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Page 1: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

1

Introduction Initiators for high polymers

InitiatorsInitiatorsInitiators for High Polymers

Initiators

Page 2: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

Initiators Initiators for High Polymers

33

Akzo Nobel,

based in the Netherlands, is a multicultural organization serving

customers throughout the world with human and animal healthcare

products, coatings, and chemicals. We employ around 61,500

people and conduct our activities in 13 business units, with

operating subsidiaries in more than 80 countries.

www.akzonobel.com

Akzo Nobel’s Polymer Chemicals business unit, headquartered

in Chicago, USA, manufactures organic peroxides, metal alkyls,

organometallic specialties, polymer additives, and antifouling

and suspending agents for the polymer production and

processing industries. Some of these products fi nd various

other applications as well. We also serve the semiconductor

industry with high purity metalorganics.

www.akzonobel-polymerchemicals.com

Contents

4 Introduction

- Initiators for High Polymers

- Safety, Research & Development

6 Storage & Safety

- Half-life

- Storage temperatures

- SADT: Self-Accelerating

Decomposition Temperature

- Tem: Emergency temperature

- Tc: Control temperature

- UN Numbers

8 Packaging

- Standard packaging

- Liquid initiators

- Solid initiators

- Additional information

10 Product data

28 Product survey

30 Half-life chart

Contact us

All information concerning these products

and/or all suggestions for handling and use

contained herein are offered in good faith

and believed to be reliable. Akzo Nobel

Polymer Chemicals, however, makes no

warranty as to accuracy and/or sufficiency

of such information and/or suggestions, as

to the product’s merchantability or fitness

for any particular purpose, or that any

suggested use will not infringe any patent.

Nothing contained herein shall be

construed as granting or extending any

license under any patent. Buyer must

determine for himself, by preliminary tests

or otherwise, the suitability of these

product for his purposes. The information

contained herein supersedes all previously

issued bulletins on the subject matter

covered. The user may forward, distribute,

and/or photocopy this document only if

unaltered and complete, including all of its

headers and footers, and should refrain

from any unauthorized use. You may not

copy this document to a website.

© 2006 Akzo Nobel Polymer Chemicals

Code: 2161 BTB Communication

Issue: June 2006

Page 3: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

Organic peroxides are also important materials

in pharmaceutical and fine chemical synthesis

or as active pharmaceutical ingredient.

We are able to supply a comprehensive range

of initiators to meet all requirements with

respect to area of application, polymerization

temperature, rate of radical formation and

storage facilities.

Listed are the highest concentrations of

formulations for each phlegmatizer.

We invite you to visit us at www.akzonobel-

polymerchemicals.com for complete product

listings. Formulations with phlegmatizers or

concentrations other than those indicated as

well as unique custom blends of various

peroxides can be made available with due

observance of safety characteristics and the

appropriate environmental and transportation

regulations. Please consult your Akzo Nobel

account manager for your specific need.

We operate organic peroxide manufacturing

sites and distribution centers all around the

world including joint ventures Ankorit -

Russia, Kayaku Akzo Corporation - Japan,

and in China Tianjin Akzo Nobel Peroxides,

Keum Jung Akzo Nobel Peroxides and Akzo

Nobel Crosslinking Peroxides.

All production sites are certified with ISO

9001 and ISO 14001 in order to ensure the

highest product quality and strictest

compliance with environmental regulations.

Akzo Nobel is a Responsible Care® company

Initiators for High Polymers

We have a long history in the organic peroxides arena, starting with

dibenzoyl peroxide for the bleaching of flour in the early 1920’s.

This Akzo Nobel invention was the beginning of the production and

application of organic peroxides worldwide. Since then, many new

organic peroxides have been added to our product line, with the

growth of plastics in everyday life.

Today, we are the world’s largest producer

of initiators for free radical polymerization

of various monomers. The main area of

application is the manufacture of high

polymers such as acrylics, low density

polyethylene (LDPE), polyvinyl chloride (PVC),

controlled-rheology polypropylene (CR-PP)

and styrenics. The largest part of our

initiators program consists of organic

peroxides (O-O initiators) which can be

divided into classes such as peroxyesters,

peroxy(di)carbonates, diacyl peroxides,

dialkyl peroxides, peroxyketals and

hydroperoxides. In addition we supply azo

(N-N) initiators and carbon (C-C) initiators.

Safety, Research & Development

Thorough understanding and knowledge of free radical chemistry and

peroxide production technology is at the basis of the development

of new, more efficient and safer products serving customer needs.

With almost a century of experience we are your reliable and

innovative partner for the supply of organic peroxides.

The Continuous Initiator Dosing (CID) venture,

which is a process improvement technology

for the manufacture of PVC, is a good

example of our efforts in the field of R&D.

Technical support and product development

are mainly provided from laboratories in

Deventer - the Netherlands, Pasadena - Tx

USA, Los Reyes - Mexico and Tianjin - China.

The first is the site of the company’s

fundamental initiator R&D. In each continent

we have a team of Technical Development

Managers who are the liaison between the

market and R&D and facilitate the technology

transfer to and from our customers.

Our success in safely handling organic

peroxides is due to our long-term

commitment to safety.

The Safety Research laboratory in Deventer

participates in R&D by the development of

safe products and processes. Investigations

are performed with the objective to assure a

high level of safety in manufacturing, handling

and transport of our products.

4

Introduction5

Page 4: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

Storage temperatures

The Ts max. is the recommended maximum

storage temperature at which the product is

stable and quality loss will be minimal.

A minimum storage temperature (Ts min.) is

given if phase separation, crystallization or

solidification of the product is known to

occur below the temperature indicated. For

safety reasons it is also recommended to

store the product above the Ts min.

indicated.

SADT: Self-Accelerating Decomposition

Temperature

The SADT is the lowest temperature at

which self-accelerating decomposition may

occur with a substance in the packaging as

used in transport. Transportation

temperatures are derived from the SADT

according to the recommendations by the

United Nations Committee of Experts on

the Transport of Dangerous Goods.

Tem: Emergency temperature

The Tem is derived from the SADT and is the

temperature at which emergency

procedures must be implemented.

Tc: Control temperature

The Tc is also derived from the SADT and is

the maximum temperature at which the

product can be safely transported. The Tc

is not required if the SADT exceeds 50°C.

Both the Tem and Tc are related to safety

and do not apply to product quality.

To maintain product quality the

recommended storage temperatures

(Ts) have to be observed.

