new method for making po eliminates undesirable side products

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appliances, groceries packaging, and in the automotive sector. The two companies have formed a research deal for the preparation of new catalyst systems for manufacturing OBCs. Mitsui said the new co-polymer offers improved flexibility and rubber elasticity in a temperature range from –60° to more than 100°C. Mitsui’s single-site catalysis technique will be employed in the project. ICIS Chemical Business, 3 Jul 2006 (Website: http://icischemicalbusiness.com) & Japan Chemical Week, 29 Jun 2006, 47 (2373), 12 & Press release from: Mitsui Chemicals Inc, Shiodoma City Center, 1-5-2 Higashi-Shimbashi, Minato-ku, Tokyo 105-7117, Japan. Website: http://www.mitsui-chem.co.jp/e/ (21 Jun 2006) Dow launches olefin block copolymers developed with Insite technology Dow is launching its Infuse range of olefin block copolymers (OBC) onto the olefin elastomers market. These combine the flexibility of polyolefin elastomers and plastomers with the heat resistance of HDPE. A novel catalyst system allowed the production of the copolymers which have alternating rigid and elastomer segments. The patented system involves a chain shuttling agent and two separate catalysts operating in tandem. Dow will position its new products in competition with styrenic block copolymers (SEBS, SIS and SBS), ethylene vinyl acetate polymers, flexible PVC, vulcanized thermoplastic elastomers, thermoplastic polyurethanes or even flexible polyolefins or other crosslinked elastomers. Dow estimates that it had sales of over $1 bn in 2004 from products developed using its Insite technology. Chimie Pharma Hebdo, 3 Jul 2006, 346 (Website: http://www.france-chimie.com) (in French) & Plastics and Rubber Weekly, 30 Jun 2006, 4 & European Plastics News, Jul/Aug 2006, 33 (7), 14 & Chemical Engineering (New York), Jul 2006, 113 (7), 19 New method for making PO eliminates undesirable side products German companies Degussa and Uhde GmbH have introduced a novel process for the production of propylene oxide. The hydrogen peroxide-based propylene oxide (HP- PO) process is claimed to be an economical technology as it yields no by-products. Using the novel process, the PO recovered via distillation is at purity greater than 99.97% weight, with final PO yields of more than 95% weight. In a related development regarding the novel HP-PO process, Uhde was awarded in Apr 2006 a contract to build a 100,000 tonne/y PO plant based on the novel HP-PO process in Ulsan, South Korea. The contract with Korean company, SKC, involves basic engineering by Uhde, technology licence by Degussa, and construction of an HP plant by Degussa-Headwaters Korea, a jv of Degussa and Headwaters Inc. The PO plant is scheduled to be operational by early 2008. Chemical Engineering Progress, Jul 2006, 102 (7), 13 GS CleanTech acquires exclusive rights to proprietary gasification technology for ethanol production GS CleanTech Corp announced its execution of an agreement with ZeroPoint Clean Technology Inc (ZeroPoint) for the exclusive rights to distribute and use ZeroPoint’s proprietary gasification, gas to liquids and fuel reforming technology in the ethanol production industry. ZeroPoint’s Biomass Gasifier is designed to standardize variable biomass feeds and optimize high yields of high-quality syngas in real- time with greatly increased capital and operating cost efficiencies at smaller scales as compared to traditional gasification technologies. The syngas output of ZeroPoint’s gasifier can either be used to generate electricity in a standard gas-fired generator or catalyzed into liquid fuels such as ethanol or diesel substitutes with the Fischer-Tropsch process. GS CleanTech Corp provides applied engineering and technology transfer services based on clean technologies and process innovations that make it cost-effective and easy to recycle and reuse resources. ZeroPoint Clean Technology Inc is commercializing patent pending and proprietary gasification, gas to liquids, and fuel reforming technology. Press release from: GS CleanTech, 27 Jul 2006 Process to turn garbage into functional carbons developed A process that converts organic waste materials into functional carbons such as carbon nanotubes has been developed by Japan Steel Works (JSW). Methane-containing biogas released from organic waste materials is decomposed using a biaxial screw- feeder reactor. The company is conducting trial operations of the process, which is based on a gas- phase catalytic reaction, at its manufacturing facility at Muroran in Hokkaido Prefecture, Japan. To evaluate the viability of the process on a commercial scale, JSW is currently developing a screw-feeder reactor that can process 20 tonne/day of organic waste materials. This capacity is sufficient to accommodate organic wastes produced everyday in a city with a population of 100,000, and produce about 400-500 kg/day of functional carbons. The planned facility is expected to be completed by the end of 2006, with experiments to be carried out for about two years. Japan Chemical Week, 22 Jun 2006, 47 (2372), 3 Alliance examines clean coal Shell Gas and Power will forge an alliance with Anglo American to further advance clean coal technologies. The partners will work on coal gasification technologies, designed to convert coal into hydrogen and carbon monoxide syngas for application in power plants. The principal objective is to develop a technology that integrates coal gasification (based on brown coal) and gas-to-liquid technologies, combined with integrated power generation and water recovery. The project will particularly focus on devising advanced drying and gasification technologies for large volume production of ultra-clean synthetic diesel, along with carbon capture and storage. Anglo American brings to the alliance its coal supply and expertise, while Shell will provide know-how on extraction, gasification, and coal conversion. The Australia- based Monash Energy project of Anglo American could also be brought into the partnership. TCE (formerly The Chemical Engineer), Jul 2006, (781), 3 Reaxa launches new metal catalyst remover The launch of four new products expands Reaxa’s QuadraPure line of 6 SEPTEMBER 2006 FOCUS ON CATALYSTS

