m.sc. degree course in chemistry syllabus and...

SRNMC Regulation-2016 Syllabus

SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE

SATTUR- 626 203 (An Autonomous institution affiliated to the Madurai Kamaraj University, Madurai)

(Re-Accredited with Grade ‘A’ by NAAC)

M.Sc. DEGREE COURSE

IN

CHEMISTRY

SYLLABUS AND REGULATIONS

UNDER

CHOICE BASED CREDIT SYSTEM (CBCS)

(Those who joined in 2016-2017 and after)


Objectives

To enable the students

1. To gain knowledge on the basic and advanced level aspects in the different

disciplines of chemistry.

2. To get an exposure to the basics in Nano chemistry and biochemistry.

3. To gain knowledge on the basic and advanced level experimental techniques.

4. To get an exposure on some current trends in chemistry.

Eligibility for Admission

B.Sc. degree with chemistry as the core subject and physics as one of the allied

subjects; the other allied subject may be any one of the following: Mathematics, Botany and

Zoology.

Duration of the Course

The duration of the course shall be two academic years comprising four semesters

with two semesters in each academic year.

Courses of Study

1. Core subjects

2. Major elective subjects

3. Non major electives

.

Credits

The term ‗credit‘ refers to the weightage given to the course, usually in relation to the

instructional hours assigned to it. The total credits required for completing Master of Science

in Chemistry is 90. The particulars of the credits for individual components and courses are

placed on Table-1.


Extra Credits Paper:

1. This paper is optional. Students may or may not select this paper. If he/she selects

this paper and if he/she passes the paper, then 3 extra credits will be added in his/her

total credit to the degree, even otherwise, it won‘t affect the completion of degree.

2. Though this paper is common to all PG programmes, the syllabus varies according to

the subject selected by the department.

3. The title of this paper is ―Model Paper for NET Examinations‖

4. Examination for this paper will be held at the end of the 4th

semester examinations.

5. There is no internal examination and only external examination for this paper.

6. Maximum marks for this paper is 100.

Scheme of Examination

It is presented on Table-2

Pattern of the Question Paper

Theory

Part A

Ten questions (Multiple choice) 10 x 1 = 10 marks

Two questions from each Unit

Part B

Five questions (either or type) 5 x 7 = 35 marks

One question from each Unit

Part C

Three questions (out of five) 3 x 10 = 30 marks

One question from each unit

---------------

Total 75 Marks

---------------

Evaluation:

The performance of the student is evaluated in terms of percentage of marks with a

provision for conversion to grade points. Evaluation for each course shall be done by a

continuous internal assessment by the concerned course teacher as well as by an end semester

examination which will be written type examination of 3 hours duration and will be


consolidated at the end of the course. The ratio of marks to be allotted to continuous internal

assessment and to end semester examination is 25:75 (i.e. Internal 25 Marks and external 75

Marks)

The components of continuous internal assessment are:

Two tests and their average 15 Marks

Seminar/Group Discussion 5 Marks

Assignment 5 Marks

Total 25 Marks

Passing Minimum

A) Theory

1. 50% of the aggregate (External+ Internal)

2. No separate pass minimum for Internal

3. 34 Marks out of 75 is the pass minimum for the External.

B) Practical

1. 50% of the aggregate (External+ Internal)

2. No separate pass minimum for Internal

3. 27 Marks out of 60 is the pass minimum for the External.

C) Project

1. 50% of the aggregate (Project Evaluation + Viva Voce+ Internal)

2. No separate pass minimum for internal.

3. 27 marks out of 60 is the pass minimum for the External.


M.Sc (CHEMISTRY)

Table -1: Course pattern

(With effect from the academic year 2016 – 2017)

Extra Credits Papers: 3 Credits

Grand Total : 93

S.No

Semester

I

II

III

IV

V

Total

Hours

Total

Credits

No. of

Courses

1

I

Core

6(5)

Core

6(5)

Core

6(4)

Elective

6(4)

Practical

6(4)

30

22

5

2

II

Core

6(5)

Core

6(4)

Core

6(5)

Elective

6(4)

Practical

6(4)

30

22

5

3

III

Core

6(5)

Core

6(5)

Core

6(5)

Elective

6(4)

Practical

6(4)

30

23

5

4

IV

Core

6(5)

Core

6(5)

Core

6(5)

Elective

6(4)

Project

6(4)

30

23

5

TOTAL

120

90

20


M.Sc (CHEMISTRY)

Table -2: Course details and scheme of examinations

(With effect from the academic year 2016 – 2017)

Semester Title of the Paper

Subject

Code

Hr

s

/we

ek

Credit

Exam

hrs.

Marks Total

Marks Int Ext

I

Organic chemistry - I

Stereochemistry and

reaction

mechanism -I

P16CHC11

6 5 3 25 75 100

Inorganic

Chemistry I –

Atomic properties,

coordination and solid

state

chemistry I

P16CHC12

6 5 3 25 75 100

Physical

Chemistry I –

Thermodynamics and

electrochemistry

P16CHC13

6 4 3 25 75 100

Major elective:

a)Environmental

Chemistry

b) Biochemistry

P16CHE11

P16CHE12

6

4

3

25

75

100

Practical I Inorganic

Chemistry

P16CHC1P1

6

4

6

40

60

100

II

Organic Chemistry II -

Natural products,

conformational analysis

and reaction

mechanism – II

P16CHC21

6 5 3 25 75 100

Inorganic Chemistry II -

Bioinorganic and solid

state

chemistry II

P16CHC22

6 4 3 25 75 100

Physical

Chemistry II -

Quantum, catalysis and

molecular spectroscopy

P16CHC23

6 5 3 25 75 100


Major Elective

a)Analytical Chemistry

b)Industrial Chemistry

P16CHE21

P16CHE22

6 4 3 25 75 100

Practical – II

Organic Chemistry

P16CHC2P1

6 4 6 40 60 100

III

Organic Chemistry III -

Reactions , reagents and

Spectroscopy

P16CHC31 6 5 3 25 75 100

Inorganic Chemistry III -

Inorganic Spectroscopy and

Nano Chemistry

P16CHC32

6 5 3 25 75 100

Physical Chemistry III -

Group theory and

nanochemistry

P16CHC33 6 5 3 25 75 100

Major elective: (Any one)

a) Computer Applications

b) Pharmaceutical

chemistry

P16CHE31

P16CHE32 6 4

3

25

75

100

Practical III

Physical chemistry

P16CHC3P1

6 4

6

40

60

100

IV

Organic chemistry -IV

Molecular rearrangements

and synthetic methods

P16CHC41 6 5 3 25 75 100

Inorganic Chemistry IV -

Nuclear and

Organometallic Chemistry.

P16CHC42 6 5 3 25 75 100

Physical Chemistry IV -

Chemical Kinetics ,

Surface, Biophysical and

Photo Chemistry

P16CHC43

6 5 3 25 75 100

Major Elective: (Any one)

a) Introduction to Nano

Science

b) Polymer Chemistry

P16CHE41

P16CHE42

6 4 3 25 75 100

1) Project

2) Review of recent aspects

of Chemistry

Viva Voce

P16CHPT41

6 4 6 40

40

20 100

Extra Credit Paper

Model Paper for NET /SET

Examination P16CHX41

3 3 100


SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)

SATTUR-626 203.

Department of Chemistry

(For those who joining in 2016-2017 and after)

Programme : M.Sc. Chemistry Subject Code : P16CHC11

Semester : I No.of Hours allotted : 6 / week

Subject : Core Paper I No of Credits : 5

Title of the Paper : ORGANIC CHEMISTRY - I

STEREOCHEMISTRY AND REACTION MECHANISM- I

Objectives

To enable the learners

To learn the basic concepts of organic chemistry

To know about the basic concept of stereochemistry in detail

To understand the aromatic character of organic compounds.

To learn the fundamentals of reaction mechanism.

Unit-I Electron displacement and structure-reactivity correlation

Inductive and field effects – bond distances - bond energies – delocalised

bonds - cross conjugation – rules of resonance effect - steric inhibition of resonance

– hyper conjugation - hydrogen bonding – addition compounds – EDA complexes -

inclusion compounds.

Quantitative treatment of the effect of structure on reactivity – The

Hammett relationship - significance of reaction and substituent‘s constants -

application of the Hammett equation in reaction mechanism – limitations and

deviation.

Unit II Stereochemistry –I

Symmetry elements - Concept of chirality , necessary and sufficient conditions

for chirality – Relationship between substrate symmetry and chirality - Projection

formulae – Wedge, Fischer, Sawhorse and Newmann - Optical isomerism due to

centre of chirality - Molecules with one stereogenic centre (chiral centre) and

molecules with more than one chiral centre – properties of enantiomers and

diastereoisomers – erythro and threo nomenclature – Cahn, Ingold and Prelog

system of designation of configuration .


Geometrical isomerism: E-Z nomenclature- determination of configuration

of geometrical isomers using physical and chemical methods – stereoisomerism in

monocyclic compounds (upto six membered ring).

Unit III Stereochemistry II

Prochirality and prosteroisomerism, enantiotopic and diastereotopic ligands

and faces and their nomenclature - pro-R and pro-S and Re and Si faces -

Stereospecfic and stereoselective reactions - Asymmetric synthesis; Cram and

Prelog rule - Optical isomerism due to axial chirality - biphenyl, Allenes and

spiranes - Molecules with planar chirality – paracyclophanes, trans-cyclooctene and

ansa compounds.

Unit –IV Aromatic Character

Aromatic character in benzene, six membered rings, five, seven and eight

membered rings – other systems with aromatic sextets – Huckel‘s rule – Craigs rule

– concept of homoaromaticity and antiaromaticity - systems with 2,4,8 and 10

electrons – systems with more than10 electrons – Alternant and nonalternant

hydrocarbons - Chemistry of cyclopentadienyl anion – Fulvene, Azulene,

Tropolones, Sydnones and Annulenes .

Novel ring system: Nomenclature of bicyclic and tricyclic systems -

chemistry of adamantane, diamantane (congressane), cubane and catenanes.

Unit –V Introduction to Reaction Mechanism

Reaction intermediates – free radicals, carbenes, nitrenes, carbanions,

carbocations – formation and stability of reaction intermediates – methods of

determination of reaction mechanism - kinetic and thermodynamic control of

chemical reaction - Kinetic and non kinetic methods for determining organic

reaction mechanism –principle of microscopic reversibility – Hammond postulate.

Partial rate factors - ortho/para ratio - Quantitative treatment of

reactivity of the electrophile (the selectivity relation).

Text books:

Text book-1

Title of the book : Reaction mechanism and reagents in organic chemistry

Names of the Author : G.R. Chatwal

Publisher : Himalaya publishing house,

Edition/Year : 5/2012


Text book-2

Title of the book : Stereochemistry of Organic compounds, Principles and

Application,

Name of the Author : D.Nasipuri

Publisher : Wiley eastern Ltd

Edition/Year : 2 /2006

Text book-3

Title of the book : Stereochemistry conformation and Mechanism

Name of the Author : P.S.Kalsi

Publisher : New age international publishers


Text book-4

Title of the book : Organic chemistry Vol-II

Name of the Author : I.L.Finar

Publisher : ELBS Longmann


Text book-5

Title of the book : Organic reaction mechanism

Name of the Author : V.K Ahluwalia

Publisher : Narosa publishing House New Delhi


Unit –I (From text book 1)

Chapter –2 (Page No.2.1- 2.46)

Unit –II (From text book –2) Chapter – 2 (Page No.15-20)

Chapter – 3 (PageNo.27-36)

Chapter – 5 (Page No. 43-67)

(From text book –4) Chapter – 4 (Page No.170-200)

Unit –III (From text book –3)

Chapter – 1 (Page No.84-130)

Unit –IV (From text book –1)

Chapter –13 (Page No.13.1-13.37)

Unit –V (From text book –5) Chapter –2 (Page No.78-118)

Reference books

Reference Book-1

Title of the book : Guide book to Mechanism in Organic chemistry

Name of the Author : Peter Sykes

Publisher : Orient longmann Ltd., New Delhi,1998,

Edition/Year : 6 / 1984


Reference Book-2

Title of the book : Organic chemistry,

Name of the Author : R.T.Morrison and R.N. Boyd,

Publisher : Prentice, Hall,

Edition/Year : 6/ 1995,

Reference Book-3

Title of the book : Mechanism and Structure of Organic Chemistry,

Name of the Author : E.S. Gould,

Publisher : Holt, Rinehart and Winston Inc, New York,


Reference Book-4

Title of the book : Stereo chemistry of carbon compounds,

Name of the Author : E.l.Eliel

Publisher : Mc Graw Hill

Edition/Year : Reprint 2008 Edition / 1975

Reference Book- 5

Title of the book : Advanced Organic Chemistry,

Name of the Author : Jerry March,

Publisher : John Wiley and Sons,

Edition/Year : 4/ 2004.

Prepared by :

Signature :



SATTUR-626 203.



SYLLABUS

Programme : M.Sc Chemistry Subject Code : P16CHC12

Semester : I No. of Hours allotted: 6 / week

Subject : Core - Paper II No. of Credits : 5

Title of the Paper : INORGANIC CHEMISTRY – I

ATOMIC PROPERTIES, COORDINATION AND SOLID STATE

CHEMISTRY -I

Objectives

To enable the learners to

Apply molecular orbital theory to the poly atomic molecules

Know about bond properties , Ionic bonding and the concepts of solid chemistry

Interrelate the structure of inorganic cage, chain and poly-acids.

Unit I : Nature of chemical bonds:

Covalent bond: Hybridisation – Calculation of S and P characters – Bent‘s rule –

VSEPR theory - M.O.theory; LCAO approximation – application of MOT to heteronuclear

diatomic molecules like NO, CO and triatomic molecule BeH2 –Structure and bonding of

electron deficient molecules like diborane.