Half-life

The most important characteristic of a polymerization initiator is its rate of decomposition

expressed by its half-life (t1/2). For this reason, the initiators in this product catalog are

arranged in descending order of activity, based on the 1.0 hour half-life temperature.

The half-life is the time required to reduce the original initiator content at a given temperature

by 50%. With the exception of hydroperoxides, the half-life is determined by differential

scanning calorimetry-thermal activity monitoring (DSC-TAM) of a dilute solution of the

initiator in monochlorobenzene. Kinetic data of the decomposition of hydroperoxides in

monochlorobenzene are determined titrimetrically.

The tables in this catalog list the temperatures at which the half-lives are 0.1 hour,

1.0 hour and 10 hours.

6

Storage & Safety7

The half-life can be calculated from the

Arrhenius equation

The Arrhenius frequency factor (A) and

activation energy (Ea) are given in the

tables.

The residual concentration of the initiator

can be calculated by means of the equation

The initiators in this product catalog are

arranged in descending order of activity,

based on 1.0 hour half-life temperature.

[I] = [I0] · e-kd·t

kd = A · e-Ea/RT and t1/2 = ln2/kd

kd = rate constant for the initiator

dissociation in s-1

A = Arrhenius frequency factor in s-1

Ea = Activation energy for the initiator

dissociation in J/mole

R = 8.3142 J/mole·K

T = temperature in K

t1/2 = half-life in s

where

where

[I0] = original initiator concentration

[I] = initiator concentration at time t

t = time measured from the start of

decomposition in s

UN Numbers

All products accepted for transport are assigned to generic entry numbers according

to classification principles as described in the recommendations by the United Nations

Committee of Experts on the Transport of Dangerous Goods. An explanation of all

relevant UN numbers is given in table 1.

Classification of Initiators ( table 1)

UN No ClassificationAkzo Nobel

Hazard rating

Maximum

container size

Organic peroxides3101 type B; liquid

type B; liquid, temperature controlledVery High 25 kg (55 lb)

3111

3103 type C; liquid

type C; solid

type C; liquid, temperature controlled

type C; solid, temperature controlled

High 50 kg (110 lb)3104

3113

3114

3105 type D; liquid

type D; solid

type D; liquid, temperature controlled

type D; solid, temperature controlled

Medium 50 kg (110 lb)3106

3115

3116

3107 type E; liquid

type E; liquid, temperature controlled

type E; solid, temperature controlled

Low 400 kg (880 lb)3117

3118

3109 type F; liquid

type F; solid

type F; liquid, temperature controlled

Very Low IBC’s / Tanks3110

3119

None Non-dangerous good No Unrestricted

Self-reactive substances3226 type D; solid

Medium 50 kg (110 lb)3236 type D; solid, temperature controlled

3234 type C; solid, temperature controlled High 50 kg (110 lb)

Page 5: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

Standard packaging

We offer a variety of packaging options for

both liquid and solid initiators. The maximum

package size for each initiator is regulated

by the United Nations, based on the hazard

classification of the initiator as shown in

table 1 on page 7.

Liquid initiators

Liquid initiators from Akzo Nobel are

available in packages shown in table 2.

Package sizes expressed in gallons are only

available in North America.

Akzo Nobel was the first organic peroxide

producer to introduce intermediate bulk

containers (IBC). We have available a

reusable 1250 liter or 330 gallon stainless

steel container for diluted organic peroxides

and peroxide emulsions. In Europe we also

have available a 1000 liter composite

container for organic peroxide suspensions.

These IBC’s offer a balance of economy and

safety for the transportation, storage and

handling of organic peroxides. They offer

several advantages over smaller packages,

such as: reduced worker exposure to organic

peroxide vapors, elimination of packaging

waste and reduced handling or organic

peroxides and packaging.

The specially designed stainless steel IBC has

obtained approvals for the transport of

organic peroxides by road and by sea. The

spring-loaded clamping device, used as an

emergency vent, is an Akzo Nobel invention

and has been patented. The Akzo Nobel

development of a cooled trailer with IBC’s

connected to a manifold eliminates the

in-house handling and transport of IBC’s.

Peroxide formulations can be directly

pumped into storage tanks by a leak-free

dry-break connection. All unloading facilities

are present on the trailer.

Continuous investment in refrigerated trucks,

bulk tankers and dedicated reefers

(refrigerated containers) specifically designed

to safely transport our products is a

demonstration of our commitment to security

of supply. We also have multiple storage

locations for all initiators to shorten lead

times.

Solid initiators

Standard packages for our solid initiators are

shown in table 3.

Most solid initiators are packaged in

polyethylene bags inside non-returnable

corrugated boxes. The number of bags per

box varies, depending on the weight of

initiator per bag.

For the availability of our products in IBC’s,

bulk or non-standard packages, consult your

Akzo Nobel account manager.

Additional information

Material Safety Data Sheets (MSDS) and

Product Data Sheets (PDS) are available at

www.akzonobel-polymerchemicals.com

On request we also provide specific

publications on the application and the safe

handling and storage of our products.

Nourytainer, Trigonox, Perkadox and Nourytainer, Trigonox, Perkadox and Nourytainer, Trigonox, Perkadox Laurox are registered Laurox are registered Lauroxtrademarks of Akzo Nobel Chemicals BV or affiliates inone or more territories.

8

Packaging9

Liquid initiators ( table 2)

Package Volume Net Weight Comments

Bottle 1 gallon 7-8 lb packaged as 4 polyethylene bottles per non-returnable carton

HDPE can 20-30 liter (5.3-8 gallon) 15-25 kg (6.8-11.3 lb) returnable, single component, polyethylene container (Nourytainer®)

Drum

15 gallon 100 lb returnable polyethylene drum

55 gallon 300-410 lb polyethylene or steel drum

200 liter 150 kg steel drum

220 liter 165-190 kg returnable polyethylene drum

IBC

330 gallon 2000 lb reusable stainless steel container

1000 liter 800-1000 kg composite container

1250 liter 850-1100 kg reusable stainless steel container

Tank Truck7000 gallon

varies with product for transport of bulk shipments of dilute type F organic peroxides20 m3

Solid initiators ( table 3)

Package Net Weight Comments

Carton varies with product polyethylene bags inside non-returnable cardboard box

Crate varies with inner package polyethylene bags inside returnable plastic crate

Drum 20-25 kg (45-55 lb) fiber drum

Page 6: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

10

Product data www.akzonobel-polymerchemicals.com

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Listed are the highest concentrations of formulations for each phlegmatizer. Please contact us for your specific need.

