-21 7440-39-317440-41-71 7440-43-91 7440-70-21 7440-47-3| 7440-48-41 7440-50-81 7439-89-617439-92-11 7439-95-41 7439-96-51 7439-97-61 7440-02-01 7440-09-71 7782-49-21 7440-22-41 7440-23-51 7440-28-01 7440-62-21 7440-66-611

1 I I II Analyte IConcentrationlCI Q1 1 I 11 Aluminum 1(Antimony 11 Arsenic 11 Barium 11 Beryl liuml(Cadmium 1(Calcium 11 Chromium 11 Cobalt 1I Copper 11 Iron 11 Lead 1IMaqnesiuml1 Manaanese i1 Mercury 1INickel 11 Potassium!(Selenium 1(Silver I1 Sod i urn 11 Thai Hum 11 Vanad i urn iIZinc I1 Cyanide 11 1

1 11 !

2.2 IUII 11 1

1.8 IUI1 1

5.3 IUI1 11 11 I

10.9 IUIi 11 i

0.9 1 1 .4.6 IUI

r i1 11 11 11 11 I1 11 11 I

1 1IM 11 IINRIINRIIF 1INRIINRIIP 1INRIIP 1INRIINRIINRIIP 1INRIINRIICVIIP IINRIINRIINRIINRIINRIINRIINRIINRII 1

Color Before: ____. Clarity Before: ____ Texture:

Color After: ______ Clarity After: ____ Artifacts:

Comments:

NC-L-10.5

FORM I - IN 7/87

Page 76: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

6 EPA SAMPLE NO.DUPLICATES ____________

I II NCL105D I

Lab Name: ENVIR._HEALTH_RESEARCH_TE Contract: OBG_____ I___________I

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDG No.: 000000

Matrix (soil/water): WATER Level (low/med): ___

% Solids for Sample: ___ "f> Solids for Duplicate: ___

Concentration Units (ug/L or mg/kg dry weight): UG/L_I i——————f-j——————————-——•———————-—————__ ^I I Control II II II I I I IlAnalyte I Limit II Sample (S) ClI Duplicate (D) ClI RPD I I Q I Ml

.11_____M_I_JJ IJNRI

INRIJ IJFJI I "l NR II I JNRII IPJ

I NR I

1 Aluminum 11 Antimony 1i Arsenic 11 Barium 11 Beryl liumlI Cadmium 1(Calcium 11 Chromium 11 Cobalt 11 Copper 11 Iron 11 Lead 11 Magnesium!1 Manqanese f1 Mercury 1INickel 1I Pot ass i urn 1I Selenium 11 Silver 1ISodium 1(Thallium 11 Vanad i urn 1(Zinc 1(Cyanide 11 i

1 11 1

10.0 I I1 II 1

5.0 I 11 1

10.0 1 I

1 11 11 1

5.0 1 11 i1 1

0.2 I 140. 0 II

1 11 11 I1 1i 11 11 11 11 1

I I I I I I 1I I I I I I 1

2. 2050 1 U 1 I 2. 2050 1 U i 1 1IN 1 1 I 1I I I I I I 1

1.8000IUII 1.B000IUII II I I I I I 1

5. 3000 IUI! 5. 3000 1 U 1 1 1I I I I I I 1I I I I I I 1I I I I I I 1

10. 9000IUII 10. 90001 Ull I

I I I I I I 1I I I I N 1

0.93001 1 1 0.83001 II 11.4 I4.6000IUII 4.6000IUI! 1

1 1 I i l l 1i l l I I I II I I I I I 1I I I I I I 1I I I 1 1 1 1I I I I I I I1 1 I I I I 1I I I I I I II I I I I I 1

I IJPJI I JNRII! INRII I JNRII 1JPJI I JNRII I JNRII IJCVII IJPJI ! JNRI

I I JNRII IJNR!I I JNRII I JNRII I JNRII I JNRII IJ NR II fl I

FORM VI - IN 7/87

flROOI992

Page 77: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY _____________

II NCL105S

Lab Name: ENVIR._HEALTH_RESEARCH_TE Contract: OBG _____ I

Lab Code: WB8 __ Case No. : BLOSE SflS No. : 1£495_ SDB No. s 000000

Matrix (soil/water): WATER Level (low/med): ___

Concentration Units (ug/L or mg/kg dry weight): UG/L_

Comments:

I I ! 11 1 Control 1 11 1 Limit 1 Spiked Sample 1lAnalyte I *R 1 Result (SBR) ClI I I 1I Aluminum 1 I I I(Antimony I I I I1 Arsenic 175-125 1 100.0000 I 11 Barium 1 I I I1 Beryl liuml I 1 1ICadmium 175-125 1 550.7000 I 1(Calcium I I i 1(Chromium 175-125 1 534. 9000 1 1(Cobalt I I I I1 Copper I I I Illron I I I II Lead 175-125 1 593.0000 1 1IMaqnesiuml 1 1 11 Manqanese 1 1 1 11 Mercury 175-125 1 1.7500 I 11 Nickel 175-125 1 504.2000 I 11 Potassium! 1 I 1I Selenium 1 ' 1 I I(Silver 1 1 I I1 Sodium I I 1 I(Thallium I I I I1 Vanadium 1 ! I IIZinc I I I I(Cyanide I I I I1 1 1 1 1

11

Sample 1Result (SR) Cl

11 1

1 12. 2050 1 U 1

I II 1

1.8000 IUI

1 15. 3000 1 U 1

1 11 11 1

10.9000IU!1 1I 1

0. 9300 1 14. 6000 1 U 1

1 11 11 11 11 1I I1 I1 11 I

11

Spike 1Added (SA) I

111

100.0!11

500. 0 I

1500. 0 I

111

500. 0 1ri

1.01500. 0 1

111111111

1 1 11 1 1! 1 1

*R IQI Ml1 1 11 INRI1 INRI

100.01 IF I1 INRI1 INRI

110. 11 IP I

1 INRI107.01 IP I

1 INRI1 INRI1 INRI

118.61 IP 11 INRI1 INRI

82.01 ICVI100.81 IP I

1 INRI1 INRIi INRI1 INRI1 INRI1 INRI1 INRI1 INRI1 I 1

FORM V (PART 1) - IN • 7/87

SROOI993

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U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET ___

I I1 NCRAW I

Lab Name: ENVIR._HEALTH_RESEARCH_TE Contract: OBG_____ I___________I

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDG No. : 000000

Matrix (soil/water): WATER Lab Sample ID: 30662___

Level (low/med): ___ Date Received: 01/02/91

% Solids: ___

Concentration Units (ug/L or mg/kg dry weight): U6/L_

1 1 1ICAS No. 1 Analyte 11 1 117429-90-5 1 Aluminum 11 7440-36-0 1 Ant imony 117440-38-2 1 Arsenic 117440-39-3 1 Barium 117440-41-7 IBerylliuml17440-43-9 1 Cadmium i17440-70-2 1 Calcium 117440-47-3 I Chromium 117440-48-4 1 Cobalt 117440-50-8 (Copper 117439-89-6 1 Iron 117439-92-1 ILead 117439-95-4 (Magnesium!17439-96-5 1 Manganese 117439-97-6 1 Mercury 117440-02-0 1 Nickel 117440-09-7 I Potassium I17782-49-2 1 Selenium 117440-22-4 (Silver 117440-23-5 1 Sodium 117440-28-0 1 Thai Hum 117440-62-2 1 Vanadium 117440-66-6 IZinc I1 1 Cyanide 11 I 1

I 1Concent r at i on 1 C ! Q

I 11 11 1

2.2 IUI1 11 1

1.8 iUI1 1

5.3 IUI1 11 1I i

10.9 IUI1 1I 1

0.2 1 14.6 IUI

1 11 1I 11 11 11 11 11 11 1

1 !IM 11 1INRIINRI

_IF_IINRIINRIIP IINRIIP 1INRIINRIINRIIP 1INRIINRIICVIIP 1INRIINRIINRIINRIINRIINRIINRIINRI1 1

NC-RAW

Color Before: ______ Clarity Before: ____ Texture:

Color After: ________ Clarity After: ______ Artifacts:

Comments:

FORM I - IN 7/87

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U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

I NCRAWF ILab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: OBG_____ I___________I

Lab Code: W88__ Case No. : BLOSE SAS No.: 12495_ SDG No. : 000000

Matrix (soil/water): WATER Lab Sample ID: 30663___

Level (low/med): ___ Date Received: 01/02/91

% Solids: ___

Concentration Units (ug/L or rng/kg dry weight): UG/L_

I 1 i I IICAS No. 1 Analyte IConcentrationlCI Q1 1 1 I I17429-90-5 1 Aluminum 1 1 117440-36-0 1 Antimony 1 1 117440-38-2 1 Arsenic 1 2.2 IUI17440-39-3 1 Barium 1 1 117440-41-7 1 Beryl Hum! I 117440-43-9 1 Cadmium 1 1.8 IUI17440-70-2 (Calcium 1 I I17440-47-3 1 Chromium 1 5.3 IU!17440-48-4 1 Cobalt 1 1 I17440-50-8 1 Copper 1 1 !17439-89-6 1 Iron 1 I I17439-92-1 ILead 1 10.9 IUI17439-95-4 IMaanesiuml 1 I17439-96-5 IMannanesel 1 117439-97-6 1 Mercury 1 0.2 1 117440-02-0 (Nickel 1 4.6 IUI17440-09-7 (Potassium! I 117782-49-2 (Selenium 1 I I17440-22-4 (Silver 1 I I17440-23-5 1 Sodium 1 I 117440-28-0 (Thallium 1 I I17440-62-2 1 Vanadium 1 1 117440-66-6 (Zinc 1 I I1 i Cyanide 1 1 1I i I I I

i iIM 11 1INRIINRIIF 1INRIINRIIP iINRIIP 1INRIINRIINRIIP 1INRIINRIICVIIP iINRIINR!INRIINRIINRIINRIINRIINRI! 1

Color Before: ______ Clarity Before: ____ Texture:

Color After: ______ Clarity After: ____ Artifacts:

Comments:

NC-RAW FILTERED

FORM I - IN 7/87

flROOJ995

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U.S. EPA - CLP

2AINITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: OBG.

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDG No.: 000000

Initial Calibration Source: SPEX

Continuing

1 11 1lAnalyte 11 11 Aluminum 11 AntimonyJ1 Arsenic _ 1.I Bar i urn 11 Beryl liuml1 Cad mi urn _ 1(Calcium !1 Chromium 11 Cobalt 11 Copper 11 Iron I1 Lead 11 Magnesium!1 Manganese 11 Mercury 1INickel 11 Potassium!ISeleniumJ(Silver ""l1 Sod i urn 11 Thai H urn J1 Vanad i urn IIZinc 1(Cyanide I1 1

Calibration Source: SPEX

Concentration Units: ug/L

1 1Initial Calibration 1 Continuing Calibration 1

True Found %R ( 1 ) 1 True Found *R ( 1 ) Found *R ( 1 ) 11 1

1 I I 1 I I I I1 I I 1 I I 1 1

20.0 1 20.701103.51 £0.0 1 21.601108.01 21.101105.511 • 1 1 ~ l I I I I1 I I 1 1 I I I

1000.0 1 1097.001109.71 1000.0 1 1068.001106.81 1064.001106.4!1 I I 1 I I I I

2000.0 1 2058.001102.91 2000.0 1 2004.001100.21 1979.001 99.011 I I 1 I I I I1 1 1 1 I I I I

1 I I 1 I I 1 I600.0 1 587.301 97.91 600.0 1 636.601106.11 618.201103.01

1 I I 1 I I I I1 I I 1 1 I I I

5.0 1 5.351107.0! 5.0 1 5.351107.01 5.441108.8!8000.0 1 8496.001106.21 8000.0 1 8217.001102.71 8200.001102.51

1 I I 1 I I 1 I1 I I 1 I I I I1 I I f I 1 I II I I 1 I I 1 11 I I 1 I I I 11 1 1 1 I I 1 1I 1 1 1 I I I I1 1 1 1 I I 1 11 I I 1 I I I I

1 11 11 Ml1 1INRIINRIIF 1INRIINRIIPJINRIIP 1INR~IINRIINRIIPJINR~IINRIICVIIP 1INRIINRIINRIINRIINRIINRIINRIINRI1 1

(1) Control Limits: Mercury 80-120? Other Metals 90-1105 Cyanide 85-115

FORM II (PART 1) - IN 7/87

'HROOI996

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U.S. EPA - CLP

2BCRDL STANDARD FOR AA AND ICP

Lab Name: ENVIR._HEALTH_RESEARCH_TE Contract: OBG.

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SD6 No.: 000000

AA CRDL Standard Source: _________

ICP CRDL Standard Source: SPEX IND.__

Concentration Units: ug/LI i——————————————pj ,I I CRDL Standard for AA I I CRDL Standard for ICP II I I I Initial Final IlAnalyte I True Found %R II True Found *R Found %R II I _______ I I1 Aluminum i 11 Antimony 1 11 Arsenic 1 1(Barium 1 11 Beryl Hum 1 11 Cadmium 1 IICalcium 1 11 Chromium 1 11 Cobalt i 11 Copper 1 11 Iron 1 11 Lead 1 1IMaqnesiuml 1I Manaanese 1 1(Mercury 1 11 Nickel i 11 Potassium! 1(Selenium 1 1[Silver 1 11 Sod i urn 1 11 Thai Hum 1 I1 Vanad i urn 1 1IZinc 1 11 1 1

I I I 1 I I 1I I I 1 1 I 11 I I I I I I .1 II 1 1 1 1I I I 1 I I 11 II 500.01 496.301 99.31 536.401 107.I l l 1 I I 11 II 500.01 461.001 92.21 503.301 100.I l l 1 I I 11 1 1 1 1 1 1I I I 1 I I 11 II 500.01 506.701101.31 542.301 108.I l l 1 I I 1I I I 1 1 I 11 I I 1 1 1 11 II 500.01 467.501 93.51 500.501 100.I l l 1 I I II I I 1 I I 1I I I 1 1 1 11 1 1 1 I I 1I I I 1 I I II I I 1 1 1 ii l l i I I 1I I I 1 I I 1

III11

3!1

71111

511I1

11_l

111I111

FORM II (PART 2) - IN 7/87

flROOI997

Page 82: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

3BLANKS

Lab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: OBG.

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDG No. : 000000

Preparation Blank Matrix (soil/water): WATER

Preparation Blank Concentration Units (ug/L or mg/kg): UG/L_

1 11 11 11 1lAnalyte 11 1(Aluminum 1(Antimony 11 Arsenic 1(Barium 11 Beryl Huml1 Cadmium 11 Calcium 11 Chromium 11 Cobalt 11 Copper 11 Iron 11 Lead 11 Magnesium!1 Manganese 11 Mercury 11 Nickel 11 Pot ass i urn 1(Selenium 1(Silver 11 Sod i urn 1I Thai Hum 11 Vanad i urn 1IZinc 1I Cyanide 1I 1

1Initial 1Calib. IBlank 1(ug/L) Cl

I1 11 1

2.2 IUI1 11 I

1.8 IUII 1

5.3 IUI1 11 11 1

10.9 I II 11 1

0.1 IU!4.6 IUI

i 11 i

1 1I 1

I 11 1

1 11 1

1 1

Continuing CalibrationBlank (ug/L)

1 C 2 C 3

1 I I I1 1 I I

2.2 IUI 2.2 IUII I I Ii 1 1 1

1.8 IUI 1.8 IU!I I I I

5. 3 IUI 5.3 IUII I I 11 1 I II I I I

10.9 1 1 10.9 1 11 1 I II I I I

0.1 IUI 0. 1 IU!4.6 IU 1 4.6 IUI

1 1 I II I I II I I I1 I I II I 1 II I I I1 1 I II I I II I I I

1 11 11 11 1

Cl 11 1

1 I !1 1 11 II1 I I1 1 11 I I1 I 11 1 11 1 I1 1 11 f I1 1 11 1 I1 1 11 1 1I I I1 II1 i 1

1 1 11 1 11 1 1I 1 1

f 1 1I 1 !1 1 1

1 1 11 1 1

Prepa- 1 1 1ration II 1Blank Cl 1 M 1

1 1 1! 1 1 NR 11 1 INR 1

2.200IUIIF 11 ilNR 11 I INR 1

1.800IUIIP 11 1 INR 1

5. 300 1 U 1 1 P I1 1 INR 1I 1 INR 11 1 INR 1

10.9001 IIP I1 1 INR 11 1 INR 1

0. 100IU1 ICV I4.6001UIIP 1

1 I INR 1I 1 INR 11 1 INR 11 1 INR 11 1 INR 11 1 INR 1I IlNR 11 1 INR 11 1 1 1

FORM III - IN 7/87

AROOI998

Page 83: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

4ICP INTERFERENCE CHECK SAMPLE

Lab Name: ENVIR._HEALTH_RESEARCH_TE Contract: OBG.

Lab Code: W88__ Case No. : BLOSE SAS No: 12495_ SDG No. : 000000

ICP ID Number: 2483______ ICS Source: ___________

Concentration Units: ug/L

i i i———————————•——,I True I Initial Found I Final Found Ii Sol. Sol. I Sol. Sol. I Sol. Sol. II Analyte A AB I A AB *R I A AB *R II__________________I_________________I_________________________II Aluminum 15000001 5000001 4490001 477000.01 95.41 4703001 488200.01 97.611 Antimony 1 11 Arsenic 1 11 Barium 1 11 Beryl Hum I I1 Cadmium 1 11 Ca 1 c i urn _ 1 500000 11 Chromium 1 11 Cobalt 1 11 Copper 1 1ilron 120000011 Lead 1 1(Magnesium 150000011 Manqanese 1 11 Mercury 1 11 Nickel 1 11 Pot ass i urn 1 1(Selenium i 11 Silver i 11 Sod i urn 1 1I Thai Hum 1 11 Vanadium 1 1IZinc 1 11 1 1

11

50015001

1000!

_500000 1 .

500150015001

200000 I10001

500000 15001 "

I10001

1I

100011

1500110001

1

1I1i1

_467800I111

18910011

467200 1111111111I1

1 11 1

525.01105.01480.01 96.01958.01 95.81

_494100.0I_98.8I.466.01 93.21574.01114.81438.01 87.61

173800.01 86.911140.01114.01

468100.01 93.61484.0! 96.8!