Unit II : Atomic Properties

Ionic radii - covalent radii – Vander Waals Radius – bond length, bond order,

bond energy, bond polarity – partial ionic character of covalent bonds – electro negativity

– electron affinity –Lattice energy-Born-Lande equation-Born Haber cycle - Covalent

character in ionic compounds - different types of electrostatic interactions - hydrogen

bonding.

Unit III: Co-ordination chemistry I

Basics of co-ordination compounds- IUPAC nomenclature of co-ordination

compounds – isomerism in co-ordination compounds – types of ligands – monodentate,

ambidentate and macrocyclic ligands – chelate and its applications – detection of complex


formation in solution – factors affecting stability constant in solution – determination of

stability constant by spectrophotometric, polorographic and potentiometric and Job‘s method.

Unit IV : Solid state chemistry – I

Elements of crystallography-space lattice - Unit cell-Crystal system - X ray

diffraction - Bragg‘s equation-Bragg‘s method-Rotation crystal method and powder method

of x-ray diffraction - Evaluation of unit cell dimensions - Structure of typical lattice

such Cesium chloride, Zinc blende, Wurzite, Rutile, Fluorite, antifluorite, perovskite,

covalent crystal as diamond and graphite.

Unit V : Inorganic chains, rings and cages

Polyacids – classification – isopoly acids like polymolybdate, polyvanadate and

polytungstate – their structures – heteropolyacids 12A, 12B, 9 and 6 heteropolyacids –

Preparation and structure: Silicates - Silicones- Phosphazenes and their polymers – S4N4 –

polymeric sulphur nitride (polythiazyl) cage compound- Boranes – nomenclature of boranes

and carboranes –Wade‘ rules – Styx number – preparation and structures of B4H10 and

C2B10H12 – borazine.

Text books

Text Book- 1

Title of the book : Selected Topics in Inorganic Chemistry

Name of the Author : Wahid U.Malik

Publisher : S.Chand and Company Ltd.


Text Book- 2

Title of the book : Principles of Inorganic Chemistry

Name of the Author : B.R.Puri and L.R.Sharma and K.C.Kalia

Publisher : Milestone Publishers,New Delhi 2008.


Unit-I (From Text Book-1)

Chapter – 5 (Page No 154 to 196)

Unit II to V (From Text Book-2)


Chapter – 4 (Page No 131 to 135 , 179 to 183)

Chapter-26 (Page No 729-734, 738 to 764)

Chapter – 6 (Page No 222 to 231, 244 to 246)



Appendix I(Page No1114 to1126)


Reference Books

Reference Book-1

Title of the book : Inorganic Chemistry.

Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,

Publisher : Harper Collins College Publishers


Reference Book-2

Title of the book : An Introduction to Inorganic Chemistry

Name of the Author : K.F.Purcell and J.C Koltz

Publisher : W.B. Saunders Company, Philadelphia,


Reference Book-3

Title of the book : Introduction to solids

Name of the Author : L.V.Azaroff

Publisher : Tata Mc Graw Hill Publishing House


Prepared by :

Signature :



(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)

SATTUR-626 203.



SYLLABUS

Programme : M.Sc .Chemistry Subject Code : P16CHC13

Semester : I No. of Hours allotted : 6 / week

Subject : Core - Paper III No. of Credits : 4

Title of the Paper : PHYSICAL CHEMISTRY – I

THERMODYNAMICS AND ELECTROCHEMISTRY

Objectives


To understand the importance and significance of thermodynamics and the principle

of chemical equilibrium.

To acquire an insight into phase rule.

To understand the principles of quantum chemistry.

To know about the importance and significance of electrochemistry and its

applications.

UNIT-I Chemical Thermodynamics

Second law of thermodynamics, concept of entropy. Gibbs-Helmholtz equation,

Maxwell relations and thermodynamic equation of state. Partial molar quantities - Chemical

potential, its variation with temperature and pressure, Gibbs Duhem equation. Experimental

determinations of fugacity of real gases (Graphical, from state equation, approximate and

generalized methods).Third law of thermodynamics – Nernst theorem, absolute entropies,

determinations of absolute entropies, exception to third law and unattainability of absolute

zero.

UNIT-II Chemical and Phase Equilibria

Spontaneous reactions, free energy of a spontaneous reaction, role of temperature,

standard free energy change of a reaction. Thermodynamic derivation for the law of

chemical equilibrium, Van‘t Hoff‘s reaction isotherm. Temperature dependence of

equilibrium constant, Integrated form of the Van‘t Hoff equation. Relation between Kp and

Kc. De Donder‘s concept of degree of advancement of a reaction.


Gibbs phase rule - its thermodynamic derivation. Application of phase rule to

three component systems - systems composed of two solids and a liquid ( crystallization of

pure components only, hydrate and double salt formation ). Formation of one pair, two pairs

and three pairs of partially miscible liquids.

UNIT – III Basic Principles of Quantum Mechanics

Planck‘s explanation about black- body radiation, de-Broglie‘s concept of matter

waves ( Experimental technique and verification), Compton effect, Heisenberg‘s uncertainty

principle, Postulates of quantum mechanics, Operators (addition, subtraction, multiplication,

commutator, Hermitian, Hamiltonian and linear operators), Rules for setting up the following

quantum mechanical operators - position, momentum, kinetic energy, potential energy, total

energy, angular momentum, raising and lowering of spin angular momentum. Orthogonality

and normalization of wave functions.

Problems on evaluation of commutators and find expressions of some

operators. Simple problems based on to find out the eigen values and eigen functions.

UNIT-IV Electrochemistry - I

Theory of electrolytic conductance – inter ionic attraction , ionic atmosphere ,

thickness of ionic atmosphere. Debye Huckel - Onsager conductance equation – its derivation

and experimental verification, deviations and modifications-Debye Falkenhagen and Wein

effects. Mean ionic activity and activity coefficients of strong electrolytes. Liquid junction

potential and membrane potential. Construction and working of metal-metal ion electrode,

hydrogen electrode, calomel electrode and oxidation-reduction electrode.

Types of cells - Electrochemical cells – primary cells, secondary cells and fuel cells.

Experimental determination of EMF of cells. Nernst equation. Applications of EMF

measurements- determination of equilibrium constant, pH and solubility product.

UNIT-V Electrochemistry - II

The electrical double layer and zeta potential. Perrin, Gouy-Chapmen and Stern

models. Butler-Volmer equation - Tafel equation. Over voltage, Hydrogen over voltage.

current-potential curves.

Potentiometric titrations – principles and types (acid- base, redox and precipitation).

Conductometric titrations – principles and types ( acid – base and precipitation )


Text books

Text book-1

Title of the book : Principles of Physical chemistry

Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania

Publication : Vishal publishing Co,New Delhi.

Edition/ year : 45 /2012

Text Book- 2

Title of the book : Advanced Physical chemistry

Name of the Author : Gurdeep Raj

Publisher : Goel Publishing Co.Meerut.


Text Book- 3

Title of the book : Quantum chemistry

Name of the Author : R.K Prasad

Publisher : New Age International publishers


Text Book- 4

Title of the book : An Introduction to Electrochemistry

Name of the Author : S.Glasstone

Publisher : East West Press (P) Ltd.



Chapter – 14 (Page No.517-541,546-549)

Unit-II (From Text Book-1)

Chapter – 16 (Page No.564-573,581-582)

(From Text Book-2)

Chapter – 18 (Page No.1050-1052, 1054-1056, 1079-1083, 1085-1088)

Unit- III (From Text Book-1)

Chapter -1(Page No.23-25, 32-39, 43, 44)

(From Text Book-3)

Chapter -2(Page No.32, 33)

Chapter -3(Page No. 34-55)

Unit-IV (From Text Book-1)

Chapter – 22 (Page No.770-829,845-850,867-887)

(From Text Book-4)


Unit-V (From Text Book-1) Chapter – 24 (Page No.845-851,867-873)


Reference Books

Reference Book-1

Title of the book : Thermodynamics for chemists

Name of the Author : S.Glasstone

Publisher : East West Press (P) Ltd,New Delhi.


Reference Book-2

Title of the book : Thermodynamics

Name of the Author : J.Rajaram and J.C. Kuriakose

Publisher : Shoban Lal Nagin, Chand & Co, New Delhi.


Reference Book-3


Name of the Author : D.N. Bajpai

Publisher : S.Chand &Company Ltd, New Delhi.


Reference Book-4

Title of the book : Electrochemistry

Name of the Author : B.K. Sharma

Publisher : Goel Publishing House,Meerut.


Prepared by :

Signature :




SATTUR-626 203.



SYLLABUS

Programme : M.Sc., Chemistry Subject Code : P16CHE11

Semester : I No. of Hours allotted : 6 / week

Subject : Paper IV Major Elective I- (a) No. of Credits : 4

Title of the Paper : ENVIRONMENTAL CHEMISTRY

Objectives:

To learn about pollutions and its types.

To know the sources and control measures of various pollution.

UNIT: I Introduction and Classification of Pollution

Introduction, definitions – Environment, Environmental Science,Environmental

education. Types of environment and its components. Definitions-Ecology,Ecosystem.Types

and components of Ecosystem.Cycling of minerals, elements and gases –Phosphate

cycle,Carbon cycle, Nitrogen Cycle, Hydrological cycle. Pollution and its types: Air

pollution, water pollution, soil pollution, radioactive pollution, thermal pollution, noise

pollution, marine pollution. Discuss its sources, effects and control measures.

UNIT: II Analysis of Pollutant

Neutron Activation Analysis-Anodic Stripping Voltametry-Atomic Absorption

Spectrophotometry-X-Ray Florescence-non-dispersive Infrared spectrometry-Fourier

transform Infrared spectroscopy- chemiluminescence-gas chromatography-High performance

Liquid chromatography-Ion selective Electrode.


UNIT: III Air Pollution

Introduction – sources of air pollution – air pollutants – classification and effects of

air pollutants – oxides of nitrogen,sulphur and carbon- acid rain-effects and control-hydrogen

sulphide – effects and control- carbon mono oxide – effects and control- photochemical smog

– effects and control – fly ash – effects and control – green house effect – global warming –

effects and control – ozone layer – ozone depletion – cholorofluoro carbons – effects and

control.

UNIT : IV Soil Pollution

Introduction, types of soil on the basis of its texture, sources of soil pollution-

fertilizers and pesticides, radioactive pollutants, soil sediments as pollutant. Soil erosion –

types,harmful effects,causes and its control measures. Solid waste management-types,

sources and effect of improper solid wastes. Process of solid waste management, disposal

methods- sanitary land filling , incineration and composting methods. Control measures of

soil pollution.

UNIT : V Industrial Pollution & Chemical Toxicology

Introduction-causes of industrial pollution–thermal power plants-nuclear power

reactors-fertilizers and chemical industry-pulp and paper industries – agro based industries-

cement industry.

Toxic chemicals in the environment – biochemical effects of arsenic, cadmium,

lead, mercury and cyanide- bio-ware agents.

Text books

Text Book- 1

Title of the book : Environmental Chemistry,

Name of the Author : A.K De,

Publisher : Wiley Eastern Ltd, Meerut.


Text Book- 2

Title of the book : Environmental chemistry

Name of the Author : B.K.Sharma

Publisher : Goel Publishing House




Chapter 1(Page No 1 to 15)

Unit II (From Text book -1)


Unit III (From Text book -2) Chapter 4 &5 (Page No 69-129)

Unit- IV (From Text Book-2)

Chapter -1(Page No. 33-34)

Chapter -2(Page No 47-55,62-64)

Chapter-3(Page No 75-80)

Unit V (From text book -1) Chapter 6(Page No 84 to 91,97 to 103)

Reference Books

Reference Book-1

Title of the book : Environmental Chemistry,

Name of the Author : B.K Sharma and H.Kaur,

Publisher : Krishna Prakashan, Meerut


Prepared by :

Signature :




SATTUR-626 203.


(For those who joining in 2016-2017 and after )

SYLLABUS

Programme : M.Sc ., Chemistry Subject Code : P16CHE12


Subject : Paper V- Major Elective – I (b) No. of Credits : 4

Title of the Paper : BIOCHEMISTRY

Objectives:


To understand the biological role of enzymes in living organisms

To get a knowledge about the metabolism and genetic information.

Unit-I Enzymes

Classifications, nomenclature,properties of enzymes, some features of active sites of

enzymes, enzyme kinetics-Michaelis-Menton model-significance of Km and VMax Values,

Enzyme inhibition-competitive and non-competitive.Allosteric interaction-Mechanism of

enzyme action .Lysozyme and carboxypeptidase.

Unit-II Generation and storage of Metabolic energy

Metabolism-basic concepts and design: glycolysis-citric acid cycle-oxidative

phosphorylation-pentose pathway and gluoneogenesis.

Glycogen and disaccharide metabolism, fatty acid metabolism –amino acid degradation

and urea cycle-photosynthesis.

Unit-III Information. Storage, transmission, expression of genetic information

DNA-Genetic role structure and replication: messenger RNA and transcription

genetic code and gene protein relationship-protein synthesis, control of gene expression -

Eukaryotic chromosomes, Recombinant DNA technology and viruses.


Unit-IV Bio-inorganic chemistry

Metalloproteins and enzymes-Blue copper proteins-copper proteins as

oxidases/reductases-Nickel containing enzymes-structure of DNA-types of nucleic acid

interactions-coordination, intercalation and hydrogen bonding-interactions of metal ions with

nucleic acid-redox chemistry. Hydrolytic chemistry-monitoring the DNA binding by UV, IR,

NMR and CV spectral techniques.

