mtbe remediation handbook - edited by ellen e. moyer and paul t. kostecki

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Book Review/ Laura L. Sanders, Book Editor MTBE Remediation Handbook reviewed by Don H. Kampbell MTBE Remediation Handbook, edited by Ellen E. Moyer and Paul T. Kostecki, provides a unique reference on relevant strategies for understanding and cleaning up methyl tert-butyl ether (MTBE) contamination in the environment. This book presents available technologies for remediating a substance that has a significant environmental impact. Em- phasis is on remediation of MTBE in spills of gasoline in which it has been used as an octane enhancer. Individual chapters of the book list useful databases and describe tech- nology to assess and remediate MTBE contamination. The book is divided into three sections consisting of 31 chapters and an appendix. Each chapter addresses a differ- ent topic, usually focused on a specific remediation technol- ogy. Generally, the opening chapters introduce the history of MTBE use and describe physical and chemical proper- ties discussed in the ensuing remediation chapters. Section I consists of seven chapters on the history of MTBE use as an octane enhancer, fate and transport of MTBE as a gaso- line component, a summary on occurrence of MTBE in sur- face and ground water, site assessment, analysis of gasoline environmental samples, and risk assessment. Section II includes nine chapters on application of remediation tech- nologies. Topics presented are receptor protection, source control, gas-based technologies, in situ chemical oxidation, aerobic in situ bioremediation, anaerobic in situ biore- mediation, phytoremediation, ground water recovery, and natural attenuation. Section II serves as a bridge from the discussion of fundamental concepts to consideration of applied MTBE remediation. Section III is devoted to reme- diation case studies and includes chapters 17 to 31 and the appendix. Its objective is to present experiences for estimat- ing remedial costs, a U.S. EPA case studies database, and use of cleanup technologies at different site locations. One of the strong points of the handbook is that it con- solidates information about remediation techniques under one cover, whereas previously the information was avail- able only in individual research papers. In the third chapter, John Wilson presents a noteworthy in-depth scientific pre- sentation on measurements of MTBE transport and fate in ground water. It is an excellent summary on resulting distribution of gasoline constituents as controlled by attenuation and hydraulic processes in contaminated ground water environments. Bruce Rittmann in chapter 16 does an exceptional job discussing in detail the pros and cons of natural attenuation with emphasis on the signifi- cance of dissolved oxygen and oxygenase enzymes. The chapter on risk assessment by Pamela Williams and Patrick Sheehan points out a definite void in data on MTBE con- tamination at low concentrations, highlighting the fact that it has not been proven harmful to human health. Robert Pirkle and Patrick McLoughlin pursued an important crit- ical review of analytical methods used for gasoline spill samples. Unfortunately, data from a U.S. EPA analytical guidance document had not been completed at the time of publishing, so was not included in their chapter presenta- tion. An important U.S. EPA database given by David Ramsden and Tie Li shows evidence that MTBE remedia- tion does occur under a variety of conditions. One special feature of the handbook is the large number of contributing knowledgeable authors: the back cover lists 52 contribu- tors’ names. The handbook would be improved if each chapter listed needs for further studies. Such information would be beneficial guidance for new researchers in environ- mental remediation. Bruce Rittmann provides a good ex- ample of this on page 338. Figures and tables are easy to understand and clarify the associated text. Only one typographical error was noticed in the entire text. The chapter-by-chapter reference lists would better facilitate a reader’s search if compiled into a single reference list for the entire book. None of the presentations on remediation techniques and case studies are too advanced for an upper class student to understand. MTBE Remediation Handbook should be in all envi- ronmental professionals’ libraries, not only for the scien- tific information on MTBE but also for the descriptions of concepts of remediation fundamentals. The handbook has a good chance of achieving the editors’ goal of improving success in the practice of MTBE remediation. Although the handbook is an excellent guide and source, industry is phasing out the addition of MTBE to gasoline, so MTBE as a widespread pollutant may eventually become nonexistent. Until that time, this book will serve as an important resource. The 670-page MTBE Remediation Handbook is pub- lished by Springer (ISBN 978-1-884940-29-3) and is available at the NGWA Bookstore at a price of $121 (members) or $166 (nonmembers). Stratford, OK 74872; [email protected] Copyright ª 2007 The Author(s) Journal compilation ª 2007 National Ground Water Association. doi: 10.1111/j.1745-6584.2007.00363.x 524 Vol. 45, No. 5—GROUND WATER—September–October 2007

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Page 1: MTBE Remediation Handbook - Edited by Ellen E. Moyer and Paul T. Kostecki

Book Review/ Laura L. Sanders, Book Editor

MTBE Remediation Handbookreviewed by Don H. Kampbell

MTBE Remediation Handbook, edited by Ellen E.Moyer and Paul T. Kostecki, provides a unique reference onrelevant strategies for understanding and cleaning up methyltert-butyl ether (MTBE) contamination in the environment.This book presents available technologies for remediating asubstance that has a significant environmental impact. Em-phasis is on remediation of MTBE in spills of gasoline inwhich it has been used as an octane enhancer. Individualchapters of the book list useful databases and describe tech-nology to assess and remediate MTBE contamination.