I I895.01 89.51

f 11 1

962.01 96.211 11 I

472.01 94.41955.01 95.51

1 1

1 1 1I I 1

1 538.01107.611 493.01 98.611 1000.01100.01

_495800 1 _51 1400. 0 1 102. 3 11 486.01 97.211 448.01 89.611 5654.01 Ii 178200.01 89.111 1063.01106.311 479000.01 95.811 496.01 99.211 1 f1 910.01 91.011 1 11 1 11 984.01 98.411 1 11 I 11 484.01 96.811 989.01 98.91I 1 1

FORM IV - IN 7/87

AROOI999

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U.S. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY

Lab Name: ENVIR. HEALTH RESEARCH TE Contract: OBG

1 11 NCL105S 11 1

Lab Code: W88 __ Case No.: BLOSE SAS No.: 12495_ SDG No.:

Matrix (soil/water): WATER Level (low/med):

Concentration Units (ug/L or mg/kg dry weight): UG/L_

I I I 11 (Control! 11 1 Limit 1 Spiked Sample 1lAnalyte 1 *R 1 Result (SSR) ClI I I !1 Aluminum I I I II Antimony I I I I1 Arsenic 175-125 1 100.0000 1 I1 Barium I I 1 11 Beryl liuml 1 I IICadmium 175-125 1 550.7000 1 1(Calcium I I 1 I1 Chromium 175-125 1 534.9000 1 11 Cobalt I I 1 I1 Copper I I I Illron I I I IILead 175-125 1 593.0000 1 1IMaqnesiumf 1 1 11 Manganese! 1 1 11 Mercury 175-125 1 1.7500 1 11 Nickel 175-125 I 504.2000 I 1(Potassium! 1 1 1(Selenium I I I I1 Silver I I I I1 Sodium I I I IIThallium I I I I(Vanadium I I I IIZinc 1 1 I I(Cyanide I I I II 1 1 I I

1 11 1

Sample 1 Spike 1Result (SR) C! Added (SA) 1 #R

1 11 11 1

2. 2050 1 U 11 1I 1

1.8000 IUI

1 15. 30001 UI

1 11 1! 1

10. 90001 UI

1 1_. ———— L 1

^ 0. 9300 1 j\4. 60001 UI

1 11 11 11 11 11 11 11 11 1

11

100.01 100.11

500.01 110.1

500.01 107.111

500.01 118.11

1.0! 82.500.01 100.

111111111

000000

1 1 11 1 11 1 1IQI Ml1 1 11 INR!1 INRI0IJFJ

1 INRIi INRI

11 IP 11 INRI

01 IP I1 INR!1 INRI1 INRI

61 IP 11 INRI1 INRI

01 ICVI81 IP 1

1 INRI1 INRI1 INRI! INRI1 INRI1 INRI1 INRI1 INRII 1 1

Comments:

FORM V (PART 1) - IN „ ,_ rt „ 7/87ARQ02000

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U.S. EPA - CLP

6 EPA SAMPLE NO.DUPLICATES

I 1I NCL105D I

Lab Name: ENVIR._HEALTH_RESEARCH_TE Contract: OBG_____ I__________I

Lab Code: W88__ Case No.: BLOSE SAS No.: 12495_ SDG No.: 000000

Matrix (soil/water): WATER Level (low/med): ___

% Solids for Sample: _____ % Solids for Duplicate: ___

Concentration Units (ug/L or mg/kg dry weight): UG/L_

1 1 II1 1 Control 1 1lAnalyte 1 Limit II1 1 II1 Aluminum 1 1 1lAntimony 1 1 11 Arsenic 1 10. 0 1 11 Barium 1 111 Beryl liuml 1 11 Cadmium 1 5.0 1 11 Calcium 1 1 11 Chromium 1 10. 0 1 11 Cobalt 1 II1 Copper 1 1 11 Iron 1 1 11 Lead 1 5. 0 1 1IMaqnesiuml 1 11 Manganese! 1 11 Mercury 1 0. 2 1 11 Nickel 1 40.0 1 I1 Potassium! 1 1(Selenium 1 1 11 Silver 1 II1 Sodium 1 1 1I Thai Hum 1 1 1(Vanadium 1 1 1IZinc 1 II(Cyanide 1 1 11 1 I I

I I I IM I I

Sample (S) CM Duplicate (D) CMM I I

I I I I I II I I 1 I I

2.2050IUII 2.£050IUIII I ! 1 I I1 1 1 I I I

1.8000 IUI I 1.80001 UNI I I I I I

5.3000IUII 5.30001UIII I I I I II I I I I I1 II ' 1 U

10. 9000 IUI 1 10.9000IUIII I I I I I

^- —————— t-Nj. | __ ____ kj |

08. 9300 1 4 1 C0. 8300 1 J \475000TU 1 1 4. 6000 ! U 1 I

I I I I I I1 1 1 I I I1 1 I I I I1 1 1 I I I1 1 1 I I II I I 1 1 1I N I I II I I I I II I I I I I

1 1 ! 1II 1 1

RPD I I Q I Ml1 1 1 1I I INRII I INR!1 1 IF 1I I INRI1 1 INRIII IP 1I I INRI1 i IP iI I INRII I INRII I INRI1 1 IP I1 1 INRI1 1 INR!

11.4 II ICV!H I P !I I INRII I INR!II INRIII INRII I INRII I INRII I INRII I INRI1 1 1 1

flR00200l

Page 86: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

f&HRTEnvironmental Health Research and Testing, Inc.

3235 Omni Drive Cincinnati, Ohio 45245 (513) 752-2950 FAX (513) 752-2261

January 1,1991

RECEIVEDO'BRIEN & GERE ENGINEERS, INC.ATTN: Mr. Tee Tong-ngork „5000 Brittonfield Parkway, Suite 300 Jf\N - 'P.O. Box 4942Syracuse, New York 13221 „„,.,-.-

««-«.-•—_ '">r~ ~'"""Dear Mr. Tong-ngork: "~"~

Please find enclosed the results of analysis for the twenty-five (25) samples received on December14, 1990.

If you have any further questions, please feel free to contact me at (513) 752-2950.

Sincerely,

Mona Risk, Ph.D. . Q*»cV-Director of Chemistry

MR:ds

Enclosures

NATIONAL OFFICES

Cincinnati Ohio • Lexington, Kentucky • Research Trianglfl ffykfflfittlrtMHmafj 11000900?3 • Birmingham, Alabama • Philadelphia, Pennsylvania • ii/TrLlcWatcUfWnt • Miami, FlorA ft U U d U U £.

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Siiii ii !n snnnnnDDDn

3R002003

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CHAIN OF CUSTODY RECORD

LABORATORIES, INC.

SURVEY:

LOCATION:

SAMPLED BY:

ORGANIZATION:

STATIONNUMBER SAMPLE LOCATION OATE

COLLECTEDTIME

COLLECTEDSAMPLEMATRIX

COMP.OR GRAB

NO. OFCONTAINERS

ANALYSISREQUIRED

Q) - O iv.-?© TS) 60- fai /W ,,Ti)c>

Vtr**^1-, frrxt,

TSc

- o,'""N Tb<L

METHOD OF SHIPMENT:

OBG Laboratories, Inc., an O'Brien & Gere Limited Company5000 Brittonfield Parkway / Suite 300 / PO Box 4942 / Syracuse, NY 13221 /(315) 437-0200

AROQ2001*

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CHAIN OF CUSTODY RECORD

LABORATORIES, INC.V*>* OOi . ISl

SURVEY:

LOCATION:

SAMPLED BY:

ORGANIZATION:

STATIONNUMBER SAMPLE LOCATION DATE

COLLECTEDTIME

COLLECTEDSAMPLEMATRIX

COMP.OR GRAB

NO. OFCONTAINERS

ANALYSISREQUIRED

U/v-iK.FiYi iT4>ft— IS't*

OH) "Z.1/25"

£ f A bO ft

~- O-IAI "N(ly |(S< ,K, LW-.kfvvv SQ ~ 0«( Uoft

BU-, bog

(S) tbft — t.Ol1*. v/

Relinquished By: DATE TIME Received By: DATE TIME

Relinquished By: DATE TIME Received By: DATE TIME

Relinquished 8 DATEal

TIMEIbVBfi

Received by Laboratory:— •« — •— »\S>r n *t j — ra V- o

DATE TIME

<

METHOD OF SHIPMENT:

OBG Laboratories, Inc., an O'Brien & Gere Limited Company5000 Brittonfield Parkway / Suite 300 / PO Box 4942 / Syracuse, NY 13221 / (315) 437-0200 ft R fl t'l ? D 0 5

Page 90: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS,INC.

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A PROJECT NO.: 12444

ANALYSIS PERFORMED: TOC Analysis

ANALYSIS METHOD: EPA Method 9060

ANALYST: J. Bums

DATE ANALYZED: 1 2-1 7-90

LAB NOTEBOOK NO. : 1 35, Pg. 25

SAMPLE NO.EHRT NO. CUSTOMER NO.

30246 ISO-0

30247 ISO-0.1

30248 ISO-0.5

30249 ISO-1

30250 ISO-5

30251 ISO-15

30252 INFLUENT

30253A ISO-OD

30253B ISO-ODDuplicate

30254 ISO-0.1 AD

30255 ISO-0.5AD

30256 ISO-LOAD

30257 ISO-5D

30258 ISO-1 5D

RESULTS(mg/L)

BDL

BDL

BDL

BDL

BDL

BDL

BDL

15.64

14.68

BDL

21.98

25.06

71.52

26.11

Detection Limit: < 10 mg/L

Pase' flR002006

Page 91: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS, INC.

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A__________ PROJECT NO.: 12444

DATE EXTRACTED: N/A_________ DATE ANALYZED: 12-14-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: ISO-0.1 EHRT SAMPLE NO.: 30247A

LAB NOTEBOOK NO.: 162, Pg. 42______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodlchloromethane < 0.502. Bromoform < 0.50

13. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene < 0.506. Chloroethane < 0.501*. 2-Chioroethylvinyl Ether < 0.508. Chloroform 6.479. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 2.4916. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 1.9019. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Page1 flR002007

Page 92: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: ISO-0.1_________ EHRT SAMPLE NO.: 30247A

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1-Trichloroethane < 0.5026. 1,1,2-Trichloroethane < 0.5027. Trichloroethene < 0.5028. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene < 0.5031. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-DIchloroethane-d4 - _____96.00%

Toluene-d8 - 98.00%

Bromofluorobenzene - 96.00%

Page2 AROQ2Q08

Page 93: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS, INC.

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A__________ PROJECT NO.: 12444

DATE EXTRACTED: N/A___________ DATE ANALYZED: 12-15-90

SAMPLE TYPE: Water Duplicate SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: ISO-0.1 EHRT SAMPLE NO.: 30247B

LAB NOTEBOOK NO.: 162. Pg. 42_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene < 0.506. Chloroethane < 0.507. 2-Chloroethylvinyl Ether < 0.508. Chloroform 7.279. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dlchlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 3.0416. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 2.4319. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Pagel flRQQ2009

Page 94: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: ISO-0.1_________ EHRT SAMPLE NO.: 30247B

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1-Trichloroethane < 0.5026. 1,1,2-Trichloroethane < 0.5027. Trichloroethene < 0.5028. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene < 0.5031. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____85.00%

Toluene-d8 - 111.00%

Bromofluorobenzene - 102.00%

Pas92 flROOZOIQ

Page 95: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS, INC.

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A__________ PROJECT NO.: 12444

DATE EXTRACTED: N/A__________ DATE ANALYZED: 12-14-90

SAMPLE TYPE: Water Sample_____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: ISO-0.5 EHRT SAMPLE NO.: 30248

LAB NOTEBOOK NO.: 162. Pg. 42_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene . < 0.506. Chloroethane < 0.507. 2-ChloroethyMnyl Ether < 0.508. Chloroform < 0.509. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane < 0.5016. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene < 0.5019. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Page1 , AR0020M

Page 96: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: ISO-0.5_________ EHRT SAMPLE NO.: 30248

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1-Trichloroethane < 0.5026. 1,1,2-Trichloroethane < 0.5027. Trichloroethene < 0.5028. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene < 0.5031. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____94.00%

Toluene-d8 - 96.00%

Bromofluorobenzene - 101.00%

Page 2 /5R0020I2

Page 97: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS. INC.

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A__________ PROJECT NO.: 12444

DATE EXTRACTED: N/A__________ DATE ANALYZED: 12-14-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: ISO-1 EHRT SAMPLE NO.: 30249

LAB NOTEBOOK NO.: 162. Pg. 42______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene < 0.506. Chloroethane < 0.507. 2-Chloroethylvinyl Ether < 0.508. Chloroform < 0.509. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane < 0.5016. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene < 0.5019. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Pagel 3R0020I3

Page 98: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: ISO-1__________ EHRT SAMPLE NO.: 30249

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1-Trichloroethane < 0.5026. 1,1,2-Trichloroethane < 0.5027. Trichloroethene < 0.5028. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene < 0.5031. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____95.00%

Toluene-d8 - 101.00%

Bromofluorobenzene - 97.00%

Page2 AR0020II*

Page 99: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

tlMViHUNMENTAL HEALFH KfcStAHCH AMU i fcb TING, INC.SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS. INC.

MPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A_________________ EHRT PROJECT NO.: 12444

DATE EXTRACTED: 12-14-90 ____ DATE ANALYZED: 12-17-90

SAMPLE TYPE: Water Sample___________ SAMPLE VOLUME: 930.00

ANALYST: K. Nusekabel__________ FINAL VOLUME: ___1.00

CUSTOMER SAMPLE NO.: ISO-0 ____ _______ EHRT SAMPLE NO.: 30259

LAB NOTEBOOK NO.: 166. Pg. 16____________ METHOD NO.: EPA 625

RESULTCOMPOUNDS__________ ug/L

1. Phenol < 5.382. Bis(2-Chloroethyl)Ether < 2.153. 2-Chlorophenol < 2.154. 1,3-Dichlorobenzene < 6.455. 1,4-Dichlorobenzene < 6.456. Benzyl Alcohol < 3.237. 1,2-Dichlorobenzene < 6.458. 2-Methylphenol < 3.239. Bis-(2-Chloroisopropyl)Ether < 4.3010. 4-Methylphenol < 3.2311. N-Nitrosp-Di-n-Propylamine < 4.3012. Hexachloroethane < 6.4513. Nitrobenzene < 3.2314. Isophorone < 2.1515. 2-Nitrophenol < 4.3016. 2,4-Dimethylphenol < 3.2317. Benzole Acid < 21.5118. Bis(2-Chloroethoxy)Methane < 2.1519. 2,4-Dichlorophenol < 4.3020. 1,2,4-Trichlorobenzene < 6.4521. Naphthalene < 1.0822. 4-Chloroaniline < 10.7523. Hexachlorobutadiene < 12.9024. 4-Chloro-3-Methylphenol < 3.2325. 2-Methylnaphthalene < 1.0826. Hexachlorocyclopentadiene < 12.9027. 2,4,5-Trichlorophenol ~" < 5.3828. 2,4,6-Trichlorophenol < 5.38

Pagei 3ROQ2G{5

Page 100: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: ISO-0________________ EHRT SAMHLE NO.: 30259

29.30.31.32.33.34.35.36.37.38.39.40.41.42.43.44.45.46.47.48.49.50.51.52.53.54.55.56.57.58.59.60.61.62.63.64.65.

2-Chloronaphthalene2-N'rtroanilineDimethylphthalateAcenaphthylene2,6-Dinitrotoluene3-N'rtroaniiineAcenaphthene2,4-Dinitrophenol4-NitrophenolDibenzofuran2,4-DinitrotolueneDiethylphthalate4-Chlorophenyl-PhenyletherRuorene4-Nitroanillne4,6-Dinitro-2-MethyiphenolN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophendPhenanthreneAnthraceneDi-n-ButylphthalateRuoranthenePyreneButyl benzylphthalate3,3'-D!chlorobenzidlneBenzo(a)AnthraceneChryseneBis(2-Ethylhexyl)PhthalateDi-n-OctylphthalateBenzo(b)RuorantheneBenzo(k)RuorantheneBenzo(a) Pyrenelndeno(1 ,2,3-cd) PyreneDibenzo(a, h) AnthraceneBenzo(g,h,i)Perylene

SURROGATE COMPOUND

Nitrobenzene-d52-RuorobiphenylTerphenyl-d14

Phenol-d52-Ruorophenol2,4,6-Tribromophenol

.

< 3.23< 10.75< 3.23< 2.15 .< 6.45 |< 10.75< 2.15< 43.01< 21.51< 6.45< 6.45< 2.15< 6.45< 3.23< 21.51< 21.51< 3.23< 6.45< 5.38< 21.51< 2.15< 2.15< 1.08< 2.15< 2.15< 3.23 4< 10.75 f< 3.23< 3.23< 2.15< 2.15< 10.75< 10.75< 6.45< 10.75< 10.75< 10.75

PERCENT RECOVERY

85.10%78.60%53.30%

25.50%35.30%55.70%

Page2 AR0020I6

Page 101: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.PESTICIDES - PCB ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS, INC.

SAMPLE SOURCE: Blosenski Landfill

WORK ORKER NO.: N/A_____________ EHRT PROJECT NO.: 12444

DATE EXTRACTED: 12-14-90 DATE ANALYZED: 12-14-90

SAMPLE TYPE: Water Sample_______ METHOD NO.: EPA 608

ANALYST: M. Cooper_________ LAB NOTEBOOK NO.: 158, Pg. 78

CUSTOMER SAMPLE NO.: ISO-0 EHRT SAMPLE NO.: 30259

RESULTCOMPOUNDS ug/L

1. AIpha-BHC < 0.00142. Beta-BHC < 0.00083. Delta-BHC < 0.00064. Gamma-BHC < 0.00065. Heptachlor < 0.00206. Aldrin < 0.00167. Heptachlor Epoxide < 0.00148. Endosulfan I < 0.00089. Dieldrin ' < 0.000410. 4,4'-DDE < 0.000411. Endrin < 0.000612. Endosulfan II < 0.0213. 4,4'-DDD < 0.0214. Endosulfan Sulfate < 0.000415. 4,4'-DDT < 0.001216. Methoxychlor < 0.000417. Endrin Ketone < 0.000318. Chlordane < 0.2019. Toxaphene < 3.00

Page1 SR0020I7

Page 102: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: ISO-0____________ EHRT SAMPLE NO.: 30259

20. Aroclor-1016 < 0.5021. Aroclor-1221 < 0.5022. Aroclor-1232 < 0.5023. Aroclor-1242 < 0.5024. Aroclor-1248 < 0.5025. Aroclor-1254 < 0.5026. Aroclor-1260 < 0.50

SURROGATE RECOVERY

Dibutylchlorendate - 55.6%

Page2

Page 103: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH Rfci>tAHCH AND TESTING, INC.SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS, INC.

AMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A__________________ EHRT PROJECT NO.: 12444

DATE EXTRACTED: 12-14-90______________ DATE ANALYZED: 12-17-90

SAMPLE TYPE: Water Sample___________ SAMPLE VOLUME: 900.00

ANALYST: K. Nusekabel __________________ FINAL VOLUME: 1.00

CUSTOMER SAMPLE NO.: ISO-0.1A ________ EHRT SAMPLE NO.: 30260

LAB NOTEBOOK NO.: 166. Pg. 16____________ METHOD NO.: EPA 625

RESULTCOMPOUNDS__________ ug/L

1. Phenol < 5.562. Bis(2-Chloroethyl)Ether < 2.223. 2-Chlorophenol < 2.224. 1,3-Dichlorobenzene < 6.675. 1,4-Dichlorobenzene < 6.676. Benzyl Alcohol < 3.337. 1,2-Dlchlorobenzene < 6.678. 2-Methylphenol < 3.339. Bis-(2-Chloroisopropyl) Ether < 4.4410. 4-Methylphenol < 3.3311. N-Nitroso-Di-n-Propylamine < 4.4412. Hexachloroethane < 6.6713. Nitrobenzene < 3.3314. Isophorone < 2.2215. 2-Nrtrophend < 4.4416. 2,4-Dimethylphenol < 3.3317. Benzole Acid < 22.2218. Bis(2-Chloroethoxy)Methane < 2.2219. 2,4-Dichlorophenol < 4.4420. 1,2,4-Trichlorobenzene < 6.6721. Naphthalene < 1.1122. 4-Chloroaniline < 11.1123. Hexachlorobutadiene < 13.3324. 4-Chloro-3-Methylphenol < 3.3325. 2-Methylnaphthalene < 1.1126. Hexachlorocyclopentadiene < 13.3327. 2,4,5-Trichlorophenol < 5.5628. 2,4,6-Trichlorophend < 5.56

/JR0020I9

Page 104: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER bAMr^LC Nu.. IOUHJ.IA_______________ cnm OMMru_ i\u.. ou<>bU

29.30.31.32.33.34.35.36.37.38.39.40.41.42.43.44.45.46.47.48.49.50.51.52.53.54.55.56.57.58.59.60.61.62.63.64.65.

2-Chloronaphthalene2-NitroanilineDimethyiphthalateAcenaphthylene2,6-Dinitrotduene3-NitroanilIneAcenaphthene2,4-Dinitrophend4-NitrophendDibenzofuran2,4-DinitrotdueneDiethylphthalate4-Chlorophenyl-PhenyletherRuorene4-Nitroaniline4,6-Dinrtrc~2-MethylphendN-Nitrosodiphenyiamine4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophendPhenanthreneAnthraceneDi-n-ButyiphthalateRuoranthenePyreneButyl benzyiphthalate3,3'-DichlorobenzidineBenzo(a)AnthraceneChryseneBis(2-Ethylhexyl)PhthalateDi-n-OctylphthalateBenzo(b)RuorantheneBenzo(k)RuorantheneBenzo(a)Pyrenelndeno(1 ,2,3-cd) PyreneDibenzo(a,h)AnthraceneBenzo(g, h,i) Perylene

SURROGATE COMPOUND

Nftrobenzene-d52-RuorobiphenylTerphenyl-d14

Phenol-d52-Ruorophend2,4,6-Tribromophenol

< 3.33< 11.11< 3.33< 2.22< 6.67 i< 11.11< 2.22< 44.44< 22.22< 6.67< 6.67< 2.22< 6.67< 3.33< 22.22< 22.22< 3.33< 6.67< 5.56< 22.22< 2.22< 2.22< 1.11< 2.22< 2.22< 3.33 .< 11.11 |< 3.33< 3.33< 2.22< 2.22< 11.11< 11.11< 6.67< 11.11< 11.11< 11.11

PERCENT RECOVERY

72.40%73.90%37.00%

21.90%31.10%64.80%

_l

Page2 3R002020

Page 105: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.PESTICIDES - PCB ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS, INC.

SAMPLE SOURCE: Blosenski Landfill

WORK ORKER NO.: N/A_____________ EHRT PROJECT NO.: 12444

DATE EXTRACTED: 12-14-90 DATE ANALYZED: 12-14-90

SAMPLE TYPE: Water Sample________ METHOD NO.: EPA 608

ANALYST: M. Cooper__________ LAB NOTEBOOK NO.: 158, Pg. 78

CUSTOMER SAMPLE NO.: ISO-0.1/f &________ EHRT SAMPLE NO.: 30261

RESULTCOMPOUNDS ug/L

1. Alpha-BHC < 0.00142. Beta-BHC < 0.00083. Delta-BHC < 0.00064. Gamma-BHC < 0.00065. Heptachlor < 0.00206. Aldrin < 0.00167. Heptachlor Epoxkte < 0.00148. Endosulfan I < 0.00089. Dieldrin < 0.000410. 4,4'-DDE < 0.000411. Endrin < 0.000612. Endosulfan II < 0.0213. 4,4'-DDD < 0.0214. Endosulfan Sulfate < 0.000415. 4,4'-DDT < 0.001216. Methoxychlor < 0.000417. Endrin Ketone < 0.000318. Chlordane < 0.2019. Toxaphene < 3.00

Pagel flR00202l

Page 106: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: ISO-0.1 A___________ EHRT SAMPLE NO.: 30261

20. Arodor-1016 < 0.5021. Aroclor-1221 < 0.5022. Aroclor-1232 < 0.5023. Aroclor-1242 < 0.5024. Aroclor-1248 < 0.5025. Aroclor-1254 < 0.5026. Arodor-1260 < 0.50

SURROGATE RECOVERY

Dibutylchlorendate -111.4%

Page2 AR002022

Page 107: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

n ni_.j«-..rMion MI*U ^SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS, INC.

MPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A______________ EHRT PROJECT NO.: 12444

DATE EXTRACTED: 12-14-90______________ DATE ANALYZED: 12-17-90

SAMPLE TYPE: Water Sample__________ SAMPLE VOLUME: 900.00

ANALYST: K. Nusekabel___________ FINAL VOLUME: • ___1J)0

CUSTOMER SAMPLE NO.: ISO-0.5A __________ EHRT SAMPLE NO.: 30262

LAB NOTEBOOK NO.: 166. Pg. 16____________ METHOD NO.: EPA 625

RESULTCOMPOUNDS__________ ug/L

1. Phend < 5.562. Bis(2-Chloroethyl)Ether < 2.223. 2-Chlorophend < 2.224. 1,3-Dichlorobenzene < 6.675. 1,4-Dichlorobenzene < 6.676. Benzyl Alcohd < 3.337. 1,2-Dichlorobenzene < 6.678. 2-Methylphend < 3.339. Bis-(2-Chloroisopropyi) Ether < 4.4410. 4-Methylphend < 3.3311. N-Nitroso-Di-n-Propylamine < 4.4412. Hexachloroethane < 6.6713. Nitrobenzene < 3.3314. Isophorone < 2.2215. 2-Nttrophend < 4.4416. 2,4-Dimethylphend < 3.3317. Benzole Acid < 22.2218. Bis(2-Chloroethoxy)Methane < 2.2219. 2,4-Dichlorophenol < 4.4420. 1,2,4-Trichlorobenzene < 6.6721, Naphthalene < 1.1122. 4-Chloroaniline < 11.1123. Hexachlorobutadiene < 13.3324. 4-Chloro-3-Methylphenol < 3.3325. 2-Methylnaphthalene < 1.1126. Hexachlorocyclopentadiene < 13.3327. 2,4,5-Trichlorophend < 5.5628. 2,4,6-Trichlorophend < 5.56

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CUSTOMER bAMri-n iNu.. IOU-U.OA_______________ cnm oMMru_

29. 2-Chloronaphthalene < 3.3330. 2-Nitroaniline < 11.1131. Dimethyiphtnalate < 3.3332. Acenaphthylene < 2.2233. 2,6-Dinitrotduene < 6.6734. 3-Nitroanitine < 11.1135. Acenaphthene < 2.2236. 2,4-Dinitrophend < 44.4437. 4-Nitrophend < 22.2238. Dibenzofuran < 6.6739. 2,4-Dinitrotduene < 6.6740. Diethylphthalate < 2.2241. 4-Chlorophenyl-Phenylether < 6.6742. Ruorene < 3.3343. 4-Nttroaniline < 22.2244. 4,6-Dinitro-2-Methylphend < 22.2245. N-Nitrosodiphenylamine < 3.3346. 4-Bromophenyl-Phenyiether < 6.6747. Hexachlorobenzene < 5.5648. Pentachlorophend < 22.2249. Phenanthrene < 2.2250. Anthracene < 2.2251. Di-n-Butylphthalate < 1.1152. Ruoranthene < 2.2253. Pyrene • < 2.2254. Butyibenzylphthalate < 3.3355. 3,3'-Dichlorobenzidine < 11.1156. Benzo(a)Anthracene < 3.3357. Chrysene < 3.3358. Bis(2-Ethylhexyl)Phthalate < 2.2259. Di-n-Octylphthalate < 2.2260. Benzo(b)Ruoranthene < 11.1161. Benzo(k)Ruoranthene < 11.1162. Benzo(a)Pyrene < 6.6763. lndeno(1,2,3-cd)Pyrene < 11.1164. Dibenzo(a,h)Anthracene < 11.1165. Benzo(g,h,i)Perylene < 11.11

SURROGATE COMPOUND PERCENT RECOVERY

NHrobenzene-d5 84.90%2-Ruorobiphenyl 77.80%Terphenyl-d14 83.50%

Phend-d5 23.00%2-Ruorophend 37.40%2,4,6-Tribromophend 66.00%

Page 2

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.PESTICIDES - PCB ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS. INC.

SAMPLE SOURCE: Blosenski Landfill

WORK ORKER NO.: N/A_____________ EHRT PROJECT NO.: 12444

DATE EXTRACTED: 12-14-90________________ DATE ANALYZED: 12-14-90

SAMPLE TYPE: Water Sample_______ METHOD NO.: EPA 608

ANALYST: M. Cooper_________ LAB NOTEBOOK NO.: 158, Pg. 78

CUSTOMER SAMPLE NO.: ISO-0.5B __ EHRT SAMPLE NO.: 30263

RESULTCOMPOUNDS ug/L

1. Alpha-BHC . < 0.00142. Beta-BHC < 0.00083. Delta-BHC < 0.00064. Gamma-BHC < 0.00065. Heptachlor < 0.00206. Aldrin < 0.00167. Heptachlor Epoxide < 0.00148. Endosulfan I < 0.00089. Dieldrin < 0.000410. 4,4'-DDE < 0.000411. Endrin < 0.000612. Endosulfan II < 0.0213. 4,4'-DDD < 0.0214. Endosulfan Sulfate < 0.000415. 4,4'-DDT < 0.001216. Methoxychlor < 0.000417. Endrin Ketone < 0.000318. Chlordane < 0.2019. Toxaphene < 3.00

Page1 ARQG2025

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CUSTOMER SAMPLE NO.: ISO-0.5B__________ EHRT SAMPLE NO.: 30263

20. Arodor-1016 < 0.5021. Arodor-1221 < 0.5022. Arodor-1232 < 0.5023. Aroclor-1242 < 0.5024. Aroclor-1248 < 0.5025. Arodor-1254 < 0.5026. Aroclor-1260 < 0.50

SURROGATE RECOVERY

Dibutylchlorendate - 69.7%

page2 . flR002026

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i AL. no\L.m tteoeMrtun MINIU » co i UMU,SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS, INC.

MPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A_____________ EHRT PROJECT NO.: 12444

DATE EXTRACTED: 12-14-90_______________ DATE ANALYZED: 12-18-90

SAMPLE TYPE: Water Sample___________ SAMPLE VOLUME: 900.00

ANALYST: K. Nusekabel FINAL VOLUME: 1.00

CUSTOMER SAMPLE NO.: ISO-1 .OA EHRT SAMPLE NO.: 30264

LAB NOTEBOOK NO.: 166, Pg. 16______________ METHOD NO.: EPA 625

RESULTCOMPOUNDS___________ ug/L

1. Phend < 5.562. Bis(2-Chloroethyi)Ether < 2.223. 2-Chlorophend < 2.224. 1,3-Dichlorobenzene < 6.675. 1,4-Dichlorobenzene < 6.676. Benzyl Alcohd < 3.337. 1,2-Dichlorobenzene < 6.678. 2-Methylphend < 3.339. Bis-(2-Chloroisopropyl) Ether < 4.4410. 4-Methyiphend < 3.3311. N-Nitroso-Di-n-Propylamine < 4.4412. Hexachlorciethane < 6.6713. Nitrobenzene < 3.3314. Isophorone < 2.2215. 2-N'rtrophend < 4.4416. 2,4-Dimethylphend < 3.3317. Benzole Acid < 22.2218. Bis(2-Chloroethoxy) Methane < 2.2219. 2,4-Dichlorophend < 4.4420. 1,2,4-Trichlorobenzene < 6.6721. Naphthalene < 1.1122. 4-Chloroaniline < 11.1123. Hexachlorobutadiene < 13.3324. 4-Chloro-3-Methylphend < 3.3325. 2-Methyinaphthalene < 1.1126. Hexachlorocyclopentadiene < 13.3327. 2,4,5-Trichlorophend < 5.5628. 2,4,6-Trichlorophend < 5.56

Pagel fi R 0 Q 2 0 2 7

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CUSTOMER SAMPLE NO,: ISQ-1.0A______________ EHRT SAMPLE NO.: 30264

29. 2-Chloronaphthalene < 3.3330. 2-Nitroaniline < 11.1131. Dimethylphthalate < 3.3332. Acenaphthylene < 2.2233. 2,6-DInitrotduene < 6.6734. 3-Nitroaniline < 11.1135. Acenaphthene < 2.2236. 2,4-Dinttrophend < 44.4437. 4-Nitrophend < 22.2238. Dibenzofuran < 6.6739. 2,4-Dinitrotduene < 6.6740. Diethylphthalate ' < 2.2241. 4-Chlorophenyl-Phenylether < 6.6742. Ruorene < 3.3343. 4-Nitroaniline < 22.2244. 4,6-Dinitro-2-Methylphend < 22.2245. N-Nitrosodiphenylamine < 3.3346. 4-Bromophenyl-Phenylether < 6.6747. Hexachlorobenzene < 5.5648. Pentachlorophend < 22.2249. Phenanthrene < 2.2250. Anthracene < 2.2251. Di-n-Butylphthalate < 1.1152. Ruoranthene < 2.2253. Pyrene < 2.2254. Butylbenzyiphthalate < 3.3355. 3,3'-Dichlorobenzidine < 11.1156. Benzo(a)Anthracene < 3.3357. Chrysene < 3.3358. Bis(2-Ethylhexyl)Phthalate < 2.2259. Di-n-Octylphthalate < 2.2260. Benzo(b)Ruoranthene < 11.1161. Benzo(k) Ruoranthene < 11.1162. Benzo(a) Pyrene < 6.6763. lndeno(1,2,3-cd)Pyrene < 11.1164. Dibenzo(a,h)Anthracene < 11.1165. Benzo(g,h,i)Perylene < 11.11

SURROGATE COMPOUND PERCENT RECOVERY

Nftrobenzene-d5 64.70%2-Ruorobiphenyl 60.00%Terphenyi-d14 50.00%

Phenol-d5 29.80%2-Ruorophend 38.60%2,4,6-Tribromophend 76.30%

Page2

Page 113: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.PESTICIDES - PCS ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS, INC.

SAMPLE SOURCE: Blosenski Landfill

WORK ORKER NO.: N/A_____________ EHRT PROJECT NO.: 12444

DATE EXTRACTED: 12-14-90__________ DATE ANALYZED: 12-14-90

SAMPLE TYPE: Water Sample________ METHOD NO.: EPA 608

ANALYST: M. Cooper__________ LAB NOTEBOOK NO.: 158, Pg. 78

CUSTOMER SAMPLE NO.: ISO-1 .OB ___ EHRT SAMPLE NO.: 30265

RESULTCOMPOUNDS ug/L

1. Alpha-BHC < 0.00142. Beta-BHC < 0.00083. Delta-BHC < 0.00064. Gamma-BHC < 0.00065. Heptachlor < 0.00206. Aldrin < 0.00167. Heptachlor Epoxide < 0.00148. Endosulfan I < 0.00089. Dieldrin < 0.000410. 4,4'-DDE < 0.000411. Endrin < 0.000612. Endosulfan II < 0.0213. 4,4'-DDD < 0.0214. Endosulfan Sulfate < 0.000415. 4,4'-DDT < 0.001216. Methoxychlor < 0.000417. Endrin Ketone < 0.000318. Chlordane < 0.2019. Toxaphene < 3.00

Pagel flR002029

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CUSTOMER SAMPLE NO.: ISO-1 .OB__________ EHRT SAMPLE NO.: 30265

20. Aroclor-1016 < 0.5021. Arodor-1221 < 0.5022. Aroclor-1232 < 0.5023. Arodor-1242 < 0.5024. Aroclor-1248 < 0.5025. Arodor-1254 < 0.5026. Arodor-1260 < 0.50

SURROGATE RECOVERY

Dibutylchlorendate - 84.7%

AR00203Q

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I CO

SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: O'BRIEN & GERE ENGINEERS. INC.

AMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A________________ EHRT PROJECT NO.: 12444

DATE EXTRACTED: 12-14-90______________ DATE ANALYZED: 12-17-90

SAMPLE TYPE: Water Sample__________ SAMPLE VOLUME: 690.00

ANALYST: K. Nusekabel FINAL VOLUME: 1.00

CUSTOMER SAMPLE NO.: Field Blk. #1 ______ EHRT SAMPLE NO.: 30266

LAB NOTEBOOK NO.: 166. Pg. 16____________ METHOD NO.: EPA 625

RESULTCOMPOUNDS___________ ug/L

1. Phend < 7.252. Bis(2-Chloroethyl)Ether < 2.903. 2-Chlorophend < 2 904. 1,3-Dichlorobenzene < 8.705. 1,4-Dichlorobenzene < 8.706. Benzyl Alcohd < 4.357. 1,2-Dichlorobenzene < 8.70"8. 2-Methylphend < 4.359. Bis-(2-Chloroisopropyl)Ether < 5.8010. 4-Methylphend < 4.3511. N-Nitroso-Di-n-Propylamine < 5.8012. Hexachloroethane < 8.7013. Nitrobenzene < 4.3514. Isophorone < 2.9015. 2-Nitrophend < 5.8016. 2,4-Dimethylphend < 4.3517. Benzole Acid < 28.9918. Bis(2-Chloroethoxy)Methane < 2.9019. 2,4-Dichlorophend < 5.8020. 1,2,4-Trichlorobenzene < 8.7021. Naphthalene < 1.4522. 4-Chloroaniline < 14.4923. Hexachlorobutadiene < 17.3924. 4-Chloro-3-Methylphend < 4.3525. 2-Methylnaphthalene < 1.4526. Hexachlorocyclopentadiene < 17.3927. 2,4,5-Trichlorophend < 7.2528. 2,4,6-Trichlorophend < 7.25

Page1 flR00203l

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CUSTOMER SAMPLE NO.: Field Blk. #1____________ EHRT SAMPLE NO.: 30266

29.30.31.32.33.34.35.36.37.38.39.40.41.42.43.44.45.46.47.48.49.50.51.52.53.54.55.56.57.58.59.60.61.62.63.64.65.

2-Chloronaphthalene2-NitroanilineDimethylphthalateAcenaphthylene2,6-Dinitrotduene3-NitroanilineAcenaphthene2,4-Dinitrophend4-NitrophendDibenzofuran2,4-DlnitrotdueneDiethylphthalate4-Chlorophenyl-PhenyletherRuorene4-Nitroaniline4,6-Dinitro-2-MethylphendN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophendPhenanthreneAnthraceneDi-n-ButylphthalateRuoranthenePyreneButyl benzyiphthalate3,3'-DichlorobenzidineBenzo(a)AnthraceneChryseneBis(2-Ethylhexyl)PhthalateDi-n-OctylphthalateBenzo(b) RuorantheneBenzo(k) RuorantheneBenzo(a) PyreneIndeno(1 ,2,3-cd) PyreneDibenzo(a,h)AnthraceneBenzo(g, h, i) Perylene

SURROGATE COMPOUND

Nitrobenzene-d52-RuorobiphenylTerphenyl-d14

Phenol-d52-Ruorophend2,4,6-Tribromophenol

< 4.35< 14.49< 4.35< 2.90 |< 8.70 "< 14.49< 2.90< 57.97< 28.99< 8.70< 8.70< 2.90< 8.70< 4.35< 28.99< 28.99< 4.35< 8.70< 7.25< 28.99< 2.90< 2.90< 1.45< 2.90< 2.90< 4.35 |< 14.49 *4< 4.35'< 4.35< 2.90< 2.90< 14.49< 14.49< 8.70< 14.49< 14.49< 14.49

PERCENT RECOVERY

97.30%94.20%57.40%

50.00%66.00%97.40% l

flROQ2032

Page 117: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

Environmental Health Research and Testing, Inc.

3235 Omni Drive Cincinnati, Ohio 45245 (513) 752-2950 FAX (513) 752-2261

November 21,1990

OBG LABORATORIES, INC.ATTN: Mr. Michael Petterelli5000 Brittonfield Parkway, Suite 300P.O. Box 4942Syracuse, New York 13221

Dear Mr. Petterelli:

Please find enclosed the results of analysis for the 4 samples received on November 8,1990; andthe 25 samples received on November 9,1990.

If you have any further questions, please feel free to contact me at (513) 752-2950.

Sincerely,

Mona Risk, Ph.D.Director of Chemistry A\& 5T#|f?£&

Enclosures

NOV 26 1990OBG I_ABS, INC.SYRACUSE, N.Y.

NATIONAL OFFICES

Cincinnati, Ohio • Lexington, Kentucky • Research Triangle Park, North Carolina •Denver, Colorado • Birmingham, Alabama • Philadelphia, Pennsylvania • San Francisco, California • Miami, Florida r\ r\ O pj O O

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CHAIN OF CUSTODY RECORD

LABORATORIES, INC.

SURVEY:

LOCATION:

SAMPLED BY:

ORGANIZATION:

-

J

STATIONNUMBER SAMPLE LOCATION DATE

COLLECTEDTIME

COLLECTEDSAMPLEMATRIX

COMP.OR GRAB

NO. OFCONFAINERS

ANALYSISREQUIRED

MOD "Z,

bo.

-t:- i

r «)

(

Relinquished By: DATE TIME Received By: DATE TIME

Relinquished By: DATE TIME Received By: DATE TIME

Relinquished By: DATE TIME _, JJeceived by Laboratory: DATE TIME-Ofc

^ <K M.r. /^uUeX P- c a, ^ 0&& LA^6l

METHOD OF SHIPMENT:P^Arhi fex nrcw, Ovt .

0 J

OBG Laboratories, Inc., an O'Brien & Gere Limited Company5000 Brittonfield Parkway / Suite 300 / PO Box 4942 / Syracuse, NY 13221 / (315) 437-0200 SRQ02Q3l|

Page 119: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill ____

WORK ORDER NO.: N/A__________ PROJECT NO.: 12307

DATE EXTRACTED: N/A__________ DATE ANALYZED: 11-09-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-I-150D EHRT SAMPLE NO.: 29358

LAB NOTEBOOK NO.: 162. Pg. 9-12_____ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride 19.765. Chlorobenzene 17.556. Chloroethane 7.537. 2-Chloroethylvinyl Ether < 0.508. Chloroform 132.279. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 49.8216. 1,2-Dichloroethane 0.8417. 1,1-Dichloroethene 14.8918. trans-1,2-Dichloroethene 137.0319. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

flR002035

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CUSTOMER SAMPLE NO.: AS-I-150D _____ EHRT SAMPLE NO.: 29358

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene 1.2925. 1,1,1-Trichloroethane 117.4826. 1,1,2-Trichloroethane < 0.5027. Trichloroethene 59.0028. Trichlorofluoromethane < 0.5029. Vinyl Chloride 13.7930. Benzene 1290.0031. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____94.00%

Toluene-d8 - 99.00%

Bromofluorobenzene - 97.00%

COMPUTER SEARCH

Trichlorotrifluoroethane - Approx 46.95

flR002036

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. • MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill_________________

WORK ORDER NO.: N/A__________ PROJECT NO.: 12307

DATE EXTRACTED: N/A__________ DATE ANALYZED: 11-09-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-E-150D_______ EHRT SAMPLE NO.: 29359A

LAB NOTEBOOK NO.: 162. Pg. 9-12_____ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 1.866. Chloroethane < 0.507. 2-Chloroethylvinyl Ether < 0.508. Chloroform 11.709. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 3.2116. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 9.8119. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

SR002037

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CUSTOMER SAMPLE NO.: AS-E-150D_______ EHRT SAMPLE NO.: 29359A

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1 -Trichloroethane 6.3326. 1,1,2-Trichloroethane < 0.5027. Trichloroethene 3.0028. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene 81.6731. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - _____99.00%

Toluene-d8 - 102.00%

Bromofluorobenzene - 98.00%

SROQ2038

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELLIiI

SAMPLE SOURCE: Blosenski Landfill _________________________________________________________________

WORK ORDER NO.: N/A__________ PROJECT NO.: 12307

DATE EXTRACTED: N/A___________ DATE ANALYZED: 11-13-90

SAMPLE TYPE: ; Water Duplicate SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-E-150D EHRT SAMPLE NO.: 29359B

LAB NOTEBOOK NO.: 162, Pg. 9-12_____ METHOD NO.: EPA 601 &602

RESULTCOMPOUNDS ug/L

Bromodichloromethane < 0.50Bromoform < 0.50Bromomethane < 0.50Carbon Tetrachloride < 0.50Chlorobenzene 1.55Chloroethane < 0.502-Chloroethylvinyl Ether < 0.50Chloroform 10.35

9. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 2.9016. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 9.3019. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichlo.ropropene < 0.5022. Methyiene Chloride < 1.00

flR002039

Page 124: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-E-150D_______ EHRT SAMPLE NO.: 29359B

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1-Trichloroethane 7.1826. 1,1,2-Trichloroethane < 0.5027. Trichloroethene 4.9828. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene 80.8531. Ethylbenzene " < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

l,2-Dichloroethane-d4 - ____96.00%

Toluene-d8 - 93.00%

Bromofluorobenzene - 103.00%

AR0020W

Page 125: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill__________________________________

WORK ORDER NO.: N/A__________ PROJECT NO.: 12307

DATE EXTRACTED: N/A_________ DATE ANALYZED: 11-13-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-l-150 EHRT SAMPLE NO.: 29360

LAB NOTEBOOK NO.: 162, Pg. 9-12_____ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 17.356. Chloroethane 7.047. 2-Chloroethylvinyl Ether < 0.508. Chloroform 128.599. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1 -Dichloroethane 47.8316. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene 14.0218. trans-1,2-Dichloroethene 130.8119. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Pagel AR0020M

Page 126: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-l-150________ EHRT SAMPLE NO.: 29360

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene 1.2725. 1,1,1-Trichloroethane 112.9126. 1,1,2-Trichloroethane < 0.5027. Trichloroethene 56.8328. Trichlorofluoromethane < 0.5029. Vinyl Chloride 12.5430. Benzene 1022.0031. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - _____98.00%

Toluene-d8 ' - 98.00%

Bromofluorobenzene - 99.00%

fiR002Ql*2

Page 127: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

AMPLE SOURCE: Blosenski Landfill_______________________

WORK ORDER NO.: N/A_________________ EHRT PROJECT NO.: 12307

DATE EXTRACTED: 11-12-90______________ DATE ANALYZED: 11-13-90

SAMPLE TYPE: Water Sample__________ SAMPLE VOLUME: 500.00

ANALYST: K. Nusekabel____________ FINAL VOLUME: 1.00

CUSTOMER SAMPLE NO.: AS-l-150___________ EHRT SAMPLE NO.: 29360

LAB NOTEBOOK NO.: 149. Pg. 83_____________ METHOD NO.: EPA 625

RESULTCOMPOUNDS__________ ug/L

1-. Phenol < 6.002. Bis(2-Chloroethyl)Ether < 4.003. 2-Chlorophenol < 4.004. 1,3-Dichlorobenzene < 12.005. 1,4-Dichlorobenzene -< 12.006. Benzyl Alcohol < 6.007. 1,2-Dichlorobenzene < 12.008. 2-Methylphenol < 6.009. Bis-(2-Chk>roisopropyl) Ether < 8.0010. 4-Methylphenol < 6.0011. N-Nitroso-Di-n-Propylamine < 8.0012. Hexachloroethane < 12.0013. Nitrobenzene < 6.0014. Isophorone < 4.0015. 2-Nitrophenol < 8.0016. 2,4-Dimethylphenol < 6.0017. Benzole Acid < 40.0018. Bis(2-Chloroethoxy)Methane < 4.0019. 2,4-Dichlorophend < 8.0020. 1,2,4-Trichlorobenzene < 12.0021. Naphthalene < 2.0022. 4-Chloroaniline < 20.0023. Hexachlorobutadiene < 24.0024. 4-Chloro-3-Methylphenol < 6.0025. 2-Methylnaphthalene < 2.0026. Hexachlorocyclopentadiene < 24.0027. 2,4,5-Trichlorophenol < 10.0028. 2,4,6-Trichlorophenol < 10.00

flR002LH3

Page 128: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-l-150______________ EHRT SAMPLE NO.: 29360

29.30.31.32.33.34.35.36.37.38.39.40.

' 41.42.43.44.45.46.47.48.49.50.51.52.53.54.55.56.57.58.59.60.61.62.63.64.65.

2-Chloronaphthalene2-NrtroanilineDimethylphthalateAcenaphthylene2,6-Dinitrotoluene3-NitroaniiineAcenaphthene2,4-Dinitrophend4-NitrophendDibenzofuran2,4-DinitrotolueneDiethylphthalate4-Chlorophenyl-PhenyletherRuorene4-NKroaniiine4,6-Dinitro-2-MethvlphendN-Nftrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophendPhenanthreneAnthraceneDi-n-ButyphthalateRuoranthenePyreneButyl benzylphthalate3,3'-DichlorobenzidineBenzo(a)AnthraceneChryseneBis(2-Ethylhexyl)PhthalateDi-n-OctylphthalateBenzo(b)RuorantheneBenzo(k)RuorantheneBenzo(a)Pyrenelndeno(1 ,2,3-cd) PyreneDibenzo(a,h)AnthraceneBenzo(g,h,i)Perylene

SURROGATE COMPOUND

Nitrobenzene-d52-FluorobiphenylTerphenyl-d14

Phend-d52-Fluorophend2,4,6-Tribromophenol

< 6.00< 20.00< 6.00 |< 4-00 "< 12.00< 20.00< 4.00< 80.00< 40.00< 12.00< 12.00< 4.00< 12.00< 6.00< 40.00< 40.00< 6.00< 12.00< 10.00< 40.00< 4.00< 4.00< 2.00< 4.00< 4.00 4< 6.00 ™< 20.00< 6.00< 6.00

6.92< 4.00< 20.00< 20.00< 12.00< 20.00< 20.00< 20.00

PERCENT RECOVERY

58.50%52.70%37.10%

10.00% *10.00% *18.30% 1

k A low recovery was obtained on the phend surrogates. The surrogate recovery was also very low on the matrixspike and matrix spike duplicate. The sample matrix is probably responsible for these low recoveries since itreproduces on 3 analyses of the same sample. paae 2

AR0020H

Page 129: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.PESTICIDES - PCB ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. • MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill________________________________

WORK ORKER NO.: N/A_____________ EHRT PROJECT NO.: 12307

DATE EXTRACTED: 11-09-90 DATE ANALYZED: 11-09-90

SAMPLE TYPE: Water Sample_______ METHOD NO.: EPA 608

ANALYST: M. Cooper_________ LAB NOTEBOOK NO.: 158. Pg. 54

CUSTOMER SAMPLE NO.: AS-l-150 EHRT SAMPLE NO.: 29360

RESULTCOMPOUNDS ug/L

1. Alpha-BHC < 0.00142. Beta-BHC < 0.00083. Delta-BHC < 0.00064. Gamma-BHC . < 0.00065. Heptachlor < 0.00206. Aldrin < 0.00167. Heptachlor Epoxide < 0.00148. Endosulfan I < 0.00089. Dieldrin < 0.000410. 4,4'-DDE < 0.000411. Endrin < 0.000612. Endosulfan II < 0.0213. 4,4'-DDD < 0.0214. Endosulfan Sulfate < 0.000415. 4,4'-DDT < 0.001216. Methoxychlor < 0.000417. Endrin Ketone < 0.0418. Chlordane < 0.2019. Toxaphene < 3.00

Page 130: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-l-150___________ EHRT SAMPLE NO.: 29360

20. Aroclor-1016 < 0.5021. Aroclor-1221 < 0.5022. Aroclor-1232 < 0.5023. Aroclor-1242 < 0.5024. Aroclor-1248 < 0.5025. Aroclor-1254 < 0.5026. Aroclor-1260 < 0.50

SURROGATE RECOVERY

Dibutylchlorendate - ____99.00%

Page2

Page 131: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. • MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill___________________________

WORK ORDER NO.: N/A__________ PROJECT NO.: 12307

DATE EXTRACTED: N/A__________ DATE ANALYZED: 11-13-50

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-E-150 EHRT SAMPLE NO.: 29361

LAB NOTEBOOK NO.: 162, Pg. 9-12______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS_____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 1.686. Chloroethane < 0.507. 2-Chloroethylvinyl Ether < 0.508. Chloroform 10.259. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 2.9916. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 9.3319. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Page 132: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-E-150________ EHRT SAMPLE NO.: 29361

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1 -Trichloroethane 7.2026. 1,1,2-Trichloroethane < 0.5027. Trichloroethene 3.4128. Trichlorofluoromethane . . < 0.5029. Vinyl Chloride < 0.5030. Benzene 82.3031. Ethylbenzene < 0.5032. Tduene 0.76

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____100.00%

Tduene-d8 - 93.00%

Bromofluorobenzene - 103.00%

Page2

Page 133: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELLI

'AMPLE SOURCE: Blosenski Landfill_________________________

WORK ORDER NO.: N/A_________________ EHRT PROJECT NO.: 12307

DATE EXTRACTED: 11-12-90_______________ DATE ANALYZED: 11-13-90

SAMPLE TYPE: Water Sample__________ SAMPLE VOLUME: 1000.00

ANALYST: K. Nusekabel FINAL VOLUME: 1.00

CUSTOMER SAMPLE NO.: AS-E-150 EHRT SAMPLE NO.: 29361

LAB NOTEBOOK NO.: 149, Pg. 83_____________ METHOD NO.: EPA 625

RESULTCOMPOUNDS__________ ug/L

1. Phend < 3.002. Bis(2-Chloroethyi)Ether < 2.003. 2-Chlorophend < 2.004. 1,3-Dichlorobenzene < 6.005. 1,4-Dichlorobenzene < 6.006. Benzyl Alcohol < 3.007. 1,2-Dichlorobenzene < 6.008. 2-Methylphend < 3.009. Bis-(2-Chloroisopropyl)Ether < 4.0010. 4-Methylphend < 3.0011. N-Nitroso-Di-n-Propylamine < 4.0012. Hexachloroethane < 6.0013. Nitrobenzene < 3.0014. Isophorone < 2.0015. 2-Nitrophend < 4.0016. 2,4-DImethyl phenol < 3.0017. BenzoicAcid < 20.0018. Bis(2-Chloroethoxy) Methane < 2.0019. 2,4-Dichlorophenol < 4.0020. 1,2,4-Trichlorobenzene < 6.0021. Naphthalene < 1.0022. 4-Chloroaniline < 10.0023. Hexachlorobutadiene < 12.0024. 4-Chloro-3-Methylphenol < 3.0025. 2-Methylnaphthalene < 1.0026. Hexachlorocyclopentadiene < 12.0027. 2,4,5-Trichlorophend <. 5.0028. 2,4,6-Trichlorophenbl < 5.00

Page1 ftR0020l*9

Page 134: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-E-150_______________ EHRT SAMPLE NO.: __29361

29.30.