Unit-V Biophysical aspects

Electron transport and oxidative phosphorylation - Thermodynamic and kinetic

aspects -Photosynthesis - An overview - Photo system II-The light harvesting

chlorophyll - protein complexes of photo system II-Role of carotenoids in photosynthesis-

The primary electron donor of photo system II, P680 - The stable primary electron

acceptor QA and the secondary electron acceptor QB –The transient intermediate electron

acceptor of photo system II,pheophytin - Oxygen evolution-The role of manganese - The

electron donor to P680+ - Charge recombination in photo system II-Photo system I-Light-

harvesting chlorophyll - protein complexes of photo system I - The primary electron donor

of photo system I ,P700- The primary electron acceptor Ao of photo system I- The

intermediate electron acceptor A1 of photo system I- Mobile electron carriers plastocynanin

and ferredoxin NADP+ - reductase.

Text books

Text Book- 1

Title of the book : Fundamentals of Biochemistry

Name of the Author : J.L Jain

Publisher : S.Chand & company Limited


Text Book- 2

Title of the book : Bioinorganic Chemistry

Name of the Author : I.Bertini, H.B.Gray S.J.Leppard and J.S Valentine

Publisher : Viva Books Pvt Ltd..



Text Book- 3

Title of the book : Biochemistry

Name of the Author : A.L.Lehninger,

Publisher : CBS publishers


Text Book -4 Title of the book : An Introduction to Inorganic Chemistry

Name of the Author : K.F. Purcell and J.C. Koltz,

Publisher : W.B. Saunders Company, Philadelpha 1980



Chapter 16 (Page No. 277-286,309-331)


Chapter 21(Page No 367-412,420-422)

Unit-III (From Text Book-3 )

Chapter 4 (Page No 791-913)

Unit IV (From Text Book -2)

Chapter 6 (page No 315-346)

Unit-V Study materials will be provided

Reference Books

Reference Book-1

Title of the book : Biochemistry

Name of the Author : B.D.Hames and N.M.Hooper

Publisher : Viva Books Ltd


Reference Book-2

Title of the book :.Bioinorganic Chemistry,

Name of the Author : G.R. Chatwal and A.K.Bhagi

Publisher : Himalaya Publishing House

Edition/Year :

Reference Book-3

Title of the book : Biochemistry,

Name of the Author : J.M. Berg, J.L.Tymoczko and L.Stryer,

Publisher : W.H.Freeman and company, New York


Prepared by :

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SYLLABUS

Programme : M.Sc ., Chemistry Subject Code : P16CHC1P1


Subject : Paper V Practical - I No. of Credits : 4

Title of the Paper : Inorganic Chemistry Practical

Objectives


To understand the principle for the estimation of binary mixture.

To apply the principle in the semi-micro analysis of an inorganic salt mixture.

To prepare the inorganic complexes

1. Semi-micro qualitative analysis: Analysis of mixtures containing one familiar and

one less familiar cations from the following W, Pb, Se, Mo, Cu, Cd, V, Mn, Ni, Co,

Zn, Ca, Ba, Sr, Li, Mg (insoluble and interfering an ion may be avoided).

2. Inorganic preparations: preparation of at least 5 inorganic complexes.

3. Quantitative analysis: separation and estimation of mixtures by volumetric and

gravimetric methods: some recommended mixtures are

i) Cu and Ni

ii) Fe and Ni

iii) Ca and Ba

iv) Cu and Zn

v) Fe and Cu

References

Reference Book-1

Title of the book : Vogel’s Text Book of Quantitative Chemical Analysis

Name of the Author : J. Bassett et al

Publisher : ELBS, Longmann, U.K



Reference Book-2

Title of the book : Inorganic Semi micro Qualitative Analysis

Name of the Author : V.V. Ramanujam

Publisher : The National Publishing Co, Chennai


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Programme : M.Sc ., Chemistry Subject Code : P16CHC21

Semester : II No. of Hours alloted : 6 / week

Subject : Core Paper VI No of Credits : 5

Title of the Paper : ORGANIC CHEMISTRY – II

NATURAL PRODUCTS, CONFORMATIONAL ANALYSIS AND REACTION

MECHANISM – II

Objectives


To know the concept of aliphatic nucleophilic and electrophilic substitution and

elimination.

To learn the concept of addition to multiple bonds.

To understand the principle of UV, IR and Mass spectroscopy and their application in

organic chemistry.

To know about the chemistry of carbohydrates and terpenoids.

To understand the concept of conformational analysis.

Unit I Aliphatic Nucleophilic Substitution

Nucleophilicity and basicity – SN1and SN2 mechanisms – Effect of substrate structure

- Effect of the attacking nucleophile – Effect of the leaving group – Effect of the reaction

medium – ambident nucleophiles – ambident substrates – neighbouring group participation

by n, π and σ bonds – SNi mechanism –– nucleophilic substitution at an allylic and a vinylic

carbon.

Aliphatic electrophilic substitution: Electrophilic substitution at saturated carbon –

SE1,SE2 and SEi mechanism.

Elimination: Elimination - E1, E2 and E1CB mechanism – stereochemistry of Elimination

– orientation of the double bond– Effect of changes in the substrates base, leaving group and

medium on E1, E2, and E1CB reactions – elimination Vs substitution – pyrolytic cis

eliminations – Bredts rule .


Unit II Addition to multiple bonds

Electrophilic, nucleophilic and free radical additions - addition to conjugated systems

– orientation of the addendum - stereochemical factors in reactions like addition of hydrogen,

halogens, hydrogen halides and hypohalous acids, hydroboration and hydroxylation -

epoxidation.

Addition to carbonyl groups – mechanism - Aldol condensation – Perkin reaction -

Knoevenagel reaction - Mannich reaction - Cannizaro reaction – Benzoin condensation -

Claisen ester condensation –Darzen‘s reaction - Reformatsky reaction - Wittig reaction –

Grignard reactions.

Addition to α,β -Unsaturated carbonyl groups : Addition of Grignard reagents to

α,β-unsaturated carbonyl compounds – Michael addition – Diels-Alder reaction .

Unit III Spectroscopy I

UV Spectroscopy: Principle - absorption spectra of conjugated dienes – α,β -

unsaturated carbonyl compounds – Woodward- Fieser rules - Scott‘s rules for aromatic

carbonyls.

IR Spectroscopy: Molecular vibrations – vibrational frequency - factors influencing

group frequencies – quantitative studies.

Mass Spectrometry: Principle – type of ions – base peak – parent ion, meta stable

and isotopic peaks – nitrogen rule – fragmentation - general rules - pattern of fragmentation

for compounds such as hydrocarbons, amines, alcohols, ketones, acids, phenols and nitro

compounds – McLafferty rearrangement – Retro Diels-Alder reaction.

UNIT IV Carbohydrates, Amino Acids, Proteins and terpenoids:

Carbohydrates: Methods used for determination of ring size – structure

elucidation of maltose, lactose and cellobiose - a brief study of starch and cellulose (structure

only).

Amino acids and Proteins: Amino acids - Peptides - Classification of proteins –

denaturation – structure of (primary, secondary, tertiary and quaternary) peptides - structural

elucidation of glutathione and oxytocin

Terpenoids: Classification of terpenoids – structural elucidation of α-pinene,

zingiberene and squalene.


Unit V Conformational analysis

Configuration and Conformation – Conformation of ethane, 1,2-dicholoro ethane and

n- butane - conformational analysis – stereoelectronic and steric factors - conformation of

simple acyclic compounds -conformation of monosubtituted and disubstituted cyclohexanes –

conformation of acyclic and cyclic systems with their physical and chemical properties –

conformational free energy – Curtin- Hammett principle - Quantitative treatment of Mobile

system - Eliel-Ro equation – conformations and reactivity of cyclohexanones.

Text books

Text book-1





Text book-2





Text Book- 3

Title of the book : Reactions, Rearrangements and Reagents

Name of the Author : Somorendra Nath Sanyal

Publisher : Bharati Bhawan Publishers


Text Book- 4

Title of the book : Elementary organic spectroscopy principles and chemical

applications

Name of the Author : Y.R.Sharma

Publisher : S.Chand and company Ltd, New Delhi

Edition/Year : Reprint /2012

Text book-5

Title of the book : Stereochemistry conformation and Mechanism

Name of the Author : P.S.Kalsi

Publisher : New age international publishers



Text book-6

Title of the book : Organic chemistry of natural products





Chapter-1(page No 12-33, 50-59)


Chapter -7 (Page No 7.1-7.61)

(From Text Book-3)

Chapter -2 (Page No 77-83, 97-107, 117-121,141-146,148-152,154-158,161-164,182-

185)

Unit-III (From Text Book-4)

Chapter-2 (Page No.9-12, 15-33, 34-42, 44-54)

Chapter-3 (Page No.69-82, 89-140)

Chapter-7 (Page No.280-328)


Chapter-1 (Page No.1.46-53, 1.115-123, 1.132-144)

Chapter-2 (Page No.2.62-93, 2.98-101)

Unit-V (From Text Book-5)


Reference Books

Reference Book-1

Title of the book : Stereochemistry of Organic Compounds, Principles and

Applications

Name of the Author : D.Nasipuri,

Publisher : New Age International (P) Ltd.,

Edition/Year : 2 / 1994.


Reference Book-2

Title of the book : Mechanism and Structure in Organic Chemistry,

Name of the Author : E.S. Gould,

Publisher : Henry Holt& Co.,New York ,


Reference Book-3

Title of the book : Organic Spectroscopy,

Name of the Author : William Kemp,

Publisher : ELBS,


Reference Book-4

Title of the book : Spectrometric Identification of Organic Compounds,

Name of the Author : Robert M.Silverstein, Francis X. Webster,

Publisher : John Wiley and Sons Inc.,


Reference Book-5

Title of the book : Spectroscopy of Organic Compounds,

Name of the Author : P.S.Kalsi,

Publisher : New Age International Publishers,


Reference Book-6

Title of the book : Advanced Organic Chemistry,

Name of the Author : Jerry March,



Reference Book-7

Title of the book : Stereo chemistry of carbon compounds,

Name of the Author : E.l.Eliel

Publisher : Mc Graw Hill

Edition/Year : Reprint 2008 /1975

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SYLLABUS

Programme : M.Sc., Chemistry Subject Code : P16CHC22

Semester : II No. of Hours allotted : 6 / week

Subject : Core Paper VII No. of Credits : 4

Title of the Paper : INORGANIC CHEMISTRY – II

BIOINORGANIC AND SOILD STATE CHEMISTRY- II

Objectives

To have an insight into study of coordination compounds and their reactions

To have an understanding of role of inorganic metal complexes in living systems

Unit I: Co-ordination Chemistry II

Theories of bonding - Werner theory –VB theory and CFT theory – splitting of d-

orbitals in Oh, Td, square planar and tetragonal distortion –Jahn-Teller distortions – CFSE

calculation in terms of Dq – factors affecting crystal field splitting – spectrochemical series –

applications of CFSE – MOT diagram of octahedral, Td and square planar complexes – effect

of π-donor and π-acceptor ligands – magnetic properties of transition metal complexes –

calculation of spin-only magnetic moments –orbital contribution to the magnetic moment –

spin orbit coupling.

Unit – II Bio – Inorganic Chemistry – I

Porphyrin ring system – metalloporphyrins – hemogolobin and myoglobin structures and

work functions – synthetic oxygen carries – cytochromes and its types – structure and work

functions in respiration – chlorophyll – structure – photosynthetic sequence – iron sulphur

proteins [ non – heme iron protein] – copper containing proteins – classification – blue

copper proteins – structure of blue copper electron transferases, copper proteins as Oxidases .

Unit – III Bio – Inorganic Chemistry – II

: Structure and function of Carboxypeptidase A –carbonic anhydrase – Inhibition and

poisoning – Corin ring system – Vitamin B12 and B12 Coenzymes – in – vivo and in – vitro

nitrogen fixation – essential and trace elements in biological systems- metal ion toxicity. -

Sodium and potassium ions pumps – chelate therapy – cis platin


Unit IV Acid – base systems and non aqueous solvents : Acid –base definition: Bronsted

– Lowry- Lux – flood- Solvent system – Lewis Usanovich – generalized acid – base concept

– steric effect on the strength of acids and bases – HSAB concept – Symbiosis.

Non Aqueous Solvents: Classification of solvents- A general study of typical reactions in

non aqueous media like liquid NH3, liquid HF, liquid N2O4 and liquid SO2 .

Unit V : Solid state chemistry II

Dislocation in solids- crystal defects-stoichiometric and non stoichiometric defects-

colour centers – Free electron and band theories – Types of solids – super conductivity –

High temperature super conductors – Types of semiconductors – Thermo electric power and

Hall effect - Photo voltaic effect – solar cell..

Text books

Text Book- 1


Name of the Author : B.R.Puri and L.R.Sharma and K.C. Kalia

Publisher : Milestone Publishers, New Delhi


Text Book- 2


Name of the Author : Wahid U.Malik et al



Text Book- 3

Title of the book : Concise Co-ordination Chemistry,

Name of the Author : R.Gopalan and V.Ramalingam,

Publisher : Vikas Publishing House PVT Ltd



764 to 780, )

Unit II (From Text Book 2)

Chapter 15, 16 and 17(Page No 510 to 550)

Unit III and IV ( From Text Book 3)


Unit IV Chapter 7 (Page No 260 to 274)

Unit V (From Text Book I)



Reference Books

Reference Book-1

Title of the book : An Introduction to Inorganic Chemistry

Name of the Author : K.F. Purcell and J.C. Koltz,

Publisher : W.B. Saunders Company, Philadelpha 1980


Reference Book-2





Reference Book-3

Title of the book : Introduction to solids

Name of the Author : L.V.Azaroff

Publisher : Tata Mc Graw Hill Publishing House


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SYLLABUS


Semester : II No. of Hours allotted: 6 / week

Subject : Core Paper VIII No. of Credits : 5

Title of the Paper : PHYSICAL CHEMISTRY - II

QUANTUM, CATALYSIS AND MOLECULAR SPECTROSCOPY

Objectives:

To apply the principles of quantum chemistry to simple systems, atomic and

molecular systems and to obtain their energies.