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appliances, groceries packaging, andin the automotive sector. The twocompanies have formed a researchdeal for the preparation of newcatalyst systems for manufacturingOBCs. Mitsui said the new co-polymeroffers improved flexibility and rubberelasticity in a temperature range from–60° to more than 100°C. Mitsui’ssingle-site catalysis technique will beemployed in the project.

ICIS Chemical Business, 3 Jul 2006 (Website:http://icischemicalbusiness.com) & Japan ChemicalWeek, 29 Jun 2006, 47 (2373), 12 & Press releasefrom: Mitsui Chemicals Inc, Shiodoma City Center, 1-5-2 Higashi-Shimbashi, Minato-ku, Tokyo 105-7117,Japan. Website: http://www.mitsui-chem.co.jp/e/ (21Jun 2006)

Dow launches olefin block copolymersdeveloped with Insite technology

Dow is launching its Infuse range ofolefin block copolymers (OBC) ontothe olefin elastomers market. Thesecombine the flexibility of polyolefinelastomers and plastomers with theheat resistance of HDPE. A novelcatalyst system allowed theproduction of the copolymers whichhave alternating rigid and elastomersegments. The patented systeminvolves a chain shuttling agent andtwo separate catalysts operating intandem. Dow will position its newproducts in competition with styrenicblock copolymers (SEBS, SIS andSBS), ethylene vinyl acetatepolymers, flexible PVC, vulcanizedthermoplastic elastomers,thermoplastic polyurethanes or evenflexible polyolefins or othercrosslinked elastomers. Dowestimates that it had sales of over $1bn in 2004 from products developedusing its Insite technology.