11

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Diisobutyryl peroxide [3437-84-1] 174.2 9.18 57 39 23 3.37E+14 109.06

TRIGONOX® 187-C30

TRIGONOX 187-W26

CH3

CH3 CH3

C O O C

O O

CH CH CH3

30

26

2.76

2.39

solution in OMS

emulsion in water and methanol

-20

-20 -25

0

0

-10

-10

-20

-20

3115

3119

HDPE can

steel IBC

Cumyl peroxyneodecanoate [26748-47-0] 306.4 5.22 75 56 38 3.12E+14 114.59

TRIGONOX 99-C75

TRIGONOX 99-W50

CR C O O

O

CH3

CH3

R2

R175

50

3.92

2.61

solution in OMS

emulsion in water and methanol

-20

-20 -25

10

5

0

-5

-10

-15

3115

3119

HDPE can

steel IBC

R + R1 + R2 = C8H19

Di(3-methoxybutyl) peroxydicarbonate [52238-68-3] * 294.3 5.44 72 57 43 9.09E+18 143.29

TRIGONOX 181

CH3

O

CH3

O

O C O O C O

O O

CH3 CH CH2 CH2 CH2 CH2 CH CH3

50 2.72 solution in toluene -10 -20 10 0 -10 3115 HDPE can

1,1,3,3-Tetramethylbutyl peroxyneodecanoate [51240-95-0] 300.5 5.32 76 57 40 3.98E+14 115.79

TRIGONOX 423-C70

TRIGONOX 423-W50

CR C O O C

O

CH3R2

R1 CH3

C

CH3

CH3

CH2 CH3

70

50

3.73

2.66

solution in OMS

emulsion in water and methanol

-15

-15 -20

15

15

15

5

5

5

-5

-5

-5

3115

3119

3119

HDPE can

HDPE can

steel IBC

R + R1 + R2 = C8H19

Cumyl peroxyneoheptanoate [130097-36-8] ** 264.4 6.05 79 59 42 1.77E+14 114.27

TRIGONOX 197-C75

CR C O O C

O

CH3

CH3

R2

R175 4.54 solution in OMS -20 10 0 -10 3115 HDPE can

R + R1 + R2 = C5H13

tert-Amyl peroxyneodecanoate [68299-16-1] 258.4 6.19 81 61 43 1.47E+14 114.38

TRIGONOX 123-C75

CR C O O C

O

CH3R2

R1 CH3

C2H5

75 4.64 solution in OMS -15 -25 20 10 0 3115 HDPE can

R + R1 + R2 = C8H19

* Not listed on TSCA ** Not listed on EINECS/ELINCSOMS = Odorless mineral spirits

C

Page 7: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

12

Product data www.akzonobel-polymerchemicals.com

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Listed are the highest concentrations of formulations for each phlegmatizer. Please contact us for your specific need.

13

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Mixture of peroxydicarbonates [78350-78-4; 19910-65-7; 105-64-6] 80 62 45 7.69E+15 125.61

TRIGONOX ADC

TRIGONOX ADC-NS60

OR C O O C O

O O

R1

98

60

7.06

4.32

solution in diethylene glycol

bis(allyl carbonate)

solution in diethylene glycol

bis(allyl carbonate)

-20

-20

-30

-30

0

0

-10

-10

-20

-20

3111

3115

HDPE can

HDPE can

R, R1 : isopropyl or sec-butyl

Diisopropyl peroxydicarbonate [105-64-6] 206.2 7.76 82 64 47 3.35E+15 124.01

PERKADOX® IPP-NS27

CH3

O C O O C O

O O

CH3 CH3CH

CH3

CH

27 2.10 solution in diethylene glycol

bis(allyl carbonate)

-15 -15 5 -5 -15 3115 HDPE can

Di(4-tert-butylcyclohexyl) peroxydicarbonate [15520-11-3] 398.5 4.01 82 64 48 7.44E+15 126.39

PERKADOX 16

PERKADOX 16S

PERKADOX 16-W75

PERKADOX 16-W40CH3

CH3

O CC

CH3

CH3

CO O C O

O O

CH3 CH3

95.5

95.5

75

40

3.83

3.83

3.01

1.61

powder

powder

wet powder or cake

suspension in water

20

20

20

20 0

40

40

40

40

35

35

35

35

30

30

30

30

3114

3114

3114

3119

carton

carton

carton

HDPE can / plastic IBC

Di(2-ethylhexyl) peroxydicarbonate [16111-62-9] 346.5 4.62 83 64 47 1.83E+15 122.45

TRIGONOX EHPTRIGONOX EHP-C75TRIGONOX EHP-W60

TRIGONOX EHP-W40STRIGONOX EHPSTRIGONOX EHPS-C75

C2H5 C2H5

O C O O C O

O O

CH3 (CH2)3 (CH2)3CH CH2 CH2 CH CH3

987560

409875

4.533.462.77

1.854.533.46

liquidsolution in OMSemulsion in water and methanol

frozen fl akesliquidsolution in OMS

-20-15-15-20-15-20-15

-25-25-25

-25

0550505

-10-5-5

-10-5

-10-5

-20-15-15-20-15-20-15

3113311531193119311831133115

HDPE canHDPE canHDPE cansteel IBCcartonHDPE canHDPE can

tert-Butyl peroxyneodecanoate [26748-41-4] 244.4 6.55 84 64 46 1.52E+14 115.47

TRIGONOX 23

TRIGONOX 23-C75

TRIGONOX 23-C30

TRIGONOX 23-W50CR C O O C

O

CH3

CH3

CH3

R2

R195

75

30

50

6.22

4.91

1.96

3.27

liquid

solution in OMS

solution in OMS

emulsion in water and methanol

-10

-10

-10

-10

-30

-25

-25

15

20

20

20

15

5

10

10

10

5

-5

0

0

0

-5

3115

3115

3119

3119

3119

HDPE can

HDPE can

steel IBC

HDPE can

steel IBC

R + R1 + R2 = C8H19

Di-sec-butyl peroxydicarbonate [19910-65-7] 234.2 6.83 82 63 47 3.19E+15 123.85

TRIGONOX SBP

TRIGONOX SBP-C60

TRIGONOX SBPS

TRIGONOX SBPS-C60CH3

O C O O C O

O O

C2H5C2H5 CH

CH3

CH

98

60

98

60

6.69

4.10

6.69

4.10

liquid

solution in OMS

liquid

solution in OMS

-20

-20

-20

-20 -30

0

0

0

0

-10

-10

-10

-10

-20

-20

-20

-20

3113

3115

3113

3115

HDPE can

HDPE can

HDPE can

HDPE can

OMS = Odorless mineral spirits

Page 8: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

14

Product data www.akzonobel-polymerchemicals.com

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Listed are the highest concentrations of formulations for each phlegmatizer. Please contact us for your specific need.