^ 31.B 32.

33.34.35.36.37.38.39.40.

' 41.42.43.44.45.46.47.48.49.50.51.52.

S:55.56.57.58.59.60.61.62.63.64.65.

2-Chloronaphthalene2-NitroanilineDimethylphthalateAcenaphthylene2,6-Dinitrotoluene3-NitroaniiineAcenaphthene2,4-Dinitrophenol4-NltrophendDibenzofuran2,4-DinitrotdueneDiethylphthalate4-Chlorophenyl-PhenyletherRuorene4-Nitroaniline4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophendPhenanthreneAnthraceneDi-n-ButyphthalateRuoranthenePyreneButyl benzylphthalate3,3'-DichlorobenzidineBenzo(a)AnthraceneChryseneBis(2-Ethylhexyl) PhthalateDi-n-OctylphthalateBenzo(b)RuorantheneBenzo(k) RuorantheneBenzo(a) Pyrenelndeno(1 ,2,3-cd) PyreneDibenzo(a,h)AnthraceneBenzo(g,h,i)Perylene

SURROGATE COMPOUND

Nitrobenzene-d52-RuorobiphenylTerphenyl-d14

Phenol-d52-Fluorophend

^ 2,4,6-Tribromophenol

< 3.00< 10.00< 3.00< 2.00< 6.00< 10.00< 2.00< 40.00< 20.00< 6.00< 6.00< 2.00< 6.00< 3.00< 20.00< 20.00< 3.00< 6.00< 5.00< 20.00< 2.00< 2.00< 1.00< 2.00< 2.00< 3.00< 10.00< 3.00< 3.00< 2.00< 2.00< 10.00< 10.00< 6.00< 10.00< 10.00< 10.00

PERCENT RECOVERY

72.00%57.40%50.90%

10.00% *10.00% *12.20%

A low recovery was obtained on the phend surrogates due to the sample matrix.

Page2 flR002050

Page 135: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.PESTICIDES - PCB ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill________________

WORK ORKER NO.: N/A_____________ EHRT PROJECT NO.: 12307

DATE EXTRACTED: 11-09-90 _____ __ DATE ANALYZED: 11-09-90

SAMPLE TYPE: Water Sample_______ METHOD NO.: EPA 608

ANALYST: M. Cooper_________ LAB NOTEBOOK NO.: 158. Pg. 54

CUSTOMER SAMPLE NO.: AS-E-150 EHRT SAMPLE NO.: 29361

RESULTCOMPOUNDS ug/L

1. Alpha-BHC < 0.00142. Beta-BHC < 0.00083. Delta-BHC < 0.00064. Gamma-BHC < 0.00065. Heptachlor < 0.00206. Aldrin < 0.00167. Heptachlor Epoxide < 0.00148. Endosulfan I < 0.00089. Dieldrin < 0.000410. 4,4'-DDE < 0.000411. Endrin < 0.000612. Endosulfan II < 0.0213. 4,4'-DDD < 0.0214. Endosulfan Sulfate < 0.000415. 4,4'-DDT < 0.001216. Methoxychlor < 0.000417. Endrin Ketone < 0.0418. Chlordane < 0.2019. Toxaphene < 3.00

Page1 flR00205l

Page 136: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

£usSTOMER SAMPLE NO.: AS-E-150__________ EHRT SAMPLE NO.: 29361

20. Aroclor-1016 < 0.5021. Aroclor-1221 < 0.5022. Aroclor-1232 < 0.5023. Aroclor-1242 < 0.5024. Aroclor-1248 < 0.5025. Aroclor-1254 < 0.5026. Aroclor-1260 < 0.50

SURROGATE RECOVERY

Dibutylchlorendate - ____166.00%

flR002052

Page 137: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

c MMirtiAorii\<_/MMiriiA i>rif\c uuruwMe rttouvcm

Lab Name: Environmental Health Research & Testing, Inc.

Customer Name: OBG LABORATORIES. INC. - MR. MIKE PETTERELLI__________________

Project No.: 12307_________ Method No.: EPA 625_____

Customer Sample No.: AS-l-150______ EHRT No.: 29360

COMPOUNDPhenol2-Chlorophenol1 ,4-DichlorobenzeneN-Nitroso-di-n-Propylamine1 ,2,4-Trichlorobenzene4-Chloro-3-MethylphenolAcenaphthene4-Nitrophenol2,4-DinitrotoluenePentachlorophendPyrene

SPIKE ADDED(ng)200200100100100200100200100200100

SAMPLE CONC.(ug/L)0.000.000.000.000.000.000.000.000.000.000.00

MS CONC.(ug/L)16.9457.9463.3779.9562.327.2163.0678.9569.5759.4449.57

MS%REC#8.5*29.063.480.062.33.6*63.139.569.629.749.6

QC LIMITSREG.12-8927-12336-9741-11639-9823-9746-11810-8024-969-10326-127

COMPOUNDPhenol2-Chlorophenol1 ,4-DichlorobenzeneN-Nitroso-di-n-Propylamine1 ,2,4-Trichlorobenzene4-Chloro-3-MethylphenolAcenaphthene4-Nitrophend2,4-DinitrotoluenePentachlorophendPyrene

MSD CONC.(ug/L)19.2253.4456.6570.6056.725.7156.7479.3566.0360.4449.76

MSD%REC#9.6*26.7*56.770.656.72.9*56.739.766.030.249.8

MS%REC#8.5*29.063.380.062.33.6*63.139.569.629.749.6

%RPD#12.18.311.012.59.421.511.00.515.31.70.40

QCLJRPD4240283828423150385031

vllTS RECJH12-89~127-12336-9741-11639-9823-9746-11810-8024-969-10326-127

# Column to be used to flag recovery and RPD values with an asterick* Values outside of QC limits

COMMENTS:

RPD: 0:overy: 7

out of 11 outside limitsout of 22 outside limits

flR002053

Page 138: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELLI

AMPLE SOURCE: Blosenski Landfill___________________________

WORK ORDER NO.: N/A________________ EHRT PROJECT NO.: 12307

DATE EXTRACTED: 11-12-90 _______ DATE ANALYZED: 11-13-90

SAMPLE TYPE: Water Blank _____ SAMPLE VOLUME: 1000.00

ANALYST: K. Nusekabel FINAL VOLUME: 1.00

CUSTOMER SAMPLE NO.: N/A_________________ EHRT SAMPLE NO.: N/A

LAB NOTEBOOK NO.: 149, Pg. 83_____________ METHOD NO.: EPA 625

RESULTCOMPOUNDS__________ ug/L

1. Phend < 3.002. Bis(2-Chloroethyl)Ether < 2.003. 2-Chlorophend < 2.004. 1,3-Dichlorobenzene < 6.005. 1,4-Dichlorobenzene < 6.006. Benzyl Alcohd < 3.007. 1,2-Dichlorobenzene < 6.008. 2-Methylphend < 3.009. Bis-(2-Chloroisopropyl)Ether < 4.0010. 4-Methylphend < 3.0011. N-Nftroso-Di-n-Propylamine < 4.0012. Hexachloroethane < 6.0013. Nitrobenzene < 3.0014. Isophorone < 2.0015. 2-Nitrophend < 4.0016. 2,4-Dimethylphend < 3.0017. BenzoicAcid < 20.0018. Bis(2-Chloroethoxy)Methane < 2.0019. 2,4-Dichlorophenol < 4.0020. 1,2,4-Trichlorobenzene < 6.0021. Naphthalene < 1.0022. 4-Chloroaniline < 10.0023. Hexachlorobutadiene < 12.0024. 4-Chloro-3-Methylphenol < 3.0025. 2-Methyinaphthalene < 1.0026. Hexachlorocyclopentadiene < 12.0027. 2,4,5-Trichlorophend < 5.0028. 2,4,6-Trichlorophend < 5.00

flR00205l*

Page 139: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: N/A_________________ EHRT SAMPLE NO.: N/A

29.30.31.32.33.34.35.36.37.38.39.40.41.42.43.44.45.46.47.48.49.50.51.52.53.54.55.56.57.58.59.60.61.62.63.64.65.

2-Chloronaphthalene2-NitroanilineDimethylphthalateAcenaphthylene2,6-Dinitrotduene3-NitroanilineAcenaphthene2,4-Dinitrophend4-NitrophendDibenzofuran2,4-DinitrotolueneDiethylphthalate4-Chlorophenyl-PhenyletherRuorene4-Nitroaniline4,6-Dinttro-2-MethylphendN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophendPhenanthreneAnthraceneDi-n-ButyphthalateFluoranthenePyreneButyl benzylphthalate3,3'-Dlchlorobenz!dineBenzo(a)AnthraceneChryseneBis(2-Ethylhexyl)PhthalateDi-n-OctylphthalateBenzo(b) RuorantheneBenzo(k) RuorantheneBenzo(a)Pyrenelndeno(1 ,2,3-cd) PyreneDibenzo(a,h)AnthraceneBenzo(g,h,i)Perylene

SURROGATE COMPOUND

Nitrobenzene-d52-FluorobiphenylTerphenyl-d14

Phenol-d52-Ruorophend2,4,6-Tribromophenol

< 3.00< 10.00< 3.00 A< 2.00 1< 6.00< 10.00< 2.00< 40.00< 20.00< 6.00< 6.00< 2.00< 6.00< 3.00< 20.00< 20.00< 3.00< 6.00< 5.00< 20.00< 2.00< 2.00< 1.00< 2.00< 2.00 M< 3.00 ^< 10.00< 3.00< 3.00< 2.00< 2.00< 10.00< 10.00< 6.00< 10.00< 10.00< 10.00

PERCENT RECOVERY

67.20%43.40%41.70%

26.60%43.90%79.50% ^

Page2 SR002055

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A PROJECT NO.: 12307 *

ANALYSIS PERFORMED: 5-Dav BOD Analysis

ANALYSIS METHOD: EPA 405.1

ANALYST: G. Stake

DATE ANALYZED: 1 1 /08-1 3/90

LAB NOTEBOOK NO.: 161, Pg. 6

SAMPLE NO.EHRT NO. CUSTOMER NO.

29360 AS-l-150

29361 A AS-E-150

29361 B AS-E-150(Duplicate)

RESULTSmg/L

BDL

BDL

BDL

DETECTION LIMIT: < 2 mg/L

flR002056

Page 141: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE:

WORK ORDER NO.:

ANALYSIS PERFORMED:

ANALYSIS METHOD:

ANALYST:

Blosenski Landfill

N/A

Total Suspended Solid Analysis

Std. Method 209C

M. Reddy

SAMPLE NO.EHRT NO. CUSTOMER NO.

29360 AS-l-150

29361 AS-E-150

PROJECT NO.: 12307

--

DATE ANALYZED: 1 1 -1 2-90

LAB NOTEBOOK NO. : 1 37, Pg. 61

RESULTSmg/L

BDL

BDL

DETECTION LIMIT: < 10 mg/L

Page1 SR002057

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: QBG LABORATORIES. INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill______________________

WORK ORDER NO.: N/A____________ PROJECT NO.: 12307

ANALYSIS PERFORMED: Ammonia Analysis_______________________

ANALYSIS METHOD: EPA 350.1 DATE ANALYZED: 11-14-90

ANALYST:

SAMPLEEHRT NO.

29360A

29360B(Duplicate)

29361

K. Nusekabel

NO.CUSTOMER NO.

AS-l-150

AS-l-150

AS-E-150

LAB NOTEBOOK NO.: 161, Pg. 12

RESULTSmg/L

BDL

BDL

BDL

DETECTION LIMIT: < 0.10 mg/L

Page1 SROG2058

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A

ANALYSIS PERFORMED: Total Kjeldahl Nitrogen

ANALYSIS METHOD: EPA 351.2

ANALYST: K. Nusekabel

PROJECT NO.: 12307

(TKN) Analysis

DATE ANALYZED: 1 1 -21 -90

LAB NOTEBOOK NO.: 161, Pg. 15

SAMPLE NO.EHRT NO. CUSTOMER NO.

29360A AS-l-150

29360B AS-l-150(Duplicate)

29361 AS-E-150

RESULTSmg/L

0.28

0.25

0.20

DETECTION LIMIT: < 0.12 mg/L

AROQ2059

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: OBG LABORATORIES,INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A PROJECT NO.: 12307

ANALYSIS PERFORMED: Phosphorus Analysis

ANALYSIS METHOD: EPA 365.2

ANALYST: M. Reddy

DATE ANALYZED: 1 1 -1 3-90

LAB NOTEBOOK NO.: 161, Pg. 10

SAMPLE NO.EHRT NO. CUSTOMER NO.

29630A AS-l-150

29360B AS-I-150(Duplicate)

29361 AS-E-150

RESULTSmg/L

BDL

BDL

BDL

Detection Limit - < 0.01 mg/L

Pagel flRQ02060

Page 145: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE:

WORK ORDER NO.:

ANALYSIS PERFORMED:

ANALYSIS METHOD:

ANALYST:

Blosenski Landfill

N/A

Oil & Grease Analysis

EPA 41 3.1

G. Stake

SAMPLE NO.EHRT NO. CUSTOMER NO.

29360 AS-i-150

29361 AS-E-150

PROJECT NO.: 12307

DATE ANALYZED: 1 1 -08-90

LAB NOTEBOOK NO. : 1 61 , Pg. 4

RESULTS(mg/L)

BDL

BDL

Detection Limit: < 10 mg/L

Pagel 3R00206!

Page 146: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME:

SAMPLE SOURCE:

WORK ORDER NO.:

ANALYSIS PERFORMED:

ANALYSIS METHOD:

ANALYST:

OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

Blosenski Landfill

N/A PROJECT NO.: 12307

TOC Analysis

EPA 9060 DATE ANALYZED: 1 1 -09-90

G. Luna LAB NOTEBOOK NO.: 135, Pg. 17

SAMPLE NO. RESULTSEHRT NO. CUSTOMER NO. mg/L

29360 AS-l-150

29361 A AS-E-150

29361 B AS-E-150(Duplicate)

BDL

BDL

BDL

Detection Limit - < 10 mg/L

flR002062

Page 147: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME:

SAMPLE SOURCE:

WORK ORDER NO.:

ANALYSIS PERFORMED:

ANALYSIS METHOD:

ANALYST:

OBG LABORATORIES,

Blosenski Landfill

N/A

COD Analysis

EPA 41 0.4

M. Reddy

SAMPLE NO.EHRT NO. CUSTOMER NO.

29360A AS-l-150

29360B AS-l-150(Duplicate)

29361 AS-E-150

INC. - MR. MIKE PETTERELLJ

PROJECT NO.: 12307

DATE ANALYZED: 1 1 -09-90

LAB NOTEBOOK NO.: 151 , Pg. 25

RESULTSmg/L

57.32

53.94

I101.16

DETECTION LIMIT: < 40 mg/L

Page1 flR002063

Page 148: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

USTOMER NAME: OBG LABORATORIES. INC. • MR. MIKE PETTERELLIr ••- • •'•••'SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A PROJECT NO.: 12307

ANALYSIS PERFORMED: Chloride Analysis

ANALYSIS METHOD: EPA 325.1

ANALYST: K. Nusekabel

DATE ANALYZED: 1 1 -09-90

LAB NOTEBOOK NO.: 1 61 , Pg. 7

SAMPLE NO.EHRT NO. CUSTOMER NO.

BLANK N/A

29360A AS-l-150

29360B AS-l-150(Duplicate)

•361 AS-E-150

RESULTS(mg/L)

BDL

21.12

21.20

21.85

DETECTION LIMIT: < 4 mg/L

Page 149: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

Detection Limit - < 5 mg/L

Pagei QR002065

SAMPLE SOURCE:

WORK ORDER NO.:

ANALYSIS PERFORMED:

ANALYSIS METHOD:

ANALYST:

Blosenski Landfill

N/A

Sulfate Analysis

EPA 375.4

J. Burns

SAMPLE NO.EHRT NO. CUSTOMER NO.

29360 AS-l-150

29361 AS-E-150

PROJECT NO.: 12307

DATE ANALYZED: 1 1 -1 2-90

LAB NOTEBOOK NO.: 161, Pg. 9

RESULTSmg/L

66.9

69.2

Page 150: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

COVER PflBE - INORefiNIC ANALYSES DATA PACKAGE

Lab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: DBS.

Lab Code: W88__ Case No.: BLOSE SAS No.: 1£307_ SDB No.: 000000

SOW No. : '_____

EPA Sample No. Lab Sample ID._ASE150_ £9361_____AS1150_ 293G0A___

ASI150D 29360B

Were ICP intere 1 ement corrections applied ? Yes/No YES

Were ICP background corrections applied ? Yes/No YESIf yes - were raw data generated beforeapplication of background corrections ? Yes/No N0_

Comments:OB8 LflBORftTORIES - BLOSENSKI LANDFILL DflTE OF ANALYSIS 11-12-90____ICP_S. STAKE_NB157_P623_METHOD_S010/_FURNACE_P. BARNWELL_NB154_PG63.METHOD AS706 SE7740/ CO~LD VAPOR J. RADER NB157 P623 METHOD 7470___

Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on floppy diskette has been authorized bythe Laboratory Manager or the Manager's de.signee, as verified by thefollowing signature.