The book is divided into three sections consisting of 31chapters and an appendix. Each chapter addresses a differ-ent topic, usually focused on a specific remediation technol-ogy. Generally, the opening chapters introduce the historyof MTBE use and describe physical and chemical proper-ties discussed in the ensuing remediation chapters. Section Iconsists of seven chapters on the history of MTBE use asan octane enhancer, fate and transport of MTBE as a gaso-line component, a summary on occurrence of MTBE in sur-face and ground water, site assessment, analysis of gasolineenvironmental samples, and risk assessment. Section IIincludes nine chapters on application of remediation tech-nologies. Topics presented are receptor protection, sourcecontrol, gas-based technologies, in situ chemical oxidation,aerobic in situ bioremediation, anaerobic in situ biore-mediation, phytoremediation, ground water recovery, andnatural attenuation. Section II serves as a bridge from thediscussion of fundamental concepts to consideration ofapplied MTBE remediation. Section III is devoted to reme-diation case studies and includes chapters 17 to 31 and theappendix. Its objective is to present experiences for estimat-ing remedial costs, a U.S. EPA case studies database, anduse of cleanup technologies at different site locations.

One of the strong points of the handbook is that it con-solidates information about remediation techniques underone cover, whereas previously the information was avail-able only in individual research papers. In the third chapter,John Wilson presents a noteworthy in-depth scientific pre-sentation on measurements of MTBE transport and fatein ground water. It is an excellent summary on resultingdistribution of gasoline constituents as controlled by

attenuation and hydraulic processes in contaminatedground water environments. Bruce Rittmann in chapter 16does an exceptional job discussing in detail the pros andcons of natural attenuation with emphasis on the signifi-cance of dissolved oxygen and oxygenase enzymes. Thechapter on risk assessment by Pamela Williams and PatrickSheehan points out a definite void in data on MTBE con-tamination at low concentrations, highlighting the fact thatit has not been proven harmful to human health. RobertPirkle and Patrick McLoughlin pursued an important crit-ical review of analytical methods used for gasoline spillsamples. Unfortunately, data from a U.S. EPA analyticalguidance document had not been completed at the time ofpublishing, so was not included in their chapter presenta-tion. An important U.S. EPA database given by DavidRamsden and Tie Li shows evidence that MTBE remedia-tion does occur under a variety of conditions. One specialfeature of the handbook is the large number of contributingknowledgeable authors: the back cover lists 52 contribu-tors’ names.

The handbook would be improved if each chapterlisted needs for further studies. Such information wouldbe beneficial guidance for new researchers in environ-mental remediation. Bruce Rittmann provides a good ex-ample of this on page 338.

Figures and tables are easy to understand and clarifythe associated text. Only one typographical error wasnoticed in the entire text. The chapter-by-chapter referencelists would better facilitate a reader’s search if compiledinto a single reference list for the entire book. None of thepresentations on remediation techniques and case studiesare too advanced for an upper class student to understand.

MTBE Remediation Handbook should be in all envi-ronmental professionals’ libraries, not only for the scien-tific information on MTBE but also for the descriptions ofconcepts of remediation fundamentals. The handbook hasa good chance of achieving the editors’ goal of improvingsuccess in the practice of MTBE remediation. Althoughthe handbook is an excellent guide and source, industryis phasing out the addition of MTBE to gasoline, soMTBE as a widespread pollutant may eventually becomenonexistent. Until that time, this book will serve as animportant resource.

The 670-page MTBE Remediation Handbook is pub-lished by Springer (ISBN 978-1-884940-29-3) and isavailable at the NGWA Bookstore at a price of $121(members) or $166 (nonmembers).

Stratford, OK 74872; [email protected] ª 2007 The Author(s)Journal compilationª2007National GroundWaterAssociation.doi: 10.1111/j.1745-6584.2007.00363.x

524 Vol. 45, No. 5—GROUND WATER—September–October 2007