To understand the theory and applications of catalysis.

To get an insight into the principles of molecular spectroscopy

UNIT: I Application of Quantum Mechanics to Simple Systems

Derivation of Schrodinger wave equation (SWE). Application of SWE to simple

systems - particle moving in one dimensional box, particle moving in a 3-D box- degeneracy

– distortion, particle moving in a ring, rigid rotator, simple harmonic oscillator. Radial

wave function and radial probability distribution function. Shapes of various atomic orbitals.

UNIT : II Approximation Methods in Quantum Mechanics

Need for approximation methods (variation and Perturbation methods). Perturbation

corrections-first order correction. Schrodinger equation for He atom. Variation theorem-

application to hydrogen and He atoms. Hartee - Fock Self Consistent Field (HFSCF) theory-

application to He atom, HFSCF method of many electron system. Electron spin and Pauli

principle, anti symmetric nature of the wave functions, Slater rules and Born-Oppenheimer

approximation.

UNIT-III Statistical Thermodynamics

Aims of statistical thermodynamics, definitions of state of a system, ensembles

(micro, macro and grand canonical). Derivation of Boltzmann distribution law, Boltzmann-


Planck equation. Partition functions-thermodynamic properties from partition functions,

partition function and equilibrium constant. Quantum statistics –Fermi-Dirac and Bose-

Einstein statistics. Population inversion. Einstein‘s and Debye‘s theories of heat capacities of

solids. Nuclear spin statistics- ortho- and para- nuclear states-calculation of residual entropy

of H2 at 0 K in terms of ortho- and para- ratio.

UNIT:IV Catalysis

Catalysis - Types, characteristics and theory of catalysis. Heterogeneous catalysis-

kinetics, retardation and effect of temperature. Classification of catalysis. Enzyme catalysis –

characteristics, factors governing the rate of enzyme reaction. Mechanism of enzyme

catalysis (Michaelis Menten equation), Line weaver and Burk plot and Eadie‘s plot

Acid–Base catalysis –Mechanism and its kinetics. Hammett and Bronsted equation,

Acidity function. Langmuir – Heinshelwood and Langmuir – Rideal- mechanism. ARRT of

surface reactions – NH3 synthesis, cracking of hydrocarbons.

UNIT-V Molecular Spectroscopy-I

Electromagnetic spectrum. Types of molecular energies. Absorption and emission of

radiation. Einstein‘s coefficient-induced emission and absorption. Rotational spectra of rigid

diatomic molecules-isotope effect in rotational spectra. Microwave spectrometer.

Informations derived from rotational spectra.

Infrared spectroscopy. Vibrational energy of diatomic molecule-infrared selection

rules-diatomic vibrating rotator. Vibrations of polyatomic molecules - overtone, combination

and hot bands. Concept of group frequencies - coupling interaction. Fermi resonance-

Fourier transform infrared spectroscopy.

Text books

Text Book- 1

Title of the book : Introductory Quantum chemistry

Name of the Author : A.K.Chandra

Publisher : Tata McGraw –Hill Publishing Company Limited,New Delhi.


Text book-2






Text Book- 3



Publisher : Goel Publishing Co,Meerut.


Text Book- 4

Title of the book : Fundamentals of molecular spectroscopy

Name of the Author : Colin N. Banwell and Elaine M.McCash

Publisher : Tata McGraw- Hill Publishing Company Limited


Unit- I & II (From Text Book-1)

Chapter -3(Page No.39-55)





Unit-III (From Text Book-2) Chapter – 25 (Page No.892-910,919-923)

Unit -IV (From text book 3)

Chapter-15(Page No.841-872)

Unit- V (From Text book-4) Chapter-2&3(Page No. 31-98)

Chapter-4(Page No. 100-126)

Reference Books

Reference Book-1

Title of the book : Quantum chemistry

Name of the Author : R.K.Prasad

Publisher : New Age International Publishers, New Delhi


Reference Book-2

Title of the book : Molecular structure and spectroscopy

Name of the Author : G.Aruldhas

Publisher : PHI Learning (P) Limited, New Delhi


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SYLLABUS


Semester : II No. of Hours allotted: 6/ week

Subject : Paper IX Major Elective –II (a) No. of Credits : 4

Title of the Paper : ANALYTICAL CHEMISTRY

Objectives:


To learn the principle of electro analytical methods & spectroanalytical methods.

To gain knowledge on the basic concepts of error analysis

Unit-I: Precipitation Techniques

Introduction-properties of precipitates and precipitating reagents –colloidal

precipitates, Co-precipitation-post precipitation –precipitates from homogeneous solution –

surface adsorption –drying and ignition of precipitates –application of gravimetric methods

Unit-II: Error Analysis

Error analysis: Classification of errors-accuracy and precision-minimization of errors-

significant figures-significant figures in computation-statistical treatment of data: mean,

median, standard deviations, variance, relative standard deviation –spread, errors-standard

deviation of computed results-Student‘s t-test-F-test-comparison of the means of two

samples-correlation and regression: linear regression (least square analysis).

Unit-III Electro analytical methods

Electro analytical techniques: Electrogravimetry, theory of eletrogravimetric analysis-

electrolytic separation and determination of metal ions.Coulometry: Electrolytic cell-working

electrodes-auxiliary electrode and reference electrode- coulometric titrations Voltammetry:

Cyclic Voltammetry - stripping, voltammetry - chronopoteniometry. Amperometry:

Amperometric titrations.


Unit-IV: Thermoanalytical Methods

Thermal analysis, theory and principles of DTA and TGA- factors affecting the

position of DT and TG traces-application of DTA and TGA to the thermal behavior of the

following compounds-crystalline coppersulphate, calcium oxalate monohydrate, calcium

acetate monohydrate, zinc hexafluosilicate-complementary nature of DTA and TGA-

principle and application of DSC-determination of degree of conversion of high alumina

cement-purity determination-phase transition study –in forensic laboratory.

Unit-V: Spectroanalytical Methods

Colorimetry: Beer and Lambert‘s law-terminology-condition for a satisfactory

colorimetric analysis-method of colour measurement or comparison-principles of

colorimetric determinations of NH3, Cr, Cu, Fe, Mn-simultaneous spectrophotometer

determination of Cr and Mn.

Nephelometry and turbidimetry:principle-determination of sulphate and phosphate-

fluorimetry:principle-application of fluorimetry in the determination of Cd,Ca,and Zn and

determination of codeine and morphine in a mixture-flame spectrometry: theory-

interferences-AAS-applications in the determination of Mg+2

and Ca+2

in tap water ,V in

lubricating oil, trace lead in a ferrous alloy and trace elements in contaminated soil.

Text books

Text Book- 1

Title of the book : Elements of analytical chemistry

Name of the Author : R.Gopalan

Publisher : Sultan Chand & sons


Text Book- 2

Title of the book : Instrumental method of chemical analysis

Name of the Author : Gurdeep chatwal

Publisher : Himalaya publishing House



Chapter 9(Page No 121 to134)




Chapter 10(Page No 139 to 145,148 to 150)

(From Text Book-2)


Chapter 28(Page No 2.541 to 2.545)





Chapter 13 to 16(Page No 2.389 to 2.398 , 2.349 to 2.416, 2.367)

Reference Books

Reference Book-1,

Title of the book : Fundamentals of Analytical Chemistry,

Name of the Author : D.A.Skoog, D.M.West and F.J.Hollar

Publisher : Harcourt College Publishers,1


Reference Book-2

Title of the book : Instrumental Methods of Analysis

Name of the Author : H.H.Williard,L.L.Merritt and J.A.Dean

Publisher : East-West press New Delhi


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(For those who joining in 2016 -2017 and after)

SYLLABUS


Semester : II No. of Hours allotted: 6 / week

Subject : Paper IX-Major Elective –II (b) No. of Credits : 4

Title of the Paper : INDUSTRIAL CHEMISTRY

Objectives:


To understand the principle and importance of chemical technology

To utilize the raw materials in chemical industry

To get the awareness about the pollution and its control

Unit-I: Principles and Importance of chemical process industry

Introduction – importance of chemical industry – new developments in chemical

technology – classification of technologies processes – unit process and unit operation –

batch and continuous process – Indian chemical industry today – basic principles of

homogeneous and heterogeneous processes.

Unit-II: Raw Materials and Energy for Chemical Industry

Raw materials-Characteristics of raw materials and their resources- methods of raw

material concentration –integral utilization of raw materials

Energy for chemical industry-power and fuels-classification of fuels-coal-fuel gases

and liquid fuels-petroleum-cracking-chemical corrosion-types of corrosion and preventive

measures

Unit-III: Water Pollution and Its Control

Introduction – types of water –soft and hard water-softening of water– water

pollution – sources of water pollution – water pollutants – classification – physical, chemical

and biological – inorganic pollutants and toxic metals – organic pollutants – -pesticides and

fertilizers – suspended particles – water quality – ill effects of water pollutants – water


pollution control – water treatment – primary, secondary and tertiary treatment – desalination

– reverse osmosis – sewage and industrial waste water treatment.

Unit-IV: Small Scale Chemical Industries

Electro-thermal and electro-chemical industries:

Electric furnace - classification - manufacture of calcium carbide - Electrolytic

manufacturing and refining of aluminium - process and theory of electroplating.

oils, fats and waxes:

Manufacturing of soyabean oil-Analysis of oils,fats and waxes- manufacture of soap

by batch process - detergent (cationic ,anionic and non-ionic) –preparation, properties and

uses of potassium chlorate . .

Unit-V: Large Scale Chemical Industries

Manufacturing process - raw materials - composition and uses of products in Portland

cement – ceramics - plastics(Polyethylene, PVC) -- synthetic fibres (Nylon66, Nylon 6,

Terylene) - natural Rubber- Refining of crude rubber - Vulcanization of rubber and Synthetic

rubbers (BunaS, Neoprene) - fertilizers(Nitrogen and phosphate) Organic insecticides

(DDT,BHC)

Text Book- 1

Title of the book : ChemicalTechnology,Vol.1.

Name of the Author: 1.Mukhlyonov(ed.),

Publisher : Mir publication, Moscow


Text Book- 2

Title of the book : Enviromental Chemistry

Name of the Author : A.K.De

Publisher : New age International (P) Limited


Text book-3

Title of the book : Industrial chemistry

Name of the Author : B.K Sharma -

Publisher : Goel publishing house.


Text book-4

Title of the book : Outlines of Chemical Technology

Name of the Author : M.Gopala Rao Drydens

Publisher : East-West Press



Text Book- 5

Title of the book : Polymer Science

Name of the Author : V.R.Gowarikar, N.V.Viswanathan and Jayadev Sreedher, ―

Publisher : Wiley Eastern Ltd., New Delhi



Chapter 2( Page No 20-25,68-89)

Chapter 3( Page No90-118)

Chapter 4( Page No 136-158)

Chapter 5( Page No159-230)

(From textbook -4)

Chapter 1(Page No.)

Unit-II(From Text Book-1)

Chapter 7(page no.287-307,316-320)

(From Text Book-2)

Chapter 12(page no292-295)

Unit-III (From Text Book-2) Chapter -9 &10 (Page No. 170-267)

Unit-IV (From Text Book-3) Chapter -40 (Page No. 1153-1155, 1169-1171, 1176-1178, 1184-1186, 1296-1298,

1305-1306)


Unit-V (From Text Book- 5)

Chapter 9 (Page No 215 to 220

Reference Books

Reference Book-1

Title of the book : Industrial chemistry

Name of the Author : B.K Sharma

Publisher : Goel publishing house.

Edition/Year : 1/

Reference Book-2

Title of the book : Chemical process industries

Name of the Author : R.Norris shreve & J.A.Brink

Publisher : McGraw Hill


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SYLLABUS

Programme : M.Sc ., Chemistry Subject Code :P16CHC2P1

Semester : II No. of Hours allotted : 6 / week

Subject : Paper X Practical - II No. of Credits : 4

Title of the Paper : ORGANIC CHEMISTRY PRACTICAL

Objectives


To estimate the organic compounds quantitatively

To prepare organic compounds by two stage preparation

To separate and analyse the given organic mixture into two different components

Separation and analysis of two component mixtures. Identification of the

components and preparation of solid derivative.

Quantitative analysis:

a. Estimation of glucose by Lane and Eynon method and Bertrand method

b. Estimation of glycine.

c. Estimation of formaldehyde.

d. Estimation of ethylmethyl ketone

Organic preparations: (only for class work)

About 5 (five) two stage preparations:

a. p-Nitroaniline from acetanilide

b. Anthranilic acid from phthalimide

c. m-Nitrobenzoic acid from methyl benzoate

d. Benzanilide from benzophenone.

e. Acetylsalicylic acid from salicylic acid


Reference book-1:

Title of the book : Small Scale Preparations

Name of the Author : A.I. Vogel

Publisher : ELSB


Reference book -2

Title of the book : Basic principles of practical Chemistry

Name of the Author : V. Venkateswaran, R.Veerasamy, A.R Kulandaivelu

Publisher : Sultan chand & sons Publishers, New Delhi


Reference book -3

Title of the book : A Laboratory Manual of Organic Chemistry

Name of the Author : S. Murugan

Publisher : Bharathi Press

Edition/Year : 3/ 1988

Prepared by:

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Programme : M.Sc ., Chemistry Subject Code :P16CHC31

Semester : III No.of Hours allotted: 6 / week

Subject : Core Paper No of Credits :5

Title of the Paper : ORGANIC CHEMISTRY - III

REACTIONS, REAGENTS AND SPECTROSCOPY

Objectives

To understand the concept of Oxidation and reduction

To know the application of reagents in organic synthesis

To apply 1H NMR and

13C NMR methods in elucidating the structure and

identification of organic molecules.

To apply the principle of ORD and CD in elucidating the structure of organic

molecules.

To know the chemistry of vitamins.