Lab Manager:

Date:COVER PAGE - IN ' 7/87

flR002066

Page 151: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

Name: ENVIR. HEALTH RESEARCH TE

Code: W88 Case No. : BLOSE

-ix (soil/water): WATER

;1 (low/med): ___

slids: ___

Concentration Units (ug/L

or Before:

or After:

ments:

AS-E-150

1ICAS No.11 7429-90-51 7440-36-01 7440-38-21 7440-39-317440-41-71 7440-43-91 7440-70-21 7440-47-31 7440-48-41 7440-50-81 7439-89-617439-92-11 7439-95-41 7439-96-51 7439-97-61 7440-02-01 7440-09-71 7782-49-21 7440-22-41 7440-23-51 7440-28-01 7440-62-21 7440-66-611

Contract: QBG

1 11 ASE150 11 1

SAS No. : 12307_ SDG No. : 000000

Lab Sample ID: 29361 ___

Date Received: 11/08/90

or nig/kg dry weight): UG/L_

1 11 Ana 1 y t e 1 Concent rat ionI 11 Aluminum 11 Ant i rnony 11 Arsenic 11 Bar i urn 11 Bery 1 1 i urn 11 Cadmium 1ICalcium 11 Chromium 11 Cobalt 11 Copper 11 Iron 1I Lead !i Magnesium!1 Manganese 11 Mercury 11 Nickel 11 Pot ass i urn 11 Se 1 en i urn 11 Silver 11 Sod i urn 11 Thai Hum 11 Vanad i urn 1IZinc 11 Cyanide 11 I

Clarity

Clarity

O fYr/U. (Jt

10.72.2

0.401.8

5.3

5.0

10.9

i i1C! Q1 11 1I U II U I1 1I U IIUI1 1IU!1 1I U I1 1I U I1 1

1IM1INRIPIFINRIPIPINRIPINRIPINRIPINRI

I I INRI0. 1

4.6IU!IUI

ICVIIP 1

1 1 INRI2. 11.9

95.5

2.4

IUIIUI1 1I U I1 1IU!

IFIPINRIPINRIP 1

I I INRI

Before :

After:

1 1 1 1

Texture:

Artifacts:

*

v<i/£ — .A LdlovO -$± djJfcJiz& Ji-uLJCt-^

FORM I - IN -7/87

AR002067

Page 152: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET ___________

II ASI150

Lab Name: ENVIR._HEALTH_RESEARCH_TE Contract: OBG_____ I_______

Lab Code: W88__ Case No. : BLOSE SAS No.: 1£307_ SDG No. : 000000

Matrix (soil/water): WATER Lab Sample ID: 29360A___

Level (low/wed): ___ Date Received: 11/08/90

•/• Solids: ___

Concentration Units (ug/L or rng/kg dry weight): US/L_

1ICAS No.11 7429-90-51 7440-36-01 7440-38-21 7440-39-317440-41-71 7440-43-91 74413-70-21 7440-47-31 7440-48-41 7440-50-81 7439-89-617439-92-11 7439-95-41 7439-96-51 7439-97-61 7440-02-01 7440-09-71 7782-49-21 7440-22-41 7440-23-51 7440-28-01 7440-62-21 7440-66-611

Color Before:

Color After:

Comments:

1 1 1 11 Analyte IConcentrationlCI Q1 1 1 I1 Alum in urn 11 Ant i rnony 11 Arsenic 1(Barium 11 Bery 1 1 i urn 11 Cadmium 11 Calcium 11 Chromium 1(Cobalt 11 Coooer 11 Iron 11 Lead i(Magnesium!1 Manganese 1! Mercury 1INickel 1! Potassium!1 Selenium 11 Silver 11 Sod i urn 11 Thallium 11 Vanad i urn 1IZinc 11 Cyanide 11 !

Clarity

Clarity

10.7£.2

0.401.8

5.3

5.0

10.9

0. 1

4.6

2.11.9

95.5

2.4

Before:

After:

1 !IUIIUI1 II U IIUII !IUI1 1IU!1 1I U Il_l __1 1IUI __IU I1 1I U IIU!1 1IUI1 1IUI1 11 1

1 1!M I1 1INRIIP 1IF 1INRIIP 1IP 1INRIIP 1INRIIP 1INRIIP 1

__ INRIINRI

__ ICVIIP 1INRIIF 1IP 1INR!IP 1INRIIP 1INRI1 i

Texture:

Artifacts:

AS-I-150

FORM I - IN • 7/87

flR002068

Page 153: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

Name: ENVIR. HEALTH RESEARCH

Code: W88 Case No. :

rix (soil/water): WATER

nlids for Sample: ___

Concentration Units

1 i II1 1 Control 1 1lAnalyte 1 Limit 1 1 Sample! 1 I I1 Aluminum 1 I 1

6DUPLICATES

_TE Contract

BLOSE SAS

(ug/L or mg/kg

: OBG

No. : 12307

Level

% Solids for

dry weight) :

1 1 11 1 1

(S) Cl i Duplicate (D) Cl1 1 1

1 1 !1 Antimony 1 60.0 II 10. 7000 IU II1 Arsenic 1 10.0 M1 Barium 1 1 11 Beryllium! 5. 0 1 11 Cadmium i 5. 0 1 1I Calcium 1 1 11 Chromium 1 10. 0 1 11 Cobalt 1 II1 Copper 1 25. 0 1 1I Iron 1 1 IILead 1 5. 0 ! 1IMaanesiuml 1 IIManaanesel 1 11 Mercury 1 0.2111 Nickel 1 40. 0 1 11 Pot ass i urn 1 1 I(Selenium 1 5. 0 1 11 Silver 1 10.0 1 11 Sodium 1 1 11 Thai Hum ! 10. 0 1 11 Vanad i urn 1 1 1IZinc 1 20.0 1 11 Cyanide I 1 11 1 I I

2. 2050 1 U M1 1 1

0. 4000 1 U 1 I

1.8000IUI i1 1 1

5. 3000 IUI I1 1 1

5. 0070 I U I I1 1 1

10. 9000 mi i1 1 I1 1 1

0. 1000 IUI 14. 6000 1 U 1 i

1 1 12. 1420IUI 11.9000 mi i

1 1 195. 5000 I U I I

I 1 12. 4000 I U I I

1 1 1i 1 1

1 110. 7000 IU!2. 20501 UI

1 10.4000IUI1. 80001 UI

1 - i5. 3000 1 U 1

I 15.0070IUI

1 110. 9000IUI

1 11 1

0. 1000IUI4. 6000IUI

1 I2. 1420IUI1.9000IUI

1 195. 5000 1 U 1

1 12. 4000 1 U 1

1 11 1

EPA SAMPLE NO.

1 11 ASI150D 11 1

SDG No. : 000000

(low/rned) : ___

Duplicate: ___

UG/L_

1 M l !1 1 1 I 11 RPD 1 IQI MlI 1 I 1 11 I I INRI1 1 1 IP 11 1 1 IF !1 I I INRI1 I I IP 1I I 1 IP 11 ! I INRI1 1 1 IP 11 II INR!1 1 1 IP 11 I i INRI1 1 1 IP I1 I I INRI1 I I INRI1 1 1 1 CV 11 1 1 IP 11 I i INRI1 1 1 IF 11 1 1 IP 11 II INRI1 N I P !1 I I INRI1 M IP 1! I 1 INRII I I I !

FORM VI - IN 7/87

3R002069

Page 154: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

2AINITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Name: ENVIR. HEALTH RESEARCH TE Contract: OBB

Lab Code: W88__ Case No.: BLOSE SAS No.: 1£307_ SDG No.: 000000

Initial Calibration Source: SPEX

Cont i nu ing Ca 1 i brat i on Source : SPE!

Concent rat

l 11 1lAnalyte 11 11 Aluminum 11 Ant i rnony 11 Arsen i c 11 Bar i urn 11 Beryllium!1 Cad mi urn 11 Calcium 11 Chromium I1 Cobalt 1i Cop per I1 Iron 1ILead 1i Magnesium!i Manganese!1 Mercury 1INickel 11 Potassium!1 Se 1 en i urn 1(Silver 11 Sod i urn 1I Thallium tt Vanad i urn 1IZinc 1(Cyanide 11 !

1Initial Calibration 1

True Found '/.R ( 1 ) !1

1500.0 1

50.0 1I

500.0 1

500.0 11

500.0 1

r500.0 1

1500.0 !

1

i5.0 1

500.0 11

10.0 1100.0 1

1

1000.0 11

500.0 11

I

1 1

507.501 101.5147.90! 95.81

1 1476.30! 95.31490. 40 1 98. 1 1

! 1549. 00 1109. 81

! 1489.00! 97.8!

1 I483.201 96.6!

' I 11 1

5.481109.61490.701 98.11

1 110. 50 1105. 0197.101 97.11

I 1946.501 94.61

1 1494.901 99.01

1 11 I

<

ion Units: ug/L

! i 1Continuing Calibration II

True Found 5'.R(1) Found JCR(l) 1 1 MI1 1

1500.0 f

50.0 11

500.0 I

500.0 I

1500.0 1

1500.0 1

1500.0 1

1I

5.3 1500.0 1

120.0 1

100.0 I1

1000.0 11

500.0 1iI

1 1508.301101.7149.801 99.61

I 1471.801 94.41483.601 96.71

1 1548.701109.71

1 1479.801 96.01

i 1478.40! 95.71

1 11 1

5.301106.01483.20! 96.61

1 119.901 99.5196.701 96.71

1 1961.901 96.21

1 1493.701 98.71

I 11 1

1 1 iNR1 IIP1 1 IF1 1 INR1 1 IPI 1 IP1 1 INR1 1 IP1 1 INR1 1 IP1 I INRI 1 IP1 1 1 NR 11 1 INR1 1 1 CV 11 ! IP 11 I I N R I1 1 IF1 1 IP 11 1 INR1 MP I1 1 INR1 IIP 11 ! INR1 M l

(1) Control Limits: Mercury 80-1205 Other Metals 90-1105 Cyanide 85-115

FORM II (PART 1) - IN 7/87

flR002070

Page 155: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP

2AINITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Name: ENVIR. HEALTH RESEARCH TE Contract: OBG

Lab Code: W88__ Case No.: BLOSE SAS No.: 1£307_ SDG No. : 000000

Initial Calibration Source: SPEX______

Continuing Calibration Source: SPEX_____

Concentration Units: ug/L

1 11 1(Analyte Ii 1(Aluminum 1(Antimony 11 Arsenic 11 Bar i urn 11 Beryllium!(Cadmium 11 Calcium 11 Chromium 11 'Cobalt !(Copper 1llron 1(Lead 1(Magnesium!1 Manganese 11 Mercury 1(Nickel 11 Pot ass i urn 1(Selenium 1(Silver 11 Sod i urn 11 Thai Ii urn _lI Vanadium !(Zinc 1(Cyanide 11 1

InitTrue

12000.

1000._1000.

2000.

5000.

600.

8000.

2000.

2000.

4000.

0

0

0

0

0

0

0

0

0

0

1

ial Calibration 1Found *R ( 1 ) 1

1111176011-1 9881 102611 19191! 5299i1 5811[I1 78471I1 19781i 206511 4135i1

1.001

11

.001

.0011

.00!1

.0011

.501

I.00

1

.001

.001

.001

I

98.

98.102.

96.

106.

96.

98.

98.

103.

103.

I01

11

8!61

10!

101

191

~l1

1111

911

21I

41

1

True

112000.0 I

11

1000.0 1

1000. 0 11

2000.0 11

5000. 0 1i

600.0 i11I

3000.0 111

2000.0 11

2000. 0 11

4000.0 1

1

Continuing CalibrationFound 54R(1) Found 3CRU)

12170.

1017.1074.

1971.

5364.

609.

8090.

_2026.

2118.

4255.

1001101.

I1

001101.

001107.1

00 1 _98.1

001107.

1901101.

1II

001101.1I

001101.i

001105.

001106.

11

1 141 1

1 11 1

7! 141 1

1 I61 1

1 13! 1

1 161 1

1 11 11 1

1! 11 11 1

31 11 1

91 11 1

41 11 11 I

111 M1INRIP-INRIINRIIP IIPJINR!IPJINRIIP 1INRIIP 1INR!INRIINRIIP 1INRIINR!IP 1INRIIP 1INRIIP 1INRI1 1

(1) Control Limits: Mercury 80-1205 Other Metals 90-1105 Cyanide 85-115

FORM II (PART 1) - IN 7/87

4R002071

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U.S. EPA - CLP

Lab Name: ENVIR. HEALTH

Lab Code: W88

Preparation

Preparation

i 11 i1 i1 !lAnalyte 11 I1 Aluminum iI Antimony 1! Arsenic 11 Barium I1 Beryllium!(Cadmium 1(Calcium 1(Chromium 1(Cobalt i1 Copper 11 Iron 11 Lead 1! Magnesium!1 Manganese 1i Mercury iI Nickel 11 Potassium!(Selenium 1(Silver 11 Sod i urn ((Thallium 11 Vanad i urn 1(Zinc 1(Cyanide i1 1

3BLANKS

RESEARCH TE Contract: OBG

Case No. : BLOSE SAS No. : 12307

SDG No. : 000000

Blank Matrix (soil/water): WATER

Blank Concentration Units (ug/L or rng/kg) : UG/L_

IInitial 1Calib. 1Blank 1(ug/L) Cl

1I 1

10.7 IUI2.2 IU!

1 I0.4 IUI1.8 IUI

I 15.3 IUI

1 15.0 IUI

1 110.9 I I

1 11 1

0.1 IUI4.6 IUI

! 12.1 IU!1.9 IU!

I i9 5 . 5 ( I

1 12. 4 IUI

1 11 I

i 11 1

Cont i nu i ng Ca 1 i brat i on 1 iBlank (ug/L) i 1

1 C 2 C 3 CM1 I

I I I I I I I10.7 I U I I I i l l2 . 2 I U ! I I i l l

i 1 I I I I I0 . 4 I U ! 1 I I I I1 . 8 I U I I I I I !

I I I I I I !5 . 3 I U I I I I I I

I I I I I I I5 . 0 I B I I I I I I

1 1 1 I I I I10.9 1 1 II 1 1 I

I I I I I I II I 1 1 1 M

0 . 1 I U I I I 1 I I4 . 6 I U I I I I I I

I I 1 1 I I I2 . 1 I U I 1 ! I l l1 . 9 I U I I I I I I

1 1 I I 1 1 !9 5 . 5 1 I I I I I I

I I I I i l l2 . 4 I U I I I 1 1 i

I I I I I I I1 I 1 I Id

1 II 1

Prepa- 1 1ration 1 1Blank C! 1 M

1 1! 1 INR

10. 700IUI IP2.200IUMF

1 i INR0. 400 1 U 1 1 P1.800IU1 IP

1 1 INR5. 300 i U 1 i P

i I INR5.010IBI IP

1 1 INR10.9001 IIP

1 1 INR1 1 INR

0.100 IUI ICV

4. 600 lUi IP1 1 INR

2. 140IUMF1.900IUI IP

1 ! INR95.5001 MP

1 1 INR2. 4001 UI IP

1 1 INR1 1 1

FORM III - IN 7/87

flR002072

Page 157: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

U.S. EPA - CLP .

4ICP INTERFERENCE CHECK SAMPLE

Lab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: OBG,

b Code: W88

P ID Number: 2483

Case No. : BLOSE SAS No: 12307_

ICS Source:

SDG No. : 0000C

Concentration Units: ug/L

1 1I True 11 Sol. Sol. 11 Analyte A AB 1I 11 Alum in urn_l 500000 1(Antimony 1 1(Arsenic 1 11 Bar i urn 1 11 Beryl Ii urn 1 11 Cadmium 1 1i Calcium _ 15000001I Chromium 1 11 Cobalt 1 I1 Copper 1 11 1 ron 1 200000 11 Lead 1 I! Magnesium 1500000!! Manqanese 1 1i Mercury 1 1INickel 1 I1 Potassium! 1(Selenium 1 1I Silver 1 11 Sod i urn 1 1(Thallium 1 i1 Vanad i urn 1 1IZinc I 1

_500000 I11

5001

500110001

500000 i500150015001

200000 110001

_500000 15001

1

10001111

I1

500110001

IInitial Found 1 Final Found

Sol. Sol. 1 Sol. Sol.A AB '/.R 1 A AB *R

1_461400! 482600. 0 1 _96. 5 1 4653001

i I I !1 1 1 I1 526.01105.21 11 489.0! 97.81 1i 910.01 91.01 1

_467900 1 _485000. 0 1 _97. 0 1 _475200 1l~ 492.0! 98. 4 l~ 11 567.01113.41 i1 420.01 84.01 1

1748001 191100.0! 95.61 17620011 992.01 99.21 1

_488100I 503300.01100.71 49290011 507.01101.41 11 1 1 I1 956.01 95.61 1I I I II 1 1 II 982.01 98.2! 11 I I II I I I1 574.01114.811 2.01 0.2! 1

480500. 01 96. 111

529.01105.8490.01 98.01924.01 92.41

_486300.0I_97.3I494.0! 98.81532.01106.41402.01 80.41

11012.01101.2

_502700. 01100.5500.01100.0

1932.01 93.2

111I1

538.01107.6955.01 95.5

1 1 1 I I I I I 1

FORM IV - IN 7/87

SR002Q73

Page 158: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CHAIN OF CUSTODY RECORD

LABORATORIES, INC.

SURVEY:

LOCATION: Uw £.<vU / 9k

SAMPLED BY:

ORGANIZATiON: D '.

STATIONNUMBER SAMPLE LOCATION DATE

COLLECTEDTIME

COLLECTEDSAMPLEMATRIX

COMP.OR GRAB

NO. OFCONTAINERS

ANALYSISREQUIRED

\. - X - ! >0 iijqfo (rriub

JU T- lift

\-IT- tOfi z- £"- 1 oo

0 »OO

1i: TO

- e - fl 4(f I V.IT

12. - e - 60 IV,\V

Relinquished By: DATE TIME Received By: DATE TIME

Relinquished By: DATE TIME Received By: DATE TIME

Relinquished By: ') DATE TIMEV.o-,

Received by Laboratory: DATE TIME

COMMENTS: HL , CMA ->!~v Ux v c/ - C" 1 H^^-GlOc or

METHOD OF SHIPMENT:

OBG Laboratories, Inc., an O'Brien & Gere Limited Company5000 Brittonfield Parkway / Suite 300 / PO Box 4942 / Syracuse, NY 13221 / (315) 437-0200$ R Q 0 2 0 7 U

Page 159: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CHAIN OF CUSTODY RECORD

LABORATORIES, INC.

