nitrogen scheme is changing

2
ï f MARKETS December 195S estimated, were about like this: Amtiioniztin Siufais Su 1958 Coke Ovens Syn- thetic Imports Nitrogen Scheme Is Changing Ammonium sulfate giving ground fo solutions, but gaining as top dressing; exports rising COKE OVEN ammonium sulfate, once the backbone of U. S. agricultural ni- trogen supply, last year slipped to the * . . . «. ι i_ ~z lOQO «£• Ι-ΚΛ JOWeSI. OUtpUl lervcu:» axucc A * / ^ ^ «.«.O *-»»*. result of curtailed coking operations in the steel industry. Steel operations dropped to as low as 4 8 % of capacity in April, recover- ing to 73% at year's end. Currently die rate is around 83.5%. As a nitrogen fertilizer material, am- monium sulfate (21% N) is slowly yielding ground to other nitrogen prod- ucts of higher analysis, especially ni- trogen solutions. Synthetic ammonium sulfate output was stepped up in 1958 but not enough to compensate for production losses at the coke ovens. The outputs, based on data supplied by the Bureau of Mines and the Bureau of the Census, with 640,000 1,100,000 140,000 (Est.) 1957 910,000 1,070,000 120,000 • Exports Heavy. Exports assume an important volume in ammonium sul- fate. It is estimated in the trade that the greater part of the synthetic pro- duced in 1957 and 1958 was exported. A good share of t h e coke oven sulfate in 1957 was also sent abroad, but out- puts from this source in 1958 provided little surplus for this purpose. Due in a measure to inroads by ni- trogen solutions, direct appKcatio*n of ammonium sulfate to crops ESS slipping, says Chester Edwards of Niteogen Products. On the other Iiaed» jfcs use as top dressing «material is Sncreatsing.. Direct application of siiîfaîae remains quite large in California, The changing nitrogen picture flavor- ing higher analysis materials is sliown in another way by the Depsart!ne*st €»f Agriculture^ summary of ct»eniicad ni- trogen materials «consumed «during; the fertilizer year ended last Juane (MS57- 1958). tTjjj. »jk«; «^««Λ*^! the coiissHnotsoQ of all chemical nitrogen materials for «di- rect application amounted tea 3.BM mil- lion tons, an increase of 1S5,€(HB t o n s over die 1956-1957 period. This report does not cower tfcue en- tire nitrogen consunipuon «niclurae but it contains some pertinent details- Use of ammonium sulfate increased S7,(J0O tons to 573,000 tons, but imitrogtsn so- lutions gained 71,000 tons to 3E7,O00 tons- Anhydrous ammonia* consump- tion expanded 124,000 tons to a. total of 577,000 tons, and this pmobably will surprise no one- Anln/dirmis novw ac- counts for some 15S& of atîl cli*onïeal nitrogen materials used in agricnalture- • Percentage Uses. Heme's th*e p e r - centage breakdown for 185*7-58= Product fesrCent Anhydrous ammonia 15-0 Ammonium nitrate 2S-S Aqua ammonia 1£-® Ammonium sulfate 15-0 Nitrogen solutions 8-0 Sodium nitrate 11-0 Other »-β Total aOO-0 The small p°*-centage for usrea J»>es not show its much greater user in soiutsons «^^3 Ajkor fertilizer fonQ?^ ÂSiso. îite sodium nitrate figures re^resemt Both Chilean and U- S. products. In its Chemical Eeon&mfcs News- letter for January, Stanfcwrd Research Institute says that fertilizer usses con- tinue to take an increasing sliare of to- tal ammonia production. The? r i s e is primarily through direct application and in the form of nitrate and s*ii*»te- And while industrial omtiets for an- hydrous ammonia are decreasing in per- centage of the market, dbey are con- tinuing their gradual expsansioio, aided bv die ûicreasin 0 " aecep!b?incc of am- monium nitrate as an explosive and use of ammonia in bisulfilte pulping of wood. 32 C&EN FEB. 2 3. 1959 More Use Made of Chemical Nitrogen Materials Selumu^^i'SU^^ %-ïïisibxmiJ} àsusu^ '•ïÏÏBJU:^&t)&$32gZ

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Page 1: Nitrogen Scheme Is Changing

ï f MARKETS

December 195S estimated, w e r e abou t like this:

Amtiioniztin Siufais Su 1958

Coke Ovens

Syn­thet ic

Imports

Nitrogen Scheme Is Changing Ammonium sulfate giving ground fo solutions, but gaining as top dressing; exports rising

C O K E OVEN ammonium sulfate, once

the backbone of U. S. agricultural ni­trogen supply, last year slipped to the * . . . «. ι i_ ~z l O Q O «£• Ι -ΚΛ JOWeSI. O U t p U l lervcu:» a x u c c A * / ^ ^ «.«.O *-»»*. result of curtailed coking operations in the steel industry.

Steel operations dropped to as low as 4 8 % of capacity in April, recover­ing to 7 3 % at year 's end. Currently die rate is around 8 3 . 5 % .

As a nitrogen fertilizer material, am­monium sulfate ( 2 1 % N ) is slowly yielding ground to other nitrogen prod­ucts of higher analysis, especially ni­trogen solutions.

Synthetic ammonium sulfate output was s tepped up in 1958 but not enough to compensate for production losses at the coke ovens. The outputs, based on data supplied b y the Bureau of Mines and the Bureau of the Census, with

640,000

1,100,000 140,000 (Est.)