UNIT: I Oxidation and reduction

Elimination of hydrogen and aromatization reactions – catalytic dehydrogenation –

mechanism and application of stereochemical aspect of the following oxidation – reduction

reactions : Oxidation reaction involving CrO3, SeO2, OsO4, lead tetra acetate, periodic acid,

N- bromosuccinimide, H2O2 - Oppenauer oxidation.

Catalytic hydrogenation – reaction involving lithium aluminium hydride, tri

isobutoxy aluminium hydride - DIBAL and sodium borohydride - Birch reduction –

Meerwein-Pondorf-Verley reduction – Wolff-Kishner reduction — Hydroboration.

UNIT :II Reagents in organic synthesis and Free radicals :

Gilman‘s reagent (lithium dimethylcuprate), lithium diisopropylamide(LDA),

Dicyclohexylcarbodiimide, 1,3-dithiane,Woodward and Prevost hydroxylation, Merrifield

resin, phase transfer catalysts, Peterson‘s synthesis and Baker‘s yeast.

Free radicals: Free radical reactions – halogenations, addition, oxidation, reduction

and rearrangement reactions – Barton, Sandmeyer, Gomberg, Bachmann, Ullmann, Pschorr

and Hundsdiecker reactions.


UNIT : III 1H NMR Spectroscopy :

1H NMR spectroscopy: Origin of NMR spectra – chemical shift, chemical shift

parameters – internal standards – factors affecting chemical shift, anisotropic effect, – NMR

concept of aromaticity – spin-spin coupling – coupling constant – first and second order

spectra– influence of stereochemical factors on chemical shift of protons – simplification of

complex spectra – deuterium substitution – spin decoupling and spin tickling – double

resonance – shift reagents – lanthanide shift reagents, chiral resolving reagents – Nuclear

Overhauser effect – CIDNP.

UNIT : IV 13

C NMR spectroscopy:

Natural abundance – H decoupling - Off-resonance decoupling – line intensities –

chemical shift equivalence - elementary study of alpha, beta and gamma effects -

hybridization of carbon - calculation of chemical shifts for aromatic and aliphatic

compounds , DEPT 13

C spectra - 13

C correlation spectroscopy - COSY, HETCOR, NOESY

and Inadequate.

Application: Application of spectral studies to characterize the organic compounds

Unit: V Chiro- optical and Analytical techniques and vitamins:

ORD and CD – principle - Cotton effect - type of ORD curves - α-haloketone rule -

octant rule - applications to determine the configuration and conformation of simple

monocyclic and bicyclic ketones-comparison of ORD and CD.

Vitamins : Introduction, classification, Structural elucidation of vitamins A, B1, B2,

B6, C, D2 and H

Text Books

Text book-1


Names of the Author : G.R.Chatwal



Text Book- 2




Edition/Year : 3 reprint / 2000


Text Book- 3

Title of the book : Elementary organic spectroscopy principles and chemical

applications

Name of the Author : Y.R.Sharma


Edition/Year : Reprint / 2012

Text Book- 4

Title of the book : Organic spectroscopy – principles and applications,

Name of the Author : Jag Mohan,

Publisher : Narosa Publishing House,

Edition/Year : 2/ 2003.


Chapter-17 (Page No.17.12-17, 27-48,56-70,91)

(From Text Book-2)

Chapter-2 (Page No.96-97, 146-148, 152-154)

Chapter-3 (Page No.199-202, 210-234, 237-246).


Chapter-17 (Page No.17.23-26)

(From Text Book-2)

Chapter-2 (Page No.91-94, 167-170, 177-180)



Chapter-5 (Page No.182-221,230-233)

(From Text Book-4)

Chapter-4 (Page No.187-197,203-256,269-288,296-306)




Chapter-5 (Page No.440-445,457-460)



Reference books:

Reference book1





Reference Book-2

Title of the book : Organic Spectroscopy,

Name of the Author : William Kemp,

Publisher : ELBS,

Edition/Year : 3 / 2008,

Reference Book-3

Title of the book : Spectrometric Identification of Organic Compounds,

Name of the Author : Robert M.Silverstein, Francis X. Webster,

Publisher : John Wiley and Sons Inc.,


Reference Book-4

Title of the book : Spectroscopy of Organic Compounds,

Name of the Author : P.S.Kalsi,

Publisher : New Age International Publishers,


Reference Book-5

Title of the book : Organic Chemistry of Natural Products volume I ,

Name of the Author : Gurdeep R. Chatwal,

Publisher : Himalaya PublishingHouse.



Reference Book-6

Title of the book : Organic Chemistry of Natural Products volume II,

Name of the Author : Gurdeep R. Chatwal



Reference Book-7

Title of the book : ORD and CD in Chemistry and Biochemistry

Name of the Author : P. Crabbe

Publisher : Academic Press,


Prepared by :

Signature :




SATTUR-626 203.



SYLLABUS

Programme : M.Sc ., Chemistry Subject Code : P16CHC32

Semester : III No. of Hours allotted: 6 / week

Subject : Core -Paper - XII No. of Credits : 5

Title of the Paper : INORGANIC CHEMISTRY III

INORGANIC SPECTROSCOPY AND NANO CHEMISTRY

Objectives:


to have an indepth study of spectral applications to the structural elucidation of

inorganic compounds.

to have an exposure to the nano technology

to understand the concept of molecular rearrangements reaction in coordination

complexes.

Unit : I Electronic Spectra of Transition Metal Complexes and Photochemistry:

d-d transition- charge transfer transition.- L-S coupling- Microstates –Term

symbol-selection rules – mechanism of breakdown of selection rules- bandwidths and shapes-

Jahn Teller effect –Orgel diagram --Tanabo-sugano diagram- Racah parameter- evaluation of

10Dq and Nephelauxetic ratio( β) for octahedral and tetrahedral complexes of d2,d

3,d

7 and d

8

configurations-photochemistry –photo redox and substitution reactions in Co(III) and Cr(III)

complexes.

Unit : II Application of Spectroscopy to the Study of Inorganic Compounds:

Mossbauer Spectroscopy:

Mossbauer effect- resonance absorption-Doppler effect- Doppler velocity –isomer

shift-magnetic hyperfine splitting-application of Mossbauer spectroscopy in the study of iron

and tin complexes.

NMR Spectroscopy: 31

P,19

F and 15

N – NMR – introduction –application in structural

problem-evaluation of rate constants –NMR of fluxional molecules –NMR of paramagnetic

molecules- contact shifts and shift reagents.


ESR Spectroscopy: Principle –presentation of the spectrum –hyperfine splitting- evaluation

of g values –factors affecting the magnitude of g –values-Zero field splitting –Kramer's

degeneracy---application of ESR in the study of transition of metal complex

UNIT : III Nanochemistry

Basic idea of nanoscience–Dimensional in nano structures-,0D,1D,2D and 3D ,

synthesis of nano materials -chemical method, sol gel , Chemical vapour deposition- Ball

milling-plasma Arcing- electrodeposition- Thermolysis

Carbon nanotubes: Types of carbon nano tubes- Structure, properties and applications of

single walled carbon nano tubes.

Nano Shells: Introduction-types- properties and applications (Ion slective film gold

nanoshell for Blood Immunoassay and cancer Detection and therapy.)

Nano polymers: Conductive polymer and Block copolymer.

Applications of nano materials- Insulation material-machine tools-high power magnets-

motor vehicle and Aircrafts.

Unit – IV Reaction Mechanism of Coordination compounds

Substitution reactions of octahedral complexes- Factors affecting reactivity octahedral of

complexes – – labile – inert complexes – Mechanism of acid hydrolysis, base hydrolysis and

anation reactions Substitution reactions of square planar complexes – Factors affecting

reactivity of square planar complexes – The trans- effect and its applications– Electron

transfer reactions – outer sphere and inner sphere electron transfer mechanisms-

complementary and non complementary reactions.

UNIT :V Molecular Rearrangements and Reaction of Coordinated Ligands:

Molecular rearrangement of four coordinated complex- six coordinated

complexes-reaction at coordinated ligands- reaction due to metal ion polarization of

coordinated ligands-hydrolysis of amino acid ester, amides and of peptides- Aldol

condensation-imine formation, hydrolysis and substituent exchange – the template effect and

macro cyclic ligands.


Text books

Text Book- 1


Name of the Author : B.R.Puri and L.R.Sharma and K.C.Kalia

Publisher : Milestone Publishers , New Delhi


Text Book- 2

Title of the book : Introduction to Nanotechnology

Name of the Author : Charles P.Poolee Jr. and Franck Owens,

Publisher : John-Wiley and Sons


Text Book- 3

Title of the book : Nano: the Essentials

Name of the Author : T.Pradeep

Publisher : Mc Graw-Hill Education,Delhi.


Text Book- 4

Title of the book : NanoTechnology

Name of the Author : Mick Wilson

Publisher : Overseas Press India Private Limited


Text Book-5

Title of the book : An Introduction to Inorganic Chemistry.

Name of the Author : K.F. Purcell and J.C Koltz ,

Publisher : W.B Saunders company,

Edition/Year : /1980

Text Book-6

Title of the book : .Spectroscopy

Name of the Author : B.K Sharma

Publisher : Geol Publishing House,Meerut


Text Book-7

Title of the book : .Slected topics in Inorganic Chemistry

Name of the Author : Wahid U.Malik ,G.D Tuli and R.D Madan

Publisher : S.Chand & company Ltd




Chapter 29 (Page No 822 to 838,872 to 876)


Chapter 14 (Page No 737 to760)


Chapter 3 (Page No 59 to 81)


Chapter 15 and 16(page No 510-542) )

Unit V (From Text Book -5) Chapter (Page No 757 to 791)

Reference Books

Reference Book-1





Reference Book-2

Title of the book : Physical Methods in Chemistry

Name of the Author : R.S.Drago

Publisher : W.B.Saunder company, London


Prepared by :

Signature :




SATTUR-626 203.



SYLLABUS



Subject : Core Paper VIII No. of Credits : 5

Title of the Paper : PHYSICAL CHEMISTRY – III

GROUP THEORY AND NANO CHEMISTRY

Objectives


To have an idea of symmetries of molecules and their fundamental concepts.

To apply the group theory to spectroscopy and molecular problems.

To know about the principles and instrumentation of nano chemistry.

To get a clear idea about various spectroscopic technique and their applications.

UNIT-I Group Theory

Molecular symmetry elements and symmetry operations. Matrix algebra- types of

matrices, matrix representation for symmetry operations (E,Cn,Sn,i, σ) and transformatuon

matrices. Group-definition and properties of a group, subgroup, isomorphic group and

classes. Group multiplication table for C2Vand C3V point groups. Representation of a group

- reducible and irreducible representations.

Great Orthogonality theorem. Construction of a character tables- C2V, C3V, C2h and

D2d. Standard reduction formula. Direct product – definition and its applications.

UNIT-II Application of Group Theory to Spectroscopy and Molecular Problems

Definition of molecular vibration, symmetry of normal mode analysis to water,

formaldehyde, ammonia, trans-N2F2 and ethylene molecule. Selection rules for IR and Raman

spectra. Selection rules for electronic transition in simple molecules like ethylene,

formaldehyde and benzene.


Group theory applied to hybridization (BCl3, PCl5, XeF4, SF6 and CH4). Simplication

for molecular orbital calculation- SALC procedure - HMO theory and delocalization energy

for cyclopropenyl ,butadiene and benzene systems.

UNIT-III Molecular Spectroscopy-II

Raman spectroscopy: Theories of Raman scattering, Rotational and vibrational

Raman spectra. Mutual exclusion principle- Laser Raman spectra. Electronic spectra of

diatomic and polyatomic molecules. Intensity of vibrational electronic spectra - Franck

Condon principle -rotational fine structure of electronic vibrational spectra. Fortrat parabola.

Dissociation and predissociation spectra.

NQR : Principles and applications –quadruple moment and electrical field, nuclear

quadruple resonance, nuclear quadruple coupling in atoms and molecules. Identification of

ionic character and hybridization.

UNIT-IV Spin Resonance Spectroscopy

NMR : Magnetic properties of nuclei, resonance condition, NMR instrumentation.

Chemical shift, spin-spin splitting, relaxation processes, line shape and line width. Double

resonance technique, ENDOR, Nuclear Overhauser effect, FT-NMR spectroscopy and

lanthanide shift reagents.

Photo electron spectroscopy – principle, XPS of elements, chemical shift, Koopman‘s

theorem, XPS of O2 molecule, valence electron photoelectron spectroscopy. UPS spectrum

of N2 and O2 molecule. Application of photoelectron spectroscopy.

UNIT : V Instrumentation in Nanochemistry:

Microscopic techniques for the characterization of nanomaterials – UV-Visible and

fluorescence spectroscopy AFM, SEM, TEM. X-ray diffraction and microanalysis.

Text books

Text Book- 1

Title of the book : Symmetry and spectroscopy of molecules

Name of the Author : K. Veera Reeddy

Publisher : New Age International Publishers



Text Book- 2

Title of the book : Group Theory in Chemistry

Name of the Author : V.Ramakrishnan and M.S. Gopinathan

Publisher : Vishal Publications


Text Book- 3

Title of the book : Fundamentals of molecular spectroscopy

Name of the Author : Colin N. Banwell and Elaine M.McCash

Publisher : Tata McGraw- Hill Publishing Company Limited


Text book-4





Text Book- 5

Title of the book : Instrumental methods of chemical analysis




Text Book- 6

Title of the book : Nano technology, basic science and emerging technologies


Publisher : Overseas Press India Private Limited,New Delhi.