SURVEY:

LOCATION:

SAMPLED BY:

ORGANIZATION:

STATIONNUMBER SAMPLE LOCATION DATE

COLLECTEDTIME

COLLECTEDSAMPLEMATRIX

COMP.OR GRAB

NO. OFCONTAINERS

ANALYSISREQUIRED

^- fe- to T- T I

Is- LA -A t>V, A -- Air- lOo F

/<*-

1 "™| l-fl . - 1 .IV." A , , . . A - f—— \

,1 *

\

1

\

VA 'i AS- e - / 20 6

Relinquished By: DATE TIME Received By: DATE TIME

Relinquished By: DATE TIME Received By: DATE TIME

-4-JTS:

DATE TIME Received by Laboratory: DATE TIME

COMMENt-5: » . ^ ^ <W-,JU Jyvix, '-F

.. 0''

-_

METHOD OF SHIPMENT:0

OBG Laboratories, Inc., an O'Brien & Gere Limited Company _ n . o n "7 C5000 Brittonfield Parkway / Suite 300 / PO Box 4942 / Syracuse, NY 13221 / (315) 437-0200 flHUUdU/3

z

Page 160: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CHAIN OF CUSTODY RECORD

LABORATORIES, INC.

SURVEY: &is ^ L^Jcf , \\

LOCATION: ' i« CcJK ?&STATIONNUMBER

>*

1 ——

SAMPLE LOCATION

Try- ra,w~

Relinquished By:

Relinquished By:

Relinquished By:ti n Jv ,.* ,

DATECOLLECTED

DATE

DATE

DATE

TIME'COLLECTED

TIME

TIME

TIME

SAMPLED BY: !K_,'r X.W /u>-- c\

ORGANIZATION^ A,,. ' '„ /» . ^J Vc?r'<^- c vrtr<~ tX.M>vi,<n>SAMPLEMATRIX

'H

COMP.OR GRAB

NO. OFCONTAINERS

(

ANALYSIS JREQUIRED

£T4 wolffeoz.

Received By: DATE TIME

Received By: DATE TIME

Received bv Laboratory: DATE TIME

COMMENTS:! \]——————^ v _ ,

-U,,

METHOD OF SHIPMENT:

OBG Laboratories, Inc., an O'Brien & Gere Limited Company /•>«-»/•5000 Brittonfield Parkway / Suite 300 / PO Box 4942 / Syracuse, NY 13221 / (315) 437-02] ) 002076

Page 161: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill ____ ____

WORK ORDER NO.: N/A__________ PROJECT NO.: 12319

DATE EXTRACTED: N/A_________ DATE ANALYZED: 11-10-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 5.00

ANALYST: J. Tobler ____ DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-l-130________ EHRT SAMPLE NO.: 29450

LAB NOTEBOOK NO.: 162, Pg. 9_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS_____ uq/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 17.426. Chloroethane 8.207. 2-Chloroethylvinyl Ether < 0.508. Chloroform 114.979. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dlchlorodifluoromethane < 0.5015. 1,1-Dichloroethane 45.1516. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene 11.8318. trans-1,2-Dichloroethene 126.7819. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

8R002077

Page 162: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-l-130________ EHRT SAMPLE NO.: 29450

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene 1.0425. 1,1,1-Trichloroethane 104.9326. 1,1,2-Trichloroethane < 0.5027. Trichloroethene 51.3428. Trichlorofluoromethane < 0.5029. Vinyl Chloride 13.9930. Benzene 1320.0031. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____100.00%

Toluene-d8 - 97.00%

Bromofluorobenzene - 103.00%

Page2 fiRQ02078

Page 163: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill _____ ____

WORK ORDER NO.: N/A__________ PROJECT NO.: 12319

DATE EXTRACTED: N/A__________ DATE ANALYZED: 11-10-90

SAMPLE TYPE: Water Sample_____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-E-130 EHRT SAMPLE NO.: 29451

LAB NOTEBOOK NO.: 162, Pg. 9_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 1.446. Chloroethane < 0.507. 2-Chloroethylvinyi Ether < 0.508. Chloroform 8.209. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 2.3016. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 7.5519. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methyiene Chloride < 1.00

Page1 fl.R002079

Page 164: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-E-130 EHRT SAMPLE NO.: 29451

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1-Trichloroethane 4.6226. 1,1,2-Trichloroethane < 0.5027. Trichloroethene 2.6428. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene 60.7531. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____96.00%

Toluene-d8 - 95.00%

Bromofluorobenzene - 98.00%

Page2 AROU2080

Page 165: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill__________________________________

WORK ORDER NO.: N/A__________ PROJECT NO.: 12319

DATE EXTRACTED: N/A__________ DATE ANALYZED: 11-10-90

SAMPLE TYPE: Water Sample_____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-l-120 EHRT SAMPLE NO.: 29452

LAB NOTEBOOK NO.: 162, Pg. 9_______ METHOD NO.: EPA 601 &602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 17.436. Chloroethane < 0.507. 2-Chloroethylvinyl Ether < 0.508. Chloroform 100.279. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 39.8216. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene 9.3518. trans-1,2-Dichloroethene 109.9719. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Paae1 8ROU208I

Page 166: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-l-120________ EHRT SAMPLE NO.: 29452

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene 1.2825. 1,1,1-Trichloroethane 98.2226. 1,1,2-Trichloroethane < 0.5027. Trichloroethene 49.5528. Trichlorofluoromethane < 0.5029. Vinyl Chloride 10.6130. Benzene 1294.0031. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

l,2-Dichloroethane-d4 - ____101.00%

Toluene-d8 - 93.00%

Bromofluorobenzene - 102.00%

COMPUTER SEARCH

Trichlorotrifluoroethane - Approx. 26 ug/L

HR002082

Page 167: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELU

SAMPLE SOURCE: Blosenski Landfill___________________

WORK ORDER NO.: N/A__________ PROJECT NO.: 12319

DATE EXTRACTED: N/A__________ DATE ANALYZED: 11-10-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-E-120_______ EHRT SAMPLE NO.: 29453

LAB NOTEBOOK NO.: 162, Pg. 9_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS_____ . ug/L

1. Bromodichloromethane < * 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 1.606. Chloroethane < 0.507. 2-Chloroethyivinyl Ether < 0.508. Chloroform 8.119. Chloromethane < 0.5010. Dibromochloromethane r < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 2.3216. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 7.6419. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

flRQ02083

Page 168: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-E-120 EHRT SAMPLE NO.: 29453

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1 -Trichloroethane 4.9126. 1,1,2-Trichloroethane < 0.5027. Trichloroethene < 0.5028. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene 65.7131. Ethyibenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____102.00%

Toluene-d8 - 89.00%

Bromofluorobenzene - 106.00%

ftR00208U

Page 169: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill __

WORK ORDER NO.: N/A__________ PROJECT NO.: 12319

DATE EXTRACTED: N/A__________ DATE ANALYZED: 11-15-90

SAMPLE TYPE: Water Sample_____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-E-120D EHRT SAMPLE NO.: 29473

LAB NOTEBOOK NO.: 162, Pg. 9_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 1.646. Chloroethane < 0.507. 2-Chloroethylvinyl Ether < 0.508. Chloroform 8.129. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 2.3316. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 7.4519. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Page1 SR002085

Page 170: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-E-120D_______ EHRT SAMPLE NO.: 29473

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1-Trichloroethane 5.5026. 1,1,2-Trichloroethane < . o.5027. Trichloroethene 2.7428. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene 68.3331. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____98.00%

Toluene-d8 - 94.00%

Bromofluorobenzene - 105.00%

Page2 SROQ2Q86

Page 171: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.SEMI-VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: . OBG LABORATORIES. INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill___________________________

WORK ORDER NO.: N/A________________ EHRT PROJECT NO.: 12319

DATE EXTRACTED: 11-12-90 _____ DATE ANALYZED: 11-13-90

SAMPLE TYPE: Water Sample__________ SAMPLE VOLUME: 1000.00

ANALYST: K. Nusekabel _____ FINAL VOLUME: 1.00

CUSTOMER SAMPLE NO.: AS-E-120 EHRT SAMPLE NO.: 29453

LAB NOTEBOOK NO.: 149. Pg. 83_____________ METHOD NO.: EPA 8270

RESULTCOMPOUNDS___________ ug/L

1. Phenol < 3.002. Bis(2-Chloroethyl)Ether . < 2.003. 2-Chlorophenol < 2.004. 1,3-Dichlorobenzene < 6.005. 1,4-Dichlorobenzene < 6.006. Benzyl Alcohol < 3.007. 1,2-Dichlorobenzene < 6.008. 2-Methylphenol < 3.009. Bis-(2-Chloroisopropyl) Ether < 4.0010. 4-Methylphend < 3.0011. N-Nitroso-Di-n-Propylamine < 4.0012. Hexachloroethane < 6.0013. Nitrobenzene < 3.0014. Isophorone < 2.0015. 2-Nitrophenol < 4.0016. 2,4-Dimethylphenol < 3.0017. Benzole Acid < 20.0018. Bis(2-Chloroethoxy)Methane < 2.0019. 2,4-Dichlorophenol < 4.0020. 1,2,4-Trichlorobenzene < 6.0021. Naphthalene < 1.0022. 4-Chloroaniline < 10.0023. Hexachlorobutadiene < 12.0024. 4-Chloro-3-Methylphenol < 3.0025. 2-Methylnaphthalene < 1.0026. Hexachlorocyclopentadiene < 12.0027. 2,4,5-Trichlorophenol < 5.0028. 2,4,6-Trichlorophenol < 5.00

Page1 flR002087

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CUSTOMER SAMPLE NO.: AS-E-120______________ EHRT SAMPLE NO.: 29453

29.30.31.

m 32.W 33.

34.35.36.37.38.39.40.41.42.43.44.45.46.47.48.49.50.51.52.

fe 53.^ B 54^ 55.

56.57.58.59.60.61.62.63.64.65.

2-Chloronaphthalene2-NitroanilineDimethylphthalateAcenaphthylene2,6-Dinitrotoluene3-NitroanilineAcenaphthene2,4-Dinrtrophenol4-N'rtrophenolDibenzofuran2,4-DinitrotolueneDiethylphthalate4-Chlorophenyl-PhenyletherRuorene4-N'rtroaniIine4,6-Dinitro-2-MethylphenolN-Nitrosodiphenylamine4-Bromophenyl-PhenyletherHexachlorobenzenePentachlorophendPhenanthreneAnthraceneDi-n-ButyphthalateRuoranthene .PyreneButyl benzylphthalate3,3'-DichlorobenzidineBenzo(a)AnthraceneChryseneBis(2-Ethylhexyl)PhthalateDi-n-OctylphthalateBenzo(b) RuorantheneBenzo(k) RuorantheneBenzo(a) Pyrenelndeno(1 ,2,3-cd) PyreneDibenzo(a,h)AnthraceneBenzo(g,h,i)Perylene

SURROGATE COMPOUND

Nitrobenzene-d52-RuorobiphenylTerphenyl-d14

Phenol-d52-Ruorophenol2,4,6-Tribromophenol

< 3.00< 10.00< 3.00< 2.00< 6.00< 10.00< 2.00< 40.00< 20.00< 6.00< 6.00< 2.00< 6.00< 3.00< 20.00< 20.00< 3.00< 6.00< 5.00< 20.00< 2.00< 2.00< 1.00< 2.00< 2.00< 3.00< 10.00< 3.00< 3.00< 2.00< 2.00< 10.00< 10.00< 6.00< 10.00< 10.00< 10.00

PERCENT RECOVERY

68.50%58.70%56.00%

10.00% *10.00% *13.80%

* A recovery lower than 10% was obtained on surrogates due to heavy emulsion.

Page2 AR002088

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.PESTICIDES - PCB ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill_________________________

WORK ORKER NO.: N/A_____________ EHRT PROJECT NO.: 12319

DATE EXTRACTED: 11-13-90 DATE ANALYZED: 11-13-90

SAMPLE TYPE: Water Sample_______ METHOD NO.: EPA 608 .

ANALYST: M. Cooper__________ LAB NOTEBOOK NO.: 158, Pg. 56

CUSTOMER SAMPLE NO.: AS-E-120 EHRT SAMPLE NO.: 29453

RESULTCOMPOUNDS ug/L

1. Alpha-BHC < 0.00142. Beta-BHC < 0.00083. Delta-BHC < 0.00064. Gamma-BHC < 0.00065. Heptachlor < 0.00206. Aldrin < 0.00167. Heptachlor Epoxide < 0.00148. Endosulfan I < 0.00089. Dieldrin < 0.000410. 4,4'-DDE < 0.000411. Endrin < 0.000612. Endosulfan II < 0.0213. 4,4'-DDD < 0.0214. Endosulfan Sulfate < 0.000415. 4,4'-DDT < 0.001216. Methoxychlor < 0.000417. Endrin Ketone < 0.0418. Chlordane < 0.2019. Toxaphene < 3.00

Pagel 3R002089

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CUSTOMER SAMPLE NO.: AS-E-120___________ EHRT SAMPLE NO.: 29453

20. Aroclor-1016 < 0.5021. Aroclor-1221 < 0.5022. Aroclor-1232 < 0.5023. Aroclor-1242 < 0.5024. Aroclor-1248 '< 0.5025. Aroclor-1254 < 0.5026. Aroclor-1260 < 0.50

SURROGATE RECOVERY

Dibutylchlorendate - ____65.30%

Page2 ARQQ209Q

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U.S. EPfl - CLP

COVER PflGE - INORGANIC ANALYSES DATA PACKAGE

Lab Name: ENVIR. HEALTH RESEARCH TE Contract: OBG____

Lab Code: W88__ Case No.: BLQSE SAS No.: 1£319_ SDG No. : 000000

SOW No.: ___

EPA Sample No. Lab Sample ID.ASE120 29453___

Were ICP interelement corrections applied ? Yes/No YES

Were ICP background corrections applied ? Yes/No YESIf yes - were raw data generated beforeapplication of background corrections ? Yes/No N0_

Comments:OBGJ.ABO RATORIES_-_BLOSENSKIJ.ANDFILL_DATE_OF_ANALYSIS_l1/1£/90____ICP_G.STflKE_NB15S_PG46_METHOD_6010/_FURNflCE_P.BflRNWELL_NB154_PG63____METHOD flS7060 SE7740/ COLD VflPOR J.RftDER NB157 PGS3 METHOD 7470_____

Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on floppy diskette has been authorized bythe Laboratory Manager or the Manager's designee, as verified by thefollowing signature.

Lab Manager:

Date:COVER PAGE - IN ' ' 7/87

SR00209I

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U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET ______________

II ASE120

Lab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: OBG_____ I___________,

Lab Code: W88__ Case No.: BLOSE SAS No.: 12319_ SDG No. : 000000

Matrix (soil/water): WATER Lab Sample ID: 29453___

Level (low/med): _____ Date Received: 11/39/90

'/. Solids: ___

Concentration Units (ug/L or mg/kg dry weight): U6/L_

1ICAS No.11 7429-90-517440-36-01 7440-38-21 7440-39-317440-41-71 7440-43-91 7440-70-21 7440-47-31 7440-48-41 7448-50-81 7439-89-617439-92-11 7439-95-41 7439-96-51 7439-97-61 7440-02-01 7440-09-71 7782-49-21 7440-22-41 7440-23-51 7440-28-0I 7440-62-21 7440-66-611

1 11 Ana 1 y t e 1 Concent rat i oni 11 Aluminum_!Antimony_l1 Arsenic

10.72.2

1 Barium 11 BerylliumI Cadmium1 Calcium _IChromium_1 Cobalt1 Copper1 IronILead(Magnesium1 Manganese1 MercuryINickel1 Potassium(SeleniumISilverI Sod i urnIThallium_! Vanad i um_1 Zinc1 CyanideI

0.401.8

1 1ICI QI 11 IIUIIUI1 1IU!I U I

1 1IM 11 IINRI

. IP 1IF 1INRIIP 1IP 1

1 1 - INRI5.3

5.0

I U I1 1IUI

IP 1INRIIP 1

I I INRI10.9

0.14.6

IUI1 i1 IIUIIUI

IP fINR!INRIICVIIP I

I I INRI2.11.9

IU!IUI

IF IIP I

I I INR!95.5 IUI IP 1

1 ! INRI2.4 IUI IP 1

I I INRII I I I

Color Before: _________ Clarity Before: ____ Texture:

Color After: _________ Clarity After: ____ Artifacts:

Comments:

AS--E-120

FORM I - IN 7/87

flR002092

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U.S. EPA - CLP

2AINITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: DBS.

Lab Code: W8S__ Case No.: BLOSE SAS No.: 12319_ SDG No.: 000000

Initial Calibration Source: SPEX______

Continuing Calibration Source: SPEX______

Concentration Units: ug/L

i 11 1lAnalyte !1 11 Alurninum_l1 Antimony 1(Arsenic 11 Bar i urn 11 Beryl liuml'1 Cadmium 11 Calcium 11 Chromium 11 Cobalt 1! Copper 11 Iron 11 Lead 11 Magnesium I1 Manganese 11 Mercury 1INickel 11 Pot ass i urn 1ISeleniuni_l1 Silver 11 Sod i urn1 Thallium 11 Vanad i urnIZinc 11 Cyanide

1Initial Calibration 1

True Found XRCl) 11

1500.0 I50.0 I

1500.0 1

500.0 i1

__500. 0_l

1500.0 1

1500.0 i

11

5.0 1500.0 1

110.0 1

100.0 11

1000.0 11

500.0 I1

1 1507.501101.5147.901 95.81

1 - 1476.301 95.3!490. 40 1 98. 1 1

1 1_ 549.001109.81

1 1489.001 97.81

1 1483.201 96.61

1 11 1

5.481109.6!490.701 98.11

1 110.501105.0197. 101 97.11

1 i946.501 94.61

1 1494.901 99.01

1 1

i 1Continuing Calibration 1 1

True Found jtR(l) Found %R(1) 1 1 MI 1

1500.0 I50.0 I

1500.0 I

500.0 I1

__ 500. 0_l_~r500.0 1

1

500.0 1

11

5.0 1500.0 1

120.0 1100.0 1

1

1000.0 11

500.0 11

1 1508.301101.7149.801 99.61

I I471.801 94.41483.601 96.71

1 1548.701109.71

1 1479.801 96.01

1 1478.401 95.71

I 11 I

5.301106.01483.201 96.61

I 119.901 99.5196.701 96.71

1961.901 96.2

1493.701 98.7

1

1 I INR1 1 IP1 I IF1 1 INR1 1 IP1 1 IP1 I I N R I1 1 IP1 I l N R !1 1 IPi I INRI1 i IP1 MNRI1 1 INR1 1 ICV1 1 IP1 1 INR1 1 IFI 1 IP1 1 INR1 1 IP1 I INR1 1 IP1 1 INR

1 1 1 I I i ! I l l

(1) Control Limits: Mercury 80-1235 Other Metals 90-113! Cyanide 85-115

FORM II (PART 1) - IN 7/87.