Chimie Pharma Hebdo, 3 Jul 2006, 346 (Website:http://www.france-chimie.com) (in French) & Plasticsand Rubber Weekly, 30 Jun 2006, 4 & EuropeanPlastics News, Jul/Aug 2006, 33 (7), 14 & ChemicalEngineering (New York), Jul 2006, 113 (7), 19

New method for making PO eliminatesundesirable side products

German companies Degussa andUhde GmbH have introduced a novelprocess for the production ofpropylene oxide. The hydrogenperoxide-based propylene oxide (HP-PO) process is claimed to be aneconomical technology as it yields noby-products. Using the novel process,the PO recovered via distillation is at

purity greater than 99.97% weight,with final PO yields of more than 95%weight. In a related developmentregarding the novel HP-PO process,Uhde was awarded in Apr 2006 acontract to build a 100,000 tonne/yPO plant based on the novel HP-POprocess in Ulsan, South Korea. Thecontract with Korean company, SKC,involves basic engineering by Uhde,technology licence by Degussa, andconstruction of an HP plant byDegussa-Headwaters Korea, a jv ofDegussa and Headwaters Inc. ThePO plant is scheduled to beoperational by early 2008.

Chemical Engineering Progress, Jul 2006, 102 (7), 13

GS CleanTech acquires exclusiverights to proprietary gasificationtechnology for ethanol production

GS CleanTech Corp announced itsexecution of an agreement withZeroPoint Clean Technology Inc(ZeroPoint) for the exclusive rights todistribute and use ZeroPoint’sproprietary gasification, gas to liquidsand fuel reforming technology in theethanol production industry.ZeroPoint’s Biomass Gasifier isdesigned to standardize variablebiomass feeds and optimize highyields of high-quality syngas in real-time with greatly increased capital andoperating cost efficiencies at smallerscales as compared to traditionalgasification technologies. The syngasoutput of ZeroPoint’s gasifier caneither be used to generate electricityin a standard gas-fired generator orcatalyzed into liquid fuels such asethanol or diesel substitutes with theFischer-Tropsch process. GSCleanTech Corp provides appliedengineering and technology transferservices based on clean technologiesand process innovations that make itcost-effective and easy to recycle andreuse resources. ZeroPoint CleanTechnology Inc is commercializingpatent pending and proprietarygasification, gas to liquids, and fuelreforming technology.

Press release from: GS CleanTech, 27 Jul 2006

Process to turn garbage intofunctional carbons developed

A process that converts organic wastematerials into functional carbons suchas carbon nanotubes has been

developed by Japan Steel Works(JSW). Methane-containing biogasreleased from organic waste materialsis decomposed using a biaxial screw-feeder reactor. The company isconducting trial operations of theprocess, which is based on a gas-phase catalytic reaction, at itsmanufacturing facility at Muroran inHokkaido Prefecture, Japan. Toevaluate the viability of the process ona commercial scale, JSW is currentlydeveloping a screw-feeder reactorthat can process 20 tonne/day oforganic waste materials. This capacityis sufficient to accommodate organicwastes produced everyday in a citywith a population of 100,000, andproduce about 400-500 kg/day offunctional carbons. The plannedfacility is expected to be completed bythe end of 2006, with experiments tobe carried out for about two years.

Japan Chemical Week, 22 Jun 2006, 47 (2372), 3

Alliance examines clean coal

Shell Gas and Power will forge analliance with Anglo American tofurther advance clean coaltechnologies. The partners will workon coal gasification technologies,designed to convert coal intohydrogen and carbon monoxidesyngas for application in power plants.The principal objective is to develop atechnology that integrates coalgasification (based on brown coal)and gas-to-liquid technologies,combined with integrated powergeneration and water recovery. Theproject will particularly focus ondevising advanced drying andgasification technologies for largevolume production of ultra-cleansynthetic diesel, along with carboncapture and storage. Anglo Americanbrings to the alliance its coal supplyand expertise, while Shell will provideknow-how on extraction, gasification,and coal conversion. The Australia-based Monash Energy project ofAnglo American could also be broughtinto the partnership.

TCE (formerly The Chemical Engineer), Jul 2006, (781), 3

Reaxa launches new metal catalystremover

The launch of four new productsexpands Reaxa’s QuadraPure line of

6 SEPTEMBER 2006

F O C U S O N C A T A L Y S T S