Unit I (From Text book 1)





Unit II (From Text book 1)


(From Text book 2)


Unit III (From Text book 4)

Chapter-4(Page No. 2.83-2.99)

Unit IV (From Text book 3)

Chapter-7 (Page No. 199-219)

(From Text book-4)

Chapter-7 (page No. 416-420)

(From Text book 4)



Unit- V (From text book 5)



Reference Books

Reference Book-1

Title of the book : Group Theory and its applications to chemistry

Name of the Author : K.V.Raman

Publisher : Tata McGraw- Hill Publishing company limited


Reference Book-2

Title of the book : Chemical applications of Group Theory

Name of the Author : F.A. Cotton

Publisher : John Wiley & Sons,New york


Reference Book-3

Title of the book : A Simple approach to group theory in chemistry

Name of the Author : S. Swarnalakshmi,T. Saroja,R.M.Ezhilarasi

Publisher : Universities Press Private Ltd


Reference Book-4

Title of the book : Molecular structure and spectroscopy

Name of the Author : G.Aruldhas

Publisher : PHI Learning (P) Limited, New Delhi


Reference Book-5


Name of the Author : Charles P.Poolee Jr. and Franck Owens,

Publisher : John-Wiley and Sons


Reference Book-6


Name of the Author : T.Pradeep

Publisher : Mc Graw-Hill Education, Delhi.


Prepared by :

Signature :



SATTUR-626 203.



SYLLABUS

Programme : M.Sc ., Chemistry Subject Code :P16CHE31


Subject : Paper XIV - Major Elective III (a) No. of Credits : 4

Title of the Paper : COMPUTER APPLICATIONS

Objectives:

To study the basic concepts of VB and its application in chemistry.

To know about basic concepts of internet.

UNIT:1 Basic Concept of VB

Introduction to visual basic-the integrated development environment-the menu bar,tool

bar,the project explorer,the tool box,the properties of window,the form designer,the form lay

out,the immediate window,the elements of the interface-programming an application

common properties,common methods and common events-customising the environment.

Working with Forms: The appearance of form – the start up form – loading,

showing and hiding forms – elementary concepts of drag and drop operations.

Basic active X controls : Elementary concepts of Text Box control, the List Box and

ComboBox controls.

Variables – declaring variables – variable types – strings, numeric and data variables-

scope and life forms of variables – constants.

UNIT: II The Language Forms And Basic Active Controls

Control flow statements: If… Then and If… Then…Else. Loop statements : DO…

Loop,For…Next and While – Wend – nested control statement – the Exit statement.

Arrays : Declaring arrays – specifying arrays – multi dimensional arrays.

Procedures: Subroutines, functions, calling procedures – arrangements – arguments passing

mechanism – using optional arguments – functions returning arrays.


UNIT:III Applications of VB in Chemistry

Writing Simple programs in Chemistry :

1. Calculation of molecular weight of organic compound,

2. Ionic strength of an electrolyte,

3. Different velocities of a gas,

4. NMR frequency values of nuclei,

5. Average rate constant,

6. Unit cell dimensions,

7. Thermodynamic parameters,

8. Reduced mass,

9. Empirical formula of an organic compound containing C,H and O,

10. Normality, molality and molarity of a solution,

11. Half life period of a radioactive material,

12. Surface tension and

13. Temperature in Kelvin scale into Celsius and vice-versa.

Practical : (Class work only)

Construcion of programs in VB language, compiling, debugging and making

executive files, printing the output.

Running Simple VB programs in Chemistry to calculate/ determine the above

problems.

UNIT :IV Basic Concepts Of Communications Systems

Communication systems : Satellites – RADAR – optical fibers – advantages

and disadvantages – ISDN – distributed systems – advantages and disadvantages.

Telecommunications: analog and digital signals – types and needs of modulations –

MODEMS – Telecommunication software.

Computer networks : An overview – communication processors – protocols

– network architecture.

Practicals (Class work only)

1. Salient features of Windows and MS Word for typing texts and equations in Chemistry

– tabular columns – advanced concepts.

2. Basic concept of creating and accessing databases using MS Access.

3. Significance of Chemdraw – drawing chemical structures and pasting them in the text.


UNIT : V Basic Concepts of Internet and Applications in Chemistry

Internet: History of internet – the working way of internet – getting connected to internet

,internet protocols – internet addressing –domain names- internet services.

www : Web Pages–homepages –web browsers –search engines –internet chat – chatting on

web.

E-mail : Introduction – working way – mailing basics – e-mail ethics – advantages and

disadvantages – creating e-mail – receiving and sending e-mails.

Internet : characterisation – advantages – drawbacks – need for internet – extranet.

Applications of internet in Chemistry : Websites in Literature survey in chemistry –

popular websites in chemistry – data bases in chemistry - URLS – WAIS – downloading the

attachment / PDF files – opening ,browsing and searching a website literature searching

online.

Practicals (Class work only) :

1. Creating e-mail id,sending and receiving e- mail, attachment files, PDF files.Opening,

browsing and searching a website – down loading– literature survey in chemistry –

online searching.

Unit I To V Study material will be provided

Reference Book-1

Title of the book : Mastering Visual Basic 6

Name of the Author : Evangelos Petroutsos

Publisher : BPB Publication


Reference Book-2

Title of the book : Visual Basic 6 Super Bible

Name of the Author : David Jung, Pierre Boutqukin, John D. Conley III, Loren Eidahl

Publisher : First Indian Edition, Techmedia, New Delhi, 1999.


Reference Book-3

Title of the book : Visual Basic 6.

Name of the Author : Gary Cornell,

Publisher : Tata-McGraw Hill, New Delhi


Prepared by :

Signature :



SATTUR-626 203.



SYLLABUS



Subject : Paper XIV Major Elective – III (b) No. of Credits : 4

Title of the Paper : PHARMACEUTICAL CHEMISTRY

Objectives


1. Know the fundamentals of Medicinal Chemistry.

2. Learn uses of antibiotics and steroids.

3. Understand the concept of chemotherapy and its agents.

Unit-I Fundamentals of Medicinal chemistry

Definitions of Medicinal Chemistry, Pharmacology and molecular pharmacology,

pharmacodynamics, pharmacophore, pharmacodynamics agents - Structure Activity

Relationship (QSAR) – Hansch approach – account of physiological effects by hydroxyl,

aldehyde, ketone, acidic, nitro, nitrite, nitrile groups and unsaturation - drug receptors ,

mechanism of drug action on enzymes, gene function, biological membranes.

Unit-II Medicinally useful antibiotics and antimalarials

Classification of antibiotics - Structural features and SAR of the following

antibiotics - penicillin G, cephalosphorin and their semisynthetic analogs (β-lactam),

streptomycin (amino glycoside), terramycin (tetracycline), erythromycin(macrolide) ,

chloramphenicol and Rifamycin.

Unit-III Chemotherapeutic agents

Antineoplastic agents: Classification, synthesis and uses of Cyclophosphamide,

Clorambucil, Busulfan, Decarbazine, Methotrexate, 6-Mercaptopurine, 5-fluorouracil and

cisplatin,

Antitubercular drugs: Classification, synthesis and uses of Isoniazid, Rifampicin,

Pyrazinamine, Ethambutol and Ethionamide.


Anti malarial drugs: Classification, synthesis and uses of Chloroquin, Primaquine,

Amaodiaquine.

Diuretics: Classification, synthesis and uses of Fursemide, Acetazolamide,

Chlorothiazide.

Unit-IV Synthesis and Therapeutic action of certain drugs

Antihypertensive drugs: Nifedipine, Captopril, Sodiumnitroprusside, clonidine,

methyldopa and guanothidine.

Antihistamines: H1-Antagonists: Pheniramine, Mepyramine, Promethazine,

H2- Antagonists: Cimetidine, Ranitidine and fomotidine.

Unit- V

Anti-inflammatory drugs: Antipyratics & Non-narcotic analgesics: Aspirin, sodium

salicylate, paracetamol, phenylbutazone, oxyphenylbutazone, ibuprofen, Mephenamicacid,

Diclofenac sodium (preparation,structure and therapeutic uses only).

CNS Stimulant drugs: Amphetamine, Caffeine, Theobromine, Theophylline (structure and

therapeutic uses only).

CNS Depressent drugs: Phenelazine, Imipramine, Amitriptyline, Desipramine (structure and

therapeutic uses only).

Text books

Text Book- 1

Title of the book : Pharmaceutical chemistry-organic

Name of the Author : G.R.Chatwal



Text Book- 2

Title of the book : A Textbook of Pharmaceutical Chemistry

Name of the Author : Jayashree Ghosh

Publisher : S.Chand& Company Ltd


Text Book- 3

Title of the book : Medicinal chemistry





Text Book- 4

Title of the book : Text book of Pharmaceutical Organic chemistry

Name of the Author : Mohammad Ali

Publisher : CBS Publichers & distributors




Chapter – 3 (Page No. 41-45, 50-56, 62,63)




Unit-III (From Text Book- 3 )

Chapter – 31 (Page No 316-333, 283 to291, 264 to271)

Unit-IV (From Text Book- 3 )

Chapter – 19 (Page No 214 to224)



(From Text Book-4)


Reference Books

Reference Book-1

Title of the book : Medicinal Chemistry

Name of the Author : Sriram.D,Yogeeswari

Publisher : PESL

Edition/Year :2/2010

Reference Book-2

Title of the book : Medicinal Chemistry

Name of the Author : Kar.Ashutosh

Publisher : New age International Publishing House


Reference Book-3

Title of the book : Introductory Medicinal Chemistry..

Name of the Author : J.B Taylor and P.D Kennewell

Publisher : Ellisworth publishers


Prepared by :

Signature :




SATTUR-626 203.


(For those who joining in 2016--2017 and after )

SYLLABUS

Programme : M.Sc ., Chemistry Subject Code :P16CHC3P1


Subject : Paper XV PRACTICAL III No. of Credits :4

Title of the Paper : PHYSICAL CHEMISTRY PRACTICAL

Objectives:

To know about the practical applications of conductometry.

To appreciate the application of potentiometric technique in the quantitative analysis.

To understand the concepts of adsorption and Chemical kinetics by carrying out

experiments.

I. Conductometric Experiments

i. Double displacement & acid base titrations

a) NH4Cl-NaOH-Mixture of CH3COOH &HCl.

b) NH4Cl- NaOH- Mixture of NH4Cl &HCl.

ii. Precipitation titration

a) Na2CO3-Pb(NO3)2 – Na2CO3

b) b) K2SO4 – BaCl2 – K2SO4.

iii. Determination of dissociation constant of weak acids.

II Adsorption Experiments

Adsorption of oxalic acid/ Acetic acid on charcoal.

III Kinetic Experiments

i. Perdisulphate and iodide ion reaction: Study of primary salt effect and

determination of concentration of given KNO3.

IV Potentiometric methods

i. Precipitation titration : Ag vs. halide mixture

ii. Redox titrations : a) permanganate vs iodide ion

b) ceric ammonium sulphate vs. ferrous ion


iii. Determination of dissociation constant of weak acids and pH of

buffer solutions

iii. Determination of solubility product of sparingly soluble salts.

References:

Reference Book-1

Title of the book : Advanced Practical Physical Chemistry

Name of the Author : J.B. Yadav

Publisher : Goel Publications, Meerut


Reference Book-2

Title of the book : Practical physical Chemistry

Name of the Author : B.Viswanathan

Publisher : Vivas Book private limited




SATTUR-626 203.



Programme : M.Sc . Chemistry Subject Code :P16CHC41

Semester : IV No.of Hours allotted: 6 / week

Subject : Paper XVI -Core Paper No of Credits : 5

ORGANIC CHEMISTRY -IV

MOLECULAR REARRANGEMENTS AND SYNTHETIC METHODS

Objectives:

To know about the various types of molecular rearrangements.

To understanding the fundamental concept of photochemistry and free radicals.

To know about alkaloids and steroids.

To get insight into the principle of green chemistry.

To know the synthetic utility of reagents.

UNIT :I Molecular Rearrangements

Mechanism of the following rearrangement reactions: Wagner – Meerwein, Pinacol-

pinacolone, Demjanov, Beckmann, Hofmann, Curtius, Wolff, Baeyer-Villeger, Stevens,

Sommelet-Hauser, Favorskii, Benzil-benzilic acid, Claisen, Cope, Fries, Dienone-phenol and

Benzidine rearrangement – photo Fries rearrangements.

UNIT :II Photochemistry and Pericyclic Reactions

Basic principles of photochemistry - Jablonskii diagram – Norrish- I and Norrish-II

type reactions – Paternò–Büchi reaction – photochemistry of olefins and dienes – cis, trans

isomerisation - photosensitization - photoreduction .

Pericyclic reactions:

Conservation of orbital symmetry – electrocyclic reactions – cyclo addition

reactions and sigmatropic rearrangements –applications of correlation diagram approach

(butadiene and hexatriene), Frontier molecular approach, Huckel-Mobius approach to the

above reactions.


UNIT III: Steroids,Harmones and Alkaloids

Steroids and Harmones: Classification – structural elucidation of cholesterol,– male

sex harmones – androsterone and testosterone – female sex harmones – oestrone, equilenin

and progesterone

Alkaloids: General methods of structural determination – Hofmann, Emde and Von

Braun degradations. structural elucidation of quinine, reserpine, morphine (synthesis not

required) and lysergic acid

UNIT : IV Green Chemistry

Twelve basic principles of green chemistry, green starting materials, green catalyst

(zeolites as solid acid catalyst) and reagents (molecular oxygen ,tetrabutylammonium

tribromide), green solvents – applications of supercritical fluids, ionic liquids and water –

solvent free techniques.

Non-conventional microwave heating - interaction of microwave radiation with the

material-difference between conventional heating and microwave heating. Dielectric

polarization-dipolar polarization-applications and advantages of microwave heating over

conventional heating.