15

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Dicetyl peroxydicarbonate [26322-14-5] 570.9 2.80 84 65 48 3.02E+15 124.30

PERKADOX 24-FL

PERKADOX 24L

PERKADOX 24-W33O C O O C O

O O

CH3 (CH2)15 (CH2)15 CH3

94.5

91

33

2.65

2.55

0.92

fl akes

powder

suspension in water

20

20

15 0

40

40

40

35

35

35

30

30

30

3116

3116

none

carton

carton

HDPE can / plastic IBC

1,1,3,3-Tetramethylbutyl peroxypivalate [22288-41-1] * 230.3 6.95 86 66 48 2.47E+14 117.50

TRIGONOX 425-C75

CH3 CH3CH2O OCC

CH3

CH3

C

CH3

CH3

C

CH3

CH3

O75 5.21 solution in OMS -15 -25 20 10 0 3115 HDPE can

tert-Butyl peroxyneoheptanoate [26748-38-9] 202.3 7.91 87 67 49 2.09E+14 117.56

TRIGONOX 257-C75

CR C O O C

CH3

CH3

O

R2

R1

CH3

75 5.93 solution in OMS -10 20 10 0 3115 HDPE can

R + R1 + R2 = C5H13

tert-Amyl peroxypivalate [29240-17-3] 188.3 8.50 91 72 55 4.12E+15 127.76

TRIGONOX 125-C75

CH3 CH3CH2O OCC

CH3

CH3

C

CH3

CH3

O75 6.37 solution in OMS -10 -30 25 15 10 3113 HDPE can

tert-Butyl peroxypivalate [927-07-1] 174.2 9.18 94 75 57 7.09E+14 123.59

TRIGONOX 25-C75

TRIGONOX 25-C25

CH3 CH3O OCC

CH3

CH3

C

CH3

CH3

O 75

25

6.89

2.30

solution in OMS

solution in OMS

-5

-5

-15

-20

20

25

15

10

15

10

0

10

5

3113

3119

3119

HDPE can

steel IBC

Bulk

Dimyristyl peroxydicarbonate [53220-22-7] 514.8 3.11 84 65 48 2.82E+15 124.10

PERKADOX 26

PERKADOX 26-W40

O C O O C O

O O

CH3 (CH2)13 (CH2)13 CH3

96

40

2.98

1.24

fl akes

suspension in water

15

15 0

35

35

30

25

25

20

20

20

15

3116

3119

3119

carton

HDPE can

plastic IBC

Di(3,5,5-trimethylhexanoyl) peroxide [3851-87-4] 314.5 5.09 96 77 59 2.84E+15 128.34

TRIGONOX 36-C75

TRIGONOX 36-C37.5

TRIGONOX 36-W50

CH3

CH3 CH3CH2 CH2CH

CH3

CHCH2 CH2C

CH3

CH3

C

CH3

CH3

C O O C

O O

75

37.5

50

3.82

1.91

2.54

solution in OMS

solution in OMS

emulsion in water and methanol

0

0

0

-10

0

-20

20

25

10

25

10

15

5

15

0

10

0

10

3115

3119

3119

3119

HDPE can

steel IBC

Bulk

HDPE can / IBC

* Not listed on TSCA OMS = Odorless mineral spirits

Page 9: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

16

Product data www.akzonobel-polymerchemicals.com

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Listed are the highest concentrations of formulations for each phlegmatizer. Please contact us for your specific need.

17

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Dilauroyl peroxide [105-74-8] 398.6 4.01 99 79 61 3.92E+14 123.37

LAUROX®

LAUROX S

LAUROX W-40

LAUROX W-25 C O O C

O O

CH3 (CH2)10(CH2)10 CH3

99

99

40

25

3.97

3.97

1.61

1.00

fl akes

powder

suspension in water

suspension in water

30

30

20

20

0

0

50

50

50

50

3106

3106

3109

none

carton

carton

HDPE can / IBC

HDPE can / IBC

Didecanoyl peroxide [762-12-9] 342.5 4.67 100 80 63 3.64E+15 130.48

PERKADOX SE-10

C O O C

O O

CH3 (CH2)8(CH2)8 CH3

98.5 4.60 fl akes 10 40 35 30 3114 carton

2,2’-Azodi(isobutyronitrile) [78-67-1] 164.2 101 82 64 2.89E+15 130.23

PERKADOX AIBN

C N N

CH3

CN

C

CH3

CN

CH3 CH3

98 solid 25 50 45 40 3234 carton / fi ber drum

2,2’-Azodi(2-methylbutyronitrile) [13472-08-7] 192.3 104 84 66 1.38E+15 128.93

PERKADOX AMBN-GR

C N N

CH3

CN

C

CH3

CN

CH3 CH3CH2 CH2

98 granules 25 45 40 35 3236 carton / fi ber drum

2,5-Dimethyl-2,5-di(2-ethylhexanoylperoxy)hexane [13052-09-0] 430.6 7.43 105 86 68 2.19E+15 130.88

TRIGONOX 141

CH2 CH2CH C

CH3

CH3

C

CH3

CH3

C O O O O

O

C

O

CH3 CH3(CH2)3 (CH2)3

C2H5

CH

C2H5

90 6.69 liquid 15 -20 35 25 20 3113 HDPE can

1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoate [22288-43-3] 272.4 5.87 109 88 69 1.62E+14 123.80

TRIGONOX 421

CH2CH C

CH3

CH3

C

CH3

CH3

C O O

O

CH3 CH3(CH2)3

C2H5

90 5.29 liquid 5 -20 30 20 15 3115 HDPE can

tert-Amyl peroxy-2-ethylhexanoate [686-31-7] 230.3 6.95 111 91 73 1.77E+15 132.11

TRIGONOX 121

TRIGONOX 121-C75

CH2CH C

CH3

CH3

C O O

O

CH3 CH3(CH2)3

C2H5

95

75

6.60

5.21

liquid

solution in OMS

5

10

-20 35

35

25

25

20

20

3115

3115

HDPE can

HDPE can

OMS = Odorless mineral spirits

Page 10: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

18

Product data www.akzonobel-polymerchemicals.com

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Listed are the highest concentrations of formulations for each phlegmatizer. Please contact us for your specific need.