SR002093

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U.S. EPA - CLP

2AINITIAL AND CONTINUING CALIBRATION VERIFICATION

Lab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: OBG_

Lab Code: W88__ Case No.: BLOSE SflS No.: 12319_ SDS No. : 000303

Initial Calibration Source: SPEX_____

Continuing Calibration Source: SPEX_____

Concentration Units: ug/L

1 1lAnalyte 1I I1 Aluminum 11 Antimony_l1 Arsenic 11 Barium 11 Beryl liuml(Cadmium I(Calcium 11 Chromium 11 Cobalt i! Copper 11 Iron 1I Lead 11 Magnesium!1 Manganese 11 Mercury 1INickel 11 Pot ass i urn 1(Selenium 11 Silver 11 Sod i urn 1I Thai Hum 11 Vanad i urn 1IZinc 11 Cyanide 11 1

InitTrue

12000.0

1000. 0_1000. 0

2030. 3

5000. 0

630.3

8303. 0

2303. 3

2000. 0

4000. 3

ial CalibrationFound *R<1)I

I I I111763.331 98.3I 1 !1 11 988.001 98.81

True

112038.3 !

11

1000.8 IJ _1026. 00 1 102. 6 1 _1000. 0_l

1 1 l~~ 11 1919.301 96.31 2833.3 11 1 I I1 5299.031106.0! 5003.0 1! 1 f 11 581.501 96.91 633.3 I1 1 11 11 11 7847. 33 1 98. 11 11 11 1978.30! 98.9i 11 2065.301103.21 11 4135.031103.4i 11 1

111

8000.0 I11

2808.0 11

2000.0 i1 14000.0 1

1

1

Continuing Calibration 1Found *R(1) Found %R(1) 1 Ml

1 11 1 1

12173.001181.41 11 1

INRIIP I

I IINRI1 1 1

1017.001101.71 I1074.001107.41 1

1 11971.301 98.61 1

I I 15364.831187.31 I

.1 1 1609.901101.61 1

111

8890.081181.111

2026.081101.3I

2118.001135.9.I

4255.031106.4

111I1111111

1 1 I1 I 1

INRIPJIP-INRIIPINRIIP-INRIIP 1INRIINRINRIIP 1INRIINRIIP IINRIPINRIPINR1

(1) Control Limits: Mercury 80-120! Other Metals 98-118! Cyanide 85-115

FORM II (PART 1) - IN 7/87

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U.S. EPA - CLP

3BLANKS

Lab Name: ENVIR. _HEALTH_RESEARCH_TE Contract: OBG.

Lab Code: W88__ Case No.: BLOSE SAS No.: 12319_ SDG No. : 888888

Preparation Blank Matrix (soil/water): WATER

Preparation Blank Concentration Units (ug/L or rng/kg): UG/L_

1 11 1 Initial1 1 Calib.1 I BlanklAnalyte I (ug/L)1 11 Aluminum 11 Antimony !1 Arsenic 11 Barium 11 Beryllium I1 Cadmium 11 Ca 1 c i urn 1I Chromium 11 Cobalt 11 Copper 11 Iron 11 Lead 11 Magnesium!1 Manganese 11 Mercury I(Nickel 11 Potassium!(Selenium 1(Silver 11 Sod i urn 11 Thallium 1

13.72.2

0.41.8

5.3

5.0

10.9

0.14.6

2.11.9

95.5

1111

Cl1

1 1IUIIUI1 1IUIIUI1 IIUI1 1IUI1 11 11 i1 IIU!IUI1 1IUIIUI1 Ii 1

I

Continuing CalibrationBlank (ug/L)

1 C 2 C 3 C

10.72.2

8.41.8

5.3

5.8

10.9

0. 14.6

2. 11.9

95.5

1 i I I 1I U I I I 1I U I I I 11 1 I I iIU! 1 1 ' 1IUI I _! 1I I I I * IIUI ! I I1 1 I I 1IBI 1 1 • 11 I I I 1I I I I I1 I I I II I I I 1iUI 1 I IIU! 1 I 1I I I I II U I I I 1I U I I I II I I I I1 1 I I 1

1 Vanadium 1 I I I I I I 1IZinc 11 Cyanide 11 1

2.4 IUI1 1I I

2.4 IUI i I 1I I 1 I 11 I I I i

Prepa-rationBlank C

I

I

_____ _ INR10.708IUI IP__2.208IUIIF____ I IlNR_0.488IUI IP_.1.8881 UI IP_

I I INR5. 3801UI I P_____I IlNR5.010IBI IP_____I Il N R10. 9831 _l IP_~_____l_l INR.__ i MNR"0.183IU!ICV4.633IUI IP_____I IlNR_2. 140IUI IF_J..988IUI IP_

I I l N R_95.580I_I IP______! IlN R_2. 480IUI IP_

I I INR

FORM III - IN 7/87

3ROG2Q95

Page 180: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELU

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A__________ PROJECT NO.: 12319

DATE EXTRACTED: N/A_______________ DATE ANALYZED: 11-10-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 5.00

ANALYST: J. Tobler___________ DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-l-100 EHRT SAMPLE NO.: 29454

LAB NOTEBOOK NO.: 162. Pg. 9_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 16.356. Chloroethane < 0.507. 2-Chloroethylvinyl Ether < 0.508. Chloroform 86.639. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 32.2516. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene 6.4018. trans-1,2-Dichloroethene 93.1919. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Page1 SR002096

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CUSTOMER SAMPLE NO.: AS-l-100________ EHRT SAMPLE NO.: 29454

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025, 1,1,1-Trichloroethane 86.5826. 1,1,2-Trichloroethane < . 0.5027. Trichloroethene 47.6928. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene 1261.0031. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____96.40%

Toluene-d8 - 87.00%

Bromofluorobenzene - 109.00%

3RG02097

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill____________________

WORK ORDER NO.: N/A__________ PROJECT NO.: 12319

DATE EXTRACTED: N/A__________ DATE ANALYZED: 11-14-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-E-100 ___ ___ EHRT SAMPLE NO.: 29455

LAB NOTEBOOK NO.: 162. Pg. 9_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 1.876. Chloroethane < 0.507. 2-Chioroethylvinyl Ether < 0.508. Chloroform 9.889. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 3.1316. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 10.2219. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

flR002098

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CUSTOMER SAMPLE NO.: AS-E-100_______ EHRT SAMPLE NO.: 29455

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1-Trichloroethane 5.4126. 1,1,2-Trichloroethane < 0.5027. Trichloroethene < 0.5028. Trichlorofluoromethane . < 0.5029. Vinyl Chloride < 0.5030. Benzene 74.0831. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____97.00%

Toluene-d8 - ____100.00%

Bromofluorobenzene - 102.00%

Page2 3ROG2099

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES. INC. - MR. MIKE PETTERELU

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A__________ PROJECT NO.: 12319

DATE EXTRACTED: N/A • _______ DATE ANALYZED: 11-15-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 0.50

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-l-90 EHRT SAMPLE NO.: 29456

LAB NOTEBOOK NO.: 162. Pg. 9_______ METHOD NO.: EPA 601 &602

RESULTCOMPOUNDS____ ug/L

1. Bromodlchloromethane < 5.002. Bromoform < 5.003. Bromomethane < 5.004. Carbon Tetrachloride < 5.005. Chlorobenzene 17.206. Chloroethane < 5.007. 2-Chloroethylvinyl Ether < 5.008. Chloroform 98.109. Chloromethane < 5.0010. Dibromochloromethane < 5.0011. 1,2-Dichlorobenzene < 5.0012. 1,3-Dichlorobenzene < 5.0013. 1,4-Dichlorobenzene < 5.0014. Dichlorodifluoromethane < 5.0015. 1,1 -Dichloroethane 37.4016. 1,2-Dichloroethane < 5.0017. 1,1-Dichloroethene 9.5018. trans-1,2-Dichloroethene 110.2019. 1,2-Dichloropropane < 5.0020. cis-1,3-Dichloropropene < 5.0021. trans-1,3-Dichloropropene < 5.0022. Methylene Chloride < 10.00

SR002IOO

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CUSTOMER SAMPLE NO.: AS-l-90________ EHRT SAMPLE NO.: 29456

23. 1,1,2,2-Tetrachloroethane < 5.0024. Tetrachloroethene < 5.0025. 1,1,1-Trichloroethane 131.4026. 1,1,2-Trichloroethane < 5.0027. Trichloroethene 55.5028. Trichlorofluoromethane < 5.0029. Vinyl Chloride < 5.0030. Benzene 1201.1031. Ethylbenzene < 5.0032. Toluene < 5.00

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____100.00%

Tduene-d8 - 88.00%

Bromofluorobenzene - 106.00%

Page2 3R002IOI

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ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill_________________________

WORK ORDER NO.: N/A__________ PROJECT NO.: 12319

DATE EXTRACTED: N/A__________ DATE ANALYZED: 11-14-90

SAMPLE TYPE: Water Sample SAMPLE VOLUME: 5.00

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-E-90 EHRT SAMPLE NO.: 29457

LAB NOTEBOOK NO.: 162, Pg. 9_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 1.966. Chloroethane < . 0.507. 2-Chloroethylvinyl Ether < 0.508. Chloroform 9.629. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodifluoromethane < 0.5015. 1,1-Dichloroethane 3.1216. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 9.7419. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Pagel 3RG02I02

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CUSTOMER SAMPLE NO.: AS-E-90________ EHRT SAMPLE NO.: 29457

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1-Trichloroethane 6.1326. 1,1,2-Trichloroethane < 0.5027. Trichloroethene 3.1128. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene 81.5031. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____96.00%

Toluene-d8 - 99.00%

Bromofluorobenzene - 104.00%

Page2 3ROQ2I03

Page 188: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELU

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A_____________ PROJECT NO.: 12319

DATE EXTRACTED: N/A___________ DATE ANALYZED: 11-15-90

SAMPLE TYPE: Water Sample____ SAMPLE VOLUME: 0.50

ANALYST: J.Tobler DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-l-80 EHRT SAMPLE NO.: 29458

LAB NOTEBOOK NO.: 162. Pg. 9_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS ug/L

1. Bromodichloromethane < 5.002. Bromoform < 5.003. Bromomethane < 5.004. Carbon Tetrachloride < 5.005. Chlorobenzene 17.206. Chloroethane < 5.007. 2-Chloroethylvinyl Ether < 5.008. Chloroform 95.209. Chloromethane < 5.0010. Dibromochloromethane < 5.0011. 1,2-Dichlorobenzene < 5.0012. 1,3-Dichlorobenzene < 5.0013. 1,4-Dichlorobenzene < 5.0014. Dichlorodifluoromethane < 5.0015. 1,1-Dichloroethane 36.2016. 1,2-Dichloroethane < 5.0017. 1,1-Dichloroethene < 5.0018. trans-1,2-Dichloroethene 106.6019. 1,2-Dichloropropane < 5.0020. cis-1,3-Dichloropropene < 5.0021. trans-1,3-Dichloropropene < 5.0022. Methylene Chloride < 10.00

Page 189: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-l-80 ___ EHRT SAMPLE NO.: 29458

23. 1,1,2,2-Tetrachloroethane < 5.0024. Tetrachloroethene < 5.0025. 1,1,1-Trichloroethane 124.3026. 1,1,2-Trichloroethane < 5.0027. Trichloroethene 59.1028. Trichlorofluoromethane < 5.0029. Vinyl Chloride < 5.0030. Benzene 1267.8031. Ethylbenzene < 5.0032. Toluene < 5.00

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____102.00%

Toluene-d8 - ____85.00%

Bromofluorobenzene - 110.00%

Page2 fl R 0 0 2 I 0 5

Page 190: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.VOLATILE ORGANIC ANALYSIS

CUSTOMER NAME: OBG LABORATORIES, INC. • MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill_________

WORK ORDER NO.: N/A______________ PROJECT NO.: 12319

DATE EXTRACTED: N/A___________ DATE ANALYZED: 11-14-90

SAMPLE TYPE: Water Sample_____ SAMPLE VOLUME: 5.00

ANALYST: J. ToWer DILUTION FACTOR: 1.00

CUSTOMER SAMPLE NO.: AS-E-80________ EHRT SAMPLE NO.: 29459

LAB NOTEBOOK NO.: 162. Pg. 9_______ METHOD NO.: EPA 601 & 602

RESULTCOMPOUNDS____ ug/L

1. Bromodichloromethane < 0.502. Bromoform < 0.503. Bromomethane < 0.504. Carbon Tetrachloride < 0.505. Chlorobenzene 2.436. Chloroethane < 0.507. 2-Chloroethylvinyl Ether < 0.508. Chloroform 12.069. Chloromethane < 0.5010. Dibromochloromethane < 0.5011. 1,2-Dichlorobenzene < 0.5012. 1,3-Dichlorobenzene < 0.5013. 1,4-Dichlorobenzene < 0.5014. Dichlorodrfluoromethane < 0.5015. 1,1-Dichloroethane 3.6316. 1,2-Dichloroethane < 0.5017. 1,1-Dichloroethene < 0.5018. trans-1,2-Dichloroethene 12.2219. 1,2-Dichloropropane < 0.5020. cis-1,3-Dichloropropene < 0.5021. trans-1,3-Dichloropropene < 0.5022. Methylene Chloride < 1.00

Pagel flRQQ2iQ6

Page 191: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

CUSTOMER SAMPLE NO.: AS-E-80________ EHRT SAMPLE NO.: 29459

23. 1,1,2,2-Tetrachloroethane < 0.5024. Tetrachloroethene < 0.5025. 1,1,1-Trichloroethane 6.2926. 1,1,2-Trichloroethane < • 0.5027. Trichloroethene 3.6328. Trichlorofluoromethane < 0.5029. Vinyl Chloride < 0.5030. Benzene 94.5331. Ethylbenzene < 0.5032. Toluene < 0.50

SURROGATE STANDARDS - % RECOVERIES

1,2-Dichloroethane-d4 - ____98.00%

Toluene-d8 - 98.00%

Bromofluorobenzene - 106.00%

Page2 QROQ2IQ7

Page 192: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

SOIL PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lao Name: ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC._______

stomer Name: OBG LABORATORIES, INC. - MR. PETTERELLI________________

Method No.: EPA 601 & 602______ Project No.: 12319

oustomer Sample No.: AS-E-80_________ EHRT No.: 29459

COMPOUND-Dichloroethene

'i nchloroetheneRonzene

ueneunlorobenzene

AMOUNT ADDED(ng)250250250250250

SAMPLE CONC.(ug/L)03.69502.4

MS CONC.(ug/L)49.762.215654.258.2

MS%REC#99117122108112

QC LIMITSREC.59-17262-13766-14259-13960-133

^RuND1,1-DichloroetheneT-' hloroethene

nzeneToluene'orobenzene

MSD CONC.(ug/L)49.261.1153.154.557.1

MSD%REC#98115116109109

MS%REC#99117122108112

%RPD#

1250.13

QCURPD2224212121

WITSREC.59-17262-13766-14259-13960-133

-"• Column to be used to flag recovery and RPD values with an asterick

* Values outside of QC limits

RPD: _____0_____ out of ___5___ outside limitsSpike Recovery:_____0_____ out of 10 outside limits

'MMENTS:

Pagel

Page 193: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE;

WORK ORDER NO.:

ANALYSIS PERFORMED:

ANALYSIS METHOD:

ANALYST:

Blosenski Landfill

N/A

5-Day BOD Analysis

EPA 405.1

G. Stake

SAMPLE NO.EHRT NO. CUSTOMER NO.

29458 AS-l-80

29459 AS-E-80

PROJECT NO.: 12319

DATE ANALYZED: 1 1 /09-1 4/90

LAB NOTEBOOK NO. : 161,

RESULTSmg/L

BDL

BDL

Pg.6

DETECTION LIMIT: < 2 mg/L

Pagel flRQ02l

Page 194: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELU

SAMPLE SOURCE:

WORK ORDER NO.:

ANALYSIS PERFORMED:

ANALYSIS METHOD:

ANALYST:

Blosenski Landfill

N/A

COD Analysis

EPA 41 0.4

M. Reddy

SAMPLE NO.EHRT NO. CUSTOMER NO.

29458 AS-l-80

29459 AS-E-80

PROJECT NO.: 12319

DATE ANALYZED: 11-09-90

LAB NOTEBOOK NO.: 151, Pg. 25

RESULTSmg/L

94.43

77.55

DETECTION LIMIT: < 40 mg/L

,£JR002MO

Page 195: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: OBG LABORATORIES. INC. • MR. MIKE PETTERELLI

SAMPLE SOURCE:

WORK ORDER NO.:

ANALYSIS PERFORMED:

ANALYSIS METHOD:

ANALYST:

Blosenski Landfill

N/A PROJECT NO.:

Total Suspended Solids Analysis

Std. Method 209C DATE ANALYZED

M. Reddy LAB NOTEBOOK

SAMPLE NO.EHRT NO. CUSTOMER NO.

29458 AS-l-80

29459 AS-E-80

12319

: 11-12-90

NO.: 137, Pg.61

RESULTSmg/L

BDL

BDL

DETECTION LIMIT: < 10 mg/L

flR002il|

Page 196: P're Design Report · Inc., an O'Brien & Gere Limited Company H B U ^ ' ^ 5000 Brittorr.s.c Parkway / PO Box 4873 / Syracuse, NY 13221 / (315) 437-6100 FAX (315} 463-7554 October

ENVIRONMENTAL HEALTH RESEARCH AND TESTING, INC.RESULT SHEET

CUSTOMER NAME: OBG LABORATORIES, INC. - MR. MIKE PETTERELLI

SAMPLE SOURCE: Blosenski Landfill

WORK ORDER NO.: N/A PROJECT NO.: 12319

ANALYSIS PERFORMED: TOC Analysis

ANALYSIS METHOD: EPA 9060

ANALYST: G. Luna

DATE ANALYZED: 1 1 -09-90

LAB NOTEBOOK NO.: 135, Pg. 1 7

SAMPLE NO.EHRT NO. CUSTOMER NO.

29458A AS-l-80

29458B AS-l-80(Duplicate)

29459 AS-E-80

RESULTSmg/L

15.40

12.80

< 10 mg/L

DETECTION LIMIT: < 10 mg/L

flR002M2