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© Outotec - All rights reserved Metallurgy Key to Recycling Markus A. Reuter Director Technology Management Outotec Oy, Finland Adjunct Professor Aalto University Helsinki Guest Professor Central South University China Professorial Fellow University Melbourne Australia Sustainable use of Earth’s natural resources

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© Outotec - All rights reserved

Metallurgy – Key to Recycling

M a r k u s A . R e u t e rDirector – Technology Management Outotec Oy, Finland

Adjunct Professor Aalto University Helsinki

Guest Professor Central South University China

Professorial Fellow University Melbourne Australia

Sustainable use of Earth’s natural resources

© Outotec - All rights reserved

Sales EUR 2,078 million (2012)

• Over 5,745 national patents or applications,

630 patent families and 70 trademarks

Ranked Globally 12th most sustainable corporation• http://corporateknights.com/report/9th-annual-global-100

Knowledge in the processing of >60 elements

>130 Non-ferrous smelters (58 Flash, 56 TSLs, 17 Kaldo)• 2013 Flash Milestones (Tongling>400,000tpa & Fanchenguang>400,000tpa)

• ca. 50% Cu , >30% Sn in TSL , close to 40% PGM matte converting

• Ca. 70% Cu in China through Outotec

650 sulfuric acid plants• World’s largest metallurgical based, Zambia and largest in Ma’aden

Minerals Processing / Hydrometallurgy• 1100 grinding mills (28MW worlds’ largest saving around 15% energy)

• >10000 flotation units (reaching 500m3)

• 1800 thickeners / >3500 filters

Ironmaking and Ferroalloys• 20 pelletizing and sintering plants for chromites (ferroalloys),

• 13 ferroalloy smelters

• 340 iron ore sintering plants / 93 iron ore pelletizing plants

Light metals / Roasting / Waste to Energy• 290 fluidized bed roasting plants / alumina calcining

World’s largest

pellet plant

(7.5 million tpy)

Samarco; Brazil

Grinding mills

LKAB Sweden

Xiangguang Copper highest

environmental award

Chinese Government.

Outotec in Brief

2 NVMP30/08/2013

© Outotec - All rights reserved

Copper production (million tonnes/a)Outotec world leading technology provider for copper production

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EUROPE

CHINAJAPAN

AFRICAAUSTRALASIA

NORTH AMERICA

LATIN AMERICA

ASIA

3

Sources. ICSG Directory Excel tables - February 2013., Brook Hunt Global

Copper production Dec. 2012

NVMP30/08/2013

© Outotec - All rights reserved

Geological vis-à-vis Urban Mine “Minerals”“Mineral Centric” from classical mining equivalent to “Product Centric” in Urban Mining

4

Geological Minerals

Chalcopyrite CuFeS2

and

>15 minors

e.g. Au, Ag, PGMs, Se etc.

Designer “Minerals”>40 elements complexly linked

NVMP

Material combinations and Designed Consumer “Minerals”

Material connections

Joined Materials

30/08/2013

© Outotec - All rights reserved

Outotec Secondary Smelting Processes

Copper Recycling GRM Danyang

Smelter TSL (S. Korea)

E-Waste and Copper Recycling Dowa

TSL (Japan)

Lead Battery Recycling

Recylex TSL (Germany)

Xiangguang Yanggu Smelter

Kaldo (China)

Boliden – Rönnskår Smelter

Kaldo (Sweden)

5 30/08/2013 NVMP

Company Location Technology Feed Capacity

Dowa Mining Kosaka, Japan Ausmelt TSL 150,000

Korea Zinc Onsan, ROK Ausmelt TSL 70,000

Global Resources & Materials Danyang, ROK Ausmelt TSL 120,000

© Outotec - All rights reserved

6 30/08/2013

DOWA Flowsheet

Outotec

© Outotec - All rights reserved

Product Centric - Processing Infrastructure

7 NVMP30/08/2013

© Outotec - All rights reserved

Outotec understands the metals business

8 NVMP30/08/2013

M.A. Reuter et al., “UNEP Metal Recycling: Opportunities, Limits, Infrastructure”,

United Nations Environmental Programme 2013

http://www.unep.org/resourcepanel/Publications/MetalRecycling/tabid/106143/Default.

aspx.

© Outotec - All rights reserved

9

Top Submerged Lance (TSL)

NVMP30/08/2013

© Outotec - All rights reserved

Controlling the FurnaceControlling the slag…

10 NVMP30/08/2013

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% L

iqiu

id S

lag

Temperature (oC)

% Slag Liquid: Fe/SiO2=1.4 : %CaO=5: log(pO2)=-6

% Al2O3

FACT Sage 6.2/Reuter

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Temperature (oC)

% Slag Liquid: Fe/SiO2=1.2 : %CaO=5: log(pO2)=-6

% Al2O3

FACT Sage 6.2/Reuter

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% L

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Temperature (oC)

% Slag Liquid: Fe/SiO2=1 : %CaO=5: log(pO2)=-8

% Al2O3

FACT Sage 6.2/Reuter

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% Slag Liquid: Fe/SiO2=1.4: %CaO=5: log(pO2)=-10

% Al2O3

FACT Sage 6.2/Reuter

© Outotec - All rights reserved

Simulation results for 1% & 8% Al on PCBAt 1150, 1200 and 1250oC

11 NVMP30/08/2013

© Outotec - All rights reserved

Metal Recycling UNEP

12 NVMP30/08/2013

Launched April 24th 2013 by

UNEP via Bundesministerium

für Umwelt, Naturschutz und

Reaktorsicherheit (BMU) in

Berlin in the presence of the

German Federal Minister of

Environment.

Lead Author: Markus A. Reuter

© Outotec - All rights reserved

Sustainable use of Earth’s natural resources

www.outotec.com

www.outotec.com/sustainability