UNIT: V - Synthetic Methods

Planning a synthesis - molecular history - starting materials - Relay approach and

convergent approach to total synthesis - Retro synthetic analysis of simple organic

compounds - functional group inter conversions -use of activating and blocking groups in

synthesis - stereo selective problems of geometrical and optical isomerism - steric crowding

– Regioselectivity – Diastereoselectivity – Enantioselectivity - Umpolung synthesis -

Robinson annelation – A schematic analysis of the total synthesis of the following

compounds:, trans-9-methyl -1-decalone and 2,4-dimethyl-2-hydroxy pentanoic acid,

Isonootkatone.

Text books

Text book-1






Text Book- 2





Text Book- 3

Title of the book : Photochemistry and Pericyclic Reactions

Name of the Author : Jagdamba Singh and Jayasingh

Publisher : New age international (p) limited, New Delhi.


Text Book- 4

Title of the book : New trends in Green chemistry

Name of the Author : V.K Ahluwalia and Kidwai ,

Publisher : Anamaya publishing house, New Delhi.


Text Book- 5

Title of the book : Organic Synthesis,.

Name of the Author : R.E. Ireland,

Publisher : prentice-Hall of India Pvt. Ltd ,

Edition/Year : 2 reprint /1998

Text book-6

Title of the book : Organic chemistry of natural products Vol-I&vol-II

Name of the Author : G.R.Chatwal,

Publisher : Himalaya publishing House New Delhi,

Edition/Year : 4 & 5 /2007, 2009


Chapter 6 (Page No.398-413, 415-424, 434-440,454-460)

(From Text Book-2)

Chapter 2 (Page No.89-94, 107-109,121-133, 172-174, 180-187)


Chapter 6 (Page No.160-183)

Chapter 7 (Page No.184-212, 218-223)









Chapter 4 (Page No.4.1-4.25,4.59-4.68,4.76-4.82,4.90-4.92,4.95-4.96)

Chapter 3 (Page No.3.6-3.19, 3.66-76, 3.109-117, 3.123-137, )


Chapter 1&2 (Page No.1-4)



Chapter 7(Page No.27-28)




Chapter 2(Page No.17-52)

Chapter 3 (Page No.55-56,81-87)

Reference Books

Reference Book-1

Title of the book : Organic Chemistry,Vol II ,

Name of the Author : I.L.Finar

Publisher : ELBS Longmann


Reference Book-2

Title of the book : Advanced Organic Chemistry,.

Name of the Author : Jerry March




Reference Book-3

Title of the book : Green chemistry (Environmental Benign Reactions)

Name of the Autho : V.K Ahluwalia ,

Publisher : Aru Books India. New Delhi.


Reference Book-4

Title of the book : Green Chemistry (Environmental Friendly Alternatives)

Name of the Author : R.Sanghi and M.M. Srivastava,

Publisher : Narosa publishing House, New Delhi.


Reference Book-5

Title of the book : Reaction Mechanism in Organic Chemistry,

Name of the Author : S.M .Mukherji and Singh

Publisher : Macmillan India Ltd


Reference Book-6

Title of the book : Pericyclic Reactions,

Name of the Author : Sankarraman ,

Publisher : Wiley VCH.


Reference Book-8

Title of the book : Organic Chemistry of Natural Products volume II,





Reference Book-9

Title of the book : The Chemistry of Steroids,

Name of the Author : W.Klyne

Publisher : Reinhold


Prepared by :

Signature :



SATTUR-626 203.



SYLLABUS

Programme : M.Sc ., Chemistry Subject Code :P16CHC42

Semester : IV No. of hours allotted: 6 / week

Subject : Core Paper XVII No. of Credits : 5

Title of the Paper : INORGANIC CHEMISTRY -IV

NUCLEAR AND ORGANOMETALLIC CHEMISTRY

Objectives : To enable the students

to have a complete study of f-block elements.

to have an idea about various analytical techniques.

to learn principles and applications in nuclear chemistry.

Unit : I Structure of Nucleus and Radioactive Decay

Composition of the nucleus –nuclear Size, shape and density-Principle, radial

and magnetic quantum numbers n/p ratio- stability of nucleus packing fraction--mass defect

and binding energy.

Radioactive decay: Group displacement law – decay series – rate of disintegration -half life

period -average life period – secular and transient equilibria - theories of alpha decay, beta

decay, gamma emission, internal conversion and electron capture - Auger effect.

Unit : II Nuclear Fission and Fusion and Application of Radioactive Isotopes:

Bethe's notation of nuclear process - nuclear reaction energies (Q-values) – fission

-energy release in nuclear fission-mass distribution of fission products-theory of nuclear

fission -fissile and fertile isotopes – energy from nuclear fusion-thermonuclear reaction in

stars - Nuclear reactor--breeder reactor- waste disposal management.

Applications of radioactive isotopes: - chemical investigations-age determination-medical

field-agriculture and analytical techniques.


Unit :III Actinides and Lanthanides: Chemistry of Lanthanides and Actinides;

Position of lanthanides and actinides in periodic table – occurrence, extraction of

lanthanides from monazite sand -ion exchange and solvent extraction method. -Electronic

configuration-properties of lanthanides-oxidation state-lanthanide contraction and its

consequences-color of lanthanides ions- magnetic properties of lanthanides.

Actinides: separation of actinide elements-separation of Pu from fission products-electronic

configuration- oxidation state-comparison of lanthanides and actinides.

Unit: IV Electro Analytical and SpectroAnalytical Methods:

Electro analytical Techniques:

Electrogravimetry: Theory of electro gravimetric analysis - electrolytic separation

and determination of metal ions. Coulometry - coulometric titrations. Voltametry: cyclic

voltammetry-Amperometry: Amperometric titrations.

Thermo analytical Methods: Principle and applications of TGA and DTA

Spectro analytical Method: principle and applications of – Fluorimetry - nepheometry and

turbidimetry - flame photometry and atomic absorptions spectroscopy .

Unit – V

Complexes of п- acceptor ligands:

Synthesis, structure and bonding in metal carbonyls and nitrosyls – Application of

EAN rule. Synthesis, properties, structure and bonding in ferrocene- olefin and acetylene

complexes.

Catalysis using organometallic compounds

Oxidative addition – reductive elimination – insertion reaction Catalytic mechanism in

the following Reactions: hydrogenation of olefins (Wilkinson catalyst) - hydroformylation

(Oxoprocess) – acetic acid from methanol – oxidation of alkenes to aldehydes and Ketones

(Wacker process) – olefin polymerization (Ziegler – Natta) – Cyclo oligomerisation of

acetylenes (Reppe‘s or Wilke‘s catalysts).


Text books

Text Book- 1

Title of the book : Essential of Nuclear Chemistry

Name of the Author : H.I .Arnikar

Publisher : Wiley Eastern Ltd.,New Delhi


Text Book- 2

Title of the book : Nuclear Chemistry

Name of the Author : U.N.Dash

Publisher : Sultan Chand and Sons, New Delhi


Text Book- 3


Name of the Author : Wahid U.Malik ,Tuli, Madan



Text Book- 4

Title of the book : Instrumental Methods of chemical Analysis

Name of the Author : Gurdeep R.Chatwal



Text Book- 5

Title of the book : Advanced Inorganic Chemistry Vol II

Name of the Author : Satya Prakash

Publisher : S.Chand & Company LTD


Text Book- 6

Title of the book : Concise Co-ordination Chemistry,

Name of the Author : R.Gopalan and V.Ramalingam,

Publisher : Vikas Publishing House PVT Ltd


Unit I (From Text book-2)

Chapter - 1 ( section 1.5 to 1.6.4, 1.8.1, 1.8.2)

Chapter - 3 (section 3.2 to3.3, 3.6.1, 3.6.2,)

Chapter - 5 (Page no 195 to 201, 214 to 227)

Unit II (From Text book -1)

Chapter 5(section 5.1 to 5.2.6, 5.7 to 5.7.3, 5.9 ,5.10)

Chapter 6 (section6.2 ,6.3 6.9)

Chapter 7 (section 7.8.1 ,7.11)

Chapter 10 (section 10.7.1.10.7.3 to 10.7.6)



Chapter 9 and 10 (274 to 331)


Chapter 26 to29 (Page No 2.523 to 2.549)

Chapter 41 (Page No 2.701 ,2.719 to 2.738)

Chapter 13 to 16(Page No 2.340 to 2.415)



(From Text Book-6)


Reference Books

Reference Book-1

Title of the book : Source Book on Atomic Energy

Name of the Author : S.Glasstone,

Publisher : Van Nostrand Reinhold Company, New York


Reference Book-2

Title of the book : Fundamentals of Analytical Chemistry,

Name of the Author : D.A .Skoog and D.M. Weat

Publisher : Saunders college Puplishing co Philadelphia


Reference Book-2

Title of the book : Instrumental Methods of Analysis

Name of the Author : H.H..Willard, LL.Merritt and J.A.Dean,

Publisher : East- West press., New Delhi


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SYLLABUS

Programme : M.Sc ., Chemistry Subject Code:P16CHC43

Semester : IV No. of Hours allotted: 6 /week

Subject : Core Paper XVIII No. of Credits : 5

Title of the Paper : PHYSICAL CHEMISTRY -IV

CHEMICAL KINETICS, SURFACE, BIOPHYSICAL AND

PHOTOCHEMISTRY

Objectives:

To get themselves exposed to kinetics and mechanism.

To derive advance knowledge on solids and surface phenomena.

To learn concepts of non-equilibrium thermodynamics and bio-energetic.

To understand the fundamental concepts of photochemistry.

UNIT - I Chemical Kinetics I:

Chain reactions and its general characteristics. Study of kinetics of chain reactions

like H2-Br2 reaction, decomposition of acetaldehyde and N2O5. Study of H2-O2 explosive

reactions.

Unimolecular reaction rate theories – the simple Lindemann treatment,

Hishelwood‘s theory, Rice, Ramsperger and Kassel(RRK) theory, Marcus theory or Rice,

Ramsperger, Kassel and Marcus (RRKM) theory and Slater‘s theory. Principle of

microscopic reversibility and detailed balancing, Kinetic isotope effect. Reactions in solution

– influence of solvent dielectric constant, ionic strength (Bronsted- Bjerrum equation –

primary and secondary salt effects).

UNIT- II Chemical Kinetics II

Fast reactions techniques – chemical relaxation methods, temperature and pressure

jump methods, ultrasonic absorption technique, reactions in flow system, continuous and

stopped flow, shock wave tube methods; chemical kinetics in crossed molecular beams and

Flash photolysis.


UNIT - III Surface Chemistry

Introduction- adsorption of gases on solids- physisorption and chemisorptions –

adsorption isotherms- Freundlich-Langmuir, BET and Temkin adsorption isotherms – surface

tension-Gibbs adsorption isotherm-surface area determination–monolayer-preparation of LB

films – micelles - critical micellar concentration (CMC)-structure- reverse micelles-micro

emulsion.

UNIT - IV Biophysical Chemistry

Basic concept of non-equilibrium thermodynamics, Onsager reciprocal relationship

– Its application to biological systems. High energy metabolites – ATP and its role in

bioenergetics, transfer of potential and coupled reaction. Biological energy conversion in

catabolism and anabolism – Biophysical applications of Mossbauer Effect, NMR imaging.

Applications of spin labeling in membrane research – Molecular recognition.

UNIT - V Photo- and Radiation Chemistry :

Physical properties of the electronically excited molecules – excited state dipole

moments, pKa and redox potentials –photo physical processes in electronically excited

molecules – Fluorescence, phosphorescence and other deactivating processes. Stern - Volmer

equation and its applications – electronic energy transfer mechanisms – photosensitization

and chemiluminescence, Experimental techniques in photochemistry – light sources –

chemical actinometry – elementary aspects of photosynthesis, photochemical conversion and

storage of solar energy. Radiation chemistry – source of high energy – interaction of high

energy radiation with matter – radiolysis of water. Experimental techniques of radiation

chemistry- Dosimeter .

Text Book- 1

Title of the book : Chemical Kinetics

Name of the Author : K.J.Laidler

Publisher : Pearson Education Private Ltd, Delhi



Text Book- 2

Title of the book : Fast Reactions

Name of the Author : J.N.Bradley

Publisher : Clarendon Press Oxford

Edition/Year : 1975

Text Book- 3



Publisher : Goel Publishing Co,Meerut.


Text Book- 4

Title of the book : Fundamentals of Biochemistry

Name of the Author : J.N.Jain

Publisher : S.Chand & Company Ltd, New Delhi

Edition/year : 6 / 2005

Text Book- 5

Title of the book : Fundamentals of Photochemisty

Name of the Author : K.K. Rohatgi Mukherjee

Publisher : New age International (P) Limited


Text Book- 6

Title of the book : Essential of Nuclear chemistry

Name of the Author : H.J.Arnikar

Publisher : New Age International Publishers







Unit-II (From Text book-2)






Unit-III (From Text book-3)

Chapter-16(Page No. 873-880, 882-894. 905-909)

Chapter-17(Page No. 952-954, 1017-1021, 1028-1030)

Unit-IV (From Text book-4)


Unit- V (From text book -5)

Chapter - 4 (Section 4.7 to 4.9)


Chapter - 5 (section 5.1)

Chapter - 9 (section 9.5)

Chapter -10 (section 10.1)

(From text book -6)

Chapter -11 (section 11.1 to 11.7.5)

Reference Book-1





Reference Book-2





Reference Book-3

Title of the book : Physical chemistry on Surfaces

Name of the Author : A.W.Adamson

Publisher : John Wiley &Sons, New York


Reference Book-4

Title of the book : Principles of Biochemistry

Name of the Author : A.L.Lehninger

Publisher : CBS Publication,New Delhi

Edition/year : 1/1984

Reference Book-5





Prepared by :

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SYLLABUS


Semester : IV No. of Hours allotted : 6 / week

Subject : paper XIX Major Elective IV (a) No. of Credits : 4

Title of the Paper : INTRODUCTION TO NANOSCIENCE

Objectives :

To understand the basic concept of nano science.

To study the synthesis and applications of nano chemistry.

To know about the characterization of nano materials.