19

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Dibenzoyl peroxide [94-36-0] 242.2 6.61 113 91 71 6.94E+13 122.35

PERKADOX L-W75

PERKADOX L-W40

PERKADOX L-DFG

PERKADOX API C O O C

O O75

40

75

75

4.95

2.64

4.95

4.95

wet powder

suspension in water

micronized powder

micronized powder

40

30

40

40

0

80

60

80

80

3104

3109

3104

3104

carton

HDPE can

carton

carton

tert-Butyl peroxy-2-ethylhexanoate [3006-82-4] 216.3 7.40 113 91 72 1.54E+14 124.90

TRIGONOX 21S

TRIGONOX 21-C70

TRIGONOX 21-C30 CH3CH C

CH3

CH3

C O O

O

CH3 (CH2)3

C2H5

97

70

30

7.17

5.18

2.22

liquid

solution in OMS

solution in OMS

10

10

10

-30

-30

35

35

25

25

25

20

20

20

15

3113

3113

3119

HDPE can

HDPE can

Bulk

tert-Butyl peroxydiethylacetate [2550-33-6] 188.3 8.50 113 93 75 2.45E+15 134.00

TRIGONOX 27

CH3CH C

CH3

CH3

C O O

O

C2H5

C2H5

96 8.16 liquid 15 -30 35 25 20 3113 HDPE can

tert-Butyl peroxyisobutyrate [109-13-7] 160.2 9.99 118 98 79 2.07E+15 135.16

TRIGONOX 41-C50

CH3CH C

CH3

CH3

C O O

O

CH3

CH3

50 4.99 solution in OMS 10 30 20 15 3115 HDPE can

1,1’-Azodi(hexahydrobenzonitrile) [2094-98-6] 224.3 123 103 85 1.10E+16 142.19

PERKADOX ACCN

N N

CN NC

98 powder 35 80 3226 fi ber drum

1,1-Di(tert-amylperoxy)cyclohexane [15667-10-4] 288.4 11.09 126 106 87 3.29E+15 139.46

TRIGONOX 122-C80

C2H5 OOC

CH3

CH3

C2H5O O C

CH3

CH3

80 8.88 solution in OMS 30 55 3103 HDPE can

1,1-Di(tert-butylperoxy)-3,3,5-trimethylcyclohexane [6731-36-8] 302.5 10.58 128 105 85 7.59E+13 127.52

TRIGONOX 29

TRIGONOX 29-B90

TRIGONOX 29-C75CH3 OOC

CH3

CH3

CH3O O C

CH3

CH3

CH3CH3CH3

95

90

75

10.05

9.52

7.93

liquid

solution in dibutyl phthalate

solution in OMS

25

25

25

-10

60

60

60

3101

3103

3103

HDPE can

HDPE can

HDPE can

OMS = Odorless mineral spirits

Page 11: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

20

Product data www.akzonobel-polymerchemicals.com

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Listed are the highest concentrations of formulations for each phlegmatizer. Please contact us for your specific need.

21

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

1,1-Di(tert-butylperoxy)cyclohexane [3006-86-8] 260.4 12.29 134 113 94 3.47E+15 142.40

TRIGONOX 22-B50

TRIGONOX 22-E50

TRIGONOX 22-C80 CH3 OOC

CH3

CH3

CH3O O C

CH3

CH3

50

50

80

6.14

6.14

9.83

solution in dibutyl phthalate

solution in mineral oil

solution in OMS

25

25

25

70

70

60

3105

3105

3103

HDPE can

HDPE can

HDPE can

tert-Amylperoxy 2-ethylhexyl carbonate [70833-40-8] 260.4 6.14 134 113 95 2.22E+16 148.41

TRIGONOX 131

CH2 CH3CH C

CH3

CH3

C OO O

O

CH3 CH2(CH2)3

C2H5

94 5.78 liquid 20 55 3105 HDPE can

tert-Amyl peroxyacetate [690-83-5] 146.2 10.94 134 114 96 6.59E+16 152.16

TRIGONOX 133-CK60

C

CH3

CH3

C O O

O

CH3 C2H5

60 6.57 solution in OMS 30 60 3107 HDPE can

tert-Butyl peroxy-3,5,5-trimethylhexanoate [13122-18-4] 230.3 6.95 135 114 94 1.94E+15 140.78

TRIGONOX 42S

TRIGONOX 42-C30

CH3

CH3 CH2 CH2CHC

CH3

CH3

CH3O OC C

CH3

CH3

O97

30

6.74

2.08

liquid

solution in OMS

25

25

-20

-20

55

55

45 40 35

3105

3109

3119

HDPE can

steel IBC

Bulk

tert-Butylperoxy isopropyl carbonate [2372-21-6] 176.2 9.08 137 117 98 2.49E+16 150.15

TRIGONOX BPIC-C75 75 6.81 solution in OMS 25 -20 70 3103 HDPE can

tert-Butylperoxy 2-ethylhexyl carbonate [34443-12-4] 246.3 6.49 137 117 98 4.07E+16 151.72

TRIGONOX 117

CH3CH C

CH3

CH3

C OO O

O

CH3 CH2(CH2)3

C2H5

95 6.17 liquid 20 55 3105 HDPE can

2,2-Di(tert-butylperoxy)butane [2167-23-9] 234.3 13.66 136 116 98 9.30E+16 154.08

TRIGONOX D-C50

TRIGONOX D-E50

CH3 C

CH3

CH3

C

CH3

C2H5

CH3O OO O C

CH3

CH3

50

50

6.83

6.83

solution in OMS

solution in mineral oil

30

30

70

80

3103

3103

HDPE can

HDPE can

OMS = Odorless mineral spirits

Page 12: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

22

Product data www.akzonobel-polymerchemicals.com

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Listed are the highest concentrations of formulations for each phlegmatizer. Please contact us for your specific need.