1957

910 ,000

1,070,000 120,000

• Exports H e a v y . Exports assume an important vo lume in ammonium sul­fate. I t is es t imated in the t rade tha t the greater pa r t of the synthetic pro­duced in 1957 and 1958 was exported. A good share of t h e coke oven sulfate in 1957 was also sent abroad, b u t out­puts from this source in 1958 provided little surplus for th i s purpose.

D u e in a measure to inroads by ni­

trogen solutions, d i rec t appKcatio*n o f ammonium sulfate to crops ESS slipping, says Chester E d w a r d s of Niteogen Products . On t h e other Iiaed» jfcs u s e as t o p dressing «material is Sncreatsing.. Direct application of siiîfaîae remains qu i t e large in California,

T h e changing ni trogen picture flavor­ing higher analysis materials is s l iown in another way b y t h e Depsart!ne*st €»f Agricul ture^ s u m m a r y of ct»eniicad n i ­trogen materials «consumed «during; t h e fertilizer year ended last Juane (MS57-1958) .

tTjjj. »jk«; «^««Λ*^! t he coiissHnotsoQ of all chemical nitrogen materials for «di­rect application amounted tea 3.BM mil­lion tons, an increase of 1S5,€(HB tons over die 1956-1957 period.

This report does not cower tfcue e n ­tire nitrogen consunipuon «niclurae b u t it contains some pert inent details- Use of ammonium sulfate increased S7,(J0O tons to 573,000 tons, but imitrogtsn so ­lutions gained 71 ,000 tons to 3E7,O00 tons- Anhydrous ammonia* consump­tion expanded 124,000 tons to a . total of 577,000 tons, a n d this pmobably will surprise no one- Anln/dirmis novw a c ­counts for some 15S& of atîl cli*onïeal nitrogen materials used in agricnalture-

• Pe rcen tage Uses . Heme's th*e p e r ­centage breakdown for 185*7-58=

Product fesrCent Anhydrous ammon ia 15-0 Ammonium ni t ra te 2S-S Aqua ammonia 1£-® Ammonium sulfate 15-0 Nitrogen solutions 8-0 Sodium nitrate 11-0

Other »-β Total aOO-0

T h e small p°*-centage for usrea J»>es not show its much greater user in soiutsons «^^3 Ajkor fertilizer fonQ?^ ÂSiso. îite sodium nitrate figures re^resemt Both Chilean and U- S. products .

In its Chemical Eeon&mfcs News­letter for January , Stanfcwrd Research Insti tute says t h a t fertilizer usses con­tinue t o take a n increasing sliare of to­tal ammonia production. The? rise is primarily through direct application and in the form of nitrate and s*ii*»te-

And while industrial omtiets for an­hydrous ammonia a re decreasing in per­centage of the market, dbey a r e con­tinuing their g radua l expsansioio, a i d e d b v d ie ûicreasin0" aecep!b?incc of am­monium ni t ra te as an explosive and use of ammonia in bisulfilte pulping of wood.

3 2 C & E N FEB. 2 3. 1 9 5 9

More Use Made of Chemical Nitrogen Materials

Selumu^^i'SU^^

%-ïïisibxmiJ} àsusu^ '•ïÏÏBJU:^&t)&$32gZ

Page 2: Nitrogen Scheme Is Changing

^ WEEK'S PRICE ψ CHANGES

February 16. 1959

B o a e m o L «torn., t o n XM«MUiiè, €*£ . !

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PAS Meets Competition T e m p o r a r y p r i c e reduct ions h a v e

b e e n e f f e c t e d b y S u m n e r Chemica l , M e w York, In « -aminosa l i cy l i c ac id . S u m n e r , a d i v i s i o n of Mi le s Labora­tories , m a d e t h e m o v e to m e e t import c o m p e t i t i o n .

S o d i u m p-aminosa l i cy la te , USP^ is n o w q u o t e d at $ 1 . 9 0 per p o u n d ; p -aminosa l i cy l i c a c i d , U S P , is S3 .40 ; a n d calc iuni p-aminosal icy late , U S P , § 3 . 1 0 p e r p o u n d . T h e prices a p p l y to iTîiïimiiirri orders o f 1 0 0 pounds .

*> C o m m e r c i a l S o l v e n t s . N e w Yorlc. i s s u e d a n e w s c h e d u l e s h o w i n g price r e d u c t i o n s for d i b u t y ! phtha ia i e . N e w t a n k c a r b a s e is £G cents per p o u n d , E a s t . N e w s c h e d u l e s w e r e also i s sued o n £ -n i t ropropane , n i t romethane , nitro-e t h a n e , I -n i tropropane , anhydrous a m ­m o n i a , b u t y l a l coho l , b u t y l ace ta te , e t h y l a c e t a t e , a m y ! acetaute, a c e t o n e , a n d S B A N o . 4 0 a lcohol .

*> W . R- G r a c e , c h e m i c a l d iv is ion, M e m p h i s , T e n n . , issued a n e w price s c h e d u l e for urea quot ing prills of 4 6 % Ν ( tree - f lowing b e a d s ) a t S I 15 per shor t t o n , freight e q u a l i z e d , carloads or truc îdoads , f .o .b . Woods tock , T e n n . W h i t e crystal l ine so l id u r e a is q u o t e d o n t h e s a m e basis , and b o t h produc t s are s h i p p e d Li 1 0 0 - p o u n d mul t iwa l l p a p e r b a g s w i t h moisture barrier.

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