UNIT : I General Introduction

Forms of Matter – Crystal structures –electronic properties of atoms and solids –

surface energy and surface tension – defining nanodimensional materials – 0D, 1D and 2D

nanostructures – size dependence of properties – special properties resulting from

nanodimensionality – potential use of nanomaterials.

UNIT : II Synthesis of nanomaterials

General approaches – nucleation process – sizes of the crystal – influence of

nucleation rate on the size of the crystal – chemical methods – Sol-gel techniques – control of

grain size – Co- precipitation - hydrolysis – sonochemical method – colloidal precipitation –

bottom up and top down approaches – kinetically confined synthesis of nanoparticles.

UNIT :III Principle and Instrumentation

Spectrophotometry, XRD, EXAFS, XPS, SEM, TEM, AFM – application to

nanomaterials characterization.


UNIT : IV Optical properties of nanomaterials:

UV-Vis, IR absorption – photoluminescence and stimulated emission – nonlinear

optical mixing – photo conductivity Magnetic properties: concepts of dia-, para-, and ferro-

magnetism – exchange correlation – exchange interaction. Electrical properties: electrical

conductivity – Hall effect – charge carrier density – activation energy; electronic properties –

field emission properties.

UNIT: V Biological nanomaterials:

Sizes of building blocks – proteins – DNA double nanowire – enzymes – protein

synthesis – Micelles and vesicles – Biomimetic nanostructures – Worm micelles and Vesicles

from block copolymers.

Text books

Text Book- 1


Name of the Author : C.P. Poole

Publisher : John Wiley & Sons, INC.


Text Book- 2


Name of the Author : T. Pradeep

Publisher : Mc Grow-Hill Education, Delhi.


Text Book- 3

Title of the book : Nanotechnology


Publisher : Oversaes India pvt Ltd









Unit-IV&V (From Text Book-1)

Chapter – 4 ( Page No.80-93)

Chapter – 12 ( Page No.310-329)

Reference Book

Title of the book : The Chemistry of Nano Materials

Name of the Author : C.N.R.Rao

Publisher : Wiley-VCH –Verlag Gmoh and co

Edition/Year : volumes 1and 2 /1980

Reference Book

Title of the book : NanoTechnology

Name of the Author :S.Shanmugam

Publisher : NJP Publisher


Prepared by :

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SYLLABUS



Subject : paper XIX Major Elective IV (b) No. of Credits : 4

Title of the Paper : POLYMER CHEMISTRY

Objectives:

To understand the chemistry of polymerization.

To study about the utility of polymers in various field.

To know about the processing of polymers.

UNIT I : Classification of Polymers and Chemistry of Polymerisation

Classification of polymers: linear polymers, non-linear or branched polymers,

cross - linked polymers, homo chain hetero chain, homopolymers co-polymers block

polymers and graft polymers.

Chemistry of polymerisation: Types of polymerization – mechanism – chain,

growth, free radical, ionic, co-ordination, ring opening, metathetical, group transfer,

polyaddition and polycondensation polymerizations.

UNIT II : Individual Polymers

Individual polymers: Monomers required general methods of preparation, repeat

units and uses of the following polymers and resins - polyethylene, polystyrene,

polyacryloniltrile, polymethylmethacrylate, PVC, polytetra - fluoroethylene, polybutadienes

and polychloroprene, polyesters, polycarbonates, polyimides, polyamides (Kevlar),

polyurethanes, polyethylene, glycols, phenol - formaldehyde, urea- formaldehyde, melamine

– formaldehyde and epoxy resins.

UNIT III: Properties of Polymers

Intrinsic properties – processing properties – basic idea of isomerism of polymers –

configuration of polymer chain – geometrical structure - syndiotatic, isotatic and atatic

polymers.


Glass transition temperature: Definition – factors affecting glass transition

temperature – relationships between glass transition temperature and (a) molecular weight,

(b) melting point and (c) plasticizer – importance of glass transition temperature –

heat distortion temperature.

Molecular weight and size of polymers : Number average, weight average,

sedimentation and viscosity average molecular weights – molecular weights and degree of

polymerisation– poly dispersity – molecular weight distribution in polymers – size of

polymer molecules – kinetics of polymerization.

UNIT IV: Polymerisation Techniques Degradation and Uses of Polymers

Polymerisation Techniques: Bulk, solution, suspension, emulsion, melt

condensation and interfacial polycondensation polymerizations. Degradation: Types of

degradation – thermal, mechanical, ultrasonic and photodegradation – photo stabilizers –

oxidative degradation – antioxidants – hydrolytic degradation. Uses of polymers in

electronics and biomedicine.

UNIT V : Polymer Processing

Polymer processing: plastics (thermo and thermosetting), elastomers, fibres,

compounding, plasticizers, colorants, flame retardants. Compression and injection mouldings

– film extrusion and calendaring – die casting and rotational casting- thermofoaming –

reinforcing.

Text books

Text Book- 1

Title of the book : Polymer Science

Name of the Author : V.R.Gowarikar, N.V.Viswanathan and Jayadev Sreedher, ―

Publisher : Wiley Eastern Ltd., New Delhi


Text Book- 2

Title of the book : Principles of Polymer science

Name of the Author : N.V.Sastry

Publisher : Narosa Publishing House



Unit-I (From Text Book - 1)

Chapter – 1 (Page No 12-14)





Chapter – 3 (Page no 86 to 97)

Chapter – 6 (Page No150 to172)


Chapter – 2 (Page no: 71-85)

Chapter – 10 (Page no: 264-289)

Unit-V (From Text Book -1)

Chapter – (Page No.206-219)

Reference Books

Reference Book-1

Title of the book : Text book of polymer science

Name of the Author : F.W.Billmeyer

Publisher : JohnWiley and sons,New York


Reference Book-2

Title of the book : Text book of polymer chemistry

Name of the Author : B.K.Sharma

Publisher : Goel pub,House, Meerut.


Reference Book-3

Title of the book : Text book of Introductory polymer chemistry

Name of the Author : G.S.Mistra

Publisher : New Age International pub , New Delhi


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SYLLABUS

Programme : M.Sc .,Chemistry Subject Code :P16CHPT41


Subject : Paper XX No. of Credits : 4

Title of the Paper : Project Work and Viva-Voce

Objectives

To develop the ability of the students to prepare a project.

To get clear idea about the new concepts in our field apart from the syllabus.

Regulations for the Project Report

Evaluation method for project:

Max. Marks Credits

Internal External

Project Evaluation 40 40

Viva Voce 20

Total 100 4

1. 50% of the aggregate (Project Evaluation + Viva Voce+ Internal)

2. No separate pass minimum for internal.

3. 27 marks out of 60 is the pass minimum for the External.

Internal examiners are the respective supervisors.

Viva voce examination to be evaluated by the external examiner.

The report of the project must be in the prescribed form. It should be typed neatly in

MS word with the equation editor or using Latex. The font size of the letter should be

13 or points with double space.


The format of the project should have the following components.

First page should contain:

Title of the project report.

Name of the candidate

Register number.

Name of the supervisor.

Address of the institution

Month and year of submission.

1. Contents.

2. Declaration by candidate

3. Certificate by supervisor

4. Acknowledgement

5. Preface

6. Chapter 1 – Preliminaries.

7. Other chapters

8. References

The number of pages in the project may be 40 to 50

Each page should contain atleast 18 lines.

Four copies of the project report with spiral binding should be submitted.

Prepared by :

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SATTUR-626 203.



SYLLABUS

Programme : M.Sc .,Chemistry Subject Code :P16CHX41


Subject : Paper XX No. of Credits : 4

Title of the Paper : Extra credit Paper

Objectives:

To create an awareness of the NET/SET Examination

To make the students prepared for NET / SET Examinations

Unit I

i) Periodic properties – Atomic radius – ionic radius, ionization potential, electron

affinity and electronegativity – Their significance in chemical bonding.

ii) VB theory, MO theory – applications – Comparision of VB and MO theories –

VSEPR theory –Bond order – Bond energy – Bond length Bond polarity – Partial

ionic character of bonds – The conceptof multi-centre bond – Electron deficient

compounds – Hydrogen bond – Its influences.

iii) Non aqueous solvents – A general study of typical reactions in non aqueous

media – comparison with reactions in aqueous media.

iv) Nuclear – chemistry – Nuclear structure – Nuclear forces –Nuclear stability –

Nuclear modes – Modes of Radioactivity decay. Nuclear Reaction- fission and

fusion

v) Orgnometallic compounds – Metallecences – Arene complexes – Non aromatic

olefins and acetylenes complexes – catalysis by organometallic compounds

Wilkinson‘s catalyst – Oxoprocess –wacker process – Ziegler – Natta catalysis.

Unit II

i) Optical activity and concept of chirality – Different kinds of optically active

compounds – Absolute configuration - R and S Notations– Methods with more

than one chiral center – Asymmetric synthesis.

ii) Geometrical isomerism resulting from double bonds – The E.Z. system of

nomenclature –Geometrical isomerism of monocyclic compounds and fused ring

systems – Stereospecific and stereo selective reactions with examples.


iii) Organic reaction mechanisms – Aliphatic nucleophilic substituion SN1 and SN2

– stereo chemistry of nucleophilic reaction –Elimination reactions E1, E2, E1cB

Mechanism – dehydration of alcohols – dehydro halogenation – cope

elemination.

iv) Reagents in organic synthesis - DCC, DDQ ,selenium dioxide ,phase transfer

catalyst, LDA – Rearrangements:- Lossen, Schmitts, Baeyer – Villiger, Pinacol –

Pinacolene, Benzoil –Benzilic acid, Benzidine, Favorski and fries rearrangements

– sigmatropic rearragements – claisen and cope rearragements. Pericyclic

reactions, selection rules – orbital symmetry – Electrocyclic reactions – cyclic

additions - sigmatropic reactions.

Unit III

i) The old quantum theory – black body radiation – Photo electric effect –

Hydrogen spectrum – Compton effect- de Broglie equation – Heisenberg‘s

uncertainty principle – Postulates of quantum mechanics – Schrödinger

equation – Operator algebra – Linear and Hermitian operators –Eigen

functions and Eigen values – Hamiltonian operators – Angular momentum.

ii) Symmetry elements and symmetry operations – Point groups – reducible and

irreducible representations, characters tables – Orthogonality theorem and its

consequences. Symmetry selection rule for IR and Raman spectra -

symmetries of normal modes of vibration – symmetry applied to MO theory

and orbital hybridization.

iii) Thermodynamic equations of state – closed and open systems – partial molar

quantities –chemical potential with temperature and pressure – third law of

thermodynamics. Fugacity – methods of determination – activity and activity

co-efficient – Maxwell‘s distribution of molecular velocities – derivation of

expression for average, most probable and root mean square velocities –

Microstates Macro states – partial functions – Sacker tetrode equation.

iv) Hammett acidity function –Acid base catalysis Bronsted relation- Enzyme

catalysis – Michaelis Menton Law – influence of PH and temperature. Surface

phenomenon – Heterogeneous catalysis – Adsorption isotherms.

v) Electrolytic conductance – applications – solubility product – Inter ionic

attraction theory – Debye- Huckel – Onsager equation – equivalent


conductivity of electrolytes. Electrode potentials – Electrochemical cells –

electrode – electrolyte interface – electrical double layer electro capillary

phenomena – electro kinetic Phenomena – Membrane potential – Polarisation

–Butler-Volmer equation.

Unit-IV

i) UV Spectroscopy: Principle - absorption spectra of conjugated dienes – α,β -

unsaturated carbonyl compounds – Woodward- Fieser rules - Scott‘s rules for

aromatic carbonyls.

ii) IR Spectroscopy: Molecular vibrations – vibrational frequency - factors

influencing group frequencies – quantitative studies.

iii) 1H NMR spectroscopy: Theory of NMR – chemical shift- factors affecting

chemical shift, spin-spin coupling – coupling constant – spin-spin splitting –

simplification of complex spectra –double resonance – lanthanide shift reagents,

chiral resolving reagents – nuclear overhauser effect – NMR concept of

aromaticity.

iv) Mossbauer Spectroscopy: Mossbauer effect- resonance absorption-Doppler effect-

Doppler velocity –isomer shift-magnetic hyperfine splitting-application of

Mossbauer spectroscopy in the study of iron and tin complexes.

v) ESR Spectroscopy: Principle –presentation of the spectrum –hyperfine splitting-

evaluation of g values –factors affecting the magnitude of g –values-Zero field

splitting –Kramer's degeneracy---application of ESR in the study of transition of

metal complex

Unit V


i) Basic idea of nanoscience–Dimensional control in nano structures-,1D,2D and 3D

nano structures , synthesis of nano materials -chemical method, sol gel -Chemical

vapour deposition- Ball milling-plasma Arcing- electrodeposition- Thermolysis

ii) Carbon nanotubes: structure and characterization of single walled carbon nano

tubes-properties and applications of nano tubes.

iii) Nano polymers:Conductive polymer and Block copolymer.

iv) Twelve basic principles of green chemistry, green starting materials, green catalyst

and reagents -green solvents –applications of supercritical fluids, ionic liquids and

water – solvent free techniques- Non-conventional microwave heating - interaction

of microwave radiation with the material-difference between conventional heating

and microwave heating.

Text Books:

Text Book:1





Text book-2





Text book-3





Text Book- 4

Title of the book : Elementary organic spectroscopy principles and

chemical applications Name of the Author : Y.R.Sharma



Reference Book:1


CSIR-UGC NET/JRF/SET Chemical sciences - Hemant Kulshrestha, Ajay Taneja,

2010,Upkar‘s Publication.

Reference Book:2

CSIR-UGC NET/JRF/SET Chemical sciences - Helder, Trueman‘s Specific series(2012)

Prepared by:

Signature :

CHAIRMAN DEAN

m.sc. degree course in chemistry syllabus and...

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