23

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

tert-Amyl peroxybenzoate [4511-39-1] 208.3 7.68 139 118 99 8.38E+15 147.02

TRIGONOX 127

C O O C

O

CH3

C2H5

CH394 7.22 liquid 20 60 3103 HDPE can

tert-Butyl peroxyacetate [107-71-1] 132.2 12.11 139 119 100 1.57E+16 149.36

TRIGONOX F-C50

TRIGONOX F-CE30

C O O C

O

CH3

CH3CH3

CH350

30

6.05

3.63

solution in OMS

solution in isoparaffi ns

10

10

-15 70

40 35 30

3103

3109

HDPE can

Bulk

Butyl 4,4-di(tert-butylperoxy)valerate [995-33-5] 334.5 9.57 143 121 102 1.91E+15 143.51

TRIGONOX 17

CH3 C

CH3

CH3

C

CH3

CH3O OO O C

CH3

CH3

(CH2)3

(CH2)2

O

OC CH3

95 9.09 liquid 30 60 3103 HDPE can

Di-tert-amyl peroxide [10508-09-5] 174.3 9.18 150 128 108 4.02E+15 148.35

TRIGONOX 201

CH2CH3 CH3C

CH3

CH3

C

CH3

CH3

CH2O O

95 8.72 liquid 30 80 3107 HDPE can

Dicumyl peroxide [80-43-3] 270.4 5.92 154 132 112 9.24E+15 152.67

PERKADOX BC-FF

C

CH3

CH3

C

CH3

CH3

O O

99 5.86 crystals 30 75 3110 HDPE can

tert-Butyl peroxybenzoate [614-45-9] 194.2 8.24 142 122 103 2.23E+16 151.59

TRIGONOX C

TRIGONOX C-C75

C O O C

O

CH3

CH3

CH398

75

8.07

6.18

liquid

solution in OMS

25

25

10

0

60

60

3103

3105

HDPE can

HDPE can

OMS = Odorless mineral spirits

Page 13: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

24

Product data www.akzonobel-polymerchemicals.com

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Listed are the highest concentrations of formulations for each phlegmatizer. Please contact us for your specific need.

25

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Di(tert-butylperoxyisopropyl)benzene [25155-25-3] 338.5 9.45 156 134 114 7.65E+15 152.69

PERKADOX 14

PERKADOX 14S-FL

CH3 O OC

CH3

CH3

C

CH3

CH3

CH3O OC

CH3

CH3

C

CH3

CH3

90

96

8.51

9.08

solid

fl akes

30

15

80

80

3106

3106

HDPE drum

carton

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane [78-63-7] 290.4 11.02 156 134 115 1.68E+16 155.49

TRIGONOX 101

TRIGONOX 101-50D-PD

TRIGONOX 101-20PP

TRIGONOX 101-7.5PP-PD

TRIGONOX 101-E30 CH3 O OC

CH3

CH3

C

CH3

CH3

CH2 CH2 O OC

CH3

CH3

C

CH3

CH3

CH3

92

50

20

7.5

30

10.14

5.51

2.20

0.83

3.31

liquid

on silica, powder

on polypropylene, beads

on polypropylene, powder

solution in mineral oil

40

30

30

30

40

10

10

80

80

70

70

70

60

3105

3106

3108

none

3109

3109

HDPE can / HDPE drum

carton

carton

carton

HDPE drum

steel IBC

tert-Butyl cumyl peroxide [3457-61-2] 208.3 7.68 159 136 115 1.17E+15 146.98

TRIGONOX T

O OC

CH3

CH3

C

CH3

CH3

CH3

95 7.30 liquid 40 10 80 3107 HDPE can

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3 [1068-27-5] 286.4 11.17 164 141 120 1.90E+15 150.67

TRIGONOX 145-E85

CH3 O OC

CH3

CH3

C C C

CH3

CH3

CH3O OC

CH3

CH3

C

CH3

CH3

85 9.50 solution in mineral oil 30 10 80 3103 HDPE can

Di-tert-butyl peroxide [110-05-4] 146.2 10.94 164 141 121 4.20E+15 153.46

TRIGONOX B

TRIGONOX B-C50

TRIGONOX B-C30 CH3 O OC

CH3

CH3

C

CH3

CH3

CH3

99

50

30

10.83

5.47

3.28

liquid

solution in OMS

solution in OMS

40

40

40

-30

-30

80

80

80

65

3107

3109

3109

3109

HDPE can / steel drum

steel IBC

steel IBC

Bulk

3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane [24748-23-0] 264.3 18.16 170 146 125 1.02E+15 150.23

TRIGONOX 301

TRIGONOX 301-25PP

CH2CH3 CH3

CH3CH2CH3

C

CC

O

O O

OO

O

CH2CH3 CH341

10

7.45

1.82

solution in isoparaffi ns

on polypropylene, beads

40

40

0

0

110

90

3105

3110

HDPE can

carton

OMS = Odorless mineral spirits

Page 14: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

26

Product data www.akzonobel-polymerchemicals.com

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Listed are the highest concentrations of formulations for each phlegmatizer. Please contact us for your specific need.

27

Product name Chemical name [CAS number] General data Storage data Kinetic data Safety data Standard package type

See also pages 8 - 9Molecular

weight

Assay

(%)

Active

oxygen (%)Physical form

Ts max.

(°C)

TS min.

(°C)

T (°C) for t1/2 A

(1/s)

Ea

(kJ/mole)

SADT

(°C)

Tem

(°C)

Tc

(°C)

UN

No.0.1 h 1.0 h 10 h

Isopropylcumyl hydroperoxide [26762-93-6] 194.3 8.24 183 154 129 2.25E+12 131.44

TRIGONOX M-55

CH3 CH

CH3

OHO

CH3

CH3

C

55 4.53 solution in diisopropylbenzene 30 -25 70 3109 HDPE can

Cumyl hydroperoxide [80-15-9] 152.2 10.51 195 166 140 1.15E+12 132.56

TRIGONOX K-90

OHO

CH3

CH3

C

90 9.46 solution in aromatic

solvent mixture

40 -30 70 3109 HDPE can / steel drum

tert-Butyl hydroperoxide [75-91-2] 90.1 17.75 207 185 164 3.18E+17 186.01

TRIGONOX A-80

TRIGONOX A-W70

OHO

CH3

CH3

CH3 C

80

70

14.20*

12.43

solution in water and DTBP *

solution in water

40

35

0

0

90

80

55

3103

3109

3109

HDPE can

HDPE can / HDPE drum

steel IBC

tert-Amyl hydroperoxide [3425-61-4] 104.1 15.36 228 190 153

TRIGONOX TAHP-W85

O

CH3

CH3

C2H5 C OH

85 13.06 solution in water 30 80 3107 HDPE can / HDPE drum

2,3-Dimethyl-2,3-diphenylbutane [1889-67-4] 238.4 284 259 237 7.34E+18 230.19

PERKADOX 30 CH3

CH3

C

CH3

CH3

C

95 fl akes 30 carton / fi ber drum

1,1,3,3-Tetramethylbutyl hydroperoxide [5809-08-5] 146.2 10.94 180 159 140 1.90E+18 181.99

TRIGONOX TMBH-L

CH3 CH2 OHO

CH3

CH3

C

CH3

CH3

C

90 9.85 liquid 20 0 60 3105 HDPE can

* Contains 12.5% Di-tert-butyl peroxide (DTBP), total act. O 15.57%

Page 15: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

28

Product surveyAll products are listed below by type of initiator and in alphabetical order with their main areas of application.

Product name Acrylics LDPE CR-PP PVC Styrenics Page Product name Acrylics LDPE CR-PP PVC Styrenics Page

29

Product name Acrylics LDPE CR-PP PVC Styrenics Page Product name Acrylics LDPE CR-PP PVC Styrenics Page

Azo initiators

PERKADOX AIBN ✓ ✓ 16

PERKADOX AMBN-GR ✓ ✓ 16

PERKADOX ACCN ✓ ✓ 18

C-C initiator

PERKADOX 30 ✓ 26

Cyclic peroxides

TRIGONOX 301 ✓ ✓ ✓ ✓ 24

TRIGONOX 301-25PP ✓ 24

Diacyl peroxides

LAUROX ✓ ✓ ✓ 16

LAUROX S ✓ ✓ ✓ 16

LAUROX W-40 ✓ ✓ 16

LAUROX W-25 ✓ ✓ 16

PERKADOX L-W75 ✓ ✓ 18

PERKADOX L-W40 ✓ ✓ 18

PERKADOX L-DFG 18

PERKADOX API 18

PERKADOX SE-10 ✓ ✓ 16

TRIGONOX 187-C30 ✓ 10

TRIGONOX 187-W26 ✓ 10

TRIGONOX 36-C37.5 ✓ ✓ 14

TRIGONOX 36-C75 ✓ ✓ ✓ 14

TRIGONOX 36-W50 ✓ 14

Dialkyl peroxides

PERKADOX 14 ✓ ✓ 24

PERKADOX 14S-FL ✓ ✓ 24

PERKADOX BC-FF ✓ ✓ 22

TRIGONOX 101 ✓ ✓ ✓ ✓ 24

TRIGONOX 101-50D-PD ✓ 24

TRIGONOX 101-20PP ✓ 24

TRIGONOX 101-7.5PP-PD ✓ 24

TRIGONOX 101-E30 ✓ 24

TRIGONOX 145-E85 ✓ ✓ ✓ 24

TRIGONOX 201 ✓ ✓ 22

TRIGONOX B ✓ ✓ ✓ 24

TRIGONOX B-C30 ✓ 24

TRIGONOX B-C50 ✓ 24

TRIGONOX T ✓ ✓ ✓ 24

Hydroperoxides

TRIGONOX A-80 ✓ ✓ 26

TRIGONOX A-W70 ✓ ✓ ✓ 26

TRIGONOX K-90 ✓ ✓ 26

TRIGONOX M-55 ✓ ✓ 26

TRIGONOX TAHP-W85 ✓ ✓ 26

TRIGONOX TMBH-L ✓ ✓ 26

Peroxycarbonates

TRIGONOX 117 ✓ ✓ ✓ 20

TRIGONOX 131 ✓ ✓ ✓ 20

TRIGONOX BPIC-C75 ✓ ✓ ✓ 20

Peroxydicarbonates

PERKADOX 16 ✓ ✓ ✓ 12

PERKADOX 16S ✓ 12

PERKADOX 16-W40 ✓ 12

PERKADOX 16-W75 ✓ ✓ ✓ 12

PERKADOX 24-FL ✓ ✓ 14

PERKADOX 24L ✓ 14

PERKADOX 24-W33 ✓ 14

PERKADOX 26 ✓ ✓ 14

PERKADOX 26-W40 ✓ 14

PERKADOX IPP-NS27 12

TRIGONOX 181 ✓ 10

TRIGONOX ADC 12

TRIGONOX ADC-NS60 12

TRIGONOX EHP ✓ ✓ ✓ 12

TRIGONOX EHP-C75 ✓ ✓ ✓ 12

TRIGONOX EHPS ✓ ✓ 12

TRIGONOX EHPS-C75 ✓ ✓ 12

TRIGONOX EHP-W40S ✓ 12

TRIGONOX EHP-W60 ✓ 12

TRIGONOX SBP ✓ 12

TRIGONOX SBP-C60 ✓ ✓ 12

TRIGONOX SBPS ✓ 12

TRIGONOX SBPS-C60 ✓ 12

Peroxyesters

TRIGONOX 121 ✓ ✓ ✓ 16

TRIGONOX 121-C75 ✓ ✓ ✓ 16

TRIGONOX 123-C75 ✓ ✓ 10

TRIGONOX 125-C75 ✓ ✓ ✓ 14

TRIGONOX 127 ✓ ✓ 22

TRIGONOX 133-CK60 ✓ ✓ 20

TRIGONOX 141 ✓ ✓ ✓ 16

TRIGONOX 197-C75 ✓ 10

TRIGONOX 21-C30 ✓ 18

TRIGONOX 21-C70 ✓ ✓ ✓ 18

TRIGONOX 21S ✓ ✓ ✓ 18

TRIGONOX 23 ✓ ✓ ✓ 12

TRIGONOX 23-C30 ✓ 12

TRIGONOX 23-C75 ✓ ✓ 12

TRIGONOX 23-W50 ✓ 12

TRIGONOX 257-C75 ✓ ✓ 14

TRIGONOX 25-C25 ✓ 14

TRIGONOX 25-C75 ✓ ✓ ✓ 14

TRIGONOX 27 ✓ ✓ ✓ 18

TRIGONOX 41-C50 ✓ ✓ ✓ 18

TRIGONOX 421 ✓ ✓ ✓ 16

TRIGONOX 423-C70 ✓ ✓ 10

TRIGONOX 423-W50 ✓ 10

TRIGONOX 425-C75 ✓ 14

TRIGONOX 42-C30 ✓ 20

TRIGONOX 42S ✓ ✓ ✓ 20

TRIGONOX 99-C75 ✓ ✓ 10

TRIGONOX 99-W50 ✓ 10

TRIGONOX C ✓ ✓ ✓ 22

TRIGONOX C-C75 ✓ ✓ ✓ 22

TRIGONOX F-CE30 ✓ 22

TRIGONOX F-C50 ✓ ✓ ✓ 22

Peroxyketals

TRIGONOX 17 ✓ 22

TRIGONOX 122-C80 ✓ ✓ ✓ 18

TRIGONOX 22-B50 ✓ ✓ ✓ 20

TRIGONOX 22-C80 ✓ ✓ ✓ 20

TRIGONOX 22-E50 ✓ ✓ ✓ 20

TRIGONOX 29 ✓ ✓ ✓ 18

TRIGONOX 29-B90 ✓ ✓ ✓ 18

TRIGONOX 29-C75 ✓ ✓ ✓ 18

TRIGONOX D-C50 ✓ ✓ ✓ 20

TRIGONOX D-E50 ✓ ✓ ✓ 20

Page 16: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

30

Half-life chart

1

10

0.1

20 40 6030 50 70 90 110 130 150 170 190 210 230 250 270 290 30080 100 120 140 160 180 200 220 240 260 280

1 7

121213141415

383839394040

4141

856

31 37

4343

3232343435

9101011

1616 17 1818 24241919 2020 23232121 33 4545 57

2222

3030 3636

42425554542525 4444 5151

48484949

2626 2929 4747

2727

2828 4646 5352525050 565632 4

Initiators for High Polymers

31

chemical nameproduct name

TRIGONOX 187 Diisobutyryl peroxide

TRIGONOX 99 Cumyl peroxyneodecanoate

TRIGONOX 423 1,1,3,3-Tetramethylbutyl peroxyneodecanoate

TRIGONOX 197 Cumyl peroxyneoheptanoate

TRIGONOX 181 Di(3-methoxybutyl) peroxydicarbonate

TRIGONOX 123 tert-Amyl peroxyneodecanoate

TRIGONOX ADC Mixture of peroxydicarbonates

TRIGONOX 23 tert-Butyl peroxyneodecanoate

TRIGONOX SBP Di-sec-butyl peroxydicarbonate

PERKADOX IPP Diisopropyl peroxydicarbonate

TRIGONOX EHP Di(2-ethylhexyl) peroxydicarbonate

PERKADOX 16 Di(4-tert-butylcyclohexyl) peroxydicarbonate

PERKADOX 24 Dicetyl peroxydicarbonate

PERKADOX 26 Dimyristyl peroxydicarbonate

TRIGONOX 425 1,1,3,3-Tetramethylbutyl peroxypivalate

TRIGONOX 257 tert-Butyl peroxyneoheptanoate

TRIGONOX 125 tert-Amyl peroxypivalate

TRIGONOX 25 tert-Butyl peroxypivalate

TRIGONOX 36 Di(3,5,5-trimethylhexanoyl) peroxide

LAUROX Dilauroyl peroxide

PERKADOX SE-10 Didecanoyl peroxide

PERKADOX AIBN 2,2'-Azodi(isobutyronitrile)

PERKADOX AMBN 2,2'-Azodi(2-methylbutyronitrile)

TRIGONOX 141 2,5-Dimethyl-2,5-di(2-ethylhexanoylperoxy)hexane

TRIGONOX 421 1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoate

PERKADOX L Dibenzoyl peroxide

TRIGONOX 21 tert-Butyl peroxy-2-ethylhexanoate

TRIGONOX 121 tert-Amyl peroxy-2-ethylhexanoate

TRIGONOX 27 tert-Butyl peroxydiethylacetate

TRIGONOX 41 tert-Butyl peroxyisobutyrate

PERKADOX ACCN 1,1'-Azodi(hexahydrobenzonitrile)

TRIGONOX 29 1,1-Di(tert-butylperoxy)-3,3,5-trimethylcyclohexane

TRIGONOX 122 1,1-Di(tert-amylperoxy)cyclohexane

TRIGONOX 22 1,1-Di(tert-butylperoxy)cyclohexane

TRIGONOX 42 tert-Butyl peroxy-3,5,5-trimethylhexanoate

TRIGONOX 131 tert-Amylperoxy 2-ethylhexyl carbonate

TRIGONOX 133 tert-Amyl peroxyacetate

TRIGONOX D 2,2-Di(tert-butylperoxy)butane

TRIGONOX BPIC tert-Butylperoxy isopropyl carbonate

TRIGONOX 117 tert-Butylperoxy 2-ethylhexyl carbonate

TRIGONOX 127 tert-Amyl peroxybenzoate

TRIGONOX F tert-Butyl peroxyacetate

TRIGONOX 17 Butyl 4,4-di(tert-butylperoxy)valerate

TRIGONOX C tert-Butyl peroxybenzoate

TRIGONOX 201 Di-tert-amyl peroxide

PERKADOX BC Dicumyl peroxide

PERKADOX 14 Di(tert-butylperoxyisopropyl)benzene

TRIGONOX 101 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane

TRIGONOX T tert-Butyl cumyl peroxide

TRIGONOX 145 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3

TRIGONOX B Di-tert-butyl peroxide

TRIGONOX 301 3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane

TRIGONOX M Isopropylcumyl hydroperoxide

TRIGONOX TMBH 1,1,3,3-Tetramethylbutyl hydoperoxide

TRIGONOX K Cumyl hydroperoxide

TRIGONOX TAHP TRIGONOX TAHP TRIGONOX T tert-Amyl hydroperoxide

TRIGONOX A tert-Butyl hydroperoxide

PERKADOX 30 2,3-Dimethyl-2,3-diphenylbutane

1

10

0.1

20 40 6030 50 70 90 110 130 150 170 190 210 230 250 270 290 30080 100 120 140 160 180 200 220 240 260 280

1

2

3

4

5

6

7

8

9

1010

11

1212

13

1414

15

1616

17

1818

1919

2020

2121

2222

2323

2424

2525

2626

2727

2828

2929

3030

31

3232

33

3434

35

3636

37

3838

3939

4040

4141

4242

4343

4444

4545

4646

4747

4848

4949

5050

51

5252

53

5454

55

5656

57

5858

5858

Page 17: Introduction Initiators - neochemical.kzneochemical.kz/File/Akzo_Data_110407-Initiators_for_High_Polymers.pdf · Introduction Initiators Initiators for high polymers for High Polymers

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